MATERIAL SAFETY DATA SHEET 1. Product and Company

MATERIAL SAFETY DATA SHEET
.
1. Product and Company Identification
space
Carpet Spot and Stain Remover
Product Name
space
235609/90-106D
Carpet cleaner
Code
space
Product use
space
Wood Wyant Inc.
42, rue de l'Artisan
Victoriaville, Québec G6P 7E3
Phone Number for Information: 1-800-361-7691
Emergency Phone: CANUTEC 1-613-996-6666
International Emergency Phone: 1-613-996-6666
Manufacturer
space
LEGEND
HMIS
Severe
Serious
Moderate
Slight
Minimal
/
Health
4
3
2
1
0
1
Flammability
0
Physical Hazard
0
Personal Protection
A
.
2. Hazards Identification
space
DANGER
EYE AND SKIN IRRITANT.
Contents under pressure. Containers may explode when heated.
Emergency overview
space
Potential short term health effects
Routes of exposure
Eye, Skin contact, Skin absorption, Inhalation, Ingestion.
space
Eyes
Causes irritation.
Skin
May cause irritation. May be absorbed through the skin.
space
NIOSH - Pocket Guide - Skin Notations
Ethylene glycol monobutyl ether
111-76-2
Potential for dermal absorption
space
Excessive intentional inhalation may cause respiratory tract irritation and central
nervous system effects (headache, dizziness).
Not a normal route of exposure. May cause stomach distress, nausea or vomiting.
Inhalation
space
Ingestion
space
Blood. Eyes. Kidney. Liver. Respiratory system. Skin.
Target organs
space
Prolonged or repeated exposure can cause drying, defatting and dermatitis.
Chronic effects
space
Symptoms may include redness, edema, drying, defatting and cracking of the skin.
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting.
Signs and symptoms
.
3. Composition / Information on Ingredients
space
Ingredient(s)
CAS #
Percent
Ethylene glycol monobutyl ether
111-76-2
7 - 13
Isobutane
75-28-5
3-7
Isopropanol
67-63-0
1-5
Propane
74-98-6
1-5
.
4. First Aid Measures
space
First aid procedures
Eye contact
space
Skin contact
#8863
Immediately flush with cool water. Remove contact lenses, if applicable, and continue
flushing for 15 minutes. Obtain medical attention immediately.
Flush with cool water. Wash with soap and water. Obtain medical attention if irritation
persists.
Page 1 of 7
Issue date
22-Mar-2007
space
Inhalation
space
Ingestion
space
Notes to physician
If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical
attention. If breathing has stopped, trained personnel should administer CPR
immediately.
Do not induce vomiting. Rinse mouth with water, then drink one or two glasses of water.
Obtain medical attention. Never give anything by mouth if victim is unconscious, or is
convulsing.
Symptoms may be delayed.
space
General advice
If you feel unwell, seek medical advice (show the label where possible). Ensure that
medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance.
.
5. Fire Fighting Measures
space
Flammable properties
Non-flammable aerosol by flame projection test.
space
Extinguishing media
Suitable extinguishing media
Carbon dioxide. Dry chemical. Foam. Fog. Water spray.
space
Unsuitable extinguishing media Not available
space
Protection of firefighters
Specific hazards arising from
the chemical
Contents under pressure. Pressurized container may explode when exposed to heat or
flame. Cool containers with flooding quantities of water until well after fire is out.
space
Protective equipment for
firefighters
Firefighters should wear full protective clothing including self contained breathing
apparatus.
space
Hazardous combustion products
May include and are not limited to: Oxides of carbon.
space
Explosion data
Sensitivity to mechanical
impact
Not available
space
Sensitivity to static discharge
Not available
.
6. Accidental Release Measures
space
Personal precautions
space
Methods for containment
space
Methods for cleaning up
Keep unnecessary personnel away. Do not touch or walk through spilled material. Do
not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Keep people away from and upwind of spill/leak.
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Stop leak if you can do so without risk. Prevent entry into waterways, sewers,
basements or confined areas.
Before attempting clean up, refer to hazard data given above. Remove sources of
ignition. Although the chance of a significant spill or leak is unlikely in aerosol
containers, in the event of such an occurrence, absorb spilled material with a
non-flammable absorbent such as sand or vermiculite.
.
7. Handling and Storage
space
Handling
Use good industrial hygiene practices in handling this material.
space
Storage
#8863
Keep out of reach of children. Do not store at temperatures above 49 °C. Keep away
from heat, open flames or other sources of ignition.
Page 2 of 7
Issue date
22-Mar-2007
.
8. Exposure Controls / Personal Protection
space
Exposure limits
Ingredient(s)
Exposure Limits
Ethylene glycol monobutyl ether
ACGIH-TLV
TWA: 20 ppm
OSHA-PEL
TWA: 50 ppm
Isobutane
ACGIH-TLV
TWA: 1000 ppm
OSHA-PEL
Not established
Isopropanol
ACGIH-TLV
TWA: 200 ppm
STEL: 400 ppm
OSHA-PEL
TWA: 400 ppm
Propane
ACGIH-TLV
TWA: 1000 ppm
OSHA-PEL
TWA: 1000 ppm
space
General ventilation normally adequate.
Engineering controls
space
Personal protective equipment
Eye / face protection
Wear safety glasses with side shields.
space
Hand protection
Not normally required when used as directed.
Skin and body protection
As required by employer code.
space
space
Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.
Avoid breathing mists or vapors.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do
not eat or drink. Wash hands and face before breaks and immediately after handling the
product.
Respiratory protection
space
.
9. Physical & Chemical Properties
space
Appearance
Aerosol.
space
Color
Hazy Colorless
space
Form
foam
space
Odor
Ethereal / Citrus.
space
Odor threshold
Not available
space
Physical state
Gas
space
pH
9.4 ± 1.0
space
Melting point
Not available
space
Freezing point
Not available
space
Boiling point
> 100 °C (> 212.00 °F)
space
Flash point
Not available
space
Evaporation rate
>1
space
Flammability limits in air, lower, %
by volume
Not available
space
Flammability limits in air, upper, %
by volume
Not available
space
Vapor pressure
481 - 550 kPa
space
Vapor density
Not available
space
Specific gravity
#8863
0.99 (Concentrate)
Page 3 of 7
Issue date
22-Mar-2007
space
Not available
Octanol/water coefficient
space
Complete
Solubility (H2O)
space
Not available
Auto-ignition temperature
space
166 g/L
VOC (Weight %)
space
Not available
Viscosity
space
Not available
Percent volatile
.
10. Chemical Stability & Reactivity Information
space
Stable under recommended storage conditions.
Chemical stability
space
Aerosol containers are unstable at temperatures above 49°C. Do not mix with other
chemicals.
Caustics. Acids. Strong oxidizing agents. Chlorine.
Conditions to avoid
space
Incompatible materials
space
Hazardous decomposition products May include and are not limited to: Oxides of carbon.
Will not occur.
Possibility of hazardous reactions
space
.
11. Toxicological Information
space
Component analysis - LC50
Ingredient(s)
LC50
Ethylene glycol monobutyl ether
2.21 mg/l/4h rat
Isobutane
658 mg/l/4h rat
Isopropanol
72.6 ppm rat; 72.6 mg/l/4h rat
Propane
Not available
space
Component analysis - Oral LD50
Ingredient(s)
LD50
Ethylene glycol monobutyl ether
470 mg/kg rat; 320 mg/kg rabbit
Isobutane
Not available
Isopropanol
4396 mg/kg rat
Propane
Not available
space
Effects of acute exposure
Eye
Causes irritation.
space
May cause irritation. May be absorbed through the skin.
Skin
NIOSH - Pocket Guide - Skin Notations
Ethylene glycol monobutyl ether
111-76-2
Potential for dermal absorption
space
Inhalation
space
Ingestion
Excessive intentional inhalation may cause respiratory tract irritation and central
nervous system effects (headache, dizziness).
Not a normal route of exposure. May cause stomach distress, nausea or vomiting.
space
Sensitization
Non-hazardous by WHMIS/OSHA criteria.
space
Chronic effects
Non-hazardous by WHMIS/OSHA criteria.
space
Carcinogenicity
Non-hazardous by WHMIS/OSHA criteria.
ACGIH - Threshold Limits Values - Carcinogens
Ethylene glycol monobutyl ether
111-76-2
Isopropanol
67-63-0
IARC - Group 3 (Not Classifiable)
A3 - Confirmed animal carcinogen with unknown relevance to humans
A4 - Not Classifiable as a Human Carcinogen
Ethylene glycol monobutyl ether
Isopropanol
Monograph 88 in preparation
Monograph 71 [1999], Supplement 7 [1987], Monograph 15 [1977]
111-76-2
67-63-0
space
Mutagenicity
Non-hazardous by WHMIS/OSHA criteria.
space
Reproductive effects
Non-hazardous by WHMIS/OSHA criteria.
space
Teratogenicity
#8863
Non-hazardous by WHMIS/OSHA criteria.
Page 4 of 7
Issue date
22-Mar-2007
.
12. Ecological Information
space
Components of this product have been identified as having potential environmental
concerns.
Ecotoxicity
Ecotoxicity - Freshwater Algae Data
Isopropanol
67-63-0
96 Hr EC50 Scenedesmus subspicatus: >1000 mg/L; 72 Hr EC50 Scenedesmus
subspicatus: >1000 mg/L
Ecotoxicity - Freshwater Fish Species Data
Ethylene glycol monobutyl ether
Isopropanol
111-76-2
67-63-0
96 Hr LC50 Lepomis macrochirus: 1490 mg/L [static]
96 Hr LC50 Pimephales promelas: 9640 mg/L [flow-through]; 96 Hr LC50 Pimephales
promelas: 94900 mg/L [flow-through] (29 days old); 96 Hr LC50 Pimephales promelas:
61200 mg/L [flow-through] (31 days old)
Isopropanol
Ecotoxicity - Water Flea Data
67-63-0
5 Min EC50 Photobacterium phosphoreum: 35390 mg/L
Ethylene glycol monobutyl ether
Isopropanol
111-76-2
67-63-0
24 Hr EC50 water flea: 1720 mg/L; 24 Hr LC50 Daphnia magna: 1698-1940 mg/L
48 Hr EC50 Daphnia magna: 13299 mg/L
Ecotoxicity - Microtox Data
space
Environmental effects
Not available
space
Aquatic toxicity
Not available
space
Persistence / degradability
Not available
space
Bioaccumulation / accumulation
Not available
space
Partition coefficient
Not available
space
Mobility in environmental media
Not available
space
Chemical fate information
Not available
.
13. Disposal Considerations
space
Waste codes
Not available
space
Disposal instructions
Dispose in accordance with all applicable regulations.
space
Waste from residues / unused
products
Not available
space
Contaminated packaging
Not available
.
14. Transport Information
space
Department of Transportation (DOT)
Basic shipping requirements:
Proper shipping name
Aerosols, non-flammable
Hazard class
2.2
UN number
UN1950
Additional information:
Packaging exceptions
<1L - Consumer Commodity ORM-D
ERG number
126
#8863
Page 5 of 7
Issue date
22-Mar-2007
space
Transportation of Dangerous Goods (TDG)
Basic shipping requirements:
Proper shipping name
AEROSOLS, non-flammable
Hazard class
2.2
UN number
UN1950
Additional information:
Special provisions
80
Packaging exceptions
<1L - Consumer Commodity
.
15. Regulatory Information
space
Canadian federal regulations
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
Canada - WHMIS - Ingredient Disclosure List
Ethylene glycol monobutyl ether
Isopropanol
111-76-2
67-63-0
1%
1%
space
US Federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities
Ethylene glycol monobutyl ether
111-76-2
1 Lb statutory RQ (no final RQ is being assigned to the generic or broad class. Includes
mono- and di- ethers of ethylene glycol, diethylene glycol and triethylene glycol
R-(OCH2CH2)n-OR'' where n = 1, 2 or 3, R = alkyl or aryl groups, R'' = R h or groups
which when removed yield glycol ethers with the structure R-(OCH2CH2)n-OH. Polymers
are excluded from glycol category); 0.454 k
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
Ethylene glycol monobutyl ether
111-76-2
Isopropanol
67-63-0
1.0 Percent de minimis concentration (applies to R-(OCH2CH2)n-OR' ethers, where n =
1,2, or 3, R=alkyl C7 or less or R = phenyl or alkyl subst. phenyl, R' = H or alkyl C7 or
less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate,
Chemical Category N230)
1.0 % de minimis concentration (only if manufactured by the strong acid process, no
supplier notification)
space
Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
space
CERCLA (Superfund) reportable quantity
Sulphuric acid: 1000.0000
space
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - Yes
Reactivity Hazard - No
No
Section 302 extremely
hazardous substance
Section 311 hazardous chemical Yes
space
space
space
Clean Air Act (CAA)
Not available
space
Clean Water Act (CWA)
Not available
space
Safe Drinking Water Act (SDWA)
Not available
space
Drug Enforcement Agency (DEA)
Not available
space
Food and Drug Administration
(FDA)
Not available
space
WHMIS status
Controlled
space
WHMIS classification
#8863
Class A - Compressed Gas, Class D - Division 2B
Page 6 of 7
Issue date
22-Mar-2007
space
WHMIS labeling
space
State regulations
This product does not contain a chemical known to the State of California to cause
cancer, birth defects or other reproductive harm.
U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances
Ethylene glycol monobutyl ether
111-76-2
Isopropanol
67-63-0
U.S. - Illinois - Toxic Air Contaminants
Present
Present
Ethylene glycol monobutyl ether
111-76-2
Present
U.S. - Louisiana - Reportable Quantity List for Pollutants
Ethylene glycol monobutyl ether
111-76-2
U.S. - Massachusetts - Right To Know List
100 Lb RQ
Ethylene glycol monobutyl ether
111-76-2
Isobutane
75-28-5
Isopropanol
67-63-0
Propane
74-98-6
U.S. - Minnesota - Hazardous Substance List
Present
Present
Present
Present
Ethylene glycol monobutyl ether
111-76-2
Skin
Isopropanol
67-63-0
Present
Propane
74-98-6
Simple asphyxiant
U.S. - New Jersey - Right to Know Hazardous Substance List
Ethylene glycol monobutyl ether
111-76-2
Isobutane
75-28-5
Isopropanol
67-63-0
Propane
74-98-6
U.S. - Pennsylvania - RTK (Right to Know) List
sn 0275
sn 1040
sn 1076; sn 2381 (strong-acid process manufacture)
sn 1594
Ethylene glycol monobutyl ether
111-76-2
Isobutane
75-28-5
Isopropanol
67-63-0
Propane
74-98-6
U.S. - Rhode Island - Hazardous Substance List
Present
Present
Environmental hazard
Present
Ethylene glycol monobutyl ether
Isopropanol
Propane
Toxic
Toxic; Flammable
Toxic; Flammable
111-76-2
67-63-0
74-98-6
space
Inventory name
Country(s) or region
Canada
Canada
United States & Puerto Rico
Inventory name
Domestic Substances List (DSL)
Non-Domestic Substances List (NDSL)
Toxic Substances Control Act (TSCA) Inventory
On inventory (yes/no)*
Yes
No
Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
.
16. Other Information
space
Disclaimer
space
Issue date
Information contained herein was obtained from sources considered technically accurate
and reliable. While every effort has been made to ensure full disclosure of product
hazards, in some cases data is not available and is so stated. Since conditions of actual
product use are beyond control of the supplier, it is assumed that users of this material
have been fully trained according to the requirements of all applicable legislation and
regulatory instruments. No warranty, expressed or implied, is made and supplier will not
be liable for any losses, injuries or consequential damages which may result from the
use of or reliance on any information contained in this document.
22-Mar-2007
space
Effective date
15-Mar-2007
space
Expiry date
15-Mar-2010
space
Prepared by
#8863
Technical Services
Page 7 of 7
Issue date
22-Mar-2007