2010 Program Book

Transcription

2010 Program Book
PLEN/01-ANYL
PLEN
Plenary Lecture
Wednesday Evening
Sheraton Waikiki
Ballrooms
Pacifichem 2010 Plenary Lecture
19:00 – 1. Catching electrons with light.
Paul Corkum
ANYL
Area 1 – Analytical
Wednesday Morning
Convention Center
301A
Analytical and Environmental Chemistry in
Human Health (#206)
Organized by: X.C. Le, G. Jiang, X. Li,
S. Richardson, L. Zhu
Presiding: M. Bartlett, M. Siu
7:30 – 1. Applying analytical chemistry to impact public health decisions by quantify
biomarkers of exposure to perchlorate
and trihalomethanes. Ben Blount*,
Liza Valentin-Blasini, Lalith Silva,
David Ashley
7:50 – 2. Methods and techniques development for emerging chemicals analysis.
Yawei Wang, Guibin Jiang*
8:10 – 3. Formation of highly toxic iodoDBPs in drinking water.
Susan D. Richardson*,
Stephen E. Duirk, Cristal Lindell,
Christopher C. Cornelison,
Thomas A. Ternes, Jennifer L. Kormos,
Michael J. Plewa, Emmamarie Smith,
William A. Mitch
8:30 – 4. Formation and occurrence of
emerging disinfection by-products of human health concern: Western Australian
perspectives. Ina Kristiana*,
Bradley Allpike, Jace Tan,
Sebastién Allard, Suzanne McDonald,
Rino Trolio, Arron Lethorn, Cynthia Joll,
Anna Heitz
8:50 – 5. Effect of galvanized pipe to haloacetic acids transformation in drinking water. Wei Wang, Lizhong Zhu*
9:10 – 6. Biomarkers for exposure and neurotoxic effects of methylmercury.
Laurie H. Chan*
9:30 – 7. Biomonitoring of children’s exposure to arsenic from playgrounds: Speciation of arsenic in urine and saliva.
Kristi Lew, Xiufen Lu, Baowei Chen,
Chris X. Le*
9:50 – 8. Isotopes in environmental health
research. Jun Yoshinaga*
10:10 – 9. Persistent organic pollutants in
the Great Lakes. Ian D. Brindle*,
Paul Helm, Christopher H. Marvin,
Eric Reiner, Li Shen, Simon Zhang,
Sarah Gewurtz,
Rosalie Zielinski-Lawrence,
Satyendra Bhavsar
10:30 – 10. Levels and trends of cyclic volatile methyl silicones in air samples from
across Canada. Mehran Alaee*,
Helena Steer
10:50 – 11. Remote sources over the North
Atlantic Ocean: Visualization of three surrounding continents.
Maria do Carmo M. Freitas*,
Isabel Dionisio, Adriano M. Pacheco
52–TECH
TECHNICAL PROGRAM
Convention Center
317A
Convention Center
301B
Non- and Minimally-Invasive Diagnostics of
Biological Systems using Vibrational
Spectroscopy (#276)
Rapid, Multi-Component Environmental
Analysis (#253)
Organized by: M.W. Blades, M. Michael,
H. Sato
Presiding: M. Blades
7:30 – 12. Advanced Raman spectroscopy in
biomedicine. Juergen Popp*
8:00 – 13. Raman spectroscopy for in vivo
cancer detection and characterization at
the macro- and microscopic levels.
Haishan Zeng, Jianhua Zhao,
Michael Short, Hequn Wang,
David I. McLean, Stephen Lam,
Annette McWilliams, Harvey Lui
8:30 – 14. Biospectroscopy for clinical assessments: Metabolomic profiling from
womb to tomb. David Burns*
9:00 – 15. Monitoring dynamics of individual
cells using laser tweezers Raman spectroscopy. James W. Chan*,
Tobias J. Moritz, Christopher R. Polage,
Douglas S. Taylor, Denise M. Krol,
Stephen M. Lane
9:30 – 16. Dental caries assessment with
OCT and polarized Raman spectroscopy.
Lin-P’ing Choo-Smith*, Mark Hewko,
Michael Sowa
10:00 – 17. Raman microscopy for imaging
molecular dynamics of living cells.
Katsumasa Fujita*
10:30 – 18. Bio-Raman spectroscopy: Diseases diagnosis and nanoparticles based
imaging. Jiming Hu*
11:00 – 19. Nanoparticle-enhanced imaging
and spectroscopy of biological samples
by nonlinear optical microscopy.
Thomas Huser*, Tyler Weeks
Convention Center
323C
New Frontiers in Separation Science (#113)
Organized by: T. Okada, P. Haddad,
M. Porter
Presiding: T. Okada, Y. Feng, C. Lucy,
P. Haddad
Organized by: R. Clement, F. Dorman,
N. Yamashita
Presiding: R. Clement
8:00 introductory remarks
8:05 – 29. Patterns of multicomponent persistent and non-persistent chemicals in
human biomonitoring studies.
Donald G. Patterson
8:45 – 30. Bioaccessibility of lead and arsenic in traditional Indian medicines.
Iris Koch, Maeve Moriarty,
Kenneth J. Reimer*, William R. Cullen,
Robert Saper
9:05 – 31. Increasing the speed of chromatographic separations without a loss in resolution: The role of selectivity and efficiency in GC and LC separations.
Frank Dorman*, Roy Lautamo,
Shawn Reese, Jack Cochran,
Paul Schettler, Mike Wittrig
9:45 – 32. Development of an analytical
method for occupational exposure assessment to pesticides in human hair by
GCxGC/TOF MS. John Dimandja*,
Charlotte Smith-Baker,
Mahmoud A. Saleh
10:05 – 33. Advanced gas chromatographic
analysis of pesticide residues.
Philip J. Marriott*, Erwan Engel,
Paul Morrison
10:25 – 34. Analysis of veterinary antibiotics
in environmental samples using a high
temperature-high efficiency HPLC
method. Heba Shaaban,
Tadeusz Gorecki*
10:45 – 35. Needle trap devices for on-site
and laboratory. Janusz Pawliszyn*
11:05 – 36. Simultaneous determination of
1,4-dioxane and formaldehyde in water
by solid phase microextraction gas chromatography-time-of-flight mass spectrometry. Hyun-Mee Park*,
Warnadi Dirwono, Ki-Soo Lee,
Kang-Bong Lee, Dong Ju Moon,
Yang Ha Cho, Yeon Hee Lee
Wednesday Afternoon
7:50 Opening remarks
7:55 – 20. New approaches to on-line sample enrichment in capillary electrophoresis. Paul Haddad*, Joselito Quirino,
Michael Breadmore, Mohamed Dawod,
Rosanne Guijt
8:25 – 21. Rapid and sensitive analysis
based on transient trapping in capillary
electrophoresis. Kenji Sueyoshi*,
Kota Hashiba, Ryuta Tanaka,
Fumihiko Kitagawa, Koji Otsuka
8:45 – 22. Advances in small particle ion
chromatography. Charles A. Lucy,
Stuart D. Chambers, M. F. Wahab,
Wei Sun, Chris Pohl
9:05 – 23. Electronic-structure simulation
study on ion adsorption and selectivity in
organic polymer resins.
Manabu Sugimoto*, Ryu Hirano
9:25 – 24. Ice chromatographic characterization of salt-doped ice. Yuiko Tasaki,
Tetsuo Okada
9:45 – 25. In-tube solid-phase microextraction based on hybrid silica monolith coupled to liquid chromatography-mass
spectrometry for fully automated analysis
of ten antidepressants in human urine
and plasma. Yu-Qi Feng*
10:05 – 26. Molecular migration on stationary phase surface in reversed-phase liquid chromatography. Kanji Miyabe
10:25 – 27. Detection and quantification of
water structuring and functioning as a
separation medium in solvation shells on
hydrophobic surfaces by liquid chromatography. Masami Shibukawa*,
Yoshiki Kondo, Keita Osuga,
Yawara Ogiyama, Shingo Saito
10:55 – 28. Electrochemically modulated liquid chromatography: An electrochemical
strategy to manipulation of chromatographic retention. Marc Porter*
Convention Center
323C
New Frontiers in Separation Science (#113)
Organized by: T. Okada, P. Haddad,
M. Porter
Presiding: D. Chiu, M. Porter, K. Miyabe,
M. Shibukawa
12:30 – 37. Interfacing droplet microfluidics
with chemical separation for cellular analysis. Daniel Chiu*
12:50 – 38. Development of microfluidic
chips for heterogeneous receptor-ligand
interaction studies. Frank A. Gomez
13:10 – 39. Metal-ion correlations in solution
and their impact on solvent extraction.
Lynda Soderholm*, S. Skanthakumar,
Richard E. Wilson
13:30 – 40. Carrier-mediated single drop microextraction in capillary electrophoresis.
Jeongmi Choi, Jihye Kim, Kihwan Choi,
Ahmed Yacine Badjah Hadj Ahmed,
Zeid A. ALOthman, Doo Soo Chung*
13:50 – 41. Preparation of extractant-impregnated porous sheets for high-speed
pre-concentration of trace elements in
environmental samples. Ryo Ishihara,
Shiho Asai, Shinsuke Yamada,
Hideyuki Hirota, Daisuke Umeno,
Kyoichi Saito*
14:10 – 42. Drastic enhancement of chemical reactivity in modified “aqueous” solution with concentrated salts or surface.
Masashi Hojo*, Tetsuya Maeda,
Yuki Uji-yie
14:30 – 43. Competitive adsorption of toluene and n-alkanes on silica: A nonlinear
optical analysis. Keng C. Chou*
14:50 – 44. Kinetic analysis of mass transfer
in porous microparticle systems.
Kiyoharu Nakatani
15:10 – 45. Fast wide-bore hydrodynamic
chromatography and its application to kinetic study. Ryoji Umehara*,
Tetsuo Okada
15:30 – 46. Analytical column characterization for differential magnetic catch and
release separation of magnetic nanoparticles. Jacob S. Beveridge*,
Mary E. Williams*
15:50 – 47. Microfluidic field flow fractionation and SPLITT techniques for nanoparticle and protein characterization and
separation. Bruce Gale*, Himanshu Sant,
Srinivas Merugu, William Johnson
16:20 Closing remarks
Convention Center
305A
Microfluidic and Nanofluidic Devices for
Chemical and Biochemical Experimentation
(#198)
Organized by: H.J. Crabtree, Y. Baba,
S. Jacobsen, J.M. Ramsey
Presiding: H. Crabtree, R. Oleschuk
12:30 – 48. What has cuneiform writing or
landing on the moon in common with microfluidic chips? Andreas Manz*
12:55 – 49. Microstructured fibers in microfluidic systems: Frits, enzymatic microreactors and nanoESI emitters.
Graham Gibson, Lili Mats,
Richard Oleschuk*
13:20 – 50. Microfluidic tools for controlling
and probing cells and tissue.
Elisabeth Verpoorte,
Paul M. van Midwoud, Patty P. Mulder,
Marjolijn T. Merema, Grietje Molema,
Geny M. Groothuis
13:45 – 51. Commercialization of microfluidics: Hope on deliverance.
Holger Becker*
14:10 – 52. Microchannels using a combination of ac and dc fields: Toward analyte
preconcentration and separation.
Brittany Branch, Steven Cramer,
Orlin Velev, Dimiter Petsev*
14:30 – 53. Fabrication of nanochannel in
thermoplastics for single DNA molecules
detection. Rattikan Chantiwas,
Jiahao Wu Wu, Mateusz L. Hupert,
Swathi R. Pullagurla,
Subramanian Balamurugan,
Sunggook Park, Dimitris E. Nikitopoulos,
Michael C. Murphy, Jost Gottert,
Steven A. Soper*
14:50 – 54. Integrated microfluidic devices
for multiplexed analysis and quantitation
of proteins in complex mixtures.
Adam T. Woolley*, Weichun Yang,
Pamela N. Nge, Ming Yu
15:10 – 55. High-efficiency capillary columns: A novel chip-based format.
Wim De Malsche*, Selm De Bruyne,
Jeff Op De Beeck, Frederic Lynen,
Pat Sandra, Han Gardeniers,
Gert Desmet
15:30 – 56. Liquid chromatography in extended-nano space using pressuredriven flow: Toward normal phase separation. Ryo Ishibashi*,
Kazuma Mawatari, Takehiko Kitamori
15:50 – 57. Microfluidic-based temperatureswing separation of multivalent metal
ions using thermoresponsive polymer hydrogel. Takehiko Tsukahara
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
01-ANYL
16:10 – 58. Molecular tracking of proteinDNA interactions under microfluidic control. Daisuke Onoshima*, Noritada Kaji,
Manabu Tokeshi, Yoshinobu Baba
Convention Center
317A
Non- and Minimally-Invasive Diagnostics of
Biological Systems using Vibrational
Spectroscopy (#276)
Organized by: M.W. Blades, M. Michael,
H. Sato
Presiding: M. Blades
12:30 – 59. Evaluation of bone and cartilage
health using noninvasive and minimally
invasive Raman spectroscopy and imaging. Michael D. Morris
13:00 – 60. Spatially offset Raman spectroscopy for subsurface assessment of
breast margins.
Anita Mahadevan-Jansen,
Matthew Keller, Daniel Masters,
Mark Kelley
13:30 – 61. Systems pathology with infrared
spectroscopic imaging. Rohit Bhargava*
14:00 – 62. Optical biopsy: In situ spectroscopy for monitoring unstained tissues
and cells. Hidetoshi Sato*
14:30 – 63. Nonlinear optical imaging and
spectroscopy of the arterial wall.
Michael Sowa, Alex Ko
15:00 – 64. Shedding new light on dark DNA
with FTIR spectroscopy.
Bayden R. Wood*, Peter Lasch,
Heinz Fabian, Dieter Naumann,
Donna Whelan, Keith Bambery,
Philip Heraud, Don McNaughton,
Mark Tobin
15:30 – 65. Development of noninvasive and
mobile FTIR techniques for measurement
of human body metabolism.
Satoshi Yoshida*
16:00 – 66. Raman microscopy for the noninvasive characterization of human embronyic stem cells.
Stanislav O. Konorov, H. Georg Schulze,
James M. Piret, Robin F. Turner*,
Michael W. Blades*
Convention Center
301A
Analytical and Environmental Chemistry in
Human Health (#206)
Organized by: X.C. Le, G. Jiang, X. Li,
S. Richardson, L. Zhu
Presiding: X. Li, L. Zhu
12:50 – 67. Solid-phase nucleic acid hybridization assay in a microfluidic platform
using quantum dots as donors in fluorescence resonance energy transfer.
Ulrich J. Krull*, Lu Chen, W. R. Algar,
Anthony J. Tavares
13:10 – 68. Monolithic capillary columns for
efficient separation of biological samples.
Hanfa Zou, Fangjun Wang, Renan Wu,
Mingliang Ye
13:30 – 69. Affinity purification of organelles
to investigate biotransformations.
Yaohua Wang, Seth Holm, Thane Taylor,
Edgar A. Arriaga*
13:50 – 70. In-line concentration of tobaccospecific N-nitrosamines by cation-selective exhaustive injection-sweeping-micellar electrokinetic chromatography.
Youyou Yang, Honggang Nie, Ning Li,
Jie Liao, Huwei Liu
14:10 – 71. Applications of the capillary isoelectric focusing/whole column imaging
detection for characterization of proteins
and interactions involving proteins.
Janusz Pawliszyn*
14:30 – 72. Investigation of chronic toxicity
of microcystins by metabolomics. Sam Li
14:50 – 73. Loss of collapsin response mediator protein1, as detected by LC-MS/MS
with iTRAQ-labeling, promotes invasion
of human gliomas expressing mutant
EGFRvIII. Leroi V. DeSouza,
Joydeep Mukherjee, Johann Micallef,
M. Zia Karim, Sidney Croul, Abhijit Guha,
K.W. Michael Siu*
15:10 – 74. Simplified diagnosis of MPS III
types A,B,C and D using MS/MS to measure enzyme activity in dried blood-spots.
Brian Wolfe, Tanvir Khaliq, C. R. Scott,
Michael H. Gelb, Frantisek Turecek
15:30 – 75. Mass spectrometric studies of
oxidatively generated DNA lesions.
Yinsheng Wang*
15:50 – 76. Principle “close-contact induced
large fluorescence polarization” and its
applications in protein-DNA binding
study. Hailin Wang, Dapeng Zhang,
Tao Li, Xiaoli Wang, Meiling Lu
16:10 – 77. Formation of non-intermediate
enzyme-substrate complex by a DNAdemethylating enzyme.
Svetlana M. Krylova,
Anna A. Karkhanina, Eleanor Bagg,
Christopher J. Schofield,
Sergey N. Krylov*
Convention Center
301B
Rapid, Multi-Component Environmental
Analysis (#253)
Organized by: R. Clement, F. Dorman,
N. Yamashita
Presiding: R. Clement
13:00 – 78. Advances in the analysis of persistent halogenated organic compounds.
Eric Reiner*, Li Shen, Simon Zhou,
Alina Muscalu, Karen MacPherson,
Adrienne Boden, Tony Chen, Terry Kolic
13:40 – 79. Increasing turnaround time for
EPA method 8270, semivolatile organic
compounds by gas chromatography mass spectrometry, with split injection.
Jack Cochran*, Michelle Misselwitz,
Gary Stidsen
14:00 – 80. Development of antimony(Sb)
analysis method for eco-products.
Sungil Kim*, Eun-mi Shin
14:20 – 81. Metal elements analysis of liquid
using laser-induced breakdown spectroscopy. Zhaoxiang Lin*, Liang Chang,
Linmei Liu, Yelin Liu, Fenlou Sun
14:40 – 82. Monitoring of environmental pollutants using kinetic methods of analysis
as an analytical tool. Surendra Prasad*
15:00 – 83. Application of kinetic catalytic
method for the determination and speciation of selenium in environmental water.
Surendra Prasad*, Vimlesh Chand
15:20 – 84. Measurement of cyanide in patients with inhalation burn injury.
David M. Klein*, Linda Su,
Mark Fountain, Yvonne Pierpoint,
David J. Smith, Wyatt G. Payne*
15:40 – 85. Drinking water exposures to nitrogenous disinfection by-products: Linking analytical chemistry with public health
protection. Jeffrey Charrois*,
Ina Kristiana, Cynthia Joll, Anna Heitz
Thursday Morning
Convention Center
327
Analytical and Environmental Chemistry in
Human Health (#206)
Organized by: X.C. Le, G. Jiang, X. Li,
S. Richardson, L. Zhu
Presiding: S. Richardson, G. Jiang
7:30 – 86. Current bioanalytical challenges in
the toxicology of organophosphates and
pyrethriods. Michael G. Bartlett
7:50 – 87. Cell electronic sensing of chemical cytotoxicity. Xing-Fang Li,
Jessica M. Boyd, Claire Mcguigan,
Birget Moe, Chris Le
8:10 – 88. Development of living cell-based
sensor device to detect cytotoxicity.
Satoshi Migita, Akiyoshi Taniguchi
8:30 – 89. Remotely controlled haloacid
bioremediation using an enzyme-based
hydrogel. Leslie Doleman, Nur Ali,
Yinan Wei, J. Z. Hilt, Sylvia Daunert
8:50 – 90. Arsenic speciation, biomarkers,
and risk assessment. Ken Reimer*,
Iris Koch, Jared Saunders, Mark Button
9:10 – 91. Monitoring of occupational exposure to arsenic in the wafer fabrication of
semiconductor industry.
Yaw-Huei Hwang*, Yeh-Hsin Chen,
Chia-Chin Hsu, Zhih-Young Lee,
I-Chun Lu
9:30 – 92. Arsenic speciation analysis in cell
lines: Evaluation of extraction tools and
solvents. Yong Cai*, Lucy Yehiayan,
Nellymar Membreno, Shannon Matulis,
Lawrence H. Boise
9:50 – 93. Environmental exposure to arsenic: Assessing risks and doses.
Elizabeth T. Snow*, Gemma Williams
10:10 – 94. Dimethylarsinite in urine is a predictor of risk of diabetes associated with
chronic exposure to inorganic arsenic.
Dana Loomis, Luz M. Del Razo,
Gonzalo Garcia-Vargas, Zuzana Drobná,
Miroslav Stýblo*
10:30 – 95. Withdrawn
10:50 – 96. A new analytical method for the
determination of polychlorinated terphenyls (PCTs) in the environment.
Atmanto H. Wibowo*, Muefit Bahadir
11:10 – 97. Organic pollutants in food, human blood, and the environment of Bangladesh. Mohammad Shoeb*,
Nilufar Nahar, Iqbal M. Mamun,
Rausan Zamir
Convention Center
323C
Innovation in Chemical Sensing and
Separation Systems toward Advanced
Chemical Analysis (#39)
Organized by: T. Hayashita,
R. A. Bartsch, H. Kim, N. Iki, A. Tong
Presiding: T. Hayashita, A. Tong, B. Cho,
H. Kim, R. Bartsch
8:00 Introductory remarks
8:10 – 98. Ultrasensitive electrochemiluminescence biosensor based on a novel
multi-labeling strategy. Hua Cui,
Dayong Tian, Chunfeng Duan, Wei Wang
8:30 – 99. Porphyrin-based chiroptical sensors for stereochemical analysis by conventional and fluorescence detected circular dichroism. Nina Berova*
8:50 – 100. DNA probing by cooperative luminous complex formation on the target.
Toshihiro Ihara*, Yusuke Kitamura,
Asuka Uemura, Noriyuki Baba,
Seiichi Nishizawa, Norio Teramae,
Akinori Jyo
9:10 – 101. Label-free fluorescent sensors
base on unmodified DNA containing a vacant site: Applications in functional
DNAs. Yu Xiang, Yi Lu*
9:30 – 102. Detection of cations in live tissues by two-photon microscopy.
Bong Rae Cho*, Chang Su Lim,
Ji Hee Han, Min Young Kang
10:00 – 103. Catecholamine sensing based
on long-range surface plasmon fluorescent spectroscopy. Nobuko Fukuda*,
Hirobumi Ushijima
10:20 – 104. Novel amide compounds via
tandem Claisen rearrangement exhibiting
molecular recognition.
Kazuhisa Hiratani*, Jie Hao,
Anil S. Kuwar
10:40 – 105. Development of supramolecular
analytical reagents based on self-assembly and host-guest interactions.
Takashi Hayashita*
11:00 – 106. Selective metal ion determinations based on molecular switchings.
Hasuck Kim*, Yang-Rae Kim,
Donghoon Han, Jong Seung Kim*,
Hyun Jung Kim
Convention Center
305A
Microfluidic and Nanofluidic Devices for
Chemical and Biochemical Experimentation
(#198)
Organized by: H.J. Crabtree, Y. Baba,
S. Jacobsen, J.M. Ramsey
Presiding: Y. Baba, M. Tokeshi
8:00 – 107. Withdrawn
8:20 – 108. Spatially controlled differentiation of pluripotent stem cells in microenvironment. Jiro Kawada, Hiroshi Kimura,
Hidenori Akutsu, Yasuyuki Sakai,
Teruo Fujii
8:40 – 109. Lab-on-a-Chip: From micro/
nanofluidic research to biomedical applications. Albert van den Berg*
9:05 – 110. Real-time investigations of cellular communication in the circulation using
microfluidic technologies. Dana Spence*
9:30 – 111. Biomedical laboratory on a chip.
Jianhua Qin*
9:55 – 112. Recent advances in acoustophoresis for microchip based cell and
particle separation. Thomas Laurell*
10:20 – 113. MEMS/Microfluidic technology
for 3-D tissue construction.
Shoji Takeuchi*
10:45 – 114. Microdevices for cell-based assays. Nancy Allbritton*
11:10 – 115. Real-time monitoring of cell-cell
communication evoked by mechanical
stimulation on suspension cells using an
integrated microfluidics. Mengsu Yang*,
Tao Xu, Cheuk-Wing Li, Wanqing Yue
Convention Center
317A
Non- and Minimally-Invasive Diagnostics of
Biological Systems using Vibrational
Spectroscopy (#276)
Organized by: M.W. Blades, M. Michael,
H. Sato
Presiding: M. Blades
8:00 – 116. Terahertz spectroscopy and imaging of frozen biological tissues.
Hiromichi Hoshina*, Aya Hayashi,
Norio Miyoshi, Yuichi Ogawa,
Shigeaki Ueno, Yukihiro Fukunaga,
Fumiaki Miyamaru, Chiko Otani
8:20 – 117. Potential of ATR-FTIR spectroscopic imaging for biomedical research.
Sergei G. Kazarian*, Andrew Chan
8:40 – 118. Detection of small molecules and
ions from conformational changes of
DNA aptamers. Jinheung Kim*,
Byul N. Oh, Misun Cha, Sungeun Lee
9:00 – 119. Characterization of adipose tissue in tumor using Raman spectroscopy.
Retno Hariyani, Akinori Taketani,
Kazuki Minami, Bibin B. Andriana,
Hidetoshi Sato
9:20 – 120. Depth profiling analysis of layered tissues by miniaturized Raman
probes. Yuko S. Yamamoto,
Yuji Matsuura, Yukihiro Ozaki,
Hidetoshi Sato*
9:40 – 121. OPO-based multimodal nonlinear optical microscopy.
Mikhail N. Slipchenko*, Ji-Xin Cheng*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–53
01-ANYL
TECHNICAL PROGRAM
10:00 – 122. Nonstaining analysis of pancreas cancer model tissue: Combination
of the narrow band autofluorescence imaging and Raman spectroscopy.
Toshiaki Suzuki, Toru Asakura,
Toru Shimosegawa, Yukihiro Ozaki,
Hidetoshi Sato
10:20 – 123. Application of SERS using
nanosphere overlayer method to biomolecules. Masayuki Futamata*,
Takeshi Kokubun, Tomomi Yanatori,
Yei-yei Yu
10:40 – 124. Raman vibration on
Zearalenone and its derivatives for nondestructive rapid detection.
Won-Seok Kang, Minsu Lee,
Sung-Wook Choi, Hyang Sook Chun,
Kwangnak Koh, Jae-Ho Kim*
11:00 – 125. Evidence of marked glycogen
variations in the characteristic Raman
signatures of human embryonic stem
cells. Stanislav O. Konorov,
H. Georg Schulze, James M. Piret,
Robin F. Turner*, Michael W. Blades*
9:55 – 136. Screening technique for discrimination of vegetable oils using ion attachment ionization mass spectrometry.
Takahisa Tsugoshi*, Yuji Mishima,
Satomi Onuki, Yuko Nishimoto,
Naoaki Saito
10:15 – 137. Rapid qualitative and quantitative nontargeted screening using fast
chromatography and up to 100,000 resolution on a benchtop orbitrap.
Brenda Kesler*, Thomas Moehring,
Dipankar Ghosh
10:35 – 138. Analysis of pharmaceutical residues in environmental water samples by
LC-TOF-MS. Xiaohong Hou*, Xin Chen,
Ning Liang
10:55 – 139. Rapid analysis of persistent environmental pollutants utilizing gas chromatography and 2-D gas chromatography coupled with time-of-flight mass
spectrometry. Mark Libardoni,
Joe Binkley, Scott Pugh, Cory Fix
Convention Center
301A
Convention Center
317A
Enabling Mass Spectrometric Techniques
for Proteomics (#277)
Comprehensive Multidimensional
Separations (#191)
Organized by: L. Li, D. Muddiman,
X. Qian
Presiding: K. Hakannson
Organized by: T. Gorecki, P. Marriott,
R. Synovec
Presiding: P. Marriott,
8:00 – 126. Driving biological discovery using quantitative mass spectrometry.
John R. Yates*
8:30 – 127. Advances in structural mass
spectrometry for integrated omics and
systems biology. John A. McLean*
9:00 – 128. Mass shift perturbation methods
for structural proteomics.
David Schriemer*
9:30 – 129. FT-ICR MS-based targeted proteomics of polyketide synthases and nonribosomal peptide synthetases.
Kristina Hakansson,
Christopher M. Rath, Bo Wang,
Liangcai Gu, Janet L. Smith,
David H. Sherman
10:00 – 130. High performance ftms analysis
of fullerene calibrants for peptide analysis. Charles L. Wilkins*,
Sasa M. Miladinovic, Thomas Egan,
Ernest K. Lewis, J. A. Schultz
10:30 – 131. Withdrawn
11:00 – 132. Tactics for the analysis of protein carbonyl modifications from in vitro
and in vivo oxidative stress.
Scott Gronert*, David Simpson,
Zafer Ugur
12:30 – 140. Comprehensive multidimensional separations: An introduction.
Tadeusz Gorecki*
12:55 – 141. Importance and optimization of
stationary phase selectivity in comprehensive GCxGC separations.
Frank Dorman*, Paul Schettler,
Jack Cochran, Mike Wittrig,
Shawn Reese, Eric Reiner
13:15 – 142. Characterization of GCxGC column sets with bidimensional retention
normalization. John Dimandja*,
Takesha Leavell, Frank L. Dorman,
Daniel W. Armstrong
13:35 – 143. Comprehensive 2-D GC and
multidimensional GC with quadrupole
mass spectrometry detection.
Hyung-Kyoon Choi*, Seung-Ok Yang,
Sun-Hee Hyun, So-Hyun Kim,
Hee-Su Kim, Yujin Kim, Hae-Eun Park,
Phillip Marriott
14:00 – 144. Use of GCxGC-HRMS and
comprehensive GCxGC-TOFMS for assessing human exposure to environmental toxicants and screening for new and
emerging chemicals.
Donald G. Patterson*
14:20 – 145. Development and application of
GC x GC - TOFMS methods for discovery-based analysis. Robert E. Synovec*,
Jamin C. Hoggard,
Elizabeth M. Humston, W. C. Siegler
14:45 – 146. Applications of comprehensive
2-D gas chromatography/time-of-flight
mass spectrometry in plant metabolomics. Xiaohui Lin, Yong Li, Xin Lu,
Hongwei Kong, Guowang Xu*
15:10 – 147. Small molecule metabolite
identifications in complex biological samples using comprehensive 2-D gas chromatography combined with time-of-flight
mass spectrometry. Mark Libardoni*,
John Heim, Pete Stevens
15:30 – 148. Diverse groups of environmental food contaminants can be determined
within a single run: Streamlining sample
preparation strategy and determination
based on comprehensive profiling.
Jana Hajslova*, Kamila Kalachova,
Jana Pulkrabova, Lucie Drabova,
Tomas Cajka
15:50 – 149. QuEChERS, cartridge SPE, and
GCxGC-TOFMS for the analysis of pesticides in dietary supplements.
Jack Cochran*, Julie Kowalski,
Michelle Misselwitz, Jason Thomas,
Rick Lake
16:10 – 150. Microchannel devices for multicolumn capillary GC. Robert A. Shellie*,
Paul M. Harvey, Samuel D. Poynter,
Roy Hibbert, Brett Barnett,
Peter A. Dawes
Convention Center
301B
Rapid, Multi-Component Environmental
Analysis (#253)
Organized by: R. Clement, F. Dorman,
N. Yamashita
Presiding: R. Clement
8:30 Introductory remarks
8:35 – 133. Ultrahigh-resolution Fourier
transform ion cyclotron resonance mass
spectrometry of petroleum: A guidebook
for environmental analysis.
Alan G. Marshall, Greg T. Blakney,
Christopher L. Hendrickson,
Amy M. McKenna, Ryan P. Rodgers
9:15 – 134. Rapid, multicomponent dioxin
analysis by gas chromatography-Fourier
transform ion cyclotron resonance mass
spectrometry. Ray E. Clement*,
Vince Taguchi, Robert Nieckarz,
Stefan Krolik
9:35 – 135. Carbamazepine and caffeine as
markers for sewage input into the water
cycle: Rapid assessment by sensitive immunoassays. Arnold Bahlmann,
José João D. Carvalho,
Kirsten G. Pannenbecker,
Michael G. Weller, Ulrich Panne,
Uwe Dünnbier, Martin Jekel,
Rudolf J. Schneider*
54 –TECH
Thursday Afternoon
Convention Center
301B
Electroanalytical Sciences (#193)
Organized by: K. Aoki, B. Liu, T. Osakai,
H. White
12:30 – 151. Opening address: Fundamental
questions about voltammetry.
Koichi Aoki*
13:20 – 152. A facile preparation of gold
nanoparticle-attached indium tin oxide
electrode and its electrochemical applications. Md. A. Aziz*, Munetaka Oyama
13:40 – 153. Conducting a polymer-coated
electrode as a reference/counter electrode in an organic phase and its application to a two-electrode type thin-layer cell
for voltammetry at the liquid | liquid interface. Yumi Yoshida*,
Satoshi Yamaguchi, Shotaro Nakamura,
Kohji Maeda
14:10 – 154. FM-AFM study of hydration at
water-metal oxides interfaces.
Takumi Hiasa*, Kenjiro Kimura,
Hiroshi Onishi, Ryohei Kokawa,
Masahiro Ohta, Kazuyuki Watanabe,
Masashi Yamazaki, Noriaki Oyabu,
Kei Kobayashi, Hirofumi Yamada
14:30 – 155. Voltammetric study on the
mechanism of electron transfer reactions
at liquid|liquid interfaces.
Hirosuke Tatsumi*
15:00 – 156. TiO2-assisted biosensors for
sensitive analysis of phosphoproteins.
Baohong Liu, Ji Ji
15:30 – 157. Relation between oxidation current of hydrogen gas and amount of the
bubbles in aqueous solution.
Hirokazu Toda*, Koichi Aoki*,
Jingyuan Chen, Toyohiko Nishiumi
15:50 – 158. Quantification of electron transport between interacting single molecules. Tomoaki Nishino*
16:10 – 159. Electron transfer mediated by
membrane-bound D-fructose dehydrogenase adsorbed at an oil/water interface.
Yuko Sasaki, Takayasu Sugihara,
Toshiyuki Osakai*
Convention Center
305A
Microfluidic and Nanofluidic Devices for
Chemical and Biochemical Experimentation
(#198)
Organized by: H.J. Crabtree, Y. Baba,
S. Jacobsen, J.M. Ramsey
Presiding: M. Ramsey, N. Allbritton
12:30 – 160. Improved ways to couple light
in and out of integrated waveguides on
microfluidic devices for biomedical applications. Jörg P. Kutter*,
Thomas G. Jensen, Pelle Ohlsson
12:55 – 161. Electrophoretic traps for probing ligand-receptor interactions.
Cornelius F. Ivory*
13:20 – 162. Nanobiodevice based single
cell analysis for cancer diagnosis and in
vivo imaging for stem cell therapy.
Yoshinobu Baba*
13:45 – 163. New approach for the label-free
detection and quantitation of DNA in integrated microfluidic analysis systems.
James P. Landers*, Dan Leslie,
Scott Barker, David Finkler, Jingyi Li
14:10 – 164. Ion and virus transport in planar
nanochannels. Stephen C. Jacobson*,
John M. Perry, Kaimeng Zhou,
Zachary D. Harms
14:35 – 165. Import of order of the porous
matrix on separation efficiency in nanoporous materials. Jed Harrison,
Neda Nazemifard, Wenmin Ye,
Ledi Wang
15:00 – 166. Sensitive and multiplex genetic
marker quantification system using CEbased SSCP combined with MLPA.
Gyoo Yeol Jung*, Jong Moon Park,
Gi Won Shin, Hee Sung Hwang,
Boram Chung, Jung Kyeong Na
15:20 – 167. Quantitative zymography in microfluidic polyacrylamide gradient gels.
Alex J. Hughes*, Amy E. Herr
15:40 – 168. Microchip electrophoresis of
oligosaccharides with large-volume sample stacking with electroosmotic flow
pump in single channel.
Takayuki Kawai*, Kenji Sueyoshi,
Fumihiko Kitagawa, Koji Otsuka
16:00 – 169. Electrokinetic flow guidance in
“click” surface modified glass nanofluidic
channels. Shaurya Prakash*,
Mehmet B. Karacor
Convention Center
323C
Innovation in Chemical Sensing and
Separation Systems toward Advanced
Chemical Analysis (#39)
Organized by: T. Hayashita,
R. A. Bartsch, H. Kim, N. Iki, A. Tong
Presiding: T. Hayashita, A. Tong, B. Cho,
H. Kim, R. Bartsch
12:30 – 170. Synthesis of gold nanoparticles
from gold nanoclusters conjugated with
thermoresponsive polymer by thermal
stimuli. Nobuo Uehara*
12:50 – 171. Capillary flow separation using
aqueous mixed solvents of ionic liquids:
Effects of water-soluble polymers.
Masaaki Tabata*, Kenta Fujii,
Thiraporn Charoenraks
13:10 – 172. Heavy-metal detection in industrial atmospheric particles using advanced chemical sensors.
Mariana Milochova*, Eugene Bychkov
13:30 – 173. Development of high-performance biodegradable chelating agents.
Kiyoshi Sawada*
13:50 – 174. Fluorescent “turn-on” chemodosimeter for Cu(II) in water via Cu(II)promoted hydrolysis of lactone moiety in
coumarin. Na Li, Yu Xiang, Aijun Tong*
14:20 – 175. Application of novel macrocyclic structures to ion chromatography.
John D. Lamb*, Na Li,
Taylor Christensen, Ammon Eaton,
Roger Harrison
14:40 – 176. Highly selective and sensitive
method to determine ppb levels of exchangeable Cd and Pb in soil using rapid
leaching with thiacalixarene and detection with kinetic differentiation mode
HPLC. Nobuhiko Iki*, Keita Kano,
Hitoshi Hoshino
15:00 – 177. Thiacrowns and calix-thiacrowns: New building blocks for sensing
materials and their crystal engineering.
So Young Lee, Hyun Jee Kim,
Ki-Min Park, Shim Sung Lee*
15:20 – 178. Development of calixarene
based fluorescence probes.
Jong Seung Kim*
15:40 – 179. Metal ion separations by extraction with proton-ionizable
calix[4]arene ligands.
Richard A. Bartsch*
16:10 Concluding remarks
Convention Center
301A
Enabling Mass Spectrometric Techniques
for Proteomics (#277)
Organized by: L. Li, D. Muddiman,
X. Qian
Presiding: A. Hawkridge
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
01-ANYL
13:00 – 180. Identification and confirmation
of biomarkers using an integrated platform for quantitative analysis of glycoproteins and their glycosylations.
David M. Lubman*, Yashu Liu,
Jintang He, Chen Li, Jorge Marrero
13:30 – 181. Discovering differentially expressed proteins among subtypes of
high-grade endometrial cancer tissues by
means of iterative proteomic analyses.
Sébastien N. Voisin, Olga Krakovska,
Leroi V. DeSouza, Blaise A. Clarke,
K.W. Michael Siu*
14:00 – 182. Spontaneous ovarian adenocarcinoma in the chicken as an experimental model for mass spectrometrybased biomarker discovery.
Adam Hawkridge*
14:30 – 183. Novel biomarker panels for human diseases derived by shotgun and
target proteomics. Rong Zeng,
Yue-Yi Deng, Hai-Quan Chen,
Yan-Sheng Liu, Rong-Xia Li
15:00 – 184. Contribution of biologics, inorganic and organic compounds in mimics
of ambient particles on determining lung
cell response. George Agnes
15:30 – 185. Methods for the glycomics profiling of cell surface glycans.
Carlito Lebrilla*
16:00 – 186. Novel proteomic tools to study
cell signaling. Andy Tao
Thursday Evening
Convention Center
Kamehameha Halls II and III
Analytical General Posters
Poster Session
19:00 – 21:00
187. Laser-fluence-depended fragment ions
using titania thin film by laser desorption/
ionization mass spectrometry.
Takashi Fujita*, Kohei Shibamoto,
Takashi Korenaga
188. Study on resonantly-excited state of
Crystal Violet molecule adsorbed on gold
nanoparticle surface by using LDI mass
spectrometry with pulse and CW double
laser system. Takayuki Matsuoka*,
Kohei Shibamoto, Tatsuya Fujino,
Takashi Korenaga
189. Qualification of Triton thermal ionization
mass spectrometer (TIMS) for uranium
and plutonium measurement.
Kevin Norbash*, Steven Bakhtiar
190. Characterization and comparison of
SARA fractions of the vacuum residue oil
by APPI and APCI FT-ICR MS.
YunJu Cho, HyeJin Lee, Sunghwan Kim*
191. Structural elucidation of molecules
comprising crude oils by ion mobility
mass spectrometry. YunJu Cho,
Sunghwan Kim*, Eunjung Bae,
Jangmi Jin, Arif Ahmed
192. Detection of alkanethiol-gold complex
anions desorbed from chemically-modified gold nanoparticle surface by using
LDI-MS. Keishiro Nagoshi*,
Kohei Shibamoto, Tatsuya Fujino,
Takashi Korenaga
193. Quantitative analysis of the phosphorylation states in a bacterial two-component system using Phos-tag SDS-PAGE.
Shiho Yanagihara,
Emiko Kinoshita-Kikuta, Eiji Kinoshita,
Tohru Koike
194. Development of high resolution imaging
technology for analysis of mRNAs distribution. Jung Sook Kim, Yu Shin Park,
Hong Gil Nam*, Joon Won Park*
195. Rolling circle amplification in micro and
extended-nano channels to detect singlemolecule DNA. Yo Tanaka, Hui Xi,
Kae Sato, Kazuma Mawatari,
Björn Renberg, Mats Nilsson,
Takehiko Kitamori
196. Phos-tag SDS-PAGE for protein phosphorylation profiling. Eiji Kinoshita*,
Emiko Kinoshita-Kikuta, Saori Okatani,
Tohru Koike
197. Phos-tag-based fluorescence resonance energy transfer system for the
analysis of phosphorylated molecules.
Masao Somura*, Kei Takiyama,
Tomomi Nagai, Eiji Kinoshita,
Emiko Kinoshita-Kikuta, Tohru Koike
198. Force-based atomic force microscopy
as an analyzing tool for immunodetection
of individual antigens captured on an antibody chip. Dhruvajyoti Roy,
Sung Hong Kwon, Ju-Won Kwak,
Joon Won Park*
199. Flow Cytometry (FACS) for characterization and sorting of murine B cells to
advance development of monoclonal antibodies. Maren Kuhne, Sascha Wagner,
Jörg A. Schenk, Hans-Jörg Kunte,
Ute Resch-Genger, Rudolf J. Schneider*
200. Design-of-Experiment approach in optimization, validation, and uncertainty assessment of hapten immunoassays.
Julia Grandke, Wolfram Bremser,
Ute Resch-Genger, Rudolf J. Schneider*
201. Development of aptamer films for use in
biosensing. Tariq Francis, David A. Blair,
Maria DeRosa*, Yanina Shevchenko,
Jacques Albert*
202. Sensitivity enhancement of SPR using
plasmonic nanostructures patterned chip.
Hyo-Sop Kim, Won-Seok Kang,
Young-A Song, Minsu Lee,
Sung-Wook Choi, Kwangnak Koh,
Jae-Ho Kim*
203. Fluorescence lifetime based pH measurements for remote monitoring with fiber optic arrays. Paul E. Henning*,
Peter Geissinger
204. Optical fiber-cased tools for the analysis of zinc in aqueous environments.
Steven Kopitzke, Peter Geissinger
205. Development of novel near-infrared
chemiluminescent probes and photoncounting apparatus for the near-infrared
luminescence analysis.
Katsunori Teranishi, Hidehiro Kubota,
Takashi Hori, Atsushi Asakawa
206. Improved, robust metric for quantifying
cluster separation in multivariate space.
James J. Harynuk*, Nikolai A. Sinkov
207. Utilization of laser-induced breakdown
spectroscopy for nutrition and trace elements mapping in plant tissues.
Karel Novotny*, Jozef Kaiser,
Michaela Galiova, Madhavi Martin,
Lucie Krajcarova, Rene Kizek,
Petr Babula
208. Alginic acid modified silica gel as preconcentration column packing materials
for on-line flow injection-flame atomic absorption spectrometry determination of
trace heavy metals in water samples.
Makoto Onozato*, Masanobu Mori,
Kazuo Hirayama
209. Fundamental properties of atmospheric
plasma soft ablation (APSA) for damagefree surface sampling. Takahiro Iwai*,
Yuichiro Takahashi, Yuta Negishi,
Kaori Shigeta, Hidekazu Miyahara,
Akitoshi Okino
210. Fundamental properties of atmospheric
helium plasma detectors for gas chromatograph. Yuichiro Takahashi*,
Yoichi Nagata, Yuta Negishi,
Hidekazu Miyahara, Osamu Fujita,
Yukio Toyoura, Akitoshi Okino
211. Multielement analysis in biocells and
nanoparticles using droplet direct injection nebulizer. Kaori Shigeta*,
Takahiro Iwai, Yuki Kaburaki,
Hidekazu Miyahara, Akitoshi Okino
212. Development of selective separation
and recovery method for gold(III) using
polymer bead containing epoxy group.
Masami Sekine, Michio Butsugan,
Shukuro Igarashi*
213. Preparation of monodispersed porous
polymer resins of 3-␮m diameter and
their application to stationary phases for
high-performance liquid chromatographic
separation of saccharides.
Kei-Ichi Kitahara,
Takako Masuda-Hanada*,
Hiroko Kokuba*, Isao Yoshihama*,
Sadao Arai*
214. Determination of polycyclic aromatic
hydrocarbons in water samples by gas
chromatography-mass spectrometry after preconcentration with hemimicelle
capped oxidized carbon nanotubes.
Hiroki Ohno, Hideyuki Katsumata*,
Satoshi Kaneco, Tohru Suzuki,
Kiyohisa Ohta
215. Air-segmented amplitude modulated
flow analysis. Hideji Tanaka*, Koji Inui,
Takeshi Ogusu, Yohei Kurokawa,
Masaki Takeuchi
216. Glycosylation analysis of recombinant
human coagulation factor VIII by LC MS/
MS. Akira Harazono, Nana Kawasaki,
Noritaka Hashii, Satsuki Itoh,
Teruhide Yamaguchi
217. Catecholamine analysis with mixedmode reversed-phase and cation-exchange column. Makoto Tsunoda*,
Takashi Funatsu
218. Capillary zone electrophoresis of inorganic anions and cations in human saliva
sample using polyvinyl alcohol-coated
capillary column. Tsukasa Yamamoto*,
Masanobu Mori, Masaya Ohtake,
Maki Kaseda, Hideyuki Itabashi
219. Research on effect of maturing of perfume by pressurizing.
Takako Kurashima*, Akio Shimizu,
Masahiro Taniuchi, Takashi Nitsu
220. Elution order and resolution for stereoisomers of some decursin derivatives
separated on cellulose based chiral stationary phases by high performance liquid chromatography. Enqi Wu*,
Yu-Seon Jang, Jianbo Chen,
Kwan Jun Lee, Eun Young Seo,
Gyu Yong Song, Hu Huang, Wonjae Lee,
Jong Seong Kang
221. Direct enantiomer separation of Thyroxine in pharmaceutical formulations by
HPLC. Enqi Wu*, Jianbo Chen,
Hongmei Zhu, Kwan Jun Lee,
Eun Young Seo, So Hee Jeon,
Wonjae Lee, Jong Seong Kang
222. Automated high throughput sample
fractionation method for the determination of PAHs, MADEP-EPH, TNRCC
method 1005-1006. Tom Hall
223. Cookbook method for integrated sample preparation for dioxin analysis in food.
Tom Hall
224. Identifying pharmaceuticals and personal care products in water, biosolids
and solids. Tom Hall
225. Quality control of modified Samgiumgagambang (SGMX) through simultaneous determination of major constituents by HPLC -DAD-ESI-MS.
Jianbo Chen*, Enqi Wu, Hongmei Zhu,
Jin Young Son, Young Ho Kim,
Chang Gyu Son, Jong Seong Kang
226. Novel Py-GC-MS approach for alcoholic beverages characterization and their
classification by multivariate statistical
analysis. Roman Selyanchyn,
Serhiy Korposh, Seung-woo Lee*
227. Integrated gas chromatography - chemometric platform suitable for field testing of food quality.
Kristen J. Skogerboe,
Elizabeth M. Humston,
Jamin C. Hoggard, Robert E. Synovec*
228. Estimation of the age of a weathered
mixture of volatile organic compounds.
Brianne M. Zorzetti, James J. Harynuk*
229. Visual determination method of chromium(VI) using a thixotropic gel.
Takashi Saito*
230. Cloud point extraction of trace heavy
metals in environmental water sample
and its application to visual determination. Nobuko Sato*, Masanobu Mori,
Takahito Nakamura, Hideyuki Itabashi
231. Comprehensive assessment of water
quality using a modified grey clustering
method: A case study in Hangzhou section of the Qiantang River, China.
Liangqian Fan, Qingyu Zhang*,
Weili Tian, Zucheng Wu, Weiguo Xu
232. Chemical characterization of dissolved
organic matter in Lake Biwa using C18
solid phase extraction. Fumiko Kitano*,
Takaya Nishimoto, Chizuru Wada,
Tetsu Kumagai, Jun Shimano,
Masahiro Maruo, Kumiko Tsuda,
Hidekado Shirai, Nobuhide Fujitake,
Kazuhide Hayakawa, Patrick Hatcher,
Yuko Sugiyama
233. Analysis of ice water by thermally stimulated depolarized current(TSDC)
method. Kazuishi Sato*,
Kunihiko Okajima, Toshinori Koizumi
234. Improved solvent collection system for
a dispersive liquid-liquid microextraction
method using low density organic solvent
for extraction of organochlorine pesticides in water samples.
Shang-Da Huang*, Chu-Chi Chang
235. Determination of trace elements in soybeans by X-ray fluorescence analysis and
its application to identification of their
production area. Akiko Otaka*,
Akiko Hokura, Izumi Nakai
236. Study on accumulation mechanism of
cadmium in rice (Oriza sativa L.) by XRF
imaging and XAFS analyses utilizing highenergy synchrotron radiation X-ray microbeam. Wakiko Yamaoka*,
Hinako Takehisa, Yoriko Hayashi,
Akiko Hokura, Yasuko Terada,
Tomoko Abe, Izumi Nakai
237. Provenance study of Middle Bronze
Age, Dark Age, and Iron Age’s potteries
from Kaman-Kalehöyük, Turkey.
Hiroko Suzuki*, Shun Kai Willy Bong,
Izumi Nakai
238. Technological and chemical study of
ancient faience objects excavated from
Northwest Saqqara, Egypt.
Rodan Harimoto*, Yoshinari Abe,
Izumi Nakai, Akiko Nishisaka,
Nozomu Kawai, Sakuji Yoshimura
239. Effect of oxoacid ions on dissolution
behavior of zinc. Masahiro Kato*,
Kazuhiko Noda, Takashi Ninomiya,
Masayuki Itagaki, Ikuro Yamaoka,
Kazumi Nishimura
240. Discrimination of L-ascorbic acid and
D-isoascorbic acid using modified Au
electrode. Masaharu Komatsu*,
Takahiro Ando, Shota Suzuki
241. Anodic polarization behavior of pure
iron under solution flow environment.
Tomohiro Tanabe*, Kazuhiko Noda,
Kazutoshi Fujiwara, Masafumi Domae
242. Effect of exposed underlying on atmospheric corrosion of galvanized steels.
Ayumu Yokota*, Kazuhiko Noda,
Hideki Katayama, Hiroyuki Masuda
243. Corrosion analysis of zinc rich paint using electrochemical measurement
method. Kohei Ota*, Kei Matumoto,
Kazuhoko Noda
244. Effect of plating bath conditions on
electroless nickel deposition on epoxy
resin substrates. Muhammad Zaimi*,
Kazuhiko Noda
245. Passivation behavior of Co-Cr alloy in
neutral solution. Ryouji Suzuki*,
Atsuhiro Yamada, Kazuhiko Noda,
Yusuke Tsutsumi, Takao Hanawa
246. Effect of additive element on polarization behavior of low alloy steels.
Shinya Adachi*, Kazuhiko Noda,
Hideki Katayama, Hiroyuki Masuda
247. Effect of conversion treatment on corrosion resistance of magnesium alloys.
Takahiro Kawamata*, Kazuhiko Noda,
Hachiro Imai
248. Influence of stress on localized corrosion initiation of stainless steel SUS304.
Toshinori Furusawa*, Kazuhiko Noda,
Keita Suzuki
249. Evalution of atmospheric corrosion on
high corrosion resistance metal by surface potential distribution measurement.
Youhei Hirohata*, Kazuhiko Noda,
Hideki Katayama, Hiroyuki Masuda
250. Solutions analysis of crevice corrosion
of stainless steel using occluded cell.
Yuki Kagawa*, Kazuhiko Noda,
Hachiro Imai, Tadashi Shinohara
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–55
01-ANYL
251. Measurement of the activation energy
of catalysis of single molecules of E. coli
␤-galactosidase using a capillary electrophoresis continuous flow assay.
Doug Craig*, Linden Chase
252. Molecular interactions of concanavalin
A lectin with phenyl glucoside derivatives
using STD NMR spectra.
Kaname Katsuraya, Yoshiki Oda,
Takashi Yamanoi*, Chisato Kurosaki,
Seizo Koshiba
253. Hydrothermal synthesis and crystal
chemistry of RE2(OH)4CO3 (RE ⫽ Er, Tm,
Yb, Lu). Masatake Nagaosa,
Kiyonori Michiba, Izumi Nakai,
Rituro Miyawaki
254. Solvent effect of ionic liquids on the distribution constant of 2-thenoyltrifluoroacetone and its metal(II) chelates: Evaluation of solvent properties based on the
regular solution theory. Keiji Kidani,
Naoki Hirayama, Kotaro Morita,
Hisanori Imura
255. Investigation of the origin of suspended
particulate matter containing Sb by using
SEM-TES-EDS system. Lina Suzuki*,
Yuki Ono, Keiichi Tanaka,
Satoshi Nakayama, Izumi Nakai
256. Analysis of taste qualities and ingredients of extract from polished rice using
taste sensor. Shu Ezaki*, Miki Yahiro,
Satoru Iiyama
257. NOESY analysis of the behaviors of the
inclusion complexes between cyclodextrins and doxorubicin. Yoshiki Oda,
Kaname Katsuraya, Takashi Yamanoi*
258. Metabolism of estradiol 17␤-sulfate by
human liver microsomes. Shinji Itoh*,
Shinji Yuasa, Kenta Ukiana,
Kaori Takanashi
259. Monitoring the bioactive components
and a method for differentiation of authentic and inauthentic rhubarbs.
Van Men Chu, Yu Seon Jang,
Hong Mei Zhu, Eun Young Seo,
Kwan Jun Lee, Wonjae Lee, Hu Huang,
Young Ho Kim, Ki Hwan Bae,
Jong Seong Kang
260. Monitoring the synthesis of tert-butoxycarbonyl-L-leucyldoxorubicin by HPLCLIF-MS and MEKC-LIF. Brandon Meyer,
Chad Satori, Yaohua Wang,
Joseph Katzenmeyer, Daniel Mullen,
George Barany, Edgar Arriaga*
261. Isolation and purification of phenylethanoid glycosides from plant extract of
Cistanche deserticola by high performance centrifugal partition chromatography. Li Li, Jing Wang, Yuge Gui,
Chunming Liu
262. Improved method for long-chain fatty
acid analysis using orbi-trap LCMS.
Xingnan Li, Adrian A. Franke
263. Metabolic profile changes associated
with the weight loss induced by berberine
in hypercholesterolemic rats. Feng Liu*,
Gwek Li Evonne Lau, Eng Shi Ong,
Fong Yau Sam Li
264. Liquid phase microextraction- using
knitting wool as the extractant phase
holder to determine UV filters in swimming pool water. Yufeng Zhang*,
Hian Kee Lee
265. Synthesis of poly[(2-hydroxy,4-butoxy)
butylene] resin and its ion-exchange
study with lanthanides (III).
Vasant M. Patel
266. Ionic liquid based hollow fiber supported liquid phase microextraction of UV
filters. Ge Dandan*, Lee Hian Kee
267. Purification by LC - Flash or HPLC, is
there really a difference? Lori Sandford*,
Linda Lloyd*, S. Ball*, K. Mapp*
Convention Center
Kamehameha Halls II and III
Innovation in Chemical Sensing and
Separation Systems toward Advanced
Chemical Analysis (#39)
Organized by: T. Hayashita,
R. A. Bartsch, H. Kim, N. Iki, A. Tong
Presiding: T. Hayashita, A. Tong, B. Cho,
H. Kim, R. Bartsch
56 –TECH
TECHNICAL PROGRAM
Poster Session
19:00 – 21:00
268. An all-round SNP detection method
based on the capillary electrophoresis of
one-base substituted single-stranded
DNA. Toru Takahashi*, Takao Sakurai,
Hitoshi Hoshino
269. DNA immobilization on the gold electrode using naphtalene diimide derivatives having dithiolane or cysteine moieties. Kosuke Yamamura, Shinobu Sato,
Shigeori Takenaka*
270. Synthesis of DNA conjugate for phototriggered new chemical ligation.
Takuma Hirayama, Akinori Jyo,
Toshihiro Ihara*
271. Cooperative DNA probing using ␤-cyclodextrin-modified DNA and nucleobase-specific fluorescent ligand.
Akika Futamura*, Asuka Uemura,
Akinori Jyo, Noriyuki Baba,
Seiichi Nishizawa, Norio Teramae,
Toshihiro Ihara*
272. Developing aptamers against intact mitochondria using capillary electrophoresis-systematic evolution of ligands
through exponential enrichment.
Thane Taylor*, Vratislav Kostal,
Michael T. Bowser, Edgar A. Arriaga
273. Investigation of protein-ligand interactions using fluorescence anisotropy.
Lin Wang, Matthew McCarroll*,
Luke Tolley
274. Investigation of fluorescence anisotropy
as a method to examine chiral interactions. Matthew McCarroll*, Leung Amy
275. Detection of clinical cut-off values of
prostate specific antigen in poly(dimethylsiloxane) microchannels for point-ofcare testing. Hiroki Okada*,
Kazuo Hosokawa, Mizuo Maeda
276. Development of analytical method for
distribution measurement of amphetamine type stimulants in organs.
Kenji Kuwayama*, Kenji Tsujikawa,
Hajime Miyaguchi, Tatsuyuki Kanamori,
Yuko T. Iwata, Hiroyuki Inoue
277. Design and function of fluorescent sensor array possessing dipicolylamino binding site. Tatsuro Nakamura, Yuri Fujii,
Nobuko Fukuda, Hirobumi Ushijima,
Takashi Hayashita
278. Synthesis and photophysical properties
of a novel TICT-type fluorescent sensor
for amino acids (IX). Akitaka Ito,
Shoji Ishizaka, Noboru Kitamura*
279. On-column affinity smart polymer gel
glucose sensor.
Chongdee Thammakhet*,
Proespichaya Kanatharana,
Panote Thavarungkul
280. Biofuel cells and biosensors with a mutated non-oxygen binding glucose oxidase. Megan M. Gillespie*,
Leonidas G. Bachas, Yinan Wei,
Sylvia Daunert, Dibakar Bhattacharyya
281. Gold glyconanoparticle-based competitive colorimetric assay for the determination of glucose in serum.
Kyung Rae Lim*, Han Nim Choi,
Won-Yong Lee
282. Study of the substituent and spacer effect on the fluorescence boronic acid
sensors for selective sugar recognition.
Mariko Maeda*, Kiyoyuki Sekine,
Koji Miyoshi, Takeshi Hashimoto,
Takashi Hayashita
283. Design of boronic acid fluorophore/aminated cyclodextrin complexes for sugar
sensing in water. Mio Kumai*,
Satoko Kozuka, Takeshi Hashimoto,
Iwao Suzuki, Takashi Hayashita
284. Sugar sensing by boronic acid azoprobe/cyclodextrin complexes.
Noriko Mihara*, Shota Oyaidu,
Takeshi Hashimoto, Takashi Hayashita
285. Development of boronic acid azoprobe/
dendrimer complexes sensors possessing sugar recognition function.
Keisuke Aimu*, Yuuki Sakai,
Yuuji Tsuchido, Takeshi Hashimoto,
Takashi Hayashita
286. Synthesis and photophysical properties
of a novel saccharide sensor based on
ruthenium(II) polypyridyl complex.
Ryo Mishima, Akitaka Ito, Shoji Ishizaka,
Noboru Kitamura*
287. Electrochemical sugar recognition using
ruthenium/dendrimer complexes.
Hiroyuki Minesaka*, Takeshi Hashimoto,
Akira Endo, Takashi Hayashita
288. Design of novel ligand for ruthenium
complex possessing the sugar recognition function. Yuka Hattori*,
Kanako Motoi, Takeshi Hashimoto,
Akira Endo, Takashi Hayashita
289. Development of crown ether azoprobe/
cyclodextrin complexes sensor possessing rotaxane structure. Kayoko Goto*,
Akira Sasaki, Takeshi Hashimoto,
Takashi Hayashita
290. Development of ditopic type azoprobe
possessing boronic acid and crown ether
recognition sites. Masashi Yasui,
Yui Endo, Takeshi Hashimoto,
Takashi Hayashita
291. Optical sensing of boron using metal
complexes with 3,3’-dihydroxy-2,2’-bipyridine and 5,6-dihydroxy-1,10-phenanthroline. Satoshi Iwatsuki*,
Kenji Chayama, Masahiko Inamo,
Hideo D. Takagi, Koji Ishihara*
292. Selective ion recognition by 2,2’bispyridylmethylamino fluorescent sensor/cyclodextrin complexes in water.
Mariko Samizo*, Satoko Kozuka,
Takeshi Hashimoto, Takashi Hayashita
293. Fabrication of biscrown ether azochromophore-surface for selective potassium
ion. Shouta Oyaidu*, Nobuko Fukuda,
Naoyuki Ishida, Takeshi Hashimoto,
Hirobumi Ushijima, Takashi Hayashita
294. Development of amphiphilic phthalocyanine derivatives having polyether chains.
Midori Kobayashi, Michiko Saitoh,
Keiichi Satoh, Kiyoshi Sawada*
295. Alkali metal-ion recognition by (␤-diketonato)ruthenium binuclear complex possessing crown ether unit.
Takeshi Hashimoto*, Yuko Igarashi,
Naoyuki Matsumoto, Akira Endo,
Takashi Hayashita
296. Electrochemical cation recognition by
using the mixed-valence state of the
dinuclear (␤-diketonato)ruthenium complexes. Akira Endo, Ryo Takahashi,
Shotaro Kawazoe, Megumi Furusawa,
Takeshi Hashimoto, Takashi Hayashita
297. Synthesis and property of (␤-diketonato)ruthenium binuclear complex bridged
by dihydroxyanthraquinone alkyl group.
Yusuke Yokose*, Takeshi Hashimoto,
Tatsuya Sasaki, Akira Endo,
Takashi Hayashita
298. Characterization of novel ruthenium
complex for molecular recognition by
changing intervalence change transfer.
Kayono Kimura, Asako Kitayama,
Takeshi Hashimoto, Akira Endo,
Takashi Hayashita
299. Electrochemical molecular recognition
of colloidal gold nanoparticles/ruthenium
complexes. Masamitsu Kimura*,
Kenji Suzuki, Ayaka Muto,
Takeshi Hashimoto, Akira Endo,
Takashi Hayashita
300. Electrochemical molecular recognition
based on ruthenium complexes assembled on amino core dendrimer.
Yurie Kuroki*, Yuta Fukuda,
Takeshi Hashimoto, Takashi Hayashita,
Akira Endo
301. pH-responsive switching of near-infrared absorption of water-soluble bis(o-diiminobenzosemiquinonato)platinum(II)
complex. Atsuko Masuya*, Nobuhiko Iki,
Chizuko Kabuto, Yasunori Ohba,
Seigo Yamauchi, Hitoshi Hoshino
302. Innovative luminescent complex by heterogeneous assembly of terbium(III), silver(I) and thiacalix[4]arene.
Teppei Tanaka, Nobuhiko Iki,
Hitoshi Hoshino
303. Supramolecular Eu(III) complex-silica
composites for the detection of volatile
organic compounds.
Yoshikazu Makioka*, Masaki Kondo,
Takeji Takamura, Yuki Taniguchi
304. Fluorescence turn-on sensors for
HSO4-. Hyun J. Kim, Min H. Lee,
Hyo S. Jung, Yeon O. Lee, Sumin Lee,
Sankarprasad Bhuniya,
Rakesh K. Mahajan*, Rajiv Puri,
Hongguang Liu, Kyoung C. Ko,
Jin Y. Lee*, Jong S. Kim*
305. “Turn-on” fluorescent polymeric microparticle sensors for the determination of
ammonia and amines in the vapor state.
Yoshitaka Takagai*, Yuki Nojiri,
Tsugiko Takase, Willie L. Hinze,
Michio Butsugan, Shukuro Igarashi
306. Trihalomethane complexation studies
using dithiocarbamate-anchored calixarene monolayers in aqueous environments. Matthew Casselman,
Alexander Wei
307. Deveropment of test strips for judging
the degradation stage of used engine oil.
Masatoshi Endo*, Tsukasa Saito,
Toshiki Watanabe, Nami Igarashi,
Kuniharu Yamamoto, Hiroshi Tochigi
308. Development of test paper for the determination of total polyphenol concentration. Masatoshi Endo*,
Chihiro Kondo, Eri Takahashi,
Masami Toi, Atsushi Sasaki
309. New strategy to design of efficient electrochemiluminecence (ECL) materials
bearing pyrene as a ␲-center.
Yeon Ok Lee, Chang Wan Bae,
Hyun Jung Kim, Hyo Sung Jung,
Min Hee Lee, Jong-seung Kim*
310. Inductive time with efficient measurement-chemi-luminescence (iTem-CL)
method for the analysis of trace metals as
trigger using an autocatalytic reaction of
metal complex. Takao Ohtomo,
Shukuro Igarashi*
311. Development of podand type fluorophore/CTA membrane sensors possessed Pb2⫹ recognition function.
Aya Yamasawa*, Naoki Tomita,
Richard A. Bartsch, Takashi Hayashita
312. Highly sensitive visual determination of
Cr(VI) by solid-phase colorimetry with a
PTFE type membrane filter.
Hitoshi Mizuguchi*, Takahiro Watanabe,
Atsushi Sasaki, Junichi Shida
313. Ultratrace determination of lead(II) in
water by electrothermal atomic absorption spectrometry after preconcentration
with a small piece of cellulose acetate
type membrane. Hitoshi Mizuguchi*,
Mirai Ishida, Tomohiro Takahashi,
Atsushi Sasaki, Junichi Shida
314. Novel hybrid adsorbents of alginate and
chemically modified silica gels and enrichment/separation of ultratrace metal
ions for ICP-MS. Kazuo Hirayama*,
Hitomi Fuda
315. Synthesis of thermosensitive gel incorporating monoaza-dithioether unit for the
extraction of class b metal ions.
Kenji Chayama*, Takumi Maehata,
Satoshi Iwatsuki
316. Withdrawn
317. Effect of substituents of ␤-diketones in
the synergistic extraction of rare-earth
ions with polyethers.
Gene Frederick D. Gagabe,
Keiichi Satoh, Kiyoshi Sawada*
318. Research on extraction, chemical compositions and bioactive effects of ostrich
oil. Van Men Chu*, Yu Seon Jang*,
Van Luong Hoang*, Tung Linh Nguyen,
Van Long Nguyen, Binh Duong Vu,
Young Ho Kim, Jong Seong Kang*
319. Development of a HPLC chromatographic method for the separation of phenolic lipids of esterified triacylglycerols
and phospholipids of krill oil. Sarya Aziz*,
Selim Kermasha
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
01-ANYL
320. Highly sensitive detection of cytochalasin E from white root rot infected plants
by precolumn derivatization coupled LCMS/MS. Masaya Kinomoto,
Naoko Inoue, Tooru Ooya,
Toshifumi Takeuchi*
321. Enantioselective analysis of ofloxacin
and ornidazole in pharmaceutical formulations by capillary electrophoresis using
single chiral selector and computational
calculation of their inclusion complexes.
Khaldun M. AL Azzam*,
Bahruddin Saad, Rohana Adnan
322. Separation at the solid level: The use of
density gradients. Bruce S. Hudson,
Jack Melton
323. Decomposition characteristics of hypochlorous acid and hypochlorite ion under
various preserving conditions.
Masatoshi Endo*, Rika Ishii,
Sachi Shiraiwa, Atsushi Sasaki,
Tatsuo Nishina, Junichi Kawashima
324. Thermal analysis of vitamin B6: EGA/
IAMS. Marta Juhasz, Toshiya Sato,
Toshihiro Fujii*
Convention Center
Kamehameha Halls II and III
New Frontiers in Separation Science (#113)
Organized by: T. Okada, P. Haddad,
M. Porter
Presiding: T. Okada
Poster Session
19:00 – 21:00
325. On-column solvent exchange for purified preparative fractions.
Gilles H. Goetz*, Emily Beck,
Peter W. Tidswell
326. QSPR modeling of thermodynamic parameters as a route to accurate modeling
of gas chromatographic retention times.
James J. Harynuk*, Bryan R. Karolat,
Rafal M. Gieleciak, Darcy B. Hager
327. Adsorptive protein refolding purification
using circulating fluidized bed.
Harpreet Kaur*, Amarjeet Bassi
328. Study on separation of rubidium and
strontium by ion-exchange chromatography for determination of their content and
isotopic composition using ICP-MS.
Minh H. Le, Trung V. Huynh,
Chien X. Nguyen
329. Temperature dependence in polymer
separation on ternary mobile phase in liquid chromatography.
Cuong Nguyen Viet, Bernd Trathnigg
330. Analysis of a solution of dispersant mixture by an ion mobility spectrometer coupled with a mass spectrometer.
Sung-Chan Jo*, Joon Seok K. Lee
331. Synthesis of a monolithic microhoneycomb with a low hydraulic resistance for
the efficient recovery of ammonia from
waste water. Takanobu Masuda,
Izumi Yamada, Shin R. Mukai*
332. Microscale electrophoresis of oligosaccharides using large-volume sample
stacking with electroosmotic flow pump.
Takayuki Kawai*, Kenji Sueyoshi,
Fumihiko Kitagawa, Koji Otsuka
333. Ion-selective nanomapping by atomic
force microscopy using tips modified
chemically with crown ether.
Wataru Taniwaki, Hitoshi Yano,
Shinpei Kado, Yoshio Nakahara,
Keiichi Kimura
334. Selective on-line preconcentration of
phosphopeptides by partially injected titania nanoparticles in capillary electrophoresis. Asako Matsuo, Kenji Sueyoshi,
Fumihiko Kitagawa*, Koji Otsuka
335. Simple and rapid on-site preconcentration and separation method using a solidphase extraction for the determination of
selenium(IV) and selenium(VI) in environmental waters. Minoru Okumura*,
Kunihiro Ando, Yasushi Seike
336. Chiral ice chromatography.
Taiki Shamoto*, Yuiko Tasaki,
Tetsuo Okada
337. Surface modification of titania by using
its thermal catalysis. Kazue Tani*,
Masatake Ozawa, Masaki Tachibana,
Hitoshi Koizumi
338. Separation and preconcentration of
trace amounts of tramp elements in irondigested solution by ion-exchange adsorption/ion-pair elution followed by
graphite furnace atomic absorption spectrometric determination. Nobuo Uehara*
339. Phosphate uptake by the adsorbent
prepared by calcining paper sludge.
Takaaki Wajima*, Kenzo Munakata
340. Femto to attoliter reactors evolved in
ice matrix. Takuya Hashimoto*,
Tetsuo Okada
341. Determination of phthalate esters in
physiological saline solution by an improved solid-phase extraction coupled to
ultra fast liquid chromatography with a
mass spectrometer. Lu Lu, Yuki Hashi,
Zhihua Wang, Jin-Ming Lin*
342. Application of transient trapping to peptide analysis in micellar electrokinetic
chromatography. Ryuta Tanaka*,
Kenji Sueyoshi, Fumihiko Kitagawa,
Koji Otsuka
343. Analysis of sialic acids by affinity capillary electrophoresis using specific interaction with tryptamines.
Risa Kusumoto*, Kenji Sueyoshi,
Fumihiko Kitagawa, Koji Otsuka
344. Acoustic separation of particles: Evaluation of chemical processes and 2-D separation in terms of material and size.
Takahiro Kanazaki*, Tetsuo Okada
345. Capillary chromatography based on
tube radial distribution of water-hydrophilic-hydrophobic organic mixture carrier solvents. Naoya Jinno,
Masahiko Hashimoto,
Kazuhiko Tsukagoshi*
346. Development of freeze-concentration
assisted liquid-phase microextraction for
the analysis of chlorophenols in water by
gas chromatography - electron capture
detection. Hou-Kuang Shih,
Jen-Fon Jen*
347. Retention behavior of aromatic amines
with ionic liquids as additive in semi-micro HPLC. Hitoshi Koizumi*,
Yuppadee Nusai, Yo Hasebe,
Masaki Tachibana, Kazue Tani,
Nobutoshi Kiba
348. Novel environment-friendly recycling
system of precious metals using proteinrich biomass. Yasuki Terashima,
Tatsuo Maruyama, Masahiro Goto,
Yoshikage Ohmukai, Hideto Matsuyama
349. Design of cellulose beads grafted with
cationic polymer for chromatographic
separation of DNA from protein solution.
Masayo Sakata*, Yuki Tatenaka,
Md Ashaduzzaman, Kei Ishikura,
Masashi Kunitake
350. Applications of microwave-assisted
C18 functionalized SBA-16 on high performance liquid chromatography for pesticides analysis. Youn Yuen Shu*,
Da-Kuei Chien, Tehlong Lai,
Jen Hsiuen Hsieh
351. Preparation of hydrophobized thermoresponsive copolymer brush grafted silica
beads as chromatographic stationary
phase. Kenichi Nagase*, Mio Kumazaki,
Jun Kobayashi, Akihiko Kikuchi,
Yoshikatsu Akiyama, Hideko Kanazawa,
Masahiko Annaka, Teruo Okano
352. Super-selective separation for steroids
using carbazole-based polymeric phase.
Kaori Shingo, Abul K. Mallik,
Usha G. Gautam, Tsuyoshi Sawada,
Makoto Takafuji, Hirotaka Ihara*
353. Investigation of adsorption behavior of
monocyclic hydrocarbons onto nonporous hydrophobic magnetite.
Takahiro Sasaki*, Shunitz Tanaka
354. Selectivity enhancement for shape-constrained isomers based on precise arrangement of weak interaction sites
through alternating copolymerization on
silica. Abul K. Mallik, Kaori Shingo,
Tsuyoshi Sawada, Makoto Takafuji,
Hirotaka Ihara*
355. New chiral discrimination method
based on intramolecular chirality propagation hypothesis. Yukiharu Fukushi*,
Noriko Okuda
356. CD and LD measurements of molecular
complexation of bilirubin at liquid/liquid
interface. Kimika Matsuura,
Hitoshi Watarai
357. Formation of chiral hetero-aggregate of
porphyrine at liquid-liquid interface.
Hideaki Takechi, Hitoshi Watarai
358. Conversion from chloroform to 1-butanol in a solvent extraction system using
4,5-bis(diphenylphosphinoyl)-1,2,3-triazole as a chelating agent for metal ions.
Shota Ono, Hiroshi Mukai
359. Binding and distribution analyses of organic cations to nonionic surfactant micelles in an aqueous solution through the
changes in electrophoretic mobility.
Toshio Takayanagi*, Ayumi Ikuta
360. Capillary electrophoretic reactor and
microchip capillary electrophoretic reactor: Capillary electrophoresis based direct
measurement method for the dissociation
kinetics of metal complexes and biomolecular complexes. Toru Takahashi*,
Nobuhiko IKi, Hitoshi Hoshino
361. Acid-base and complex formation reaction of aminopoly(methylenephosphonate) immobilized silica-gel.
Keiichi Satoh*, Kiyoshi Sawada
362. Enhancement of an analytical method
for the determination of siloxanes in biogas. Che-yun Eom*, Nam-Hoon Lee,
Sun-Ho Song, Sae-Rom Jeong,
Kwang-Bum Hur, Chae-Young Lee
363. Laws of polymers in liquid chromatography. Alexander Skvortsov*
Convention Center
Kamehameha Halls II and III
Analytical and Environmental Chemistry in
Human Health (#206)
Organized by: X.C. Le, G. Jiang, X. Li,
S. Richardson, L. Zhu
Presiding: C. Le
Poster Session
19:00 – 21:00
364. Development of a novel quantitative
GC/MS using multidimensional property
database. Naoki Sugimoto*,
Maiko Tahara, Reiji Kubota,
Kumiko Shimizu, Kazuichi Hayakawa,
Tetsuji Nishimura
365. Effects of rainfall on the concentrations
of fifteen trace elements in spring water
samples. Masayuki Gotoh*,
Yumi Manaka, Tadashi Furuhata,
Mikio Tosaka, Yu Asano
366. Fifteen trace elements in eluate from
aluminum and enamel cookware using
ICP-MS. Yumi Manaka*,
Masayuki Gotoh, Katsumi Kano,
Yu Asano
367. Rapid, convenient method for the separation of the components of gentamicin:
Synthesis of a single chemiluminescent
conjugate for gentamicin immunoassay.
Jonathan Grote*, Richard Himmelsbach,
Don Johnson
368. Environmental analysis and water quality exposure monitoring of Yamato river
water system using an in vitro bioassay
system in Japan. Akiyoshi Sawabe*,
Kazuki Ikushima, Katsuaki Sasai,
Ryuji Takeda, Ryo Kamata,
Shiho Kageyama, Daisuke Nakajima,
Fujio Shiraishi, Akira Iida
369. Interpreting and understanding the
elimination space of chemical biomarkers: A case study using the National
Health and Nutrition Examination Survey
dataset. Daniel T. Chang*,
Michael-Rock Goldsmith,
Rogelio Tornero-Velez, Yu-Mei Tan,
Jeffre C. Johnson, Shane D. Peterson,
Joachim Pleil, Curtis C. Dary
370. Air pollution at an urban tunnel in Lisbon, Portugal.
Maria do Carmo M. Freitas*,
Nuno Canha, Isabel Dionisio, Ho M. Dung
371. Determination of trace amounts of Cd,
Pb, Cr in drinking water by preconcentration of their polymeric dithiocarbamate
chelates on a micromembrane filter and
atomic adsorption analysis. Jun-ichi Itoh,
Rikoh Kamei, Tomoya Ueno,
Takahiro Tomonaga, Makoto Horikawa
372. Metabolism, toxicty of designer drug,
novel minor metabolites of ␣-methylfentanyl in rat. Shinichi Suzuki*,
Yasuhiro Suzuki
373. Withdrawn
374. Water state analysis in environmental
compatible thermo reversible hydrogels.
Yuko Nishimoto*, Yuichi Iitaka,
Toru Aikawa, Itsuro Takenoshita
375. Concentration and characteristics of
phthalates in indoor settled dust of Beijing area in China. Xiaoyi Wang*,
Xingtao Lin, Jingqiang Zhao, Ting Shen,
Xiaolei Yu, Shuying Wang
376. Determination of trace cerium in water
samples by ICP-AES after solid phase extraction on chelating fibrous sorbent.
Hiroaki Minamisawa*,
Hiromichi Asamoto,
Mayumi Minamisawa, Kazunori Saitoh,
Tatsuro Nakagama, Masami Shibukawa
377. Interaction between amino acids and
hypochlorous acid in the functional water.
Mao Yasutomi, Atsuo Iwasawa,
Yuko Nishimoto*
378. New microplate method for the quantitative evaluation of fibrinogen coagulation. Yidan Liu, Nanting Ni, Minyong Li,
Weixuan Chen, Binghe Wang*
379. Study on determination of chlorpyrifos
in fruits and vegetables using dispersive
liquid-liquid extraction combined with
high performance liquid chromatography-uv detection. Takehiro Kojima*,
Satoko Jyu-man, Nao Motizuki,
Yuka Mori
380. Analysis of nitro polycyclic aromatic hydrocarbons in atmospheric environment
by gas chromatography-mass spectrometry with negative ion chemical ionization
mode. Youn Yuen Shu, Hai-Ying Chien,
Wen-Wei Cheng, Yen-Heng Chen,
Colin S. Chen, Thomas C Yang,
Mu-Sheng Lee
381. Detecting viable but nonculturable E.
coli O157:H7 in water. Xing-Fang Li,
Yanming Liu, Chuan Wang, Feng Li
382. VOC-adsorption and desorption properties of woodceramics prepared from
cedar waste. Satomi Onuki,
Toshihiro Okabe, Takahisa Tsugoshi,
Yuko Nishimoto*
383. Discrimination of Polygonum mulfiflorum, Cynanchum wilfordii and Cynanchum auriculatum by genetic and chemical analysis. Changhee Cho,
Jong Hwa Lee*, Rack Seon Seong,
Ju Young Park, Young Hoon Shim,
Ji Yeon Kim, Seong Ye Hyeon,
Ji Sang Whang, Sun Ho Kim,
Dong Sup Kim, Wan Kyun Whang
384. Analysis and occurrences of pharmaceuticals and personal care products
from environmental samples.
Seung-Woon Myung*
385. Serum levels of perfluoroalkyl compounds in human maternal and umbilical
cord blood samples. Minkyun Kim*,
Jaeho Yang
386. Dissolved forms of metal ions and pHbuffering effect in the acidic river.
Eri Takahashi, Eishi Yoshikawa,
Atsushi Sasaki, Masatoshi Endo*
387. Predicting contaminant diffusion and
partitioning behaviours from time resolved membrane introduction mass
spectrometry. Megan Willis, Chris G. Gill,
Erik T. Krogh*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–57
01-ANYL
388. Combining chemical, electrical, and filtration strategies to isolate giant mitochondria. Scott P. Rose, Vratislav Kostal,
Edgar A. Arriaga*
389. Effect of pH on the interaction between
aluminium ions and poly(acrylic acid).
Mayumi Etou*, Yuka Masaki,
Shouqin Bai, Yoshihiro Okaue,
Takushi Yokoyama
390. Withdrawn
391. Application of stationary phase optimized liquid chromatography to peptides
separations. Dong-ying Chen*, Jing Lu,
Gerhard K. E. Scriba
392. Preparation metal alginates from algae
and their characteristic evaluation.
Jin-San Kim, Tara Sankar Pathak,
Ki-Jung Paeng
Convention Center
Kamehameha Halls II and III
Rapid, Multi-Component Environmental
Analysis (#253)
Organized by: R. Clement, F. Dorman,
N. Yamashita
Presiding: R. Clement
Poster Session
19:00 – 21:00
393. Determination of furfural content in preextraction stream of biomass by headspace gas chromatography. Hailong Li*,
Huaiyu Zhan, Xinsheng Chai, Mengru Liu,
Shiyu Fu
Convention Center
Kamehameha Halls II and III
Non- and Minimally-Invasive Diagnostics of
Biological Systems using Vibrational
Spectroscopy (#276)
Organized by: M.W. Blades, M. Michael,
H. Sato
Presiding: M. Blades
Poster Session
19:00 – 21:00
394. Optical biopsy: Simultaneous measurement of hyper spectral fluorescence image and Raman spectra. Hidetoshi Sato*
395. Nondestructive quantitative analysis of
body fatty acid compositions by Raman
spectroscopy. Retno Hariyani,
Akinori Taketani, Kazuki Minami,
Hidetoshi Sato
396. In situ analysis of live single cultured
cell using Raman spectroscopy.
Hiroshi Kosugi, Ken Kurokawa,
Yusuke Oshima, Hidetoshi Sato
Convention Center
Kamehameha Halls II and III
Enabling Mass Spectrometric Techniques
for Proteomics (#277)
Organized by: L. Li, D. Muddiman,
X. Qian
Presiding: L. Li
Poster Session
19:00 – 21:00
397. Development of off-line 2-D LC tandem
mass spectrometry for comprehensive
tissue proteome analysis. Nan Wang,
Liang Li
398. Laserspray ionization approaches for
rapid selection of singly and multiply
charged ions for improved protein identification. Charles N. McEwen,
Barbara S. Larsen, Sarah Trimpin
399. Specific substrates of cold inducible
chaperonin in hyperthermophilic archaeon Thermococcus kodakaraensis.
Le Gao, Atsushi Danno, Wakao Fukuda,
Tadayuki Imanaka, Shinsuke Fujiwara*
400. Simple and rapid proteolysis by protease-immobilized microfluidic reactor for
proteomic analysis. Masaya Miyazaki*,
Hiroshi Yamaguchi, Hideaki Maeda
401. Proteomic analysis of posttranslational
modifications at cysteine residues in signaling pathways. Kong-Joo Lee*,
Jaehoe Jeong, Jae Jin Lee, Eunsun Lee,
Eunok Paek, Hee-Jung Kim
58 –TECH
TECHNICAL PROGRAM
Friday Morning
9:25 – 417. Determination of polychlorinated
biphenyls, organochlorine pesticides,
chlorobenznes in sediment, soil and
sludge samples using GCxGC-ECD.
Alina Musclu, Eric Reiner, Steven Liss,
Tony Chen
9:45 – 418. Comprehensive chromatography
(GCxGC and LCxLC) for the analysis of
complex samples. Luigi Mondello*,
Peter Q. Tranchida, Giorgia Purcaro,
Paola Dugo, Giovanni Dugo
10:05 – 419. Comprehensive liquid chromatography from a practitioner’s perspective. Isabelle Francois*, Pat Sandra
10:30 – 420. Application of 2-D LC in pharmaceutical analysis.
C. J. Venkatramani*, Kavita Mistry,
Nicholas Chetwyn
10:50 – 421. Characterization of commercial
polymeric surfactants by 2-D liquid chromatography and MALDI TOF-MS.
Shazia Abrar*, Bernd Trathnigg
11:10 – 422. Multidimensional separations
with parallel capillary electrophoresis as
the second dimension.
Cameron D. Skinner, John D. Chin*
Convention Center
323C
Convention Center
301B
New Frontiers of Plasma Spectrochemistry
(#84)
Electroanalytical Sciences (#193)
402. 2-D SDS-PAGE and MALDI-TOF/TOF
MS analysis of nanoscale amounts of
bone matrix proteins.
Grazyna (Gyna) Sroga*,
Deepak Vashishth
403. Identification of Arg-gingipain inhibitors
in legume seeds, using targeted-proteomics approaches. Eiichi Saitoh*,
Mayumi Taiyoji, Kensuke Ohkubo,
Kasahara Hitoshi, Masayuki Taniguchi,
Sadami Ohtsubo
404. Novel 4-flex isobaric mass tags, PBAG
and ACYBAG, for quantitative proteomics. Yongsik Jung, Hee-Yoon Lee*,
Min-Soo Suh, Hye-Joo Yoon,
Seung Koo Shin
405. Nondestructive ionization method
based on ion association reaction in nonpolar solvent. Atsushi Takamizawa*,
Naoto Niizuma, Takashi Korenaga
406. Consequences of peptide dimethylation
on ion exchange separation and ionization efficiency: an optimization study.
Dennis Orton, Alan A. Doucette*
Organized by: N. Furuta, G. Hieftje,
R. Sturgeon
Presiding: G. Hieftje
7:30 Opening remarks
7:35 – 407. New directions and opportunities
in plasma source mass spectrometry.
David W. Koppenaal*,
Charles J. Barinaga, George J. Hager,
Martin Liezers, Tony Carado
8:15 – 408. Brand-new sample introduction
systems for bio/medical applications.
Akitoshi Okino*, Kaori Shigeta,
Takahiro Iwai, Yuichiro Takahashi,
Yuki Kaburaki, Yuta Negishi,
Hidekazu Mitahara
9:30 – 409. Analyte transport, solvent loading and nanoparticle vaporization: Implications for analysis of solutions and solids by ICP-OES and ICP-MS.
John W. Olesik*, Patrick Gray,
Elodie Linard, Josh Dettman
10:10 – 410. ICP spectrometry of micro- and
nanoparticles. Kay Niemax*
10:50 – 411. Effect of sample matrix on ion
transmission through the vacuum interface of an inductively coupled plasma
mass spectrometer.
Paul B. Farnsworth*, Ross Spencer,
Nicholas Taylor
Convention Center
317A
Comprehensive Multidimensional
Separations (#191)
Organized by: T. Gorecki, P. Marriott,
R. Synovec
Presiding: R. Synovec
7:30 – 412. Strategies for comprehensive
2-D gas chromatography analysis of essential oils. Philip J. Marriott*,
Sung Tong Chin,
Bussayarat Maikhunthod,
Christian Ruehle
7:55 – 413. Separation of elaidic and vaccenic acids in foods using GC⫻GC-time of
flight mass spectrometry. Jaeho Ha*,
Dongwon Seo, Dong-bin Shin,
Homoon Seog, Kwang-Won Lee
8:20 – 414. Addressing the challenges of analyzing trace alkyl phosphate contamination of petrochemical samples by
GC⫻GC. James J. Harynuk*,
Katie D. Nizio, Aleisha D. Rossé
8:45 – 415. Applications of multidimensional
separation in the petroleum industry.
Frank C. Wang*
9:05 – 416. GCxGC characterization of naturally produced organobromine compounds. Peter S. Haglund,
Karin Lofstrand, Lillemor Asplund
Organized by: K. Aoki, B. Liu, T. Osakai,
H. White
Presiding: K. Aoki
7:30 – 423. Interpretation of the potential response of polymer-membrane type ionselective electrodes based on ion-transfer voltammetry. Toshiyuki Osakai*,
Yoshitsugu Sato
8:10 – 424. Simultaneous voltammetric determination of nitrate and nitrite ions by
using a pretreated copper electrode.
Shovon M. Shariar*, Teruo Hinoue
8:30 – 425. Determination of concentration
and diffusion coefficient by the combination of regular and micro electrodes.
Jingyuan Chen*, Hua Zhang,
Koichi Aoki, Hirokazu Toda
8:50 – 426. Electrochemical sensor for tryptophan and serotonin using glassy carbon paste electrodes in the presence of
interfering substances.
Katsuhiko Nishiyama*, Akiko Kai,
Kazufumi Inada
9:10 – 427. Programmed release of aminecontaining molecules based on electroactive self-assembled monolayers.
Daewha Hong*, Kyungtae Kang*,
Seok-Pyo Hong, Insung S. Choi
9:30 – 428. Electrochemical aspects of laser
desorption ionization. Liang Qiao,
Baohong Liu, Hubert Girault
10:20 – 429. Electrochemical impedance to
analyze porous electrode in energy conversion devices. Masayuki Itagaki*,
Isao Shitanda, Kunihiro Watanabe
10:40 – 430. Electron-transfer number of oligomers having 1-step 2-electron transfer
units. Toyohiko Nishiumi*, Koichi Aoki
11:10 – 431. Determination of standard entropy change of ion transfer across 1,2dichloroethane|water interface by thermal
modulation voltammetry using visible laser heating. Teruo Hinoue*,
Hirosuke Tatsumi, Yui Terauchi
8:20 – 433. Single-molecule observation of
DNA conformational transition by microfluidic devices. Hiroshi Suzuki,
Noritada Kaji*, Yukihiro Okamoto,
Manabu Tokeshi, Yoshinobu Baba
8:40 – 434. Study of unique electrical conduction in extended-nano space using
streaming potential/current measurement. Kyojiro Morikawa*,
Kazuma Mawatari, Takehiko Tsukahara,
Takehiko Kitamori
9:00 – 435. Nanofluidic devices for characterizing individual DNA molecules.
J. Michael Ramsey*, Laurent D. Menard,
Chad E. Mair, Jean P. Allarie,
Hanno Weitering, Massimiliano Di Ventra
9:25 – 436. Extended-nano fluidic devices
for analytical and green chemistry.
Takehiko Kitamori*
9:50 – 437. Studies of transport with scanning probe techniques. Lane Baker,
Chiao-Chen Chen, Maks Derylo
10:15 – 438. Compatibility challenges for
performing PCR on PDMS microfluidic
chips. H. J. Crabtree*, Jana Lauzon,
Yuen Ching Wong, Tina Liang,
Robert W. Johnstone, Alex J. Stickel,
Dammika P. Manage,
Christopher J. Backhouse,
Linda M. Pilarski
10:40 – 439. Microfluidic devices for medical
diagnostics. Manabu Tokeshi*
11:05 – 440. Point-of-care diagnostics for
global health. Paul Yager*
Convention Center
301A
Enabling Mass Spectrometric Techniques
for Proteomics (#277)
Organized by: L. Li, D. Muddiman,
X. Qian
Presiding: P. Yang
8:00 – 441. Ultrahigh mass resolution extends the reach of structural analysis for
proteins and their complexes.
Alan G. Marshall, Greg T. Blakney,
Mark R. Emmett, Neil L. Kelleher,
Christopher L. Hendrickson
8:30 – 442. Non-stick proteomics: ammonium perfluorooctanoate as substitute for
SDS. Alan A. Doucette*, D. B. Vieira,
A. Crowell
9:00 – 443. Microbial glycosylation: The
outer surface of the archaeon Methanosarcina mazei. Deborah R. Francoleon,
A. J. Ytterberg, Pinmanee Boontheung,
Unmi Kim, Patricia A. Denny,
Paul C. Denny, Joseph A. Loo,
Robert Gunsalus, Rachel O. Loo*
9:30 – 444. Characterization of N-glycosylation in the extracellular region of CD44s
and exploration of its recognination
mechanism by LSECtin. Xiaohong Qian,
Huanhuan Han*, Yangjun Zhang
10:00 – 445. N-glycoproteome: Interpreting
information of N-glycosites and corresponding glycan compositions/structures
from mass spectrometric outputs.
Pengyuan Yang*, Yaohan Chen
10:30 – 446. Middle-down proteomic analysis: A status check. Catherine Fenselau*
Convention Center
305A
Microfluidic and Nanofluidic Devices for
Chemical and Biochemical Experimentation
(#198)
* Principle Author
Organized by: H.J. Crabtree, Y. Baba,
S. Jacobsen, J.M. Ramsey
Presiding: S. Jacobson, L. Baker
8:00 – 432. Ultra rapid flow-through PCR
system with disposable electrochemical
printed chip. Yusuke Fuchiwaki,
Masato Saito, Shin-ichi Wakida,
Eiichi Tamiya, Hidenori Nagai*
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
01-ANYL
11:00 – 447. Top-down mass spectrometry
of charge-enhanced proteins and protein-ligand complexes.
Sabrina A. Benchaar,
Rajeswari Lakshmanan, Sheng Yin,
Rachel R. Ogorzalek Loo,
Joseph A. Loo*
Friday Afternoon
Convention Center
323C
New Frontiers of Plasma Spectrochemistry
(#84)
Organized by: N. Furuta, G. Hieftje,
R. Sturgeon
Presiding: N. Jakubowski
12:30 – 448. Sources, spectrometers, and
systems for plasma spectrochemistry.
Gary M. Hieftje, Eyal Elish,
Carsten Engelhard, Jeremy A. Felton,
Alexander W. Graham,
Meghan C. McCormick, Kevin P. Pfeuffer,
Steven J. Ray, Jacob T. Shelley,
Christie G. Enke, David W. Koppenaal,
Charles Barinaga
13:10 – 449. Characterization of nanolayered
materials using a pulsed-radiofrequency
glow discharge plasma coupled to a time
of flight mass spectrometer.
Jorge Pisonero*, Nerea Bordel,
Alfredo Sanz-Medel,
Antonino Licciardello, Agnes Tempez
13:50 – 450. Novel mass analyzers and excitation sources for atomic spectroscopy.
Steven J. Ray, Elise Dennis,
Alex Graham, Eyal Elish, Gary M. Hieftje*,
Christie Enke, Charles Barinaga,
David Koppenaal
15:05 – 451. Photochemical vapor generation: Status and prospects.
Ralph E. Sturgeon*, Chengbin Zheng,
Xiandeng Hou
15:45 – 452. Development of high performance concentric nebulizer for ICP-OES
and ICP-MS. Kazumi Inagaki,
Shin-ichiro Fujii, Koichi Chiba*
Convention Center
301B
(Bio-)Chemical/Electrochemical Sensors
and Sensing Materials (#255)
Organized by: K. Suzuki, E. Bakker,
P. Buhlmann, D. Citterio, O. Niwa
Presiding: K. Suzuki, D. Citterio
12:30 Opening remarks
12:35 – 453. Electrochemiluminescent microarrays for multiplexed detection.
David Walt*, Christopher LaFratta,
Elena Benito Peña, Frederique Deiss,
Neso Sojic, Guillermo Orellana,
Matthew Symer
13:05 – 454. Withdrawn
13:25 – 455. Sol-gel film containing metal
and semiconductor nanoparticles for gas
sensing. Alessandro Martucci*,
Enrico Della Gaspera, Dario Buso
13:45 – 456. Sol-gel immobilized porous
nanocapsules for sensor applications.
Bill Ganus, Erno Lindner,
Eugene Pinkhassik*
14:05 – 457. Multipoint fiber-optic hydrogen
gas sensor. Shinji Okazaki*,
Hidemoto Nakagawa, Murata Kenji,
Kenzo Fukuda
14:25 – 458. Abasic site-based DNA aptamers for analytical applications.
Seiichi Nishizawa, Norio Teramae
14:45 – 459. Conjugation of quantum dots
and aptamers on an optical fibre for cocaine detection. Ewan K. Galbraith*,
Tong Sun
15:05 – 460. Optical sugar sensing film
based on competitive binding between
boronic acid receptor and functional dye
immobilized on hydrogel matrix.
Koji Tohda*, Noriyuki Goshima,
Tomoyo Kosaka
15:25 – 461. Optical technology using solidphase microextraction and fluorescence
detection for on-site monitoring of bacteria in water. R. Stephen Brown*,
Eric J. Marcotte, Christine E. Dunkinson,
W. Peter Aston, Douglas Wilton,
Peter Gallant
15:45 – 462. Molecule recognition by fluorescent ligands using abasic site-containing oligonucleotides. Norio Teramae*
Convention Center
317A
Novel Applications of Magnetic Fields in
Analytical Chemistry (#260)
Organized by: H. Watarai, I. Fritsch,
C.B. Fuh, B. Yellen
Presiding: C. Fuh, H. Watarai
12:30 Opening remarks
12:35 – 463. Magnetic and electromagnetic
separation, detection, and imaging.
Hitoshi Watarai*
12:55 – 464. Simultaneous measurement of
natural and magnetic optical rotation under pulsed magnetic field.
Masayori Suwa*, Kayoko Miyamoto,
Yusuke Nakano, Hitoshi Watarai
13:15 – 465. Redox-magnetohydrodynamic
microfluidics. Melissa C. Weston,
Matthew D. Gerner, Christena K. Hooten,
Cajon Gonzales, Vishal Sahore,
Ingrid Fritsch*, Kakkattukuzhy M. Isaac,
Nicholas Leventis
13:40 – 466. Magnetic field effects in electrochemical reactions. Gerd Mutschke*,
Denis Koschichow, Ralf Peipmann,
Andreas Bund, Jochen Fröhlich,
Tom Weier, Kristina Tschulik,
Margitta Uhlemann
14:00 – 467. Magnetic field effect as a tool
for identification of pathways of photoinduced reactions with radical pairs as
transient intermediates in organized assemblies. Brotati Chakraborty,
Samita Basu*
14:20 – 468. In situ optical observation and
numerical analysis of the behavior of feeble magnetic particles under high magnetic fields. Noriyuki Hirota*,
Tsutomu Ando, Yoshio Sakka
14:40 – 469. Magnetically induced modulations of light scattering in chromatophores of goldfish scale.
Masanobu Kudo, Masakazu Iwasaka*,
Satoru Kurita, Norio Owada
15:00 – 470. Recognition of molecular chirality by magnetoelectrodeposited metal
films. Iwao Mogi*
15:20 – 471. Magneto-lithography-patterning beyond flat and uniform surfaces.
Ron Naaman, Amos Bardea,
Anand K. Tatikonda
15:40 – 472. Magnetic response of aqueous
systems and analytical aspects.
Yuta Honma, Govindachetty Saravanan,
Tomohisa Matsushita, Atom Hamasaki,
Sumio Ozeki*
16:05 – 473. New method of high-resolution
electron spin resonance using a microcantilever. EIji Ohmichi*, Shuya Hirano,
Noriaki Mizuno, Hitoshi Ohta
Convention Center
305A
Recent Advances in Bioanalysis: UltraSmall Volumes, Global Metabolite Profiling
and Single Cells (#56)
Organized by: D. Chiu, S. Boxer,
P. Britz-McKibbin, T. Matsunaga,
K. Otsuka, G. Zhou
Presiding: D. Chiu
12:45 Introductory remarks
12:50 – 474. Controlling the rates of biochemical reactions and signaling networks by shape-and-volume changes.
Owe Orwar*
13:25 – 475. High-resolution, quantitative
signalling assay for G-protein-coupled receptors by flow cytometry.
Akihiko Kondo*, Jun Ishii,
Nobuo Fukuda, Chiaki Ogino
13:45 – 476. Artificial cells to study the basic
cell function of exocytosis.
Ann-Sofie Cans, Michael Kurczy,
Lisa Simonsson, Kelly Adams,
Carina Berglund, Fredrik Höök,
Andrew Ewing
14:20 – 477. Gold nanoparticle-based SERS
spectroscopy of embryonic stem cell differentiation process.
Sathuluri Ramachandra Rao,
Hiroyuki Yoshikawa*,
Mohammad Mosharraf Hossain,
Eiichi Tamiya
14:40 – 478. Digital microfluidics for chemistry, biology, and medicine.
Aaron Wheeeler*
15:15 – 479. Magnetic micro-analysis of
droplet interface and cell surface.
Hitoshi Watarai*
15:50 – 480. High-density microwell arrays
for studying cell populations at the single
cell level. David Walt*,
Ragnhild Dragoey Whitaker,
Aaron Phillips
16:25 Closing remarks
Convention Center
301A
Enabling Mass Spectrometric Techniques
for Proteomics (#277)
Organized by: L. Li, D. Muddiman,
X. Qian
Presiding: Y. Ishihama
13:00 – 481. Enzymology and proteomics
collide and a new method for discovery of
natural products is born. Neil Kelleher,
Bradley Evans, Stefanie Bumpus,
Ioanna Ntai, Yunqiu Chen,
Jessica Albright, Paul Thomas
13:30 – 482. Development of technology and
methods for large-scale phosphoproteome analysis. Hanfa Zou*,
Mingliang Ye, Xinning Jiang,
Guanghui Han, Fangjun Wang
14:00 – 483. Desorption ionization of peptides and metabolites from tunable nanoporous GLAD films. Jed Harrison*,
Abebaw Jemere, Louis Bezuidenhout,
Michael Brett
14:30 – 484. Laserspray ionization: A new
approach for protein characterization.
Sarah Trimpin
15:00 – 485. Automated refinement of mass
spectrometry instrument methods for targeted proteomics. Brendan MacLean,
Daniela Tomazela, Matt Chambers,
David Tabb, Daniel Liebler,
Michael MacCoss*
15:30 – 486. One-shot proteomics to unveil
the expressed proteome and phosphoproteome on a microarray scale.
Yasushi Ishihama*
16:00 – 487. LC/MS-based shotgun method
for whole proteome analysis. Liang Li
492. Development of the mass spectrometer
equipped with ECRIS and its application
to the isotopic analyses. Masanori Kidera,
Masayoshi Toda, Mika Makita,
Yohei Mitsubori, Tatsuhiko Tanaka,
Kazuya Takahashi*
493. Development of discharge-emission
spectrometer system with ion generable
equipment. Megumi Mizumura,
Hiromichi Yamabe, Erika Hayakawa,
Mitunori Araki, Kouichi Tsukiyama
494. Use of high-resolution mass spectrometry and atmospheric-pressure chemical
ionization for elemental speciation of aviation fuel. Duane A. Rogers*,
Robert E. Morris, Kevin J. Johnson
495. Capillary electrophoresis-mass spectrometry for metal speciation with matrix
solution. Masashi Wakasugi*,
Tatsuya Urabe, Tomohiro Oikawa,
Miho Tanaka
496. Laser induced plasma dynamics in air
using homogenized femtosecond laser
pulses. Osman Sorkhabi*, Xianglei Mao,
Travis N. Owens, Jhanis J. Gonzalez,
R. E. Russo
497. Sample introduction into a flowing nitrogen post discharge and kinetics studies.
Aleš Hrdlika*, Markéta Procházková,
Vítezslav Otruba, Viktor Kanický,
František Krma, Vera Mazánková,
Ivana Bocková
498. Improvement of the capabilities of inductively coupled plasma spectrometry
by replacing the desolvation system of an
ultrasonic nebulization system with a preevaporation tube. Christian Agatemor,
Asfaw Alemayehu, Diane Beauchemin
499. Microwave-assisted sample preparation for trace inorganic analysis.
Joaquim A. Nobrega*, Cezar A. Bizzi,
Erico M. Flores, Rochele S. Picoloto,
Juliano S. Barin
500. Spectrochemistry at plasma/liquid interfaces(1): Construction of a confocal
microscope equipped with a custommade discharge cell. Hiroharu Yui*,
Yuta Kusama, Hisaya Kato, Yuu Someya
501. Spectrochemistry at plasma/liquid interfaces(2): Spatial distribution of electron
density and electron temperature.
Yuta Kusama, Hisaya Kato,
Yuu Someya, Hiroharu Yui
502. Spectrochemistry at plasma/liquid interfaces(3): Time-evolution of H and OH
radicals. Yuu Someya, Hisaya Kato,
Yuta Kusama, Hiroharu Yui
503. Direct evidence of He-induced excitation process of H atoms in cooled laser
plasma. Koo H. Kurniawan*,
Kiichiro Kagawa
Convention Center
Kamehameha Halls II and III
Electroanalytical Sciences (#193)
Friday Evening
Organized by: K. Aoki, B. Liu, T. Osakai,
H. White
Presiding: K. Aoki
Convention Center
Kamehameha Halls II and III
Poster Session
19:00 – 21:00
New Frontiers of Plasma Spectrochemistry
(#84)
504. Selective determination of corrosion
products on copper by voltammetry using a strongly alkaline electrolyte.
Shigeyoshi Nakayama*,
Takenori Notoya, Toshiyuki Osakai
Organized by: N. Furuta, G. Hieftje,
R. Sturgeon
Presiding: N. Furuta
Poster Session
19:00 – 21:00
488. Circulation of silica from river to ocean:
Study on chemical species by FAB-MS.
Miho Tanaka, Kazuya Takahashi
489. Chemical speciation of aluminum and
chromium in the process of coprecipitation by ESI-MS. Tatsuya Urabe*,
Miho Tanaka
490. Characterization on dissolution of lead
and tin chemical speciation by ESI-MS.
Akihiro Muraoka, Tatsuya Urabe,
Miho Tanaka
491. Identification and quantitation of pharmaceutical material by halogenated and
organometallic speciation using LCICP-MS and LC-LTQ/Orbitrap MS.
Bradley J. Shaw*, Gary Guo,
David Semin
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–59
01-ANYL
505. Novel L-aspartate amperometric biosensensing using thermostable L-aspartate dehydrogenase. Yosuke Okezaki,
Haitao Zheng, Kazunari Yoneda,
Haruhiko Sakuraba, Toshihisa Ohshima,
Shin-ichiro Suye*
506. Evolution of L-aspartate dehydrogenase for optimum pH shift using errorprone RCA for biosensing.
Kayo Yamaguchi, Yosuke Okezaki,
Kazunari Yoneda, Haruhiko Sakuraba,
Toshihisa Ohshima, Shin-ichiro Suye*
507. Fabrication of gold nanoparticle-spacemodified electrodes.
Daisuke Nakashima, Munetaka Oyama*
508. Cyclic voltammetry at glassy carbon
and gold electrodes treated by laserpulse irradiation. Taito Nakazawa*,
Yuko Wada, Teruo Hinoue
509. Cyclic voltammetry of meso-tetrakis(Nmethylpyridinium-4-yl)porphyrin and
meso-tetraphenylporphyrin on carbonnanotube-modified electrodes.
Setsuko Kudo*, Masamichi Hirokawa,
Satoki Goto, Takaaki Eyama
510. Electrochemical control of the bioluminescence by bacterial luciferase by using
modified gold electrode. Shuto Yamada*,
Shinya Yamasaki, Tatsuya Suyama,
Ko Takehara
511. Identification of electrochemically deposited species of metal ions in the presence of chelating agents in solution by
using a cyclic voltammetry combined
with the time differential QCM method.
Kenta Takagi, Toru Ozeki*
512. Microelectrode voltammetry in viscous
solution of polyethylene glycols. Yi Guo
513. Alkaline ion effects on photocatalytic
reactions at titania/electrolyte solution interface observed by quartz crystal microbalance method and microscope
electrophoresis. Yoshikiyo Kato*,
Yasuhiro Hashimoto, Hiroki Koike
514. Double electrode fabricated with plural
layers of microporous membrane electrodes. Hitoshi Mizuguchi*,
Kanako Shibuya, Azumi Fuse,
Tomoko Hamada, Masamitsu Iiyama,
Kazuhiro Tachibana, Tatsuo Nishina,
Junichi Shida
515. Highly sensitive determination of metal
ions by stripping voltammetry with microporous membrane electrodes.
Hitoshi Mizuguchi*, Chiaki Monma,
Masamitsu Iiyama, Kazuhiro Tachibana,
Tatsuo Nishina, Junichi Shida
516. On line monitoring system of metallic
impurity in concd alkaline solutions by
anodic stripping voltammetry with microporous membrane electrodes.
Hitoshi Mizuguchi*, Toru Hisamatsu,
Masamitsu Iiyama, Kazuhiro Tachibana,
Tatsuo Nishina, Junichi Shida
517. Amperometric measurement of ␣-glucosidase activity using hydroquinone-␣D-glucopyranoside as substrate.
Kojiro Miki*, Makoto Horii,
Tatsuro Hayashi
518. Synchronization of multiple potential
oscillations in liquid membrane systems.
Yoshihide Tatsuno, Yumi Yoshida,
Kohji Maeda
519. STM and voltammetric studies of the
formation process of phase-separated binary self-assembled monolayers on gold.
Suguru Murayama*, Yuki Kitazumi,
Naoya Nishi, Takashi Kakiuchi
Convention Center
Kamehameha Halls II and III
Microfluidic and Nanofluidic Devices for
Chemical and Biochemical Experimentation
(#198)
Organized by: H.J. Crabtree, Y. Baba,
S. Jacobson, J.M. Ramsey
Presiding: H. Crabtree, S. Prakash
Poster Session
19:00 – 21:00
520. High sensitive DNA detection with the
combination of two kinds of fluorescent
dyes by microchip electrophoresis.
Yuka Yamaguchi, Shouki Yatsushiro,
Shohei Yamamura, Kaori Abe,
Yasuo Shinohara, Masatoshi Kataoka
60 –TECH
TECHNICAL PROGRAM
521. Microfluidic approach for anticancer
drug analysis based on hydrogel encapsulated tumor cells. Dan Gao*,
Jin-Ming Lin*
522. Microfluidic hydrogel for more flexible
cell-based applications. Yan Xu,
Kihoon Jang, Kazuma Mawatari,
Tomohiro Konno, Kazuhiko Ishihara,
Takehiko Kitamori*
523. New method for label-free detection of
biomolecules using nanostructures.
Takao Yasui*, Noritada Kaji,
Yukihiro Okamoto, Manabu Tokeshi,
Yasuhiro Horiike, Yoshinobu Baba
524. Development of a microchip-based
southern hybridization analysis system.
Kiichi Sato*, Keisuke Aono,
Etsuro Yoshimura
525. Analysis of a single molecular enzymatic reaction by micro- and nanofabricated structures. Kazuki Iijima*,
Noritada Kaji, Yukihiro Okamoto,
Manabu Tokeshi, Yoshinobu Baba
526. Microfluidic sensor for the detection of
double- and single-stranded DNA binding
proteins by the changes of fluorescence
intensity. Wang Jun*, Okamoto Yukihiro,
Kaji Noritada, Tokeshi Manabu,
Baba Yoshinobu
527. Microfluidic device for single embryo
coculture with microporous membranesupported endometrial cells.
Hiroshi Kimura*, Hiroko Nakamura,
Tomonori Akai, Takatoki Yamamoto,
Hideshi Hattori, Yasuyuki Sakai,
Teruo Fujii
528. Microfluidic dorsal root ganglia neuronal culturing for imaging nerve growth
factor transport. Yasuko Osakada,
Kai Zhang, Bianxiao Cui*
529. Selective adhesion of target cancer
cells from red blood cell suspension using a peptide aptamer-coated microfluidic device. Shohei Kaneda,
Tamiko Minamisawa, Kiyotaka Shiba,
Teruo Fujii*
530. Detection of non-fluorescent molecules
in extended nanochannel using differential interference contrast thermal lens microscope. Hisashi Shimizu*,
Kazuma Mawatari, Takehiko Kitamori
531. Development of easy-to-use microchip
for therapeutic drug monitoring.
Kanako Sugiura*, Noritada Kaji,
Yukihiro Okamoto, Manabu Tokeshi,
Yoshinobu Baba
532. Development of micro-gas analyzer
with a high efficient extraction unit for onsite monitoring. Shinichiro Hiki*,
Maki Saito, Isao Tanaka,
Kazuma Mawatari, Takehiko Kitamori
533. Stable coating using Nafion thin membrane for fast electroosmotic flow in
PDMS microchips. Mariko Seno,
Kenji Sueyoshi, Fumihiko Kitagawa,
Koji Otsuka
534. Study on microchip electrophoresis of
proteins using microheater integrated
PDMS chip. Kana Tanigawa,
Kenji Sueyoshi, Fumihiko Kitagawa,
Koji Otsuka
535. Effect of buffer pH value on concentration polarization near microchannelnanochannel interfaces.
Cheng-Peng Yeh, Ruey-Jen Yang*
536. Structure analysis of water confined in
extended-nano space by Raman spectroscopy. Takuya Murao,
Kazuma Mawatari, Takehiko Kitamori*
537. Polyelectrolyte coating for poly(dimethylsiloxane) microchip capillary electrophoresis. Yan Liu*, Zachary D. Kihm
538. Rapid and sensitive analysis based on
transient trapping in microchip electrophoresis. Kenji Sueyoshi*,
Fumihiko Kitagawa, Koji Otsuka
539. High efficient extraction of DNA in
blood plasma using microfluidic devices.
Tatsuki Sano, Yukihiro Okamoto,
Noritada Kaji, Manabu Tokeshi,
Yoshinobu Baba
540. Microfluidic device with tilted micropost
array for cell concentration.
Toyohiro Naito*, Noritada Kaji,
Yukihiro Okamoto, Manabu Tokeshi,
Yoshinobu Baba
541. Microfluidic devices for the radiometal
labeling of biomolecules.
David E. Reichert*, Dexing Zeng,
Birce Onal, Tobias D. Wheeler,
Amit V. Desai, Paul J. Kenis
542. New microdevice to rapidly constract
multifunctional envelope-type nanodevice for gene therapy. Katsuma Kitazoe,
Yukihiro Okamoto*, Noritada Kaji,
Manabu Tokeshi, Kentaro Kogure,
Hideyoshi Harashima, Yoshinobu Baba
543. Observation of solid surfaces modified
with proteins and antibody through
chemical linkers. Kengo Hanaya*,
Megumi Tsunoda, Takuma Sasaki,
Shiro Koyota, Norito Kotani,
Shinya Ariyasu, Akikazu Murakami,
Takachika Azuma, Ryo Abe,
Toshihiro Suzuki, Masanori Hayase,
Takao Okada, Shin Aoki
544. Development of microfluidic chip for
continuous-flow droplet generation and
fusion and its application for protein crystallization. Masatoshi Maeki,
Masaya Miyazaki*, Hiroshi Yamaguchi,
Hideaki Maeda
545. Microchamber array for cell-free protein
synthesis from single DNA molecules.
Soo Hyeon Kim, Yannick Rondelez,
Shoji Takeuchi, Satoko Yoshizawa,
Dominique Fourmy, Teruo Fujii*
546. Development of the interface for single
cell analysis in the extended-nano space.
Kentaro Shirai*, Yo Tanaka,
Yasuhiko Sugii, Kazuma Mawatari,
Takehiko Kitamori
547. Microfluidic chip-capillary electrophoresis for separation and determination of
low abundance proteins. Ruige Wu,
Ying Sing Fung, William S. B. Yeung
548. Development of membrane-assembled
microdevice for high-throughput bioanalysis. Kenji Sueyoshi, Saeko Kinami,
Fumihiko Kitagawa, Koji Otsuka
549. Detection of polychlorinatedbiphenyl by
using antibody-bound fluoroplastic capillary bundle structure. Yoshiaki Ukita,
Chiwa Kataoka, Masahiro Takeo,
Seiji Negoro, Yuzuru Takamura,
Yuichi Utsumi
550. Development of the microfluidic concentration chip of nucleated red blood
cell for fetal DNA diagnosis from maternal
blood. Takeshi Kumo*, Yuichi Tomizawa,
Yoshiaki Ukita, Mikiko Kita,
Haruo Takabayashi, Eiichi Tamiya,
Yuzuru Takamura
551. Monitoring of nanoparticle reactions inside a room-embedded microchip.
Yuri Shoji*, Mihoshi Suginobu,
Takeshi Eitoku, Kenji Katayama
552. Integration of highly efficient gene analysis system on a microchip.
Jun Wakabayashi*, Yo Tanaka,
Kae Sato, Kazuma Mawatari,
Tanaka Yuki, Mats Nilsson,
Takehiko Kitamori
Convention Center
Kamehameha Halls II and III
(Bio-)Chemical/Electrochemical Sensors
and Sensing Materials (#255)
Organized by: K. Suzuki, E. Bakker,
P. Buhlmann, D. Citterio, O. Niwa
Presiding: K. Suzuki, D. Citterio
556. Targeting of an intracellular protein by
confocal light scattering imaging of antibody-tagged gold nanoparticle.
Kentaro Sato, Kazuhiko Fujiwara*,
Yusuke Yatsurugi, Sou Yamamoto,
Hideaki Itoh, Nobuaki Ogawa
557. Engineered post-synapse model cell
and characterize it as functional model
for neural drug high through-put analysis.
Akito Tateishi, Satoshi Migita,
Kari Keinänen, Shinya Ikeno,
Tetsuya Haruyama*
558. Inhibitor effects on mitochondrial bioelectrocatalysis. Caitlin N. Fischer,
David Wentzel, Marguerite Arechederra,
Shelley Minteer
559. Novel tumor-specific imaging method
via genetically expressed tags.
Takuya Mashiba, Yuki Hasegawa,
Aki Honda, Daniel Citterio, Koji Suzuki*
560. Silver core gold shell nanoprobes used
for the detection of DNA through an ultrasensitive SERS based technique.
Thuy T. Nguyen, Derrick Mott,
Yoshiya Aoki, Prerna Singh,
Kenzo Fujimoto, Mikio Koyano,
Shinya Maenosono*
561. Direct visual detection of DNA using
dendritic aggregation of silica nanoparticles. Jing Yu Piao, Eun Hee Park,
Kihwan Choi, Bo Quan, Doo Soo Chung*
562. Resonant light scattering imaging of
protein functionalized gold nanoparticle
in a biological cell. Kazuhiko Fujiwara*,
Yusuke Yatsurugi, Kentaro Sato,
Sou Yamamoto, Hideaki Itoh,
Nobuaki Ogawa
563. Nanoparticle diffraction for in situ DNA
detection on nanoscale DNA patterns.
Yulin Chen
564. Comparison of the nonspecific binding
of DNA-conjugated gold nanoparticles
between polymeric and monomeric selfassembled monolayers. Jagotamoy Das,
Jinkyung Jo, Sanyong Jon,
Haesik Yang*
565. Novel labeling reagents for combined
immuno-chemical sensing.
Yuta Katayama, Koji Abe, Koji Suzuki,
Daniel Citterio*
566. Detection of influenza virus RNA amplified by RT-PCR using immunochromatographic assay. Genki Maeda,
Keiichiro Yamanaka, Masato Saito,
Ritsuko Koketsu, Tadahiro Sasaki,
Kazuyoshi Ikuta, Eiichi Tamiya,
Toshiro Miyahara, Naoki Nagatani*
567. Phosphorothioate DNA self-assembly
developed on gold substrates as characterized by IR, ellipsometry, microgravimetric analysis, and AFM for application
to SNPs bioassay taking advantage of
supramolecular conformation transitions.
Hisao Yoshinaga, Koji Nakano*,
Takayuki Kimura, Nobuaki Soh,
Toshihiko Imato
568. Photochromic micelles as a potential
magnetic resonance imaging-visible drug
delivery system. Yushi Heta,
Kentaro Kumaki, Hiroki Hifumi,
Daniel Citterio, Akihiro Tanimoto,
Koji Suzuki*
569. Optical detection of enzyme reactions
by using a fluorogenic liposome.
Tomohiro Miyatake, Hiroto Murata,
Sakie Tojo, Stefan Matile
Poster Session
19:00 – 21:00
553. Diversity of FAD dependent glucose dehydrogenases and their potential application for the glucose enzyme sensors.
Yuki Anze, Mitsuharu Nakajima,
Kazushige Mori, Koji Sode*
554. Biomolecular engineering of multiheme
cytochrome c responsible for direct electron transfer capability of glucose dehydrogenase complex. Anna Imai,
Katsuhiro Kojima, Wakako Tsugawa,
Stefano Ferri, Koji Sode*
555. Real-time monitoring of L-lactic acid
levels in fish by enzyme sensor system.
Hideaki Endo*, Kengo Hatanaka,
Huifeng Ren, Kyoko Hibi
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
01-ANYL
570. Template-directed formation of luminescent lanthanide complex using the
DNA probes and application to gene
analysis. Nobuhiko Kaihara,
Yusuke Kitamura*, Takeshi Tomimori,
Toshihiro Ihara, Makoto Chikira
571. Highly strong binding of 2-amino-1,8naphthyidines to an abasic site in RNA
duplex and their application to the detection of noncoding microRNA.
Megumi Kudo*, Yusuke Sato,
Seiichi Nishizawa, Norio Teramae
572. Fluorescent-signaling small ligands for
HIV-1 TAR RNA. Yuka Chinda,
Yusuke Sato, Seiichi Nishizawa,
Norio Teramae
573. Design of label-free molecular beacons
based on an abasic site-binding fluorescent molecule. Yusuke Sato*,
Seiichi Nishizawa, Norio Teramae
574. 2-Amino-1,8-naphthyridines as a fluorescent signaling ligand for A-site RNA.
Masafumi Rokugawa*,
Toshiki Ichihashi, Yusuke Sato,
Seiichi Nishizawa, Norio Teramae
575. Aptasensor based on regulation of abasic-site-binding ligand fluorescence.
Zhiai Xu*, Yusuke Sato,
Seiichi Nishizawa, Norio Teramae
576. Fluorescent imprinted polymer films for
human serum albumin. Yuuki Inoue,
Hirobumi Sunayama, Tooru Ooya,
Toshifumi Takeuchi*
577. Withdrawn
578. Long-wavelength fluorescent probe for
alkaline phosphatase. Ken Ikegami,
Keitaro Umezawa, Daniel Citterio,
Koji Suzuki*
579. Development of electrogenerated
chemiluminescence-based enzyme
linked immunosorbent assay for determination of disease markers. Ryoji Kurita*,
Kumi Arai, Kohei Nakamoto, Dai Kato,
Osamu Niwa
580. Aptamer-based thrombin detection by
the DNA-assisted inhibition of enzyme.
Josui Shimada*, Tatsuo Maruyama,
Noriho Kamiya, Masahiro Goto
581. Development of fluorescent reagents
for the detection of proteins and their application to high-throughput protein analysis. Yoshio Suzuki*, Kenji Yokoyama
582. Novel luciferin-based bright chemiluminescent probe for the detection of reactive oxygen species. Maki Sekiya*,
Keitaro Umezawa, Akemi Sato,
Daniel Citterio, Koji Suzuki
583. Synthesis of diazacrown ether derivatives having two pyrene or perylene moieties and detection of alkali metal ions.
Yukihiro Nishimura*, Sadao Arai
584. Acid-base equilibria of a series of pH indicator dyes entrapped inside mesoporous silica. Manato Namekawa*,
Toshio Kamijo, Akira Yamaguchi,
Norio Teramae
585. Development of polymeric nanoparticle-based sensing inks and inkjetprinted health care chips. Kaori Kotera,
Koji Abe, Koji Suzuki, Daniel Citterio*
586. Fluorescent sensing of pH and/or dissolved oxygen using membranes made
from polymerizable sensing monomers.
Yanqing Tian*, Bradley R. Shumway,
Deirdre R. Meldrum
587. Ion optodes based on fluoroionophores
immobilized to a mesoporous silica thin
film. Yuki Hiruta, Yosuke Ando,
Daniel Citterio, Koji Suzuki*
588. Modification of mesoporous silica
membrane with Schiff-base ligands for
Cu(II) ion sensing. Xiaotong Chen*,
Manato Namekawa, Toshio Kamijo,
Akira Yamaguchi, Norio Teramae,
Aijun Tong
589. Fabrication of cyclodextrin-functionalized nanoporous membrane and application for enantiometric separation.
Shohei Yoshikawa*, Hiroyuki Arafune,
Akira Yamaguchi, Norio Teramae
590. Dithizone nanofiber thin film for highly
sensitive and selective detection of Hg(II).
Yukiko Takahashi*,
Supamas Danwittayakul,
Toshishige M. Suzuki
591. New fluorescent dyes for single-laser
multicolor fluorescence analysis.
Tetsuya Mizuno, Keitaro Umezawa,
Daniel Citterio, Koji Suzuki*
592. Development of chemical sensing inks
for a paper-based environmental analysis
chip. Tomoaki Ii, Koji Suzuki,
Daniel Citterio*
593. Spatiotemporal visualisation system for
expired ethanol after drinking.
Kohji Mitsubayashi*, Xin Wang,
Eri Ando, Kazutaka Kita,
Daishi Takahashi, Takahiro Arakawa
594. Contact lens type glucose sensor for
continuous monitoring of tear sugar level.
Kohji Mitsubayashi*, MingXing Chu,
Yoshitaka Hiranuma, Daishi Takahashi,
Takahiro Arakawa, Hiroyuki Kudo,
Hideo Hiramatsu
595. Development of an optical fiber oxygen
sensor for monitoring a high-level nuclear
waste underground repository.
Shinji Okazaki, Hidemoto Nakagawa*,
Yuki Nakamura, Yoshitaka Nabetani,
Kazuo Miyamura, Takashi Arai
596. Mass-sensitive environmental monitoring using quartz crystal microbalance
electrodes modified with nanoassembled
thin films. Serhiy Korposh,
Roman Selyanchyn, Do-Hyeon Yang,
Seung-Woo Lee*
597. Template fabrication of nanostructured
metal materials with a periodical structure. Susumu Yamaguchi,
Akira Yamaguchi, Norio Teramae*
598. Fabrication of porphyrin nanoassembled n-type semiconductor ammonia
gas sensors. Takuya Matsunaga,
Sergiy Korposh, Do-Hyeon Yang,
Seung-Woo Lee*, Yoshihiko Isobe
599. Nasicon-based potentiometric oxygenic gas sensor combined with metal
oxide for the low temperature operation.
Kenji Obata*, Shigenori Matsushima
600. Carbon nanofilms on diamond for gas
and temperature sensing applications.
Vivek Kumar*, Alexandra A. Bergman,
Anshel A. Gorokhovsky,
Alexander M. Zaitsev
601. Colorimetric sensor arrays for odor
sensing based on polymer films.
Yusuke Jimbo, Daniel Citterio,
Kouji Suzuki*
602. Organic vapor sensing using surfacefunctionalized porous silicon.
Vanessa Lopez Barquero,
Juan Pablo Badilla,
Arturo Ramirez-Porras*,
Bradley D. Fahlman*
603. Influence of humidity on gasochromic
behavior of Pt/WO3 thin films.
Ryousuke Yamasaki, Shinji Okazaki,
Hidemoto Nakagawa, Daisuke Ito,
Takashi Yokoyama
604. Preparation of ionic liquid gel and application to hydrogen gas sensor.
Miki Saito*, Hideki Myoubudani,
Katsuhiko Tsunashima,
Takeshi Yamauchi, Norio Tsubokawa,
Syuji Harada
605. CO sensing properties of anodized TiO2
films equipped with noble-metal electrodes under H2 atmosphere.
Takeo Hyodo*, Masashi Yonemura*,
Yasuhiro Shimizu*
606. CO sensing property and mechanism of
CuO-loaded SnO2 sensors in a reducing
atmosphere. Shinsuke Hirao,
Yuji Iwasaki, Hiroyuki Yamaura,
Hidenori Yahiro*
607. Ultrasensitive detection of DNA in diluted serum using NaBH4 electrooxidation mediated by [Ru(NH3)6]3⫹ at
indium⫺tin oxide electrodes.
Jagotamoy Das, Seonhye Son,
Haesik Yang*
608. Advanced chemical sensors based on
chalcogenide glasses.
Eugene Bychkov*, Mariana Milochova
609. Direct DNA electroanalysis by using a
nanocarbon film. Dai Kato*, Akio Ueda,
Mayuri Komoriya, Keisuke Goto,
Shigeru Hirono, Osamu Niwa
610. Electrochemical determination of urinary damaged DNA molecules by using a
sputtered nano-carbon film electrode.
Mayuri Komoriya, Dai Kato, Ryoji Kurita,
Shigeru Hirono, Osamu Niwa*
611. Surface-mounted ultrathin films for superior electrochemical sensors.
Zachary Thomas, Erno Lindner,
Eugene Pinkhassik*
612. Electrochemical characterization of the
electron transport chain for sensing applications. Lindsey Pelster*,
Shelley D. Minteer
613. Electrochemical detection of aberrant
methylated genes by using ferrocenylnaphthalene diimide. Shinobu Sato,
Yusuke Kanezaki, Shigeori Takenaka*
614. Surface-modified boron-doped diamond electrode for highly sensitive detection of glucose. Masaru Horitani,
Takeshi Kondo, Makoto Yuasa*
615. Fabrication and electrochemical properties of conductive diamond hollow fibers. Yasutaka Kodama*,
Takeshi Kondo, Makoto Yuasa
616. Crystal-face-selective supporting of
metal nanoparticles on polycrystalline diamond thin film. Takeshi Kondo*,
Kousuke Hirata, Takeshi Kawai,
Makoto Yuasa
617. High-sensitive detection of coenzyme
Q10 at boron-doped diamond electrode.
Kazuya Sakai, Takeshi Kondo,
Makoto Yuasa*
618. Electrochemical immunosensing chip
using selective surface modification, capillary-driven microfluidic control, and signal amplification by redox cycling.
Byung-Kwaon Kim, Hyunwoo Lee,
Sanyong Jon, Haesik Yang*
619. Synthesis of triphenylamine derivatives
substituent and its application as a superoxide sensor. Shin Nishiura,
Takeshi Kondo, Makoto Yuasa*
620. Design and function evaluation of a superoxide anion radical sensor using iron
porphyrin derivative bearing thienyl
group. Syouta Suzuki, Takeshi Kondo,
Makoto Yuasa*
621. “All-inkjet-printed” low-cost potentiometric ion sensing chip. Yushi Kameoka,
Koji Abe, Koji Suzuki, Daniel Citterio*
622. Ultrasensitive nucleic acid biosensing
via RNA polymerase amplification and
nanoparticle-enhanced SPR imaging.
Iuliana E. Sendroiu, Lida K. Gifford,
Andrej Luptak, Robert M. Corn
623. Microfluidic on-chip immunoassay by
plasmonic gold nanohole array fabricated
by nanoimprint technique.
Kohei Nakamoto, Ryoji Kurita,
Osamu Niwa*
624. Multiplexed attomole detection of biomarkers with enzymatically amplified
SPR imaging in multichannel, low volume
microfluidic biochips. Ting N. Hu,
Robert M. Corn*
625. Small molecule-immobilized surface
plasmon resonance biosensors for gene
detection. Seiichi Nishizawa,
Norio Teramae
626. Ultrasensitive surface plasmon resonance detection method using biofunctionalized gold nanomaterials.
Hye Rim Sim, Min Jeong Kwon,
Eun Ji Nam, Hye Jin Lee*
627. Highly sensitive antibody arrays modified by plasma polymerization.
Kazuyoshi Yano, Sunao Watanabe,
Akira Iwasaki, Hirotaka Miyachi,
Takuo Akimoto
628. Nanoporous waveguide sensor for
highly sensitive chemical and biochemical detection. Kazuhiro Hotta*,
Akira Yamaguchi, Norio Teramae
629. Detection of the DNA viscoelasiticity by
using an AR-QCM method.
Masanori Otsuka, Takayoshi Kawasaki,
Yoshio Okahata*
630. Development of noble gene probes
based on DNA-templated formation of
platinum-ruthenium dinuclear complex.
Yusuke Kitamura*, Takeshi Tomimori,
Satoshi Mita, Makoto Chikira
631. Direct monitoring of DNA phosphorylation catalyzed by polynucleotide kinase
on a quartz-crystal microbalance.
Kensuke Uemura*, Hiroshi Yoshimine,
Hiroyuki Furusawa, Yoshio Okahata
632. Design of a quartz crystal microbalance
with flow system for a highly sensitive detection of small biomolecules.
Hiroshi Yoshimine, Hiroyuki Furusawa,
Yoshio Okahata
633. Measurements of surface absorbed
lipid bilayer with a combination methodology of reflective interferometric spectroscopy and the quartz crystal microbalance. Taisuke Kojima,
Takayoshi Kawasaki, Yoshio Okahata*
634. Development of enzyme-immobilized
macroporous Pt films by utilizing polymethylmethacrylate microspheres as a
template. Goshi Ideriha, Takeo Hyodo,
Yasuhiro Shimizu
635. Electrochemical evaluation of biomolecular interaction using an electrode
covered with a biomaterial film.
Kazuharu Sugawara*, Asako Yugami,
Masashi Kawai, Tomoyuki Takayanagi,
Shunitz Tanaka
636. Computer controlled venepuncture system for blood test. Hirokazu Saito*,
Koki Nobetsu, Kohei Nakamizo,
Susumu Tarao
637. Autonomous drug-release system
based on chemo-mechanical energy conversion for blood sugar control.
Munkhbayar Munkhjargal, Ryodai Kato,
Daishi Takahashi, Takahiro Arakawa,
Hiroyuki Kudo, Kohji Mitsubayashi*
638. Effective use of dielectric-based detector for soil moisture in analysis of chemical components of binary-liquid solutions. Sumonmarn Chan-Eam*,
Phoonthawee Saetear*, Jirayu Sitanurak,
Suchada Samrit, Rattikan Chantiwas,
Nuanlaor Ratanawimarnwong,
Kanchana Uraisin, Prapin Wilairat,
Supatra Manatrinon,
Khongpan Rungprateepthaworn,
Duangjai Nacapricha*
639. Construction of microsensors for in situ
monitoring of biofilms. Hisashi Satoh*,
Satoshi Okabe
Saturday Morning
Convention Center
305A
Recent Advances in Bioanalysis: UltraSmall Volumes, Global Metabolite Profiling
and Single Cells (#56)
Organized by: D. Chiu, S. Boxer,
P. Britz-McKibbin, T. Matsunaga,
K. Otsuka, G. Zhou
Presiding: P. Britz-McKibbin
7:30 Opening remarks
7:35 – 640. Mass spectrometry-based therapeutic metabolomics. Gary Siuzdak*
8:15 – 641. Detection of internal body time
based on blood metabolome analysis.
Hiroki R. Ueda*
8:55 – 642. Combined mass spectrometry
and NMR metabolomics approach to detect breast cancer recurrence.
Daniel Raftery*
9:25 – 643. Metabolic profiles associated
with cholesterol lowering effects of berberine in rats. Sam Li
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–61
01-ANYL
9:45 – 644. 1H NMR-based metabolomics
approach for analysis of APAP hepatotoxicity. Kiyoshi Fukuhara*, Akiko Ohno,
Wataru Hori, Takashi Yamoto,
Haruhiro Okuda
10:05 – 645. Urine, plasma and cystic kidney
tissue metabolome changes during disease progression for a Lewis Polycystic
Kidney (LPK) rat model of autosomal recessive polycystic kidney disease.
Hayley White*, Garth Maker,
Catherine Rawlinson, Trish Fleming,
Jacqueline Phillips, Robert D. Trengove
10:45 – 646. Withdrawn
11:05 – 647. Differential metabolomics for
assessment of N-acetyl-L-cysteine intervention in strenuous exercise: Impact of
oxidative stress attenuation on fatigue reduction. Philip Britz-McKibbin*,
Richard Lee, Daniel West, Stuart Phillips
Convention Center
323C
New Frontiers of Plasma Spectrochemistry
(#84)
Organized by: N. Furuta, G. Hieftje,
R. Sturgeon
Presiding: R. Sturgeon
7:30 Opening remarks
7:35 – 648. From selenospecies in plants to
biomarkers for hemorrhagic stroke.
Joseph Caruso*, Renee Easter,
Yaofang Zhang, Karolin Kroening
8:15 – 649. Identification of selenoprotein P
(Sel-P) in plasma and liver by using
HPLC-ICPMS and SDS-PAGE.
Naoki Furuta*, Tatsuya Sakai,
Keita Ishimi, Yoshinari Suzuki
9:30 – 650. Multiparameter analysis of microsomal CYP-profiles by means of laser
ablation inductively coupled plasma
mass spectrometry (LA-ICP-MS).
Norbert Jakubowski*, Larissa Waentig,
Peter Roos
10:10 – 651. Beyond 30 markers in single
cells with mass cytometry.
Dmitry R. Bandura, Olga I. Ornatsky,
Vladimir I. Baranov, Scott D. Tanner
10:50 – 652. Can we correctly determine
metal-protein associations for labile metalloproteins using ICPMS?
James A. Holcombe*,
Haley Finley-Jones, Isaac Arnquist
Convention Center
301A
Analytical Applications and New Technical
Developments of Soft X-Ray Spectroscopy
(#145)
Organized by: Y. Muramatsu, J. Ahn,
A. Burren, C. Glover, C. Heske, J. Kawai,
B.S. Kim, F. Larkins, D. Lindle,
A. Moewes, R. Perera, L. Terminello,
H. Wakita
Presiding: Y. Muramatsu, A. Van Buuren,
J. Kawai
7:30 Introductory remarks
7:35 – 653. Application of soft X-ray PEEM
to the observations of electronic structure, valence state and molecular orientation at nanoscale. Yuji Baba*,
Tetsuhiro Sekiguchi, Iwao Shimoyama,
Norie Hirao, Ayumi Narita
7:50 – 654. Velocity map imaging for the
characterization and diagnostics of molecular beams. Hideki Katayanagi*,
Koichiro Mitsuke
8:05 – 655. Ultimate-resolution soft X-ray microspectroscopy. Rainer H. Fink*,
Joerg Raabe, Christian Hub, Iris Schmid
8:25 – 656. Automated assay of internally
mixed individual particles using X-ray
spectromicroscopy maps. Ryan Moffet,
Tobias Henn, Alexander Laskin,
Mary Gilles*
8:45 – 657. Recent soft X-ray developments
at the Australian Synchrotron.
Robert Lamb, Bruce Cowie,
Alan Buckley, William Skinner,
Frank Larkins
62–TECH
TECHNICAL PROGRAM
9:25 – 658. 3-D photoelectron microscopy
and soft X-ray emission spectroscopy for
nanodevices at spring-8 University of Tokyo beamline. Masaharu Oshima
10:05 – 659. Ultrahigh resolution soft X-ray
emission spectrometer at BL07LSU of
SPring-8. Yoshihisa Harada*,
Masaki Kobayashi*, Masaharu Oshima,
Yasunori Senba, Haruhiko Ohashi,
Takashi Tokushima, Yuka Horikawa,
Shik Shin
10:20 – 660. Highly efficient soft X-ray emission spectrometer using a transmission
grating. Hiroyuki Yamane, Takaki Hatsui,
Nobuhiro Kosugi
10:35 – 661. Angular anisotropy of X-ray
emission from acetic acid molecules in
solution. Yuka Horikawa*, Hidemi Arai,
Takashi Tokushima, Atsunari Hiraya,
Shik Shin
10:50 – 662. Silicon drift detector applications in soft X-ray absorption spectroscopy. Thomas Regier*, Robert Blyth,
David Chevrier, David Beauregard,
Andrew Achkar, Hiroki Wadati,
David Hawthorn
11:10 – 663. Palmtop EPMA. Jun Kawai*,
Eisuke Hiro
Convention Center
301B
(Bio-)Chemical/Electrochemical Sensors
and Sensing Materials (#255)
Organized by: K. Suzuki, E. Bakker,
P. Buhlmann, D. Citterio, O. Niwa
Presiding: O. Niwa, P. Buhlmann
7:30 – 664. Electrochemically deposited aryl
films for controlled binding capacity in
surface based bioassays.
Mark T. McDermott*, Chris Grant,
John Toman
7:50 – 665. Near-zero fouling peptide monolayer for surface plasmon resonance
sensing in crude biological fluids.
Jean-Francois Masson,
Olivier R. Bolduc*, Joelle N. Pelletier
8:10 – 666. 3-D ordered macroporous
(3DOM) carbon and fluorous phases:
Highly selective potentiometric measurements of heavy metals and perfluorocarboxylates in the ppb and ppt range.
Philippe Buhlmann*, Chun-Ze Lai,
Melissa A. Fierke, Andreas Stein
8:30 – 667. Improving blood compatibility of
intravascular chemical sensors using nitric oxide releasing/generating polymeric
coatings. Mark E. Meyerhoff*
9:00 – 668. Development of BioFET based
checkers for single drop analysis of salivary nitrate. Shin-ichi Wakida*,
Takashi Miyado, Naohiro Yoshida,
Tomoki Kobayashi, Tomohisa Mori,
Yasuhiko Shibutani
9:20 – 669. Ion sensing concepts for reagent
free sample manipulation and calibration
free detection. Eric Bakker,
Ewa Grygolowicz-Pawlak,
Apon Numnuam
9:40 – 670. Ion-selective electrodes based
on a pyridyl-containing triazolophane:
Manipulating halide selectivity by mixing
dipole-promoted binding with hydrogen
bonding. Elsayed M. Zahran, Yuran Hua,
Semin Lee, Amar H. Flood,
Leonidas G. Bachas*
10:00 – 671. Positive-feedback-mode scanning electrochemical microscopy imaging
of DNA-grafted benzoquinone polymer
cast film for micrometer-sized hybridization biosensor applications.
Koji Nakano*, Kaori Nakamura,
Takayuki Kimura, Hisao Yoshinaga,
Nobuaki Soh, Toshihiko Imato
10:20 – 672. DNA biosensing by scanning
electrochemical microscopy.
Piotr M. Diakowski*,
Heinz-Bernhard Kraatz*
10:40 – 673. Rapid determination of two
pesticides based on the dielectrophoretic
particle manipulation.
Tomoyuki Yasukawa*,
Javier Ramon-Azcon, Fumio Mizutani*
11:00 – 674. Electrochemical immunosensor
platform: from desktop to high throughput. Hubert Girault*
Convention Center
317A
Novel Applications of Magnetic Fields in
Analytical Chemistry (#260)
Organized by: H. Watarai, I. Fritsch,
C.B. Fuh, B. Yellen
Presiding: B. Yellen, H. Watarai
7:55 – 675. Bio-ferrofluidics for lab-on-achip and rapid diagnostics applications.
Hur Koser*
8:20 – 676. Gold/Iron-oxide composite
nanoparticles as new type of magnetic
nanocarrier for in vivo and in vitro applications. Satoshi Seino*, Yuichi Koga,
Yohei Mukai, Yoshiaki Okada,
Takashi Nakagawa, Takao A. Yamamoto,
Takefumi Doi, Shinsaku Nakagawa
8:40 – 677. Electrophoretic analysis of biomolecules using magnetic particles.
Fumihiko Kitagawa*,
Takafumi Samukawa, Kenkichi Nagai,
Kenji Sueyoshi, Koji Otsuka
9:00 – 678. Protein detection using functional magnetic nanoparticles in thin
channels. C. Bor Fuh, Cf Hsu, Sj Jian,
Jr Chan, Hweiyan Tsai
9:25 – 679. High enrichment of lysosomes
through endocytosis of dextran coated
magnetic nanoparticles and novel magnetic separation. Chad Satori*,
Joseph Katzenmeyer, Edgar A. Arriaga
9:45 – 680. Effects of magnetic processing
on photoproperties due to organization
and orientation of gold nanorods.
Hiroaki Yonemura*, Natsuko Sakai,
Junichi Suyama, Sunao Yamada
10:05 – 681. Magnetic purification and separation of nanoparticles.
Mary Elizabeth Williams*,
Jacob S. Beveridge, Jason R. Stephens,
Andrew H. Latham
10:30 – 682. Pseudo single crystal method:
A novel approach to diffraction study.
Tsunehisa Kimura*, Fumiko Kimura
10:50 – 683. X-ray single crystal analysis of a
pseudo single crystal of protein microcrystalline powders. Fumiko Kimura*,
Kimihiko Mizutani, Bunzo Mikami,
Tsunehisa Kimura
11:10 – 684. Identification of single grain material by observing magnetic ejection and
rotation in a short microgravity achieved
in an ordinary laboratory. Chiaki Uyeda*
Saturday Afternoon
Convention Center
305A
Recent Advances in Bioanalysis: UltraSmall Volumes, Global Metabolite Profiling
and Single Cells (#56)
Organized by: D. Chiu, S. Boxer,
P. Britz-McKibbin, T. Matsunaga,
K. Otsuka, G. Zhou
Presiding: P. Britz-McKibbin
12:30 – 685. Quantitative metabolomics:
How far can we go? David S. Wishart*
13:10 – 686. Chemically specific imaging of
lipid distribution in the plasma membranes of individual cells with high lateral
resolution. Mary L. Kraft*,
Jessica F. Frisz, Kaiyan Lou,
Peter K. Weber, Kevin J. Carpenter,
Ian D. Hutcheon
13:40 – 687. LC-MS based metabonomics:
Separation window extending from either
hydrophilic or hydrophobic metabolites to
global metabolites. Guowang Xu*,
Xianzhe Shi, Qin Yang, Sumin Zhao,
Yuanhong Shan, Xinjie Zhao,
Peiyuan Yin, Xin Lu
14:20 – 688. Development of new lipid
metabolomics system using supercritical
fluid chromatography/mass spectrometry. Takeshi Bamba*, Atsuki Matsubara,
Eiichiro Fukusaki
14:40 – 689. Complementary untargeted
metabolite profiling and targeted assays
for enzyme discovery in Escherichia coli.
Martin Robert*, Tom M. Conrad,
Natsumi Saito, Masahiro Sugimoto,
Kenji Nakahigashi, Tomoyoshi Soga,
Bernhard . Palsson, Masaru Tomita
15:10 – 690. Development of a new interface
for automated high performance capillary
electrophoresis mass spectrometry for
the analysis of proteins, peptides, glycans, biomarkers and pharmaceuticals.
E. Jane Maxwell, Xuefei Zhong,
Roxana Jayo, David D. Chen*
15:30 – 691. Metabolomic approach to monitoring animal diseases using mass spectrometry. Hiroyuki Tazaki*,
Kinya Katayama, Touko Sato,
Toshiro Arai, Kazuhide Nakagaki
15:50 – 692. High performance analysis of
biogenic compounds by microchip electrophoresis with on-line sample concentration techniques. Kenji Sueyoshi,
Takayuki Kawai, Kota Hashiba,
Ryuta Tanaka, Fumihiko Kitagawa,
Koji Otsuka*
16:20 Closing remarks
Convention Center
323C
New Frontiers of Plasma Spectrochemistry
(#84)
Organized by: N. Furuta, G. Hieftje,
R. Sturgeon
Presiding: N. Furuta
12:30 – 693. Laser ablation: Applications,
commercialization, and nanometer capabilities. Richard Russo*, Xianglei Mao,
Vassillia Zorba, Jhanis Gonzalez,
Dayana Oropeza
13:10 – 694. Quantitative imaging of heterogeneous samples using laser ablationicp-ms. Detlef Günther, Reto Glaus,
Bodo Hattendorf, Joachim Koch,
Luca Flamingi, Robert Kovacs,
Hao Wang, Mattias Fricker,
Gisela Fontaine
13:50 – 695. Nontraditional applications of
the laser ablation technique into the earth
sciences. Takafumi Hirata*,
Satoki Okabayashi, Takaomi Yokoyama
15:05 – 696. Wonderful world of isotopic
analysis via (multicollector) ICP mass
spectrometry. Frank Vanhaecke*,
David De Muynck, Dmitry Malinovsky,
Lieve Balcaen, Luc Moens,
Martín Resano, Patrick Degryse
15:45 – 697. Application of laser ablationbased methods and multivariate statistics
to provenance studies of artefacts.
Viktor Kanický*, Lubomír Prokeš,
Linda Zaorálková, Aleš Hrdlika,
Tomáš Vaculovi, Antonín Prichystal,
Michaela Galiová, Karel Novotný
16:25 Closing remarks
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
01-ANYL
Convention Center
301A
Analytical Applications and New Technical
Developments of Soft X-Ray Spectroscopy
(#145)
Organized by: Y. Muramatsu, J. Ahn,
A. Burren, C. Glover, C. Heske, J. Kawai,
B.S. Kim, F. Larkins, D. Lindle,
A. Moewes, R. Perera, L. Terminello,
H. Wakita
Presiding: A. Moewes, C. Heske,
L. Terminello
12:30 – 698. Soft X-ray spectroscopy of materials for photoelectrochemical devices.
Clemens Heske*, Marcus Bär,
Lothar Weinhardt
12:50 – 699. Electronic states of carbon in
iron phthalocyanine-based oxygen reduction catalysts by soft X-ray absorption
spectroscopy. Hideharu Niwa*,
Makoto Saito, Masaki Kobayashi,
Yoshihisa Harada, Masaharu Oshima,
Shogo Moriya, Katsuyuki Matsubayashi,
Yuta Nabae, Shigeki Kuroki,
Takashi Ikeda, Kiyoyuki Terakura,
Jun-ichi Ozaki, Seizo Miyata
13:05 – 700. Quantitative covalency measurements in tetrahedral MO4- anions
(M ⫽ Mn, Tc, Re) using oxygen K-edge
XAS and NRIXS spectroscopy.
Stefan G. Minasian, Enrique R. Batista,
Kevin S. Boland, Joseph A. Bradley,
David L. Clark, Steven D. Conradson,
Stosh A. Kozimor*, Wayne W. Lukens,
Richard L. Martin, Gerald T. Seidler,
David K. Shuh*, Tolek Tyliszczak,
Ping Yang
13:25 – 701. Soft X-ray absorption spectroscopy and theory to elucidate the role of 5f
electrons in actinide materials.
Roy Copping, Byoungseon Jeon,
Simon Teat, Tolek Tyliszczak,
Niels Gronbech-Jensen,
Andrew Canning, Geza Szigethy,
Kenneth N. Raymond, David Shuh*
13:45 – 702. Soft X-ray resonant inelastic
scattering: A selective probe in materials
science. Joseph Nordgren*
14:25 – 703. Application of resonant inelastic
X-ray scattering to molecules and solids.
Dennis Lindle*
15:05 – 704. Surface and size manipulation
of the magnetic properties of CdSe quantum dots. Rob Meulenberg,
Jonathan Lee, Scott McCall, Kalid Hanif,
D. Haskel, J. Lang, Lou Terminello,
Tony van Buuren
15:20 – 705. In situ X-ray spectroscopy for
investigation of advanced materials for
electrical energy storage.
Jonathan R. Lee*, Trevor M. Willey,
Michael H. Nielsen, Jinghua Guo,
Jeff Dahn, Tony van Buuren
15:35 – 706. Understanding bandgap and
electronic structure of crystalline materials. Alexander Moewes*, Teak Boyko
15:55 – 707. Bandgap profile across a silicon
oxynitride ultrathin film epitaxially grown
on 6H-SiC(0001), studied by XES and
XAS. Hiroshi Tochihara*, Seigi Mizuno,
Tetsuroh Shirasawa
16:10 – 708. Characterization of graphitelike layered material BC2N by X-ray absorption and emission spectroscopy.
Masayuki Kawaguchi*,
Hiroshi Yamamoto, Yasuji Muramatsu
Convention Center
301B
(Bio-)Chemical/Electrochemical Sensors
and Sensing Materials (#255)
Organized by: K. Suzuki, E. Bakker,
P. Buhlmann, D. Citterio, O. Niwa
Presiding: K. Suzuki, E. Bakker
12:30 – 709. Oligopyrrole-based chemosensors. Jonathan L. Sessler*
13:00 – 710. Detection of mercury ion in an
engineered nanopore. Xiyun Guan*,
Qitao Zhao*
13:20 – 711. Fast catalytic and electrocatalytic oxidation of sodium borohydride on
palladium nanoparticles and its application to ultrasensitive DNA detection.
Haesik Yang
13:40 – 712. Arranging proteins in multiple
electroactive layers on electrodes for analytical purpose. Fred Lisdat*,
David Sarauli*, Roman Dronov*,
Frieder Scheller*, Dirk Kurth*,
Helmuth Möhwald*
14:00 – 713. Recent development on electroanalytical application of boron-doped
diamond electrodes. Yasuaki Einaga*
14:20 – 714. Biochemical sensing at in vitro
cancer cell constructs. Miklos Gratzl*
14:50 – 715. Electrochemical behavior and
the determination of methyl jasmonate.
Zilin Chen*, Yaqian Liao, Fang Wang
15:10 – 716. Label-free, reagent-free, and
“signal-on” DNA detection based on supramolecular electrochemistry.
Hiroshi Aoki*, Akiko Kitajima,
Hiroaki Tao
15:30 – 717. Maskless fabrication of nanospine like structure on nanocarbon film
with UV/ozone treatment realizing for enzyme direct electron transfer with enzymes. Osamu Niwa*, Akio Ueda,
Dai Kato, Ryoji Kurita, Tomoyuki Kamata,
Shigeru Umemura, Shigeru Hirono
15:45 – 718. Chemical sensors and immunosensors fabricated by inkjet printing.
Daniel Citterio*, Koji Suzuki
16:00 – 719. Polymers and nanoparticles for
bioassays based upon atomic mass
spectrometry. Mitchell A. Winnik*,
Olga Ornatsky, Daniel Majonis,
Isaac Herrera
Convention Center
317A
Novel Applications of Magnetic Fields in
Analytical Chemistry (#260)
Organized by: H. Watarai, I. Fritsch,
C.B. Fuh, B. Yellen
Presiding: I. Fritsch, H. Watarai
12:30 – 720. Nonlinear magnetic separation
in a traveling wave. Benjamin Yellen,
Lu Gao, Norman Gottron III,
Lawrence Virgin
12:55 – 721. Single crystal analysis of a
pseudo single crystal: 13C solid-state
NMR measurement without magic angle
spinning. Ryosuke Kusumi*,
Tsunehisa Kimura
13:15 – 722. DNA sequencing using magnetic tweezers. Michael J. Barrett,
Piercen Oliver, Peng Cheng,
Jin Seon Park, Hana Lim, Dmitri Vezenov
13:40 – 723. DNA migration under the magnetic field. Shun Ozawa*,
Daiki Kurosaka, Chiharu Tanaka,
Isao Yamamoto, Tadashi Takamasu
14:00 – 724. Dependence of DNA orientation
on surface condition in the magnetic field.
Akio Katsuki, Keiko Fujimura,
Masao Fujiwara, Yoshihisa Fujiwara,
Yoshifumi Tanimoto
14:20 – 725. MQCM/VSM: A new instrument
for study of magnetic materials.
Jiri Janata*, Kevin C. Vavra,
George Y. Yu, Isao Sasaki, Mira Josowicz
14:45 – 726. Development of a new pulsed
magnet system and dynamic behavior of
lipid membranes. Atom Hamasaki*,
Sumio Ozeki
15:05 – 727. Phase transition under high
magnetic field. Isao Yamamoto*,
Tatsuya Mizuno, Shun Ozawa,
Tadashi Takamasu
15:25 – 728. Diamagnetic susceptibility
change in solid-liquid phase transition of
organic materials measured by a magnetic levitation technique.
Kohki Takahashi, Iwao Mogi,
Satoshi Awaji, Kazuo Watanabe
15:45 – 729. Effects of magnetic fields on
freezing processes in aqueous solution.
Masaya Onishi, Masakazu Iwasaka*,
Satoru Kurita, Norio Owada
Saturday Evening
Convention Center
Kamehameha Halls II and III
On-site and In-vivo Instrumentation and
Applications (#36)
Organized by: J. Pawliszyn, N. Dovichi,
O.Gangfeng
Presiding: J. Pawliszyn
Poster Session
19:00 – 21:00
730. Microfabricated planar electrode ion
traps for portable mass spectrometry.
Daniel Austin*, Zhiping Zhang,
Ying Peng, Brett Hansen, Aaron Hawkins,
Milton Lee, Miao Wang, Hannah Quist,
Brandon Barney, Junting Wang
731. Application of automated 96-thin film
SPME for determination of tranexamic
acid in cardiac surgical patient operated
with use of cardiopulmonary bypass.
Barbara Bojko, Fatemeh Mirnaghi,
Dajana Vuckovic, Erasmus Cudjoe,
Md Ehsanul Hoque, Marcin Wasowicz,
Janusz Pawliszyn
732. On-site determination of impurity in
gypsum using simple pretreatment
method based on ion exchange resin dissolution. Yoshinori Tsukagoshi,
Hikaru Sawai, Atsushi Manaka*,
Masamoto Tafu, Tetsuji Chohji
733. Rapid urinalysis of amphetamines by
thermal desorption counter flow introduction atmospheric pressure chemical ionization mass spectrometry.
Hiroyuki Inoue*, Hiroaki Hashimoto,
Susumu Watanabe, Yuko T. Iwata,
Tatsuyuki Kanamori, Hajime Miyaguchi,
Kenji Tsujikawa, Kenji Kuwayama,
Toshiyasu Mikuma, Takefumi Yokokura,
Masuyoshi Yamada
734. Novel application of GS-AED for the
study of the sulfidation behavior of the
Co(Ni)Mo(W) hydrotreating catalysts.
Evgenia Kirichenko*,
Anastasya Pashigreva,
Galina Bukhtiyarova, Aleksandr Noskov
735. In-line monitoring of ethanol along a fermentation process by means of a wireless sensor network.
Juan Vicente Capella*,
Alberto Bonastre, Rafael Ors,
Miguel Peris
736. Mass transfer dynamics of two-phase
hollow fiber liquid-phase microextraction
and its application to fast drug analysis.
Shufen Cui*, Gangfeng Ouyang,
Shuo Tan, Janusz Pawliszyn*
737. Evaluation of direct analysis in real time
mass spectrometry for onsite monitoring
of batch slurry reactions. Liguo Song*,
David S. Cho, Stephen C. Gibson,
Deepak Bhandari, Mary E. McNally,
Ron M. Hoffman, Kelsey D. Cook
738. Simple and rapid determination of selenium and its application to flue gas desulfurization wastewater. Hiroyuki Masaki*,
Seiichi Ohyama, Kazuo Sato
739. Transitions in use of cobalt-blue colorant in ancient Middle East.
Yoshinari Abe*, Rodan Harimoto,
Tadashi Kikugawa,
Kriengkamol Tantrakarn, Izumi Nakai
740. Laser-induced shockwave chromatography: A microscopic and immediate
analysis of nanoparticles/nanomolecules.
Nobuyuki Ichinose*, Shinpei Nakamura,
Tetsuhiko Nagahara
741. Development of non-destructive spectroscopic system for identification of natural dyes in Japanese historical textiles
toward on-site analysis in museum.
Yoshiko Sasaki*, Ryouhei Fukae,
Ken Sasaki
742. Blood plasma separation pmma device
using capillary phenomenon and its application for point of care testing device.
Hiroaki Sakamoto*, Ranko Hatsuda,
Kazuhiro Miyamura, Haruki Shiraishi,
Susumu Sugiyama
Convention Center
Kamehameha Halls II and III
Recent Advances in Bioanalysis: UltraSmall Volumes, Global Metabolite Profiling
and Single Cells (#56)
Organized by: D. Chiu, S. Boxer,
P. Britz-McKibbin, T. Matsunaga,
K. Otsuka, G. Zhou
Presiding: T. Matsunaga,
P. Britz-McKibbin, D. Chiu
Poster Session
19:00 – 21:00
743. New technologies for analyzing gene
expressions in single cells.
Masataka Shirai*, Hideki Kambara
744. Single DNA molecule detection by onbead padlock/rolling circle amplification.
Kae Sato*, Yuri Kitamura, Kiichi Sato,
Kazuma Mawatari, Mats Nilsson,
Takehiko Kitamori
745. Transcriptional activation of global repressor target genes through chromatin
remodeling by GTS1 overexpression.
Kouichi Kuroda, Mitsuaki Sanada,
Mitsuyoshi Ueda
746. Immuno rolling circle amplification using BAP-C2 fusion protein for signal enhancement in cancer cell biomarker detection. Farhima Akter*, Masayasu Mie,
Eiry Kobatake
747. High throughput peptide ligand screening for G protein-coupled receptor in
combination with membrane-displayed ligand using a single yeast cell.
Keisuke Hara, Kouichi Kuroda,
Mitsuyoshi Ueda*
748. Development of transgenic technology
for goldfish, Carassius auratus.
Shin-ichi Akiyama, Yutaka Tamaru*
749. Functional analysis of physiologically
dangerous stress-response proteins related to organic-solvent-tolerance in
yeast Saccharomyces cerevisiae.
Naoki Ozato*, Ken Matsui,
Kouichi Kuroda, Mitsuyoshi Ueda
750. Synthesis and evaluation of new nucleic
acid substrates for pyrosequencing.
Tomoharu Kajiyama,
Masayasu Kuwahara, Mari Goto,
Hideki Kambara
751. Designed peptide library for cell analyses. Takuya Kikuchi, Kenji Usui,
Hisakazu Mihara*
752. Structure identification of soybean soponins before and after hydrolyzed by
Aspergillus sp.848s by ultra performance
liquid chromatography-quadrupole time
of flight mass spectrometry. Jing Tian*,
Zhenyu Hong, Bin Zhai, Longquan Xu
753. Characterization of moonlighting protein in post-genomic research.
Natsuko Miura*, Kouichi Kuroda,
Mitsuyoshi Ueda
754. Proteome analysis of yeast cell surface
proteins using monolithic 2D-HPLC system. Aya Kirino*, Hironobu Morisaka,
Kouichi Kuroda, Mitsuyoshi Ueda
755. Molecular analysis of XBD in Pdr1p mutants leading to multidrug resistance and
organic-solvent tolerance in yeast Saccharomyces cerevisiae. Nao Nishida*,
Naoki Ozato, Mitsuaki Sanada,
Kouichi Kuroda, Mitsuyoshi Ueda
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–63
01-ANYL
756. Application of mesh-tube gel to protein
separation as a separation medium for
isoelectric focusing electrophoresis.
Hiroaki Tanaka*, Yuko Ichimura,
Rie Saito, Hiroki Hotta, Kin-ichi Tsunoda,
Toshihiko Saheki, Koki Onda,
Yasuaki Kojima, Tamao Odake
757. Development of single template PCR
technology with capillary plate toward
single-cell analysis. Yoshiko Okamura,
Hideki Kambara, Tadashi Matsunaga,
Haruko Takeyama*
758. Single cell separation and characterization on compact disk (CD) shaped micro
fluidic device. Shunsuke Furutani*,
Hidenori Nagai, Yuzuru Takamura,
Izumi Kubo
759. Rapid and efficient detection of circulating tumor cells from whole blood using a
microfluidic device equipped with a size
selective microcavity array.
Masahito Hosokawa, Atsushi Arakaki,
Yorikane Fukuda, Tomoko Yoshino,
Tsuyoshi Tanaka, Tadashi Matsunaga*
760. Development of high-throughput protein production system using zebrafish
embryos. Hideo Miyake*,
Hajime Nakatani*, Masaru Obata*,
Masatoshi Hashimoto*, Yutaka Tamaru*
761. High throughput cell profiling using
CMOS sensor based on lens-less imaging. Tatsuya Saeki, Yoshihiko Sunaga,
Tsuyoshi Tanaka, Tadashi Matsunaga
762. Direct construction of open-sandwich
(OS) ELISA system for sensitive detection
of thyroid hormone thyroxine.
Kamrun N. Islam*, Masaki Ihara,
Jinhua Dong, Noriyuki Kasagi,
Toshihiro Mori, Hiroshi Ueda
763. Synthesis and characterization of alginate hybrid polymer beads.
Sanghyuk Kang, Pathak S. Tara,
Seon Yeong Kim, Taekyeong Joo,
Ki-jung Paeng*
764. Development of the transparent goldfish toward bioanalysis from single cells
to whole-body and -life imaging.
Yutaka Tamaru*, Shin-ichi Akiyama*
765. Selection of DNA aptamers using
atomic force microscopy. Chiaki Ogino*,
Yusuke Miyachi, Kazuki Nosaka,
Taiji Hayase, Akihiko Kondo
766. Ultraviolet photothermal image of a single nonstained yeast cell measured with
reflection objective. Noriyuki Fujii*,
Akira Harata
767. Detection of kinase activity by phosphate-affinity electrophoresis on a PDMS
microchip. Aishan Han*,
Kazuo Hosokawa, Mizuo Maeda
768. In vivo visualization of the N-myristoyltransferase activity using zebrafish embryos expressed by an enhanced green
fluorescent protein with myristoylation
signal sequence. Hisayoshi Ishikawa*,
Yutaka Tamaru
769. Toxic amyloid oligomer detection system using molecular chaperone.
Masafumi Sakono*, Tamotsu Zako,
Masafumi Yohda, Mizuo Maeda
770. Fusion of giant vesicles encapsulating
enzymes by centrifugation.
Mariko Matsunaga, Taro Toyota,
Masanori Fujinami*
771. Adhesion of giant vesicles controlled by
optical trapping. Asuna Shiga,
Taro Toyota, Tomonori Nomoto,
Masanori Fujinami*
772. Development of the nanoimprint technology-based Plasmon biosensor chip.
Akito Kitamura*, Masato Saito,
Kenji Kondo, Hiroyuki Yoshikawa,
Eiichi Tamiya
773. Piezoelectric quartz crystal biosensor
for assessing mitochondria extracted
from cell based on its cardiolipin content.
Wenfeng Zhao*, Ying Sing Fung,
Hui Sun, Wai Sum Owaisum
774. Direct analysis of cell culture secretomics from cell trapping microfluidics using
ion mobility-mass spectrometry detection. Jeffrey R. Enders,
Christina C. Marasco, Kevin T. Seale,
John P. Wikswo, John A. McLean*
64 –TECH
TECHNICAL PROGRAM
775. Temperature effect during electric pulse
application on membrane breakdown of
Staphylococci cells. Minoru Suga*,
Kenji Sawano, Hiroaki Shinohara,
Ken-Ichi Kodaira
776. Quantitative imaging for beating frequency of ES-derived cardiomyocyte.
Eiichi Shimizu*, Masato Saito,
Yoshinori Yamaguchi, Eiichi Tamiya
777. Gene expression analysis of GK knockout mice for diabetic inducing factors.
Tae Sugiyama, Ryousuke Iida,
Yuki Amakusa, Hisakage Funabashi,
Hideaki Matsuoka, Mikako Saito*
778. Phenotypic analysis of GK knockout
mice for evaluation of diabetic inducing
factors. Ryousuke Iida, Tae Sugiyama,
Yuki Amakusa, Hisakage Funabashi,
Hideaki Matsuoka, Mikako Saito*
779. Profiling the selectivity of DNA ligases in
an array format with mass spectrometry.
Joohoon Kim, Milan Mrksich
780. Analysis of endogenous jasmonates in
several plants by LC-ESI-MS.
Zilin Chen*, Lihong Liu, Juan Du,
Chen Su, Ling Zhu
781. Convenient bioanalytical tools for understanding a behavior of proteins using
yeast model systems. Seiji Shibasaki*,
Mitsuyoshi Ueda
782. Capillary isoelectric focusing of giant
mitochondria. Gregory Wolken*,
Vratislav Kostal, Edgar Arriaga*
783. Nanoscale computed tomography: Micro-angiography and cellular interactions
with nanoparticles. Ivan M. Kempson,
Chia-Chi Chien, Tsung-Yu Chen,
Enrong Li, Hsiang-Hsin Chen,
Cheng-Liang Wang, Yeukuang Hwu
784. Bioluminescence detection of small
RNA with stand-alone rolling circle amplification. Yaumasa Mashimo*,
Masayasu Mie, Keiko Gomi,
Eiry Kobatake
785. Expanding bioluminescence multiplexing beyond duel-analytes: Application of
semisynthetic aequorin for multiple cytokine detection. Daniel Scott,
C. M. Ensor, Kim Anderson,
Sylvia Daunert*
786. Thrombin binding aptamer-peptide
conjugate for fluorescence imaging of potassium ion in living cells.
Keiichi Ohtsuka, Yusuke Sato,
Hirohisa Hayashida, Tomoki Matsuda,
Kiwamu Takemoto, Takeharu Nagai,
Shigeori Takenaka*
787. Dynamic analysis of gene expression
balance in target single-ES cells towards
a more clear-cut indicator of differentiation. Hisakage Funabashi*,
Wataru Satani, Makoto Takatsu,
Mikako Saito, Hideaki Matsuoka
788. Development and optimization of the on
chip microchamber array PCR and RTPCR. Masato Saito, Kentaro Hidari,
Yoshinori Yamaguchi, Eiichi Tamiya
789. Strategies for untargeted biomarker discovery in amniotic fluid.
Michel R. Boisvert*, David H. Burns,
Kristine G. Koski, Cameron D. Skinner
790. Noninvasive and quantitative imaging
analysis for the maturation and the drug
toxicity cardiomyocytes in microchip.
Yoshinori Yamaguchi*, Masato Saito,
Eiichi Tamiya
791. Evaluation of fluorescence properties of
pharmaceutical compounds.
Matthew McCarroll*, Daniel Dyer,
Lin Wang
792. MALDI-MS-based metabolite analysis
for high-throughput screening and in situ
imaging. Daisuke Miura*,
Daichi Yukihira, Yoshinori Fujimura,
Hirofumi Tachibana, Hiroyuki Wariishi
793. Shotgun lipidomics of lipid extract from
mouse brain. Taeseong Park,
Gui Nam Kim, Hyun Soo Choi,
Young Hwan Kim*
794. Quenchbody: An antibody probe that
fluoresces upon antigen binding.
Hiroshi Ueda*, Ryoji Abe, Masaki Ihara,
Hiroaki Takagi, Takahiro Hohsaka
Convention Center
Kamehameha Halls II and III
Convention Center
301A
New Frontiers of Plasma Spectrochemistry
(#84)
Analytical Applications and New Technical
Developments of Soft X-Ray Spectroscopy
(#145)
Organized by: N. Furuta, G. Hieftje,
R. Sturgeon
Presiding: N. Furuta
Poster Session
19:00 – 21:00
795. Analysis of inclusions in steel by helium
microwave induced plasma atomic emission spectrometry. Makoto Ohishi,
Tadashi Kikuchi*
796. Forensic discrimination of cigarette ash
by the analysis of trace elements by ICPMS. Yasuhiro Suzuki*, Shinich Suzuki
797. Direct multi-element analysis of tobacco smoke using ICP-TOFMS coupled
with gas-converter apparatus.
Masaki Ohata*, Hiromu Sakurai,
Kazumi Inagaki, Kohei Nishiguchi,
Keisuke Utani, Akiharu Hioki,
Koichi Chiba
798. Multielement profiling analysis of symbiotic zoothanthellae in bivalve (Tridacna
crocea) living on the coral reef.
Akihide Itoh*, Sho Kuwae,
Shoko Ganaha, Eriko Oura
799. Straightforward phosphorylation analysis using nano HPLC-ICPMS.
Yoshinari Suzuki*, Naoki Furuta
800. Microbore anion-exchange chromatography hyphenated to inductively coupled
plasma mass spectrometry for efficient
separation of oligonucleotides and their
sensitive determination by phosphorous
selective detection. Yuka Takasaki,
Kazumi Inagaki, Tomonari Umemura*
801. HPLC-ICP-MS and species-specific
isotope dilution LC-MS for DMAA and arsenosugar speciation in biological samples. Takayoshi Kuroiwa*,
Tomohiro Narukawa, Shinichi Miyashita,
Toshikazu Kaise, Koichi Chiba
802. Determination of total selenium and selenomethionine in certified reference material of selenium enriched yeast
(SELM-1) by isotope dilution analysis using ICP-3DQMS. Tatsuya Mukai*,
Yoshinari Suzuki, Naoki Furuta
803. Selenium heavy metal antagonism in
soybeans. Traci Hanley*, Qilin Chan,
Joseph Caruso
804. Speciation analysis of inorganic antimony in inhalable airborne particulate
matter. Akihiro Iijima*, Keiichi Sato,
Tomohiro Ikeda, Hikaru Sato,
Kunihisa Kozawa, Naoki Furuta
805. Determination of trace elements in airborne particulate matter by using LAICP-MS and its analytical validation.
Keiichi Sato*, Yuichi Watanabe,
Naoki Furuta
806. Imaging of corrosion of metallic materials for a nuclear reactor cooling circuit by
LA-ICP-MS. Tomas Vaculovic,
Tereza Warchilova, Viktor Kanicky,
Tomas Simo, Oldrich Matal
807. Laser induced breakdown spectroscopy in analysis of molten metals.
Tomas Vaculovic, Zbynek Zverina,
Viktor Kanicky
808. Microchemical characterization of
questioned documents using elemental
analysis determined by laser-based
methods (LIBS and LA-ICP-MS).
Tatiana Trejos, Jose Almirall
809. Microwave-assisted LIBS: Extending
the laser induced plasma lifetime for trace
detection. Yuan Liu*, Matthieu Baudelet,
Martin Richardson
810. Characterization of laser induced
breakdown spectroscopy (LIBS) in the
ablative removal and analysis of photovoltaic (PV) precursory materials.
Travis N. Owens*, Jhanis J. Gonzalez,
Osman Sorkhabi, Xianglei Mao,
Costas Grigoropoulos, Richard E. Russo
Organized by: Y. Muramatsu, J. Ahn,
A. Burren, C. Glover, C. Heske, J. Kawai,
B.S. Kim, F. Larkins, D. Lindle,
A. Moewes, R. Perera, L. Terminello,
H. Wakita
Presiding: R. Perera, T. Kurisaki
19:00 – 811. Recent new soft X-ray spectrometers developed for the analysis of
biochemical samples. Tsutomu Kurisaki,
Shuji Matsuo, Rupert C. Perera,
James H. Underwood, Hisanobu Wakita
19:40 – 812. Characterization of minerals
and archeological samples by soft X-ray
spectroscopy. Tsutomu Kurisaki*,
Daisaku Tanaka, Shinitirou Kokubu,
Hisanobu Wakita
19:55 – 813. Complementary spectro-microscopic techniques: Chemical composition and properties of atmospheric aerosols. Mary Gilles, Ryan Moffet,
Alexander Laskin
20:15 – 814. Metals in the environment: Understanding environmental issues
through quantitative analysis of X-ray absorption spectroscopy. Jeffrey Cutler*,
Jeffrey Warner, Lisa Van Loon
20:35 – 815. Behavior of chlorine in fly ash
during dioxin formation.
Masaki Takaoka*, Takashi Fujimori,
Kazuyuki Oshita
Convention Center
Kamehameha Halls II and III
Ionic Liquids for Analytical Chemistry and
Analytical Chemistry for Ionic Liquids (#166)
Organized by: T. Kakiuchi, D. Armstrong,
A. Bond
Presiding: T. Kakiuchi
Poster Session
19:00 – 21:00
816. Study of intermolecular interactions in
chiral ionic liquids. Laurel M. Heckman*,
Joel Burnette, Todd Hopkins
817. Tetraalkylphosphonium-based ionic liquids for dye extraction and ionization of
small-molecule MALDI analytes.
Katherine S. Lovejoy, Srinivas Iyer,
Geraldine M. Purdy, Timothy C. Sanchez,
Andrew T. Koppisch, Rico E. Del Sesto
818. Cation dependence of acid-base properties of CF3SO3- based protic ionic liquids. Xuedan Song*, Ryo Kanzaki,
Shin-ichi Ishiguro, Yasuhiro Umebayashi
819. Electronic absorption spectra of gaseous imidazolium- and pyridinium-based
ionic liquids. Takahiro Ogura,
Nobuyuki Akai, Akio Kawai,
Kazuhiko Shibuya*
820. Frequency modulation AFM in ionic liquids using quartz tuning fork sensor.
Motohiko Fujimura, Takashi Ichii*,
Kuniaki Murase, Hiroyuki Sugimura
821. Functional ionic liquids as ionophores
and matrixes in chemical sensors.
Aleksandar Radu*, Andrew Kavanagh,
Robert Byrne, Simon Coleman,
Matthias Hilder, Noel Clark,
Dermot Diamond
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
01-ANYL
822. Ambient pressure X-ray photoelectron
studies of ionic liquids with water and
CO2. Alexandria Margarella*,
Theresa M. McIntire, Ming H. Cheng,
Hendrik Bluhm, Zhi Liu,
John C. Hemminger
823. In situ SEM observation of lithium electrodeposition/stripping process in roomtemperature ionic liquids.
Yoshitomo Nishimura, Tetsuya Tsuda,
Hitoshi Kageyama, Hajime Matsumoto,
Susumu Kuwabata*
824. In situ TEM observation of polymerization reaction in ionic liquids.
Hiroshi Aoki, Tetsuya Tsuda*,
Susumu Kuwabata*
825. Solvation structure of Li-ion in low-viscosity ionic liquid, 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)amide.
Kenta Fujii*, Shuto Mori, Shiro Seki,
Shin-ichi Ishiguro, Yasuhiro Umebayashi
826. Significance of the phase-boundary potential in the analysis of extraction of
metal ions using ionic liquid-water twophase systems. Ryota Teraoka*,
Yuki Kitazumi, Naoya Nishi,
Takashi Kakiuchi
827. Optical, magnetic and thermal properties of transition metal complexes in ionic
liquid. Makoto Kurihara*, Akira Imada,
Takaharu Suzuki, Ayumi Ito
828. Distribution and solute⫺solvent interactions of aromatic compounds in biphasic
ionic liquid/water systems.
Shoichi Katsuta*, Kohichi Nakamura,
Yoshihiro Kudo, Yasuyuki Takeda
829. Electrochemical avenue toward Cu(In,Ga)Se2 -based solar cells by means of
ionic liquids. Mohammad Harati, Jia Jia,
Kévin Giffard, Kyle Pellarin,
Carly Hewson, David A. Love,
Woon Ming Lau, Zhifeng Ding*
830. Investigation of electric double layer dynamics in ionic liquid gated Si transistors.
Takashi Yanase, Tetsuya Hasegawa,
Toshihiro Shimada
831. Influence of the phase-boundary potential between ionic liquid and water on
spontaneous emulsification at IL|W interface. Yuma Suzuki*, Yuki Kitazumi,
Naoya Nishi, Takashi Kakiuchi
832. Design of ionic liquid salt bridge based
on phosphonium-type ionic liquids.
Hideaki Sakaida*, Yuki Kitazumi,
Naoya Nishi, Takashi Kakiuchi
Sunday Morning
Convention Center
Kamehameha Halls II and III
Fluorescent Sensors by Design (#181)
Novel Applications of Magnetic Fields in
Analytical Chemistry (#260)
Organized by: M. McCarroll, D. Dyer,
F. Li, U. Yasuteru
Presiding: M. McCarroll
Organized by: H. Watarai, I. Fritsch,
C.B. Fuh, B. Yellen
Presiding: H. Watarai
Poster Session
19:00 – 21:00
833. Magnetic-field-responsive agarose-gel/
carbon-fiber composite.
Yusuke Umehara*, Fumiko Kimura,
Tsunehisa Kimura
834. Development of high gradient immunomagnetic separation system for the detection of Flavobacterium psychrophilum.
Uni Ryumae, Kyoko Hibi,
Yasutoshi Yoshiura, Huifeng Ren,
Hideaki Endo*
835. In situ measurement of magnetic alignment of crystalline polymers.
Masafumi Yamato*, Tsunehisa Kimura,
Kohki Takahashi, Kazuo Watanabe
836. Kinetic analysis of magnetic alignment
of rod-like pseudo single crystal.
Shu Tsukui, Tsunehisa Kimura
837. Magnetic processing for a novel paperbased piezo actuator. Chiaki Tsuboi,
Tsunehisa Kimura, Yoshiro Tajitsu
838. X-ray diffraction from magnetically
aligned microcrystalline powder.
Kenji Matsumoto*, Fumiko Kimura,
Tsunehisa Kimura
839. X-ray diffraction study of pseudo single
crystal of cellobiose. Hiroko Matsumoto,
Tsunehisa Kimura
Convention Center
323C
On-site and In-vivo Instrumentation and
Applications (#36)
Organized by: J. Pawliszyn, N. Dovichi,
O. Gangfeng
Presiding: J. Pawliszyn
7:30 – 840. Sampling and sample treatment
methods for on-site analysis of bacteria
using gas chromatography-mass spectrometry. Tai V. Truong, Dan Li,
Douglas N. VanDerwerken,
John R. Williams, Cory W. Taylor,
Richard A. Robison, H. Dennis Tolley,
Anthony D. Rands,
Christopher R. Bowerbank,
Stephen A. Lammert, Milton L. Lee*
8:00 – 841. Nanoparticle labelling and mass
spectrometry detection of microbial
pathogens and proteins. Feng Li,
Chuan Wang, Qiang Zhao, Xiufen Lu,
Chungang Yuan, Xing-Fang Li,
Chris X. Le*
8:30 – 842. A simple and fast solid-phase
microextraction technique for non-lethal
monitoring of contaminants in fish muscle. Gangfeng Ouyang*, Ken D. Oakes,
Leslie Bragg, Shuang Wang, Shufen Cui,
Mark R. Servos*, Janusz Pawliszyn*
8:50 – 843. Capillary isoelectric focusing for
analysis of Barrett’s Esophagus biopsies
and single cells. Lauren Ramsay,
Norman Dovichi*
9:20 – 844. Direct tissue sampling from explanted human liver. Yaohua Wang,
Erik N. Cressman, Edgar A. Arriaga*
9:50 – 845. Moving beyond microscopy
imagingѧfluorescence fluctuation analysis
reveals protein interactions and transport
in living cells. Paul W. Wiseman*
10:10 – 846. Using electrochemistry in the
brain to study dopamine, a neurotransmitter. Adrian C. Michael*
10:40 – 847. In vivo solid phase microextraction. Janusz Pawliszyn*
11:00 – 848. Solid sample analysis on centrifugal microfluidic devices. Eric Salin*,
David A. Duford, Yongqing Xi
Convention Center
301B
7:30 – 849. Relationship between the symmetry of ␲⫺systems and excited state
and the electrochemical properties of tetraazaporphyrins. Nagao Kobayashi*
7:50 – 850. Facile method for the development of various fluorescent sensors.
Tomoya Hirano*
8:10 – 851. APAC probes: Fluorescent sensors for sequence-specific dsDNA detection. Satoshi Obika*
8:30 – 852. In vivo cancer imaging with rationally designed fluorescence probes.
Yasuteru Urano*, Masayo Sakabe,
Daisuke Asanuma, Mako Kamiya,
Tetsuo Nagano, Mikako Ogawa,
Nobuyuki Kosaka, Peter L. Choyke,
Hisataka Kobayashi
8:50 – 853. Fluorescent sensors for in situ
analysis of biomolecules.
Shinsuke Sando*
9:10 – 854. Experimental evaluation of response selective sensors.
Matthew McCarroll*, Daniel J. Dyer,
Lichang Wang, Hudson George,
Quin Best
9:30 – 855. Luminescent probes based on
rare-earth upconversion nanophosphors.
Fuyou Li
9:50 – 856. Switchable fluorescent sensors
based on diarylethene. Tao Yi*, Ying Zou,
Xijun Piao, Xinhua Cao
10:10 – 857. Boronic acid based carbohydrate sensors. Tony D. James
10:30 – 858. Red visible/NIR fluorescent
sensors based on pi conjugated borondipyrromethene dyes. Zhen Shen*,
Hua Lu, Yanwei Wang, Ana Descalzo,
Knut Rurack, Nagao Kobayashi
10:50 – 859. Sensing and imaging of biological matter using novel luminescent sensors and imaging agents.
Thorfinnur Gunnlaugsson
11:10 – 860. Design and synthesis of response selective fluorescent sensors.
Dan Dyer*, Quinn Best, Ruisong Xu,
George Hudson, Matthew McCarroll,
Lichang Wang
10:15 – 875. Application of ionic liquids on
extractions and supercritical fluid chromatography. Guor-Tzo Wei,
Chia-Ying Lee, Hsiu-Liang Chen,
Fu-Min Chu, Wei-Ting Wang
10:45 – 876. Selective permeation of rare
earth metals by highly stable supported
liquid membrane based on ionic liquids.
Masahiro Goto*
11:15 – 877. Task-specific ionic liquids of alkyl polyaminium salts for scavenging
transition-metal ions and metal complexes. Masayasu Iida*,
Sayaka Kawakami, Emi Syouno
Convention Center
301A
Convention Center
305A
Advances in Flow-based Analytical
Techniques (#207)
Recent Advances in Bioanalysis: UltraSmall Volumes, Global Metabolite Profiling
and Single Cells (#56)
Organized by: I. McKelvie, G. Christian,
K. Grudpan, T. Imato
Presiding: K. Grudpan, I. McKelvie
7:30 Introductory remarks
7:35 – 861. Brief history of flow injection
analysis and flow analysis conferences.
Gary D. Christian
7:55 – 862. Flow injection analysis: From
beaker to microfluidics - applications to
chemical oceanography.
Jaromir Ruzicka*
8:30 – 863. Magnetic microbeads immunoassay based on sequential injection.
Kazuhira Sakamoto, Koji Nakano,
Nobuaki Soh, Toshihiko Imato*
8:50 – 864. Recent advances in chemiluminescence detection for flow analysis.
Paul S. Francis*
9:25 – 865. Macroscopic approach to studying kinetics at equilibrium: The power of
flow analysis. Sergey N. Krylov,
Maxim V. Berezovski, Victor Okhonin
9:45 – 866. Luminescent electrode interfaces
for sensing applications.
Conor F. Hogan*, Egan H. Doevan,
Gregory Barbante, David Piper
10:20 – 867. Development of biocatalyst
based microreactors for lipid transformations and blood profiling.
Samuel M. Mugo*, Karl Ayton
10:40 – 868. Principle and application of amplitude modulated multiplexed flow analysis. Hideji Tanaka*
11:00 – 869. Flow analysis employing natural
reagents and modern information technology devices for the aids of cost effective green (analytical) chemistry.
Kate Grudpan*
Convention Center
317A
Ionic Liquids for Analytical Chemistry and
Analytical Chemistry for Ionic Liquids (#166)
Organized by: T. Kakiuchi, D. Armstrong,
A. Bond
Presiding: D. Armstrong, M. Goto
7:40 Introductory remarks
7:45 – 870. Unique ability of ionic liquids to
dissolve raw biopolymers such as cellulose and chitin, provides an opportunity
to develop analytical techniques for molecular weight determination.
Robin D. Rogers*, Ning Sun, Ying Qin
8:15 – 871. Experimental and theoretical investigations of ionic fluids: Applications
to enzyme catalyzed hydrolysis of cellulose. Jacob W. Petrich*, Xueyu Song,
Daniel W. Armstrong
8:45 – 872. Ionic liquids in separations and
mass spectrometry.
Daniel W. Armstrong
9:15 – 873. Exploiting the versatility of ionic
liquids in separation science.
Jared L. Anderson*, Christa Graham,
Yunjing Meng, Cong Yao, Qichao Zhao
9:45 – 874. Investigations of surface confined ionic liquid stationary phases using
supercritical fluid chromatography.
Patrice R. Fields*, Thomas L. Chester,
Apryll M. Stalcup
Organized by: D. Chiu, S. Boxer,
P. Britz-McKibbin, T. Matsunaga,
K. Otsuka, G. Zhou
Presiding: T. Matsunaga
7:45 Opening remarks
7:50 – 878. Quantitative analysis of multiple
gene expressions in single-cells.
Hideki Kambara*
8:30 – 879. Analysis of gene mutation and
gene expression from a very limited
amount of exfoliated colonocytes in feces
by digital counting of single molecules.
Guohua Zhou, Zongtai Qi, Lili Deng,
Huan Huang
8:50 – 880. Analysis of intracellular molecules in a living cell using a nanoneedle
functionalized with molecular probes.
Chikashi Nakamura*, Takanori Kihara,
Yosuke Amemiya, Narutoshi Yoshida,
Taro Kitagawa, Shingo Mieda,
Noriyuki Nakamura, Jun Miyake
9:10 – 881. Global transcription profiling of
complex biological processes of cellular
differentiation at the single-cell resolution.
Mitinori Saitou*, Kazuki Kurimoto
9:50 – 882. Evaluation of mRNA and protein
expresssions at single-cell level.
Hitoshi Shiku, Daisuke Okazaki,
Kosuke Ino, Tomokazu Matsue
10:10 – 883. DNA-Lipid conjugates control
interactions and fusion in model cells.
Steven Boxer*
10:50 – 884. Real-time observation of model
membrane dynamics induced by Alzheimer’s amyloid beta. Masahiro Takagi*,
Tsutomu Hamada,
Mun’delanji Vestergaard,
Masamune Morita
11:10 – 885. High density microcavity array
for target cell analysis from heterogeneous cell populations. Atsushi Arakaki,
Masahito Hosokawa,
Tadashi Matsunaga*
Convention Center
303A
Optical Waveguide Techniques for the
Analyses of Materials and Interfaces (#74)
Organized by: K. Tsunoda, M. Gee,
S.S. Saavedra, L. Sun
Presiding: S. Saavedra, L. Sun
8:00 Opening remarks
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–65
01-ANYL
8:05 – 886. Advances in surface wave spectroscopies for the interrrogation of molecular films. Sergio B. Mendes*
8:35 – 887. Optical waveguide sensor based
on nanoporous/metal multilayer films.
Akira Yamaguchi*
9:05 – 888. Evanescent wave cavity-based
spectroscopy for the study of dynamical
interfacial phenomena.
Stuart R. Mackenzie*, Pat Unwin,
Simon Neil, Mathias Schnippering,
Hayley Powell
9:35 – 889. Chemical detection using microoptical devices. Hans-Peter Loock*,
John Saunders, John A. Barnes,
Cathleen M. Crudden, Gianluca Gagliardi,
Danxia Xu, Adam Densmore,
Siegried Janz, Rubin Ma
9:55 – 890. Polyelectrolyte adsorption kinetics under an applied potential using optical waveguide lightmode spectroscopy.
Paul Van Tassel
10:25 – 891. Combining reactive or animated
polymer films with waveguide transduction platforms for chemical analysis and
sensing. Paul L. Edmiston*
10:55 – 892. In situ observation of adsorption behaviors of dyes on the electrode/
solution interface by internal reflection
spectroscopy. Li-Xian Sun*, Shujun Qiu,
Fen Xu, Chunhong Jiang, Jian Zhang,
Naoki Matsuda
Convention Center
Kamehameha Halls II and III
Analytical Applications and New Technical
Developments of Soft X-Ray Spectroscopy
(#145)
Organized by: Y. Muramatsu, J. Ahn,
A. Burren, C. Glover, C. Heske, J. Kawai,
B.S. Kim, F. Larkins, D. Lindle,
A. Moewes, R. Perera, L. Terminello,
H. Wakita
Presiding: Y. Muramatsu
Poster Session
10:00 – 12:00
893. X-ray absorption spectroscopic characterization of phosphorus-doped TiO2 with
visible-light photocatalytic activity.
Motoki Iwase*, Keiji Yamada,
Tsutomu Kurisaki, Hisanobu Wakita
894. Adsorption behavior of tellurium oxoanion on d-MnO2. Yuka Katsuyama,
Chiya Numako, Yoshihiro Okaue,
Takushi Yokoyama
895. Quantitative analysis method of nitrogen in graphitic carbon materials using
total-electron-yield soft X-ray absorption
spectroscopy. Taiji Amano*,
Yasuji Muramatsu, Eric M. Gullikson
896. Local-structure analysis of the oxidized
graphitic carbon dispersoids using soft Xray absorption spectroscopy.
Natsuki Inoue*, Yasuji Muramatsu,
Yukihiro Aoyama, Masahide Kawaraya,
Hideyuki Hisashi, Eric M. Gullikson
897. Total-electron-yield soft X-ray absorption spectroscopy for the quantitative
analysis of carbon materials.
Yasuji Muramatsu*, Eric M. Gullikson
898. X-ray fluorescence imaging of growing
chemical patterns. Kenji Sakurai,
Mari Mizusawa
899. Measurement of unpaired electron species in dry DNA thin films irradiated with
synchrotron soft X-rays around oxygen
and nitrogen K-edge studied by EPR.
Toshitaka Oka, Akinari Yokoya,
Kentaro Fujii, Yoshihiro Fukuda,
Masatoshi Ukai
Sunday Afternoon
Convention Center
323C
On-site and In-vivo Instrumentation and
Applications (#36)
Organized by: J. Pawliszyn, N. Dovichi,
O.Gangfeng
Presiding: J. Pawliszyn
66 –TECH
TECHNICAL PROGRAM
12:30 – 900. On-site environmental analysis:
Overview of challenges and opportunities. Ray E. Clement
13:00 – 901. Development of a low power
ion trap mass spectrometer for Earth and
Mars applications. Robert J. Cotter*,
Veronica Pinnick, Theresa Evans-Nguyen
13:30 – 902. Person portable gas chromatograph-toroidial ion trap mass spectrometer in conjunction with solid phase micro
extraction sampling for field analytical
measurements. Douglas W. Later*
13:50 – 903. On-line monitoring of air toxics
in the Seattle-Tacoma airshed from a mobile membrane introduction tandem mass
spectrometry system. Nicholas G. Davey,
Jake M. Etzkorn, Morten Martinsen,
Ji H. Park, Robert S. Crampton,
Cole T. Fitzpatrick, Timothy V. Larson,
Chris D. Simpson, Michael G. Yost,
Erik T. Krogh, Chris G. Gill*
14:10 – 904. The development of a rugged,
field-portable membrane introduction
tandem mass spectrometer (MIMS-MS/
MS) and its use as an on-line monitor for
volatile and semi-volatile organic compounds in the Alberta oil sands.
Nicholas G. Davey, Morten Martinsen,
Oyvind Mikkelsen, Rudolf Schmid,
Christian Collin-Hansen, Erik T. Krogh,
Chris G. Gill*
14:30 – 905. Solid-state light sources: An excellent match with the needs of portable
and on-site analytical instrumentation.
Markéta Ryvolová, Petr Smejkal,
Nantana Nuchtavorn, Tomasz Piasecki,
Lenka Krmová, Mahbub Akhter,
František Foret, Leena Suntornsuk,
Pleun Maaskant, Mirek Macka*
14:50 – 906. Chemical detection using fiber
cavity ring-down spectroscopy.
Hans-Peter Loock*, Jack A. Barnes,
Klaus Bescherer, Adrienne H. Cheung,
Jessica Litman, Helen Waechter
15:10 – 907. Miniaturized sample preparation device for gas chromatographic analysis of volatile organic compounds.
Yoshihiro Saito*, Ikuo Ueta,
Kiyokatsu Jinno
15:30 – 908. A polymer-based thin film trap
and optical detection system for hydrophobic compounds in water.
Rebecca A. Jarrell, John P. Hassett
15:50 – 909. Vacuum headspace solidphase microextraction.
Elefteria Psillakis*, Nicolas Kalogerakis
16:10 – 910. Micro- electron spin resonance
(ESR/EPR) spectroscopy for on-site free
radical analysis. Christopher White
Convention Center
305A
Recent Advances in Bioanalysis: UltraSmall Volumes, Global Metabolite Profiling
and Single Cells (#56)
Organized by: D. Chiu, S. Boxer,
P. Britz-McKibbin, T. Matsunaga,
K. Otsuka, G. Zhou
Presiding: T. Matsunaga
12:30 – 911. Single-cell analyses of protein
activity and nucleic acids by in situ proximity ligation assays and padlock probes.
Ola Söderberg*
13:10 – 912. Novel proteomic tools for highly
sensitive high-throughput protein profiling. Kenji Yokoyama*, Yoshio Suzuki,
Nao Sakaguchi, Hideki Kinoshita,
Atsunori Hiratsuka
13:30 – 913. Structure, function and application of hyperthrmophilic molecular chaperones. Masafumi Yohda*,
Ayumi Nakagawa, Taro Kanzaki,
Hiroshi Sekiguchi, Yuji C. Sasaki
13:50 – 914. Raman spectroscopy and imaging of single living cells.
Hiro-o Hamaguchi*
14:30 – 915. Application of femtosecond laser and monolithic materials to single cell
analysis. Mitsuyoshi Ueda*
14:50 – 916. Quantitative electrochemical
cytometry of nanometer transmitter vesicles. Andrew G. Ewing*, Lisa Mellander,
Donna Omiatek, Michael Heien
15:30 – 917. Analysis of respiratory activity
of single oocytes and embryos with a
noninvasive and highly sensitive measurement using scanning electrochemical
microscopy. Hiroyuki Abe*,
Hitoshi Shiku, Tomokazu Matsue
15:50 – 918. On-chip cellular manipulation
and analysis based on micro channel array. Satoshi Konishi*
16:10 Closing remarks
Convention Center
303A
Optical Waveguide Techniques for the
Analyses of Materials and Interfaces (#74)
Organized by: K. Tsunoda, M. Gee,
S.S. Saavedra, L. Sun
Presiding: K. Tsunoda, S. Mendes
12:30 – 919. Frequency-domain, planar
waveguide spectroelectrochemistry: Development and application to optical
switching and charge transfer kinetics in
redox-active thin films. Zeynep O. Araci,
Walter J. Doherty III, Anne F. Runge,
Clayton R. Shallcross, Neal R. Armstrong,
S. Scott Saavedra*
13:00 – 920. In situ observation of uv-visible
absorption spectra of adsorption process
and electron transfer reaction of cytochrome c on ITO electrode by slab optical
waveguide spectroscopy.
Naoki Matsuda*, Takahiro Okabe
13:30 – 921. Application of polymer coated
slab optical waveguide to the electrode
surface analysis. Hiroki Hotta*,
Takuya Hashimoto, Naoko Futami,
Kin-ichi Tsunoda*
14:00 – 922. Planar optical waveguide biosensors for the early diagnosis of infection. Basil I. Swanson,
Harshini Mukundan, Aaron S. Anderson,
Kevin W. Grace, Dominique Price
14:30 – 923. Electric-field-modulated surface plasmon-coupled directional emission: Efficient discrimination of single
base mismatch. Shuo-Hui Cao,
Tang-Tang Xie, Wei-Peng Cai, Qian Liu,
Yao-Qun Li*
14:50 – 924. Membrane-mediated detection
of pathogen-associated motifs on a
waveguide-based platform.
Harshini Mukundan*, Dominique Price,
Anu Chaudhary, Aaron Anderson,
Gabriel Montano, Basil I. Swanson*
15:10 – 925. Molecular orientation control of
cationic porphyrins on clay surfaces.
Shinsuke Takagi*, Dai Masui,
Tetsuya Shimada, Hiroshi Tachibana,
Haruo Inoue
15:40 – 926. Ex situ investigation of vacuumevaporated copper phthalocyanine film
by multimode slab optical waveguide
spectroscopy. Zhi-mei Qi*, Fang Chen,
Shanhong Xia, Naoki Matsuda
16:10 – 927. Attenuated total reflectance
spectroscopy of coumarin organosilane
molecules adsorbed on a fused silica surface. Maria Antoaneta Bratescu*,
Nagahiro Saito, Osamu Takai
Convention Center
317A
Ionic Liquids for Analytical Chemistry and
Analytical Chemistry for Ionic Liquids (#166)
14:30 – 932. Analytical challenges in ionic
liquids. Doug MacFarlane*
15:00 – 933. Does the N2O analogy work for
ionic liquids? Devan E. Kestel,
Burcu Gurkan, Joan F. Brennecke
15:30 – 934. Thermodynamics of conformational equilibrium of an ionic liquid, bis(trifluoromethanesulfonyl)amide, bound to
the lithium ion. Shin-ichi Ishiguro*,
Shyto Mori, Yasuhiro Umebayashi,
Kenta Fujii
16:00 – 935. Microphase separation of ionic
liquids relaxed by methanol.
Toshiyuki Takamuku*,
Takuya Shimomura, Kenta Fujii
16:15 – 936. Ultraslow relaxation of the electrical double layer at the ionic liquid|
metal interface probed by surface plasmon resonance. Naoya Nishi,
Toshiyuki Motokawa, Yuki Kitazumi,
Takashi Kakiuchi*
Convention Center
301B
Fluorescent Sensors by Design (#181)
Organized by: M. McCarroll, D. Dyer,
F. Li, U. Yasuteru
Presiding: M. McCarroll
12:50 – 937. Optical imaging using split-reporter reconstitution analysis: From single cells to living animals.
Takeaki Ozawa*
13:10 – 938. Benzylidene malononitriles as
environmental friction probes. Durba Roy,
Min Liang, Chet Swalina, Hui Jin,
Mark Maroncelli*
13:30 – 939. Sensing applications for photon
upconverting nanoparticles.
Peng Zhang*, Manoj Kumar
13:50 – 940. Development of near infraredfluorescent nanophosphors for disease
diagnosis and therapy. Tamotsu Zako*,
Hiroshi Hyodo, Kosuke Tsuji,
Kimikazu Tokezen, Hidehiro Kishimoto,
Masaaki Ito, Kazuhiro Kaneko,
Kohei Soga, Mizuo Maeda
14:10 – 941. Design of hypoxia-sensitive fluorescent probes activated by enzymatic
one-electron reduction for hypoxic cancer cell imaging. Hirokazu Komatsu*,
Hiroshi Harada, Hisatsugu Yamada,
Takeo Ito, Kazuhito Tanabe,
Masahiro Hiraoka, Sei-ichi Nishimoto
14:30 – 942. Selective detection of phosphotyrosine using Tb(III) complexes.
Hiroki Akiba, Yuki Watanabe,
Jun Sumaoka, Makoto Komiyama*
14:50 – 943. Photonic nanosensors for selective detection of reactive oxygen species and their roles in carcinogenesis.
Kui Chen*, Annie Wilson,
Laura McCormick, Dorothy Blake,
Christopher Graham
15:10 – 944. Fluorescence technique for
probing out-of-plane dye diffusion in ultrathin supported polymer films.
Hui Deng*, Manish K. Mundra,
John M. Torkelson
15:30 – 945. Withdrawn
15:50 – 946. Detection of aberrant DNA
methylation with a bis-acridinyl peptide
carrying fluorescein (FKA).
Keiichi Ohtsuka, Satoshi Honda,
Shigeori Takenaka*
Organized by: T. Kakiuchi, D. Armstrong,
A. Bond
Presiding: A. Bond, U. Domanska
12:30 – 928. Extraction of copper (II) ions
from aqueous solutions with a methimazole-based ionic liquid. Alan M. Bond*,
Juan M. Reyna-Gonzalez,
Angel J. Torriero, Amal I. Siriwardana,
Iko M. Burgar
13:00 – 929. Ionic liquid chelate extraction
system for extraction of metals.
Naoki Hirayama*
13:30 – 930. Solvent extractions based on
ionic liquids: Ion recognition through ionic
liquids. Huimin Luo*, Sheng Dai
14:00 – 931. Separation of liquids with liquid-liquid extraction using ionic liquids.
Urszula M. Domanska-Zelazna
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
01-ANYL
16:10 – 947. Novel QD-based bioassay for
screening inhibitors of HIV-1 protease
cleavage sites using a genetically programmable protein module.
Wilfred Chen*, Payal Biswas,
Marylynn Yates
Convention Center
301A
Advances in Flow-based Analytical
Techniques (#207)
Organized by: I. McKelvie, G. Christian,
K. Grudpan, T. Imato
Presiding: T. Imato, G. Christian
12:50 Introductory remarks
12:55 – 948. Control of electro-osmotic flow
using self-assembled surfactant bilayer
coatings. Charles A. Lucy*,
Mahmoud F. Bahnasy, M. D. Gulcev,
Amy M. MacDonald
13:30 – 949. Analytical conditions and separation performance of capillary chromatography based on tube radial distribution of water-hydrophilic-hydrophobic
organic mixture carrier solvents under
laminar flow conditions.
Kazuhiko Tsukagoshi*
13:50 – 950. Preparation of gold coated
plastic microbeads for separation analysis. Tsutomu Nagaoka*, Hiroshi Shiigi,
Yojiro Yamamoto, Shiho Tokonami
14:10 – 951. Hybrid analytical system composed of solid phase extraction and
stopped-in-loop flow spectrophotometry
for the determination of urinary vanadium/creatinine ratio. Norio Teshima*,
Nuanlaor Ratanawimarnwong,
Tadao Sakai, Duangjai Nacapricha
14:30 – 952. Batch and on-line separation of
metals ions based on polymer inclusion
membranes. Spas D. Kolev*
15:05 – 953. Utilization of simultaneous injection effective mixing analytical
method. Tadao Sakai*, Norio Teshima,
Daisuke Noguchi,
Nuanlaor Ratanawimarnwong,
Duangjai Nacapricha, Shoji Motomizu
15:25 – 954. Potential in-line system for simultaneous analyses of dissolved CO2,
sugar and color in carbonated drink industry. Duangjai Nacapricha*,
Saowapak Teerasong,
Sumonmarn Chan-Eam,
Kamonthip Sereenonchai,
Natchanon Amornthammarong,
Nuanlaor Ratanawimarnwong
15:45 – 955. Determination of trace water in
organic solvents by means of selective
vaporization and highly sensitive humidity
sensor. Shin-Ichi Ohira*, Kayoko Goto,
Purnendu K. Dasgupta, Kei Toda
16:05 – 956. Micellar solutions as alternative
to organic solvents in flow injection analysis. Najma Memon*, M. Hanif Memon,
M. Iqbal Bhanger
Sunday Evening
Convention Center
Kamehameha Halls II and III
Optical Waveguide Techniques for the
Analyses of Materials and Interfaces (#74)
Organized by: K. Tsunoda, M. Gee,
S. Saavedra, L. Sun
Presiding: K. Tsunoda
Poster Session
19:00 – 21:00
957. Quantification of a functional group introduced on the glass surface using slab
optical waveguide. Takeo Ishii*,
Hiroki Hotta, Tomokazu Masuda,
Hiroaki Ozaki, Kin-ichi Tsunoda
958. Construction of a lipid bilayer membrane on the slab optical waveguide surface and the observation of chemical reactions at the lipid bilayer/solution
interface. Takahiro Sakurai*, Yuki Saito,
Akiko Ieiri, Toshitada Yoshihara,
Seiji Tobita, Hiroki Hotta,
Kin-ichi Tsunoda
959. Adsorption and desorption dynamics of
mesoporous silica film as studied by optical waveguide spectroscopy.
Hiroyuki Arafune, Kazuhiro Hotta,
Akira Yamaguchi, Norio Teramae
960. Linear dichroism measurement system
with a slab optical waveguide for the
analyses of adsorption states of dyes on
TiO2 surface. Atsushi Sakurazawa*,
Hiroki Hotta, Humio Okada,
Keisuke Suda, Kenji Kakiage,
Minoru Hanaya, Kin-ichi Tsunoda
961. Highly efficient slab optical waveguide
chemical sensors based on the absorption response of indicators.
Naofumi Ohta*, Masayuki Uehara,
Hiroki Hotta, Kin-ichi Tsunoda
962. Design of nanoassembled mesoporous
film structures using SiO2 nanoparticles
on long period grating optical fibers.
Serhiy Korposh, Stephen James,
Seung-Woo Lee*
963. Optical gas sensing using tetrakis-(4sulfophenyl)porphine-based nanoassembled thin films. Wataru Yasukochi,
Sergiy Korposh, Roman Selyanchyn,
Seung-Woo Lee
964. Humidity detection by using a hybrid
sensor of optical waveguide and quartz
crystal microbalance. Kazunari Shinbo*,
Makoto Iwasaki, Shunya Otuki,
Yuichi Kanbayashi, Yasuo Ohdaira,
Akira Baba, Keizo Kato, Futao Kaneko,
Nobuo Miyadera
965. Cytochrome c adsorption to chemically
modified silica surfaces.
Geoffrey C. Hoops, Brianna Richine
Convention Center
317A
Ionic Liquids for Analytical Chemistry and
Analytical Chemistry for Ionic Liquids (#166)
Organized by: T. Kakiuchi, D. Armstrong,
A. Bond
Presiding: C. Tran, Y. Ouchi
19:00 – 966. Ion solvation and liquid structure of ionic liquids as nano-organized
media. Yasuhiro Umebayashi*
19:30 – 967. Spectroscopy for and by ionic
liquids. Chieu D. Tran
20:00 – 968. Nonlinear vibrational spectroscopic studies on buried interfaces of
ionic liquids. Yukio Ouchi*
20:30 – 969. Study on the acid-base reaction
and solvation in protic ionic liquids.
Ryo Kanzaki*, Xuedan Song,
Yasuhiro Umebayashi, Shin-ichi Ishiguro
20:45 – 970. Actuation mechanism of electrochemical artificial muscle device using
ionic liquid⫺polymer composite.
Tetsuya Tsuda*, Rentaro Sakao,
Yuichi Sato, Kazuhiko Matsumoto,
Rika Hagiwara, Susumu Kuwabata
Convention Center
Kamehameha Halls II and III
Fluorescent Sensors by Design (#181)
Organized by: M. McCarroll, D. Dyer,
F. Li, U. Yasuteru
Presiding: M. McCarroll
Poster Session
19:00 – 21:00
971. Development of novel cell-permeable
SNARF derivative as an intracellular fluorescent pH indicator. Eiji Nakata*,
Yoshihiro Yukimachi, Yoshijiro Nazumi,
Yoshihiro Uto, Hiroshi Maezawa,
Hitoshi Hori
972. Recyclable fluorimetric and colorimetric
mercury-specific sensor by using porphyrin-functionalized Au@SiO2 core/shell
nanoparticles. Youngje Cho,
Jagadese J. Vittal, Shim Sung Lee,
Jong Hwa Jung*
973. Highly sensitive and selective sensor
based on bodipy-functionalized magnetic
nanoparticles for detecting lead in living
cells. Hyun Jong Son, Hye Young Lee,
Jung Mi Lim, Dongmin Kang,
Won Seok Han, Jagadese Vittal,
Shim Sung Lee, Jong Hwa Jung*
974. Highly sensitive detection of protein
with fluorescence enhancement technology by a multilayered substrate fabricated with Ag and Al2O3.
Takuo Akimoto*, Mitsuru Yasuda
975. Localizable and highly sensitive calcium
indicator based on a BODIPY fluorophore. Mako Kamiya*, Kai Johnsson*
976. Novel ratiometric fluorescent sensors
for heavy metal ions based on 3-aryl substituted boron-dipyrromethene dye.
Akira Hafuka*, Hiroki Taniyama,
Yutaka Yamagishi, Maiko Yuasa,
Son Sang-Hyun, Koji Yamada*,
Hisashi Satoh*
977. Fluorescent cation sensors and chelators for analysis and chelation of toxic
heavy metal ions in the environment.
Chandrika Kulatilleke*, Saliya de Silva
978. High sensitive and selective fluorescent
probe for mercury(II) and silver(I) ions.
Koji Tsukamoto*, Hatsuo Maeda
979. Polymeric crack sensors based on anthracene dimer moieties. Ye Hyun Jo,
Sung-Youl Cho, Chan-Moon Chung*
980. Development of fluorescence activatable probes for ␤-galactosidase and their
application as a diagnostic tool for the
detection of peritoneal metastases of
ovarian tumors in mouse models.
Daisuke Asanuma*, Mako Kamiya,
Mikako Ogawa, Nobuyuki Kosaka,
Yukihiro Hama, Yoshinori Koyama,
Peter L. Choyke, Hisataka Kobayashi,
Tetsuo Nagano, Yasuteru Urano
981. Development of a novel copper(I) fluorescent probe utilizing copper-dioxygen
activation mechanism. Masayasu Taki*,
Shohei Iyoshi, Yukio Yamamoto
982. Structural, electrochemical, and photophysical properties of fluorescent copper
probes containing multidentate thioether
ligand. Shohei Iyoshi, Masayasu Taki,
Yukio Yamamoto*
983. Development of novel fluorescence
probes for hydrogen peroxide.
Masahiro Abo*, Yasuteru Urano,
Tetsuo Nagano
984. Development of highly sensitive novel
fluorescence probes to detect activity of
protease based on unique intramolecular
spirocyclization and its application to tumor imaging in vivo. Masayo Sakabe,
Mikako Ogawa, Nobuyuki Kosaka,
Hisataka Kobayashi, Tetsuo Nagano,
Yasuteru Urano
985. Application of ruthenium metalloglycocluster for affinity evaluation between
carbohydrates and lectins by fluorescence emission and polarization.
Tomoko Okada*, Taro Makino,
Norihiko Minoura
Convention Center
Kamehameha Halls II and III
Advances in Flow-based Analytical
Techniques (#207)
Organized by: I. McKelvie, G. Christian,
K. Grudpan, T. Imato
Poster Session
19:00 – 21:00
986. Surface plasmon resonance sensor on
a compact disk-like microfluidic device.
Akihide Hemmi, Takashi Usui,
Akihiro Moto, Tatsuya Tobita,
Toshihiko Imato, Katsumi Uchiyama,
Hizuru Nakajima*
987. Integrated fluorescence detection system using organic light emitting diodes as
light source. Mayo Miyake,
Yukiko Okuma, Akihide Hemmi,
Daisuke Yokoyama, Masayuki Yahiro,
Chihaya Adachi, Toshihiko Imato,
Katsumi Uchiyama, Hizuru Nakajima*
988. Chemiluminescence of cerium(IV)-rhodamine B system in a reversed micellar
medium of cetyltrimethylammonium chloride in 1-hexanol-cyclohexane and invention of new flow injection analysis.
Yusuke Tsunemine*, Tamer Hasanin,
Yasuaki Okamoto, Satoshi Tsukahara,
Terufumi Fujiwara
989. Flow injection-tandem spectrophotometric detection system for determination
of cadmium and lead using soret-band
sift of a water-soluble porphyrin.
Jun-ichi Itoh*, Norihiro Takemoto,
Yoichi Wada, Jun-ichiro Uemura
990. Synthesis of cellulose functionalized
with polyallylamine and its application to
on-line collection and determination of
phosphate. Takashi Sumida*,
Minoru Yamashita, Yuka Okazaki,
Nozomu Tsuruta, Hirohisa Kawakita,
Hayato Shinohara, Takashi Hukutomi
991. Development of micro-flow analytical
techniques for hydrothermal reactions.
Kunio Kawamura*, Keisuke Ikoma,
Tomoko Yasuda, Hiroki Nagayoshi,
Hitoshi Takeya, Shukuro Igarashi,
Hideaki Hisamoto, Toshio Yao
992. On-line gas diffusion/ion exchange preconcentration technique for the determination of trace ammonium ion in environmental water samples by flow injection
analysis. Minoru Ueda, Keisuke Fukui,
Keiro Higuchi, Norio Teshima,
Tadao Sakai*
993. Flow injection determination of oxalate
by photochemical reaction and near infrared spectrophotometry.
Makoto Kurihara*, Shohtaro Kato,
Chiharu Ura, Rumi Satake
994. Rapid detection of point mutations
based on oligonucleotide ligation.
Masahiko Hashimoto*,
Kazuma Yoshida, Kazuhiko Tsukagoshi
995. Direct detection of nonlabeled amino
acids using micro-HILIC-HPLC with ultraviolet thermal lens spectroscopy.
Yujiro Sumi, Akira Harata
996. Fluorimetric flow injection analysis of
fluoride ion with alkylsilylated fluoresceins. Toshio Takayanagi*, Mayu Nakaya,
Hiroki Yamashita, Mitsuko Oshima,
Shoji Motomizu
997. Determination of nefopam in pharmaceutical preparations by sequential injection analysis with chemiluminescence detection. Miroslav Polasek*,
Lucie Stepankova, Petr Solich
998. Microfluidic chip-based nanoliquid
chromatography-tandem mass spectrometry for bioanalysis.
Ming-Ren S. Fuh*, Hsin-Yu Bai,
Shu-Ling Lin, Shun-An Chan
999. Chemiluminescence from the decomposition of peroxymonocarbonate and its
application in flow injection analysis.
Jin-Ming Lin*, Hui Chen
1000. On-line sample preparation in the sequential injection systems. Petr Solich*,
Hana Sklenárová*, Jana Škrlíková*,
Petra Záková, Petr Chocholouš,
Vasil Andruch, Miroslav Polášek
1001. Preparation and evaluation of chelating functional group modified polymer
monolith as sorbent using for preconcentration and matrix separation for ICP-AES
and ICP-MS. Masahiko Murakami*,
Masaya Hirano
1002. On-line selective determination of glucose via two-step immobilized enzymatic
reactions. Yoshitaka Nakashima,
Lee Wah Lim, Toyohide Takeuchi*
1003. Downscaling chemical analysis employing flow-based techniques.
Kate Grudpan*, Supaporn K. Hartwell,
Tinakorn Kanyanee, Wasin Wongwilai,
Kanchana Watla-iad,
Somchai Lapanantnoppakhun
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–67
01-ANYL/02-INOR
Monday Morning
Convention Center
301A
Advances in Flow-based Analytical
Techniques (#207)
TECHNICAL PROGRAM
INOR
Area 2 – Inorganic
Wednesday Morning
Organized by: I. McKelvie, G. Christian,
K. Grudpan, T. Imato
Presiding: D. Nacapricha, T. Sakai
Hilton
Nautilus I & II
Frontiers in Organometallic Chemistry (#68)
7:30 Introductory remarks
7:35 – 1004. Trace analysis of dissolved species by vaporization-collection micro flow
system. Kei Toda*, Haruka Kuwahara,
Shin-Ichi Ohira
8:10 – 1005. Automated analysis for perchlorate in atmospheric aerosol.
Masaki Takeuchi*, Kaoru Yoshioka,
Yusuke Toyama, Ai Kagami,
Hideji Tanaka
8:30 – 1006. All injection analysis: A simple
flow injection system for monitoring.
Hideyuki Itabashi*
8:50 – 1007. Development of flow chemical
analyzers using computer-controllable
pumps and valves and their application to
trace analysis. Shoji Motomizu*,
Keiro Higuchi
9:25 – 1008. Determination of tramp elements in steel by flow injection analysis
using on-line separation and atomic absorption spectrometric detection.
Koichi Oguma*
9:45 – 1009. Microdetermination of heavy
metal ions in flow streams with use of immobilized apoenzymes chemically or
physically regenerated from their corresponding metalloenzymes. Ikuo Satoh*
10:20 – 1010. Flow injection analysis methodology for the determination of pyrite
mineral reactivity. Owen D. Osborne*,
Claire E. Lenehan, Allan Pring
10:40 – 1011. On-line determination of wadcyanide based on cyanide-ligand exchange by amperometric gas diffusionflow injection. Hermin Sulistyarti*,
Spas D. Kolev
11:00 – 1012. On-line digestion in flow analysis: Evolution and applications in environmental chemistry. Ian D. McKelvie*,
Peter S. Ellis, Brady S. Gentle
Organized by: G. Bertrand, M. Fryzuk,
K. Tatsumi
Presiding: K. Tatsumi
7:30 – 1. New ammoxidation catalysts from
rhenium carbonyl cluster complexes containing antimony and bismuth ligands.
Richard D. Adams*, William C. Pearl
8:00 – 2. New cyclopentadienylmetal-fused
thiophenes, carboxylic anhydrides and
dithiins. John P. Selegue*,
Uttam R. Pokharel, Deepshikha Gupta,
Sean Parkin
8:30 – 3. Transition metal complexes containing bulky tin groups. Burjor Captain*,
Veeranna Yempally, Lei Zhu, Derek Isrow,
George Fortman, Carl D. Hoff
9:00 – 4. Aspects of hydrodesulfurization
and hydrodenitrogenation as modeled by
trimethylphosphine molybdenum and
tungsten compounds. Gerard Parkin*
9:30 – 5. Organometallic rhenium- and molybdenumoxides and their applications.
Fritz E. Kühn*
10:00 – 6. Progress and challenges in organometallic chemistry of buckybowls.
Marina A. Petrukhina*
10:30 – 7. Design and catalytic performances of supported metal-complex catalysts on oxide surfaces. Mizuki Tada*
11:00 – 8. Cyclometallated complexes: Formation and functions. Andy T. Hor*,
Wenhua Zhang, Jian Jin Hu,
David J. Young
Hilton
Kahili I/II
Discrete Coordination Systems with
Switchable Structures and Properties (#143)
Convention Center
317A
Organized by: T. Konno, A. Hor, K. Lu
Presiding: T. Konno
Ionic Liquids for Analytical Chemistry and
Analytical Chemistry for Ionic Liquids (#166)
7:30 – 9. Discrete multinuclear system with
switchable structures and properties.
Takumi Konno*
7:50 – 10. Supramolecular architectures derived from Cu(II) complexes of 1,3-aryllinked bis-␤-diketonato ligands: Toward a
pressure controlled molecular switch.
Leonard F. Lindoy*, Katrina A. Jolliffe,
Jack K. Clegg, George V. Meehan,
Simon Parsons, Peter A. Tasker,
Peter Turner, Fraser J. White
8:20 – 11. Nanoelectronics molecular metal
wires and related molecular materials.
Shie-Ming Peng
8:50 – 12. Absolute asymmetric photoisomerization of a photochromic rhodium
dithionite complex in chiral crystals.
Kiyoshi Isobe
9:10 – 13. Single-crystalline photochromism
of a platinum complex.
Nobuyuki Matsushita*, Kousei Araki,
Hajime Nishimura, Noriko Miura,
Minami Senda, Tomomi Fujiwara
9:30 – 14. Discrete supramolecular soft
metal complexes of thiamacrocycles
bearing less-common stoichiometries.
Sunhong Park, So Young Lee,
Hyun Jee Kim, Shim Sung Lee*
10:00 – 15. Coordination-driven self-assembly of electron-rich tetrathiafulvalenebased architectures. Marc Sallé*,
Sebastien Goeb, Jean-Yves Balandier,
Sebastien Bivaud, Paul Dron,
Marcos Chas, Guillaume Bastien
10:30 – 16. Metal-organic macrocycles, metal-organic polyhedra, and metal-organic
frameworks. Myoung Soo Lah*
10:50 – 17. Redox-active octanuclear copper complexes. Tatsuya Kawamoto,
Yukiko Hayashi
Organized by: T. Kakiuchi, D. Armstrong,
A. Bond
Presiding: I. Pletnev, T. Kakiuchi
7:45 – 1013. Preparation and potential electrochemical applications of ionic liquidfunctionalized nanocomposites. Li Niu*
8:15 – 1014. Ionic liquids with nonfluorinated
anions for separations and ion sensing.
Igor Pletnev*
8:45 – 1015. Ionic liquid monolayer for sensor applications.
Jean-Francois Masson,
Mathieu Branca*, Mathieu Ratel,
Andreea R. Schmitzer
9:00 – 1016. New pH electrode with ionic liquid junction as a salt-bridge. Yota Kudo,
Ryoei Kikuchi, Kazuhiko Fujiwara,
Manabu Shibata, Keiko Kuwamoto,
Satoshi Nomura, Takashi Kakiuchi,
Nobuaki Ogawa*
9:15 – 1017. Electrode kinetics of some
metal complexes in an amide-type ionic
liquid. Yasushi Katayama*,
Yusuke Kawahara, Yuichi Toshimitsu,
Takashi Miura
9:30 – 1018. Significance of ultraslow dynamics of the structure of ionic liquid in
the vicinity of the interface on electrochemical measurement.
Takashi Kakiuchi*, Yukinori Yasui,
Yuki Kitazumi, Naoya Nishi
10:00 Closing remarks
68 –TECH
11:10 – 18. Interconverting between two different classes of architectures along two
different pathways switches on and off ligand-based mixed-valency.
Amar H. Flood*, Kumar Parimal,
Edward H. Witlicki
Hilton
Rainbow II
Electron Transfer and Electrochemistry of
Transition Metal Containing Inorganic and
Organometallic Materials (#187)
Organized by: H. Nishihara,
A. Abd-El-Aziz, P. Harvey, B.Z. Tang
Presiding: H. Nishihara
7:30 Opening remarks
7:40 – 19. Control of intramolecular electron
transfer in cyanide-bridged molecular
squares. Masayuki Nihei*,
Yoshihiro Sekine, Hiroki Oshio
8:05 – 20. Intermetallic communication mediated by carbon-silicon hybrid connectors. Claude Lapinte*,
Jean-René Hamon, Harald Stûger
8:30 – 21. Electrical properties of Pd(dmit)2
salts up to 20 GPa by using a diamond
anvil cell. HengBo Cui*, Naoya Tajima,
Reizo Kato
8:50 – 22. Fluorine mimic effect in a new molecular superconductor, fluorinated alkylammonium salt of Pd(dmit)2.
Mitsushiro Nomura, Akiko Tajima,
HengBo Cui, Hiroshi M. Yamamoto,
Reizo Kato*
9:10 – 23. Ferrocene-peptide conjugates:
Probing electron transfer. Bernie Kraatz*
9:35 – 24. Development of manganese oxide-based cathode catalysts for anionexchange membrane fuel cells.
Morihiro Saito*, Masato Akiyoshi,
Tatsuya Takakuwa, Yu Matsui,
Akimasa Tasaka, Minoru Inaba,
Takeo Hatai, Jun Kuwano
9:55 – 25. Proton-induced tuning of metalmetal interaction in dinuclear Ru complexes bearing benzimidazolyl ligand.
Masa-aki Haga, Masamichi Ishikubo,
Katsuhiko Kanaizuka
10:15 – 26. Modulation of the electronic
communication within the backbone of a
family of molecular motors.
Gwenael Rapenne*
10:40 – 27. Relationship between the molecular structures and spectroscopic and
electrochemical properties of giant aromatic molecules. Nagao Kobayashi*
11:00 – 28. Electro- and photonic properties
of conjugated organometallic polymers
built upon quinone diimines or benzenediiamines and platinum(II).
Pierre D. Harvey*
Hilton
Sea Pearl III/IV
Actinides and the Environment: A
Multidisciplinary Look at What We Know
and What We Need to Know (#38)
Organized by: H. Nitsche, D. Kaplan,
C. Liu, Z. Yoshida
Presiding: H. Nitsche, T. Kimura
7:45 – 29. Actinide adsorption at solid-liquid
interfaces: Current status and future challenges. Takumi Saito*
8:15 – 30. Structure of plutonium oxide on
mineral surfaces. Annie Kersting,
Brian Powell, Mavrik Zavain,
Pihong Zhao, Zurong Dai
8:45 – 31. Thermodynamic data for environmentally important actinide species.
Takayuki Sasaki*
9:15 – 32. Plutonium sorption to silica: Influence of radiolysis and sorption entropy.
Amy Hixon*, Michael Lilley, Brian Powell
9:35 – 33. Interactions of bulk and mesoporous ferrihydrite with plutonium (VI).
Luna K. Schwaiger*, Harun Tüysüz,
Deborah Wang, Yung-Jin Hu,
Tashi Parsons-Moss, Peidong Yang,
Heino Nitsche
9:55 – 34. Effect of fulvic acid on the sorption of plutonium to minerals.
Laura Simpkins*, Brian A. Powell
10:15 – 35. Interactions of plutonium(VI) with
mixed goethite/manganese-substituted
goethite using microprobe X-ray analysis.
Yung-Jin Hu*, Luna K. Schwaiger,
Samuel M. Webb, Deborah L. Wang,
Heino Nitsche
10:35 – 36. High-sensitive measurement of
XAFS for uranium and other trace elements in crustal materials using bent
crystal analyzer. Yoshio Takahashi*
11:05 – 37. Radionuclide sorption: Models,
data, and applications. Wangsuo Wu
Hilton
Hibiscus I/II
Molecular Photonics (#9)
Organized by: F. Castellano, T. Majima,
V. Yam
Presiding: F. Castellano
8:00 – 38. Synthesis, structural and electronic properties of some new erbiumbased materials. Ian S. Butler,
Hassane Assaaoudi, Janusz A. Kozinski
8:20 – 39. Photo-responsive self-assembled
molecular flasks. Takashi Murase,
Hiroki Takezawa, Makoto Fujita*
8:40 – 40. Blue phosphorescent emitters:
Platinum and silver NHC complexes.
Thomas Strassner
9:00 – 41. Nanocrystal chemosensors based
on energy transfer: Application to bioimaging. Daniel G. Nocera
9:30 – 42. Atom-like optical properties of
colloidal PbS and PbSe quantum dots for
near-IR applications.
Frank C. van Veggel*
10:00 – 43. Designing plasmonic crystal
platforms for ultrasensitive biosensing.
Teri W. Odom*
10:30 – 44. Photonic properties of polymer
nano-junctions. Pavel Anzenbacher*,
Manuel A. Palacios, Fengyu Li
11:00 – 45. Metal strings and clusters in supramolecular assemblies.
Mitsuhiko Shionoya*
Hilton
Rainbow III
Metal Ion Complex Interactions with
Nucleic Acids (#30)
Organized by: J. Morrow, R. Keene,
M. Komiyama
Presiding: J. Morrow
8:00 – 46. Interaction of ruthenium(II) lightswitch complexes with DNA structures
within living cells. Martin Gill,
Hanan Derrat, Guiseppe Battaglia,
Carl Smythe, Jim A. Thomas*
8:35 – 47. Structural and functional consequences of platinum anticancer drug
binding to free and nucleosomal DNA.
Stephen J. Lippard
9:10 – 48. Metal ion interaction with pyrimidine-pyrimidine base pairs in DNA duplexes. Akira Ono*
9:45 – 49. Importance of RNA as a target for
Pt(II) anticancer compounds.
Victoria DeRose*, Erich G. Chapman,
Alethia A. Hostetter, Amanda Miller,
Maire F. Osborn
10:20 – 50. Hybrid inorganic-peptide nucleic
acid structures. Catalina Achim*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
10:55 – 51. Lanthanide binuclear helicates
as bioprobes for nucleic acid and cancerous tissue analysis.
Jean-Claude G. Bünzli*
Hilton
South Pacific I
Early Main Group Chemistry (#100)
Organized by: P. Andrews, T. Chivers,
K. Henderson
Presiding: T. Chivers
8:00 – 52. Advances in alkali-metal-mediated metallation. Robert E. Mulvey*
8:30 – 53. Lithium aluminate bases for selective organic synthesis. Hiroshi Naka*
8:50 – 54. Exposing the hidden complexity
of stoichiometric and catalytic metathesis
reactions: Elucidation and applications of
Mg-Zn hybrids. Matthew McCall,
Pablo García-Alvarez, Eva Hevia*,
Jonathan Chua, Alan Kennedy
9:10 – 55. Geminal dianions: Roles of
charge-separation and aggregation in
governing kinetic basicity.
Kenneth Henderson*, Seth N. Brown,
Katherine L. Hull
9:30 – 56. Alkali metal promoted anion rearrangements and their role in asymmetric
synthesis. Phil Andrews*, Steve Bull,
Magdaline Koutsaplis
9:50 – 57. Structure-reactivity relationships
in lithium enolates. David B. Collum
10:20 – 58. Application of diffusion NMR
techniques to alkali metal complexes.
Paul G. Williard*, Weibin Li,
Gerald Kagan, Russell Hopson
10:40 – 59. Structure and reactivity of lithium
enolates. Kristopher J. Kolonko,
Hans J. Reich*
11:00 – 60. Lithium enolates and lithium
amides for asymmetric synthesis.
Steven D. Bull*
Hilton
Lehua Suite
Preparation and Reactions of Early
Transition Metal and Lathanide
Compounds (#150)
Organized by: T. Takahashi, G. Deacon,
R. Jordan, Z. Xi
Presiding: T. Takahashi
8:00 – 61. Preparation of group 3 metal complexes with N,N’-bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene ligand via
salt metathesis and direct reduction reactions. Hayato Tsurugi*, Tarun K. Panda,
Hiroshi Kaneko, Kuntal Pal,
Kazushi Mashima
8:30 – 62. Use of the lanthanide contraction
for the syntheses of diverse lanthanide
methacrylate complexes: Investigations
toward lanthanide templating for polymer
resins. Daniel B. Rego*, Paul M. Forster,
Philippe F. Weck, Kenneth R. Czerwinski
9:00 – 63. Radioactive electron-rich metalmetal triple bonds: The Tc2X4(PMe3)4
complexes (X ⫽ Cl, Br).
Alfred Sattelberger, Frederic Poineau,
Paul Forster, Tanya Todorova,
Laura Gagliardi, Ken Czerwinski
9:30 – 64. Synthesis and characterization of
new binary technetium halides.
Frederic Poineau, Alfred Sattelberger,
Paul Forster, Philippe Weck,
Erik Johnstone, Longzhou Ma,
Ken Czerwinski
10:00 – 65. Activation of C-H, C⫽O, and
C⫽S bonds by polynuclear rare earth
metal polymethyl carbene/methylene
complexes. Jianquan Hong,
Lixin Zhang*, Zhengxing Zhang,
Xiaying Yu, Meng Li, Xigeng* Zhou*
10:30 – 66. Metallacarboranes of f-block elements: New synthetic strategies, novel
structural patterns, and applications.
Narayan S. Hosmane
11:00 – 67. Structure-bonding insights and
reactivity patterns of f-element carbenes
with formal M⫽C double bonds.
Stephen T. Liddle*, David P. Mills,
Ashley J. Wooles, Oliver J. Cooper,
Jonathan McMaster, William Lewis,
Alexander J. Blake
Hilton
Rainbow I
Functional Molecules of the Heavier Main
Group and Transition Metal Elements (#156)
Organized by: F. Ozawa, D. Gates,
P. Power
Presiding: F. Ozawa, C. Cummins
8:00 Introductory remarks
8:05 – 68. Silylene and stannylene complexes in new stoichiometric and catalytic
transformations. T. Don Tilley*
8:30 – 69. Diversified reactivity of neutral silylene and germylene complexes.
Hiromi Tobita*, Hisako Hashimoto
8:55 – 70. Ligand-induced dinitrogen cleavage. Paul Chirik
9:20 – 71. Dinuclear half-sandwich (␩6arene)Fe(II) dinitrogen complexes having
a disilametallacycle skeleton.
Yusuke Sunada*, Tsuyoshi Imaoka,
Hideo Nagashima
9:40 – 72. Application of nucleophilic boryl
anion to organic synthesis and organotransition metal chemistry.
Makoto Yamashita*,
Tomomi Terabayashi, Takashi Kajiwara,
Yuri Okuno, Kyoko Nozaki*
10:00 – 73. Click reactions with strained
phosphorus heterocycles.
Rainer Streubel*
10:25 – 74. Rich chemistry of phosphaalkenes: From novel structures and bonding
to applications in asymmetric catalysis.
Joshua I. Bates, Julien Dugal-Tessier,
Gregory R. Dake*, Derek P. Gates*
10:50 – 75. Structure and reactivity of iron(I)
complex bearing a bis(phosphaethenyl)pyridine ligand. Yumiko Nakajima,
Fumiyuki Ozawa*
11:10 – 76. Advances in phosphine dehydrocoupling and applications.
Rory Waterman*
Hilton
Coral I
Carbon-fluorine Bond Activation: a
Crossroads for Inorganic, Organic, and
Environmental Chemistry (#248)
Organized by: O. Ozerov, T. Akiyama,
J. Love
Presiding: O. Ozerov
8:00 Introductory remarks
8:05 – 77. Large contribution of projected
hydrofluorocarbons (HFCs) emissions to
future climate forcing. Guus Velders*
8:45 – 78. Carbon-fluorine bond activation
by early and late transition metals.
William D. Jones*
9:25 – 79. C-F bond activation in organic
synthesis. Kenji Uneyama*,
Shinya Utsumi, Toshimasa Katagiri
10:05 – 80. Modeling hydrodefluorination of
fluoroaromatics at ruthenium N-heterocyclic carbene complexes: Novel arene migratory insertion accounts for unusual
1,2-regioselectivity. Julien A. Panetier,
Michael K. Whittlesey,
Stuart A. Macgregor
10:45 – 81. What’s special about C-F oxidative addition at group 10 metals?
Robin Perutz*, John E. McGrady,
Stuart A. Macgregor, Torsten Beweries,
Naser Jasim
Hilton
Coral II
Syntheses and Applications of MetalOrganic Frameworks (#97)
Organized by: M.P. Suh, C. Kepert,
S. Kitagawa, J. Long, G. Shimizu
Presiding: S. Kitagawa
8:30 – 82. New ligands for discrete and infinite metal-organic materials.
Michael J. Zaworotko, Jason Perman,
George Norton, Wenge Qiu
9:00 – 83. From metal-organic polyhedra to
metal-organic frameworks.
Hong-Cai Zhou*, Jian-Rong Li
9:30 – 84. Multicomponent liquid phase epitaxy of layer-based SURMOFs.
Roland A. Fischer*, Denise Zacher,
Angelique Bétard, Mikhail Meilikhov,
Kirill Yusenko, Osama Shekhah,
Tatjana Ladnorg, Christof Woell
10:00 – 85. Metal-organic frameworks and
the “gene” for carbon dioxide capture.
Omar Yaghi
10:30 – 86. Post-synthetic modification of
rigid porous coordination polymers.
Jan Reedijk
10:50 – 87. Layer-by-Layer growth of highlycrystalline preferentially-oriented MOF
nanofilms on solid surfaces.
Rie Makiura*, Osami Sakata,
Hiroshi Kitagawa
11:10 – 88. Nanosized porous coordination
polymer crystals fabricated by coordination modulation method.
Shuhei Furukawa*, Stephane Diring,
Hiromitsu Uehara, Takaaki Tsuruoka,
Susumu Kitagawa
Wednesday Afternoon
Hilton
Hibiscus I/II
Molecular Photonics (#9)
Organized by: F. Castellano, T. Majima,
V. Yam
Presiding: V. Yam
12:30 – 89. Phosphorescent, heteroleptic,
bis-cyclometalated complexes of Platinum(IV). Dustin M. Jenkins,
Stefan Bernhard*
12:50 – 90. Nonradiative decay processes in
cyclometalated iridium complexes.
Peter I. Djurovich*, Mark E. Thompson
13:10 – 91. Strategy for improving the lightharvesting properties of tridentate cyclometalated Ru(II) complexes.
Kiyoshi C. Robson, Bryan D. Koivisto,
Curtis P. Berlinguette*
13:30 – 92. Metal complexes for advanced
optoelectronic devices, i.e. solar cells
and LEDs. Mark Thompson
14:00 – 93. Photomobile materials based on
crosslinked photochromic liquid-crystalline polymers. Tomiki Ikeda*,
Mizuho Kondo, Munenori Yamada,
Yumiko Naka, Jun-ichi Mamiya,
Motoi Kinoshita, Atsushi Shishido
14:30 – 94. High efficiency near-infrared
phosphorescent materials and devices.
Kirk S. Schanze, Jon Sommer,
Kenneth Graham, Yixing Yang,
John R. Reynolds, Jiangeng Xue
15:00 – 95. Luminescent cyclometalated
Iridium(III) polypyridine complexes as biological labels and probes.
Kenneth K. Lo*
15:30 – 96. Electroluminescent metal complexes and their assemblies.
Luisa De Cola*, Matteo Mauro,
Noviyan Darmawan
16:00 – 97. Tuning optical and electronic
properties using computational chemistry
and spectroscopy. Keith Gordon*
13:30 – 100. Unraveling the mechanism of
transition metal catalysed amine-borane
dehydrocoupling using rhodium phosphine fragments. Andrew S. Weller*
13:55 – 101. C-CN and N-CN bond cleavage
catalyzed by a transition-metal complex.
Hiroshi Nakazawa*, Kozo Fukumoto,
Kouji Kamata, Masumi Itazaki
14:20 – 102. Organometallic approaches to
dinitrogen activation and functionalization. Michael Fryzuk
14:50 – 103. Isocyanide analogs of the unsaturated binary carbonyls.
Josh Figueroa*, Liezel Labios,
Grant Margulieux
15:15 – 104. Iron catalysts for the enantioselective reduction of ketones.
Robert H. Morris*
15:40 – 105. Making and breaking triple
bonds: Synthesis, reactivity, and deactivation of catalysts for the metathesis of
nitriles and alkynes. Marc J. Johnson*,
Eric S. Wiedner, Jeff W. Kampf
16:05 – 106. Allyl complexes of group 2, 3,
and 13 metals: Structure, bonding, and
reactivity. Jun Okuda*
Hilton
Coral II
Syntheses and Applications of MetalOrganic Frameworks (#97)
Organized by: M.P. Suh, C. Kepert,
S. Kitagawa, J. Long, G. Shimizu
Presiding: C. Kepert
12:30 – 107. Evolution of porous coordination polymers. Susumu Kitagawa*
13:00 – 108. Porous frameworks for hydrogen storage and carbon dioxide capture.
Myunghyun P. Suh*, Hye Jeong Park,
Dea Ho Hong, Dae Woon Lim
13:30 – 109. Flexible porous coordination
polymers for gas sorption.
Xiao-Ming Chen*
14:00 – 110. Gas adsorption and selectivity
by metal-organic framework materials.
Martin Schroder*
14:30 – 111. MOFs with amine lined pores
for carbon dioxide capture.
George Shimizu,
Ramanathan Vaidhyanathan,
Simon Iremonger, Isaac Martens
15:00 – 112. CO2 and O2 capture in metalorganic frameworks.
Thomas M. McDonald, Zoey R. Herm,
Eric Bloch, Kenji Sumida, Lily Huang,
Leslie J. Murray,
Deanna M. D’Alessandro,
Aude Demessence, Maw Lin Foo,
Jeffrey R. Long*
15:30 – 113. Mixture adsorption in metal organic frameworks: Toward a systematic
evaluation/prediction with respect to a
given application. Philip L. Llewellyn*,
Sandrine Bourrelly, Andrew Wiersum,
Christelle Vagner
15:50 – 114. Guest-induced structural transformations and specific guest adsorptions of flexible porous coordination polymers. Ryotaro Matsuda*, Hiroshi Sato,
Sareeya Bureekaew, Joobeom Seo,
Susumu Kitagawa
16:10 – 115. Pressure-induced pore modification and amorphization in a metal-organic framework. Karena W. Chapman*,
Gregory J. Halder, Peter J. Chupas
Hilton
Nautilus I & II
Frontiers in Organometallic Chemistry (#68)
* Principle Author
Organized by: G. Bertrand, M. Fryzuk,
K. Tatsumi
Presiding: R. Adams
12:30 – 98. Activation of small molecules
promoted by coordinatively unsaturated
half-sandwich rhodium and iridium complexes of 2,6-dimesitylphenyl thiolate.
Kazuyuki Tatsumi*, Mayumi Sakamoto,
Yasuhiro Ohki
13:00 – 99. Hydrogen activation in water.
Seiji Ogo*
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–69
02-INOR
TECHNICAL PROGRAM
Hilton
Kahili I/II
Hilton
Rainbow II
Discrete Coordination Systems with
Switchable Structures and Properties (#143)
Electron Transfer and Electrochemistry of
Transition Metal Containing Inorganic and
Organometallic Materials (#187)
Organized by: T. Konno, A. Hor, K. Lu
Presiding: K. Tsuge
12:30 – 116. Helix inversion and helicity control of single-helical zinc(II)-lanthanum(III)
oligonuclear complexes.
Shigehisa Akine*, Tatsuya Nabeshima
12:50 – 117. Orange and yellow crystals of
copper(I) complexes bearing 8-diphenylphosphinoquinoline: A pair of distortion isomers of intrinsically tetrahedral
complex. Takayoshi Suzuki*,
HIroshi Yamaguchi, Akira Hashimoto,
Koichi Nozaki, Noriaki Ikeda,
Satoshi Kawata, Masaaki Kojima,
Hideo D. Takagi
13:10 – 118. Switchable ruthenium vinylidene system by a novel skeletal rearrangement. Ying-Chih Lin*
13:40 – 119. Metallosupramolecular structures with polycarbene ligands.
Ekkehardt Hahn*
14:10 – 120. Fluorescent tin(IV) and indium(III) complexes with Schiff base ligands. Kentaro Takano,
Makoto Takezaki, Toshihiro Tominaga,
Haruo Akashi, Hideaki Takagi,
Takashi Shibahara*
14:30 – 121. Dual photo- and electro-chromic dinuclear Fe- and Ru-complexes with
␴-bonded dithienylethene bridge.
Takashi Koike, Munetaka Akita*
14:50 – 122. Dynamic reversibility between
two-State transition metal propagators
for the living coordination polymerization
of ␣-olefins. Lawrence R. Sita*, Jia Wei,
Wei Zhang
15:10 – 123. Functional supramolecular
chemistry strategies for the deployment
of biomimetic catalysts. Suk Joong Lee,
Byungman Kang, Kyoung-Tae Youm,
Ryan K. Totten, Joseph T. Hupp*,
SonBinh T. Nguyen*
15:40 – 124. Switchable structures and
properties resulting from the metal coordination of hybrid ligands.
Pierre Braunstein*, Roberto Pattacini
Hilton
Lehua Suite
Preparation and Reactions of Early
Transition Metal and Lathanide
Compounds (#150)
Organized by: T. Takahashi, G. Deacon,
R. Jordan, Z. Xi
Presiding: T. Takahashi
12:30 – 125. How to synthesize “feebly”
chiral organic compounds via ZACAlipase-catalyzed acetylation Pd or Cucatalyzed cross-coupling. Eiichi Negishi*
13:10 – 126. Ansa-zirconocenes by intramolecular [2⫹2]cycloaddition: A case of dynamic topochemical reaction control.
Ingo Greger, Gerald Kehr,
Roland Fröhlich, Jan Paradies,
Gerhard Erker*
13:50 – 127. Preparation and free radical reactions of Ti(III) and Ti(IV) propargyl complexes: The synthesis of titanacyclobutene and, by transmetallation,
boracyclobutene compounds.
Richard C. Bauer, Masaki Morita,
Jeffrey S. Quesnel, Jeremy Gauthier,
Jeffrey M. Stryker*
14:30 – 128. Versatile metal-based processes in synthesis: From Fischer carbene complexes to late transition metal
catalysis. Jose Barluenga
15:10 – 129. Highly stereoselective construction of multiple stereogenic centers
by the reactions of allyl- and allenyltitanocenes with ketones.
Takeshi Takeda*
15:40 – 130. Benzylidene in the platform of
half-metallocene complexes of tantalum.
Kazushi Mashima*, Tsuyoshi Ohno,
Hayato Tsurugi
70 –TECH
Organized by: H. Nishihara,
A. Abd-El-Aziz, P. Harvey, B.Z. Tang
Presiding: H. Nishihara
12:30 – 131. Mechanism of ammonia formation from dinitrogen and dihydrogen using an iron-phosphine complex.
David R. Tyler*, Chantal G. Balesdent,
Justin L. Crossland
12:55 – 132. Redox-active metallomesogens: Fluctuated structures and electrochemical bistability. Ho-Chol Chang*,
Kazuki Komasaka, Tomoki Shiozaki,
Keisuke Kishida, Takeshi Ohmori,
Susumu Kitagawa, Atsushi Kobayashi,
Masako Kato
13:15 – 133. Metallophosphors and metallopolyynes as new electrofunctional materials for optoelectronic applications.
Wai-Yeung Wong*
13:40 – 134. Ru(II) complexes with amide
linked oligothienyl(diimine) ligands for
photochemical energy conversion.
Marek B. Majewski*,
Frederick M. MacDonnell,
Michael O. Wolf
14:00 – 135. Electron transfer in organic and
organometallic fullerenes on electrode
surfaces and switchable photocurrent
generation. Takahiko Ichiki,
Yutaka Matsuo, Nakamura Eiichi*
14:20 – 136. Silole-based electroluminescent materials and devices. Yuning Hong,
Ben Zhong Tang
14:45 – 137. Application of mixed-valence
Cu(I)-Cu(II) metal-organic frameworks as
photosensitizers of dye-sensitized solar
cells. Kyung Ho Kim*, Yoshie Inuzuka,
Naoya Tanaka, Takashi Okubo,
Masahiko Maekawa,
Takayoshi Kuroda-Sowa
15:05 – 138. Fine control of metal assembly
in dendrimers. Kimihisa Yamamoto*
15:30 – 139. Polymetallocenes: Electroactive
metallopolymers. Ian Manners*,
George Whittell
15:55 – 140. Synthesis and cyclic voltammetric studies of functionalized organoiron materials. Alaa S. Abd-El-Aziz*,
Patrick O. Shipman, Diana J. Winram,
Chis Rock, Elizabeth Strohm,
Paul R. Shipley
Hilton
Sea Pearl III/IV
Actinides and the Environment: A
Multidisciplinary Look at What We Know
and What We Need to Know (#38)
Organized by: H. Nitsche, D. Kaplan,
C. Liu, Z. Yoshida
Presiding: Z. Yoshida, N. Wall
12:45 – 141. Actinide adsorption at mineral
surfaces: Density functional modeling for
the example of uranyl on kaolinite.
Notker Roesch*
13:15 – 142. Modeling the chemistry of actinide species in the environment.
Wibe A. de Jong*, Donald Johnson,
Raymond Atta-Fynn, Vanda Glezakou,
Ping Yang, Eric Bylaska
13:40 – 143. Computational modeling of
NMR properties of uranyl complexes with
environmental significance. Guo Chen,
Jun Li*
14:00 – 144. Interaction of aqueous uranium
species with TiO2 surfaces.
Samuel O. Odoh, Qing-Jiang Pan,
Georg Schreckenbach*
14:20 – 145. Quantifying structure-stability
relationships of actinide complexes in solution using X-ray scattering.
Lynda Soderholm*, Richard E. Wilson,
S. Skanthakumar
14:50 – 146. Effects of bacterial adsorption
on the speciation and reduction of uranium in the subsurface. Jeremy B. Fein*
15:15 – 147. Mineralization of actinides on
the surface of microorganisms and minerals. Toshihiko Ohnuki*
15:40 – 148. Modeling plutonium interactions with complex molecules and interfaces. Brian A. Powell*,
Trevor N. Zimmerman, Laura A. Simpkins
16:10 – 149. Influence of microorganisms on
the oxidation-state distribution of multivalent actinides under anoxic conditions.
Donald T. Reed*, Juliet Swanson,
David Ams, Marian Borkowski,
Jean Francois Lucchini,
Michael Richmann, Hnin Khaing
Hilton
Coral I
Carbon-fluorine Bond Activation: a
Crossroads for Inorganic, Organic, and
Environmental Chemistry (#248)
Organized by: O. Ozerov, T. Akiyama,
J. Love
Presiding: T. Akiyama
12:45 Introductory remarks
12:50 – 150. Unexpected intermediates in
C-F bond activation by Ni(0) complexes
and their influence on selectivity and catalysis. Samuel A. Johnson*,
Jillian A. Hatnean, Meghan E. Doster
13:30 – 151. Selective oxidative additions of
fluorinated aromatics with nickel(0) and a
nitrogen ancillary ligand, en route to catalysis. Meghan E. Doster,
Samuel A. Johnson*
13:50 – 152. Low-valent niobium mediated
double activation of C-F/C-H bonds.
Takahiko Akiyama*
14:30 – 153. Alkyl fluorides as promising alkylating reagents. Nobuaki Kambe*
15:10 – 154. Heterolytic splitting of E-F/E-H
bonds (E ⫽ C, Si) and E-F/E-H metathesis via silylium and carbenium cations:
Thermodynamic and kinetic considerations. Dmitry G. Gusev*, Oleg V. Ozerov
15:50 – 155. Transformation of C-F bonds
via electrophilic activation of fluoro alkenes. Junji Ichikawa*
Hilton
South Pacific I
Early Main Group Chemistry (#100)
Organized by: P. Andrews, T. Chivers,
K. Henderson
Presiding: K. Henderson
12:50 – 156. Post-Grignard reagents: Diversity of the reduction of halogenoarenes
with calcium. Matthias Westerhausen*,
Sven Krieck, Reinald Fischer,
Gritt Volland
13:20 – 157. Organocalcium chemistry: The
“sleeping beauty” in the early main group
metal block. Sjoerd Harder*
13:50 – 158. Allyl complexes of the s-block
metals: ␴⫺, ␲⫺, and cation-␲ bonding
and reactions. Timothy P. Hanusa*,
Stephen C. Chmely, Keith T. Quisenberry,
Rosemary E. White, Cameron K. Gren
14:10 – 159. Volatile perfluoro-tert-butoxide
complexes of s- and f-block elements:
Synthesis, structure, and thermal analysis. Karin Ruhlandt-Senge*,
William D. Buchanan
14:30 – 160. Samarium(II) mediated reactions and novel Sm(II)-amides.
Göran Hilmersson*
14:50 – 161. Alkaline earth metal compounds as catalysts for asymmetric reactions. Shu Kobayashi
15:20 – 162. Catalysis with Group 2 element
complexes. Michael S. Hill*
15:40 – 163. Group II centered catalysts: A
computational study. Patricia Hunt*,
Mike Hill, Andy Sykes, Florence Slater
16:00 – 164. Molecular group 2 metal(I) complexes: from chemical landmarks to versatile reagents. Cameron Jones
Hilton
Rainbow III
Metal Ion Complex Interactions with
Nucleic Acids (#30)
Organized by: J. Morrow, R. Keene,
M. Komiyama
Presiding: M. Komiyama
13:00 – 165. Programmable metal assembly
in artificial DNA and PNA.
Kentaro Tanaka*, Yasuyuki Yamada,
Marie Suzuki, Shinya Kano,
Yoshihiro Minagawa, Yasuo Azuma,
Yutaka Majima
13:35 – 166. Interactions of metallointercalators with nucleic acids.
Janice R. Aldrich-Wright*
14:10 – 167. Bifunctional recognition of DNA
or RNA structures by Zn(II) macrocycle
complexes. Janet R. Morrow*,
Matthew A. Fountain,
Imee Marie A. del Mundo
14:45 – 168. DNA-osmium complex: Pinpoint detection of methylated cytosines.
Akimitsu Okamoto*, Kazuo Tanaka,
Kazuki Tainaka, Akiko Nomura
15:20 – 169. Inert dinuclear polypyridyl ruthenium(II) complexes as cytotoxic lipophilic cations: A new paradigm for an
old molecule. Richard Keene*,
Michelle Pisani, Kirsten Heimann,
Grant Collins
Hilton
Rainbow I
Functional Molecules of the Heavier Main
Group and Transition Metal Elements (#156)
Organized by: F. Ozawa, D. Gates,
P. Power
Presiding: D. Gates, Y. Yamamoto
13:00 – 170. Synthesis, structures, and reactivities of two isomers of stable hexacoordinated dihydrophosphates.
Takayuki Kawashima, Hideaki Miyake,
Naokazu Kano
13:25 – 171. Radical functionalization of
white phosphorus. Brandi M. Cossairt,
Christopher Cummins
13:50 – 172. Synthesis and properties of intramolecular charge transfer systems
bearing crowded triarylphosphines.
Shigeru Sasaki*, Kazunobu Ogawa,
Naoto Iida, Kazuhiro Nakamura,
Masatoshi Izawa, Masaaki Yoshifuji,
Noboru Morita
14:10 – 173. Novel chiral heterocyclic and
macroheterocyclic polyphosphines.
Andrey A. Karasik*,
Svetlana N. Ignatieva, Elvira I. Musina,
Anna S. Balueva, Kirill B. Kanunnikov,
Yulia S. Spiridonova, Olga E. Naumova,
Oleg G. Sinyashin
14:30 – 174. Origin of the reactivity of organoheteroatom compounds under radical
conditions. Shigeru Yamago*
14:55 – 175. Interpnictogen compounds.
Neil Burford*, Eamonn Conrad
15:20 – 176. Synthesis and properties of
chalcogen-containing carboxylic and
phosphinic acid salts and their derivatives. Toshiaki Murai*, Kazuyasu Tani,
Tsutomu Kimura, Ken Morishita,
Masaki Monzaki
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
15:40 – 177. Facile construction of phosphorus clusters via cationic phosphorus synthons. Michael H. Holthausen,
Jan J. Weigand*
16:00 – 178. Pnictogen building blocks
based on highly-charged ligand-stabilized cations. Kai-Oliver Feldmann,
Jan J. Weigand*
Thursday Morning
Hilton
Nautilus I & II
Frontiers in Organometallic Chemistry (#68)
Organized by: G. Bertrand, M. Fryzuk,
K. Tatsumi
Presiding: M. Fryzuk
7:30 – 179. Organometallic “soft” materials:
Synthesis, mechanisms, self-assembly,
and functions. Ian Manners*
8:00 – 180. Catalysis in dendritic nanoreactors. Didier Astruc*, Abdou K. Diallo,
Catia Ornelas, Liyuan Liang,
Elodie Boisselier, Jaime Ruiz
8:30 – 181. The odd bit of carbon.
Anthony F. Hill*, Rian D. Dewhurst,
Richard L. Cordiner, Jörg Wagler,
Rong Shang, Annie L. Colebatch,
Caitlin A. McQueen, Ian A. Cade,
Rowan D. Young, Anthony C. Willis
8:55 – 182. Isolation of monomeric and
dimeric organobromocuprates and mixed
diorganocuprates based on the size-controllable “Rind” ligands and their oxidation reactions. Mikinao Ito,
Daisuke Hashizume, Tsukasa Matsuo,
Kohei Tamao
9:20 – 183. New chiral phosphonium indenylide complexes of titanium and ruthenium. Michael C. Baird*,
Kevin G. Fowler, Shalyn L. Littlefield,
Jessica F. Sonnenberg
9:45 – 184. Carbene formation at (PNP)Ir.
Nigel J. Brookes, Matthew T. Whited,
Alireza Ariafard, Robert Stranger,
Robert H. Grubbs, Brian F. Yates*
10:10 – 185. Metal alkynyl-based nonlinear
optical switches. Mark G. Humphrey*,
Katy A. Green, Marie P. Cifuentes,
Timothy C. Corkery, Marek J. Samoc
10:40 – 186. New palladium(II) and platinum(II) NHC complexes: Synthesis and catalytic activity. Thomas Strassner*
11:05 – 187. Chemistry of uranium monobis- and tris-imido complexes.
James M. Boncella*, Liam P. Spencer,
Robert E. Jilek, David S. Kuiper,
Brian L. Scott
Hilton
Kahili I/II
Discrete Coordination Systems with
Switchable Structures and Properties (#143)
Organized by: T. Konno, A. Hor, K. Lu
Presiding: A. Hor
7:30 – 188. Luminescence switchable Rebased metallacyclic supramolecules.
Kuang-Lieh Lu*
7:50 – 189. Electron injection system regulated with a rotational motion on copper
complex. Shoko Kume*,
Hiroshi Nishihara
8:10 – 190. Synthesis and electrochemical
properties of hexaazatriphenylene
bridged di- and tri-nuclear ruthenium
complexes. Tadashi Yamaguchi*,
Hiroyoshi Ohtsu, Yusuke Yagi
8:30 – 191. Recoverable catalysts with the
poly(imidazolium)skeleton.
Ling-Kang Liu
9:00 – 192. Bimetallic catalyst systems for
sequential reactions. Joanne H. Ho,
Laurent Poorters, Barbara A. Messerle*
9:30 – 193. Carbon-sulfur bond cleavage reactions of dibenzothiophene derivatives
mediated by iron and ruthenium carbonyls. Masakazu Hirotsu*, Chiaki Tsuboi,
Takanori Nishioka, Isamu Kinoshita
9:50 – 194. Nano trefoil: Reversible complexation by a silver-vorous molecule having two 4-(pyridine-4-yl)benzyl and two
3,5-difluolobenzyl groups in the sidearms. Yumiko Tsuruoka,
Shunsuke Kuwahara, Yoichi Habata*
10:10 – 195. Octanuclear copper(I) clusters
supported by dichcophosphate ligands:
anion induced modulation of the core size
and symmetry. Chen-Wei Liu*,
Ping-Kuei Liaw, Yao-Jheng Huang,
Jean-Yves Saillard, Samia Kahlal
10:30 – 196. Efficient formation of organometallic macrocycles via C-H activation
directed self-assembly. Guo-Xin Jin*
11:00 – 197. Regulating the primary and secondary coordination spheres within transition metal complexes through modular
ligand design. A. S. Borovik*
Hilton
Rainbow II
Redox Redux: The Renaissance of NonInnocent Ligand Complexes (#217)
Organized by: J. Soper, S. Colbran,
R. Hicks
Presiding: J. Soper
7:30 Introductory remarks
7:35 – 198. Saddled with noninnocence: The
most strongly nonplanar metallocorrole.
Abhik Ghosh*, Abraham Alemayehu,
Kolle Thomas
7:55 – 199. Guilty as charged: The case for
ligand noninnocence in “mixed valence”
chemistry. Paul J. Low*
8:15 – 200. Characterizations and electronic
structures of oxidized metal(II)-salen-tyoe
complexes. Yuichi Shimazaki*
8:35 – 201. Two- and three-center electron
transfer arrangements in redox-active coordination compounds. Wolfgang Kaim*
9:05 – 202. 2,2’-Bipyridine, the archetypal
noninnocent ligand: The [Cr(bpy)3]z (z ⫽
3⫹, 2⫹, 1⫹, 0, 1-, 2-, 3-) electron transfer
series. Karl Wieghardt*,
Chris Scarborough, Stephen Sproules,
Serena DeBeer George
9:35 – 203. Photoinduced multi-electron reduction of mononuclear Ru complexes.
Koji Tanaka*, Takashi Fukushima,
Tohru Wada
10:05 – 204. Investigation of the locus of oxidation and spectroscopic features of oxidized copper and nickel bis-phenoxide
complexes. Daniel Stack*, Tim Storr,
Pratik Verma, Erik Wasinger,
Yuichi Shimazaki
10:35 – 205. Noninnocent behavior in ruthenium complexes of verdazyl radicals.
Robin G. Hicks*, Steve D. McKinnon
Hilton
Sea Pearl III/IV
Actinides and the Environment: A
Multidisciplinary Look at What We Know
and What We Need to Know (#38)
Organized by: H. Nitsche, D. Kaplan,
C. Liu, Z. Yoshida
Presiding: C. Liu, A. Kersting
7:45 – 206. Actinide mineralization related to
radionuclide mobility in nuclear waste repository performance and environmental
transport. Peter C. Burns*
8:15 – 207. Periodicity in actinide inorganic
chemistry. Richard Wilson*,
L. Soderholm
8:45 – 208. Encapsulation of the uranyl dication. Orion B. Berryman, Stephan Beer,
Dariush Ajami, Julius Rebek
9:05 – 209. Enhanced Pu transport in a vadose zone: Identifying coupled biogeochemical processes from an 11-year field
study. Daniel Kaplan*,
Christopher Bagwell, Amy Hixon,
Yung-Jin Hu, Ravi Kukkadapu,
Fred Molz, Heino Nitsche, Brian Powell,
Kimberly Roberts, Luna K. Schwaiger
9:35 – 210. Reduction of uranyl in gamma irradiated condition. Chunli Liu*,
Tao Chen, Zhong Zheng
9:55 – 211. Co-precipitation of Np^5⫹ into
rock forming minerals.
Jessica Morrison*, Andrew Quicksall,
Peter C. Burns
10:15 – 212. Spectral studies of actinides
speciation in the environment.
Punam Thakur, James L. Conca,
Gregory R. Choppin
10:35 – 213. Interaction of Eu(III) with oxides
and minerals studied by batch, XPS and
EXAFS techniques. Xiangke Wang*
10:55 – 214. Form of actinides and radionuclides in the environments revealed by
scanning transmission electron microscopy (STEM). Satoshi Utsunomiya*
Hilton
Coral I
Carbon-fluorine Bond Activation: a
Crossroads for Inorganic, Organic, and
Environmental Chemistry (#248)
Organized by: O. Ozerov, T. Akiyama,
J. Love
Presiding: O. Ozerov
7:45 Introductory remarks
7:50 – 215. Environmental fate, disposition,
and persistence of polyfluoriated chemicals in the environment.
Scott A. Mabury*
8:30 – 216. Recent progress in activating unreactive bonds of organofluorine compounds. Hideki Amii*
8:50 – 217. Oxidative addition of sp3-C-F
and C-O bonds by pincer-ligated iridium
complexes. Jongwook Choi,
Thomas J. Emge,
Karsten Krogh-Jespersen,
Alan Goldman*
9:30 – 218. Modeling the fate and exposure
of perfluorinated alkyl acids.
Ian T. Cousins*
10:10 – 219. C-F bond activation by electrophilic main group catalysts.
Oleg Ozerov*, Weixing Gu,
Christos Douvris, Dmitry G. Gusev,
Billy J. McCulloch, Bruce M. Foxman,
Chun-Hsing Chen,
Joseph H. Reibenspies
10:50 – 220. C-F bond activation using lowvalent cobalt, iron and nickel complexes.
Xiaoyan Li, Hongjian Sun
Hilton
Hibiscus I/II
10:00 – 226. Self-assembled metal coordination polymers and nanostructures by
metal-metal and metal-ligand interactions: Functions and structures.
Chi-Ming Che*
10:30 – 227. Aggregation effects on conjugated polymer photophysics.
Lewis Rothberg*, Steven Paquette,
David McCamant, Justin Rhinehart,
Onur Kas, Manoj Charati, Mary Galvin,
Kristi Kiick
11:00 – 228. Developing metal-polycyclic-aromatics as a new class of organometallic
emitters. John H. Yip*
Hilton
Rainbow III
Metal Ion Complex Interactions with
Nucleic Acids (#30)
Organized by: J. Morrow, R. Keene,
M. Komiyama
Presiding: R. Keene
8:00 – 229. DNA hydrolysis by Ce(IV) complex prepared from Ce(III) precursor.
Tuomas Lönnberg, Yuichiro Aiba,
Yuya Hamano, Jun Sumaoka,
Makoto Komiyama
8:35 – 230. Tuning the excited state reactivity of transition metal complexes for enhanced reactivity with biomolecules.
Claudia Turro*, Randy P. Thummel,
Kim R. Dunbar, Robert M. Snapka
9:10 – 231. Heterodinuclear ligand-bridged
coordination compounds and their interaction with DNA. Jan Reedijk
9:45 – 232. Simultaneous imaging of cell
hypoxia and cobalt prodrug activation in
spheroids constructed from transfected
cells. Trevor W. Hambley*,
Nicole S. Bryce, Kim J. Byung
10:20 – 233. Characterization of lanthanide
ion binding sites in nucleic acids by direct
excitation luminescence and NMR spectroscopy. Matthew Fountain*,
Christopher M. Andolina, Janet Morrow*
10:55 – 234. DNA interactions of anticancer
polynuclear Pt(II) complexes.
Seiji Komeda*, Masahiko Chikuma,
Loren D. Williams, Nicholas P. Farrell
Hilton
Coral II
Syntheses and Applications of MetalOrganic Frameworks (#97)
Molecular Photonics (#9)
Organized by: F. Castellano, T. Majima,
V. Yam
Presiding: G. Meyer
8:00 – 221. Photophysics and broadband
nonlinear absorption of platinum terdentate or diimine complexes.
Wenfang Sun*, Bingguang Zhang,
Yunjing Li, Timothy M. Pritchett
8:20 – 222. Highly phosphorescent homoleptic and heteroleptic iridium complexes
based on aryltriazole cyclometallating ligands. Eli Zysman-Colman*,
Sébastien Ladouceur, François Mathieu,
Daniel Fortin
8:40 – 223. Engineering of cyclometallated
platinum(II) complexes incorporating
acetylide ligands for chemosensing.
Jean-Luc Fillaut*, Pierre-Henri Lanoë,
Hubert Le Bozec, Véronique Guerchais*,
J. A. Gareth Williams
9:00 – 224. Coupled-oscillator photophysics
and the elaboration of chromophores
having exceptional low energy triplet
states. Timothy Duncan, Animesh Nayak,
Paul Frail, Tomoya Ishizuka,
Louise Sinks, Kai Song, Shen Hung,
Inge Asselberghs, Koen Clays,
Michael J. Therien*
9:30 – 225. Photoswitching and electronic
communication in linked platinum dithienylethene acetylides.
Matthew N. Roberts, Carl-Johan Carling,
Jeffrey K. Nagle, Neil R. Branda,
Michael Wolf*
Organized by: M.P. Suh, C. Kepert,
S. Kitagawa, J. Long, G. Shimizu
Presiding: J. Long
8:00 – 235. Molecular modeling of metal-organic frameworks for separations applications. Randall Q. Snurr*
8:30 – 236. Theoretical modeling of gas
sorption in MOF’s: The effects of topology and polarization. Brian Space,
Jonathan Belof, Abraham Stern,
Katherine Forrest
9:00 – 237. Identification of coexisting strong
and weak H2 binding sites in transitionmetal-containing MOFs. Jisoon Ihm*,
Moon-Hyun Cha, Jaehyun Bae
9:30 – 238. Nanoprotonics in coordination
polymers. Hiroshi Kitagawa*
10:00 – 239. Combining multiple functions
within framework materials.
Cameron J. Kepert*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–71
02-INOR
10:30 – 240. Adsorption-induced lattice transition of MOFs with flexible structures:
Free-energy analysis based on molecular
simulation. Minoru Miyahara*,
Hayato Sugiyama, Yasushi Mino,
Ryohei Numaguchi, Satoshi Watanabe,
Hideki Tanaka
10:50 – 241. Porous metal-organic frameworks exhibiting reversible magnetic responses. Chang Seop Hong*,
Dae Won Ryu, Jin Wuk Lee
11:10 – 242. Metal-organic frameworks with
unusual optical and biological properties.
Katharina M. Fromm*, Jing Chen
Hilton
South Pacific I
Early Main Group Chemistry (#100)
Organized by: P. Andrews, T. Chivers,
K. Henderson
Presiding: P. Andrews
8:00 – 243. Metal complex-catalyzed dehydrogenation of early main group BN compounds. R. Tom Baker*
8:30 – 244. Bidentate Lewis acidic borane
with a telluronium ion as an anion-binding
site. Haiyan Zhao, Francois P. Gabbai*
9:00 – 245. Chemistry of halogenated closododecaborates [B12X12]2- (X ⫽ F, Cl, Br,
I). Carsten Knapp*
9:20 – 246. Synthesis and reactivity studies
of low-valent group 13 metal amido complexes. Zachary D. Brown,
James C. Fettinger, Philip P. Power*
9:40 – 247. Molecular precursors for the
chemical vapour deposition (CVD) of gallium and indium oxide thin films.
Leanne G. Bloor*, Claire J. Carmalt,
Ivan P. Parkin, David Pugh
10:00 – 248. Sequestration of the destructive
greenhouse gases, nitrous oxide and carbon dioxide, by main group- and transition metal-based frustrated Lewis pairs.
Rebecca Neu, Edwin Otten,
Douglas W. Stephan*
10:20 – 249. Ring-opening polymerization of
strained sandwich compounds with aluminum or gallium in bridging positions.
Bidraha Bagh, Joe B. Gilroy,
Anne Staubitz, Jens Müller*
10:40 – 250. Ga-Ga bonds as effective templates for the generation of large macrocycles and cages. Werner Uhl*,
Henrik R. Bock, Hauke Westenberg
11:00 – 251. Highly stable functionalizable
platform chelate for Ga isotopes.
Chris Orvig*, Eszter Boros,
Cara L. Ferreira, Jacqueline F. Cawthray,
Eric W. Price, Dennis W. Wester,
Michael J. Adam*
TECHNICAL PROGRAM
10:30 – 257. Five-membered metallacycloalkynes and metallacycloallenes.
Noriyuki Suzuki*
11:00 – 258. Vanadium-catalyzed oxidative
bromination with molecular oxygen.
Toshikazu Hirao*, Kotaro Kikushima,
Toshiyuki Moriuchi*
Hilton
Rainbow I
Functional Molecules of the Heavier Main
Group and Transition Metal Elements (#156)
Organized by: F. Ozawa, D. Gates,
P. Power
Presiding: N. Burford, P. Power
8:00 – 259. Groups 2 and 13 metal(I) heterocycles: Fundamentally appealing yet
functional compounds. Cameron Jones
8:25 – 260. Synthesis and electronic properties of 16 ␲-electron porphyrins.
Yohsuke Yamamoto*
8:50 – 261. Synthesis and reactivity of group
14 alkoxides: Understanding periodic
trends. Jennifer Robin Fulton*,
Lorenzo Ferro, Eric C. Tam,
Nick C. Johnstone, Hazel Cox,
Martyn P. Coles, Peter B. Hitchcock
9:10 – 262. Preparation and FET activity of
star-shaped oligothiophenes with an organosilicon core. Joji Ohshita*,
Yosuke Hatanaka, Shigenori Matsui,
Tomonobu Mizumo, Yoshihito Kunugi,
Yoshihito Honsho, Akinori Saeki,
Shu Seki, Julius Tibbelin,
Henrik Ottosson
9:30 – 263. Complexes of low valent main
group species with crown-ethers and related ligands. Charles L. Macdonald*,
Rajoshree Bandyopadhyay,
Benjamin F. Cooper, Warren W. Friedl,
Christopher J. Allan, Paul A. Rupar,
Paul J. Ragogna, Kim M. Baines
9:55 – 264. Addition polymerization of
silenes and germenes. Kim M. Baines*
10:20 – 265. Synthesis and properties of stable 1,2-bis(metallocenyl)dimetallenes as
novel d-␲ electron systems.
Takahiro Sasamori*, Akihiro Yuasa,
Hisashi Miyamoto, Norihiro Tokitoh*
10:40 – 266. Reactions of long bond isomers
of 1,3-dimetallabicyclo[1.1.0]butanes.
Takeaki Iwamoto*, Dongzhu Yin,
Koya Inomata, Shintaro Ishida,
Mitsuo Kira
11:00 – 267. New ␲-bonded molecules: Disilynes RSi⬅SiR with silicon-silicon triple
bonds and their unusual reactivity.
Akira Sekiguchi
11:25 Closing remarks
Thursday Afternoon
Hilton
Lehua Suite
Preparation and Reactions of Early
Transition Metal and Lathanide
Compounds (#150)
Organized by: T. Takahashi, G. Deacon,
R. Jordan, Z. Xi
Presiding: T. Takahashi
8:00 – 252. Coupling of Cp ligand with diene
moiety of titanacyclopentadienes and unusual C-C cleavage. Zhiyi Song,
Ken-ichiro Kanno, Kiyohiko Nakajima,
Tamotsu Takahashi*
8:30 – 253. Reactivity of alkynylzirconates.
Xiaoyu Yan, Chanjuan Xi*
9:00 – 254. Highly efficient and selective
synthesis of multisubstituted olefins from
alkynylboronates mediated by a zirconocene complex. Yasushi Nishihara*
9:30 – 255. Exploring the fundamental coordination chemistry of a family of sterically
demanding indenyl ligands.
Gregory P. McGovern,
Fernando Hung-Low, Chris A. Bradley
10:00 – 256. Employment of an anionic-nitrogen heterocyclic carbene in main and
early transition metals for unusual reactivities and possible catalysis application.
Tiow-Gan Ong*, Wei-Chih Shih,
Chung-Chih Tsai, Cheng-Feng Liang,
Yu-Chen Hu
72–TECH
Hilton
Hibiscus I/II
Molecular Photonics (#9)
Organized by: F. Castellano, T. Majima,
V. Yam
Presiding: M. Thompson
12:30 – 268. Spectroscopic insights into the
function of a supramolecular hydrogenevolving photocatalyst.
Benjamin Dietzek*, Michael Schmitt,
Sven Rau, Juergen Popp
12:50 – 269. Tris-heteroleptic cyclometalated ruthenium sensitizers for dye-sensitized solar cells. Paolo G. Bomben,
Bryan D. Koivisto, Curtis P. Berlinguette*
13:10 – 270. Stark effects at sensitized titanium dioxide molecular photonic materials. Gerald Meyer, Shane Ardo
13:40 – 271. Dye sensitized solar cells based
organic chromophores and nanostructured TiO2 for n-type and NiO for p-type.
Licheng Sun, Xichuan Yang,
Anders Hagfeldt
14:10 – 272. Designing polymers for light
harvesting and solar cells. Zhenan Bao*
14:40 – 273. Electron transfer from the porphyrin S2 state in a zinc porphyrin-rhenium bipyridyl dyad having carbon dioxide reduction activity. Haruo Inoue*
15:10 – 274. Platinum(II) complexes for the
light driven generation of hydrogen from
water: New developments and results including energy upconversion.
Rich Eisenberg, Pingwu Du,
Theresa McCormick,
Theodore Lazarides, Jacob Schneider,
Paul Jarosz, David McCamant
15:40 – 275. Efficient photo-electronic devices by supramolecular chemistry.
Mamoru Fujitsuka, Tetsuro Majima*
Hilton
Nautilus I & II
Frontiers in Organometallic Chemistry (#68)
Organized by: G. Bertrand, M. Fryzuk,
K. Tatsumi
Presiding: I. Manners
12:30 – 276. Triphosphorus-containing molecules and materials. Brandi M. Cossairt,
Alexandra Velian, Daniel Tofan,
Christopher Cummins
13:00 – 277. Novel concepts in organometallic polyphosphorus chemistry.
Manfred Scheer*, Fabian Dielmann,
Andrea Schindler, Stefan Welsch
13:25 – 278. Unusual boron centered ligands
in the coordination sphere of platinum.
Holger Braunschweig
13:50 – 279. Synthesis and reactions of
NHC-stabilized (L) Pn(III) Cations
[LPnCl2]⫹ and [L2PnCl]2⫹ (Pn ⫽ P, As,
Sb). Jan J. Weigand*, Florian D. Henne,
Kai-Oliver Feldmann
14:15 – 280. Challenging the norm: Impact
of abnormal carbene ligands in transition
metal chemistry and catalysis.
Martin Albrecht, Anneke Krüger,
Manuel Iglesias, Ralte Lalrempuia
14:40 – 281. Bonding model for bent heavy
allenes. Mitsuo Kira*, Takeaki Iwamoto,
Shintaro Ishida
15:05 – 282. Applications of frustrated Lewis
pairs in organometallic chemistry.
Doug Stephan*
15:35 – 283. 3-Iminophosphine palladium
catalysts for C-N bond-forming reactions.
Andrew R. Shaffer, Glenn Kuchenbeiser,
Joseph Schmidt*
16:00 – 284. Novel families of carbon ligands, novel catalytic reactions.
Guy Bertrand*
Hilton
South Pacific I
Chemistry of Sulfur-Bridged Multimetallic
Complexes (#96)
Organized by: T. Rauchfuss, G. Jin,
T. Matsumoto, Y. Mizobe
Presiding: T. Rauchfuss
12:30 – 285. Transition metal dithiolene
complexes: Sulfur-bridged dimetallic and
multimetallic structures in electron transfer and for organic transformations.
Ulrich Fekl*, Daniel J. Harrison,
Neilson Nguyen
13:05 – 286. New nanosized copper and silver clusters with sulfur and selenium ligands: Synthesis, structures, and properties. Dieter Fenske*
13:40 – 287. Untamed thiolates: Bridging
roles for poly(methimazolyl)borates.
Anthony F. Hill*, Mark R. Foreman,
Ian A. Cade, Matthew K. Smith,
Never Tshabang, Rowan D. Young,
David Koedyk, Anthony C. Willis,
Ian R. Crossley
14:15 – 288. Heterometallic sulfide complexes from sulfur-rich [MS4]rings.
Andy T. Hor*, Jingqiu Li, Sheau W. Chien
14:50 – 289. Design and assembly of Mo(W)/
Cu/S cluster-based coordination compounds. Jian-Ping Lang*
15:25 – 290. Ligand-to-metal ratio controlled
assembly of cobalt complexes containing
ortho-carborane-thiolato and butyl-thiolato ligands. Yuguang Li*, Qibai Jiang,
Hong Yan
16:00 – 291. Organometallic chemistry of
1,2-dichalcogenolato carboranes.
Guo-Xin Jin*
Hilton
Coral II
Syntheses and Applications of MetalOrganic Frameworks (#97)
Organized by: M.P. Suh, C. Kepert,
S. Kitagawa, J. Long, G. Shimizu
Presiding: G. Shimizu
12:30 – 292. Reactivity and flexibility in metal-organic frameworks.
Matthew J. Rosseinsky*
13:00 – 293. Chiral metal-organic frameworks as a tunable platform for asymmetric catalysis. Wenbin Lin*
13:30 – 294. Microporous metal organic
framework materials: Porosity, functionality and applications. Jing Li*
14:00 – 295. Engineering of metal-organic
framework catalysts. Seth Cohen*
14:30 – 296. Synthetic pores for storage, catalysis, and transport. Kimoon Kim*
15:00 – 297. Catalytic metal-organic framework materials. Joseph Hupp*,
SonBinh T. Nguyen, Abraham Shultz,
Omar K. Farha
15:30 – 298. Switching redox-active site by
valence-tautomerism in Prussian blue analogs: Robust frameworks for reversible
Li storage. Masashi Okubo*,
Tetsuichi Kudo, Itaru Honma
15:50 – 299. Design and fabrication of metaladeninate MOFs for environmental applications. Nathaniel L. Rosi*, Jihyun An
16:10 – 300. Networked cages and capsules: Rich host-guest chemistry in a
crystal. Yasuhide Inokuma,
Makoto Fujita*
Hilton
Kahili I/II
Discrete Coordination Systems with
Switchable Structures and Properties (#143)
Organized by: T. Konno, A. Hor, K. Lu
Presiding: K. Lu
12:30 – 301. Redox non-innocent tripodal
carbanion of tris(2-pyridylthio)methyl
compleses mimics the photosynthetic
behavior. Isamu Kinoshita*,
Riichi Miyamoto, Yuko Masuda,
Masakazu Hirotsu, Takanori Nishioka,
Hideki Hashimoto
12:50 – 302. d8/d10 Metal and lanthanide(III)
heteropolynuclear arrays and sensitized
lanthanide(III) luminescence by energy
transfer from organometallic chromophores. Zhong-Ning Chen*,
Hai-Bing Xu
13:10 – 303. Dynamic polymorph transfer
and solvation effects of a spin-crossover
complex. Jun Tao*
13:30 – 304. Opto-magnetic switchable
properties of Fe(II) spin crossover complexes. Yu Wang*, Chou-Fu Sheu,
Che-Hsiu Shih, Masaki Takata
14:00 – 305. Multifunctional materials from
iron/dipyrazolylpyridine spin-crossover
switches. Malcolm A. Halcrow
14:30 – 306. Reversible sulfurization-desulfurization of bis(dithiolene)W complexes.
Hideki Sugimoto*, Shinobu Itoh
14:50 – 307. Macrocyclic and axial ligand effects in ruthenium porphycene compounds. Masaaki Abe*, Toru Okawara,
Shiho Ashigara, Hisashi Shimakoshi,
Yoshio Hisaeda*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
15:10 – 308. Extending cyanide ligand
chemistry: The coordination complexes
of cyanoacetylides. Paul J. Low*
15:40 – 309. Proton-coupled electron transfers with separated redox and acid sites.
Jim Mayer, Jeffrey J. Warren,
Virginia W. Manner, Jessica M. Wittman,
Todd F. Markle, Tristan A. Tronic,
Adam L. Tenderholt
16:10 Closing remarks
Hilton
Rainbow III
Advances in Metal-Mediated Bond
Activation: From Unusual Bonding Motifs to
Applications in Catalysis (#146)
Organized by: K. Caulton, S. Komiya,
M. Stradiotto
Presiding: S. Komiya
12:30 – 310. First synthesis and structural
authentication of remarkably stable “exoallylic” ␩3-furyl complexes: Heterocyclic
analogs of ␩3-benzyls.
Rian D. Dewhurst*, Peter Brenner,
Krzysztof Radacki
12:50 – 311. New pincer complexes and catalysts. Dmitry G. Gusev
13:10 – 312. Visible light-assisted reductive
elimination of triorganoplatinum-manganese heterodinucler complex.
Sanshiro Komiya*
13:30 – 313. Photochemical E-H bond activation by chiral rhodium and ruthenium
complexes. Robin Perutz*,
Marius V. Câmpian, Barbara Procacci,
Odile Eisenstein, Ulrike Helmstedt
13:50 – 314. Unique primary carbon-nitrogen bond scission across a W-W multiple
bond and methyl dehydrogenation.
Adam S. Veige*, Soumya Sarkar,
Andrew J. Peloquin, Jeffrey A. Culver,
Ion Ghiviriga, Khalil A. Abboud
14:10 – 315. Template synthesis of tethered
carbenes via phosphinimine-donor ligand
precursors. Parisa Mehrkhodavandi*,
Insun Yu
14:30 – 316. Late transition metal complexes
featuring silyl pincer ligation: Applications
in challenging bond cleavage reactions.
Laura Turculet*
14:50 – 317. Stoichiometric and catalytic homo/hetero coupling reactions of conjugated dienes and acrylates by ruthenium(0) complex. Masafumi Hirano*,
Yumiko Sakate, Yasutomo Arai,
Nobuyuki Komine, Sanshiro Komiya*,
Martin A. Bennett*
15:10 – 318. Heterometallic trinuclear polyhydrido complexes containing ruthenium
and osmium: Remarkable heterometallic
effect in cleavage of nitrogen-hydrogen
bonds of ammonia. Hiroharu Suzuki*
15:30 – 319. Reactions of late transition
metal complexes relevant to C-H bond
activation and functionalization.
Karen Goldberg
15:50 – 320. Synthesis and reactivity of a
Rh(III) half-sandwich complex featuring
the ambiphilic bifunctional ligand
PMe2CH2AlMe2.
Frédéric-Georges Fontaine,
Josée Boudreau
16:10 – 321. Unprecedented N-N coupling
of NO ligands on dinuclear ruthenium
complexes and their application to NO reduction cycle. Yasuhiro Arikawa*,
Taiki Asayama, Naoki Matsumoto,
Keisuke Umakoshi, Masayoshi Onishi
Hilton
Rainbow II
Redox Redux: The Renaissance of NonInnocent Ligand Complexes (#217)
Organized by: J. Soper, S. Colbran,
R. Hicks
Presiding: S. Colbran
12:30 – 322. Paramagnetic heteroleptic dithiolene complexes. Marc Fourmigue,
Mitsushiro Nomura, Thomas Cauchy
12:50 – 323. Coordination rods and squares
with redox-active heterocyclic bridging ligands. Rene T. Boere*,
Mohammed R. Hassan
13:10 – 324. Photoinduced valence tautomerism in Co complexes. Osamu Sato*
13:40 – 325. Polynuclear metal complexes
with redox-active polynucleating ligands.
Colette Boskovic*, Kerwyn Alley,
Yanyan Mulyana, Brendan Abrahams,
Ayman Nafady, Alan Bond, Keith Murray
14:10 – 326. Reversible oxidative O2 binding
in metal-organic host materials.
Cameron J. Kepert*, Peter D. Southon,
David J. Price, Pia K. Nielsen,
Christine H. McKenzie
14:40 – 327. Light induced redox isomeric
interconversion of cobalt-dioxolene complexes. Andrea Dei*
15:10 – 328. Analysis of the electronic and
amphiphilic behavior in five-coordinate
iron(III) complexes with electroactive
[N2O2] donor type ligands.
Claudio N. Verani*
Hilton
Rainbow I
Fundamental and Applied Inorganic
Fluorine Chemistry and Their Impacts on
Energy Conservation and the Environment
(#249)
Organized by: R. Hagiwara,
K. Matsumoto, H. Mercier,
G. Schrobilgen, R. Syvret
Presiding: R. Hagiwara, G. Schrobilgen
12:45 Introductory remarks
12:50 – 329. Dinitrogen difluoride chemistry:
Improved syntheses of cis-and transN2F2, synthesis, and characterization of
N2F⫹Sn2F9-, ordered crystal structure of
N2F⫹Sb2F11-, high-level electronic
structure calculations of cis-N2F2, transN2F2, F2N⫽N, and N2F⫹, and mechanism of the trans-cis isomerization of
N2F2. Karl O. Christe*, David A. Dixon,
Daniel J. Grant, Ralf Haiges,
Fook S. Tham, Ashwani Vij, Vandana Vij,
Tsang-Hsiu Wang, William W. Wilson
13:20 – 330. Uses of weakly interacting anions. Josef Michl*
13:50 – 331. Combining nitrogen, sulfur, and
fluorine: A rather unique and diverse
chemistry. Ruediger J. Mews*
14:10 – 332. Preparation and protonation of
the thiosulfuric acids in superacids.
Andreas J. Kornath, Mathias Hopfinger,
Martina Wild
14:30 – 333. Ag(I)OTf as a valuable precursor
towards novel inorganic derivatives of
carbon aka dream of “expanded diamonds”. Wojciech Grochala*
14:50 – 334. Safety improvement of lithium
ion battery by fluorination and fluorine
compounds. Tsuyoshi Nakajima*,
Takashi Achiha, Xiaohong Kang,
Hidetoshi Utsunomiya, Yoshimi Ohzawa,
Zoran Mazej, Boris Zemva
15:20 – 335. Influence of the surface properties of carbon anode on the kinetics of
the fluorine evolution reaction.
Henri Groult*, Alain Tressaud,
Christine Labrugère, Isabelle Crassous,
Wikenson Simond, Cléine Belhomme,
Alain Colisson, Bertrand Morel,
Marc Dubois
15:50 – 336. Preparation of highly pure LiPF6
by using fluorine gas.
Susumu Yonezawa, Hayato Umeda,
Meguru Oe, Jae-ho Kim,
Masayuki Takashima
16:10 – 337. New Ce1-xZrxF4 solid solution.
Romain Clarenc, Etienne Durand,
Alain Tressaud, Christophe Legein,
Alain Demourgues
Hilton
Sea Pearl III/IV
Schiff Base Macrocycles and Materials
(#60)
Organized by: M. MacLachlan,
S. Brooker, C. Lee
Presiding: M. MacLachlan
12:50 Introductory remarks
12:55 – 338. Construction of homo- and hetero- oligometallic systems with fused salphen ligands. Hirohiko Houjou*
13:25 – 339. Magnetically and electrochemically interesting di- and poly-metallic
complexes of new generation Schiff-base
macrocycles. Sally Brooker*,
Humphrey L. Feltham, Scott A. Cameron,
Sanyal Rajni, Jonathan A. Kitchen,
Victoria A. Milway, David S. Larsen,
Frederik Kloewer, Yanhua Lan,
Annie K. Powell, Jeffery L. Tallon,
Rodolphe Clerac
13:55 – 340. Supramolecular assembly behavior and catalytic features of macrocyclic metallosalen structures.
Arjan W. Kleij*, Robert M. Haak,
Eduardo C. Escudero-Adán,
Jordi Benet-Buchholz, Giovanni Salassa,
Ana M. Castilla
14:25 – 341. Microwave synthesis of substituted diformyl phenols for use in Schiff
base macrocycles. Vanessa McCaffrey*,
Chris Omerza, Luke Holly,
Waqas Qureshi
14:55 – 342. Synthesis and chemical properties of pi-extended, meso-alkylidenyl porphyrinoids. Chang-Hee Lee*,
Seung-Doo Jeong
15:25 – 343. Structural and reactivity studies
of bimetallic Schiff-base systems.
Tim Storr*, Tim Dunn, Khatera Hazin,
Caterina Ramogida
15:55 – 344. New metallo-supramolecular
assemblies derived from Schiff base ligands and Zn(II), Cd(II), Ag(I) or Fe(II).
Qi-Long Zhang, Bi-Xue Zhu,
Yun-Qian Zhang, Zhu Tao, Jack K. Clegg,
Leonard F. Lindoy*,
Christopher R. Glasson,
George V. Meehan, Gang Wei
13:05 – 352. C-F activation and derivatization of perfluoropropene in the coordination sphere of rhodium. Thomas Braun*,
Anna Lena Raza, Michael Teltewskoi,
Falk Wehmeier
13:45 – 353. C-F activation via a boryl-assisted pathway. Michael Teltewskoi,
Julien A. Panetier, Stuart A. Macgregor,
Thomas Braun
14:05 – 354. C-F-activation using NHC stabilized nickel complexes. Udo Radius*
14:45 – 355. Catalytic transformations of
polyfluoroarenes. Jennifer Love*
15:25 – 356. Carbon-fluorine bond activation
and functionalization of fluoroolefins promoted by adjacent metals.
Martin Cowie, Michael Slaney,
Jason Anderson, Robert McDonald,
Michael Ferguson
16:05 Concluding remarks
Thursday Evening
Hilton
Coral II
Controlling the Structure and Properties of
Solids (#20)
Organized by: B. Kennedy,
Y. Shimakawa, P. Woodward
Presiding: B. Kennedy
19:00 – 357. Studies of the double perovskites, A2FeMoO6 and A(2-x)A’(x)MnRuO6, a closer look at the contrasting
role of chemical order.
Patrick M. Woodward,
Rebecca Ricciardo, Tricia Meyer,
Jennifer Soliz
19:40 – 358. High-quality ilmenite-hematite
solid solution thin films grown on A-plane
sapphire substrates.
Tomohiko Matoba*, Koji Fujita,
Shunsuke Murai, Katsuhisa Tanaka
20:00 – 359. Withdrawn
20:20 – 360. Reduction pathway to SrFeO2
and Sr3Fe2O5 with iron in a square planar
coordination. Cedric Tassel*,
Yoshihiro Tsujimoto, Yuichi Shimakawa,
Kazuyoshi Yoshimura, Hiroshi Kageyama
20:40 – 361. Withdrawn
Hilton
Lehua Suite
Convention Center
Kamehameha Halls II and III
Preparation and Reactions of Early
Transition Metal and Lathanide
Compounds (#150)
Metal Ion Complex Interactions with
Nucleic Acids (#30)
Organized by: T. Takahashi, G. Deacon,
R. Jordan, Z. Xi
Presiding: T. Takahashi
13:00 – 345. Predictable stereocontrolled
synthesis of chiral group 4 metallocenes.
Richard Jordan*
13:30 – 346. Withdrawn
14:00 – 347. Unique chemical properties of
non-traditional zirconium-carbon bonds.
Zuowei Xie*
14:30 – 348. Molybdenum-catalyzed asymmetric ring-closing metathesis of 1,1’-diallylmetallocenes: catalytic asymmetric
synthesis of planar-chiral metallocenes.
Masamichi Ogasawara*,
Susumu Watanabe, Kiyohiko Nakajima,
Tamotsu Takahashi*
15:00 – 349. Withdrawn
15:30 – 350. Zirconocene-mediated reactions in syntheses of compounds with the
isoprenoid framework. Martin Kotora*
16:00 – 351. Carbon-carbon bond cleavage
reaction on titanium.
Tamotsu Takahashi*
Hilton
Coral I
Carbon-fluorine Bond Activation: a
Crossroads for Inorganic, Organic, and
Environmental Chemistry (#248)
Organized by: O. Ozerov, T. Akiyama,
J. Love
Presiding: J. Love
13:00 Introductory remarks
Organized by: J. Morrow, R. Keene,
M. Komiyama
Presiding: J. Morrow
Poster Session
19:00 – 21:00
362. Chiral bisterpyridine coordination polymer: effect of substituent on DNA binding
and nuclease activity. Jinghua Li,
Masayoshi Higuchi, Zdenek Futera
363. Developing novel nanoparticulated live
cell imaging system using luminescence
enhancement of Eu(III) and Tb(III) encapsulation. Diana L. Harms,
David A. Corcoran, Patty K. Fu*
364. Selective aggregation of a Pt-Gd complex within a tumor cell nucleus.
Ellen Crossley, Jade Aitken, Stefan Vogt,
Hugh Harris*, Louis Rendina*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–73
02-INOR
365. Site-selective scission of doublestranded DNA by Ce(IV)/EDTA and only
one mixed-base PNA. Yuichiro Aiba,
Yuya Hamano, Alessandro Accetta,
Stefano Sforza, Rosangela Marchelli,
Roberto Corradini, Makoto Komiyama*
366. Synthesis, characterization and biological activity of copper(II) and zinc(II) complexes with 2,4-dihydroxybenzaldehyde
N(4)-alkyl thiosemicarbazone and 1,10phenanthroline. Kong W. Tan*,
Hoi L. Seng, Chew H. Ng, Seik W. Ng,
Mohd. J. Maah
367. Palladium and copper analogs of cytotoxic platinum intercalators.
Anwen M. Krause-Heuer,
Peter Leverett, Albert Bolhuis,
Sharon M. Kelly,
Janice R. Aldrich-Wright*
368. Seeking selective DNA binding through
synergistic design.
Janice Aldrich-Wright*, Nikita Orkey,
Maxine Grant
369. Photoregulation of oxidative DNA cleavage activity of a novel binuclear copper
complex. Takeo Ito*, Kouhei Takeuchi,
Kanako Akamatsu, Sei-ichi Nishimoto*
370. Synthesis, X-ray crystal structures and
DNA cleavage properties of copper(II)
complexes of 1,4,7-triazacyclononane ligands featuring guanidinium pendants.
Linda Tjioe*, Tanmaya Joshi,
Bim Graham, Leone Spiccia
371. Synthesis, characterisation and evaluation of PNA-ruthenium complex hybrids
for Targeted Corrective Gene Conversion
(TCGC). Tanmaya Joshi*, Gilles Gasser,
Robert Kapsa, Leone Spiccia
372. Investigation of novel platinum(II) anticancer compounds and their biological
significance.
Kieran Garbutcheon-Singh*,
Janice R. Aldrich-Wright, Simon Myers
373. DNA binding structure of ternary Pt(II)
and Zn(II) complexes of phenanthroline
and edda. Yusuke Nakamura*,
Yusuke Kitamura, Hoi-Ling Seng,
Chew Hee Ng, Makoto Chikira
374. Synthesis and biological activity of
platinum(II) metallointercalators.
Madhura Manohar*,
Janice R. Aldrich-Wright,
Minoo Moghaddam
375. Synthesis, characterisation, and biological activity of novel platinum(II) intercalators as potential anticancer compounds.
Benjamin Harper*,
Janice R. Aldrich-Wright
376. Assay of DNA mismatches and potassium ions using an aptamer probe and
light switch complex. Jinheung Kim*,
Misun Cha, Byul N. Oh, Yingji Sun
377. Comparative study of the DNA interaction of ternary amino acid Schiff base
chromium(III) and copper(II) complexes
having planar heterocyclic ligands.
Shota Kitajijma, Masato Kimura,
Yusuke Kitamura, Makoto Chikira*
378. Effects of various bridged-ligands on
substitution reaction toward DMSO of
dinuclear ruthenium(II) complexes.
Takeshi Yamada*, Misaki Nakai,
Yasuo Nakabayashi
379. Photochemical reaction of ruthenium(II)-ammine complexes containing bipyridinium cations as prodrugs.
Yuya Kubota*, Misaki Nakai,
Yasuo Nakabayashi
380. Oxidative DNA cleavage by cyclometalated ruthenium(II) complexes.
Hiroshi Sugiyama*, Yoshiki Shinpuku,
Misaki Nakai, Yasuo Nakabayashi
381. Synthesis and base-recognition behavior of nucleobase tethered bis(2,2’-bipyridine)platinum(II) complexes.
Yuji Kawanishi*, Takashi Funaki
382. Synthesis, characterization, and DNA
modification of new dicopper Schiff-base
complexes. Shi Jian, Tojo Midori,
Kitamura Yusuke, Chikira Makoto
74 –TECH
TECHNICAL PROGRAM
Hilton
Nautilus I & II
Actinides and the Environment: A
Multidisciplinary Look at What We Know
and What We Need to Know (#38)
Organized by: H. Nitsche, D. Kaplan,
C. Liu, Z. Yoshida
Presiding: D. Kaplan, W. Wu
19:00 – 383. Stability of tetravalent technetium in presence of natural and synthetic
organic ligands. Nathalie A. Wall*,
Baohua Gu
19:30 – 384. Abiotic reduction of uranium
and technetium by various Fe(II) forms in
aquifers. Ravi Kukkadapu*,
Tanya Peretyazhko, John Zachara,
James McKinley, Patricia Fox,
Davis James, Nikolla Qafoku, Arey Bruce,
Philip Long
20:00 – 385. Chemistry of transuranium elements in salt-base repository.
Marian Borkowski*, Donald Reed,
Jean-Francois Lucchini,
Michael Richmann, Hnin Khaing,
Julie Swanson, David Ams
20:20 – 386. Remediation and recovery of
uranium and technetium from contaminated groundwater using graphite electrodes: Impacts of aqueous geochemistry. Juan Peng*, Kelvin B. Gregory
20:40 – 387. Alternative solution for treatment of long-lived radioactive isotopes in
nuclear waste. Barbara Szpunar*,
Chary Rangacharyulu, Jerzy Szpunar
Convention Center
Kamehameha Halls II and III
Schiff Base Macrocycles and Materials
(#60)
Organized by: M. MacLachlan,
S. Brooker, C. Lee
Presiding: M. MacLachlan
Poster Session
19:00 – 21:00
388. Solid-state emission properties of
trans-bis(salicylaldiminato)platinum complexes bearing macrocyclic poly(oxyethylene) units. Kanako Fukumoto,
Naruyoshi Komiya, Takeshi Naota*
389. Emission properties of methylenevaulted trans-bis(salicylaldiminato)platinum(II) complexes. Minoru Okada,
Naruyoshi Komiya, Takeshi Naota*
390. Electro- and photoactive subphthalocyanine-based systems. Tomas Torres*,
David González-Rodríguez,
Esther Carbonell, Mine Ince,
Anais Medina, M. Victoria Martinez-Diaz,
Christian G. Claessens, Dirk M. Guldi
391. Condensation reaction of iridium complexes with N-amino-iminopyridine ligands for constructing dinuclear complexes. Keisuke Nakao, Hayato Tsurugi,
Kazushi Mashima*
Convention Center
Kamehameha Halls II and III
Frontiers in Organometallic Chemistry (#68)
Organized by: G. Bertrand, M. Fryzuk,
K. Tatsumi
Presiding: G. Bertrand
Poster Session
19:00 – 21:00
392. Synthesis, structure, and reactivities of
tetrasilyl-substituted trisilaallene.
Hiroaki Tanaka, Masaaki Ichinohe,
Akira Sekiguchi*
393. Heterolitic oxidative addition of Pd(I)Pd(I) dinuclear complexes with phosphines. Sen-ichi Aizawa*,
Wataru Maekawa, Ayana Taniguchi
394. Withdrawn
395. Carbon-silicon bond cleavage reactions
of alkynylsilanes with a platinum complex. Yuya Ishiguro, Yasuhiro Okuda,
Kentaro Takagi, Yasushi Nishihara*
396. Synthesis and structure analysis of neutral nickel(II) complexes bearing nitrogenoxygen bidentate ligands.
Daisuke Ogawa, Kenki Tanemura,
Kiyohiko Nakajima, Kentaro Takagi,
Yasushi Nishihara*
397. Divergent reactivity of phospha-iminines and applications towards late metal
catalysts. Christopher C. Brown,
Douglas W. Stephan
398. Design and synthesis of simply supramolecular device for photochemical
hydrogen production. Konomi Sato,
Yusuke Kataoka, Wasuke Mori*
399. Theoretical studies of excited states of
dirhodium(II) tetracarboxylate.
Yusuke Kataoka*, Yasutaka Kitagawa,
Toru Saito, Yasuyuki Nakanishi,
Takashi Kawakami, Wasuke Mori,
Kizashi Yamaguchi, Mitsutaka Okumura
400. Crystal structure and gas adsorption of
tetracarboxyl rhenium halide forming
Paddlewheel type. Yuto Suzuki*,
Yusuke Kataoka, Wasuke Mori
401. Facile ligand exchange reaction as a
convenient tool for measurement of ⌬⌬G
of the oxidative addition of benzoyl halides to palladium(0) complex.
Atsushi Sanagawa*, Takanori Iwasaki,
Hitoshi Kuniyasu, Nobuaki Kambe
402. Synthesis and luminescence behavior
of novel iridium complexes with tridentate
biphenylpyridine ligand. Marina Kamo,
Yuji Koga, Kouki Matsubara
403. Catalytic transfer deuterogenation in
D2O as deuterium source with HCO2H
via rapid H/D exchange using iridium catalysts with 4,4’-dihydroxy-2,2’-bipyridine.
Yuichiro Himeda*
404. Synthesis and reactivity of dinuclear
Cp*Rh amido and imido complexes.
Tomohiro Okawa, Shohei Otsuki,
Shin Takemoto*, Hiroyuki Matsuzaka*
405. R/X exchange reaction of cis[PtR2{P(NMeCH2)2X}2] (R ⫽ Me, Et, Ph, p
-tol; X ⫽ Cl, Br). Yuka Shigesato,
Masumi Itazaki, Hiroshi Nakazawa*
406. Synthesis and structures of metal complexes with aryloxides/anilides hybrid ligands. Yutaka Ishida*,
Hiroyuki Kawaguchi
407. Group 8 transition metal complexes
bearing dianionic, tridentate ligands and
their reactivity with Lewis acids.
Adam McKinty*, Doug Stephan
408. Synthesis of chiral alkyne-dicobalt
hexacarbonyls. Takumichi Sugihara*,
Chika Harumori
409. Indenyl complexes of Mn(II) and their
reactions with oxygen donor ligands.
Ryan M. Meier*, Jeffrey A. Crisp,
Timothy P. Hanusa,
William W. Brennessel
410. Synthesis of cobalt dithiolene complexes with boronic ester and applications of these complexes to functional
materials. Akihide Onozawa,
Mariko Sogawa, Kousuke Terada,
Mitsushiro Nomura, Toru Sugiyama,
Masatsugu Kajitani
411. Multistate organometallic switches.
Mark S. Jennaway*, Katy A. Green,
Marie P. Cifuentes, T. C. Corkery,
Marek Samoc, Mark G. Humphery
412. Synthesis of novel boryl-substituted
molybdenum carbyne complexes.
Rong Shang*, Anthony F. Hill
413. Development of six-, five- and four-coordinate Ru(II) hydride complexes supported by N-heterocyclic ligands for catalytic addition of H-H and C-H bonds
across multiple bonds. John P. Lee,
Magaly A. Ramirez, T. B. Gunnoe*,
Thomas R. Cundari, Paul D. Boyle,
Jeffrey L. Petersen
414. Cycloaddition reactions of borylene
complexes. Eva Siedler*,
Holger Braunschweig
415. Novel trimetalloboron compounds from
reactions of [{(␩5C5H5)(OC)2Mn}2B][Li(dme)3] with reactive
metal centers. Sebastian Oestreicher,
Holger Braunschweig
416. Syntheses of bulky and electron-deficient carbene ligands. Tetsuo Sato*,
Yoichi Hirose, Daisuke Yoshioka,
Shuichi Oi*
417. Unusual reactivity of Lewis acids with
group 8 metal complexes.
Michael P. Boone, Douglas W. Stephan*
418. New, tuneable zirconium-diamidophosphine complexes for dinitrogen activation. Kyle D. Parker*, Michael D. Fryzuk*
419. Metalloborylene complexes showing a
widespread pattern of reactivity.
Katharina Kraft, Holger Braunschweig
420. Late transition metal complexes as tunable Lewis-bases. Juergen Bauer*,
Holger Braunschweig
421. Synthesis, structure and reactivity of
distanna-[2]metallocenophanes.
Thomas Arnold, Holger Braunschweig
422. Synthesis, structure and reactivity of
transition metal-bridged metalloarenophanes and 1,1=-bisphosphinotrochrocenes. Maria Friedrich,
Holger Braunschweig
423. Radical reactivity of CpCr(III)␤-diketiminate alkyl compounds as a useful tool for
C-C bond formation. K. C. MacLeod,
Kevin M. Smith*
424. Catalytic hydrogenation and cyclization
of aromatic nitriles with nickel compounds. Juventino J. Garcia*,
Paulina Zerecero-Silva
425. Preparation of oxo-bridged titanium
alkoxo complexes for catalytic applications. Al Nielson*
426. Ferrocene tagged novel organic moiety:
Synthesis, crystal structure and electrochemical aspects. Rahul Bhattacharya*,
Sumana Chanda*, Jnan P. Naskar
427. Synthesis and coordination chemistry
of novel diphosphido ligands.
Jamie Ritch, Paul Hayes*
428. Heterogeneous borane cocatalyst for
ethylene polymerization.
Ying-Jen Wanglee, Susannah Scott*
429. Visible light-driven hydrogen production
catalyzed by nickel and cobalt catalysts
containing cyclic phosphine ligands with
pendant bases.
Matthew P. McLaughlin*,
Theresa M. McCormick,
Richard S. Eisenberg, Patrick L. Holland
430. Withdrawn
431. Withdrawn
432. Organophosphate neurotoxin hydrolysis by molybdenum metallocenes.
Louis Y. Kuo*
433. Photochemically and thermally induced
intermetallic borylene transfer.
Stefanie Bertsch, Holger Braunschweig
434. Synthesis and reactions of dinuclear
iridium complex bearing ␮2-NH ligand.
Shigeki Kuwata*, Takashi Kimura,
Koji Ishiwata, Takao Ikariya*
435. Utilization of planar chiral arene chromium tricarbonyl complexes as dynamic
complexes by stereoselective chromium
tricarbonyl migration reactions.
Ken Kamikawa*, Shunsuke Kinoshita,
Akiyoshi Mori
436. Stable doubly hydrogen-bridged butterfly-shaped diborane(4) compound.
Yoshiaki Shoji, Tsukasa Matsuo*,
Daisuke Hashizume, Hiroyuki Fueno,
Kazuyoshi Tanaka, Kohei Tamao*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
437. Coordination chemistry of bidentate
and tridentate N-aryl-substituted iminoN-heterocyclic carbene ligands.
Gino G. Lavoie*, Sarim Dastgir,
Anna C. Badaj, Timothy G. Larocque
438. Synthesis and reactivity of late transition metal vinylborane complexes.
Kristopher Kolpin*, David J. Emslie
439. Highly unsaturated platinum complexes
featuring boron-based ligands.
Peter Brenner*, Holger Braunschweig
440. Mechanistic investigations of palladium-catalyzed cross-coupling reactions
by electrospray ionization mass spectrometry. Krista Vikse*, Cara Manning,
J. S. McIndoe
441. Anionic N-heterocyclic carbenes with
N,N’-bis(fluoroaryl) and N,N’-bis(perfluoroaryl)substituents. Matthew G. Hobbs,
Chrissy J. Knapp, Patrick T. Welsh,
Javier Borau-Garcia, Tom Ziegler,
Roland Roesler*
442. New, efficient and direct preparation of
TlTp and related complexes with TlBH4.
Masahiro Yoshimura, Shinji Tanaka,
Kazuomi Tsuda, Masato Kitamura*
443. Electrochemical investigations of hydrogen-generating organometallic iron
compounds. Elizabeth S. Donovan,
Sarah Froberg, Greg A. Felton*
444. Versatile coordination chemistry of
complexes containing seleno- and telluroether ligands. Risto S. Laitinen*,
Raija Oilunkaniemi, Merja Poropudas,
Ludmila Vigo
445. Homogeneous nickel- and palladiumcatalyzed anaerobic oxidation of secondary alcohols at mild temperatures.
Oscar Navarro*
446. Neutral silane catalyst: Fac-mer isomerization of [Mo(CO)3(L)3] complexes (L ⫽
phosphite). Kozo Fukumoto*,
Hiroshi Nakazawa
Convention Center
Kamehameha Halls II and III
Early Main Group Chemistry (#100)
Organized by: P. Andrews, T. Chivers,
K. Henderson
Presiding: P. Andrews
Poster Session
19:00 – 21:00
447. Chiral ligands in s-block organometallic
complexes. Gemma M. Robertson,
Charles T. O’Hara*, Alan R. Kennedy
448. New utility heterometallic alkali-metal
amides: Closing the open dimer.
Stuart D. Robertson,
David R. Armstrong, Alan R. Kennedy,
Robert E. Mulvey*
449. Synergistic synthesis and structures of
zincated aromatic substrates.
Liam Balloch, Robert E. Mulvey*,
Toni Ratanen, Stuart D. Robertson,
Victor Snieckus*
450. Ring, ring, ring: Reactions of organo-alkali metal and alkali metal ates with tricyclic ketones. Ben J. Fleming,
Charles T. O’Hara*, Alan R. Kennedy
451. Two TMP ligands are better than one
for lithium-mediated alumination reactions. Ben Conway, Elaine Crosbie,
Robert E. Mulvey*, Stuart D. Robertson
452. 9-Borabicyclo[3.3.1]nonane-based
frustrated Lewis pairs: Expanding the
scope of metal-free hydrogenation.
Jeffrey M. Farrell, Douglas W. Stephan*
453. Peralkylated barium complexes.
Olaf Michel, Cäcilia Maichle-Mössmer,
Karl W. Törnroos, Reiner Anwander*
454. Transformation of an ethylenediamine
to a diaza-ethene via alkali metal mediated zincation. Ross Campbell,
Pablo Garcia Alvarez, Robert Mulvey,
Jörg Sassmannshausen, Tell Tuttle
455. Syntheses and structural study of halosulfite ions. Isoroku Nagasawa*,
Seigo Hikida, Chika Kurogi, Yukimi Doira,
Keisuke Mori, Hiroshi Kitagawa
456. Reaction of arynes with DMF and
salicylaldehydes: General synthesis of
xanthenes, xanthones, and xanthols.
Nahoko Matsunaga, Kentaro Okuma,
Noriyoshi Nagahora, Kosei Shioji
457. Synthesis, structures and reactivity of
novel alkali-metal boraamidinates and
boraguanidinates. Tristram Chivers*,
Andrea Corrente
458. Structure and reactivity studies of tethered mixed anion lithium complexes: A
model for superbase reactivity based on
a structural hypothesis.
Michael G. Gardiner*,
Bryce Lockhart-Gillett, Brian F. Yates
459. Three-coordinate diamido aluminum alkyls vs. four-coordinate analogs: Single
component catalysts for the ring opening
polymerization of cyclic esters.
Stephen Foley*, Jackson Chitanda,
Jeremy Olson, Curtis Ball
460. Synthesis of multidentate ligands with a
boryl moiety and their transition metal
complexes. Javier Borau-Garcia,
Michael J. Bosch, Roland Roesler*
461. Withdrawn
Convention Center
Kamehameha Halls II and III
Discrete Coordination Systems with
Switchable Structures and Properties (#143)
Organized by: T. Konno, A. Hor, K. Lu
Presiding: T. Konno
Poster Session
19:00 – 21:00
462. Metal cluster assembly using rhombic
macrocycles with inward metal binding
sites. Masumi Kuritani, Shohei Tashiro,
Mitsuhiko Shionoya*
463. Autocatalytic formation of dimer and
helix metallosupramolecular assemblages. Nobuto Yoshinari*,
Takumi Konno
464. Luminescent mechanochromism of silver complexes with a diphosphione
bridged by phenylene group.
Toshiaki Tsukuda*, Marina Kawase,
Ayumi Dairiki, Kenji Matsumoto,
Taro Tsubomura*
465. Reactivities of iridium(III) NSC(NR2)S2complexes generated by photolysis of
azido-dithiocarbamato complexes.
Keita Ariyoshi*, Takayoshi Suzuki,
Masaaki Kojima
466. Syntheses and properties of mononuclear manganese(II), -(III), and -(IV) complexes with a tripodal ligand.
Yukinari Sunatsuki*, Yukana Kishima,
Tamami Kobayashi, Tomoka Yamaguchi,
Takayoshi Suzuki, Masaaki Kojima
467. Switchable properties of metal complexes utilizing a quinone/hydroquinone
ligand system. Masato Kido,
Tsugiko Takase, Dai Oyama*
468. Encapsulated anion in a cubane-like
tetranuclear spin crossover iron(II) complexes. Hiroki Kondo*, Koshiro Nishi,
Naohide Matsumoto, Seiichiro Iijima,
Malcolm A. Halcrow, Yukinari Sunatsuki,
Masaaki Kojima
469. Selective formation of an AgI2AuI2 metalloring by mixing AgI4 and AuI4 metallorings. Yusuke Takino*,
Tatsuya Kawamoto, Kiyoshi Tsuge,
Takumi Konno
470. Cobalt complexes with a linear chain
type hexadentate ligand containing amidate and thioether groups.
Yuki Yamane*, Yukinari Sunatsuki,
Takayashi Suzuki, Masaaki Kojima
471. Reversible expansion and contraction
of a chelating metalloring in a NiIIAuI
complex with D-penicillaminate.
Yuji Hashimoto*, Asako Igashira,
Kiyoshi Tsuge, Takumi Konno
472. Geometrical isomers of cobalt(III) complexes with unsymmetrical tridentate (hydroxybenzamido)alkylamines.
Ryoji Mitsuhashi, Yukinari Sunatsuki,
Takayoshi Suzuki, Masaaki Kojima
473. Synthesis and self-assembly of an
AuI4CoIII2 hexanuclear complex containing D-penicillaminate. Raeeun Lee*,
Asako Igashira, Kiyoshi Tsuge,
Takumi Konno
474. Withdrawn
475. Characterization of pyrazine-bridged
ruthenium binuclear complexes and examination of their electrochromic properties. Sara Tsuyuki, Ryota Tanabe,
Kiyoshi Sato, Motowo Yamaguchi*
476. Development of the new photochemical
functional ruthenium complex showing
switching property on photochemical reaction of a ligand. Yoshitaka Mizuno,
Taiga Masano, Kiyoshi Sato,
Motowo Yamaguchi*
477. Metal substitution reactions of a
NiII2AuI3 pentanuclear complex with
D-penicillaminate. Akeha Fukushima,
Asako Igashira, Kiyoshi Tsuge,
Takumi Konno*
478. Crystal structures and isomerization reactions of dinuclear Ir(III)-Rh(III) complexes bridged by 5-methyltetrazolate.
Asuka Takayama, Takayoshi Suzuki,
Yukinari Sunatsuki, Masaaki Kojima
479. Tuning of redox potential in tridentate
benzimidazolyl Ru complexes having cyclometalated ligand. Shinpei Yoshikawa,
Katsuhiko Kanaizuka, Masa-aki Haga*
480. Thermochromism in Uranyl thiocyanate
complexes. Noboru Aoyagi*,
Kojiro Shimojo, Ryuji Nagaishi,
Hirochika Naganawa, Takaumi Kimura
481. Synthesis and reaction of ruthenium(II)
azido complexes bearing 2-pyridinethiolate. Go Nakamura*, Takayoshi Suzuki,
Yukinari Sunatsuki, Masaaki Kojima
482. Reactivity between metal complexes
bearing imidazole group and tetraphenylborate ion. Takanori Nagase*,
Yukinari Sunatsuki, Takayoshi Suzuki,
Masaaki Kojima
483. DFT calculations of the excited states of
Zn-TQENs. Ryo Miyamoto*, Yuji Mikata
484. Synthesis and luminescent properties
of gold(III) complexes with sulfur-containing amino acid. Kouhei Hayashida,
Kiyoshi Tsuge, Toshiaki Tsukuda,
Takumi Konno
485. Linkage of emissive D-penicillaminato
iridium(III) complexes by silver(I).
Yuta Sarukawa*, Asako Igashira,
Kiyoshi Tsuge, Takumi Konno
486. Synthesis and magneto-spectroscopic
study of Gd(III) complexes with multidentate peptide. Eiichi Kume*,
Ryo Miyamoto
487. Synthesis and properties of ruthenium
porphycene complexes having solvent ligands in the axial sites and application to
construct bridged assemblies.
Shiho Ashigara, Toru Okawara,
Masaaki Abe*, Hisashi Shimakoshi,
Yoshio Hisaeda*
488. Physical properties of dithiolate Ni complexes, Na[Ni(pdt)2], and K[Ni(pdt)2], connected by coordinate bonds.
Nozomi Ishihara, Shinya Takaishi,
Masahiro Yamashita
489. Structures and magnetic property of
seven-coordinate molybdenum(II) complexes containing 1,1,1-tris(dimethylphosphino)ethane. Atsushi Kikuma,
Takayoshi Suzuki, Yukinari Sunatsuki,
Masaaki Kojima
490. Neutral rhenium-biimidazole complex
as photoswitch and selective fluoride ion
sensor. Cheng-Hua Lee, Zong-Zhan Lu,
M. Velayudham, Kuang-Lieh Lu
491. Discrete rhenium complexes with
switchable photophysical properties.
Cheng-Hua Lee, Yu-Ping Lee,
Tien-Wen Tseng, Kuang-Lieh Lu
492. Electrochemically induced linkage
isomerization switched on/off by protolysis in 2-mercaptopyridine ruthenium(II)
complexes. Tomohiko Hamaguchi*,
Yoshimasa Inoue, Kikujiro Ujimoto,
Satoshi Kawata, Isao Ando
Convention Center
Kamehameha Halls II and III
Functional Molecules of the Heavier Main
Group and Transition Metal Elements (#156)
Organized by: F Ozawa, D. Gates,
P. Power
Presiding: F. Ozawa
Poster Session
19:00 – 21:00
493. Synthesis and properties of ruthenium
seleno- and tellurocarbonyl complexes.
Yuichiro Mutoh*, Naoki Kozono,
Miho Araki, Noriko Tsuchida,
Keiko Takano, Youichi Ishii*
494. Silylboronic esters bearing a dialkylamino group on silicon: New silylene
equivalents for palladium-catalyzed C-Si
bond formation. Toshimichi Ohmura*,
Kohei Masuda, Ichiro Takase,
Michinori Suginome*
495. Synthesis and reactivity of (␩3-␣-silabenzyl)tungsten complexes.
Takashi Komuro, Eiji Suzuki,
Yuto Kanno, Hiromi Tobita*
496. Multidentate P-stereogenic optically active polymers: Synthesis and coordination behaviors to transition metals.
Hiroaki Imoto*, Yasuhiro Morisaki,
Yoshiki Chujo
497. Luminescent homodinuclear copper(I)
complexes linked by 3,5-bis{6-(2,2=dipyridyl)}pyrazole. Jing-Lin Chen,
Bo Wu, He-Rui Wen
498. Possible new approaches to the synthesis of small luminescent gold clusters.
Sergei Ivanov*, Indika Arachchige
499. Iridium gallyl complexes.
Virginia Montiel-Palma*,
Clara J. Durango-García,
L. Verónica Henao-Holguín,
Rodolfo Valle-Altamirano,
Miguel Angel Muñoz-Hernandez,
Gabriel Merino
500. Reactivity of disilyne toward nitriles, silylcyanides, and isocyanides.
Katsuhiko Takeuchi, Masaaki Ichinohe,
Akira Sekiguchi*
501. Studies of a weakly coordinating phosphorus(V)anion. Paul W. Siu,
Derek P. Gates*
502. Synthesis, structure, and reactions of
novel silicon analogs of
bicyclo[1.1.1]pentanes.
Daisuke Tsushima, Shintaro Ishida,
Hiroyuki Isobe, Takeaki Iwamoto*
503. Unusual reactivity of a novel digermene.
Kiera McNeice, Vladimir Y. Lee,
Akira Sekiguchi
504. 121Sb Mössbauer spectra of antimony(V)-porphyrin complexes.
Makoto Toinaga*, Shiro Matsukawa,
Masashi Takahashi
505. Synthesis of group 10 metal complexes
bearing a new phosphine ligand tethered
with three thioether moieties, tris(2-isopropylthiomethylphenyl)phosphine.
Shinji Sahara*, Nobuhiro Takeda,
Masafumi Unno
506. Synthesis and reactions of a hydrido(hydrogermylene)ruthenium complex
with several unsaturated organic compounds. Chikako Furuya,
Hisako Hashimoto, Hiromi Tobita*
507. Transition metal-catalyzed arylation of
tertiary silanes. Yoshinori Yamanoi*,
Aldes Lesbani, Hitoshi Kondo,
Hiroshi Nishihara
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–75
02-INOR
508. Reactions of a hydrido(hydrogermylene)tungsten complex with isothiocyanates and isocyanates. Tetsuya Fukuda,
Hisako Hashimoto, Hiromi Tobita*
509. Chiral stannyllitium isolated by the complexation of (⫺)-sparteine.
Hanae Yamada, Hidekazu Arii,
Masato Nanjo, Kunio Mochida*
510. Synthesis of platinum complex with the
trans spanning diphosphino ligand as a
precursor of trans bis(silyl)platinum complex. Rei Hashimoto, Hidekazu Arii,
Pramesh N. Kapoor*, Kunio Mochida*
511. Disilane-bridged dinuclear platinum
complex formed the reaction of zero-valence platinum complex with 1,2-diphenyldisilane. Masaki Kanai, Hidekazu Arii,
Kunio Mochida*
512. Thermal reactivity of cis- and transbis(triaryl-substituted group 14 element)platinum(II). Misato Suga*
513. Synthesis of a hypervalent pentacoordinate boron compound with nitrogen donors. Yuichi Hirano*,
Yohsuke Yamamoto
514. Synthesis of germanium(II) hydride by
␤-hydrogen elimination on the germanium center. Taiyo Amari,
Fumiya Nakadate, Hidekazu Arii,
Kunio Mochida
515. Synthesis of copper-germylene complexes bearing a ␤-diketiminate ligand
with aliphatic alkyl groups.
Fumiya Nakadate, Hidekazu Arii,
Kunio Mochida*
516. Reactivities of ruthenium seleno- and
tellurocarbonyl complexes.
Naoki Kozono, Yuichiro Mutoh*,
Youichi Ishii
517. Synthesis of bulky para-phenylene type
di-functional compounds based on an shydrindacene skeleton.
Makoto Hachiya, Mikinao Ito,
Yoshiaki Shoji, Tsukasa Matsuo,
Kohei Tamao*, Yongming Li, Hayato Tsuji
518. Synthesis and property of group 6
metal complexes with tris(2-alkylthiophenyl)phosphine ligands.
Yohko Yamamoto*, Nobuhiro Takeda,
Masafumi Unno
519. Terphenyl stabilized divalent heavier
group 14 element acetylide complexes.
Hao Lei, Philip P. Power*
520. Silylplatinum complexes with the
diphosphino ligand formed by the Si-H/
Si-Si activation of unsymmetric disilanes.
Hidekazu Arii, Makiko Takahashi,
Kunio Mochida*
521. Reactivities of a stable primary-alkylsubstituted S-nitrosothiol bearing a cavity-shaped framework. Shohei Sase,
Noriaki Abe, Yohei Aoki, Kei Goto*
522. Iron(IV) complexes bearing two group
14 element ligands: Syntheses and their
ligand exchange reactions.
Masahiro Kamitani, Masumi Itazaki,
Kensuke Ueda, Hiroshi Nakazawa*
523. Catalytic activity of a novel (␮-oxo)tetraruthenium cluster towards selective oxidation of alcohols and dehydrogenative
cyclization of 2-aminophenethyl alcohols.
Yu Kimura, Takashi Kanda, Kenji Wada,
Akio Toshimitsu, Teruyuki Kondo*
524. New synthetic route for 2-phosphanaphthalenes. Noriyoshi Nagahora,
Tatsuya Wasano, Kosei Shioji,
Kentaro Okuma
525. Experimental and theoretical studies of
iron-catalyzed cross-coupling reactions
with grignard reagents.
Yoshihiro Okada, Lung Wa Chung,
Takuji Hatakeyama, Hikaru Takaya,
Keiji Morokuma, Masaharu Nakamura*
526. Planar hexagonal Pd-Pt tetranuclear
complexes. Makoto Tanabe,
Ryohei Yumoto, Tetsuyuki Yamada,
Kohtaro Osakada
527. Novel P,N-containing macrocyclic and
macrobicyclic tetraphosphines with aliphatic (C3-C5) spacer between phosphorus atoms. Oleg G. Sinyashin*,
Andrey A. Karasik, Roman N. Naumov,
Kirill B. Kanunnikov
76 –TECH
TECHNICAL PROGRAM
528. Synthesis, structure, and properties of
multinuclear group-11 metal complexes
bearing metal complex ligand moiety.
Hiroaki Matsumoto, Naoko Nishina*,
Kenta Sakamoto, Shota Mochizuki,
Yuhki Shibuya, Keiko Nabari,
Mitsuru Kondo*
529. Attempts at synthesis of anti-apicophilic stiboranes using the rigid tridentate
ligand. Shiro Matsukawa*,
Toshihiro Takeuchi, Hirokazu Nishikawa,
Hideaki Yamamichi, Masashi Takahashi,
Yohsuke Yamamoto
530. Synthesis and properties of cyclic organosilicon compounds. Yuki Toma,
Ken-ichiro Kanno, Soichiro Kyushin*
531. Synthesis and structure of ruthenium
and iridium complexes with PSi chelate ligand. Yasushi Miyauchi, Hidekazu Arii,
Kunio Mochida*
532. Metal nanoparticles supported on nitrogen-containing carbon nanofibers: Selective reduction of nitroarenes to anilines
and hydroxylamines. Youngjin Lee,
Keita Tsuji, Yukihiro Motoyama*,
Seong-Ho Yoon, Hideo Nagashima
Convention Center
Kamehameha Halls II and III
Electron Transfer and Electrochemistry of
Transition Metal Containing Inorganic and
Organometallic Materials (#187)
Organized by: H. Nishihara,
A. Abd-El-Aziz, P. Harvey, B.Z. Tang
Presiding: H. Nishihara
Poster Session
19:00 – 21:00
533. Reaction of 1,1’-bis(dimethylsilyl)metallocene with transition-metal methyl complexes. Masumi Itazaki,
Makiko Minakata, Akio Ichimura,
Hiroshi Nakazawa*
534. Charge/discharge characteristics of Sisubstituted olivine LiFePO4 as a positive
electrode for large-scale LIBs.
Morihiro Saito*, Taku Hosomi,
Taishi Ogata, Naoki Honda,
Akimasa Tasaka, Minoru Inaba
535. Immobilization of metal ion in polypyrrole matrix for oxygen reduction reaction
and charge storage in acidic media.
Hong-Kee Lee, Ji-Eun Ahn,
Ho-Nyun Lee, Hyun-Jong Kim*,
Myung-Keun (M.K.) Han, Hansung Kim
536. Layer-by-layer fabrication of novel
Ru/Os dinuclear complexes having a
strong metal-metal interaction on surface. Takuya Nakabayashi,
Katsuhiko Kanaizuka, Masa-aki Haga*
537. Pyrimidine ring inversion behaviors of a
copper(I) complex containing 4-methyl-2pyridyl-pyrimidine and their effects on the
photoprocess. Michihiro Nishikawa,
Kuniharu Nomoto, Shoko Kume,
Keiichi Inoue, Makoto Sakai,
Masaaki Fujii, Hiroshi Nishihara
538. Withdrawn
539. Magnetic and conducting properties of
new halide-bridged mixed-valence Cu(I)Cu(II) 1D coordination polymers Including
dithiocarbamate derivatives.
Naoya Tanaka, Kyung Ho Kim,
Takashi Okubo*, Masahiko Maekawa,
Takayoshi Kuroda
540. Multistep redox property of molecular
loops composed of integrated multinuclear clusters. Atsushi Inatomi,
Masaaki Abe*, Hisashi Shimakoshi,
Yoshio Hisaeda*
541. Programmable stacked nanoarrays of
porphyrins and phthalocyanines.
Yasuyuki Yamada, Marie Suzuki,
Kentaro Tanaka
542. Synthesis and electrochemical properties of mixed-metal cluster complexes
modified with ferrocenyl carboxylates.
Atsushi Ikegami, Masaaki Abe*,
Yoshio Hisaeda*
543. Immobilization of polynuclear ruthenium
complexes bearing hexakis(alkylthiol) anchors on gold electrode and their redox
behaviors. Hideki Kato
Convention Center
Kamehameha Halls II and III
Hilton
Kahili I/II
Carbon-fluorine Bond Activation: a
Crossroads for Inorganic, Organic, and
Environmental Chemistry (#248)
Olefin Oligomerization and Polymerization
Catalyzed by Early Transition Metals (#22)
Organized by: O. Ozerov, T. Akiyama,
J. Love
Presiding: T. Akiyama
Poster Session
19:00 – 21:00
544. Defluorination with water and nickel(0)
complexes. Juventino J. Garcia*,
Rigoberto Barrios-Francisco,
Alma Arevalo
545. Efficient and high-yield synthesis of difluorocyclopropanes. Kojun Oshiro,
Yoshimichi Morimoto, Hideki Amii*
546. Cationic palladium(II)-catalyzed FriedelCrafts-type cyclizations of 1,1-difluoro-1alkenes. Kohei Fuchibe,
Toshiyuki Morikawa, Tomohiro Ichitsuka,
Daishi Fujita, Hiroyuki Tanabe,
Misaki Yokota, Junji Ichikawa*
547. Selective oxidative additions of fluorinated aromatics with nickel(0) and a nitrogen ancillary ligand, en route to catalysis. Meghan E. Doster,
Samuel A. Johnson*
548. Nb(0)-mediated synthesis of 2,3-disubstituted indene derivatives by activation
of C-F bond of trifluoropropenes.
Kohei Atobe, Kohei Fuchibe,
Yukari Fujita, Keiji Mori,
Takahiko Akiyama*
549. Hydrodefluorination of fluoroaromatics
by [RuH2(CO)(NHC)(PPh3)2]: An explanation for the 1,2-regioselectivity.
Julien A. Panetier, Stuart A. Macgregor,
Michael K. Whittlesey
Friday Morning
Hilton
Coral II
Controlling the Structure and Properties of
Solids (#20)
Organized by: B. Kennedy,
Y. Shimakawa, P. Woodward
Presiding: P. Woodward
7:30 – 550. Square-planar iron oxides: High
pressure study. Hiroshi Kageyama*
8:00 – 551. Mixed oxide formation from thermal decomposition of heteronuclear 2,3pyridinecarboxylate complexes.
Alina M. Balu*, Rafael Luque,
Ana Lazarescu, Iurii Simonov,
Galina Filipova, Maria Gdaniec,
Constantin Turta
8:20 – 552. Cationic inorganic and metal-organic materials for catalysis and anion
trapping. Scott Oliver
8:40 – 553. New metal oxide based hybrid
semiconductors and their properties and
functionality. Xiao Zhang,
Thomas J. Emge, Jing Li*
9:00 – 554. Mixed ionic and electronic conduction in hydrated Ba4Nb2O9 and
Ba4Ta2O9: Structures, phase transitions,
and dynamics. Chris D. Ling*,
Maxim Avdeev
9:30 – 555. Electrochemical synthesis of
electrode materials with controlled architectures for use in clean energy production. Kyoung-Shin Choi*
10:00 – 556. Topochemical methods for the
construction of metal-nonmetal arrays
within layered perovskite hosts.
Jonglak Choi, K. G. Ranmohotti,
Elisha Josepha, John B. Wiley*
10:20 – 557. High pressure synthesis of new
A-site-ordered perovskites.
Takashi Saito*, Takenori Tohyama,
Yuichi Shimakawa
10:40 – 558. New inorganic second-order
NLO materials based on metal iodates.
Jiang-Gao Mao*, Chuan-Fu Sun,
Ting Hu, Bing-Ping Yang
Organized by: K. Theopold, K. Mashima,
Z. Xie
Presiding: K. Theopold
7:30 – 559. Copolymerization of ethylene
with cycloolefin or cyclodiolefin by bis(beta-dikitiminato)titanium complexes activated with modified methylaluminoxane.
Yuesheng Li*
8:10 – 560. Center-center and center-surface cooperative enchainment effects for
the catalytic synthesis of new polyolefin
materials. Tobin J. Marks
8:50 – 561. Oligo- and polymerization catalysts based on bis(phenolato) early transition metal complexes. Jun Okuda*
9:30 – 562. Design, synthesis of titanium(IV)
complexes bearing monoanionic [ONX]
(X ⫽ O, S, Se, P) tridentate ligands and
their behaviour in ethylene homo- and copolymerization. Yong Tang*
10:10 – 563. Metallocenium dications and silylium-metallocenium hetero-dications:
Generation and roles in polymerization of
polar and nonpolar alkenes.
Yuetao Zhang, Eugene Y. Chen*
10:50 – 564. Remote substituent effects
upon olefin polymerization behavior of
chelating ␴-aryl group 4 catalysts.
Michael C. Chan*, Ben L. So
Hilton
Rainbow I
Fundamental and Applied Inorganic
Fluorine Chemistry and Their Impacts on
Energy Conservation and the Environment
(#249)
Organized by: R. Hagiwara,
K. Matsumoto, H. Mercier,
G. Schrobilgen, R. Syvret
Presiding: K. Matsumoto, H. Mercier
7:30 – 565. Approaches in the syntheses of
fluorine compounds and methods of
growths of single crystals. Zoran Mazej*,
Evgeny Goreshnik
8:00 – 566. Order and disorder in ammonium
fluoro- and oxofluorometallates: Products
of natural minerals fluorination.
Natalia Laptash
8:30 – 567. [AgF2] layers: Excursion to positive and negative pressure regimes.
Mariana Derzsi*
8:50 – 568. Environmental friendly replacement of lead diazide: The synthesis of
bismuth azides from bismuth fluorides.
Ralf Haiges*, Karl O. Christe
9:10 – 569. Benzene radical cations.
Konrad Seppelt*, Hashem Shorafa,
Matthias Molski, Beate Paulus
9:30 – 570. Transparent MgF2-films by solgel coating. Erhard Kemnitz*
10:00 – 571. Role of oxygen in the stabilization of nanofluorides and their impact on
reactivity properties.
Alain Demourgues*, Durand Etienne,
Clarenc Romain, Tressaud Alain
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
10:30 – 572. Low temperature flux growth of
NaYF4:Ln (Ln⫽Yb, Er, Tm) crystals and
layers with upconversion fluorescence.
Toshiko Wakabayashi,
Katsuya Teshima*, SunHyung Lee,
Shuji Oishi
10:50 – 573. Preparation and characterization of Ni-PTFE plate as an electrode for
alkaline fuel cell. Jae-Ho Kim*,
Hirotaka Kinoshita, Susumu Yonezawa,
Toshihide Tsukatani,
Masayuki Takashima
11:10 – 574. Nanofabrication of tin oxide for
anode active materials by the liquid
phase deposition method.
Minoru Mizuhata*, Yuki Umekage,
Ramanujam Kumaresan, Koichi Ui
10:10 – 588. Pyridine-bis(oxazoline) and
pyridine-bis(thiazoline) ligands as sensitizers of lanthanide ion visible and nearinfrared luminescence.
Ana de Bettencourt-Dias*,
Subha Viswanathan, Daniel T. de Lill,
Patrick S. Barber, Alexandra Rollett,
Anthony M. Bass, Joseph Neiman,
Sultan Altun
10:40 – 589. Band-gap and morphology
controls by molecular architecture of
highly arylated-silanes. Won-Sik Han,
Kyung-Ryang Wee, Sunnam Kwon,
Sang Ook Kang*
Hilton
Rainbow II
Organoboron, Organosilicon and
Organophosphorus as Optoelectronic and
Energy-related Materials (#35)
Redox Redux: The Renaissance of NonInnocent Ligand Complexes (#217)
Organized by: J. Soper, S. Colbran,
R. Hicks
Presiding: R. Hicks
7:50 – 575. Noninnocent ligands: How to
turn a loss into a gain.
Evgeny V. Dikarev*
8:10 – 576. Stabilisation of unusual metal oxidation states: The role of noninnocent
thioether and thiolate donors.
Martin Schroder*
8:30 – 577. Characterization of ruthenium
2-iminoquinone complexes through experimental and theoretical studies.
Jonathan Rochford, Ming-Kang Tsai,
James T. Muckerman, Etsuko Fujita*
9:00 – 578. Multi-electron processes, dioxygen activation, and electrochemistry of
Zr, Ti, and Mo diimine complexes.
Mahdi M. Abu-Omar*
9:30 – 579. Redox chemistry of Fe(Cl4SQ)3
and its activity as an electrocatalyst for
water oxidation. Cortlandt Pierpont*,
Joseph Kelly, Nathan Hawkey,
Paul Nelson, Michael Krysiak,
Hshin Hui Huang
10:00 – 580. Noninnocent ligand complexes
in late metal organometallic chemistry.
Thomas B. Rauchfuss*,
Mark R. Ringenberg
10:30 – 581. Pyrrolide ligand platforms as redox-active entities. Theodore Betley*
11:00 – 582. Radical models for the CuB
centre of heme-copper oxidases.
Stephen Colbran
Hilton
Hibiscus I/II
Molecular Photonics (#9)
Organized by: F. Castellano, T. Majima,
V. Yam
Presiding: T. Majima
8:00 – 583. Photophysical studies of phosphorescent three-coordinate Cu(I)-(Nheterocyclic carbene) complexes.
Valentina A. Krylova*, Peter I. Djurovich,
Matthew T. Whited, Mark E. Thompson
8:20 – 584. Transannular torsion dominates
Franck-Condon dynamics in strongly absorbing metallodipyrrin complexes: A resonance Raman study. Mark Waterland*,
Tracey McLean, Shane Telfer,
Keith Gordon, Samuel Lind
8:40 – 585. Studies of the photoexcited
states of MM quadruply bonded systems:
Dynamics and charge distributions.
Malcolm H. Chisholm*
9:10 – 586. Supramolecular functional systems in electrically active molecular assemblies. Takayoshi Nakamura*,
Toru Endo, Shin-ichiro Noro,
Tomoyuki Akutagawa
9:40 – 587. Geometric influences on intramolecular electron transfer in metallosupromecular assemblies.
Richard Keene*, Deanna D’Alessandro,
Emma Laird, Elizabeth Fellows
Hilton
Nautilus I & II
Organized by: S. Wang, F. Jaekle,
Y. Wang, S. Yamaguchi
Presiding: S. Wang
8:00 Opening remarks
8:10 – 590. Applications of boron chemistry
in the development of materials for linear
and nonlinear optics. Todd B. Marder*
8:40 – 591. Borirenes and boroles: New
chemistry from old heterocycles.
Holger Braunschweig
9:10 – 592. Synthesis and properties of triarylboranes bearing peripheral o-carborane cages. Kang Mun Lee, Taewon Kim,
Jung Oh Huh, Youngkyu Do, Min H. Lee*
9:30 – 593. Insight into the mechanism of difluoroboron-diketonate-polylactide luminescence. Guoqing Zhang, Tiandong Liu,
Ruffin E. Evans, Cassandra L. Fraser
10:00 – 594. Lewis acidic properties of
heavier group 15 onium ions.
Casey R. Wade, Tzu-Pin Lin,
Francois P. Gabbai*
10:30 – 595. Creation of functional molecules utilizing characteristics of boron.
Takayuki Kawashima*
11:00 – 596. Tuning the photochromic properties of N,C-chelate organoboron compounds. Chul Baik, Hazem Amarne,
Zachary M. Hudson, Sephen Murphy,
Suning Wang*
Hilton
Lehua Suite
Organo-f-Element Compounds: From Novel
Chemical Transformations to Applications
in Catalysis and Materials Science (#46)
Organized by: F. Edelmann, D. Berg,
G. Deacon, Z. Hou, J. Kiplinger
Presiding: G. Cloke, D. Berg
8:00 Introductory remarks
8:10 – 597. Variable nuclearity scorpionatesupported lanthanide polyhydrides: Synthesis, structure, and reactivity.
Jianhua Cheng, Kuburat Saliu,
Michael J. Ferguson, Robert McDonald,
Josef Takats*
8:40 – 598. Rare-earth metal methylidene,
methine, and carbide complexes.
Reiner Anwander*,
Melanie Zimmermann, H. M. Dietrich,
Rannveig Litlabø, Laura C. Gerber,
Dorothea Rauschmaier, Lars N. Jende,
Karl W. Törnroos,
Cäcilia Maichle-Mössmer
9:10 – 599. Rare-earth metal polyhydride
complexes with non-cyclopentadienyl ligands. Zhaomin Hou*
9:30 – 600. Expanding reductive and organometallic transformations via the f elements. William J. Evans*
10:00 – 601. Rare earth transition metal
bonding. Rhett Kempe
10:30 – 602. Lanthanide complexes of soft ligands. David Berg*, Jin Zou,
Brendan Twamley, Tosha Barclay
10:50 – 603. Imidazolin-2-iminato complexes of rare earth metals with very short
metal-nitrogen bonds: Experimental and
theoretical studies. Matthias Tamm*,
Tarun K. Panda, Alexandra G. Trambitas
Hilton
South Pacific I
Chemistry of Sulfur-Bridged Multimetallic
Complexes (#96)
Organized by: T. Rauchfuss, G. Jin,
T. Matsumoto, Y. Mizobe
Presiding: T. Rauchfuss
8:00 – 604. Reduction of proton to evolve
hydrogen catalyzed by cubane-type metal-sulfido clusters. Yasushi Mizobe*,
Hidetake Seino
8:35 – 605. Understanding what controls the
rates of proton transfer to Fe-S-based
clusters. Richard A. Henderson*
9:05 – 606. Syntheses and structural characterization of new iron-sulfur-nitrosyl clusters. Dimitri Coucouvanis*,
Charalambos Kalyvas
9:35 – 607. Synthesis, structure and chemistry of novel M2(␮-S)(␮-S2) (M ⫽ Mo, W)
complexes. Charles G. Young*,
Craig Gourlay, Michelle K. Taylor,
Patrick J. Lim, David J. Evans
10:05 – 608. From iron sulfide minerals to
[FeFe] hydrogenase models.
Wolfgang Weigand*
10:35 – 609. Synthesis of [Fe8S7] clusters
analogous to the metal-sulfur clusters in
nitrogenase. Yasuhiro Ohki*,
Kazuyuki Tatsumi
Hilton
Rainbow III
Advances in Metal-Mediated Bond
Activation: From Unusual Bonding Motifs to
Applications in Catalysis (#146)
Organized by: K. Caulton, S. Komiya,
M. Stradiotto
Presiding: M. Stradiotto
8:00 – 610. Synthetic and kinetic investigation into bond activations by organolutetium complexes supported by a monoanionic carbazole-based pincer ligand.
Paul G. Hayes*, Kevin R. Johnson
8:20 – 611. Multiple metal centres: Efficient
catalysis of tandem reactions for heterocycle synthesis. Joanne H. Ho,
Joerg Wagler, Barbara A. Messerle*
8:40 – 612. Copper N-heterocyclic carbene
catalysts: A rich mine of structural and
bonding motifs. Andy T. Hor*,
Xiaoyan Han, Zhiqiang Weng
9:00 – 613. Intramolecular C-H and C-F
bond activation by Co(II) and Fe(II) complexes. Cora E. MacBeth,
Matthew B. Jones
9:20 – 614. Exploiting P,N-ligands for the
palladium-catalyzed cross-coupling of
aryl chlorides and amines: Broad substrate scope, chemoselectivity, and novel
room temperature ammonia arylation
chemistry. Mark Stradiotto*
9:40 – 615. Iron-catalysed C-H bond functionalization. Theodore Betley*
10:00 – 616. Modular tantalum amidate
complexes for the catalytic hydroaminoalkylation of amines and N-heterocycles.
Laurel Schafer
10:20 – 617. C-Cl bond activation in chloroalkanes. Pierre Braunstein*,
Roberto Pattacini, Suyun Jie
10:40 – 618. Scorpions and crabs: The
chemistry of metallaboratranes and boron pincer complexes. Anthony F. Hill*,
Ian R. Crossley, Ian A. Cade,
Jörg Wagler, Matthew K. Smith,
Anthony C. Willis
11:00 – 619. Formation and reactivity of a bimetallic ruthenium platinum carbido complex. Shin Takemoto*, Kenji Karitani,
Hidenobu Morita, Hiroyuki Matsuzaka*
Hilton
Coral I
Molecular Design in Bioinorganic
Chemistry (#173)
Organized by: T. Hayashi, D. Goldberg,
P. Kennepohl, H. Masuda
Presiding: D. Goldberg, J. Kovacs
8:00 Opening remarks
8:10 – 620. Synthetic approaches to dicopper and tricopper centers for constructing
biomimetic model compounds of multicopper proteins. Yasuhiro Funahashi*,
Tomoaki Toyama, Kojiro Nagata,
Kotaro Yoshii, Tomohide Nishikawa,
Kensuke Fukui, Yuji Kajita,
Yuko Wasada-Tsutsui,
Tomohiko Inomata, Tomohiro Ozawa,
Hideki Masuda
8:30 – 621. Modelling the Mo(V) states of
molybdoenzymes: dioxo- and oxosulfidoMo(V) complexes and their conjugate acids. Charles G. Young*, Victor W. Ng,
Michelle K. Taylor, Jonathan M. White
8:50 – 622. Activation and catalytic reduction of dioxygen: Lessons from heme enzyme chemical models.
Yoshinori Naruta*, Jin-Gang Liu,
Takehiro Ohta, Annada C. Maity,
Yuta Shimizu, Fumito Tani
9:30 – 623. High-valent metal-oxo corrolazine complexes and their relationship to
biologically relevant hydrogen-atomtransfer and oxygen-atom-transfer processes. David Goldberg*,
Katharine Prokop, Pannee Leeladee,
Amanda McGown, Kevin Cho
10:00 – 624. Metal ion Lewis acidity control
over the preferred reaction pathways of
metastable intermediates observed in dioxygen and superoxide reactions.
Julie Kovacs*, Michael Coggins,
Santiago Toledo, Morgan Gleaves
10:30 – 625. Bioorganometallic chemistry of
mercury: A functional model for mercury
detoxification by organomercurial lyase,
MerB. Gerard Parkin*
11:00 – 626. Bis(thione) ligands and the
preparation of synthetic analogs of methanobactin. Daniel Rabinovich*
Hilton
Sea Pearl III/IV
Schiff Base Macrocycles and Materials
(#60)
Organized by: M. MacLachlan,
S. Brooker, C. Lee
Presiding: S. Brooker
8:30 – 627. Assembly of dynamic polyimine
nanocapsules. Ralf Warmuth*
9:00 – 628. Conjugated Schiff bases as functional materials? Will Skene*,
Satyananda Barik, Bolduc Andréanne,
Stéphane Dufresne
9:30 – 629. Double template effects: Mechanism and manipulation. Vickie McKee*
10:00 – 630. Cooperative complexation and
functions of Schiff base macrocycles and
related ligands. Tatsuya Nabeshima*
10:30 – 631. Thiolate¡Halogen chargetransfer adducts of macrocyclic aminothiophenolate complexes.
Berthold Kersting*
Convention Center
Kamehameha Halls II and III
Actinides and the Environment: A
Multidisciplinary Look at What We Know
and What We Need to Know (#38)
Organized by: H. Nitsche, D. Kaplan,
C. Liu, Z. Yoshida
Presiding: R. Wilson, A. Hixon
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–77
02-INOR
Poster Session
10:00 – 12:00
632. Study of rapid radiochemical separation
technique on short-lived fission product
nuclides. You-qian Ding*,
Zhi-hong Yang, Guo-shu Mao,
Sheng-dong Zhang
633. Effect of temperature and radiolysis on
the separation of actinides, lanthanides,
and transition metals using the combined
extractant HDEHP and CMPO.
Michael W. Dunlevy*, Art Gelis,
M. A. Brown, Gregg Lumetta,
George Vandegrift
634. Development of a liquid scintillation detector coupled with a capillary-electrophoresis apparatus for analysis of spent
nuclear fuel. Hidetoshi Kikunaga*,
Takashi Yoshimura, Kazuhiro Ooe,
Naruto Takahashi, Hiromitsu Haba,
Yutaka Ezaki, Toshiaki Mitsugashira,
Atsushi Shinohara
635. Solubility of some transuranic elements
in groundwater. Chunli Liu, Tao Chen,
Mao Sun, Xiangyun Wang, Wenyu Tian,
Chun Li, Xiaoyu Liu, Luhua Wang,
Zhong Zheng
636. Preparation of the special Pu-239 material. Guo-shu Mao*, Sheng-dong Zhang,
You-qian Ding, Ya-ping Zhao
637. Radiolytic stability of actinide-complexed extraction ligands under aqueous
acidic reprocessing conditions.
Delora K. Gaskins, Thomas D. Cullen,
Stephen P. Mezyk, Leigh R. Martin,
Bruce J. Mincher
Convention Center
Kamehameha Halls II and III
Syntheses and Applications of MetalOrganic Frameworks (#97)
Organized by: M.P. Suh, C. Kepert,
S. Kitagawa, J. Long, G. Shimizu
Presiding: M. Suh
Poster Session
10:00 – 12:00
638. Molecular dynamics simulations on the
phase transitions and molecular motions
of benzene molecules confined in IRMOF-1. Kohei Takakura*,
Takahiro UEDA, Keisuke MIYAKUBO,
Taro EGUCHI, Bodo MARTIN,
Peter COMBA
639. Fabrication of photoconductive poly(Nvinylcarbazole) in 1-D coordination
nanochannels. Noriyuki Uchida,
Takashi Uemura*, Susumu Kitagawa*
640. Novel Cu(I) metallamacrocycles toward
structurally and functionally new inorganic anion receptors.
Masahiko Maekawa*, Takashi Okubo,
Takayoshi Kuroda-Sowa,
Megumu Munakata, Susumu Kitagawa
641. Proton conductivity of an oxalatebridged honeycomb shaped metal-organic framework. Masaaki Sadakiyo*,
Teppei Yamada, Hisashi Okawa,
Hiroshi Kitagawa
642. Selective carbon dioxide adsorption in
amine functionalised metal-organic
frameworks. Simon S. Iremonger,
Vaidhyanathan Ramanathan,
George K. Shimizu*
643. Supramolecular organization of tris-dithiolato transition metal complexes:
Structures, opto- and electrochemical
properties. Takeshi Matsumoto,
Hirokazu Yano, Atsushi Kobayashi,
Ho-Chol Chang, Masako Kato*
644. Microporous 2-D MOF based on zinc(II),
terephthalate, and 4,4’-dipyridyldisulfide:
Synthesis, structure, gas adsorption, and
photoluminescence studies.
Chih-Chieh Wang*
645. Desolvated structures and gas sorption
properties vs. activation methods of a porous metal-organic framework.
Hye Jeong Park*, Dae-Woon Lim*,
Myunghyun P. Suh*
646. Evaluation of heterogeneous metal-organic framework organocatalysts prepared by postsynthetic modification.
Sergio J. Garibay, Zhenqiang Wang,
Seth Cohen
78 –TECH
TECHNICAL PROGRAM
647. Synthesis and properties of MOF compound with rare earth elements and 2,4PDC. Ryosuke Matsumura,
Kazuyoshi Uematsu, Tadashi Ishigaki,
Kenji Toda, Mineo Sato
648. Topologies and selective gas sorption
properties of small pore MOFs having
mixed-donor ligands with non-coordinating polar atoms. Jinwoo Seo,
Hyungphil Chun*
649. Metathesis in single crystal: Postsynthetic modification via framework constituting metal ion exchange.
Sunirban Das*, Yonghwi Kim,
Hyunuk Kim, Kimoon Kim
650. High crystallinity Rh-based metal-organic frameworks: [Rh2M2(BDC)4] (M ⫽
Cu, Zn). Satoshi Matsunaga*,
Ken-ichi Hasada, Nanako Endo,
Wasuke Mori*
651. Rational assembly and property study
of microporous metal-carboxylate frameworks in ncb-net. Yue-Biao Zhang,
Jie-Peng Zhang*, Xiao-Ming Chen*
652. Self-assembled honeycomb structures
with 1-D channels constructed from a series of cyclam-type complexes.
Kazuaki Tomono*, Mika Yamawaki,
Hiromi Kawamura, Kazuo Miyamura
653. Crystalline molecular sponge: A networked coordination cage that absorbs
fullerenes in high concentration.
Tatsuhiko Arai, Yasuhide Inokuma,
Makoto Fujita*
654. Reaction of organozinc reagents with
an aldehyde in a porous network crystal.
Koki Ikemoto, Yasuhide Inokuma,
Makoto Fujita
655. Electrochemical analysis of reversible
Li-ion storage reaction in Prussian blue
analogs metal-organic frameworks by lattice-gas model. Yoshifumi Mizuno*,
Masashi Okubo, Katsuyoshi Oh-ishi,
Tetsuichi Kudo, Haoshen Zhou,
Itaru Honma
656. Synthesis and chemical sensing functions of novel luminescent coordination
polymers based on a Pt(II) complex.
Hirofumi Hara*, Atsushi Kobayashi,
Masako Kato
657. Lewis acid metal-organic framework
catalysts. Kristine K. Tanabe,
Seth M. Cohen*
658. Initiate flexibility and sorption selectivity
in rigid metal-organic frameworks by alkylether-functionalised linkers.
Roland A. Fischer*, Sebastian Henke,
Rochus Schmid
659. Hydrogen storage in metal-organic
frameworks with bare metal sites.
Chun Chen*, Cameron J. Kepert,
Peter D. Southon, Craig M. Brown
660. Possible control of molecular adsorption and desorption in metal coordination
polymers. Naoki Muramatsu*,
Yoshiyuki Kageyama, Goro Maruta,
Sadamu Takeda
661. Novel porphyrin-based metal carboxylate framework:
[Zn4(OH)2(H2O)2(ZnTCPEP)2(DABCO)].
Nanako Endo, Satoshi Matsunaga*,
Wasuke Mori*
662. Molecular engineering for synthesizing
new metal organic frameworks with multifunctional properties. Ming Xue,
Shilun Qiu*
663. Preparation and catalytic properties of
metal carbonyl clusters incorporated in
Metal-Organic-Frameworks.
Chikako Asai, Takeshi Kubota*,
Yasuaki Okamoto
664. Influence of bridging and inclusion tecton on network stability, porosity and gas
adsorption of metal-organic frameworks.
Anil D. Naik, Mathieu Monaux,
Alexandre Léonard, Bernard Tinant,
Bao-Lian Su, François Robert,
Yann Garcia*
665. Thioether-laced porous coordination
networks for uptake of functional metal
species. Zhengtao Xu*, Xiao-Ping Zhou,
Matthias Zeller, Allen D. Hunter
666. Functional cyclobutane derivatives for
metal organic frameworks.
Goutam K. Kole*, Jagadese J. Vittal
667. Supramolecular metal organic framworks and coordination polymers organized by strong, noncovalent ␲-␲ stacking interactions: Single crystal to single
crystal transformations. Daniel Reger*,
Jacob Horger, Agota Debreczeni,
Mark Smith
668. Microporous metal-organic frameworks
based on pillared Kagomé layers showing
peculiar absorbate selectivity.
Myoung Soo Lah*
669. Incorporating additional functionality
into metal-organic frameworks.
Christopher Sumby*
670. Controlled multiscale synthesis of porous coordination polymer in nano/micro
regimes. Stephane Diring*,
Shuhei Furukawa, Susumu Kitagawa
671. Protection and deprotection approach
for constructing metal-organic frameworks having large pore aperture.
Teppei Yamada*, Hiroshi Kitagawa
672. Homochiral coordination polymers for
stereoselective sorption.
Danil N. Dybtsev, Kyungwon Suh,
Kimoon Kim
673. Stability of metal-organic framworks
against water: Molecular dynamics with
ReaxFF reactive force field.
Sang Soo Han*, Seung-Hoon Choi,
Jaheon Kim, Adri C. van Duin
674. Tailored thermal expansion in metal-organic frameworks. Yue Wu*,
Cameron J. Kepert
675. Charge-carrier transport properties of a
new intercalation compound consisting
of 2D copper(I)-bromide layers and incorporated TTF cations. Takashi Okubo*,
Kyung Ho Kim, Yuma Yoshito,
Naoya Tanaka, Tomonari Wakabayashi,
Masahiko Maekawa,
Takayoshi Kuroda-Sowa
676. Crystalline nanochannel host composed of helical Pd3-metallo-macrocycles. Ryou Kubota, Shohei Tashiro,
Mitsuhiko Shionoya*
677. Soft templates tailored via guest exchange. Matteo Lusi*,
Leonard J. Barbour
678. Metal organic frameworks with noncoordinating functional groups: Effects on
structures and properties.
Prashant Bhatt, Leonard J. Barbour*
679. Correlation between host-guest interaction and adsorption structures in coordination space: A Monte Carlo simulation
study. Manabu Sugimoto, Makoto Ide
680. Au@ZIFs:Stabilisation of homogeneously dispersed cavity-size matching
Au nanoparticles inside functionalized zeolite imidazolate type metal-organic
frameworks. Roland A. Fischer*,
Daniel Esken, Stuart Turner,
Oleg I. Lebedev, Gustaaf van Tendeloo
681. Targeted synthesis of porous organic
frameworks by Yamamoto type Ullmann
reaction that store gas. Teng Ben,
Shilun Qiu*
682. Fabrication and characterization of tetraalkoxyphthalocyanine-molybdate hybrid Langmuir-Blodgett film for photoinduced electron transfer system.
Hisanao Usami*, Tatsuya Ohno,
Eiji Suzuki
685. Intramolecular alkylation of ␣-diimine ligands giving amido—imino and diamido
scandium and yttrium complexes as catalysts for intramolecular hydroamination/
cyclization. Hiroshi Kaneko,
Tsurugi Hayato, Panda K. Tarun,
Kazushi Mashima*
686. Zirconium complex of (Z)-substituted
[5]culumene. Nozomu Ohara,
Kosuke Nishimura, Yoshiro Masuyama,
Noriyuki Suzuki*
687. Synthesis of polyfunctionalized compounds via metallation of terminal
alkynes having a phenylseleno group.
Kazuki Shintaku, Hajime Maeda*,
Masahito Segi*
688. Seven-membered ring formation via
7-endo-trig cyclization of heptatrienes
synthesized by Zr-mediated selective
coupling reactions. Eri Igarashi,
Ken-ichiro Kanno, Shenyong Ren,
Kiyohiko Nakajima, Tamotsu Takahashi*
689. Synthesis and reactivity of seven-membered cycloalkyne complexes.
Takashi Tsuchiya, Yoshiro Masuyama,
Noriyuki Suzuki*
690. Generation and reactivity of new low
valent titanium alkoxides.
Tsuyoshi Kawaji, Sentaro Okamoto*
691. Lanthanide complexes with 2,6-pyridinedicarboxamide based macrobicyclic
ligand. Jide Xu*, Kenneth N. Raymond
692. Thermal and antimicrobial aspect of
poly[(2-hydroxy,4-butoxy) butylene] ligand and its polychelates with lanthanides (III). Jayantilal D. Joshi*,
Vasant M. Patel
693. Regio- and stereoselective synthesis of
multisubstituted aliphatic olefins via zirconacycles. Yoshiaki Okada,
Megumi Kinoshita, Kentaro Takagi,
Yasushi Nishihara*
694. Efficient route to cyclic alkenylboronates via zirconacycle formation/ring-closing metathesis sequences.
Daisuke Saito, Kentaro Takagi,
Yasushi Nishihara*
695. Reaction of laser-evaporated lanthanide
atoms (Sc, Yb) with cyclopentadiene.
Jun Miyazaki*, Yasuhiro Yamada
696. Zirconium-mediated formation of disilylpentacene and its application.
Zhiying Jia, Shi Li, Ken-ichiro Kanno,
Tamotsu Takahashi*
697. Zirconocene mediated synthesis of
phenylene-thiophene monomers and oligomers. Debabrata Payra, Zhiyi Song,
Ken-ichiro Kanno, Tamotsu Takahashi*
698. Zirconium-mediated synthesis of acene
derivatives by homologation method and
coupling method. Yun-Hua Wang, Shi Li,
Zhiyi Song, Tamotsu Takahashi*
699. Double C-C bond cleavage of titanocene derivatives. Haijun Li, Zhiyi Song,
Tamotsu Takahashi*
700. Synthesis and physiochemical characterization of carbon backbone modified
[Gd(TTDA)(H2O)]2- derivatives.
Yun M. Wang*, Ying H. Lin, Gyan Singh,
Ya H. Chang
701. Design of ligand for pinacol coupling reaction. Akihiro Miyasaka, Toru Amaya*,
Toshikazu Hirao*
Convention Center
Kamehameha Halls II and III
Preparation and Reactions of Early
Transition Metal and Lathanide
Compounds (#150)
Organized by: T. Takahashi, G. Deacon,
R. Jordan, Z. Xi
Presiding: T. Takahashi
Poster Session
10:00 – 12:00
683. Five-membered metallacycloallene
compounds derived from 1,3-enynes.
Taichiro Shimura, Yoshiro Masuyama,
Noriyuki Suzuki*
684. Regioselective formation of five-membered titanacycles by [2⫹2⫹1] cycloaddition. Shigeki Oishi, Takafumi Inoue,
Kaoru Ohomika, Akira Tsubouchi,
Takeshi Takeda*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
Friday Afternoon
Hilton
Coral II
Controlling the Structure and Properties of
Solids (#20)
Organized by: B. Kennedy,
Y. Shimakawa, P. Woodward
Presiding: Y. Shimakawa
12:30 – 702. Novel UV excitable phosphors
for white light-emitting diodes.
Ru-Shi Liu, Shu-Fen Hu*
13:00 – 703. Recent development in highperformance piezo ferroelectric single
crystals. Zuo-Guang Ye*, Xifa Long,
Alexei A. Bokov, Yujuan Xie
13:20 – 704. Oxynitride materials for visiblelight-driven water splitting.
Peter Khalifah*, Limin Wang,
Alexandra Reinert, James Ciston,
Peichuan Chen, Alexander Orlov,
Zhijun Xu, Genda Gu, Wei Kang,
William Woerner, John Parise
13:40 – 705. Modification of oxides via reductive fluorination. Yoji Kobayashi*,
Mingliang Tian, Miharu Eguchi,
Jung eun Kwak, Thomas E. Mallouk,
Hiroshi Kageyama
14:00 – 706. Room temperature synthesis
and luminescence properties of whitelight-emitting vanadate phosphor,
RbVO3. Kenji Toda*, Ayano Toda,
Kazuyoshi Uematsu, Tadashi Ishigaki,
Mineo Sato
14:20 – 707. Temperature and composition
dependent phase transitions in the
fresnoite family. Siegbert Schmid*,
Patryck K. Allen
14:50 – 708. Radiation response of pyrochlore and defect fluorite compounds.
Gregory Lumpkin*, Karl Whittle,
Yan Gao, Robin Grimes, Kurt Sickafus
15:20 – 709. Time-resolved, in situ diffraction studies of chemical syntheses.
Dermot O’Hare*, Saul Moorhouse,
Gareth Williams, Michael Drakopoulos
15:40 – 710. Electron microscopy investigations of complex oxides. Tom Vogt*
16:00 – 711. Operational Angstonautics: Using the pair-distribution-function approach to study materials in-situ.
Peter J. Chupas*, Karena W. Chapman
Hilton
Kahili I/II
Olefin Oligomerization and Polymerization
Catalyzed by Early Transition Metals (#22)
Organized by: K. Theopold, K. Mashima,
Z. Xie
Presiding: K. Mashima
12:30 – 712. Stereospecific copolymerization of styrene and isoprene with polar
monomers by rare-earth metal catalysts.
Zhaomin Hou*
13:10 – 713. 1,3-Diene polymerization with
single-component rare-earth metal catalysts. Reiner Anwander*, H. M. Dietrich,
Melanie Zimmermann,
Christoph Schädle, Karl W. Törnroos,
Cäcilia Maichle-Mössmer
13:50 – 714. Group 4 metallacarboranes and
their behavior in ethylene polymerization.
Zuowei Xie*
14:30 – 715. Rare earth metal catalysts for
the generation of biopolymers and polycis-1,4-butadiene. Peter W. Roesky*
15:10 – 716. Imidazolin-2-imides and imidazolin-2-imines: Ligands with superbasic
N-donor groups. Matthias Tamm*
15:50 – 717. Controlled benzylation of ␣-diimine ligands leading to mono- and
bis(amido)M(CH2Ph)n (n ⫽ 2, 3) complexes as catalyst precursors for polymerization of ␣-olefins. Hayato Tsurugi*,
Ryuji Ohnishi, Hiroshi Kaneko,
Tarun K. Panda, Kazushi Mashima
Hilton
Hibiscus I/II
Functional Molecule-Based Magnets (#25)
Organized by: M. Yamashita,
G. Christou, J. Miller, K. Murray,
T. Sugawara, R. Thompson
Presiding: G. Christou, H. Oshio
12:30 – 718. Metal complexes with multiple
bistability. Hiroki Oshio*
13:00 – 719. Building block approaches for
tuning magnetic and optical bistability.
Yuanzhu Zhang, Dongfeng Li,
Rodolphe Clérac*, Marguerite Kalisz,
Corine Mathonière*,
Stephen M. Holmes*
13:20 – 720. Room temperature spin crossover and LIESST behaviour in dinuclear
Fe(II) metallo-helicates and related species. Paul E. Kruger*, Rosanna Archer,
Alan Ferguson, Wolfgang Schmitt,
Diane Pelleteret, Ian McKeogh,
Rodolphe Clérac, Etienne Harte,
Corine Mathonière
13:40 – 721. Guest-induced magnetic
switching in porous spin-crossover coordination polymers. Masaaki Ohba*,
Ko Yoneda, Ryo Ohtani, Ana B. Gaspar,
Jose A. Real*, Susumu Kitagawa*
14:00 – 722. Unique two-step spin crossover
in the mononuclear compound [Fe(bapbpy)(NCS)2]: Influence of temperature,
light, and pressure. Jan Reedijk
14:30 – 723. Soft metal complexes with multifunction. Shinya Hayami*
14:50 – 724. Jahn-Teller effect in cobalt(II)
spin-crossover molecular building blocks:
A theoretical study. Gergely Juhasz*,
Kazunari Yoshizawa
15:05 – 725. Giant negative magnetoresistance effect in phthalocyanine-based
magnetic conductors. Tamotsu Inabe*,
Toshio Naito, Hiroyuki Tajima,
Noriaki Hanasaki, Masaki Matsuda
15:20 – 726. Hybrid magnetic superconductors by chemical design.
Eugenio Coronado*,
Magdalena Makarewicz,
Carlos Martí-Gastaldo,
Efrén Navarro-Moratalla,
Helena Prima-García, Antonio Ribera,
Juan P. Ruiz-Prieto
15:50 – 727. Covalent-bonded donor/acceptor assemblies: Control of charge-transfer
for the design of synergistic magnetic/
conducting materials. Hitoshi Miyasaka
16:10 – 728. Ferroelectricity in magnetic
[Ni(dmit)2] salts. Tomoyuki Akutagawa*,
Takayoshi Nakamura
Hilton
Lehua Suite
Organo-f-Element Compounds: From Novel
Chemical Transformations to Applications
in Catalysis and Materials Science (#46)
Organized by: F. Edelmann, D. Berg,
G. Deacon, Z. Hou, J. Kiplinger
Presiding: R. Kempe, M. Gardiner
12:30 – 729. Lanthanide complexes containing borabenzenes: Synthesis, structures
and reactivities. Peng Cui,
Yuanyuan Yuan, Yaofeng Chen
13:00 – 730. Extended lanthanide sandwich
complexes. Anja Edelmann,
Volker Lorenz, Cristian G. Hrib,
Frank T. Edelmann*
13:20 – 731. New coordination polymers and
coordination oligomers of the rare earth
elements. Peter W. Roesky*
13:50 – 732. Steric effects in solvent mediated reversible Sm(III)/Sm(II) processes
and ligand-based reduction chemistry.
Michael G. Gardiner*
14:20 – 733. Reductive transformations of
carbon oxides by uranium(III) mixed
sandwich complexes. Geoff Cloke*,
Alistair Frey, Owen Summerscales,
Peter Hitchcock, Martyn Coles,
Robin Blagg, Jennifer Green,
Georgina Aitken, Laurent Maron
14:50 – 734. Carbon dioxide activation and
functionalization chemistry at reactive
uranium coordination complexes.
Karsten Meyer*
15:20 – 735. New uranium chemistry with
uranium-metal bonds.
Stephen T. Liddle*,
Benedict M. Gardner, Dipti Patel,
John Stewart, David P. Mills,
David M. King, Andrew D. Cornish,
Jonathan McMaster, William Lewis,
Alexander J. Blake
15:40 – 736. Living and catalytic polymerizations of naturally renewable butyrolactone-based vinyl monomers by lanthanide catalysts. Garret M. Miyake,
Stacie E. Newton, Wesley R. Mariott,
Eugene Y. Chen*
16:00 – 737. Reactivity of high-valent uranium alkyls. Trevor Hayton, Skye Fortier
Hilton
South Pacific I
Chemistry of Sulfur-Bridged Multimetallic
Complexes (#96)
Organized by: T. Rauchfuss, G. Jin,
T. Matsumoto, Y. Mizobe
Presiding: T. Rauchfuss
12:30 – 738. Thiolate-bridged dinuclear Fe(CO)x(CN)y-Ni complexes (x,y ⫽3,0; 2,2;
1,2) modelling the active site of [NiFe] hydrogenase. Kazuyuki Tatsumi*,
Yasuhiro Ohki, Zilong Li, Soichiro Tanino,
Kazunari Yasumura, Masaru Ando,
Satoko Shimokata
13:05 – 739. Electron and proton transfers in
diiron organometallic complexes related
to the hydrogenases.
Frederic Gloaguen*,
Jean-François Capon,
Philippe Schollhammer, Jean Talarmin
13:40 – 740. Substituent effects on the electrochemistry of [FeFe]-hydrogenase active site mimics and the catalytic reduction of protons to molecular hydrogen.
Dennis L. Lichtenberger*,
Richard S. Glass, Dennis H. Evans
14:15 – 741. Electron extraction from hydrogen. Seiji Ogo*
14:50 – 742. Influence of sulfoxygenation on
the properties of dithiolato-bridged biomimetics of the [fefe]-hydrogenase active
site. Marcetta Y. Darensbourg*, Bin Li,
Tianbiao Liu, Michael B. Hall,
Michael L. Singleton
15:25 – 743. Proton-hydride diiron dithiolate
complexes and their reactivities relevant
to the enzymatic hydrogen formation and
uptake at the FeFe-hydrogenase active
site. Mei Wang*, Ning Wang, Lin Chen,
Ping Li, Fujun Wang, Licheng Sun
16:00 – 744. Organometallic hydrides as
structural and functional analogs of the
active sites of the hydrogenases.
Thomas B. Rauchfuss, Bryan E. Barton,
Matthew T. Olsen, David Schilter
Hilton
Rainbow III
Advances in Metal-Mediated Bond
Activation: From Unusual Bonding Motifs to
Applications in Catalysis (#146)
Organized by: K. Caulton, S. Komiya,
M. Stradiotto
Presiding: M. Hirano
12:30 – 745. Isolation and reactivity of latent
low coordinate cationic rhodium PNP pincer compounds. Adrian B. Chaplin,
Andrew S. Weller*
12:50 – 746. Syntheses and properties of
group 9 metal PBP-pincer complexes.
Makoto Yamashita*, Maki Hasegawa,
Segawa Yasutomo, Kyoko Nozaki*
13:10 – 747. Reactivity control by an electron rich pincer ligand.
Kenneth G. Caulton*,
Nikolay P. Tsvetkov, Jose Andino,
Tao He, Alice Hui, Rene Buell, Maren Pink
13:30 – 748. Synthesis of phosphaosmocenes and their reactions with acyl
electrophiles: C⫽O cleavage and C-C
coupling within metal-coordination
sphere. Masamichi Ogasawara*,
Minoru Shintani, Susumu Watanabe,
Kiyohiko Nakajima, Tamotsu Takahashi*
13:50 – 749. Properties of rhodium chalcogenolato complexes bearing hydrotris(pyrazolyl)borato ligand and application to activation of small molecules.
Hidetake Seino*, Yoshiyuki Misumi,
Yoshihiro Hojo, Yasushi Mizobe
14:10 – 750. Competitive oxidative addition
of C-H, C-O, and other C-X bonds in (PNP)Rh complexes. Oleg Ozerov*,
Yanjun Zhu, Sylvain Gatard,
David E. Herbert,
Panida Surawatanawong,
Justin R. Walensky
14:30 – 751. C-H bond functionalization with
carboxylato-ruthenium(II) catalysts.
Pierre Dixneuf*, Percia Arockiam,
Cedric Fischmeister, Christian Bruneau
14:50 – 752. Novel reactions and intermediates in titanocene chemistry: Intramolecular 1,5-␴ bond metathesis via ␧-agostic
interactions, a highly novel, non-fluxional
␤-agostic alkyltitanocene complex.
Michael C. Baird*, Francoise Sauriol,
Alexandre F. Dunlop-Briere,
Jessica F. Sonnenberg,
Sarah J. Chadder, Peter H. Budzelaar
15:10 – 753. Reaction of hetero-nickelacycles with AlMe3: Formation of heteroaluminacycles. Masato Ohashi
15:30 – 754. Sterically demanding “umbrella” ligands for the stabilization of low
coordinate bonding environments.
Eric Rivard*, Ibrahim Al-Rafia,
Paul Lummis, Robert McDonald,
Michael J. Ferguson
15:50 – 755. Hydrogen atom abstraction by
an iron(III) imido complex.
Ryan E. Cowley, Nathan A. Eckert,
Patrick L. Holland*
16:10 – 756. Novel metathesis reaction of
hydrocarbyl ligands across triruthenium
plane. Atsushi Tahara*, Toshiro Takao,
Hiroharu Suzuki
Hilton
Coral I
Molecular Design in Bioinorganic
Chemistry (#173)
Organized by: T. Hayashi, D. Goldberg,
P. Kennepohl, H. Masuda
Presiding: T. Hayashi, P. Farmer
12:30 – 757. De novo designed Zn(II) metallohydrolases. Vincent L. Pecoraro*,
Melissa Zastrow, Anna Peacock
13:10 – 758. Rational design of functional
metalloproteins: Beyond the primary coordination sphere. Yi Lu*,
Nicholas M. Marshall, Kyle D. Miner,
Siu Yee New, Arnab Mukherjee
13:40 – 759. Coordination chemistry in protein cages. Yoshihito Watanabe*
14:10 – 760. Artificial metalloenzymes based
on the incorporation of a metal moiety
within a protein scaffold: Recent advances and challenges.
Thomas R. Ward*
14:40 – 761. How HpNikR recognizes DNA:
Metal ion requirements and DNA sequence selectivity. Sarah L. Michel,
Abby West, Sarah Evans
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–79
02-INOR
15:10 – 762. Modification of hemoproteins
by heme-substitution. Takashi Hayashi*,
Takashi Matsuo, Akira Onoda
15:40 – 763. Heme-modified proteins as biosensors of HNO. Patrick Farmer*,
Murugaeson R. Kumar*, Tara Clover
16:10 – 764. Design of mononuclear nonheme-iron enzymes with novel reactivities. Grit D. Straganz*,
Cornelia Konstantinovics,
Cristiana Di Giuro
Hilton
Tapa III
Electron Transfer and Electrochemistry of
Transition Metal Containing Inorganic and
Organometallic Materials (#187)
Organized by: H. Nishihara,
A. Abd-El-Aziz, P. Harvey, B.Z. Tang
Presiding: H. Nishihara
12:30 – 765. Giant dendritic molecular batteries. Didier Astruc, Catia Ornelas,
Rodrigue Djeda, Jaime Ruiz
12:55 – 766. Synthesis and electrochemical
behavior of organic-shell/inorganic-core
hybrid nanoparticles prepared by wet
processing. Mami Yamada*
13:20 – 767. Regeneration of oxidized photosensitizers: Quantum- chemical portray
of a general mechanism.
Timofei Privalov*, Jonas Nyhlen,
Gerrit Boschloo, Anders Hagfeldt,
Lars Kloo
13:40 – 768. Toward tuneable electrochemiluminescence. Conor F. Hogan*,
Reshmi Kiran, Ellen Reid, Sarah Laird,
Gregory Barbante
14:00 – 769. New special pair model comprising meso-di-p-anisylaminoporphyrin:
Enhancement of visible-light absorptivities and quantification of electronic communication in the mixed-valent cation
radical. Ryota Sakamoto*,
Michihiro Nishikawa, Shoko Kume,
Hiroshi Nishihara
14:20 – 770. Multifunctional coordination
complexes with redox active ligands derived from TTFs: Conductivity, magnetism, and luminescence.
Lahcene Ouahab*
14:45 – 771. Synthesis and electron transfer
processes of redox-active macrocyclic
clusters. Masaaki Abe*, Atsushi Inatomi,
Yoshio Hisaeda
15:05 – 772. Electron tunneling in FeS proteins: Respiratory complex I of electron
transport chain. Alexei Stuchebrukhov*,
Tomoyuki Hayashi
15:25 – 773. Studies of intramolecular electron transfer in ligand bridged bimetallic
complexes: From spectroelectrochemistry to TD-DFT. Paul J. Low*
15:45 – 774. Group 8 metal complexes with
pendant oligothiophene ligands for light
harvesting applications.
Stephanie A. Moore*, Saeid Kamal,
Michael O. Wolf, Brian O. Patrick
16:05 – 775. Electro-, photo-, and magnetofunctionalization of metalladithiolenes.
Hiroshi Nishihara*
16:25 Closing remarks
Hilton
Rainbow II
Redox Redux: The Renaissance of NonInnocent Ligand Complexes (#217)
Organized by: J. Soper, S. Colbran,
R. Hicks
Presiding: T. Betley
12:30 – 776. Non-innocent behavior of aryldicyanamide bridging ligands.
Robert J. Crutchley*, Serge I. Gorelsky,
Wolfgang Kaim, Biprajit Sarkar
12:50 – 777. Alkene addition and reactivity
with oxidized metal thiolates.
Craig Grapperhaus*, Kagna Ouch,
Rajat Chauhan, Mark S. Mashuta
13:20 – 778. Linking the making and breaking of bonds to electron transfer reactions
of diarylaminoaryloxide ligands.
Seth N. Brown*
80 –TECH
TECHNICAL PROGRAM
13:50 – 779. Redox-active ligand systems
that display base-dependent nuclearity.
Cora E. MacBeth, Savita K. Sharma,
Philip S. May
14:20 – 780. Reactivity behavior of metal
complexes supported by chelated-ferrocene ligands. Paula L. Diaconescu*
14:50 – 781. Multi-electron reactivity from
redox-active-ligand complexes of electrophilic transition metals. Alan Heyduk*
15:20 – 782. Bis(imino)pyridine iron and cobalt imide, nitride and oxo chemistry: Importance of a redox-active chelate.
Paul Chirik*
15:50 – 783. Redox-active ligands facilitate
coupling reactions at square planar manganese, iron and cobalt. Jake D. Soper*
Hilton
Rainbow I
Fundamental and Applied Inorganic
Fluorine Chemistry and Their Impacts on
Energy Conservation and the Environment
(#249)
Organized by: R. Hagiwara,
K. Matsumoto, H. Mercier,
G. Schrobilgen, R. Syvret
Presiding: R. Hagiwara, K. Matsumoto
12:45 – 784. Ionic liquids based electrolytes
for application in Li-ion batteries and dye
sensitized solar cells.
Nikolai V. Ignat’ev*, Michael Schmidt,
Will R. Pittner, Michael Schulte,
Kentaro Kawata, Hiromi Shinohara,
Peer Kirsch, Jan A. Sprenger,
Peter Barthen, Maik Finze, Walter Frank,
André Wenda, Eduard Bernhardt,
Helge Willner
13:15 – 785. On the way to improved polymer electrolyte membrane materials:
Preparation and handling of tetrafluoroethylene (TFE) in an academic laboratory.
Todd S. Sayler, Alfred Waterfeld,
Richard E. Fernandez,
Joseph S. Thrasher*
13:45 – 786. OCF3 containing compounds:
Promising building blocks.
Karsten Koppe*, Thorsten Meier,
Vural Bilir, Walter Frank*,
Nikolai V. Ignat’ev*
14:05 – 787. 2,2-Difluoro-1,3-dimethyl-imidazolidine (DFI) and its analogs as fluorinating and carbene (NHC) transfer reagents. Gerd-Volker Roeschenthaler*,
Tobias Boettcher
14:25 – 788. Synthesis and characterization
(C2F5)3BCO and (C3F7)3BCO.
Michael Gerken*, Gottfried Pawelke,
Helge Willner*
14:45 – 789. Recent synthetic and structural
developments in krypton and xenon
chemistry: Coordination complexes of
NgF2 (Ng ⫽ Kr, Xe), new Xe-N bonds, a
hydroxyl-derivative of Xe(IV), and the first
noble-gas cations stabilized by metal oxide fluoride anions.
Gary J. Schrobilgen*, David S. Brock,
Michael J. Hughes, Gregory L. Smith,
Johnathan Casalis de Pury,
Helene P. Mercier
15:15 – 790. Reliable prediction of molecular
properties of fluorinated inorganic compounds. David A. Dixon*
15:45 – 791. Investigation of novel inorganic
species by matrix-isolation spectroscopy
and state-of-the-art quantum-chemical
calculations. Sebastian Riedel
16:05 – 792. Strategies and experimental results to obtain organyliodine hexafluoride
molecules. Hermann-Josef Frohn*,
Vadim V. Bardin
16:25 Concluding remarks
Hilton
Nautilus I & II
Organoboron, Organosilicon and
Organophosphorus as Optoelectronic and
Energy-related Materials (#35)
Organized by: S. Wang, F. Jaekle,
Y. Wang, S. Yamaguchi
Presiding: T. Marder
13:00 – 793. Organoborane-functionalized
conjugated oligomers and polymers.
Haiyan Li, Pangkuan Chen,
Frank Pammer, Frieder Jaekle
13:30 – 794. Phenol-pyridine boron and beryllium complexes with luminescent and
semiconducting properties. Yue Wang
14:00 – 795. Mainchain-type organoboron
polymers: Synthesis and photoluminescence properties. Yoshiki Chujo*
14:30 – 796. Synthesis of benzophosphole
derivatives and their utility as n-type material for organic semiconducting devices.
Hayato Tsuji*, Kosuke Sato,
Yoshiharu Sato, Eiichi Nakamura*
14:50 – 797. Multiply bonded low coordinate
phosphorus in pi-conjugated materials.
John Protasiewicz*
15:20 – 798. Boron-containing ␲-electron
materials. Shigehiro Yamaguchi*
15:50 – 799. Dithienophospholes for organic
photovoltaics. Thomas Baumgartner*
811. Silicon based inorganic/organic hybrid
materials for highly efficient deep blue
phosphorescent OLEDs.
Kyung-Ryang Wee, Ju-Eun Kim,
Ae-Li Kim, Soonnanm Kwon,
Sang Ook Kang*
812. Toward optically innocent ligands in ruthenium acetylides. Adam Barlow,
Marie P. Cifuentes, Mark G. Humphrey
813. Organoplatinum(II) complexes with
chromophore-acceptor dyad studied by
ultrafast time-resolved absorption spectroscopy. Siu-Wai Lai, Yong Chen,
Wai-Ming Kwok, Xi-Juan Zhao,
Wai-Pong To, Wen-Fu Fu*,
Chi-Ming Che*
Hilton
Sea Pearl III/IV
Organized by: B. Kennedy,
Y. Shimakawa, P. Woodward
Presiding: P. Woodward
Schiff Base Macrocycles and Materials
(#60)
Organized by: M. MacLachlan,
S. Brooker, C. Lee
Presiding: C. Lee
13:00 – 800. Catechol-imines as ligands for
the self-assembly of helicates and metallosupramolecular tetrahedra.
Markus Albrecht*
13:30 – 801. Oligopyrrole Schiff base macrocycles. Jonathan L. Sessler*
14:00 – 802. Shape-persistent multinuclear
(Pt-salphen)n luminophores as phosphorescent coordination architectures.
Michael C. Chan*, Zhengqing Guo,
Wah-Leung Tong
14:30 – 803. Effect of zinc(II) on the synergistic extraction and luminescence of europium(III) with ␤-diketone and Schiff
bases as ligands. Sayaka Tamaki,
Koji Tsuchiya, Hirofumi Yajima*
15:00 – 804. Shape Schiffting: Using imine
chemistry to construct macrocycles with
unusual geometries. Samuel Guieu,
Mark J. MacLachlan*
15:30 – 805. Manipulation of small molecules within well-defined macrocyclic
Pacman environments. Jason Love*,
Aline Devoille, James Leeland,
Polly Arnold, Elham Askarizadeh,
Sahar Bani Yaghoob
16:00 – 806. Imino-and aminopyrrolic synthetic receptors for molecular recognition
of carbohydrates: A new entry in the
Schiff base chemistry. Stefano Roelens*
Friday Evening
Convention Center
Kamehameha Halls II and III
Molecular Photonics (#9)
Organized by: F. Castellano, T. Majima,
V.W. Yam
Presiding: F. Castellano
Poster Session
19:00 – 21:00
807. Metal-containing oligo(phenyleneethynylene)s: Syntheses and nonlinear optical
properties. Mark G. Humphrey*,
Marie P. Cifuentes, Marek J. Samoc,
Bandar A. Babgi, Gulliver T. Dalton,
Luca Rigamonti
808. New cationic iridium(III) complexes containing two phenylpyridine based ligands
and one diphosphine ligand for highly efficient organic light-emitting diodes.
Young-Inn Kim, Hoe-Joo Seo,
Myungkwan Song, Young-Kwan Song,
Sung-Ho Jin
809. Synthesis and characterization of
Gold(I) and Platinum(II)-tetracenyl complexes. Minh Hai Nguyen, John H. Yip*
810. Photophysical and photochemical
properties of nanosized metal-organic
frameworks. Takashi Tachikawa*,
Jun Rye Choi, Mamoru Fujitsuka,
Tetsuro Majima
Hilton
Coral II
Controlling the Structure and Properties of
Solids (#20)
19:00 – 814. Ternary rare-earth arsenides.
Stanislav S. Stoyko, Peter E. Blanchard,
Arthur Mar*
19:30 – 815. First order phase transition in
Cu and Co molybdates: Applications to
thermochromism and piezzochromism.
Alain Demourgues, Penin Nicolas,
Robertson Lionel, Gaudon Manuel
19:50 – 816. Extreme volume expansion observed in a small-pore zeolite.
Yongjae Lee*
20:10 – 817. Structural and magnetic transitions in SrRu1-xCuxO3.
Brendan Kennedy*, Jimmy Ting,
Zhaoming Zhang
20:30 – 818. Rietveld analysis of deuteriumsubstituted oxy-hydroxyapatite using
neutron diffraction. Hirotaka Fujimori*,
Kensuke Morita, Keisuke Okanishi,
Kenji Oyama, Masatomo Yashima
Hilton
Nautilus I & II
Organoboron, Organosilicon and
Organophosphorus as Optoelectronic and
Energy-related Materials (#35)
Organized by: S. Wang, F. Jaekle,
Y. Wang, S. Yamaguchi
Presiding: T. Matsuo
19:00 – 819. Development of bulky Rind
groups having longer alkyl chains for soluble ␲-conjugated disilene oligomers.
Liangchun Li*, Daisuke Hashizume,
Takeo Fukunaga, Tsukasa Matsuo*,
Kohei Tamao*
19:20 – 820. Borenium cations with first row
p-block substituents.
Catherine Bonnier*, Warren E. Piers,
Masood Parvez
19:40 – 821. Synthesis of dithienobismoles
as novel phosphorescence materials.
Joji Ohshita*, Shigenori Matsui,
Tomonobu Mizumo
20:00 – 822. Synthesis and characterization
of dithienosilole derivatives and their application to Organic Light-Emitting Diodes(OLEDs). Eunji Lee, Narae Jung,
Jinho Kim, Youngjin Kang*,
Hyoungkeun Park
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
20:20 – 823. Reactivity of 1-chloro-2,3,4,5tetraphenylborole. Johannes Wahler,
Holger Braunschweig
Convention Center
Kamehameha Halls II and III
Organo-f-Element Compounds: From Novel
Chemical Transformations to Applications
in Catalysis and Materials Science (#46)
Organized by: F. Edelmann, D. Berg,
G. Deacon, Z. Hou, J. Kiplinger
Presiding: F. Edelmann
Poster Session
19:00 – 21:00
824. Lanthanide alkyl complexes supported
by a piperazidine-bridged bis(phenolato)
ligand: Synthesis, characterization, and
catalysis for the controlled polymerization
of L-lactide. Yingming Yao, Yunjie Luo,
Dan Lin, Wenyi Li, Yong Zhang, Qi Shen
825. New lanthanide sandwich complexes
with bulky cyclooctatetraenyl ligands.
Anja Edelmann, Cristian G. Hrib,
Frank T. Edelmann*
826. Trivalent and divalent lanthanide complexes supported by carbazole-bis(oxazoline) ligands. David Berg*, Jin Zou
827. Reactivity of diamido-actinide organometallic complexes.
Cassandra E. Hayes, Daniel B. Leznoff*
828. Reactivity of sterically crowded non-Cp
organolutetium complexes: A synthetic
and kinetic investigation.
Kevin R. Johnson, Paul G. Hayes*
829. Novel cyanoporphyrazine ytterbium
complexes for potential optoelectronic,
photonic and biophotonic applications.
Ilya Grigoryev*, Larisa Klapshina,
Svetlana Lermontova, Andrey Lukyanov
830. Scandium-catalyzed copolymerization
of non-conjugated dienes with styrene
and ethylene. Masayoshi Nishiura,
Fang Guo, Zhaomin Hou*
831. Synthesis and characterization of xerium(III)/(IV) and yttrium (III) salfen and
phosfen alkoxide complexes.
Erin Broderick*, Paula Diaconescu
832. Yttrium hydride clusters bearing mono(pentamethylcyclopentadienyl) ligands.
Takanori Shima, Masayoshi Nishiura,
Zhaomin Hou*
833. New ligand for actinide(III)/lanthanide(III)
separation. Denise Girnt*,
Peter Roesky*, Andreas Geist*,
Melissa A. Denecke*
834. Homoleptic all nitrogen coordinated
rare earth complexes: Potential precursors for the MOCVD of rare earth nitride
thin films. Tobias Thiede*,
Michael Krasnopolski, Andrian Milanov,
Anjana Devi, Roland A. Fischer*
835. Trends and inconsistencies in the
bonding modes observed in a series of
lanthanide and actinide complexes with
unsupported metal-metal bonds.
Stefan G. Minasian, Jamin L. Krinsky,
John Arnold*
836. Extremely rigid non-cyclopentadienyl ligands for the development of thorium
and uranium organometallic and redox
chemistry. David J. Emslie*,
Carlos A. Cruz,
Balamurugan Vidjayacoumar,
Sougandi Ilango, Terry Chu
Convention Center
Kamehameha Halls II and III
Advances in Metal-Mediated Bond
Activation: From Unusual Bonding Motifs to
Applications in Catalysis (#146)
Organized by: K. Caulton, S. Komiya,
M. Stradiotto
Presiding: K. Caulton
Poster Session
19:00 – 21:00
837. Identification of near-linear agostic interactions in the complexes
[{M(CpSiMe2H)Cl3}2] (M ⫽ Ti, Zr, Hf and
Mo). Al Nielson*, John Harrison,
Matthias Lein
838. Phosphine-tethered cyclic and acyclic
carbenes: Template synthesis and reactivity. Insun Yu, Christopher J. Wallis,
Parisa Mehrkhodavandi*
839. Synthesis and reactivity of boron-based
pincer ligand complexes. Rong Shang*,
Anthony F. Hill, James Park,
Suprita K. Singh
840. Synthesis and reactivity of linked phosphino-borinate ester frustrated Lewis
pairs. Andy Chapman*, Duncan Wass
841. Application of new heterobidentate ligands in hydroamination catalysis employing late transition metal complexes.
Mark Stradiotto*
842. Carbon-nitrogen bond cleavage in
o-acylanilines on ruthenium complexes
and its relevance to catalytic coupling reactions with organoboronates.
Tetsuro Koreeda, Takuya Kochi,
Fumitoshi Kakiuchi*
843. P-C reductive elimination from organopalladium(II) phosphine complexes.
Masayuki Wakioka, Fumiyuki Ozawa*
844. sp3 Carbon-hydrogen bond cleavage
reaction in 5-coordinated (2,6-dimethylbenzenethiolato)- and (2,6-dimethylphenoxo)ruthenium(II) complexes.
Masafumi Hirano*, Sayaka Togashi,
Muneaki Ito, Yasuto Yanagisawa,
Nobuyuki Komine, Sanshiro Komiya
845. Mechanical stirring can control the selectivity of palladium-catalyzed allylation
in water/hexane biphasic media.
Sanshiro Komiya*
846. Synthesis of the bis(vinylidene)-bridged
dinuclear complexes via internal alkyneto-vinylidene isomerization.
Rina Nakamura, Yousuke Ikeda,
Yuichiro Mutoh, Youichi Ishii*
847. Isomerization involving C-H bond cleavage promoted by Lewis and Brønsted acids in (2-Allylaryloxo)ruthenium(II) complex. Masahiro Murakami,
Toshinori Kuga, Nobuyuki Komine,
Masahumi Hirano*, Sanshiro Komiya*
848. Palladium-catalyzed cycloisomerization
of 2-(cyanomethyl)phenyl esters leading
to 3-acyl-2-aminobenzofurans.
Masahito Murai*, Kouichi Ohe
849. New palladium(II) complexes for ligand
enabled CH and O2 activation at a single
metal center. Andrei Vedernikov*,
Dao-Yong Wang
850. Reversibility of disubstituted vinylideneinternal alkyne isomerization at cationic
ruthenium complexes. Kohei Imai,
Yusuke Kimura, Yuichiro Mutoh,
Youichi Ishii*
851. C-H and C-F bond activation by Ni(0)
complexes: Does phosphine size matter?
Jillian Hatnean, Samuel A. Johnson*
852. Pyridyl pyrrolides as redox-active ligands. Kenneth G. Caulton*,
Jose Andino, Jaime Flores,
Joseph Massa, Nikolay P. Tsvetkov,
Robert Wolfe, Hyunsoo Park, Maren Pink
853. Synthesis and reactivities of C-N chelating pyrazole-iridium complex and its
application to catalytic intramolecular hydroamination. Yohei Kashiwame,
Shigeki Kuwata, Takao Ikariya*
Hilton
Coral I
Molecular Design in Bioinorganic
Chemistry (#173)
Organized by: T. Hayashi, D. Goldberg,
P. Kennepohl, H. Masuda
Presiding: D. Goldberg, P. Holland
19:00 – 854. Dinuclear nickel complexes
modeling of the active site of acetyl CoA
synthase: A mechanistic insight.
Tsuyoshi Matsumoto*, Mikinao Ito,
Kazuyuki Tatsumi
19:30 – 855. High-spin iron hydrides of relevance to nitrogenase mechanism.
Karen P. Chiang, Keying Ding,
Thomas R. Dugan, Azwana Sadique,
Eckhard Bill, William W. Brennessel,
Patrick L. Holland*
20:00 – 856. Long and winding road: The
search for a synthetic analog of the photosynthetic {Mn4CaOx} oxygen-evolving
complex (OEC). George Christou*
20:30 – 857. Bio-inspired polyporphyrin assemblies for various accessories in photosystems and their related antennas.
Pierre D. Harvey*, Roger Guilard
Convention Center
Kamehameha Halls II and III
Redox Redux: The Renaissance of NonInnocent Ligand Complexes (#217)
Organized by: J. Soper, S. Colbran,
R. Hicks
Presiding: J. Soper
Poster Session
19:00 – 21:00
858. Synthesis and reactivity of chromium
diimine alkoxide complexes.
Kevin M. Smith*, Wen Zhou
859. Withdrawn
860. Redox regulated binding of alkenes to
rhenium thiolates. Craig Grapperhaus*,
Kagna Ouch, Mark S. Mashuta
861. Synthesis and characterization of tri-nuclear cobalt mix-valence complex with
2,3,6,7,10,11-hexahydroxytriphenylene.
Yusaku Suenaga*, Yukiko Umehata,
Toshie Minematsu
862. Alkene addition to a Ru-coordinated
thiyl radical: Synthesis by chemical oxidants and reactivity studies.
Rajat Chauhan, Mark S. Mashuta,
Craig Grapperhaus*
863. Molecular structures and physicochemical properties of novel multinuclear molybdenum complexes with redox active ligands. Hirokazu Yano,
Takeshi Matumoto, Ho-Chol Chang,
Atsushi Kobayashi, Masako Kato*
864. Synthesis and electrochemical behavior
of tetraammineruthenium complexes of
quinonoid with N, O-coordination.
Ippei Umemura, Tomohiko Hamaguchi,
Satoshi Kawata, Isao Ando*
865. Preparation and physical properties of
cobalt complex bridged by redox-active
ligand. Akihiko Nobukuni, Osamu Sato,
Shinji Kanegawa
Convention Center
Kamehameha Halls II and III
Fundamental and Applied Inorganic
Fluorine Chemistry and Their Impacts on
Energy Conservation and the Environment
(#249)
Organized by: R. Hagiwara,
K. Matsumoto, H. Mercier,
G. Schrobilgen, R. Syvret
Presiding: H. Mercier, G. Schrobilgen,
R. Syvret
Poster Session
19:00 – 21:00
866. Fluorine diffusion assisted by diffusing
silicon on Si(111)-(7x7). Satoko Kuwano,
Yasunori Fujikawa, Koji S. Nakayama,
Tadaaki Nagao, Jurek T. Sadowski,
Raouf Z. Bahktizin, Toshio Sakurai*
867. Effect of the nature of glass matrix on
the lifetime of the fluorescence of terbium
containing oxide fluoride glasses.
Fumihiro Nishimura, Jae-ho Kim,
Susumu Yonezawa, Masayuki Takashima
868. Inorganic fluorine chemistry in Bordeaux: From the synthesis to thermal stability investigations of (nano)fluorides.
Etienne Durand*, Alain Demourgues,
Alain Tressaud
869. Preparation of Nd2Eu2O3F6 thin film on
porous alumina substrate.
Ryushin Shiun, Jae-ho Kim,
Susumu Yonezawa, Yasuo Hasegawa,
Masayuki Takashima
870. Manganese dissolution behavior from
of surface fluorinated LiMn2O4.
Shunsuke Murata, Jae-ho Kim,
Susumu Yonezawa,
Masayuki Takashima, Junichi Imaizumi,
Nobuharu Koshiba
871. Effects of surface fluorination of various
plastic materials on the adherence between metal and plastics.
Yusuke Maruyama, Susumu Yonezawa,
Jae-ho Kim, Masayuki Takasima,
Hajime Kiyokawa
872. Sintering and characterization of AB5
type hydrogen storage alloy powder
coated with Ni-PTFE composite film.
Akihiro Ohata, Jae-Ho Kim,
Susumu Yonezawa*,
Masayuki Takashima
873. Fabrication of binary metal oxide nanocomposites by the liquid phase deposition method using polymer solution.
Minoru Mizuhata*, Yuki Umekage,
Ramanujam Kumaresan
874. Surface fluorination of fine carbon material and its application to the material
for composite plating. Toshimasa Kubo,
Jae-ho Kim, Susumu Yonezawa*,
Masayuki Takashima
875. Highly conductive ionic plastic crystals
based on fluorohydrogenate anions.
Ryosuke Taniki*, Kazuhiko Matsumoto,
Rika Hagiwara
876. Physical and electrochemical properties
of difluorophosphate ionic liquids.
Kazuhiko Matsumoto*, Rika Hagiwara
877. Highly conductive fluorohydrogenate
liquid salts and their applications to energy conversion devices.
Rika Hagiwara*, Kazuhiko Matsumoto,
Toshiyuki Nohira, Takeshi Enomoto,
Atsushi Senda, Jia Xu
Saturday Morning
Hilton
Coral II
Controlling the Structure and Properties of
Solids (#20)
Organized by: B. Kennedy,
Y. Shimakawa, P. Woodward
Presiding: B. Kennedy
7:30 – 878. Preparation and characterization
of copper antimony oxides.
Tilo Soehnel*, Eric Rey, Ping-Zhan Si,
Neeraj Sharma, Chris Ling,
Maxim Avdeev, Bernt Johannessen
8:00 – 879. Synthesis of LiMn2O4 spinel, a
Li-ion battery cathode material, via an organic permanganate oxidation reaction.
Bart M. Bartlett*, Brendan J. Liddle,
Brendan P. Clifford
8:20 – 880. Rb16Cd25.39(3)Sb36: An electron deficient zintl phase containing infinite dodecahedron chains. Ling Chen*
8:40 – 881. Magnetism and superconductivity in layered iron-chalcogenides.
Kazuyoshi Yoshimura*, Mami Matsui,
Masatomo Kawa, Jinhu Jang,
Hiroto Ohta, Chishiro Michioka
9:00 – 882. Preparation of layered manganese oxide partially-substituted for Mn by
period-four transition metal and the application to ultra capacitor.
Takahiro Takei*, Yoshinori Yonesaki*,
Nobuhiro Kumada*, Nobukazu Kinomura*
9:20 – 883. Electrodeposition as a tool to investigate the lithiation of Cu2Sb.
Amy Prieto*, James Mosby*,
Derek Johnson*
9:50 – 884. Oxidation and reduction of oxide
thin films. Yuichi Shimakawa*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–81
02-INOR
10:20 – 885. Self-assembly of cluster based
hybrid inorganic-organic materials.
Abdou Lachgar*, Lei Chen,
Jian Jun Zhang
10:40 – 886. Electric fields in chemical vapor
deposition. Russell Binions*,
Michael Warwick
11:00 – 887. Magnetic and transport properties of chromium-based nitride solid solution thin films. Kei Inumaru*,
Satoshi Izumi, Kunihiko Koyama,
Kazuma Tanaka, Shoji Yamanaka
Hilton
Kahili I/II
Olefin Oligomerization and Polymerization
Catalyzed by Early Transition Metals (#22)
TECHNICAL PROGRAM
10:45 – 902. Spintronics based on singlemolecule quantum magnets.
Masahiro Yamashita
11:15 – 903. Construction of heterospin 1-D
complexes with a slow relaxation of the
magnetization. Satoru Karasawa,
Noboru Koga*
Hilton
Coral IV
Dioxygen Activation Chemistry and
Catalytic Oxidation Reactions (#108)
Organized by: S. Itoh, W. Nam,
A. Rosenzweig, W. Tolman
Presiding: A. Rosenzweig, S. Itoh
7:30 – 888. Mechanistic investigations of
ethylene trimerization based on chromium-pyrrole catalyst system.
Takayuki Aoshima*, Hisao Urata,
Eiji Tanaka
8:10 – 889. New ligands and activation
methods in chromium catalyzed selective
oligomerization of ethylene.
Duncan Wass*, Arminderjit Dulai
8:50 – 890. New synthetic method for generating low-valent early transition metals:
Tantalum ligand-free catalyst system for
highly selective trimerization of ethylene
affording 1-hexene. Kazushi Mashima*,
Teruhiko Saito, Hiromasa Tanahashi,
Rocío Arteaga-Müller, Hayato Tsurugi
9:30 – 891. How to solve the conundrum of
selective ethylene tetramerization?
Sandro Gambarotta*
10:10 – 892. Well-defined chromium catalysts for selective trimerization of ethylene. Klaus H. Theopold*,
Wesley Monillas, John Young,
Jingmei Shen, Glenn Yap
10:50 – 893. Zirconium-mediated linear
alkyne coupling and its application.
Tamotsu Takahashi*
7:30 Opening remarks
7:35 – 904. Oxidation of methane by a biological dicopper center.
Ramakrishnan Balasubramanian,
Stephen M. Smith, Swati Rawat,
Megen A. Culpepper, Liliya A. Yatsunyk,
Timothy L. Stemmler,
Amy C. Rosenzweig*
8:10 – 905. Probing the hydrophobic pockets of metalloenzymes designed for activation of aliphatics. Steve S. Yu*,
Chun-Wei Chang, Kok-Yaoh Ng,
Li-Lan Wu, Zong-Lin Yang,
Ravirala Ramu, Sunney I. Chan
8:45 – 906. Geometric and electronic structure contributions to Cu/O2 reactivity.
Edward I. Solomon
9:20 – 907. Using synthetic chemistry to understand dioxygen activation by copper
protein active sites. William B. Tolman*
9:55 – 908. Phenolate hydroxylation by simple side-on-peroxide copper complexes:
electrophilic hydroxylation through bisoxo-bis-cu(III) species. Daniel Stack*,
Peng Kang, Pratik Verma, Erik Wasinger,
Julia Woertink, Edward Solomon
10:30 – 909. Modeling mononuclear copper
reaction centers of copper monooxygenases and copper oxidases.
Shinobu Itoh*
10:55 – 910. Copper and heme-copper dioxygen reactivity. Kenneth D. Karlin*
Hilton
Hibiscus I/II
Hilton
Coral I
Functional Molecule-Based Magnets (#25)
Molecular Design in Bioinorganic
Chemistry (#173)
Organized by: K. Theopold, K. Mashima,
Z. Xie
Presiding: Z. Xie
Organized by: M. Yamashita,
G. Christou, J. Miller, K. Murray,
T. Sugawara, R. Thompson
Presiding: B. Thompson, K. Murray
Organized by: T. Hayashi, D. Goldberg,
P. Kennepohl, H. Masuda
Presiding: P. Kennepohl, K. Yoshizawa
7:30 – 894. Iron(II) triazole complexes:
mono-, di- and tri-nuclear SCO complexes. Sally Brooker*,
Jonathan A. Kitchen, Victoria A. Milway,
Guy N. Jameson, Jeffrey L. Tallon,
Claudio Gandolfi, Martin Albrecht
8:00 – 895. Magnetic and conducting hybrid
materials from molecular building blocks.
Melanie Pilkington*
8:20 – 896. Role of delocalization in development of photomagnetic and magnetoconducting materials. Natia L. Frank*,
Bin Yan, Dooley Brynn,
Michelle Paquette, Mark Zsombor,
Jordan Cramen
8:40 – 897. Polynuclear metal clusters: from
high-spin molecules to nanoporous materials. George Christou
9:10 – 898. Structural control of the magnetic anisotropy of lanthanide based
SMMs. Takashi Kajiwara*
9:25 – 899. Lanthanide approach for highenergy barrier single-molecule magnets.
Muralee Murugesu*
9:45 – 900. Trianglar cores as building units
for new molecular magnets.
Hui-Lien Tsai*, Chen-I Yang,
Wolfgang Wernsdorfer, Shao Po Hung,
Yu-Jhe Tsai, Kai-Hung Cheng,
Motohiro Nakano, Gene-Hsiang Lee,
Ting-Shen Kuo, Minghuey Shieh
10:15 – 901. Single-molecule magnets
based on double-decker phtalocyanine
lanthanide complexes: New organizations
and properties. Jaume Veciana*
7:30 – 911. Copper coordination chemistry
and its cellular consequences.
David Kennedy, Craig McKay,
John Pezacki*
7:50 – 912. His93Gly myoglobin cavity mutant is a versatile scaffold for spectroscopic modeling of heme protein active
sites, applications to novel heme transport proteins, and oxidative enzymes.
John H. Dawson*, D. M. Indika Bandara,
Jing Du, Masanori Sono
8:30 – 913. Cytochrome P450: The active
oxidant and its spectrum.
Michael T. Green
9:00 – 914. Approaches toward the heme
electronic structure. Yoshiki Ohgo*,
Daisuke Hashizume, Yoshihisa Harada,
Mikio Nakamura
9:30 – 915. Water-assisted oxo mechanism
for the heme metabolism by heme oxygenase: A computational quantum chemical study. Kazunari Yoshizawa*
10:00 – 916. Probing reaction mechanisms
in metalloproteins using resonance Raman and rapid freeze quench techniques.
Pierre Moenne-Loccoz, Erik T. Yukl,
Takahiro Hayashi
10:30 – 917. Manganese and iron K-Beta Xray emission spectroscopy as a probe of
biological and chemical catalysis.
Serena DeBeer*
11:00 – 918. Transition metal adducts of singlet dioxygen: electronic and steric control of dioxygen spin state and reactivity.
Pierre Kennepohl*, Danielle Covelli
82–TECH
Hilton
Rainbow II
Hilton
South Pacific I
Advances in Nuclear Chemistry of
Transactinide Elements (#218)
New Frontiers in Polyoxometalate
Chemistry (#251)
Organized by: Y. Nagame, C. Duellmann,
H. Nitsche, P. Schwerdtfeger, Z. Qin
Presiding: Y. Nagame
Organized by: M. Nyman, C. Boskovic,
N. Mizuno, L. Xu
Presiding: M. Nyman
7:30 – 919. Chemistry of superheavy elements: Experimental achievements and
perspectives. Matthias Schaedel*
8:00 – 920. Synthesis of superheavy elements at FLNR. Sergey N. Dmitriev*
8:30 – 921. Heavy element studies at the
Berkeley gas-filled separator.
Kenneth E. Gregorich*
9:00 – 922. Research activites on superheavy element chemistry and physics at
Paul Scherrer Institute and Bern University. Andreas Türler*
9:30 – 923. Status and prospects of heavy
elements at IMP. Hushan Xu
10:00 – 924. Superheavy element nuclear
chemistry at RIKEN. Hiromitsu Haba*,
Daiya Kaji, Yoshitaka Kasamatsu,
Hidetoshi Kikunaga, Yukiko Komori,
Hisaaki Kudo, Yuki Kudou,
Kouji Morimoto, Kosuke Morita,
Yuichiro Nagame, Kazuhiro Ooe,
Kazutaka Ozeki, Nozomi Sato,
Atsushi Shinohara, Takayuki Sumita,
Atsushi Toyoshima, Kazuaki Tsukada,
Akihiko Yokoyama, Akira Yoneda,
Takashi Yoshimura
10:30 – 925. Preparation and characterization of actinide targets for superheavy element studies. Klaus Eberhardt*,
Christoph E. Düllmann, Jens V. Kratz,
Bettina Lommel, Jörg Runke,
Matthias Schädel
11:00 – 926. Withdrawn
7:30 – 936. Electronic and structural properties of polyoxometalates.
Josep M. Poblet*,
Antonio Rodríguez-Fortea, Xavier López,
Anna Clotet, Xavier Aparicio,
Laia Vilà-Nadal, Jorge J. Carbó
8:00 – 937. Neutral polyoxovanadate with
pendant aquo-hydroxo-copper groups.
Tomoji Ozeki*, Takahisa Koroki,
Akifumi Iida
8:20 – 938. Ranking the lacunary,
(Bu4N)9{H[␣2-P2W17O61]} polyoxometalate’s nanocluster stabilizing ability.
Richard G. Finke*
8:40 – 939. Structural topologies of uranyl
peroxide polyoxometalates.
Peter C. Burns*, Ginger Sigmon,
Daniel Unruh, Jie Ling, Tori Z. Forbes
9:00 – 940. Non equilibrium structured polyoxometalate assemblies. Leroy Cronin*
9:30 – 941. Tetraruthenium and tetracobalt
polyoxometalates as efficient homogeneous catalysts for water oxidation:
Physicochemical properties and reaction
mechanism. Yurii V. Geletii*,
Claire Besson, Qiushi Yin, Yu Hou,
Alexsey Kuznetsov,
Djamaladdin G. Musaev, Anna Proust,
Bodgan Botar, Paul Kögerler,
Craig L. Hill1*
9:50 – 942. Porous metal oxide materials
prepared using polyoxometalate.
Masahiro Sadakane*, Wataru Ueda
10:20 – 943. Self-assembly of organically
grafted polyoxometalate supramolecular
complexes. Lixin Wu
10:40 – 944. Noble metal based polyoxometalates. Natalya V. Izarova,
Maria Barsukova, Ulrich Kortz*
11:10 – 945. Chemistry of technetium-99
polyoxometalates: Understanding fundamental chemistry of technetium-99 incorporated into metal oxide matrices.
Lynn Francesconi*
Hilton
Rainbow I
Chemistry and Materials Science at High
Pressures (#239)
Organized by: Y. Song, I. Butler, Y. Lee,
R. Manaa
Presiding: Y. Song
7:30 Opening remarks
7:40 – 927. Materials chemistry under extreme conditions. Russell J. Hemley*
8:20 – 928. Structural transitions in amorphous materials at high pressure.
Jeffery L. Yarger*, Emmanuel Soignard,
Samrat Amin, Keri McKiernan
8:45 – 929. Pressure-induced bonding
changes in oxide glasses: Insights from
nonresonant inelastic X-ray scattering
and solid-state NMR. Sung Keun Lee*
9:10 – 930. Direct analysis of X-ray-induced
radiolysis effects on ferrous chloride
aqueous solutions at elevated temperatures and pressures. Alan Anderson,
Robert Mayanovic,
Naveen Dharmagunawardhane
9:35 – 931. Recent studies on the high-pressure vibrational spectra of biomaterials.
Ian S. Butler
9:55 – 932. Ab initio simulations of simple
fluids under pressure: Thermo-chemical
data and physical properties.
Giulia Galli*
10:20 – 933. First-principles studies of structural transformations in crystalline solids:
Applications of metadynamics and related methods. Dennis D. Klug,
Yansun Yao, Jian Sun, Roman Martonäk
10:45 – 934. Ab initio discovery of nanoscale
detonation in hydrazoic acid. Evan Reed*
11:10 – 935. Hydrogen bonding under highpressure. Riad Manaa*, Laurence Fried
Hilton
Sea Pearl III/IV
Nanoscale Characterization of Functional
Materials by Nuclear Probes (#275)
Organized by: K. Nomura, A. Hill,
J. Stevens, H. Wei, Y. Yamada
Presiding: K. Nomura
7:30 – 946. Moessbauer studies of Fe-As
based superconductors. Amar Nath*,
Airat Khasanov, Satish C. Bhargava
8:10 – 947. Magnetic order and superconductivity in SrFe2As2. Marek Bystran*,
Jaroslav Kohout, Karel Závěta,
Adriana Lanok
8:30 – 948. Mössbauer study of iron and iron
based compound films produced by laser
deposition. Yasuhiro Yamada*,
Ryo Usui, Yoshio Kobayashi
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
8:50 – 949. XPS and Mössbauer study on
room-temperature ferromagnetic SnO2
nanoparticles co-doped with dilute Co
and Fe ions. Jun Okabayashi*,
Kiyoshi Nomura, Kumiko Okamura,
Yasuhiro Yamada
9:10 – 950. Mossbauer and XAFS study of
Yttrium Aluminum Garnet (YAG) doped
with dilute Fe ions. Kiyoshi Nomura*,
Zoltan Nemeth*, Kenji Sakurai*,
Mari Mizusaki*
9:30 – 951. Local fields at impurity sites in
ZnO observed by the TDPAC method.
Wataru Sato*, Sayaka Komatsuda,
Yoshinori Itsuki, Yoshitaka Ohkubo
10:00 – 952. In-Field 57Fe Mössbauer spectrometry applied to Fe oxides.
Jean-Marc Greneche*
10:40 – 953. Structural change and spinstate switching triggered by sorption of
benzene molecule for the assembled iron
complex bridged by 1,3-bis(4-pyridyl)propane. Satoru Nakashima*,
Masaki Atsuchi, Katsuya Inoue
11:00 – 954. Study on the charge transfer
phase transition in iron mixed-valence
complexes, A[Fe(II)Fe(III)(dto)3](A ⫽
(CnH2n⫹1)4N, spiropyran; dto ⫽
C2O2S2) by means of muon spectroscopy and 57Fe Moessbauer spectroscopy. Masaya Enomoto*, Noriyuki Kida,
Norimichi Kojima, Isao Watanabe,
Takao Suzuki
Hilton
Rainbow III
Advances in Metal-Mediated Bond
Activation: From Unusual Bonding Motifs to
Applications in Catalysis (#146)
Organized by: K. Caulton, S. Komiya,
M. Stradiotto
Presiding: K. Caulton
7:50 – 955. Synthesis and reactivity of low
valent indenyl cobalt complexes.
Chris A. Bradley, Fernando Hung-Low
8:10 – 956. The weird and the wonderful:
Lessons from unusual nonheme nitrosyls.
Abhik Ghosh*
8:30 – 957. High oxidation state palladium
and platinum organometallics: Binuclear
species and selectivity in decomposition
of Pd(IV) phosphine complexes related to
roles in organic synthesis.
Allan J. Canty*, Manab Sharma,
Brian F. Yates, Nigel Brookes
8:50 – 958. New ligand motifs for ligand enabled CH and O2 activation at a single
metal center (Pt, Pd).
Andrei Vedernikov*, Shrinwantu Pal,
Dao-Yong Wang
9:10 – 959. Nickel phosphine compounds
and the activation of C-H bonds.
Samuel A. Johnson*, Robert Beck,
Jillian A. Hatnean
9:30 – 960. Coordinatively unsaturated
phosphaalkene complexes of 3d metals.
Fumiyuki Ozawa, Yumiko Nakajima
9:50 – 961. Identification of non-classical agostic interactions in transition metal complexes containing the CH(ArO)3 ligand.
Al Nielson*, John Harrison,
Matthias Nielson
10:10 – 962. Visible-light promoted bimetallic catalysis. Akiko Inagaki,
Munetaka Akita*
10:30 – 963. C-H activation/borylation of
arenes promoted by Cp*Fe complexes of
N-heterocyclic carbene.
Tsubasa Hatanaka, Yasuhiro Ohki,
Kazuyuki Tatsumi*
10:50 – 964. C-H bond activation, C-N bond
activation and C- to N-tautomerism in a
ruthenium N-heterocyclic carbene complex: A combined experimental and computational study. L. Jonas L. Haller,
Michael J. Page, Stuart A. Macgregor*,
Michael K. Whittlesey
11:10 – 965. Group 4 and 5 amidate complexes and their use toward catalytic
amine synthesis. Jean Michel Lauzon,
Patrick Eisenberger, Michael Fryzuk*,
Laurel Schafer*
Hilton
Nautilus I & II
Poster Session
10:00 – 12:00
Organoboron, Organosilicon and
Organophosphorus as Optoelectronic and
Energy-related Materials (#35)
980. Complex coordination networks from
back-folded dendrimers: Supramolecular
topologies and intersecting subnets.
Zhengtao Xu*, Yan-Qiong Sun,
Chen Yang, Matthias Zeller,
Allen D. Hunter
981. Bis(hemicages) as new motifs for chemosensors and molecular logic gates.
Eli Zysman-Colman*, Gabriel St-Pierre,
Daniel Fortin
982. Metal-linked molecular capsules providing large ␲-conjugated frameworks.
Norifumi Kishi, Michito Yoshizawa*,
Munataka Akita*
983. Fluorescent tetrazole-based metal-organic framework gel as chemosensor for
phosgene gas via transformation.
Hyejin Lee, Sungmin Seo Seo,
Jagadese J. Vittal, Jong Hwa Jung*
984. Precise arrangement of Ag(I) and Cu(I)
ions on disk-shaped ligands.
Junichi Furukawa, Hiraoka Shuichi,
Shionoya Mitsuhiko*
985. Structures and photoluminescence
properties of Cu(I) coordination polymers
of 2,4,6-trithiomorpholino-1,3,5,-triazine.
Hojin Yang, Garam Park, Hyunji Kim,
Tae Ho Kim, Jineun Kim*
986. Square/triangle equilibria in platinum(II)
thiacrown supramolecular complexes.
Zachary T. Perry*, Gregory J. Grant,
Rishi D. Naik, Markus Germann,
Thomas Blake
987. Solvent effects on guest exchange,
binding and encapsulated dynamics in a
supramolecular host.
Jeffrey S. Mugridge, Carmelo Sgarlata,
Robert G. Bergman,
Kenneth N. Raymond
988. Chiral symmetry breaking of metal
complex compound. Takayuki Kato*
989. Conjugation of organic-metallic hybrid
polymers and DNA for application to
DDS. Jinghua Li, Masayoshi Higuchi,
Zdenek Futera
990. Anomalous water molecules and mechanistic effects of water nanotube clusters
confined to molecular porous crystals.
Makoto Tadokoro*, Takashi Ohhara,
Takeshi Yamada, Masaharu Oguni,
Osamu Yamamuro
991. Fluorescent enhancement of tetrazolebased coordination polymer hydrogel.
Ji Ha Lee, Hyejin Lee, Sungmin Seo,
Moo Lyong Seo, Jong Hwa Jung*
992. Synthesis and complementary recognition of ␤-hairpin peptides stabilized by artificial DNA base-pairing amino acids.
Katsuhiro Isozaki*, Hikaru Takaya,
Masaharu Nakamura, Kazushi Miki
993. Conformation conversion from bowl to
chiral capsule and C-Hѧanion hydrogen
bonding in the self-assembly of metalmethylene hetero-bridged calix[n] naphthanoimidazoliums (n⫽ 4, 6).
Ting-zheng Xie*
994. Synthesis of 14-nuclear coordination
cage compounds using imidazole-derived ligands. Azusa Yokoi*,
Naoko Harada, Yukinari Sunatsuki,
Takayoshi Suzuki, Masaaki Kojima
995. Synthesis and electronic states of a
new mixed valence Cu(I)/Cu(II)/Cu(III)
cluster. Hiroyasu Kuwamoto,
Kyung Ho Kim, Takashi Okubo,
Masahiko Maekawa, Takayoshi Kuroda
996. Fabrication of a highly-crystalline metalorganic framework nanofilm with a porphyrin derivative on solid surface.
Soichiro Motoyama*, Rie Makiura,
Osami Sakata, Hiroshi Kitagawa
997. Metal ion assisted assembly of 1D polyrotaxanes based on Cucurbituril.
Huilan Chen*, Zhibin Wang
998. Second-order optical nonlinearities of
clay-organic hybrid materials.
Kota Yamamoto*, Ryoya Matsunaga,
Yasutaka Suzuki, Jun Kawamata
999. Ligand donor/acceptor effects for platinum(II) and palladium(II) thiacrown complexes. Natalie Talbott, Greg Grant
1000. Macrocyclic Pd complexes composed
of pyridine-modified thymidine.
Junpei Kuwabara, Junichi Hoshino,
Takaki Kanbara*
Organized by: S. Wang, F. Jaekle,
Y. Wang, S. Yamaguchi
Presiding: Y. Wang
8:00 – 966. Organophosphorus and organometallic helicene derivatives.
Reau Regis*
8:30 – 967. Phosphorescent metal complexes with ancillary chelates deriving
from benzyldiphenylphosphine and analogs. Yun Chi*
9:00 – 968. Properties and applications of luminescent triarylboron complexes of
platinum(II). Zachary M. Hudson,
Suning Wang*
9:20 – 969. Synthetic, structural and reaction
chemistry of cationic transition-metal borylene complexes. Simon Aldridge*,
Dragoslav Vidovic, David A. Addy,
Christina Y. Tang
9:50 – 970. Exploring the B-N/C⫽C isosterism in conjugated carbon-rich compounds. Adam J. Marwitz, Eric R. Abbey,
Ashley N. Lamm, Shih-Yuan Liu*
10:20 – 971. Small molecule activation with
pentarylboroles. Warren Piers*,
Cheng Fan, Lauren G. Mercier,
Adrian Houghton, Masood Parvez
10:50 – 972. Borane-functionalized late transition metal complexes.
David J. Emslie*, Kristopher B. Kolpin,
Bradley E. Cowie
Hilton
Lehua Suite
Organo-f-Element Compounds: From Novel
Chemical Transformations to Applications
in Catalysis and Materials Science (#46)
Organized by: F. Edelmann, D. Berg,
G. Deacon, Z. Hou, J. Kiplinger
Presiding: J. Takats, K. Meyer
8:00 – 973. Cleavage of inert bonds by Pacman shaped uranium complexes.
Polly L. Arnold*, Jason B. Love*,
Anne-Frederique Pecharman,
Emma Hollis, Guy Jones
8:30 – 974. Reactions of heterocycles with
electrophilic ferrocene-diamide complexes. Paula L. Diaconescu
9:00 – 975. Structure, magnetic properties
and reactivity of uranium compounds.
Marinella Mazzanti
9:30 – 976. Actinide metals with multiple
bonds to carbon: Synthesis, and reactivity of U⫽C and Th⫽C bis(iminophosphorano)methandiide pincer complexes.
Ronald G. Cavell*, Guibin Ma,
Michael J. Ferguson, Robert McDonald
9:50 – 977. New actinide and lanthanide
aminodiboranates and their utility as biomedical reagents and as chemical vapor
deposition precursors. Scott R. Daly,
Do Y. Kim, Gregory S. Girolami*
10:10 – 978. Are 5f electrons really active in
the reactivity of organoactinide complexes? Laurent Maron*
10:30 – 979. Synthesis of novel actinideframework solids. Dermot O’Hare,
Kang Min Ok, Gareth Williams,
Paul Thomas, Aran Samra
Convention Center
Kamehameha Halls II and III
Self-Assembly and Coordination Chemistry
(#164)
Organized by: M. Fujita, L. MacGillivray,
L. Stephen, S. Y Yu, M. Yoshizawa
Presiding: M. Fujita
1001. Synthesis and self-assembies of
amidinate and guanidinate substituted
Pt4 clusters. Shinji Tanaka,
Akihiro Yagyu, Masashi Kikugawa,
Kazushi Mashima*
1002. Synthesis of novel organic cyclic or
cage modules for metal ion assembly.
Ryo Shomura, Shuhei Higashibayashi,
Hidehiro Sakurai, Masayoshi Higuchi*
1003. Coordination chemistry of bismuth(III)
carboxylates-synthesis and structural investigation. Ish Kumar*, Philip Andrews,
Peter Junk
1004. Structural characterization and selfassembly of imidovanadium compounds.
Masafumi Nishina, Toshiyuki Moriuchi*,
Toshikazu Hirao*
1005. Bismuth(III) complexes of nonsteroidal
anti-inflammatory drugs and their activity
against Helicobacter pylori. Ish Kumar*,
Philip Andrews, Richard Ferrero,
Peter Junk
1006. Photohydration of alkynes within a
self-assembled coordination cage.
Hiroki Takezawa*, Yuki Nishijima,
Takashi Murase, Makoto Fujita
1007. Structural changes of aggregation
structure of symmetric and asymmetric
dialkyl quaternary ammonium cations in
crystals of [Ni(dmit)2] salts. Kotaro Dai*,
Kazuaki Tomono, Kazuo Miyamura
1008. Withdrawn
1009. Synthesis and characterization of
novel uranyl chromate framework structures containing cation-cation interactions. Daniel K. Unruh*,
Michelle Baranay, Megan Stoffer,
Peter C. Burns
1010. Advancements in self-assembly of
rhodium(III) molecular cubes and
squares. Hitesh V. Vashi*,
Gregory J. Grant
1011. Highly fluorescent Zn(II)-linked molecular capsules. Zhiou Li, Norifumi Kishi,
Michito Yoshizawa*, Munetaka Akita*
1012. Matrix syntheses of gold ion clusters
within self-assembled cages.
Takafumi Osuga*, Kosuke Ono,
Yoshihiro Yamauchi, Takashi Murase,
Makoto Fujita
1013. 2-D polyoxometalate compound
based on manganese(II) monosubstituted
Keggin polyanions anion chains and silver-bipy cation chains. Ya-guang Chen*
1014. Vapochromism of a self-assembled
hydrogen-bonded proton-transfer complex. Atsushi Kobayashi*,
Masa-aki Dosen, Mee Chang,
Shin-ichiro Noro, Kiyohiko Nakajima,
Masako Kato*
1015. Dynamic contact angle analysis on
self-assembled monolayer.
Atsushi Maeda*, Kohki Hirao
1016. Direct synthesis and characterization
of hybrid inorganic-organic materials by
using several cross-linkers in the presence of n-hexadecylamine as surfactant.
Zeid A. Alothman*, Ismail K. Warad
1017. What kind of bridging ligand can form
multi-interlocked supramolecules?
Morihiko Fukuda, Ryo Sekiya,
Reiko Kuroda*
1018. Understanding Zn..O and Zn..N coordination in extended porphyrin coordination materials. Stephanie Gould*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–83
02-INOR
1019. Structural transformation and mechanochromism of Zn(II) based coordination
frameworks containing dipyridyl-amide ligands. Tsung-yi Chang*,
Biing-Chiau Tzeng*, Hwo-Shuenn Sheu
1020. Peptide-coated, self-assembled
M12L24 coordination spheres and their
immobilization onto an inorganic surface.
Masatoshi Ikemi, Takashi Kikuchi,
Sachiko Matsumura, Kiyotaka Shiba*,
Sota Sato, Makoto Fujita*
1021. In situ preparation and catalytic activation method for copper nano-particles
from self-assembled acetylides.
Ken Judai, Shigenori Numao,
Junichi Nishijo, Nobuyuki Nishi*
1022. Mixed-valence copper clusters constructed by the carbon-carbon bond formation of a substituted hydrazone ligand.
Mee Chang, Atsushi Kobayashi,
Ho-Chol Chang, Masako Kato
1023. Simultaneous binding of Ag⫹ ion and
counter anions by the silver-vorous molecule bearing urea units in the aromatic
side-arms. Mai Utsunomiya,
Shunsuke Kuwahara, Yoichi Habata*
1024. Synthesis of water soluble and stable
metal-organic bismuth(III) complexes.
Ish Kumar*, Philip Andrews, Peter Junk
1025. Synthesis of a water soluble tetraarmed cyclen. Yoichi Habata*,
Yoko Okeda, Shunsuke Kuwahara
1026. Synthesis of bis- and mono-quaterphenyl crown ethers. Rie Chamura,
Shunsuke Kuwahara, Yoichi Habata*
1027. Synthesis of a cylindrical cryptand
based on the silver-vorous molecule.
Yoichi Habata*, Yutarou Nihei,
Shunsuke Kuwahara
1028. Solid state fluorescence spectra of the
metal complexes with a silver-vorous
molecule bearing two anthracene units in
the side-arms. Kaoru Kikukawa,
Shunsuke Kuwahara, Yoichi Habata*
1029. Selective cyclization of terpenoids
within self-assembled cages.
Yuki Nishijima, Takashi Murase,
Makoto Fujita*
1030. Synthesis and analysis of structure
and physicality of novel metal complex
discotic liquid crystal. Keiichi Abe*,
Ayumi Shioda, Kazuaki Tomono,
Kazuo Miyamura
1031. Self-assembly and host-guest properties of metallosupramolecular 3-D nanocages with dimetallic clips.
Xuan-feng Jiang*
1032. Anion-controlled structural changes of
Hg2⫹ complexes with chiral podands.
Mari Ikeda, Shunsuke Kuwahara,
Shim Sung Lee, Yoichi Habata*
1033. Coordination polymer-typed polyrotaxane by a DB24C8 - bis[4-(phenyl-3)yl)pyridine] units - Zn(II) system.
Tetsuya Hiraoka, Shunsuke Kuwahara,
Yoichi Habata*
1034. Induced residual dipolar coupling by
encapsulation. Osamu Morohara,
Daishi Fujita, Sota Sato,
Yoshiki Yamaguchi, Koichi Kato,
Makoto Fujita*
1035. Synthesis and analysis of pi-extended
TTF-fused salphen complexes.
Yuto Suzuki*, Kazuaki Tomono,
Kazuo Miyamura
1036. Stoichiometric control of multiple different tectons in coordination-driven selfassembly: Preparation of fused metallacyclic polygons. Junseong Lee,
Koushik Ghosh, Peter Stang
1037. Supramolecular approach for implementation of quantum computers: Oligo(imidazole)-based triple-helicate as matter spin qubit. Yumi Yakiyama*,
Yasushi Morita, Tsuyoshi Murata,
Shigeaki Nakazawa, Tomoaki Ise,
Daisuke Hashizume, Daisuke Shiomi,
Kazunobu Sato, Masahiro Kitagawa,
Kazuhiro Nakasuji, Takeji Takui
1038. Concave halogen-bonding ligands for
supramolecular structure.
Hiroshi M. Yamamoto*, Hengbo Cui,
Reizo Kato
1039. Highly orientated microarchitectures
of lipophilic 1-D MMX complexes.
Rempei Kuwahara, Keisuke Fujino,
Keita Kuroiwa, Nobuo Kimizuka*
84 –TECH
TECHNICAL PROGRAM
1040. Comparison of the crystal structure of
[Ni(dmit)2] complex salts with symmetric
and asymmetric aralkyl ammonium cations. Saeki Masahiro*, Dai Kotaro,
Tomono Kazuaki, Miyamura Kazuo
1041. Observation of surface structure of
Schiff-base copper(II) complexes substituted with N-alkyl chains of various
lengths by STM. Kazuki Urano*,
Tatsunori Naka, Kazuaki Tomono,
Kazuo Miyamura
1042. Systematic control of the metallophilic
interaction in a dinuclear metal complex
motif. Tadashi Ohba,
Atsushi Kobayashi*, Ho-Chol Chang*,
Masako Kato*
1043. Synthesis of NCN pincer transitionmetal complex-bound norvaline and their
catalysis. Kazuki Ogata,
Daisuke Sasano, Katsuhiro Isozaki,
Hirofumi Seike, Hikaru R. Takaya*,
Masaharu Nakamura*
1044. Grafting of molecular assemblies onto
porous silica particles as stationary
phase in RP-HPLC.
Thiraporn Charoenraks, Naoko Azuma,
Makoto Takafuji, Hirotaka Ihara*
1045. Fabrication of clay-dye composites
exhibiting enhanced two-photon absorption cross-sections. Yasutaka Suzuki*,
Yuta Tenma, Jun Kawamata
1046. Synthesis and structural analysis of alkylated (dmio)M(4Cn-bpy) complex.
Yu Kobayashi, Tomomi Tashiro,
Kazuaki Tomono, Kazuo Miyamura
1047. Synthesis and characterization of self
assembled charge neutral macrocycles.
Tom Fyles, Andrew K. Dambenieks
1048. Formation of novel ultrasmall gold
clusters via reassembling of preformed
cluster. Yutarou Kamei*,
Yukatsu Shichibu, Katsuaki Konishi
1049. HCl-induced nuclearity convergence
of polydisperse gold clusters via re-assembly process: Facile synthesis of magic-number icosahedral Au13 clusters.
Yukatsu Shichibu*, Katsuaki Konishi
1050. Vapochromism of terpyridine(thiocyanato)platinum(II) complexes.
Yuki Fukuzawa*, Atsushi Kobayashi,
Shin-ichiro Noro, Masako Kato
1051. Construction of a water-soluble
M12L24 spherical complex with sugar
coating. Asana Takahashi, Daishi Fujita,
Sota Sato, Makoto Fujita
1052. Four-legged mixed-valence metal-organic nanotube. Kazuya Otsubo*,
Hiroshi Kitagawa, Yusuke Wakabayashi,
Jun Ohara, Shoji Yamamoto,
Hiroyuki Matsuzaki, Hiroshi Okamoto
1053. Ruthenium(II) thiacrown complexes:
Synthetic, spectroscopic, electrochemical, and single crystal X-ray studies of
[Ru(15S5)Cl](PF6). Gregory J. Grant*,
Daron E. Janzen
1054. Organic reactions within the porous
coordination networks.
Takehide Kawamichi,
Yasuhide Inokuma, Masaki Kawano,
Makoto Fujita*
1055. Development of helical zinc complexes composed of zinc SALEN and
bridging linker units. Kiyoka Eda*,
Yuji Koga, Kouki Matsubara
1056. Degradation of a multi-interlocked supramolecule by aromaticsulfonates.
Ryo Sekiya*, Morihiko Fukuda,
Reiko Kuroda*
1057. Synthetic and structral studies of zincSALOPHEN containing metallopeptides.
Takatsugu Shimada, Setsuko Ando,
Kouki Matsubara*
Saturday Afternoon
Hilton
Kahili I/II
Olefin Oligomerization and Polymerization
Catalyzed by Early Transition Metals (#22)
Organized by: K. Theopold, K. Mashima,
Z. Xie
Presiding: S. Gambarotta
12:30 – 1058. Homo- and copolymerization
processes catalyzed by half-metalocene
complexes of titanium. Tae-Jin Kim,
Sung-Kwan Kim, Jong-Sok Hahn,
Sang Ook Kang
13:10 – 1059. Group 4 metallocene-catalyzed synthesis and application of polyethylenes with functional side groups.
Myung Hwan Park, Jun Ha Park,
Youngkyu Do*, Min Hyung Lee*
13:50 – 1060. New isoalkene (co-)polymers
via highly electrophilic organometallic initiators. Manfred Bochmann*
14:30 – 1061. Ph2C-Bridged and chiral-atbridge multisubstituted C1-symmetric
group 4 ansa-metallocenes for highly
isospecific propylene polymerization.
Jean-François Carpentier*,
Evgueni Kirillov*, Nicolas Marquet,
John A. Gladysz*, Abbas Razavi
15:10 – 1062. Precision hydrocarbons via
the living coordinative chain transfer oligomerization and co-oligomerization of
ethene, ␣-olefins and ␣,␻-nonconjugated
dienes. Lawrence R. Sita*, Jia Wei,
Rennisha Wickham
15:50 – 1063. Switchable catalysts: From
ethylene polymerization to selective and
non-selective oligomerization and back.
Indira Thapa*, Sandro Gambarotta
Hilton
Hibiscus I/II
Functional Molecule-Based Magnets (#25)
Organized by: M. Yamashita,
G. Christou, J. Miller, K. Murray,
T. Sugawara, R. Thompson
Presiding: E. Coronado, S. Gao
12:30 – 1064. Some recent progress in single-ion magnets. Song Gao*
13:00 – 1065. Rational design of single-molecule magnets. Maik Heidemeier,
Hubert Theil, Veronika Hoeke,
Carl-Georg Frhr. v. Richthofen,
Bastian Feldscher, Erich Krickemeyer,
Thorsten Glaser
13:15 – 1066. New single molecule magnet
clusters of Mn and Mn-Ln (3d-4f) with triethanolamine and other coligands.
Keith S. Murray*, Stuart K. Langley,
Boujemaa Moubaraki, Nicholas Chilton,
Ian A. Gass
13:45 – 1067. Switchable molecules: Valence tautomers and single-molecule
magnets. Colette Boskovic,
Yanyan Mulyana, Chris Ritchie,
Brendan Abrahams, Keith Murray,
Paul Kögerler, Lorenzo Sorace
14:05 – 1068. Magnetic materials based on
cobalt phosphonates and dehydrationrehydration induced reversible magnetic
changes. Li-Min Zheng*,
Song-Song Bao, Li-Rong Guo,
Yan-Hui Su, Peng-Fei Wang, Xu Liang
14:35 – 1069. Determination of exchange
couplings in dinuclear 4f-3d heterometallic nanosized magnets. Takayuki Ishida*,
Ryo Watanabe, Kei Fujiwara,
Atsushi Okazawa, Gou Tanaka,
Shunsuke Yoshii, Hiroyuki Nojiri
14:50 – 1070. New functionalities emerging
in large clusters. Dante Gatteschi*,
Maria Fittipaldi, Lorenzo Sorace,
Lisa Castelli, Claudia Innocenti,
Claudio Sangregorio
15:20 – 1071. Novel hysteresis in coordination networks containing the 5-aminoisophthalate ligand. Paul Wood*,
Richard Mole, Gerald Weldon,
Thomas Legerton, Markus Hoelzel,
Anatoliy Senyshyn, Sean Giblin
15:35 – 1072. Coexistence of orthogonal
spin systems of Rh(II,III) and Pt(II,III) in a
mixed-valent 1-D chain.
Kazuko Matsumoto*, Kazuhiro Uemura
15:55 – 1073. Controlling structure and magnetism of coordination polymers under
extreme conditions of pressure and magnetic field. John A. Schlueter*,
Jamie L. Manson, Greg J. Halder,
Karena W. Chapman,
Myung H. Whangbo, Janice L. Musfeldt
16:10 – 1074. New valence tautomers and
related compounds. David Shultz*
Hilton
Lehua Suite
Organo-f-Element Compounds: From Novel
Chemical Transformations to Applications
in Catalysis and Materials Science (#46)
Organized by: F. Edelmann, D. Berg,
G. Deacon, Z. Hou, J. Kiplinger
Presiding: Z. Hou, P. Arnold
12:30 – 1075. Synthesis, X-ray structure and
reactivity of tris-␤-diketiminate lanthanide
complexes: Sterically induced activation.
Shen Qi, Rui Jiao, Mingqiang Xue,
Xiaodong Shen, Yong Zhang,
Yingming Yao
13:00 – 1076. Highly selective organo-f-element mediated catalytic hydrofunctionalization processes. scope and mechanism. Tobin J. Marks*
13:30 – 1077. Molecular alkyl and hydride
complexes of the lanthanides.
Jun Okuda*
14:00 – 1078. Synthesis of the CGC-ligands
stabilized rare-earth metal complexes
and their unique catalysis on specific selective living and immortal polymerizations of conjugated dienes.
Zhongbao Jian*, Dongtao Liu*,
Dongmei Cui
14:30 – 1079. Rare earth metal-organics: Toward greener corrosion inhibitors.
Glen Deacon, Maria Forsyth, Peter Junk
15:00 – 1080. Designing lanthanide edifices
with organic ligands for highly luminescent materials and probes.
Jean-Claude G. Bünzli*
15:20 – 1081. New challenges with f elements for quantum chemists.
Laura Gagliardi*
15:40 – 1082. Cyclopentadienyl-phosphazene constrained geometry complexes of
rare-earth metals. Joerg Sundermeyer*,
Alex Petrov, Konstantin Rufanov,
Noa Hangaly, Michael Elfferding
16:00 – 1083. Group 3 metal complexes
supported by tridentate bis(naphtholate)
ligands for stereoselective ring-opening
polymerization of racemic lactones.
Jean-François Carpentier*,
Evgueni Kirillov*, Ekaterina Grunova
Hilton
Rainbow III
The Construction of Photofunctional
Supramolecular Metal Complexes (#94)
Organized by: M. Kato, P. Ford,
G. Hanan, H. Ishida, V. Yam
Presiding: V. Yam, G. Hannan, H. Ishida,
M. Kato
12:30 Introductory remarks
12:35 – 1084. DNA charge transport chemistry. Jacqueline K. Barton*
13:05 – 1085. Emission properties of platinum(II) and gold(I) complexes based on
electrostatic assembly along polypeptides. Toshiyuki Moriuchi*,
Masahiro Yamada, Kazuki Yoshii,
Toshikazu Hirao*
13:20 – 1086. Competitive energy and electron transfer in the excited state on lightharvesting dendritic Ir(III) complexes,
[(C^N)2Ir(LX-Gn)]. Ah-Reum Hwang,
Won-Sik Han, Ho-Jin Son,
Chyongjin Pac, Dae Won Cho*,
Sang Ook Kang*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
13:35 – 1087. Photofunctions of novel ruthenium complexes synthesized based on
“peptide origami”. Hitoshi Ishida*,
Yoshimi Shiina, Yuya Takasugi,
Shigero Oishi
13:50 – 1088. Synthesis of bacteriochlorophyll-d analogs possessing modified
substituents at the B-ring and their chlorosomal self-aggregation.
Hitoshi Tamiaki*
14:10 – 1089. Formation of long-lived charge
separated states in donor-acceptor
linked dyads by metal ion coupled and
decoupled electron transfer.
Kei Ohkubo*, Shunichi Fukuzumi*
14:25 – 1090. Oligonuclear Ru(II) and Rh(II)
complexes for the photochemical production of hydrogen. Masanari Hirahara,
Saya Tanaka, Ken Sakai*,
Michael W. Cooke, Garry S. Hanan*
14:40 – 1091. Photoinduced hydrogen production with supramolecular ensembles.
Stefan Bernhard*, Eric D. Cline
14:55 – 1092. Water oxidation catalyzed by
mononuclear aquaruthenium complexes.
Shigeyuki Masaoka*, Masaki Yoshida,
Ayano Kimoto, Kosei Yamauchi,
Ken Sakai*
15:10 – 1093. Photoinduced water oxidation
by using Ru(II) dendrimers as photosensitizers. Sebastiano Campagna,
Fausto Puntoriero, Giuseppina La Ganga
15:25 – 1094. Synthesis, photophysics, and
photocatalysis of linear-shaped and ringshaped oligomers of Re(I) diimine complexes. Osamu Ishitani*
15:45 – 1095. Polarized luminescent lanthanide complex in molecular ultra-thin
films. Miki Hasegawa*
16:00 – 1096. Commercially viable dyes for
solar energy applications.
Charles M. Drain*, Alexander Falber,
Alessandro Varotto, Lynn Francesconi,
Charles T. Black, Chang-Yong Nam
Hilton
Coral II
Dioxygen Activation Chemistry and
Catalytic Oxidation Reactions (#108)
Organized by: S. Itoh, W. Nam,
A. Rosenzweig, W. Tolman
Presiding: J. Bollinger, M. Ikeda-Saitoh
12:30 – 1097. Dioxygen activation at protein
active sites and synthetic carboxylatebridged diiron complexes.
Stephen J. Lippard
13:05 – 1098. Trapping a non-heme mononuclear Fe(III)-superoxo intermediate.
Michael M. Mbughuni,
Mrinmoy Chakrabarti,
Michael P. Hendrich, Eckard Münck,
John D. Lipscomb*
13:40 – 1099. How the iron- and 2-oxoglutarate-dependent aliphatic halogenases
avoid competing hydroxylation.
Megan L. Matthews, Linde A. Miles,
Christopher S. Neumann, Tyler L. Grove,
Squire J. Booker, Carsten Krebs,
Christopher T. Walsh,
Joseph M. Bollinger
14:15 – 1100. Heme oxygenase catalytic
mechanism. Masao Ikeda-Saito*,
Toshitaka Matsui, Masaki Unno
14:50 – 1101. Mössbauer, EPR and DFT
studies of synthetic ␮-oxo bridged
FeIVFeIV and FeIVFeIII complexes containing an FeIV⫽O site: An exchangedriven spin transition and a million-fold
reactivity increase upon core opening.
Eckard Munck*, Lawrence Que
15:15 – 1102. Modeling activation of oxygen
by supported transition metals.
Christopher J. Cramer*
15:50 – 1103. Isotopic probing of reactions
involving molecular oxygen, superoxide,
hydrogen peroxide and water.
Justine Roth*
Hilton
Coral I
Molecular Design in Bioinorganic
Chemistry (#173)
Organized by: T. Hayashi, D. Goldberg,
P. Kennepohl, H. Masuda
Presiding: H. Masuda, Z. Guo
12:30 – 1104. Molecular design in medicinal
inorganic chemistry. Chris Orvig*
13:10 – 1105. Targeted delivery and selective activation of platinum-based drugs.
Zijian Guo*
13:40 – 1106. Biocoordination chemistry of
Ni(II) and Zn(II) in chaperones HypA and
GroES. Hongzhe Sun*, Wei Xia,
Tianfan Cheng, Shujian Cun, Hongyan Li
14:10 – 1107. Mechanistic insights into biomineralization using porous protein
crystals. Takafumi Ueno*
14:40 – 1108. Design of peptide foldamers
exploiting ferrocene-peptide conjugates.
Bernie Kraatz
15:10 – 1109. Molecular design of bioinspired catalysts with vitamin B12 functions. Yoshio Hisaeda*
15:40 – 1110. Design of copper complexes
activating dioxygen species as an active
site model of copper-oxygenases.
Hideki Masuda*
16:10 – 1111. Structural and mutagenic approach to create human serum albuminbased oxygen carrier.
Teruyuki Komatsu*
Hilton
Rainbow II
Advances in Nuclear Chemistry of
Transactinide Elements (#218)
Organized by: Y. Nagame, C. Duellmann,
H. Nitsche, P. Schwerdtfeger, Z. Qin
Presiding: Y. Nagame
12:30 – 1112. Relativistic and quantum electrodynamic effects for the superheavy elements. Peter Schwerdtfeger*,
Andreas Hermann, Heinz Gäggeler,
Nicola Gaston, Christian Thierfelder
13:00 – 1113. Theoretical predictions of the
chemical behaviour of superheavy elements. Valeria Pershina*
13:30 – 1114. Chemical investigation of element 114: Ups and downs.
Robert Eichler*, Farid S. Abdullin,
Nikolay V. Aksenov, Yuri V. Albin,
Alexey V. Belozerov, Gospodin Bozhikov,
Victor I. Chepigin, Rugard Dressler,
Sergey N. Dmitriev, Heinz W. Gäggeler,
Alexander Gorshkov,
Roger A. Henderson, Siegfried Hübener,
Mikhail G. Itkis, Viacheslav Y. Lebedev,
Yuri V. Lobanov, Oleg N. Malyshev,
Kenton J. Moody, Yuri T. Oganessian,
Oleg V. Petrushkin,
Alexander N. Polyakov, David Piguet,
Andrey G. Popeko, Peter Rasmussen,
Roman N. Sagaidak, Alexey Serov,
Igor V. Shirokovsky, Dawn Shaughnessy,
Sergei V. Shishkin, Mark A. Stoyer,
Nancy J. Stoyer, Alexander I. Svirikhin,
Evgeny E. Tereshatov, Yura S. Tsyganov,
Vladimir K. Utyonkov, Grigori K. Vostokin,
Maciej Wegrzecki, David Wittwer,
Phillip A. Wilk, Alexander V. Yeremin
14:00 – 1115. Research activities on SHE
with TASCA at GSI.
Alexander Yakushev*
14:30 – 1116. Superheavy element chemistry with SISAK. Jon Petter Omtvedt*,
Jorolf Alstad, Tor Bjørnstad,
Christoph E. Düllmann,
Kenneth E. Gregorich, Nalinava S. Gupta,
Johannes Nilssen, Heino Nitsche,
Fereshteh Samadani, Matthias Schädel,
Frøydis Schulz, Andreas Türler,
Alexander B. Yakushev
15:00 – 1117. Electrochemistry of the heaviest elements. Atsushi Toyoshima*,
Kazuaki Tsukada, Masato Asai,
Yoshihiro Kitatsuji, Yasuo Ishii,
Tetsuya Sato, Zijie Li, Nozomi Sato,
Takahiro Kikuchi, Ichiro Nishinaka,
Yuichiro Nagame, Yoshitaka Kasamatsu,
Hiromitsu Haba, Kazuhiro Ooe,
Atsushi Shinohara, Wataru Sato,
Kazuhiko Akiyama, Julia Even,
Matthias Schädel
15:30 – 1118. Current research on superheavy element chemistry at LLNL.
Dawn A. Shaughnessy, Kenton Moody,
Roger Henderson, Julie Gostic
16:00 – 1119. Gas-phase chemistry of group
5 elements with bromine. Zhi Qin*,
Maosheng Lin
Hilton
Rainbow I
Chemistry and Materials Science at High
Pressures (#239)
Organized by: Y. Song, I. Butler, Y. Lee,
R. Manaa
Presiding: C. Yoo
12:30 Opening remarks
12:35 – 1120. Novel polymeric and metallic
states of simple molecules under extreme
conditions. Choong-Shik Yoo*
13:00 – 1121. Luminescence spectroscopy
of square-planar platinum(II) and palladium(II) complexes at variable pressure:
Molecular electronic structure and intermolecular effects. Christian Reber*
13:25 – 1122. Behavier of supramolecular
crystals under high pressure. Kai Wang*,
Run Wang*, Bo Zou*, Guangtian Zou*
13:50 – 1123. Elastic anomalies in lanthanide
metals. Oliver Tschauner*
14:15 – 1124. Effect of pressure on the properties of energy materials, structure, and
elasticity of LiMn2O4 nanorods and
bonding in a novel NH3BH3-H2 compound. Yu Lin*, Yuan Yang,
Wendy L. Mao, Ho-kwang Mao
14:30 – 1125. Nanostructured materials under high pressure. Zhaohui Dong,
Yang Song*
14:45 – 1126. High-pressure reactions triggered by photodissociation of R-OH species. Roberto Bini, Matteo Ceppatelli,
Vincenzo Schettino
15:10 – 1127. High pressure - high temperature studies on Xe-H2; Xe-Cl2; Xe-Br2,
and Xe-I2 systems.
Maddury S. Somayazulu*,
Russell J. Hemley
15:35 – 1128. Toward new energy-rich molecular systems: Polynitrogen.
Jonathan Crowhurst*, M Riad Manaa,
Joseph M. Zaug, Alexander F. Goncharov
16:00 – 1129. High-pressure and high-temperature synthesis, structures, and physical properties of binary germanides of
electropositive elements.
Hiroshi Fukuoka*, Daisuke Saito,
Fumiko Ohtsu, Momoko Harada,
Mayumi Yoshikawa, Kazuya Baba,
Kei Inumaru
Hilton
South Pacific I
New Frontiers in Polyoxometalate
Chemistry (#251)
13:40 – 1133. Transition metal substituted
polyoxometalates for group transfers.
Anna Proust*, Claire Besson,
Geoffroy Guillemot, Guillaume Izzet,
Jean-Hugues Mirebeau,
Christine Courillon, Emma Gallo
14:10 – 1134. Hybrid polyoxometalates:
Merging organic and inorganic domains
for enhanced catalysis.
Marcella Bonchio*, Mauro Carraro,
Andrea Sartorel, Gianfranco Scorrano
14:30 – 1135. Late-transition-metal oxo
complexes and other unique functional
structures based on POMs. Craig L. Hill,
Kevin P. O’Halloran, Rui Cao, Jie Song,
Zhen Luo, Hillesheim Daniel,
Djamaladdin G. Musaev,
Hardcastle I. Kenneth
15:00 – 1136. Experimental synthesis and
theoretical calculations: Polyoxometalate-based inorganic-organic hybrid materials. Zhong-Min Su*
15:20 – 1137. Exploring diversity within the
Lindqvist hexametalate platform.
John Errington*, Laura Coyle,
Gavin Harle, Balamurugan Kandasamy,
Paul Middleton
15:40 – 1138. Electron transfer: Oxygen
transfer oxidation reactions catalyzed by
polyoxometalates. Ronny Neumann*
16:10 – 1139. Size-selective sorption of
small organic molecules in macrocationpolyoxometalate hybrid ionic crystal stabilized by ␲-␲ interactions.
Sayaka Uchida, Hanae Tagami,
Noritaka Mizuno*
Hilton
Sea Pearl III/IV
Nanoscale Characterization of Functional
Materials by Nuclear Probes (#275)
Organized by: K. Nomura, A. Hill,
J. Stevens, H. Wei, Y. Yamada
Presiding: K. Nomura
12:30 – 1140. ␮SR and Mössbauer studies
of spin crossover complexes.
Yann Garcia*, Stewart J. Campbell,
James S. Lord, Philipp Gütlich
13:10 – 1141. ␮SR study of linear two-coordinate Fe complexes with bulky arylthiol
ligands. Yasuyuki Ishii, Isao Watanabe*,
Yoshio Kobayashi, Takashi Nagatomo,
Mikinao Ito, Tsukasa Matsuo, Y. Shoji,
Kohei Tamao
13:30 – 1142. Muonium in calcium phosphate. Kenya Kubo*
14:00 – 1143. NMR analyses of functionalized inorganic-organic solids.
Brad F. Chmelka*
14:40 – 1144. Positron and NMR analysis of
metal organic frameworks.
Matthew R. Hill*, Cara Doherty,
Anita J. Hill, Timothy J. Bastow
15:00 – 1145. Study of polymers by positron
annihilation spectroscopy.
Yoshinori Kobayashi*
15:30 – 1146. Positron annihilation lifetime
spectroscopy characterization of novel
membrane materials.
Geoffrey M. Geise*, Hao Ju, Wei Xie,
Alyson C. Sagle, Cara M. Doherty,
James I. Mardel, Anita J. Hill,
James E. McGrath, Benny D. Freeman,
Donald R. Paul
15:50 – 1147. Mastering hierarchical porosity. Paolo Falcaro, Anita J. Hill
Organized by: M. Nyman, C. Boskovic,
N. Mizuno, L. Xu
Presiding: M. Nyman
12:30 – 1130. Heterogeneous catalysts
based on polyoxometalates and coordination polymer MIL-101.
Oxana A. Kholdeeva,
Natalia V. Maksimchuk,
Konstantin A. Kovalenko,
Vladimir P. Fedin
13:00 – 1131. Isotopic oxygen exchange in
polyoxoniobate clusters.
Rene L. Johnson*, Eric M. Villa,
C. André Ohlin, William H. Casey
13:20 – 1132. Do polyoxometalates catalyze
cycloalkane nitration? Ahmet Gunay*,
Mark A. Barteau, Klaus Theopold
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–85
02-INOR
16:10 – 1148. Chemistry and mineralogy at
the Mars-Exploration-Rover landing site
Meridiani Planum, Mars.
Goestar Klingelhoefer*
Hilton
Nautilus I & II
Organoboron, Organosilicon and
Organophosphorus as Optoelectronic and
Energy-related Materials (#35)
Organized by: S. Wang, F. Jaekle,
Y. Wang, S. Yamaguchi
Presiding: S. Yamaguchi
13:00 – 1149. Synthesis and optoelectronic
properties of silole-based materials.
Junwu Chen*
13:30 – 1150. Synthesis and properties of
novel extended ␲-conjugated systems of
heavier main group elements.
Yusuke Tanabe, Takahiro Sato,
Yoshiyuki Mizuhata, Norihiro Tokitoh*
14:00 – 1151. Synthesis, structure and reactivity of a disilyne-NHC complex.
Torahiko Yamaguchi, Akira Sekiguchi*
14:20 – 1152. ␲-Conjugated disilenes and
phosphasilenes stabilized by fused-ring
bulky “Rind” groups. Tsukasa Matsuo*
14:50 – 1153. Planar diamond-shaped cyclobutadiene silicon analog with polarized
Si-Si bonds. Katsunori Suzuki,
Tsukasa Matsuo, Daisuke Hashizume,
Hiroyuki Fueno, Kazuyoshi Tanaka,
Kohei Tamao
15:10 – 1154. Stable unsaturated silicon
compounds showing intramolecular
charge transfer transition.
Takeaki Iwamoto*
15:40 – 1155. Trace detection of explosives
with polymers containing silole and boronate fluorophores. William C. Trogler*
16:10 – 1156. Formation of H-aggregates of
oligosilanes nanocrystallized by a reprecipitation method. Kenkichi Sakamoto*,
Yuki Morita, Yuji Shibata, Takeshi Kida
Hilton
South Pacific III
Chemistry of Sulfur-Bridged Multimetallic
Complexes (#96)
Organized by: T. Rauchfuss, G. Jin,
T. Matsumoto, Y. Mizobe
Presiding: T. Rauchfuss
13:00 – 1157. Synthesis, structures and
properties of 1D-, and 3D- polymeric
metal arene-thiolato complexes.
Andreas Eichhoefer*, Karin Fink,
Richard A. Mole, Paul T. Wood
13:30 – 1158. Theoretical study of dinitrogen
activation on cubane-type MIr3S4 clusters (M ⫽ Ru, Mo, W).
Hiromasa Tanaka*, Fumihiro Ohsako,
Hidetake Seino, Yasushi Mizobe,
Kazunari Yoshizawa
14:00 – 1159. Modeling hydrogenase enzymes: Structure, redox, and function.
Martin Schroder*
14:30 – 1160. Models for the oxidized form
of the iron hydrogenase active site: Synthesis, structure, and reaction with hydrogen. Dennis M. Heinekey*,
Steven L. Matthews*
15:00 – 1161. Reactivity of nickel thiolate
complexes in the development of biomimetic compounds. Elisabeth Bouwman
15:30 – 1162. Structure and reactivity of homobinuclear group 10 metal complexes
with new multidentate N,S-hybrid ligands. Matthias Bierenstiel*
16:00 – 1163. Sulfur bridged iron nitrosyl
complexes: Syntheses, structures, and
DFT investigations. Lijuan Li*,
Rongming Wang,
Miguel A. Camacho-Fernandez, Wei Xu,
Jian Zhang
86 –TECH
TECHNICAL PROGRAM
Saturday Evening
Convention Center
Kamehameha Halls II and III
Controlling the Structure and Properties of
Solids (#20)
Organized by: B. Kennedy,
Y. Shimakawa, P. Woodward
Presiding: B. Kennedy
Poster Session
19:00 – 21:00
1164. Magnetic phase diagram of alternating
chain compound Pb2V3O9.
Kazuhiro Nawa*, Chishiro Michioka,
Kazuyoshi Yoshimura
1165. Electronic properties of solid solution
Ba1-xKx(Fe1-yCoy)2As2. Suzuki Shunpei*,
Kenya Ohgushi, Kiuchi Yohko, Ueda Yutaka
1166. Quadruple-layered perovskite
(CuCl)Ca2NaNb4O13: Unusual octahedral
tilting and absence of magnetic order.
Atsushi Kitada*, Yoshihiro Tsujimoto,
Yoshitami Ajiro, Yasuo Narumi,
Koichi Kindo, Masakazu Nishi,
Yoko Kiuchi, Masaki Ichihara,
Yutaka Ueda, Kazuyoshi Yoshimura,
Yasutomo J Uemura, Hiroshi Kageyama
1167. Characterization of the structural and
magnetic properties in Ba2-xLaxMnRuO6
perovskites. Jennifer R. Soliz*,
Patrick M. Woodward
1168. Synthesis, structure and magnetic
properties of (Sr1-xBax)FeO2.
Takafumi Yamamoto*, Takashi Saito,
Naoaki Hayashi, Mikio Takano,
Cedric Tassel, Yoshihiro Tsujimoto,
Atsushi Kitada, Kenji Ohoyama,
Yuichi Shimakawa,
Kazuyoshi Yoshimura, Hiroshi Kageyama
1169. Sr2FeO3: A new member of the spin
ladder family. Liis Seinberg*,
Hiroshi Kageyama, Naoaki Hayashi
1170. Electric properties and crystal structures of M2(WO4)3 (M⫽Sc, Y, In) synthesized hydrothermally.
Rie F. Shimanouchi*, Takaaki Tsuji,
Ryusuke Yagi, Hitoshi Nishizawa
1171. Dielectric and magnetic properties of
LiNbO3-type MnMO3(M ⫽ Ti, Sn).
Akihisa Aimi, Tetsuhiro Katsumata,
Daisuke Mori, Desheng Fu, Mitsuru Itoh,
Toru Kyômen, Yoshiyuki Inaguma*
1172. Synthesis and structure analysis of
novel single crystal oxide, Na-Co-Te-O.
Yue Jin Shan*, Yuta Yoshioka,
Keitaro Tezuka, Hideo Imoto
1173. Hydrothermal synthesis and physical
properties of 4d and 5d pyrochlores with
high oxidation states. Sato Hirohiko*,
Terada Toshihiko, Hara Shigeo
1174. NMR/NQR studies of the A-site-ordered perovskite ACu3V4O12.
Atsushi Tanizawa*,
Kazuyoshi Yoshimura, Takashi Saito,
Yuichi Shimakawa
1175. Room-temperature ferromagnetic
BiFeO3 synthesized by a self-catalyzed
fast reaction process. Zuo-Guang Ye*,
Jiangtao Wu, Shaoyu Mao,
Zhaoxiong Xie, Lansun Zheng
1176. Synthesis and properties of PbOstructure FeTe1-xSex (0⬉x⬉0.5).
Mami Matsui*, Jinhu Yang, Hiroto Ohta,
Chishiro Michioka, Kazuyoshi Yoshimura
1177. Chemical vapor deposition approaches to multifunctional thin films.
Russell Binions*, Michael Warwick
1178. Self-assembly process in liquid phase
system. Junhui Xiang*
1179. Syntheses and properties of higher
borides RB50-type (R ⫽ Rare earth elements) compounds. Kunio Kudou*,
Shigeru Okada
1180. Structural conversions of metal oxide
frameworks under hydrothermal conditions. Takamasa Nishida, Yu Ohshiro,
Takamitu Sugitani, Yu Katayama,
Kazuo Eda*
1181. Synthesis and characterization of NiO
and NiO/Mg nanoparticles.
Alejandro Diaz*, Victor Manuel Martínez,
Andreas Reiber
1182. Hydrothermal reaction by microwave
heating for synthesis of LiFePO4 as cathode material. Chihiro Sato*,
Kazuyoshi Uematsu, Tadashi Ishigaki,
Hirokazu Okawa, Kenji Toda, Mineo Sato
1183. Ag⫹ ion conducting solid electrolyte
with NASICON-type structure.
Takatoshi Higuchi, Shinji Tamura,
Nobuhito Imanaka*
1184. Divalent Mg2⫹ ion conducting solid
with NASICON-type structure.
Yasunori Hoshino, Shinji Tamura,
Nobuhito Imanaka*
1185. Microparticulation and carbon-coating
of LiFePO4 by solid-state method with
polymer materials. Hironobu Tsuji*,
Kazuyoshi Uematsu, Tadashi Ishigaki,
Hirokazu Okawa, Kenji Toda, Mineo Sato
1186. Intercalation of sodium into graphitelike layered material BC2N by electrochemical method. Kaoru Yamada,
Masayuki Kawaguchi*
1187. Synthesis and structure of a new inorganic-organic hybrid compound
[Zn(en)2]3[V10O28]. Hui-Yuan Ma*
1188. Unexplored thermal transformation
behavior of 2-D bound gadolinium hydroxide layers: Fabrication of oriented
crystalline films of gadolinium oxychloride
nanosheets suitable for the multicolor luminescence with color tunability.
Young-su Yoon, Ki Woong Kim,
Won Kyung Chung, In Su Lee*
1189. Characteristics of coated ground calcium carbonate and its effects on the
property of paper. Hong-wei Zhang*
1190. Preparation of diamond-like B/C film
by hot filament CVD method.
Yoshihisa Ishimaru, Yusuke Ashida*,
Masayuki Kawaguchi*, Nobuhito Ohno*
1191. Withdrawn
1192. Theoretical study of the ligand field
splitting of octahedral metal complex.
Ryosuke Watanabe*, Tomohiko Ishii,
Genta Sakane
1193. Syntheses, hardness, and magnetic
properties of Sc2AlB6 and Lu2AlB6.
Shigeru Okada*, Kunio Kudou,
Toetsu Shishido, Takao Mori
1194. Permeability and reversible guest-exchange of seemingly nonporous metallocycles. Anneli Kleyn*,
Leonard J. Barbour
1195. Synthesis and crystal structure of the
quaternary borocarbide GdCo2B2Cx (x ⫽
0 ⬃ 1). Shigeru Okada*, Kunio Kudou,
Toetsu Shishido
1196. Syntheses and physical properties of
REPd3Bx (RE ⫽ La, Gd, Lu, Sc).
Toetsu Shishido, Shigeru Okada*,
Kunio Kudou, Takao Mori
1197. Low-temperature crystallization of
TiO2. Keiko Fukushi*, Sae Nakajima,
Kazuyoshi Uematsu, Tadashi Ishigaki,
Kenji Toda, Mineo Sato
1198. Synthesis of gallium nitride using a fluidized bed. Masanori Arai,
Kazuyoshi Uematsu, Tadashi Ishiaki,
Kenji Toda, Mineo Sato
1199. Hydrogen evolution from water under
visible photoirradiation by using molybdenum hexanuclear halide cluster compounds. Taiki Kanda, Atsushi Anzai,
Shoji Yamanaka, Kei Inumaru*
1200. Structural characterization of dielectric
perovskite oxynitride SrTaO2N.
Yaru Zhang*, Teruki Motohashi,
Yuji Masubuchi, Shinichi Kikkawa
1201. Neutron diffraction study on the anion
ordering in oxynitride perovskites,
SrTaO2N, CaTaO2N, LaTaON2, and LaNbON2. Young-Il Kim*, Eunhye Lee
1202. Oxynitride type Li ionic conductors
with layered perovskite structure,
LiLaTa2O7⫺3xN2x. Young-Il Kim*,
Eunhye Lee, Seung-Ju Kim,
Sung-Chul Kim
1203. Control of the structural transition of
antiferromagnetic CrN epitaxial thin films
synthesized by using MBE and PLD.
Satoshi Izumi, Shoji Yamanaka,
Kei Inumaru*
1204. Structure and properties of elemental
substituted FeTiO3.
Daisuke Nakatsuka*, Tatsuo Fujii,
Makoto Nakanishi, Jun Takada
1205. Synthesis and physical property of
PbO-type FeSe. Masatomo Kawa*,
Yang Jinhu, Hiroto Ota, Chisiro Michioka,
Kazuyoshi Yoshimura
1206. Synthesis and NOx adsorption of lithium ferrite powder by mechanochemical
method. Shigeru Okada,
Kiyomi Kamamoto, Kunio Kudou*,
Kiyokat Iizumi
1207. Frequency-selective enhancement of
optical birefringence by localized surface
plasmon resonance. Shunsuke Murai*,
Ryosuke Hattori, Koji Fujita,
Katsuhisa Tanaka
1208. Crystal grown and some properties of
iron silicides from gallium metal solution.
Kunio Kudou*, Shigeru Okada,
Takao Mor, Toetsu Shishido
1209. Science in the art of a traditional Japanese stoneware. Yoshihiro Kusano*,
Yuuki Kojima, Minoru Fukuhara,
Jun Takada, Yasunori Ikeda,
Mikio Takano, Akira Doi
1210. Reevaluation of ancient red iron oxides excavated from archaeological sites.
Ryu Murakami, Hiromi Tsuji,
Takashi Miyazaki, Teruaki Danno,
Hideki Hashimoto, Yoshihiro Kusano,
Jun Takada
1211. Topotactic phase transformation of
␤-Fe2O3 into ␣-Fe2O3. Teruaki Danno,
Hiroshi Asaoka, Makoto Nakanishi,
Tatsuo Fujii, Yasunori Ikeda,
Yoshihiro Kusano, Jun Takada
1212. Synthesis of some calcium phosphate
crystals using disposal biomass by metasilicate gel method.
Takayuki Kohiruimaki*
1213. Innovative functional material, “biogenous iron oxide” (I): Isolation of Leptothrix cholodnii OUMS1 and morphological and chemical characters of uniquelyshaped microtubes.
Michinori Sawayama*, Tomoko Suzuki,
Hideki Hashimoto, Mitsuaki Furutani,
Tomonari Kasai, Masaharu Seno,
Hitoshi Kunoh, Jun Takada
1214. Innovative functional material, “biogenous iron oxide” (II): Structural and elemental analyses of microtubes produced
by Leptothrix cholodnii OUMS1.
Mitsuaki Furutani, Michinori Sawayama,
Tomoko Suzuki, Hitoshi Kunoh,
Noriyasu Kimura, Jun Takada*
1215. Innovative functional material, “biogenous iron oxide” (III): Structural and
physicochemical analyses of twisting
iron-oxide stalks produced by Gallionella
ferruginea. Tomoko Suzuki*,
Nobuyuki Matsumoto, Hideki Hashimoto,
Hitoshi Kunoh, Jun Takada
1216. Innovative functional material, “biogenous iron oxide” (IV): Potential of electrochemical property of microtubes produced by Leptothrix ochracea as a novel
battery material. Hideki Hashimoto*,
Hiroshi Asaoka, Yoshifumi Watanabe,
Takashi Nishimori, Ryosuke Miyake,
Mitsuaki Furutani, Yoshihiro Kusano,
Noriyasu Kimura, Tomonari Kasai,
Tomoko Suzuki, Hitoshi Kunoh,
Yasunori Ikeda, Masaharu Seno,
Makoto Nakanishi, Tatsuo Fujii,
Jun Takada
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
Convention Center
Kamehameha Halls II and III
Olefin Oligomerization and Polymerization
Catalyzed by Early Transition Metals (#22)
Organized by: K. Theopold, K. Mashima,
Z. Xie
Presiding: K. Theopold
Poster Session
19:00 – 21:00
1217. Titanium catalysts for the copolymerization of the ethylene with functional olefins. Xiao-Hong Yang, Xiu-Li Sun,
Yong Tang
1218. Ancillary ligand effect on mono-, bis-,
and tris-(2-alkyl/aryl-phenoxy) titanium(IV)
chlorides. Tae-Jin Kim, Sung-Kwan Kim,
Jong Sok Hahn, Sang Ook Kang*
1219. Ethylene tetramerization catalysts
based on Cr(III)/DPPDME and optimization of their catalytic performance by
modification of phenyl substituents on
phosphines. Jae-Ho Chung,
Tae-Jin Kim, Sung-Kwan Kim,
Sang Ook Kang*
1220. Mass spectrometry and synthetic investigations of methylaluminoxane and
related derivatives. Tyler Trefz,
Scott McIndoe*
1221. Synthesis, characterization and catalytic activity of a new {(2-pyridylimines)Ni(Br)2} catalysts for ethylene polymerization. Ibrahim M. Al-Najjar*,
Abdulhamid A. Alsaygh,
Mohammad H. Al-Musawi
1222. New palladium aryl sulfonate phosphine catalysts for the preparation of
functionalized polyolefins: Synthesis,
characterization, and studies of intermediates. Laurence Piché*,
Jean-Christophe Daigle,
Jerome P. Claverie
1223. Cationic organizinc lactide polymerization catalysts supported by P-chiral ancillary ligands. Hudson Sun,
Craig A. Wheaton, Paul G. Hayes*
Convention Center
Kamehameha Halls II and III
Organoboron, Organosilicon and
Organophosphorus as Optoelectronic and
Energy-related Materials (#35)
Organized by: S. Wang, F. Jaekle,
Y. Wang, S. Yamaguchi
Presiding: S. Wang
Poster Session
19:00 – 21:00
1224. Photochemical reactions of phenylated cyclic 8 and 6-memberd germoxanes. Takafumi Miyoshi, Hidekazu Arii,
Masanobu Wakasa, Kunio Mochida*
1225. Synthesis of optically active pentavalent phosphorus compounds having sulfur or selenium atoms using prolinol as an
asymmetric source. Kazuya Shido,
Hajime Maeda*, Masahito Segi*
1226. Fabrication and properties of oligosilane nanocrystals including aromatic
compounds: The first observation of exciplex-like emission of oligosilanes with aromatic compounds. Yuki Morita,
Kenkichi Sakamoto*
1227. Synthesis of ␲-curved molecules with
phosphorus junction via intramolecular
tandem phospha-Friedel-Crafts reaction.
Sigma Hashimoto, Tsuyoshi Oba,
Takuji Hatakeyama*,
Masaharu Nakamura*
1228. Substituent effects on the intramolecular double cyclization of phosphanyl,
boryl-substituted diphenylacetylenes.
Eriko Yamaguchi*, Aiko Fukazawa,
Emi Ito, Hiroshi Yamada,
Shigehiro Yamaguchi
1229. Synthesis and properties of 3,6-diarylsubstituted 1,2-dihydro-1,2-azaborine.
Takuhiro Taniguchi,
Shigehiro Yamaguchi
1230. Preparation and photophysical properties of oligosilanes with various aromatic substituents. Takeshi Kida,
Yuji Shibata, Yuki Morita,
Kenkichi Sakamoto*
1231. Reduction of base-stabilized difluoroborane compounds with one-electron
reducing agents. Yoshitaka Aramaki,
Makoto Yamashita*, Kyoko Nozaki*
1232. Borole-containing ladder ␲-conjugated compounds. Azusa Iida,
Shigehiro Yamaguchi*
1233. Selective cleavage of carbon-phosphorous bond of phosphonium salts: A
facile synthesis of unsymmetrical phosphines. Naohisa Nakagawa,
Yuya Yoshimoto, Takuji Hatakeyama,
Masaharu Nakamura*
1234. ␲-Conjugated disilenes bearing polycyclic aromatic groups stabilized by bulky
“Rind” groups. Megumi Kobayashi*,
Daisuke Hashizume, Takeo Fukunaga,
Tsukasa Matsuo, Kohei Tamao
Convention Center
Kamehameha Halls II and III
The Construction of Photofunctional
Supramolecular Metal Complexes (#94)
Organized by: M. Kato, P. Ford,
G. Hanan, H. Ishida, V. Yam
Presiding: M. Kato
Poster Session
19:00 – 21:00
1235. Photoluminescence properties of
mononuclear europium(III) complexes
with tetradentate Schiff base ligands:
Emission intensity differences which depend on the variation of ligands and
counter anions.
Masanobu Tsuchimoto*, Shouta Ebato,
Masayuki Watanabe, Kiyohiko Nakajima
1236. Direct observation of photo-excited
state geometrical change of copper(I)
hexanuclear complex by crystallographic
studies under photo-illumination.
Yoshiki Ozawa*, Toru Ishida,
Koshiro Toriumi
1237. Crystalline-state photochromism of
rhodium dithionite complexes: Crystal
stabilization factors. Hidetaka Nakai*,
Yousuke Miyano, Kiyoshi Isobe
1238. Luminescence change by the solvent
of crystallization, solvent reorganization,
and vapochromism of neutral dicyanoruthenium(II) complex in the solid state.
Kazuteru Shinozaki*, Taichi Abe,
Takayoshi Suzuki
1239. Tb(III) complexes as probes for phosphotyrosine sensing. Jun Sumaoka*,
Hiroki Akiba, Yuki Watanabe,
Makoto Komiyama*
1240. Coordination compounds for energy
applications - complexes of indolizino[2,3-b]quinoxaline-derived ligands.
Christopher Sumby*
1241. Photoinduced electron transfer processes of BODIPY-triphenylamine-linked
platinum triad system. Shuichi Suzuki*,
Nobuhiro Ieki, Ryoji Sugimura,
Takahiro Naitoh, Masatoshi Kozaki,
Kazutoshi Keyaki, Koichi Nozaki,
Noriaki Ikeda, Keiji Okada*
1242. Carbon nitride as a metal-free polymeric photocatalyst for water splitting under visible light. Kazuhiko Maeda,
Xinchen Wang, Markus Antonietti,
Kazunari Domen*
1243. Syntheses and emissive properties of
mixed-halogeno silver(I) complexes with
4,4=-bipyridine. Kiyoshi Tsuge,
Masaaki Dosen, Yoshitaka Kawada,
Shoji Ishizaka, Noboru Kitamura,
Masako Kato, Yoichi Sasaki
1244. Photoluminescent properties of chalcohalide-capped octahedral hexarhenium(III) complexes. Takashi Yoshimura,
Ayumi Matsuda, Yuki Ito, Akitaka Ito,
Shoji Ishizaka, Satoshi Shinoda,
Hiroshi Tsukube, Noboru Kitamura,
Atsushi Shinohara
1245. Photophysical properties of novel
fused and native polyaryl-bipyridinium
dyes and their RU(II) and OS(II) molecular
dyads for charge separtion.
Fausto Puntoriero, Francesco Nastasi,
Sebastiano Campagna, Jérôme Fortage,
Fabien Tuyèras, Philippe Lainé
1246. Synthesis and photophysics of ruthenium(II) polypyridyl supramolecular complexes linked with gold(I) or platinum(II)
organometallics. Michito Shiotsuka*,
Naoki Nishiko, Katsuya Sako,
Kazutoshi Keyaki, Koichi Nozaki
1247. Form and function: Luminescent corners composed of platinum(II), a dithiolene, and two divergent diimines.
Bradley W. Smucker*, Paul J. Derry,
Mina Zilaie, Sam Oats, Jon A. Payne,
Rathna Nuti
1248. Highly luminescent terbium(III) complex having N-phenylcarbazolyl-functionalized pentamethylcyclopentadienyl ligands. Takeshi Yatabe, Hidetaka Nakai*,
Koichi Nozaki, Kiyoshi Isobe
1249. Synthesis and photo-energy harvesting phenomenon of multinuclear metal
complexes: Mesoporous organosilica superhybrids. Kazuhide Koike*,
Youhei Yamamoto, Tatsuto Yui,
Hiroyuki Takeda, Shinji Inagaki,
Osamu Ishitani*
1250. Self-assembly of zinc chlorins assisted
by polypeptides. Tomohiro Miyatake*,
Yumi Mukai, Mikiya Watanabe
1251. Synthesis of tumor-targeting lanthanide complexes for time-gated fluorescence imaging. M. Inoue, T. Ito*,
E. Kusaka, K. Akamatsu, K. Tanabe,
S. Nishimoto*
1252. Unique light energy collections and
transfers between the oreganosilica and
the metal complexes. Tatsuto Yui,
Keita Sekizawa, Hiroyuki Takeda,
Kazuhide Koike, Shinji Inagaki,
Osamu Ishitani*
1253. Magneto-chiral dichroism of porphyrin
J-aggregates. Yuichi Kitagawa,
Hiroshi Segawa, Kazuyuki Ishii*
1254. Isolation and characterization of extramembranous light-harvesting complexes from the green sulfur photosynthetic bacterium containing unnatural
bacteriochlorophyll c. Risato Nishimori,
Tadashi Mizoguchi, Hitoshi Tamiaki,
Yoshitaka Saga*
1255. Photoreactions and luminescence
properties of the metal complexes related
to protonation and deprotonation behavior of the hydrazone ligands.
Kiyohiko Nakajima*, Daisuke Yamada,
Yukari Taguchi, Hiroyuki Horiki,
Atsushi Kobayashi, Ho-Chol Chang,
Masako Kato
1256. Flexible emission properties of self-associated platinum(II) complexes functionalized with long alkyl-chains.
Mayu Yanagida, Atsushi Kobayashi,
Ho-Chol Chang, Masako Kato
1257. Effect of macrocyclic structures on
demetalation properties of zinc complexes of cyclic tetrapyrrole molecules.
Yoshitaka Saga*, Sayaka Hojo,
Yuki Hirai
1258. Flexible cubane-like framework in
crystalline state: Structure and luminescent properties of [Cu4I4(PPh3)4].
Hakuba Kitagawa*, Yoshiki Ozawa,
Yuichi Akahama, Haruki Kawamura,
Koshiro Toriumi
1259. Development of photo-hydrogenevolving molecular devices by an inclusion complex. Masanari Hirahara*,
Shigeyuki Masaoka, Ken Sakai
1260. Electronic structure and ligand molecule dependence of emission wavelength
of binuclear metal complex.
Masahiro Kenmotsu*, Tomohiko Ishii,
Kiyoshi Tsuge, Yoichi Sasaki,
Genta Sakane
1261. Self-aggregates of zinc chlorin dyads
possessing an oligo-oxyethylene linker.
Tomohiro Miyatake*, Fumika Sasaki,
Hitoshi Tamiaki
1262. Theoretical and experimental studies
of adsorption spectra of palladium porphyrin. Yusuke Kataoka*, Konomi Sato,
Yasutaka Kitagawa, Toru Saito,
Yasuyuki Nakanishi, Takashi Kawakami,
Wasuke Mori, Kizashi Yamaguchi,
Mitsutaka Okumura
1263. Novel ruthenium(II) polypyridyl complexes having arylborane charge transfer
units (1): Spectroscopic and photophysical properties. Yuki Ando, Akitaka Ito,
Eri Sakuda, Noboru Kitamura*
1264. Physical property measurements of
MV[Ni(dmit)2]2 in search of optical switchable conductor. Takahiro Takano*,
Yukihiro Takahashi, Toshio Naito,
Tamotsu Inabe
1265. Zero-field splitting parameters of
phosphorescent states in highly emissive
iridium(III) complexes with tridentate ligands. Koichi Nozaki,
Hiroaki Kawakami*, Munetaka Iwamura,
Masa-aki Haga
1266. Synthesis and optical properties of
mono-, di-, and tri-␤-diketone metal
complexes attaching chlorophyll derivatives. Yusuke Kinoshita*,
Youhei Yamamoto, Hitoshi Tamiaki
1267. Novel ruthenium(II) polypyridyl complex having an aylborane charge transfer
unit (2): Photochemical properties.
Ayu Kurahashi, Yuki Ando, Akitaka Ito,
Eri Sakuda, Noboru Kitamura*
1268. Novel ruthenium(II) polypyridyl complexes having arylborane charge transfer
units (3): Spectroscopic properties of
dendric complexes. Eri Sakuda,
Yuki Ando, Akitaka Ito, Noboru Kitamura*
1269. Synthesis and photophysical properties of novel platinum(II) complexes having arylborane charge transfer units.
Eri Sakuda, Noboru Kitamura*
1270. Dual emission behavior of alkynelinked dinuclear ruthenium(II) complexes.
Eri Sakuda, Kousuke Mochida,
Rikiya Tsugawa, Akitaka Ito,
Noboru Kitamura*
1271. Emission properties and photofunctionality of cyclometalated dinuclear platinum(II) complexes. Rie Aoki*,
Atsushi Kobayashi, Ho-Chol Chang,
Masako Kato
1272. Syntheses and photochemical hydrogen evolution of multifunctional photocatalysts of dinuclear rhodium complexes
tethered to polyoxometalates.
Saya Tanaka, Shigeyuki Masaoka,
Garry S. Hanan, Ken Sakai*
1273. Synthesis and spectroscopic properties of cyclometalated iridium(III) complexes having arylborane charge transfer
units (2). Takeo Hirokawa, Akitaka Ito,
Eri Sakuda, Noboru Kitamura*
1274. Synthesis of macrocyclic multinuclear
ruthenium complexes and their inclusion
behavior and photochemical reaction.
Motowo Yamaguchi*, Makoto Obara,
Kiyoshi Sato
1275. Photochemistry of the hydroxyporphycene and its metal complexes.
Toru Okawara, Masaaki Abe*,
Hisashi Shimakoshi, Yoshio Hisaeda*
1276. Synthesis and photochemical properties of new hybrid systems constructed
with polyoxometalates and ring-shaped
Re(I) multinuclear complexes.
Tsuyoshi Asatani*, Yuki Nakagawa,
Tatsuki Morimoto, Tatsuto Yui,
Osamu Ishitani
1277. Face-selective hydride reduction of an
NAD(P)⫹ model compound using Ru(II)
complexes as photocatalyst.
Kichitaro Koga*, Osamu Ishitani
1278. Supramolecular metal complexes of
␲-conjugated acyclic oligopyrroles.
Takashi Hashimoto, Takuma Nishimura,
Hiroaki Kobayashi, Masahiro Hasegawa,
Hiromitsu Maeda*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–87
02-INOR
1279. Photocatalytic CO2 reduction for selective formation of formic acid using
multinuclear ruthenium(II) complexes.
Yusuke Tamaki, Kazuhide Koike,
Osamu Ishitani*
1280. Control of interfacial electron transfer
between Ru(II) complexes and semiconductors for constructing artificial photosynthesis. Keita Sekizawa,
Kazuhide Koike, Tatsuto Yui,
Osamu Ishitani*
1281. Cyclometallated ruthenium(II) complexes as sensitizers for dye-sensitized
solar cells. Takashi Funaki*,
Hiromi Funakoshi,
Nobuko Onozawa-Komatsuzaki,
Kazuyuki Kasuga, Mitsuhiko Kurashige,
Kazuhiro Sayama, Hideki Sugihara*
1282. Photochemical and photocatalytic
properties of rhenium(I) complexes bearing a viologen moiety.
Tatsuki Morimoto*, Osamu Ishitani
1283. Enhanced solid-state luminescence of
the Cd complex of 6-aminoterpyridine
dimer. Yuka Kamoya, Keisuke Kojima,
Toshiki Mutai, Koji Araki*
1284. Withdrawn
1285. Design and synthesis of C3-symmetric
iridium complexes targeting homotrimer
proteins. Hiroki Ohwada,
Yasuki Matsuo, Shuhei Ohtawa,
Masanori Kitamura, Shuhei Ogawa,
Ryo Abe, Hideo Yagita, Kou Okumura,
Shin Aoki
1286. Photo-excitation energy transfer from
ruthenium(II) complex to chromate(III)
complex in double complex salt and
aqueous solution. Takuhiro Otsuka*,
Youkoh Kaizu
1287. Enhancement of emission properties
of metal complexes through ligand deuteration. Taichi Abe, Akira Miyazawa,
Hideo Konno, Yuji Kawanishi*
Convention Center
Kamehameha Halls II and III
Chemistry of Sulfur-Bridged Multimetallic
Complexes (#96)
Organized by: T. Rauchfuss, Y. Mizobe,
G. Jin
Presiding: T. Rauchfuss
Poster Session
19:00 – 21:00
1288. Synthesis and redox properties of [1:3]
site differentiated [4Fe-4S] clusters coordinated by carboxylates and imidazoles.
Tamaki Terada, Tsuyoshi Matsumoto,
Kazuyuki Tatsumi*
1289. Synthesis of coordinatively unsaturated mesityl-iron-thiolate complexes and
their reactions with elemental sulfur.
Takayoshi Hashimoto*, Yasuhiro Ohki,
Kazuyuki Tatsumi
1290. Efficient formation of organorhodium
macrocycles via C-H activation directed
self-assembly. Ying-Feng Han, Hao Li,
Guo-Xin Jin
1291. Synthesis of [MoFe3S4] cubane clusters from molybdenum trisulfido complexes bearing a
{bis(pyrazolyl)methyl}siloxy ligands.
Shunsuke Senda, Yasuhiro Ohki,
Kazuyuki Tatsumi*
1292. Application of Co-Ag dodecanuclear
thiolato complexes toward eco-friendly
type antimicrobial agent.
Toshiaki Yonemura*, Keisuke Fujihara
1293. Sulfurization-triggered migration of an
alkyl ligand at an Ir-Re dinuclear complex.
Akizumi Nezaki, Kazuya Arashiba,
Yuichiro Mutoh, Youichi Ishii*
Convention Center
Kamehameha Halls II and III
Advances in Nuclear Chemistry of
Transactinide Elements (#218)
Organized by: Y. Nagame, C. Duellmann,
H. Nitsche, P. Schwerdtfeger, Z. Qin
Presiding: Y. Nagame
88 –TECH
TECHNICAL PROGRAM
Poster Session
19:00 – 21:00
1294. Study on nuclear fusion reactions of
oxygen-16 on targets of deformed nuclei.
Akihiko Yokoyama*, Miwako Arai,
Atsushi Asano, Hideki Kaiya,
Hidetoshi Kikunaga, Norikazu Kinoshita,
Kazuhiro Ooe, Naruro Takahashi,
Tadashi Saito
1295. Measurement of excitation function of
natLu(p,xn)175Hf and gas-jet transfer experiments of Hf for online solvent extraction of rutherfordium. Yuki Kikutani*,
Yukiko Komori, Kazuhiro Ooe,
Hiroyuki Fujisawa, Ai Kuriyama,
Reona Takayama, Hidetoshi Kikunaga,
Yoshitaka Kasamatsu,
Takashi Yoshimura, Naruto Takahashi,
Atsushi Shinohara
1296. Measurement of the first ionization potential of Lr. Nozomi Sato*, Masato Asai,
Kazuaki Tsukada, Tetsuya K. Sato,
Atsushi Toyoshima, Zijie Li,
Yuichiro Nagame, Matthias Schädel,
Shin-ichi Ichikawa
1297. Cation-exchange behavior of rutherfordium, 104Rf, in H2SO4/HNO3 mixed
solutions ([H⫹] ⫽ 1.0 M). Zijie Li,
A. Toyoshima, K. Tsukada, M. Asai,
Y. Kasamatsu, T. Sato, N. Sato,
T. Kikuchi, X. Liang, Y. Nagame, H. Haba,
S. Goto, K. Akiyama, M. Nishikawa,
Y. Takeda, M. Murakami, S. Igarashi,
K. Sueki
1298. FIA-based continuous extraction system for superheavy element chemistry.
Yuki Kudou*, Hiromitsu Haba,
Yoshitaka Kasamatsu, Kosuke Morita
1299. Development of an on-line liquid scintillation ␣-particle detection system for
aqueous chemical studies of superheavy
elements. Yukiko Komori*,
Kazuhiro Ooe, Hiroyuki Fujisawa,
Ai Kuriyama, Reona Takayama,
Yuki Kikutani, Hidetoshi Kikunaga,
Yoshitaka Kasamatsu,
Takashi Yoshimura, Naruto Takahashi,
Hiromitsu Haba, Yuki Kudou,
Atsushi Shinohara
1300. New apparatus AIDA-II for aqueous
chemistry of the heaviest elements.
Kazuaki Tsukada,
Yoshitaka Kasamatsu, Masato Asai,
Atsushi Toyoshima, Yasuo Ishii,
Yuichiro Nagame
1301. Gas chromatographic behavior of
chloride compounds of group-4 elements. Hirofumi Murayama*,
Masashi Murakami, Shinichi Goto,
Hisaaki Kudo, Kazuaki Tsukada,
Masato Asai, Atsushi Toyoshima,
Tetsuya K. Sato, Yuichiro Nagame
Convention Center
Kamehameha Halls II and III
Chemistry and Materials Science at High
Pressures (#239)
Organized by: Y. Song, I. Butler, Y. Lee,
R. Manaa
Presiding: Y. Lee
Poster Session
19:00 – 21:00
1302. Zirconium tungstate in deep water oil
wells: A cure for annular pressure buildup. Robert E. Hermes*
1303. Stability of CO2 hydrate in Ulleung basin sediment suspension.
Kyoungjin Lee*, Woojin Lee*
1304. High-pressure Raman study of N,
N-diethyl-N-methyl-N-(2-methoxyethyl)
ammonium tetrafluoroborate-H2O mixtures. Yusuke Imai*, Takahiro Takekiyo,
Hiroshi Abe, Yukihiro Yoshimura
1305. Structural transition in iron-based superconductors under high pressure.
Jing geng Zhao, Lu Hong Wang,
Da Wei Dong, Zhi Guo Liu, Zhen Hai Yu,
Hao Zhe Liu, Yong Yu, Chang Qing Jin
1306. High-pressure gas adsorption properties of several microporous coordination
polymers. Yusuke Kataoka,
Wasuke Mori*, Kazuki Masuda,
Yuhei Miyazaki, Konomi Sato,
Satoshi Ozeki, Hiroshi Matsuda
1307. Synthesis and properties of binary ytterbium germanides prepared by highpressure and high-temperature reactions.
Momoko Harada, Hiroshi Fukuoka*,
Kei Inumaru
1308. Thermal parameters of sodium atoms
in the type II silicon clathrate single crystal Na24Si136. Masaya Komatsu,
Kei Inumaru, Shoji Yamanaka*
1309. High-pressure synthesis and superconductivity of the ternary compound
Ca2Al3Si4. Yuki Tanaka, Kei Inumaru,
Shoji Yamanaka*
Convention Center
Kamehameha Halls II and III
New Frontiers in Polyoxometalate
Chemistry (#251)
Organized by: M. Nyman, C. Boskovic,
N. Mizuno, L. Xu
Presiding: M. Nyman
Poster Session
19:00 – 21:00
1310. Uranyl peroxide nanoclusters grown
from U (VI) mineral phases.
Ginger E. Sigmon, Angela Schad,
Peter C. Burns*
1311. Synthesis, structural characterization,
and Lewis acid catalysis of a novel dialuminum-substituted silicotungstate.
Yuji Kikukawa, Kazuhiro Uehara,
Sayaka Uchida, Kazuya Yamaguchi,
Noritaka Mizuno*
1312. All-inorganic coordination chemistry of
polyoxovanadates as macrocyclic ligands. Yoshihito Hayashi*
1313. Selective oxidation of organosilanes to
silanols with hydrogen peroxide catalyzed by a lacunary polyoxotungstate.
Keigo Kamata, Ryo Ishimoto,
Noritaka Mizuno*
1314. Withdrawn
1315. Magnetic and conductive polypyrrole
prepared by chemical oxidation of Keggin
anion [Co(III)W12O40]5-. Lin Xu*,
Liping Jia
1316. [In(pydc)(Hpydc)(H2O)][In(pydc)(Hpydc)/
(CH3COO)]H5 [SiW12O40].7H2O: A new
tetranuclear indium cluster based on silicotungstate. Jingping Wang, Suzhi Li,
Jingyang Niu
1317. Forming processes of high dimensional Mo-O framework for the
[Mo36O112(H2O)16]8- compounds with
1,3-diamino-2-propanol. Kazuo Eda*,
Tatsuya Koduka, Yuichi Iriki
1318. Effect of basic solvents on dissociation of the protonated decavanadate
dimers into the monomers by using 51VNMR. Tatsuhiro Kojima, Tomoji Ozeki*
1319. New expanding application of polyoxometalate solids: Thin films, phosphors, and ionic conductors.
Haruo Naruke*
1320. New rare earth metal-organic framework with isolated guest Keggin silicotungstate fragments as anion templates.
Jingyang Niu, Suzhi Li, Jingping Wang
1321. Structure control of inorganic-organic
hybrid composites based on supramolecules and polyoxometalates.
Kazuhiro Uehara, Noritaka Mizuno*
1322. Structural chemistry and molecular
chirality in sandwich-type polyoxometallolanthanoates. Jun Iijima,
Haruo Naruke
1323. Counterion effect on the self-assembly
of functionalized polyoxometalate-surfactants. Dong Li*, Jie Zhang, Panchao Yin,
Andrew J. Bassler, Jie Song,
Craig L. Hill*, Tianbo Liu*
1324. Novel octaperoxophosphotetratungstate. Masato Hashimoto,
Katsutoshi Kato*, Shinnya Kitaura
1325. Novel peroxohexatungstate.
Masato Hashimoto, Akitsugu Shiga*
1326. Construction of zero- to 2-D POMbased compounds through adjusting the
metal cations and polyanions.
Jun Peng*, Pengpeng Zhang,
Haijun Pang, Min Zhu, Dandan Wang,
Mingguan Liu
1327. Straightforward method for making
versatile Keggin polyoxometalate microtubes: Toward component-tunable tubular structure. Jun Peng*, Yan Shen,
Haijun Pang, Pengpeng Zhang,
Dan Chen, Changyun Chen,
Huanqiu Zhang
1328. Surfactant with Dawson type polyoxometalates as polar head: A concentration
and water dependent single-layer vesicle
to multilayer vesicle transition.
Panchao Yin*, Dong Li, Emily Bitterlich,
Tianbo Liu*, Leroy Cronin*
1329. Syntheses of inorganic-organic hybrid
crystals composed of octamolybdates
and a surfactant with ␲ electrons.
Keisuke Mikurube, Yukihiro Abe,
Takeru Ito*, Haruo Naruke,
Takahisa Koroki, Tomoji Ozeki
1330. Inorganic-organic hybrid crystals constructed by polyoxomolybdate and cationic surfactant. Takeru Ito*,
Toshihiro Yamase
1331. Resolution and crystal structure determinaton of optically active chiral
POM,[H4Mo10Co2O38]6-. Uk Lee*,
Hea-Chung Joo
1332. Efficient epoxidation of homoallylic alcohols with H 2O2 catalyzed by a selenium-containing peroxotungstate.
Tomohisa Hirano, Shinjiro Kuzuya,
Keigo Kamata*, Noritaka Mizuno
1333. Assembly of crown ether alkali metal
supermolecular complexes with metaloxide cluster. Xiaoming Lu*
1334. Structural studies of Ln series all-inorganic macrocyclic polyoxovanadate
complexes by X-ray structures and EXAFS. Masaki Nishio, Yoshihito Hayashi*,
Misaki Katayama, Kazuhiko Ozutsumi
1335. Synthesis and molecular structure of a
sandwich-type aluminum(III) complex
composed of Keggin-type tri-lacunary
polyoxotungstate. Chika Kato*,
Yurika Katayama, Masao Kato,
Miyuki Nakagawa, Masaru Nagami,
Mikio Yamasaki
1336. Conductivity and thermal stability of
polyoxomolybdophosphates.
Eri Ishikawa*, Yuji Hayashi,
Kenich Imaeda, Makoto Watanabe
Hilton
South Pacific III
Nanoscale Characterization of Functional
Materials by Nuclear Probes (#275)
Organized by: K. Nomura, A. Hill,
J. Stevens, H. Wei, Y. Yamada
Presiding: K. Nomura
19:00 – 1337. Mössbauer study of corrosion
resistance of steel coated with Zn and
Zn-Al alloy. Yasufumi Morinaga*,
Sachiko Fujimoto, Yasuhiro Yamada,
Yoshio Kobayashi
19:05 – 1338. Mössbauer study of iron nitride films produced by pulsed laser deposition. Ryo Usui*, Yasuhiro Yamada,
Yoshio Kobayashi
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
19:10 – 1339. Study on the magnetism and
anomalous behavior of 57Fe Mössbauer
spectra for iron(II) complex coordinated
by verdazyl radical. Hajime Kamebuchi*,
Atsushi Okazawa, Masaya Enomoto,
Jun Harada, Keiichiro Ogawa,
Masashi Okubo, Cyrille Train,
Michel Verdaguer, Norimichi Kojima
19:15 – 1340. Dilute magnetic properties of
Fe doped Al2O3 powders prepared by a
sol gel method. Kiyoshi Nomura*,
Jun Okabayashi, Ryosuke Kinoshita,
Isao Sakamoto
19:20 – 1341. Observation of local fields in
impurity-doped ZnO by means of the TDPAC method. Sayaka Komatsuda*,
Wataru Sato, Yoshitaka Ohkubo
19:25 – 1342. Mössbauer studies of linear
two-coordinate Fe complexes with bulky
arylthiol ligands. Yoshio Kobayashi,
Takashi Nagatomo, Mikinao Ito,
Tsukasa Matsuo, Yoshiaki Shoji,
Isao Watanabe, Yasuyuki Ishii,
Kohei Tamao
19:30 – 1343. Highly efficient and stable
iron-hydroxyapatite supported gold catalyst for CO oxidation. Kunfeng Zhao,
Junhu Wang, Botao Qiao, Yanjie Zhang,
Changzi Jin, Tao Zhang
19:35 Discussions for all short presentations
in this evening session
Sunday Morning
Convention Center
Kamehameha Halls II and III
Inorganic General Posters
Poster Session
10:00 – 12:00
Coordination chemistry
1344. New insights into the stability of lanthanide-Kläui complexes. Kevin Allen*,
Emma Nicholls-Allison*, David J. Berg
1345. Relationship between photophysical,
chiroptical, and structural properties of
lanthanide-containing complexes.
Bao Le, Servando G. Ponce,
Gilles Muller*
1346. Dinuclear tantalum(III)
complexes[Ta2Cl6(L)3] (L ⫽ sulfide type ligands): Preparation, structures, and the
catalytic activity for the regioselective cyclotrimerization of alkynes.
Masatohsi Matsuura, Takashi Fujihara*,
Akira Nagasawa
1347. Photomagnetic properties of iron(II)
spin crossover complexes based on stilbene-attached ligands.
Kazuhiro Takahashi,
Michihiro Nishikawa, Yuta Hasegawa,
Shoko Kume, Hiroshi Nishihara
1348. Kinetics and mechanism of trans-tooxo ligand substitution in the oxo-carboxylate triply bridged diruthenium(III) complex. Yohei Ido, Kiyoshi Sakaguchi,
Minako Tasei, Suguru Minami,
Takashi Fujihara, Akira Nagasawa*
1349. Syntheses, molecular structures and
electrochemical properties of mono- and
dinuclear nickel(II) complexes with 2,5diamino-1,4-benzoquionediimines.
Keiji Ohno, Takashi Fujihara*,
Akira Nagasawa
1350. Synthesis and characterization of Pdindole complexes. Takuya Suzuki,
Yuichi Shimazaki, Tatsuo Yajima,
Tadashi Shiraiwa
1351. Synthesis, crystal structure, and physical properties of new multinuclear platinum complexes. Yosuke Konno,
Ken Sakai
1352. Synthesis, carbohydrate- and DNAbinding studies of cationic 2,2’:6’,2’’- terpyridineplatinum(II) complexes containing
N- and S-donor boronic acid ligands.
Simin S. Hosseini*, Mohan Bhadbhade,
Ronald Clarke, Peter Rutledge,
Louis Rendina
1353. Double ring inversion of bipyrimidine
coordinated to copper correlated to redox behavior. Yusuke Takara,
Tatsuya Masui, Michihiro Nishikawa,
Shoko Kume, Hiroshi Nishihara
1354. Withdrawn
1355. Synthesis and characterization of the
novel phosphines with a ferrocene skeleton. Fumio Ando*, Hua Hong,
Jugo Koketsu
1356. Withdrawn
1357. Thermal and antimicrobial aspect of
poly[(2-hydroxy,4-butoxy) butylene] ligand and its polychelates with lanthanides (III). Vasant M. Patel
Organometallic reactions
1358. Synthesis of imino- and aminophosphine containing pincer ligands: Metal
complexation and ligand reactivity.
Michael J. Sgro, Douglas W. Stephan*
1359. Synthesis of hydrophilic iminophosphorane organogold (III) complexes:
Study of their cytotoxicity against solid
tumors in vitro and their interaction with
biomolecular targets. Monica Carreira,
Fangwei Liu, Claribel Nunez, Laura Vela,
Isabel Marzo, Maria Contel*
1360. Efficient cyclopropylation of carbonyl
compounds and imines using low-valent
samarium species. Akishi Nitta,
Daiki Noro, Masaki Tsushima,
Yasuo Yokoyama*, Shoko Suzuki
1361. Synthesis, characterization, and MMA
polymerization activity of cobalt(II) and
iron(II) catalysts bearing new [bpmaL] ligands. Hyosun Lee*, Minkyu Yang,
Jong Hwa Jeong
1362. Ring-opening polymerization of lactide
using well-defined cationic zinc catalysts.
Craig A. Wheaton, Paul G. Hayes*
1363. Activation and reduction of CO2 by
aluminum-based frustrated Lewis pairs.
Gabriel Menard, Douglas W. Stephan*
1364. Synthesizing frustrated Lewis pairs for
applications in the activation of small
molecules and catalysis.
Cheryl A. Tanur, Douglas W. Stephan*
1365. Activation of olefins by bulky m-terphenyl aluminum hydrides.
Christopher E. Melton*, Philip P. Power
1366. Formation of diaryl telluroxides and
tellurones by photosensitized oxygenation of diaryl tellurides. Makoto Oba*,
Yasunori Okada, Kazuhito Tanaka,
Kozaburo Nishiyama, Wataru Ando
Surface metal complexes
1367. Preparation and electrochemical properties of metal complex oligomer wires on
the Si(111) surface. Hiroaki Maeda*,
Yoshinori Yamanoi, Hiroshi Nishihara
1368. Development of a novel method for
Pd-catalyzed arylation of hydrogen-terminated Si(111) wafers. Junya Sendo*,
Yusuke Yabusaki, Yoshinori Yamanoi,
Hiroshi Nishihara
Coordination polymers
1369. Multizonal crystalline systems and
self-assembly: A summary of results.
S Russell Seidel*, Kathryn E. Dorst,
Abigail V. Hunter, Mia Jurjevic,
Joseph S. Campanelli, Kenneth L. Martin,
Carly S. Anderson, Russell G. Baughman,
Juan C. Alicea, Andrew Barthelmess,
Sara B. Spector, Richard T. Wilkens,
Russell Ainbinder
1370. Interpenetrated giant metal-organic
frameworks from bulky organic building
unit. Cheng-Hua Lee, Kuang-Lieh Lu
1371. Single-crystal to single-crystal (SCSC)
transformations at discrete dimeric copper complexes and polymeric mercury
complexes. Mobin Shaikh,
Pradeep Mathur, Lahiri K. Goutam
Inorganic solids
1372. Iodometric quantification of electron
incorporated in 12CaO7Al2O3.
Toshihiro Yoshizumi*, Hideo Hosono,
Katsuro Hayashi
1373. Preparation of thermally stable ␥-alumina powders from La3⫹-doped polyhydroxoaluminum composite gels.
Tomohiro Yamaguchi*, Susumu Hinata,
Takayuki Fujita, Seiichi Taruta,
Kunio Kitajima
1374. Different solid phases and liquid phase
of K2TaF7 and other potassium fluorotantalates. Miroslav Boca*
1375. Addition of water retentive compounds on preparation of titanium phosphate pigments. Taisuke Yamaguchi*,
Hiroaki Onoda
1376. Preparation of porous phosphate with
various acidic and basic compounds.
Hiroaki Onoda*
1377. Synthesis, acid and base resistance of
nickel-cerium(⫹III) phosphate pigments.
Takeshi Sakumura*, Hiroaki Onoda
1378. Studies on the reaction kinetics between nitrous acid and n,n-dimethylhydroxylamine. Gaoliang Li*, Hui He*
1379. Synthesis of poly[(2-hydroxy,4-butoxy)
butylene] resin and its ion-exchange
study with lanthanides (III).
Jayantilal D. Joshi*, Dineshbhai R. Patel
Hilton
Hibiscus I/II
Functional Molecule-Based Magnets (#25)
Organized by: M. Yamashita,
G. Christou, J. Miller, K. Murray,
T. Sugawara, R. Thompson
Presiding: T. Sugawara, J. Miller
7:30 – 1380. Routes to porous magnets
based on spin clusters. Annie Powell*
8:00 – 1381. M(TCNE)x-based (TCNE ⫽ tetracyanoethylene) magnets: New materials and a structure-function relationship.
Joel S. Miller
8:30 – 1382. Quantum entanglements and
manipulation of molecular-spin qubits by
pulsed electron magnetic multiple resonance technique. Kazunobu Sato*,
Nakazawa Shigeaki, Robabeh Rahimi,
Tomohiro Yoshino, Ayaka Tanaka,
Tomoaki Ise, Shinsuke Nishida,
Kazuo Toyota, Daisuke Shiomi,
Yasushi Morita, Masahiro Kitagawa,
Hideyuki Hara, Patrick Carl, Peter Höfer,
Takeji Takui*
8:45 – 1383. Polymetallic oxalate-based 2-D
magnets: Soluble molecular precursors
for the nanostructuration of magnetic oxides. Carlos Martí-Gastaldo*,
Eugenio Coronado,
José R. Galán-Mascarós,
Massimiliano Cavallini
9:05 – 1384. Pressure-induced sequential
orbital reorientation in a magnetic framework material. Gregory Halder*,
Karena Chapman, John Schlueter,
Jamie Manson
9:20 – 1385. Approach to create a universal
2-D spectrochemical series.
Tomohiko Ishii*, Shino Tsuboi,
Genta Sakane, Masahiro Yamashita,
Brian K. Breedlove
9:35 – 1386. Ferrimagnetic mixed-valence
and mixed metal formate analogs of
Prussian blue. Karl S. Hagen*,
Sunil K. Naik, Boi H. Huynh,
Antonio Masello, George Christou
9:55 – 1387. Pyrazine-bridged 2-D QHAFs:
Highly isolated systems. Veli Selmani,
Christopher P. Landee,
Mark M. Turnbull,
Joaquim Jornet-Somoza, Mercè Deumal,
Juan J. Novoa, Tom Lancaster,
Stephen Blundell
10:15 – 1388. 1-D molecular aggregates of
self-associated nitroxide biradicals: A solution to biradical paradox.
Yuki Kanzaki*, Daisuke Shiomi,
Takatoshi Sawai, Kazunobu Sato,
Keiji Okada, Takeji Takui
10:30 – 1389. Optical and electrical responses of organic radical materials.
Kunio Awaga*
11:00 – 1390. First-principles study of the
mechanism of the magnetic biestability in
the TTTA (1,3,5-trithia-2,4,6-triazapentalenyl) magnet. Caroline S. Clarke,
Joaquim Jornet, Fernando Mota,
Mercè Deumal, Juan J. Novoa*
Hilton
Coral II
Dioxygen Activation Chemistry and
Catalytic Oxidation Reactions (#108)
Organized by: S. Itoh, W. Nam,
A. Rosenzweig, W. Tolman
Presiding: W. Nam, W. Tolman
7:30 – 1391. Bio-inspired hydrocarbon oxidation by nonheme iron catalysts.
Lawrence Que*
8:05 – 1392. Dioxygen activation of oxoperoxodiiron complexes: Effect of carboxylate donors of supporting ligand.
Masahito Kodera*, Tomohiro Yasunaga,
Yutaka Hitomi
8:40 – 1393. Reactivity of peroxo-diiron(III)
and -dicopper(II) complexes: Functional
models for dioxygen activating dimetalloenzymes. Masatatsu Suzuki*
9:15 – 1394. Biomimetic C-H activation by
binuclear high-valent iron complexes.
Julia B. Strautmann, Stephan Walleck,
Susanne Dammers,
Carl-Georg Frhr. v. Richthofen,
Thorsten Glaser
9:40 – 1395. Structural and spectroscopic
characterization and reactivities of metaloxygen intermediates in dioxygen activation chemistry. Wonwoo Nam*
10:15 – 1396. Utilizing noncovalent interactions in metal-mediated activation of dioxygen: Detecting high valent oxometal
species and determining their role in oxidative processes. A. S. Borovik*
10:50 – 1397. Proton-coupled electron
transfer in dioxygen chemistry.
Jim Mayer*, Mauricio Cataneo,
Christopher R. Waidmann,
Shoshanna M. Barnett, Scott A. Ryken,
Tristan A. Tronic, Colin T. Carver,
Jeffrey J. Warren, Thomas R. Porter,
Alexander R. Fox
Hilton
Coral I
Self-Assembly and Coordination Chemistry
(#164)
Organized by: M. Fujita, L. MacGillivray,
L. Stephen, S. Y Yu, M. Yoshizawa
Presiding: S. Loeb, M. Takeuchi,
M. Higuchi
7:30 – 1398. Coordination self-assemblies:
Design and synthesis. Makoto Fujita*
7:45 – 1399. Supramolecular materials from
multifunctional ␤-diketones.
Andrew W. Maverick*, Chandi Pariya,
Jackson K. Cherutoi, Frank R. Fronczek
8:15 – 1400. Versatility of supramolecular
coordinationchemistry. Rolf Saalfrank*
8:45 – 1401. Self-assembled main group coordination complexes.
Virginia M. Cangelosi,
Justin L. Crossland, Sean A. Fontenot,
Darren W. Johnson*
9:00 – 1402. f-Directed synthesis and the
photophysical evaluations of lanthanide
luminescent self-assembly supramolecular structures. Thorfinnur Gunnlaugsson
9:15 – 1403. Tape- and capsule-shaped anthracene oligomers. Michito Yoshizawa*
9:30 – 1404. Neutral Re(I) metal complexes
as efficient anion binders. Samik Nag,
Amlan K. Pal, Garry S. Hanan*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–89
02-INOR
9:45 – 1405. Exploiting polydentate 1,2,3triazoles “click” ligands to generate functional metallosupramolecular architectures. James D. Crowley*, Kelly J. Kilpin,
Emma L. Gavey
10:00 – 1406. Transition-metal-bound peptide: Synthesis, structure, and functions.
Hikaru R. Takaya*, Daisuke Sasano,
Kazuki Ogata, Katsuhiro Isozaki,
Hirofumi Seike, Masaharu Nakamura
10:15 – 1407. Rotaxanes as ligands in metalligand self-assembly. Stephen Loeb*,
Elizabeth Viljoen
10:30 – 1408. Coordination-based abiotic
molecular machines. Chad Mirkin*
11:00 – 1409. Million fold rate enhancement
and chiral selectivity in a chiral cluster assembly. Kenneth N. Raymond,
Robert G. Bergman,
Courtney J. Hastings, Casey J. Brown
Hilton
Rainbow II
Advances in Nuclear Chemistry of
Transactinide Elements (#218)
Organized by: Y. Nagame, C. Duellmann,
H. Nitsche, P. Schwerdtfeger, Z. Qin
Presiding: Y. Nagame
7:30 – 1410. Production of new isotopes using the 242Pu(48Ca,5n)285114 nuclear reaction. Paul Ellison*, Ken Gregorich,
Jill Berryman, Darren Bleuel, Rod Clark,
Mario Cromaz, Irena Dragojevic,
Jan Dvorak, Paul Fallon,
Carolina Fineman-Sotomayor,
Jacklyn Gates, Oliver Gothe, I-Yang Lee,
Walter Loveland, Augusto Macchiavelli,
Joseph McLaughlin, Stefanos Paschalis,
Marina-Kalliopi Petri, Jing Qian,
Liv Stavsetra, Mathis Wiedeking,
Heino Nitsche
8:00 – 1411. Confirmations of the synthesis
of 278113 produced by the
209Bi(70Zn,n)278113 reaction.
Kouji Morimoto*, Kosuke Morita,
Daiya Kaji, Hiromitsu Haba,
Kazutaka Ozeki, Yuki Kudou,
Nozomi Sato, Takayuki Sumita,
Akira Yoneda, Takatoshi Ichikawa,
Yasuyuki Fujimori, Sin-ichi Goto,
Tianheng Huang, Eiji Ideguchi,
Yoshitaka Kasamatsu, Kenji Katori,
Yukiko Komori, Hiroyuki Koura,
Hisaaki Kudo, Masafumi Murakami,
Akira Ozawa, Ryutaro Sakai,
Fuyuki Tokanai, Kazuaki Tsukada,
Takayuki Yamaguchi, Atsushi Yoshida
8:30 – 1412. Bridging the gap from superheavy elements to the known nuclides:
The 48Ca⫹232Th reaction.
Jacklyn Gates*, Kenneth E. Gregorich,
Jill S. Berryman, Darren L. Bleuel,
Roderick M. Clark, Mario Cromaz,
Irena Dragojevic, Paul A. Ellison,
Paul Fallon, Oliver R. Gothe,
Walter D. Loveland,
Augusto O. Macchiavelli,
Joseph McLaughlin, Stefanos Paschalis,
Marina-Kalliopi Petri, Jing Qian,
Mathis Wiedeking, Heino Nitsche
9:00 – 1413. Decay properties of 261Rf and
262Rf. Shin-ichi Goto*,
Masashi Murakami, Hirohumi Murayama,
Hisaaki Kudo, Daiya Kaji, Koji Morimoto,
Hiromitsu Haba, Yoshitaka Kasamatsu,
Yuki Kudo, Kosuke Morita
9:30 – 1414. Anion-exchange behavior of Db
in HF and HNO3 mixed solution using an
on-line chemical apparatus.
Kazuaki Tsukada,
Yoshitaka Kasamatsu, Masato Asai,
Atsushi Toyoshima, Yasuo Ishii, Zijie Li,
Tetsuya K. Sato, Yuichiro Nagame,
Matthias Schaedel, Shin-ichi Goto,
T. Hasegawa, Hisaaki Kudo,
Hiromitsu Haba, Y. Kudou,
Hidetoshi Kikunaga, K. Ooe, H. Fujisawa,
Wataru Sato, Atsushi Shinohara,
Yasuji Oura, Kazuhiko Akiyama, T. Nanri,
M. Araki, Akihiko Yokoyama,
Keisuke Sueki
90 –TECH
TECHNICAL PROGRAM
10:00 – 1415. Electrolytic oxidation of nobelium with a microchannel-electrode chip.
Kazuhiro Ooe*, Yukiko Komori,
Hiroyuki Fujisawa, Ai Kuriyama,
Reona Takayama, Yuki Kikutani,
Hidetoshi Kikunaga,
Yoshitaka Kasamatsu,
Takashi Yoshimura, Naruto Takahashi,
Hiromitsu Haba, Yuki Kudou,
Yutaka Ezaki, Atsushi Shinohara
10:20 – 1416. On-line isothermal gas chromatographic behavior of group-5 elements as homologues of Db.
Tetsuya K. Sato*, Kazuaki Tsukada,
Masato Asai, Atsushi Toyoshima,
Yoshitaka Kasamatsu, Yasuo Ishii,
Zijie Li, Nozomi Sato, Takahiro Kikuchi,
Shaohu Liang, Yuichiro Nagame,
Matthias Schädel
10:40 – 1417. IRiS: Exploring new frontiers in
neutron-rich isotopes of the heaviest elements. Jan Dvorak*, Michael Block,
Christoph E. Düllmann, Sophia Heinz,
Rolf-Dietmar Herzberg, Matthias Schädel
11:10 – 1418. New gas-filled recoil ion separator GARIS-II developed for SHE study.
Daiya Kaji*, Kouji Morimoto,
Nozomi Sato, Akira Yoneda,
Hiromitsu Haba, Kazutaka Ozeki,
Takayuki Sumita, Kosuke Morita
Hilton
Rainbow I
Chemistry and Materials Science at High
Pressures (#239)
Organized by: Y. Song, I. Butler, Y. Lee,
R. Manaa
Presiding: R. Manaa
7:30 – 1419. Quantum chemical simulations
of tribochemical reactions.
Nicholas J. Mosey*
7:55 – 1420. Chemistry under pressure.
John S. Tse*
8:20 – 1421. Atomic-scale theoretical studies of energy transfer and inelastic deformation in condensed phase high explosives. Thomas Sewell*
8:45 – 1422. Equation of state of Titan’s interior: A thermo-chemical assessment.
Michaael Howard*, Sorin Bastea,
Bishun Khare, Chris McKay
9:00 – 1423. Calculation of activation and reaction volumes using molecular dynamics simulations. Nicholas Boon,
Elna Deglint, Essex Edwards,
Heather Martens, Paul Dance, Van Dinh,
Noham Weinberg*
9:15 – 1424. Synthesis of glycine-CO2 complexes in impacts of comets on early
Earth. Nir Goldman*, Evan J. Reed,
Laurence E. Fried, I-Feng W. Kuo,
Amitesh Maiti
9:30 – 1425. Unraveling shock-induced
chemistry using ultrafast lasers.
David S. Moore*, Shawn D. McGrane,
Cynthia A. Bolme, R. J. Scharff,
Margo Greenfield
9:55 – 1426. Journey to 3-D synchrotron Xray imaging and diffraction studies for
materials under high pressure extreme
conditions. Haozhe Liu*, Luhong Wang*,
Xianghui Xiao, Francesco De Carlo,
Peter Lee, Jon Almer
10:20 – 1427. Hydrogen chemistry and dynamics in compressed materials by highresolution diamond anvil cell NMR.
Takuo Okuchi*
10:45 – 1428. Synchrotron infrared spectroscopy under extreme conditions.
Zhenxian Liu
11:10 – 1429. Use of anomalous X-ray scattering and Monte-Carlo simulation for the
determination of the structures of amorphous materials at high pressure.
Simon M. Clark*, Bora Kalkan,
Alan K. Soper, Sabyasachi Sen
Hilton
South Pacific I
New Frontiers in Polyoxometalate
Chemistry (#251)
Organized by: M. Nyman, C. Boskovic,
N. Mizuno, L. Xu
Presiding: M. Nyman
7:30 – 1430. Counter-ion association and
exchange around polyoxometalate macroanions. Tianbo Liu*, Joseph M. Pigga
8:00 – 1431. Synthesis, morphology, and applications of polyoxometalate-containing
block copolymers. Josh Peng*,
Sanjiban Chakraborty
8:20 – 1432. The influence of heteropolytungstates on functional mobility of ribosomes. Ada Yonath
8:50 – 1433. Withdrawn
9:10 – 1434. Molecular nanomagnets from ligand substitution with polyoxometalates.
Xikui Fang*
9:30 – 1435. Electrochemical and photochemical studies on Dawson-type
[P2W18O62]6-, [S2W18O62]4- and
[S2Mo18O62]4- polyoxometalates as catalysts for water oxidation in ionic liquid
media. Alan M. Bond*,
Gianluca Bernardini, Anthony G. Wedd
10:00 – 1436. Thermal and mechanical properties of polymer nanocomposites containing surfactant encapsulated polyoxometalates. Lucas P. Johnson*,
Janis Matisons
10:20 – 1437. Two-electron reduced species, ␤-[PMo12O40]5- and [W10O32]6-, involved in UV-photolyses of heptametalates of Mo and W. Toshihiro Yamase*
10:50 – 1438. Unveiling the polyoxoniobates
architecture: High-nuclearity isopolyoxoniobates with pentagonal building blocks.
Ryo Tsunashima*, De L. Long,
Haralampos N. Miras, David Gabb,
Chullikkattil P. Pradeep, Leroy Cronin*
11:10 – 1439. Electrochemical and ion-pairing phenomena of [M6O19]8- (M⫽Nb,Ta).
Mark Antonio, May Nyman
Hilton
South Pacific III
Nanoscale Characterization of Functional
Materials by Nuclear Probes (#275)
Organized by: K. Nomura, A. Hill,
J. Stevens, H. Wei, Y. Yamada
Presiding: K. Nomura
7:30 – 1440. Positron and nuclear magnetic
resonance studies of phase evolution in
aluminium alloys. Timothy J. Bastow,
Matthew D. Lay,
Christopher R. Hutchinson, Anita J. Hill
8:00 – 1441. Positron annihilation lifetime
spectroscopy of hierarchically structured
porous materials. Cara Doherty*,
Anita J. Hill
8:20 – 1442. Positron annihilation study of
functional porous thin films. Kenji Ito*,
Yoshinori Kobayashi
8:40 – 1443. Development of positron probe
microanalyzer for a 2-D defect mapping.
Masanori Fujinami
9:00 – 1444. Vibrational studies of FeS clusters in NiFe-hydrogenase by means of
nuclear resonant vibrational spectroscopy. Saeed Kamali*
9:40 – 1445. Sn Mössbauer spectroscopy of
ZnO-SnO-P2O5 glasses.
Hiroyo Segawa, Satoru Inoue,
Kiyoshi Nomura
10:00 – 1446. Trichloroethylene (TCE) decomposing ability and local structure of
the Fe-Fe3O4 mixture. Shiro Kubuki*,
Kazuhiko Akiyama, Zoltan Homonnay,
Erno Kuzmann, Tetsuaki Nishida
10:20 – 1447. 155Gd Mössbauer spectroscopic and XRD study of solid solution of
CeO2 and Gd2O3. Masashi Takahashi*,
Kazutaka Imai, Shiro Matsukawa,
Etsuji Yamamoto, Akio Nakamura*
10:40 – 1448. Mössbauer spectroscopic investigations of novel bimetal catalysts for
preferential CO oxidation in H2. Kuo Liu,
Jie Yin, Wansheng Zhang, Junhu Wang,
Yanqiang Huang, Aiqin Wang,
Jianyi Shen, Tao Zhang
Hilton
Rainbow III
The Construction of Photofunctional
Supramolecular Metal Complexes (#94)
Organized by: M. Kato, P. Ford,
G. Hanan, H. Ishida, V. Yam
Presiding: V. Yam, G. Hannan, H. Ishida,
M. Kato
7:50 – 1449. Vapochromic behavior and vapor-induced self-organization of platinum
complexes with dicarboxybipyridine.
Masako Kato*, Tsubasa Yonemura,
Atsushi Kobayashi
8:05 – 1450. Mechanochromic and nonmechanochromic photoluminescence of
gold(I)-isocyanide complexes.
Hajime Ito*, Masaya Sawamura,
Sayaka Kurenuma, Takuma Okura
8:20 – 1451. Design and assembly strategies
toward photofunctional molecular and
supramolecular metal complexes.
Vivian W. Yam*
8:50 – 1452. Long-lived luminescence of d10
metal complexes. Taro Tsubomura*,
Kenji Matsumoto, Toshiaki Tsukuda
9:05 – 1453. Design of photoactivatable ligands and their complexes with tunable
isocyano rhenium(I) diimine luminophore.
Vincent Chi-Chiu Ko*
9:20 – 1454. Photochemical studies on Cr(III)
cyclam complexes: Photosensitization
with semiconductor quantum dots and
nitric oxide release. Peter C. Ford*,
Alexis D. Ostrowski
9:35 – 1455. Photochemistry of transition
metal complexes bearing arylborane
charge transfer units. Noboru Kitamura
9:55 – 1456. Spectroscopic and TD-DFT
characterization of charge transfer excited states of mono- and bi-metallic
complexes. John F. Endicott*,
Marco M. Allard, Onduro S. Odongo,
H. B. Schlegel
10:10 – 1457. Photophysical properties of
nine-coordinate Eu(III) complexes with tridentate phosphine oxides.
Yasuchika Hasegawa
10:25 – 1458. Two-photon absorbing
4-(9,9’-di(2-ethylhexyl)-7-diphenylaminofluoren-2-yl)-2,2’:6’,2”-terpyridine platinum complexes. Wenfang Sun*,
Zhiqiang Ji, Yunjing Li,
Timothy M. Pritchett, Nikolay S. Makarov,
Joy E. Haley, Aleks Rebane
10:40 – 1459. Phthalocyanine-based fluorescence probes for detecting Vitamin C.
Kazuyuki Ishii*, Kensuke Kubo,
Kikuo Komori, Yasuyuki Sakai
10:55 – 1460. Smart quantum dot sensors
for metabolic tumor profiling afforded by
supramolecular concepts.
Daniel G. Nocera
11:25 Closing remarks
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
Hilton
Kahili I/II
Hilton
Lehua Suite
Coordination Chemistry toward Artificial
Photosynthesis and Energy Conversion
Processes (#194)
Structural and Functional Aspects of
Coordination Polymers (#133)
Organized by: K. Tanaka, J. Muckerman,
K. Sakai, L. Sun
Presiding: K. Tanaka
7:50 Opening remarks
7:55 – 1461. Water oxidation by single site
molecular catalysts. Thomas J. Meyer
8:40 – 1462. Water oxidation goes via 7-coordination of Ru catalysts with low overpotentials. Licheng Sun*, Lele Duan,
Andreas Fischer, Yunhua Xu,
Lianpeng Tong
9:15 – 1463. Catalysis of mononuclear ruthenium complexes in oxygen evolution from
water. Shigeyuki Masaoka*,
Masaki Yoshida, Ayano Kimoto,
Kosei Yamauchi, Ken Sakai*
9:40 – 1464. Studies of oxomanganese complexes for natural and artificial photosynthesis. Victor Batista*,
Eduardo Sproviero, Ting Wang,
Declan Clarke, Gary Brudvig
10:15 – 1465. Water oxidation by mononuclear catalysts. Derek J. Wasylenko,
Chelladurai Ganesamoorthy,
Bryan D. Koivisto,
Matthew A. Henderson,
Curtis P. Berlinguette*
10:40 – 1466. Electrocatalytic water oxidation to oxygen at low overpotentials by a
manganese porphyrin dimer modified ITO
electrode. Zaki N. Zahran*,
Takehiro Ohta, Yoshinori Naruta
11:05 – 1467. Investigations of molecular
catalysts for water oxidation.
Derek J. Wasylenko,
Chelladurai Ganesamoorthy,
Mathew A. Henderson, Bryan D. Koivisto,
Curtis P. Berlinguette*
Hilton
Nautilus I & II
Organoboron, Organosilicon and
Organophosphorus as Optoelectronic and
Energy-related Materials (#35)
Organized by: S. Wang, F. Jaekle,
Y. Wang, S. Yamaguchi
Presiding: F. Jaekle
8:00 – 1468. Toward boron-functionalized
regioregular polythiophenes.
Frank D. Pammer, Haiyan Li,
Frieder Jäkle*
8:20 – 1469. Controlling amine-borane dehydrogenation with homogeneous catalysts. R. Tom Baker*
8:50 – 1470. Dually switchable, phosphorusbased heterotetracenes. Yi Ren,
Thomas Baumgartner*
9:10 – 1471. 9,10-Dihydro-9,10-diboraanthracene: A novel ditopic borane for hydroboration polymerization.
Matthias Wagner*, Andreas Lorbach*
9:40 – 1472. Phosphorus-containing pi-conjugated systems as sensory materials.
Takanobu Sanji*
10:00 – 1473. New applications of frustrated
Lewis pairs. Doug Stephan*
10:30 – 1474. Synthesis of triazolyl methylsubstituted thio-, amino-, and oxy-undecahydrododecaborates for potential
application to boron neutron capture
therapy. Hiroyuki Nakamura*,
Mohamed E. El-Zaria, Hyun Seung Ban,
Afaf R. Genady
10:50 – 1475. Catalytic routes to functional
main group polymers and materials.
Ian Manners*
Organized by: S. Telfer, S. Cohen,
D. Leznoff
Presiding: S. Telfer
8:20 – 1476. Porous coordination polymer
crystal on porous coordination polymer
(PCP on PCP). Shuhei Furukawa,
Kenji Hirai, Susumu Kitagawa*
9:00 – 1477. Novel metal-organic frameworks (MOFs) for asymmetric catalysis
and enantiomer separation.
Koichi Tanaka*, Ken-ichi Ootani,
Daisuke Hirayama
9:30 – 1478. Coordination polymers that can
be processed into gels and fibers.
Jagadese J. Vittal
10:00 – 1479. Chiral coordination polymers
from camphor: Directionality by design.
Christopher M. Fitchett, Peter J. Steel
10:30 – 1480. Developing chemical triggers
for spin state switching in coordination
complexes and materials.
Matthew Shores*, Zhaoping Ni,
Ashley M. McDaniel,
Stephanie R. Fiedler, Christina M. Klug
11:00 – 1481. Size controlled formation of
porous coordination polymers and thin
films on gold substrate.
Stephane Diring*, Shuhei Furukawa,
Hiromitsu Uehara, Susumu Kitagawa
Convention Center
Kamehameha Halls II and III
Molecular Design in Bioinorganic
Chemistry (#173)
Organized by: T. Hayashi, D. Goldberg,
P. Kennepohl, H. Masuda
Presiding: T. Hayashi
Poster Session
10:00 – 12:00
1482. Preparation and crystal structural
characterization of iron porphyrin nitrosamine compounds: Insights into the direct heme-nitrosamine interaction.
Nan Xu, Douglas R. Powell,
George B. Richter-Addo*
1483. Kinetic analysis of reduction of formyl
groups in chlorophylls and pheophytins.
Kana Sadaoka, Yoshitaka Saga*
1484. Hangman and Pacman corrole-complexes as biomimetic enzyme models.
Matthias Schwalbe*
1485. Synthesis and reactivity of a novel dicopper(II) complex as a benzene hydroxylation catalyst. Mana Goto*,
Yuji Kajita, Hideki Masuda
1486. Synthetic model studies for the
trinuclear copper cluster sites of multicopper oxidases. Kojiro Nagata,
Kensuke Fukui, Tomohiko Inomata,
Tomohiro Ozawa, Yasuhiro Funahashi,
Hideki Masuda*
1487. Biomimetic study of dioxygen-activation on dicopper complexes for understanding molecular mechanism of Tyrosinase. Tomoaki Toyama*, Kotaro Yoshii,
Yuko Wasada-TsuTsui, Yuji Kajita,
Tomohiko Inomata, Tomohiro Ozawa,
Hideki Masuda, Yasuhiro Funahashi
1488. Model reaction of methyl coenzyme M
reductase: Methane formation via C-S
bond cleavage of Ni(I) cyclam complexes
having methylthio-substituted pendant
chains. Jun-ichi Nishigaki,
Tsuyoshi Matsumoto, Kazuyuki Tatsumi*
1489. Electron from hydrogen and how to
get it. Takahiro Matsumoto*
1490. Structural characterization of N3S2 ligand field isomerism on bioinspired Ni(II)
centers. Michael Jensen*, Huaibo Ma,
Jeffrey L. Petersen, Victor G. Young
1491. Photoinduced electron-transfer reactions of dendrimer-type carbonic anhydrase inhibitors containing tris(2,2’-bipyridine)ruthenium(II) complex.
Hiroshi Takashima*, Fumie Nakagaki,
Pirika Awano, Keiichi Tsukahara
1492. Elucidation of metal-ion accumulation
on protein surfaces by using porous lysozyme crystals containing Rh(III) ions.
Satoshi Abe, Susumu Kitagawa,
Takafumi Ueno*
1493. Functional characteristics of hemerythrin-like domain from the perspective of its large substrate tunnel.
Yasunori Okamoto, Akira Onoda,
Takashi Hayashi*
1494. Artificial metalloenzyme constructed
by a covalently-linked rhodium(I) complex
within a protein matrix.
Kazuki Fukumoto, Akira Onoda,
Takashi Hayashi*
1495. Microbial defense against nitric oxide:
Scavenging mechanism of NO by flavodiiron proteins. Takahiro Hayashi*,
Jonathan Caranto, David A. Wampler,
Donald M. Kurtz, Pierre Moënne-Loccoz
1496. Control of electronic structures of oneelectron oxidized products of iron(III) porphyrin complexes by means of axial ligands and deformation mode of
porphyrin ring. Akira Ikezaki*,
Mikio Nakamura
1497. Seeking the low-spin iron(III) porphyrinoids with the purest (dxz, dyz)4(dxy)1
ground state. Akira Ikezaki*,
Jyunpei Ono, Yoshiki Ohgo,
Mikio Nakamura
1498. Electronic structure of highly ruffled
low-spin iron(III) porphyrinates with electron withdrawing heptafluoropropyl
groups at the meso positions.
Akira Tozuka, Miyoko Taniguchi,
Souhei Kouno, Akira Ikezaki,
Yoshiki Ohgo, Mikio Nakamura*
1499. QM/MM study on water-assisted oxo
mechanism for heme oxygenase.
Tomonori Nishimi, Takashi Kamachi,
Kazunari Yoshizawa
1500. Withdrawn
1501. Comparative and in vitro activity study
of some organotin(iv) carboxylate derivatives against leukemia cancer cell, l-1210.
Sutopo Hadi*, Mita Rilyanti,
Yuli Ambarwati
1502. Syntheses and photodynamic activities of sugar linked in porphyrin as a dual
drug of diagnostic imaging and photodynamic therapy. Misaki Nakai*,
Tomohiro Maeda, Shigenobu Yano,
Shiho Sakuma, Eiko Otake,
Akimichi Morita, Yasuo Nakabayasi
1503. Mercury(II)-selective fluorescent response of bisquinoline derivatives with
thioether linkage. Yuji Mikata*,
Fumie Nakagaki
1504. Metallo-thiacalix[4]arenetetrasulfonate
as an artificial peroxidase mimesis and its
application to clinical chemistry.
Shinjiro Tsukikawa, Hirotaka Ohsaki,
Masahiko Inoguchi, Junichi Odo
1505. Synthesis, characterization, and antitumor activity of cisplatin type Pt(II) and
Pd(II) complexes containing a Schiff base
derived from amino sugar. Hiromi Ohi*,
Akio Toshimitsu, Shigenobu Yano
1506. Gold nanoparticles modified electrodes: Effect of particle size on electrochemical response of metalloproteins.
Masato Suzuki, Kenichi Murata,
Nobuhumi Nakamura*, Hiroyuki Ohno
1507. Photochemical and electrochemical
properties of B12-Ru(bpy)3 catalytic system. Junichi Aoki, Hisashi Shimakoshi,
Masaaki Abe, Yoshio Hisaeda*
1508. Solution structural and functional
study of the Helicobacter pylori prolyl
isomerase and chaperone SlyD.
Hongyan Li, Tianfan Cheng, Wei Xia,
Hongzhe Sun*
Sunday Afternoon
Hilton
Hibiscus I/II
Functional Molecule-Based Magnets (#25)
Organized by: M. Yamashita,
G. Christou, J. Miller, K. Murray,
T. Sugawara, R. Thompson
Presiding: A. Powell, K. Awaga
12:30 – 1509. Spin-transition-like behavior of
radical chelate complexes accompanied
by twisted deformation around a
copper(II)⫺nitroxide coordination bond.
Atsushi Okazawa*, Takayuki Ishida,
Norimichi Kojima
12:45 – 1510. Synthesis and magnetic properties of dialkoxy-substituted dithiazolyl
radicals. Jeremy M. Rawson*,
Efren Navarro, Robert Less,
Antonio Alberola
13:15 – 1511. Paramagnetic thiazyl and
selenazyl ligands: Intermolecular interactions. Kathryn E. Preuss*
13:35 – 1512. Organic metallic magnet exhibiting giant negative magnetoresistance. Tadashi Sugawara,
Hideji Komatsu, Ryusuke Kondo,
Michio M. Matsushita, Kentaro Suzuki
14:05 – 1513. Heavy atom radicals as conductive and magnetic materials.
Richard T. Oakley
14:35 – 1514. Magnetic and optical properties of functional cyanoaurate-based coordination polymer materials.
Daniel Leznoff*
14:55 – 1515. Novel magnetic functionalities
on cyano-bridged metal assemblies.
Ohkoshi Shin-ichi*
15:25 – 1516. Atypical resposnses of metal
polycyanide networks to external stimuli.
Kosmas Prassides*
15:45 – 1517. Light-induced phase collapse
in a rubidium manganese hexacyanoferrate. Hiroko Tokoro, Shin-ichi Ohkoshi
16:00 – 1518. Photoeffects in nanometer
scale heterostructures of Prussian blue
analogs. Daniel R. Talham*,
Mark W. Meisel*, Matthieu F. Dumont,
Daniel M. Pajerowski, Matthew J. Andrus,
Elisabeth S. Knowles
Hilton
Coral II
Dioxygen Activation Chemistry and
Catalytic Oxidation Reactions (#108)
Organized by: S. Itoh, W. Nam,
A. Rosenzweig, W. Tolman
Presiding: C. Riordan, T. Kojima
12:30 – 1519. Dioxygen activation by nickel
complexes: Strategies, structures, and
reactivity. Charles G. Riordan*
13:05 – 1520. Design of bio-inspired homogeneous and heterogeneous oxidation
catalysts. Shiro Hikichi*
13:40 – 1521. Selective and catalytic oxygenation by ruthenium complexes with
water as an oxygen source.
Takahiko Kojima*
14:15 – 1522. Oxygen-atom transfer reactions of ruthenium complexes bearing
macrocyclic tertiary amine ligands.
Tai Chu Lau*
14:50 – 1523. Withdrawn
15:25 – 1524. Developing catalysts for hydrocarbon oxidation. Melanie Sanford
16:00 – 1525. Environmentally benign iron
catalysts using hydrogen peroxide for epoxidations of olefins. Kristin Schroeder,
Kathrin Junge, Man K. Tse,
Matthias Beller*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–91
02-INOR
TECHNICAL PROGRAM
Hilton
Lehua Suite
Hilton
South Pacific I
Structural and Functional Aspects of
Coordination Polymers (#133)
New Frontiers in Polyoxometalate
Chemistry (#251)
Organized by: S. Telfer, S. Cohen,
D. Leznoff
Presiding: S. Cohen
Organized by: M. Nyman, C. Boskovic,
N. Mizuno, L. Xu
Presiding: M. Nyman
12:30 – 1526. Coordination polymers with
variable length ligands and multifunctional nanoballs. Stuart Batten*
13:00 – 1527. Controlled synthesis of coordination polymer particles (CPPs) and
their utilization. Moonhyun Oh*
13:30 – 1528. Doping, conductivity, and redox chemistry of a dithiolene-based
metal organic framework.
Yoji Kobayashi, Benjamin Jacobs,
Mark D. Allendorf, Jeffrey R. Long
14:00 – 1529. Synthesis, structure, and spin
structure of chiral magnets.
Katsuya Inoue*
14:30 – 1530. Mixed-component and tagged
metal-organic frameworks.
Andrew D. Burrows
15:00 – 1531. Dithiolene complexes as metallo-ligands. Marc Fourmigue*,
Olivier Jeannin, Alessia Famengo
15:30 – 1532. Design of photo-controllable
magnetic and superconducting materials.
Yasuaki Einaga*
16:00 – 1533. Synthesis and magnetic interactions in low-dimensional copper halides coordination polymers.
Susan N. Herringer, Jan L. Wikaira,
Christopher P. Landee,
Mark M. Turnbull*
12:30 – 1546. Polynuclear transition metal
clusters based on lacunary polyoxometalates. Yang-Guang Li*, Zhi-Ming Zhang,
Qiong Wu, Yong-Hui Wang, Ying Lu,
En-Bo Wang*
13:00 – 1547. Molecular cluster batteries of
polyoxometalate materials.
Hirofumi Yoshikawa, Shun Hamanaka,
Naoya Kawasaki, Heng Wang,
Toshihiko Yokoyama, Kunio Awaga
13:20 – 1548. Lacunary polyoxometalates as
ligands for lanthanoid complexes with interesting electronic and magnetic properties. Colette Boskovic*, Chris Ritchie,
Evan Moore, Manfred Speldrich,
Paul Kögerler
13:40 – 1549. Polyoxometalate materials
with optical, magnetic or electrocatalytic
properties. Pierre Mialane*,
Anne Dolbecq
14:10 – 1550. Organic-inorganic hybrid gels
created from polyoxometalate-containing
molecules. Wei Wang*, Bo Liu*, Jie Yang,
Yongliang Wang, Miao Yang,
Zijian Zhang, Yaokun Han,
Ingo Lieberwirth, Christian Kübel
14:30 – 1551. Polyoxometalates in molecular
spintronics. Eugenio Coronado*,
Salvador Cardona-Serra,
Juan M. Clemente-Juan,
Elena Pinilla-Cienfuegos, Nicolas Suaud
15:00 – 1552. Reversible photoswitchable
fluorescence in thin films of inorganic
nanoparticle and polyoxometalate assemblies. Shaoqin Liu*, Hongyue Chen,
Bin Qin, Zhiyong Tang
15:20 – 1553. From magnetic polyoxometalates toward molecular spintronics.
Paul Kögerler*
15:50 – 1554. Polymeric peroxometalates.
Masato Hashimoto*, Akitsugu Shiga,
Hiroki Sasakura, Hiroaki Adachi,
Takashi Tanaka, Tomohiro Minami,
Hiroaki Fujiwara, Taichi Sato
16:10 – 1555. Magnetic polyoxometalates in
molecular electronics.
Juan M. Clemente-Juan*,
Salvador Cardona-Serra,
Eugenio Coronado,
Alejandro Gaita-Ariño, Nicolas Suaud,
Juan J. Palacios
Hilton
Coral I
Self-Assembly and Coordination Chemistry
(#164)
Organized by: M. Fujita, L. MacGillivray,
L. Stephen, S. Y Yu, M. Yoshizawa
Presiding: Y. Shu-Yan, Y. Matsuo,
Y. Negishi
12:30 – 1534. Macrocyclization by continuous metal-metal bonding. Shu-yan Yu*
12:45 – 1535. Functional metal oxide containers. Leroy Cronin*
13:15 – 1536. Some new aspects of inorganic self-assembly. Xintao Wu*
13:45 – 1537. Precise synthesis and characterization of thiolate-protected Au25-nMn
(M ⫽ Pd or Au) bimetallic clusters.
Yuichi Negishi*
14:00 – 1538. Metallacrown cavitands that
bind either cation or anion guests.
Malcolm A. Halcrow*
14:15 – 1539. Controlled fabrication of
fullerene into microsphere of nanoplates
through porphyrin polymer assisted selfassembly. Masayuki Takeuchi*,
Xuan Zhang
14:30 – 1540. Supramolecular chirality in
self-assembled LB films and organogel.
Minghua Liu*, Li Zhang, Penglei Chen,
Tianyu Wang
14:45 – 1541. Device application of organicmetallic hybrid polymers with electrochromic properties. Masayoshi Higuchi*
15:00 – 1542. Self-assembly of cationic metal-organic nanocages as models for soluble macrocations in solution.
Tianbo Liu*, Dong Li
15:15 – 1543. Organic and organometallic
fullerene derivatives having self-assembly
capabilities. Yutaka Matsuo*
15:30 – 1544. Multinuclear calixarene-cobalt
complexes in the nucleation, growth, and
self-assembly of magnetic nanostructures. Alexander Wei*
16:00 – 1545. Edible MOFs in the making.
Fraser Stoddart*, Ronald A. Smaldone,
Ross S. Forgan, Hiroyasu Furukawa,
Alexandra M. Slawin,
Jeremiah J. Gassensmith, Omar M. Yaghi
92–TECH
Hilton
Rainbow I
Chemistry and Materials Science at High
Pressures (#239)
Organized by: Y. Song, I. Butler, Y. Lee,
R. Manaa
Presiding: I. Butler
12:50 – 1556. Investigations of the behavior
of completely siliceous zeolite ZSM-5 under high external pressures. Yueqiao Fu,
Song Yang*, Yining Huang*
13:15 – 1557. High pressure transformations
in water and semiconductor clathrates.
Chris A. Tulk*, A. Moreira dos Santos,
J. Neuefeind, J. Molaison, D. Klug,
V. Honkimaki, B. Sales
13:40 – 1558. Structural study of hydrogenated fullerenes under high pressure.
Bingbing Liu*, Xuemei Zhang,
Quanjun Li, Honglei Ma,
Thomas Wågberg, Bertil Sundqvist
14:05 – 1559. High-pressure studies of hydride complexes by Raman and infrared
spectroscopy. Ang Liu*, Yang Song*
14:25 – 1560. Spectroscopic investigation of
high-pressure gas absorption into a
small-pore zeolite. Dan Liu*, Weiwei Lei*,
Zhenxian Liu*, Yongjae Lee*
14:40 – 1561. High-pressure polymerization
of liquid pyridine. Christian D. Grant*,
I-Feng Kuo, Jonathan C. Crowhurst
14:55 – 1562. High-pressure behavior of a
family metal formates, [PA⫹][M2⫹(CHO2)3], PA ⫽ protonated amine (e.g. DMA⫹),
M ⫽ Mg2⫹, Co2⫹, Mn2⫹ and Zn2⫹.
John B. Parise*, Lauren A. Borkowski
15:20 – 1563. High-pressure transitions of
earth’s materials and analog materials:
Post-spinel and post-perovskite transitions. Masaki Akaogi*,
Shoichi Tsukamoto, Hiroshi Kojitani,
Yuichi Shirako, Akito Enomoto
15:45 – 1564. In situ XAS aaainvestigations
of the adsorption of metal aions on metal
oxide nanoparticles in aqueous fluids to
500 °C. Robert A. Mayanovic*,
Alan J. Anderson, Peter R. Meredith,
William A. Bassett
16:10 – 1565. High-pressure chemistry with
periodic mesostructured materials.
Kai Landskron*, Paritosh Mohanty,
Yingwei Fei, Li Zhang, Ho-Kwang Mao,
Neil Coombs, Ilke Arslan, Nigel Browning,
Volkan Ortalan
16:25 Concluding remarks
Hilton
Kahili I/II
Coordination Chemistry toward Artificial
Photosynthesis and Energy Conversion
Processes (#194)
Organized by: K. Tanaka, J. Muckerman,
K. Sakai, L. Sun
Presiding: K. Tanaka
13:00 – 1566. Artificial photosynthesis using
metal complexes. Osamu Ishitani*
13:35 – 1567. Solar fuel generation using
transition metal complexes.
Etsuko Fujita*, James T. Muckerman
14:10 – 1568. Toward the development of
artificial photosynthesis generating hydrogen energy from water and sunlight.
Ken Sakai*
14:45 – 1569. Hydrogen production by hydrogenase-inspired Ni and Co complexes
in acetonitrile and water: Are pendant
bases necessary in aqueous solution?
James T. Muckerman, Etsuko Fujita,
Yolanda A. Small, Jonathan Skone
15:20 – 1570. Hydrogen evolution at low
overpotentials. Jonas C. Peters*
15:55 – 1571. Photocatalytic H2 production
by noble metal-free molecular catalysts.
Mei Wang*, Pan Zhang, Jingfeng Dong,
Xueqiang Li, Licheng Sun
Sunday Evening
Convention Center
Kamehameha Halls II and III
Functional Molecule-Based Magnets (#25)
Organized by: M. Yamashita,
G. Christou, J. Miller, K. Murray,
T. Sugawara, R. Thompson
Presiding: M. Yamashita
Poster Session
19:00 – 21:00
1572. Magnetic anisotropy designed SMM
including Er(III) ion. Aika Yamashita,
Akiko Watanabe, Takashi Kajiwara,
Shigehisa Akine, Tatsuya Nabeshima,
Motohiro Nakano, Tomoo Yamamura
1573. Monodysprosium(III) SMM with extremely high barrier for magnetic relaxation. Akiko Watanabe, Aika Yamashita,
Takashi Kajiwara, Motohiro Nakano,
Tomoo Yamamura
1574. Control of charge-transfer in the
[Ru2]2TCNQ system: Isolation of fully
charge-transferred complexes with
TCNQ2-. Takaumi Morita*,
Hiromichi Kamo*, Natsuko Motokawa*,
Hitoshi Miyasaka*, Masahiro Yamashita*
1575. Chromium acetylide based magnetic
materials. Junichi Nishijo,
Nobuyuki Nishi
1576. Construction of a novel topological
frustrated system: A frustrated metal
cluster in a helical space.
Satoshi Kawata*, Ryuta Ishikawa,
Akira Fuyuhiro, Sumio Kaizaki,
Motohiro Nakano, Tetsuya Takeuchi,
Shojiro Kimura, Takanari Kashiwagi,
Masayuki Hagiwara, Koichi Kindo
1577. Charge transfer induced spin transition in a cyanide-briged molecular
square. Yoshihiro Sekine,
Masayuki Nihei, Hiroki Oshio*
1578. Dielectric properties of ferromagnetic
(fluoroanilinium)([18]crown-6)[MnCr(ox)3]
salts. Endo Toru*, Akutagawa Tomoyuki,
Noro Shin-Ichiro, Nakamura Takayoshi
1579. Organic polyanionic high-spin molecules with topological pseudo-degeneracy as models for organic ferromagnetic
metals. Shigeaki Nakazawa*,
Kazunobu Sato, Daisuke Shiomi,
Masafumi Yano, Takamasa Kinoshita,
Luisa Franco, Celina Lazana,
Candida Shohoji, Koichi Itho, Takeji Takui
1580. Spin equilibrium of cationic FeIII complex [FeIII(Hqhna)2]Cl. Sohey Enomoto,
Motohiro Nakano
1581. Molecular structure and magnetic
property of CuII2 FeIII2 tetranuclear complex. Yuta Maeyoshi, Motohiro Nakano
1582. Synchronicity in valence tautomeric
bistability and macroscopic phase transitions. Ho-Chol Chang*, Daisuke Kiriya,
Susumu Kitagawa
1583. Synthesis and magnetic property of
tri-nuclear Co(II) complex with bis(catecholate) ligand. Yusaku Suenaga*,
Yuki Nakaguchi, Yasuhiro Fujishima,
Hisashi Konaka, Koji Okuda
1584. Chemically sensitive magnetization in
octacyanido bimetallic assemblies.
Daisuke Takahashi, Kenta Imoto,
Yoshihide Tsunobuchi, Shin-ichi Ohkoshi
1585. Observation of ferroelectricity on
cyano-bridged metal assembly-based
magnets. Kosuke Nakagawa,
Hiroko Tokoro, Shin-ichi Ohkoshi
1586. Structures and magnetic prperties in
photoresponsive heterospin dinuclear
single-molecule magnets having various
substituents. Daisuke Yoshihara*,
Satoru Karasawa, Noboru Koga
1587. Synthesis, crystal structures and magnetic properties of [1,2,5]thiadiazolo[3,4f][1,10]phenanthroline 1,1-dioxide salts: A
new anion radical/ligand for moleculebased magnetism. Yoshiaki Shuku*,
Rie Suizu, Kunio Awaga
1588. Diamino triazole-based ligands as
polynuclear cluster building blocks.
Graham N. Newton, Hiroki Oshio
1589. Facile preparation of UCl3(thf)1.5 and
its pyridine adducts for SMM studies.
Tomoo Yamamura*, Suguru Ohta,
Isamu Satoh, Takashi Kajiwara,
Tatsuo Shikama
1590. Crystal structures and magnetic properties on the nitrate complexes with tridentate N-donors ligands.
Junichi Nishioka*, Shinji Kanegawa,
Osamu Sato
1591. Modification of charge-transfer in a
2-D donor/acceptor metal-organic framework by the insertion of electronic meddler into interlayer electronegative pockets. Miho Takemura, Natuko Motokawa,
Hitoshi Miyasaka, Masahiro Yamashita
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
02-INOR
1592. Magnetic/conducting bifunctionality
due to conjugated functional moieties in a
stacked ferrimagnetic chain.
Yuichiro Asai*, Natsuko Motokawa,
Kazuya Kubo, Hitoshi Miyasaka,
Masahiro Yamashita
1593. Synthesis and self-assembly of oxovanadium(IV) and related metal complexes.
Chihiro Maeda*, Naoki Yoshioka*
1594. Synthesis and magnetic properties of
quadruple-decker phthalocyanine complexes. Wakako Kuroda,
Takamitsu Fukuda*, Akira Fuyuhiro,
Naoto Ishikawa
1595. Physical properties of a conductor
based on axially substituted ruthenium
phthalocyanine. Tatsuya Nakatsugawa,
Yukihiro Takahashi, Toshio Naito,
Tamotsu Inabe
1596. Geometric control of ground state in
copper verdazyl complexes.
David Brook*, Janice Wong,
Khan Van-Tu, Gordon Yee,
Michael Hundley, David Rogow
1597. Magnetic bistability in alkylferrocenium salts coupling with a liquid-solid
phase transition. Yusuke Funasako*,
Takashi Inagaki, Tomoyuki Mochida,
Takahiro Sakurai, Hitoshi Ohta,
Ko Furukawa, Toshikazu Nakamura
1598. Study on the spin equilibrium and
magnetic ordering in
Ph4P[MnIIFeIII(mto)3] (Ph ⫽ C6H5, mto ⫽
C2O3S). Koichi Kagesawa*,
Atsushi Okazawa, Masaya Enomoto,
Norimichi Kojima
1599. Very strong ferromagnetic exchange in
a new verdazyl analog of terpyridine.
David Brook*, Cardius Richardson,
Benjamin C. Haller, Gordon Yee,
Michael Hundley
1600. Theoretical study of magnetic interactions in ringed complexes.
Yasutaka Kitagawa*, Yusuke Kataoka,
Toru Saito, Yasuyuki Nakanishi,
Takashi Kawakami, Shusuke Yamanaka,
Mitsutaka Okumura, Kizashi Yamaguchi
1601. Synthetic strategies for the rational improvement of triplesalen-based singlemolecule magnets (SMMs).
Bastian Feldscher, Hubert Theil,
Thorsten Glaser
1602. Magnetic and electronic properties of
triple-decker phthalocyanine complexes
having two 4f-systems and an unpaired
␲-electron. Takashi Nishikawa*,
Takamitsu Fukuda, Akira Fuyuhiro,
Naoto Ishikawa
1603. Preparation and magnetic properties
of [Mo(CN)7]-based magnet.
Asuka Namai, Keisuke Tomono,
Yoshihide Tsunobuchi, Koji Nakabayashi,
Shin-ichi Ohkoshi*
1604. Spin crossover molecular sensors operating below, around and above room
temperature. Anil D. Naik,
Marinela M. Dîrtu, Aurelian Rotaru,
Léonard Spinu, Dirk Poelman,
Jacqueline Marchand-Brynaert,
Yann Garcia*
1605. Multifunctional metallomesogens
based on the dynamic electrons.
Shinya Hayami*
1606. Magneto-optical spectra of colored
magnetic thin films composed of cyanido-bridged metal assembly.
Yoshiaki Funato, Hiroko Tokoro,
Wataru Kosaka, Shin-ichi Ohkoshi
1607. Octacyanoniobate-based magnets
with novel functionalities. Kenta Imoto,
Wataru Kosaka, Yoshihide Tsunobuchi,
Shin-ichi Ohkoshi
Convention Center
Kamehameha Halls II and III
Dioxygen Activation Chemistry and
Catalytic Oxidation Reactions (#108)
Organized by: S. Itoh, W. Nam,
A. Rosenzweig, W. Tolman
Presiding: S. Itoh
Poster Session
19:00 – 21:00
1608. Monooxygenase activity of arthropod
hemocyanin subunits.
Nobutaka Fujieda, Aki Yakiyama,
Shinobu Itoh
1609. Roles of zinc and iron in peptide amidation. Chizu Shimokawa, Saori Harada,
Yuichiro Higashimoto, Hideaki Sato,
Masakazu Sugishima, Masato Noguchi*
1610. Reactivity of mononuclear copper(II)
alkylperoxo complexes. Tetsuro Tano,
Minoru Kubo, Takashi Ogura,
Nobutaka Fujieda, Hideki Sugimoto,
Shinobu Itoh
1611. Structural and functional models for
the active site of quercetin 2,3-dioxygenase: Ligands effects. Ying-Ji Sun*,
Yi-An Gao, Yun-Xia Wang,
Qian-Qian Huang, Yang Liu, Shinobu Itoh
1612. Model substrate and complexes for
the active site of acireductone dioxygenase. Ying-Ji Sun*, Yun-Xia Wang,
Yi-An Gao, Qian-Qian Huang, Yang Liu,
Jinheung Kim
1613. Theoretical study of methane-tomethanol conversion by pMMO.
Yoshihito Shiota, Kzunori Hori,
Kazunari Yoshizawa*
1614. Mechanistic studies on the intramolecular debenzylation by copper-dioxygen
complexes supported by TPA derivatives.
Tomoaki Mizukawa, Masayasu Taki*,
Naoko Sakai, Yukio Yamamoto
1615. Insights into the mechanism and stereospecificity of deoxyhypusine hydroxylase, a non-heme diiron enzymes involved in regulating eukaryotic cell
growth. Van V. Vu, Myung H. Park*,
Lawrence Que*
1616. Nonheme Fe(II) enzymes: The role of
structure revisited. Cristiana Di Giuro,
Cornelia Konstantinovics,
Grit D. Straganz*
1617. Catalytic C-H oxygenation by tailormade binuclear iron complexes mimicking the active site of soluble methane
monooxygenase. Stephan Walleck,
Thorsten Glaser
1618. Effect of metal ions on electron-transfer properties of oxoiron species: Control
of reaction mechanisms by selecting
metal ions. Yuma Morimoto*,
Hiroaki Kotani, Yong-Min Lee,
Wonwoo Nam, Shunichi Fukuzumi
1619. Mononuclear carboxylate-rich oxoiron(IV) complexes. Aidan R. McDonald*,
Lawrence Que
1620. Simple and efficient iron catalyst for
epoxidation of aromatic olefins with 30%
hydrogen peroxide. Takefumi Chishiro*,
Kazuya Iwao, Yoshihiro Kon,
Kazuhiko Sato
1621. DFT study of the mechanism of oxoiron(IV) formation from H2O2 and a nonheme iron(II) complex. Hajime Hirao,
Lawrence Que, Keiji Morokuma*
1622. Solution capturing end-on peroxo and
hydroperoxo intermediates of heme enzymes. Jin-Gang Liu*, Takehiro Ohta*,
Yuta Shimizu*, Yoshinori Naruta*
1623. Mechanistic studies for the activation
of dioxygen and the role of the superoxy
hemin in the aqueous system of Fe(III)TMPyP-MBTH-O2. Taku Nakano*,
Hiroko Kakuda
1624. Theoretical investigation on the mechanisms of hydroxylation reactions with
compound I in P450. Hiroshi Isobe,
Shusuke Yamanaka, Mitsutaka Okumura,
Kizashi Yamaguchi
1625. Combined DFT and electrostatics
study of the proton pumping mechanism
in cytochrome c oxidase.
Alexei Stuchebrukhov
1626. Dioxygenase-like activity of an isolable
nickel(II)-superoxo compound.
Anna Company, Shenglai Yao,
Kallol Ray, Matthias Driess
1627. Reactivity for dioxygen and substrate
aerobic oxidations of nickel complexes
having a para-substituted thiophenolato
ligand. Jun Nakazawa, Shiro Hikichi*
1628. Synthesis of silica-loaded metal complexes having a N-(2-aminoethyl)salicylideneaminato tridentate ligand and their
alkene oxidation reaction with various oxidants. Takahiro Akashi, Jun Nakazawa,
Shiro Hikichi*
1629. Development of novel scorpionate ligands-based immobilized metallocomplex catalysts. Takeshi Kasai,
Jun Nakazawa, Shiro Hikichi*
1630. Synthesis, characterization, electrochemistry of cobalt hangman porphyrins
and cobalt hangman corroles for oxygen
electrocatalysis. Dilek D. Kiper,
Daniel G. Nocera*
1631. Series of peroxomanganese(III) complexes supported by tetradentate aminopyridyl ligands: Detailed spectroscopic
and computational studies.
Robert A. Geiger,
Swarup Chattopadhyay, Victor W. Day,
Timothy A. Jackson*
1632. Preferential CO oxidation in hydrogenrich stream over Ru/carbon catalysts.
Nobuhiko Horiuchi*, Takanori Miyake,
Toshimitsu Suzuki, Na-oki Ikenaga
1633. Cerium(IV)- and light-driven water oxidation catalyzed by mononuclear ruthenium(II) complexes with 1,10-phenanthroline-2,9-dicarboxylate ligand.
Lianpeng Tong, Licheng Sun*
1634. Reversible coordination of O2 and unusually high frequency hydride chemical
shift in [Ru(NHC)4H]⫹ (NHC ⫽ N-heterocyclic carbene): A DFT study.
Jonas Haller, Elena Mas-Marzá,
Aitor Moreno, John P. Lowe,
Stuart A. Macgregor, Mary F. Mahon,
Paul S. Pregosin, Michael K. Whittlesey
1635. Oxygen transfer catalysis by mononuclear highly symmetric d° metal complexes: Effect of Lewis bases co-ligands.
Giulia Licini*, Cristiano Zonta,
Miriam Mba
1636. Oxidative dehydrogenation of propane
with lattice oxygen of V2O5/SiO2.
Kenta Fukudome, Na-oki Ikenaga,
Takanori Miyake, Toshimitsu Suzuki
1637. Thermal generation of reactive oxygen
species. Kayoko Tahara, Yoshihiro Abe*,
Soichiro Kawamoto, Tadahiko Mashino
Convention Center
Kamehameha Halls II and III
Structural and Functional Aspects of
Coordination Polymers (#133)
Organized by: S. Telfer, S. Cohen,
D. Leznoff
Presiding: S. Telfer
Poster Session
19:00 – 21:00
1638. Cu(I) coordination polymers of N,N’bis(3-(methylthio)propyl) pyromellitic diimide. Garam Park, Hojin Yang,
Hyunji Kim, Tae Ho Kim, Jineun Kim*
1639. Self-template-directed formation of
coordination-polymer hexagonal tubes
and rings. Won Cho, Hee J. Lee,
Moonhyun Oh*
1640. Morphology-selective preparation of
coordination polymer particles (CPPs).
Hee J. Lee, Won Cho, Moonhyun Oh*
1641. Strong blue luminescent copper(I) coordination polymers. Tae Ho Kim,
Hojin Yang, Garam Park, Hyunjee Kim,
Jineun Kim*
1642. Guest responsive elongated Fe(II)Pt(II)
porous coordination polymers providing
spin transition. Masashi Arai,
Masaaki Ohba, Ryo Ohtani, Ko Yoneda,
Ana B. Gaspar, Jose A. Real,
Susumu Kitagawa
1643. Dielectric properties of quasi-1-D bromine-bridged Pd complexes.
Shohei Kumagai*, Shinya Takaishi,
Hitoshi Miyasaka, Masahiro Yamashita,
Nobuyuki Abe, Takahisa Arima
1644. Withdrawn
1645. Phosphine coordination materials
based on new ambidentate ligands.
Ana J. Nunez, Simon Humphrey*
1646. Interaction between dietary fibers and
toxic heavy metals as revealed by vibrational spectroscopy. Takashi Ohno*,
Noriko Tachibana, Yukiko Hamada,
Shiori Manabe, Yukihiro Kimura
Convention Center
Kamehameha Halls II and III
Coordination Chemistry toward Artificial
Photosynthesis and Energy Conversion
Processes (#194)
Organized by: K. Tanaka, J. Muckerman,
K. Sakai, L. Sun
Presiding: K. Tanaka
Poster Session
19:00 – 21:00
1647. Photo-hydrogen-evolving characteristics of some new molecular devices involving Ru(bpy)2(phen)2⫹ and
PtCl2(phen) units. Takuya Fukuda,
Shigeyuki Masaoka, Ken Sakai*
1648. Synthesis, crystal structure and photochemical hydrogen-evolving activity of a
water-soluble Pt(II)-porphyrin complex.
Hoda El-Ghamry*, Shigeyuki Masaoka,
Ken Sakai
1649. RuPt-based photo-hydrogen-evolving
molecular device tethered to peptide viologen acceptors. Yu Shibahara,
Makoto Ogawa, Masaoka Shigeyuki,
Ken Sakai*
1650. Thermal hydrogen production from
water promoted by Pt(II)-based molecular
catalysts. Kosei Yamauchi,
Shigeyuki Masaoka, Ken Sakai*
1651. Syntheses, characterization, and photo-hydrogen-evolving properties of new
complexes having (2-phenylpyridinato)platinum(II) unit. Masayuki Kobayashi,
Shigeyuki Masaoka, Ken Sakai*
1652. Photochemical hydrogen production
from water over micro-porous coordination polymer catalyst. Konomi Sato,
Yusuke Kataoka, Wasuke Mori*
1653. Ligand-assisted rhodium catalyzed
selective decomposition of formic acid.
Tao Chen, Kuo-Wei Huang*
1654. Iron-dithiolene complexes as functional models of [FeFe]-hydrogenases:
Hydrogen production from water catalyzed by biorelevant Fe2(␮-S)2 cores.
Toshiki Yamaguchi, Shigeyuki Masaoka,
Ken Sakai*
1655. Photochemical H2 molecular production from water using a novel Zn-Pd coordination polymer. Yuhei Miyazaki,
Yusuke Kataoka, Wasuke Mori*
1656. Carbon dioxide fixation and hydrogen
storage: Hydrogenation of bicarbonate
and decomposition of formic acid using
iridium complexes with 4,4’-dihydroxy2,2’-bipyridine. Yuichiro Himeda*
1657. Highly active mononuclear Ru catalysts for water oxidation: O-O bond formation via direct radical coupling.
Lele Duan*, Jonas Nyhlén,
Timofei Privalov, Licheng Sun
1658. Oxygen evolution from water catalyzed by mononuclear ruthenium complexes with a tridentate ligand in a facial
fashion: New insights into the mechanism. Masaki Yoshida,
Shigeyuki Masaoka, Ken Sakai*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–93
02-INOR/03-MACR
1659. Kinetic studies on the oxygen evolution from water catalyzed by mononuclear ruthenium complexes.
Ayano Kimoto*, Kosei Yamauchi,
Shigeyuki Masaoka, Ken Sakai
1660. Synthesis and oxygen-evolving activity of dinuclear ruthenium complexes with
a single aquaruthenium site.
Takashi Kozakura, Shigeyuki Masaoka,
Ken Sakai
1661. Biotransformation using photogenerated cofactors by metal complexes and
sensitizer. Jinheung Kim*, Jin A. Kim,
Ga Y. Kim, Misun Cha
1662. Oxygen evolution from water catalyzed by the ITO electrode modified with
[Ru(tpy)(bpy)OH2]2⫹ derivatives.
Josaku Kiyota, Shigeyuki Masaoka,
Ken Sakai*
1663. Molecular design and synthesis of artificial protein (peptide origami) bearing a
ruthenium complex as the core and its
photo-induced charge separation.
Yoshimi Shiina, Shigero Oishi,
Hitoshi Ishida*
1664. Aminoethylglycine-modified ruthenium
complexes: Scaffolds for photocatalysts.
Carl P. Myers, Mary E. Williams*
1665. Photoelectrochemistry of dinuclear ruthenium complexes bearing aqua ligand
on ITO or TiO2 electrode for achieving
energy conversion catalysts.
Shinya Masuno, Katsuhiko Kanaizuka,
Masa-aki Haga*
1666. Synthesis and characterization of the
iridium complexes for photoluminescence. Minchul Chung*, Ho-Geun Ahn,
Chee-Hun Kwak
1667. Syntheses and electronic properties of
novel iridium(III) complexes containing
cyclometalating ligands and terpyridine
derivative. Yoshiki Shinpuku*,
Misaki Nakai, Yasuo Nakabayashi
1668. Hybrid organic-inorganic chromophores for light-harvesting applications. Bryan D. Koivisto,
Kiyoshi C. Robson, Paolo G. Bomben,
Curtis P. Berlinguette*
1669. Synthesis of nanocrystalline N-doped
titania and its characterization on solar
application.
Cahyorini Kusumawardani*,
Suwardi Suwardi, Sayekti Wahyuningsih,
Pan Jisheng
Monday Morning
Hilton
Coral II
Dioxygen Activation Chemistry and
Catalytic Oxidation Reactions (#108)
Organized by: S. Itoh, W. Nam,
A. Rosenzweig, W. Tolman
Presiding: C. White, S. Stahl
7:30 – 1670. Iron-catalyzed asymmetric oxidative coupling of 2-naphthols and its
mechanism. Tsutomu Katsuki
8:05 – 1671. Organometallic copper oxidase
reactions: New opportunities for selective
aerobic oxidation of C-H bonds.
Shannon S. Stahl*
8:40 – 1672. Reactions of late transition
metal complexes with molecular oxygen.
Karen Goldberg
9:15 – 1673. Withdrawn
9:50 – 1674. Recent developments in oxygen activation by transition metal complexes. Andreja Bakac*
10:25 – 1675. Prediction and demonstration
of bimetallic catalysts with improved selectivity for ethylene epoxidation.
Mark A. Barteau*, Joseph Dellamorte,
Lauterbach Jochen
10:50 – 1676. Nonheme Fe(PDP) catalyst for
predictably selective C—H oxidation.
M. Christina White*
11:25 Concluding remarks
94 –TECH
TECHNICAL PROGRAM
Hilton
Coral I
Self-Assembly and Coordination Chemistry
(#164)
Organized by: M. Fujita, L. MacGillivray,
L. Stephen, S. Y Yu, M. Yoshizawa
Presiding: L. MacGillivray, T. Uemura,
T. Ueno
7:30 – 1677. Green synthesis of organic ligands: Applications in coordinationdriven self-assembly.
Leonard R. MacGillivray*,
Tamara D. Hamilton,
Giannis S. Papaefstathiou,
Dejan-Kresimir Bucar, Qianli Chu
7:45 – 1678. Functional metal-organic
framework materials. Joseph Hupp*,
Omar K. Farha
8:15 – 1679. Supramolecular assembly of
multimetallic complexes.
Mark MacLachlan*, Peter Frischmann,
Samuel Guieu
8:45 – 1680. Polymer chemistry in coordination nanochannels. Takashi Uemura*,
Susumu Kitagawa
9:00 – 1681. Coordination chemistry within
nanoporous molecular crystals of a
phthalocyanine derivative.
Neil B. McKeown, C. Grazia Bezzu,
Madeleine Helliwell
9:15 – 1682. Direct formation of redox active
2D complexed adlayer consisting of bisterpyridine and cobalt ion on Au(111).
Soichiro Yoshimoto*, Yuta Ono,
Katsuhiko Nishiyama, Isao Taniguchi
9:30 – 1683. Dimentional encapsulation of
halogen-bonded supramolecular anions.
Antonio Abate, Gabriella Cavallo,
Manu Lahtinen,
Pierangelo Metrangolo*, Tullio Pilati,
Giuseppe Resnati, Kari Rissanen,
Giancarlo Terraneo
9:45 – 1684. Fluorescence modulation of
lanthanide complexes. Wenwu Qin,
Jie Mao, Weisheng Liu*, Minyu Tan
10:00 – 1685. Self-assembly of dynamic covalent cages and frameworks.
Radu Custelcean, Nathan Duncan,
Benjamin Hay
10:15 – 1686. Metal complexes functionalized on tubular protein architectures.
Takafumi Ueno*
10:30 – 1687. Building multimetallic nanostructures with DNA. Hanadi Sleiman*,
Hua Yang, Christopher McLaughlin,
Pik Kwan P. Lo, Faisal Aldaye
11:00 – 1688. Metal-organic nanocapsules:
Dimers vs. hexamers. Jerry L. Atwood,
Scott J. Dalgarno, Andrew V. Mossine,
Harshita Kumari, Drew Fowler,
Cheryl Ragan, Andrew Maerz,
Nathaniel Schuster
Hilton
Kahili I/II
Coordination Chemistry toward Artificial
Photosynthesis and Energy Conversion
Processes (#194)
10:10 – 1693. Seven-coordinate Ru-centers
and preorganization of (semi-) rigid ligand
backbone: rationalization of mono- and
bi-nuclear pathways of catalytic water
oxidation. Timofei Privalov*, Lele Duan,
Jonas Nyhlen, Yunhua Xu,
Andreas Fischer, Licheng Sun*,
Bjorn Akermark
10:35 – 1694. Immobilization of visible-light
absorbing polyoxometarate derivatives
on oxygen evolving MnO2 nanoclusters.
Toshihiro Takashima*,
Ryuhei Nakamura, Kazuhito Hahimoto
11:00 – 1695. Photochemical methanol synthesis from carbon dioxide using artificial
photosynthesis system consisting of sensitizer and dehydrogenases.
Yutaka Amao*
11:25 Closing remarks
Hilton
Lehua Suite
Structural and Functional Aspects of
Coordination Polymers (#133)
Organized by: S. Telfer, S. Cohen,
D. Leznoff
Presiding: D. Leznoff
8:00 – 1696. Thermolabile groups in metalorganic frameworks: Suppression of interpenetration, postsynthetic cavity expansion and protection of reactive
functional groups. Shane Telfer*
8:30 – 1697. Phosphine coordination materials and their potential for applications in
catalysis. Simon M. Humphrey*
9:00 – 1698. New biomolecule-based and
NIR-emitting MOFs for molecular sensing, labeling, and encryption applications.
Nathaniel L. Rosi*, Stephane Petoud,
Kiley White, Demetra Chengelis,
Kristy Gogick, Jihyun An, Chad Shade
9:30 – 1699. Kinetic synthesis of a porous
coordination network and ab initio powder structure analysis. Masaki Kawano*
10:00 – 1700. Mesostructured materials
through coordination chemistry.
Mark MacLachlan, Xavier Roy
10:30 – 1701. Vapochromic and birefringent
properties of functional cyanoauratebased coordination polymer materials.
Daniel Leznoff*
11:00 – 1702. Exploring postsynthetic modification in metal-organic frameworks.
Seth Cohen*
MACR
Area 3 – Macromolecular
Wednesday Morning
Convention Center
328
Polymeric Materials from Renewable
Resources (#6)
Organized by: K. Tanaka, J. Muckerman,
K. Sakai, L. Sun
Presiding: K. Tanaka
Organized by: V. Finkenstadt,
S. Chakraborty, R. Konduri, X. Liao,
L. Liu
Presiding: S. Chakraborty
7:50 – 1689. Further observations on water
oxidation catalyzed by mononuclear
Ru(II) complexes. Randolph Thummel*,
Ruifa Zong, Nattawut Kaveevivitchai,
Maya El Ojaimi
8:25 – 1690. Water oxidation catalyzed by
dinuclear Ru complexes. Koji Tanaka*,
Tohru Wada
9:00 – 1691. Redox non-innocence and the
mechanism of water oxidation by the
Tanaka catalyst. Mu-Hyun Baik*
9:35 – 1692. Light-driven water oxidation
catalyzed by carbon-free, stable, fast and
soluble inorganic complexes.
Craig L. Hill, Yurii V. Geletii,
Claire Besson, Qiushi Yin,
Zhuangqun Huang, Yu Hou,
Alexey Kaledin, Djamaladdin Musaev,
Tianquan Lian, Anna Proust
7:30 – 1. Potential halogen-free flame retardants for textile applications.
SeChin Chang*, Brian Condon,
Thach-Mien Nguyen, Elena Graves,
Michael Easson
8:00 – 2. Developing renewable polymers: A
novel synthesis of fluorenone.
Brenna A. Brown*, Jonathan G. Veinot
8:30 – 3. Development of biodegradable superabsorbent hydrogels based on cellulose. Toshio Yoshimura*,
Rumiko Fujioka
9:00 – 4. Synthesis and refractive-index
property of hyperbranched polymer containing calixarene structure in the main
chain. Tadatomi Nishikubo*,
Yusuke Fujihara, Hiroto Kudo
9:30 – 5. Diversified uses of agave tequilana:
From high content fructose syrups and
functional foods to drug delivery systems
to the colon. Guillermo Toriz*,
Ezequiel Delgado, Héctor J. Contreras,
Marcos A. Escalante,
Alvaro D. Martínez-Gómez,
Rosa I. Corona-González
10:00 – 6. Enhancement in the performance
of corn starch based polymer electrolytes
incorporating deep eutectic solvent for
use in “green” polymer batteries.
Ramesh T. Subramaniam*,
R.Shanti Rajantharan
10:30 – 7. Inter-cross-linking siloxane polysaccharide hybrid materials: Formation,
stability, and sequestering behaviour.
Andrew J. Vreugdenhil*,
Christophe Bliard
11:00 – 8. Agricultural polymers as corrosion
inhibitors. Victoria Finkenstadt*,
Claudiu Bucur, Gregory Cote,
Kervin Evans
Convention Center
325B
Chemistry and Functional Properties of Soft
Interfaces (#42)
Organized by: A. Takahara, K. Char,
K. Kurihara, M. Maeda, Z. Su, G. Warr,
K. Wynne
Presiding: A. Takahara, T. McCarthy
7:30 Opening remarks
7:35 – 9. Tuning the amphiphilicity of building blocks for controlled self-assembly:
Toward responsive materials and surfaces. Xi Zhang*, Pengbo Wan,
Yapei Wang, Yugui Jiang
8:00 – 10. Surface modification with copolyoxetane soft block polyurethanes:
Correlating quaternary charge density via
streaming potentials with contact antimicrobial behavior. Kenneth J. Wynne*,
Kennard Brunson, Asima Chakravorty,
Murari Gupta, Dennis Ohman,
Lynn Wood, Julio Alvarez,
Fernando Luna-Vera
8:15 – 11. Block copolymer self-assembly
mechanics and imaging from the single
molecule to thin film level, and relevance
to anti-fouling coatings. Gilbert Walker*
8:40 – 12. New paradigm of biomolecular
soft-interfaces as chiral reaction fields for
supramolecular asymmetric photochirogenesis. Takehiko Wada*,
Yui Sugawara, Masaki Nishijima,
Mihoko Ui, Yasuyuki Araki,
Seiji Sakamoto, Kohei Tsumoto,
Kazushi Kinbara, Yoshihisa Inoue
8:55 – 13. Metathesis approach toward the
preparation of soft biomaterials.
Kenneth B. Wagener*, James Leonard,
Diane Turek, Kenneth Sloan
9:15 – 14. Polymer- and nanoparticle-shelled
bubbles based on microfluidics.
Myung Han Lee, Teresa Brugarolas,
Varesh Prasad, Jennifer Kay,
Jennifer Kunkel, Daeyeon Lee*
9:30 – 15. Synthesis of temperature responsive cationic amphiphilic block copolymer
by reversible addition: Fragmentation
chain transfer process and their self-assembly studies. Arjun Ghosh*,
Shin-ichi Yusa, Hideki Matsuoka,
Yoshiyuki Saruwatari
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR
9:45 – 16. Understanding supramolecular
aggregation of polyoxometalates-containing polymers and macromolecules.
Wei Wang*, Yaokun Han,
Yongliang Wang, Bo Liu, Yu Xiao,
Jie Yang
10:10 – 17. Tunable wettability via counterion exchange at the surface of polyelectrolyte multilayers. Liming Wang*,
Bo Peng, Zhaohui Su
10:25 – 18. Three different types of “directed
self-assembly” to control the chemistry
and functional properties of soft interfaces. Thomas McCarthy, Pei Bian,
Peiwen Zheng, Joseph W. Krumpfer
10:50 – 19. Size exclusion chromatography
of quantum dots and nanoparticles by
utilizing nanoparticle repelling surface of
concentrated polymer brush.
Toshihiko Arita*, Tomoka Yoshimura,
Tadafumi Adschiri
11:05 – 20. Why polyelectrolyte multilayers
are special. Joe Schlenoff*
Convention Center
323A
Polymer Materials Performance,
Degradation and Optimization (#64)
Organized by: M. Celina, T. Dargaville,
H. Kudoh
Presiding: M. Celina
7:30 Opening remarks
7:35 – 21. Tales of an expert witness: Materials performance issues in UK courts.
Terry Henman*
8:05 – 22. Withdrawn
8:35 – 23. Rheological property and adhesive performance of polymer coated film
for telecommunication plant.
Yukitoshi Takeshita*, Seizou Sakata,
Takashi Sawada, Richard Jackson,
Ryuichi Nishio
8:55 – 24. Overview on advances in the science, chemistry, processing, and modeling toward the optimization of foam materials. Mathew C. Celina*,
Jamie M. Kropka, Nicholas H. Giron,
Ana B. Trujillo, Rheka R. Rao,
Lisa A. Mondy, James H. Aubert
9:25 – 25. Polyolefin nanocomposites by
metallocene catalysts.
Walter O. Kaminsky*
9:55 – 26. Polymer based delivery of vapor
phase lubrication for MEMS devices.
Ana Trujillo*, Christina Lucero,
Michael Dugger, Mathew Celina
10:15 – 27. Role of hyperthermal atomic/molecular collisions on a space environmental effect of polymeric materials.
Masahito Tagawa*, Kumiko Yokota
10:35 – 28. Combined effect of atomic oxygen and vacuum ultraviolet on polymer
degradation: Relevance to space environmental effect on polymer degradation.
Kumiko Yokota*, Masahito Tagawa
Convention Center
323B
Hybrid Conjugated Polymer Materials (#82)
Organized by: M. Wolf, R. Advincula,
S. Valiyaveettil, K. Yamamoto
Presiding: S. Valiyaveetil
7:30 Introductory remarks
7:40 – 29. Graphene edges and nanographene: Electronic/magnetic structure and
nanofabrications. Toshiaki Enoki*
8:10 – 30. Hybrid nanoparticle-conjugated
polymer dendrons and dendrimers.
Rigoberto Advincula*
8:40 – 31. High molecular weight hybrid
polymers by reaction of
[p-IC6H4SiO1.5]8 with divinylbenzene:
Potential routes to highly and multi- functionalized conjugated materials.
Richard M. Laine*, Jae H. Jung,
Sarah Clark
9:00 – 32. Detection and separation of anthrax lethal factor DNA based on polydiacetylene complex beads. Hakjin Kim,
Gilsun Lee, Dongjune Ahn*
9:20 – 33. Nanopatterned polythiophene thin
films prepared by surface-initiated polymerization. Euiyong Hwang, Jinwoo Choi,
Kathie L. Lusker, Jayne C. Garno,
Evgueni E. Nesterov*
9:40 – 34. Investigating metallosupramolecular polymers: From conjugated systems to stimuli-responsive materials.
Stuart J. Rowan*, Christoph Weder
10:10 – 35. Morphology evolution of polyaniline microstructures in toluene and their
film properties. Hardy S. Chan*,
Tao Wen, Chorng Haur Sow
10:40 – 36. Design of stimuli-responsive
macromolecular complexes using helixforming polysaccharides.
Tomohiro Shiraki*, Arnab Dawn,
T. N. Lien Le, Youichi Tsuchiya,
Seiji Shinkai
11:00 – 37. Hybrid supramolecular mesoporous materials. Katsuhiko Ariga*
Convention Center
321B
The New Age of Advanced Materials:
Supramolecular Architectures and Smart
Materials (#98)
Organized by: E. Yashima, T. Aida,
F. Caruso, M. Lee, K. Wooley
Presiding: E. Yashima
7:30 – 38. Advanced and smart polymeric
materials via metal-mediated living radical polymerization. Mitsuo Sawamoto*
8:00 – 39. Accurate control over macromolecular objects through non-covalent interactions. Craig J. Hawker*
8:30 – 40. Covalent dynamic polymers
based on C⫽N bonds in imines and hydrazones. Shunsuke Fujii*
9:00 – 41. Combinations of polymerization
strategies and self assembly processes
to afford functional polymers and regioselectively-functionalized nanoscopic objects. Karen L. Wooley*
9:30 – 42. Multifunctional nanoscale films:
Putting molecules to work. Gero Decher*
10:00 – 43. Stimuli responsive morphology
switching polymeric materials.
Rachel O’Reilly*
10:30 – 44. End capped cascade degradable
linear polymers, copolymers and supramolecular assemblies.
Elizabeth R. Gillies*, Matthew A. DeWit,
Annelise Beaton
10:45 – 45. Mechanistic aspects of self-repairing reactions in polymeric networks.
Marek W. Urban*, Biswajit Ghosh
11:00 – 46. Precision synthesis of diagnostic
and sensory polymer brushes.
Harm-Anton Klok
11:15 – 47. Stimuli responsive polymer colloids using switchable surfactants: Reversible coagulation and redispersion using CO2 as a trigger. Masatoshi Mihara,
Catherine O’Neill, Philip Jessop*,
Michael F. Cunningham*
Convention Center
327
Azobenzene Polymers for Photo-Reversible
Structures and Surfaces (#144)
Organized by: C. Barrett, T. Ikeda,
P. Palffy-Muhoray, Y. Zhao
Presiding: C. Barrett, C. Barrett
7:30 Opening remarks
7:40 – 48. Photomobile polymer nanoparticles prepared by soap-free emulsion
polymerization. Atsushi Shishido,
Yuki Takamiya, Tomiki Ikeda*
8:10 – 49. Exploiting azobenzene for photoswitchable molecular systems with maximum extension and shrinkage.
Stefan Hecht*, David Bleger,
Maria M. Russew, Carsten Winterboer,
Zhilin Yu
8:40 – 50. Azo-benzene: A light sensitive
molecular switch. Hai-Ping Cheng*
9:00 – 51. Probing local field enhancements
in plasmonic nanostructures with azopolymers thin films.
François Lagugné-Labarthet*,
Betty Galarreta
9:20 – 52. Nanotechnology of azobenzenemodified DNA for constructing photoresponsive nanostructures and nanodevices. Xingguo Liang*,
Toshio Mochizuki, Hidenori Nishioka,
Hiroyuki Asanuma
9:40 – 53. Azo polymer nano/micro-structures: Construction and photoinduced
deformation behavior. Xiaogong Wang*,
Dongrui Wang, Gang Ye, Junpeng Liu,
Miaocai Guo
10:10 – 54. Visible-light-driven soft actuation
materials based on azo-containing liquidcrystalline polymers. Yanlei Yu*,
Xiaoying Li, Futao Cheng, Ruoyuan Yin,
Wei Wu
10:40 – 55. Hydrogen-bonded polymer-azobenzene complexes: Facile route toward
aggregation control, photo-orientation,
and efficient mass transfer.
Arri Priimagi*, Jaana Vapaavuori,
Olli Ikkala, Martti Kauranen, Matti Kaivola,
Paul Rochon
11:00 – 56. Temperature effect on the photodriven oscillation behaviors of monodomain azo-liquid crystalline polymer networks. Kyungmin Lee,
Bunning J. Timothy, White J. Timothy*
11:20 Closing remarks
Convention Center
322AB
Polyolefins Chemistry and Beyond - From
Bench to Commercial Scale (#211)
Organized by: F. Sibtain, M. Chan,
K. Nozaki, R. Waymouth
Presiding: R. Waymouth
8:00 Introduction
8:05 – 57. Metal catalyzed copolymerization
of olefins with polar vinyl monomers.
Richard Jordan*
8:45 – 58. Design of efficient titanium complex catalysts for precise olefin polymerization. Kotohiro Nomura*
9:15 – 59. Nature of the active sites in a high
efficiency bimetallic Ziegler-Natta polymerization catalyst on a mixed MgCl2/
SiO2 support. Susannah L. Scott*,
Ming-Yung Lee
9:45 – 60. Commercialization of polyolefin
catalyst systems: Synergistic interaction
between chemistry and engineering.
Fazle Sibtain*, Eric Clavelle
10:15 – 61. Adsorbent product application
technology considerations in the production of polyolefins. David L. Smith*
10:45 – 62. Synthesis of new type of functionalized polyolefins for photonic device
application via the extended use of single
site catalysts. Jun Ha Park,
Myung Hwan Park, Youngkyu Do*,
Min Hyung Lee*
Wednesday Afternoon
14:30 – 67. Degradation of poly(L-lactic acid)
and biocomposites in various alkaline
and temperature treatments.
Brent Tisserat*, Victoria L. Finkenstadt
15:00 – 68. Renewable block polymers.
Marc Hillmyer*
15:30 – 69. Thermal conductivity of poly(lactic acid) and carbon nanofibers composites. LinShu Liu*, Lihan Huang,
Cheng-Kung Liu
Convention Center
325B
Chemistry and Functional Properties of Soft
Interfaces (#42)
Organized by: A. Takahara, K. Char,
K. Kurihara, M. Maeda, Z. Su, G. Warr,
K. Wynne
Presiding: K. Char, G. Warr
12:30 – 70. Confined polymer systems: Synergies between simulations and neutron
scattering experiments. Roland Faller*,
Ian Elliott, Beste Bayramoglu,
Dennis Mulder, Tonya Kuhl
12:45 – 71. X-ray and neutron scattering researches on biological membrane interfaces: Stability and insertion mechanism
of biomolecules onto phospholipid
monolayers, and bilayers.
Kwanwoo Shin*
13:10 – 72. Complex nanostructures with lamellae and micelles of block copolymers.
Byeong-Hyeok Sohn*
13:35 – 73. Network swelling competing with
translational entropy in autophobic polymer dewetting. Michele Sferrazza*,
Wilfried Béziel
13:50 – 74. Antisticking molecular layers in
UV nanoimprint lithography.
Masaru Nakagawa*
14:15 – 75. Electrochemical imaging techniques with scanning probe and addressable microelectrode array. Hitoshi Shiku,
Yasufumi Takahashi, Kosuke Ino,
Tomokazu Matsue
14:30 – 76. Local conformation of poly(methyl methacrylate) at interfaces by infrared-visible sum-frequency generation
spectroscopy. Keiji Tanaka*
14:55 – 77. Specific crystal structure of
poly(3-hydroxybutyrate) thin films studied
byinfrared reflection-absorption spectroscopy. Harumi Sato*, Yukihiro Ozaki,
Isao Takahashi
15:10 – 78. Coarse-grained simulation study
of the interface between polymer film and
liquid. Hiroshi Morita*, Keiji Tanaka,
Masao Doi
15:25 – 79. Direct evaluation of chain dimension of single macromolecule by superresolution optical microscopy technique.
Hiroyuki Aoki*, Kazuki Mori,
Shinzaburo Ito
15:40 – 80. Nanopatterning from self-assembly of degradable chiral block copolymers. Rong-Ming Ho
16:05 – 81. High-density array of 1-D nanostructures by using AAO templates with
surface or interfacial modification.
Jinseok Byun, Jin Kon Kim*
Convention Center
328
Polymeric Materials from Renewable
Resources (#6)
Organized by: V. Finkenstadt,
S. Chakraborty, R. Konduri, X. Liao,
L. Liu
Presiding: V. Finkenstadt
12:30 – 63. Relationship between lignin configuration and lignin-based polymeric materials. Yi-ru Chen, Simo Sarkanen*
13:00 – 64. Withdrawn
13:30 – 65. Material utilization of isolated
lignins via diversified microcompositions
with synthetic polymers.
Yoshikuni Teramoto*,
Yusuke Nakanishi, Yoshiyuki Nishio
14:00 – 66. Biorenewable polyethylene
terephthalate (PET) mimics derived from
lignin. Stephen A. Miller*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–95
03-MACR
Convention Center
323A
Polymer Materials Performance,
Degradation and Optimization (#64)
Organized by: M. Celina, T. Dargaville,
H. Kudoh
Presiding: H. Kudo
12:30 – 82. Recent progress in resist materials and processes for extreme ultraviolet
(EUV) and electron beam (EB) lithography. Seiichi Tagawa*
13:00 – 83. Tailoring the performance of
polymers for photolithography and biosensor applications. Idriss Blakey*
13:30 – 84. Modeling the effects of radiation
and temperature on the mechanical properties of silicone elastomers.
Richard Gee*, Amitesh Maiti,
Todd Weisgraber, Sarah Chinn,
Robert Maxwell
13:50 – 85. Principle component analysis of
19
F NMR spectra for the characterization
of radiation-induced degradation of fluoropolymers. Brian Mayer*,
James Lewicki, Sarah Chinn,
Robert Maxwell
14:10 – 86. Radiation modification of PTFE
and some polymer fibers. Guozhong Wu
14:40 – 87. Erosion of FEP teflon and PMMA
by VUV radiation and hyperthermal O or
Ar atoms. Jianming Zhang*,
Ned F. Lindholm, Amy L. Brunsvold,
Hari P. Upadhyaya, Timothy K. Minton*,
Masahito Tagawa
15:00 – 88. Oxidative degradation property
of proton exchange membranes based
on fluorinated polymer prepared by radiation-induced grafting. Akihiro Oshima*,
Naohiro Mitani, Kazuki Fujii, Yukiko Sato,
Masakazu Washio
15:20 – 89. Uranium collection from seawater with adsorbent prepared by radiationinduced graft polymerization.
Masao Tamada*, Noboru Kasai,
Noriaki Seko, Takao Shimizu
15:50 – 90. Fabrication of functionally gradient PEM using heavy ion beams grafting.
Masakazu Washio*, Fumiya Shiraki,
Yuji Oshima, Yuya Takasawa,
Hajime Fujita, Tomoko Gowa,
Hisaaki Kudo, Toshitaka Oka,
Yoshimasa Hama, Takeshi Murakami,
Akihiro Oshima
16:10 – 91. Application of radiation modified
hydrophilic polymers for enhance of oil
recovery. Hai Le*, Phong T. Nguyen,
Toan V. Le, Lan T. Nguyen
Convention Center
323B
Hybrid Conjugated Polymer Materials (#82)
Organized by: M. Wolf, R. Advincula,
S. Valiyaveettil, K. Yamamoto
Presiding: R. Advincula
12:30 – 92. New conjugated polymers for
plastic solar cells. Mario Leclerc*
13:00 – 93. New copolymer semiconductors
for high performance solar cells.
Samson A. Jenekhe*
13:30 – 94. Charge transporting block copolymers based on poly(triphenylamine) for
photovoltaic cells. Kousuke Tsuchiya*,
Shota Iino, Tatsuro Kikuchi,
Malee Songeun, Kenji Ogino*
13:50 – 95. Semiconductor organic-inorganic nanocomposites at the air/water interface and their performance in thin film
solar cells. Zhiqun Lin*, Jun Xu,
Matthew Goodman, Malika Jeffries-EL,
Jacob Petrich
14:10 – 96. Hybrid materials based on quantum dots-conjugated polymers for IR
photodetection and solar cells.
Kyoung Kuk Jang, Prem Prabhakaran,
Namchul Cho, Kwang-Sup Lee*
14:30 – 97. Semifluorinated polymers and
composites from fluorinated olefins.
Dennis W. Smith*, Scott Iacono,
Rhett Smith, Andrew Neilson,
John Ballato, Jean-Marc Cracowski,
Neetu Tomar, Rajneesh Verma,
Dakarai Brown
96 –TECH
TECHNICAL PROGRAM
15:00 – 98. Conjugated polymer - nanomaterial hybrids: Synthesis, structure, and
property investigation.
Suresh Valiyaveettil*
15:30 – 99. Label-free fast protein detection
using P3MT and aptamer. Hyun Choi,
Chunzhi Cui, Gil Sun Lee,
Dong June Ahn*
15:50 – 100. Electropolymerized poly(tripyridinio mesithylene): Its high-density
charge storage and photo-induced
charge separation. Naoki Sano*,
Wataru Tomita, Kenichi Oyaizu,
Hiroyuki Nishide
16:10 – 101. Synthesis and characterization
of block copolymers with poly(3-hexylthiophene) segments by the combination
of ATRP and Grignard metathesis polymerization. Kunlun Hong, Xiang Yu,
Yugang Li, Hugh M. O’Niell,
Jimmy W. Mays
Convention Center
321B
The New Age of Advanced Materials:
Supramolecular Architectures and Smart
Materials (#98)
Organized by: E. Yashima, T. Aida,
F. Caruso, M. Lee, K. Wooley
Presiding: M. Lee
12:30 – 102. Supramolecular networks and
nanocomposites: Search of the missing
link. Ludwik Leibler*,
François Tournilhac, Sylvie Tencé-Girault,
Damien Montarnal, Thomas Perié
13:00 – 103. Diels Alder polymers and remending materials. Fred Wudl*
13:30 – 104. Smart polymer capsules based
on responsive polymers for biomedical
applications and encapsulated biocatalysis. Frank Caruso*
14:00 – 105. Functional self-assembled architectures from polymers and viruses.
Roeland Nolte*, Mauri Kostiainen,
Jeroen Cornelissen
14:30 – 106. Self-assembled nano-probe for
labeling and imaging endogenous protein
in test tube and in live cell.
Itaru Hamachi*
15:00 – 107. Synthetic biosupramolecular
photosystems. Stefan Matile*
15:30 – 108. Nano-Trojan horse: A concept
for a pathogen sensing smart wound
dressing. Toby Jenkins*,
Andrew L. Loftus, Geraldine Mulley,
Jin Zhou
15:45 – 109. Programming the morphology
of polymeric micelles with peptides, enzymes, and DNA.
Nathan C. Gianneschi*,
Miao-Ping Chien, Ti-Hsuan Ku,
Matthew P. Thompson,
Lyndsay M. Randolph, Anthony M. Rush
16:00 – 110. Influence of architecture on the
behavior of multi-sensitive microgels.
Walter Richtering*, Jochen Kleinen,
Christine Scherzinger
16:15 – 111. Diyne-based foldamers: Toward poly(diacetylene) organic nanotubes. Jean-Francois Morin*,
Jules N. Romeo
Convention Center
322AB
Polyolefins Chemistry and Beyond - From
Bench to Commercial Scale (#211)
Organized by: F. Sibtain, M. Chan,
K. Nozaki, R. Waymouth
Presiding: K. Nozaki
12:30 Introduction
12:35 – 112. Polymerization of olefins with FI
catalysts: Principles and industrial applications. Haruyuki Makio, Terunori Fujita*
13:15 – 113. Transmetallation between selective ethylene oligomerization catalyst
and zinc alkyls: New strategy towards
end-functionalized ethylene oligomers.
Kyung-sun (Karen) Son,
Robert M. Waymouth*
13:45 – 114. Probing [C-HѧF-C] and related
contacts as models of weak attractive ligand-polymer interactions.
Michael C. Chan*
14:15 – 115. Synthesis of star polyethylenes
via ethylene multifunctional “living” polymerization. Zhibin Ye
14:45 – 116. Expanding the versatility of
pyridyl amine ligands: Cyclometallated
L2X platforms for ethylene trimerization.
Steven D. Brown*
15:15 – 117. Synthesis of new PP structures
containing polar groups and cross-linkers, and applications in energy storage.
T. C. Mike Chung*, Xuepei Yuan,
Yuichi Matsuyama
15:45 – 118. Unravelling the mechanism of
polymerisation with the commercial Phillips catalyst. David McGuinness*,
Noel Davies, James Horne, Ivan Ivanov
Convention Center
327
Azobenzene Polymers for Photo-Reversible
Structures and Surfaces (#144)
Organized by: C. Barrett, T. Ikeda,
P. Palffy-Muhoray, Y. Zhao
Presiding: C. Barrett
12:50 Opening remarks
13:00 – 119. Azobenzene-containing sidechain liquid crystalline polymers of novel
architectures. Dehui Han, Xia Tong,
Yue Zhao*
13:30 – 120. Liquid crystalline surface-tethered azobenzene polymer brushes.
Takahiro Seki*, Takayuki Uekusa,
Kenjiro Imai, Soutarou Kakehi,
Shusaku Nagano
14:00 – 121. Withdrawn
14:20 – 122. New azo polyelectrolytes for
photomechanics and reversible biosurfaces. Christopher Barrett*,
Zahid Mahimwalla,
Alexis Goulet-Hanssens
14:50 – 123. Photon-induced multi-phase
transitions of liquid crystals via alternative
change of the molecular shape.
Daisuke Tanaka, Hisato Ishiguro,
Kazuki Ohnishi, Hirosato Monobe,
Yo Shimizu*, Kingo Uchida*
15:20 – 124. Shooting and swimming azobenzene single crystals in triacrylate solution. Namil Kim, Tom Sutter,
Dmitry Golovaty, Thein Kyu*
15:40 – 125. Active photoalignment control
of microphase separation cylinders in
azobenzene block copolymer.
Shusaku Nagano*, Tomoya Murase,
Yusuke Koizuka, Yuya Shinohara,
Yoshiyuki Amemiya, Takahiro Seki*
16:00 Closing remarks
Thursday Morning
Convention Center
328
Polymeric Materials from Renewable
Resources (#6)
Organized by: V. Finkenstadt,
S. Chakraborty, R. Konduri, X. Liao,
L. Liu
Presiding: L. Liu
7:30 – 126. Development of new crops and
products for the U.S. Steven C. Cermak,
Terry A. Isbell
8:00 – 127. Analysis and identification of ancient lacquer excavated from Kyoto.
Takayuki Honda*, Lu Rong,
Nobuhiko Kitano, Tetsuo Miyakoshi
8:30 – 128. Development of the hybridized
oriental lacquer paints with partially epoxidized linseed oils as reactive diluents.
Takahisa Ishimura*, Rong Lu,
Takashi Yoshida, Tetsuo Miyakoshi
9:00 – 129. Polymers prepared from plant
oils in liquid carbon dioxide.
Zengshe (Kevin) Liu*
9:30 – 130. Degradation rates of glycerol
polyesters at acidic and basic conditions.
Ronald Holser*
10:00 – 131. Withdrawn
10:30 – 132. Cashew nut oils polyols for
polyurethanes. Mihail Ionescu*,
Xianmei Wan, Zoran S. Petrovic
11:00 – 133. Biobased industrial lubricants.
Sevim Z. Erhan*
Convention Center
325B
Chemistry and Functional Properties of Soft
Interfaces (#42)
Organized by: A. Takahara, K. Char,
K. Kurihara, M. Maeda, Z. Su, G. Warr,
K. Wynne
Presiding: K. Wynne, Y. Nagasaki
7:30 – 134. Controlled assembly of viral
nanoparticles as biocompatible scaffold.
Qian Wang*, Yuan Lin, Elizabeth Balizan,
Nisaraporn Suthiwangcharoen,
Guihua Xiao, Zhaohui Su
7:55 – 135. Development of 3D-layered tissues by control of cellular interfaces.
Michiya Matsusaki, Koji Kadowaki,
Mitsuru Akashi*
8:10 – 136. Molecularly engineered charge
conversion of proteins for sensitive potentiometry. Tatsuro Goda,
Yuji Miyahara*
8:25 – 137. Antimicrobial polyelectrolyte
multilayer films that release chlorine via
N-halamine functionality.
Steven N. Kaganove*, Tracy Zhang,
Stephen Cendrowski, Keri Niec,
Deebika Balu
8:40 – 138. Polysiloxane-based, contact-active antimicrobial coatings.
Partha Majumdar*, Shane Stafslien,
Justin Daniels, Elizabeth Crowley,
Nathan Gubbins, Lyndsi Vander Wal,
Bret Chisholm, Erin Nyren-Erickson
8:55 – 139. Thermoresponsive soft interfaces for modulated interaction with biomolecules. Akihiko Kikuchi*,
Taka-Aki Asoh
9:10 – 140. Dendritic sugar interface and biological functionality. Yoshiko Miura*
9:35 – 141. Design of pH-sensitive radicalcontaining nanoparticle (RNP) as the EPR
imaging of acidic pH environments.
Toru Yoshitomi, Takashi Mamiya,
Hirofumi Matsui, Aki Hirayama,
Yukio Nagasaki*
9:50 – 142. Sensitive and selective detection
of lectins on hybrid monolayer surface
with protruding carbohydrate group.
Yukari Sato*, Kyoko Yoshioka,
Teiichi Murakami, Mutsuo Tanaka,
Osamu Niwa
10:05 – 143. Molecular recognition at the exterior surface of a zwitterionic telomer
brush. Hiromi Kitano*, Hisatomo Suzuki,
Kohji Ohno
10:20 – 144. Characterization of aqueous
phosphorylcholine-modified chitosan interfaces as bioactive substrates for stemcell growth and proliferation.
Shivaji Sharma, Kim Tardif, Zhi-mei Miao,
Jean-Francois Tanguay,
Francoise M. Winnik*
10:45 – 145. Structural study on noncrosslinking aggregation of gold nanoparticles with DNA. Masahiro Fujita*,
Mizuo Maeda
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR
11:00 – 146. Antibody-immobilized cell rolling column for quick stem cell separation.
Tetsuji Yamaoka*
11:15 – 147. Microbial culture on nanofibrous cellulose and its applications for
bioprospecting. Shigeru Deguchi*,
Mikiko Tsudome, Kaoru Tsujii,
Susumu Ito, Koki Horikoshi
Convention Center
323B
Hybrid Conjugated Polymer Materials (#82)
Organized by: M. Wolf, R. Advincula,
S. Valiyaveettil, K. Yamamoto
Presiding: K. Yamamoto
7:30 – 148. Bottom-up synthesis of electroand photo-functional molecular wires on
the surface. Hiroshi Nishihara*
8:00 – 149. Charge and exciton transport in
organometallic conjugated oligomers and
polymers. Kirk S. Schanze,
Julia R. Keller, John R. Miller, Chen Liao
8:30 – 150. Synthesis and properties of
n-heterocyclic carbene polymers.
Alan H. Cowley*, Adam B. Powell,
Christopher W. Bielawski
8:50 – 151. Dynamic/living conjugated polymers - long scaffolds for covalently binding of metal complexes. Will Skene*,
Satyananda Barik, Dufresne Stéphane
9:10 – 152. Dendritic encapsulation of a porphyrin with a rigidly constructed coreshell architecture that assists dissociation
of a radical ion pair. Takane Imaoka*,
Kimihisa Yamamoto*
9:30 – 153. Photoluminescent and electroluminescent materials consisting of novel
conducting metallopolymer architectures.
Xiao-Yan Chen, Julie M. Stanley,
Travis W. Hesterberg, Lauren A. Lytwak,
Bradley J. Holliday*
10:00 – 154. Polymetallocenes: Synthesis,
self-assembly and functions.
Ian Manners*
10:30 – 155. Design and synthesis of novel
␲-conjugated polymers containing group
16 elements by reactions of organometallic polymers having titanacyclopentadiene units. Hiroki Nishiyama,
Ikuyoshi Tomita
10:50 – 156. Hybrid conductive polymer and
Si-based electrode for lithium-ion chemistry. Gao Liu*, Shidi Xun,
Xiangyun Song, Honghe Zheng,
Vince Battaglia
11:10 – 157. Polymers featuring tricoordinate boron and redoxactive metal centers. Frank D. Pammer, Haiyan Li,
Frieder Jaekle*, Kshitij Parab
Convention Center
321B
The New Age of Advanced Materials:
Supramolecular Architectures and Smart
Materials (#98)
Organized by: E. Yashima, T. Aida,
F. Caruso, M. Lee, K. Wooley
Presiding: F. Caruso, T. Aida
7:30 – 158. Synthesis and function of multiple-stranded helical polymers and oligomers. Eiji Yashima*, Yoshio Furusho
7:45 – 159. Synthesis and functions of artificial double helical molecules based on
supramolecular approach.
Yoshio Furusho*, Eiji Yashima*
8:00 – 160. Responsive soft materials based
on conformationally preorganized building blocks. Stefan Hecht*,
Marie-Anne Berlin, Tamer El Malah,
Robert M. Meudtner, Denise Zornik
8:30 – 161. Water-soluble nanofibers with
supramolecular chirality. Myongsoo Lee*
9:00 – 162. Functional aromatic amide foldamers. Ivan Huc
9:30 – 163. How to control supramolecular
polymerization processes. Bert Meijer*
10:00 – 164. Expanding the scope of supramolecular polymers. Samuel Stupp*
10:30 – 165. Bioinspired synthesis of complex functional systems. Virgil Percec*
11:00 – 166. Aquamaterial: A new environmentally and biofriendly material.
Qigang Wang, Yasuhiro Ishida,
Justin L. Mynar, Takuzo Aida*
Convention Center
323A
Polymer Materials Performance,
Degradation and Optimization (#64)
Organized by: M. Celina, T. Dargaville,
H. Kudoh
Presiding: B. Fayolle
8:00 – 167. Polymer oxidation mechanisms
by thermal and radiation ageing for cables in nuclear power plant.
Tadao Seguchi*, Kiyotoshi Tamura,
Akihiko Shimada, Akira Idesaki,
Takeshi Ohshima, Hisaaki Kudoh
8:30 – 168. Radiation and thermal ageing
studies of polymer materials used in cable insulation in nuclear power plants-1:
General. Hisaaki Kudo*, Tadao Seguchi,
Kiyotoshi Tamura, Takeshi Ohshima,
Akira Idesaki, Akihiko Shimada
9:00 – 169. Temperature dependence on radiation induced degradation of ethylenepropylene-diene elastomer.
Masayuki Ito*
9:20 – 170. Rheological and spectrophotometric analyses on thermal oxidative
properties of poly(phenylene sulfide).
Yong Hoon Kim*
9:40 – 171. Predicting performance variability in aging silicone elastomers.
Robert Maxwell*, Sarah Chinn,
Mogon Patel, Richard Gee, Long Dinh
10:10 – 172. Thermal stability and volatile
out-gassing studies on ethylene vinyl acetate copolymer formulations.
Niaz Khan, Mogon Patel*,
Dave Netherton, Paul Morrell,
Philip Monks, Simon Pitts, David Plant,
Anthony Skinner
10:40 – 173. Recent developments in polymers lifetime prediction. Bruno Fayolle,
Emmanuel Richaud
11:00 – 174. Chemical degradation of high
density polyethylene in contact with chlorine disinfectants: Characterization and
modeling. Clémence Devilliers*,
Bruno Fayolle, Lucien Laiarinandrasana,
Emmanuelle Gaudichet-Maurin
Convention Center
322AB
Polyolefins Chemistry and Beyond - From
Bench to Commercial Scale (#211)
Organized by: F. Sibtain, M. Chan,
K. Nozaki, R. Waymouth
Presiding: F. Sibtain
8:00 Introduction
8:05 – 175. Polyolefins production at commercial scale: Using models to improve
plant operation and product properties.
Kim B. McAuley*
8:45 – 176. Stereospecific bis(phenolate)
ether complexes for olefin polymerization.
Robert M. Waymouth*,
Elizabeth T. Kiesewetter, Soeren Randoll,
Madalyn Radlauer
9:15 – 177. Controlled isomerization polymerization of cycloolefins and dienes catalyzed by Pd complexes.
Osakada Kohtaro*, Daisuke Takeuchi
9:45 – 178. Exploiting a catalyst’s affinity for
alpha-olefins. Stephen A. Miller*
10:15 – 179. Polymerization of olefins with
single-site catalyst captured on aminefunctionalized surface of SBA-15.
Jeong Suk Lee, Young Soo Ko*,
Jong-Ji Jeon, Jin-Heong Yim
10:45 – 180. Control of polyethylene polymer
microstructure in a dual reactor process.
Stephen J. Brown*, Christopher Dobbin
Thursday Afternoon
Convention Center
328
Polymeric Materials from Renewable
Resources (#6)
Organized by: V. Finkenstadt,
S. Chakraborty, R. Konduri, X. Liao,
L. Liu
Presiding: V. Finkenstadt, L. Liu
12:30 – 181. Novel synthetic products from
the common milkweed (Asclepias syriaca
L) and their potential in the rural farm
economy. Rogers E. Harry-O’kuru*
13:00 – 182. Semicrystalline copolyamides
based on the renewable monomer, 1,9nonane diamine. Jie He*, Alex Kugel,
Bret Chisholm
13:30 – 183. Chromatographic separation of
polysaccharides by degree of substitution. Wolfgang Radke, Hiwa O. Gareb*
14:00 – 184. Wheat gluten-based renewable
polymer materials: Chemical modification, material performance and biodegradation. Xiaoqing Zhang*
14:30 – 185. Polymerization of dairy-proteinbased bioplastic composites in presence
of functional organic acids.
Charles Onwulata*,
Sudarsan Mukhopadyay
15:00 – 186. Development of antimicrobial
food packaging using polymeric materials
from renewable resources. Tony Jin*
15:30 – 187. ␬ Carrageenan and chitosan interpenetrating network for transdermal
drug delivery. Soma Chakraborty*
Convention Center
325B
Chemistry and Functional Properties of Soft
Interfaces (#42)
Organized by: A. Takahara, K. Char,
K. Kurihara, M. Maeda, Z. Su, G. Warr,
K. Wynne
Presiding: K. Kurihara, Z. Su
12:30 – 188. Gradient wettability surfaces.
Yanchun Han*
12:55 – 189. PNIPAM copolymers and nanocomposites with responsive hydration
properties. David Bergbreiter*
13:10 – 190. Direct measurement of glass
transition temperature gradient at the
polymer bilayer interfaces by nanothermal analysis. Noriyuki Tanji, Hui Wu,
Motoyasu Kobayashi,
Atsushi Takahara*
13:25 – 191. Tuning Tg by 100 K in multilayer
polymer films and nanostructured block
copolymer/homopolymer blends.
Soyoung Kim*, Connie Roth,
Rodney Priestley, Robert Sandoval,
Michelle Mok, Linda Broadbelt,
John Torkelson*
13:40 – 192. Is the dynamics of polymer
films consistent with their Tg?
Zhaohui Yang, Yoshihisa Fuiji,
Chi Hang Lam, Ophelia Tsui*
14:05 – 193. Infiltration of a neutral aqueous
solution into thin poly(styrene) films.
Shoichi Kubo, Masaru Nakagawa*
14:20 – 194. Adhesion of stimuli-responsive
hydrogels by electrophoresis.
Taka-Aki Asoh*, Akihiko Kikuchi*
14:35 – 195. Entropically driven super-lubrication of concentrated polymer brushes
in solvents. Yoshinobu Tsujii*,
Akihiro Nomura, Weiping Gao,
Kohji Ohno, Takeshi Fukuda
15:00 – 196. Preparation of the gel with arrayed micro rods and investigation of its
volume alteration property.
Satoshi Takahashi*, Sachiko Obara,
Takashi Ymauchi, Norio Tsubokawa,
Kazuhiro Fukami, Tetsuo Sakka,
Yukio Ogata
15:15 – 197. Ion transport gating with
switchable mixed polyelectrolyte
brushes. Mikhail Motornov*,
Tsz Kin Tam, Marcos Pita, Ihor Tokarev,
Evgeny Katz, Sergiy Minko
15:30 – 198. Adsorbed layer structure of polymerisable surfactants at the solid/aqueous solution interface. Gregory Warr,
Annabelle C. Blom,
Khwanrat Chatjaroenporn,
Kathryn A. White, Regina Schwering,
Robert W. Baker, Paul A. FitzGerald
15:45 – 199. Observation of PEG thickness
of PEG-PLys based polyplex micelle.
Kensuke Osada*, Theofilus A. Tockary,
Kazunori Kataoka
16:00 – 200. Reliable measurements of slip
using the AFM. Liwen Zhu, Phil Attard,
Chiara Neto*
Convention Center
323B
Advanced Polymeric Membranes for
Environmental, Biomedical and
Bioengineering Application (#51)
Organized by: A. Higuchi, B. Freeman,
A. Hill, Y.M. Lee
Presiding: A. Higuchi, V. Chen
12:30 – 201. Direct ex vivo expansion of hematopoietic stem cells from umbilical
cord blood on membranes.
Akon Higuchi*
13:10 – 202. Thermal, mechanical and
chemical modifications of titania nanoparticles as antifouling additives and
coatings for PES membranes.
Amir Razmjou*, Jaleh Mansouri,
Vicki Chen, May Lim, Mega Ng,
Rose Amal
13:50 – 203. Experimental evaluation and
theoretical analysis of affinity membrane
adsorbers. Simone Dimartino,
Cristiana Boi, Giulio C. Sarti*
14:30 – 204. Thermo-responsive poly(N-isopropylacrylamide-co-acrylic acid) copolymers grafted onto track-etched polycarbonate films. Jessie S. Lue*,
Chi-Hwa Chen, Chao-Ming Shih
15:10 – 205. Understanding the differences
in ion sorption and salt transport between
highly charged and less highly charged
polymer desalination membrane materials. Geoffrey M. Geise*,
Linda K. Passaniti, James E. McGrath,
Benny D. Freeman, Donald R. Paul
15:30 – 206. Plasma polymerization at atmospheric pressure: An environmental
friendly approach to synthesize biocompatible, hybrid, barrier or ion - exchange
coatings. Delphine Merche*,
Bernard Nisol, Nicolas Vandencasteele,
Julie Hubert, François Dabeux,
Abdelkrim Batan, Herman Terryn,
François Reniers*
15:50 – 207. High-internal-free-volume
glassy polymers for advanced membrane
applications. Ho Bum Park*,
Yoon Jin Cho, Byung Kook Ahn
Convention Center
323A
Polymer Materials Performance,
Degradation and Optimization (#64)
Organized by: M. Celina, T. Dargaville,
H. Kudoh
Presiding: S. Al-Malaika
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–97
03-MACR
12:30 – 208. PP clay nanocomposites degradation and stabilisation.
Sahar Al-Malaika*, Joana Barbas,
Husam Sheena
13:00 – 209. Utility of nanocomposites in fire
retardancy. Charles A. Wilkie*
13:30 – 210. Evaluation of degradation on
Nylon-6 and Nylon-6/montmorillonite
nanocomposites by color measurement.
Mikiya Ito*, Kazukiyo Nagai
13:50 – 211. Withdrawn
14:10 – 212. Thermal degradation behavior
of siloxane elastomer impregnated carbon nanotube areogel networks.
James P. Lewicki*, Brian Mayer,
Marcus Worsley, Ted Baumann,
Robert Maxwell
14:40 – 213. Nanofibrous structures by single particle nanofabrication. Shu Seki*
15:10 – 214. Withdrawn
15:30 – 215. Protecting polymers with
atomic layer deposition coatings.
Timothy K. Minton*, Bohan Wu,
Jianming Zhang, Ned Lindholm,
Jennifer O’Patchen, Steven M. George,
Markus D. Groner
15:50 – 216. Nanoindentation on nanocoatings: Analyzing the effects of nanoparticles on the nanomechanical properties
of silicone ceramer materials.
Atul Tiwari*, Lloyd H. Hihara
16:10 – 217. Nano-scale fabrication of perfluorinated polymers using focused ion
beams. Akihiro Oshima*,
Tomohiro Takahashi, Satoshi Okubo,
Naoyuki Fukutake, Yuya Takasawa,
Tomoko Gowa, Masakazu Washio,
Seiichi Tagawa
Convention Center
321B
The New Age of Advanced Materials:
Supramolecular Architectures and Smart
Materials (#98)
Organized by: E. Yashima, T. Aida,
F. Caruso, M. Lee, K. Wooley
Presiding: K. Wooley
12:30 – 218. Advanced macromolecular materials from dupramolecular chemistry.
Ulrich (Uli) Wiesner*
13:00 – 219. Self-assembly in soft coordination nanosystems. Nobuo Kimizuka*
13:30 – 220. Graphene as unique multitalent
- catalyst, semiconductor, nanowire, protein template. Klaus Müllen*
14:00 – 221. Highly fluorescent molecules
and polymers incorporating excited state
intramolecular proton transfer.
Soo Young Park
14:30 – 222. Dye assemblies for supramolecular electronics. Frank Würthner*
15:00 – 223. Novel synthesis and property of
BN nanotubes and nanosheets.
Yoshio Bando*, Zhi Chunyi,
Tang Chengchun, Dmitri Golberg
15:30 – 224. Dynamic covalent polymers
driven by stimuli-responsive metathesis
reactions. Hideyuki Otsuka*,
Shigehisa Kamimura, Shinsuke Nagano,
Atsushi Irie, Takeshi Maeda,
Masamichi Nishihara, Atsushi Takahara
15:45 – 225. Technomimetic rotatory nanodevices driven by electron transfer or
STM Tip. Gwenael Rapenne*
16:00 – 226. Hierarchical self assembly of
aqueous supramolecular polymers by
cucurbit[8]uril. Oren Scherman*
16:15 – 227. Polymers with molecular memory based on restricted rotation.
Ken D. Shimizu*
Convention Center
322AB
Polyolefins Chemistry and Beyond - From
Bench to Commercial Scale (#211)
Organized by: F. Sibtain, M. Chan,
K. Nozaki, R. Waymouth
Presiding: M. Chan
12:30 Introduction
12:35 – 228. Iron procatalysts in olefin polymerization worthy for commercial consideration. Wen-Hua Sun*
98 –TECH
TECHNICAL PROGRAM
13:15 – 229. Coordination polymerization of
polar monomers. Kyoko Nozaki*
13:45 – 230. In search for single component
catalysts for ethylene oligo- and polymerization? Sandro Gambarotta*
14:15 – 231. Insights into metallocene activation. Steven P. Diefenbach*
14:45 – 232. Production of organometallic
compounds for polymerization catalysts.
Toshio Sumida*, Mayumi Nishida
15:15 – 233. Scalable production of precision polyolefins via living coordinative
chain-transfer polymerization of ethene,
␣-olefins and ␣,␻-nonconjugated dienes.
Lawrence R. Sita*, Jia Wei, Wei Zhang
15:45 – 234. Recent advances in olefin block
copolymers: Polydispersity, phase behavior, and photonic polyethylene.
Phillip Hustad*, Jeffrey D. Weinhold,
Brian Landes, Patricia L. Roberts,
Eddy I. Garcia-Meitin, Gary R. Marchand
Thursday Evening
Convention Center
Kamehameha Halls II and III
Polymeric Materials from Renewable
Resources (#6)
Organized by: V. Finkenstadt,
S. Chakraborty, R. Konduri, X. Liao,
L. Liu
Presiding: V. Finkenstadt, L. Liu,
S. Chakraborty
Poster Session
19:00 – 21:00
235. Chemoenzymatic synthesis of amylosegrafting heteropolysaccharides.
Yuji Omagari, Jun-ichi Kadokawa*
236. Elucidation of the structure of a highly
active catalytic system for CO2/epoxide
copolymerization: A salen-cobaltate
complex of an unusual binding mode.
Anish Cyriac, Sung Jae Na,
BunYeoul Lee*
237. Terpolymerizations of CO2, propylene
oxide, and various epoxides using a cobalt(III) complex of salen-type ligand tethered by four quaternary ammonium salts.
Sang-Hwan Lee, Jong-Eon Seong,
Bun-Yeoul Lee*
238. Anion variation on a cobalt(III) complex
of salen-type ligand tethered by four quaternary ammonium salts for CO2/epoxide
copolymerization. Eun Seok Park,
Jina Yoo, Bun Yeoul Lee*
239. Preparation and physicochemical properties of water-insoluble glycosaminoglycan composite films. Masafumi Ohashi,
Mineo Hashizume
240. Short route from glycerol to polyureathane adhesives. Mariusz Maminski*,
Pawel Parzuchowski, Magdalena Krol
241. Right- and left-handed helices from cellulose oligomers: Why create them?
Naozumi Teramoto, Mitsuhiro Shibata,
Morton H. Litt, Iraj Ganjian,
Navzer Sachinvala*
242. Synthesis and characterization of superabsorbent hydrogels based on carboxymethyloxyalkylcellulose. Risa Sanui,
Rumiko Fujioka, Toshio Yoshimura*
243. Biodegradable network poly(ether urethane)s from natural resources.
Akito Ooi*, Wataru Sakai,
Naoto Tsutsumi, Minoru Nagata
244. Preparation and properties of chitosan/
poly(␥-glutamic acid) complex.
Naomichi Hirotani, Shinsuke Ifuku,
Minoru Morimoto, Hiroyuki Saimoto*
245. Synthesis of carboxymethylchitin derivatives having polymerizable groups.
Atsushi Terada, Shinsuke Ifuku,
Minoru Morimoto, Hiroyuki Saimoto
246. Preparation of a thermosensitive chitosan/N-isopropylacrylamide copolymer
through atom transfer radical polymerization. Takeshi Miwa*, Shinsuke Ifuku,
Minoru Morimoto, Hiroyuki Saimoto
247. Sugarcane bagasse: Depolymerization
of the extracted lignin in presence of anthraquinone derivatives, application to
the preparation of lignin- phenolic type
resins and use as reinforcement in phenolic type thermosets.
Cristina G. da Silva, Elisabete Frollini*,
Stephane Grelier, Frederique Pichavant,
Alain Castellan*
248. Enzymatic and acid hydrolysis of sisal
pulp for elaboration of biocomposites
and bioethanol production.
Talita M. Lacerda, Elisabete Frollini*,
Christian Gardrat, Frederique Pichavant,
Veronique Coma*
249. Enhancement hydrolyzation of cellulose
with cellulase through ultrasonic treatment. Jun Ye, Qing-xia Chen, Jun Chen,
Jian Xiong*
250. Biopolymer research in Costa Rica:
From aquaculture waste streams to
added value derivatives for biomedical
applications. Maria Sibaja,
Sergio Madrigal-Carballo*,
José Vega-Baudrit, Vanessa Zamora,
Marianelly Esquivel, Maikol Ramos
251. Enantioselective and product-selective
alternating copolymerization of carbon dioxide and epoxide. Kaori Sakurai,
Isamu Esashika, Hidetoshi Goto,
Hiroshi Sugimoto*
252. Biopolymer research in Costa Rica:
From aquaculture waste streams to
added value derivatives for biomedical
applications.
Sergio Madrigal-Carballo*,
Jose Vega-Baudrit, Vanessa Zamora,
Maikol Ramos, Marianelly Esquivel,
Maria Sibaja
253. Preparation and properties of green
composites based on fruit peel and some
biodegradable plastics. Chihiro Higashi,
Rumiko Fujioka, Toshio Yoshimura*
Convention Center
325B
Chemistry and Functional Properties of Soft
Interfaces (#42)
Organized by: A. Takahara, K. Char,
K. Kurihara, M. Maeda, Z. Su, G. Warr,
K. Wynne
Presiding: A. Takahara, M. Maeda
19:00 – 254. Functional modification of soft
interfaces with polymer-binding peptides.
Takeshi Serizawa*
19:25 – 255. Self-reproducing vesicular system associated with self-replication of
DNA. Tadashi Sugawara,
Kensuke Kurihara, Mieko Tamura,
Koh-ichiroh Shohda, Taro Toyota,
Kentaro Suzuki
19:40 – 256. Characterization of peptide and
protein interactions with surfaces.
Tobias Weidner, Joseph E. Baio,
Lara J. Gamble, David G. Castner*
19:55 – 257. Novel high-sensitive immunoassay interface with orientation-controlled antibodies. Madoka Takai*,
Nobuyuki Tajima, Kazuhiko Ishihara
20:10 – 258. Nanoscale study of the mechanical properties of individual live bacteria using atomic force microscopy.
Michelle L. Gee*, Huabin Wang,
Jonathan Wilksch, Richard A. Strugnell
20:35 – 259. Bio-recognizing surface design
for bio-transistor. Akira Matsumoto,
Naoko Sato, Horacio Cabral,
Kazunori Kataoka, Yuji Miyahara*
20:50 Closing remarks
Convention Center
323A
Polymer Materials Performance,
Degradation and Optimization (#64)
Organized by: M. Celina, T. Dargaville,
H. Kudoh
Presiding: K. George
19:00 – 260. Bioresorbable polymeric devices for bone repair: Strategies to optimise performance. Fraser Buchanan*
19:30 – 261. PLLA-based networks for biomedical applications. Karina George*,
Francois Schue, Traian Chirila,
Edeline Wentrup-Byrne
20:00 – 262. Modification of water-absorption and adhesive properties of polyolefins and other chemically-stable polymeric materials. Hitoshi Kanazawa*,
Aya Inada, Jun Sato, Yoshitaka Sugeno
Convention Center
Kamehameha Halls II and III
Hybrid Conjugated Polymer Materials (#82)
Organized by: M. Wolf, R. Advincula,
S. Valiyaveettil, K. Yamamoto
Presiding: M. Wolf
Poster Session
19:00 – 21:00
263. Development of dendritic structures
having potential gradient. Ken Albrecht,
Kimihisa Yamamoto*
264. Controlled assembly of ferrocene derivatives as redox-active molecules in dendritic polyphenylazomethines.
Yousuke Ochi, Mana Suzuki,
Takane Imaoka, Masaki Murata,
Yasuaki Einaga, Hiroshi Nishihara,
Kimihisa Yamamoto*
265. Supramolecular complex of a donortype dendrimer with fullerenes.
Yasunori Kuramoto*, Ken Albrecht,
Kimihisa Yamamoto
266. Photoinduced electron transfer in phenylazomethine dendrimer having stepwise metal assembling ability.
Hiroki Kobayashi*, Takane Imaoka,
Kimihisa Yamamoto
267. Synthesis and property of terminal
modified dendritic polyphenylazomethine
as a novel soft-material. Yousuke Ochi,
Keisuke Azuma, Kozue Sakurai,
Kimihisa Yamamoto*
268. Preparation and characterization of polybenzoxazole-silica hybrids.
Mikako Takenaka*, Yasuharu Yamada
269. Synthesis of polymers having spiropyran moieties in the main-chain.
Yuhki Tanaka, Jun-ichi Kadokawa*
270. New cardo polymer: 2,6-Dimethyl-1,5dibenzoylnaphthalene-containing polycarbonates. Chika Yamashita,
Kazuko Nakazono, Yasuhiro Khosaka,
Takahiro Kojima, Katsumoto Hosokawa,
Toshikazu Takata*
271. Synthesis and characterization of polypyrrole alternative copolymer films.
Yusuke Hoshina*, Takaomi Kobayashi
272. Fine discrimination of molecular shape
by a dendrimer with nanopockets.
Tetsuro Yamashita, Takane Imaoka,
Kimihisa Yamamoto*
273. All-organic polymer actuators containing conjugated polymers. Yong Ho Kim*,
Sin Woo Lee, Jong Wan Kim,
Jin Woo Bae, Jae Young Jho
274. Synthesis of stable ditopic nitrile N-oxide and its application to cross-linking via
click chemistry. Morio Yonekawa,
Lee Young-Gi, Yasuhito Koyama,
Toshikazu Takata*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR
275. Synthesis and polymerization of hetero
aromatic-hybridized cardo monomers,
and property of the resulting polymers.
Hitoshi Okuda, Yasuhito Koyama,
Toshikazu Takata*
276. Significant size effect on catalytic activity of subnano platinum clusters.
Saori Omura, Wang Jae Chun,
Atsunori Sonoi, Takane Imaoka,
Kimihisa Yamamoto*
277. Catalytic activity of oxygen reduction
reaction by dendrimer-encapsulated
metal nanoparticles. Yushi Hongo,
Atsunori Sonoi, Takane Imaoka,
Wang-Jae Chun, Kimihisa Yamamoto*
Convention Center
Kamehameha Halls II and III
Azobenzene Polymers for Photo-Reversible
Structures and Surfaces (#144)
Organized by: C. Barrett, T. Ikeda,
P. Palffy-Muhoray, Y. Zhao
Presiding: C. Barrett
Poster Session
19:00 – 21:00
Friday Morning
9:50 – 306. Targeted engineering of Cupriavidus necator chromosome for biosynthesis of poly(3-hydroxybutyrate-co-3hydroxyhexanoate) from vegetable oil.
Jun Mifune, Satoshi Nakamura,
Toshiaki Fukui*
10:10 – 307. In vivo characterization of polyhydroxyalkanoate production capability
and substrate specificity of polyhydroxyalkanoate synthase of Burkholderia cepacia strain JC-1. Normi Mohd Yahaya*,
Julian Chin Hock Chye*,
Amirul Al-Ashraf Abdullah
10:30 – 308. Biodegradable composites and
blends from hardwood hemicellulose.
Arthur J. Stipanovic*, Vincent Barber,
Nicholas Stam
11:00 – 309. Development of amphiphilic
block copolymers based on biopolyesters and their biomaterials applications.
Jun Li*
Convention Center
323B
Convention Center
321B
Advanced Polymeric Membranes for
Environmental, Biomedical and
Bioengineering Application (#51)
Synthesis, Structure, and Physical
Properties of Advanced Polymer Gels (#136)
290. Synthesis of new COC, dihydrodicyclopentadiene/ethylene and dihydrotricyclopentadiene/ethylene. Seung Hyun Do,
Seung Tack Yu, Bun Yeoul Lee*
291. Study on polymerization performances
in slurry process using supported nonmetallocene catalysts. Chuanfeng Li,
Yuefeng Gu, Lin Kan, Bo Liu, Xiaoli Yao,
Jiye Bai, Shaohui Chen
292. Nickel complexes as procatalysts in
olefin polymerization. Cunyue Guo,
Jiangang Yu, Tianpengfei Xiao,
Wen-Hua Sun*
293. Structure-property relationship of various hydrogenated poly(norbornene-biimides)s prepared from ring opening metathesis polymerization.
Kyung-Hwan Yoon, Insun Park,
Do Y. Yoon*
278. Withdrawn
279. Reversible photoswitching of azobenzene-functionalized self-assembled
monolayers. Daisuke Ishikawa*,
Takumu Honda, Eisuke Ito, Mina Han,
Masahiko Hara
280. Azobenzene-peptide containing polyelectrolyte multilayer films showing photo-controlled cell adhesion.
Alexis Goulet-Hanssens,
Christopher J. Barrett
281. Spectroscopy and isomerization kinetics of azo dyes complexed with metal
ions. Jeffrey A. Gray*,
Joshua E. Szekely, Philip A. Weiss
282. Fully aromatic polyimide containing
azobenzene as a side group: Synthesis
and properties under ultraviolet light exposure. Seung Woo Lee*, Se Jin Kwon
283. Guest-host polymers revisited: High
and stable photoinduced anisotropy mediated by chromophore aggregation.
Arri Priimagi*, Andriy Shevchenko,
Francisco J. Rodriguez, Martti Kauranen,
Matti Kaivola, Paul Rochon
284. Synthesis, crystal structure and photochemical properties of azobenzene-palladium complexes. Mina Han*,
Tomohiro Hirade, Masahiko Hara
285. Fabrication of crosslinked liquid-crystalline polymer films with a periodic structure. Keisuke Saito, Jun-ichi Mamiya,
Atsushi Shishido, Tomiki Ikeda*
286. Preparation and photomobile property
of crosslinked liquid-crystalline polymers
with cholesteric phases. Yohei Yoshida,
Jun-ichi Mamiya, Tomiki Ikeda*
287. Phototriggered mass migration azo
polymer systems involving photocrosslinking unit. Li Wenhan*,
Shusaku Nagano, Takahiro Seki
7:30 – 294. Molecularly imprinted nanofiber
membranes. Masakazu Yoshikawa*
8:10 – 295. Response of human mesenchymal stem cells to the morphology variation of polyhydroxyalkanoate (PHA) membranes. Yi-Ming Sun*, Bo-Yi Yu
8:50 – 296. Effect of surface morphology on
antifouling property of porous hollow fiber
membranes. Hideto Matsuyama*,
Takeshi Katagiri, Yoshikage Ohmukai,
Tatsuo Maruyama, Tomohiro Sotani
9:30 – 297. Stimuli-responsive and tunablebioadhesive soft membranes of nonionic
poly(N-isopropyl acrylamide) containing
zwitterionic polysulfobetaine.
Yung Chang*
10:00 – 298. Novel polymers of intrinsic microporosity (PIMs) for membrane applications. Neil B. McKeown, Mariolino Carta,
Kadhum J. Msayib, Peter M. Budd,
Detlev Fritsch
10:30 – 299. Fabrication of Poly (vinyl alcohol) macromer for biomedical application.
Narahari Mahanta, Yiwei Teow,
Suresh Valiyaveettil
11:00 – 300. Use of remote oxygen plasma
to create protein resistant surfaces.
Nicolas Vandencasteele*,
Bérangère Broze, Stéphanie Collette,
Caroline De Vos, Pascal Viville,
Roberto Lazzaroni, François Reniers
Convention Center
Kamehameha Halls II and III
Organized by: H. Uyama, G.G. Chen,
S.S. Im, T. Iwata, C. Nomura
Presiding: G. Chen, H. Uyama
Polyolefins Chemistry and Beyond - From
Bench to Commercial Scale (#211)
Organized by: F. Sibtain, M. Chan,
K. Nozaki, R. Waymouth
Presiding: F. Sibtain
Poster Session
19:00 – 21:00
288. Effects of phosphine in synthesis of regioblock polybutadiene with CoCl2based catalyst via reversible coordination
of Lewis base. Zhengguo Cai,
Masahito Shinzawa, Yuushou Nakayama,
Takeshi Shiono*
289. Magnetic orientation of low molecular
weight polyethylene. Gaku Ishikawa*,
Nofumi Naga, Masafumi Yamato,
Keiichi Noguchi
Organized by: A. Higuchi, B. Freeman,
A. Hill, Y.M. Lee
Presiding: M. Yoshikawa, K. Tung
Convention Center
328
Biodegradable and Biomass Plastics (#95)
7:30 – 301. Structure analysis and enzymatic
degradation of beta-form in poly[(R)-3hydroxybutyrate] fibers and films.
Tadahisa Iwata*
8:00 – 302. Microbial cell factories for production of polymers and hydroxyalkanoic
acids. George Guo-Qiang Chen*
8:30 – 303. Charged Poly(␤-hydroxyalkanoates). Carmen Scholz*, Jeff Sparks
9:00 – 304. Current advances in microbial
cell factories for lactate-based polyesters
driven by lactate-polymerizing enzymes.
Seiichi Taguchi*
9:30 – 305. Non-enzymatic stem cell detachment with biodegradable thermosensitive
poly[(R)-3-hydroxybutyrate]-based copolymers. Xian Jun Loh*
Organized by: K. Ito, M. Sibayama,
R. Siegel, C. Wu
Presiding: K. Ito, M. Shibayama
7:30 – 310. Slide-ring materials using supramolecular architecuture. Kohzo Ito*
7:45 – 311. Mechanical and osmotic properties of slide-ring gels with movable crosslinks. Kenji Urayama*
8:15 – 312. Composite hydrogels with temperature sensitive heterogeneities.
Walter Richtering*, Judith Meid,
Swen Lehmann
8:45 – 313. Dielectric relaxation studies on
the dynamic arrest/jamming of concentrated colloidal dispersions. Dan Zhu,
Yi Hu, Jian Shen, Chi Wu
9:15 – 314. Small angle scattering studies of
high strength interpenetrating network
hydrogels. Dale Waters*, Kristin Engberg,
Rachel Parke-Houben, Michael Toney,
Curtis W. Frank
9:45 – 315. Why is a double-network gel so
tough? A discussion on its common features with tough tissues.
Jian Ping Gong*
10:15 – 316. 3-D Optical forming of highstrength gels. Keiichi Sugita,
Ruri Hidema, Hidemitsu Furukawa*
10:30 – 317. Crystallization influenced by gel
formation in prior microphase separation
of multi-block copolymers. Yu Ma,
Wenbing Hu*
10:45 – 318. Gelation mechanism and physical properties of Tetra-PEG gel.
Takamasa Sakai*, Manami Kurakazu,
Yuki Akagi, Takuya Katashima,
Takuro Matsunaga, Mitsuhiro Shibayama,
Ung-il Chung
11:00 – 319. Theory of phase transitions in
polyelectrolyte gels.
Murugappan Muthukumar*
Convention Center
325B
8:30 – 322. Tunable, amphiphilic, hyperbranched fluoropolymers and multiple
strategies to enhance antifouling: From
nanoscopic heterogeneity to the surface
presentation of active deterrents.
Philip M. Imbesi, Christopher Fidge,
Neeraj Gohad, Kevin A. Pollack,
Andrew S. Mount, Karen L. Wooley*
8:50 – 323. Mimicking the phase transition of
proteins with synthetic polymers.
Takeshi Mori*, Yasushi Maeda,
Tomohiro Hirano, Keiji Minagawa,
Masami Tanaka, Takuro Niidome,
Yoshiki Katayama
9:20 – 324. Folding and function of long
multiblock copolymer chains prepared by
the SAAP. Chi Wu
9:40 – 325. Effects of salt, chain length, and
pH on the “non-surface activity” of ionic
amphiphilic diblock copolymers.
Hideki Matsuoka, Arjun Ghosh,
Tomoyuki Onishi, Masahiro Hachisuka
10:00 – 326. Probing hydrophobic interactions with pyrene-labeled amphiphilic
macromolecules. Christine Keyes-Baig,
Howard Siu, Jean Duhamel*,
Javed Akbar, Shawn Wettig*
10:30 – 327. Hydration behavior of partially
hydrophilically modified poly(N-isopropylacrylamide) in aqueous solution.
Toshiyuki Shikata, Tomoko Maeda
10:50 – 328. Responsive macromolecular
assemblies: Sol/gel transition induced by
coupling pH and temperature.
Dominique Hourdet*, Elodie Siband,
Yvette Tran
11:10 – 329. Taciticity effects on the phase
behaviors of poly(N-isopropylacrylamide)
and poly(N,N-diethylacrylamide) in water.
Yukiteru Katsumoto, Noriyuki Kubosaki,
Yuki Etoh, Naotsugu Shimoda,
Tatsuhiko Miyata
Convention Center
323A
Controlled/Living Radical Polymerization:
Mechanisms, Catalysts, Reaction
Engineering, Materials and Applications
(#236)
Organized by: S. Zhu, T. Fukuda, B. Li,
K. Matyjaszewski, M. Monteiro
Presiding: S. Zhu
7:30 – 330. ATRP: From mechanism to materials. Krzysztof Matyjaszewski*
8:00 – 331. Development of switchable
RAFT agents. Graeme Moad*,
Massimo Benaglia, Chen Ming,
John Chiefari, Keddie Daniel,
Ezio Rizzardo, San H. Thang
8:30 – 332. Gradient copolymers: Molecular
design via controlled radical polymerization for applications ranging from interfacial agents and compatibilizers for nanostructured blends to damping materials.
John M. Torkelson*, Michelle M. Mok,
Robert W. Sandoval, Jungki Kim
8:50 – 333. Metal-catalyzed chain- and stepgrowth radical polymerization for precision polymer synthesis.
Masami Kamigaito*, Kotaro Satoh,
Kanji Nagai, Masato Mizutani
Amphiphilic Polymers: Fundamentals and
Applications (#231)
Organized by: T. Sato, K. Akiyoshi,
C. McCormick, F. Winnik
Presiding: T. Sato, F. Winnik, K. Akiyoshi
7:30 Introductory remarks
7:40 – 320. Direct penetration of amphiphilic
phospholipid polymers across living cell
membrane. Kazuhiko Ishihara*,
Tatsuro Goda, Yuusuke Goto
8:10 – 321. Imaging the lateral structure of
poly(ethylene glycol)-grafted phosphocholine membranes and insulin insertion.
Valeria Tsoukanova*, Kanwal Tanwir
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–99
03-MACR
9:10 – 334. Synthesis and characterization of
hyperbranched polyacrylamide using
semi-batch reversible addition-fragmentation chain transfer (RAFT) copolymerization of acrylamide and N,N’-methylenebisacrylamide. Dunming Wang,
Wen-Jun Wang, Bo-Geng Li,
Shiping Zhu
9:30 – 335. Kinetics of controlled/living radical polymerization: Bulk and miniemulsion. Hidetaka Tobita*
10:00 – 336. New polymer synthesis by controlling the kinetic process of ATRP of
AB* inimers. Bo-Tao Dong,
Yong-Quan Dong, Zi-Chen Li*
10:30 – 337. Continuous atom transfer radical polymerization with low catalyst concentration. Nicky Chan*,
Robin A. Hutchinson,
Michael F. Cunningham, Jan Meuldijk
10:50 – 338. Kinetic modeling of atom transfer radical and nitroxide mediated polymerization. Dagmar R. D’hooge,
Lien Bentein, Evelyn B. Burrick,
Marie-Françoise Reyniers*, Guy B. Marin
11:10 – 339. Hybrid atom transfer radical polymerization system for balanced polymerization rate and polymer molecular
weight control. Santiago Faucher*,
Shiping Zhu, Mark Machado
Convention Center
322AB
Functional Block Copolymer Assemblies
(#57)
Organized by: T. Lodge, J. Bang, C. Han,
M. Hillmyer, Y. Matsushita
Presiding: T. Lodge
7:50 – 340. Block copolymer thin film assemblies containing functional nano-objects. Kookheon Char*
8:20 – 341. Photo-assisted controlled radical
polymerization and its application.
Yang Wan-Tai, Yin Minzhen, Li Huiling,
Liu Lianying, Ma Yuhong
8:50 – 342. Design of photo-crosslinkable
block copolymers for various nano-fabrications. Joona Bang*, Dongjune Hwang,
Misang Yoo, Seyong Kim
9:10 – 343. Self-assembly of P3HT-based
diblock copolymers and their application
in organic solar cells. Kai Xiao*,
Xiang Yu, Jihua Chen, Kunlun Hong,
David Geohegan
9:30 – 344. Fully conjugated block copolymers by ring-opening metathesis polymerization. Michael L. Turner*,
James W. Kingsley, Chin Y. Yu,
Andrew C. Spring, Masaki Horie,
David G. Lidzey, Simon King,
Saif A. Haque, Jenny Nelson
9:50 – 345. Perpendicular orientation of cylindrical nanodomains in a block copolymer thick film. Hisakazu Fujiwara,
Go Kimura, Yohei Mizuno,
Shinichi Sakurai*
10:20 – 346. Liquid crystalline block copolymer: Roll-to-roll processable nanostructured films and template processes.
Tomokazu Iyoda*
10:50 – 347. Controlling the location of thermally stable polymer coated inorganic
nanorods using block copolymer templates. Bumjoon J. Kim*
11:10 – 348. Shape memory block copolymers. Kevin A. Cavicchi, Pengzhan Fei
Convention Center
327
Polymer Nano-Hybrids at Bio-Interfaces
(#127)
Organized by: Y. Chujo, C.S. Ha,
K. Uhrich, K. Wynne
Presiding: K. Uhrich
8:00 Opening remarks
100 –TECH
TECHNICAL PROGRAM
8:10 – 349. More fluorous surface modifier
makes it less oleophobic: Fluorinated-siloxane copolymer/PDMS fumed silica
coatings and nanocomposites.
Kenneth J. Wynne, Souvik Chakrabarty,
Wei Zhang, Ying Zheng, Lorenzo Orsini,
Andrea Morelli, Giancarlo Galli,
Emo Chiellini
8:35 – 350. Polymer brush nanosponges for
protein separations. Dan Dyer*,
Ven Ney Wong, Bojan Mitrovic,
Gary Kinsel
8:55 – 351. Biochemical-to-optical signal
transduction by responsive hydrogel/noble metal nanoparticle composite thin
films. Ihor Tokarev*, Iryna Minko,
Venkateshwarlu Gopishetty, Evgeny Katz,
Sergiy Minko
9:15 – 352. Remarkable polarization and
alignment of biological cells on high-aspect-ratio polymer nanohybrid arrays.
Michael A. Bucaro, Benjamin Hatton,
Joanna Aizenberg*
9:40 – 353. Covalent attachment of multilayers (CAM) to poly(tetrafluoroethylene)
(PTFE) surfaces: Patterning of bioactive
species. Marek W. Urban*,
Nattharika Aumsuwan
10:00 – 354. Nanohybrid gel of polyethylene
glycol and silica as a matrix for cell CT
imaging. Fengyu Su*,
Vivek Nandakumar, Laimonas Kelbauska,
Yanqing Tian, Yuguang Jin, Celeste Riley,
Brent L. Vernon, Roger H. Johnson,
Deirdre R. Meldrum
10:20 – 355. Hybrid inorganic-organic polymers as nanostructured platforms for
bone tissue engineering.
Harry R. Allcock*, Arlin L. Weikel,
Cato T. Laurencin, Lakshmi S. Nair
Convention Center
Kamehameha Halls II and III
Polymer Materials Performance,
Degradation and Optimization (#64)
Organized by: M. Celina, T. Dargaville,
H. Kudoh
Presiding: M. Celina, H. Kudo
Poster Session
10:00 – 12:00
356. Radiation and thermal ageing studies of
polymer materials used in cable insulation in nuclear power plants-2: Flame retardant ethylene propylene rubber (EPR).
Hisaaki Kudo*, Tadao Seguchi,
Kiyotoshi Tamura, Takeshi Ohshima,
Akira Idesaki, Akihiko Shimada
357. Radiation and thermal ageing studies of
polymer materials used in cable insulation in nuclear power plants-3: Crosslinked polyethylene (XLPE).
Hisaaki Kudo*, Tadao Seguchi,
Kiyotoshi Tamura, Takeshi Ohshima,
Akira Idesaki, Akihiko Shimada,
Takanori Tago
358. Radiation and thermal ageing studies of
polymer materials used in cable insulation in nuclear power plants-4: Polyvinylchloride (PVC). Akira Idesaki*,
Tadao Seguchi, Kiyotoshi Tamura,
Takeshi Ohshima, Akihiko Shimada,
Hisaaki Kudoh
359. Radiation and thermal ageing studies of
polymer materials used in cable insulation in nuclear power plant-5: Silicone
rubber (SiR). Akihiko Shimada*,
Tadao Seguchi, Kiyotoshi Tamura,
Takeshi Ohshima, Akira Idesaki,
Hisaaki Kudo
360. Analysis of the amylose macromolecules products on MALDI-TOF, created
by mechanochemical influence.
Guzel Kireeva*, Viktoria Kurova,
Sergey Varfolomeev, Vladimir Zhorin
361. Synthesis of microscopic carboxymethylcellulose hydrogels with metal ions by
radiation-induced crosslinking.
Naotsugu Nagasawa*, Bozena Rokita,
Piotr Ulanski, Akihiro Hiroki,
Mitsumasa Taguchi, Janusz M. Rosiak,
Masao Tamada
362. Poly(ethylene terephthalate) nanosheet
prepared by CO2 laser supersonic multidrawing. Akihiro Suzuki*, Kyouhei Arino
363. Application of photochemical generation of superbases to photoreactive materials. Koji Arimitsu*, Ryosuke Endo
364. Characterization of lacquers using
EGA-Probe IAMS; Pyrogram.
Toshiya Sato, Masamichi Tsukagoshi,
Toshihiro Fujii*
365. Syntheses of styrenic copolymers having bulky substituent group via polymer
reaction and property of cycloolefin copolymers modified with them.
Yuiko Yoshikawa*, Kazufumi Kohno,
Hiromu Saito, Akinori Toyota
366. Post-irradiation effects on the chemical
structure of the ion-beam irradiated isotactic-polypropylene. Toshitaka Oka,
Akihiro Oshima, Hisaaki Kudo,
Takeshi Murakami, Masakazu Washio,
Yoshimasa Hama
367. Thermal decomposition of poly(L-lactic
acid) on TiO2. Jong-Liang Lin*
368. Colorless and high-Tg polyimides with a
bis-spironorbornane and alkanone structure. Ryosuke Kimura, Sho Doi,
Toshihiko Matsumoto*
369. Theoretical study of radiation reactivity
on photoacid generators for EUV lithography. Masayuki Endo*,
Kazuyuki Enomoto, Hiroki Yamamoto,
Seiichi Tagawa
370. Double-edged sword: Coumarins in the
photodegradation and fungal deterioration of the Phormium fibres. Ying Tang*,
Gerald J. Smith*, Jolon M. Dyer,
Sue Scheele
371. Ozonolysis and functionalization of natural rubber. Susumu Harashima,
Toshihiko Matsumoto*, Akihiro Fujiwara
372. Study on membrane electrode assemblies with functionally modified IEC.
Taeko Yoshikawa*, Fumiya Shiraki,
Hajime Fujita, Akihiro Oshima,
Masakazu Washio
373. Interaction of mesenchymal stem cells
with conjugated polymers.
Jungmok You, June Seok Heo,
Teahoon Park, Youjeong Choi,
Han-Soo Kim, Hyun Ok Kim*,
Eunkyoung Kim*
374. Preparation of graft phosphoric adsorbent onto nonwoven cotton fabric in pilot
scale. Noriaki Seko*, Noboru Kasai,
Takuya Shibata, Hiroyuki Hoshina,
Makikatsu Takahashi
375. Study on reduction of metal ions in
functionalized fluorinated-polymers by
means of plasma exposure.
Hidehiro Tsubokura*,
Tomohiro Takahashi, Hajime Fujita,
Tomoko Gowa, Hiroki Yamamoto,
Akihiro Oshima, Seiichi Tagawa,
Masakazu Washio
376. Synthesis of photobase generators with
9-xanthenylmethyl groups and their application to photoreactive materials.
Ryuta Mizuochi, Koji Arimitsu*
377. Synthesis of novel photobase generators to generate strong bases and their
application to photoreactive materials.
Masayoshi Yanagi, Koji Arimitsu*
378. Photobase generators based on photocyclization reactions and their application
to photoreactive materials. Ayaka Oguri,
Koji Arimitsu*
379. Photobase-catalyzed pigmentation of
latent pigments for monitoring the migration of bases in polymer films.
Midori Arai, Koji Arimitsu*
380. Preparation of novel water-soluble acid
amplifiers and their application to watersoluble chemically amplified photoresists.
Daiki Ishii, Koji Arimitsu*
381. Synthesis of novel photoreactive acid
amplifiers and their application to chemically amplified photoresists.
Kyoko Nishidono, Koji Arimitsu*
382. Development of novel water-soluble
photopolymers sensitized with water-soluble photobase generators.
Hiroaki Koiwa, Koji Arimitsu*
383. Studies on the deterioration mechanism
of raw lacquer film based on ultraviolet irradiation. Yoshimi Kamiya*, Rong Lu,
Chuichi Watanabe, Tetsuo Miyakoshi
384. Improvement of thermal and mechanical properties of Poly (L-lactic acid) by
blending and radiation-induced crosslinking. Takanori Tago*,
Naotsugu Nagasawa,
Mitsumasa Taguchi, Masao Tamada,
Hisaaki Kudo, Yosuke Katsumura
385. Study on depth profile of acid generator
distribution in poly(4-hydroxystyrene)
films using X-ray photoemission spectroscopy(XPS). Hiroki Yamamoto,
Takahiro Kozawa, Seiichi Tagawa
386. Synthesis of thermal acid generators
(TAGs) and their application to thermal
curing materials. Itaru Kondo,
Koji Arimitsu*, Hikaru Imamura
387. Acid proliferation reaction for sensitivity
enhancement of EUV resists.
Kazuyuki Enomoto*, Hiroki Yamamoto,
Akihiro Oshima, Takahiro Kozawa,
Seiichi Tagawa
388. Synthesis of oxidatively degradable
polymers by oxidative coupling polymerization and their application.
Kentaro Nagashima, Nobuhiro Kihara*
389. Synthesis and oxidative degradation of
poly(acylsemicarbazide).
Midori Katayama, Nobuhiro Kihara*
390. Evaluation of biodegradable adsorbent
for arsenic(V) synthesized by radiation-induced graft polymerization.
Hiroyuki Hoshina*,
Makikatsu Takahashi, Noboru Kasai,
Noriaki Seko
391. Photobase-generating reactions of carboxylates derived from arylacetic acid
and a base and their application to photoreactive materials. Masaru Imazeki,
Koji Arimitsu*
Convention Center
Kamehameha Halls II and III
The New Age of Advanced Materials:
Supramolecular Architectures and Smart
Materials (#98)
Organized by: E. Yashima, T. Aida,
F. Caruso, M. Lee, K. Wooley
Presiding: E. Yashima, M. Lee, T. Aida,
K. Wooley, F. Caruso
Poster Session
10:00 – 12:00
392. Molecular “screw and nut”: Stereo-specific formation of poly(L-lactide)-based
polyrotaxane and its protease triggered
degradation behavior. Yuichi Ohya*,
Seigo Takamido, Koji Nagahama,
Tatsuro Ouchi, Ryo Katoono,
Nobuhiko Yui
393. Helical folding of poly(naphthalenecarboxamide) bearing hydrophobic side
chain. Koichiro Mikami,
Akihiro Yokoyama*, Tsutomu Yokozawa*
394. Synthesis of an amphiphilic block copolymer bearing an optically active
␲-conjugated polymer chain and the chiroptical properties of its micelle.
Katsuhiro Maeda*, Satoru Nozaki,
Tomoyuki Ikai, Shigeyoshi Kanoh
395. Control and modulation of chirality for
azobenzene-substituted polydiacetylene
LB films with circularly polarized light.
Gang Zou*, Hao Jiang, Qi J. Zhang,
Mitsumasa Iwamoto
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR
396. Synthesis and chiroptical properties of
helical oligopeptides from an achiral
amino acid, 4-aminopiperidine-4-carboxylic acid. Joon-il Cho, Kazushi Kinbara,
Takuzo Aida*
397. Synthesis and chirality sensing properities of polyacetylenes bearing biphenyl
pendants with dynamic axial chirality.
Kouhei Shimomura, Katsuhiro Maeda,
Tomoyuki Ikai, Shigeyoshi Kanoh*,
Eiji Yashima
398. Synthesis and self-assembling behaviors of rigid-rod helical diblock polyisocyanides. Motonori Banno,
Zong-Quan Wu, Kanji Nagai,
Shin-ichiro Sakurai, Kento Okoshi,
Eiji Yashima
399. Resolution of enantiomers by HPLC using diastereomeric right- and left-handed
helical poly(phenyl isocyanide)s bearing
L-alanine pendants immobilized on silica
gel. Kazumi Tamura, Toshitaka Miyabe,
Hiroki Iida, Eiji Yashima*
400. Synthesis and secondary structure of
optically active poly(phenylactylene)
bearing phosphorylcholine moiety.
Minako Murata*, Kayo Terada,
Tsuyoshi Ando, Shiho Hirohara,
Masao Tanihara
401. Synthesis of main-chain-type polyrotaxanes by new click polymerization using homoditopic nitrile N-oxides via rotaxanation-polymerization protocol.
Yasuhito Koyama, Young-Gi Lee,
Morio Yonekawa, Toshikazu Takata*
402. Application of host-guest self-assembly
to polymer science. Harry W. Gibson*,
Minjae Lee, Zhenbin Niu,
Mason A. Rouser, Matthew A. Flack,
Daniel V. Schoonover
403. Biasing molecular chirality arising from
thermodynamically controlled double stereodifferenciation. Shuichi Hiraoka*,
Shiho Miyake, Atsuya Muranaka,
Masanobu Uchiyama, Motoo Shiro,
Mitsuhiko Shionoya
404. Formation of self-assembled nanorings
from ␲-conjugated oligomers.
Shiki Yagai, Yusaku Goto,
Yoshihiro Kikkawa, Takashi Karatsu,
Akihide Kitamura
405. Perylene bisimides possessing cyanuric
acid modules: Control of supramolecular
architectures and self-sorting. Mari Usui,
Shiki Yagai*, Tomohiro Seki,
Yoshihiro Kikkawa, Takashi Karatsu,
Akihide Kitamura
406. Novel liquid-crystalline materials composed of a cylindrical helix.
Takashi Kajitani, Yuki Suna,
Atsuko Kosaka, Shigenori Fujikawa,
Takanori Fukushima, Takuzo Aida
407. Liquid crystalline oligopeptides with dynamic helical properties. Ryoichi Matsui,
Yoshimitsu Itoh, Yasuhiro Ishida,
Takuzo Aida*
408. Universal design strategy for uniformly
alignable discotic columnar liquid crystals. Daigo Miyajima, Fumito Araoka,
Hideo Takezoe*, Takuzo Aida*
409. Enhanced affinity of [2]-rotaxane-based
crosslinked polymers to Angiotensin III.
Kohei Oomori, Tooru Ooya,
Toshifumi Takeuchi*
410. Development of asymmetric organocatalysts based on cellulose derivatives
bearing N-oxide groups. Tomoyuki Ikai*,
Munetsugu Moro, Katsuhiro Maeda,
Shigeyoshi Kanoh
411. Side-chain shuffling and higher-order
structure modification of imine-functionalized poly(L-lysine). Toshiyuki Oyama*,
Yui Ozaki, Akio Takahashi
412. Successive catalytic reactions specific
to Pd-based rotaxane complex as a result
of wheel translation along the axle.
Ayumi Kawasaki, Norihito Miyagawa,
Yasuhito Koyama, Toshikazu Takata*
413. Gear-shaped amphiphile: A strategy for
truly discrete aggregates by precise regulation of intermolecular engagement.
Takashi Nakamura, Shuichi Hiraoka*,
Motoo Shiro, Mitsuhiko Shionoya
414. Induction of one-handed helical oligo(pbenzamide)s by domino effect based on
planar-axial-helical chirality relay.
Jun Yamaguchi*, Ken Kamikawa
415. Syntheses of highly conductive insulated molecular wires having a poly(phenylene ethynylene) units.
Akihisa Wadahama, Jun Terao*,
Tetsuaki Fujihara, Yasushi Tsuji
416. Synthesis of optically-active catenanes
utilizing amidinium-carboxylate salt
bridge formation and control of their catenane structure. Yuji Nakatani*,
Yoshio Furusho, Eiji Yashima
417. Chirality organization of oligoanilines
through hydrogen bonds of amino acid
moieties. Satoshi D. Ohmura,
Toshiyuki Moriuchi*, Kenji Morita,
Toshikazu Hirao*
418. Synthesis and secondary structure of
optically active PEGylated poly(phenylacetylene)s. Kayo Terada*, Tsuyoshi Ando,
Shiho Hirohara, Masao Tanihara
419. Synthesis of a star polymer consisting
of helical polyisocyanides and its chiral
recognition ability. Toshitaka Miyabe*,
Hiroki Iida, Eiji Yashima
420. Polysaccharide-based thermal sensitive
microgels with stable and reversible photoluminescence. Hongjing Dou*,
Weihai Yang, Kang Sun, Wanwan Li,
Ke Tao
421. Membrane-bound light harvesting bioconjugates as chloroplast mimics.
David Hvasanov*, Joshua R. Peterson,
Jörg Wiedenmann, Pall Thordarson
422. Crown ether/sec-ammonium salt-based
main chain-type polyrotaxane: First directed synthesis and its applications.
Kazuko Nakazono*, Tomonori Ishino,
Tomoyuki Takashima, Toshikazu Takata*
423. Preparation of amylose-polylactide inclusion complexes by vine-twining polymerization. Koji Ueno, Yoshiro Kaneko,
Jun-ichi Kadokawa*
424. Synthesis of topologicalgel composed
␥-cyclodextrin and hydroxyl-terminated
polybutadiene. Numata Mutsuaki*,
Kouzai Hiroaki
425. Fused porphyrin dimer as a new class
of optoelectronically active core for semiconducting liquid crystals.
Tsuneaki Sakurai*, Shu Seki,
Atsuhiro Osuka, Takuzo Aida*
426. Macroscopic mechanical control over
molecular conformation affects the efficiency of fluorescence resonance energy
transfer. Soichiro Ogi,
Kazunori Sugiyasu, Masayuki Takeuchi*
427. Hydrogen-bond-directed nanostructurization of ␲-conjugated oligomers.
Shiki Yagai*
428. Development of a method to interconnect molecular wires between nanoelectrodes by sequential coupling reaction.
Kyohei Homma, Jun Terao*,
Tetsuaki Fujihara, Yasushi Tsuji
429. Folded polymers with H- and J-like
stacking of conjugate units.
Tohru Hoshino, Jun-ichi Watanabe,
Masaru Kudo, Sentaro Okamoto*
430. C2-chiral tetraarylferrocenes: Synthesis
and chiroptical features of multijoint oligomers composed of ␲-conjugated rigid
rods and chiral ferrocene joints.
Takahiro Fukino, Norifumi Fujita,
Takuzo Aida*
431. Controlling formation of supramolecular
hydrogel by redox. Masaki Nakahata,
Yoshinori Takashima,
Hiroyasu Yamaguchi, Akira Harada
432. Dendritic supramolecular polymers for
fluorescence patterning. Joo-Ho Kim,
Woo-Dong Jang*
433. Synthesis and characterization of poly(p-phenylenevinylene) graft copolymer
for light emitting diode. Kaori Funatsu*,
Kousuke Tsuchiya, Kenji Ogino
434. Network polymer formed by photodimerization of cinnamate as a photoinduced mendable material.
Nobuhiro Oya, Sukarsastmadja Petty,
Naoko Yoshie*
435. Reconstruction of polyelectrolyte multilayers (PEMs) onto porous templates and
their size-depending selectivity for molecules. Won San Choi*, Md. A. Rahim,
Ha-Jin Lee
436. Controlled fabrication and optical properties of highly fluorescent 1D and
semi-2D nanostructures of a dipolar organic molecular system.
Ravi Kumar Kanaparthi,
Anunay Samanta*
437. Photoswitchable hydrogel formed by
cyclodextrin and azobenzene polymers.
Shingo Tamesue, Yoshinori Takashima,
Hiroyasu Yamaguchi, Seiji Shinkai,
Akira Harada*
438. Cyclodextrin peptide hybrids as drug
responsive flexible nano-materials.
Hikaru Amano, Ayumi Kobayashi,
Natsuki Yoshida, Keita Hamasaki*
439. Nature inspired chemistry: From lipid
rafts toward adaptive hydrogel-based
biomaterials. Maartje Bastings*,
Roxanne Kieltyka, Erwin Kemps,
Patricia Dankers, Bert Meijer
440. Protein adsorption property of polyglycerol dendrimer-immobilized surface.
Yoshiki Mitachi, Tooru Ooya,
Toshifumi Takeuchi*
441. Stimuli-responsive bionanotubes by supramolecular polymerization of chemically modified chaperonin-based biomolecular machineries. Shuvendu Biswas*,
Kazushi Kinbara, Noriyuki Ishii,
Hideki Taguchi, Takuzo Aida
442. Supramolecular nanotube hydrogels
having a 1-D confined nanospace and
2-D meshworks for proteins.
Naohiro Kameta*, Mitsutoshi Masuda,
Toshimi Shimizu
443. Synthesis of bioinspired cyclic oligopeptides and their controlled assembly. Kohei Sato, Yoshimitsu Itoh*,
Takuzo Aida*
444. Multifunctional nanoparticles for drug
delivery. Xiuru Li, Jun Guo, Xinghai Ning,
Jinkeng Asong, Margreet A. Wolfert,
Geert-Jan Boons*
445. Water-soluble anthracenophanes as
fluorescent receptors for nucleotides prepared by self-assembly-based cyclization. Yuichi Yoshida, Shigeaki Yamori,
Tooru Ooya, Toshifumi Takeuchi*
446. Amphiphile self-assembly materials in
nanomedicine. Nelly Gong,
Minoo Moghaddam, Sharon Sagnella,
Charlotte Conn, Xavier Mulet,
Lynne Waddington,
Calum J. Drummond*
447. Reversible chemistry in the synthesis of
linear polymers and smart, “self-healing”
anti-biofouling coatings.
Christopher Fidge, Solène I. Cauët,
Philip M. Imbesi, Karen L. Wooley*
448. Novel polyion complex vesicles consisting of siRNA toward nano-therapeutic
system. Sayan Chuanoi,
Akihiro Kishimura*, Kanjiro Miyata*,
Tomoya Suma, Yasutaka Anraku,
Makoto Oba, Kazunori Kataoka*
449. Gene suppression by complex consisting of ␤-1,3-glucan and antisense oligonucleotides stabilized with phosphorothioate backbone. Shinichi Mochizuki*,
Kazuo Sakurai
450. Enzymatic activity in polygrycerol dendrimer-contained solution.
Takaya Ogawa, Tooru Ooya,
Toshifumi Takeuchi*
451. Withdrawn
452. Synthesis of novel low-bandgap polymers consisting of thieno[3,4-b]thiophene
as a building block.
Tomoyuki Yamamoto, Tomoyuki Ikai,
Katsuhiro Maeda, Shigeyoshi Kanoh*
453. Crystal engineering: Copper-free 1,3-dipolar cycloaddition of azide and alkyne
facilitated by arene-perfluoroarene interaction. Yuguo Ma*, Ben-Bo Ni,
Feng Zhai
454. Fullerene-carbon nanotubes assemblies as temperature indicator for photothermal conversion. Yanfei Shen,
Andre G. Skirtach, Helmuth Möhwald,
Takashi Nakanishi*
455. Conjugated protein-like molecularly imprinted tunable binding sites coupled
with cofactors. Toshifumi Takeuchi*,
Kohei Takeda, Atsushi Kuwahara,
Takuya Mori, Tooru Ooya
456. 2-D supramolecular living polymerization of small polyion complexes.
Akihiro Kishimura*, Yasutaka Anraku,
Yuichi Yamasaki, Kazunori Kataoka
457. Design of excimer-based luminescent
materials using a barb-shaped polymer
as a scaffold. Keisuke Kurauchi,
Yasunao Miyamura, Takuzo Aida*
458. Self-assembly of amphiphilic chlorophylls on a soft-template.
Munenori Numata
459. Mesoporous thin films meet macromolecular brush polymers: Tuning the surface and volume chemistry of nanocavity
arrays with tailored perm-selective or optical properties. Alejandra Calvo,
Basit Yameen, M. Cecilia Fuertes,
Federico Williams, Omar Azzaroni,
Galo J. Soler-Illia*
460. Ketenes in polymer chemistry.
Martin Wolffs, Frank A. Leibfarth,
Matthew J. Kade, Moon Bongjin,
Craig J. Hawker*
461. Synthesis and inclusion behavior of cyclic hexakis(m-phenyleneiminomethylene). Saori Sugaya,
Toshihiko Matsumoto*, Yasuaki Kikuchi
462. Synthesis of ladder cyclic oligomer
based on dynamic covalent chemistry by
the reaction of resorcinol and 1,9-nonanedial. Hideatsu Ishihara,
Hiroto Kudou, Tadatomi Nishikubo
463. Novel theory for heterogeneous polymer solutions and polymer composites.
Jiang Ji*, Guangde Tu
464. Ring-expansion polymerization of cyclic
tetrathioesters with thiiranes.
Yuki Takeshi, Hiroto Kudo,
Tadatomi Nishikubo*
465. Precision synthesis of engineered macromolecules with ionic liquid side chains
for hybridization with carbon nanotubes.
Xiaoyu Long, Norifumi Fujita,
Takanori Fukushima, Takuzo Aida*
466. Carbon-rich nanostructures from molecular precursors. Tobias Hoheisel,
Stephen Schrettl, Ruth Szilluweit,
Holger Frauenrath*
467. Water-compatible supramolecular single chain nanoparticle via living radical
polymerization toward aqueous compartmentalized catalysis. Takaya Terashima,
Anja R. Palmans, E. W. Meijer
468. Hydrophobic region of polyglycerol
dendrimers. Haejoo Lee, Tooru Ooya,
Toshifumi Takeuchi*
469. A2 ⫹ B4 condensation reaction of resorcinol (A2 monomer) and o-, m-, and pbenzenedicarboaldehyde (B4 monomer).
Hiroyuki Seki, Hiroto Kudo,
Tadatomi Nishikubo*
470. Tunable polyelectrolytes multilayer templates for high loading of metal nanoparticles. Ha-Jin Lee*, Md. A. Rahim,
Won San Choi, Il Cheol Jeon
471. Selective macrocycle synthesis based
on ␲-stacked precipitation-driven cyclization and reversible interchange of linear oligomers. Toshihiko Matsumoto*,
Kozo Ishida, Seitaro Oishi
472. Nanostructured polymer colloids.
Connal Luke, Craig J. Hawker
473. Encouraged self-repairing of 1D molecular assembly in mesoporous silica by a
“nanoscopic template effect”.
Hendrik O. Lintang*, Takuzo Aida*,
Kazushi Kinbara, Takashi Yamashita
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–101
03-MACR
474. Synthesis of WO3 and MoO3 hollow
nanospheres templated by polymeric micelle with core-shell-corona structure.
Kenichi Nakashima*, Jingjing Liu,
Dian Liu, Sasidharan Manickam,
Yuuichi Yokoyama, Shin-ichi Yusa
475. Exploring dendrimer design for pulp
and paper applications.
Annie Castonguay*, E. Ladd,
M. Polverari, A. Lepo, T. van de Ven,
A. Kakkar
Friday Afternoon
Convention Center
323B
Advanced Polymeric Membranes for
Environmental, Biomedical and
Bioengineering Application (#51)
Organized by: A. Higuchi, B. Freeman,
A. Hill, Y.M. Lee
Presiding: B. Freeman, M. Guiver
12:30 – 476. Structure-property relations in
polymers for gas separations.
Benny Freeman*
13:10 – 477. Membranes pore characterization techniques: A status quo and future
development. Kuo-Lun A. Tung*,
Kueir-Rarn Lee, Juin-Yih Lai,
Wei-Song Hung, Tian-Tsair Wu,
Yan-Ching Jean, Yi-Ming Sun,
Yen-Fang Song, Gung-Chian Yin,
Yi-Ming Chen
13:50 – 478. Tailoring ladder-type polymers
with intrinsic microporosity (PIMs) for
highly permeable gas separation membranes. Michael D. Guiver*, Naiying Du,
Gilles P. Robertson, Ho Bum Park,
Ingo Pinnau
14:30 – 479. Temperature-difference controlling evapomeation characteristics in
concentration of bio-ethanol by poly[1(trimethylsilyle)-1-propyne] membranes.
Tadashi Uragami*
15:10 – 480. Porous substructure support
for the preparation of thin film composite
(TFC) membrane in high temperature gas
separations. Suresh Mulmi,
Sang Hoon Han, Seung Ju Kim,
Young Moo Lee*
15:30 – 481. Metal organic framework-based
gas separation membranes.
Matthew R. Hill*, Aaron W. Thornton,
Anita J. Hill, Bradley P. Ladewig,
Constantinos Dimitrakakis
15:50 – 482. Investigation into the porosity of
polymeric membranes using positron annihilation lifetime spectroscopy.
Cara Doherty, Anita J. Hill
16:10 – 483. Patterning membranes.
Paolo Falcaro, Dario Buso, Anita J. Hill
Convention Center
322AB
Functional Block Copolymer Assemblies
(#57)
Organized by: T. Lodge, J. Bang, C. Han,
M. Hillmyer, Y. Matsushita
Presiding: M. Hillmyer
12:30 – 484. On the self-assembly of diblock
copolymer within self-consistent field
theory. Dadong Yan*, Bing Miao,
Tongchuan Suo
13:00 – 485. Self-consistent field theory
study on the self-assembly of block copolymers. Zhao-Yan Sun*, Li-Jia An
13:20 – 486. Role of a differentiating nonsolvent in formation mechanism of highly
ordered microdomains in a semi-dilute
solution of a ultra-high-molecular-weight
block copolymer. Koji Ando,
Shigeru Okamoto*, Naoki Sakamoto,
Tadashi Inoue, Daisuke Yamaguchi,
Satoshi Koizumi, Hirokazu Hasegawa,
Naokiyo Koshikawa
13:40 – 487. Using immiscible solvent vapors to control the architecture in thin film
of block copolymers. Bokyung Kim,
Sung W. Hong, Thomas J. McCarthy,
Thomas P. Russell, Soojin Park,
Sung-Kwon Hong
102–TECH
TECHNICAL PROGRAM
14:10 – 488. Templated block copolymers
for sub-10 nm self-assembled nanolithography. Caroline A. Ross*
14:40 – 489. Directed assembly of block copolymer films on lithographically defined
nanopatterned surfaces. Paul Nealey*,
Juan de Pablo
15:10 – 490. Block copolymer lithography integrated with conventional photolithography toward functional carbon nanomaterial production. Sang Ouk Kim*
15:30 – 491. New morphologies created by
ABC triblock terpolymers with molecular
weight and composition distribution.
Yushu Matsushita, Atsushi Takano
15:50 – 492. In situ small-angle scattering
study of block copolymers in supercritical
carbon dioxide. Masateru Ito,
Kohichi Mayumi, Hideaki Yokoyama*,
Kohzo Ito, Mituhiro Shibayama,
Kenji Sugiyama
16:10 – 493. Changes in domain spacing
and morphology of block copolymers
upon chemical modification. Sarah Siti,
Daisuke Kawaguchi, Yushu Matsushita*
Convention Center
328
Biodegradable and Biomass Plastics (#95)
Organized by: H. Uyama, G.G. Chen,
S.S. Im, T. Iwata, C. Nomura
Presiding: T. Iwata, H. Uyama
12:30 – 494. Toughening of carbon dioxidepropylene oxide copolymer by hydrogen
bonding interaction. Xianhong Wang*,
Lijie Chen, Yuesheng Li, Fosong Wang
13:00 – 495. Enzyme-catalyzed synthesis of
monomers and polymers for bioplastics.
Yong Hwan Kim*
13:30 – 496. Enzymatic synthesis and chemical recycling of polythioesters as environmentally benign process.
Shuichi Matsumura
13:50 – 497. Synthesis and properties of biodegradable cationomers based on aliphatic poly(ester-urethane)s.
Yuushou Nakayama*, Takamichi Inaba,
Naoki Matsubara, Yosuke Toda,
Zhengguo Cai, Takeshi Shiono
14:10 – 498. Synthesis and function of periodic copolymers consisting 3-hydroxybutyrate and aspartate units. Hideki Abe*
14:30 – 499. New biosynthesized cellulosechitin copolymers. David L. Kaplan
15:00 – 500. Enhancing functionality and
performance of cellulosic materials in
combination with other polymeric/inorganic components. Yoshiyuki Nishio*
15:30 – 501. Preparation and characterization of xylan ester derivatives.
Noreen Grace V. Fundador*,
Akio Takemura, Tadahisa Iwata
15:50 – 502. Thermo-plasticized cellulose
derivative and its utilization for a fiber.
Hidekazu Kano*, Hiroyuki Yamada,
Yoshitaka Aranishi, Tai Sasamoto
16:10 – 503. Preparation of chitin nanowhiskers using an ionic liquid and their composite materials. Jun-ichi Kadokawa*,
Akihiko Takegawa
Convention Center
321B
Synthesis, Structure, and Physical
Properties of Advanced Polymer Gels (#136)
Organized by: K. Ito, M. Sibayama,
R. Siegel, C. Wu
Presiding: R. Siegel, C. Wu
12:30 – 504. Molecular interactions in double
network hydrogels. Wenli Wu,
Sanghun Lee, Vijay J. Tirumala,
Michi Nagao, Taiki Tominaga,
Jian Ping Gong
13:00 – 505. Internal motions of linear chains
and spherical microgels in theta and poor
solvents. Chi Wu, Zhuojun Dai
13:30 – 506. Structural hierarchy and
nanoscale interactions of cartilage proteoglycans. Ferenc Horkay*
14:00 – 507. Novel hydrogels from self-assembly of homotelechelic and heterotelechelic triblock copolymers.
Timothy Lodge*, Rajiv Taribagil,
Marc Hillmyer
14:30 – 508. Structure of nanocomposite hydrogel investigated by means of contrast
variation small-angle neutron scattering.
Hitoshi Endo*, Toshihiko Nishida,
Mitsuhiro Shibayama, Huan-jun Li,
Kazutoshi Haraguchi
14:45 – 509. Synthesis and characterization
of star polymers and nanogels by RAFT
polymerization. Angel Licea-Claverie*,
Lorenzo A. Picos-Corrales,
Jesus Alvarez-Sanchez,
Jose M. Cornejo-Bravo
15:15 – 510. Reversible hydrogels through
ternary complexation with cucurbit[8]uril.
Oren Scherman*
15:30 – 511. Nanocomposite gels prepared
by in-situ photopolymerization in an
aqueous system. Kazutoshi Haraguchi*
16:00 – 512. Molecular design of lipophilic
polyelectrolytes and their gels.
Kazuki Sada*
Convention Center
325B
Amphiphilic Polymers: Fundamentals and
Applications (#231)
Organized by: T. Sato, K. Akiyoshi,
C. McCormick, F. Winnik
Presiding: T. Sato, F. Winnik, K. Akiyoshi
12:30 – 513. Responsive micelles, vesicles
and organogels from poly(lysine)-containing block copolymers. Daniel Savin*,
Sandeep Naik, Jacob Ray,
Ashley Montgomery
13:00 – 514. New series of stimuli-responsive polymers with various shapes and
different sequence distributions.
Sadahito Aoshima*, Shokyoku Kanaoka
13:20 – 515. Effects of sequence distribution, concentration, and pH on gradient
copolymer and block copolymer micelle
formation in aqueous and nonaqueous
media. Stephen Marrou*, Jungki Kim,
Christopher Wong, John Torkelson
13:40 – 516. Design of amphiphilic polymers
as antimicrobial agents. Kenichi Kuroda*
14:10 – 517. Delivery of a red two-photon
absorbing emitter into mouse macrophage RAW cells using poly(ethylene glycol)-b-poly(epsilon-caprolactone) block
copolymers. Yanqing Tian*,
Wen-Chung Wu, Ching-Yi Chen,
Sei-Hum Jang, Meng Zhang,
Tim Strovas, Yongzhong Li, Yuguang Jin,
Fengyu Su, Brad Cookson, Alex K. Jen,
Deirdre R. Meldrum
14:30 – 518. Biodegradable nanogels prepared from amphiphilic oligolactidegrafted polysaccharides for protein drug
delivery. Yuichi Ohya*, Koji Nagahama,
Tatsutoshi Murakami, Tatsuro Ouchi
14:50 – 519. Smart polymer-protein conjugates and sugar-responsive micelles.
Brent S. Sumerlin*, Debashish Roy,
Jennifer N. Cambre, Abhijeet P. Bapat,
Ming Li, Hongmei Li
15:20 – 520. Small angle X-ray scattering
from polymeric micelles encapsulating
hydrophobic drugs. Kazuo Sakurai*,
Isamu Akiba, Shiraishi Ken-ichi,
Yokoyama Masayoshi
15:40 – 521. Polyion complex micelles with
two oppositely charged diblock copolymers containing poly(ethylene glycol).
Shin-ichi Yusa*, Yuuichi Yokoyama,
Yotaro Morishima
16:10 – 522. Amphiphilic liquid crystalline
block copolymer film: Orientation control
and structural transcription.
Zhao Yongbin, Iyoda Tomokazu*
Convention Center
323A
Controlled/Living Radical Polymerization:
Mechanisms, Catalysts, Reaction
Engineering, Materials and Applications
(#236)
Organized by: S. Zhu, T. Fukuda, B.G Li,
K. Matyjaszewski, M. Monteiro
Presiding: K. Matyjaszewski
12:30 – 523. Synthesis of long-chain
branched (arborescent) polystyrenes of
controlled architecture via inimer-type
RAFT polymerization and characterization using high-resolution SEC.
Judit E. Puskas*, Andrew J. Heidenreich
12:50 – 524. Kinetic modeling of RAFT polymerization: To comprehend mechanism
and manipulate chain structures of polymer. Bo-Geng Li*, Yingwu Luo*,
Rui Wang, Xiaoying Sun, Shiping Zhu*
13:10 – 525. Towards controlled metal catalyzed radical polymerizations of dienes.
Alexandru D. Asandei*,
Christopher P. Simpson, Hyun S. Yu,
Olumide Adebolu
13:30 – 526. Synthesis functionalized polyethylene block copolymers by combining
ethylene “living” coordination polymerization with “living” radical polymerization.
Kejian Zhang, Zhibin Ye*,
Ramesh Subramanian
13:50 – 527. Precise design and polymer reactions for star-like nanogels via dynamic
covalent exchanges toward their molecular imaging. Yoshifumi Amamoto,
Hideyuki Otsuka*, Atsushi Takahara*
14:10 – 528. Synthesis and characterization
of star-shaped sodium (polystyrenesulfonate) by atom transfer radical polymerization of ethyl styrene sulfonate.
Kunlun Hong, Yugang Li, Xiang Yu,
Jimmy W. Mays
14:30 – 529. Recent advances in the MADIX
process. Mathias Destarac*
14:50 – 530. Determination of transfer-coefficients in the pre- and main-equilibrium
of the RAFT-polymerization.
Marco Drache, Lars Nothdurft,
Olaf I. Strube, Gudrun Schmidt-Naake
15:10 – 531. Influence of the nitroxide stability on the livingness of polystyrene prepared by NMP. Denis J. Bertin*,
Didier Gigmes, Yohann Guillaneuf,
Jessica Marchand, Jean Luc Couturier
15:30 – 532. RAFT polymerization from
nanoparticle surfaces: Designed interfaces in polymer nanocomposites.
Brian C. Benicewicz*, Yu Li, Atri Rungta,
Sanat Kumar, Douglas Dukes,
Linda Schadler
15:50 – 533. Preparation of cationic polyelectrolyte brushes with narrow molecular
weight distributions by the surface-initiated polymerization.
Motoyasu Kobayashi, Masami Terada,
Moriya Kikuchi, Atsushi Takahara*
16:10 – 534. Smart surfaces prepared by
ATRP grafting and termination mechanism of radicals on flat surface.
Shiping Zhu
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR
Convention Center
327
Polymer Nano-Hybrids at Bio-Interfaces
(#127)
Organized by: Y. Chujo, C.S. Ha,
K. Uhrich, K. Wynne
Presiding: K. Wynne
13:00 – 535. Mesoporous biopolymer/silica
nanohybrids for controlled drug release.
Chang-Sik Ha*, V. K. Rana
13:25 – 536. Self assembled biomaterial surfaces for control of mesenchymal stem
cell behaviour. Justin J. Cooper-White*
13:50 – 537. Supramolecular polymeric
nanostructures for delivery of drugs and
genes. Yi-Yan Yang*, Chuan Yang,
Jeremy P. Tan, Ying Zhang,
Zhan Yuin Ong, Kazuki Fukushima,
James L. Hedrick*
14:15 – 538. Fabrication and properties of
nanosheets for biomedical applications.
Shinji Takeoka*, Toshinori Fujie,
Akihiro Saito, Manabu Kinoshita,
Daizoh Saitoh
14:40 – 539. Opportunities for electrospun
polymeric materials in regenerative medicine and drug delivery. Gary Wnek
15:05 – 540. Polymeric immunonanoparticles for targeted delivery.
Molly S. Shoichet*, Jiao Lu, Karyn Ho,
Shawn Owen, Ahmed Aman,
Rima Al-Awar, Raffi Tonikian,
Sachdev Sidhu
15:30 – 541. Imidazolium cation-modified
metal nanoparticles as potential biological application. Kensuke Naka*,
Asako Narita, Yoshiki Chujo
15:55 – 542. Biostabilization of white-light
emitting nanocrystals with nanoscale amphiphilic macromolecules for biomedical
applications. Sarah Sparks,
Michael Schreuder, Sandra Rosenthal,
Kathryn Uhrich*
Friday Evening
Convention Center
Kamehameha Halls II and III
Advanced Polymeric Membranes for
Environmental, Biomedical and
Bioengineering Application (#51)
Organized by: A. Higuchi, B. Freeman,
A. Hill, Y.M. Lee
Presiding: A. Higuchii, H. Matsuyama
Poster Session
19:00 – 21:00
543. Terminally-crosslinked sulfonated poly(fluorenyl ether sulfone) as a highly conductive and stable proton exchange
membrane. Roshni Lilly Thankamony,
Hyoung-Juhn Kim, Tae-Hyun Kim*
544. Development of biocompatible dialysis
membrane by physical adsorption human
Thrombomodulin. Masaaki Omichi,
Michiya Matsusaki, Ikuro Maruyama,
Mitsuru Akashi*
545. Direct ex vivo expansion of hematopoietic stem cells from umbilical cord blood
on membranes. Akon Higuchi*
546. Preparation and properties of waterborne polyurethane-silane for protective
marine coatings.
Mohammad Mizanur Rahman,
Ho-Hwan Chun, Hyun Park
547. Enhancement of fibroblast adhesion
and the proliferation on planar crystal oriented poly(␧-caproractone) film.
Hidehumi Takei, Takefumi Narita,
Satoshi Osawa*
548. Gas transport and anisotropic diffusion
properties of the crystalline structures of
semi-crystalline polymers.
Yuki Okumura*, Miki Tsurunaga,
Hiroaki Yoshimizu
549. Metal ions accelerate humic acid fouling during ultrafiltration of polyethersulfone hollow fiber membrane. Hao Yan*,
Akihito Moriya, Tatsuo Maruyama,
Yoshikage Ohmukai, Hideto Matsuyama
550. Gas transport properties and higher-ordered structure of the cellulose membrane prepared by oxidation using with
TEMPO catalyst. Jun Kojima*,
Hiroaki Yoshimizu
551. Gas separation and vapor permeation
through polydimethylsiloxane membranes: Effect of cross-linker density and
inorganic filler loading in membranes.
Jessie S. Lue*, Chen Luen Tsai,
Da-Tung Lee, Chun-Hong Chu
552. Structure-property relationship of hyperbranched polyimides for CO2/CH4
separation. Masako Miki*,
Yasuharu Yamada
553. Preparations and properties of novel
biocompatible polyurethanes containing
a phospholipid component.
Yuhki Sakagami, Yu Nagase
554. Ion beam treatment of the surface of
Nafion membranes for direct methanol
fuel cells. Jae-Hak Choi*, Jung-Soo Lee,
Chan-Hee Jung, In-Tae Hwang,
Young-Chang Nho
555. Characterizations of glassy-polymer
films treated with several physical manners by NMR spectroscopy.
Masahiro Okazawa*, Yumiko Fukasawa,
Hiroaki Yoshimizu
556. Experimental and theoretical analysis of
the solubility and diffusivity of gases and
vapors in mixed matrix membranes.
Maria-Chiara Ferrari, Michele Galizia,
Maria Grazia De Angelis, Giulio C. Sarti*
557. Water sorption properties of ethylenevinyl alcohol copolymer studied by H-2
NMR. Masashi Kuno*, Hiroaki Yoshimizu
558. Coating with macroporous polyarylate
on the polyethylene separator via a nonsolvent induced phase separation process for the enhancement of thermal stability. Keun won Song, Chang keun Kim*
559. Novel membrane-based drug delivery
capsule for retinal neuroprotection.
Nobuhiro Nagai*, Takeaki Kawashima,
Norihiro Kumasaka, Hirokazu Kaji,
Hideyuki Onami, Matsuhiko Nishizawa,
Toshiaki Abe
560. Surface modification of acetylenelinked glycolipid vesicle by click chemistry. Hidehiro Ito*, Toshiaki Kamachi,
Eiji Yashima
561. Preparation and separation properties
of cellulose hybrid materials.
Tada-Aki Yamagishi*,
Norihito Motosugi, Tomoki Ogoshi,
Akihiko Takada
562. Molecular simulation of gas transport
behaviors and micro-structure of the hybrid amorphous silica membrane.
Kai-Shiun Chang, Tomohisa Yoshioka,
Toshinori Tsuru, Kuo-Lun Tung*
563. Study of the organic fouling mechanism
on fluoropolymeric microfiltration membranes for water applications.
Nien-Jung Lin*, Kuo-Lun Tung*,
Yu-Ling Li
564. Membrane surface engineering for fouling-tolerant membrane-based liquid separations. Ho Bum Park*, Hye Jin Shin,
Hyo Won Kim, Young Hoon Cho,
Tae Hwan Choi
565. Gas diffusivity, solubility and permeability of polysulfone-poly(ethylene oxide) copolymer membranes. Ho Bum Park*,
Hee Wook Yoon, Hyo Won Kim
566. Analyses of the free volume and small
molecule transport behaviors in the polymeric membrane: A molecular dynamics
simulation. Chao-Hsiang Kang*,
Kai-Shiun Chang, Kuo-Lun Tung
Convention Center
Kamehameha Halls II and III
Functional Block Copolymer Assemblies
(#57)
Organized by: T. Lodge, J. Bang, C. Han,
M. Hillmyer, Y. Matsushita
Presiding: T. Lodge
Poster Session
19:00 – 21:00
567. Self assembly induced nanostructure of
fluorescent block copolymers.
Jungmok You, Jeong-Ae Yoon,
Jeonghun Kim, Yuna Kim, Teahoon Park,
Chih-Feng Huang, Jung H. Kim,
Krzysztof Matyjaszewski,
Eunkyoung Kim*
568. Supramolecular assembly of end-functionalized polymer mixture confined in
nanospheres. June Huh*, Ji Young Jung,
Je Wook Lee, Cheolmin Park, Won Ho Jo
569. Outermost surface functionalized thermoresponsive polymeric micelles for biomedical applications.
Masamichi Nakayama*, Jun Akimoto,
Yayoi Kawahara, Hideko Kanazawa,
Teruo Okano
570. Synthesis of an AB2 star copolymer and
its application for polyion complexes in
aqueous media. Atsushi Kobayashi,
Akihiro Kishimura*, Shigehiro Hiki,
Kazunori Kataoka
571. Study on the lamellae-Fddd transition
of block copolymer. Kuniaki Matsuda,
Myung Im Kim, Mikihito Takenaka,
Kazuki Ito, Hirokazu Hasegawa
572. Vertically oriented cylindrical microdomains in thick films by using block copolymer micelles and solvent annealing for
optoelectronic application.
Sungnam Kim*, Hye Jeong Kim,
Jueun Jung, Sung Woo Heo,
Taihyun Chang, Jin Kon Kim,
Seung Bin Kim
573. Thermoresponsive morphology transition of block-type supramacromolecules
via hydrogen bonding in an ionic liquid
and its dependence on the number of hydrogen bonding units.
Hajime Yamagishi, Atsushi Noro,
Yushu Matsushita
574. Preparation and morphology control of
block copolymer/metal salt hybrids.
Yoshio Sageshima*, Atsushi Noro,
Yushu Matsushita
575. Photo-induced self-assembly of multistimuli responsive block copolymers in an
ionic liquid. Yutaro Nakamura,
Takeshi Ueki, Kazuyuki Niitsuma,
Ayuko Yamaguchi, Timothy P. Lodge,
Masayoshi Watanabe
576. Syntheses of diblock copolymers composed of ␲-conjugated polymer segments toward the development of the
plastic photovoltaic cells.
Hiroki Higashiura, John R. Miller,
Sadayuki Asaoka*
577. Microphase segregated nanostructure
of the liquid crystalline diblock copolymer
composed of a silicon-containing segment. Tomoe Tanaka, Tomohiro Yorisue,
Hiroyuki Hanahata, Motonori Komura,
Tomokazu Iyoda, Sadayuki Asaoka*
578. Ordered complex nanostructures from
combination of two types of block copolymers. Sehee Kim, Kookheon Char*,
Byeong-Hyeok Sohn*
579. Effect of pressure on the dispersion of
gold nanoparticles in polystyrene-blockPoly (n-pentyl methacrylate) copolymer
thin film. Ara Jo, Jin Kon Kim*
580. 3-D observation of Fddd phase in
diblock copolymer thin film. Jueun Jung,
Hae-Woong Park, Junyoung Lee,
Taihyun Chang*, Hidekazu Sugimori,
Hiroshi Jinnai
581. Ordered bicontinuous double-diamond
structure in diblock copolymer/homopolymer blend.
Katsuhiro Yamamoto*, Hideaki Takagi*,
Shigeru Okamoto, Shinichi Sakurai
582. Controlled arrangement of ferritin molecules on a self-assembled nano pattern
of diblock copolymer. Go Sakaguchi,
Mikihito Takenaka, Hirokazu Hasegawa
583. Reverse thermal hydrogels of poly(propylene oxide)-b-poly(ethylene oxide)-bpoly(propylene oxide) ␣,␻-bisphosphate
induced by multivalent metal ions.
Sang Won Jeong*, Minkwan Kim,
Chul Su Baek, Hyun-Chul Kim,
Eunjoo Kim, Se Guen Lee, Sung Jun Lee
584. Thin hybrid block copolymer micelle
films with tunable electro-optic properties. Cheolmin Park, Jinwoo Sung
585. Surface interaction influence on transition behavior of block copolymer films.
Eunhye Kim, Seunghoon Choi,
Hyungju Ahn, Du Yeol Ryu*
586. Self-assembled block copolymers for
amplified biodetection. Manoj Nayak,
Andrzej Rys, Hanadi F. Sleiman*,
Hassan S. Bazzi*
587. Gold-glycopolymer complexes for the
treatment of rheumatoid arthritis.
Samuel Pearson*, Martina H. Stenzel
588. Thermo-responsive self-assembly of
Poly(N-isopropylacrylamide)-DNA block
copolymers. Kyosuke Isoda,
Naoki Kanayama, Masanori Fujita,
Tohru Takarada*, Mizuo Maeda*
589. Side-chain cobaltocenium-containing
block copolymers. Chuanbing Tang*,
Lixia Ren, Christopher Hardy, Deon Doxie
Convention Center
Kamehameha Halls II and III
Polymer Nano-Hybrids at Bio-Interfaces
(#127)
Organized by: Y. Chujo, C.S. Ha,
K. Uhrich, K. Wynne
Presiding: Y. Chujo
Poster Session
19:00 – 21:00
590. Signal regulation of 19F MR probes
based on functional nanomaterials for
molecular imaging. Narufumi Kitamura,
Kazuo Tanaka, Yoshiki Chujo*
591. Photonic crystals derived from colloidal
assemblies and photolithography for label-free detection of biomolecules.
Su Yeon Lee, Shin-Hyun Kim,
Chul-Joon Heo, Hyerim Hwang,
Seung-Man Yang*
592. Preparation and characterization of
nanocapsules containing capsaicin by
coacervation methods. Jincheng Wang*,
Sihao Chen*, Jianzhong Lou
593. Minimizing formaldehyde use in the
synthesis of metal nanomaterials.
Scott M. Reed*
594. Tailored amino acid based block copolymers via ATRP. Ildoo Chung*,
Jihee Son, Sangwook Jung
595. Synthesis of virus/polymer composite
materials using the “grafting-from”
method. Jerry R. Oxsher, Laying Wu,
Erin Davis, Tony Neely, Qian Wang*
Convention Center
Kamehameha Halls II and III
Synthesis, Structure, and Physical
Properties of Advanced Polymer Gels (#136)
Organized by: K. Ito, M. Sibayama,
R. Siegel, C. Wu
Presiding: K. Ito
Poster Session
19:00 – 21:00
596. Electromechanical properties of ionic
liquid/silicone gels. Yukihiko Inoue,
Hu Yan, Hidenori Okuzaki
597. Synthesis and reaction of cross-linked
polymers with diarylbibenzofuranone
units. Keiichi Imato,
Nishihara Masamichi, Otsuka Hideyuki,
Takahara Atsushi*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–103
03-MACR
598. Novel gel actuators based on quinones.
Shailesh K. Goswami*, John McAdam,
Jim Simpson, Lyall Hanton,
Stephen Moratti*
599. Organic-inorganic hybrid slide-ring gels
prepared from a novel silicone-based
polyrotaxane. Kazuaki Kato*, Kohzo Ito
600. Dynamics of polyrotaxane in solutions
and slide-ring gels investigated by neutron spin echo. Koichi Mayumi*,
Hitoshi Endo, Michihiro Nagao,
Hideaki Yokoyama,
Michael Monkenbusch, Jürgen Allegaier,
Vitaliy Pipich, Olaf Holderer,
Dieter Richter, Mitsuhiro Shibayama,
Kohzo Ito
601. Preparation of hydrogels by inclusion of
amylose in vine-twining polymerization.
Kyutoku Tsuyoshi, Yoshiro Kaneko,
Jun-ichi Kadokawa*
602. Polyethylene oxide based cross-linked
networks. Smita Ghosh*, Lyall Hanton,
Stephen Moratti*
603. Application of polymer gels for adsorption of heavy metal ions.
Hideaki Tokuyama*, Shuji Sakohara
604. Control of polymer network structure by
photochromic cross-linker.
Tomonari Ogata*, Kanayo Imura,
Kohei Itoh, Yutaka Kuwahara,
Seiji Kurihara
605. Structural analysis of homogeneous
network gel. Takuro Matsunaga,
Kengo Nishi, Yuki Akagi,
Takamasa Sakai, Ung-il Chung,
Mitsuhiro Shibayama*
606. Theoretical modeling of solvation structure and gelation of an oligomeric electrolyte. Olga Lyubimova, Sergey Gusarov,
Alexander Kobryn, Andriy Kovalenko
607. Hydrogel consisted of imogolite with
high mechanical strength in response to
cross-linking density.
Kazuhiro Shikinaka, Yoshihito Osada,
Kiyotaka Shigehara*
608. Novel thermo- and pH-stimuli responsive hydrogels based on 2-hydroxyethyl
acrylate. Maxim A. Dergunov,
Sergey A. Dergunov, Eugene Pinkhassik*,
Grigoriy A. Mun*
609. Volume phase transition of slide-ring
gels. Akinori Bando, Kazuaki Kato,
Yasuhiro Sakai, Hideaki Yokoyama,
Kohzo Ito*
610. Adsorption of alcohol into the nanoporous structure for syndiotactic polystyrene and p-methylstyrene.
Kenichi Furukawa, Takahiko Nakaoki*
611. Thermal and vibrational analyses of
phase structure for poly(vinyl alcohol) hydrogel. Tatsuro Nakano,
Takahiko Nakaoki*
612. Improvement of water retentivity of
polysaccharide based hydro-gel modified
by the acylation. Kazuya Hanada,
Hiroshi Yoshida, Satoshi Osawa*
613. Structure and dynamics of water in
shake gel. Satoshi Morikubo*,
Yurina Sekine, Tomoko Ikeda-Fukazawa
614. Elastic properties of rigid polymer gels
linked by symmetrical tetrafunctional
cross-linker. Naoki Yoshihara*,
Daichi Kusano, Yusaku Nomoto,
Mitsuhiro Shibayama, Takamasa Sakai,
Toshiyuki Watanabe
615. Porous materials of polyacrylonitrile by
phase separation. Keisuke Okada,
Tatsuya Oka, Takashi Tsujimoto,
Hiroshi Uyama
616. Precise network structure control of reorganizable chemical gels.
Yoshifumi Amamoto, Moriya Kikuchi,
Hiroyasu Masunaga, Sono Sasaki,
Hideyuki Otsuka*, Atsushi Takahara*
617. Synthesis of symmetric and asymmetric
multi-layer gels consisting of different
poly(N-alkylacrylamide) layers and their
thermosensitive behavior.
Takashi Iizawa*, Akihiro Terao
618. Nanohybrid self-crosslinked PDMA/silica hydrogels. Dominique Hourdet*,
Linn Carlsson, Séverine Rose,
Alba Marcellan*, Tetsuharu Narita,
Costantino Creton
619. Observation of the fracture process of
tough Double Network hydrogels.
Tasuku Nakajima, Qui Ming Yu,
Takayuki Kurokawa, Jian Ping Gong*
104 –TECH
TECHNICAL PROGRAM
620. Biopolymeric matrices for bioactive
agent protection and controlled delivery.
Tien-Canh Le*, Mathieu Millette,
Monique Lacroix
621. Fast stimuli responsive and mechanically strong polyrotaxane based hydrogels. Abu B. Imran*, Yukikazu Takeoka,
Takahiro Seki, Yasuhiro Sakai, Kohzo Ito
622. Synthesis and optical properties of organic-inorganic hybrid semi-IPN gels
containing conjugated polymers.
Naofumi Naga*, Tomoharu Miyanaga,
Hidemitsu Furukawa
623. Bound solvent in isotactic polypropylene gel. Takahiko Nakaoki*,
Narumi Fujiwara
624. Assembly of stimulus sensitive gel particles with DNA-dye complex.
Takashi Nishiyama*, Takeshi Yamauchi,
Norio Tsubokawa, Yoshiharu Kagami
625. Polyrotaxane elastomer with macrocrosslinker. Yasuhiro Sakai*,
Aoi Inomata, Christian Ruslim,
Michiko Ito, Junko Suda,
Changming Zhao, Hideaki Yokoyama,
Kohzo Ito
626. Strengthening of the hydrogel with porous inorganic particles.
Hideyuki Mitomo*, Taiki Tominaga,
Ken-Ichi Sano, Kuniharu Ijiro,
Yoshihito Osada
627. Spontaneous redifferentiation of dedifferentiated human articular chondrocytes
on hydrogel surfaces. Jing Jing Yang*,
Yong Mei Chen, Jian Fang Liu,
Takayuki Kurokawa, Jian Ping Gong
628. pH-responsive microgels containing
novel carboxy-carrying monomer.
Hiroki Nagaoka, Risei Wada,
Hidenobu Shimizu*, Masaru Okabe
629. Effect of hydroxylated fullerene on gas
permeability of thermoplastic polyurethane elastomer. Ryouhei Dobashi*,
Masahiro Tajima, Katsuji Matsunaga
630. Formation of porous particles throughout gelation process for Poly(hydroxybutyrate-co- hydroxyvalerate). Yuto Hoki,
Takahiko Nakaoki*
631. Preparation of antigen-responsive hydrogels having temperature-responsive
polymer chains. Yuri Kojima,
Yurie Ohkita, Takashi Miyata*,
Tadashi Uragami
632. Preparation of stimuli-responsive gel
particles that recognize target molecules.
Yuta Hata, Takashi Miyata*,
Tadashi Uragami
633. Synthesis of organic hybrid gels using
click reactions. Hitomi Nagino,
Naofumi Naga, Hidemitsu Furukawa
634. Synthesis of modified polyrotaxanes
having functional pendant groups or long
side chains. Jun Araki*, Keisuke Kagaya,
Naoto Tsukamoto, Kousaku Ohkawa
635. Thermo-reversible ion-gel based on the
hierarchical self-assembly of doubly
thermo-sensitive ABC-triblock copolymer
in an ionic liquid. Yuzo Kitazawa,
Takeshi Ueki, Kazuyuki Niitsuma,
Satoru Imaizumi, Timothy P. Lodge,
Masayoshi Watanabe*
636. Effects of module-functionalites on
polymer network structure. Yuki Akagi,
Takuro Matsunaga, Mitsuhiro Shibayama,
Ung-il Chung, Takamasa Sakai
637. Liquid crystalline polyrotaxane with
movable mesogenic sidechains.
Masatoshi Kidowaki*, Kazuki Kinoshita,
Kohzo Ito
638. Preparation of spherical PVA hydrogels
bearing ␤-cyclodextrin and their application as immobilizing support for microbes. Hikaru Tokunaga, Taiji Ito,
Hirohito Yamasaki*
639. Preparation of spherical photocrosslinkable hydrogels bearing ␤-cyclodextrin and their application as immobilizing support for microbes.
Hirohito Yamasaki*, Narumi Uchida,
Yasuyuki Nagasawa, Ito Taiji,
Kimitoshi Fukunaga
640. Thermoresponsive dehydroalanine
polymer gel with rapid response and high
repetition durability. Yoshihiko Tezuka*,
Hitoshi Tanaka
641. Molecularly imprinted polymers prepared by controlled/living radical polymerization. Shogo Sasaki,
Shigeaki Yamori, Tooru Ooya,
Toshifumi Takeuchi*
Saturday Morning
Convention Center
325B
NMR Spectroscopy of Polymers: Innovative
NMR Strategies for Complex
Macromolecular Systems (#12)
Organized by: T. Asakura, H.N. Cheng,
A. English, F. Horii, P. Macdonald,
H. Spiess, J. White, A. Whittaker
Presiding: T. Asakura
7:30 – 642. Solid-state NMR studies of elastic proteins. Kristin K. Kumashiro*
8:00 – 643. Structure of silk-based peptides
(Glu)n(Ala-Gly-Ser-Gly-Ala-Gly)4 (n⫽4-8)
studied by solid-state NMR.
Yasumoto Nakazawa*, Aya Nagano,
Tetsuo Asakura
8:30 – 644. Elucidating structure and dynamics in spider silk with multidimensional, multinuclear solid-state MAS
NMR. Gregory P. Holland,
Janelle E. Jenkins*, Xiangyan Shi,
Jeffery L. Yarger
9:00 – 645. Hornet (Vespa) silk: Structural
studies by solid-state NMR.
Tsunenori Kameda*
9:30 – 646. Investigation of filler-matrix interactions and confinement effect in polymer nanocomposites.
Pramoda K. Pallathadka, Mya Khine Yi,
He Chaobin
10:00 – 647. Characterization of microbial
poly(amino acid)s and their polymer
blends by solid state NMR.
Shiro Maeda*, Ko-Ki Kunimoto
10:30 – 648. Local dynamics of self-confined
chains in poly(styrene)/poly(vinyl methyl
ether) blends: A solid-state NMR study.
Cedric Lorthioir*, Françoise Lauprêtre
11:00 – 649. Cellulose dissolution into novel
solvent systems monitored by nuclear
magnetic resonance (NMR) spectroscopic methods. Tommi Virtanen*,
Sirkka L. Maunu
Convention Center
323B
Advanced Polymeric Membranes for
Environmental, Biomedical and
Bioengineering Application (#51)
Organized by: A. Higuchi, B. Freeman,
A. Hill, Y.M. Lee
Presiding: A. Hill, Y. Lee
7:30 – 650. Thermally rearranged polymer
membranes for gas separation at high
temperature. Young Moo Lee*
8:10 – 651. Pore design in membranes.
Anita J. Hill, Aaron W. Thornton
8:50 – 652. pH-responsive nanofiltration
membranes by surface modification.
Sumith R. Wickramasinghe,
Heath H. Himstedt, Kathryn M. Marshall,
Xianghong Qian
9:30 – 653. Nano capping electrolyte and
pore-filling electrolyte membranes for extremely low humidity PEFC operations.
Takeo Yamaguchi*, Lee Jumyeung,
Hidenori Ohashi, Takanori Tamaki
10:10 – 654. Multiblock copolymers based
on poly(sulfide sulfone nitrile) for proton
exchange membrane fuel cells.
Dongwon Shin, Chi Hoon Park,
Kwansoo Lee, Chang Hyun Lee,
James E. McGrath, Young Moo Lee*
10:30 – 655. Mixed-matrix membranes
(MMMs) comprising metal organic frameworks and novel perfluorocyclobutylbased polymers or high temperature
polyimides for gas separations.
John P. Ferraris*, Kenneth J. Balkus,
Inga H. Musselman, Grace J. Kalaw,
Ma. Josephine C. Ordoñez,
Sumudu N. Wijenayake
10:50 – 656. Polymeric membranes containing poly(amidoamine) (PAMAM) dendrimer for preferential CO2 separation
over H2. Ikuo Taniguchi,
Ryosuke Shimizu, Shohong Duan,
Teruhiko Kai, Shingo Kazama*
11:10 – 657. Synthesis of crosslinkable sulfonated poly(arylene ether) for PEMFC.
Myung-Hwan Jeong, Kwan-Soo Lee,
Young-Jea Kim, Da-Young Kim, Un Ko,
Jae-Suk Lee*
Convention Center
322AB
Functional Block Copolymer Assemblies
(#57)
Organized by: T. Lodge, J. Bang, C. Han,
M. Hillmyer, Y. Matsushita
Presiding: J. Bang
7:30 – 658. Using interfacial manipulations to
control ordering in block copolymers.
Thomas Epps*, Julie Albert,
Jong K. Park, Raghunath Roy
8:00 – 659. Block copolymer electrolytes for
lithium batteries. Nitash Balsara*
8:30 – 660. Stimuli responsive ionic liquidbased block copolymers and materials.
John Texter*
8:50 – 661. Design and preparation of thermoreversible supramolecular gels and
their viscoelastic properties.
Atsushi Noro*, Hayashi Mikihiro,
Akihisa Ohshika, Yushu Matsushita
9:10 – 662. Ion gels from block polymers and
ionic liquids: Applications as gate dielectrics in organic thin film transistors.
Timothy Lodge*, Sipei Zhang,
Keun-Hyung Lee, Dan Frisbie, Yu Lei
9:30 – 663. Stimulus responsive photonic
block copolymers. Edwin L. Thomas*
10:00 – 664. Giant single crystals of block
copolymers. Shigeru Okamoto*,
Koji Ando, Kazuhiro Sato,
Takahiko Yamanaka, Masahiro Mouri,
Akihiko Ikeda, Hirokazu Hasegawa,
Naokiyo Koshikawa
10:30 – 665. Nanoconfined ferroelectricity in
poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polystyrene copolymers. Fangxiao Guan, Jing Wang,
Lei Zhu*
10:50 – 666. Molecular design for conducting materials based on microphase separation of phthalocyanine-containing block
copolymers. Junko Aimi*, Takuzo Aida,
Krzysztof Matyjaszewski,
Motonori Komura, Tomokazu Iyoda
11:10 – 667. Effect of film thickness on the
phase behaviors of diblock copolymer
thin film. Jueun Jung, Hae-Woong Park,
Taihyun Chang*, Hiroshi Jinnai,
Kazuyuki Matsunaga
Convention Center
328
Biodegradable and Biomass Plastics (#95)
Organized by: H. Uyama, G.G. Chen,
S.S. Im, T. Iwata, C. Nomura
Presiding: H. Uyama, S. Im
7:30 – 668. Current status of biomass-based
plastics development in Japan.
Isao Inomata
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR
8:00 – 669. Recent development of green
plastic poly(lactic acid) in China.
Xuesi Chen*, Zhiming Chen*,
Xinchao Bian*, Lidong Feng, Yanlong Liu,
Hua Bai*
8:30 – 670. Physical properties of the stereoblock poly(lactic acid)s (sb-PLAs) melt
spun fibers. Jae-Chang Lee*,
Yoshiharu Kimura, Hideki Yamane,
Zhen Tang, Kazuaki Sogo
8:50 – 671. Study on biodegradable aliphatic
polyester nanocomposites.
SungYeon Hwang*, SeungSoon Im
9:10 – 672. Ecobionanocomposites: Hierarchical nanocomposites incorporating stereocomplexation. John R. Dorgan*,
Birgit Braun, Laura O. Hollingsworth
9:40 – 673. PLA impact modifiers based on
rubber containing copolymers.
In-Joo Chin*, Na-Yeon Kim,
Jae-Yoon Lee, Chantiga Choochottiros
10:10 – 674. Phase separation and degradation behaviors of the electrospun fibrous
blends of PHBHHx/PDLLA.
Yi-Ming Sun*, Mei-Ling Cheng,
Po-Ya Chen, Chin-Hung Lan
10:40 – 675. Preparation of heat stable polylactide using supercritical fluid technology. Soo Hyun Kim*, Purba Purnama
Convention Center
321B
Synthesis, Structure, and Physical
Properties of Advanced Polymer Gels (#136)
Organized by: K. Ito, M. Sibayama,
R. Siegel, C. Wu
Presiding: K. Ito, R. Siegel
7:30 – 676. Swelling and mechanical behaviors of hydrogels containing phenylboronic acid sidechains. Ronald A. Siegel,
Siddharthya K. Mujumdar,
Clinton R. Jones, Mei Lee
8:00 – 677. Photocrosslinked hydrogels from
thermoresponsive PEGMEMA-PPGMAEGDMA copolymers containing multiple
methacrylate groups: Synthesis, mechanical property, swelling, protein release,
and cytotoxicity. Hongyun Tai*,
Wenxin Wang*, Daniel Howard,
Tina Vermonden, Wim E. Hennink,
Seiji Takae, Patrick S. Stayton,
Allan S. Hoffman, Cameron Alexander,
Steven M. Howdle, Kevin M. Shakesheff
8:15 – 678. Glucose responsive polymer gel
as element for robust and self-regulated
insulin delivery system.
Akira Matsumoto, Takehiko Ishii,
Kazunori Kataoka, Yuji Miyahara*
8:30 – 679. Manipulation through chemical
design and environmental triggers of gels
formed by amphiphilic telechelic polymers in water. Francoise M. Winnik*
9:00 – 680. Drug release studies and biological properties of chitosan/dextran-based
hydrogels for surgical use.
Jaydee Cabral*, Stephen Moratti,
Lyall Hanton, Manal Aziz,
Cathrin Kirchhoefer, Olaf Bork,
Heather Brooks
9:15 – 681. Self-oscillating polymer and gels
as novel functional materials.
Ryo Yoshida*
9:45 – 682. Stimuli-responsive hybrid polymer-gel microstructures: From environmentally induced actuation to self-sustained oscillations. Michael Aizenberg*,
Philseok Kim, Lauren D. Zarzar,
Jeffrey Epstein, Joanna Aizenberg*
10:15 – 683. In situ gelling microgels and microgel-hydrogel composites for drug delivery. Daryl Sivakumaran,
Cameron McLean, Todd Hoare*
10:45 – 684. Design and fabrication of stimuli-responsive Janus microgels.
Daisuke Suzuki*, Yoshitaka Umeda,
Toshihiro Hirai
11:00 – 685. Bioconjugated hydrogels that
respond to a target biomolecule.
Takashi Miyata*
Convention Center
308A
Amphiphilic Polymers: Fundamentals and
Applications (#231)
Organized by: T. Sato, K. Akiyoshi,
C. McCormick, F. Winnik
Presiding: T. Sato, F. Winnik, K. Akiyoshi
7:30 – 686. Poly(allylamine) derivatives exhibiting UCST-type solution behavior under physiological conditions.
Naohiko Shimada, Arihiro Kano,
Atsushi Maruyama*
8:00 – 687. Amphiphilic glycogen nanoball.
Haruko Takahashi, Shin-ichi Sawada,
Kazunari Akiyoshi*
8:20 – 688. 19F MRI agents: Effect of structure and preparation methods on self-assembly and imaging performance.
Hui Peng, Idriss Blakey,
Bronwin Dargaville, Firas Rasoul,
Stephen Rose, Kristofer Thurecht,
Andrew Whittaker*
8:40 – 689. Multisensitive microgels at oilwater interfaces. Walter Richtering*,
Tingting Liu, Bastian Brugger
9:00 – 690. Interaction of amphiphilic polyelectrolytes with cyclodextrins.
Akihito Hashidzume, Akira Harada
9:30 – 691. Shear-thickening in aqueous surfactant-associative thickener mixtures.
Raymond H. Fernando*, Sean Manion,
Laura Johnson
9:50 – 692. Crowding agent induced phase
transition of block copolymer in solution.
Rong Wang*
10:10 – 693. Arborescent polypeptide micelles. Mario Gauthier*, Greg Whitton
10:30 – 694. Synthesis of amphhiphilic block
copolymers as precursors of tubular
guides for peripheral nerve repair.
Denis J. Bertin*, Benoit Clement,
Thomas Trimaille, Didier Gigmes,
Kamel Mabrouk, Laurence Schacher,
Nabyl Khenoussi
10:50 – 695. Role of crystallinity in the selfassembly of amphiphilic polyethylenes in
water. Jerome P. Claverie*,
Jean-Christophe Daigle,
Françoise Winnik, Vladimir A. Kryuchkov
11:20 Closing remarks
Convention Center
323A
Controlled/Living Radical Polymerization in
Dispersed Systems (#160)
Organized by: M. Okubo,
M. Cunningham, J. Schork, P. Zetterlund
Presiding: M. Okubo, B. Charleux
7:45 Introductory remarks
7:50 – 696. Fundamentals of RAFT ab initio
emulsion polymerization and block coplymer synthesis. Ying-Wu Luo*
8:30 – 697. RAFT/MADIX polymerization of
N-vinyl monomers in aqueous media.
Hideharu Mori*
8:50 – 698. Nanorattles using RAFT as a new
generation of opacifier. Duc Nguyen*,
Chris Such, Matt Baker, Brian Hawkett
9:10 – 699. Direct synthesis and self-assembling of amphiphilic block copolymers in
a selective solvant via controlled/living
radical polymerization.
Bernadette Charleux, Stéphanie Boisse,
Jutta Rieger, Xuewei Zhang,
Gaelle Pembouong, Patricia Beaunier,
Min-Hui Li
9:50 – 700. Hybrid core-shell nanoparticles
prepared by RAFT emulsion polymerization. Jerome P. Claverie,
Wei-Heng Zhong, Paramita Das,
Thomas Alnasser
10:10 – 701. Anisotropic nanoparticles via
RAFT mediated emulsion polymerization.
Brian S. Hawkett*, Binh T. Pham,
Ulrich Hall, Azniwati A. Aziz
10:30 – 702. Nitroxide-mediated surfactantfree emulsion polymerization of n-butyl
methacrylate with a small amount of styrene. Mary E. Thomson,
Anna-Marie Manley, Jason Ness,
Scott Schmidt, Michael F. Cunningham*
10:50 – 703. Controlled/living radical polymerization in miniemulsion using low-energy emulsification. Siqing Cheng,
Yi Guo, Yusuke Sugihara,
Per B. Zetterlund
11:10 – 704. High solids nitroxide mediated
microemulsion polymerization of methyl
methacrylate with a small amount of styrene and the synthesis of poly(methyl
methacrylate-co-styrene)-block-(n-butyl
methacrylate-co-styrene) polymers.
Mary E. Thomson, Jason Ness,
Scott Schmidt, Michael F. Cunningham*
Convention Center
327
Polymer Nano-Hybrids at Bio-Interfaces
(#127)
Organized by: Y. Chujo, C.S. Ha,
K. Uhrich, K. Wynne
Presiding: C. Ha
8:10 – 705. Construction of MRI contrast
agents using nanobuilding blocks, dendrimers, polymers, and nanoparticles, for
the quantitative analysis of biological
events. Kazuo Tanaka, Yoshiki Chujo*
8:35 – 706. Bioactive nanostructures from
peptide assembly. Myongsoo Lee*
9:00 – 707. Triazine dendrimers: Synthesis,
characterization, and applications.
Eric Simanek*
9:25 – 708. Withdrawn
9:50 – 709. Design of pH-sensitive nanoparticle for novel theranostics toward antioxidative stress injury. Yukio Nagasaki*
10:15 – 710. Polymer nanoparticle-based
cancer therapeutics: from concept to
clinic. Mark E. Davis
10:40 – 711. Organic-inorganic hybrid polysaccharide nanogels for biomedical application. Kazunari Akiyoshi*
11:05 Closing
Convention Center
Kamehameha Halls II and III
Chemistry and Functional Properties of Soft
Interfaces (#42)
Organized by: A. Takahara, K. Char,
K. Kurihara, M. Maeda, Z. Su, G. Warr,
K. Wynne
Presiding: K. Kurihara, M. Maeda, Z. Su,
G. Warr, K. Char, A. Takahara, K. Wynne
Poster Session
10:00 – 12:00
712. Polymerization of styrene-divinylbenzene in single-bilayer nanotubes as templates. Shota Ono, Yutaka Okazaki,
Hirokuni Jintoku, Makoto Takafuji,
Hirotaka Ihara*
713. Preparation of polyelectrolyte-complex
microcapsules by electrospray. Yu Fukui,
Tatsuo Maruyama*, Yuko Iwamatsu,
Akihiro Fujii, Tsutomu Tanaka,
Yoshikage Ohmukai, Hideto Matsuyama*
714. Layer by layer assembly of stereoregular polystyrene derivatives on substrate.
Hiroharu Ajiro, Mitsuru Akashi
715. Quantitative evaluation of stiffness of
dialkylpolysilane on carbon nanotubes.
Woojung Chung, Michiya Fujiki,
Masanobu Naito*
716. Characterization of NS polypeptides
and its interactions with cell surfaces.
Toru Honda, Tomoko Yoshino,
Masayuki Takahashi,
Tadashi Matsunaga*
717. Biocompatibility of segmented poly(dimethylsiloxane)s containing trehalose
units and their prospects.
Naozumi Teramoto*, Emi Iwata,
Tsuyoshi Asakura, Masaki Unosawa,
Navzer D. Sachinvala, Mitsuhiro Shibata
718. Surface engineering of antibody/PEG
hybrid: Densely packed PEG layer and its
effect on immobilized antibody.
Yukio Nagasaki*, Xiaofei Yuan,
Dolça Fabregat, Keitaro Yoshimoto
719. Hierarchical and functional control of
engineered blood vessel tissues by hierarchical cell manipulation.
Koji Kadowaki, Michiya Matsusaki,
Mitsuru Akashi*
720. Polyelectrolyte multilayers modified porous membrane achieve rapid immunoassay with protein condensing.
Heyun Shen, Junji Watanabe,
Takami Akagi, Mitsuru Akashi*
721. Surface segregation of poly(2-methoxyethyl acrylate) in the mixture with poly(methyl methacrylate). Toyoaki Hirata,
Hisao Matsuno, Masaru Tanaka,
Keiji Tanaka*
722. Fabrication of apatite/commonly used
polymer interfaces using wet processes.
Mineo Hashizume*, Atsushi Sakai,
Yuri Sakamoto, Hideharu Kawakubo
723. Facile surface modifications for polyimide films that enable their sol-gel coating
with metal oxides.
Michihisa Hirashima*, Mineo Hashizume
724. Structural change at the outermost surface of poly(methyl methacrylate) induced
by water. Ayanobu Horinouchi,
Yoshihisa Fujii, Norifumi Yamada,
Keiji Tanaka*
725. Dynamic mechanical analysis of poly(methyl methacrylate) nanofiber-mats.
Jie Zhan, Hisao Matsuno, Keiji Tanaka*
726. Neuronal cell patterning on commercial
multielectrode arrays. Koji Ikeda,
Munehiro Yamaguchi, Masaaki Suzuki*,
Suguru N. Kudoh, Daisuke Ito,
Tsutomu Uchida, Kazutoshi Gohara
727. SPM interaction study of Al2O3 surfaces in electrolyte solutions.
Toshihiro Isobe*, Mikiro Hayashi,
Akira Nakajima
728. Single-molecule imaging of DNA duplex
immobilized on surfaces with scanning
tunneling microscope.
Takahito Ohshiro*, Mizuo Maeda
729. Surface modification of polymers using
specific-binding peptides.
Takaaki Date*, Takeshi Serizawa
730. Caged compounds based on gold
nanoparticles bearing a photocleavable
tether. Jun Nakanishi*,
Hidekazu Nakayama, Shingo Kaneko,
Kazuo Yamaguchi
731. Synthesis and characterization of nonsurface active/surface active transition
polymer. Tomoyuki Ohnishi,
Ghosh Arjun, Matsuoka Hideki
732. Properties of biomimetic artificial bilayer
membranes in water. Goh Matsuo*,
Masaru Tomita, Tomoyoshi Soga
733. Enhancement of PHB adsorption and
disruption activities by amino acid substitution in substrate-binding domain of
PHB depolymerase. Liu Tzea Tan,
Tomohiro Hiraishi*, Naoya Komiya,
Sudesh Kumar, Mizuo Maeda
734. Odd-even effect on the molecular arrangements at solid/liquid interface.
Yoshihiro Kikkawa*, Emiko Koyama,
Seiji Tsuzuki, Kyoko Fujiwara,
Masatoshi Kanesato
735. Tip- enhanced Raman scattering studies on polymer thin films.
Yukihiro Ozaki*, Harumi Sato,
Yasutaka Kitahama, Toshiaki Suzuki,
Isao Takahashi
736. Anti-biofouling properties of a telomer
brush with pendent glucosylurea groups.
Hiromi Kitano*, Astushi Hayashi,
Hisatomo Suzuki, Naoki Kanayama,
Yoshiyuki Saruwatari
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–105
03-MACR
737. Hydrogel-modified field effect transistor
for lectin recognition. Yasuhiro Maeda,
Akira Matsumoto, Yoshiko Miura,
Yuji Miyahara
738. Anti-biofouling properties of amphoteric
polymer brush constructed on a glass
substrate. Takuya Kondo,
Hiromi Kitano*, Kohji Ohno
739. Structural characterization of
PNIPAAm-DNA conjugate by small-angle
X-ray scattering. Wei Yang Ooi,
Masahiro Fujita, Kumar Sudesh,
Mizuo Maeda*
740. Monolayer characterization and photocurrent generation of organic semiconductor molecules with partial structure of
graphene skeleton. Chika Akabane,
Ken-ichi Iimura*, Norihiro Kato,
Takanori Fukushima, Yohei Yamamoto,
Takuzo Aida
741. Development of nano-scale Coulter
counter using a nanopore.
Makoto Takemasa, Masahiro Fujita,
Mizuo Maeda
742. Orientation control of the double helical
morphology in the thin film of an ABC
triblock terpolyme. Song Hong,
Hidekazu Sugimori, Ryuhei Kimoto,
Takeshi Kaneko, Volker Abetz,
Hiroshi Jinnai
743. Adipocyte patterning by using functionality of surface molecules.
Munehiro Yamaguchi, Kouji Ikeda,
Masaaki Suzuki, Hiromu Watanabe,
Tsutomu Uchida, Masafumi Nagayama,
Kazutoshi Gohara
744. RAFT synthesis of cationic amphiphilic
diblock copolymer and nanostructure
analysis of its monolayer on the water
surface. Shinichi Fujita*, Arjun Ghosh,
Shin’ichi Yusa, Yoshiyuki Saruwatari,
Hideki Matsuoka
745. Creation of pH-responsive silica gel micro particle. Masamichi Inoue*,
Shin-ichi Yusa, Yotaro Morishima,
Yoshinobu Nakamura, Syuji Fujii,
Yasuhiko Iwasaki, Yasuhisa Shibata
746. Infrared spectroscopy study on intermolecular interaction and phase separation of PS/PVME polymer blends.
Takeshi Miyake, Harumi Sato,
Takeji Hashimoto, Yukihiro Ozaki
747. Coupling between metal nanoparticles
and fluorescent dyes with layer-by-layer
assembled polymer films. Ki-Se Kim*,
Byeong-Hyeok Sohn
748. Effect of salt and ion species on the
nanostructure of polyelectrolyte brush at
the air/water interface.
Hideki Matsuoka*, Shunichi Nakayama,
Shinichi Fujita, Yuta Yamakawa,
Arjun Ghosh
749. DNA-functionalized thermoresponsive
amphiphilic copolymers: Preparation and
self-assembly. Pengju Pan,
Masahiro Fujita*, Mizuo Maeda*
750. Synthesis and property of polyrotaxane
networks exploiting pseudopolyrotaxane
cross-linker. Keum hee Jang,
Takayuki Arai, Yasuhito Koyama,
Toshikazu Takata*
751. Structural control of a double helical
morphology in an ABC triblock terpolymer. Hidekazu Sugimori, Song Hong,
Kazuyuki Matsunaga, Takeshi Kaneko,
Volker Abetz, Hiroshi Jinnai
752. Adsorption and release behavior of hyaluronan from the surface of hydrogel contact lenses. Susan E. Burke*,
Catherine A. Scheuer, Krista M. Fridman,
Vicki L. Barniak
753. ABC phenomenon of nanocarrier-based
MRI contrast agents and the importance
for tumor targeting. Kouichi Shiraishi,
Huili Ma, Kumi Kawano, Yoshie Maitani,
Masayuki Yokoyama
754. Functional actuator based on high-density array of polypyrrole nanorods.
Gumhye Jeon, Seung Yun Yang,
Jinseok Byun, Jin Kon Kim*
755. Spontaneous periodic change of the interface tension at oil/water by KCl addition. Yohey Shibuya, Shou Yoneda,
Ken Adachi, Akira Nakajima,
Toshihiro Isobe, Sachiko Matsushita*
106 –TECH
TECHNICAL PROGRAM
756. Interaction between silica in the presence of the pH responsive poly(ethyleneimine): Correlation between colloidal
probe adhesion measurements and yield
stress. Shannon Notley
757. Dynamic wettability analysis of hydrophobic polymers. Shinya Takahashi*,
Sayo Kobayashi, Takuya Yamamoto,
Tomoyuki Kasemura, Hiroshi Kimura,
Akira Tsuchida
758. Synthesis of amphiphilic liquid crystalline polymers and their self-assembly in
water. Hiroki Kotegawa,
Takashi Miyata*, Tadashi Uragami
759. Electrically-induced formation of interfacial layers between liquid crystals and
polymer sublayers. Yoshio Makino*,
Masahiro Morimoto, Takuya Aoshima,
Takaya Ito, Atsushi Kubono*
760. Viscoelastic behavior of interfacial layer
formed between pressure-sensitive adhesive and adherend. Katsunori Inaishi*,
Keiichi Oka, Junji Gonda, Takaya Ito,
Atsushi Kubono*
761. Novel blood compatible surfaces using
a nitroxy radicals containing polymer with
antioxidant ability. Yu Yamaguchi,
Toru Yoshitomi, Akihioko Kikuchi,
Yukio Nagasaki*
762. Preparation and surface properties of
“reactive” polymer brushes with exchangeable side chains. Tomoya Sato,
Yoshifumi Amamoto, Hideyuki Otsuka,
Atsushi Takahara
763. Molecular modeling investigation of
binding and activity of horseradish peroxidase immobilized on a PHEMA polymer
brush. Barry L. Farmer, Zhifeng Kuang,
Rajesh Naik, Richard A. Vaia,
Sarah M. Lane
764. Manipulation of surface properties: attachment of nanometer-thick anti-fouling
sticker on versatile substrates.
Hirohmi Watanabe, Aya Fujimoto,
Motoyasu Kobayashi, Atsushi Takahara
765. Precision design and construction of
the surface of nanoparticle for the oligonucleotide delivery. Yutaka Ikeda,
Daisuke Kubota, Yukio Nagasaki
766. Precise control of surface physicochemical properties for electrospun poly(methyl methacrylate) derivative fibers by
surface initiated radical polymerization.
Takahiro Yano*, Weng On Yah,
Hiroki Yamaguchi, Yuki Terayama,
Masamichi Nishihara,
Motoyasu Kobayashi, Hideyuki Ootsuka,
Atsushi Takahara
767. Long-circulation behavior of size-controllable polyion complex vesicles (nanoPICsomes) in mice. Akihiro Kishimura*,
Yasutaka Anraku, Makoto Oba,
Kazunori Kataoka*
768. Thermo-responsive chromatography
using polymer brush grafted porous polystyrene beads. Aya Mizutani,
Kenichi Nagase, Akihiko Kikuchi,
Hideko Kanazawa, Yoshikatsu Akiyama,
Jun Kobayashi, Masahiko Annaka,
Teruo Okano
769. Characterization of liquid crystal thin
film under electric field. Shinya Nakano,
Masashi Mizukami, Noboru Ohta,
Naoto Yagi, Ichiro Hatta, Kazue Kurihara*
770. Protein-resistant and conductive membranes on conducting polymers. Bo Zhu,
Shyh-Chyang Luo, Sekine Jun,
Hsiao-hua Yu*
771. Resonance shear measurement of
nanoconfined ionic liquids.
Kazuhide Ueno, Motohiro Kasuya,
Masayoshi Watanabe,
Masashi Mizukami, Kazue Kurihara*
772. Crystallization-induced optical resolution controlled by external fields.
Michio Matsumoto, Yoshimitsu Itoh*,
Takuzo Aida*
773. Scanning tunneling microscopic study
of noncyclic isobutenyl compounds: Effects of hydrogen bond and tandem
Claisen rearrangement. Kazuhiro Omori,
Kikkawa Yoshihiro*, Masatoshi Kanesato,
Kazuhisa Hiratani*
774. Tribological properties of poly(1-(2methacryloyloxy)ethyl-3-butylimidazolium
bis(trifluoromethanesulfonyl)imide) brush
surfaces. Tatsuya Ishikawa,
Motoyasu Kobayashi, Atsushi Takahara
775. Alternating current cloud point extraction on a microfluidic chip for preconcentration of membrane-associated biomolecules. Naoki Sasaki*,
Kazuo Hosokawa, Mizuo Maeda
776. Surface property of temperature-responsive polymeric thin surface observed
by atomic force microscopy.
Yoshikazu Kumashiro,
Kazuhiro Fukumori, Hironobu Takahashi,
Masamichi Nakayama,
Yoshikatsu Akiyama, Kiyotaka Sakai,
Masayuki Yamato, Teruo Okano*
777. Control of amyloidosis on the multivalent sulfonated sugar. Tomohiro Fukuda,
Erino Matsumoto, Shunsuke Onogi,
Yoshiko Miura*
778. Characterization of interfacial water
structure at thermo-responsive material
surfaces studied by SFG spectroscopy.
Hidenori Noguchi, Yusuke Waki,
Sakaguchi Kazuyasu, Uosaki Kohei
779. Chiral segregation from achiral molecule in 1,1’-bis substituted ferrocen derivatives. Moon Gun Choi*, Oleg N. Kadkin,
Eun Ho Kim, So Yeon Kim,
Young Joon Rha, Yoon Hee Kim
780. Preparation and characterization of surface grafted poly(␥-benzyl-L-glutamate)
with narrow molecular weight distribution.
Jin Nishida, Koji Mitamura,
Motoyasu Kobayashi, Atsushi Takahara*
781. Raman spectra of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) thin films
by Raman microscopic spectroscopy.
Yuko S. Yamamoto, Harumi Sato,
Hidetoshi Sato, Yukihiro Ozaki*
782. Effect of graft-density on molecular motion of polystyrene brush. Hiroshi Arita,
Koji Mitamura, Moriya Kikuchi,
Motoyasu Kobayashi, Atsushi Takahara*
783. Analysis of liquid marble formation.
Daisuke Matsukuma,
Hirohmi Watanabe, Atsushi Takahara*
784. Radical polymer brushes on Al prepared by surface initiated polymerization
and its electrode performance in rechargeable device.
Katsuyuki Takahashi, Hiroyuki Nishide*,
Bryuzgin Evgeny,
Alexander V. Navrotskiy, Ivan A. Novakov
785. Controlled assembly of proteins pattern
in the glass capillaries. Yuan Lin*,
Zhaohui Su, Zhongwei Niu, Qian Wang
Convention Center
Kamehameha Halls II and III
Controlled/Living Radical Polymerization:
Mechanisms, Catalysts, Reaction
Engineering, Materials and Applications
(#236)
Organized by: S. Zhu, T. Fukuda, B.G Li,
K. Matyjaszewski, M. Monteiro
Presiding: S. Zhu
Poster Session
10:00 – 12:00
786. Toward nitroxide mediated photopolymerization. Yohann Guillaneuf*,
Denis Bertin, Didier Gigmes,
Davy-Louis Versace, Jacques Lalevée,
Jean-Pierre Fouassier
787. Synthesis of double-calixarene from
simple condensation of 2,4-dihydroxybenzaldehyde and resorcinol.
Hiroto Kudo*, Takuya Shudo,
Tadatomi Nishikubo
788. Amine free Cu-mediated atom transfer
radical polymerization. Han Hong,
Yeap-Hung Ng, Yen-Min Wong,
Christina L. Chai
789. Synthesis of linear tetrablock quaterpolymer by combining atom transfer radical polymerization and a click coupling
approach. Aleya Hasneen, Ho Seok Han,
Hyun-jong Paik
790. Controlled polymerization of methacrylate having active ester groups and derivation to poly(methacrylamide) library.
Tsuyoshi Ando, Shunsuke Shimizu*,
Kayo Terada, Shiho Hirohara,
Masao Tanihara
791. Synthesis of concentrated polymer
brushes via surface-initiated TERP.
Shota Konishi*, Eiichi Kayahara,
Shigeru Yamago, Akihiro Nomura,
Atsushi Goto, Yoshinobu Tsujii
792. Synthesis of stereoblock PMMA by using of multi-vinyl monomer derived from
novolac. Yoichi Saito, Reiko Saito*
793. Development of a solid polymer electrolyte with high ion-conductive network
structure for a safety lithium ion battery.
Takaya Sato*, Tatsuya Igarashi,
Takashi Morinaga, Shoko Marukane,
Kohji Ohno, Yoshinobu Tsujii,
Takeshi Fukuda
794. Fe(III)-mediated living radical polymerization: A unique system with a higher oxidation state iron catalysts.
Hiroshi Aoshima, Kanji Nagai,
Kotaro Satoh, Masami Kamigaito*
795. Nanocomposite of ZnO nanoparticle
with PEO -b- PMMA. Youngjun Cho,
Jinheung Kim, Yujin Kim, Jae Yeol Lee,
Jungahn Kim*
796. Synthesis of ␣-azido-␻-anhydride-hetero-bifunctionalized poly(ethylene oxide)
and its application for preparation of
nano-sized ZnO particles. Yujin Kim,
Jeongsoon Kim, Junghwa Lee,
Joo Hoon Kim, Jungahn Kim*
797. Synthesis of graphene oxide and its
modification PEO exhibiting water-soluble property. Joo-Hyun Nam,
Sangmi Lee, Jae Yeol Lee,
Ho-Jung Kang, Jungahn Kim*
798. Control of adhesion property of acrylate
block copolymers containing stimuli-responsible side-chains. Eriko Sato,
Tadashi Inui, Akikazu Matsumoto*
799. Synthesis of thermo-responsive 4-arms
star-shaped diblock copolymer.
Masanori Ito*, Shin-ichi Yusa,
Yotaro Morishima, Isamu Kaneda
Convention Center
Kamehameha Halls II and III
Frontiers of Precisely Controlled Polymer
Synthesis: Fine Control of Polymerization
Reaction and Impact on Advanced Material
Designs (#257)
Organized by: T. Kitayama, S. Aoshima,
M. Kamigaito, G. Moad, J. Puskas
Presiding: T. Kitayama
Poster Session
10:00 – 12:00
800. Controlled copolymerization of
(meth)acrylates and vinyl ethers by organoheteroatom-mediated controlled/living
radical polymerization. Eri Mishima*,
Shigeru Yamago
801. Synthesis of poly(diene sulfone)s using
diene monomers by regiospecific and alternating radical copolymerization and
their characterization. Naruki Tanaka,
Asako Mihashi, Eriko Sato,
Akikazu Matsumoto*
802. Radical polymerization of conjugated
dienes with Cu/amine complexes on the
silica particle. Hiroko Okamoto,
Kiyoshi Endo*
803. Controlled polymerization of bulky silyl
methacrylates. Kenji Ishitake,
Kanji Nagai, Kotaro Satoh,
Masami Kamigaito*, Yoshio Okamoto
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR
804. One-pot transformation from living cationic to RAFT polymerization.
Keiji Matsuzuka, Kenta Yamashita,
Shinji Sugihara*, Isao Ikeda
805. Synthesis and some properties of surface-functionalized polymer particles prepared by amphiphilic macromonomers
with precisely-controlled architecture.
Noor Faizah Che Harun*,
Kohei Sawada, Jin Motoyanagi,
Masahiko Minoda
806. Withdrawn
807. Synthesis of graft copolymers with
poly(vinyl chloride) macromonomer.
Kazuhiro Dohi, Kiyoshi Endo*
808. Specific sequence formation in partial
click modification of poly(propargyl
methacrylate). Takehiro Kitaura*,
Tatsuki Kitayama
809. Asymmetric polymerization of N-substituted maleimide and optical resolution
ability of their polymers. Tsutomu Oishi*,
Motohisa Azechi, Kazuhiro Yamabuki,
Kenjiro Onimura
810. Living cationic polymerization of isobutyl vinyl ether with acetylacetone/Lewis
acid initiating system.
Minato Takeguchi, Shokyoku Kanaoka,
Sadahito Aoshima
811. Controlled cationic polymerization and
aldol group transfer polymerization of
bulky silyl vinyl ether.
Mitsumasa Nakawaki, Kanji Nagai,
Kotaro Satoh, Masami Kamigaito*
812. Isomerization cationic polymerization of
vinylcyclohexane. Madoka Kimura*,
Shokyoku Kanaoka, Sadahito Aoshima
813. Living cationic polymerization of ␣-, ␤-,
and p-substituted styrenes.
Kosaku Yasuoka*, Jun Ashida,
Shokyoku Kanaoka, Sadahito Aoshima
814. Survey of an initiating system for the
controlled synthesis of fullerene polymer
conjugates via living cationic polymerization. Masashi Suzuki, Ryo Miyabara,
Jin Motoyanagi, Masahiko Minoda*
815. Monomer isomerization in the polymerization of cis-2-butene with (␣-diimine)Ni(II)/Et2AlCl catalyst. Yoshitaka Tone,
Kiyoshi Endo*
816. Development of rhodium complexes
bearing a tetrafluorobenzobarrelene ligand for the polymerization of phenylacetylene. Naoya Onishi,
Masashi Shiotsuki*, Fumio Sanda,
Toshio Masuda
817. Utilization of alkyne [2⫹2⫹2] cycloaddition reactions to macromolecule synthesis. Yuuki Sugiyama, Chie Takegoshi,
Sentaro Okamoto*
818. Controlled cyclopolymerization of 4,4disubstituted 1,6-heptadiyne derivates by
Grubbs catalyst. In Sun Lee,
EunHye Kang, Tae-Lim Choi*
819. Dendronized polymer synthesis via cyclopolymerization of 1,6-heptadiyne derivatives by Ruthenium-based alkylidene
initiator. EunHye Kang, In Sun Lee,
Tae-Lim Choi*
820. Ring-opening homo- and copolymerizations of racemic lactide and/or ␧-caprolactone using homosalen-Al complexes.
Nobuyoshi Nomura*, Azusa Akita,
Ryohei Ishii, Mitsunori Mizuno
821. Controlled polycondensation of
␤-amino acid based on continuous
monomer addition. Tsuyoshi Ando,
Kazuaki Ikoma*, Kayo Terada,
Shiho Hirohara, Masao Tanihara
822. Chain-growth condensation polymerization of amino acid immobilized on solid-support. Masashi Takahashi,
Hiromichi Baba, Akihiro Yokoyama,
Tsutomu Yokozawa*
823. One pot synthesis of head-to-head alicyclic polyimide using unsymmetrical spirodianhydride. Kazuaki Shirai,
Kazuaki Kudo*
824. Synthesis of poly(p-phenylenevinylene)
under the conditions of catalyst-transfer
Suzuki-Miyaura polymerization.
Masataka Nojima, Akihiro Yokoyama,
Tsutomu Yokozawa*
825. Study of catalyst-transfer SuzukiMiyaura coupling polymerization for the
synthesis of polypyridine. Rena Shibata,
Yutaka Nanashima, Akihiro Yokoyama,
Tsutomu Yokozawa*
826. Synthesis of novel polypyridine bearing
bule light-emitting properties.
Yutaka Nanashima, Akihiro Yokoyama,
Tsutomu Yokozawa*
827. Synthesis of polybenzamide-b-polystyrene block copolymer via combination of
chain-growth condensation polymerization (CGCP) and atom transfer radical polymerization (ATRP). Chih-Feng Huang,
Akihiro Yokoyama, Tsutomu Yokozawa*
828. Preparation of “RAFT gel” via chemoselective polycondensation of a dicarboxylic acid containing a pendant mercapto
groups with diols and succesive crosslinking. Ken Yamamoto, Akinori Takasu
829. Living anionic polymerization with lithiation products of poly(p-methylstyrene) as
a macroinitiator and preparation of multibranched polymers therefrom.
Ryota Uemura, Hideki Nishimura,
Kaoru Adachi, Yasuhisa Tsukahara*
830. Synthesis of novel poly(vinyl ether)-polysaccharide conjugates by precisely
controlled polymerization.
Masahiko Minoda*, Mariko Maeda,
Shizuka Mori, Jin Motoyanagi
831. Synthesis and properties of amino acid
based optically active photo-responsive
poly(phenyleneethynylene)s.
Hiromitsu Sogawa*, Masashi Shiotsuki,
Fumio Sanda
832. Organic chemistry approaches towards
structurally defined, laterally infinite unimolecular networks (2-D polymers).
Junji Sakamoto*, Patrick Kissel,
Thomas Bauer, Animesh Saha, Ming Li,
Payam Payamyar, Marco Servalli,
A. D. Schlüter*
833. Synthesis and functionalization of starshaped poly(ethylene oxide)s and their
application as an antifouling material to a
solid surface. Ju Eun Kim*,
Jeong Yun Heo, Jungahn Kim,
Youngro Byun, Cheol-Hee Ahn
834. Synthesis of new polysaccharides and
carbohydrate-based star polymers.
Kazuyuki Hattori*, Takashi Yoshida,
Taichi Shiga
835. Synthesis and property of well-defined
PEG-b-hyperbranched polyamide.
Yoshihiro Ohta, Teruaki Kanoh,
Akihiro Yokoyama, Tsutomu Yokozawa*
836. Functional group conversion of diols via
dehydration polycondensations with a dicarboxylic acid containing a disulfide linkage. Yuka Sato, Akinori Takasu
837. Synthesis and characterization of welldefined “click polyesters”. Yu Nagao*,
Akinori Takasu
838. Green and flexible process for hydrogenation of nitrile butadiene rubber. Yin Liu,
Qinmin Pan, Garry L. Rempel
Saturday Afternoon
Convention Center
325B
NMR Spectroscopy of Polymers: Innovative
NMR Strategies for Complex
Macromolecular Systems (#12)
Organized by: T. Asakura, H. N. Cheng,
A. English, F. Horii, P. Macdonald,
H. Spiess, J. White, A. Whittaker
Presiding: A. English
12:30 – 839. Solid-state NMR study of nanofibers. Kazuhiko Yamada*
13:00 – 840. NMR studies of nanoparticle
dispersion and morphology in polymeric
nanocomposites. Bo Xu,
Johannes Leisen, Ute Boehme,
Ulrich Scheler, Haskell W. Beckham
13:30 – 841. Characterization of surfacemodified titania nano-particles by solidstate nuclear magnetic resonance.
Hiroyuki Souma, Ryo Chiba,
Shigenobu Hayashi*
14:00 – 842. Corona dynamics in nanoscale
ionic materials. Peter A. Mirau*,
Mike Jespersen, Richard A. Vaia,
Robert Rodriquez,
Emmanuel P. Giannelis,
Ernst von Meerwall
14:30 – 843. Ideal chain packing and mobility and their relationships to structural organization and properties of semi-crystalline polymers. Toshikazu Miyoshi
15:00 – 844. Probing the conformations and
motions of solid polymers with NMR.
Alan E. Tonelli*
15:30 – 845. Elucidation of the backbone
conformation in polyfluorene in different
phases by solid-state NMR.
Hironori Kaji*, Tatsuya Fukushima,
Yohei Kiuchi, Atsushi Goto
16:00 – 846. Solid state NMR studies of
structure and dynamics in polyethylene
precisely functionalized with carboxylic
acid groups. Todd M. Alam*,
Michelle E. Seitz, Francisco Buitrago,
Karen I. Winey, Christopher D. Chan,
Kathleen L. Opper, Travis W. Baughman,
Kenneth B. Wagener
Convention Center
328
Biodegradable and Biomass Plastics (#95)
Organized by: H. Uyama, G.G. Chen,
S.S. Im, T. Iwata, C. Nomura
Presiding: H. Uyama, C. Nomura
12:30 – 847. Microbial production and biodegradation of polyhydroxyalkanoates.
Yoshiharu Doi*
13:00 – 848. Biomass carbon ratio of biomass plastics determined by accelerator
mass spectroscopy. Masao Kunioka*,
Masahiro Funabashi
13:30 – 849. Agriculturally-based bioproducts. Gregory M. Glenn*, William J. Orts,
Artur P. Klamczynski, Delilah Wood,
Syed Imam, Bor-Sen Chiou
13:50 – 850. Mechanism of enzymatic degradation of poly(hydroxybutyrate) as revealed by kinetics of its depolymerase
mutants. Tomohiro Hiraishi*,
Mizuo Maeda
14:10 – 851. In vitro crystallization of poly (3hydroxybutyrate) granules in biopolyester
recovery and purification. Jian Yu*,
Michael Porter
14:30 – 852. Controlled radical (co)polymerization of renewable vinyl monomers for
novel biobased polymers. Kotaro Satoh,
Kanji Nagai, Masami Kamigaito
14:50 – 853. Synthesis and degradation of
polymers derived from malic acid.
Andrew Dove*, Ryan Pounder,
Michael Bennison
15:10 – 854. Bio-based and biodegradable
silk protein-bacterial polyester hybrid materials. Keiji Numata*, Yoshiharu Doi
15:30 – 855. Progress of PBS copolymer research, development and industrialization. Jun Xu*, Baohua Guo
16:00 – 856. Aliphatic polyesters crosslinked by reversible bonds: Remendability
and thermo-responsibility.
Naoko Yoshie, Mariko Watanabe,
Hitomi Araki, Kazuki Ishida
13:25 – 859. Fddd phase boundary of polystyrene-block-polyisoprene diblock copolymer melts. Mikihito Takenaka*,
Myung Im Kim, Kuniaki Matsuda,
Hirokazu Hasegawa
13:45 – 860. Self-assembling dendritic block
copolymers. Byoung-Ki Cho*
14:05 – 861. Cyclodextrin-based ordered
materials through self-organization.
Akira Harada*
14:30 – 862. Stimuli-responsive smart hybrid
capsules prepared via layer-by-layer assembly. Kiyofumi Katagiri*, Yuji Imai,
Masato Nakamura, Atsunori Matsuda,
Kunihito Koumoto
14:50 – 863. Formation of self-organized calcium phosphate crystals through gel-mediated processing. Chikara Ohtsuki*,
Taishi Yokoi, Koichi Kikuta,
Masakazu Kawashita
15:10 – 864. Chirality in mesoporous materials: The sergeants and soldiers effect in
solid materials. Cathleen M. Crudden*
15:35 – 865. Selective synthesis of four polymorphs of TiO2 and their morphology
control using water-soluble titanium complex. Koji Tomita*, Kazuhiro Yamamoto,
Toru Sasaki, Valery Petrykin,
Makoto Kobayashi, Masato Kakihana
15:55 – 866. Self assembly in hybrid organic-inorganic cluster systems.
Leroy Cronin*
Convention Center
321A
Synthesis, Structure, and Physical
Properties of Advanced Polymer Gels (#136)
Organized by: K. Ito, M. Sibayama,
R. Siegel, C. Wu
Presiding: K. Ito, M. Shibayama
12:30 – 867. Peptide-directed self-assembly
of hybrid hydrogels. Jindrich Kopecek,
Jiyuan Yang
13:00 – 868. New frontiers of polymer gels
swollen by ionic liquids.
Masayoshi Watanabe*, Takeshi Ueki
13:30 – 869. Redox active nanogel transfer
between ionic liquid and water.
Takeshi Ueki, Masayoshi Watanabe
13:45 – 870. Polysaccharide nanogel bottom-up systems for biomedical application. Kazunari Akiyoshi*
14:15 – 871. Stimuli-responsive thin hydrogel films. Sergiy Minko
14:45 – 872. Using environmentally responsive gels for soft machinery: A physicist
approach. Eran Sharon*
15:15 – 873. Nonvolatile full color block copolymer photonic gels.
Youngjong Kang*, Eunjoo Kim,
Changjoon Kang, Daehyun Kim,
Jaeyon Kim
15:45 – 874. Structural colored soft materials
without angle dependence.
Yukikazu Takeoka
16:00 – 875. Small-angle neutron scattering
on Tetra-PEG gels.
Mitsuhiro Shibayama,
Takuro Matsunaga, Takamasa Sakai,
Yuki Akagi, Ung-il Chung
Convention Center
321B
Molecular-Based Ordered Materials
Formed Through Self-Organization (#102)
Organized by: T. Kato, M. Francis,
D. Gin, X. Guo, H. Kikuchi, C. Nuckolls
Presiding: C. Nuckolls, M. Francis,
X. Guo, T. Kato
12:30 Introductory remarks
12:35 – 857. Polycatenation under kinetic
and thermodynamic control.
Fraser Stoddart, Mark A. Olson,
Lei Fang, Ali Coskun, Ashish N. Basuray
13:00 – 858. Supramoelcular amphiphiles for
controlled self-assembly. Xi Zhang,
Chao Wang, Zhiqiang Wang
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–107
03-MACR
Convention Center
313A
Frontiers of Precisely Controlled Polymer
Synthesis: Fine Control of Polymerization
Reaction and Impact on Advanced Material
Designs (#257)
Organized by: T. Kitayama, S. Aoshima,
M. Kamigaito, G. Moad, J. Puskas
Presiding: T. Kitayama, F. Sanda,
E. Chen, M. Kamigaito
12:30 – 876. Stereochemically and chiroptically controlled polar vinyl polymers by
coordination polymerization.
Eugene Y. Chen
13:00 – 877. Coordination copolymerization
of ethylene with vinyl acetate and allyl acetate. Shingo Ito, Kagehiro Munakata,
Masafumi Kanazawa, Kyoko Nozaki*
13:20 – 878. Effect of ring incorporation on
chain topology of ethylene-cyclopentene
copolymers. Shawn Morgan, Zhibin Ye*,
Ramesh Subramanian
13:40 – 879. Polymerization of diazocarbonyl
compounds initiated with (NHC)Pd/borate systems. Eiji Ihara*
14:10 – 880. Controlled polymerization of
acetylenic monomers catalyzed by late
transition metal complexes.
Masashi Shiotsuki*, Naoya Onishi,
Fumio Sanda, Toshio Masuda
14:30 – 881. Phenylenevinylene homopolymers and block copolymers by ringopening metathesis polymerization.
Michael L. Turner*, Chin Y. Yu,
David G. Lidzey, James Kingsley,
Simon King, Saif A. Haque, Jenny Nelson
14:50 – 882. Ring-opening metathesis block
and alternating copolymerizations of
amino acid functionalized norbornene
monomers. Fumio Sanda*,
Sutthira Sutthasupa, Masashi Shiotsuki,
Toshio Masuda
15:20 – 883. Ring-opening polymerization of
␻-pentadecalactone by highly active rare
earth tetrahydroborates.
Yuushou Nakayama*, Naoki Watanabe,
Kenta Sasaki, Zhengguo Cai,
Takeshi Shiono*
15:50 – 884. Towards ultrahigh molecular
weight polycaprolactone with hydrozirconation derived alkoxides.
Alexandru D. Asandei, Gobinda Saha,
Olumide Adebolu,
Christopher P. Simpson
16:10 – 885. Reexamination of the reactivity
of amino acid N-carboxy anhydrides (38):
Preparation of monodispersed high molecular weight polypeptides by the polymerization of amino acid N-carboxy anhydrides. Hitoshi Kanazawa*
Convention Center
322AB
Functional Block Copolymer Assemblies
(#57)
Organized by: T. Lodge, J. Bang, C. Han,
M. Hillmyer, Y. Matsushita
Presiding: Y. Matsushita
12:50 – 886. Functional nanomaterials based
on nanoporous block copolymer templates. Seung Yun Yang, Wonchul Joo,
Jeong In Lee, Ara Jo, Jin Kon Kim*
13:20 – 887. Block copolymer micelles with
nanoparticles and fluorophores.
Byeong-Hyeok Sohn*
13:50 – 888. Swelling induced order-order
transitions of block copolymers in supercritical carbon dioxide and fabrication of
nanocellular and porous thin films.
Hideaki Yokoyama*, Masateru Ito,
Yasuhiro Sakai, Kohzo Ito,
Kenji Sugiyama
14:10 – 889. Separation membranes from
multifunctional block polymers.
Marc Hillmyer*
14:30 – 890. Fabrication and selective permeation of micropase-separated freestanding membrane with visualized transport channels. Taro Kimura*,
Shingo Hadano, Motonori Komura,
Tomokazu Iyoda
108 –TECH
TECHNICAL PROGRAM
14:50 – 891. Block copolymer modified epoxies - extraordinary toughness at no
cost. Frank S. Bates*
15:20 – 892. Micro phase separation of polyrotaxane. Kohzo Ito*, Hideaki Yokoyama
15:50 – 893. Nanoporous thin-film membranes from block-polymers: Using selfconsistent field theory calculations to
guide polymer synthesis.
Joseph G. Cordaro*, Edward H. Feng,
Gregory O’Bryan, Amalie L. Frischknecht,
Geoffrey L. Brennecka, Michael S. Kent
16:10 – 894. Block-copolymer-templated
electropolymerization for conducting
polymer nanowires. Hideaki Komiyama,
Motonori Komura, Keiji Nagai,
Tomokazu Iyoda, Kaori Ito*
Convention Center
302AB
Nano Structure and Function of OrganicInorganic Hybrid Polymers (#152)
Organized by: K. Matsukawa, C.S. Ha,
F. Jaekle, K. Naka, I. Tomita
Presiding: K. Matsukawa
12:50 Introductory remarks
12:55 – 895. Organic-inorganic polymer
nano-hybrids based on sol-gel reaction.
Yoshiki Chujo*
13:25 – 896. Thermally stable transparent
sol-gel synthesized siloxane hybrid materials for LED encapsulation.
Byeong-Soo Bae*, Joon-Soo Kim,
SeungCheol Yang
13:45 – 897. Synthesis and properties of organoarsenic polymers via bismetallation
of acetylenic compounds.
Kensuke Naka*, Takuji Kato,
Tatsuo Shimamoto, Manabu Arita,
Yasuhiro Morisaki, Yoshiki Chujo
14:05 – 898. Nanostructure and function of
block copolymer-inorganic hybrid materials. Ulrich (Uli) Wiesner*
14:25 – 899. Preparation of inorganic-organic hybrids using inorganic nanosheets
as nano-building blocks.
Yoshiyuki Sugahara*
14:45 – 900. Organic-inorganic hybrid organosilicate polymers for nanoelectronics
and optoelectronics. Do Y. Yoon*
15:05 – 901. High refractive index hybrid materials from bis-phenyl fluorene derivatives. Kimihiro Matsukawa*,
Takuma Yoshimoto, Noboru Nishioka,
Seiji Watase
15:25 – 902. Hole injection/transport materials derived from Heck and sol-gel chemistry for application in solution processed
organic electronic devices.
Yerang Kang, Younhee Lim,
Young-Seo Park, Do Young Jang,
Joo Hyun Kim, Jang-Joo Kim,
Alan Sellinger, Do Y. Yoon*
15:45 – 903. Preparation of ladder-like polysilsesquioxanes forming chiral conformations and hexagonal stacking structures. Yoshiro Kaneko*, Nobuo Iyi
16:00 – 904. Polymeric micelles with pending pair-wise carboxylate groups afforded
via thiol-ene and -yne “click” chemistry
for cis-platinum drug delivery.
Vien T. Huynh, Gaojian Chen,
Paul D. Souza, Martina Stenzel*
16:15 – 905. Formation of redox-active metallopolymers on electrodes by a layer-bylayer molecular fabrication method.
Katsuhiko Kanaizuka,
Takuya Nakabayashi, Miyabi Sannodo,
Sono Sasaki, Masa-aki Haga*
Convention Center
323A
Controlled/Living Radical Polymerization in
Dispersed Systems (#160)
Organized by: M. Okubo,
M. Cunningham, J. Schork, P. Zetterlund
Presiding: P. Zetterlund, M. Cunningham
12:50 – 906. Atom transfer radical polymerization (ATRP) in dispersed media.
Krzysztof Matyjaszewski*
13:30 – 907. Preparation of Poly(acrylic acid)
by atom transfer radical polymerization in
supercritical carbon dioxide.
Hideto Minami, Atsushi Tanaka,
Yasuyuki Kagawa, Masayoshi Okubo*
13:50 – 908. Metal oxide accelerated atom
transfer radical polymerization of PEO
macromonomer. Kaoru Adachi,
Yasuhisa Tsukahara*
14:10 – 909. Core-functionalized designer
star polymers via living radical polymerization: Microgel-core reaction vessel toward living radical polymerization and catalysis. Takaya Terashima,
Mitsuo Sawamoto
14:30 – 910. Preparation of “mushroom-like”
nonspherical polymer particles by controlled/living radical polymerization in
aqueous dispersed systems.
Takuya Tanaka, Nobuko Fukami,
Hideto Minami, Masayoshi Okubo*
14:50 – 911. Functional microspheres having
designed shell layers.
Haruma Kawaguchi*
15:30 – 912. Preparation of block copolymer
particles by emulsifier-free, organotellurium-mediated living radical emulsion polymerization. Yukiya Kitayama,
Kazuya Kishida, Hideto Minami,
Masayoshi Okubo*
15:50 – 913. Living radical polymerization
with organic redox (pseudo-redox) catalysts. Atsushi Goto*, Yoshinobu Tsujii,
Takeshi Fukuda, Hironori Kaji
16:10 – 914. Structure-colored self-assembled colloidal gel consisting of polymergrafted silica nanoparticle and ionic liquid. Tomomi Nagatsuka,
Kazuhide Ueno, Tomohiro Yasuda,
Masayoshi Watanabe
Convention Center
323B
Biomimetic Engineering of Hierarchically
Structured Polymer Materials (#126)
Organized by: M. Shimomura, T. Iyoda,
D. Pochan, M. Winnik
Presiding: M. Shimomura
13:00 Introductory remarks
13:10 – 915. Superhydrophobic metal-polymer hybrid surfaces having wettability
gradients prepared by self-organization.
Daisuke Ishii*, Hiroshi Yabu,
Masatsugu Shimomura
13:40 – 916. Block copolymer-inspired multiple morphologies from self-assembly of
amphiphilic polymer-stabilized quantum
dots. Matthew G. Moffitt*, Yunyong Guo
14:20 – 917. Large-scale ordering of a graft
polymer toward photomechanical function. Nobuhiko Hosono, Takashi Kajitani,
Takanori Fukushima, Takuzo Aida
14:50 – 918. Application of bio-inspired design in the development of a medical device. Susan E. Burke*, Vicki L. Barniak,
Krista M. Fridman, Catherine A. Scheuer,
Srini Venkatesh
15:20 – 919. Patterning of superhydrophobic
and superhydrophilic nanostructured silicon surfaces by UV-O3 treatment.
Yuji Hirai*, Hiroshi Yabu,
Yasutaka Matsuo, Kuniharu Ijiro,
Masatsugu Shimomura*
Saturday Evening
20:20 – 922. Recent developments in solution NMR of polymers. Peter L. Rinaldi*
Convention Center
322AB
Functional Block Copolymer Assemblies
(#57)
Organized by: T. Lodge, J. Bang, C. Han,
M. Hillmyer, Y. Matsushita
Presiding: T. Lodge
19:00 – 923. Improvement on the thermostability of a polymer micelle via topology effects. Satoshi Honda,
Takuya Yamamoto*, Yasuyuki Tezuka*
19:20 – 924. Critical micelle temperatures
and micelle core glass transition temperatures: Fluorescence studies of block copolymer-solvent systems.
Christopher M. Evans,
Jonathan D. Saathoff,
Kevin J. Henderson, Kenneth R. Shull,
John M. Torkelson
19:40 – 925. Interchain hydrogen-bonding
and co-nonsolvency effect of block polymers in aqueous or mixed aqueous solvents. Charles C. Han, Jinkun Hao,
Guangcui Yuan, He Cheng
20:00 – 926. Control of nano-/micron-sized
structures in aqueous media through the
polyion complex formation of water-soluble block copolymers.
Akihiro Kishimura*, Hiroyuki Matsuda,
Yasutaka Anraku, Yuichi Yamasaki,
Kazunori Kataoka
20:20 – 927. Synthesis of block copolymers
containing pyridine moiety and their selfassembly. Nam-Goo Kang,
Beom-Goo Kang, Jae-Suk Lee*
20:40 – 928. Chemical composition distribution in block copolymers.
Chang Yeol Ryu*
Convention Center
Kamehameha Halls II and III
Molecular-Based Ordered Materials
Formed Through Self-Organization (#102)
Organized by: T. Kato, M. Francis,
D. Gin, X. Guo, H. Kikuchi, C. Nuckolls
Presiding: C. Nuckolls, H. Kikuchi,
D. Gin, M. Francis, X. Guo, T. Kato
Poster Session
19:00 – 21:00
929. Orientational control of the organic/inorganic hybrid materials through approaches inspired by biomineralization.
Tatsuya Nishimura, Takashi Kato*
930. Appearance and electro-optical properties of blue phases using dual frequency
liquid crystals. Gihwan Lim*,
Hiroki Higuchi, Yasushi Okumura,
Hirotsugu Kikuchi
931. UCST-type phase separation of polymers with pendant imidazolium salts in
aqueous media and synthesis of double
thermoresponsive block copolymers.
Hayato Yoshimitsu*,
Shokyoku Kanaoka, Sadahito Aoshima
932. Enhancement of enantioselectivity of
asymmetric hydrogenation of an enamide
using molecular imprinting and BSA.
Sean X. Liu*, Steven Bernard,
Justine Lee
Convention Center
325B
NMR Spectroscopy of Polymers: Innovative
NMR Strategies for Complex
Macromolecular Systems (#12)
Organized by: T. Asakura, H. N. Cheng,
A. English, F. Horii, P. Macdonald,
H. Spiess, J. White, A. Whittaker
Presiding: H. Cheng
19:00 – 920. Solid state NMR methods for
studying polymer dynamics.
Hans W. Spiess*
19:40 – 921. Use of the pulsed-field-gradient
method to study diffusion in polymer systems. Ernst D. von Meerwall*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR
933. The (substituted methylene)-type side
chain liquid-crystalline polymers: Part 1.
Jun Mikami*, Nozomu Fujii,
Kazuhiro Shikinaka, Masatoshi Tokita,
Junji Watanabe, Kiyotaka Shigehara
934. Highly ordered structures in polymeric
thin films prepared by vapor deposition
polymerization. Takaya Ito*,
Nozomi Yamamoto, Katsunori Inaishi,
Taisuke Kumagai, Atsushi Kubono*
935. Mechanical stimuli-induced change in
photoluminescent color of liquid crystals.
Yoshimitsu Sagara, Takashi Kato*
936. The (substituted methylene)-type side
chain liquid-crystalline polymers: Part 2.
Jun Mikami*, Nozomu Fujii,
Kazuhiro Shikinaka, Masatoshi Tokita,
Junji Watanabe, Kiyotaka Shigehara
937. Immobilization of bio-molecule onto the
self-assembled phospholipid layer fabricated by plasma-assisted method and its
activity evaluation. Shin-ichi Kondo*,
Takako Hiruma, Yasushi Sasai,
Yukinori Yamauchi, Masayuki Kuzuya
938. One-pot synthesis of TiO2 hollow
spheres via a ligand etching process.
Quang-Duc Truong*,
Makoto Kobayashi, Hideki Kato,
Masato Kakihana
939. Magnetite synthesis by mimic peptides
from the Mms6 protein of magnetotactic
bacteria. Atsushi Arakaki,
Tadashi Matsunaga*
940. Self-assembling processes and sol-gel
transition of 12-hydroxystearic acid and
12-hydroxystearate solutions.
Hiroyuki Takeno*, Akiko Maehara,
Tomonori Hosoyama, Norimasa Nomura,
Shingo Kondo
941. Fabrication of conjugated azomethine
compounds on metal oxide surface.
Hirotaka Yonai*, Hideyuki Murata
942. Influence of elastic constants of host
liquid crystal upon blue phases.
Mine Keita*, Hiroki Higuchi,
Yasushi Okumura, Hirotsugu Kikuchi
943. Morphological and orientational control
of transition metal hydroxides by using
soluble polymers and organic matrices.
Satoshi Kajiyama, Yuya Oaki,
Tatsuya Nishimura, Takashi Kato*
944. Cyclo-dipeptides derivatives as ubiquitous gelling agent. Young-Hwan Jeong,
Jung-A Kim, Woo-Dong Jang*
945. Mesoporous silica film with vertical
alignment by assist of interactions between substrate surface and molecules.
Mitsuo Hara, Shusaku Nagano,
Takahiro Seki*
946. Hydrogen-bond-oriented diversification
of self-assembled oligothiophene nanoarchitectures. Shiki Yagai,
Marina Gushiken, Yoshihiro Kikkawa,
Takashi Karatsu, Akihide Kitamura
947. Synthesis and photocatalytic properties
of Brookite-type TiO2 thin film.
Toru Sasaski*, Kazyhiro Yamamoto,
Koji Tomita, Yasuyuki Miura,
Makoto Kobayashi, Masato Kakihana
948. Synthesis and water-splitting activity of
NaTaO3 photocatalyst using a hydrothermal method and a solvothermal method.
Yuma Matsumoto*, Koji Tomita,
Yoshika Sekine, Masato Kakihana
949. Hydrothermal growth of NaLa(WO4)2:
Er3⫹/Yb3⫹ microcrystals with controlled-morphology and up-conversion
luminescent properties.
Takuro Kidokoro, Takaaki Taniguchi,
Ken-ichi Katsumata, Kiyoshi Okada,
Nobuhiro Matsushita, Katsuya Tsujiuchi,
Kohei Soga, Koji Tomita
950. Preparation and photocatalytic activity
of TiO2 thin films using water-soluble titanium complexes. Yukiaki Ono,
Kazuhiro Yamamoto, Koji Tomita,
Masato Kakihana, Munenori Sakai,
Akira Nakajima, Akira Fujishima,
Ken-ichi Katsumata,
Nobuhiro Matsushita, Kiyoshi Okada
951. New class of low-molecular-weight gelators that can harden water, organic solvents, edible oil, and ionic liquids.
Nami Minakuchi, Tatsuo Maruyama*,
Kazuki Hoe, Yoshikage Ohmukai,
Hideto Matsuyama*
952. Dependence of the initial growth on
functional groups of substrate during organic vapor deposition. Masaaki Kino*,
Kiyoshi Hagihara, Takaya Ito,
Atsushi Kubono*
953. Ion-induced self-assemblies of discotic
block codendrimers. Jin-Woo Choi*,
Byoung-Ki Cho
954. Synthesis of fluorine-containing vinyl
ether polymers by living cationic polymerization and their UCST-type phase separation behavior. Dai Fukami,
Hiroaki Shimomoto, Takabumi Nagai,
Ken-ichi Katsukawa, Shokyoku Kanaoka,
Sadahito Aoshima*
955. 1-D nanostructured materials consisting of noncovalently linked molecular
chains build by ammonium hydroxycarboxylates. Yuki Konuma,
Yusuke Yoshida, Akihiko Kanazawa*
956. Synthesis and properties of fluorinated
binaphthyl chiral dopants.
Kota Kakisaka*, Hiroki Higuchi,
Yasushi Okumura, Hirotsugu Kikuchi
957. Diffusion behavior of polymers upon
photopolymerization process in chiral
nematic phases. Kim Hyojin*,
Higuchi Hiroki, Okumura Yasushi,
Higashiguchi Kenji, Kikuchi Hirotsugu
958. Two modes of asymmetric polymerization of phenylacetylenes having an
L-amino alcohol residue. Jia Hongge*,
Abe Yunosuki, Teraguchi Masahiro,
Aoki Toshiki*, Kaneko Takashi,
Ohishi Tomoyuki, Kakihana Yuriko
959. Structure and electro-optic response of
liquid crystal blue phases and polymerstabilized blue phases.
Hirotsugu Kikuchi*, Hiroki Higuchi
960. Ion-conductive polymer films with 3-D
ion nanochannels formed by liquid-crystalline ammonium salts.
Takahiro Ichikawa, Masafumi Yoshio,
Atsushi Hamasaki, Junko Kagimoto,
Hiroyuki Ohno, Takashi Kato*
961. Chiral nematic phases induced by redox activite chiral dopants.
Tomohiro Horinouchi*, Hiroki Higuchi,
Yasushi Okumura, Takanori Suzuki,
Hirotsugu Kikuchi
962. Discotic liquid crystals constructed by
hierarchical self-assembly of rod-like diacetylene molecules. Tomoyo Shimogaki,
Akikazu Matsumoto*
963. Hydrothermal synthesis of multineedle
rutile and brookite type titanium dioxide
nanostructures using novel water-soluble
titanium complexes. Makoto Kobayashi,
Koji Tomita, Valery Petrykin,
Masato Kakihana
964. Charge-transfer complex formation of
linear-shaped molecules having intramolecular electron-donor-acceptor interaction. Hiroki Higuchi*, Yoko Tanaka,
Hirotsugu Kikuchi
965. Ion conducting nanomaterials selfformed by aliphatic amine hydrochlorides
showing a columnar liquid-crystalline
property. Nobuaki Takahashi,
Yuki Konuma, Koki Saito,
Akihiko Kanazawa*
Convention Center
Kamehameha Halls II and III
Controlled/Living Radical Polymerization in
Dispersed Systems (#160)
Organized by: M. Okubo,
M. Cunningham, J. Schork, P. Zetterlund
Presiding: P. Zetterlund, M. Cunningham
Poster Session
19:00 – 21:00
966. Preparation of polymer particles with
encapsulated hexadecane as heat storage materials by microsuspension ATRP
in aqueous dispersed system.
Toyoko Suzuki, Tsugumi Mizowaki,
Masayoshi Okubo*
967. Nanoparticle synthesis by nitroxide-mediated radical polymerization of CO2-expanded monomer. Da Wei Pu,
Frank P. Lucien, Per B. Zetterlund*
968. Compartmentalization in nitroxide-mediated radical polymerization of butyl acrylate in dispersed systems.
Per B. Zetterlund*
969. Confined space effect in nitroxide-mediated radical polymerization of n-butyl
acrylate in microemulsion.
Seita Tomoeda, Junpei Wakamatsu,
Per B. Zetterlund, Masayoshi Okubo*
970. Effect of stirring rate on emulsifier-free,
organotellurium-mediated living radical
emulsion polymerization of styrene.
Hirotaka Moribe, Yukiya Kitayama,
Masayoshi Okubo*
971. Preparation of cross-linked polymer
particles with encapsulated liquid crystal
by microsuspension polymerization utilizing the SaPSeP method.
Naoko Takenokuma, Toyoko Suzuki,
Masayoshi Okubo*
972. Preparation of high solids content emulsion by emulsifier-free, organotelluriummediated living radical emulsion polymerization. Yukiya Kitayama, Shogo Sasaki,
Hideto Minami, Masayoshi Okubo*
973. Withdrawn
974. Preparation of novel polymer particles
as photolatent multifunctional amines
and their application to UV-curing materials. Yuka Kunisawa, Koji Arimitsu*,
Yasuyuki Yamada, Takeshi Wakiya
Convention Center
Kamehameha Halls II and III
Amphiphilic Polymers: Fundamentals and
Applications (#231)
Organized by: T. Sato, K. Akiyoshi,
C. McCormick, F. Winnik
Presiding: T. Sato
Poster Session
19:00 – 21:00
975. Helix-coil transition and association behavior of hydrophobically-modified water-soluble polypeptides.
Katsuhiro Inomata*
976. Normally oriented cylindrical nanostructures with high aspect ratios in amphiphilic PEO-LC diblock copolymers films.
Sadayuki Asaoka*, Takayuki Uekusa,
Hitomi Tokimori, Motonori Komura,
Takeshi Yamada, Hirohisa Yoshida,
Tomokazu Iyoda
977. Photoresponsive association behavior
of leuco dye-containing polyanion.
Shouta Kousaka, Shin-ichi Yusa,
Morishima Yotaro
978. Temperature-responsiveness of amphiphilic block copolymer micelle containing poly(n-octadecyl acrylate).
Yusuke Akino*, Hiroyasu Masunaga,
Hiroki Ogawa, Isamu Akiba,
Kazuo Sakurai
979. Phase transition dynamics of thermoresponsive polymers in aqueous solutions as revealed by a laser T-jump technique. Kanae Kikuchi*,
Noboru Kitamura, Hiroaki Simomoto,
Shokyoku Kanaoka, Sadahito Aoshima,
Yasuyuki Tsuboi
980. Thermally induced morphology change
of thermoresponsive block copolymer micelles in aqueous solution.
Kohei Tanaka, Takahiro Sato*,
Shin-ichi Yusa
981. Acid labile self-assembled nanogel by
hydrophobized polysaccharide for drug
carrier. Nobuyuki Morimoto,
Sayaka Hirano, Haruko Takahashi,
David H. Thompson*, Kazunari Akiyoshi*
982. Nanogel formation of vitamin B6-bearing pullulan cross-linked with water soluble proteins. Yoshihiro Sasaki,
Yuji Tsuchido, Kazunari Akiyoshi*
983. Synthesis of biocompatible and
thermo-responsive polymer micelles
cross-linked by gold nano particle.
Fumi Goto, Yusa Shin-ichi,
Morishima Yotaro, Ishihara Kazuhiko
984. Tacticity effect on the intra- and intermolecular interaction of poly(2-hydroxyethyl methacrylate). Misato Yamamoto
985. Synthesis of specialty polyethylene by a
titanium-poss-ethylaluminum sesquichloride based catalysts system.
Akshay M. Mehta, Gopal L. Tembe,
Parimal A. Parikh, Girish N. Mehta
986. Aggregation of surfactant with virus-like
particle. Megumi Sakou,
Takayoshi Kawahara,
Takemasa Sakaguchi, Isamu Akiba*
987. Effect of surfactant concentrations on
rheological properties of HEC. Jun Ye,
Yang-ming Chen, Mei-Jun Chen,
Jian Xiong*
988. Sol-gel transition and microstructure of
PLA-PEG amphiphilic copolymer aqueous solutions. Yeon Hung Oh,
Hye-Jin Jeon, Le Lam Ngo,
Hyun Hoon Song
989. Nano-encapsulation of lipase with amphiphilic polysaccharide nanogel.
Shin-ichi Sawada, Setsuko Yamane,
Kazunari Akiyoshi
990. Dependence of drying induced crack
patterns on ionic groups in partially neutralized poly(styrene-ran-methacrylic
acid) ionomers. Jeong-A Yu*,
Kwang-Hwan Ko, Joon-Seop Kim
991. CpG DNA delivery by cationic amphiphilic polysaccharide nanogels.
Junichi Yasuoka, Sayaka Toita,
Shin-ichi Sawada, Kazunari Akiyoshi*
992. Regiospecific accumlation of porphyrins at the normally oriented cylindrical
microphase segregation interface in the
liquid crystalline amphiphilic block copolymer film. Masashi Aotani,
Motonori Komura, Tomokazu Iyoda,
Sadayuki Asaoka*
993. Molecular mobility of cellulose chains
affected by interactions of entanglement
points in solution. Ayaka Maeda*,
Daisuke Tatsumi
994. Micellar structure of amphiphilic statistical and alternating copolymers in aqueous solution. Takahiro Sato*,
Motoki Ueda, Mari Mizuse,
Akihito Hashizdume
Convention Center
323C
Frontiers of Precisely Controlled Polymer
Synthesis: Fine Control of Polymerization
Reaction and Impact on Advanced Material
Designs (#257)
Organized by: T. Kitayama, S. Aoshima,
M. Kamigaito, G. Moad, J. Puskas
Presiding: T. Kitayama, J. Puskus
19:00 – 995. Green polymer chemistry: Precision synthesis of novel dendrimers using enzyme catalysis. Judit E. Puskas,
Kwang Su Seo, Chrys Wesdemiotis,
Madalis Casiano
19:30 – 996. Orthogonal approaches to dendrimer synthesis. Maxwell J. Robb*,
Per Antoni, Luis M. Campos,
Maria I. Montanez, Michael Malkoch,
Eva Malmstrom, Craig J. Hawker
19:50 – 997. Synthesis of multicyclic polymers. Takuya Yamamoto*, Naoto Sugai,
Hiroyuki Heguri, Yasuyuki Tezuka*
20:10 – 998. Synthesis of novel polymers
containing adamantyl skeletons.
Takashi Ishizone*
20:40 – 999. Block copolymer approach to
architectural polymers. Guojun Liu*,
Gabriel Njikang, Jiwen Hu, Hongjing Dou
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–109
03-MACR
Sunday Morning
Convention Center
Kamehameha Halls II and III
Macromolecular General Posters
Poster Session
10:00 – 12:00
Polyacrylamides
1000. Solution behavior of N-isopropylacrylamide copolymers: Effect of copolymer
structure. Yukihiko Inoue*, Koji Hoshino,
Kazufumi Ashizawa, Noritaka Ohtani
1001. Effect of composition on phase transition of aqueous solution of syndiotactic
N-alkylacrylamide copolymer.
Hiroaki Yamamoto, Tomohiro Hirano*,
Koichi Ute
1002. Low temperature radical polymerization of N-alkyl-␣-fluoroacrylamides.
Takahiro Furutani, Hiroaki Yamamoto,
Tomohiro Hirano, Koichi Ute
1003. Stereocontrol of radical polymerization
of N-methyl-N-(2-pyridyl)acrylamide utilizing conformational switching.
Akihiro Morikami, Tomohiro Hirano*,
Koichi Ute
1004. Asymmetric radical cyclopolymerization of N-allyl-N-tert-butylacrylamide in
the presence of tartrates.
Miki Shinomiya, Akihiro Morikami,
Tomohiro Hirano, Koichi Ute
1005. Synthesis and application of poly(vinyl
alcohol) having TEMPO unit in their pentant groups. Rikiya Sato, Yasuhiro Kiryu,
Yasuhiro Ikeda, Yosuke Tokiwa,
Shiomi Tazaki
1006. Living anionic polymerization of 2-(2(4-vinylphenyl)ethynyl)pyridine).
Beom-Goo Kang*, Nam-Goo Kang,
Jae-Suk Lee
1007. Living anionic polymerizations of styrene derivatives para-substituted with triphenylamine moieties.
Beom-Goo Kang*, Nam-Goo Kang,
Jae-Suk Lee
1008. Double covalent domino effect in
poly(n-hexyl isocyanate). Priyank Shah*,
Beom-Goo Kang, Jae-Suk Lee
1009. Pd(0)-catalyzed polycondensation of
aryl-substituted propargylic carbonates
and nucleophiles. Noriyuki Nishioka,
Toshio Koizumi
1010. Comparison of diverse oxy anionic initiators for anionic polymerization of
n-hexyl isocyanate. Joon-Keun Min*,
Priyank N Shah, Da-Young Kim,
Jae-Suk Lee
1011. Effects of polar compounds on the
monomer reactivity ratio and stereoregularity in radical copolymerization of
(meth)acrylates. Seiko Asakawa,
Norihito Koga, Hikaru Momose,
Tomohiro Hirano, Koichi Ute*
1012. Creation and evaluation of new deoxygenation system. Rikiya Sato,
Yusuke Mori
1013. Thin polymer films prepared by interfacial click reaction. Shuhei Kai,
Md. Ashaduzzaman, Masashi Kunitake*
Engineering and bio materials
1014. Effect of ion-exchange capacity (IEC)
on the proton conductivity of perfluorosulfonic ionomers (PFSI). Xiaoyan Luo,
Timothy J. Peckham, Zhi qing Shi,
Yongming Zhang, Steven Holdcroft*
1015. Synthesis of organosoluble polyimides
and their functionalization: Incorporation
of triphenylamine units into the polymer
main and/or side chain.
Yasuo Saegusa*, Hideo Takazawa
1016. Sulfonated polybenzimidazoles as
proton exchange membranes and acidbase cross-linkers. Kristen J. Soo,
Owen D. Thomas, Timothy J. Peckham,
Uma Thanganathan, Yunsong Yang,
Steven Holdcroft*
1017. Crosslinkable sulfonated poly(arylene
ether)s containing PFCB.
Myung-Hwan Jeong*, Kwan-Soo Lee,
Young-Jea Kim, Da-Young Kim, Un Ko,
Jae-Suk Lee
110 –TECH
TECHNICAL PROGRAM
1018. High-performance poly(biphenylene
oxide)s containing trifluoromethyl groups
via nitro displacement reaction.
Sun Dal Kim, Du Youn Ga,
Sang Youl Kim*, Im Sik Chung*
1019. Development of photosensitive polycarbonates with adamantane structures
based on negative-tone reaction development patterning. Sohei Yasuda,
Akio Takahashi, Toshiyuki Oyama*,
Shinobu Yamao
1020. Improvement in dyeability of a paraaramid fiber by electron beam graft polymerization. Norie Kitagawa*,
Kazumasa Hirogaki, Isao Tabata,
Kenji Hisada, Teruo Hori
1021. Study on polybenzoxazine modified
with epoxy resin. Mika Kagawa*,
Toshio Oyama, Akio Takahashi
1022. Study on the effect of high pressure
hydrogen on the higher order structure of
rubber materials by FT-IR spectroscopy.
Yuzo Itoh*, Ryota Satoh,
Tadatomo Kawai, Hirotada Fujiwara,
Junichiro Yamabe, Shin Nishimura
1023. Facile preparation of hybrid polymer
hydrogels using inorganic nanoparticles
as multifunctional crosslinking points.
Makoto Takafuji, Shin-ya Yamada,
Hirotaka Ihara*
1024. Remote substituent effect on the thermolysis of Meldrum’s moiety in polymer
matrix. Seungyun Lee, Frank Leibfarth,
Hyeyeon Park, Craig Hawker,
Bongjin Moon*
1025. Formation mechanism of silk fibroin
3D porous material by freeze-thaw process of fibroin-solvent mixture and controlling the pore size. Yasushi Tamada*,
Tsunenori Kameda, Yoshiyuki Toshima
Stimuli response
1026. Thermal- and pH- responsive polymers with elastin-like polypeptides containing an acidic amino acid.
Aiko Yamazaki, Yasumasa Fukushima*
1027. Thermal- and pH- responsive polymers with elastin-like polypeptides containing basic amino acids.
Shintaro Shoji, Yasumasa Fukushima*
1028. Thermal-responsive polymers with
collagen-like polypeptides. Shohei Iida,
Yasumasa Fukushima*
1029. pH- Responsive copolymers with alternating amphiphilic polypeptides to
form a well-ordered sheet structure.
Takuya Fuse, Yasumasa Fukushima*
1030. Optical properties of a conjugated
polyelectrolyte complexed with various
biopolymers in aqueous solution.
Yasuko Nakamura, Ryoko Kanenaga,
Han Y. Woo, Ken Terao, Takahiro Sato
Active polymer materials
1031. Donor/acceptor polythiophene block
copolymers containing perylene.
Takayoshi Uno, Yasumasa Fukushima*
1032. Donor/acceptor polyfluorene block
copolymers. Yoko Yamaguchi,
Yasumasa Fukushima*
1033. Designed synthesis of functional materials by palladium-catalyzed coupling
polymerization of thiophene derivatives
and aryl dihalides using C-H bonds as
polymerizable functions.
Shoichi Kawamitsu, Ikuyoshi Tomita
1034. Synthesis and characterization terthiophene derivatives for solution processed
otft. So Hee Kang, Dong Hee Lee,
Hyuon Hui Kang, Moon Seong Kang,
Dae Sung Chung, Chan Eon Park,
Soon-Ki Kwon, Yun-Hi Kim*
1035. Synthesis of substituted polyacetylenes with terphenyl moieties in the side
chain. Hideaki Sasaki
1036. Polyacetylene induced one-handed
helix by rotaxane molecular chirality in the
side chain. Fumitaka Ishiwari,
Yasuhito Koyama, Kazuko Nakazono,
Toshikazu Takata*
1037. Coupling process between solid-liquid
extraction and photocatalytic degradation in wastewater treatment.
Caroline Felix*, Florent Perret*,
Nathalie Pérol, Chantal Guillard
Convention Center
307AB
Starch
1038. Structural characterization of cyclic
amylose in solution. Yoshiaki Yuguchi,
Makoto Takemasa, Shinichi Kitamura
1039. Novel ternary super engineering plastic alloy: Poly(phenylene sulfide)/poly(ethylene-co-glycidyl methacrylate)/poly(phenyl sulfone). Saori Nara,
Hideko T. Oyama*, Motonobu Furuta,
Shigenari Shida
1040. Molecular structure of amylose allomorphs: Some recent advances.
Jean-Luc Putaux, Nicole Montesanti,
Dmitri Popov, Christian Riekel,
Gabrielle Véronèse, Alain Buléon,
Mateus Cardoso, Morgane Morin,
Yoshiharu Nishiyama, Karim Mazeau,
Henri Chanzy
1041. Glycodendrimers prepared by in vitro
enzymatic extension of glycogen surface
chains. Jean-Luc Putaux,
Gabrielle Véronèse, Alain Buléon
Organized by: T. Lodge, J. Bang, C. Han,
M. Hillmyer, Y. Matsushita
Presiding: C. Han
Characterizations
1042. Characterization of hyperbranched copolymer by means of multivariate analysis
of 13C NMR spectra. Ryota Kamiike,
Hikaru Momose, Tomohiro Hirano*,
Koichi Ute
1043. Structure and properties of uniaxially
stretched poly(L-lactic acid) (PLLA)/ poly(aspartic acid-co-L-lactide) (PAL) blend
films. Sakiko Hirai*, Hideko T. Oyama,
Hitoshi Onishi
1044. Analysis on molecular orientation in
the nematic ordered cellulose film with a
combined method of vapor-phase deuteration and polarized FTIR.
Yukako Hishikawa*, Eiji Togawa,
Tetsuo Kondo
Convention Center
325B
NMR Spectroscopy of Polymers: Innovative
NMR Strategies for Complex
Macromolecular Systems (#12)
Organized by: T. Asakura, H. N. Cheng,
A. English, F. Horii, P. Macdonald,
H. Spiess, J. White, A. Whittaker
Presiding: H. Spiess
7:30 – 1045. Dynamics of disordered structure of pi-conjugated polymers investigated by solid-state NMR.
Naoki Asakawa*, Yoshio Inoue,
Takakazu Yamamoto, Koji Yazawa*
8:00 – 1046. Polymer plasticizer interactions
by deuterium NMR. Frank D. Blum,
Boonta Hetayothin, Rakesh R. Nambiar
8:30 – 1047. Polymers under mechanical
stress: An NMR investigation.
Ute Böhme, Bo Xu, Johannes Leisen,
Haskell W. Beckham, Ulrich Scheler*
9:00 – 1048. Pulsed field gradient diffusion
NMR and morphology in magnetically
aligned bicelles. Peter M. Macdonald*
9:30 – 1049. Analysis of molecular motion of
rubbers under the fast MAS.
Atsushi Asano*, Shunsuke Hori,
Masashi Kitamura, Chikako Tanaka,
Takuzo Kurotsu
10:00 – 1050. Role of stereochemistry in diffusion of polypropylene: Comparison of
dynamic Monte-Carlo simulation and
NMR experiment.
Ernst D. von Meerwall*,
Numan Waheed, Wayne Mattice
10:30 – 1051. Molecular mobility and phase
composition in polyolefins: From fundamentals to applied research.
Victor Litvinov*
11:00 – 1052. NMR observations of polymer
chain dynamics in bulk melts and in
nanoscopic confinement.
Kay Saalwachter*, Fabian Vaca Chavez,
Cornelius Franz, Salim Ok,
Martin Steinhart
Functional Block Copolymer Assemblies
(#57)
7:30 – 1053. Design/synthesis of stimuli-responsive block copolymers for various
biomedical application. DooSung Lee,
GuangHui Gao
8:00 – 1054. Peptide-based block copolymers for biomedicine. Timothy Deming
8:30 – 1055. Monodisperse multifunctional
polymers for targeted therapeutics.
Sang-Min Lee, DeeDee Smith,
Archana Krovi, Thomas V. O’Halloran*,
SonBinh T. Nguyen*
8:50 – 1056. Drug incorporation into an amphiphilic polymer micelle explored with
synchrotron SAXS. Isamu Akiba*,
Satoshi Hashida, Hiroyasu Masunaga,
Hiroki Ogawa, Naoto Yagi,
Kouichi Shiraishi, Masayuki Yokoyama,
Kazuo Sakurai
9:10 – 1057. Doubly responsive block copolymer micelles in water. Bin Zhao*
9:30 – 1058. Self-assembly of amino acid
derived block copolymers. Zhibo Li*
10:00 – 1059. Gelable block copolymers for
shaped polymeric nanoobjects.
Yongming Chen*
10:30 – 1060. Micelles of ABC triblock copolymers under special solvation conditions. Guojun Liu*, John Dupont,
Hongjing Dou, Gabriel Njikang, Jiwen Hu,
Liangzhi Hong
10:50 – 1061. Alternating polymer vesicles.
Stephen Fenimore, Ludmila Abezgauz,
Chia-Chi Ho, Dganit Danino, Carlos Co*
11:10 – 1062. Surface functionalization of
polymer vesicles with dendritic ligands.
Elizabeth R. Gillies*, Colin V. Bonduelle,
Ali Nazemi, Bo Li, Ryan Amos
Convention Center
323A
Radical Polymerization Kinetics and
Mechanisms (#219)
Organized by: G. Russell, A. Goto,
R. Hutchinson, G. Moad, P. Zetterlund
Presiding: M. Buback, R. Hutchinson
7:30 – 1063. Perspectives on radical polymerization kinetics. Gregory T. Russell*
7:50 – 1064. Notes on kinetics of conventional and controlled/living radical polymerizations. Takeshi Fukuda*
8:30 – 1065. Mass spectrometry as a mechanistic tool: From photo-initiation to unravelling the complexities of acrylate free
radical polymerization.
Christopher Barner-Kowollik*,
Thomas Junkers, Anna-Marie Zorn,
Dominik Voll, Sandy P. Koo
9:10 – 1066. Emulsion polymerization using
CO2 switchable surfactants: Stabilization
and aggregation of polymer latexes.
Candace Fowler, Philip G. Jessop*,
Michael F. Cunningham*
9:30 – 1067. Competition between degradation and grafting of xyloglucan during
emulsion polymerisation. Peter Lovell*,
Amilcar Pillay Narrainen
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR
10:10 – 1068. Free radical miniemulsion polymerization reactions observed by timeresolved Xe-129 NMR. Mathis Duewel*,
Nicolas Vogel, Clemens Weiss,
Katharina Landfester, Hans W. Spiess,
Kerstin Muennemann
10:30 – 1069. Synthesis and self-assembly
of pH-sensitive amphiphilic gradient copolymer containing fluorine.
Yanjun Chen*, Wen Luo
10:50 – 1070. Nitroxide mediated polymerization parameters adjustment using acid-base equilibria in alkoxyamines of imidazoline series with multiple ionizable
groups. Elena G. Bagryanskaya,
Maria Edeleva, Igor Kirilyuk
11:10 – 1071. Role of diradical intermediates
in the thermal ring-opening polymerization (ROP) of hydrocarbon-bridged
[2]metallocenophanes. Joe B. Gilroy,
David E. Herbert, Anne Staubitz,
Andrew J. Stonor, Laurent Chabanne,
Mairi F. Haddow, Ian Manners*
Convention Center
322AB
Frontiers of Precisely Controlled Polymer
Synthesis: Fine Control of Polymerization
Reaction and Impact on Advanced Material
Designs (#257)
Organized by: T. Kitayama, S. Aoshima,
M. Kamigaito, G. Moad, J. Puskas
Presiding: M. Kamigaito, J. Lee,
S. Aoshima, T. Nakano
7:30 – 1072. Synthesis and characterization
of novel glycosurfaces by surface-initiated polymerization. Anca Mateescu,
Jianding Ye, Ravin Narain,
Maria Vamvakaki*
8:00 – 1073. Controlling macromolecular architecture by atom transfer radical polymerization (ATRP).
Krzysztof Matyjaszewski*
8:30 – 1074. Development of telechelic polyacrylate by atom transfer radical polymerization. Yoshiki Nakagawa*
9:00 – 1075. Synthesis of architectural polymers by using chain-functionalized
diblock copolymer anion(s). Akira Hirao*
9:30 – 1076. Stereoblock and triblock (co)polymers of (meth)acrylates.
Takehiro Kitaura*, Tatsuki Kitayama
9:50 – 1077. Multibranched polymers of various branched architectures by living anionic polymerization. Hideki Nishimura,
Ippei Mori, Ryota Uemura, Kaoru Adachi,
Yasuhisa Tsukahara*
10:10 – 1078. Chemoselective and cyclization polymerization of di(meth)acrylate
monomers. Tatsuki Kitayama,
Takehiro Kitaura
10:30 – 1079. Synthesis and photoinduced
structural transition of single-handed helical, optically active polyacrylates.
Tamaki Nakano*, Takeshi Sakamoto,
Shin-ichiro Sato
11:00 – 1080. Living anionic polymerization
of isocyanate and their chirality study.
Priyank Shah, Joon-Keun Min,
Jae-Suk Lee*
Convention Center
321B
Molecular-Based Ordered Materials
Formed Through Self-Organization (#102)
Organized by: T. Kato, M. Francis,
D. Gin, X. Guo, H. Kikuchi, C. Nuckolls
Presiding: C. Nuckolls, D. Gin, X. Guo,
T. Kato
7:45 – 1081. Organic light-emitting devices
using single crystals. Hajime Nakanotani,
Yuto Kakizoe, Chihaya Adachi*
8:10 – 1082. Molecular electronic devices
with point contacts formed from sp2 carbon nanomaterials. Xuefeng Guo*
8:30 – 1083. Nanographenes and their assemblies. Klaus Müllen*
8:55 – 1084. Preparation, structures, and
physical properties of tetrakis(alkylchalcogeno)tetrachalcogenafulvalene.
Gunzi Saito*, Yukihiro Yoshida,
Hideki Yamochi, Takehiko Mori,
Hiroo Inokuchi
9:15 – 1085. Charge transport in bicontinuous cubic and related smectic phases.
Jean-Moïse Suisse, Hiroyuki Mori,
Hirosato Monobe, Shoich Kutsumizu*,
Yo Shimizu*
9:35 – 1086. Site-selective immobilization of
colloids on Au substrates via a noncovalent supramolecular “handcuff”.
Oren Scherman*
9:55 – 1087. Photovoltaic coaxial nanotubes
with molecular graphene/fullerene heterojunction. Yohei Yamamoto*,
Guanxin Zhang, Wusong Jin,
Takanori Fukushima, Akinori Saeki,
Shu Seki, Takuzo Aida
10:15 – 1088. Reversible mechanochromic
luminescent difluoroboron ␤-diketonates.
Guoqing Zhang, Jiwei Lu, Tiandong Liu,
Michal Sabat, Cassandra L. Fraser
10:40 – 1089. Self-organization of fully conjugated macrocycles: Synthesis and
functional properties. Masahiko Iyoda*
11:05 – 1090. Segregated graphenes: From
controlled growth to photocatalytic tailoring toward electronic devices.
Liu Zhongfan*
Convention Center
328
Separation and Characterization of
Synthetic and/or Biological
Macromolecules: The Principles, Practices
and Applications (#179)
Organized by: Y. Wang, T. Chang,
S. Kinugasa
Presiding: Y. Wang
7:50 – 1091. Flow field-flow fractionation of
biomolecules for proteomics research.
Myeong Hee Moon*
8:20 – 1092. Open-column separation techniques in characterization of the proteinnanoparticle complexes.
Wenwan Zhong*, Ni Li,
Samantha Sachermeyer,
Jonathan Ashby, Shang Zeng
8:50 – 1093. Free solution electrophoresis of
DNA: How can we make it work?
Gary W. Slater*
9:20 – 1094. Rapid electrophoretic DNA separations using surfactant systems.
James W. Schneider*
9:50 – 1095. Continuous and rapid separation of soft matters using microfluidic
systems. Minoru Seki*, Masumi Yamada
10:20 – 1096. Surface plasmon resonance
imaging of microdotted proteins.
Yi Chen*
10:50 – 1097. Solvent-dependent global and
helical conformation of amylose tris(3,5dimethylphenylcarbamate) and amylose
tris(phenylcarbamate) in solution.
Ken Terao*, Maiko Tsuda,
Yasuko Nakamura, Yusuke Kita,
Shinichi Kitamura, Takahiro Sato
11:10 – 1098. Dilute solution properties of
schizophyllan/polynucleotide complexes
explored with GPC/MALS and synchrotron small angle X-ray scattering.
Kazuo Sakurai*, Tubasa Matuzaki
Convention Center
323B
Biomimetic Engineering of Hierarchically
Structured Polymer Materials (#126)
Organized by: M. Shimomura, T. Iyoda,
D. Pochan, M. Winnik
Presiding: M. Shimomura
8:10 – 1099. ABC triblock copolymer helices
from solution assembly. Hongjing Dou,
Guojun Liu*, John Dupont,
Liangzhi Hong, Ken-ichi Niihara,
Ryuhei Kimoto, Hiroshi Jinnai
8:40 – 1100. Recognition of oligopeptides in
water by molecularly imprinted cyclodextrin polymers. Jun Sumaoka*,
Makoto Komiyama*
9:10 – 1101. High resolution imaging of the
hierarchical structure of indomethacin
carrying dendrimers by scanning tunneling microscopy. Shawn L. Riechers,
Christopher J. Fleming*, Nai-Ning Yin,
Gabriel Chu, Gang-yu Liu
9:40 – 1102. Withdrawn
10:10 – 1103. Large-area, lightweight and
thick biomimetic composites with superior material properties via fast, economic
and green pathways. Olli T. Ikkala*,
Andreas Walther, Ingela Bjurhager,
Jani-Markus Malho, Jaakko Pere,
Janne Ruokolainen, Lars Berglund
10:40 – 1104. Preparation of patterned-honeycomb films by photo-crosslinking of
poly (1,2-butadiene). Yuki Nakamichi,
Yuji Hirai, Hiroshi Yabu,
Masatsugu Shimomura
Convention Center
327
Nano Structure and Function of OrganicInorganic Hybrid Polymers (#152)
Organized by: K. Matsukawa, C.S. Ha,
F. Jaekle, K. Naka, I. Tomita
Presiding: K. Naka
8:30 – 1105. Synthesis of ladder oligo- and
polymethylsilsesquioxanes from silafunctional cyclotetrasiloxanes.
Hiroyasu Seki, Takahiro Gunji,
Yoshimoto Abe, Noritaka Abe
8:45 – 1106. From polyoxometalate-polymer
hybrid polymers to polyanion-polymer
hybrid amphiphiles: Synthesis, hierarchical self-assembly, and proton nanochannel constitution. Wei Wang*,
Yaokun Han*, Yu Xiao, Zijian Zhang,
Wei Yu, Minbiao Hu, Ping Zheng
9:00 – 1107. Emission property of trivalent
europium embedded in silsesquioxanes.
Seiji Watase*, Kazuya Ito,
Shota Kitagawa, Yasuchika Hasegawa,
Noboru Nishioka, Kimihiro Matsukawa
9:15 – 1108. Block copolymer based multifunctional hybrid nanostructures for applications in green nanotechnology and
biosensing. Dong Ha Kim*,
Yoon Hee Jang, Yu Jin Jang,
Min-Ah Cha, Ji Yong Lee, Jieun Lee
9:30 – 1109. Optically and electrically active
periodic mesoporous organosilicas.
Shinji Inagaki*
9:50 – 1110. Synthesis, properties and potential applications of phosphine-containing macromolecules. Derek P. Gates*
10:10 – 1111. Formation of hybrid materials
by the reactions of Si-␲ alternate polymers with inorganic oxides. Joji Ohshita*
10:30 – 1112. Hybrid materials from block
copolymer-metal complexes.
Robert B. Grubbs*
10:50 – 1113. Oligosilanes wrapped with
amylose. Takanobu Sanji*
11:10 – 1114. Hybrid polymers via regioselective catalytic grafting of organic or inorganic templates. Bhanu P. Chauhan*
Convention Center
Kamehameha Halls II and III
Biodegradable and Biomass Plastics (#95)
Organized by: H. Uyama, G.G. Chen,
S.S. Im, T. Iwata, C. Nomura
Presiding: H. Uyama
1117. Improving the monomer-supplying
function of FabH for polyhydroxyalkanoate production through site-specific mutagenesis. Alexander P. Mueller*,
Christopher T. Nomura
1118. Production and characterization of
poly-3-hydroxybutyrate from biodieselderived glycerol by Burkholderia cepacia
ATCC 17759. Chengjun Zhu*,
Christopher T. Nomura,
Joseph A. Perrotta, Arthur J. Stipanovic,
James P. Nakas
1119. Structure, physical property and enzymatic degradation of poly[(R)-3-hydroxybutyrate-co-4-hydroxbutyrate] films with
uniaxial cold-drawing. Zhang JiaQi,
Kusuya Kenichi, Ito Kazuki,
Iwata Tadahisa
1120. Preparation, structure analysis and enzymatic degradation of poly [(R)-3-hydroxybutyrate-co-(R)-3-hydroxyhexanoate] gel-films. Taizo Kabe*,
Toshisa Tanaka, Kenichi Kasuya,
Kazuki Ito, Akio Takemura,
Tadahisa Iwata
1121. Studies of thin films of polymer blends
by 2-D correlation spectroscopy.
Soo Ryeon Ryu, Min Kyung Kim,
Isao Noda, Young Mee Jung*
1122. ␤-Oxidation inhibition of pentanoic
acid for biosynthesis of polyhydroxyalkanoate from W. eutropha.
Risa Yamagishi, Takahiko Nakaoki*,
Sadatsugu Kitamura, Daisuke Ishii
1123. Microbial production of lactate (LA)based polyesters with tailor-made monomer composition using engineered LApolymerizing enzymes. Miwa Yamada,
Ken’ichiro Matsumoto, Takanori Nakai,
Kotaro Shimizu, Shu Uramoto,
Fumi Shozui, Seiichi Taguchi
1124. Fabrication of poly(3-hydroxyalkanoate) nanoporous material by phase separation. Takashi Fujimoto,
Takashi Tsujimoto, Hiroshi Uyama
1125. Miscibility and mechanical properties
of biodegradable poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)/poly(␧caprolactone) blend. Kenji Katsumata*,
Nobuo Nakamura, Yoshio Inoue
1126. Drug-impregnation in porous fibers of
microbial poly[(R)-3-hydroxybutyrate-co4-hydroxybutyrate] by one-step drawing
method with small crystal nuclei.
Chizuru Hongo, Hiroyuki Ichino,
Toshihisa Tanaka, Kazuki Ito,
Kentaro Uesugi, Akihisa Takeuchi,
Yoshio Suzuki, Tadahisa Iwata*
1127. Analysis of high-strength biodegradable polyester poly[(R)-3-hydroxybutyrate] copolymer fibers by X-ray tomography and enzymatic degradation.
Toshihisa Tanaka*, Kentaro Uesugi,
Akihisa Takeuchi, Yoshio Suzuki,
Tadahisa Iwata
1128. Atomic force microscopic study on
mechanical properties of poly[(R)-3-hydroxybutyrate], cellulose acetate and native cellulose single nanofibers.
Shinichiro Iwamoto*, Masafumi Asano,
Akira Isogai, Tadahisa Iwata
1129. Identification of the pathway for polyhydroxyalkanoate (PHA) production from
unrelated carbon sources in Pseudomonas putida KT2440. Qin Wang
1130. Biosynthesis of polyhydroxyalkanoate
from amino acids by W. eutropha.
Manato Sakamoto, Takahiko Nakaoki*
Poster Session
10:00 – 12:00
1115. “Facelift” of polyhydroxyalkanoate
granules: Alteration in their numbers and
sizes by altering the key polyhydroxyalkanoate synthase enzyme.
Normi Mohd Yahaya*, Teh Boon Aun,
Lim Gaik Ling, Tomohiro Hiraishi,
Seiichi Taguchi, Yoshiharu Doi
1116. Establishment of a fatty acid biosynthesis-linked pathway to generate biodegradable polyesters. Ryan Tappel*,
Christopher Nomura
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–111
03-MACR
1131. Mechanical properties of blend film of
poly(3-hydroxybutyrate) and poly(hydroxybutyrate-co-hexanoate).
Yushi Edagawa, Takahiko Nakaoki*,
Kazuma Matsuura
1132. Copolymer composition of poly(3-hydroxyalkanoates) biosynthesized from
fatty acid and glycerin by Pseudomonas
putida. Takahiro Miura, Daisuke Ishii,
Takahiko Nakaoki
1133. Fabrication of micro- and nanostructures on flexible biobased polymer films.
Takamichi Shinohara,
Shirahase Tomoko, Atsushi Takahara
1134. Synthesis of poly(lactide) based block
copolymers: Molecular weight control.
Ryo Watanabe*,
Masahiro Yoshizawa-Fujita,
Yuko Takeoka, Masahiro Rikukawa
1135. Synthesis and characterization of
PLA-PDMS copolymers.
Mizuho Nagata*, Yasuharu Yamada
1136. Nucleation enhancement effect in
poly(L-lactide) (PLLA)/poly(␧-caprolactone) (PCL) blend induced by locally activated chain mobility resulting from limited
miscibility. Koji Yazawa*, Fuji Sakai,
Kenichi Nishikawa, Yoshio Inoue
1137. Synthesis of uniform oligomers of Dand L-mandelic acids and copolymers of
mandelic acid and lactic acid.
Yusuke Hemmi, Akonori Saito,
Hikaru Momose, Tomohiro Hirano,
Koichi Ute*
1138. Fabrication of polylactone/HAp composites by microwave irradiation.
Saori Kadota*,
Masahiro Yoshizawa-Fujita,
Yuko Takeoka, Masahiro Rikukawa
1139. Preparation and characterization of
PLLA/nanoparticle-HAp composite fibers. Kenta Kikuchi*,
Masahiro Yoshizawa-Fujita,
Yuko Takeoka, Masahiro Rikukawa
1140. Synthesis of branched poly(lactic acid)
and its application to functional additives
for biomass plastics. Yoshimi Haza*,
Takashi Tsujimoto, Hiroshi Uyama
1141. Radiation-induced modification of biodegradable polymers. Jae-Hak Choi*,
In-Seol Kuk, Chan-Hee Jung,
In-Tae Hwang, Jung-Soo Lee,
Young-Chang Nho
1142. Development of novel bio-based polymers using glyceric acid from raw glycerol. Tokuma Fukuoka*, Hiroshi Habe,
Dai Kitamoto, Keiji Sakaki
1143. Preparation of liquid crystalline polyesters and cellulose derivatives from
plant-derived phenolic compounds and
cellulose. Daisuke Ishii*, Hiroshi Fukui,
Mizuki Nakagawa, Hiroki Maeda,
Kouhei Nose, Hisao Hayashi
1144. Development of new functional plant
oil-based polymeric materials.
Takashi Tsujimoto, Hiroshi Uyama
1145. Drug releasing properties of electrospun non-woven fabrics prepared from
cellulose and chitosan.
Kousaku Ohkawa*, Jun Araki
1146. Synthesis and properties of hyperbranched polymers containing amino
acid moieties in the main chain.
Toshiki Ohshiro, Hiroto Kudo,
Tadatomi Nishikubo*
1147. Gelatin/poly (ethylene oxide) blend
films with compositional gradient: Fabrication and characterization.
Takashi Saito*
1148. Synthesis of AAB-sequence-regulated
copolymers from naturally-occurring terpene by controlled radical copolymerization in fluoroalcohol. Masaru Matsuda,
Kanji Nagai, Kotaro Satoh,
Masami Kamigaito*
1149. Development of highly thermostable
and functional polymers from naturallyoccurring aromatic amino acid. Kai Kan*,
Tatsuo Kaneko
1150. Photomechanical phenomenon induced by cooperative photoreaction of
continuous cinnamoyl structures.
Katsuaki Yasaki*, Daisaku Kaneko,
Koji Yazawa, Tatsuo Kaneko*
112–TECH
TECHNICAL PROGRAM
1151. Degradable polyesters with low-temperature flow: Mechanism of pressure-induced phase miscibility.
Ikuo Taniguchi*, Shingo Kazama,
Anne M. Mayes
1152. Study of epoxy resin by lignin.
Kaori Nakagawa, Oyama Toshiyuki,
Akio Takahashi*, Yoshiaki Okabe,
Hiroyuki Kagawa, Yoshitoshi Nakamura
1153. Some nylons are biodegraded by a
thermophilic bacterium. Kosuke Tomita*
1154. Biodegradable protective clothing for
a nuclear facility.
Michael E. Cournoyer*,
Cynthia L. Kowalczyk
1155. Biodegradation of polymers and polymeric composites. Ravi B. Srivastava*
1156. Advances in well-defined rosin-containing biodegradable polymers.
Chuanbing Tang*, Kejian Yao,
Jifu Wang, Perry Wilbon,
Chunpeng Wang, Fuxiang Chu
Sunday Afternoon
Convention Center
325B
NMR Spectroscopy of Polymers: Innovative
NMR Strategies for Complex
Macromolecular Systems (#12)
Organized by: T. Asakura, H. N. Cheng,
A. English, F. Horii, P. Macdonald,
H. Spiess, J. White, A. Whittaker
Presiding: P. Macdonald
12:30 – 1157. Structural characterization of
polymeric materials by higher resolution
and higher sensitivity solid-state NMR.
Fumitaka Horii*
13:00 – 1158. D2O, silica, and zirconium
phosphate in Nafion channels studied by
NMR. Xueqian Kong,
Klaus Schmidt-Rohr
13:30 – 1159. NMR rescaling revisited.
Michael E. Ries*, Michael Brereton,
Aman Bansal
14:00 – 1160. Self assembly and dynamics
of synthetic polymers and polypeptides
from NMR spectroscopy.
Hans W. Spiess*
14:30 – 1161. Hierarchal dynamics of poly(butyl acrylate) measured by latex state
NMR spectroscopy. Seiichi Kawahara*,
Kazuya Watanabe,
Yoshimasa Yamamoto, Keiichi Akabori
15:00 – 1162. Understanding transport and
anisotropy in ionic polymers.
Louis A. Madsen*, Jianbo Hou, Jing Li,
Zhiyang Zhang, Kyle G. Wilmsmeyer
15:30 – 1163. Characterizing polysaccharides solutions, local motions and films
with (solid-state) NMR.
Carmina Gartner Vargas,
Patrice Castignolles, Robert Graf,
Hans W. Spiess, Michael J. Gidley,
Marianne Gaborieau*
16:00 – 1164. Unraveling the mechanism of
peroxide crosslinking of EPDM by use of
advanced MAS 13C NMR combined with
selective 13C labeling. Pieter Magusin*
Convention Center
328
Separation and Characterization of
Synthetic and/or Biological
Macromolecules: The Principles, Practices
and Applications (#179)
Organized by: Y. Wang, T. Chang,
S. Kinugasa
Presiding: T. Chang
12:30 – 1165. Determination of polymer molar mass, composition, and architecture
in a single analysis. S Kim R. Williams*,
J. R. Runyon
13:00 – 1166. Anti-virus activity of polylysine
dendrimer with sulfated oligosaccharides.
Takashi Yoshida*, Shuqin Han,
Taisei Kanamoto, Hideki Nakashima
13:20 – 1167. Asymmetric flow field flow
fractionation of asymmetric particles and
polymers. Erick Soto-Cantu, Yiying Yue,
Rafael Cueto, Qinglin Wu,
Paul S. Russo*
13:50 – 1168. Twirling and stretching of
polymers in FFF. Yongmei Wang*
14:20 – 1169. Potential of asymmetrical flow
field flow fractionation in the characterization of dendritic biopolymers.
Albena Lederer*, Susanne Boye,
Dietmar Appelhans
14:50 – 1170. Second virial coefficient of unperturbed semiflexible rings. Daichi Ida*,
Daisuke Nakatomi, Takenao Yoshizaki
15:10 – 1171. Capillary electrophoresis of
polyelectrolytes and polysaccharides copolymers. Patrice Castignolles*,
Rozet S. Roi, Tina Kiefer,
Claudia Skworzow, Sabine Fluegel,
Manfred Schmidt
15:30 – 1172. Liquid chromatography under
limiting conditions of enthalpic interactions: A novel tool for separation of complex polymer systems. Dusan Berek*
Convention Center
323A
Radical Polymerization Kinetics and
Mechanisms (#219)
Organized by: G. Russell, A. Goto,
R. Hutchinson, G. Moad, P. Zetterlund
Presiding: G. Russell, C. Barner-Kowollik
12:30 – 1173. Detailed studies into radical
polymerization kinetics via SP-PLP-EPR.
Michael Buback*, Johannes Barth
13:10 – 1174. Transfer to polymer and
branching in the radical polymerization of
acrylates. Patrice Castignolles*,
Sandy Koo, Anatoly Nikitin,
Thomas Junkers,
Christopher Barner-Kowollik,
Marianne Gaborieau
13:30 – 1175. Radical generators for polymer modification: A mechanistical study.
Denis J. Bertin*, Sylvain R. Marque,
Marie Leblanc, Yohann Guillaneuf
13:50 – 1176. Mechanism of hydrogentransfer reaction in nitroxide mediated
polymerization of methacrylate derivatives. Yohann Guillaneuf,
Mariya Edeleva, Elena Bagryanskaya*,
Didier Gigmes, Sylvain Marque*
14:10 – 1177. Initiation of RAFT polymerization. Graeme Moad*, Yen K. Chong,
Roger Mulder, Ezio Rizzardo,
San H. Thang
14:30 – 1178. Synthesis and modifications of
reactive block copolymers via RAFT polymerization. Gudrun Schmidt-Naake,
Oliver I. Strube, Lars Nothdurft
14:50 – 1179. Modeling the propagation step
in free-radical polymerization.
Michelle L. Coote*,
Zemma Holmes-Story, Junming Ho,
Ching Y. Lin
15:30 – 1180. Nature of the Alfrey-Price Q
and e parameters. Marvin Charton*
15:50 – 1181. Solvent effects on free-radical
copolymerization propagation kinetics of
hydroxy-functional methacrylates and acrylates. Kun Liang, Robin Hutchinson*
16:10 – 1182. Radical polymerization kinetics of cationic double-charged monomers
in homogeneous phase.
Ricardo Losada*, Hamideh Ahmadloo,
Christine J. Wandrey
13:00 – 1184. Controlled anionic polymerization of styrenes and alkyl methacrylates
using a flow microreactor system.
Atsuo Miyazaki*, Aiichiro Nagaki,
Yutaka Tomida, Jun-ichi Yoshida
13:20 – 1185. Metal oxides for green precision polymer synthesis: living cationic polymerization of vinyl ethers and other possibilities. Arihiro Kanazawa,
Kotaro Satoh, Masami Kamigaito,
Shokyoku Kanaoka, Sadahito Aoshima*
13:40 – 1186. Synthesis and characterization
of mono-allyl-terminated polyvinylethers
with pendant biocide moieties.
Samim Alam*, Shane Stafslien,
Justin Daniels, Lyndsi Vander Wal,
Bret Chisholm
14:00 – 1187. Synthesis of novel fullerene
polymer conjugates by living polymerization. Jin Motoyanagi, Ryo Miyabara,
Masashi Suzuki, Masahiko Minoda*
14:20 – 1188. Well-defined multibranched
polymers by base-assisting living cationic
polymerization: selective synthesis of star
and flower-shaped polymers of vinyl
ethers. Shokyoku Kanaoka,
Takahiro Tokuyama, Aya Yanagisawa,
Yusuke Ueba, Sadahito Aoshima
14:40 – 1189. Synthesis and properties of
poly(m-benzamide) architectures.
Tsutomu Yokozawa*, Tomoyuki Ohishi,
Akihiro Yokoyama
15:10 – 1190. Controlled syntheses of
␲-conjugated polymers: Mechanistic
studies and catalyst development.
Anne J. McNeil*
15:30 – 1191. Externally initiated controlled
synthesis of poly(3-hexylthiophene).
Christine K. Luscombe*,
Hugo Bronstein, Natalia Doubina,
Shane D. Boyd, Michaelina Stoddard
15:50 – 1192. Highly efficient externally initiated living Kumada polycondensation:
Controlled preparation of complex polythiophene architectures. Jinwoo Choi,
Evgueni E. Nesterov*
16:10 – 1193. Photonic polymer matrices induced from cholesteric liquid crystals on
polymers via multiple UV-induced polymerizations. Jui-Hsiang Liu*, Hao Fang,
Jahromi M. J. Niknam, R. Balamurugan
Convention Center
321B
Molecular-Based Ordered Materials
Formed Through Self-Organization (#102)
Organized by: T. Kato, M. Francis,
D. Gin, X. Guo, H. Kikuchi, C. Nuckolls
Presiding: T. Kato, H. Kikuchi, D. Gin,
M. Francis
12:50 – 1194. Supramolecular biomaterials:
A modular approach to bioactivity.
Bert Meijer*
13:15 – 1195. Supramolecular assmbly of
functional materials for bioinspired applications. Woo-Dong Jang*, Chi-Hwa Lee,
Jung-A Kim, Juho Kim
13:35 – 1196. Solvent responsive structurally
colored balloons. Kenji Higashiguchi,
Tomohiro Oda, Kenji Matsuda*
13:55 – 1197. Supramolecular approaches
to stimuli-responsive materials.
Stuart J. Rowan*
Convention Center
322AB
Frontiers of Precisely Controlled Polymer
Synthesis: Fine Control of Polymerization
Reaction and Impact on Advanced Material
Designs (#257)
Organized by: T. Kitayama, S. Aoshima,
M. Kamigaito, G. Moad, J. Puskas
Presiding: T. Kitayama, T. Yokozawa,
S. Aoshima, J. Puskus
12:30 – 1183. Studies of living anionic polymerization of (meth)acrylates in the presence of di-phenoxy alkylaluminum.
Kenichi Hamada*, Yoshihiro Morishita*,
Toyoaki Kurihara, Axel H. Mueller
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR
14:20 – 1198. Synthesis and molecular-assembly of star-type nanomolecules
based on noria. Yoko Nambu*,
Toshiyuki Kataoka, Yoko Yoshitake,
Hiroto Kudo, Takayuki Ikehara,
Tadatomi Nishikubo
14:40 – 1199. Syntheses and self-assembly
of conjugated perylenediimide oligomers
of high electron affinity. Dahui Zhao*,
Qifan Yan
15:00 – 1200. Assembly of ultralarge molecular weight polymers into ordered arrays.
Ned B. Bowden, M. B. Runge, Jun Yoo
15:25 – 1201. Solvato-morphotic nanostructures from peptide-synthetic hybride
block copolymers. Nobuyuki Higashi*,
Masato Koike, Tomoyuki Koga
15:45 – 1202. 1-D assembly of silica nanospheres in liquid phase. Ayae Sugawara,
Masashi Fukao, Takeshi Sakamoto,
Atsushi Shimojima, Tatsuya Okubo*
16:05 – 1203. Chemically modified viral capsids as nanoscale agents for diagnostic
imaging and drug delivery.
Matthew Francis*
Convention Center
323B
15:30 – 1215. Design of organoboron ion
gels and their ion conductive properties.
Noriyoshi Matsumi*, Keigo Aoi
15:45 – 1216. Synthesis and characterization
of inorganic nanoshells using miniemulsion periphery polymerization.
Xiaosong Wang*
16:00 – 1217. Metal nanoparticle/polymer
hybrid particles: Formation of metal
nanoparticles by UV-irradiation to the
polymer surface. Toshiyuki Tamai*,
Mitsuru Watanabe, Kimihiro Matsukawa
16:15 – 1218. Study of several variables on
silica encapsulation by poly(n-butyl acrylate-co-methyl methacrylate) via emulsion
polymerization. Andrés F. Vargas*,
Eric S. Daniels, E. D. Sudol,
Andrew Klein, Betty L. López
Sunday Evening
Convention Center
Kamehameha Halls II and III
NMR Spectroscopy of Polymers: Innovative
NMR Strategies for Complex
Macromolecular Systems (#12)
Biomimetic Engineering of Hierarchically
Structured Polymer Materials (#126)
Organized by: T. Asakura, H. N. Cheng,
A. English, F. Horii, P. Macdonald,
H. Spiess, J. White, A. Whittaker
Presiding: A. Whittaker
Organized by: M. Shimomura, T. Iyoda,
D. Pochan, M. Winnik
Presiding: M. Shimomura
Poster Session
19:00 – 21:00
13:00 – 1204. Supramolecular bioactive
membranes and hydrogels formed by hierarchical assembly. Patricia Dankers*,
Bert Meijer
13:30 – 1205. Preparation of polypyrrole fibers by electro polymerization and its application to biomimetic actuator.
Takeshi Yamauchi*, Takeo Sato,
Genki Endo, Norio Tsubokawa
14:00 – 1206. Precise honeycomb microarray has 3-D topographic effects on periodontal ligament cells.
Nagayoshi Iwama, Hiroshi Ishihata,
Hidetoshi Shimauchi,
Masatsugu Shimomura*
14:30 – 1207. Selective introduction of Au
nanoparticles into polymer particles with
phase separation structures.
Kazutaka Koike*, Takayuki Nakanishi,
Kiwamu Motoyoshi, Takeshi Higuchi,
Hiroshi Yabu, Masatsugu Shimomura
Convention Center
327
Nano Structure and Function of OrganicInorganic Hybrid Polymers (#152)
Organized by: K. Matsukawa, C.S. Ha,
F. Jaekle, K. Naka, I. Tomita
Presiding: F. Jaekle
13:00 – 1208. [RSiO1.5]8/10/12 3-D Nanobuilding blocks (NBs) for structural, photonic and electronic applications by Fcatalyzed rearrangements.
Richard M. Laine
13:30 – 1209. Novel anti-corrosive organicinorganic hybrid coatings for the protection of metal against corrosion.
Mijeong Han*
13:50 – 1210. Hybridization of single-walled
carbon nanotube with novel metal nanoparticles. Moni Chauhan*, Esther Ahn,
Chi Kwan Wong, Eunchul Kim,
Tirandai Hemraj-Benny*
14:10 – 1211. Preparation of inorganic nanoparticles and their arrangement.
Tetsu Yonezawa*
14:30 – 1212. In-situ preparation of poly(acrylic acid)/Ag nanocomposites.
Soonho Lim*, Tae Ho Kim, Heesuk Kim
14:50 – 1213. Novel ␲-conjugated polymers
possessing versatile elements from regioregular organotitanium polymers.
Ikuyoshi Tomita*, Hiroki Nishiyama
15:10 – 1214. Functional materials via boron
modification of block copolymers.
Chengzhong Cui, Fei Cheng,
Frieder Jaekle
1219. Characterization of microbial poly (␥glutamic acid) and its polymer blends by
solid-state NMR. Shiro Maeda*,
Shingo Oumae, Hui Xiong
1220. Molecular dynamics of regioregular
poly(3-alkylthiophene) investigated by
NMR relaxation and an interpretation of
temperature dependent optical absorption. Koji Yazawa*, Yoshio Inoue,
Masataka Tansho, Tadashi Shimizu,
Naoki Asakawa*
1221. Difference HRMAS NMR for exploring
cell-wall polymer changes associated
with mutations. William T. Winter,
DeAnn Barnhart*
1222. 2-D NMR studies of isotopically-enriched native and recombinant elastin.
Kosuke Ohgo, Walter P. Niemczura,
Kristin K. Kumashiro*
1223. Solid-state NMR analysis of a molecular orientation in poly(9,9-di-n-octyl-2,7fluorene) thin films. Masashi Fukuchi*,
Tatsuya Fukushima, Yurie Shimahara,
Atsushi Goto, Hironori Kaji
1224. Bonding states of organic molecules
modifying the surface of boron nitride
probed by solid-state NMR.
Hiroyuki Souma, Shigenobu Hayashi*
1225. Temperature dependence of molecular motion and orientation of natural rubber under the fast MAS.
Masashi Kitamura, Atsushi Asano*,
Chikako Tanaka, Takuzo Kurotsu
1226. Accessing quantitative degrees of
functionalization on poly(divinyl benzene)
microspheres via solid-state NMR spectroscopy. Marianne Gaborieau*,
Leena Nebhani, Robert Graf,
Leonie Barner,
Christopher Barner-Kowollik
1227. Enhancement of peak separation and
tetrad assignment in 1H and 13C NMR
spectra of D/L co-poly(lactic acid).
Koto Suganuma*, Hironori Matsuda,
Tetsuo Aasakura
1228. NMR study of the magnetically oriented layered-structure of liquid-crystalline all-aromatic polyester with n-alkyl
side chains. Toshihito Karakasa*,
Risa Tsuji, Hiroaki Yoshimizu
1229. Characterization of methacrylate copolymers and terpolymers by diffusionordered NMR spectroscopy (DOSY) and
multivariate analysis of NMR spectra.
Tomoya Maeda, Tatsuya Naono,
Hikaru Momose, Tomohiro Hirano,
Koichi Ute*
1230. Structural characterization of silk-like
materials containing polyglutamic acid
sequence by 1H and 13C solution NMR.
Aya Nagano, Sato Hirohiko,
Nakazawa Yasumoto, Asakura Tetsuo*
1231. Characterization of carbon black-filled
natural rubber vulcanizates by solid-state
NMR spectroscopy equipped with field
gradient-magic angle spinning probe.
Oraphin Chaikumpollert*,
Yoshimasa Yamamoto*,
Seiichi Kawahara*
1232. Synthesis of high-silica and low-silica
zeolite monoliths with trimodal pores.
Yasuaki Tokudome, Kazuki Nakanishi,
Sho Kosaka, Ayuta Kariya,
Teiichi Hanada, Hironori Kaji*
1233. Dynamic structure of polyaniline/␤-cyclodextrin inclusion complex studied by
13
C solid-state NMR spectroscopy.
Yuichi Hasegawa*, Yoshio Inoue,
Tadashi Shimizu, Masataka Tansho,
Koji Yazawa*
1234. Secondary structural analyses of amphiphilic peptides composed of two kinds
of amino acid residues. Chikako Tanaka,
Atsushi Asano, Takuzo Kurotsu
1235. Solid-state NMR analyses of spider
dragline silks and S.c.ricini silk fibroin fibers, and polyalanine as a model peptide
for the crystalline region.
Shunsuke Kametani*,
Yasumoto Nakazawa, Tetsuo Asakura
1236. 13C solid state NMR and molecular
dynamics studies of the structural change
of the model peptides for local structure
of Nephila clavipes dragline silk (MaSp1)
by stretching. Tatsuya Hayashi*,
Makiko Ikenaga, Shizuo Yamazaki,
Shunsuke Kametani, Akihiro Aoki,
Tetsuo Asakura
1237. Production and NMR analysis of silklike proteins containing cell-adhesive sequences for bone scaffold.
Kenta Miyazawa*, Ai Yoshida,
Yu Suzuki, Tetsuo Asakura
1238. Lamellar structure of Bombyx mori silk
fibroin model peptide, (Ala-Gly-Ser-GlyAla-Gly)5 studied using solid state NMR.
Tatsuya Ogawa*, Yu Suzuki,
Akihiro Aoki, David P. Knight,
Tetsuo Asakura
1239. Generation of silk I structure of Bombyx mori silk fibroin in aqueous solution
studied with NMR. Yuya Satoh,
Yu Suzuki, Tetsuo Asakura
1240. Dependence of sorption amount of Xe
on Xe-129 NMR chemical shift of Xe in
polymers. Hiroaki Yoshimizu*
1241. Local order and packing arrangement
in novel donor-acceptor copolymers from
solid-state NMR. Michael Ryan Hansen,
Pierre Beaujuge, Don Cho, Chad Amb,
Hoi Nok Tsao, Wojciech Pisula,
John R. Reynolds, Klaus Müllen
1242. Solid-state NMR analysis of local
structures in electron transport materials
for organic light emitting diodes.
Tatsuya Fukushima*, Hironori Kaji
Convention Center
321B
Molecular-Based Ordered Materials
Formed Through Self-Organization (#102)
Organized by: T. Kato, M. Francis,
D. Gin, X. Guo, H. Kikuchi, C. Nuckolls
Presiding: T. Kato, H. Kikuchi,
M. Francis, X. Guo
19:00 – 1243. Design of new reactive lyotropic liquid crystal networks and new
thermotropic ionic liquid crystal platforms. Douglas Gin*, Robert Kerr,
Evan Hatakeyama, Magdalene Reynolds,
Andrew LaFrate
19:20 – 1244. Semiconducting lamellar
structure of perylene bisimide dyes
formed by complementary hydrogen
bonding interactions. Tomohiro Seki,
Shiki Yagai, Takashi Karatsu,
Akihide Kitamura, Yukihiro Maruya,
Ken-ichi Nakayama
19:40 – 1245. Thermochromic luminescent
smectic liquid crystals. Shogo Yamane,
Yoshimitsu Sagara, Takashi Kato*
20:00 – 1246. Controlled fabrication and optical properties of highly fluorescent 1D
and semi-2D nanostructures of a dipolar
organic molecular system.
Ravi Kumar Kanaparthi,
Anunay Samanta*
20:20 – 1247. Solvothermal synthesis of
spherical particles of titanic acid using
water-soluble titanium complex and their
conversion to titanium dioxide with mesopores by subsequent heat treatment.
Makoto Kobayashi, Hideki Kato,
Masato Kakihana
20:40 – 1248. Liquid-crystalline side-chain
polymers containing terthiophene-based
mesogens with high carrier mobilities.
Masahiro Funahashi, Aya Matsui,
Takashi Kato*
Convention Center
Kamehameha Halls II and III
Biomimetic Engineering of Hierarchically
Structured Polymer Materials (#126)
Organized by: M. Shimomura, T. Iyoda,
D. Pochan, M. Winnik
Presiding: M. Shimomura
Poster Session
19:00 – 21:00
1249. Control of water repellency and adhesive properties of hydrophilic-hydrophobic hybrid structures in polymer surfaces.
Akihito Takahashi, Daisuke Ishii*,
Hiroshi Yabu, Masatsugu Shimomura*
1250. Preparation of metallic honeycomb
films by photochromism of spiropyran
and electroless plating.
Takayuki Nakanishi*, Yuji Hirai,
Miki Kojima, Hiroshi Yabu,
Masatsugu Shimomura
1251. Withdrawn
Convention Center
Kamehameha Halls II and III
Nano Structure and Function of OrganicInorganic Hybrid Polymers (#152)
Organized by: K. Matsukawa, C.S. Ha,
F. Jaekle, K. Naka, I. Tomita
Presiding: K. Matsukawa, I. Tomita
Poster Session
19:00 – 21:00
1252. Hydrolysis behavior of the precursor
for the bridged polysilsesquioxane [1,
4-Bis(triethixysilyl)benzene].
Hitomi Saito*, Yuki Nishio,
Yoshiyuki Sugahara
1253. Correlation between properties and
structures of epoxy-functionalized phenylsilsesquioxanes. Kazuhiro Yoshida*,
Kazumi Hashimoto, Mitsukazu Ochi
1254. Synthesis of functionalized thermoresponsive polysilsesquioxane by use of
mercapto group. Fukutaro Minami,
Shin-ichi Yamamoto, Osamu Moriya*
1255. Synthesis of thermoresponsive organic-inorganic hybrid polymer containing
silsesquioxane structure by click chemistry. Shin-ichi Yamamoto*,
Fukutarou Minami, Osamu Moriya
1256. Ring-opening polymerization for synthesis of grafted polysilsesquioxane.
Osamu Moriya*, Shin-ichi Yamamoto,
Yorihisa Tanaka, Mikihiro Kashio,
Toshio Sugizaki
1257. Syntheses and properties of polysiloxanes with cage-silsesquioxanes in the
main chain. Takahiro Shioda,
Yoshimoto Abe, Takahiro Gunji*,
Noritaka Abe
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–113
03-MACR
1258. Synthesis and properties of alkoxy
silsesquioxanes by the dehydrogenative
condensation. Yusuke Sekiguchi,
Takahiro Gunji, Noritaka Abe*,
Yoshimoto Abe
1259. Synthesis and properties of polymethylsilsesquioxane/polymethoxysiloxane
block copolymers. Hironori Kaburaki,
Yoshimoto Abe, Takahiro Gunji*,
Noritaka Abe
1260. Synthesis and characterization of
alkoxysilane that has arylsulfonic acid ester. Kazuki Yamamoto, Yoshimoto Abe,
Takahiro Gunji*, Noritaka Abe
1261. Syntheses and optical properties of
dumbbell-type polyhedral oligomeric silsesquioxanes. Kensuke Naka,
Hitoshi Araki*
1262. Synthesis and properties of imidazolefunctionalized POSS-core dendrimers.
Tomoaki Sato, Shizuka Masuoka,
Ryusuke Shinke, Kensuke Naka
1263. Solvent-free synthesis of functional siloxanes bearing 4-trifluoromethylphenyl
group. Yasunobu Egawa*,
Masafumi Unno
1264. 1-D nanostructures of ␲-conjugated
molecules by ␲-stacking in a mixed-valent state. Kazunori Hayakawa,
Kensuke Naka
1265. Interlayer surface modification of the
protonated layered tetratitanate H2Ti4O9 .
xH2O with phenylphosphonic acid.
Shintaro Nagahama*, Yumi Kato,
Yoshiyuki Sugahara
1266. Intercalation of triethylphosphine oxide into the interlayer space of
HLaNb2O7.xH2O. Nagisa Toihara*,
Yoriyoshi Yoneyama, Akira Shimada,
Yoshiyuki Sugahara
1267. Fabrication of biomacromolecular
nanowires by single particle nanofabrication technique (SPNT). Atsushi Asano*,
Satoshi Tsukuda, Masaki Sugimoto,
Shu Seki
1268. Hydroxyapatite-armored biodegradable polymer microspheres fabricated via
Pickering-type emulsion route.
Taiki Nishimura, Syuji Fujii*,
Masahiro Okada, Tsutomu Furuzono,
Yoshinobu Nakamura
1269. Biorepellent activity of capsaicin-intercalated into layer double hydroxide.
Yoshio Muraoka, Kumi Shirai,
Takeshi Yamauchi, Norio Tsubokawa
1270. Introduction of antibacterial groups
onto the silica nanoparticle surface and
their properties. Takashi Kawahara,
Takeshi Yamauchi, Norio Tsubokawa*
1271. Immobilization of flame retardant onto
silica nanoparticle. Kumi Shirai*,
Akira Yuuki, Kazuhiro Fujiki,
Takeshi Yamauchi, Norio Tsubokawa
1272. Grafting of antibacterial polymer onto
silica nanoparticle surface by SI-ATRP in
a solvent-free dry-system.
Hiroshi Matsuda, Takashi Kawahara,
Takeshi Yamauchi, Norio Tubokawa*
1273. Synthesis of oligosiloxanes by using
Wilkinson’s catalyst. Natsuko Kondo*,
Takahiro Gunji, Yoshimoto Abe,
Noritaka Abe
1274. Syntheses and physical properties of
silicon-containing polymers with cyclic
structures in the polymer backbone.
Eiichi Akiyama*, Keita Noguchi
1275. Design and synthesis of functional
␲-conjugated polymers containing selenophene units in the main chain by reaction of organometallic polymers having titanacyclopentadiene units.
Hiroki Nishiyama, Ikuyoshi Tomita
1276. Preparation and characterization of
KN ferroelectrics by precursor method
using triethanolamine. Hiroyuki Ueno,
Abe Yoshimoto, Gunji Takahiro*,
Abe Noritaka
1277. Improvement in ionic conductivity of
polyether/clay composites.
Shunsuke Kitajima, Yoichi Tominaga*
1278. Ionic conductivity of silatrane/salt
complexes. Tomonobu Mizumo,
Risa Fujita, Joji Ohshita*
1279. Highly branched organoboron polymer
electrolytes for enhanced ionic conductivity. Sonu R. Shankar,
Noriyoshi Matsumi*
114 –TECH
TECHNICAL PROGRAM
1280. Role of functional groups in polysilsesquioxanes for dispersing gold nanoparticles. Yuta Motohisa, Seiji Watase,
Mitsuru Watanabe, Toshiyuki Tamai,
Masuyama Araki, Kimihiro Matsukawa*
1281. Preparation of platinum nanoparticles
using polyethyleneimine as a stabilizer
and their properties. Takanori Imai,
Takahiro Gunji*, Noritaka Abe,
Yoshimoto Abe
1282. Synthesis of conducting polymer-palladium nanocomposite-coated latex particles in aqueous media. Syuji Fujii*,
Soichiro Matsuzawa,
Yoshinobu Nakamura, Atsushi Ohtaka,
Takuto Teratani, Kensuke Akamatsu,
Takaaki Tsuruoka, Hidemi Nawafune
1283. Synthesis and characterization of
phenanthroline platinum complexed.
Yusuke Shimura, Yoshimoto Abe,
Takahiro Gunji*, Noritaka Abe
1284. Epoxy resin monolith supporting palladium catalyst for a column reactor.
Akira Tomita, Seiji Watase,
Toshiyuki Tamai, Araki Masuyama,
Kimihiro Matsukawa*
1285. Optical properties of 1,4-dihydro-1,4diarsinine-bridged dihaloplatinum(II)
complexes. Takuji Kato, Kensuke Naka,
Manabu Arita, Yasuhiro Morisaki,
Yoshiki Chujo
1286. Fabrication of high refractive and
transparent PMMA/TiO2 hybrid film.
Shuhei Yamada, Emiko Mouri,
Kohji Yoshinaga*
1287. Microwave-assisted synthesis of organic-inorganic hybrids and their optical
applications. Yuichi Kajiwara,
Atsushi Nagai, Yoshiki Chujo*
1288. Synthesis of silicon-containing porphyrin dye for high durable dye-sensitized solar cells. Takurou Abe*,
Masafumi Unno
1289. Photomechanical effect of azobenzene thin polymer films measured with an
AFM cantilever based sensor.
Zahid S. Mahimwalla,
Christopher J. Barrett*, Yoshihiko Nagai
1290. Effective refractive index of colloidal
crystal system formed by colloidal silica
modified with ferrocely-grafted polymer.
Kohji Yoshinaga*, Zhiguo Ma,
Miwa Watanabe, Emiko Mouri
1291. Solubilization of single walled carbon
nanotube and attachment on inorganic
oxide surface. Daiki Tanaka,
Junya Matsukawa, Tomonobu Mizumo,
Joji Ohshita, Yoshihito Kunugi
1292. Grafting of polymers onto carbon
nanotube surface by ligand-exchange reaction. Kazuhiro Fujiki*,
Tsutomu Kamimura, Kei Yaotome,
Tetsuo Sumiyoshi, Kumi Shirai,
Norio Tsubokawa
1293. Enhanced chlorine-resistance of reverse osmosis membrane via addition of
nano-carbon materials. Wansuk Choi,
Junwoo Park, Sang Gon Kim,
Sung Hyun Kim, Joona Bang*
1294. Synthesis and properties of polymers
containing fullerene in the main chain.
Ryotaro Tani, Yoshomoto Abe,
Takahiro Gunji*, Noritaka Abe
1295. Preparation of organic/inorganic hybrids containing SWCNTs and VGCFs.
Taiga Ogata, Yoshimoto Abe,
Takahiro Gunji*, Noritaka Abe
1296. Synthesis and property of calcium carbonate composite particles with carboxylic acid-terminated dendritic macromolecules. Yuka Tanaka, Kensuke Naka
1297. Modification of dispersibility of nanodiamond by grafting of PEG and by the
introduction of ionic groups onto the surface. In oh Cha, Kumi Shirai,
Kazuhiro Fujiki, Takeshi Yamauchi,
Norio Tsubokawa*
Convention Center
Kamehameha Halls II and III
Separation and Characterization of
Synthetic and/or Biological
Macromolecules: The Principles, Practices
and Applications (#179)
Organized by: Y. Wang, T. Chang,
S. Kinugasa
Presiding: Y. Wang
Poster Session
19:00 – 21:00
1298. AFM observation of molecular stretching of stimuli-responsive polymer chain.
So Mutobe, Kunika Uehara,
Shinpei Kado, Yoshio Nakahara,
Keiichi Kimura
1299. Curdlan sulfate coated membrane filter with influenza virus capturing function.
Tegshi Muschin*, Takashi Yoshida
1300. Branching analysis using 2-D liquid
chromatography with the multiple detection. Seonyoung Ahn, Taihyun Chang*
1301. Selectivity studies in the fractionation
of wheat straw with formic acid.
Yongming Fan*, Xiaohong Xie,
Yao Chen, Mingfei Li
Convention Center
Kamehameha Halls II and III
Radical Polymerization Kinetics and
Mechanisms (#219)
Organized by: G. Russell, A. Goto,
R. Hutchinson, G. Moad, P. Zetterlund
Presiding: P. Zetterlund
Poster Session
19:00 – 21:00
1302. Reinvestigation of the penultimate unit
effect in free-radical copolymerisation.
Zemma Holmes-Story, Ching Y. Lin,
Michelle L. Coote*
1303. Theoretical prediction of Q-e values of
vinyl monomers for radical polymerization. Susumu Kawauchi*,
Shinnosuke Takahashi, Keigo Saito,
Yusuke Tamura
1304. Measuring the disproportionation-tocombination ratio in radical polymerization. Majed M. Alghamdi*,
Gregory T. Russell, Michael Buback,
Felix Huff
1305. Using apparent molecular weight from
SEC in controlled/ living polymerization
and kinetics of polymerization.
Patrice Castignolles,
Yohann Guillaneuf*
1306. Development of two synthetic routes
for functionalized polymers using azide
radical generated by hypervalent iodine.
Juhee Kim, Bongjin Moon*
Monday Morning
Convention Center
325B
NMR Spectroscopy of Polymers: Innovative
NMR Strategies for Complex
Macromolecular Systems (#12)
8:30 – 1309. Effect of molecular architecture
on the performance of 19F MRI imaging
agents. Hui Peng, Idriss Blakey,
Bronwin Dargaville, Firas Rasoul,
Stephen Rose, Kristofer Thurecht,
Andrew K. Whittaker*
9:00 – 1310. Xe-129 NMR of polymers.
Hiroaki Yoshimizu
9:30 – 1311. NMR studies of biomass and its
reaction products. H. N. Cheng*
10:00 – 1312. Application of melt-state NMR
spectroscopy for polyolefin characterisation in industry. Matt Parkinson*,
Isa Fonseca, Gerhard Hubner
10:30 – 1313. Advanced solution 2D-NMR
studies of fluoropolymers.
Peter L. Rinaldi*, Xiahohong Li,
Eric B. Twum, Elizabeth F. McCord,
Peter A. Fox, Jon L. Howell, Don Lyons
11:00 – 1314. Structure of model peptides
for the crystalline region of Bombyx mori
silk fibroin in fluorinated solvents studied
by NMR. Yu Suzuki*, John T. Gerig,
Tetsuo Asakura
Convention Center
328
Separation and Characterization of
Synthetic and/or Biological
Macromolecules: The Principles, Practices
and Applications (#179)
Organized by: Y. Wang, T. Chang,
S. Kinugasa
Presiding: M. Moon
7:30 – 1315. Characterization of complex
polymers using 2-D LC and related techniques. Bernd Trathnigg
8:00 – 1316. Copolymer characterization by
coupled LC - MS/MS techniques.
Jana Falkenhagen*, Steffen Weidner,
Christina Schmid,
Christopher Barner-Kowollik
8:30 – 1317. Characterization of branched
polymers by HPLC. Taihyun Chang*,
Seonyoung Ahn, Hyojoon Lee
9:00 – 1318. Confocal Raman microscopy to
study the polymer adsorption and transport in nanoporous silica.
Chang Yeol Ryu*
9:30 – 1319. Understanding and predicting
2-D chromatography of block copolymers from the fundamentals of confined
macromolecules. Alexei A. Gorbunov*,
Andrey V. Vakhrushev
10:00 – 1320. How well can one separate
statistical copolymers according to both
chemical composition and sequence distribution? Yutian Zhu, Yongmei Wang*
10:20 – 1321. Separations of linear and
branched polymers by 2-D liquid chromatography. Wolfgang Radke,
Michael AlSamman*
10:50 – 1322. Characterization of polymacromonomer consisting of polyisoprene
backbone with polystyrene side chains.
Yo Nakamura*, Yuji Hatanaka
11:10 – 1323. Chromatographic analysis of
comb shaped polymers using different
isotope sensitivity. Seonyoung Ahn,
Taihyun Chang*
Organized by: T. Asakura, H. N. Cheng,
A. English, F. Horii, P. Macdonald,
H. Spiess, J. White, A. Whittaker
Presiding: F. Horii
7:30 – 1307. Structure-relaxivity relationships of polyether-magnetite nanoparticles for enhanced transverse relaxivities.
Judy S. Riffle*, Philip P. Huffstetler,
William C. Miles, Jue Liang,
Sharavanan Balasubramaniam,
Richey M. Davis, Matthew Carroll,
Robert C. Woodward,
Timothy G. St. Pierre
8:00 – 1308. Swelling and diffusion: Pharmaceutical tablets as studied by NMR imaging. Yu Juan Wang,
Héloïse Therien-Aubin, Wilms E. Baille,
Cédric Malveau, Robert H. Marchessault,
Mircea A. Mateescu, Julian X. Zhu
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
03-MACR/04-ORGN
Convention Center
322AB
Frontiers of Precisely Controlled Polymer
Synthesis: Fine Control of Polymerization
Reaction and Impact on Advanced Material
Designs (#257)
Organized by: T. Kitayama, S. Aoshima,
M. Kamigaito, G. Moad, J. Puskas
Presiding: G. Russell, M. Kamigaito,
G. Moad
8:00 – 1324. Synthesis of stereoregular
poly(N-isopropylacrylamide)s via low
temperature radical polymerization and
phase transition of aqueous solution
thereof. Tomohiro Hirano*
8:30 – 1325. RAFT polymerization of N-vinylimidazolium salts for controlled synthesis
of polymeric ionic liquids.
Hideharu Mori*
9:00 – 1326. Developments in switchable
RAFT polymerization for block copolymer
synthesis. Daniel J. Keddie,
Carlos Guerrero-Sanchez,
Graeme Moad*, Ezio Rizzardo*,
San Thang*
9:20 – 1327. Well-defined 1:1 and 2:1 sequence-regulated copolymers by controlled radical copolymerization.
Kotaro Satoh, Kanji Nagai,
Masami Kamigaito
9:40 – 1328. Facile synthesis of degradable
polyperoxides by radical alternating copolymerization and their applications as
functional materials. Eriko Sato*,
Hiroshi Tamura, Akikazu Matsumoto*
10:00 – 1329. Quantitative investigation of
the effect of AIBN on polymer-end structure in organoheteroatom-mediated living
radical polymerization.
Yasuyuki Nakamura*, Yukie Kitada,
Yu Kobayashi, Ray Biswajit,
Shigeru Yamago
10:20 – 1330. Radical chain end chemical
transformation of SG1-based polystyrenes. Yohann Guillaneuf,
Pierre-Emmanuel Dufils,
Laurent Autissier, Marion Rollet,
Didier Gigmes, Denis Bertin
10:40 – 1331. Synthesis of w-end functionalized polymers by highly chemoselective
heteroatom-metal exchange reactions.
Eiichi Kayahara, Hiroto Yamada,
Shigeru Yamago*
11:00 – 1332. Well-defined chitosan graft
copolymers as potential gene carriers.
Hongqian Bao*, Lin Li
Convention Center
321B
Molecular-Based Ordered Materials
Formed Through Self-Organization (#102)
Organized by: T. Kato, M. Francis,
D. Gin, X. Guo, H. Kikuchi, C. Nuckolls
Presiding: C. Nuckolls, H. Kikuchi,
D. Gin, T. Kato
8:10 – 1333. Interaction-assisted approach
for realization of biaxial mesophases.
Keiki Kishikawa*, Sumihiro Aikyo,
Seiji Akiyama, Takahiro Inoue,
Masahiro Takahashi, Shigeo Kohmoto
8:30 – 1334. Self-organized assemblies
formed at interfaces of liquid crystals.
Nicholas L. Abbott*
8:55 – 1335. Entropically-driven various
smectic liquid crystalline phases observed in binary mixtures of rigid-rod helical polysilanes with different molecular
lengths. Kento Okoshi*, Junji Watanabe
9:15 – 1336. Photopolymerization behavior
and nanostructure development of reactive lyotropic liquid crystals.
Lucas Sievens, Allan Guymon
9:35 – 1337. Supramolecularly assembled
discotic liquid crystals with cavities.
Shigeo Kohmoto*, Yu Kuroda,
Masahiro Takahashi, Keiki Kishikawa
9:55 – 1338. Photo-triggered mass migrating
motions in inorganic-organic liquid crystalline hybrids. Takahiro Seki*,
Kaori Nishizawa, Shusaku Nagano
10:20 – 1339. Liquid crystals with axially
chiral 3,3’-dinitro-2,2’,6,6’-tetramethylbiphenyl cores: The lateral shielding effect
of bicyclo[2.2.2]octane-1-carboxylate
side-chains. Khurshid Ayub, Mark Moran,
Carmen Lazar, Robert Lemieux*
10:45 Closing remarks
Convention Center
327
Nano Structure and Function of OrganicInorganic Hybrid Polymers (#152)
Organized by: K. Matsukawa, C.S. Ha,
F. Jaekle, K. Naka, I. Tomita
Presiding: C. Ha
8:20 – 1340. Surface and interface characterization of silane coatings deposited on
aluminium by dipcoating, vacuum plasma
and atmospheric plasma.
Abdelkrim Batan*, Fabiola Brusciotti,
Iris De Graeve, Jean Vereecken,
Mireille Wenkin, Marcel Piens,
Herman Terryn, Jean-Jacques Pireaux,
François Reniers
8:35 – 1341. Silica/polymer hybrid hollow
nanoparticles with tunable channels.
Linqi Shi
8:50 – 1342. Novel thermosetting inorganic
polymers alternately bearing a polyhedral
oligomeric silsesquioxane and dimethylsiloxanes. Masashi Kunitake*
9:05 – 1343. Nanoparticle-mediated high
performance shape memory polymer network. Jie Song*, Jianwen Xu
9:20 – 1344. Synthesis of epoxy resin-silica
nanocomposites by using perhydropolysilazane as a precursor of silica domains. Reiko Saito*, Tohru Kumagai,
Yosuke Fujii
9:35 – 1345. Curing behaviors and physical
properties of hybrids from epoxy resins
and hydroxyl terminated poly(dimethyl siloxane)s via cationic polymerizations.
Dai Soo Lee*, Seon Suk Lee,
Dinh Huong Nguyen, Gwang Seok Song
9:50 – 1346. Syntheses and properties of
POSS-based polymers. Takahiro Gunji*,
Yoshimoto Abe, Noritaka Abe
10:10 – 1347. Preparation and characterization of polyimide based nanohybrids.
Chang-Sik Ha*
10:30 – 1348. Borazine polymers for functional materials and ceramics precursors.
Yuko Uchimaru
10:50 – 1349. Cyclolinear polycarbosilanes:
A new type of organosilicon polymer.
Leonard V. Interrante*, Xinxing Liu,
Jitendra S. Rathore
ORGN
Area 4 – Organic
Wednesday Morning
Hilton
South Pacific II
Designed pi-Electronic Systems: Synthesis,
Properties, Theory and Function (#29)
Organized by: M. Haley, G. Bodwell,
T. Kubo, Y. Tobe
Presiding: M. Haley
7:30 – 1. Synthesis, structure and functions
of a phenylene-bridged disilaalkene macrocage as a framed molecular top.
Wataru Setaka*, Kentaro Yamaguchi
7:50 – 2. Hydrazone-based chemically activated configurational rotary switches.
Ivan Aprahamian*, Shainaz M. Landge,
Xin Su
8:10 – 3. Recent development of novel multioxadiazoles and the study of their photophysical behavior. Man-kit Leung*
8:30 – 4. Cofacially-arrayed polybenzenoid
nanostructures for molecular wires. Rajendra “Raj” Rathore*
8:50 – 5. Design vs. serendipity in the synthesis of new aromatic architectures.
Robert A. Pascal*
9:30 – 6. Rings ‘n things: Shape-persistent
molecules via Schiff base chemistry.
Mark MacLachlan*, Joseph Hui,
Jian Jiang
9:50 – 7. Synthesis and characterization of
new pi-extended heteroarenes for electronic materials. Kazuo Takimiya*
10:10 – 8. Engineering new molecular materials from complex aromatic components.
James Wuest*
10:50 – 9. Transannular approaches to polycyclic aromatic hydrocarbons from dehydrobenzoannulenes. Yoshito Tobe*
11:10 – 10. Enhanced optical effects in conjugated organic systems and assemblies.
Theodore Goodson*
Hilton
Iolani I/II
Chemistry of Novel Nanocarbons Fullerenes, Carbon Nanotubes and Related
Materials (#45)
Organized by: T. Akasaka, Y. Li, F. Wudl
Presiding: N. Martin, M. Prato
7:30 – 11. Amazing diversity of carbon cluster science. Eiichi Nakamura*
8:15 – 12. Recent progress in nanodiamonds. Eiji Osawa*
8:45 – 13. Sequential click reactions for the
multiple functionalization of fullerene
hexaadducts.
Nierengarten Jean-Francois*
9:15 – 14. First enantioselective catalysis of
fullerene derivatives. Nazario Martin*
9:45 – 15. Preparation and characterization
of fulleranes, hydrogenated CNTs, graphane, [60]fullerene-acene adducts and
semiconducting nanoparticles based on
[60]fullerene-acene adducts.
Glen P. Miller, Irvinder Kaur,
Jonathan B. Briggs, Jeremy Kintigh,
Yushu Li, Yi Xu, Nathan Stein,
Polina Prusevich
10:15 – 16. Metal catalysis for nanocarbon
chemistry. Kenichiro Itami*
Hilton
Sea Pearl V/VI
The Science and Strategy of Process
Chemistry: From Molecules to
Pharmaceutical Drugs (#85)
Organized by: T. McDermott, S. Caron,
G. McLachlan, I. Shinkai
Presiding: M. Chen
7:30 Introductory remarks
7:35 – 17. Process design and crystal engineering of XtalFluor-salts: Selective fluorination reagents with enhanced thermal
stability and ease of handling.
Michel Couturier*, Alexandre L’Heureux,
Francis Beaulieu, Christopher Bennett,
David R. Bill, Simon Clayton,
Francois LaFlamme,
Mahmoud Mirmehrabi, Sam Tadayon,
David Tovell
8:13 – 18. Withdrawn
8:51 – 19. Facilitating chemical synthesis using flow techniques. Malte Brasholz
9:29 – 20. Development of process synthesis
of rosiglitazone by use of microwave irradiation. Santosh L. Gaonkar,
Hiroki Shimizu*
10:07 – 21. Process development of an efficient synthetic route to GDC-0941.
Qingping Tian*, Zhi-gang K. Cheng,
Herbert Yajima, Keena Green,
Rebecca Rogers, Scott Savage,
Srinivasan Babu, Mark Reynolds,
Greg Sowell, David Askin
10:45 Concluding remarks
Hilton
Coral V
New Dimensions of Green Sustainable
Chemistry: Novel Reactions and Catalysts
(#132)
Organized by: S. Kobayashi, P. Anastas,
T. Braish, M. Krische, C.J. Li
Presiding: S. Kobayashi
7:30 – 22. Solar photochemistry: Visible light
photocatalysis of organic reactions for
greener chemical synthesis.
Tehshik P. Yoon*, Michael A. Ischay,
Juana Du, Zhan Lu
7:45 – 23. Novel solid-state photoreversible
polymerization of thymine-based monomers. Priscilla Johnston*, Kei Saito
8:00 – 24. Byproduct-free C-C bond formation via catalytic transfer hydrogenation:
Hydroxyalkylation of unsaturates.
Michael J. Krische*
8:30 – 25. Acid-catalyzed addition of C-H or
O-H bonds to unsaturated molecules.
Jun-Chul Choi, Kazufumi Kohno,
Hiroyuki Yasuda, Toshiyasu Sakakura*
8:45 – 26. New acid-base cooperative catalysis under near neutral pH conditions using aminoorganoboron complexes.
Shunsuke Oishi, Ryoji Noyori,
Susumu Saito
9:00 – 27. On inventing new reactions for
atom economy. Barry M. Trost*
9:30 – 28. Rhodium- and palladium-catalyzed synthesis of organophosphorus
compounds using diphosphine disulfides
and dioxides. Mieko Arisawa,
Masahiko Yamaguchi
9:45 – 29. Thionation and sulfidation reactions via in situ reductive or oxidative activation of elemental sulfur.
Fumitoshi Shibahara*, Rie Sugiura,
Eiji Yamaguchi, Takafumi Kanai,
Toshiaki Murai
10:00 – 30. Development of a robust, environmentally responsible process: The
tasocitinib citrate story.
Rajappa Vaidyanathan*
10:30 – 31. Copper-free Wacker-type oxidation of internal olefins using PdCl2-DMA
catalyst system. Takato Mitsudome,
Tomoo Mizugaki, Koichiro Jitsukawa,
Kiyotomi Kaneda*
10:45 – 32. Useful chemical transformations
utilizing ␮-oxo-bridged hypervalent iodine reagents. Toshifumi Dohi,
Teruyoshi Uchiyama,
Kei-ichiro Fukushima, Daishi Kato,
Yasuyuki Kita*
11:00 – 33. Ruthenium(II) catalysts: Multiple
process promoters for C-C bond formation. Pierre Dixneuf*, Min Zhang,
Sylvie Derien
Hilton
Honolulu II
Organic Solid-State Chemistry: Structure,
Synthesis & Reactivity (#155)
Organized by: R. Bishop,
M. Garcia-Garibay, R. Kuroda
Presiding: R. Bishop
7:30 – 34. Preferential enrichment of amino
acid-organic acid co-crystals with a racemic crystal structure. Rui Tamura*,
Sekai Iwama, Rajesh G. Gonnade,
Hiroki Takahashi, Hirohito Tsue
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–115
04-ORGN
8:10 – 35. Solid-state reactivity of alkyl nitrenes. Anna D. Gudmundsdottir*
8:40 – 36. Polymorphic transition of pharmaceutical crystals investigated by ab initio
structure determination from powder diffraction data. Hidehiro Uekusa*,
Etsuo Yonemochi, Katsuhide Terada
9:10 – 37. Self-assembly of amphiphilic
amino acid derivatives into metallosupramolecular architectures. Feng Xue*,
Siu Yee New, Yude Thio
9:30 – 38. Photochromism of spiropyrans
and spirooxazines in the solid state.
Jun Harada*, Yuta Kawazoe,
Keiichiro Ogawa*
10:00 – 39. Selective Diels-Alder type reactions of tetracene derivatives in molecular
crystals. Qian Miao*, Zhixiong Liang
10:20 – 40. Advances in temperature-resolved diffraction and X-ray photodiffraction: Emerging analytical tools for direct
observation of unstable and intermediate
molecular species in the solid state.
Pance Naumov*
10:50 – 41. Accessing new regions of phase
space for organic materials: Pharmaceuticals, explosives, and proteins.
Adam J. Matzger*
Hilton
Honolulu I
Carbanions: Modern Perspectives in
Structure, Reactivity, and Synthesis (#229)
Organized by: B. Gawley, V. Snieckus,
K. Tomioka
Presiding: B. Gawley
7:30 Welcome remarks
7:40 – 42. C-H bond activation by directed
ortho metalation. Victor Snieckus*
8:20 – 43. Synthesis of N-aryl and N-alkyl
anthranilic acids via the SNAr reaction of
unprotected 2-fluoro and 2-methoxybenzoic acids by lithioamides.
Jacques Mortier*
9:00 – 44. Generation and reactions of aryllithiums bearing an electrophilic functional group using a flow microreactor
system. Heejin Kim, Aiichiro Nagaki,
Jun-ichi Yoshida*
9:20 – 45. Enantioselective synthesis of
allenes via carbolithiation of conjugated
enynes with organolithiums using an integrated flow microreactor system.
Yutaka Tomida, Aiichiro Nagaki,
Jun-ichi Yoshida*
9:40 – 46. Site specific electrostatic perturbation of conjugation, SSEPOC, among
internally solvated organolithium compounds. Gideon Fraenkel*
10:10 – 47. Synergic surprises from bimetallic metallating agents: Cleave and capture chemistry. Robert E. Mulvey*
10:50 – 48. Constriction of unique heterocycles and chiral building blocks via carbanion addition processes for drug candidates. Chris Senanayake*
Hilton
South Pacific III
Metal Catalysis for Asymmetric Synthesis
(#282)
Organized by: H. Sasai, A. Charette,
H. Davies, D. Yang
Presiding: H. Sasai, H. Davies
7:45 – 49. Extraordinary effect of microwave
irradiation on the atropo-enantioselective
methanolysis reaction of biaryl lactones.
Satoshi Kikuchi*, Tatsuyuki Tsubo,
Tohru Yamada
8:05 – 50. Asymmetric Suzuki-Miyaura coupling. Yasuhiro Uozumi*,
Yutaka Matsuura, Takayasu Arakawa,
Yoichi M. Yamada
8:25 – 51. Highly efficient chiral organometallic catalysts for homo- and heterogeneous asymmetric hydrogenation.
Kuiling Ding*
TECHNICAL PROGRAM
8:55 – 52. Metal-linked multinuclear catalyst
for highly efficient catalytic asymmetric
alkylation reactions. Kohei Endo*,
Mika Ogawa, Keisuke Tanaka,
Daisuke Hamada, Sayuri Yakeishi,
Takanori Shibata
9:15 – 53. Palladium- and nickel-catalyzed
coupling reactions of alkyl electrophiles.
Greg Fu*
9:45 – 54. Asymmetric cyclization reactions
through palladium and silver catalysis.
Dan Yang*, Kai-Tai Yip, Min Yang,
Wei He, Hao-Guo Chen, Ke-Sheng Song,
Kai-Yip Lo
10:15 – 55. New insights in the structure of
chiral rhodium dimer catalysts and their
use in the asymmetric cyclopropanation
of alkenes. Andre B. Charette*
10:45 – 56. P-chiral phosphine ligands with
tert-butylmethylphosphino groups for
highly efficient asymmetric catalyses.
Ken Tamura, Masashi Sugiya,
Tsuneo Imamoto*
11:05 – 57. Mechanism of enantioselection
in rhodium-catalyzed asymmetric hydrogenation of prochiral alkenes.
Ilya D. Gridnev, Tsuneo Imamoto
Hilton
South Pacific IV
New Directions of Supramolecular
Chemistry toward Nanomaterial Science,
Biomedical Science, and Supramolecular
Catalysts (#47)
Organized by: S. Aoki, W. Chung,
J. Davis, T. Haino
Presiding: S. Aoki, T. Haino
8:00 Introductory remarks
8:05 – 58. Cucurbituril-based nanomaterials
and their applications. Kimoon Kim*
8:30 – 59. Synthesis of metallodendrimers
for advanced nanomaterials.
Kimihisa Yamamoto*
8:55 – 60. Formation of helical and macrocyclic structures: Anion-driven conformation control of ␲-conjugated oligopyrroles. Yohei Haketa, Kanako Kitaguchi,
Hiromitsu Maeda*
9:10 – 61. Fullerene recognition by calixarene/thiacalixarene derivatives.
Pavel Lhotak*, Martin Kas,
Ondrej Kundrat, Ivan Stibor, Kamil Lang
9:25 – 62. Fullerene bilayer vesicles displaying hydrophobic surface in an aqueous
phase and on solid surfaces.
Koji Harano, Tatsuya Homma,
Eiichi Nakamura*
9:40 – 63. Application of molecular capsules
as reaction chambers. Dariush Ajami*,
Julius Rebek Jr.*
9:55 – 64. Synthesis of interlocked compounds by the reaction of macrocyclemetal complexes. Ryu Yamasaki,
Shinichi Saito*
10:10 – 65. Functionalized catalytic and energy conversion systems with monoclonal antibodies. Hiroyasu Yamaguchi*,
Akira Harada
10:25 – 66. Soluble pentacene precursors:
Strategic design, synthesis, and characterization. Tahsin J. Chow*
10:40 – 67. Incorporating dynamic components into metal organic framework materials. Stephen Loeb*, Kelong Zhu,
Nicholas Vukotic
11:05 – 68. Molecular and supramolecular
pentiptycene chemistry: From self-assembly to control of rotary motions.
Jye-Shane Yang*
Hilton
Coral IV
Novel Synthetic Methodology and Its
Application to Natural Product Synthesis
(#63)
Organized by: F. West, V. Rawal,
M. Toyota
Presiding: M. Toyota
8:00 – 69. Withdrawn
8:45 – 70. Diastereoselective and enantioselective olefin metathesis.
Siegfried Blechert*
116 –TECH
9:15 – 71. Heterocyclization by intramolecular carbometallation of alkynes.
Jacques F. Maddaluno*,
Muriel Durandetti, Catherine Fressigné,
Frédéric Le Strat, Anne-Lise Girard,
Lucie Hardou, Rudy Lhermet
10:00 – 72. Z-selective intramolecular Horner-Wadsworth-Emmons reaction for the
synthesis of macroclic lactons.
Kaori Ando, Kenji Narumiya,
Hiroaki Takada, Taiji Teruya
10:20 – 73. Normal polarity N-heterocyclic
carbene catalysis: Application to the total
synthesis of iridoid natural products.
David W. Lupton
10:40 – 74. Efficient route to polycyclic 2,5dihydropyrroles via ring fragmentation/
1,3-dipolar cycloaddition.
Matthias Brewer*, Cristian Draghici,
Qiufeng Huang
14:30 – 87. Strengths and limitations of highthroughput purification platforms for supporting pharmaceutical discovery synthesis. Ray McClain*
15:00 – 88. Circular dichroism (CD) directed
chiral separation by semi-prep supercritical fluid chromatography (SFC) with
open-bed fraction collection.
Muneo Saito*, Yoshiteru Horikawa,
Kazutoshi Kamezawa,
David J. Tognarelli, Takeshi Kanomata,
Masao Bounoshita
15:30 – 89. Integrating directed enzyme evolution with high throughput chromatography. Steve Collier
16:00 – 90. Challenges in mass directed SFC
purification. John Van Antwerp*
Hilton
Honolulu III
Designed pi-Electronic Systems: Synthesis,
Properties, Theory and Function (#29)
Supramolecular Photochemistry (#125)
Organized by: M. Haley, G. Bodwell,
T. Kubo, Y. Tobe
Presiding: T. Kubo
Organized by: Y. Inoue, C. Bohne,
V. Ramamurthy, C. Tung
Presiding: L. Shimizu, G. Cosa
8:00 – 75. Spin chemistry of H2@C60 and
friends. Nicholas J. Turro*
8:30 – 76. Light controlled guest binding in a
molecular cavitand. Orion B. Berryman,
Aaron C. Sather, Julius Rebek*
8:50 – 77. Bright supramolecules with logic
and sensing functions. He Tian
9:20 – 78. Studies of photochemical and reaction container properties of poly(ether
imine) and poly(alkyl aryl ether) dendrimers. N. Jayaraman*, G. Jayamurugan,
Y. Rajesh, B. Natarajan, V. Ramamurthy,
J. Nithyanandhan
9:50 – 79. Photocatalytic hydrogen evolution
from [FeFe] hydrogenases mimics.
Li-Zhu Wu*, Chen-Ho Tung, Bin Chen
10:20 – 80. Fluorescent marriage between
thiazole orange and
p-sulfonatocalix[4]arene. Sara Mooi,
Belinda Heyne
10:40 – 81. Asymmetric photochemical synthesis using serum albumins as chiral
templates. Asao Nakamura*,
Kota Hiranuma, Takamasa Yamada,
Masumi Ohbuchi, Masashi Arai
11:00 – 82. Energy, electron and spin exchange between encapsulated and free
molecules in water.
Vaidhyanathan Ramamurthy,
Nithyanandhan Jayaraj, Shipra Gupta,
Mintu Porel, Anand Parthasarathy,
Judy Y-C Chen, Steffen Jockusch,
Nicholas J. Turro, Maria F. Ottaviani
Wednesday Afternoon
Hilton
Sea Pearl I/II
Interface between Organic Synthesis and
Chromatography (#19)
Organized by: C. Welch, W. Farrell,
M. Hyun, A. Rajendran
Presiding: C. Welch
12:30 – 83. Simplified approach to high
throughput analysis of organic reactions
using MISER chromatography (multiple
injections in a single experimental run):
The chromatogram is the graph.
Christopher Welch*
13:00 – 84. Integration of organic synthesis
and chromatography: New routes in the
high-throughput screening of catalysts.
Oliver Trapp*
13:30 – 85. Impact of optimized fast LC-MS
methods in the drug discovery environment. John Eschelbach*,
Dorothy Zhuomei*, Wolfgang Goetzinger*
14:00 – 86. Advantages and disadvantages
of a multi-technique high throughput purification process. William Farrell,
David Masters-Moore, Loanne Chung,
Christine Aurigemma
Hilton
South Pacific II
12:30 – 91. Dynamic helical molecules with
an extremely high pi-electron density.
Shinji Ando, Eisuke Ohta,
Atsuko Kosaka, Takanori Fukushima*,
Daisuke Hashizume, Hiroyuki Koshino,
Azusa Muraoka, Hiroshi Ushiyama,
Takuzo Aida*
12:50 – 92. Symmetrical and unsymmetrical
cruciforms. Uwe Bunz*, Jua Tolosa*
13:10 – 93. Möbius aromaticity in expanded
porphyrins. Atsuhiro Osuka
13:50 – 94. Oligo- and polymeric pentacene
materials: Synthesis and performance.
Rik R. Tykwinski*, Dan Lehnherr,
Jianbo Gao, Frank A. Hegmann
14:10 – 95. Aromatic self-assembly in the
design of electronic materials.
John E. Anthony*
14:50 – 96. Indenofluorenes — stable antiaromatic alternatives to pentacenes?
Michael M. Haley*, Daniel T. Chase,
Aaron G. Fix, Cameron L. Hilton
15:10 – 97. Synthesis and characterization of
the first nonacene derivative and
progress toward the first cyclacene.
Glen P. Miller*, Irvinder Kaur
15:30 – 98. Stable high-spin molecules in
materials science. Keiji Okada*,
Shuichi Suzuki, Masatoshi Kozaki
16:10 – 99. Oligoacenes with terminal cyclopentadienylmetal groups.
John P. Selegue*, Uttam R. Pokharel,
Ilya Vinogradov, Bidhya L. Maharjan,
Minh Truong, Sean Parkin
Hilton
Iolani I/II
Chemistry of Novel Nanocarbons Fullerenes, Carbon Nanotubes and Related
Materials (#45)
Organized by: T. Akasaka, Y. Li, F. Wudl
Presiding: D. Guldi, A. Balch
12:30 – 100. Advances in the chemistry and
application of carbon nanomaterials.
Robert C. Haddon
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
13:00 – 101. Crystallographic studies of samarium containing endohedral fullerenes
and related fullerenes. Alan L. Balch,
Marilyn M. Olmstead,
Brandon Q. Mercado, Hua Yang,
Ziyang Liu, Christine M. Beavers
13:30 – 102. Artificial photosynthetic reaction center based on porphyrins and
phthalocyanines. Shunichi Fukuzumi*
14:00 – 103. Sc2S@C2n (n ⫽ 40-50): A novel
sulfide cluster endohedral fullerene family. Luis Echegoyen, Ning Chen
14:30 – 104. Synthesis and functionalization
of fullerene derivatives for organic electronic devices. Yutaka Matsuo*
14:50 – 105. Determination of minim lead (⌱⌱)
in water by single-walled carbon nanotubes and DNA modified electrode.
Yongfu Lian, Hong Zhao
15:10 – 106. Organic synthesis of endohedral fullerenes. Yasujiro Murata*
15:30 – 107. Titanium (III)-based endohedral
mixed metal nitride clusterfullerenes:
Synthesis, structure, and property.
Shangfeng Yang*
15:50 – 108. Recent progress in the photoelectron spectroscopy on endohedral
fullerenes. Shojun Hino*
16:10 – 109. 2-D organic metal based on
fullerene. Gunzi Saito*, Akihiro Otsuka,
Mitsuhiko Maesato, Dmitri V. Konarev*,
Rimma N. Lyubovskaya,
Salavat S. Khasanov
Hilton
Coral IV
Novel Synthetic Methodology and Its
Application to Natural Product Synthesis
(#63)
Organized by: F. West, V. Rawal,
M. Toyota
Presiding: J. Maddaluno
12:30 – 110. [CpRu(␩3-C3H5)(2-pyridinecarboxylato)]PF6 complex supported on a
ferromagnetic microsize particle
Fe3O4@SiO2. Shinji Tanaka,
Tomoaki Seki, Yu Minematsu,
Masato Kitamura*
12:50 – 111. Total syntheses of spiroannulated natural products with allelopathic
activity. Kozo Shishido
13:35 – 112. Development of palladium-catalyzed cycloalkenylation and its application to natural product synthesis.
Masahiro Toyota*
14:20 – 113. Acetylene and its cobalt complex as the mutifunctional tool in organic
synthesis. Minoru Isobe*,
Wei-Chung Chang, Ya-Ting Lin,
Kuan-Hsun Huang
14:50 – 114. Progress toward the antiproliferative agent popolohuanone E: A general approach to complex cis-fused
decalins featuring catalytic carbon insertion methodology. Jason S. Kingsbury*,
Hilan Z. Kaplan
15:20 – 115. Cascade of Vilsmeier-Haack
cyclization and azomethine ylide cycloaddition towards daphnilactone B and congeners. Guillaume Bélanger*,
Jonathan Boudreault, François Lévesque,
Véronique Darsigny, Michaël Doré
15:40 – 116. Design and synthesis of novel
molecular scaffolds with anti-infective activity. Eric J. Sorensen
Hilton
Sea Pearl V/VI
The Science and Strategy of Process
Chemistry: From Molecules to
Pharmaceutical Drugs (#85)
Organized by: T. McDermott, S. Caron,
G. McLachlan, I. Shinkai
Presiding: S. Wittenberger
12:30 Introductory remarks
12:35 – 117. Catalytic C-H oxidation:
[|#11#|]Recent insights and advances.
Justin Du Bois*
13:13 – 118. Complex natural products as a
driving force for discovery in organic
chemistry. Brian M. Stoltz
13:51 – 119. Hydrogenation for C-C bond
formation. Michael J. Krische
14:29 – 120. Process intensification via hightemperature continuous flow processing.
C Oliver Kappe*, Bernhard Gutmann
15:07 – 121. Direct carboxylation of heteroaromatic compounds with CO2 with
the aid of alkylaluminum halides.
Koji Nemoto*, Satoru Onozawa,
Megumi Konno, Naoya Morohashi,
Tetsutaro Hattori
15:45 – 122. Polymorph control of a sedative
hypnotic. Scott Zook*, Don Hettinger
16:23 Concluding remarks
Hilton
Honolulu III
Supramolecular Photochemistry (#125)
Organized by: Y. Inoue, C. Bohne,
V. Ramamurthy, C. Tung
Presiding: L. Wu, N. Jayaraman
12:30 – 123. High diastereospecificity in the
photochemical synthesis of compounds
with stereogenic adjacent all-carbon quaternary carbons.
Miguel A. Garcia-Garibay*,
Saori Shiraki, Marino J. Resendiz
13:00 – 124. Morphology and shape
changes of crystals of isopropylbenzophenone derivatives via single-crystal-tosingle-crystal photocyclization.
Hideko Koshima*, Hidetaka Uchimoto,
Junki Kubota
13:20 – 125. Porous assemblies of bis-urea
macrocycles used as confined environments for reactions. Linda S. Shimizu*,
Mahender B. Dewal, Sandipan Dawn,
Jun Yang
13:50 – 126. Environmental effects on organic photoactive centers in biological
systems: Lessons to be learned from the
solid-state small-molecule supramolecular photochemistry. Pance Naumov*
14:10 – 127. Molecular radiometer driven by
visible light. Tsunehiko Higuchi*,
Sadanori Nonogaki, Shinnosuke Ueda,
Nobuki Kato, Naoki Umezawa
14:30 – 128. Enantio-and diastereoselective
photodimerization of alkyl 2-naphthoates
in chiral confined media.
Chen-Ho Tung*, Li-Zhu Wu, Bin Chen,
Li-Ping Zhang
15:00 – 129. Binding of chromophores on
semiconductor surfaces using supramolecular hosts. Elena Galoppini*,
Marina Freitag, Yongyi Zhang,
Agneszka Klimczak
15:30 – 130. Modulating the photophysics
and photochemistry of a conjugated
polyelectrolyte via interaction with nanobeads and lipid vesicles. Gonzalo Cosa*,
Pierre Karam, An Ngo, Hsiao-Wei Liu
16:00 – 131. Advanced molecular design for
photoactive nano and bulk materials with
p/n-heterojunction. Yohei Yamamoto,
Weishi Li, Wusong Jin,
Takanori Fukushima, Takuzo Aida*
Hilton
Coral V
New Dimensions of Green Sustainable
Chemistry: Novel Reactions and Catalysts
(#132)
Organized by: S. Kobayashi, P. Anastas,
T. Braish, M. Krische, C.J. Li
Presiding: M. Krische
12:30 – 132. Synthesis of new adamantanelinked 1,2,4-trioxanes. Viktor Schlundt*,
Axel G. Griesbeck
12:45 – 133. Precision synthesis of copolymers of bezaldehydes and their complete
degradation to conjugated aldehydes:
Controlled and alternating cationic copolymerization of benzaldehyde derivatives
with vinyl ethers. Shokyoku Kanaoka,
Yasushi Ishido, Ryosuke Aburaki,
Sadahito Aoshima*
13:00 – 134. Role of molecular activation as
a deliberate strategy for green synthesis.
David S. Black*
13:30 – 135. Catalytic oxidative carbonylation of amines to ureas.
Lisa McElwee-White*, Ampofo K. Darko,
Phillip A. Shelton, Li Zhang,
Seth M. Dumbris, Jennifer I. Johns
13:45 – 136. An improved synthesis of the
macrolide antibiotic PF-4287881 is described. Tamim F. Braish,
Mark Flanagan, Bryan Li,
Thomas Magee
14:00 – 137. Small molecule with a big impact: Inspirations from proline catalysis.
Benjamin List
14:30 – 138. Asymmetric [3⫹2] cycloaddition reactions using a chiral silver amide
catalyst. Yasuhiro Yamashita,
Shu Kobayashi*
14:45 – 139. Tail-to-tail dimerization of
methyl methacrylate catalyzed by N-heterocyclic carbene. Shin-ichi Matsuoka*,
Atsushi Washio, Yoshiya Ota,
Akiho Katada, Kenji Ichioka, Koji Takagi,
Masato Suzuki
15:00 – 140. Catalytic asymmetric carbenoid
insertion into heteroatom-hydrogen
bonds. Qi-Lin Zhou
15:30 – 141. Asymmetric ring-forming reactions by sustainable processes.
Tomislav Rovis
16:00 – 142. New discovery in asymmetric
phase-transfer catalysis. Keiji Maruoka*
13:50 – 153. Asymmetric synthesis of multisubstituted ␤-lactams from ␣-amino acids via memory of chirality using a
Cs2CO3/EtOH system.
Tomoyuki Yoshimura,
Masatoshi Takuwa, Makoto Uyama,
Kazuhiro Hayashi, Daiki Monguchi,
Takahiro Sasamori, Norihiro Tokitoh,
Takeo Kawabata*
14:10 – 154. Leveraging the reactivity of
thioesters and activated hydrazones in
the development of new synthetic methods. Don M. Coltart*
14:40 – 155. Glimpse at the myriad structures of an enolate. Paul G. Williard
15:10 – 156. Metalated nitriles: Tunable,
chiral organometallics. Fraser Fleming*,
Dinesh Nath, Bhaskar Pitta,
Robert Mycka, Matthew Purzyki
15:50 – 157. Torquoselective olefination with
ynolates. Mitsuru Shindo*
Hilton
Honolulu II
12:30 – 158. Cross coupling of secondary
boronic esters with retention of stereochemistry. Ben W. Glasspoole,
Jonathon Moir, Amy Holland,
Véronique Laberge,
Cathleen M. Crudden*
12:50 – 159. Rhodium-catalyzed asymmetric
addition of arylboron reagents to alkenylboranes. Tamio Hayashi, Keigo Sasaki
13:10 – 160. Enantioselective transformations of rhodium carbenoid intermediates.
Huw M. Davies
13:40 – 161. New multi-component transition metal-catalyzed carbocyclization reactions. P. Andrew Evans*
14:10 – 162. Converting C-H to C-C bonds:
Synthesis of veratramine.
Douglass F. Taber*, Berry James,
Peter DeMatteo
14:30 – 163. Combined transition metal and
Lewis acid catalysis in the hydroboration
of olefins. Cathleen M. Crudden*
14:50 – 164. Cationic rhodium(I) complexes
for asymmetric catalysis. Ken Tanaka*
15:20 – 165. Recent advances in the chiral
diene ligands for asymmetric catalysis.
Tamio Hayashi*
15:50 – 166. Enantioselective dehydrative
catalytic cyclization of ␻-hydroxy allyl alcohols. Tomoaki Seki, Satoru Aoyama,
Masaharu Matsushita, Ganesh Salunke,
Shinji Tanaka, Masato Kitamura*
16:10 – 167. Design and synthesis of novel
chiral N-heterocyclic carbene precursors.
Abigail Hubbard*, Daniel Eddings,
Robert Gawley
Organic Solid-State Chemistry: Structure,
Synthesis & Reactivity (#155)
Organized by: R. Bishop,
M. Garcia-Garibay, R. Kuroda
Presiding: M. Garcia-Garibay
12:30 – 143. Hydrogen-bonded host networks constructed with urea derivatives,
stabilization of labile anions, and designed construction of rosette ribbon and
layers. Thomas C. Mak*,
Chi-Keung Lam, Jie Han
13:10 – 144. Dynamics of solid-state processes: Following two-phase solid-state
reactions with a modern diffractometer.
Chun-Hsing Chen, Aaron R. Gell,
Shai R. Posner, Bruce M. Foxman*
13:40 – 145. Synthesis and solid state self
assembly of novel fused planar aromatic
compounds. Suresh Valiyaveettil*,
Balaji Ganapathi
14:10 – 146. Host-guest interactions in cryptophane inclusion complexes studied
with VTNMR and LCNMR. Ping He,
Panayiotis Nikolaou, Laura Walkup,
Kathleen Chaffee, Thierry Brotin,
Jean-Pierre Dutasta, Boyd Goodson*
14:30 – 147. How to control stereochemistry
of solid-state reactions? Reiko Kuroda*,
Ryo Sekiya
15:00 – 148. Solid state polymerization of
amino acid NCAs with reference to the
crystal structures. Hitoshi Kanazawa*
15:20 – 149. Steroidal inclusion compounds:
Molecular and supramolecular chirality.
Mikiji Miyata*, Norimitsu Tohnai,
Ichiro Hisaki
15:50 – 150. Supramolecular catalysis in the
organic solid state via dry grinding.
Leonard R. MacGillivray*,
Anatoliy N. Sokolov,
Dejan-Kresimir Bucar, Jonas Baltrusaitis
Hilton
Honolulu I
Hilton
South Pacific III
Metal Catalysis for Asymmetric Synthesis
(#282)
Organized by: H. Sasai, A. Charette,
H. Davies, D. Yang
Presiding: A. Charette, D. Yang
Hilton
South Pacific IV
New Directions of Supramolecular
Chemistry toward Nanomaterial Science,
Biomedical Science, and Supramolecular
Catalysts (#47)
Organized by: S. Aoki, W. Chung,
J. Davis, T. Haino
Presiding: J. Davis, W. Chung
Carbanions: Modern Perspectives in
Structure, Reactivity, and Synthesis (#229)
* Principle Author
Organized by: B. Gawley, V. Snieckus,
K. Tomioka
Presiding: K. Tomioka
12:30 – 151. Synthesis of higher carbohydrates on dioxanone scaffold.
Marek Majewski*
13:10 – 152. Short-lived C-O axially chiral
enolates for asymmetric synthesis.
Takeo Kawabata*
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–117
04-ORGN
12:45 – 168. Supramolecular polymerization
driven by molecular recognition.
Takeharu Haino
13:10 – 169. Transmembrane ion transport
facilitated by synthetic and natural compounds. Jeff Davis*
13:35 – 170. Synthetic approach to metallofoldamers with oxime-based peptides.
Shohei Tashiro, Koji Matsuoka,
Mihoko Yamada, Mitsuhiko Shionoya*
13:50 – 171. Synthesis and photophysical
properties of self-assembled metalogels
featuring phenyl ethynyl framework with
elaborated long-chain pyridine-2,6-dicarboxamides. Shih-Sheng Sun*
14:05 – 172. Synthesis, membrane localization, and transport activity of a series of
intrinsically fluorescent diphenylacetylene-containing ion channel molecules.
Tom Fyles, Joanne M. Moszynski
14:20 – 173. Probing the GM3-lactose carbohydrate-carbohydrate interaction with
glyconanoparticles. Haruo Yamada*,
Ayami Sagisaka
14:35 – 174. Monomeric and dimeric pyrimidinophanes: Synthesis and biological activity. Anton E. Nikolaev*,
Vyacheslav E. Semenov,
Rashid K. Giniyatullin, Vladimir S. Reznik
14:50 – 175. Mixed glycoluril/crown ether
cage: Synthesis and properties of self-assembly at water/air interface. Marc Vidal,
Vanessa Kairouz, Andreea Schmitzer*
15:05 – 176. Self-complement double helix
of oligo-2-pyridylamines via hydrogenbonds and their quadruple helix of metal
strings. Shie-Ming Peng
15:30 – 177. 2-D self-assembly of triangular
molecules on surfaces via alkyl group interdigitation: Dynamics and control.
Yoshito Tobe*
Thursday Morning
Hilton
South Pacific II
Designed pi-Electronic Systems: Synthesis,
Properties, Theory and Function (#29)
Organized by: M. Haley, G. Bodwell,
T. Kubo, Y. Tobe
Presiding: G. Bodwell
7:30 – 178. Towards the direct assessment
of pi-conjugation effects on molecular
properties. Clemence Corminboeuf
7:50 – 179. Tetrahedrane to cyclobutadiene:
A new extended ␴⫺␲ conjugated system.
Masaaki Nakamoto, Yusuke Inagaki,
Motoaki Nishina, Tatsumi Ochiai,
Akira Sekiguchi*
8:10 – 180. Columnar liquid crystals: Models
systems of self-assembly.
Vance E. Williams*
8:30 – 181. Relationship between structure
and antiaromaticity of planar cyclooctatetraenes. Tohru Nishinaga*
8:50 – 182. Toward 2-D polymers.
A. Dieter Schlüter, Junji Sakamoto
9:30 – 183. Coupling nature of two electrons
in bisanthroxyls. Takashi Kubo*
9:50 – 184. A B-B bond-containing polycyclic ␲-electron system: Dithieno-1,2-dihydro-1,2-diborins and their dianionic species. Atsushi Wakamiya*,
Takafumi Araki, Kenji Mori,
Shigehiro Yamaguchi
10:10 – 185. Boraacenes and analogs: Syntheses, structures, and properties.
Warren Piers, Lauren G. Mercier,
Thomas K. Wood, Adrian Houghton,
Masood Parvez
10:50 – 186. Imaging, organizing and polymerizing pi-conjugated molecules on flat
surfaces. Dmitrii F. Perepichka*
11:10 – 187. Synthesis by ␲-expanded porphyrins and their use as sensitisers in
photochemical solar energy upconversion. Maxwell J. Crossley*,
Tony Khoury, Yuen Y. Cheng,
Raphael G. Clady, Murad J. Tayebjee,
N. J. Ekins-Daukes, Timothy W. Schmidt
118 –TECH
TECHNICAL PROGRAM
Hilton
Iolani I/II
Chemistry of Novel Nanocarbons Fullerenes, Carbon Nanotubes and Related
Materials (#45)
Organized by: T. Akasaka, Y. Li, F. Wudl
Presiding: L. Echegoyen, L. Dunsch
7:30 – 188. Functionalized carbon nanotubes: Versatile building blocks in nanomedicine and materials science.
Maurizio Prato*
8:15 – 189. Chirality dependent charge
transfer in carbon nanotubes.
Dirk M. Guldi*
8:45 – 190. Biomedical applications of endohedral metallofullerenes.
Harry C. Dorn
9:15 – 191. Role of fullerene cap structures
on the growth of single wall carbon nanotubes. Yohji Achiba*
9:45 – 192. Supramolecular-driven synthesis
and photophysical properties of a novel
phthalocyanine-C60 fullerene bisadduct
triad. Tomas Torres*, Giovanni Bottari,
Juan Antonio Suanzes Pita,
Olga Trukhina, Dirk Guldi
10:15 – 193. Maximum pentagon separation
rule: A guideline for the structures of endohedral metallofullerenes.
Josep M. Poblet*,
Antonio Rodríguez-Fortea, Núria Alegret,
Alan Balch
10:45 – 194. Molecular surgical approach to
endohedral fullerenes. Koichi Komatsu*
Hilton
Sea Pearl V/VI
The Science and Strategy of Process
Chemistry: From Molecules to
Pharmaceutical Drugs (#85)
Organized by: T. McDermott, S. Caron,
G. McLachlan, I. Shinkai
Presiding: T. McDermott
7:30 Introductory remarks
7:35 – 195. Discovery of tasocitinib citrate
(CP-690,550-10): A potent and selective
JAK inhibitor. Mark Flanagan
8:04 – 196. Process development of tasocitinib citrate (CP-690,550-10): A potent
and selective JAK inhibitor.
Mark Flanagan, Rajappa Vaidyanathan*
8:33 – 197. Targeting tumor angiogenesis:
Discovery of linifanib, a potent and orally
active angiogenesis inhibitor. Yujia Dai*
9:02 – 198. ABT-869: Development of a potent VEGF inhibitor. Albert Kruger*
9:31 – 199. Discovery and practical asymmetric synthesis of small molecule, nonpeptide inhibitor of LFA-1 (Part 1).
Rene Lemieux, Chris H. Senanayake
10:00 – 200. Discovery and practical asymmetric synthesis of small molecule, nonpeptide inhibitor of LFA-1 (Part 2).
Chris Senanayake
10:29 – 201. MK-7009: A potent hepatitis C
virus NS3/4A protease inhibitor.
Nigel J. Liverton, Cheng Chen
10:58 – 202. Chemical development of MK7009: A potent hepatitis C virus NS3/4A
protease inhibitor. Cheng Chen,
Nigel J. Liverton
11:27 Concluding remarks
Hilton
Coral V
New Dimensions of Green Sustainable
Chemistry: Novel Reactions and Catalysts
(#132)
Organized by: S. Kobayashi, P. Anastas,
T. Braish, M. Krische, C.J. Li
Presiding: C. Li
7:30 – 203. Bimetallic Au shell-Pd core
nanocatalysts for the selective aerobic
oxidation of allylic alcohols.
Adam F. Lee*, Christine Ellis,
James Naughton, Karen Wilson
7:45 – 204. Palladium-catalyzed direct oxidation of ␣,␤-unsaturated aldehydes with
hydrogen peroxide. Daisuke Imao,
Yoshihiro Kon, Takuya Nakashima,
Kazuhiko Sato*
8:00 – 205. Towards more sustainable
chemistries: Can flow chemistry help?
Steven V. Ley*
8:30 – 206. Aerobic oxidation of alcohols using nitroxyl radical catalysts.
Masatoshi Shibuya, Yuji Osada,
Masaki Tomizawa, Yoshiharu Iwabuchi*
8:45 – 207. Environmentally benign oxidations catalyzed by polymer incarcerated
metal nanocluster catalysts.
Hiroyuki Miyamura, Shu Kobayashi*
9:00 – 208. Flow chemistry and continuous
processing in the pharmaceutical industry. Joel M. Hawkins
9:30 – 209. Oxidation of alcohols with molecular oxygen catalyzed by reusable
nanoporous gold. Naoki Asao*,
Naoya Hatakeyama, Menggen Bateer,
Yoshinori Yamamoto, Mingwei Chen,
Wei Zhang, Akihisa Inoue
9:45 – 210. Development of one-pot sequential reaction system using resin-supported peptide catalyst.
Kengo Akagawa*, Kazuaki Kudo
10:00 – 211. Instantaneous cross-coupling
using catalytic membrane-installed microchannel devices. Yasuhiro Uozumi*
10:30 – 212. Biomass and carbon dioxide as
renewable resources for the chemical industry. Haruyuki Makio, Terunori Fujita*
Hilton
Honolulu II
Organic Solid-State Chemistry: Structure,
Synthesis & Reactivity (#155)
Organized by: R. Bishop,
M. Garcia-Garibay, R. Kuroda
Presiding: R. Kuroda
7:30 – 213. Structure-property relationships
of diyne-diol compounds. Len Barbour*,
Dinabandhu Das, Tia Jacobs
8:10 – 214. Reversible color switching organic zeolite composed of 4⫹4 cubic ion
pair cluster. Norimitsu Tohnai*,
Atsushi Yamamoto, Toshiyuki Sasaki,
Ichiro Hisaki, Mikiji Miyata
8:40 – 215. Synthesis and structure of different crystal forms of a simple achiral diol.
Isa Y. Chan, Roger Bishop*,
Mohan M. Bhadbhade,
Marcia L. Scudder
9:00 – 216. Recent progress in the design
and characterization of amphidynamic
materials and crystalline molecular machines. Miguel A. Garcia-Garibay*
9:30 – 217. Influence of UV light on the solidstate reactions and structural transformations. Jagadese J. Vittal
10:00 – 218. Photochromic modification in
cobaloxime complexes with salicylideneaminopyridine derivative as an axial base
ligand. Akiko Sekine*, Sayaka Ina,
Kohei Johmoto, Hidehiro Uekusa*
10:20 – 219. Azacalix[5]arene pentamethyl
tther: Synthesis, crystal structure, and
gas adsorption behavior under ambient
condition. Hirohito Tsue*, Kohei Ono,
Satoshi Tokita, Koichi Ishibashi,
Kazuhiro Matsui, Kazuyuki Miyata,
Hiroki Takahashi, Rui Tamura
10:50 – 220. Road from Dutch Resolution as
new resolution method to attrition induced grinding. Richard M. Kellogg*
Hilton
Honolulu I
Carbanions: Modern Perspectives in
Structure, Reactivity, and Synthesis (#229)
Organized by: B. Gawley, V. Snieckus,
K. Tomioka
Presiding: F. Fleming
7:30 – 221. Reaction mechanisms of alkyland aryllithium reagents with carbonyl
compounds. Kristin N. Plessel,
Amanda C. Jones,
Rebecca Maksymowicz, Hans J. Reich*
8:10 – 222. Catalytic dynamic resolution of
chiral organolithiums. Bob Gawley*
8:50 – 223. Kinetics of enantiomerization
and resolution of N-Boc-2-lithiopiperidine. Timothy K. Beng*, Robert Gawley
9:10 – 224. Functionalized scalemic alphachloroalkyllithiums in the stereospecific
reagent controlled homologation of boronic esters toward polycyclic targets.
Paul Blakemore*, Christopher Emerson
9:40 – 225. Enantioselective direct Mannichtype reaction catalyzed by chiral lithium
complexes. Kazuaki Ishihara*,
Manabu Hatano, Takahiro Horibe
10:10 – 226. Selective generation of carbanion using organic superbase.
Yoshinori Kondo*
10:50 – 227. Structure-reactivity relationships in the chemistry of lithium diisopropylamide: Discussions of the role of catalysis and autocatalysis of deaggregation.
David B. Collum
Hilton
Sea Pearl I/II
Interface between Organic Synthesis and
Chromatography (#19)
Organized by: C. Welch, W. Farrell,
M. Hyun, A. Rajendran
Presiding: M. Hyun
8:00 – 228. Synthesis of crown ether-based
and ligand exchange chiral stationary
phases and their applications.
Myung H. Hyun*
8:30 – 229. Synthesis and characterization of
novel polysaccharide-based chiral packing materials. Yoshio Okamoto*,
Tomoyuki Ikai, Junqing Li, Jun Shen
9:00 – 230. On the mechanism of chiral recognition by cellulose tris(4-methylbenzoate). Tohru Shibata*, Kazuyoshi Ueda
9:30 – 231. Solvent programmable polymers
for separations applications.
Ken D. Shimizu*, Yagang Zhang
10:00 – 232. Synthetic strategies for new
chromatographic stationary phases.
Christopher Welch*
10:30 – 233. Supporting medicinal chemistry
through high throughput achiral supercritical fluid chromatography, an orthogonal approach to reversed phase liquid
chromatography. Warren B. Potts*,
Andy Aubin*, Rui Chen*,
Harbaksh Sidhu*
11:00 – 234. Cyclofructans: New chiral selectors for separations, e e. determinations, and possibly synthesis.
Daniel W. Armstrong
Hilton
South Pacific IV
New Directions of Supramolecular
Chemistry toward Nanomaterial Science,
Biomedical Science, and Supramolecular
Catalysts (#47)
Organized by: S. Aoki, W. Chung,
J. Davis, T. Haino
Presiding: S. Aoki, J. Davis
8:00 – 235. Supramolecular analytical chemistry. Eric V. Anslyn*
8:25 – 236. Array-based sensing of proteins
and cells using nanoparticle-polymer/
biopolymer conjugates. Uwe Bunz,
Vincent Rotello*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
8:50 – 237. Module assembly for disrupting
protein-protein interactions and dual inhibition of prenyltransferases.
Junko Ohkanda*, Shinnosuke Machida,
Chiaki Oura, Kazuo Harada, Nobuo Kato
9:05 – 238. Calixarene derivatives that recognize methylated lysines on the surfaces
of proteins and disrupt a key cancercausing protein-protein interaction.
Fraser Hof*
9:20 – 239. Synthetic lectins.
Anthony P. Davis
9:35 – 240. Photo-conversion of higher-order structures composed of peptide amphiphiles and its biological application.
Takahiro Muraoka*, Honggang Cui,
Chung Y. Koh, Samuel I. Stupp
9:50 – 241. Umbrella-rotaxane: Toward new
transporters for cyclic drugs delivery.
Christine Chhun*, Andreea R. Schmitzer
10:05 – 242. Budding and fission of artificial
cell membrane triggered by a chemical
stimulus. Kazuma Yasuhara*,
Zhonghua Wang, Hiroshi Ito,
Hiroyuki Noriyasu, Jun-ichi Kikuchi
10:20 – 243. Supramolecular assembly by
metal-ligand coordinations for molecular
recognition and catalytic reactions in
aqueous solution. Shin Aoki
10:45 – 244. Self-assembly of peptide hybrids. Jon R. Parquette
Hilton
Coral IV
Novel Synthetic Methodology and Its
Application to Natural Product Synthesis
(#63)
Organized by: F. West, V. Rawal,
M. Toyota
Presiding: F. West
8:00 – 245. Studies in complex molecule
synthesis: Indoles, indolines, and indolynes. Neil Garg*
8:20 – 246. Application of chemoenzymatic
and other methods to the synthesis of biologically active natural products.
Martin G. Banwell*
9:05 – 247. Expedient oxidative dearomatization approaches toward complex
bridged bicyclic natural products.
Jon T. Njardarson
9:35 – 248. New approaches toward prenylated pyrroloindole natural products.
Rajesh Viswanathan*
9:55 – 249. Bistramides: Specific and potent
small-molecule agents that target actin
cytoskeleton. Sergey Kozmin
10:40 – 250. Step economy and function oriented synthesis: Strategies for eradicating HIV/AIDS, overcoming cancer resistance, and treating Alzheimer’s disease.
Paul A. Wender*
10:10 – 256. Two-component liquid crystals
as chiral reaction media: Highly enantioselective photodimerization of an anthracene derivative driven by the ordered micro-environment. Yasuhiro Ishida,
Achalkumar Ammathnadu Sudhakar,
Kazuhiko Saigo
10:40 – 257. Cation-␲ controlled solid-state
photodimerization of alkenylpyridines.
Shinji Yamada*, Yuka Nojiri
11:00 – 258. Supramolecular photochirogenesis with biomolecular hosts.
Masaki Nishijima, Cheng Yang,
Tadashi Mori, Takehiko Wada,
Kazuki Bando, Tamotsu Zako,
Masafumi Sakono, Mizuo Maeda,
Tamara Pace, Cornelia Bohne,
Yoshihisa Inoue*
14:10 – 271. Progress toward the chemical
synthesis of single-chirality carbon nanotubes. Lawrence T. Scott*
14:50 – 272. Quadrannulene: synthesis and
properties of a [4]circulene.
Benjamin T. King*
15:10 – 273. New pi systems containing 1,8pyrenylene units. Graham J. Bodwell*,
Venkataramana Gandikota,
Kiran S. Unikela, Simon Brake
15:30 – 274. Synthesis of new 3-D host molecules: Construction of organic tubes
and capsules and their inclusion phenomena. Teruo Shinmyozu*
16:10 – 275. Development of electronegative
␲-conjugated systems toward n-type organic field-effect transistor materials.
Yutaka Ie, Yoshio Aso
Hilton
South Pacific III
Hilton
Iolani I/II
Metal Catalysis for Asymmetric Synthesis
(#282)
Chemistry of Novel Nanocarbons Fullerenes, Carbon Nanotubes and Related
Materials (#45)
Organized by: H. Sasai, A. Charette,
H. Davies, D. Yang
Presiding: H. Sasai, Y. Dan
8:00 – 259. Enantioselective oxidative coupling of 2-naphthols using dinuclear vanadium complex. Shinobu Takizawa,
Tomomi Katayama, Rajesh Doss,
Hiroaki Sasai*
8:20 – 260. Partially hydrolysed titanium
alkoxides as remarkable precatalysts in
the enantioselective synthesis of chiral intermediates. Abdul Majeed Seayad,
Balamurugan Ramalingam,
Kazuhiko Yoshinaga, Takushi Nagata,
Christina L. Chai*
8:40 – 261. Enantioselective aerobic oxidation of doubly activated secondary alcohols and synergistic ion specific transport
by chiral vanadyl(V) complexes.
Chien-Tien Chen*, Ya-Hui Lin*,
Santosh Salunke*, Jun-Qi Kao*,
Shiue-Shien Weng*
9:10 – 262. Stereoselective aziridination of
alkenes. Helene Lebel*
9:40 – 263. Combined coinage metal catalysis for the synthesis of bioactive molecules. Norbert Krause*
10:00 – 264. Asymmetric C-C bond-formation via Cu(I)-catalyzed activation of
C-nucleophiles. Motomu Kanai*
10:30 – 265. Copper-catalyzed boron addition reactions to unsaturated carbon-carbon bonds. Jaesook Yun*
11:00 – 266. Pd-catalyzed asymmetric synthesis of unfunctionalized axially chiral allenic hydrocarbons.
Masamichi Ogasawara*,
Hidetoshi Murakami, Tamotsu Takahashi*
Thursday Afternoon
Hilton
Honolulu III
Supramolecular Photochemistry (#125)
Organized by: Y. Inoue, C. Bohne,
V. Ramamurthy, C. Tung
Presiding: K. Yoon, H. Sleiman
8:00 – 251. Mechanisms for dark and lightactivated antimicrobial activity of poly(phenyleneethynylenes) and oligo(phenyleneethynylenes). David G. Whitten*,
Ying Wang, Zhijun Zhou, Linnea Ista,
Thomas Corbitt, Eunkyung Ji,
Anand Parthasarathy, Gabriel P. Lopez,
Kirk S. Schanze
8:30 – 252. Critical stereocontrol of chiral
photocyclodimerization of 2-anthracenecarboxylate through combined use of ␣and ␥-cyclodextrins as scaffold and host.
Cheng Yang*, Yoshihisa Inoue*
8:50 – 253. Syntheses and photochromic
properties of terarylene derivatives having
intra- and inter-molecular interactions.
Tsuyoshi Kawai*
9:20 – 254. Withdrawn
9:50 – 255. Withdrawn
Hilton
South Pacific II
Designed pi-Electronic Systems: Synthesis,
Properties, Theory and Function (#29)
Organized by: M. Haley, G. Bodwell,
T. Kubo, Y. Tobe
Presiding: Y. Tobe
12:30 – 267. New soluble and stable NIR
dyes based on polycyclic aromatics.
Chongjun Jiao, Kai Zhang, Jinling Li,
Junhong Yao, Xiaojie Zhang, Jishan Wu*
12:50 – 268. Hexaradialenes via successive
ring openings of trisalkoxytricyclobutabenzenes: Synthesis, reactivity, and
characterization. Toshiyuki Hamura,
Shinya Shinozaki, Keisuke Suzuki
13:10 – 269. From molecules to materials.
Colin Nuckolls*
13:50 – 270. Solution-stability and optical
resolution of triply-helical metal complexes of quaterimidazole.
Yasushi Morita*, Yumi Yakiyama,
Tsuyoshi Murata, Tomoaki Ise,
Kazunobu Sato, Takeji Takui,
Kazuhiro Nakasuji
Organized by: T. Akasaka, Y. Li, F. Wudl
Presiding: J. Nierengarten, H. Dorn
12:30 – 276. Synthetic approach to carbonrich materials incorporating nanochannels: Toward a synthesis of carbon nanotubes. Mitsuharu Suzuki, Yves Rubin*
13:00 – 277. ESR UV-Vis-NIR spectroelectrochemistry of a derivatised endohedral
fullerene: The special case of
Sc3N@C80(CF3)2. Lothar Dunsch*,
Alexey Popov, Natalia Shustova,
Mary Mackey, Curtis Cumbe,
Paige Philips, Steven Stevenson,
Steven Strauss, Olga Boltalina
13:30 – 278. Novel structure of endohedral
fullerenes. Chun-Ru Wang*
13:50 – 279. Precise control of supramolecular interactions between fullerenes
and metalloporphyrins: Applications for
molecular and materials sciences of carbon nanoclusters. Kentaro Tashiro*,
Takuzo Aida
14:10 – 280. Switchable open-cage
fullerenes as molecular water container.
Liangbing Gan*, Dazhi Yang,
Qianyan Zhang
14:30 – 281. Carbon nanostructures for photochemistry and solar energy conversion.
Hiroshi Imahori*
14:50 – 282. Synthesis, isolation and properties of Sm-containing endohedral metallofullerenes. Zujin Shi*, Jia Liu,
Zhenan Gu
15:10 – 283. Donor-acceptor conjugates of
lanthanum endohedral metallofullerene,
La2@C80, and ␲-extended tetrathiafulvalene. Yuta Takano*,
M. Ángeles Herranz, Nazario Martín,
Shankara Gayathri Radhakrishnan,
Dirk M. Guldi, Takahiro Tsuchiya,
Takeshi Akasaka, Shigeru Nagase
15:30 – 284. Exploring the exohedral reactivity of TNT endohedral metalloFullerenes
(EMFs): The encapsulation effect and the
fullerene strain energy. Sílvia Osuna,
Marcel Swart*, Josep Maria Poblet,
Miquel Solà*
15:50 – 285. Production and purification of
N@C60. Tomonari Wakabayashi*,
Airi Yoshikawa
16:10 – 286. Functionalization of singlewalled carbon nanotubes with well-defined, functional polymers.
Alex Adronov*, Nicole Rice, Patigul Imin,
Ryan Chadwick
Hilton
Sea Pearl V/VI
The Science and Strategy of Process
Chemistry: From Molecules to
Pharmaceutical Drugs (#85)
Organized by: T. McDermott, S. Caron,
G. McLachlan, I. Shinkai
Presiding: S. Caron
12:30 Introductory remarks
12:35 – 287. Beyond the Simmons-Smith reagent: The development of new zinc carbenoid reagents and their use in the cyclopropanation of alkenes.
Andre Charette*
13:13 – 288. Development of iodomethylzinc
phosphates as cyclopropanating agents
in the synthesis of novel hedgehog pathway antagonists. Julian Adams,
Brian C. Austad*, Mark L. Behnke,
Alfredo C. Castro, Matt Campbell,
Jeanne Ferguson, Michael A. Foley,
Michael J. Grogan, Andrew Hague,
Louis Grenier, Joseph C. Helble,
Priscilla Lo, Caroline Lory,
Somarajan J. Nair, Stephane Peluso,
James R. Porter, Martin R. Tremblay,
Lin-Chen Yu, André Charette
13:51 – 289. Asymmetric cyclization via axially chiral enolates at ambient temperature. Takeo Kawabata*
14:29 – 290. Synthesis of a poly(ADP-ribose)polymerase inhibitor utilizing a memory
of chirality cyclization.
Lawrence Kolaczkowski*,
Jufang H. Barkalow, David M. Barnes,
Anthony R. Haight
15:07 – 291. Rhodium-catalyzed asymmetric
alkynylations. Takahiro Nishimura*,
Tamio Hayashi*
15:45 – 292. Practical asymmetric conjugate
alkynylation of Meldrum’s acid derived
acceptors: Access to chiral ␤-alkynyl acids. Shawn D. Walker*, Sheng Cui*,
Jacqueline C. Woo,
Christopher J. Borths,
Herschel Mukherjee, Maosheng J. Chen,
Margaret M. Faul
16:23 Concluding remarks
Hilton
Honolulu III
Supramolecular Photochemistry (#125)
Organized by: Y. Inoue, C. Bohne,
V. Ramamurthy, C. Tung
Presiding: W. Nau, Y. Ishida
12:30 – 293. Intramolecular dimer radical
cation and anion of [3n]cyclophanes.
Mamoru Fujitsuka, Tetsuro Majima*
13:00 – 294. Photochromism and enhanced
emission of amphiphilic organic dyes
self-assembled in water.
Kenji Matsuda*, Takashi Hirose
13:20 – 295. Efforts to materialize artificial
photosynthesis. Kyung Byung Yoon*
13:50 – 296. Novel strategy of supramolecular asymmetric photochirogenesis with
tailor-made biomolecular interfaces as
chiral reaction fields. Takehiko Wada*,
Yui Sugawara, Masaki Nishijima,
Mihoko Ui, Kazushi Kinbara,
Kohei Tsumoto, Yasuyuki Araki,
Seiji Sakamoto, Yoshihisa Inoue
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–119
04-ORGN
14:10 – 297. DNA as a programmable template to organize photoactive materials.
Hanadi Sleiman*, Hua Yang,
Pik Kwan P. Lo,
Christopher K. McLaughlin,
Yongqiang Wen, Graham Hamblin
14:40 – 298. Synthesis and characterization
of new spirooxazine based on
calix[4]arenes. Jianying Wang*,
Changgen Feng, Qingxuan Zeng,
Guangyou Zhang
15:00 – 299. Binding dynamics of 1-(2-naphthyl)ethylammonium cation with
cucurbit[7]uril. Hao Tang,
Denis Fuentealba, Young Ho Ko,
Narayanan Selvapalam, Kimoon Kim,
Cornelia Bohne*
15:30 – 300. Photofunctional materials: From
simple molecules to supramolecular assemblies. Vivian W. Yam*
16:00 – 301. Self-assembled coordination
cages and networks as photoreactors.
Makoto Fujita*
Hilton
Coral V
New Dimensions of Green Sustainable
Chemistry: Novel Reactions and Catalysts
(#132)
Organized by: S. Kobayashi, P. Anastas,
T. Braish, M. Krische, C.J. Li
Presiding: T. Braish
12:30 – 302. Cascade reactions for sustainable conversion of fatty acid methyl esters. Simon Desset*,
Thomas Hermanns,
Jürgen Klankermayer, Walter Leitner
12:45 – 303. Chemical and biotechnological
approaches to rare sugars as practical
chirons for organic synthesis.
Daniel Best,
Alexander C. Weymouth-Wilson,
Akihide Yoshihara, Ken Izumori,
Francis X. Wilson, George W. Fleet
13:00 – 304. Greener, biocatalytic manufacturing of sitagliptin. John H. Grate
13:30 – 305. Development of dialkyl carbonate intermediates in the diphenyl carbonate process using CO2.
Budianto Bijanto, Masaaki Shinohata,
Nobuhisa Miyake
13:45 – 306. Application of dioxygen in transition metal catalyzed reactions.
Ning Jiao*, Zhuangzhi Shi, Chun Zhang
14:00 – 307. Preparation of chiral amines
and amino acids by biocatalysis.
Ronald L. Hanson*
14:30 – 308. Development of innovative
technologies for reducing environmental
loads for advanced utilization of chitin resources: Effect of hydrothermal treatment
on enzymatic degradation of chitin.
Mitsumasa Osada*, Chika Miura,
Yuko Nakagawa, Mikio Kaihara,
Mitsuru Nikaido, Kazuhide Totani
14:45 – 309. Chemo-and biocatalysis in ionic
liquids: One-pot two steps synthesis of
enantiomerically pure biaryl alcohols.
Vincent Gauchot*, Andreea Schmitzer*,
Wolfgang Kroutil
15:00 – 310. Explore new reactivities for synthetic efficiency. Chao-Jun Li*
15:30 – 311. One-pot synthesis in total synthesis of (-)-oseltamivir. Yujiro Hayashi*
16:00 – 312. Why select alternative chemical
synthetic routes: The role of green chemistry in the design, synthesis and use of
novel, nitrogen heterocyclic drug candidates. Milton T. Hearn*
Hilton
Honolulu I
Carbanions: Modern Perspectives in
Structure, Reactivity, and Synthesis (#229)
Organized by: B. Gawley, V. Snieckus,
K. Tomioka
Presiding: V. Snieckus
12:30 – 313. Design, reactivities, and function of organozincate reagents.
Masanobu Uchiyama
120 –TECH
TECHNICAL PROGRAM
13:10 – 314. Consecutive aminolithiationcarbolithiation of olefins.
Kiyoshi Tomioka*, Tokutaro Ogata,
Susumu Tsuchida, Hiromi Baba,
Atsunori Kaneshige, Ken-ichi Yamada,
Yasutomo Yamamoto
13:50 – 315. Theoretical/computational
study on the gem-dizinc mediated reaction. Shinsuke Komagawa,
Taniyuki Furuyama,
Masanobu Uchiyama*, Mutsumi Sada,
Seijiro Matsubara*
14:10 – 316. NMR studies of a ternary complex reagent of lithium ester enolate,
chiral diether, and lithium diisopropylamide in an asymmetric Michael reaction.
Yasutomo Yamamoto,
Yorinobu Yasuda, Hiroyuki Nasu,
Kiyoshi Tomioka*
14:40 – 317. Catalytic asymmetric allylic arylation by chiral NHC-Cu catalyst and aryl
Grignard reagents. Ken-ichi Yamada,
Khalid B. Selim, Hirotsugu Nakanishi,
Kiyoshi Tomioka*
15:10 – 318. Tandem reaction initiated by
1,4-addition of bis(iodozincio)methane for
1,3-diketone formation.
Seijiro Matsubara*
15:50 – 319. Nucleophilic addition reactions
to pyridinium and iminium salts: Expedient access to indolizidine alkaloids and
other useful chiral building blocks.
Andre Charette*
13:10 – 330. Development of luminescence
probes for target ions. Jong Seung Kim*,
Young Hoon Lee, Hyun Jung Kim,
Hyo Sung Jung, Yeon Ok Lee,
Min Hee Lee
13:35 – 331. Macrocyclic reagents for chiral
discrimination in NMR. Tadashi Ema*,
Daisuke Tanida, Kazuki Hamada,
Toshinobu Korenaga, Takashi Sakai
13:50 – 332. Calixarene-based assembly of
functional nanomaterials: Chiral gold
nanoparticles and amines confined in
chiral pockets. Andrew Solovyov*,
Jeong-Myeong Ha, Alexander Katz
14:05 – 333. Molecular balance for measuring noncovalent interactions.
Ken D. Shimizu
14:20 – 334. Synthesis of DNA oligo-catenane by photoligation. Takeaki Uehara,
Kenzo Fujimoto, Yuichi Ohya
14:35 – 335. Porous nanocapsules with “invisible” walls. Eugene Pinkhassik*
14:50 – 336. Reactions inside and outside of
water-soluble nano-capsules.
Bruce Gibb, Corinne Gibb, Simin Liu
15:15 – 337. Design and synthesis of metallo-supramolecular systems with cooperative and responsive functions.
Tatsuya Nabeshima*
15:40 Concluding remarks
Hilton
South Pacific III
Novel Synthetic Methodology and Its
Application to Natural Product Synthesis
(#63)
Metal Catalysis for Asymmetric Synthesis
(#282)
Organized by: H. Sasai, A. Charette,
H. Davies, D. Yang
Presiding: H. Davies, D. Yang
12:30 – 320. Asymmetric catalytic N-phosphonyl imine chemistry: The use of metalamino acid complexes as catalysts and
metal cyanides for asymmetric catalytic
strecker reaction. Guigen Li,
Parminder Kaur, Suresh Pindi,
Walter Wever, Trideep Rajale
12:50 – 321. Formation of C-C bonds via
catalytic hydrogenation and transfer hydrogenation. Michael J. Krische*
13:20 – 322. Intertwined nature of chemical
synthesis and the discovery process.
Brian M. Stoltz
13:50 – 323. Synthesis, resolution and asymmetric applications of 3,3’-disubstituted
BINAP and xylBINAP derivatives.
Danica A. Rankic, Daniela Lucciola,
J. M. Hopkins, Brian A. Keay*
14:10 – 324. Enantioselective ortho-lithiation
for the synthesis of planar-chiral paracyclophanes. Kazumasa Kanda,
Kohei Endo, Takanori Shibata*
14:30 – 325. C—H oxidation and organic
synthesis. M. Christina White*
15:00 – 326. Enantioselective rhodium(II)catalyzed cyclopropanation of alkenes
with ␣-EWG diazoacetophenones: PMPketones as stereoselectivity controllers.
Vincent Lindsay*, André B. Charette
15:20 – 327. Novel oxidative asymmetric cyclizations promoted by Pd-SPRIX catalyst. Hiroaki Sasai*
15:50 – 328. Enantioselective C-C bond formation using new camphor derived chiral
ligands. Biing-Jiun Uang*
Hilton
South Pacific IV
New Directions of Supramolecular
Chemistry toward Nanomaterial Science,
Biomedical Science, and Supramolecular
Catalysts (#47)
Organized by: S. Aoki, W. Chung,
J. Davis, T. Haino
Presiding: W. Chung, T. Haino
12:45 – 329. Chromogenic and fluorogenic
sensing of heavy metal ions based on
calix[4]arenes functionalized by 1,3-dipolar cycloadditions. Wen-Sheng Chung*,
I-Ting Ho, Kai-Chi Chang,
Annamalai Senthilvelan
Hilton
Coral IV
Organized by: F. West, V. Rawal,
M. Toyota
Presiding: M. Banwell
12:45 – 338. Synthesis of bioactive alkaloids
via a samarium diiodide-promoted reductive carbon-nitrogen bond cleavage reaction. Toshio Honda*
13:30 – 339. Development and application of
oxidative bond forming reactions of silyl
bis-enol ethers. Regan J. Thomson*
14:00 – 340. New synthetic methods and
new process discovery with [3,3]-sigmatropic rearrangements (33SRs) of N,O-diacyl hydroxylamines and related systems.
Patrick Perlmutter*, Helen R. Lagiakos,
Craig Forsyth, Neeranat Thienthong,
Marie-Isabel Aguilar
14:20 – 341. Homogenous Lewis and Brønsted acid catalyzed strategies for carbocycle and N-heterocycle synthesis.
Philip W. Chan
14:40 – 342. Synthetic studies toward
N-methylwelwitindolinone C isothiocyanate. Viresh Rawal*
15:25 – 343. Nodulisporic acid A synthetic
studies: Application of a novel BuchwaldHartwig/Heck cascade to unite the eastern and western hemispheres.
Amos B. Smith*
16:10 – 344. Synthetic studies toward antascomicin B. Matt McIntosh*
Hilton
Honolulu II
Supramolecular Catalysis (#280)
Organized by: J. Parquette, J. Badjic,
M. Organ, Q. Zhou
Presiding: J. Badjic
12:50 Introduction
12:55 – 345. Complementary double-helical
molecules that catalyze asymmetric reactions. Eiji Yashima*, Yoshio Furusho
13:25 – 346. Facile synthesis and characterization of zinc(II)-included hemicryptophanes. Yoshimasa Makita*,
Shin-ichi Fujiwara, Akiya Ogawa
13:55 – 347. Host-guest complexes with ␣and ␤-cyclodextrins: A versatile strategy
to assemble efficient catalysts.
Andreea R. Schmitzer*, Loic Leclercq,
Mathieu Lacour, Samantha H. Sanon
14:25 – 348. Conformational control, remote
chirality transfer and asymmetric induction in dendritic catalysis.
T. V. RajanBabu*, Jon Parquette,
Jianfeng Yu
14:55 – 349. Selective hydrolysis of phosphate monoester in aqueous solution by
supramolecular catalysts formed by selfassembly of bipyridyl-appended
bis(Zn2⫹-cyclen) complex, cyanurate,
and copper (cyclen ⫽ 1,4,7,10-tetraazacyclododecane). Shin Aoki*,
Mohd Zulkefeli Mat Jusoh, Motoo Shiro
15:25 – 350. Dendronized fluorinated alcohols as catalysts for the epoxidation of
alkenes with hydrogen peroxide.
Albrecht Berkessel*, Jan Krämer,
Rainer Haag, Florian Mummy
15:55 – 351. Enhanced reactions in helical
aromatic oligoamide foldamers.
Ivan Huc*
Hilton
Sea Pearl I/II
Interface between Organic Synthesis and
Chromatography (#19)
Organized by: C. Welch, W. Farrell,
M. Hyun, A. Rajendran
Presiding: A. Rajendran
13:00 – 352. Large scale industrial chromatography. Georges Guiochon*
13:35 – 353. Integration of chiral chromatography in chemical development and
cGMP synthesis. Yvan Ruland*,
Jeff Marcoux*
14:10 – 354. Continuous preparative chromatography to obtain enantiomers of antineoplastic agent mitotane using Simulated Moving Bed (SMB) and varicol.
Cesar C. Santana*, Absolon C. da Silva,
Airton G. Salles, Quezia B. Cass,
Carlos Roque D. Correia
14:45 – 355. Comparison of chromatographic and synthetic routes to manufacture chiral thiourea. Larry Miller*,
Karl Hansen, Seb Callie
15:20 – 356. Rational design of preparative
supercritical fluid chromatography.
Wenda Chen, Reza Hagpanah,
Mohammand Aman Ullah,
Arvind Rajendran*
15:55 – 357. Investigation of a continuous
chromatographic purification process via
simulated moving bed chromatography
for an api route evaluation.
Carlos A. Orihuela*,
Michael Rasmussen, Alex Chu-Kung,
Timothy Towne, Robert Miller
Thursday Evening
Hilton
South Pacific II
Designed pi-Electronic Systems: Synthesis,
Properties, Theory and Function (#29)
Organized by: M. Haley, G. Bodwell,
T. Kubo, Y. Tobe
Presiding: M. Haley
19:00 – 358. Relative aromaticities of the cyclic C7 and C8 neutral, anionic, and cationic species determined by dihydropyrene annelation. Reginald H. Mitchell,
David J. Berg, Pengrong Zhang
19:15 – 359. Azulenocyanine: A new family
of phthalocyanines with intense near-IR
absorption. Atsuya Muranaka*,
Mitsuhiro Yonehara, Nagao Kobayashi,
Masanobu Uchiyama
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
19:30 – 360. Synthesis of pyrene based difurans, cyclophanes, and polyarenes.
David Franz, Peter Dibble*
19:45 – 361. Modular synthesis of 1H-indene, dihydro-s-indacene derivatives and
ladder-type oligo(phenylenevinylene)s as
new ambipolar materials.
Xiaozhang Zhu*, Chikahiko Mitsui,
Hayato Tsuji*, Eiichi Nakamura*
20:00 – 362. Reduced dimensionality in organic nonlinear optical materials.
Stephanie J. Benight, Lewis E. Johnson,
Daniel B. Knorr, Rene M. Overney,
Bruce E. Eichinger, Bruce H. Robinson,
Larry R. Dalton*
20:15 – 363. Spin-unrestricted density functional theory study on the electronic
structures and optical properties of openshell extended ␲-conjugated systems.
Ryohei Kishi*, Masayoshi Nakano*,
Hitoshi Fukui, Kyohei Yoneda,
Takashi Kubo, Kenji Kamada, Koji Ohta,
Edith Botek, Benoît Champagne
20:30 – 364. Synthesis of new ladder and
semi-ladder polymers based on indolocarbazole for Organic Field Effect Transistors. Nicolas Cocherel*,
Oscar Navarro, Michael Turner
20:45 – 365. Well-defined luminescent fluoreneborane oligomers and macrocycles.
Pangkuan Chen, Frieder Jaekle*
21:00 – 366. Emission enhancement and
quenching by low-molecular thyophene
derivatives. Koji Miyamoto,
Hirokuni Jintoku, Tsuyoshi Sawada,
Makoto Takafuji, Takashi Sagawa,
Hirotaka Ihara*
Hilton
Coral I
Chemistry of Novel Nanocarbons Fullerenes, Carbon Nanotubes and Related
Materials (#45)
Organized by: T. Akasaka, Y. Li, F. Wudl
Presiding: Y. Rubin
19:00 – 367. Stabilization of fused-pentagon
fullerenes by chlorination. Su-Yuan Xie*,
Lan-Sun Zheng, Rong-Bin Huang
19:20 – 368. Production yields in metallofullerene series: Free-metal ionization
potentials as governing parameters.
Zdenek Slanina*, Takeshi Akasaka,
Shigeru Nagase
19:40 – 369. Transition metal complexes of
the Li@C60 cation: Synthesis and structure determination. Takahito Watanabe,
Takashi Komuro, Masato Itoh,
Hiromi Tobita*, Hiroshi Okada,
Takeshi Sakai, Yoshihiro Ono,
Yasuhiko Kasama
20:00 – 370. Spectroscopic identification of
bond strain and ␲ interactions in a series
of saturated carbon-cage molecules:
Adamantane, twistane, octahedrane, and
cubane. Trevor M. Willey*,
Jonathan R. Lee, Dan Brehmer,
Lasse Landt, P. R. Schreiner, A. A. Fokin,
B. A. Tkachenko, N. A. Fokina,
T. van Buuren
20:20 – 371. High-yield synthesis and characterization of nitrogen atom encapsulated fullerene by using a nitrogen RFplasma technique. Soon Cheon Cho*,
Toshiro Kaneko, Sunao Miyanaga,
Rikizo Hatakeyama
20:40 – 372. Fabrication of CaCO3/SWNTs
nanocomposite using fullerodendron-assisted approach. Tomoyuki Tajima,
Akira Tsutsui, Yutaka Takaguchi*
Hilton
Coral IV
Novel Synthetic Methodology and Its
Application to Natural Product Synthesis
(#63)
Organized by: F. West, V. Rawal,
M. Toyota
Presiding: F. West
19:00 – 373. Some new Nazarov chemistry.
Marcus A. Tius*, Ashok K. Basak,
Naoyuki Shimada, William F. Bow,
David A. Vicic
19:45 – 374. Use of spirolacotonyltetralones
as key intermediates for natural product
synthesis. Ishikawa Tsutomu*,
Akagi Yuhsuke, Yamada Shin-ichiro,
Etomi Natsuno, Kumamoto Takuya,
Nakanishi Waka
20:30 – 375. Zinc carbenoid-mediated approach to the papyracillic acids.
Charles Zercher*, Jennifer Mazzone
Hilton
South Pacific I
The Science and Strategy of Process
Chemistry: From Molecules to
Pharmaceutical Drugs (#85)
Organized by: T. McDermott, S. Caron,
G. McLachlan, I. Shinkai
Presiding: T. Watson
19:00 – 376. Regulatory roundtable discussion: API around the Pacific Rim.
Todd McDermott, Timothy Watson,
Okuda Haruhira, Frank Montgomery,
John Lepore, Moheb Nasr
Convention Center
Kamehameha Halls II and III
Organic Solid-State Chemistry: Structure,
Synthesis & Reactivity (#155)
Organized by: R. Bishop,
M. Garcia-Garibay, R. Kuroda
Presiding: R. Bishop, R. Kuroda,
M. Garcia-Garibay
Poster Session
19:00 – 21:00
377. Application of preferential enrichment
to amino acids with a racemic crystal
structure. Sekai Iwama*,
Rajesh G. Gonnade, Masahiro Horiguchi,
Hiroki Takahashi, Hirohito Tsue,
Rui Tamura
378. Mechanofluorochromism of heteropolycyclic donor-␲-acceptor fluorescent
dyes. Yousuke Ooyama*,
Hiroshi Fukuoka, Kenji Komaguchi,
Ichiro Imae, Yutaka Harima
379. Structure and mechanism of tunnel water dehydration of Cephalexin investigated by powder X-ray diffraction.
Masahide Aoki, Hidehiro Uekusa*
380. Spontaneous enantiomeric resolution of
DL-phenylalanine-fumaric acid co-crystals based on a preferential enrichment
protocol. Rajesh Gonnade*, Sekai Iwama,
Mori Yuko, Hiroki Takahashi,
Hirohito Tsue, Rui Tamura
381. Control of relationship between conformational and color conformational and
color polymorphism of sulfide compound
with 2-methyl-1,4-naphthoquinone unit.
Takafumi Kinuta, Takunori Harada,
Nobuo Tajima, Tomohiro Sato,
Reiko Kuroda, Yoshio Matsubara,
Yoshitane Imai*
382. Study on the inclusion complex of 2,2’bis(diphenylphosphinoyl)-1,1’-binaphthyl
and derivatives. Kazuyuki Hashimoto,
Bunpei Hatano*, Tatsuro Kijima
383. Polymorphs and pseudopolymorphs of
solvated crystals of indantrione-1,2-dioxime. Mitsuaki Suzuki, Keiji Kobayashi*
384. Definition of right- (supR, supP) and
left-handedness (supS, supM) on three
types of chiral hydrogen bond networks
composed of primary ammonium carboxylates. Toshiyuki Sasaki,
Norimitsu Tohnai, Ichiro Hisaki,
Mikiji Miyata*
385. Column structures of salts between carboxylic acids and amino acid amides
having a trityl group and their application
for optical resolution of carboxylic acids.
Ken Megumi, Shoji Matsumoto,
Motohiro Akazome*
386. Withdrawn
387. Synthesis of the dimethyl-substituted
TTF-DT-fused donors and electrical conductivity of their molecular conductors.
Atsushi Wada, Hiroki Akutsu,
Shin’ichi Nakatsuji, Jun-ichi Yamada*
388. Synthesis of the bis(methylthio)-substituted ␲-electron donors: Toward control
of electron correlation. Kohei Fujikawa,
Kazuhiro Takeuchi, Hiroki Akutsu,
Shin’ichi Nakatsuji, Jun-ichi Yamada*
389. Selection of 21 axes and determination
of right- and left-handedness of 21 helices in crystalline structure of Cinchona
alkaloids. Kazuaki Sakaguchi*,
Ichiro Hisaki, Norimitsu Tohnai,
Mikiji Miyata
390. Toward 2D polymers using designed
monomers based on 1,8-anthrylenes.
Patrick Kissel, A. D. Schlüter*,
Junji Sakamoto*
391. Structures and properties of some ferrocene-containing compounds.
Kazuya Fujiwara, Hiroki Akutsu,
Jun-ichi Yamada, Masaharu Satoh,
Shin’ichi Nakatsuji
392. Polymorphism of
octadehydrotribenzo[14]annulene with
methyl ester groups and superstructuredependent optical properties.
Eriko Kometani, Ichiro Hisaki,
Norimitsu Tohnai, Mikiji Miyata
393. Modulation of solid-state luminescence
quantum efficiency based on CH-O intermolecular interaction. Toshiki Matsuoka,
Tomoaki Hinoue, Yuji Mizobe,
Ichiro Hisaki, Mikiji Miyata,
Norimitsu Tohnai
394. Enhanced two-photon absorption
cross-section of organic materials in solid
state. Yuki Tanaka*, Jun Kawamata
395. Modulation of molecular arrangements
and solid-state optical properties of the
charge-transfer complexes composed of
organic salts and TCNQ. Yuta Doi,
Norimitsu Tohnai, Atsushi Yamamoto,
Mitsuru Kurata, Ichiro Hisaki,
Mikiji Miyata
396. Construction of C3-symmetric crystals
with inclusion space of
dehydrobenzo[12]annulene derivatives.
Hirofumi Senga, Ichiro Hisaki,
Norimitsu Tohnai, Mikiji Miyata
397. Solvent-free reductive coupling of benzaldehydes with nano-size calcium on
amorphous carbon. Yoshiharu Mitoma*,
Aki Nishimura, Naoyoshi Egashira,
Mitsunori Kakeda, Cristian Simion,
Shogo Sakita, Tetsuji Okuda
398. New Ullmann-type, solvent-free, coupling of halogenated aryls in the presence
of nano-size metallic calcium and calcium
oxide. Yoshiharu Mitoma*,
Keisuke Kagawa, Naoyoshi Egashira,
Mitsunori Kakeda, Cristian Simion
399. Influence of crystal packing on reactivity of solid-state cycloaddition of azide
and alkyne. Ben-Bo Ni*, Yuguo Ma*
400. Incorporating molecular rotors in metalorganic frameworks for the construction
of inertial solid-state molecular rotors.
Cortnie S. Vogelsberg*,
David Tranchemontagne, Saeed I. Khan,
Omar M. Yaghi, Miguel A. Garcia-Garibay
401. Structural study of charge ordered insulating phase of DODHT salts.
Hiroyuki Nishikawa*, Hiroki Oshio,
Momoka Higa, Ryusuke Kondo,
Sei-ichi Kagoshima, Akiko Nakao,
Hiroshi Sawa
402. Photoinduced micropatterning by polymorphic crystallization of a photochromic
diarylethene in a polymer film.
Daichi Kitagawa*, Seiya Kobatake
403. Self-assembly and polymerization of
macrocyclic diacetylenes.
Linda S. Shimizu*, Yuewen Xu
404. Construction of a layered framework
with guest-responsive channels composed of disulfonic acid and amine.
Tomofumi Hirukawa, Norimitsu Tohnai,
Ichiro Hisaki, Mikiji Miyata
405. Effects of 1-D hydrogen-bond networks
on the stability of the enol and keto forms
in 2-(2’-hydroxyphenyl)benzimidazole microcrystals. Saori Nagao,
Kiichi Amimoto, Issui Kiyota,
Kenichiro Saita, Shinkoh Nanbu,
Hiroshi Sekiya*
406. Anomal emission from photoexcited 4’N,N-dialkylamino-3-methoxyflavone microcrystals arise from isomerization under strong intermolecular ineractions.
Issui Kiyota*, Kazuyuki Hino,
Hirofumi Nakano, Kiyohiko Nakajima,
Masayuki Nakagaki, Hiroshi Sekiya
407. Absolute asymmetric synthesis involving intramolecular 2⫹2 photocycloaddition reaction using chiral crystal.
Masami Sakamoto*,
Fumitoshi Yagishita, Takashi Mino,
Tsutomu Fujita
408. Synthesis, crystal structures and physical properties of charge-transfer complexes and radical salts composed of bis(propylenedioxy)dibenzotetrathafulvalene
(BPDO-DBTTF) donor.
Tomoko Inayoshi*, Masaki Sanada,
Shiro Matsumoto
409. Photomechanical motion of spiropyran
crystals. Hidetaka Uchimoto,
Koshima Hideko
410. Development for accurate crystal-structure analysis of a surface-shallow layer by
X-ray diffraction and its application to the
epitaxial crystals of halogen-bridged
platinum(II,IV) complexes.
Hiroaki Yamanaka*, Daisuke Yamashita,
Minoru Mitsumi, Yoshiki Ozawa,
Koshiro Toriumi, Osami Sakata
411. Solidification behavior of 2,4,6-triarylphenoxyl radicals. Takahiro Mori,
Taisetsu Ueno, Naoto Hayashi*,
Junro Yoshino, Hiroyuki Higuchi,
Hideyuki Tukada*
412. Water vapor induced switching of photochromic property of acid-base salicylideneaniline co-crystals. Kohei Johmoto,
Akiko Sekine, Hidehiro Uekusa*
413. Development of multi-component chiral
inclusion crystals derived from natural
chiral compounds and their application to
enantioseparation of racemates.
Koichi Kodama*, Eriko Sekine,
Ayaka Kanno, Takuji Hirose
414. Crystal phase transition and solid-state
photoisomerization of benzyl (Z,Z)-muconate polymorphs studied by direct observation of crystal structure change.
Natsuko Nishizawa, Daisuke Furukawa,
Akikazu Matsumoto*
415. Mesoporous silica as solid solvent: Its
application to the Diels-Alder reaction of
C60. Satoshi Minakata*,
Kazuhisa Nakayama
416. Structural and physical properties of
DMEDO-EBDT salts. Toru Morikawa,
Takashi Shirahata, Hisakazu Miyamoto,
Yoshiaki Nakano, Hideki Yamochi,
Yohji Misaki*
417. Hydration and dehydration mechanism
and crystal structure of tetracaine hydrochloride. Sayaka Ina, Akiko Sekine,
Hidehiro Uekusa*, Etsuo Yonemochi,
Katsuhide Terada
418. Efficient solid-state ESIPT luminescence of imidazopyridine derivatives:
Packing effect on the luminescence.
Hideaki Shono, Tatsuya Ohkawa,
Haruhiko Tomoda, Toshiki Mutai*,
Koji Araki*
419. Multiple crystal forms produced just by
variation of the recrystallisation solvent.
Roger Bishop*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–121
04-ORGN
420. Polymorphism of dehydrobenzoannulenes caused by methyl-esterification:
Their superstructures and anomalous
properties. Ichiro Hisaki*,
Hajime Shigemitsu, Eriko Kometani,
Norimitsu Tohnai, Mikiji Miyata*
421. Crystal structures and physical properties of molecular conductors derived from
stereoisomers of DMDH-TTP.
Jun-ichi Yamada*, Kouki Miura,
Shun Ichikawa, Satoshi Shimono,
Hiroki Akutsu, Shin’ichi Nakatsuji,
Lee Martin
422. Phase transitions of quasi-1-D molecular conductor (DMEDO-TTF)2PF6.
Takashi Shirahata*, Tadashi Kawamoto,
Tadahiko Ishikawa, Yoshiaki Nakano,
Yohji Misaki, Shin-ya Koshihara,
Hideki Yamochi, Takehiko Mori
423. Cation-␲ controlled reorientation of
pyridine derivatives on exposure to HCl
gas. Shinji Yamada*, Yoko Tokugawa,
Yuka Nojiri
424. Selective pseudo-polymorphic transformation pathways of organic crystalline
materials established using powder X-ray
diffraction analysis. Kotaro Fujii,
Yasunari Ashida, Hidehiro Uekusa*,
Fang Guo, Kenneth D. Harris
425. Molecular recognition of alcohols by inclusion compounds of dipeptides and
ammonium salts of N-trityl amino acids.
Motohiro Akazome*, Ken Megumi,
Shusaku Toma, Shoji Matsumoto
426. Development of high lightfast developer
for thermal papers. Satoshi Kodama,
Hiroshi Fujii, Hidehiro Uekusa*
427. Hydrogen-bonding organic conductors.
Yuka Kobayashi*, Takashi Ogura,
Daisuke Hashizume,
Toshikazu Nakamura, Kou Furukawa
428. Crystal structures and curing temperature modification of host-guest inclusion
compound type new curing agent.
Takeda Takenori, Hidehiro Uekusa*,
Akiko Sekine, Natsuki Amanokura,
Satoru Abe, Tetsuya Sahara,
Hiroshi Suzuki
Convention Center
Kamehameha Halls II and III
Carbanions: Modern Perspectives in
Structure, Reactivity, and Synthesis (#229)
Organized by: B. Gawley, V. Snieckus,
K. Tomioka
Presiding: B. Gawley
Poster Session
19:00 – 21:00
429. Steric effect of a flexible alkyl chain on a
ligand for CuAAC reaction.
Keisuke Asano, Seijiro Matsubara*
430. Synthesis of selenoamides and selenoimidates by reaction of lithium enolates,
isoselenocyanates, and acid chlorides.
Tatsuya Watanabe, Hajime Maeda*,
Masahito Segi*
431. Panorama of computational study on
mechanism of alkyne haloboration.
Chao Wang, Masanobu Uchiyama*
432. Three-component synthesis of optically
active propargylamines using pybim-copper(I) catalyst. Mutsuyo Ohara,
Yuko Nakamura, Shuichi Nakamura*,
Norio Shibata, Takeshi Toru
Hilton
South Pacific III
Metal Catalysis for Asymmetric Synthesis
(#282)
Organized by: H. Sasai, A. Charette,
H. Davies, D. Yang
Presiding: H. Sasai, A. Charette
19:00 – 433. Tuning copper and ruthenium
catalyzed reactions using N-heterocyclic
carbene ligands. Shawn Collins*
19:30 – 434. Efficient enantioselective synthesis of 1-vinyltetrahydroisoquinoline via
Pd-catalyzed intramolecular allylic amination for the formal total syntheses of
Schulzeines A-C. Chi-Feng Lin,
Iwao Ojima*
122–TECH
TECHNICAL PROGRAM
19:50 – 435. Coinage metal-catalyzed asymmetric C-C and C-N bond formation reactions. Chi-Ming Che*
20:20 – 436. Gold(I)-catalyzed enantioselective reactions. Dean Toste
Hilton
South Pacific IV
Friday Morning
Organized by: J. Rainier, R. Anderson,
M. Murata
Presiding: J. Rainier
Hilton
Sea Pearl V/VI
Reactive Intermediates and Unusual
Molecules - A Celebration of Bob Moss’s 70
years (#1)
Organized by: M. Platz, M. Abe, W. Leigh
Presiding: M. Platz
7:30 – 437. Ion radicals of unsaturated silicon compounds: The cation-radical and
anion-radical of disilene, and the anionradical of disilyne. Akira Sekiguchi
8:00 – 438. Triradicals and beyond.
Wolfram Sander*, Patrik Neuhaus,
Dirk Grote, Sugumar Venkataramani
8:30 – 439. Spin alignment in tetraradicals,
based on the substituent effect on the
ground state spin-multiplicity of localized
1,3-diyls. Manabu Abe,
Takeshi Nakamura, Ko Fukukawa,
Tatsuhisa Kato, Yoshihisa Fujiwara
9:00 – 440. Thermoluminescence originating
from the singlet excited state of 1,4-diarylcyclohexane-1,4-diyls: A potentially
general strategy for the observation of
short-lived biradicals. Hiroshi Ikeda*
9:30 – 441. Redox chemistry of stable P-heterocyclic biradicals. Shigekazu Ito*
10:00 – 442. Experimental consideration on
intermolecular spin-spin interaction of delocalized singlet biradicals.
Takashi Kubo*
10:30 – 443. New reactivity of a 1,2-diaryldisilyne, the first carbon-substituted disilyne. Joon S. Han, Koji Hironaka,
Takahiro Sasamori, Yoshiyuki Mizuhata,
Norihiro Tokitoh*
11:00 – 444. Chiral neutral radicals with an
extremely spin-delocalized nature.
Yasushi Morita*, Akira Ueda,
Shuichi Suzuki, Masatoshi Kozaki,
Keiji Okada, Shinsuke Nishida,
Tomoaki Ise, Kazunobu Sato,
Takeji Takui
Hilton
South Pacific II
Asymmetric Organocatalysis (#62)
Organized by: K. Maruoka, L. Deng,
L. Gong
Presiding: K. Maruoka, L. Gong, L. Deng
7:30 – 445. N-heterocyclic carbene-catalyzed ring expansion of azacycloalkane2-carboxaldehydes for the synthesis of
lactams. Karen Thai, Li Wang,
François Bilodeau, Michel Gravel*
7:50 – 446. Improving the enantioselectivity
of proline based catalysts with ␣-substitution. David Barker,
Margaret A. Brimble, Kevin Sparrow,
Sok Teng Tong
8:10 – 447. Enantioselective oxidative kinetic
resolution of racemic secondary alcohols
using chirally modified AZADOs.
Yoshiharu Iwabuchi*
8:30 – 448. Chiral ammonium betaines as a
unique organic molecular catalyst.
Takashi Ooi*
9:00 – 449. Design and utility of chiral carbenes for asymmetric umpolung.
Tomislav Rovis*
9:30 – 450. Bio-inspired chiral primary amine
catalysts. Sanzhong Luo*
10:00 – 451. Hypervalent iodine reagents:
new entry to organocatalysts for green
oxidations. Yasuyuki Kita*
10:30 – 452. Asymmetric reactions with bifunctional and dual-functional catalysis.
Li Deng*
11:00 – 453. Chiral Brønsted acid catalysis
for asymmetric synthesis.
Hisashi Yamamoto*
Marine Natural Products: Isolation, Biology,
Ecology, and Synthesis (#80)
7:30 – 454. Synthesis of marine natural products at 4700 feet above sea level.
Jon D. Rainier*
8:00 – 455. Marine natural products in extrema: The extraordinary and the enigmatic. Tadeusz F. Molinski*
8:30 – 456. Confirmation of the cellular target of pateamine A. James Matthews,
Paul Teesdale-Spittle*
8:50 – 457. Synthesis and biology of laddershaped polyethers isolated from marine
dinoflagellate for exploring biological
functions. Tohru Oishi*
9:20 – 458. Elements of the structure elucidation of isolates from the twilight zone
Sponge Suberea sp. collected from waters around Guam. Anthony D. Wright*,
Peter Schupp, Claudia Kohlert-Schupp,
John M. Pezzuto, Tamara P. Kondratyuk,
Eun-Jung Park, Laura Marler
9:40 – 459. Mode of action of theonellamides, antifungal bicyclic peptides from
a marine sponge. Shinichi Nishimura,
Shigeki Matsunaga, Hideaki Kakeya,
Minoru Yoshida
10:00 – 460. Antibacterial marine natural
products that inhibit the bacterial cell division protein FtsZ. Carole Bewley*,
Alberto Plaza, Jessica Keffer
10:30 – 461. Marine huge molecules.
Daisuke Uemura
11:00 – 462. New and highly bioactive marine cyanobacterial natural products discovered by innovative assays and technologies. Alban Pereira*, Kevin Tidgewell,
Hyukjae Choi, Joshawna Nunnery,
Emily Mevers, Eduardo Esquenazi,
Robin Kinnel, Thomas Murray,
Pieter Dorrestein, William Gerwick
Hilton
Iolani I/II
New Advances in Metal-Catalyzed
Alkylation and Fluoroalkylation (#115)
Organized by: D. Vicic, V. Dong,
N. Kambe
Presiding: V. Dong
7:30 Introductory remarks
7:35 – 463. Recent advances in Cu-catalyzed aromatic trifluoromethylation.
Hideki Amii*, Hideaki Kondo,
Masahiro Oishi
8:15 – 464. Organometallic aspects of metalcatalyzed trifluoromethylation of organic
halides. David Vicic*
8:50 – 465. Zinc reagent-mediated perfluoroalkylation reaction. Xuan Wang,
Atsuya Muranaka, Masanobu Uchiyama*
9:30 – 466. Electrophilic trifluoromethylation
of a variety of substrates using hypervalent iodine reagents. Antonio Togni*
10:10 – 467. Resent progress of monofluoromethylation reactions using FBSM
and FBDT as synthetic equivalents for
monofluoromethide species.
Norio Shibata*
10:50 – 468. Catalytic methods for enantioselective C-F bond formation with fluoride sources. Abigail G. Doyle*
Hilton
Honolulu III
Achieving Efficiency in Organic Reactions
via Greener Processes and Practices (#139)
Organized by: I. Ryu, D. Curran,
P. Jessop, S. Lee
Presiding: K. Fukase, I. Ryu, O. Kappe
7:30 – 469. Study of microfluidic reactions
toward production of biofunctional molecules: Application to glycan synthesis.
Koichi Fukase*
8:00 – 470. Continuous-flow synthesis of vitamin D3. Shinichiro Fuse,
Nobutake Tanabe, Masahito Yoshida,
Hayato Yoshida, Takayuki Doi,
Takashi Takahashi
8:20 – 471. Scale-up of microwave-assisted
reactions using high-temperature/pressure microreactor technology.
C Oliver Kappe*, Toma N. Glasnov,
Tahseen Razzaq, David Obermayer,
Bernhard Gutmann, Markus Damm
8:40 – 472. Flash chemistry using flow microreactors. Jun-ichi Yoshida*
9:10 – 473. Energy-saving photoreaction
system using microreactor and compact
light source. Takahide Fukuyama,
Ilhyong Ryu
9:30 – 474. Efficient dehydrocondensing reaction accelerated at a micellar interface.
Munetaka Kunishima*
9:50 – 475. New facile general method for
the conjugation of three different molecules. Hyung Min Chi, Dong Seok Shin,
Hyeong Baik Kim, Byoung Se Lee,
Dae Yoon Chi*
10:20 – 476. Fluorous-based green technologies for organic synthesis and medicinal
chemistry. Wei Zhang*
10:40 – 477. Carbohydrate synthesis using
heavy fluorous tags. Mamoru Mizuno*,
Kohtaro Goto, Hiroko Kawakami,
Mami Tojino
11:00 – 478. Development of tandem reaction by using the Blaise reaction intermediate. Sang-gi Lee*
Hilton
Honolulu I
Organic Solid-State Chemistry: Structure,
Synthesis & Reactivity (#155)
Organized by: R. Bishop,
M. Garcia-Garibay, R. Kuroda
Presiding: R. Bishop
7:30 – 479. Bernauer’s bands. Bart Kahr*,
Alexander Shtukenberg, Erica Gunn,
Massimo Gazzano, John Freudenthal,
Eric Camp
8:10 – 480. Structure-property relationship
of polycyclic aromatic compounds containing fused furan rings.
Naoto Hayashi*, Yoko Saito,
Junro Yoshino, Hiroyuki Higuchi,
Hiroyuki Yoshida*, Naoki Sato
8:40 – 481. New sterically driven mode for
generation of helical chirality.
Vadim A. Soloshonok*
9:10 – 482. Photomechanical bending of
molecular crystals. Hideko Koshima*,
Hidetaka Uchimoto, Naoko Ojima,
Kyoko Takechi
9:30 – 483. Free energy simulation of molecular crystal thermodynamics.
Bruce S. Hudson, Sharon A. Rivera,
Matthew R. Hudson, Damian G. Allis
10:00 – 484. Photodimerization of chromone
derivatives and a new methodology of
chiral induction using preferential crystallization with photoracemization.
Masami Sakamoto*,
Fumitoshi Yagishita, Masayuki Kanehiro,
Takashi Mino, Tsutomu Fujita
10:20 – 485. Structures and dynamics of organic ferroelastics and ferroelectrics.
Mark D. Hollingsworth*,
Farhod Nozirov, Roman B. Gajda,
Shane M. Nichols, Eric J. Chan,
Werner Kaminsky
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
10:50 – 486. Selective encapsulation of
block copolymers in crystalline supramolecular architectures.
Angiolina Comotti*, Silvia Bracco,
Bernardo Moltrasio, Piero Sozzani
Hilton
South Pacific III
Recent Advances in Natural Products as
Anticancer Agents (#279)
Organized by: D. Kingston, J. Li,
S. Matsunaga, R. Quinn
Presiding: D. Kingston
7:30 Introductory remarks
7:40 – 487. Antibiotic-like molecules from
symbiont cultures. Ren X. Tan*
8:10 – 488. Antitumor activities of secondary
metabolites from higher fungi in China.
Ji-Kai Liu*
8:45 – 489. Chemical and biological diversity
of natural resveratrol oligomers.
Hui Ming Ge*, RenXiang Tan
9:05 – 490. Search for bioactive natural
products targeting TRAIL signaling for tumor-selective apoptosis inducement.
Masami Ishibashi*
9:40 – 491. Biologically active compounds
produced by cellular slime molds.
Haruhisa Kikuchi, Yuzuru Kubohara,
Yoshiteru Oshima*
10:00 – 492. Formosan plant-based as anticancer agents. Yang-Chang Wu*
10:35 – 493. Conformational studies of
highly potent antitumor steroidal glycosides from Ornithogalum saundersiae.
Kaori Sakurai, Takuro Fukumoto,
Keiichi Noguchi, Masafumi Yohda
10:55 – 494. Discovery of novel anticancer
agents of diverse natural origin.
A. Douglas Kinghorn
Hilton
Coral IV
Novel Synthetic Methodology and Its
Application to Natural Product Synthesis
(#63)
Organized by: F. West, V. Rawal,
M. Toyota
Presiding: V. Rawal
7:45 – 495. Development and applications of
metal-free amination reactions of alkenes
and alkynes. André M. Beauchemin*
8:05 – 496. Total synthesis of marine diterpene natural products of the cladiellin
family using metal carbenoids.
Stephen Clark*, Raphaelle Berger,
Stewart Hayes
8:50 – 497. Convergent synthesis of a library
of complex cuticular hydrocarbons to decode chemical communication in social
insects. John Nielsen*,
Charlotte G. Jørgensen,
Karin Mannerstedt, Patrizia D’Ettorre,
Luke Holman
9:10 – 498. Synthetic studies on polypropionates. Dale E. Ward*, Nikki E. Theaker,
Md. M. Zahedi, Fabiola Becerril-Jimenez,
Alieh Kazemeini
9:40 – 499. Synthesis of microstegiol via
␥-carbonyl cations. Rafiq A. Taj,
James R. Green*
10:00 – 500. New ways to generate TMM
diradicals for the synthesis of cyclopentanoid natural products. Hee Yoon Lee*
10:45 – 501. Functionalized organoboronates in the design of stereocontrolled
methodologies and their application to
natural product synthesis. Dennis Hall*
Hilton
Sea Pearl I/II
Cooperative Catalysis (#14)
Organized by: Y. Uozumi, R. Danheiser,
K. Ding, A. Nishida
Presiding: Y. Uozumi
7:50 Introductory remarks
8:00 – 502. Highly enantioselective Diels-Alder reactions of Danishefsky’s dienes
with electron-deficient alkenes catalyzed
by Yb(III)-BINAMIDE complexes.
Atsushi Nishida*, Shiharu Hiraoka,
Nozomi Toudou, Shinji Harada
8:20 – 503. Novel method for synthesizing
spiro[4,5]cyclohexadienones through a
Pd-catalyzed intramolecular ipso-FriedelCrafts allylic alkylation of phenols.
Tetsuhiro Nemoto, Mariko Yoshida,
Yuta Ishige, Mutsumi Kanematsu,
Yuta Kohno, Yasumasa Hamada*
8:40 – 504. Catalytic enantioselective construction of ␤-quaternary stereocenters
through conjugate cyanation of ␤-disubstituted carbonyl compounds.
Motomu Kanai*, Yuta Tanaka,
Masakatsu Shibasaki
9:00 – 505. Surface-mediated transfer hydrogenation on oxide-supported Ir-dimer
catalysts. Satoshi Muratsugu*,
Yuko Kushida, Hidetaka Nakai,
Kiyoshi Isobe, Takehiko Sasaki,
Mizuki Tada
9:20 – 506. Cooperative catalysis in multicomponent reactions based on trapping
of oxonium ylides. Yu Qian, Xinfang Xu,
Xin Guo, Taoda Shi, Wenhao Hu*
9:50 – 507. Reactions of Grignard reagents
catalyzed cooperatively by iron and copper complexes. Eiji Shirakawa,
Tamio Hayashi
10:20 – 508. Self-assembly of dinuclear main
group catalyts for asymmetric synthesis.
Barry M. Trost*
11:00 – 509. Cooperative catalysis in enantioselective reactions using chiral N,N’-dioxide. Xiaoming Feng*, Xiaohua Liu,
Lili Lin
Hilton
Honolulu II
Supramolecular Catalysis (#280)
Organized by: J. Parquette, J. Badjic,
M. Organ, Q. Zhou
Presiding: J. Parquette
7:50 Introductory remarks
8:00 – 510. Artificial enzymes that work in
water. Ronald Breslow*
8:30 – 511. Supramolecular concepts in homogeneous catalysis. Bernhard Breit
9:00 – 512. Supramolecular chiral phosphorous ligands based on crown ether for
asymmetric hydrogenation.
Qing-Hua Fan*
9:30 – 513. Lessons learned from the development of heterobimetallic supramolecular catalysts via self-assembly.
James M. Takacs*
10:00 – 514. Preparation and catalytic application of metal-diisocyanide monolayer
on gold surface. Kenji Hara*,
Yoshinori Kaji, Atsushi Fukuoka
10:30 – 515. New hydrogen bond donor
scaffolds for asymmetric catalysis.
Viresh Rawal*
11:00 – 516. Development of hydrogen
bonding modules (HBMs) as bioinspired
nanoscale adhesion agents.
Steven C. Zimmerman*,
Cyrus A. Anderson, Darrell W. Kukendall
Hilton
Coral V
Mechanistic Organic Photochemistry (#89)
Organized by:
H. Zimmerman and A. Griesbeck,
T. Ichimura, A. Kutateladze, P. Wan
Presiding: H. Zimmerman
8:00 – 517. Sensors for chiral and achiral anion detection based on aminoalcoholurea-phthalimide triades and N-acylluminols. Axel G. Griesbeck*,
Sebastian Hanft, Yrene Diaz-Miara,
Raul Perez-Ruiz, Robert Fichtler,
Axel Jacobi von Wangelin, Alan de Kiff
8:35 – 518. Photogeneration and study of
acyl nitroso compounds.
John P. Toscano*
9:10 – 519. Synthesis and characterization of
metal nanoparticles from an organic
chemist’s perspective. Juan C. Scaiano*
9:45 – 520. Green photochemical synthesis
using novel microreaction system.
Teijiro Ichimura*, Yoshihisa Matsushita,
Tadashi Suzuki
10:20 – 521. Development of new photolabile protecting groups. Pengfei Wang*
10:55 – 522. Photoinduced electron transfer
reactions from nanoparticles, in ionic liquids and applications to photorheological
fluids. Daniel E. Falvey*
Convention Center
Kamehameha Halls II and III
Interface between Organic Synthesis and
Chromatography (#19)
Organized by: C. Welch, W. Farrell,
M. Hyun, A. Rajendran
Presiding: C. Welch
Poster Session
10:00 – 12:00
523. Mechanism elucidation of the phasetransfer reaction for the sample with a lot
of reactive points. Satomi Tanaka,
Jyunya Nagai, Ryuichi Shiba
524. Serine-histidine conjugate revealing
high affinity to ␤-aminophosphonate as
the analog of the hydrolysis intermediate
of ␤-alanine ester: Retardation of the hydrolysis. Ai Shiratori, Nobuhiro Kihara*
Convention Center
Kamehameha Halls II and III
Designed pi-Electronic Systems: Synthesis,
Properties, Theory and Function (#29)
Organized by: M. Haley, G. Bodwell,
T. Kubo, Y. Tobe
Presiding: M. Haley
Poster Session
10:00 – 12:00
525. Theoretical studies on the structures
and strain energies of cycloparaphenylenes. Yasutomo Segawa,
Haruka Omachi, Kenichiro Itami*
526. Multi-input-and-multi-output molecular
response systems based on helical piframework. Takanori Suzuki*,
Tatsuo Nehira, Yasuyo Yoshimoto,
Hidetoshi Kawai, Kenshu Fujiwara
527. Synthesis and characterization of ␤-alkyl substituted hexaphyrin(1.1.1.1.1.1).
Masaaki Suzuki*, Tyuji Hoshino,
Saburo Neya
528. Synthesis, structure, and redox properties of 1,1’-bis(aryloligothienyl)ferrocenes.
Satoshi Ogawa*, Haruka Kobayashi,
Hiroki Muraoka
529. Preparation of cyclophanes consisting
of oligothiophene units and control of
their dynamic properties by formation of
the rotaxane structure. Akihiko Tsuge*,
Katsuji Nakamura, Tetsuji Moriguchi,
Koji Araki
530. Development of novel porphyrin derivatives based on steric properties of amide
bond. Mio Matsumura,
Atsuya Muranaka, Masanobu Uchiyama,
Hyuma Masu, Isao Azumaya,
Hiroyuki Kagechika, Aya Tanatani*
531. Substituent effects on emissions of trimethylenemethane biradicals.
Yasunori Matsui, Hiroshi Ikeda*,
Hayato Namai, Toshiki Sera,
Kazuhiko Mizuno*
532. Synthesis and properties of tetra(5-aryl2-thienyl)thiophenes. Hiroki Muraoka,
Takanori Tanifuji, Satoshi Ogawa*
533. Synthesis and properties of acetylene
extended radiaannulenes with redox site.
Masashi Hasegawa*, Yasuhiro Mazaki
534. Synthesis of C3 symmetric chiral host
molecules with three buckybowls units.
Satoru Onogi*, Shuhei Higashibayashi,
Hidehiro Sakurai
535. Reaction of cage-opened fullerene derivative with Grignard reagents and subsequent transannular cyclization.
Yuta Morinaka, Michihisa Murata,
Kei Kurotobi, Koichi Komatsu*,
Yasujiro Murata*
536. Synthesis and properties of perylene bisimide derivatives incorporated with various ␲-donor units. Tetsuo Iwanaga,
Hiroko Ida, Shinji Toyota*
537. Synthesis and spectral properties of
first member of new class of double helicene polycyclic aromatic hydrocarbons.
Takehiko Yamato*, Arjun Paudel
538. Modular synthesis of cycloparaphenylenes. Haruka Omachi,
Sanae Matsuura, Yasutomo Segawa,
Kenichiro Itami*
539. Photochemical synthesis of anthraditiophene and dithienylanthracene oligomers. Ryuta Kato*, Daiki Kuzuhara,
Tetsuo Okujima, Hiroko Yamada,
Hidemitsu Uno
540. Synthesis of p-tertbutylazacalix[4]arene with hydroxy
groups. Hirohito Tsue*, Kazuyuki Miyata,
Koichi Ishibashi, Kohei Ono, Rui Tamura
541. New stable high-spin diradical: nitroxide-substituted nitronyl-nitroxide diradical. Takanori Furui, Masato Kuratsu,
Shuichi Suzuki, Masatoshi Kozaki,
Daisuke Shiomi, Kazunobu Sato,
Takeji Takui, Keiji Okada*
542. Superstructure dependent optical and
electrical properties of dehydrobenzoannulene crystals. Ichiro Hisaki*,
Hirofumi Senga, Eriko Kometani,
Norimitsu Tohnai, Mikiji Miyata*
543. Light-harvesting porphyrin array composed of three kinds of porphyrins.
Atsuhiro Uetomo, Masatoshi Kozaki*,
Shuichi Suzuki, Keiji Okada*
544. Unprecedented radical-radical reaction
of a [2.2]paracyclophane derivative containing imidazolyl radical moiety.
Sayaka Hatano, Ken Sakai, Jiro Abe*
545. Conjugated pyridinium betaines showing unusual dual charge transfer characteristics. Kazuhiro Ohkawa,
Atsushi Kimoto, Jiro Abe*
546. Fast photochromism of naphthalenebridged imidazole dimers. Mao Suzuki,
Kana Fujita, Jiro Abe*
547. Straightforward synthesis of laddertype indolocarbazoles via double Suzukiand Cadogan reactions.
Elisabeth Da Silva, Bernhard Witulski*
548. Synthesis and properties of 2,2’-bis(spirodienone)-bridged-3,3’-bithiophene derivatives: An unusual redox behavior
coused by ring-opening.
Hiroyuki Kurata*, Takahisa Fujimoto,
Yumiko Atsuji, Yasukazu Hirao,
Kouzou Matsumoto, Takashi Kubo
549. Efficient strategy for enhancing the
photosensitivity of fast photochromic
molecules. Katsuya Mutoh,
Sayaka Hatano, Jiro Abe*
550. Open-shell character of diphenoquinone derivatives. Yoshihiro Amano,
Azusa Kikuchi, Jiro Abe*
551. Real-time photoswitching of chiral
nematic phase by the fast photochromic
dyes. Tetsuya Kato, Kana Fujita,
Jiro Abe*
552. Selective observation of tetramethyleneethane-type biradical and radical cation intermediates on laser flash photolysis. Yusuke Kano, Hiroshi Ikeda*,
Koshiro Ochiai, Yasutake Takahashi,
Kazuhiko Mizuno*
553. Synthesis of 2,1-benzisoselenazoles
and their complexation toward copper
salts. Norihioko Nemoto, Rui Umeda,
Yutaka Nishiyama*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–123
04-ORGN
554. Synthesis, crystal structure, and solidstate optical properties of alkyl-substituted tetracenes. Chitoshi Kitamura*,
Yasushi Abe, Takuya Ohara,
Chika Matsumoto, Hideki Tsukuda,
Hiroyuki Kano, Akio Yoneda,
Takeshi Kawase, Takashi Kobayashi,
Hiroyoshi Naito
555. Construction of nanoscale covalent assembly using snowflake-shaped dendrimers as the key modular building
blocks. Shirou Morita,
Masatoshi Kozaki, Shuichi Suzuki,
Keiji Okada
556. New synthesis of indenone derivatives
and application to dibenzopentalene synthesis. Kenta Katsumoto,
Takeru Fujiwara, Chitoshi Kitamura,
Takeshi Kawase*
557. Synthesis and properties of teranthene:
Onset of “edge state” in molecular-sized
nanographene molecule.
Akihito Konishi*, Akihiro Shimizu,
Yasukazu Hirao, Kouzo Matsumoto,
Hiroyuki Kurata, Takashi Kubo,
Masayoshi Nakano, Benoît Champagne
558. Regioselective synthesis and photophysical properties of carbazole nitroso
derivatives. Maki Ando, Yuji Yamanaka,
Kazushige Hori*, Keita Tani
559. Studies on the synthesis and properties
of dendrimer molecule based on tetrakis(2-thienyl)methane framework.
Sota Kugo, Kouzou Matsumoto,
Daisuke Takajo, Yasukazu Hirao,
Hiroyuki Kurata, Takashi Kubo*
560. Synthesis and photophysical properties
of novel Schiff bases containing carbazole chromophore. Kazushige Hori*,
Yuji Yamanaka, Keita Tani
561. Synthesis, properties and synthetic applications of diformylacenes.
Shuhei Katsuta*, Hiroko Yamada,
Tetsuo Okujima, Hidemitsu Uno
562. Remarkable acceleration for back-reaction of fast photochromic molecule.
Yuka Harada, Sayaka Hatano,
Atsushi Kimoto, Jiro Abe*
563. Synthesis and properties of novel polyheterocyclic aromatic compounds fused
naphthimide unit. Hiroaki Nishida,
Rui Umeda*, Motohiro Otono,
Yutaka Nishiyama
564. Stable neutral radicals based on the
quinoxalinoquinoxaline skeleton: Electrochemical amphotericity and electric conduction as a single component.
Youhei Miura, Hiroshi Chiba,
Hidetoshi Kawai, Kenshu Fujiwara,
Takanori Suzuki*
565. Conductance measurement of phenylpyridine-coordinated tetraphenylporphyrin rhodium chlorides using STM.
Takeshi Sakano, Kenji Higashiguchi,
Kenji Matsuda*
566. Selenium-catalyzed reductive deoxygenation of various aromatic nitro compounds with carbon monoxide.
Shigeru Morishita, Rui Umeda,
Yutaka Nishiyama*
567. Crystal structure and solid state properties of quartz type hydrogen bonded network of tetrakis(4-pyridyl)methane dication. Daisuke Inokuchi*,
Kouzou Matsumoto, Yasukazu Hirao,
Hiroyuki Kurata, Takashi Kubo
568. Synthesis and property of tripod compound containing aryl ethynylene.
Hiroki Nakagawa, Changfeng Hong,
Kazuhiko Nakatani*
569. Syntheses of multi-substituted anthracenes using ruthenium-catalyzed regioselective C-H bond arylation.
Kentaroh Kitazawa, Takuya Kochi,
Fumitoshi Kakiuchi*
570. Synthesis and characterization of
m-calix[3]amide having ␲-conjugated
system. Ryohei Yamakado*,
Shin-ichi Matsuoka, Masato Suzuki,
Koji Takagi*
571. Synthesis and properties of dioxaporphyrin. Soji Shimizu*, Ryo Hiramatsu,
Nagao Kobayashi
124 –TECH
TECHNICAL PROGRAM
572. Crystal structure and solid state properties of quartz type hydrogen bonded network of tetrakis(4-pyridyl)methane dication. Daisuke Inokuchi*,
Kouzou Matsumoto, Yasukazu Hirao,
Hiroyuki Kurata, Takashi Kubo
573. Synthesis of the novel ligands based on
tetrakis(2-pyridyl)methane and their metal
complexes. Kazuaki Kawashita,
Kouzou Matsumoto, Yasukazu Hirao,
Hiroyuki Kurata, Takashi Kubo*
574. Construction of novel chiral redox
memory unit: Electrochemical switching
of racemization barriers.
Takanori Suzuki*, Kazuhisa Wada,
Yasuyo Yoshimoto, Hidetoshi Kawai,
Kenshu Fujiwara
575. Synthesis and luminescent properties
of ␲-conjugated polymers containing organoboron quinolates in the main-chain.
Yuichiro Tokoro, Atsushi Nagai,
Yoshiki Chujo*
576. Allosteric bindings of thiacalix[4]arenebased receptors with 1,3-alternate conformation having two different side arms.
Hirotsugu Tomiyasu, Takehiko Yamato
577. Synthesis and molecular structures of
17,17-dialkyltetrabenzo[a,c,g,j]fluorenes
with considerably high fluorescent quantum yields in the solid state.
Yusuke Tanigawa, Chitoshi Kitamura,
Takeshi Kawase, Takashi Kobayashi,
Hiroyoshi Naito
578. Conjugated oligomers of perylenediimide with increased electron affinity and
self-association ability. Qifan Yan,
Dahui Zhao
579. Design, synthesis and function of stimuli-responsive ␲-conjugated pyridine derivatives. Akihiko Hatakeyama,
Satoaki Onitsuka, Hiroshi Furuno,
Junji Inanaga*
580. Intramolecular tandem cyclization and
subsequent anomalous dimerization of
dehydrobenzo[14]annulene derivatives.
Nobusue Shunpei, Akihiro Shimizu,
Kazukuni Tahara, Yoshito Tobe*
581. Structure-property relationship of thirdorder nonlinear optical properties and
open-shell characters for graphene
nanoflakes with antidot structure.
Kyohei Yoneda, Masayoshi Nakano
582. Indium(III)-catalyzed cyclization of 1,1difluoroallenes: Construction of naphthalene and phenanthrene frameworks.
Kohei Fuchibe, Yuka Mayumi,
Ken Wang, Misaki Yokota, Junji Ichikawa*
583. Diffraction study of organic ferroelectrics under high-pressures and at lowtemperatures. Reiji Kumai*,
Sachio Horiuchi, Yoshinori Tokura
584. Photochromic terarylene derivatives
having donor or acceptor groups on their
central aromatic ring.
Yuichiro Kutsunugi*,
Takuya Nakashima, Tsuyoshi Kawai
585. Development of a route for automated
synthesis of porphyrin arrays.
Takenori Nosaka, Ayuko Yamana,
Takuji Ogawa*
586. Swivel-cruciform oligothiophene trimers. Balaji Ganapathy,
Hian Twan Chang, Suresh Valiyaveettil*
587. Synthesis and photophysical properties
of novel fluorescent azo-hydrazone-type
boron complexes. Haruka Ooyama,
Katsuhira Yoshida*
588. Convenient synthesis of multialkylated
acenes by means of RuH2(CO)(PPh3)3catalyzed C-H alkylation.
Daiki Matsumura, Takuya Kochi,
Fumitoshi Kakiuchi*
589. Pd-catalyzed synthesis of
amidoaza[5]helicene and axially chiral
amino acid. Junya Yamamoto*,
Yuki Kitamura, Ayano Hashimoto,
Takumi Furuta, Hyuma Masu,
Isao Azumaya, Toshiyuki Kan,
Takeo Kawabata
590. Photoisomeriation and functionalization
of [1.1]meta-stillebenophanes.
Masakazu Konishi, Tsuyoshi Sawada*,
Takuya Hongo, Hirotaka Ihara
591. Photoswitching dihydropyrene annelated with dihydrothieno[3,4-b]pyrazine
moiety. Mizue Kuroki,
Tsuyoshi Sawada*, Tomoya Ogawa,
Kentaro Shimojo, Hirotaka Ihara
592. New series of electrochromic systems
based on bis(diarylethenyl)thiophene
framework. Yusuke Ishigaki,
Hiroki Higuchi, Hidetoshi Kawai,
Kenshu Fujiwara, Takanori Suzuki*
593. Synthesis, photochromic, and electrical
properties of diarylethene derivatives
having oxadiazole and/or carbazole substituents. Yoshiyuki Takayama,
Yu Arima, Kentaro Shoji, Kazushige Hori,
Koji Kubono, Yasuhiro Kakihara,
Tsuyoshi Tsujioka, Keita Tani*
594. Synthesis and properties of partially
overlapped [3.3](3,9)carbazolophane-acceptor dyads. Keita Tani*,
Kazushige Hori, Koji Kubono,
Hiroaki Benten, Hideo Ohkita,
Shizaburo Ito, Masahide Yamamoto
595. Photophysical properties of dual fluorescent porphyrins. Jun Nakamura*,
Tetsuo Okujima, Kengo Suzuki,
Kiyomasa Hosokawa, Hiroko Yamada,
Hidemitsu Uno, Noboru Ono
596. Construction of supramolecular structure and fiber formation based on
tetrathiafulvalenopyridazine derivative.
Ryota Inoue, Masashi Hasegawa*,
Yasuhiro Mazaki
597. Highly efficient excitation energy transfer by controlling the molecular ordering
in porphyrin and pyrene assembly.
Koji Miyamoto, Hirokuni Jintoku,
Tsuyoshi Sawada, Makoto Takafuji,
Tsuyoshi Sagawa, Hirotaka Ihara*
598. Synthesis and properties of syn- and
anti- bisbridged[10]annulenocyclopentadienide
anions. Naoko Matsumoto,
Daisuke Miyamoto, Kana Inoue,
Yuji Sugiura, Yoshikazu Horino,
Ryuta Miyatake, Mitsunori Oda,
Shigeyasu Kuroda*
599. Mechanochromism of 2,2’-bis(spirodienone)-bridged-3,3’-bithiophene derivatives. Hiroyuki Kurata*, Yumiko Atsuji,
Yasukazu Hirao, Kouzou Matsumoto,
Kiichi Amimoto, Takashi Kubo
600. Optical resolution of chiral buckybowls
by chiral HPLC. Ryoji Tsuruoka,
Shuhei Higashibayashi,
Takeharu Ishikawa, Shinji Toyota,
Hidehiro Sakurai*
601. Synthesis and structural properties of
[2.n]metacyclophan-1-ynes with bent triple bond. Yuki Uchikawa,
Takehiko Yamato
602. Novel [2.2]paracyclophane-bridged imidazole dimer with a pyrenyl chromophore. Hiroaki Yamashita, Jiro Abe*
603. Synthesis and physical properties of
zethrene derivatives. Daijiro Hibi,
Rui Umeda, Takashi Takeda,
Akihiro Shimizu, Yoshito Tobe*
604. Synthesis of [30]octaphyrin(0.0.0.0.0.0.0.0) with highly symmetric
␲-system. Tetsuo Okujima*,
Guangnan Jin, Daiki Kuzuhara,
Chie Ando, Shigeki Mori, Noboru Ono,
Hiroko Yamada, Hidemitsu Uno
605. Structure and properties of naphthodifurans and anthradifurans.
Takayuki Kameyama, Naoto Hayashi*,
Junro Yoshino, Hiroyuki Higuchi
606. Structure and properties of polycyclic
aromatic compounds containing fused
furan rings at the center of the molecule.
Masayuki Iwagami, Yoko Saito,
Naoto Hayashi*, Junro Yoshino,
Hiroyuki Higuchi
607. Structure and properties of benzodifurans bearing heteroaromatic substituents at the 2 and 6-positions.
Shota Nishigaki, Yoko Saito,
Naoto Hayashi*, Junro Yoshino,
Hiroyuki Higuchi
608. Effects of orientation of fused furan
rings on properties of isomeric polycyclic
aromatic compounds. Yoko Saito,
Manami Terauchi, Miho Ito,
Naoto Hayashi*, Junro Yoshino,
Hiroyuki Higuchi
609. Electron acceptor character and behavior as an oxidizing agent of o- and p-chloranil dimers. Hiroyuki Nakagawa,
Yuko Sugiyama, Naoto Hayashi*,
Junro Yoshino, Hiroyuki Higuchi
610. Mixture consisting of quinone dimer
and hydroquinone dimer. Akifumi Kanda,
Kiyomi Matsui, Naoto Hayashi*,
Junro Yoshino, Hiroyuki Higuchi
611. Photoinduced electron transfer triad
systems based on bipyridine-diacetylide
platinum complexes. Ryoji Sugimura,
Shuichi Suzuki, Masatoshi Kozaki,
Kazutoshi Keyaki, Koichi Nozaki,
Noriaki Ikeda, Kimio Akiyama, Keiji Okada
612. 2-D homochiral nanoporous molecular
network of dehydrobenzo[12]annulenes:
Design strategy, control, and induction.
Hiroyuki Yamaga, Kazukuni Tahara,
Yoshito Tobe*
613. Steric control of ␲-dimerization of oligothiophene radical cations.
Masaki Tateno, Tohru Nishinaga*,
Masayoshi Takase, Koichi Komatsu,
Masahiko Iyoda
614. Photo- and thermal reaction of 2-alkoxy
and 2-alkylthio 2H-azepines.
Nozomi Adachi, Hideki Okamoto,
Kyosuke Satake
615. Synthesis of C3 symmetric buckybowls.
Shuhei Higashibayashi, Nasir B. Baig,
Hidehiro Sakurai*
616. Synthesis and properties of aryl and
ethynyl substitutied benzanthorone derivatives. Teruaki Namba, Rui Umeda,
Yutaka Nishiyama
617. Syntheses of syn- and anti-indenofluorenes by intramolecular tandem annulation reaction of
octadehydrodibenzo[12]annulene derivative. Takashi Takeda, Koji Inukai,
Kazukuni Tahara, Yoshito Tobe*
618. Synthesis and properties of biazulenes
and diazulenylethynes. Nobuyuki Itou*,
Toshihiro Murafuji, Tomoyuki Hatazawa
619. Synthesis of star-shaped
tetrakisdehydrobenzo[12]annulene by
alkyne metathesis reaction.
Yuki Yamamoto, Yuan Gao,
Dustin Gross, Kazukuni Tahara,
Jeffrey S. Moore, Yoshito Tobe*
620. Synthesis and propeties of acene condensed bridged annulenes. Takako Abe,
Shinobu Nakanishi, Taihei Kano,
Ayana Ide, Hinako Shinoda,
Ryuta Miyatake, Yoshikazu Horino,
Mitsunori Oda, Shigeyasu Kuroda*
621. Studies of a phenalenyl-based molecule
with triradical character. Mitsuya Aoba,
Akihiro Shimizu, Yasukazu Hirao*,
Kouzou Matsumoto, Hiroyuki Kurata,
Takashi Kubo*
622. Development of multi-functional materials using TTF derivatives containing a
1,3-Benzothiazole ring.
Sadayoshi Hayashi, Sayo Yokota,
Rika Uezono, Hideki Fujiwara*
623. Synthetic studies of cage-shaped oligothiophenes. Hiroyuki Kurata*,
Kazuhiko Adachi, Yasukazu Hirao,
Kouzou Matsumoto, Takashi Kubo
624. Synthesis, structures, and photochemical properties of bianthrone thiophene
analogs. Natsuki Takehana,
Kyoko Kawamoto, Daisuke Mitsui,
Masashi Hasegawa, Gaku Yamamoto,
Yasuhiro Mazaki*
625. Synthesis and properties of the poly
substituted azulene derivatives.
Mikihiro Ueno, Taihei Kano,
Mina Miyazaki, Ryuta Miyatake,
Yoshikazu Horino, Mitsunori Oda,
Shigeyasu Kuroda*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
626. Synthesis, photochromic, and electrical
properties of diarylethene derivatives
having 9-carbazolyl substituent.
Yu Arima, Tsuyoshi Tsujioka,
Koji Kubono, Kazushige Hori,
Kentaro Shoji, Yasuhiro Kakihara,
Keita Tani*
627. Synthesis and reaction of Schiff bases
derived from azulene-2-boronic acid ester and amino acid. Hiroki Tanaka*,
Toshihiro Murafuji
628. Stabilization and isolation of anthroxyl
radical species. Yasukazu Hirao*,
Toru Saito, Akihito Konishi,
Kouzou Matsumoto, Hiroyuki Kurata,
Takashi Kubo*
629. New homoconjugated and spiro systems by [2⫹2] cycloadditions of donorsubstituted alkynes and DDQ.
Shin-ichiro Kato, Marten T. Beels,
Philip Laporta, W. Bernd Schweizer,
Corinne Boudon, Jean-Paul Gisselbrecht,
Ivan Biaggio, François Diederich
630. Phosphonium- and borate-bridged
dithienylethene oligomers.
Yuki Nekohashi, Aiko Fukazawa,
Hiroshi Yamada, Shigehiro Yamaguchi*
631. Synthesis, structures and properties of
novel cross-conjugated pi-electron donors with 1,3-dithiole rings.
Yohji Misaki*, Kayoko Yamamoto,
Hiroaki Horiuchi, Atsushi Fujioka,
Yukiko Murakami, Miho Watanabe,
Hisakazu Miyamoto, Takashi Shirahata,
Masashi Hasegawa, Yasuhiro Mazaki
632. Syntheses and properties of 1,3-dithiole
[4]- and [6]dendralenes with thiophene inserted. Masataka Nishiwaki,
Takashi Shirahata, Hisakazu Miyamoto,
Yohji Misaki*
633. Synthesis and properties of ␲-fused
core-modified porphyrin oligomers.
Hajime Watanabe, Hiroki Uoyama,
Shigeki Mori, Tetsuo Okujima,
Hiroko Yamada, Hidemitsu Uno*
634. Synthesis and optical properties of new
corrole isomer containing N-linked bipyrrole unit. Yasunori Kawabe,
Motoki Toganoh, Hiroyuki Furuta*
635. Facile reaction path to 3H-azepine from
alkylphenylnitrene. Siti Mariyah Ulfa,
Hideki Okamoto, Kyosuke Satake*
636. Facile, and catalyst-free synthetic approach of meso-aminoporphyrins by the
reduction of in-situ generated meso-azidoporphyrins. Ken-ichi Yamashita,
Kazuyuki Kataoka, Mokoto Asano,
Ken-ichi Sugiura
637. Synthesis, structure, and electronic and
photophysical properties of two- and
three-layered [3.3]paracyclophane-based
donor-acceptor systems.
Motonori Watanabe*, Kenta Goto,
Masahiko Shibahara, Teruo Shinmyozu
638. Synthesis and properties of novel ttf
dimers and trimers. Ken-ichi Nakamura,
Tomomi Hashimoto, Hisakazu Miyamoto,
Takashi Shirahata, Masashi Hasegawa,
Yasuhiro Mazaki, Yohji Misaki*
639. Synthesis and properties of
bicyclo[2.2.2]octadiene-connected
hexaphyrin. Shigeki Mori,
Hiroki Uoyama, Takahiro Takiue,
Hidemitsu Uno*
640. Synthesis and properties of 1,1’-bis(diacetylene-group) connected ferrocene(pai-electronic system) derivatives.
Junro Yoshino, Rumi Shimuzu,
Emi Hasegawa, Daigo Kawai,
Takuya Toyama, Naoto Hayashi,
Hiroyuki Higuchi*
641. Synthesis and optical properties of starshaped oligothiophenes.
Tomoyuki Narita, Masayoshi Takase,
Tohru Nishinaga, Masahiko Iyoda*,
Kenji Kamada, Koji Ohta
642. Fluorescence study of polyetherchained naphthalimide with metal cation.
Satoshi Nakajima, Kazuho Suda
643. Synthesis and photophysical properties
of thienylcalbazoles. Yosuke Nakamura,
Shin-ichiro Kato, Hiroaki Taguchi
644. Syntheses and magnetic properties of
nitroxide substituted nitronyl nitroxide
with high coplanarity. Tasuku Kumagai,
Shuichi Suzuki, Masato Kuratsu,
Masatoshi Kozaki, Daisuke Shiomi,
Kazunobu Sato, Takeji Takui, Keiji Okada
645. New organic radical with strong donor
ability: Building blocks for magneto-conducting materials. Mark S. Zsombor,
Natia L. Frank*
646. Preparation and properties of poly(arylene) containing Si unit-bridged diphenylamine. Hideki Hayashi*,
Hidenobu Nakao
647. Nonplanar ␲-conjugated stable openshell molecules: Syntheses and 3-D molecular/electronic-spin structures.
Akira Ueda, Shinsuke Nishida,
Shuichi Suzuki, Keiji Okada, Tomoaki Ise,
Daisuke Shiomi, Kazunobu Sato,
Takeji Takui, Kazuhiro Nakasuji,
Yasushi Morita*
648. Novel syntheses, properties and applications of functionalized benzosiloles.
Laurean Ilies, Chikahiko Mitsui,
Hayato Tsuji, Yoshiharu Sato,
Eiichi Nakamura
649. Synthesis of metal-containing fused
polycyclic compounds and their characteristics. Satoru Inoue,
Taniyuki Furuyama, Kengo Yoshida,
Atsuya Muranaka, Masanobu Uchiyama*
650. Relationship between nonlinear optical
properties and open-shell characters in
polycyclic aromatic hydrocarbons including phenalenyl radicals and graphene
nanoflakes. Masayoshi Nakano*,
Hitoshi Fukui, Kyohei Yoneda,
Takuya Minami, Ryohei Kishi,
Takashi Kubo, Kenji Kamada, Koji Ohta,
Edith Botek, Benoît Champagne
651. Elucidation of intra- and intermolecular
covalent bonds of phenalenyl-based delocalized singlet biradicals.
Akihiro Shimizu, Mikio Uruichi,
Kyuya Yakushi, Masayoshi Nakano,
Daisuke Shiomi, Kazunobu Sato,
Takeji Takui, Yasukazu Hirao,
Kozo Matsumoto, Hiroyuki Kurata,
Takashi Kubo*
652. Intra- and intermolecular interactions in
bi- and terthiophenes: structural implications. Martin Pomerantz*,
Nashaat Turkman
653. Development of fast photochromic molecules. Jiro Abe*
654. Synthesis, structure and properties of
␩5-cyclopentadienyl [1,2-bis(dimethyldihydropyrenyl)-3,4-dialkyl-␩4-cyclobutadienyl]cobalt complexes.
Pengrong Zhang, Zinka Brkic,
Allen Oliver, Reginald Mitchell*,
David Berg*
655. Synthesis of [2.2]paracyclophanebased through-space conjugated polymers. Yasuhiro Morisaki*, Shizue Ueno,
Yoshiki Chujo
656. Synthesis of meso-␤ directly linked porphyrin rings. Naoki Aratani*,
Jianxin Song, Hiroshi Shinokubo*,
Atsuhiro Osuka*
657. 5-Alkylthiophene-fused porphyrazines:
Application to solution-processed organic thin-film devices. Miyazaki Eigo*,
Kaku Ayaka, Mori Hiroki,
Iwatani Masahito, Takimiya Kazuo
658. Synthesis and properties of diacetylene-bridged porphyrins bearing a proton
acceptor moiety. Junro Yoshino,
Mizuki Tsujiguchi, Takuya Matsukihira,
Hideto Kempe, Yui Kozake,
Naoto Hayashi, Hiroyuki Higuchi
659. Room-temperature ferroelectricity in
hydrogen-bonded organic crystals.
Sachio Horiuchi*, Yusuke Tokunaga,
Gianluca Giovannetti, Silvia Picozzi,
Hirotake Itoh, Ryo Shimano, Reiji Kumai,
Yoshinori Tokura
660. Towards exceedingly small internal reorganization energies for ␲-conjugated
organic molecules through rational theoretical design. Ito Chao,
Yu-Chang Chang, Wei-Chi Chen,
Wai-Tao Peng, Hsing-Yin Chen,
Ming-Yu Kuo
661. Cyclophanes from bis(isobenzofuran)s:
Working toward molecular belts and cyclacenes. Peter W. Dibble*, David Franz,
Steve Robbins, Matt Hannon,
Michelle Thibault, Kris Fischer
662. Well-defined (NHC)-Pd complexes for
the synthesis of polytriaryl amines.
Mario Hoyos, Michael L. Turner,
Oscar Navarro*
663. N-Heterocyclic carbene embedded in
porphyrin framework. Motoki Toganoh,
Takayoshi Hihara, Hiroyuki Furuta*
664. Simple meso-functionalization of porphyrins through nucleophilic substitution
reaction: Catalyst-free synthesis of mesoazido-, amino-, and alkoxyporphyrins.
Ken-ichi Yamashita, Kazuyuki Kataoka,
Motoko Asano, Ken-ichi Sugiura
665. Efficient two- to five-photon excited violet emission of calix[4]arene-based multidipolar assembly. Man Shing Wong*,
Xiao Ling Zhang, Ping Fang Xia
Convention Center
Kamehameha Halls II and III
Chemistry of Novel Nanocarbons Fullerenes, Carbon Nanotubes and Related
Materials (#45)
Organized by: T. Akasaka, Y. Li, F. Wudl
Presiding: T. Akasaka, Y. Li
Poster Session
10:00 – 12:00
666. Bis-functionalization of La2@C80.
Midori O. Ishitsuka, Shingo Sano,
Haruka Enoki, Satoru Sato,
Hidefumi Nikawa, Takahiro Tsuchiya,
Zdenek Slanina, Naomi Mizorogi,
Takeshi Akasaka*, Shigeru Nagase
667. Theoretical study of endohedral structures and electronic properties of scandium carbide endohedral metallofullerenes. Naomi Mizorogi*,
Takeshi Akasaka, Shigeru Nagase
668. Thermal carbosilylation of
dimetallofullereneLa2@Ih-C80.
Michio Yamada, Mari Minowa,
Masahiro Kako, Satoru Sato,
Naomi Mizorogi, Zdenek Slanina,
Takahiro Tsuchiya, Takeshi Akasaka*,
Shigeru Nagase*
669. Construction of supramolecular complex based on endohedral metallofullerene and exTTF tweezer.
Takahiro Tsuchiya, Risa Nakamura,
Ayumi Sato, Mateusz Wielopolski,
Naomi Mizorogi, Takeshi Akasaka*,
Dirk M. Guldi*, Emilio M. Perez,
Nazario Martín*, Shigeru Nagase*
670. Preparation, characterization and reactions of arc- and nanodiamond-derived
carbon nano-onions. John P. Selegue*,
Mahendra K. Sreeramoju,
Rituraj Borgohain, John D. Craddock
671. Enantiomeric separation of fullerodendron formed by diastereoselective DielsAlder reaction. Nobuhiro Takahashi,
Tomoyuki Tajima, Naoki Tsugawa,
Yutaka Takaguchi*
672. New methanofullerenes containing
amide as electron acceptor for construction photovoltaic properties. Yongjun Li,
Huibiao Liu, Yuliang Li*
673. Fabrication of fullerene aggregates on
nanoscale. Huibiao Liu, Yongjun Li,
Yuliang Li*
674. Anti-proliferative activities on cancer
cell by cationic fullerene derivatives.
Shigeo Nakamura, Sachiko Yokoo,
Shoko Kondo, Yuki Koizumi,
Kyoko Takahashi, Tadahiko Mashino
675. Synthesis and evaluation of novel
fullerene derivatives from 1,3-dion compounds. Tomoaki Endo*,
Shin-ichiro Yoshida, Hiroyuki Momma,
Eunsang Kwon*
676. Kinetics and regioselectivity of fulleroid
in Diels-Alder reaction and mCPBA oxidation: Influence of strain at the bridgehead olefin. Naohiko Ikuma,
Nobuhide Tanaka, Satoko Sumioka,
Ken Kokubo, Takumi Oshima*
677. Construction of supramolecular system
based on La-metallofullerene ligand/metalloporphyrin ligand. Ryo Aoyama,
Tsuchiya Takahiro, Takeshi Akasaka*
678. Synthesis and characterization of endhedral metallofullerene/organic-donor
dyad. Akira Nakata, Takahiro Tsuchiya,
Takeshi Akasaka*
679. Fabrication of graphene from sputtered
amorphous carbon. Heunku Kang,
Suguru Noda*
680. Synthesis of fullerenols having fluorophore moiety. Ken Kokubo*,
Shogo Shirakawa, Itsuka Morita,
Naohiko Ikuma, Takumi Oshima
681. Synthesis of highly soluble multi-arylated [60]fullerene derivatives directed to
resist materials. Miyato Kashihara,
Mai Kato, Tomomi Yano,
Katsutomo Tanaka, Ken Kokubo*,
Naohiko Ikuma, Takumi Oshima
682. Synthesis of substuted cycloparaphenylenes from sequare-shaped tetranuclear platinum complexes.
Takahiro Iwamoto*, Shigeru Yamago
683. Structural determination and chemical
functionalization of metal carbide endofullerene Sc2C2@C80. Hiroki Kurihara*,
Yuko Iiduka, Hidefumi Nikawa,
Naomi Mizorogi, Takahiro Tsuchiya,
Shigeru Nagase, Takeshi Akasaka
684. Organometallic fullerene-polymers with
potential applications in molecular electronics. Claes-Henrik E. Andersson,
Sascha Ott, Helena Grennberg*
685. Isolation and characterization of
La@C76(C6H5). Takayoshi Tsuchiya,
Tsuyoshi Ito, Hidefumi Nikawa,
Zdenek Slanina, Naomi Mizorogi,
Takahiro Tsuchiya, Takeshi Akasaka*,
Shigeru Nagase
686. Regioselective exohedral functionalization of La@C82 and its 1,2,3,4,5-pentamethylcyclopentadiene and adamantylidene adducts. Satoru Sato,
Yutaka Maeda, Koji Inada,
Hidefumi Nikawa, Michio Yamada,
Naomi Mizorogi, Takahiro Tsuchiya,
Tadashi Hasegawa, Slanina Zdenek,
Takeshi Akasaka*, Tatsuhisa Kato,
Shigeru Nagase
687. Conductivity and cristalline quality variations by magnesium atoms doping in
epitaxial-grown C60 thin films.
Crisoforo Morales*, Nobuaki Kojima,
Seiji Nishi, Naoki Ogata,
Masafumi Yamaguchi
688. Synthesis and characterization of novel
electron donor-acceptor conjugated molecule based on C60 and ␲-extended
tetrathiafulvalene. Azusa Iwano,
Lai Feng, Yuta Takano,
Takahiro Tsuchiya, Takeshi Akasaka*,
María Ángeles Herranz, Nazario Martín*
689. Synthesis and complexation behavior of
paramagnetic metallofullerene ligand.
Azusa Oshima, Yuya Yokosawa,
Takahiro Tsuchiya, Takeshi Akasaka*,
Naoki Aratani, Atsuhiro Osuka
690. Synthesis and characterization of stable
[4⫹2] derivatives of La@C82.
Yuki Nagashima*, Yuta Takano,
Satoru Sato, Naomi Mizorogi,
Zdenek Slanina, Takahiro Tsuchiya,
Takeshi Akasaka, Shigeru Nagase,
M. Angeles Herranz, Nazario Martin
691. Improved synthesis of PCBM: Reaction
of p-tosylhydrazone with C60 in an aqueous two-phase system. Toshiyuki Iwai*,
Fukashi Matsumoto, Kazuyuki Moriwaki,
Yuko Takao, Takatoshi Ito,
Toshinobu Ohno*
692. Selective synthesis of azafulleroids from
C60 and amides using N-iodosuccinimide. Toshiki Nagamachi,
Satoshi Minakata*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–125
04-ORGN
693. Reactivity control by encapsulation of
endohedral species. Yukiko Tanabe,
Satoru Sato, Yuko Iiduka,
Makoto Hachiya, Hidefumi Nikawa,
Naomi Mizorogi, Takahiro Tsuchiya,
Takeshi Akasaka*, Shigeru Nagase
694. Quantum chemical approach to photoinduced charge transfer processes in Znporphyrin-oligo-fluorene-C60.
Georgios Katsukis, Linda Brinkhaus,
Mateusz Wielopolski, Dirk M. Guldi*
695. Photoinduced charge-transfer processes in Zn-porphyrin-oligo-fluorene-C60 Linda Brinkhaus, Georgios Katsukis,
Mateusz Wielopolski, Martin R. Bryce,
Dirk M. Guldi*
696. Supramolecular inclusion of
[60]fullerene into calixaren bisporphyrin
hosts. Julia Schornbaum*,
Bruno Grimm, Dirk M. Guldi
Convention Center
Kamehameha Halls II and III
New Directions of Supramolecular
Chemistry toward Nanomaterial Science,
Biomedical Science, and Supramolecular
Catalysts (#47)
Organized by: S. Aoki, W. Chung,
J. Davis, T. Haino
Presiding: S. Aoki
Poster Session
10:00 – 12:00
697. Shape-selective molecular recognition
in confined space provided by calixarene-capped porphyrin and its thermodynamic behavior. Hajime Iwamoto*,
Saori Nishi, Takeharu Haino
698. Synthesis and conformational analysis
of helical aromatic multilayered ureas.
Mayumi Kudo, Takayuki Hanashima,
Atsuya Muranaka, Hisako Sato,
Masanobu Uchiyama,
Hiroyuki Kagechika, Aya Tanatani*
699. Novel strategy to selectively detect
Fe(III) in aqueous media driven by hydrolysis of a rhodamine 6G Schiff base.
Min Hee Lee, Jun Won Park,
Jong Seung Kim*, Chulhun Kang*,
Hyun Jung Kim, Hyo Sung Jung,
Yeon Ok Lee
700. Cysteine selective coumarin-based
chemodosimeter. Hyo Sung Jung,
Hyun Jung Kim, Min Hee Lee,
Yeon Ok Lee, Jae Hong Lee,
Jong Seung Kim*
701. Supramolecular cavitand chemistry.
Melissa J. Latter*
702. Crystal engineering with a novel tetrameric heteroatomic cyclophane.
Anneli Kleyn*, Leonard J. Barbour
703. Switching machine for rotaxane-specific chirality: A brake function for the
shuttling motion between enantiomeric
rotaxanes. Keiji Hirose*,
Hajime Furutani, Yoshito Tobe
704. Selective transformation of a crown
ether/sec-ammonium salt-type rotaxane
to N-alkylated rotaxanes. Sakiko Suzuki,
Kazuko Nakazono, Toshikazu Takata*
705. Spherical molecular container having
two hydrophobic pockets.
Ryota Ohkawa, Michito Yoshizawa*,
Munetaka Akita*
706. Self-assembly of molecular tweezers
with a 2,4,6-triphenyl-1,3,5-triazine
spacer in the solid state.
Yosuke Hisamatsu, Shin Aoki,
Hidenori Aihara*
707. Synthesis of structured oligoethylene
glycols. Kota Adachi*,
Takahiro Muraoka, Kazushi Kinbara
708. Development of amphiphilic oligomers
adopting higher-order structures in a lipid
membrane. Tatsuya Shima*,
Takahiro Muraoka, Kazushi Kinbara
709. Click end-capping reaction of rotaxanes exploiting stable nitrile N-oxide.
Tohru Matsumura, Yasuhito Koyama,
Toshikazu Takata*
710. Inhibition of quorum sensing using cyclodextrins. Tsukasa Ikeda*,
Tomoya Sato, Takuya Imai,
Takuya Kamiyama, Mabike Mamenzigou,
Satoshi Ito, Tomohiro Morohoshi,
Norihiro Kato
126 –TECH
TECHNICAL PROGRAM
711. Quorum sensing quenching in gramnegative bacteria using modified cyclodextrins. Takuya Imai, Satoshi Ito,
Tomohiro Morohoshi, Norihiro Kato,
Tsukasa Ikeda*
712. Preparation and dynamic hydrolytic behavior of imine-bridged [n]rotaxanes and
multiple interlocked systems.
Hiroyoshi Sugino, Hidetoshi Kawai,
Takeshi Umehara, Kenshu Fujiwara,
Takanori Suzuki*
713. Construction of nanoscopic phases
within M12L24 coordination spheres.
Kiyotaka Takao, Kosuke Suzuki,
Sota Sato, Makoto Fujita*
714. Soft materials based on ␲-conjugated
anion-responsive molecules.
Yoshitaka Terashima, Yohei Haketa,
Hiromitsu Maeda*
715. Synthesis of noncyclic amide compounds via tandem Claisen rearrangement and their structure and functions.
Jie Hao, Anil S. Kuwar, Kosuke Izumi,
Midori Goto, Yoshinobu Nagawa,
Masatoshi Kanesato, Kazuhisa Hiratani*
716. Acid/base controllable molecular switch
based on a neutral phenanthroline guest
penetrated pseudorotaxane.
Masahiro Muraoka, Kakeru Aoyama,
Hiromitsu Irie, Mamoru Ohta,
Yohji Nakatsuji
717. Synthesis of [5]catenane via olefin metathesis reaction of pseudorotaxane composed of [2]catenane and secondary-ammonium salt. Hajime Iwamoto*,
Shinzi Tafuku, Takeharu Haino
718. Alignment of gold clusters on DNA via a
zinc finger-metallothionein fusion protein.
Shinya Ariyasu, Takeshi Yamamura,
Shin Aoki
719. Synthesis and catalytic activity of pyridine-incorporated SPM-metal complex.
Atsushi Shigeto, Shinichi Saito,
Ryu Yamasaki*
720. Synthesis and catalytic activity of macrocyclic BINOL derivatives.
Natsuko Ichihara, Eiko Takahashi,
Nobutaka Ueda, Ryu Yamasaki,
Shinichi Saito
721. Dynamic behavior of 3,3=-oligoBINOL
derivatives and its application to asymmetric catalysis. Ranganath V. Kalluri,
Shin-ichiro Tabuchi, Kentaro Ishizuka,
Toshio Kawanami, Hiroshi Furuno,
Satoaki Onitsuka, Junji Inanaga*
722. Convenient modular method for specific labeling of targeting proteins by catalytic amidation: MoAL method.
Munetaka Kunishima*,
Shuich Nakanishi, Ryo Tsurusaki,
Hiroyuki Tanaka, Kazuhito Hioki
723. Self-assembly of bisporphyrin cleft possessing trinitrofluorenone.
Tomoko Oshita, Akihide Watanabe,
Toshiaki Ikeda, Takeharu Haino*
724. Cytochrome c-binding “proteo-dendrimers” as a new type of apoptosis inhibitors working in HeLa cells system.
Hideki Azuma*, Yoshida Yuuka,
Dharam Paul, Satoshi Shinoda,
Hiroshi Tsukube, Takeshi Nagasaki
725. Cation recognition of macrocyclic trisdipyrrin-BF2 complex through efficient
BF-cation interactions.
Naoya Sakamoto, Tatsuya Nabeshima
726. Pressure effects on the inclusion complexation of water-soluble cucurbit[7]uril
with methylene blue in alcohol-water mixtures. Sho Tamaki*, Yoshimi Sueishi
727. Tetraphenylurea-cavitand for anion
binding. Sungjong Seo, Yeon Sil Park,
Kyungsoo Paek*
728. Ureidopyrimidone molecular capsule
based on a quadruple hydrogen bonding.
Yeon-Sil Park*, Kyungsoo Paek
729. Supramolecular chemistry and self-assembly of the N-acylglyoxylic amides and
N-acylglyoxylic esters. Venty Suryanti*,
Pall Thordarson, James Hook,
David S. Black, Naresh Kumar
730. Measurement of nitric oxide scavenging
capacity in lipophilic antioxidants using
modified ␤-cyclodextrin as a water-solubility enhancer. Masashi Hori*,
Yoshimi Sueishi, Yashige Kotake
731. Towards free-standing discrete 2D coordination polymers: Shape-persistent
monomers with terpyridinyl units for lateral periodic growth. Thomas Bauer,
A. Dieter Schlüter, Junji Sakamoto
732. Guest-binding and molecular delivery of
water-soluble cyclophanes having a
pyrene moiety. Osamu Hayashida*,
Chika Eguchi, Tomomi Nakashima,
Yu Oyama, Kosei Shioji
733. Self-assembly and photophysical properties of tris(phenylisoxazolyl)benzene
functionalized with photoresponsive
groups. Toshiaki Ikeda*, Hiroshi Saito,
Tetsuya Masuda, Takeharu Haino
734. Coordination-driven self-assembly:
Synthesis and application of ruthenium
metallacycles. Mi- Eun Moon*,
Vaishali Vajpayee, Anurag Mishra,
Peter J. Stang, Ki-Whan Chi
735. Structure-activity relationship studies of
macrocyclic hexaoxazole (6OTD) dimers
and an evaluation of their telomeric G4
stabilizing properties. Keisuke Iida,
Masayuki Tera, Takatsugu Hirokawa,
Shin-ya Kazuo, Kazuo Nagasawa*
736. Tape-shaped anthracene oligomers
with m-pyridine spacers.
Takayuki Iijima, Michito Yoshizawa*,
Munetaka Akita*
Convention Center
Kamehameha Halls II and III
The Science and Strategy of Process
Chemistry: From Molecules to
Pharmaceutical Drugs (#85)
Organized by: T. McDermott, S. Caron,
G. McLachlan, I. Shinkai
Presiding: T. McDermott
Poster Session
10:00 – 12:00
737. Analysis of the essential oil of Gaultheria fragrantissima Wall.
Shankar P. Paudel
738. Efficient synthesis of KW-7158, unique
dihydrothienobenzothiepine tricyclic
compound, therapeutic agent for urge
urinary incontinent. Eiichiro Imai*,
Tetsuo Matsushita, Arata Yanagisawa,
Takashi Mimura, Shin-ichiro Mohri
739. Novel amide and ester prodrugs of
olmesartan: Synthesis, bioconversion,
and pharmacokinetic evaluation.
Chang Hyun Oh*, Jin-Hun Park,
Jeong-Soo Chang,
Mohammed I El-Gamal,
Won-Kyoung Choi, Woong San Lee,
Hyun-Il Kim, Young-Jin Cho,
Bong Sang Lee, Hong-Ryeol Jeon,
Young Sub Lee, Young Wook Choi,
Jaehwi Lee, Hye Jin Chung
740. N-methylimidazole-mediated efficient
C-acylation of Meldrum’s acid with carboxylic acids or acid chlorides.
Nanae Matsuo, Mami Morimoto,
Hidefumi Nakatsuji, Yoo Tanabe
741. Safe and efficient scale-up from bench
to kilo lab and beyond.
Peter J. Ralbovsky*, Lloyd MacPherson
742. Highly stereocomplementary method
for the preparation of (E)- and (Z)-␣,␤substituted unsaturated esters utilizing
stereoretentive reduction of (E)- and (Z)stereodefined enol tosylates.
Takeyuki Suzuki, Kanako Ueno,
Hidefumi Nakatsuji, Yoo Tanabe
743. Dehydration-type (E)-stereoselective TiClaisen condensation between ␣-heteroatom-substituted acetates and formyl
esters. Hideya Kitaguchi, Hiroaki Mura,
Ryohei Nagase, Yoo Tanabe
744. Stereocomplementary preparation for
trisubstituted (E)- and (Z)-␣,␤-unsaturated esters utilizing successive enol tosylations and Fe-catalyzed cross couplings
of ␤-ketoesters and ␣-formylesters.
Hiroshi Nishiakdo, Hidefumi Nakatsuji,
Kanako Ueno, Yoo Tanabe
745. Design, synthesis, and biological evaluation of a novel series of aryl alkynylthiophenes: Discovery of a potential peripheral cannabinoid-1 receptor antagonists
with weight-loss and thermogenesis-induced effects in DIO mice.
Chun-Ping Chang
746. Discovery and synthesis of CAL-101, a
potent and selective inhibitor of the phosphatidylinositol 3-kinase p110␦ isoform.
Jerry B. Evarts, Roger G. Ulrich
Convention Center
Kamehameha Halls II and III
Supramolecular Photochemistry (#125)
Organized by: Y. Inoue, C. Bohne,
V. Ramamurthy, C. Tung
Presiding: Y. Inoue
Poster Session
10:00 – 12:00
747. Solvent and temperature effects on diastereodifferentiating Paternó-Büchi reaction of chiral cyanobenzoates with diphenylethene upon direct and chargetransfer excitations.
Kazuyuki Matsumura, Emi Nishiuchi,
Tadashi Mori*, Yoshihisa Inoue*
748. Supramolecular fluorescence thiophene
host system by using 2-amino-1,2-diphenylethanol. Yoshitane Imai*,
Naoki Shiota, Takafumi Kinuta,
Tomohiro Sato, Nobuo Tajima,
Reiko Kuroda, Yoshio Matsubara
749. Porphyrin - silica gel composite acting
as cobalt-free humidity indicator.
Tomoko Matsumoto, Masahide Yasuda
750. Water-soluble phosphrousporphyrins
for visible light-assisted sterilization of
Saccharomyces cerevisiae.
Tomohiko Shinbara, Masahide Yasuda
751. Enantiodifferentiating anti-Markovnikov
photoaddition of water to 1,1-diphenylpropene included and sensitized by
naphthoyl-curdlan. Mami Imai*,
Gaku Fukuhara, Cheng Yang,
Tadashi Mori, Yoshihisa Inoue
752. Catalytic bio-supramolecular photocyclodimerization of 2-anthracencecarboxylate mediated by serum albumin.
Hanako Kato*, Masaki Nishijima,
Gaku Fukuhara, Cheng Yang,
Tadashi Mori, Yoshihisa Inoue
753. Entrainer effects on photosensitized enantiodifferentiating cyclization and
isomerization in supercritical carbon dioxide. Yasuhiro Nishiyama,
Hirosuke Saito, Takehiko Wada,
Yoshihisa Inoue, Kiyomi Kakiuchi
754. Reversible transformation and fluorescent properties in polymorphic crystals of
n- butylammonium 2-naphthalenesulfonate. Atsushi Yamamoto,
Masaaki Matsumoto, Tomoaki Hinoue,
Yuji Mizobe, Ichiro Hisaki, Mikiji Miyata,
Norimitsu Tohnai
755. Photochirogenesis in chiral ionic liquid:
Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid in
(R)-1-methyl-3-(2,3-dihydroxypropyl)imidazolium bistriflimide. Gaku Fukuhara*,
Cinzia Chiappe, Andrea Mele,
Bernardo Melai, Fabio Bellina,
Yoshihisa Inoue
756. Diastereodifferentiating photocyclodimerization of 2-anthracenecarboxylate tethered to amylose scaffold.
Tomohiro Nakamura*, Gaku Fukuhara,
Cheng Yang, Tadashi Mori,
Yoshihisa Inoue
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
757. Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid
mediated by (S)-prolinol.
Shinya Katsumata*, Yuko Kawanami,
Gaku Fukuhara, Masaki Nishijima,
Cheng Yang, Tadashi Mori,
Yoshihisa Inoue
758. Photocyclodimerization of 2-hydroxyanthracene and supramolecular photochirogenesis with chiral hydrogenbonding template TKS-159.
Hiroaki Umehara, Gaku Fukuhara,
Cheng Yang, Masaki Nishijima,
Tadashi Mori, Yoshihisa Inoue
759. Photocyclization vs. photorearrangement of 4-aryl-1,1-dicyanobutenes confined in polymeric media. Tadashi Ito,
Emi Nishiuchi, Tadashi Mori,
Cheng Yang, Gaku Fukuhara,
Yoshihisa Inoue
760. Synthesis and changeable chiroptical
properties of axially chiral binapthyls
linked to a photochromic azobenzene.
Kazuto Takaishi*, Masuki Kawamoto
761. Liquid crystalline and solid-state fluorescent system with cis-trans photoisomerization of stilbene.
Chien-Chih Chen*, Norimitsu Tohnai,
Tomoaki Hinoue, Ichiro Hisaki,
Mikiji Miyata
762. Diastereoselective [2⫹2] photocycloaddition of chiral cyclic enone supported on
silsesquioxane with ethylene.
Yuuki Yanagisawa, Yamaguchi Hiroki,
Nishiyama Yasuhiro, Tsutsumi Ken,
Morimoto Tsumoru, Kakiuchi Kiyomi
763. Intermolecular radical addition to alkenes via photochemical decarboxylation
of free carboxylic acids.
Yasuharu Yoshimi*, Keisuke Nishikawa,
Minoru Hatanaka, Tatsuya Itou
764. Synthesis of macrocyclic lactone by intramolecular radical cyclization via photochemical decarboxylation.
Keisuke Nishikawa, Yasuharu Yoshimi*,
Minoru Hatanaka, Tatsuya Itou
765. Formation of anion via photochemical
decarboxylation of malonates.
Takashi Naoe, Yasuharu Yoshimi*,
Tatsuya Itou
766. Influence of side chain on photochemical decarboxylation of tripeptides.
Kousuke Maeda, Yasuharu Yoshimi*
767. Addition of alkyl radicals to glyoxylic
oxime ether via photochemical decarboxylation of free carboxylic acids.
Kosuke Kobayashi, Yasuharu Yoshimi*,
Minoru Hatanaka, Tatsuya Itou
768. Photochemical decarboxylation of free
carboxylic acids in water using photosensitive surfactant. Kazuki Sugiyama,
Yasuharu Yoshimi*
769. Decarboxylation of aminomalonates by
photogenerated cation radicals of arenes.
Nguyen M. Hung, Yasuharu Yoshimi*,
Minoru Hatanaka, Tatsuya Itou
770. Supramolecular enantiodifferentiating
photoisomerization of cyclooctene included and sensitized by ␤-cyclodextrin
derivatives. Wenting Liang*,
Cheng Yang, Yoshihisa Inoue*,
Runhua Lu, Gaku Fukuhara, Tadashi Mori
771. Electronic circular dichroism of neutral
and protonated aza[6]helicenes and their
supramolecular complexation behavior.
Yoshito Nakai, Tadashi Mori,
Gaku Fukuhara, Cheng Yang,
Yoshihisa Inoue
772. Spectrocopic study on the inclusion
complex of cryptophane-M and chloroform. Xueming Li*, Yanqi Shi*,
Jianchun Yang*, Fang Gao*,
Wenjing Yang, Wulin Li
773. Guest-dependent luminescent switching system in the solid state of 9,10-anthracene derivatives. Misa Sugino,
Norimitsu Tohnai, Ichiro Hisaki,
Mikiji Miyata
774. Mechanistic studies of the excitationwavelength dependence of enantiodifferentiating photosensitized isomerization of
(Z)-cyclooctene. Daisuke Yoneda*,
Hirosuke Saito, Gaku Fukuhara,
Cheng Yang, Tadashi Mori,
Takehiko Wada, Yoshihisa Inoue
775. Bio-supramolecular photochirogenesis:
Enantiodifferentiating photocyclodimerization of 2-anthracencecarboxylate mediated by mammalian serum albumins.
Masaki Nishijima, Tadashi Mori,
Takehiko Wada, Yoshihisa Inoue
776. Fluorescence modulation of phenol derivatives toward the development of organic gas sensing system.
Masaaki Akamatsu, Ken Okamoto,
Taizo Mori, Hideki Sakai, Masahiko Abe,
Jonathan P. Hill, Katsuhiko Ariga*
777. Selective photoinduced energy transfer
from a thiophene rotaxane to acceptor.
Kazuya Sakamoto,
Yoshinori Takashima,
Hiroyasu Yamaguchi, Akira Harada
778. Highly efficient fluorescent molecules
based on 5,5’-benzimidazole-2,2’-bipiridine. Hitoshi Ishida*,
Shun-ichi Kawasaki, Shigero Oishi
779. Reversible transformation and concomitant fluorescence switching in inclusion
crystals of ammonium anthracene disulfonate. Tomoaki Hinoue,
Norimitsu Tohnai, Ichiro Hisaki,
Mikiji Miyata*
780. Development of novel molecular rotors
with two photoswitchable units.
Shunsuke Kuwahara*, Yuki Nakano,
Yoichi Habata
781. Synthesis and photoresponsive properties of a macrocycle based on an azobenzene-linked ligand. Masaki Yamamura*,
Yuki Okazaki, Tatsuya Nabeshima
782. Structure control of photosensitized
dendrimers for light emitting application.
Hideki Kawai, Tetsuya Sengoku,
Masaki Takahashi, Hidemi Yoda
783. Regioselective photocyclodimerization
of olefins pre-organized using host-guest
interactions. Hiromi Irie, Shuuhei Hara,
Asao Nakamura*
784. Colorimetric detection of anions by a
new thiourea-phthalimide dyad.
Sebastian Hanft, Axel G. Griesbeck
785. Visualization of the binding of drug molecules to Human serum albumin by fluorescent probe displacement.
Yoshiaki Sakatani, Asao Nakamura*
786. Synthesis and properties of
[3.3](1,6)pyrenophanes. Yu Matsuno,
Hajime Maeda*, Masahito Segi*
787. Metal ion-induced changes in photochromic properties of bisviologen derivatives. Tetsuo Kuwabara*,
HaoCheng Guo, Hiroki Orii
788. Synthesis of azobiphenyl having pyridyl
groups and its dynamic behavior by photoisomerization. Rie Arai,
Hidetoshi Goto, Hiroshi Sugimoto*
Convention Center
Kamehameha Halls II and III
New Dimensions of Green Sustainable
Chemistry: Novel Reactions and Catalysts
(#132)
Organized by: S. Kobayashi, P. Anastas,
T. Braish, M. Krische, C.J. Li
Presiding: S. Kobayashi, P. Anastas
Poster Session
10:00 – 12:00
789. Palladium-catalyzed decarboxylative
coupling of biomass-derived cinnamic
acids. Tetsuya Satoh*, Mana Yamashita,
Koji Hirano, Masahiro Miura*
790. Synthesis of p-quinones using catalytic
hypervalent iodine oxidation of p-dialkyoxyarenes. Takayuki Yakura*,
Ayaka Ozono, Yu Yamauchi, Yuan Tian
791. Rare-metal-free aromatic carbon-nitrogen bond formation reactions.
Takuji Hatakeyama, Yuya Yoshimoto,
Imayoshi Ryuji, Sujit K. Ghorai,
Masaharu Nakamura*
792. Development of an efficient method for
the preparation of 5-hydroxyl-1,3-dioxiane as the smallest 1,3-protected glycerol from a mixture of 1,2- and 1,3-protected glycerol, and a versatile synthesis
of Branched Oligo-Glycerols (BGL) from
the purely prepared 5-hydroxyl-1,3-dioxiane. Hatsuhiko Hattori*,
Kohsuke Yoshitomi, Ayato Katagiri,
Hisao Nemoto
793. New class of nitroxyl radical catalysts
for oxidation of alcohols.
Yusuke Sasano, Masatoshi Shibuya,
Masaki Tomizawa, Yoshiharu Iwabuchi*
794. Synthesis of seven-menbered cyclic
ureas by the [5⫹2] cycloaddition reaction
of 2-vinylaziridines and electron-deficient
isocyanates. Eri Kanno, Shunsuke Koya,
Kenichi Yamanoi, Shinichi Saito*
795. Regio- and stereo-selective addition of
carboxylic acids to alkynes catalyzed by
phosphine-modified Ru/CeO2.
Masami Nishiumi*, Hiroki Miura,
Kenji Wada, Saburo Hosokawa,
Masashi Inoue
796. Magnetically recoverable osmium catalysts immobilized on magnetite nanoparticles. Ken-ichi Fujita*,
Manabu Yamazaki, Taku Ainoya,
Teruhisa Tsuchimoto, Hiroyuki Yasuda
797. Synthesis of substituted dienes via coupling of alkynes with acrylic compounds
by oxide-supported Ru catalysts.
Hiroki Miura*, Shun Shimura,
Saburo Hosokawa, Kenji Wada,
Masashi Inoue
798. Coupling reaction of benzylic and allylic
chlorides with butenylgallium or -indium
species. Kensuke Kiyokawa,
Makoto Yasuda, Akio Baba*
799. Selective synthesis of N-alkyl hydroxylamines by the hydrogenation of various
nitroalkanes using supported palladium
catalysts. Yasumasa Takenaka*,
Takahiro Kiyosu, Goro Mori,
Jun-Chul Choi, Toshiyasu Sakakura,
Hiroyuki Yasuda*
800. Synthesis and fluorescence properties
of 2-arylquinolines and 1,4-dihydropyridines. Shunsuke Sueki, Ryo Takei,
Junya Abe, Chiharu Okamoto,
Isao Shimizu, Keisuke Seto,
Yukio Furukawa
801. Catalytic oxidative coupling of methane
in an electric field. Yasushi Sekine*,
Kazumasa Oshima, Keisuke Tanaka,
Masahiko Matsukata, Eiichi Kikuchi
802. Immobilized Cu(II) on organic-inorganic
hybrid materials: The effective and reusable catalysts for Biginelli reaction.
Xiao-Jin Huang, Xiao-Jie Liu,
Xiu-Li Zhang*
803. Aerobic oxidation of alcohols and direct
oxidative ester formation catalyzed by
polymer-immobilized bimetallic nanocluster catalysts. Kosuke Kaizuka,
Hiroyuki Miyamura, Shu Kobayashi*
804. Mechanistic studies of zinc hydroxidecatalyzed allylation of aldehydes by ESIMS. Miyuki Yamaguchi, Shu Kobayashi*
805. Silver oxide as a novel catalyst for carbon— carbon bond-forming reactions in
aqueous media. Arata Tanoue,
Masaharu Ueno, Shu Kobayashi*
806. Highly enantioselective Friedel-Craftstype alkylation reactions of indoles with
chalcone derivatives using a chiral barium
catalyst as a Brønsted base.
Yuichiro Kano, Tetsu Tsubogo,
Yasuhiro Yamashita, Shu Kobayashi*
807. Catalytic carbon-carbon bond-forming
reactions of ␣-aminoacetonitrile with imines. Masatoshi Matsumoto,
Yasuhiro Yamashita, Shu Kobayashi*
808. Synthesis of cyclic-C-linked carbo-␤amino esters and peptides via ring closing metathesis. Basker Sundararaju*,
Achard Mathieu, Sharma V. Gangavaram,
Bruneau Christian*
809. Synthesis and application of alkenylindium by carboindation using indium tribromide, alkynes, and ketene silyl acetals. Yoshihiro Nishimoto,
Makoto Yasuda, Akio Baba*
810. Novel oxide catalyst for oxidative coupling of methane. Keisuke Tanaka,
Yasushi Sekine*, Jyunki Inoue,
Masahiko Matsukata, Eiichi Kikuchi
811. Evaluation of back-shielded gallium
complexes by theoretical calculation and
their application for a catalytic reaction.
Hideto Nakajima, Makoto Yasuda,
Akio Baba*
812. Asymmetric catalysis in ionic liquids:
Development of diionic chiral metal complex catalysts immobilizable to ionic liquids. Saori Fujii, Hiroshi Furuno*,
Satoaki Onitsuka, Junji Inanaga*
813. Indium trichloride/trimethylsilyl bromide-catalyzed ␣-alkylation of carbonyl
compounds by direct use of alcohol derivatives and vinyl esters.
Yoshiharu Onishi, Yoshihiro Nishimoto,
Makoto Yasuda, Akio Baba*
814. Indium-catalyzed retro-Claisen rearrangement. Shun-ichi Yamamoto*,
Atsushi Kawata, Taihei Noborio,
Takashi Matsuki, Kazumi Takata,
Yoichiro Kuninobu, Kazuhiko Takai
815. Chemo- and regioselective hydroindation. Ikuya Shibata*, Shinji Miyamoto
816. Ruthenium complexes featuring P,Ochelating ligands: Regioselective allylation directly from alcohol.
Basker Sundararaju*, Achard Mathieu,
Sharma Gangavaram. V. M,
Bruneau Christian
817. Preparation of indoles by intramolecular
cyclization of o-alkynylaniline catalyzed
by silver nitrate. Hideyuki Noguchi,
Mohamed Soliman Mohamed Ahmed,
Keiji Mori, Takahiko Akiyama*
818. Selective synthesis of homoallylic alcohol or homoallylic ether by indium triiodide-catalyzed direct hydroallylation of
ester. Yoshihiro Inamoto,
Yoshihiro Nishimoto*, Makoto Yasuda,
Akio Baba
819. Utilization of CO2 for carbonic acid ester process. Masaaki Shinohata,
Budianto Bijanto, Nobuhisa Miyake*
820. Innovative process for carbonates from
CO2. Nobuhisa Miyake*,
Masaaki Shinohata, Budianto Bijanto
821. Glycosylation of unprotected and unactivated sugars. Bala Kishan Gorityala,
Xue-Wei Liu*
822. Oxidative carbonylation of aniline to
methyl-N-phenylcarbamate: Performance
and mechanism of highly efficient cobalt
catalysts. Joerg Sundermeyer*,
Fuming Mei, Andreas Jacob,
Marcus Harrer, Felix Gärtner
823. Polymer-supported dirhodium(II) catalyst for asymmetric amination reaction.
Tadashi Ohara, Koji Takeda,
Masahiro Anada, Hisanori Nambu,
Shunichi Hashimoto*
824. First sequential Mukaiyama-Michael reaction/crossed-Claisen condensation using two molar ketene silyl acetals and one
molar ␣,␤-unsaturated esters promoted
by a NaOH catalyst. Hiroaki Tamagaki,
Yuuya Nawate, Ryohei Nagase,
Yoo Tanabe
825. t-Butoxide-meditated arylation of benzene with aryl halides in the presence of a
catalytic amount of a 1,10-phenanthroline
derivative. Eiji Shirakawa*, Ken-ichi Itoh,
Tomohiro Higashino, Tamio Hayashi*
826. Synthesis of four spermidine analogs
using various ionic liquids.
Francis C. Mayville*,
Weston J. Umstead
827. Mild and environment-friendly oxidation
of alcohols using PEG-TEMPO in combination with oxone. Mariko Nakano,
Masayuki Okudomi,
Kazutsugu Matsumoto*
828. Vanadium-catalyzed oxidative bromination using bromide salt and Lewis acid
under molecular oxygen.
Kotaro Kikushima, Toshiyuki Moriuchi*,
Toshikazu Hirao*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–127
04-ORGN
829. General, robust, and stereocomplementary preparation of ␤-ketoester enol
phosphates using (RO)2POCl-N-methylimidazole agents and its application to
the stereoretentive synthesis of tri- and
tetra- (E)- or (Z)- ␣,␤-unsaturated esters.
Hiroshi Hori, Mami Morimoto,
Hidefumi Nakatsuji, Yoo Tanabe
830. Simple synthesis of fluorine-containing
heterocyles by noncatalytic 1,3-dipolar
cyclization of azomethine imines with
tert-butyl-(␣-trifluoromethyl)acrylate
(MAF-TBE). Takayuki Nishimine,
Shinichi Ogawa, Etsuko Tokunaga,
Norio Shibata*
831. Photocatalytic aerobic epoxidation of
alkenes in the mixed solvent under visible
light irradiation by iron(III) porphyrin with
Mg-Al hydrotalcite anionic clay.
Terumichi Izawa*, Kentaro Teramura*,
Tetsuya Shishido, Tsunehiro Tanaka
832. Chitosan stabilized metal nanoclusters
as efficient catalysts for aerobic oxidation
of alcohols. Arumugam Murugadoss,
Hidehiro Sakurai*
833. Withdrawn
834. Development of triazolium ionic liquids.
Jae-Sang Ryu*, Yunkyung Jeong
835. Environmentally benign photocatalytic
reactions in microstructured devices.
Yoshihisa Matsushita*,
Shinichi Ookawara
Convention Center
Kamehameha Halls II and III
Metal Catalysis for Asymmetric Synthesis
(#282)
Organized by: H. Sasai, A. Charette,
H. Davies, D. Yang
Presiding: H. Sasai, D. Yang, A. Charette,
H. Davies
Poster Session
10:00 – 12:00
836. Design of chiral ligands with axially
chiral C-N bonds for palladium catalyzed
asymmetric reaction. Takashi Mino*,
Haruka Yamada, Kazuya Wakui,
Masami Sakamoto, Tsutomu Fujita
837. Preparation of new ClickFerrophos ligands and their application to asymmetric synthesis. Kazumi Imae*,
Kenta Shimizu, Kenichi Ogata,
Shin-ichi Fukuzawa*
838. Synthetic approach of optically active
milnacipran and the analogs via catalytic
enantioselective reaction using a disulfonamide derived from L-phenylalanine.
Takuya Nagai, Yuko Hirose,
Naka Koyata, Takuya Noguchi,
Masashi Kawasaki, Masayuki Kirihara,
Nobuyuki Imai*
839. Synthetic approach of optically active
␣-amino acid containing a cyclopropane
ring via catalytic enantioselective reaction
using a disulfonamide derived from
L-phenylalanine. Masaki Serizawa,
Naka Koyata, Yuko Hirose, Azusa Izumi,
Yuki Fuda, Takuya Nagai,
Takuya Noguchi, Tsuyoshi Miura,
Nobuyuki Imai*
840. Chiral polydentate anionic NHC of Pd
complex: Synthesis and asymmetric catalysis. Miaki Kawakami,
Satoshi Sakaguchi*
841. Asymmetric Cu-catalyzed 1,4-addition
of R2Zn to enone in the presence of a
chiral azolium salt. Ayako Harano,
Satoshi Sakaguchi*
842. Catalytic enantioselective SimmonsSmith reaction of 3-aryl-3-siloxymethyl-2butenols using L-phenylalanine deriveddisulfonamide and synthesis of optically
active cis-2-[(1-adamantylamino)methyl]1-phenylcyclopropane derivatives.
Yuko Hirose, Takuya Nagai,
Naka Koyata, Takuya Noguchi,
Nobuyuki Imai*
843. Asymmetric synthesis of axially chiral
biaryl bisphosphine by rhodium-catalyzed intramolecular double [2 ⫹ 2 ⫹ 2]
cycloaddition. Fumiya Mori*,
Naohiro Fukawa, Ken Tanaka
128 –TECH
TECHNICAL PROGRAM
844. Copper (II)-catalyzed asymmetric acylation of ␴-symmetric 1,3-diols utilizing a
novel C2-symmetric chiral diamine ligand. Terumichi Enomoto,
Aki Kawashima, Ryuichi Shirai*
845. Chiral multinuclear catalyst for palladium-catalyzed asymmetric alkylative ringopening reaction. Keisuke Tanaka,
Kohei Endo, Takanori Shibata*
846. Development of asymmetric hydrogenation of N-heteroaromatic compounds
catalyzed by chiral iridium dinuclear complexes. Takuto Nagano,
Takashi Ohshima, Damien Cartigny,
Tahar Ayad,
Virginie Ratovelomanana-Vidal,
Jean-Pierre Genet, Kazushi Mashima
847. Development of multinuclear catalyst
using SPINOL-PHOS for Cu-catalyzed
asymmetric conjugate addition of organometallic reagents. Hamada Daisuke,
Endo Kohei, Shibata Takanori*
848. Highly enantioselective 1,4-addition of
dialkylzincs to enones using novel N,N,Ptridentate ligands. Kenjiro Kawamura*,
Hitomi Fukuzawa, Masahiko Hayashi
849. Novel spiro chiral oxazoline ligands for
asymmetric catalysis. Akira Narayama,
Kazutaka Shibatomi*, Yoshinori Soga,
Tsubasa Muto, Seiji Iwasa
850. Enantioselective construction of fluorinated quaternary stereogenic centers via
catalytic asymmetric Diels-Alder reaction.
Kazutaka Shibatomi*,
Fumito Kobayashi, Seiji Iwasa,
Hisashi Yamamoto
851. Enantioselective hydrocyanation of aldehydes catalyzed by ruthenium-lithium
combined complex. Nobuhito Kurono,
Tatsuya Yoshikawa, Mikio Yamasaki,
Takeshi Ohkuma*
852. Formation of multi-stereogenic centers
using catalytic diastereoselective nitroaldol reaction. Takayoshi Arai*,
Yoshinori Taneda, Yoko Endo
853. Enantioselective synthesis of chiral tripodal cage compounds by intramolecular
[2⫹2⫹2] cycloaddition of branched
triynes and diyne-nitriles.
Toshifumi Uchiyama, Kohei Endo,
Takanori Shibata*
854. Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic
and aliphatic sulfinates.
Mitsuhiro Ueda*, John F. Hartwig
855. Chiral induction by cinchona alkaloids
in the rhodium(II) catalyzed X-H (X ⫽ N,O)
insertion reaction. Hiroaki Saito*,
Ryo Iwai, Taketo Uchiyama,
Muneharu Miyake, Shinichi Miyairi*
856. Catalytic asymmetric cyclopropanation
reactions of succinimidyl diazoacetate
and diazoacetamides with alkenes catalyzed by oxazolinylbenzene-Ru(II) complexes. Soda Chanthamath,
Kazutaka Shibatomi, Seiji Iwasa
857. Asymmetric synthesis of dihydrobenzofuran natural products via intramolecular
C-H insertion reaction catalyzed by chiral
dirhodium(II) carboxylates.
Yoshihiro Natori, Koji Takeda,
Hisanori Nambu, Shunichi Hashimoto*
858. Catalytic synthesis of various cyclic
polyphenylenes by consecutive inter- and
intramolecular cycloadditions.
Hirashima Hiroyuki, Endo Kohei,
Shibata Takanori
859. DFT study on 5-endo-trig type cyclization of ␤,␥ unsaturated carboxylic acids
using Pd-SPRIX catalyst.
Randa K. Gabr, Gan B. Bajracharya,
Xianjin Lin, Kazuhiro Takenaka,
Shinobu Takizawa, Yoshihiro Okada,
Takuji Hatakeyama, Masaharu Nakamura,
Hiroaki Sasai*
860. Asymmetric rhodium-catalyzed cyclopropene hydroacylation: A new route to
highly functionalized chiral cyclopropanes. Diem T. Phan, Vy M. Dong*
861. Asymmetric construction of chiral multicyclic skeletons by rhodium-catalyzed
cycloaddition cascade.
Masayuki Kobayashi, Takeshi Suda,
Hidetomo Imase, Ken Tanaka*
862. Asymmetric synthesis of axially chiral
1-arylisoquinolines by rhodium-catalyzed
[2 ⫹ 2 ⫹ 2] cycloaddition.
Norifumi Sakiyama*, Daiki Hojo,
Ken Tanaka
863. Coupling reaction of aryl halides and
formamides by using nickel-phosphite
catalytic system. Ah-Byeol Park,
Sunwoo Lee
864. Synthesis of diaryl alkynes from propiolic acid by using palladium catalyst.
Kyungho Park, Sunwoo Lee
865. Asymmetric synthesis of axially chiral
4-aryl-2-quinolinones by transition-metalcatalyzed intramolecular hydroarylation.
Tetsuro Shibuya, Yu Shibata,
Ken Tanaka*
866. Asymmetric synthesis of helicene-like
molecules by rhodium-catalyzed intermolecular double [2 ⫹ 2 ⫹ 2] cycloaddition.
Naohiro Fukawa, Takeshi Suda,
Ken Tanaka*
867. Catalytic enantioselective Diels-Alder
reaction of Danishefsky diene using chiral
Yb complexes. Shinji Harada,
Nozomi Toudou, Shiharu Hiraoka,
Atsushi Nishida*
868. Withdrawn
869. Synthesis of Pd-CNT nanocomposites
and its application for the hydrodehalogenation of aryl halides. Yong Kim,
Sunwoo Lee, Hyun Chul Choi,
Ja Young Kim
870. Rhodium-catalyzed asymmetric [2 ⫹
2 ⫹ 2] cycloadditions of diynes and
enynes with 1,3-dicarbonyl compounds.
Takeshi Suda, Ken Tanaka*
871. Stereoselective conjugate addition of
␣-ketoesters to nitroalkenes catalyzed by
chiral Ni(OAc)2-diamine complexes.
Yoshitaka Hamashima,
Ayako Nakamura, Sylvain Lectard,
Daisuke Hashizume, Mikiko Sodeoka
872. New sp2N/sp3N combined chiral tetradentate ligands R-BINAN-R’-Py: An application to asymmetric hydrogenation of
aromatic ketones. Hiroshi Nakatsuka,
Toshimitsu Muraoka, Hanmin Huang,
Masahiro Yoshimura, Masato Kitamura*
873. Efficient ring opening reaction of oxaand aza-bicyclic alkenes catalyzed by
palladium with ferrocene-based phosphine ligand. Tetsuo Ohta*,
Yoshinori Suzuma, Yohei Oe
874. Synthesis of cyclic allenes and allenophanes by palladium-catalyzed cyclization of malonate-tethered 2-bromo-1,3dienes. Masamichi Ogasawara*,
Hiroaki Ichio, Hidetoshi Murakami,
Tamotsu Takahashi*
875. Synthesis and application of helically
chiral phosphine derivatives with atropisomeric dienyl skeleton.
Masamichi Ogasawara*,
Hikaru Nakajima, Kiyohiko Nakajima,
Tamotsu Takahashi*
876. Enantioselective synthesis of ␥-lactones via intramolecular Wacker-type cyclization catalyzed by Pd-SPRIX.
Mitsutoshi Akita
877. Pd(II)-catalyzed oxidative tandem cyclization for the construction of oxa-heterohelicene. Akihiro Tanoue, Ryo Irie*
878. Mo-catalyzed asymmetric synthesis of
planar-chiral metallocenylphosphines
and their application as chiral ligands.
Masamichi Ogasawara*,
Susumu Watanabe, Sachie Arae,
Kiyohiko Nakajima, Tamotsu Takahashi*
879. Methylene-bridged P-chiral diphosphine ligands and related compounds:
Efficient preparation and application in
catalytic asymmetric reactions.
Ken Tamura, Daisuke Mayama,
Masashi Sugiya, Tomokazu Ogura,
Yui Ikematsu, Imamoto Tsuneo*
880. Enantioselective Friedel-Crafts reaction
of ␤-trifluoromethylated acrylates with
pyrroles. Satoru Suzuki, Yiyong Huang,
Etsuko Tokunaga, Norio Shibata
881. Palladium-catalyzed asymmetric halocyclization of ␣-allylmalonamide.
Keiko Ishimaru, Shinya Iikawa,
Daishirou Minato, Masami Kuriyama,
Osamu Onomura*
882. Enantioselective nickel-catalyzed conjugate addition of diethylzinc to enones
using chiral ␤-amino alcohol.
Chih-Hao Tseng, Biing-Jiun Uang*
883. Enantioselective addition of dialkylzinc
to N-(diphenylphosphinoyl)imines mediated by chiral ␤-amino alcohol.
Wei-Ming Huang, Biing-Jiun Uang*
884. Enantioselective Darzens reaction by
chiralselenide catalysts.
Shin-ichi Watanabe*, Risa Hasebe,
Jun Ouchi, Hideko Nagasawa,
Tadashi Kataoka
885. Synthesis and characterization of the
new axially chiral bis(isoquinoline) ligand
and its metal complexes.
Hiroki Tokushima, Shinji Umeda,
Ryo Irie*
886. Asymmetric radical fragmentation reaction. Jake Zimmerman*,
Joshua Judkins, Amanda Holloway,
Andro Youssef, Elizabeth Buenger
887. Rhodium-catalyzed asymmetric conjugated alkynylation of ␣,␤-unsaturated aldehydes. Takahiro Nishimura*,
Takahiro Sawano, Tamio Hayashi*
888. Rhodium/chiral diene-catalyzed asymmetric 1,4-addition of arylboroxines to
␤,␤-disubstituted ␣,␤-unsaturated ketones. Ryo Shintani*, Momotaro Takeda,
Takahiro Nishimura, Tamio Hayashi*
Friday Afternoon
Hilton
Sea Pearl V/VI
Reactive Intermediates and Unusual
Molecules - A Celebration of Bob Moss’s 70
years (#1)
Organized by: M. Platz, M. Abe, W. Leigh
Presiding: W. Leigh
12:30 – 889. Transition state spectroscopy
of oxyallyl. Takatoshi Ichino,
Stephanie M. Villano, Adam J. Gianola,
Daniel J. Goebbert, Luis Velarde,
Andrei Sanov, Stephen J. Blanksby,
Xin Zhou, David A. Hrovat,
W. C. Lineberger*, Weston T. Borden*
13:00 – 890. Development of a novel bioscavenger against chemical nerve
agents. Christopher M. Hadad
13:30 – 891. Reactive carbene, ketene and
radical intermediates on planar and nanoparticle metal surfaces.
Mark S. Workentin*
14:00 – 892. Surface-mounted molecular rotors. Josef Michl*
14:30 – 893. Gas phase reactions gold carbenes and nitrenes. Peter Chen*
15:00 – 894. Nitrene rearrangements.
Curt Wentrup*, David Kvaskoff
15:30 – 895. Chemistry of aryloxenium ions
and their nitrenium ion analogs.
Michael Novak, Yue-Ting Wang,
Mrinal Chakraborty, Kyoung Joo Jin
16:00 – 896. Development of analytical tools
for nitroxyl (HNO) detection.
John P. Toscano*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
Hilton
South Pacific II
Asymmetric Organocatalysis (#62)
Organized by: K. Maruoka, L. Deng,
L. Gong
Presiding: K. Maruoka, L. Gong, L. Deng
12:30 – 897. Enantiodivergent reaction by
conformationally flexible guanidine-thiourea bifunctional organocatalyst.
Kazuo Nagasawa*
12:50 – 898. Development of organocatalytic
cascade reactions for rapid construction
of diverse heterocyclic architectures.
Wen-Jing Xiao*
13:10 – 899. Chiral base catalyzed enantioselective reactions. Choon Hong Tan*
13:30 – 900. Recent progress in the chiral
phosphoric acid catalyzed reactions.
Takahiko Akiyama*
14:00 – 901. Enamine chemistry: Enzymes,
organocatalysis, and new therapeutic approaches. Carlos F. Barbas*
14:30 – 902. Amine-catalyzed pericyclic or
cascade asymmetric reactions.
Ying-Chun Chen*
15:00 – 903. Asymmetric catalysis with hydrogen-bond donors. Yoshiji Takemoto*
15:30 – 904. Mechanistic studies of organocatalytic reactions. Donna Blackmond*
16:00 – 905. Origin of prebiotic chirality in
amino acids and sugars.
Ronald Breslow*
Hilton
South Pacific IV
Marine Natural Products: Isolation, Biology,
Ecology, and Synthesis (#80)
Organized by: J. Rainier, R. Anderson,
M. Murata
Presiding: M. Murata
12:30 – 906. NMR guided isolation of secondary metabolites from marine organisms. Peter T. Northcote*
13:00 – 907. New marine siderophores: Tuning the relative hydrophilicity and hydrophobicity. Alison Butler*, Moriah Sandy,
Julia Vraspir
13:30 – 908. Total synthesis and biological
evaluation of the large non-ribosomal
peptide polytheonamide B.
Masayuki Inoue*
14:00 – 909. Natural products from symbiotic microorganisms isolated from octocorals. Brad Haltli, Fabrice Berrue,
Russell Kerr*
14:30 – 910. New compounds from marine
animal-bacteria associations.
Eric Schmidt*
15:00 – 911. Our recent study on puffer fish
toxins. Mari Yotsu-Yamashita*,
Riku Kaneko, Kyohei Yamada,
Hideki Yamaguchi, Norihisa Miseki,
Yuko Cho, Keiichi Konoki
15:30 – 912. Chemical synthesis, biosynthesis, and biomechanistic studies of the
pyrrole-2-aminoimidazole marine alkalord
family including palau’amine.
Daniel Romo*
16:00 – 913. Discovery of bioactive marine
natural products and synthesis of pharmacophore analogs.
Raymond J. Andersen*
Hilton
Iolani I/II
New Advances in Metal-Catalyzed
Alkylation and Fluoroalkylation (#115)
Organized by: D. Vicic, V. Dong,
N. Kambe
Presiding: D. Vicic
12:30 – 914. Ni-catalyzed cross coupling of
non-activated alkyl halides. Xile Hu*
13:10 – 915. Metal-catalyzed direct alkylations with unactivated alkyl halides.
Lutz Ackermann*
13:50 – 916. Iron-catalyzed cross-coupling
reaction: An effective method of alkylating various organometallic reagents.
Masaharu Nakamura*
14:30 – 917. Ni-catalyzed cross-coupling of
alkyl Grignard and alkylzinc reagents with
organic halides. Diego J. Cardenas*,
Elena Buñuel, Vilas B. Phapale,
Manuel Guisán-Ceinos
15:10 – 918. Transition metal catalyzed alkylation reactions by the use of Grignard reagents. Nobuaki Kambe*
15:50 – 919. Functionalization of sp3-hybridized carbon centers through cleavage of
unstrained carbon-carbon ␴ bonds.
Eric Fillion*, Yen Nguyen, Jérôme Jacq,
Tiantong Lou, Ashraf Wilsily
Hilton
Honolulu III
Achieving Efficiency in Organic Reactions
via Greener Processes and Practices (#139)
Organized by: I. Ryu, D. Curran,
P. Jessop, S. Lee
Presiding: D. Curran, A. Studer,
P. Jessop
12:30 – 920. Switchable solvents incorporating water. Philip G. Jessop*,
Sean M. Mercer, Lam Phan, Lisa Kozycz,
Christoph J. Dürr
13:00 – 921. Synthetic organic reaction with
photo and molecular oxygen.
Akichika Itoh
13:20 – 922. Photochemical C-C bond formation between alcohols and olefins by
an environmentally-benign radical reaction. Akihiko Ouchi*, Chuanxiang Liu,
Masayuki Kaneda, Takeshi Hyugano
13:40 – 923. Photoredox catalysis: Enabling
chemical synthesis with visible light.
Corey R. Stephenson*
14:10 – 924. Novel biphasic reaction system
of ferric chloride dissolved imidazolium
salt and benzotrifluoride: Application to
electron transfer reactions and Lewis acid
promoted reactions. Eietsu Hasegawa*,
Nohara Hiroi, Chika Osawa,
Hiroyuki Tsuchida
14:30 – 925. Synthesis and spectroscopic
study of dually substituted phenylene(poly)ethynylenes with diphenylamino/
cyano groups. Akihiro Orita*,
Jing-Kun Fang, Xin Yang,
Daisuke Matsuo, Yoshinori Suzuma,
Junzo Otera
14:50 – 926. Nitroxides and chinones as environmentally benign green oxidants.
Armido Studer*
15:20 – 927. Mild synthesis of furans from
1,3-ketoesters and cis-4-oxo-2-enals.
Satoshi Kojima*, Akihisa Iwamoto,
Yoshiaki Sashihara
15:40 – 928. Novel formation of iodobenzene
derivatives from 1-(methylthio)-1,3-alkadien-5-ynes via iodine-indued C-C bond
formation. Shoji Matsumoto*,
Kenji Takase, Masato Kimura,
Hitohiro Nishimura, Keisuke Sakamoto,
Motohiro Akazome
16:00 – 929. N-Heterocyclic carbene boranes: A new class of radical hydrogen
atom donors made from only first row elements. Dennis P. Curran
13:25 – 932. Investigating active principles
of complementary and alternative medicines (CAMs). Jurgen T. Rohr*,
Pallab Pahari, Irfan Baig,
Khaled A. Shabaan, Raj Kumar,
Bal L. Lokeshwar, Chendil Damodaran
13:45 – 933. Discovery of novel splicing factor 3b inhibitors, pladienolide and its derivatives. Yoshiharu Mizui*
14:20 – 934. Cyclopamine: the bad, the ugly
and now the good. Stephen T. Lee,
Dale R. Gardner, Kip E. Panter
14:40 – 935. Recent progress on the biosynthesis of peptide antitumor antibiotics.
Kenji Watanabe, Hiroki Oguri,
Hideaki Oikawa*
15:15 – 936. Discovery and biosynthesis of a
new family of anti-cancer macrolides by
exploitation of the Streptomyces ambofaciens genome sequence. Greg Challis*,
Lijiang Song, Lauren Ray,
Christophe Corre, Bertrand Aigle,
Luisa Laureti, Pierre Leblond
15:35 – 937. Exploring cell cycle inhibitors:
Discovering new targets for cancer treatment. William Fenical*, James J. LaClair
16:10 – 938. Selective release of potent
N-alkylisatin based cytotoxins via hydrolysis of pH sensitive imine linkers.
Lidia Matesic, Julie M. Locke,
Kara L. Vine, Ranson Marie,
John B. Bremner, Danielle Skropeta*
Hilton
Sea Pearl I/II
14:20 – 950. Enantioselective approach to
lactones: Design, mechanism, and
scope. Vy M. Dong
14:55 – 951. New approach to bis-heterocycles via coupling and double cyclization
cascade. Kouichi Ohe, Takahiko Murata,
Kazuhiro Okamoto, Koji Miki
15:10 – 952. Carbon-carbon bond formation
and pyrrole synthesis via the [3,3] sigmatropic rearrangement of O-vinyl oxime
ethers. Laura Anderson*,
Heng-Yen Wang, Daniel S. Mueller,
Rachna Sachwani, Hannah N. Londino,
Alla Papirnyak
15:25 – 953. Transition metal-catalyzed stereoselective cyclization reactions for the
synthesis of complex natural products.
Chulbom Lee*
16:00 – 954. Regio- and stereoselective
Heck arylation of allylic alcohol and amine
derivatives using arenediazonium salts.
Carlos Roque D. Correia,
Jason G. Taylor, Patricia Prediger,
Fernando P. Guandalim
16:15 – 955. Discovery and development of
scandium(III) catalysts for the diazoalkane-carbonyl homologation reaction:
Optically active 2-aryl cycloalkanones by
catalytic asymmetric carbon insertion.
Jason S. Kingsbury*, David C. Moebius,
Victor L. Rendina
Hilton
Coral V
Mechanistic Organic Photochemistry (#89)
Cooperative Catalysis (#14)
Organized by: Y. Uozumi, R. Danheiser,
K. Ding, A. Nishida
Presiding: R. Danheiser
12:50 Introductory remarks
13:00 – 939. Enantioselective catalysis
based on transition metal enolate chemistry. Mikiko Sodeoka*
13:40 – 940. Catalytic transformations of
C-H bonds, carbon-dioxide, and simple
olefins. Vy M. Dong
14:10 – 941. Cooperative catalysis of organic and organometallic catalysts for
hydroacylation and C-C double bond
cleavage of ␣,␤-unsaturated aldehyde.
Chul-Ho Jun*, Kyung-Mi Cha,
Eun-Ae Jo, Yura Lee
14:30 – 942. Nickel/Lewis acid-catalyzed
carbocyanation reaction of unsaturated
bonds. Akira Yada, Shiro Ebata,
Tomoya Yukawa, Hiroaki Idei, Di Zhang,
Yoshiaki Nakao*, Tamejiro Hiyama*,
Masashi Ikawa, Sensuke Ogoshi*
14:50 – 943. Direct polymerization of 2-bromothiophenes based on direct arylation
reaction. Ryo Takita, Qifeng Wang,
Yuuta Kikuzaki, Yuki Nakamura,
Masayuki Wakioka, Fumiyuki Ozawa*
15:10 – 944. Cooperative catalysis in enantioselective cyanation of aldehydes.
Zhipeng Zhang*, Kuiling Ding*
15:30 – 945. Catalysis in total synthesis.
Kyriacos C. Nicolaou*
16:20 Concluding remarks
Hilton
South Pacific III
Hilton
Honolulu II
Recent Advances in Natural Products as
Anticancer Agents (#279)
Transition Metal Catalysis: Mechanism and
Practice (#283)
Organized by: D. Kingston, J. Li,
S. Matsunaga, R. Quinn
Presiding: J. Liu
Organized by: K. Nozaki, J. Stryker,
F.D. Toste
Presiding: K. Nozaki
12:30 – 930. Using yeast tubulin to map the
binding site of the microtubule-stabilizing
agent, peloruside A.
Paul Teesdale-Spittle, Reem Hanna,
A. Jonathan Singh, Pahk Thepchatri,
James Snyder, Paraskevi Giannakakou,
David Bellows, Peter Northcote,
John Miller
12:50 – 931. Mode of action of an anticancer
agent that inhibits pre-mRNA splicing.
Minoru Yoshida*
12:50 – 946. Synthesis of functional polymers using metathesis initiators.
Robert H. Grubbs
13:25 – 947. Iron- and cobalt-catalyzed
cross-coupling reactions through C-H
bond activation. Naohiko Yoshikai
13:50 – 948. Palladium pincer-complex catalysis for selective synthesis.
Kalman J. Szabo
14:05 – 949. Carbonylative coupling of
amidrazones or amidines for direct or
modular synthesis of 5-aryl-1,2,4-triazoles from aryl halides. Steve Staben*,
Nicole Blaquiere
Organized by:
H. Zimmerman and A. Griesbeck,
T. Ichimura, A. Kutateladze, P. Wan
Presiding: T. Ichimura
13:00 – 956. Creating new C-C and C-H
bonds via alkyne photochemistry.
Igor Alabugin*
13:35 – 957. Proton and water-mediated
photochemical reactions at distal sites of
aromatic compounds. Peter Wan*
14:10 – 958. Photoassisted detection and
amplification of molecular recognition
events: Mechanistic and applied studies.
Andrei G. Kutateladze*,
Tiffany Gustafson
14:45 – 959. Photo-responsive morphological change of niobate/azobenzene-polyfluorinated surfactant hybrid compounds.
Haruo Inoue*
15:20 – 960. Photochemical confluence of
Type II, Wolff, and Favorskii rearrangements for a single chromophore: The
mechanistic and synthetic consequences
for p-hydroxyphenacyl.
Richard S. Givens*, Marina Rubina,
Kenneth Stensrud, Elizabeth D. Cope,
Chamani Perera, Sanjeewa Senadheera,
Peter Sebej, Lovely A. Anthony,
Petr Klan*, John P. Toscano*,
Evans S. Anthony
15:55 – 961. Photochromism by intermolecular proton transfer. Keiichiro Ogawa*,
Jun Harada, Masatoshi Miura
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–129
04-ORGN
Hilton
Honolulu I
Practical Applications of Basic Research on
Molecular Recognition (#222)
Organized by: W. Hinze, C. Easton,
K. Kano
Presiding: K. Kano, W. Hinze
13:00 Introductory remarks
13:10 – 962. Recognition and catalysis in
deep cavitands. Julius Rebek*
13:40 – 963. Synthesis and host-guest properties of multivalent cyclophane hosts.
Osamu Hayashida, Daisuke Sato,
Noriko Yahiro, Keiichiro Kimura
14:00 – 964. Unique properties of heme-protein models composed of iron porphyrins
and cyclodextrin dimers. Koji Kano*
14:30 – 965. Binding of cyanide anion to
iron-porphyrin supramolecules.
Kenji Watanabe, Hiroaki Kitagishi,
Koji Kano
14:50 – 966. An iron(II)porphyrin-cyclodextrin supramolecular complex that removes CO in a living organism.
Hiroaki Kitagishi, Koji Kano
15:10 – 967. Molecular fibres and wires in
solid-state and solution self-assemblies
of cyclodextrin [2]-rotaxanes.
Christopher J. Easton, Hwi-Young Lee,
Subashani Maniam, Hideki Onagi
15:40 – 968. Artificial polymerases and molecular chaperones. Akira Harada*
16:10 – 969. Molecular machines at work.
Hideki Onagi*, Christopher J. Easton,
Stephen F. Lincoln, Roger J. Coulston,
Allan B. Gamble
Friday Evening
Hilton
South Pacific IV
Reactive Intermediates and Unusual
Molecules - A Celebration of Bob Moss’s 70
years (#1)
Organized by: M. Platz, M. Abe, W. Leigh
Presiding: M. Abe
19:00 – 970. Triplet sensitized cis-trans
isomerization of simple alkenes and their
applications. Anna D. Gudmundsdottir*
19:30 – 971. Generation and characterization of triplet thienylcarbenes.
Robert J. McMahon*, Caroline R. Pharr
20:00 – 972. Photonic amplification by a singlet-state quantum chain reaction in the
photodecarbonylation of crystalline diarylcyclopropenones.
Gregory Kuzmanich,
Stephanie C. Doan, Matthew N. Gard,
Benjamin J. Schwartz,
Miguel A. Garcia-Garibay
20:30 – 973. Kinetic and thermodynamic parameters for the reactions of simple silylenes and germylenes with alkenes and
dienes in solution. William J. Leigh*,
Lawrence A. Huck, Saurabh S. Chitnis,
Margaret Reid
21:00 – 974. Fun with germanium: from digermenes to donor-stabilized germylenes
and germanium cations. Kim M. Baines*
21:30 – 975. Role of sulfenic acids in the antioxidant activity of allicin and other plantderived thiosulfinates. Derek A. Pratt*
Convention Center
Kamehameha Halls II and III
Cooperative Catalysis (#14)
Organized by: Y. Uozumi, R. Danheiser,
K. Ding, A. Nishida
Presiding: Y. Yamada, T. Osako
Poster Session
19:00 – 21:00
976. Enantioselective ring opening of epoxides by fluoride anion promoted by a cooperative dual-catalyst system.
Julia A. Kalow*, Abigail G. Doyle
977. Facile preparation of linear polystyrenestabilized Pd nanoparticles in water.
Atsushi Ohtaka*, Takuto Teratani,
Ryohei Fujii, Kanako Ikeshita,
Osamu Shimomura, Ryoki Nomura
130 –TECH
TECHNICAL PROGRAM
978. Recovery of in situ-generated Pd nanoparticles with linear polystyrene.
Atsushi Ohtaka*, Ryozo Kuroki,
Takuto Teratani, Osamu Shimomura,
Ryoki Nomura
979. Ionically convoluted polymeric phosphotungstate-catalyzed chemoselective
oxidation of secondary alcohols with
30% aq H2O2. Chung Keun Jin*,
Yoichi M. Yamada, Yasuhiro Uozumi
980. Development of aquacatalytic systems
based on pincer palladium complexes:
Catalytic ability in water. Go Hamasaka,
Tsubasa Muto, Yasuhiro Uozumi*
981. Studies of ligand effects on the tetranuclear zinc cluster catalyses for mechanistic investigation. Yukiko Hayashi*,
Yusuke Maegawa, Kazushi Agura,
Takanori Iwasaki, Takashi Ohshima,
Kazushi Mashima
982. Catalytic membrane-installed microchannel devices for instaneous organic
transformations. Toshihiro Watanabe,
Yoichi M. Yamada, Naoshi Fukuyama,
Tomohiko Beppu, Kaoru Torii,
Yasuhiro Uozumi*
983. Ionically convoluted poly(spiroborate)
iridium catalyst for the dehydrative alkylation of anilines with alcohols in water.
Yoichi M. Yamada, Hidetoshi Ohta,
Yasuhiro Uozumi*
984. Construction of contiguous tetrasubstituted chiral carbon stereocenters via direct catalytic asymmetric aldol reaction of
␣-isothiocyanato esters with ketones.
Hiroyuki Morimoto, Tatsuhiko Yoshino,
Gang Lu, Shigeki Matsunaga*,
Masakatsu Shibasaki*
985. Formation and reactivity of six-membered oxa-nickelacycles generated by
oxidative addition of cyclopropyl ketones
to nickel(0). Takashi Tamaki*,
Masato Ohashi, Sensuke Ogoshi
986. Platinum-catalyzed direct amination of
allylic alcohols assisted by microwave
and ligand effects. Yasuhito Nakahara*,
Yoshiki Miyamoto, Junji Ipposhi,
Masaru Utsunomiya, Takashi Ohshima,
Kazushi Mashima
987. Aerobic alcohol oxidation and SuzukiMiyaura coupling in water with self-supported bipyridyl-palladium catalysts.
Takao Osako, Yasuhiro Uozumi*
988. Enantioselective aza-Morita-Baylis-Hillman (aza-MBH) domino reactions promoted by acid-base organocatalyst.
Naohito Inoue, Shinobu Takizawa,
Shuichi Hirata, Tue Nguyen,
Hiroaki Sasai*
989. Bifunctional organocatalyst bearing (S)1,1’-spirobiindane as chiral backbone.
Kimiko Kiriyama, Shinobu Takizawa,
Hiroaki Sasai*
990. Nickel-catalyzed cross-coupling of aryl
fluorides and organozinc reagents via cooperative C-F bond activation.
Yuki Nakamura, Naohiko Yoshikai,
Laurean Ilies, Eiichi Nakamura
991. Polymeric membranous acid catalystinstalled microchannel devices for organic synthesis. Maki Minakawa,
Yoichi M. Yamada, Yasuhiro Uozumi
992. Development of aquacatalytic systems
based on pincer palladium complexes:
Preparation of an amphiphilic NCN pincer
palladium complex. Tsubasa Muto,
Go Hamasaka, Yasuhiro Uozumi*
993. Development of bifunctional organocatalysts for enantioselective Morita-Baylis-Hillman reaction. Shinya Murakami,
Shinobu Takizawa, Hiroaki Sasai*
994. Catalytic asymmetric aldol reactions
and mechanistic studies using chiral zinc
complexes. Toshinari Itakura,
Susumu Itoh, Masamichi Ikegami,
Sei-ichi Tsukamoto, Masanori Kitamura,
Shin Aoki*
995. Photocatalytic aerobic expoxidation of
cyclohexene under visible light irradiation
by various metalloporphyrin complexes
with Mg-Al hydrotalcite anionic clay.
Terumichi Izawa*, Kentaro Teramura*,
Tetsuya Shishido, Tsunehiro Tanaka
996. Hydrogen bonding directed asymmetric
esterification catalyst for pyroglutamic
acid. Shota Ohtsuka, Nobuhiro Kihara*
997. Development of length selective acylation catalyst using hydrogen bonding of
amide. Noriaki Tsuzuki,
Nobuhiro Kihara*
Hilton
Coral IV
Novel Synthetic Methodology and Its
Application to Natural Product Synthesis
(#63)
Organized by: F. West, V. Rawal,
M. Toyota
Presiding: D. Hall
19:00 – 998. Revisiting reactions of thionyl
chloride: Stereoretentive methods for the
one-pot synthesis of halides and amides
from alcohols. Deboprosad Mondal,
Song Ye Li, Salvatore D. Lepore*
19:20 – 999. Use of free radical based reactions in the synthesis of natural products.
Yvan Guindon*, Philippe Mochirian,
Jean François Brazeau, François Godin,
Ioannis Katsoulis
19:50 – 1000. Onium ylides as scaffolds for
the construction of heterocyclic and carbocyclic natural products.
Frederick G. West*
Hilton
Coral V
Mechanistic Organic Photochemistry (#89)
Organized by: H. Zimmerman,
A. Griesbeck, T. Ichimura,
A. Kutateladze, P. Wan
Presiding: H. Zimmerman
19:00 – 1001. Photosensitized reactions of
highly substituted 1,3-Cyclohexadienes:
Photoisomerization of 9,10-deoxytridachione to photodeoxytridachione.
Paul B. Jones*, Anna Fedders,
James Blair, Matt Secrest, Jessica Querin
19:20 – 1002. Photochemical generation of
activated enediynes: Unusual reactivity
and unexpected mechanisms.
Andrei Poloukhtine,
Dinesh Pandithavidana,
Alexander Kuzmin, Vladimir Popik*
19:40 – 1003. Mechanisms of singlet oxygen
reactions: From synthesis to photolithography and molecular motors.
Torsten Linker*, Werner Fudickar
20:00 – 1004. Photochemistry of adamantyl
derivatives of hydroxybiphenyls: ESIPT
vs. photosolvolysis. Nikola Basaric*,
Nikola Cindro, Damir Bobinac,
Ivana Zabcic, Mlinaric-Majerski Kata,
Yunyan Hou, Wan Peter*
20:20 – 1005. New Norrish II precursors as
excellent photocages for fragrance release. Olga Khintse*, Axel G. Griesbeck
20:40 – 1006. Excited state hydrogen transfer in ortho-nitro benzaldehyde: A correlation diagram translated to a conical intersection cascade. Annapaola Migani,
Verónica Leyva, Ferran Feixas,
Inés Corral, Leticia González,
Lluís Blancafort*
Convention Center
Kamehameha Halls II and III
Practical Applications of Basic Research on
Molecular Recognition (#222)
1009. Optical resolution of 2-amino-3-methylpentanoic acid. Makiko Kimura*,
Tatsuo Yajima, Tadashi Shiraiwa
1010. Synthesis of novel quaterphenyl derivatives for chiral amplification of primary
amines. Shunsuke Kuwahara*,
Akira Yamaguchi, Yoichi Habata
1011. Syntheses of optical active ␣-alkylserines. Hidetoshi Ogata*,
Tatsuo Yajima, Tadashi Shiraiwa
1012. Optical resolution of N-phenyl-DL-␣phenylglycine. Miki Kitano*,
Tatsuo Yajima, Tadashi Shiraiwa
1013. Optical resolution of (2RS,3SR)-␤phenylserine. Katsuya Nishimura*,
Tatsuo Yajima, Tadashi Shiraiwa
1014. Chiral discrimination ability of C 2
-symmetric chiral 18-crown-6 derivatives.
Misako Nakamura, Takashi Hashimoto,
Yoshiaki Kojitani, Masahiro Muraoka,
Yohji Nakatsuji*
1015. Chiral interactions in metal complexes
for optical resolutions of amino acids.
Tatsuo Yajima*, Makiko Kimura,
Ayaka Uno, Noriya Ishida, Shoko Ito,
Tadashi Shiraiwa
1016. New ratiometric perborate-selective
probes based upon coumarin-fluorescein
conjugate. Myung Gil Choi,
Ji Young Hwang, Su Young Eor,
Suk-Kyu Chang*
1017. Development to molecularly imprinted
polymers crosslinked by the non-covalent bonding between functional groups.
Masaki Katoh, Nobuhiro Kihara*
1018. Phenylurea oligomers capable of folding to helical structures by anion binding.
Gang Woo Lee*, Kyu-Sung Jeong
1019. Simple introduction of deuterium at
␣-position of carbonyl in diazirinyl compounds for photoaffinity labeling.
Yuta Murai, Yasuyuki Hashidoko,
Yasumaru Hatanaka, Makoto Hashimoto
1020. Fluorescence of hydroxynaphthoic acids in aqueous micellar solutions and in
the presence of gold(III) and beryllium(II).
Haidi Fiedler*, Marcelo Silva,
Lizandra M. Zimmermann,
Jorge A. Pedro, René A. Nome,
Faruk Nome
1021. Organic gas sensing property of selforganized honeycomb-patterned films
fabricated by calixarene derivatives.
Eisaku Nomura*, Koichi Hayashi,
Keisuke Sakaguchi, Yuhi Miyakawa,
Hiroyoshi Naito
1022. Preparation for N-benzyl derivatives of
threonines. Serina Ichimura*,
Tatsuo Yajima, Tadashi Shiraiwa
1023. Approach toward polycatenane.
Masatoshi Kawai, Haruki Mori,
Nobuhiro Kihara*
1024. Synthesis of macrocyclic sulfoximine
that can recoguize cyclic amides Kouta Iijima and Nobuhiro Kihara. Kouta Iijima,
Nobuhiro Kihara*
1025. Thermodynamically controlled deracemization of ketones utilizing host-guest
inclusion complexation. Hiroto Kaku*,
Takeshi Nishii, Mitsuyo Horikawa,
Tetsuto Tsunoda
1026. Inclusion behaviors and molecular recognition of 3,7,12,24-tetrahydroxycholane. Liu Wen-Tzu*, Hisaki Ichiro,
Tohnai Norimitsu, Miyata Mikiji
1027. Hierarchical structures and molecular
recognition in inclusion crystals of 23-sulfonocholic acid. Hirohide Yabuguchi,
Yusuke Yamahata, Ichiro Hisaki,
Norimitsu Tohnai, Mikiji Miyata
Organized by: W. Hinze, C. Easton,
K. Kano
Presiding: K. Kano, C. Easton, W. Hinze
Poster Session
19:00 – 21:00
1007. Supported liquid membrane transport
of alkali metal cations by monoazacryptand with a partially fluorinated sidearm and the corresponding monoazacrown ethers. Yohji Nakatsuji,
Misako Nakamura, Shingo Fujimoto,
Masahiro Muraoka
1008. Expanding the scope of the CFTA
method: determination of absolute stereochemistry of ␣-methyl-␣-amino esters.
Tomoya Fujiwara*, Yoshio Takeuchi,
Kenji Omata, Kuninobu Kabuto
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
1028. Syntheses and guest-binding behaviors of peptide-based cyclophane oligomers. Tomomi Nakashima,
Yu-ki Nakamura, Osamu Hayashida,
Kazuaki Ichimura
1029. Binding of p-nitrophenolate ion to
mono-(deoxy-guanidino)-␣-cyclodextrins. Keita Takezawa,
Tatsuyuki Yamamoto, Yoshihisa Matsui,
Keisuke Yoshikiyo*
1030. Can cyclodextrin-porphyrin supramolecular system regulate the DNA-binding
ability of GAL4 zinc finger protein?
Shigeru Negi*, Takuya Ogasawara,
Nobuyuki Kawamura, Koji Kano,
Yukio Sugiura
1031. Synthesis of guest-specific host molecules by dynamic combinatorial chemistry. Masahito Tsutsui, Asao Nakamura*
1032. Chemical constituents of YUZU and
LIME essential oils andtTheir antioxidative activities. Shinya Tachibana,
Shinichi Tanimoto, Satomi Hukai,
Koichiro Tajima, Yoshihiro Murai,
Masato Nomura
1033. Gold nanoparticles bearing oxygen
carrying supramolecule and PEG.
Keiichi Karasugi, Hiroaki Kitagishi,
Koji Kano*
1034. Study on the TiO2 particle/epoxy resin
composites. Changkwon Moon*,
Aaron M. Forster
Hilton
South Pacific III
Recent Advances in Natural Products as
Anticancer Agents (#279)
Organized by: D. Kingston, J. Li,
S. Matsunaga, R. Quinn
Presiding: R. Quinn
19:00 – 1035. Investigation of marine organisms for potential cancer therapeutics.
Amy Wright
19:30 – 1036. Yaku’amides A and B, cytotoxic linear peptides from a marine
sponge Ceratopsion sp. Reiko Ueoka,
Yuji Ise, Shigeru Okada,
Shigeki Matsunaga*
20:00 – 1037. Investigating the anticancer
potential of ascidian natural products using high content screening.
Rohan A. Davis*
20:30 – 1038. Detection, structural determination and bioactivity of metabolites from
bryozoans and cyanobacteria.
Michele Prinsep*, Jonathan Puddick,
Aaron Andersen, Christopher Moody,
Libero Caracausi
Saturday Morning
Hilton
Sea Pearl V/VI
Reactive Intermediates and Unusual
Molecules - A Celebration of Bob Moss’s 70
years (#1)
Organized by: M. Platz, M. Abe, W. Leigh
Presiding: M. Platz
7:30 – 1039. Can surface plasmon fields provide a new way to photosensitize organic
photoreactions? Juan C. Scaiano*
8:00 – 1040. Multiplicity control in aryl(trifluoromethyl)carbenes.
Robert S. Sheridan*,
Myoung-Geun Song, Sean Ross,
Rachel Lecker
8:30 – 1041. o-Naphtoquinone methides:
From the mechanism of formation and reactivity to the design of photocages and
photoclick chemistry tools.
Selvanathan Arumugam, Vladimir Popik*
9:00 – 1042. Persistent triplet diphenylcarbenes: Steric protection by ortho- or
para-substituents. Katsuyuki Hirai*,
Toshikazu Kitagawa, Hideo Tomioka
9:30 – 1043. Attempted synthesis of triplet
carbenes. Yohsuke Yamamoto*,
Shin-ichi Fuku-en
10:00 – 1044. Relative reactivity of nucleophiles toward a para-benzyne derived
from an enediyne. Charles L. Perrin*,
Gabriel J. Reyes-Rodriguez,
Phaneendrasai Karri
Hilton
Iolani I/II
Hilton
South Pacific III
New Advances in Metal-Catalyzed
Alkylation and Fluoroalkylation (#115)
Recent Advances in Natural Products as
Anticancer Agents (#279)
Organized by: D. Vicic, V. Dong,
N. Kambe
Presiding: N. Kambe
Organized by: D. Kingston, J. Li,
S. Matsunaga, R. Quinn
Presiding: S. Matsunaga
7:30 – 1048. Organocatalytic oxidations by
aminoxyl radicals. Kana Yamamoto*
7:50 – 1049. Development of an asymmetric
organocatalytic Wittig reaction.
James J. Kiddle*, Samir Pirani
8:10 – 1050. New developments in catalytic
asymmetric phosphoric acid-catalyzed
processes and applications.
Jon C. Antilla
8:30 – 1051. Phosphine-catalyzed annulations. Ohyun Kwon
9:00 – 1052. Diarylprolinol silyl ether as an
effective organocatalyst. Yujiro Hayashi*
9:30 – 1053. Asymmetric Morita-Baylis-Hillman reaction and its surroundings.
Min Shi*
10:00 – 1054. Enantioselective nucleophilic
catalysis. Greg Fu
10:30 – 1055. Chiral phosphoric acids as
versatile catalysts for enantioselective
carbon-carbon bond forming reactions.
Masahiro Terada*
11:00 – 1056. Urea and thiourea derivatives
in asymmetric catalysis.
Eric N. Jacobsen
7:30 – 1066. Nickel-catalyzed cross-coupling of alkyl halides with phenylethynyland trimethylsilylethynyllithium reagents.
Hongjian Sun, Xiaoyan Li
8:00 – 1067. Development of Et2Zn and/or
zinc mediated Reformatsky-type reaction
of ethyl dibromofluoroacetate: Facile access to three types of fluorinated compounds with chemo- and diastereoselectivity. Atsushi Tarui, Naoto Kawashima,
Tetsuya Kawakita, Koji Matsumoto,
Akari Momoda, Takuro Yoshimatsu,
Kazuyuki Sato, Masaaki Omote,
Akira Ando*
8:30 – 1068. Transition-metal catalyzed reactions of carbonyl compounds and trifluoromethylated compounds: A sp3C-H
bond activation induced by ␣ heteroatom
effect. Shun-Ichi Murahashi*
9:10 – 1069. Catalytic allylation of alkyl halides with allylic metals creating quaternary carbons. Hideki Yorimitsu*,
Koichiro Oshima
9:50 – 1070. Electroreductive metal complexes assisted fluoroalkylation.
Yulia H. Budnikova*,
Dmitry Y. Mikhaylov,
Tatyana V. Gryaznova,
Mikhayl N. Khrizanphorov,
Oleg G. Sinyashin
10:20 – 1071. Insight into nickel-catalyzed
carbon-carbon coupling reactions by
spectroelectrochemistry. Axel Klein*
Hilton
South Pacific IV
Hilton
Honolulu III
Marine Natural Products: Isolation, Biology,
Ecology, and Synthesis (#80)
Achieving Efficiency in Organic Reactions
via Greener Processes and Practices (#139)
Organized by: J. Rainier, R. Anderson,
M. Murata
Presiding: R. Andersen
Organized by: I. Ryu, D. Curran,
P. Jessop, S. Lee
Presiding: S. Lee, D. Chi, A. Orita
7:30 – 1082. Marine natural products with
unique structures and activity against tumor cells. Mark T. Hamann*
8:00 – 1083. Antibody-drug conjugates- new
opportunities for natural products in oncology. Frank E. Koehn*, Haiyin He,
Jeff Janso, Hui Yang, Xidong Feng
8:35 – 1084. Exploration of schweinfurthins
as potential anti-cancer agents.
David F. Wiemer*
8:55 – 1085. Synthesis of macrocyclic diaryl
ether heptanoid natural products and
their evaluation as NF-kB inhibitors.
Vashti C. Bryant, Kishore G. Kumar,
Abijah M. Nyong, Smitha Kizhake,
Amarnath Natarajan*
9:15 – 1086. Synthesis of azaspirene analogs and their anti-angiogenetic activities.
Nobuhiro Kanomata*, Shun Hirasawa,
Shinnosuke Sakai,
Shinnosuke Wakamori,
Batsuren Choijamts, Yasuko Naganuma,
Makoto Emoto
9:35 – 1087. Design and synthesis of simplified paclitaxel analogs based on the
T-taxol bioactive conformation.
Jielu Zhao, Susan Bane,
James P. Snyder, Haipeng Hu,
Kamalika Mukherjee, David G. Kingston*
9:55 – 1088. Total synthesis of the spirastrellolides - antimitotic spiroacetal macrolides isolated from the marine sponge
Spirastrella coccinea. Ian Paterson*
10:15 – 1089. Total synthesis of syringolin A
and B. Tannya R. Ibarra-Rivera,
Goutam Biswas, Michael Pirrung*
10:35 – 1090. Scaffolds defining anti-cancer
activity. Ronald J. Quinn
11:10 – 1091. Synthesis and biological studies of resorcylic acid lactones as protein
kinase inhibitors for the development of
cancer chemotherapeutics. Anqi Chen*,
Wendy Goh, Jin Xu, Winnie Chiang,
Christina L. Chai
7:30 – 1057. On the origin of decapropionates from Siphonaria zelandica - total
synthesis and isomerization of the putative common precursor. Dale E. Ward,
Garrison E. Beye
7:50 – 1058. Neuropharmacologically active
natural products from marine cyanobacteria: Isolation, structure elucidation, and
investigations of biological activity.
Joshawna K. Nunnery*, Tara Byrum,
Zhengyu Cao, Thomas F. Murray,
William H. Gerwick
8:10 – 1059. Enantioselective synthesis and
determination of the absolute configurations of marine oxylipin topsentolide A1.
Ken Ishigami*, Munetaka Kobayashi,
Hidenori Watanabe
8:30 – 1060. Antiprotozoan agents from marine invertebrates. Yoichi Nakao*,
Shin-Taro Ishigami, Yasuyuki Goto,
Shin-Ichiro Kawazu,
Yoshitsugu Matsumoto
9:00 – 1061. Tedanolide and the evolution of
polyketide inhibitors of eukaryotic protein
synthesis. Richard E. Taylor
9:30 – 1062. Development of libraries based
on a scaffold derived from a marine cyclic
peroxide. Ronald J. Quinn
10:00 – 1063. Discovery of new marine metabolites through genome mining.
Bradley Moore*, Paul Jensen
10:30 – 1064. Natural products: Opportunities for discovery. Jef De Brabander*
11:00 – 1065. Marine natural product antitumor agents. Chris M. Ireland*
7:30 – 1072. Atom economic, catalytic
amine synthesis using early transition
metals of low toxicity. Laurel Schafer
8:00 – 1073. Platinum on carbon-catalyzed,
facile hydrogenation of aliphatic and aromatic ketones under mild conditions.
Yasunari Monguchi, Yuta Fujiwara,
Youhei Iwasaki, Tomohiro Maegawa,
HIronao Sajiki*
8:20 – 1074. Incorporation of fluoroustagged saccharides in animal cell and
production of glycolipids.
Maria Carmelita Z. Kasuya,
Shinya Nakano, Ruriko Katayama,
Mami Tojino, Mamoru Mizuno,
Kenichi Hatanaka
8:40 – 1075. Improving the efficiency of
complex molecule synthesis through carbon-hydrogen bond functionalization reactions. Paul Floreancig*
9:10 – 1076. Coupling reaction of primary alcohols with 2-alkynes catalyzed by iridium complex. Yasushi Obora*,
Shintaro Hatanaka, Yasutaka Ishii*
9:30 – 1077. Organocatalytic C-acylation of
N-alkyl-pyrroles. James E. Taylor*,
Steven D. Bull, Jonathan M. Williams
9:50 – 1078. Withdrawn
10:20 – 1079. (S)-Ibuprofen, the asymmetric
orphan drug. David Chavez*,
James Salvador
10:40 – 1080. Efficient syntheses of 9-membered masked enediyne and taxol aided
by an automated synthesizer.
Takashi Takahashi*, Yoshikazu Tanaka*,
Shinichiro Fuse*
11:00 – 1081. Thermal [2 ⫹ 2] cycloaddition
reactions of allene-ynes: Exploring the
scope, mechanism, and application to
natural product synthesis.
Kay M. Brummond*, Joshua M. Osbourn
10:30 – 1045. Reactivity of organic species
in the gas phase. Jeehiun K. Lee*,
Anna Zhachkina, Min Liu
11:00 – 1046. Dynamic control of carbene
reactions to strained C-C bonds.
Dina Merrer*
11:30 – 1047. Solvation and complexation of
carbenes. Robert A. Moss
Hilton
South Pacific II
Asymmetric Organocatalysis (#62)
Organized by: K. Maruoka, L. Deng,
L. Gong
Presiding: K. Maruoka, L. Gong, L. Deng
Hilton
Sea Pearl I/II
Cooperative Catalysis (#14)
Organized by: Y. Uozumi, R. Danheiser,
K. Ding, A. Nishida
Presiding: A. Nishida
7:50 Introductory remarks
8:00 – 1092. Heterogeneous catalytic asymmetric synthesis in water with polymeric
palladium complexes. Yasuhiro Uozumi*
8:20 – 1093. Oxidative desymmetrization of
diols by iridium catalyst.
Takeyuki Suzuki*, Kazem Ghozati,
Takatani Shuhei, Tadashi Katoh,
Hiroaki Sasai
8:40 – 1094. Catalytic dehydrative S-allylation of thiols and thioic S-acids.
Shinji Tanaka, Prasun K. Pradhan,
Yusuke Maegawa, Masato Kitamura*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–131
04-ORGN
9:00 – 1095. Reactions of arylaldehydes by a
sulfoxylalkyl-substituted N-heterocyclic
carbene catalyst. Masahiro Yoshida*,
Nagisa Terai, Yuki Katagiri, Wen-Bin Zhu,
Kozo Shishido
9:20 – 1096. Development of new direct catalytic reactions using tetranuclear zinc
clusters. Takashi Ohshima
9:50 – 1097. Asymmetric Friedel-Crafts alkylation reactions by chiral Brønsted acids.
Shuli You*
10:20 – 1098. Lewis base activation of Lewis
acids: On beyond silicon.
Scott E. Denmark*
11:00 – 1099. Withdrawn
Hilton
Coral V
Mechanistic Organic Photochemistry (#89)
Organized by:
H. Zimmerman and A. Griesbeck,
T. Ichimura, A. Kutateladze, P. Wan
Presiding: H. Zimmerman
8:00 – 1100. Controlling photochemistry with
weak noncovalent forces and confined
spaces. Vaidhyanathan Ramamurthy,
Nithyanandhan Jayaraj,
Revathy Kulasekaran, Rajib Choudhury,
Shampa Samanta, Shipra Gupta,
Mintu Porel
8:35 – 1101. Design of new photoremovable
protecting groups. Petr Klan*,
Dominik Heger, Laxminarayana Kammari,
Tomas Solomek, Ngoy B. Pitchou
9:10 – 1102. Photochemistry and spectroscopy of carbon-chain compounds.
Robert J. McMahon*
9:45 – 1103. Photochemical reactions to
probe reactivity on monolayer protected
metal nanoparticles and to build new architectures. Mark S. Workentin*
10:20 – 1104. Regioselective intramolecular
photocycloaddition of 1-cyanonaphthalenes bearing alkenyl and alkynyl groups.
Kazuhiko Mizuno*
10:55 – 1105. Photochemical methods for
the study of silicon, germanium, and tin
analogs of alkenes and carbenes.
William J. Leigh*
Hilton
Honolulu I
Practical Applications of Basic Research on
Molecular Recognition (#222)
Organized by: W. Hinze, C. Easton,
K. Kano
Presiding: C. Easton, F. Nome
8:00 – 1106. New tools for bioimaging: A
step toward in situ chemistry of complicated admixture systems.
Yasuhiro Aoyama*
8:30 – 1107. Protein affinity capture at
genomic DNA-modified surfaces: A new
route to aptamer discovery.
Linda B. McGown*, Tian Zhang,
Brian Lin
9:00 – 1108. Surface forces measurements
to evaluate biological molecular recognition. Kazue Kurihara*
9:30 – 1109. Induced circular dichroism for
determination of heparin adulteration.
Apryll M. Stalcup*, Floyd E. Stanley,
Andrew M. Warner, Lisa A. Meyers
9:50 – 1110. Design of artificial zinc finger
nuclease based on unnatural His4-type
zinc finger catalytic domain.
Shigeru Negi*, Yukio Sugiura
10:10 – 1111. Gas chromatographic separation of isotopic molecules using a cavitand-impregnated ionic liquid stationary
phase. Chieu D. Tran*, Irena Mejac,
Julius Rebek, Richard J. Hooley
10:40 – 1112. Magnetic chiral chiral ionic liquids from amino acids. Isiah M. Warner*,
Min Li, Sergio de Rooy, David Bwambok,
Bilal El-Zahab, John F. DiTusa
11:10 – 1113. Multi-stimuli responsive organic materials based on fluorene derivative. Masayuki Takeuchi*,
Chakkooth Vijayakumar
132–TECH
TECHNICAL PROGRAM
Hilton
Honolulu II
Transition Metal Catalysis: Mechanism and
Practice (#283)
Organized by: K. Nozaki, J. Stryker,
F.D. Toste
Presiding: K. Nozaki
8:10 – 1114. Design of metal catalyst for
asymmetric synthesis.
Hisashi Yamamoto*
8:45 – 1115. Carbon dioxide as a carbon resource for organic synthesis.
Kyoko Nozaki
9:00 – 1116. Nickel-catalyzed cross coupling
reactions with epoxides and azaaromatics. Abigail G. Doyle*
9:15 – 1117. Highly regio- and enantioselective hydroformylation using formaldehyde. Tsumoru Morimoto*,
Gouki Makado, Kiyomi Kakiuchi
9:30 – 1118. Metal catalyzed one step synthesis: Developing direct approaches to
molecule assembly from basic building
blocks. Bruce Arndtsen*
10:05 – 1119. Efficient immobilization of organic functional group onto silica surface
with vinylsilane by transition metal/HCl
homogeneous catalysts. Chul-Ho Jun*,
Jung-Woo Park, Ji-Hwan Choi
10:20 – 1120. Synthesis of biologically relevant carbazoles and carbolines via rhodium and ruthenium catalyzed [2⫹2⫹2]
cycloaddition reactions with functionalized ynamides. Bernhard Witulski*,
Romain Oudot
10:35 – 1121. Transition-metal catalyzed addition of acid chlorides or formamides to
alkynes. Yasushi Tsuji*
Convention Center
Kamehameha Halls II and III
Diversity Oriented Synthesis (#32)
Organized by: M. Pirrung, W. Dai,
S.B. Park
Presiding: M. Pirrung, W. Dai, S. Park
Poster Session
10:00 – 12:00
1122. Rapid assembly of resorcylic acid lactone frameworks via sequential palladium-catalyzed coupling reactions.
Shinichiro Fuse, Sakae Sugiyama,
Takashi Takahashi
1123. Synthesis and identification of artificial
glutamate analogs as a novel AMPA receptor-selective antagonist.
Masato Oikawa*, Minoru Ikoma,
Martin B. Gill, Shanti Frausto,
Geoffrey T. Swanson, Ryuichi Sakai
1124. Chromone and flavonoid library with
diverse heterocyclic units and their bioactivity on neural stem cells.
Midori A. Arai*, Natsuki Yanase,
Kazune Koryudzu, Youichi Maekawa,
Masami Ishibashi*
1125. N-Biaryl quinolone carboxylic acids as
selective M1 positive allosteric modulators: A parallel synthesis approach.
William D. Shipe*
1126. Chemistry at the Southwest Comprehensive Center for Drug Discovery and
Development: A variety of novel probelike scaffolds produced in 2 or 3 steps using multi-component reaction methodologies. Christopher Hulme*, Zhigang Xu,
Nathalie Meurice
1127. Novel multicomponent cascade reaction. Amitabh Jha*
1128. Concise synthesis and structural diversification of artemisinin analogs.
Takahisa Hiruma, Yutaka Yamagishi,
Hiroki Oguri*, Hideaki Oikawa
1129. DOS approaches to novel sultams.
Paul R. Hanson*
1130. Combinatorial synthesis of ␣-iminocarboxamide library. Hisashi Masui,
Shinichiro Fuse, Takashi Takahashi
1131. Stereo-divergent access to bispyrrolidinoindoline skeletons.
Mitsuhiro Wada, Takahisa Murata,
Hiroki Oguri*, Hideaki Oikawa
1132. Divergent and biomimetic synthesis of
the aspidosperama/iboga-type alkaloids
and their analogs. Haruki Mizoguchi,
Hiroki Oguri*, Hideaki Oikawa
Convention Center
Kamehameha Halls II and III
Novel Synthetic Methodology and Its
Application to Natural Product Synthesis
(#63)
Organized by: F. West, V. Rawal,
M. Toyota
Presiding: F. West
Poster Session
10:00 – 12:00
1133. Synthetic efficiency: Using atom-economical and chemoselective approaches
towards total syntheses of agelas alkaloids, terpestacin and bryostatins.
Guangbin Dong*, Barry M. Trost*
1134. Towards enantioselective synthetis of
allocolchicinoïds. Sebastien Cardinal*,
Pierre-Luc Boudreault, Normand Voyer
1135. 2-Phenylpyridine: An extractable electron carrier that can be utilized at room
temperature in the active copper syntheses of functionalized organocopper reagents. Gregory W. Ebert*,
Xiaogang Zhao, Yu Chen, Alphajor Barrie
1136. Development of a new synthetic
method of five-membered rings including
three adjacent chiral centers by a silyl triflate-promoted tandem epoxide rearrangement-cyclization.
Takeshi Kodama*, Shingo Harada,
Takeshi Tanaka, Yoshimitsu Tachi,
Yoshiki Morimoto
1137. Asymmetric total synthesis of (⫹)-helianane. Masahiro Yoshida*,
Kayo Yamamoto, Tomotaka Mizuguchi,
Kozo Shishido
1138. Highly diastereoselective synthesis of
tetrahydrobenzofuran derivatives by palladium-catalyzed reaction of propargylic
esters with substituted ␤-dicarbonyl
compounds. Masahiro Yoshida*,
Mariko Higuchi, Chiyuki Sugimura,
Kozo Shishido
1139. Stereoselective rhodium(II)-catalyzed
oxonium ylide formation-[2,3] shift of diazoketoesters and its application to synthesis of cinatrins. Takayuki Yakura*,
Ayaka Ozono, Wenqi Niu,
Katsuaki Matsui
1140. Asymmetric synthesis of pachastrissamine using rhodium(II)-catalyzed C-H
amination. Takayuki Yakura*, Wenqi Niu,
Seiichi Sato, Yuya Yoshimoto
1141. Asymmetric 1,3-dipolar cycloaddition
reactions catalyzed by Pybox-, BINIM-,
and BINAN-metal complexes.
Hiroyuki Suga*, Shingo Yasumura,
Ayano Inaba, Yuki Adachi, Michiko Sano,
Akikazu Kakehi
1142. Deprotection method through the chemoselective cleavage of benzoyloxy
group using samarium(II) dibromide.
Takayuki Hosaka, Frank G. Yosua,
Masaki Tsushima, Yasuo Yokoyama*,
Shoko Suzuki
1143. Synthetic study of the EFGH ring segment of ciguatoxin CTX3C (2).
Naoya Fujita, Yuki Sato,
Hiroyoshi Takamura, Isao Kadota,
Yoshinori Yamamoto
1144. Platinum-catalyzed diastereoselective
cyclization of 2-formylarylboronic acids
with allenes. Masahiro Yoshida,
Shoko Ohno, Kennosuke Matsuda,
Kozo Shishido
1145. Enantioselective reduction of ␣,␤-unsaturated ketones using chiral lactam alcohol and phenoxyborane.
Yasuhiro Kawanami*, Masaya Kiguchi,
Takamasa Okazaki
1146. Studies on the novel synthetic methods of the phenylalanine derivatives.
Kazuyuki Umemura, Yumi Kitagou,
Nobutada Motoki
1147. Medicinal plant resources for bioprospecting and drug development in
tribal rich district, Parbat, Nepal.
Ram L. Shrestha*
1148. Ytterbium(III) triflate catalyzed tandem
Friedel-Crafts alkylation/hydroarylation of
propargylic alcohols with phenols as an
expedient route to indenols.
Xiaoxiang Zhang*, Wanteng Teo,
Philipwaihong Chan*
1149. Synthetic studies of concavine by palladium-catalyzed cycloalkenylation.
Yousuke Komori, Masahiro Toyota*
1150. Synthetic studies towards total synthesis of ␣-skytanthine by means of
Pd(II)-catalyzed oxidative cyclization.
Kazutaka Takeda, Masahiro Toyota*
1151. Asymmetric methods for the synthesis
of pyran-based natural products.
Thomas E. Smith, Jennifer L. Green,
Mary B. Daub, Cale D. Weatherly,
Edwin T. Layng, Zebulon G. Levine,
Amanda Huey, Pamela M. Choi,
Marian M. Deuker, Rachel C. Patel
1152. Stereoselective synthesis of functionalized 1,2,3,4-tetrahydroisoquinolines
from chiral aziridines. Wonkoo Lee*,
Kyung Yeon Kang, Kyu Myung Lee,
Jun Hee Kim, Hyun-Joon Ha*
1153. Highly efficient synthesis of halo hydrofurans from Brønsted acid-catalyzed
hydroxylation/halocyclization of cyclopropyl methanols with water and N-halosuccinamide. Srinivasa R. Mothe*,
Prasath Kothandaraman, Philip W. Chan*
1154. Useful and general one-pot synthetic
method of secondary, allyl and propargyl
alcohols from esters. Ah Ram Jeon,
Jae Kyo Park, Duk Keun An*
1155. Gold-catalyzed cycloisomerization reaction of 2-tosylaminophenylprop-1-yn3-ols as a versatile platform for indole
synthesis. Prasath Kothandaraman,
Weidong Rao, Shi Jia Foo,
Philip W. Chan*
1156. Toward solutions to the problem of
controlling E-O-enolate geometry of lactate esters. Sefat Alwarsh*,
McIntosh Matt
1157. Gold-catalyzed intramolecular cyclization of (2-aminophenyl)-cyclopropyl
methanols as an expedient route to 2,3dihydro-1H-benzazepines and indolines.
Chuhui Huang*, Susanti Dewi,
Prasath Kothandaraman,
Wai Hong P. Chan
1158. Alkylative aziridine ring openning and
the formal synthesis of tyroscherin.
Doo-Ha Yoon, Yongeun Kim,
Hyun-Joon Ha*, Won Koo Lee
1159. Asymmetric synthesis of (R)-2-(2-chloroethyl)pyrrolidine-1-carboxylic acid ethyl
ester. Hee-Doo Kim*, Seung-Jin Kim
1160. Ti(O-i-Pr)4/Me3SiCl/Mg-mediated reductive cleavage of sulfonyl amides and
esters to amines or alcohols with thiols.
Sentaro Okamoto*, Noriaki Sho-ji,
Tsuyoshi Kawaji, Chikashi Matsuno
1161. Synthesis of C,D-ring intermediates of
natural vitamin D and their analogs.
Naoto Hayashi, Kiyohide Ken-motsu,
Yu-suke Hasegawa, Sentaro Okamoto*
1162. Efficient synthesis of dihydroisoxazoles and isoxazoles by iodocyclization
of alkoxyamine derivatives.
Takashi Okitsu*, Kana Sato,
Taterao M. Potewar, Akimori Wada
1163. Reagent-controlled oxidative aromatization in iodocyclization: A versatile synthesis of dihydropyrazoles and pyrazoles.
Takashi Okitsu, Kana Sato,
Akimori Wada*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
1164. Facile synthesis of medium-sized cyclic amines based on Friedel-Crafts reaction via iminium cation by use of indole
derivatives. Masanori Imai*,
Nobuhiko Kishi, Sakiko Toyoda,
Megumi Mizukami, Shinji Nagumo
1165. Highly selective one-pot [2⫹3]-cycloaddition reaction via isomerization of
3-butynoates to allenoates.
Magesh Sampath, Teck-Peng Loh*
1166. Synthetic studies on jiadifenin, a neurotrophic sesquiterpene.
Kenichi Harada, Akiko Imai,
Kazuharu Uto, Miwa Kubo, Hideaki Hioki,
Yoshiyasu Fukuyama*
1167. Synthesis of bioactive compounds via
hypervalent iodine-mediated intramolecular aminocyclization. Hiroko Kakuda*,
Masayuki Kirihara, Yasutake Takahashi
1168. Stereoselective synthesis of 2,6-disubstituted tetrahydropyran-4-carboxaldehyde via Prins-type cyclization.
Sun-Joon Min*, Young Seub Kim*,
Yong Seo Cho, Jae Kyun Lee,
Kihang Choi
1169. Asymmetric synthesis of highly substituted cyclobutane compounds.
Kuo-Wei Tsao, Minoru Isobe*
1170. Construction of a quaternary carbon
by using ZnX2-promoted allylic substitution. Yuki Kaneko, Yohei Kiyotsuka,
Yuichi Kobayashi*
1171. Novel method for construction of medium-sized cyclic amines based on intramolecular Friedel-Crafts reaction of vinyloxiranes. Megumi Mizukami,
Koji Wada, Masanori Imai,
Norio Kawahara, Masaaki Miyashita,
Hiroyuki Akita, Shinji Nagumo
1172. New method for the angular methyl insertion to fused cyclic ethers.
Yuka Fujisawa, Takayuki Kishi,
Hiroyoshi Takamura, Isao Kadota
1173. Functionalized cyclobutane synthesis
applying toward Solanoeclepin.
Chia-Yi Cheng, Anuch Hasakunpaisarn,
Supaporn Niyomchon, Minoru Isobe*
1174. Withdrawn
1175. Use of alkyl nitronates within the
Henry reaction. Ian Pottie*,
Amanda Pilgrim, Frank MacDonald
1176. Novel rearrangement via the intramolecular Hosomi-Sakurai reaction.
Daisuke Kikuchi, Masahiro Yoshida,
Kozo Shishido*
1177. Preparation of 1,3-butadien-2-yl indium and its application to tandem DielsAlder/cross-coupling reaction.
Phil Ho Lee*, Dahan Eom, Dongjin Kang,
Jaeyoung Lee
1178. Indium-mediated allenyl cross-coupling/cycloisomerization for synthesis of
indolizines. Phil Ho Lee*,
Kwangmoo Lee, Dahan Eom,
Jeongmin Suh
1179. Stereoselective synthesis of the northeastern sector of bielschowskysin from a
functionalized cyclopropanecarbaldehyde. Allan Patrick G. Macabeo*,
Oliver Reiser
1180. Facile approach to optically active
␣-alkylidene-␤-amino esters by thermal
Overman rearrangement. Sung I. Lee*,
Soon Y. Moon, Do H. Ryu*
1181. Nucleophilic substitution reaction at
nitrogen of sulfonamides with phosphide
anion: An efficient deprotection and
transformation method for tosylamides.
Suguru Yoshida, Kazunobu Igawa,
Katsuhiko Tomooka*
1182. Synthesis of 1,4-dihydronaphthalenes
through platinum-catalyzed intramolecular hydroarylation of allenyl arenes.
Phil Ho Lee*, Doosup Shin, Juntae Mo,
Junsung Bae
1183. Indium-mediated 1,3-butadien-2-ylation of imines for preparation of 2-aminomethyl-1,3-diene derivatives.
Phil Ho Lee*, Youngchul Park,
Sanghyuk Kim, Dahan Eom
1184. Efficient multialkynyl cross-coupling
reactions with tetra(alkynyl)indates.
Phil Ho Lee*, Dahan Eom, Subin Choi
1185. N-Heterocyclic carbene-catalyzed
highly regioselective intermolecular
cross-acyloin condensation of acetaldehyde. Mingyu Jin*, Do H. Ryu*,
Jung W. Yang*
1186. Palladium-catalyzed cross-coupling
reaction with 1,3-butadien-2-yl indium.
Phil Ho Lee*, Dahan Eom
1187. Studies on the reaction of chlorosulfonyl isocyanate with various chiral ethers
in the ring systems and its application to
the total syntheses of (⫹)-Sertraline and
(⫹)-Indatraline. Young Hoon Jung*,
Sang-Hwi Lee, QingRi Li, Sunjoo Kim
1188. Stereocontrolled synthesis of cyclic
polyglycerols. Masahiro Hamada,
Takao Kishimoto, Noriyuki Nakajima
1189. Cationic gold(I)-catalyzed intramolecular cyclization of ␥-hydroxyalkynones.
Masahiro Egi, Kaori Shimizu,
Kenji Azechi, Moriaki Saneto, Shuji Akai*
1190. Novel domino process for benzyne
preparation from ortho-(trimethylsilyl)phenols followed by cycloaddition.
Nishiyama Tsuyoshi*
1191. Synthesis of the spirolactone compounds via a novel framework rearrangement reaction. Daisuke Sue,
Takeo Kawabata, Kazunori Tsubaki*
1192. C-N bond forming reaction utilizing
new Mitsunobu reaction.
Tetsuto Tsunoda*, Hiroto Kaku,
Izumi Sakamoto
1193. Organocatalytic regioselective acylation of carbohydrates with functionalized
acid anhydrides toward efficient synthesis of 4-O-acylglycosides.
Yoshihiro Ueda, Wataru§ Muramatsu,
Takumi Furuta, Takeo Kawabata
1194. Efficient synthesis of quinolines and
4H-3,1-benzothiazines from 2-alkynylnitrobenzenes and 2-alkynylanilines.
Saori Ozaki, Kentaro Okuma,
Noriyoshi Nagahora, Kosei Shioji
1195. Synthesis of 2,3,6-trisubstituted 2Hpyran-5-carboxylates by regioselective
addition of acetoacetates to 2-alkyl-2enals. Wei Peng, Kazumi Ashida,
Toshiaki Hirabaru, Tsutomu Inokuchi*
1196. Solid-phase synthesis of protected
␣-amino phosphonic acid oligomers.
Yoshitaka Ishibashi, Kengo Miyata,
Hironori Kutsuna, Sho Kawakami,
Masato Kitamura*
1197. Iodosulfonylation of olefins with sodium benzenesulfinate and I2 in water.
Satoshi Minakata*, Yuki Mitani
1198. Bis(2-t-butylphenyl)phosphonoacetamides for the highly cis-selective synthesis of ␣,␤-unsaturated amides.
Kaori Ando*, Shigeo Nagaya,
Yuko Tarumi
1199. Concise synthetic approach for
clausenamide using 1,3-dipolar cycloaddition. Atsushi Toyao, Kazuhiro Tanda,
Akiko Watanabe, Masanori Sakamoto,
Tetsuo Yamasaki
1200. Novel stereoselective synthesis of the
spiroketal structure using Pd (II) catalyst
and application to the synthesis of spirofungin A and B. Masahiro Miyazawa*,
Taku Murayama, Kenta Iwama,
Akinori Hatanaka, Takao Sanga,
Hajime Yokoyama, Yoshiro Hirai
1201. 2-(Phenylseleno)ethanesulfonamide as
a novel and robust protective group of
amine that can be deprotected by the
radical reaction. Yoshinori Uzawa,
Nobuhiro Kihara*
1202. Development of efficient intermolecular disulfide bond formation in H2-RLX
peptide hormone. Kyoko Takayama*,
Kouki Matsubara, Setsuko Ando,
Yuji Koga
1203. Bridged and fused bicyclic diazenium
salts derived from aryl hydrazone precursors. Matthias Brewer*, Jodi Wyman,
Nezar Al Bataineh, Muhammad I. Javed
1204. Designing and synthesis of nucleobase-containing thioglycosides and their
chemical glycosylation. Shigeto Saito,
Shinya Komabiki, Masanori Kitamura,
Shin Aoki*
1205. Total synthesis of bryostatin using atom-economical and chemoselective approaches. Guangbin Dong*,
Barry M. Trost*
1206. Novel Lewis acid catalysed syntheses
of amides. Clare Liana Allen*,
Jonathan Williams
1207. Intramolecular enolate-imine cyclisation reactions for the asymmetric synthesis of histriononicotoxin.
Robert M. Archer, Steve Bull*
1208. New practical strain release ring expansion reactions and their natural product synthetic applications.
Jon T. Njardarson
1209. Oxepines, 2-C-branched pyranosides,
and C-furanosides from cyclopropyl carbohydrates. Joanne E. Harvey*,
Russell J. Hewitt
1210. 2-Azido-1,3-dimethylimidazolinium
chloride: An efficient diazo-transfer reagent for 1,3-dicarbonyl compounds.
Mitsuru Kitamura*
1211. New variant of Reformasky-Claisen rearrangement mediated by indium chloride. Jun Ishihara*, Yuki Watanabe,
Noriko Koyama, Yukihiro Nishino,
Keisuke Takahashi, Susumi Hatakeyama*
1212. Tandem electrocyclic ring closure reactions to form oxaziridines.
Lucy R. Peacock*, Steven Bull
1213. Asymmetric synthesis of highly substituted ␦-lactones. Jennifer C. Peed,
Ignacio Perigñán-Domínguez,
Iwan R. Davies, Steven Bull*
1214. Studies on the oxo-Povarov reaction.
Rivka R. Taylor, Robert A. Batey*
1215. Vinylogous aza-Morita-Baylis-Hillman
reaction of activated 1,3-butadienes.
Kristen N. Clary, Thomas G. Back
1216. Towards the total synthesis of (⫾)-vinigrol. Jason Poulin*,
Christiane Grise-Bard, Louis Barriault
1217. Toward the total synthesis of morphine via a tandem oxy-Cope/Claisen/
ene reaction. Kassandra Lepack*,
Joel Marcotte, Louis Barriault
1218. Novel palladium-catalyzed allylic alkylation cascade for the synthesis of furanopyrones. Mark J. Bartlett,
Joanne E. Harvey*
1219. New one pot tandem pericyclic oxyCope/ene/Claisen/Diels-Alder reaction.
Boubacar Sow*, Ross M. Maclean,
Jason Poulain, Louis Barriault
1220. Synthesis of indole oligomers related
to eumelanin. Paul B. Huleatt*,
Hung A. Duong, Yun Lei Tan,
Christina L. Chai
1221. Synthetic studies on (⫹)-aristoteline
and its analogs via tandem Michael addition—[3,3]sigmatropy reaction.
Makoto Furuya, Ayumi Nagatomo,
Masahiro Toyota*
1222. Total syntheses of luotonins A and B.
Ken Natsuki, Masahiro Toyota*
1223. Withdrawn
1224. Oxy-Favorskii rearrangement as a tool
for the synthesis of stereochemically defined bicyclic ethers and its application to
the total synthesis of (⫾)-communiol E.
Shoji Kobayashi*, Tatsuhiro Kinoshita,
Takuji Kawamoto, Araki Masuyama,
Ilhyong Ryu
1225. Acyl-Claisen approach to the synthesis of complex natural products.
David Barker*, Claire Rye,
Benjamin Dickson, Nora Dittrich
1226. Interrupted Nazarov reactions using
vinyl siloxyallenes. Yen-Ku Wu,
F. G. West*
1227. Scope and limitations of the intramolecular 4⫹1 cycloaddition between a dialkoxycarbene and an electron-deficient
diene. Francis Beaumier*, Claude Spino
1228. Umpoled tandem reaction of alphaimino esters. Makoto Shimizu*,
Iwao Hachiya, Isao Mizota
1229. Unprecedented [2⫹2]-condensation of
imines: Remarkable substituent effects
and application to natural products synthesis. Katsunori Tanaka*,
Shinji Hirosaki, Takayuki Iwata,
Eric R. Siwu, Koichi Fukase
1230. Intramolecular enolate-imine cyclisation reactions for the synthesis of
␤-amino acids. Caroline D. Evans,
Steven D. Bull*
1231. 6,7,n-Tricyclic ring synthesis via electrophilic cyclization of vinylogous propargyl acetate-Co2(CO)6 complexes.
Izabela Kolodziej*, James R. Green
1232. New synthetic strategies and spectral
studies on verdazyl-derived heteraphanes. Abbarna A. Cumaraswamy*,
Julie L. Lukkarila, Jeremy Dang,
Gordon K. Hamer, Michael K. Georges
1233. Parallel kinetic resolution of dehydroisoleucine using Sharpless asymmetric dihydroxylation. David Dietrich*,
David M. Perrin
1234. Withdrawn
1235. Dendralene-irontricarbonyl complexes: Preparation, properties, and practical
applications. Henry Toombs-Ruane,
Nik Osinski, Cindy Wills, Anthony Willis,
Michael Paddon-Row, Michael Sherburn
1236. Studies toward the total synthesis of
haterumalides. Baldip Kang,
Robert A. Britton*
1237. Total synthesis of variecolortides A-C.
Christian A. Kuttruff, Dirk Trauner*
Saturday Afternoon
Hilton
Sea Pearl V/VI
Anion Coordination Chemistry (#15)
Organized by: B. Hay,
K. Bowman-James, K. Nam, F. Pfeffer
Presiding: F. Pfeffer
12:30 – 1238. Addressing association entropy in host-guest binding: Some lessons taught by abiotic anion receptors.
Franz P. Schmidtchen*,
Wiebke Antonius, Tomas Bríza,
Eberhardt Herdtweck
13:00 – 1239. Anion recognition by N-heterocyclic C-H hydrogen bonding.
Kiyoshi Sato*
13:30 – 1240. Strong CH hydrogen bonds
and the photo-controlled regulation of
anions. Amar H. Flood*, Yuran Hua,
Kevin P. McDonald, Semin Lee
14:00 – 1241. Strong and selective outer
sphere ligands for metallate anions; applications in extractive hydrometallurgy.
Ross J. Ellis, Kathy C. Sole,
Peter A. Tasker*
14:30 – 1242. Anion-␲ interactions in crystal
structures - commonplace or extraordinary? Benjamin Hay*, Radu Custelcean
15:00 – 1243. Anion-␲ interactions in salts
bearing pentafluorophenyl groups.
Markus Albrecht*, Michael Müller,
Kari Rissanen
15:30 – 1244. Quantification of anion-␲ interactions using calix[4]pyrrole model
systems. Pablo Ballester*
16:00 – 1245. Halogen bonding: New tool for
anion recognition and coordination.
Giuseppe P. Resnati*, Serena Biella,
Pierangelo Metrangolo, Tullio Pilati,
Giancarlo Terraneo
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–133
04-ORGN
Hilton
Coral IV
C-H Functionalization, Memorial
Symposium for Professor Keith Fagnou
(#18)
Organized by: H. Lebel, T. Driver, K. Itami
Presiding: H. Lebel
12:30 – 1246. Use of strain to promote ring
opening and ring closing reactions.
Mark Lautens*
13:30 – 1247. Three-step synthesis of triarylated azoles through sequential C-H bond
arylation reaction using cationic palladium complex. Eiji Yamaguchi*,
Fumitoshi Shibahara, Toshiaki Murai
13:55 – 1248. Advances in the use of dioxygen as a stoichiometric oxidant in Pd-catalyzed oxidative functionalization of C-H
bonds. Shannon S. Stahl*
14:20 – 1249. Catalytic C-H borylation of
alkenes by iridium and palladium catalysis. Kalman J. Szabo*
14:45 – 1250. Transition metal-catalyzed
synthesis of N-heterocycles from azides.
Benjamin J. Stokes, Huijun Dong,
Ke Sun, Linda Urnezis, Tom G. Driver*
15:10 – 1251. Strategies towards the synthesis of the dictyodendrins via iterative metal-catalyzed C-H bond functionalization.
Fionn O’Hara, Matthew J. Gaunt*
15:35 – 1252. Progress in Pd-catalyzed C-H
oxidation. Melanie Sanford
Hilton
South Pacific II
Asymmetric Organocatalysis (#62)
Organized by: K. Maruoka, L. Deng,
L. Gong
Presiding: K. Maruoka, L. Gong, L. Deng
12:30 – 1253. Enantioselective photoredox
catalysis. David MacMillan
13:00 – 1254. Recent progress of asymmetric trifluoromethylation reaction.
Norio Shibata*
13:30 – 1255. Asymmetric cooperative and
relay catalysis by organo/metal binary
systems. Liu-Zhu Gong*
14:00 – 1256. Design of high-performance
organocatalysts for practical asymmetric
synthesis. Keiji Maruoka*
14:30 – 1257. Primary amino acid-based enantioselective organocatalytic synthetic
methods. Yixin Lu
14:50 – 1258. Hypervalent iodine-catalyzed
enantioselective oxidative cycloetherification of 3-(2-hydroxyphenyl)propan-1ones to 2,3-dihydrobenzofuran-2-carbonyl derivatives. Kazuaki Ishihara*,
Muhammet Uyanik, Hiroaki Okamoto,
Takeshi Yasui
15:10 – 1259. New directions with carbene
catalysis. Karl Scheidt*
15:30 – 1260. Enantioselective formal cycloaddition reactions of ketenes catalyzed by N-heterocyclic carbenes.
Song Ye*
15:50 – 1261. Enantioselective direct carbon-carbon bond forming reactions of
5-membered ring substrates using aldolase-type organocatalyst.
Nobuyuki Mase*
16:10 – 1262. New strategies in developing
powerful enantioselective organocatalytic
cascade reactions. Shilei Zhang, Hao Li,
Xin-Shuai Zhang, Chenguang Yu,
Jian Wang, Liansuo Zu, Hexin Xie,
Wei Wang*
Hilton
South Pacific IV
Marine Natural Products: Isolation, Biology,
Ecology, and Synthesis (#80)
Organized by: J. Rainier, R. Anderson,
M. Murata
Presiding: J. Rainier
12:30 – 1263. Total synthesis of amphidinolide Q. Haruaki Ishiyama*,
Masahiro Hangyou, Yohei Takahashi,
Jun’ichi Kobayashi*
134 –TECH
TECHNICAL PROGRAM
12:50 – 1264. Synthetic and biological studies of the spongian diterpene Macfarlandin E. Martin Schnermann*,
Chris Beaudry, Christine Sütterlin,
Larry Overman
13:10 – 1265. Screening for activators of
protein kinase C using its C1 domain
peptide: Identification and biological activities of bryostatin 10 from Japanese
bryozoan. Ryo C. Yanagita,
Takeshi Fujiwara, Kazuhiro Irie
13:30 – 1266. Synthetic study of the polyol
marine natural product symbiodinolide.
Hiroyoshi Takamura*, Takeshi Murata,
Takashi Abe, Takahiro Asai,
Masayuki Sano, Junki Ando,
Yuichiro Kadonaga, Isao Kadota*,
Daisuke Uemura
13:50 – 1267. Halenaquinone derivatives
from South Pacific sponges of the genus
Xestospongia as inhibitors of phospholipase A2 and farnesyltransferases.
Brent R. Copp*, Jiayi Wang,
Arlette Longeon, Mélanie Roué,
Cécile Debitus,
Marie-Lise Bourguet-Kondracki
14:10 – 1268. Synthesis and reactivities of
aplyronine A probes. Hideo Kigoshi*,
Masaki Kita, Yuichiro Hirayama,
Miyuki Sugiyama, Yuki Saito
14:30 – 1269. A MALDI-directed genomisotopic approach to the discovery of novel
natural products in cyanobacteria.
Robin Kinnel, Eduardo Esquenazi,
Adam Jones, Emily Monroe,
Pieter Dorrestein, Lena Gerwick,
William H. Gerwick*
14:50 – 1270. Molecular mode of action of
amphidinol 3, a potent antifungal compound isolated from marine dinoflagellate. Respati T. Swasono*,
Toshihiro Houdai, Ryota Mouri,
Nobuaki Matsumori, Tohru Oishi,
Michio Murata
15:10 – 1271. Withdrawn
15:30 – 1272. Structural elucidation of okadaic acid binding protein 2.1.
Seketsu Fukuzawa, Marie Makino,
Koichiro Kodama, Haruhiko Ehara,
Takuhiro Ito, Shun-ichi Sekine,
Shigeyuki Yokoyama*, Kazuo Tachibana*
15:50 – 1273. Structural study on polyether
carboxylic acids from the dinoflagellate
Karenia brevisulcata in New Zealand.
Masayuki Satake*, Yuka Hamamoto,
Kazuo Tachibana, Patrick Holland,
Feng Shi, Veronica Beuzenberg,
Patrick Edwards, Steven M. Pascal
16:10 – 1274. Novel N-methylated 8-oxoisoguanines from Pacific sponges with
diverse neuroactivities. Ryuichi Sakai*,
Tsuyoshi Sakurada, Martin B. Gill,
Shanti Frausto, Keiichi Noguchi,
Keiko Shimamoto, Geoffrey T. Swanson*
Hilton
Tapa II
Total Synthesis of Natural Products and
Related Compounds (#134)
Organized by: R. Williams, S.H. Kang,
K. Tanino
Presiding: R. Williams
12:30 – 1281. Formal synthesis of kopsinine
by asymmetric conjugate amination-tandem alkylation. Shingo Harada,
Takeo Sakai, Ken-ichi Yamada,
Yasutomo Yamamoto, Kiyoshi Tomioka*
12:50 – 1282. Total syntheses of ␤-C-glycoside natural products via oxocarbenium
cations. Michael Jennings*
13:10 – 1283. Studies towards the total synthesis of the brasilinolides.
Michael P. Housden*,
Christopher J. Cordier, Paul M. Burton,
Friedrich A. Mühlthau, Olivier Loiseleur,
Ian Paterson
13:30 – 1284. Synthetic studies on gelsemoxonine. Jun Shimokawa,
Takaaki Harada, Satoshi Yokoshima,
Tohru Fukuyama*
13:50 – 1285. Synthesis of securinol B: Sequence of Vilsmeier-Haack and Mannich
cyclizations. Guillaume Bélanger*,
Robin Larouche-Gauthier,
Marianne Dupuis, Gary O’Brien
14:10 – 1286. Synthesis of dragmacidin D
via direct C⫺H bond arylation.
Junichiro Yamaguchi*,
Debashis Mandal, Atsushi D. Yamaguchi,
Kirika Ueda, Kenichiro Itami*
14:30 – 1287. Rapid synthesis of the A-D
and G-J fragments of gambieric acid A.
Stephen Clark*, Subhabrata Chaudhury,
Euan Fordyce, Thomas Hameury,
Bora Sieng
14:50 – 1288. Synthetic studies on antibiotic
BE-43472B. Yu Yamashita,
Akiomi Takada, Hiroshi Takikawa,
Keisuke Suzuki*
15:10 – 1289. Phosphate tether-mediated
processes for application in natural product synthesis. Paul R. Hanson*
15:30 – 1290. Total synthesis of natural ansa-compounds using intramolecular
Doetz benzannulation. Yoko Saikawa*,
Kyosuke Tanaka, Masahito Watanabe,
Kohdai Ishibashi, Hiroshi Matsuyama,
Masaya Nakata*
15:50 – 1291. Total synthesis of (⫹)-haplophytine. Hirofumi Ueda, Hitoshi Satoh,
Koji Matsumoto, Kenji Sugimoto,
Tohru Fukuyama, Hidetoshi Tokuyama*
Hilton
Honolulu III
Hilton
Iolani I/II
Design and Synthesis of Biologically Active
Compounds for Elucidating Mode-ofAction (#148)
Frontiers in Biocatalysis Applications to
Organic Synthesis (#124)
Organized by: T. Oishi, C. Forsyth, H. Lee
Presiding: T. Oishi
Organized by: R. Kazlauskas, T. Sakai,
J. Wu
Presiding: R. Kazlauskas
12:30 – 1292. Synthesis of novel derivatives
of tetracaine as enhanced ion channel
blockers. Sarah Kirk*, Evan Jackson,
Kenneth Melich, Jeffrey Karpen
12:45 – 1293. Biologically active novel
branched pyrrolidines: synthesis of
isoDAB and isoLAB. Daniel Best,
Sarah F. Jenkinson, A. W. Saville,
Atsushi Kato, Francis X. Wilson,
George W. Fleet
13:00 – 1294. Synthesis and biological profile of simple analogs of tumor-promoting
aplysiatoxin as unique leads for anticancer drugs. Kazuhiro Irie*, Yu Nakagawa,
Keisuke Tanaka, Ryo C. Yanagita,
Harukuni Tokuda
13:20 – 1295. Fragment-based approaches
to designing selective molecules for SAR
and MoA studies. Paul Hawkins*,
Geoffrey Skillman, Joseph Corkery,
Kevin Schmidt
13:40 – 1296. Potent, fast-acting anticancer
agent that induces apoptotic cell death
through an unusual biochemical pathway.
Paul J. Hergenrother*
12:30 – 1275. Molecular origami of
polyketide natural products. Sheryl Tsai*
13:15 – 1276. Protease reaction kinetics on a
quartz-crystal microbalance.
Yoshio Okahata, Hiroyuki Furusawa
14:00 – 1277. Use of whole cells as biocatalysts for efficient production of bioactive
secondary metabolites.
Jian-Jiang Zhong*
14:45 – 1278. Activation of enzyme by the
ionic liquids. Toshiyuki Itoh*
15:30 – 1279. Chemical modification of biogenous iron oxide to create an excellent
enzyme scaffold. Yuki Miyazaki,
Takashi Sakai*, Ai Murakami,
Noriko Sakamoto, Tadashi Ema,
Hideki Hashimoto, Mitsuaki Furutani,
Makoto Nakanishi, Tatsuo Fujii,
Jun Takada*
15:55 – 1280. Asymmetric resolution of dynamic systems. Olof Ramstrom*
14:00 – 1297. Synthesis of novel natural
products and analogs for studying mode
of action. Craig Forsyth*
14:30 – 1298. Sphingolipids, old compounds
but new targets: Synthesis of sphingolipid analogs as chemical tools.
Sanghee Kim*, Dong Jae Baek,
Chaemin Lim, Yun Mi Lee, Jihee Cho
15:00 – 1299. Recent progress in oxacycle
synthesis: Radical, Prins, and carbonyl
ylide cycloaddition reactions. Eun Lee*,
Jae Hoon Jung, Snag Kook Woo,
Min Sang Kwon, Ki Po Jang,
Chan Hyuk Kim
15:30 – 1300. Total synthesis and biological
mode of action of macrocyclic histone
deacetylase inhibitors.
Robert M. Williams*
16:00 – 1301. Asymmetric synthesis of (-)dysiherbaine. Sung Ho Kang*
Hilton
Sea Pearl I/II
Cooperative Catalysis (#14)
Organized by: Y. Uozumi, R. Danheiser,
K. Ding, A. Nishida
Presiding: K. Ding
12:50 Introductory remarks
13:00 – 1302. Cooperative non-covalent interactions in asymmetric catalysis.
Eric N. Jacobsen
13:40 – 1303. Development of chiral bifunctional organocatalysts. Hiroaki Sasai*
14:10 – 1304. Chiral pyridyl bis(imidazolidine)-Cu(OTf)2: Catalytic asymmetric reaction using imino esters.
Takayoshi Arai*, Asami Mishiro
14:30 – 1305. Cooperative catalysis by multifunctional polymers. Patrick H. Toy
14:50 – 1306. Development recyclable iridium catalyst for C-H borylation.
Mayumi Nishida, Tuyoshi Tagata,
Atsushi Nishida*
15:10 – 1307. Enantioselective [4 ⫹ 2] cycloadditions of iminoacetonitriles.
Rick L. Danheiser*
15:30 – 1308. Recent progress in asymmetric cooperative catalysis.
Masakatsu Shibasaki*
16:20 Concluding remarks
Hilton
Coral V
Mechanistic Organic Photochemistry (#89)
Organized by:
H. Zimmerman and A. Griesbeck,
T. Ichimura, A. Kutateladze, P. Wan
Presiding: A. Kutateladze
13:00 – 1309. Singlet fission. Josef Michl*
13:35 – 1310. Wavelength-dependent enantiodifferentiating photoisomerization of
cyclooctene sensitized by chiral benzenepolycarboxylates: Dramatic enhancement of optical yield. Daisuke Yoneda,
Hirosuke Saito, Cheng Yang,
Tadashi Mori, Takehiko Wada,
Yoshihisa Inoue*
14:10 – 1311. Influence of the structure of
bile salt aggregates on the guest binding
dynamics or the guest’s photochromism.
Cornelia Bohne, Kentaro Morimitsu,
Denis Fuentealba, Allyson Miller,
Tamara C. Pace, Cerize S. Santos,
Kathie Thurber
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
14:45 – 1312. Diradicals and zwitterions in
organic photochemistry.
Howard E. Zimmerman*
15:20 – 1313. Fluorescent protein chromophores as scaffolds for new sensor
applications. Laren M. Tolbert
15:55 – 1314. Photochemical asymmetric reaction in fluid media using the molecular
chirality controlled by spontaneous crystallization. Masami Sakamoto*
Saturday Evening
Hilton
Honolulu I
Poster Session
19:00 – 21:00
Practical Applications of Basic Research on
Molecular Recognition (#222)
1330. Ab initio CASSCF/MRMP2 studies on
the photochemical reaction pathways of
quintet ground-state phenylene-1,3-dinitrene. Kenji Sugisaki, Kazuo Toyota,
Kazunobu Sato, Daisuke Shiomi,
Takeji Takui
1331. Photoisomerization of perfluoroaryltetrahedranes to perfluoroarylcyclobutadienes. Yusuke Inagaki,
Masaaki Nakamoto, Akira Sekiguchi*
1332. Synthesis, structure, and reactions of
novel isolable dialkylsilylenes.
Takashi Abe, Ryoji Tanaka,
Shintaro Ishida, Mitsuo Kira,
Takeaki Iwamoto*
1333. Theoretical study on the mechanism
and diastereoselectivity of NaBH4 reduction. Daisuke Kaneno*,
Yasumitsu Suzuki, Shuji Tomoda
1334. Generation of biradicals and their reactivity in a low temperature matrix.
Satoshi Maeda*, Manabu Abe*
1335. B3LYP and CASPT2 calculations of
the effect of relay orbitals on the throughbond interactions between mutually perpendicular pairs of allyl radicals.
Charity Flener Lovitt, Hao Dong,
David A. Hrovat, Rolf Gleiter,
Weston T. Borden*
1336. Substituent effects on the acetolysis
rates of phenylethyl sulfonates bearing ␣or ␤-CF3 group. Satoshi Usui*,
Tatsuya Kojima, Ken Hazama, Mie Ohta,
Keiko Kato, Mutsuo Okamura
1337. Two-electron oxidation of allene compounds bearing acridene skeletons.
Shin-ichi Fuku-en*, Tomoyuki Yano,
Torahiko Yamaguchi,
Yohsuke Yamamoto
1338. Highly selective stereodivergent synthesis of separable amide rotamers and
their synthetic application.
Masashi Nakamura, Nobutaka Ototake,
Syunsuke Yamada, Osamu Kitagawa*
1339. Alkoxy-group effect on the lifetime of
singlet 2,2-dialkoxycyclopentane-1,3diyls. Tomoyuki Nakagaki*,
Yoshihisa Fujiwara, Manabu Abe
1340. Regioselectivity in the Paternò-Büchi
reaction of geraniol derivatives.
Ken Hisamoto*
1341. Synthesis, thermochemical and kinetic
studies of novel diarylamine antioxidants.
Jason J. Hanthorn, Derek A. Pratt*,
Luca Valgimigli
1342. Theoretical study of the substituent effects on the gas phase stabilities of benzylic anions. Kazuhide Nakata*,
Mizue Fujio, Kichisuke Nishimoto,
Yuho Tsuno
1343. Substituent effect at C7 on the stereoselectivity in the denitrogenation reaction
of DBH derivatives. Manabu Abe*,
Shingo Yagi
1344. Synthesis and characterization of new
spirooxytellurane [10-Te-4(C3O)] having
SO3 unit. Soichi Sato*,
Takahiro Yamashita, Ernst Horn
1345. New synthetic method of 3,3’-disubstituted-2,2’-dihalobiaryls via an aryne intermediate. Mayumi Mizukami,
MInako Hara, Soichi Sato*
1346. Advances in cubane chemistry.
Ronny Priefer*
1347. Study of the formation of silene/silylene intermediates in the decomposition
of silacyclobutanes on a W filament.
Yujun Shi*, Ling Tong, Brian Lo,
Brett Eustergerling, Xinmao Li
Organized by: W. Hinze, C. Easton,
K. Kano
Presiding: C. Tran, K. Kurihara
13:00 – 1315. Boromycin and cyclofructan
as chiral sensors for enantioselective molecular recognition and analyses.
Daniel W. Armstrong
13:30 – 1316. Social self-sorting: Alternating
supramolecular oligomer consisting of
isomers. Yoshinori Takashima*,
Naoki Tomimasu, Hiroyasu Yamaguchi,
Akira Harada
13:50 – 1317. Molecular recognition and
transport in fluorous media.
Stephen Weber*, Abul Hussam,
Hong Zhang, Yanhong Yang
14:20 – 1318. Fishing for modifications: Designing synthetic probes for methylated
lysine and arginine. Amanda Whiting,
Fraser Hof
14:40 – 1319. Mechanism of dephosphorylation of organic phosphates in functional
micelles and in the presence of synzymes. Faruk Nome*, Elisa Orth,
Bruno S. Souza, Eduardo Wanderlind,
Tiago A. Brandão
15:10 – 1320. Size recognition in the nonionic surfactant mediated extraction of
silver nanoparticles.
Yoshitaka Takagai*, Willie L. Hinze
15:30 – 1321. Enantioselective binding of
non-aromatic molecules to cyclodextrins
via ternary complex formation using
“spacer” molecules. Willie Hinze*,
Najma Memon
Hilton
Honolulu II
Transition Metal Catalysis: Mechanism and
Practice (#283)
Organized by: K. Nozaki, J. Stryker,
F.D. Toste
Presiding: K. Nozaki
13:00 – 1322. Catalysis with transition metalheteroatom bonds. Dean Toste
13:35 – 1323. Novel reactions mediated by
copper hydrides. Pauline Chiu*
14:10 – 1324. Gold(I)-catalyzed synthesis of
fused-carbocycles. Louis Barriault*,
Francis Barabé, Patrick Lévesque,
Gabriel Bellavance
14:25 – 1325. Construction of carbon frameworks through carbon-carbon bond
cleavage. Masahiro Murakami*,
Masanori Shigeno, Takanori Matsuda
15:00 – 1326. Palladium-catalyzed oxidative
amination reactions. Forrest Michael*
15:15 – 1327. Copper-catalyzed skeletal rearrangement of O-propargylic oximes.
Itaru Nakamura*, Toshiharu Araki,
Masashi Okamoto, Tomoki Iwata,
Dong Zhang, Masahiro Terada
15:30 – 1328. Transition metal-catalyzed fluorination. Tobias Ritter
16:05 – 1329. Novel transition metal ironcatalyzed organic reactions.
Yi-Cheng Zhang, Kai Ren, Pin-Hua Li,
Lei Wang*
Convention Center
Kamehameha Halls II and III
Reactive Intermediates and Unusual
Molecules - A Celebration of Bob Moss’s 70
years (#1)
Organized by: M. Platz, M. Abe, W. Leigh
Presiding: M. Platz
1348. Synthesis and properties of stable
base-free dialkylsilanimines and THF-mediated silanimine-silaenamine isomerization via 1,3-silyl migration.
Takeaki Iwamoto*, Nobuyoshi Ohnishi,
Zhenyu Gui, Shintaro Ishida,
Hiroyuki Isobe, Satoshi Maeda,
Koichi Ohno, Mitsuo Kira*
1349. Highly reactive difluorobenzocyclooctyne is kinetically stabilized by ␤-cyclodextrin. Ellen M. Sletten*,
Hitomi Nakamura, John C. Jewett,
Carolyn R. Bertozzi
1350. Antioxidant substance, such as homogentidic acid, production by the transformation of sweet potato using Aspergillus niger. Takehiko Tsuruta*
1351. ␤-Effects of the group 4 metals: mechanisms of desilylation and degermylation
of carbenium ions. Asimo Karnezis,
Richard O’Hair, Jonathan White
1352. Dependence of the photochemistry of
8-azidoadenosine on pH: Diiminoquinone
formation vs. nitrenium ion formation.
Maxim Panov, Denis Nilov,
R. M. Wilson*, Alexander N. Tarnovsky
1353. Effective nitrenium ion for photoaffinity
labeling (PAL): 2-N-alkylamino-5-azidopyridine. Valentyna Voskresenska,
Maxim Panov, Mikhail Ryazantsev,
R. M. Wilson*, Alexander N. Tarnovsky
1354. Inter-and intramolecular trapping of
cyclopropanone intermediates in the
photooxygenation of 1,2-dihydropentalenes. Ihsan Erden*, Christian Gaertner
1355. Mechanistic studies of allium-derived
antioxidants. Philip Lynett, Krista Butts,
Vipraja Vaidya, Derek Pratt*
Convention Center
Kamehameha Halls II and III
New Advances in Metal-Catalyzed
Alkylation and Fluoroalkylation (#115)
Organized by: D. Vicic, V. Dong,
N. Kambe
Presiding: R. Lewis
Poster Session
19:00 – 21:00
1356. Palladium-catalyzed asymmetric synthesis of allylic fluorides.
Matthew H. Katcher, Abigail G. Doyle*
1357. Synthesis of a new isoindole based nitrone: 1,1-dimethyl-3-(trifluoromethyl)1H-isoindole N-oxide. Bunpei Hatano*,
Katunori Miyoshi, Haruna Sato,
Tomohiro Ito, Tateaki Ogata,
Tatsuro Kijima
1358. Novel introduction of tetrafluoroethylene units into organic molecules INTO.
Shinya Takano, Yoshikazu Takahashi,
Tsutomu Konno*, Takashi Ishihara
1359. Reductive coupling reaction of aromatic aminal using zinc and chlorotrimethylsilane. Tomoharu Tachikawa,
Bunpei Hatano*, Tatsuro Kijima
1360. Gold-catalyzed functionalization of silyl enol ethers. Tetsuro Kaneko*,
Haruo Aikawa, Naoki Asao
1361. New catalytic reaction sequence for
aromatic difluoromethylation.
Kenichi Fujikawa, Yasutaka Fujioka,
Hideki Amii*
1362. Development of chiral dinuclear zinc
bisamidinate catalyst: asymmetric alkylation of ␣-ketoesters.
Masahiro Yamanaka*, Masamitsu Inaba
1363. Synthesis of 1-alkylidene-2-trifluoromethyl-1H-indene derivatives.
In Howa Jeong*, Youn Young Hong
1364. Iron-catalyzed cross-coupling reaction
using organoaluminum reagents.
Shintaro Kawamura, Kentaro Ishizuka,
Masaharu Nakamura
1365. Synthesis of 2,2-difluoro-1-tributylstannylethenyl tosylate and its diarylation
reaction. In Howa Jeong*,
Seung Yeon Han
1366. Ruthenium catalyzed cascade N, C-dialkylation of amine via hydrogen borrowing methodology. Basker Sundararaju*,
Tang Zhou, Achard Mathieu*,
Sharma Gangavaram. V. M,
Bruneau Christian
1367. Withdrawn
1368. Chiral zinc bisamidine catalyzed
asymmetric aldol reaction of ␣-ketoesters. Ryo Gotoh,
Masahiro Yamanaka*
1369. (sp3)C-(sp3)C cross-coupling reaction
catalyzed by transition metals having unsaturated carbon ligands.
Ryohei Shimizu*, Takanori Iwasaki,
Hitoshi Kuniyasu, Nobuaki Kambe
1370. Synthesis of 2-trifluoromethyl-3-phenylsulfonyl-1,3-butadiene and its reactivities toward various nucleophiles.
In Howa Jeong*, Eun Joon Yang
1371. Development of highly efficient and
novel reactions using iridium catalysts.
Akihiro Shibamoto*,
Tomohiro Hashizume, Yasutaka Ishii
1372. Recent developments in nickel and
copper trifluoromethylation reactions.
Robert Lewis, David Vicic*
Convention Center
Kamehameha Halls II and III
Frontiers in Biocatalysis Applications to
Organic Synthesis (#124)
Organized by: R. Kazlauskas, T. Sakai,
J. Wu
Presiding: T. Sakai
Poster Session
19:00 – 21:00
1373. Purification and characterization of a
novel keto ester reductase from the green
alga, Chlorella sorokiniana: Comparison
of enzymological properties with other
microbial keto ester reductases.
Kohji Ishihara*, Rieko Iwai,
Nami Matsumoto, Noriyoshi Masuoka,
Hitomi Yamaguchi, Nobuyoshi Nakajima
1374. Effective synthesis of versatile optically active zerumbone derivatives.
Sayo Ohta, Ayumi Saito,
Kaoru Nakamura, Takashi Kitayama*
1375. Development of ionic liquids as solvents for lipase-catalyzed reaction.
Yoshikazu Abe, Kazuhide Yoshiyama,
Shuichi Hayase, Motoi Kawatsura,
Toshiyuki Itoh*
1376. Cooperative activation of a lipase by
the ionic liquid coating with amino acids.
Kazuhide Yoshiyama,
Sayaka Moriyama, Yoshikazu Abe,
Shuichi Hayase, Motoi Kawatsura,
Toshiyuki Itoh*
1377. Phosphorylase-catalyzed N-formyl-␣glucosaminylation of maltooligsaccharides. Satoshi Kawazoe,
Jun-ichi Kadokawa*
1378. Preparation of compounds with chiral
silicon center by enzymatic reactions.
Rumi Marui, Kazuki Nishimoto,
Toru Yamamoto, Masakazu Mihara,
Atsuhito Kuboki*, Susumu Ohira
1379. Biotransformation of the biological active compounds using plant cultured
cells. Hiroki Hamada,
Ryohei Yamamoto, Takahiro Ohara,
Hiroya Imai, Megumi Kitagawa,
Hirotaka Hirano
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–135
04-ORGN
1380. Purification and characterization of
three ␣-keto ester reductases from Streptomyces avermitilis: An approach based
on protein chemistry and bioinformatics.
Kohji Ishihara*, Momoko Yoshida,
Mika Morishita, Natsumi Ikeda,
Miyuki Nishi, Michiru Noguchi,
Aya Murata, Hitomi Yamaguchi,
Nobuyoshi Nakajima
1381. Purification and characterization of reductases with excellent enantioselectivity
from Geotrichum candidum. Chen Cao*,
Yasuo Nakata*, Takuro Fukae*,
Shuji Kanamaru, Tomoko Matsuda
1382. Protein engineering of arylmalonate
decarboxylase G74C, a cofactor-independent racemase. Robert Kourist,
Daisuke Uemura, Kenji Miyamoto*
1383. Study of enzymatic reaction and protein structure under microwave irradiation. Yuta Toriuchi, Karei Sai,
Seigo Kimoto, Daisuke Wakino,
Takeo Yoshimura, Shokichi Ohuchi*
1384. Structure-guided site-directed mutagenesis of arylmalonate decarboxylase.
Yusuke Miyauchi, Daisuke Uemura*,
Kenji Miyamoto
1385. CO2 fixation with acetyl-CoA carboxylases under high-pressure CO2.
Taisuke Abe, Yoshihisa Asanuma,
Tomoko Matsuda*
1386. Method to alter enzyme thermostability using support vector machines
(SVMs). Hitomi Tsubamoto,
Masahiro Yokota, Soichiro Okuzawa,
Yasubumi Sakakibara, Kenji Miyamoto*,
Daisuke Uemura
1387. Enhanced activity of lipase-catalyzed
esterification of fatty acids esters by using chiral ionic liquid-coated Candida
rugosa lipase.
Mohd Basyaruddin Abdul Rahman*,
Khairulazhar Jumbri, Mahiran Basri,
Emilia Abdulmalek, Bimo Ario Tejo,
Abu Bakar Salleh,
Raja Noor Zaliha Abdul Rahman
1388. Micorowave-assisted multicomponent
reaction for ␣-aminoketones as a precursor of ephedrine analogs.
Tsutomu Inokuchi, Li-Jian Ma, Yu Zhang
1389. Overexpression of malate dehydrogenase for development of carbon dioxide
fixation reaction. Yoshihisa Asanuma*,
Taisuke Abe, Tomoko Matsuda
1390. Switching from an esterase to a hydroxynitrile lyase mechanism requires
only two amino acid substitutions.
Romas Kazlauskas*
1391. Crystal structure of D-tagatose
3-epimerase Cys66Ser from Pseudomonas cichorii. Yasuhiro Tahara,
Tomohiko Ishii, Hiromi Yoshida,
Sigehiro Kamitori, Ken Izumori
1392. Approaches to new chiral building
blocks by means of Bacillus subtilis epoxide hydrolase. Ken-ichi Shimizu,
Maki Sakamoto, Toshinori Higashi,
Mitsuru Shoji, Takeshi Sugai*
1393. Kinetic resolution of primary alcohols
by using immobilized lipases on ionic liquid-coated inorganic support.
Akihiko Yoshida, Ai Murakami,
Tadashi Ema, Takashi Sakai*
1394. Study on hydrolase-catalyzed preparation of 2,2-disubstituted cyanoacetates,
and malonates. Toru Kurihara,
Yuki Tatsumi, Toshinori Higashi,
Mitsuru Shoji, Takeshi Sugai*
1395. Enzymatic preparation of ␣-methylene-␥-butyrolactones from tulip tissues
with a novel tuliposide-converting enzyme. Yasuo Kato*, Taiji Nomura,
Shinjiro Ogita
1396. Synthesis of both enantiomers of
␥-dodecalactone via enzymatic hydrolysis of 1,2-diol monotosylate derivatives.
Kazumasa Usuda, Hirokazu Okabe,
Yasutaka Shimada,
Kazutsugu Matsumoto*
1397. Deracemization of 1,2-diol monotosylate derivatives by a combination of enzymatic hydrolysis with the Mitsunobu inversion. Hirokazu Okabe,
Kazumasa Usuda, Yasutaka Shimada,
Kazutsugu Matsumoto*
136 –TECH
TECHNICAL PROGRAM
1398. Asymmetric domino reaction by an esterase from sulfolobus tokodaii strain 7.
Takashi Kumon, Reina Wada,
Kenji Miyamoto*, Daisuke Uemura
1399. Additive effect of phosphate buffer as
cosolvent for efficient kinetic resolution of
1,1,1-trifluoro-2-alkanol by lipase-catalyzed reaction in an ionic liquid solvent
system. Yumiko Takagi*,
Yuuki Yamashita, Toshiyuki Itoh
1400. Lipase-catalyzed dynamic kinetic resolution for the synthesis of optically active
cyanohydrins. Takashi Sakai*,
KeFei Wang, Toshinobu Korenaga,
Tadashi Ema
Convention Center
Kamehameha Halls II and III
Achieving Efficiency in Organic Reactions
via Greener Processes and Practices (#139)
Organized by: I. Ryu, D. Curran,
P. Jessop, S. Lee
Presiding: D. Curran
Poster Session
19:00 – 21:00
1401. Iron salt-catalyzed cascade type onepot double alkylation of indole with vinyl
ketones. Shin-ichiro Matsui,
Jun-ka Kobayashi, Shuichi Hayase,
Motoi Kawatsura, Toshiyuki Itoh*
1402. Asymmetric intramolecular conjugate
addition via short-lived C-O axially chiral
enolate. Keisuke Tomohara,
Tomoyuki Yoshimura, Takeo Kawabata*
1403. Direct asymmetric aldol reaction in
brine with recyclable fluorous sulfonamide organocatalyst. Tsuyoshi Miura*,
Kie Imai, Mariko Ina, Norihiro Tada,
Nobuyuki Imai, Akichika Itoh
1404. Palladium-catalyzed tandem ␥-arylation and aromatization of 2-cyclohexen1-one as an alternative to para-C-H arylation of phenol. Tatsushi Imahori*,
Toru Tokuda, Tatsuya Taguchi,
Hiroki Takahata
1405. Oxidative coupling reaction of aminobenzenes with olefins catalyzed by Pd(II) /
HPMoV / O2 system. Yohei Mizuta,
Yosuke Shimizu, Yasushi Obora*,
Yasutaka Ishii*
1406. Selective synthesis of 2-mercaptonicotinates and chlorine gas free synthesis
of isothiazolopyridin-3-ones.
Masao Shimizu*, Yusuke Higuchi,
Takeo Konakahara
1407. Oxidation reaction for the [4⫹2] cycloadducts of selenoketones with cyclopentadiene by MCPBA and chloramine T.
Toshiki Kenmochi, Hajime Maeda*,
Masahito Segi*
1408. anti-Markovnikov hydroamination of
arylacetylenes catalyzed by 8-quinolinolato rhodium complexes.
Sakai Kazunori, Takuya Kochi,
Fumitoshi Kakiuchi*
1409. Synthesis of fluorous crown ethers
and their application to fluorous biphase
organic reaction. Kenji Koike,
Takashi Yamanoi*, Yoshiki Oda,
Akihiro Yoshida, Mikio Watanabe
1410. Intermolecular aerobic oxidative amination of alkenes with amines catalyzed
by the Pd/NPMoV/O2 system.
Yasushi Obora*, Yosuke Shimizu,
Yasutaka Ishii*
1411. Surfactant-free synthesis of sub-nanometer-sized transition-metal nanoclusters
and their use in catalysis.
Megumi Hyotanishi, Hiroko Yamamoto,
Hideya Kawasaki*, Yasushi Obora*
1412. NbCl3-catalyzed [2⫹2⫹2] three-component cycloaddition reaction of terminal
alkynes, internal alkynes and alkenes
leading to tetrasubstituted-1,3-cyclohexadienes. Yasushi Satoh,
Yasushi Obora*
1413. Research of synthesis of nitazoxanide.
Dishun Zhao*, Bin Lv, Erhong Duan,
Juan Zhang
1414. Cascade radical iodoperfluoroalkylation for the synthesis of organofluorine
compounds. Hideto Miyabe*,
Eito Yoshioka, Shigeru Kohtani
1415. Synthesis of 3-formylfurans and diformylpyrans from acetals with aldehydes
using Lewis acid as a key catalyst.
Norihide Horikawa, Ken-ichi Tamaso,
Yasushi Obora*, Yasutaka Ishii*
1416. Lanthanum metal-assisted coupling
reaction of diaryl ketone with dialkyl ketone under carbon dioxide.
Yutaka Nishiyama*, Ryoma Narishige,
Rui Umeda
1417. Reductive dehalogenation of gem-dihaloalkenes with lanthanum metal.
Namika Anahara, Takumi Yuasa,
Rui Umeda, Yutaka Nishiyama
1418. Environmentally benign synthesis of
furans and pyrroles using cationic gold(I)
catalysts. Masahiro Egi, Kenji Azechi,
Shuji Akai*
1419. Synthesis of cyclic carbonates: Lanthanum metal compound-catalyzed reaction of epoxides with carbon dioxide.
Yuya Komaki, Rui Umeda,
Yutaka Nishiyama*
1420. Iridium complex catalyzed Guerbet reaction of ␣,␻-diols. Yuka Anno,
Yasushi Obora*, Yasutaka Ishii*
1421. Sustainable catalysis by using supported palladium nanoparticles on ionic
nanomaterials. Ju Yeon Shin,
Sang-gi Lee*
1422. ␣-Alkylation of acetonitrile with alcohols by iridium complex.
Takuya Sawaguchi, Yasushi Obora*
1423. Liposomal uptake of dansylated fluoroalkyl glycoside. Ruriko Katayama,
Shinya Nakano,
Maria Carmelita Z. Kasuya,
Kenichi Hatanaka
1424. Synthesis of ␣-sialosides under microfluidic conditions. Yosuke Uchinashi,
Katsunori Tanaka, Koichi Fukase
1425. Cross-coupling of two aryl halides in
flow microreactor systems: Space integration of halogen-lithium exchange and
Murahashi coupling. Aiichiro Nagaki,
Akira Kenmoku, Yuya Moriwaki,
Atsushi Hayashi, Jun-ichi Yoshida*
1426. Tandem synthesis of ␥-butyrolactone
by using the Blaise reaction intermediate.
Young Ok Ko, Sang-gi Lee*
1427. Mechanistic study on 7-endo selective
radical cyclzation toward efficient synthsis of 2-benzazepines. Yuriko Ishihara,
Akio Kamimura*
1428. Effective synthesis of fluorous-FMOC
reagents and application to fluorous mixture synthesis of biological active peptides. Yuya Sugiyama, Yuki Kurata,
Atsushi Miyazaki, Takayuki Shioiri,
Masato Matsugi*
1429. Synthesis and RCM reactions using
recyclable Grubbs-Hoveyda catalyst activated by a light-fluorous tag.
Yuki Kobayashi, Naoki Suzumura,
Takayuki Shioiri, Masato Matsugi*
1430. Reaction kinetics of D-xylose in high
temperature water. Taku M. Aida*,
Naohiro Shiraishi, Masaki Kubo,
Akira Ikarashi, Takuji Yamagata,
Masaru Watanabe, Richard L. Smith
1431. Total synthesis of cucurbitoside-type
phenolic glycosides by fluorous mixture
synthesis. Masaru Kojima*,
Yutaka Nakamura, Kazuki Komori,
Seiji Takeuchi
1432. One-pot synthesis of 5-hydroxy-(␣aminomethylene)benzofuran-2(3H)-ones
via tandem Blaise-Nenitzescu type reaction. Yu Sung Chun, Sang-gi Lee
1433. Application of a continuous microflow
system to radical multi-component reactions. Akira Fusano,
Takahide Fukuyama, Ilhyong Ryu*
1434. Sequential reaction of arynes via insertion into the amides and trapping reaction
with dialkylzincs. Eito Yoshioka,
Shigeru Kohtani, Hideto Miyabe*
1435. Rhodium-catalyzed synthesis of enol
ethers by anti-Markovnikov addition of alcohols to terminal arylacetylenes.
Masataka Kondo, Takuya Kochi,
Fumitoshi Kakiuchi*
1436. Oligosaccharide synthesis by using
fluorous tagging method. Kohtaro Goto*,
Nuermaimaiti Nueramina, Junki Gonsho,
Yuhsuke Kumazaki, Shunsuke Kitazawa,
Yuriko Hirose, Mamoru Mizuno
1437. New cyclopropanation via radical-anion process of nitroalkanes.
Hideki Matsu, Ryota Takeuchi,
Takayuki Yoshida, Ayako Kadowaki,
Akio Kamimura*
1438. Koch-Haaf reaction using a hastelloymade microreactor. Yu Mukai*,
Takahide Fukuyama, Ilhyong Ryu
1439. One-pot synthesis of substituted 1,4dienes via the consecutive radical-mediated bromoallylation of alkynes and Pdcatalyzed cross-coupling reactions.
Takashi Kippo*, Takahide Fukuyama,
Ilhyong Ryu
1440. Efficient recycling of osmium catalyst
in oxidative olefin cleavage reaction
through chemoentrapment approach.
Byeong Moon Kim, Seyoung Kim,
Jooyoung Chung
1441. Novel synthesis of 2,4-diiodoquinoline
derivatives by the photoinduced reaction
of o-alkynylaryl isocyanides with iodine.
Takenori Mitamura, Akiya Ogawa*
1442. Tin-free radical coupling addition to
alkenes. Mami Tojino, Mamoru Mizuno
1443. Water-soluble catalytic system for
supportless recycling of ligand and osmium in asymmetric dihydroxylation.
Seyoung Kim*, Daewon Lee,
Byeong Moon Kim
1444. Application of porimerized BINAP ligand to Buchwald-Hartwig amination.
Aoi Ishibashi, Toshiyuki Kamei*,
Yoshinori Takamatsu, Hiroyuki Hosoi,
Toyoshi Shimada*
1445. Chemoselective intramolecular alkylative trapping of the Blaise reaction intermediate. Ju Hyun Kim, Sang-gi Lee*
1446. Nitroxide-mediated radical polymerization of methyl methacrylate using a microflow reactor. Yoshito Kajihara*,
Takahide Fukuyama, Ilhyong Ryu,
Armido Studer
1447. Solvent-free Horner-Wadsworth-Emmons reaction using DBU. Kaori Ando,
Kyohei Yamada*
1448. Crossed Ti-Claisen condensation between ␣,␣-disubstituted thioesters and
N-acylbenzotriazoles giving less accessible ␣,␣-disubstituted ␤-keto thioesters.
Misaki Kobayashi, Kenji Hozumi,
Ryohei Nagase, Yoo Tanabe
1449. Construction of three consective
asymmetric centers utilizing Ti-ClaisenAldol domino reaction.
Yoshikazu Masuyama,
Syogo Nakazawa, Akihiro Tanaka,
Ryohei Nagase, Yoo Tanabe
1450. Fluorous surface-active distannoxane
catalyst: C-C bond formation by miscibility-tunable cationic fluorous distannoxane. Akihiro Orita*, Shoko Tanabe,
Tatsuhiko Ono, Junzo Otera
1451. Diastereoselective [2⫹2] photocycloaddition of chiral cyclic enone and cyclopentene using a microflow reactor
system. Kimitada Terao, Ken Tsutsumi,
Hiroki Yamaguchi, Syogo Yoshimura,
Yasuhiro Nishiyama, Tsumoru Morimoto,
Kiyomi Kakiuchi*, Takahide Fukuyama,
Ilhyong Ryu*
1452. Copper-free Sonogashira coupling reaction using rigid trans-coordinatable bidentate ligand. Shingo Atobe,
Motohiro Sonoda, Akiya Ogawa
1453. Iodoamidation of olefins with chloramine salts and I2 in aqueous media.
Satoshi Minakata*, Junpei Hayakawa
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
1454. Synthetic study on glycosylated fluorous gold nanoparticles. Yoichi Fujita,
Taichi Nagasaki, Toshiyuki Inazu*
1455. 18F-ApoPep-1: a PET imaging probe
for chemotherapy-induced apoptosis of
tumor cells. Byoung Se Lee,
Woon Jung Jung, Hyun Ju Sung,
Sang Don Park, Sang Ju Lee,
Seung Jun Oh, Dae Yoon Chi*
1456. Synthesis of five-membered ring seleno sugar derivatives (selenofuranose) via
cycloaddition reaction of selenoaldehydes and ring contraction reaction.
Makoto Torihata, Hajime Maeda*,
Masahito Segi*
1457. Preparation of pentavalent six-membered cyclic phosphorus compound having two selenium atoms and evaluation as
a selenating reagent. Kouhei Sakata,
Hajime Maeda*, Masahito Segi*
1458. Optical resolution by fluorous biphasic
system. Masahito Kawashima,
Takayuki Suzuki, Yuko Ishii,
Toshiyuki Inazu*
1459. Continuous microflow synthesis using
fluorous method. Hiroko Kawakami,
Mamoru Mizuno
1460. Synthesis of 1,2-benzisothiazolin-3one derivatives from 1,3-benzoxathiin-4ones. Masao Shimizu*, Tetsuya Yoshida,
Teruaki Shimazaki, Wataru Ando,
Takeo Konakahara
Convention Center
Kamehameha Halls II and III
Boronic Acids: Synthetic and Biological
Applications (#199)
Organized by: B. Wang, P. Duggan,
D. Hall, M. Suginome
Presiding: B. Singaram
Poster Session
19:00 – 21:00
1461. Diastereoselective 1,2-addition of arylboronic acids to Garner’s aledehyde using palladium/thioether-imidazolinium
chloride system. Terumichi Enomoto,
Masami Kuriyama*, Ryuichi Shirai*
1462. Synthesis and biological evaluation of
1,2-diphenylcarboranes as HIF-1␣ inhibitors. Lisa Tazaki*
1463. Synthesis and liposome formation of
dodecaborate-coniugated cholesterols
for efficient boron delivery system on
neutron capture therapy.
Tatsuro Miyoshi, Hyun Seung Ban,
Hiroyuki Nakamura*
1464. Cu(I)-catalyzed regio- and enantioselective monoborylation of 1,3-dienes.
Yusuke Sasaki, Hajime Ito*,
Masaya Sawamura
1465. Development of closo-dodecaborates
for liposomal boron delivery of neutron
capture therapy. Shoji Tachikawa*,
Hiroyuki Nakamura
1466. Palladium-imidazolinium carbene-catalyzed arylation of aldehydes with arylboronic acids in water. Masami Kuriyama*,
Natsuki Ishiyama, Rumiko Shimazawa,
Osamu Onomura*
1467. Discovery of carborane-conjugated
triazines as topoisomerase inhibitors.
Ayano Takeuchi*, Atsushi Shoji,
Hyun Seung Ban, Takao Yamori,
Hiroyuki Nakamura
1468. Preparation of novel phenylboronic
acid containing polymer for sugar recognition. Inami Yuki, Taka-Aki Asoh,
Akihiko Kikuchi*
1469. Discovery of carboranes as 20S proteasome activators.
Hidemitsu Minegishi,
Minako Maruyama, Yuka Yasui,
Kazuki Shimizu, Hyun Seung Ban,
Hiroyuki Nakamura*
1470. Stereoselective synthesis of ␤-borylallylsilanes via palladium-catalyzed stereocomplementary isomerization of double
bond. Toshimichi Ohmura*,
Kazuyuki Oshima, Michinori Suginome*
1471. Cobalt-catalyzed highly regioselective
annulations of o-(methoxycarbonyl)phenylboronic acid with functionalized
alkynes via fine tuning of ligands.
Pao-Shun Lin*, Chien-Hong Cheng
1472. Synthesis of sterically bulky amido-Nimidazolium salts and their application as
the ligands in the Suzuki-Miyaura coupling reactions of heteroaromatic halides
and the synthesis of Milrinone and Irbesartan. Rajeshkumar Manian,
Sunwoo Lee*
1473. Preparation of borylbenzynes under
mild conditions and their regioselective
Diels-Alder reactions. Akira Takagi,
Takashi Ikawa, Shuji Akai*
Convention Center
Kamehameha Halls II and III
Recent Advances in Natural Products as
Anticancer Agents (#279)
Organized by: D. Kingston, J. Liu,
S. Matsunaga, R. Quinn
Presiding: D. Kingston, S. Matsunaga,
R. Quinn, J. Liu
Poster Session
19:00 – 21:00
1474. Chemical constituents from Fissistigma latifolium. Yu Hsuan Lan*,
Chia chen Lin
1475. Search for bioactive compounds from
medicinal plants of Bangladesh regarding
anti-cancer properties. Ayumi Ohsaki*,
Masaaki Ozawa, Kaori Taniguchi,
Akio Kishida, Firog Ahmed,
Samir K. Sadhu, Masami Ishibashi
1476. Isolation, spectroscopic analyses,
chemical transformation and biological
evaluation of novel Gelsemium alkaloids.
Yousuke Yamada, Mariko Kitajima,
Noriyuki Kogure,
Wongseripipatana Sumphan,
Hiromitsu Takayama*
1477. Stereochemistry of bisabolane sesquiterpenes, in Ligularia lankongensis.
Rurina Miyazaki, Kana Mitsui,
Chiaki Kuroda, Hiroyuki Onuki,
Hiroshi Hirota
1478. Study of anticancer and antiprotozoa
products from tropical plants.
Kanami M. Yasumoto*, Hiromi Nochi,
Koichi Tamoto, Hiroyuki Fuchino,
Yutaka Agatsuma, Motoyoshi Satake,
Setsuko Sekita
1479. Erythrinan alkaloids from Erythrina
crista-galli with inhibitory activity on LSPinduced nitric oxide production.
Shunsuke Kawamata, Masaaki Ozawa,
Tadahiro Etoh, Masahiko Hayashi,
Kanki Komiyama, Akio Kishida,
Ayumi Ohosaki, Chiaki Kuroda
1480. Novel fluorescent compound from a
tropical medicinal plant, Qussia amara.
Kaori Taniguchi, Masaaki Ozawa,
Tsuyoshi Maruyama, Akio Kishida,
Shigeru Murata, Ayumi Ohsaki*
1481. Cytotoxic ursolic acid derivatives from
Bangladeshi medicinal plants,Surauja
roxburghii. Kishor Mazumder, Eric,
R. Siwu, Katsunori Tanaka, Koichi Fukase
1482. Iridals in Iris delavayi collected in
Hengduan Mountains of China.
Yu Hasegawa*, Chiaki Kuroda,
Xun Gong
1483. Structures and biological activities of
constituents from Erythrina velutina.
Masaaki Ozawa, Tadahiro Etoh,
Masahiko Hayashi, Kazuki Honda,
Kanki Komiyama, Akio Kishida,
Ayumi Ohsaki*
1484. Structure analysis of steroid glycoside
from Ornithogalum saundersiae.
Takuro Fukumoto*, Keiichi Noguchu,
Masafumi Yohda, Kaori Sakurai
1485. Search for cytotoxic compounds from
Tilia kiusiana. Marie Shimada,
Masaaki Ozawa, Kojiro Iwamoto,
Akio Kishida, Ayumi Ohsaki*
1486. Anticancer activity and SAR studies of
largazole. Yanxia Liu*,
Lilibeth A. Salvador, Seong Rim Byeon,
Yongcheng Ying, Jason C. Kwan,
Jiyong Hong, Hendrik Luesch
1487. Cancer chemopreventive potential of
marine-derived phenazines.
Laura Marler*, John M. Pezzuto,
Ratnakar N. Asolkar, William Fenical,
Martin Conda-Sheridan, Mark Cushman
1488. Cathepsin B inhibitors from a Japanese marine sponge. Yasufumi Imae,
Shuhei Murayama, Shigeru Okada,
Shigeki Matsunaga*
1489. Cytotoxic cembranoid diterpenes from
Indonesian specimens of the soft coral
Nephthea sp. Indra H. Januar,
Ekowati Chasanah, Dianne M. Tapiolas,
Cherie A. Motti, Anthony D. Wright*
1490. Cell differentiation inducers from a
marine sponge Biemna sp. Reiko Ueoka,
Yuji Ise, Shigeru Okada,
Shigeki Matsunaga
1491. Pyrrospirones and pyrrocidines, cytotoxic alkaloids from an endophytic fungus, Neonectria ramulariae Wollenw KS246. Yoshihito Shiono*,
Azusa Kosukegawa, Takuya Koseki,
Tetsuya Murayama, Nozomi Fujisawa,
Ken-ichi Kimura
1492. Plant-derived endophytes from Australian medicinal plants: Producers of
novel bioactive secondary metabolites.
Yvonne Fazendin*, Kieran Lim
1493. Tryptopeptin A, a novel TGF-␤ signaling inhibitor from Streptomyces sp.
Yuta Tsunematsu, Shinya Oishi,
Nobutaka Fujii, Shinichi Nishimura,
Akira Hattori, Hideaki Kakeya*
1494. Toward the total synthesis of the chivosazoles. S. B. Jennifer Kan,
Lisa Gibson, Ian Paterson*
1495. Synthesis of fluorescently labelled analogs of antitumor saponin OSW-1.
Noriyuki Sato, Takuro Fukumoto,
Kaori Sakurai
1496. Synthetic studies toward the aplyronines, potent anticancer marine macrolides
isolated from Aplysia kurodai .
Sarah J. Fink*, Lydia Y. Lee,
Ian Paterson
1497. Corosolic acid inhibits glioblastoma
cell proliferation by suppressing the activation of signal transducer and activator
of transcription-3 (Stat3) in tumor cells
and tumor-associated macrophages.
Yukio Fujiwara*, Yoshihiro Komohara,
Tsuyoshi Ikeda, Motohiro Takeya
1498. Anticancer and antimicrobial evaluation of marine macro- and micro-organism extracts collected from Indonesian
waters. Ekowati Chasanah,
Indra H. Januar, Dianne M. Tapiolas,
Cherie A. Motti, Catherine H. Liptrot,
Anthony D. Wright*
Convention Center
Kamehameha Halls II and III
Transition Metal Catalysis: Mechanism and
Practice (#283)
Organized by: K. Nozaki, J. Stryker,
F.D. Toste
Presiding: K. Nozaki
Poster Session
19:00 – 21:00
1499. Synthesis of palladium complex bearing abnormal NHC ligand and application
to cross coupling reaction.
Tatsuhito Nakamura, Kenichi Ogata,
Shin-ichi Fukuzawa*
1500. Gold-catalyzed dehydration of alcohols. Yohei Seya, Kazuteru Umetsu,
Naoki Asao
1501. Synthesis of 2-substituted indoles
through one-pot Pd catalyzed reaction.
Haruo Yamada*, Hajime Nagao
1502. Construction of indoles by coppercatalyzed cyclization of ortho-substituted
aryl isocyanide. Mamoru Tobisu,
Keika Koh, Hirokazu Fujihara,
Naoto Chatani*
1503. “Stereoelectronic effect” as a reaction
control factor in ruthenium carbene metathesis.
Sheikh Mohammad Abdul H. Siddiki,
Takashi Sugimura*
1504. Solution behavior of chiral ␩6-arene/
N-tosylethylenediamine-ruthenium complexes: key to efficient asymmetric hydrogenation. Aki Matsuoka, Fusheng Bie,
Yoshiki Yamaguchi, Yuehui Li,
Koichi Kato, Noriyuki Utsumi,
Kunihiko Tsutsumi, Takeshi Ohkuma,
Kunihiko Nurata, Hiroshi Naka,
Christian A. Sandoval, Ryoji Noyori
1505. Development of salen Ti(III) complex
catalyzed radical cyclization.
Haruo Yamada*, Yuichiro Munemoto
1506. Synthesis of isoxazoles by a transition
metal-catalyzed domino reaction of alkynyl oxime ethers. Masafumi Ueda,
Aoi Sato, Takeaki Naito, Okiko Miyata*
1507. Why did incorporation of acrylonitrile
to a linear polyethylene become possible? Comparison of phosphine-sulfonate
ligand with diphosphine and imine-phenolate ligands in the Pd-catalyzed
ethyelene/acrylonitrile copolymerization.
Kyoko Nozaki*, Shuhei Kusumoto,
Noda Shusuke, Kochi Takuya,
Lung W. Chung, Keiji Morokuma*
1508. Novel one-step, quimioselective conversion of acetals into silyl ethers catalyzed by aluminium trichloride.
Julian Bergueiro*, Javier Montenegro,
Susana Lopez
1509. Nickel-catalyzed ring-opening threecomponenet coupling of methylenecyclopropanes with aldehydes and silanes.
Yuka Atsuumi, Ogata Kenichi*,
Fukuzawa Shin-ichi*
1510. Rhenium-catalyzed benzannulation of
o-alkynylbenzaldehyde with alkyne.
Kenta Kaiba, Rui Umeda,
Yutaka Nishiyama*
1511. Pd-catalyzed Negishi alkyl-aryl crosscoupling using (o-methoxyphenyl)diphenylphosphine as a ligand.
Yugo Nishimura, Shunsuke Odo,
Yasushi Nishihara, Kentaro Takagi*
1512. Cross-coupling reactions of alkynylsilanes with aryl iodides catalyzed by
Cu(I) salt under neutral condition.
Shitaro Noyori, Arisa Yamamoto,
Eiji Inoue, Kentaro Takagi,
Yasushi Nishihara*
1513. Metal transition catalyzed borylative
cyclization reactions of polyunsaturated
compounds. Virtudes Pardo-Rodríguez,
Ruth López-Durán, Elena Buñuel,
Diego Jesús Cárdenas*
1514. Synthesis and catalytic activity of
novel xantphos-Ru complexes for addition of carboxylic acids onto olefins.
Yohei Oe*, Shoko Higashi,
Hiroto Takenaka, Tetsuo Ohta,
Yoshihiko Ito
1515. Rhodium-catalyzed [4 ⫹ 2] carbocyclization of 2-alkynylbenzaldehydes with
alkynes. Daiki Hojo*, Ken Tanaka
1516. Rhodium-catalyzed multicascade reactions of dienynes to produce substituted dihydronaphthalenes. Eri Okazaki,
Ken Tanaka*
1517. Withdrawn
1518. Iron-catalyzed synthetically efficient
epoxidation of olefins with hydrogen peroxide assisted by pyridine systems.
Mingyu Jiao*, Hirofumi Matsunaga,
Tadao Ishizuka
1519. Rhodium(I)-catalyzed cyclocarbonylation reaction of enynes with sugars.
Tsumoru Morimoto*, Keiichi Ikeda,
Kiyomi Kakiuchi
1520. Thermodynamic equilibration in Pd(0)catalyzed interconversion of highly constrained [2.1.2] bicyclic lactones: Its
mechanistic investigation.
Young Taek Han, Seung-Mann Paek,
Young-Ger Suh*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–137
04-ORGN
1521. CuI catalyzed C-C and C-O coupling
reactions using hydrazone ligands.
Fumitoshi Yagishita, Takashi Mino*,
Masanori Shibuya, Masami Sakamoto,
Tsutomu Fujita
1522. Synthesis and application of atropisomeric dihydrobenzofuran-based bisphosphine (BICMAP). Takashi Mino*,
Masatoshi Hashimoto, Yoshiaki Naruse,
Shohei Kobayashi, Masami Sakamoto,
Tsutomu Fujita
1523. Palladium-catalyzed synthesis of complex heterocycles. Igor Dubovyk,
Andrei K. Yudin*
1524. Facile synthesis of substituted dibenziodolium salts and their palladium-catalyzed transformation to carbazoles.
Tania Welsch, Bernhard Witulski*
1525. Palladium-catalyzed vinylselenation of
allenes. Maiko Okuyama*,
Susumu Tsuda, Shin-ichi Fujiwara,
Takanori Iwasaki, Hitoshi Kuniyasu,
Nobuaki Kambe
1526. Stereoselective construction of substituted chromans by palladium-catalyzed
cyclization of propargylic carbonates with
2-(2-hydroxyphenyl)acetates.
Masahiro Yoshida*, Mariko Higuchi,
Kozo Shishido
1527. Nickel-catalyzed Suzuki-Miyaura coupling of epoxides. Daniel K. Nielsen,
Abigail G. Doyle*
1528. Convenient synthesis of triphenylenes
by rhodium-catalyzed [2 ⫹ 2 ⫹ 2] cycloaddition. Yayoi Sawada, Ken Tanaka*
1529. Photoinduced oxidative coupling reaction catalyzed by [Ru(bpy)3]2⫹.
Takashi Koike*, Munetaka Akita*
1530. Synthesis of 1,3-diarylpropene by palladium-catalyzed C-C bond formation using hydrazone ligands. Kiminori Hirai,
Takashi Mino*, Tomoko Koizumi,
Kenji Kajiwara, Masami Sakamoto,
Tsutomu Fujita
1531. Pd/light induced radical multi-component reactions. Akira Fusano,
Shuhei Sumino, Takahide Fukuyama,
Ilhyong Ryu*
1532. Palladium-catalyzed oxidative C-H
functionalization of alkenes.
Juhanes Aydin, Nicklas Selander,
Kálmán Szabó*, Johanna Larsson
1533. Monovalent nickel complex bearing
bulky N-heterocyclic carbene catalyzed
Kumada cross-coupling reactions.
Shinya Nagao, Yuji Koga,
Kouki Matsubara
1534. Synthesis of monocyclic compounds
by the nickel-catalyzed [4⫹3⫹2] cycloaddition. Korehito Kato, Ryu Yamasaki,
Shinichi Saito*
1535. Rhodium-catalyzed [3 ⫹ 2] and [2 ⫹ 1]
cycloadditions of propargyl esters with
electron-deficient alkynes and alkenes.
Yu Shibata, Ken Tanaka*
1536. Manganese-catalyzed regioselective
synthesis of tetrasubstituted benzenes
from ␤-keto esters and terminal alkynes.
Mitsumi Nishi*, Salprima S. Yudha,
Yoichiro Kuninobu, Kazuhiko Takai
1537. Nickel-catalyzed Tishchenko reaction
via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex. Yoichi Hoshimoto,
Sensuke Ogoshi*
1538. Improved precursor for palladium(0)
cross-coupling catalysts.
Michael C. Baird*, Andrew W. Fraser,
Laura E. Hull
1539. Platinum-catalyzed cascade cyclization-ring expansion reaction of propargylic aziridines. Yoshida Masahiro*,
Yohei Maeyama, Mohammad Al-Amin,
Shishido Kozo
1540. Synthesis of silole derivatives via the
rhodium-catalyzed carbon-silicon bond
cleavage. Mamoru Tobisu,
Masahiro Onoe, Naoto Chatani*
1541. Nickel-catalyzed [4⫹2] cycloaddition
of enones with alkynes.
Takuya Kurahashi*, Seijiro Matsubara*
1542. Alkenylative cross-coupling reaction of
alkyl aryl sulfide under Ni-SIPr catalysis.
Kentaro Ishizuka, Satoaki Onitsuka,
Hirofumi Seike, Takuji Hatakeyama,
Junji Inanaga, Masaharu Nakamura*
138 –TECH
TECHNICAL PROGRAM
1543. Gold-catalyzed cyclization of (prop-2ynyloxy)benzaldehydes as an expedient
route to (Z)-benzo[b]oxepin-3(2H)-ones.
Ella M. Sze*, Weidong Rao,
Ming Joo Koh, Philip W. Chan
1544. Studies on the palladium-catalyzed
construction of the aryl allyl ethers.
Hisataka Kobayashi,
Makoto Kanematsu, Masahiro Yoshida,
Kozo Shishido*
1545. Rhodium⫺catalyzed cross⫺coupling
of vinyl ethers with Grignard reagents.
Yoshinori Miyata, Yuuki Fujii,
Takanori Iwasaki, Hitoshi Kuniyasu,
Nobuaki Kambe*
1546. Evaluation of relative ⌬G of the oxidative addition of benzoyl halides to platinum(0) utilizing ligand exchange reaction.
Daisuke Nakane, Hitoshi Kuniyasu*,
Nobuaki Kambe
1547. Chemoselective and regiospecific Suzuki-Miyaura cross coupling reaction of
1,1-organodiboronates at room temperature. Takahiro Ookubo, Kohei Endo,
Takanori Shibata
1548. Gold-catalyzed reactions of pyridine
N-oxides having alkyne moieties leading
to N-heterocycles. Sachie Kitabata,
Masahito Murai, Kazuhiro Okamoto,
Kouichi Ohe
1549. Stereoselective control by face-toface vs edge-to-face aromatic interactions: The case of C3-Ti(IV) amino trialkolate sulfoxidation catalysts.
Gabriella Santoni, Miriam Mba,
Marcella Bonchio, William A. Nugent,
Cristiano Zonta, Giulia Licini*
1550. SNAr reaction of nonactivated fluoroarenes using ruthenium catalysts.
Hiroya Yokoyama, Takanori Shibata,
Kohei Endo, Maiko Otsuka
1551. Bromide transfer reactions catalyzed
by molybdenum hexacarbonyl.
Takumichi Sugihara*,
Yasuko Tomizawa, Yuji Shimizu,
Yu Kainuma, Tatsuro Kobayashi,
Yuta Takamura
1552. Use of bulky phosphine ligands in the
palladium-catalyzed synthesis of brominated heterocycles. Stephen Newman,
Mark Lautens*
1553. Nickel catalyzed codimerization of
acrylic acid derivatives and alkynes.
Hiroaki Horie, Ichiro Koyama,
Takuya Kurahashi*, Seijiro Matsubara*
1554. N-Heterocyclic carbene ligands bearing ethylene glycol chains: Effects of
chain length in palladium-catalyzed Suzuki-Miyaura coupling reaction.
Takahiro Yoshikawa, Hidetoshi Ohta,
Tetsuaki Fujihara, Jun Terao,
Yasushi Tsuji*
1555. Synthesis and photophysical property
of 1,2-diarylbenzosiloles.
Mamoru Tobisu, Katsuaki Baba,
Masahiro Onoe, Naoto Chatani*
1556. Development of a bowl-shaped pyridine ligand and its applications in catalysis. Yuichirou Horimoto, Tinghua Xu,
Kazuhiko Semba, Tetsuaki Fujihara,
Jun Terao, Yasushi Tsuji*
1557. Rhodium-catalyzed borylation of nitriles. Mamoru Tobisu, Hirotaka Kinuta,
Yusuke Kita, Naoto Chatani*
1558. Ruthenium metathesis catalysts with
sulfonate and phosphonate ligands.
Peili Teo, Robert H. Grubbs
1559. Hydrosilylation of sterically congested
ketones using a copper catalyst bearing a
bowl-shaped phosphine.
Kazuhiko Semba, Tetsuaki Fujihara,
Jun Terao, Yasushi Tsuji*
1560. Beayer-Villiger type rearrangement
promoted by bivalent palladium.
Minoru Tamiya*, Futa Takada,
Nobuhisa Isaka, Masaji Ishiguro*
1561. Triethynylphosphine-gold(I)-catalyzed
cyclization of alkynyl silyl enol ether: Seven-membered ring formation. Hideto Ito,
Hirohisa Ohmiya, Masaya Sawamura*
1562. Origin of the minor enantiomer in
BINAP-Ru-catalyzed hydrogenation of
3-phenyl-2-butenoic acid.
Masaki Tsukamoto*,
Masahiro Yoshimura,
Yoshitaka Ishibashi, Hiroshi Nakatsuka,
Masato Kitamura*
1563. Mn(III)-catalyzed aerobic oxidation of
tetramic acid and tetronic acid derivatives. Md. A. Haque*, Hiroshi Nishino
1564. Transition-metal-catalyzed decarbonylative isomerization of N-allenylcarbamochalcogenates to 3-chalcogeno-1azadienes. Daisuke Shiro*,
Hiroyuki Nagai, Susumu Tsuda,
Shin-ichi Fujiwara, Takanori Iwasaki,
Hitoshi Kuniyasu, Nobuaki Kambe
1565. Copper-catalyzed allenylation of imines via retro-allenylation of 2,3-butadien1-ol derivatives and its application to the
synthesis of pyrrolines. Masahiro Sai,
Hideki Yorimitsu, Koichiro Oshima
1566. Highly chemoselective nickel-catalyzed three-component cross-trimerization of three distinct alkynes.
Kenichi Ogata*, Yuka Atsuumi,
Shin-ichi Fukuzawa
1567. Dehydrative allylation of alcohols and
deallylation of allyl ethers catalyzed by
[CpRu(CH3CN)3]PF6 and 2-pyridinecarboxylic acid derivatives: Effect of ␲-accepting ability and COOH acidity of ligand on reactivity. Shinji Tanaka,
Tomoaki Seki, Hiroshi Nakatsuka,
Masato Kitamura*
1568. Withdrawn
1569. Copper-catalyzed oxidative homocoupling of indoles. Yuta Nagase,
Teruhisa Tsuchimoto*
1570. Gallium-catalyzed Bromocyanation of
alkynes with cyanogen bromide.
Masahito Murai*, Ryo Hatano,
Kouichi Ohe
1571. Synthesis of medium-sized rings by
the Ni-catalyzed cycloaddition reactions.
Shinichi Saito*, Ryu Yamasaki
1572. Ironing it out: A unifying concept for
iron catalyzed cross coupling reactions.
Matthias Mayer*,
Axel Jacobi von Wangelin
1573. Heterogeneous ligand-free palladium
on carbon-catalyzed Stille coupling.
Yuki Yabe, Yuki Fujita,
Yoshinari Sawama, Tomohiro Maegawa,
Yasunari Monguchi, Hironao Sajiki*
1574. Ligand-free and heterogeneous catalytic system for Hiyama cross-coupling
reaction. Takayoshi Yanase,
Yasunari Monguchi, Hironao Sajiki*
1575. In situ time-resolved XAFS study of reaction mechanism of aryl halide homocoupling mediated by nickel complex.
Hiroyuki Asakura, Tetsuya Shishido,
Kentaro Teramura, Tsunehiro Tanaka*
1576. Iridium-catalyzed reaction of carbamoyl chlorides with internal alkynes to
prepare 2-quinolones. Tomohiro Iwai,
Tetsuaki Fujihara, Jun Terao,
Yasushi Tsuji*
1577. Ruthenium-catalyzed coupling of alkenyl triflates with heteroatom nucleophiles. Eiji Shirakawa*, Yusuke Imazaki,
Tamio Hayashi*
1578. Transition-metal-catalyzed addition of
organotellurium compounds to carboncarbon unsaturated bonds.
Shin-ichi Fujiwara*, Hiroyuki Nagai,
Nobuaki Kambe
1579. Copper-catalyzed reductive carboxylation of an alkyne using a hydrosilane
under carbon dioxide. Tetsuaki Fujihara,
Tinghua Xu, Kazuhiko Semba, Jun Terao,
Yasushi Tsuji*
1580. Development of chemoselective hydrogenation using palladium catalysts
supported on the synthetic zeolite.
Tohru Takahashi*,
Masatoshi Yoshimura, Hiroyasu Suzuka,
Yoshinari Sawama, Tomohiro Maegawa,
Yasunari Monguchi, Hironao Sajiki
Sunday Morning
Convention Center
Kamehameha Halls II and III
Organic General Posters
Poster Session
10:00 – 12:00
Methodologies, synthesis with metals and
organocatalysts
1581. Gold(I)-catalyzed addition of heteroatom-hydrogen bonds to alkynes to access enamines, pyrroles and furans.
Søren Kramer*, Julie L. Madsen,
Mario Rottländer, Troels Skrydstrup
1582. Preliminary study toward the developpement of a general gold(I)-catalyzed
6-endo-dig carbocyclization.
Francis Barabé*, Louis Barriault
1583. Supported gold nanoparticles-catalyzed one-pot synthesis of indoles and
aniline derivatives from nitroarenes under
hydrogenation condition.
Yoshihiro Yamane, Xiaohao Liu,
Akiyuki Hamasaki, Tamao Ishida,
Masatake Haruta, Takushi Yokoyama,
Makoto Tokunaga*
1584. Carbonylation reactions catalyzed by
cobalt oxide supported gold nanoparticles under syngas atmosphere.
Akiyuki Hamasaki, Xiaohao Liu,
Shingo Haraguchi, Yoshihiro Yamane,
Makoto Tokunaga*
1585. Palladium catalyzed benzylation of NBoc indole boronic acids.
Laurent Gomez*, Aaron M. Kearney,
Adrienne Landr-Bayle
1586. Reduction of organic substrates in
aqueous media using hypophosphorous
acid-palladium system. Kaori Kojima,
Makoto Oba*, Kozabro Nishiyama
1587. Palladium-catalyzed reaction of
propargylic oxiranes and phenols: Synthesis of new unsaturated alcohols via
successive nucleophilic attacks of phenols. Toshio Koizumi*, Koji Sugie
1588. Pd-catalyzed oxidation of alcohols using halobenzene under inert condition.
Minkyoung Lim, Hakjune Rhee*
1589. Kinetic resolution of P-chirogenic
compounds by palladium catalyzed alcoholysis of vinyl ethers. Hisashi Itoh,
Eiji Yamamoto, Shigeyuki Masaoka,
Ken Sakai, Makoto Tokunaga*
1590. Iron catalyzed coupling reactions of
2-bromofuran. William Tam*,
Jamie Haner
1591. Ruthenium-catalyzed [2⫹2] cycloadditions of 2-aza-3-oxabicyclo[2.2.1]hept-5enes. William Tam*, Robin Durham
1592. Asymmetric ruthenium-catalyzed
[2⫹2] cycloadditions of bicyclic alkenes.
William Tam*, Jordan Goodreid
1593. New preparation method of aldehydes
by ruthenium-catalyzed reduction of carboxylic acids with hydrosilanes.
Konoka Miyamoto, Yu-ichi Kubo,
Yukihiro Motoyama, Hideo Nagashima*
1594. Highly enantioselective hetero-DielsAlder reactions between Rawal’s diene
and aldehydes catalyzed by chiral
dirhodium(II) carboxamidates.
Yudai Watanabe, Takuya Washio,
Masahiro Anada, Shunichi Hashimoto*
1595. Copper-catalyzed sulfidations of aryl
halides using sulfur element.
Nobukazu Taniguchi
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
1596. Substitutent effects on the syntheses
of various planer-chiral [10]parapyridinophadiynes. Norihiko Sakamoto,
Nobuhiro Kanomata*
1597. Catalytic enantio- and regioselective
additions into diketones: mechanistic investigation. Torsak Luanphaisarnnont,
David A. Evans*
1598. Copper-catalyzed oxidative sulfidation
and selenidation of imidazo[1,5-a]pyridines with elemental sulfur and selenium.
Takafumi Kanai, Eiji Yamaguchi,
Fumitoshi Shibahara*, Toshiaki Murai
1599. Selenation of carbonyl compounds
with elemental selenium. Saki Kubota,
Fumitoshi Shibahara*, Toshiaki Murai
1600. Cationic iridium-catalyzed regioselective synthesis of 4-substituted benzoheteroles. Yu-ki Hashimoto,
Kyoji Tsuchikama, Kohei Endo,
Takanori Shibata*
1601. Synthesis of N-arylimides, enimides,
ynimides using polyvalent organobismuth
compounds and the application of ynimides toward click chemistry.
Takuya Sueda*, Naoki Teno
1602. Synthesis and reactions of cyclic unsaturated phosphonium salts with a
phospholene skeleton. Hua Hong,
Jugo Koketsu, Fumio Ando*
1603. Electronic effects of substituents in
sulfides: Mechanism elucidation of vanadium catalyzed sulfoxidation.
Kwang-Hyun Ahn*, Woo-Sun Lee,
Yong-Chul Jeong, Jin-A Kim
1604. AlCl3-mediated defluorinative diarylhydroxylation transformation of CF3: Chemoselective arylation of CF3 and chlorocarbonyl groups attached to aromatic
rings. Akiko Okamoto,
Kazuhiro Kumeda, Noriyuki Yonezawa*
1605. Metal-free direct biaryl coupling reaction of heteroaromatic compounds via iodonium intermediate. Koji Morimoto,
Nobutaka Yamaoka, Tomofumi Nakae,
Toshifumi Dohi, Yasuyuki Kita*
1606. Reaction of acetals and C-nucleophiles: A novel carbon-carbon bond
forming reaction via pyridinium-type
salts. Ozora Kubo, Kenzo Yahata,
Tomohiro Maegawa, Hiromichi Fujioka*
1607. Lewis acid-catalyzed direct condensation between phthalides and primary
amines to give bioactive phthalimidines.
Ichiro Takahashi*, Yuusuke Horino,
Yoshihiko Sugiura, Sho Inagaki,
Minoru Hatanaka, Shinzo Hosoi
1608. Synthesis of fluorous BINOL and its
phosphoric acid derivative.
Masaaki Omote*, Akari Ikeda,
Atsushi Tarui, Kazuyuki Sato, Akira Ando
1609. Water soluble organocatalysts for
asymmetric aldol reaction in aqueous
media. Tomoya Machinami*,
Kazuya Sekihara, Ayumi Tsutsui,
Daisuke Miura, Takashi Fujimoto
1610. Bicyclic guanidine-catalyzed direct
asymmetric allylic addition of n-aryl succinimides. Jianmin Wang,
Choon-Hong Tan
Simple synthesis, reactions, electron
transfer
1611. Synthesis of substituted 3-iodopyrroles by the cyclization of propargylic
aziridines. Masahiro Yoshida*,
Salina Easmin, Mohammad Al-Amin,
Yuuki Hirai, Kozo Shishido
1612. Pentanidium catalyzed enantioselective phase transfer reactions. Ting Ma*
1613. Synthesis and biological properties of
novel anionic surfactant, potassium acetate salt of (5-alkyl-2-methyl-1,3-thiazole)s. Akihiro Shirai*, Yasuko Fumoto,
Hideaki Maseda, Hiroki Kourai
1614. Mild deprotection of methylene acetals and application to highly regiocontrolled protection of diols.
Yutaka Minamitsuji, Kento Senami,
Ozora Kubo, Kenzo Yahata,
Tomohiro Maegawa, Hiromichi Fujioka*
1615. Rearrangements of [2.2.1]bicyclic tertiary alcohols under various conditions.
Te-Fang Yang*, Chien-Hung Shen,
Li-Hsun Chen, Li-Ta Kao,
Chih-Hsiang Chuang
1616. Nucleophilic deoxofluorination of catechols. Hiroyuki Nemoto,
Tsuyoshi Nishiyama, Shuji Akai*
1617. Reactions of ethyl allyl- and propargylacetoacetate with thiourea: Products and
conditions. Anton E. Nikolaev*,
Vyacheslav E. Semenov,
Dilyara R. Sharafutdinova,
Vladimir S. Reznik
1618. Stereoselective synthesis of 2-substituted-3-aminopiperidine derivatives via
aza-Michael reaction. Takeshi Noda*,
Takuya Shimogaki, Asuka Usui,
Aya Saito
1619. One-pot synthesis of highly functionalized morphans from C-glycosides.
Wei Zou, Kannan Vembaiyan,
MIlan Bhasin, Dean Williams
1620. New developments on the 1,2,3-dithiazole ylidene chemistry.
Heraklidia Ioannidou,
Panayiotis A. Koutentis*
1621. New synthetic method for versatile
chiral synthon of 1,2-diamines using oxidation of 2-imidazolone. Iori Eshita,
Hirofumi Matsunaga, Tadao Ishizuka
1622. Sulfonylation-induced N- to O-acetyl
migration in 2-acetamidoethanol derivatives. Takao Yamaguchi, Dusan Hesek,
Mijoon Lee, Allen G. Oliver,
Shahriar Mobashery*
1623. Switchable regioselectivity in nucleophilic addition of primary amines to silylbenzynes: Synthesis of 2- and 3-silylanilines. Takashi Ikawa,
Tsuyoshi Nishiyama, Takashi Shigeta,
Shinya Mohri, Shinsuke Morita,
Yuki Terauchi, Sho-ichi Takayanagi,
Masahiro Egi, Satoshi Fujii, Yasuyuki Kita,
Shuji Akai*
1624. Divergent synthesis of cyclic peptides
facilitated by amphoteric aziridine aldehydes. Vishal Rai, Ryan Hili,
Andrei K. Yudin*
1625. Verdazyl radicals as substrates for organic synthesis: The synthesis of substituted oxadiazolones, tetrahydropyrazolotriazinones and triazoles.
Matthew Bancerz*, Eric K. Chen,
Gordon K. Hamer, Michael K. Georges
1626. Synthesis of 2-substituted-3-aminopiperidine derivertives via nucleophilic reactions to N-acylimminium ion intermediates. Takeshi Noda*, Yasuhide Tsunoda,
Jin-ichi Yonekawa
1627. Efficient synthesis of cyclopropyl silyl
ketones by the reaction of 1-silylcyclopropyl anions with dichloromethyl methyl
ether. Kenta Nakae, Mitsunori Honda,
Mitsuhiro Suda, Masahito Segi,
Ko-Ki Kunimoto
1628. Stereoselective synthesis of 1,3-diol
derivatives via desilylation of ␤-methoxyacylsilanes. Akira Horita,
Mitsunori Honda, Mitsuhiro Suda,
Masahito Segi, Ko-Ki Kunimoto
1629. Stereoselective synthesis of 1,2,3-triols from desilylation of ␣,␤-unsaturated
acylsilanes. Sho Numada,
Mitsunori Honda, Mitsuhiro Suda,
Masahito Segi, Ko-Ki Kunimoto
1630. Highly selective synthesis of small and
large fused multicyclic molecule by tandem dienyne ring closing metathesis and
Diels-Alder reaction. Hyeon Park,
Tae-Lim Choi*
1631. Synthesis of sulfides and 1,5-benzothiazines via novel Michael reaction.
Saori Itabashi*, Rong Lu,
Tetsuo Miyakoshi
1632. Synthesis and properties of fullerene
derivatives bearing O-acetylated phenylglucoside-substituted pyrrolidine.
Taizo Hatta, Keiji Mizuki,
Akifumi Yagami, Yuta Ikehara,
Naoki Nakaie, Takuji Yoshimoto
1633. Synthesis and properties of [10]parapyridinophane derivatives having a hydroxyl group on their ansa-bridges.
Takahiro Motoshiromizu,
Nobuhiro Kanomata*
1634. Synthesis and cyclization of N-tioacyl
1,2-aminoalcohols with 2-pyridyl group.
Eri Nagaya, Shinsuke Tahara,
Fumitoshi Shibahara, Toshiaki Murai*
1635. Reaction of phosphorothioic acid esters with TBAF leading to phosphorothiofluoridic acid salts. Kyohei Yamada,
Toshiaki Murai*, Toru Takenaka
1636. New synthesis of glycerol carbonate
from glycerol using sulfur-assisted carbonylation with carbon monoxide.
Takeo Nakai, Masatoshi Mihara,
Takumi Mizuno
1637. Synthesis of 2-aryl-4(3H)-quinazolinones obtained by coupling reaction of
N-substituted aryl amidine derivative and
carbonates. Shunichi Aikawa,
Norihiro Ohtubo, Chiharu Sekiguchi,
Shogo Ihara, Yasuhiko Yoshida
1638. Reaction behavior and structural features of aroylated naphthalenes: Imination of carbonyl group in non-coplanarly
accumulated aromatic-rings molecule of
congested oblique-configuration.
Atsushi Nagasawa, Shoji Watanabe,
Ryosuke Mitsui, Akiko Okamoto,
Noriyuki Yonezawa*
1639. Electrophilic aromatic substitution reaction of 8-position in 1-monoaroylnaphthalene: Nitration/bromination behavior
and structural features of the resulting
aroylnaphthalenes. Takahiro Nishijima,
Kotaro Kataoka, Ryosuke Mitsui,
Akiko Okamoto, Noriyuki Yonezawa*
1640. Electron-transfer oxidation of the phenolate anion derived from a vitamin E
model. Ikuo Nakanishi, Kei Ohkubo,
Tomonori Kawashima, Keiko Inami,
Ken-ichiro Matsumoto,
Masataka Mochizuki, Kiyoshi Fukuhara,
Haruhiro Okuda, Nobuo Ikota,
Shunichi Fukuzumi, Toshihiko Ozawa,
Kazunori Anzai
1641. Electrochemical generation of phosphorus ylides (PY) and iminophosphorane
(IP) from aminoalkylphosphonium salt
(APS) and their reaction behaviors.
Fumio Ando*, Hiroko Matsunaga,
Osamu Niyomura, Jugo Koketsu
1642. Photocycloaddition of aromatic aldehydes to substituted isoxazoles: Preparative synthesis of bicyclic oxetanes with
photochromic properties.
Marco Franke*, Hidehiro Kotaka,
Axel G. Griesbeck
1643. Nucleophilic-type substitution reaction
of electropositive substituted aromatic
compounds via photoinduced electron
transfer. Hiroto Yamada*,
Reina Sakamoto, Morihiro Kitamura,
Sadao Miki
1644. Photoinduced NO release in mitochondria. Taeko Horinouchi,
Hidehiko Nakagawa*, Takayoshi Suzuki,
Kiyoshi Fukuhara, Naoki Miyata*
1645. Alternative photoinduced release of
HNO or NO from an acyl nitroso compound. Hidehiko Nakagawa*,
Kazuya Matsuo, Yusuke Adachi,
Eri Kameda, Hiroki Tsumoto,
Takayoshi Suzuki, Naoki Miyata*
1646. NO release from 2,6-dimethylnitrobenzene based NO releasers worked with
two-photon excitation in cells.
Kazuhiro Hishikawa,
Hidehiko Nakagawa*, Taeko Horinouchi,
Toshiaki Furuta, Kiyoshi Fukuhara,
Takayoshi Suzuki, Naoki Miyata*
1647. Generation of highly reactive oxygen
species from nitrobenzene derivative by
photoirradiation. Naoya Ieda,
Hidehiko Nakagawa*, Taeko Horinouchi,
Takayoshi Suzuki, Kiyoshi Fukuhara,
Naoki Miyata*
1648. Radical addition reaction of phosphoroselenoic acid esters bearing a binaphthyl group to alkenes. Takafumi Ando,
Masaki Monzaki, Toshiaki Murai*
1649. Introduction of an alkynyl group to imidazo[1,5-a]pyridines and their fluorescence. Yoshimasa Douke,
Toshifumi Shibahara*, Toshifumi Murai
1650. Evaluation of solvent effects in Lewis
acid catalyzed bromination of benzoylacetates. Hidetoshi Yamamoto*,
Masahiro Komeda, Tatsushi Seto,
Yuko Takao, Maki Samitsu,
Michinori Sumimoto, Kenji Hori,
Takuya Miyata, Yasuaki Hanasaki
1651. Theoretical studies on chemoselectivity in bromination of acetoacetanilide.
Hidetoshi Yamamoto*,
Masahiro Komeda, Maki Samitsu,
Yuko Takao, Tatsushi Seto,
Michinori Sumimoto, Kenji Hori,
Takuya Miyata, Yasuaki Hanasaki
1652. Synthesis of CO2-philic 2-pyridinemethanol derivatives and its use for
metal extraction in sc-CO2.
Lim Byung-Jo, Lee Byeongno,
Kim Hakwon*
1653. Optimization of the carrot reduction of
benzil. John C. Bush, Bruce Baldwin
1654. Oxidation of aliphatic residue of its esters with hydrophobic substrate.
Yasumasa Minemoto*, Mokoto Yoshida,
Hiroto Saito, Akio Takeda, Eiji Nakajima,
Tadashi Kometani
1655. Enantioselective synthesis of ␣-fluorinated ␤-amino acid derivatives via asymmetric mannich reaction and selective
deacylation/decarboxylation reactions.
Yuanhang Pan, Choon-Hong Tan
Natural products synthesis and
characterization
1656. Remarkable synthesis of chiral epoxyzerumbone and its unique derivative
via transannular reaction.
Takashi Kitayama*, Masataka Awata,
Yasuhiko Yoshida, Yasushi Kawai
1657. Host selection of a Lauraceae-feeding
swallowtail butterfly (Graphium sarpedon
L.): Feeding and oviposition stimulants
from the camphor tree leaves (Cinnamomum camphora Sieb).
Shinicbi Tebayashi*, Yasunori Horie,
Ryu Wakui, Yoshichika Nishimura,
Yoshitaka Nishiyama, Yasunori Ikeno,
Chul-Sa Kim
1658. Concise and efficient synthesis of substituted ␣-pyrones and the application to
the total synthesis of breviones.
Masahiro Yoshida*, Hironobu Takai,
Chika Mitsuhashi, Yoko Matsuoka,
Kozo Shishido*
1659. Oxa-conjugate addition route to the
chemoenzymatic synthesis of neopeltolide. Taylor P. Hari, Burkhardt I. Wilke,
Christopher N. Boddy*
1660. Asymmetric synthetic strategy of fosfomycin using biocatalysis.
Brent D. Feske*, Erik Davis,
Christian Morocco, Julie Finnell
1661. Synthetic studies toward the human
telomerase inhibitors the rubromycins.
Gregory Czaban*, Robyn Crumbie,
Gary Dennis, Margaret Brimble
1662. Toward a general gethodology for the
synthesis of epidithiopiperazinedione
(ETP compounds). Daniel W. Tay*,
Paul B. Huleatt, Christina L. Chai
1663. Synthesis of meso-diaminopimelic
acid and its application to the biologically
active peptides. Yukako Saito,
Tomokazu Watanabe, Yuichi Yoshimura,
Hiroki Takahata
1664. Synthesis of ␤-CyD derivatives with
multiple functional groups by click reaction. Hirofumi Ooyama, Yoshiki Oda,
Keiko Takahashi, Takashi Yamanoi*
1665. Synthetic studies of novel decahydrofluorene-type natural products.
Ryo Kato, Hiromi Uchiro*
1666. Synthesis of highly oxygenated 3-hydroxyflavone derivatives. Misun Ko,
HoonGyu Park, Hakwon Kim*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–139
04-ORGN
1667. Anti-inflammatory lignans from Magnolia fargesii. Hua Li, Jae Yeon Kim,
Hyo Jin Lim, Hwa Jin Lee, Hee Doo Kim,
Raok Jeon, Jae-Ha Ryu*
1668. Anti-hyperglycemic compounds from
kiwifruit. Miyuki Shirosaki,
Tomoyuki Koyama*, Kazunaga Yazawa
1669. Flavonoid-based therapeutic agents.
Megan Thornton, Luke Henderson,
Fred Pfeffer
1670. Stereoselective synthesis and biological evaluation of bioactive constituents
from the Brazilian plant Tabebuia avellanedae. Kazunori Ueda,
Masanobu Kotera, Takahiro Nishitani,
Mitsuaki Yamashita, Masafumi Kaneko,
Katsumi Nishimura, Hrukuni Tokuda,
Akira Iida*
1671. One-pot synthesis of 4-alkenylcatechol by a modified Dakin reaction.
Yuta Harada*, Takahisa Ishimura,
Rong Lu, Tetsuo Miyakoshi
Carbohydrates
1672. Novel sugar-self guest hybrid cyclodextrins The dependency of arm structure on the molecular structure.
Shoji Fujiwara, Yoshiki Oda,
Takashi Yamanoi, Keiko Takahashi*
1673. Synthesis of a library of novel 2-Cbranched sugars. Peter W. Moore*,
Russell J. Hewitt, Joanne E. Harvey
1674. Syntheses of spirocompounds from
1-C-vinylated sugars.
Takashi Yamanoi*, Sho Matsuda,
Yoshiki Oda, Akihiro Yoshida
1675. Stereoselective formation of 1,2-cis-␣glycosidic linkages by glycosidation using 2-acetamido-2-deoxy-␣-D-glucopyranosyl acetate derivatives.
Takashi Yamanoi*, Yoshiki Oda,
Wako Kaburagi, Masanobu Midorikawa,
Keiko Takahashi
1676. Application of bulky silyl protecting
groups for oligosaccharide synthesis.
Noriyoshi Takahata*, Tetsuo Koyama,
Koji Matsuoka, Daiyo Terunuma,
Ken Hatano
1677. Synthesis and anti-inflammatory activity of glycosyl 5,6-dihydroergosterol derivatives. HoonGyu Park, Tae Hoon Lee,
Jiyoung Kim*, Soo Jeong Kim,
Hakwon Kim*
1678. Preparation and properties of modified
beta-1,3-glucans. Shun-ichi Tamaru*,
Daisuke Tokunaga, Seiji Shinkai*
1679. Understanding the phenomenon of ice
recrystallization and its inhibition using
carbohydrate derivatives.
Chantelle Capicciotti, Mathieu Leclère,
Yun Liu, Robert N. Ben*
1680. Application to drug derivery system of
carbosilane dendrimer having periphery
Lactose. Kentaro Otomo,
Nobuaki Honsyo, Hiroaki Aizawa,
Masumi Villeneuve, Daiyo Terunuma,
Koji Matsuoka, Ken Hatano
1681. Characterization of the complex formation of 1,6-anhydro sugars with potassium using 1H and 39K NMR spectroscopy. Takayuki Kato, Yousuke Usui,
Koji Tsubono, Osamu Kamo,
Toshiyo Kato, Kazuo Furihata,
Takashi Fujimoto, Tomoya Machinami,
Mitsuru Tashiro*
1682. Single threading of retinoid into cyclodextrin, structure of pseudorotaxane evidenced by NMR spectroscopy.
Sayo Morimoto, Toshiaki Narusawa,
Keiko Takahashi*
1683. Synthesis and application of phosphoroselenoic acid esters derived from alcohols possessing a chiral carbon atom remote from a hydroxyl group. Hikaru Ito,
Toshiaki Murai*
Nucleic acids and anlogues
1684. Design and synthesis of a dihydrothiopyrano-nucleoside derivative as a novel
nucleoside unit for nucleic acid medicine.
Yoshiko Yamazaki*, Yuichi Yoshimura,
Hiroki Takahata
1685. Synthesis of radioiodinated carbocyclic cytosine analogs: A new potential
PET imaging agent for HSV1-TK expression. Hyunseok Ahn*, Gwangil An,
Hakjune Rhee
140 –TECH
TECHNICAL PROGRAM
1686. Dissecting cytisine: Synthesis of novel
bispidine derivatives and structure-affinity relationships for nicotinic acetylcholine
receptors (nAChRs). Christoph Eibl*,
Daniela Guendisch
1687. Hybrid compounds derived from the
natural product cytisine: Synthesis and in
vitro evaluation for ion channels.
Christoph Eibl*, Dianqing Sun,
Daniela Guendisch
1688. Synthesis of substituted methyl ketones as inhibitors of Atg4b.
Thanh-Giau Nguyen, Robert Young*
1689. Organelle-specific evaluation of nuclear redox status with a DNA binding
spin probe. Mamiko Ikeda,
Hidehiko Nakagawa*, Takayoshi Suzuki,
Naoki Miyata*
1690. Linker and sequence dependence of
water-proton relaxivities in oligonucleotides carrying TEMPO. Emi Tanimoto*,
Manami Okazaki, Yuichiro Sato,
Tomoyasu Tanaka, Satoru Karasawa,
Noboru Koga
1691. Interaction of N-fused porphyrin with
nucleic acid. Satoshi Touden,
Yoshiya Ikawa, Hiroyuki Furuta
Biological activities
1692. Inhibitory effects of prenylated phenolic compounds isolated from Piper longum on melanin biosynthesis in B16 cells.
Osamu Ohno, Taeko Watabe,
Kazuhiko Nakamura, Masaru Kawagoshi,
Nobuo Uotsu, Tomohiro Chiba,
Masayoshi Yamada, Kohji Yamaguchi,
Kaoru Yamada, Kenji Miyamoto,
Daisuke Uemura
1693. Easy, selective and efficient methods
for the synthesis of chiral hetero-functionalized calix[4]arene based receptors
for enantioselective molecular recognition. Joackim Bois, Aurelia Schopp,
Jeff Espinas, Ulrich Darbost,
Mostafa Taoufik, Helene Parrot,
Isabelle Bonnamour*, Caroline Felix*
1694. Novel pyrimidines as potent inhibitors
of the Aurora kinases.
Michael L. Curtin*, Howard R. Heyman,
Robin R. Frey, Niru B. Soni,
Patrick A. Marcotte, Junling Li, Jun Guo,
Keith B. Glaser, Debra A. Montgomery,
Cherrie K. Donawho, Daniel H. Albert,
James R. Jankowski, Jennifer J. Bouska,
Michael R. Michaelides, Christin Tse
1695. Synthesis and fonctionnalization of
p-tBucalix[9]arene for polluant complexation. Mouna Ferchichi, Ulrich Darbost,
Faouzi Meganem, Isabelle Bonnamour
1696. Stereochemical study of sphingolipid
derivatives by vibrational circular dichroism. Atsufumi Nakahashi,
Mostafa A. Hammam, Shota Saito,
Kenji Monde*
1697. Calixarene-based copper-centered redox switch as data storage prototype.
Ulrich Darbost*, Vanessa Penin,
Erwann Jeanneau, Caroline Felix,
Francis Vocanson, Christophe Bucher,
Guy Royal, Isabelle Bonnamour
1698. Redox chemistry of antioxidative dihydropyridine derivatives bearing a pyrazole
moiety. Ikuo Nakanishi*,
Masato Kamibayashi, Kei Ohkubo,
Tomonori Kawashima,
Ken-ichiro Matsumoto, Tomoki Inaba,
Ikuo Kawasaki, Masayuki Yamashita,
Nobuo Ikota, Shunichi Fukuzumi,
Toshihiko Ozawa, Kazunori Anzai
1699. Water extract of Houttuynia cordata
Thunb. leaves exerts anti-obesity effects
by inhibiting fatty acid and glycerol absorption. Tomoyuki Koyama*,
Mitsuyoshi Miyata, Kazunaga Yazawa
1700. BACE-1 inhibitors from Cordia sebestina. Jingqiu Dai*, Philip Williams*
Materials and polymers
1701. Crystal structures of highly congested
aromatic rings accumulated molecules:
Structural features and influence of substituent. Yuichi Kato, Shoji Watanabe,
Toyokazu Muto, Ryosuke Mitsui,
Kosuke Nakaema, Akiko Okamoto,
Noriyuki Yonezawa*
1702. Functionalized aromatic glycidyl ether:
Plausible compound for better LCD back
light unit. Jeong eun Bae*,
Hakjune Rhee, Baek sun Kim,
Dong guk Kim
1703. Synthesis and properties of novel nonionic surfactants with acid decomposition
function derived from diethyl tartrate.
Daisuke Ono*, Ryoma Ueno,
Hirofumi Sato, Motohiro Shizuma,
Araki Masuyama, Masaki Nakamura
1704. Photoresponsive tetrafurcating-polymer possessing adamantane core with
Td local symmetry. Daijiro Yuasa*
1705. Preparation and properties of organic
thin films constructed by pi-rich framework. Shun-ichi Tamaru, Shou Mihara,
Seiji Shinkai
1706. Synthesis of new disulfide polymers
using solvent-free conditions.
Naoki Tanifuji*, Kohei Yamamoto,
Eriko Teramoto
1707. Synthesis and characterization of new
phenothiazine derivatives containing
benzimidazole moieties: Novel conjugated donor-acceptor molecules.
Kwang-Hyun Ahn*, Yong-Bum Cha,
Xiao-Hang Zhang, Eun-Kyung Je
1708. Photophysical properties of photochromic diarylethenes with electron donating and withdrawing substituents.
Shi-Chong Pang, Kwang-Hyun Ahn*,
Tie-Long Gao, Yong-Chul Jeong,
Sung-Ik Yang
1709. 3-D oligomeric material composed of
repeating adamantane units.
Kentaro Ikeda*, Keiko Iwasaki,
Sadao Mki
1710. Novel ambident agent having kinetically stabilized nitrile N-oxide moiety directed toward catalyst-free polymer modification and cross-linking reaction.
Kaori Miura, Morio Yonekawa,
Yasuhito Koyama, Toshikazu Takata
1711. External-stimuli responsive fluorescence of quinoline compounds in the solid-state. Yuichiro Abe*,
Satoru Karasawa, Noboru Koga
1712. Synthesizing fluorescent chalcones.
Mary Bruce, Bruce Baldwin
1713. Synthesis of fluorescent chalcones.
Katherine A. Bement, Bruce Baldwin
1714. Synthesis of fluorescent ruthenium
containing chalcones.
Joshua G. Frederick, Bruce Baldwin
1715. Syntheses and photochromic properties of diaryletehenes having thieno[3,2b]thiophene rings. Naoki Tanifuji,
Masahiro Irie, Kenji Matsuda
1716. Introduction of thionated esters into
imidazo[1,5-a]pyridines and their photophysical properties. Ichirota Onda,
Fumitoshi Shibahara*, Toshiaki Murai*
1717. Synthesis and investigation of inhibition photo-degradation of a novel polysilane with silole group in the side chain.
Yuuki Isobe*, Satoshi Kamibayashi,
Koji Matsuoka, Daiyo Terunuma,
Takeshi Fukuda, Norihiko Kamata,
Ken Hatano
1718. Preparation and application of silole
derivatives for electric materials.
Keita Mori*, Ryohei Kobayashi,
Takeshi Fukuda, Tetsuo Koyama,
Norihiko Kamata, Koji Matsuoka,
Daiyo Terunuma, Ken Hatano
Hilton
Sea Pearl V/VI
Theoretical
1719. Withdrawn
1720. Theoretical study on a starting palladium (2) complex for the Heck reaction.
Masayoshi Kurata*
1721. Study on fusing computational chemistry and cheminformatics developing
synthetic routes for an amide derivative
with physiologically activity.
Yujiro Matsuo*
1722. Predicting experimental yields as an
index to rank synthesis routes: Application to the Claisen-Schmidt reaction.
Shintaro Sato*
Organized by: M. Pirrung, W. Dai,
S.B. Park
Presiding: M. Pirrung
Anion Coordination Chemistry (#15)
Organized by: B. Hay,
K. Bowman-James, K. Nam, F. Pfeffer
Presiding: B. Hay
7:30 – 1723. Mega anion hosts from simple
building blocks.
Kristin Bowman-James*, Victor W. Day,
Sung O. Kang, Qiqiang Wang
8:00 – 1724. Ionpair induced self-assembly
and host-guest chemistry in polar solvents. Carsten Schmuck*
8:30 – 1725. Anion templated assembly of
interlocked host structures. Paul Beer
9:00 – 1726. Anion recognition and separation with self-assembled cage receptors.
Radu Custelcean*, Peter Bonnesen,
Benjamin Hay, Jerome Bosano,
Nathan Duncan
9:30 – 1727. Pyrrole-based anion receptors.
Jonathan L. Sessler*
10:00 – 1728. Indole-based anion receptors.
Kyu-Sung Jeong*
10:30 – 1729. Neutral anion receptors effective in highly competitive solvents.
Janusz Jurczak*
11:00 – 1730. Anion binding and chirality
transmission of N-(chiral-amido)thioureas. Fang Wang, Li-Cai Ye,
Jin-He Wang, Zhao Li, Yun-Bao Jiang*
Hilton
Coral IV
C-H Functionalization, Memorial
Symposium for Professor Keith Fagnou
(#18)
Organized by: H. Lebel, T. Driver, K. Itami
Presiding: K. Itami
7:30 – 1731. Strategy to form C-C bond via
the CDC reaction of CH and CH bonds.
Chao-Jun Li*
8:30 – 1732. New oxidative palladium-catalyzed alkene C-H functionalization.
Lukasz T. Pilarski, Nicklas Selander,
Dietrich Böse, Kálmán J. Szabó
8:55 – 1733. Transition metal-catalyzed oxidative coupling of aromatic substrates
with alkynes and alkenes via C-H and/or
C-C bond cleavage. Tetsuya Satoh*,
Koji Hirano, Masahiro Miura*
9:20 – 1734. C-H amination reactions with
N-tosyloxycarbamates. Helene Lebel*
9:45 – 1735. Rhenium-catalyzed regioselective alkylation of phenol derivatives.
Yoichiro Kuninobu*, Takashi Matsuki,
Kazuhiko Takai
10:10 – 1736. Direct catalytic functionalization of aliphatic and aromatic C-H bonds
by metal-induced carbene transfer reactions. Pedro J. Perez
10:35 – 1737. Ruthenium-catalyzed regioselective introduction of carbonyl functionality on aromatic ring via C-H bond cleavage. Fumitoshi Kakiuchi
Hilton
Sea Pearl I/II
Diversity Oriented Synthesis (#32)
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
04-ORGN
7:30 – 1738. Total and diversity-oriented
synthesis of natural products.
Michael Pirrung*, Goutam Biswas,
Tannya R. Ibarra-Rivera
8:00 – 1739. Natural product-based libraries
for chemical biology and drug discovery.
Derek S. Tan*
8:30 – 1740. Catalytic asymmetric construction of multiple stereogenic centers in diversity-oriented synthesis.
Takayoshi Arai*
9:00 – 1741. Synthesis of natural products
and their derivatives based on combinatorial chemistry and laboautomation.
Takashi Takahashi
9:30 – 1742. Diversity-oriented synthesis of
a stereochemically diverse CNS-focused
azetidine library for psych-HTS.
Jason T. Lowe, Berenice Lemercier,
Lakshmi Akella, Florence Wagner,
Edward Holson, Lisa Marcaurelle
10:00 – 1743. Generation of novel drug-like
five-membered heterocycles using carbon disulfide with solid support based on
diversity oriented synthesis.
Young-Dae Gong*, Taeho Lee
10:30 – 1744. Applying new strategies for diversity oriented synthesis.
Stephen Martin*
11:00 – 1745. Exploiting allenes and expanding chemical space.
Kay M. Brummond*
7:30 – 1753. Alkaloid synthesis inspired by
the Zincke ring-opening of pyridines.
Christopher Vanderwal*
8:00 – 1754. Guanidinium toxins: Unique
natural products in both form and function. Justin Du Bois*
8:30 – 1755. Studies in the total synthesis of
highly oxygenated natural products.
Masayuki Inoue*
9:00 – 1756. Ramberg-Bäcklund route to
aigialomycin D and designed analogs.
Joanne E. Harvey*, Samuel Ting,
Lynton Baird, Mattie Timmer,
Reem Hanna, John Miller,
Paul Teesdale-Spittle
9:30 – 1757. Cyclopropanes as vehicles for
natural product total synthesis.
Michael A. Kerr*
10:00 – 1758. Synthetic study on polyketidederived polycyclic natural products.
Keisuke Suzuki*
10:30 – 1759. Total syntheses of natural
products via ester-enolate Claisen rearrangement. Sanghee Kim
11:00 – 1760. New cyclization strategies for
the total syntheses of the marine natural
products cortistatin A and nakadomarin
A. Raymond L. Funk, Mark G. Nilson
Hilton
Honolulu III
Hilton
Iolani I/II
Design and Synthesis of Biologically Active
Compounds for Elucidating Mode-ofAction (#148)
Frontiers in Biocatalysis Applications to
Organic Synthesis (#124)
Organized by: T. Oishi, C. Forsyth, H. Lee
Presiding: T. Oishi
Organized by: R. Kazlauskas, T. Sakai,
J. Wu
Presiding: T. Sakai
7:30 – 1761. Anticancer activities of artemisnin-peptide conjugates.
Tomikazu Sasaki*, Henry Lai,
Narendra P. Singh, Byron Gallis
7:45 – 1762. Toward selective chemotherapeutic drugs: The design and synthesis of
small molecule inhibitors of the Bcl-2
family of proteins. Paul H. Bernardo,
Kah-Fei Wan,
Thirunavukkarasu Sivaraman,
Janarthanan Krishnamoorthy, Jin Xu,
Henry Y. Mok, Victor C. Yu,
Christina L. Chai
8:00 – 1763. Photo-generated carbene in
chemical genetics: A nonselective strategy for target identification and mode-ofaction study of biologically active natural
products. Naoki Kanoh*
8:20 – 1764. Design and synthesis of haloneplanocin A as novel mechanism-based
inhibitor of S-adenosylhomocysteine hydrolase. Lak Shin Jeong*, Sun Choi,
Kang Man Lee
8:40 – 1765. Synthesis of a series of vitamin
D analogs as ligands for human vitamin D
receptor: Super agonists, antagonists,
and studies on metabolism.
Atsushi Kittaka*, Daisuke Sawada,
Masashi Takano, Shinobu Honzawa,
Midori A. Arai, Nozomi Saito,
Shinji Kakuda, Hiroshi Saito,
Ken-ichiro Takagi,
Midori Takimoto-Kamimura,
Kazuya Takenouchi, Masaaki Kurihara,
Tai C. Chen, Toshiyuki Sakaki
9:00 – 1766. Withdrawn
9:30 – 1767. Cell death control molecules.
Mikiko Sodeoka
10:00 – 1768. Targeting heterocyclic natural
products at 4700 feet above sea level.
Jon D. Rainier*
10:30 – 1769. Asymmetric total synthesis
and structure-activity relationship of (-)deguelin as novel HIF-1␣ inhibitor.
Young-Ger Suh*, Dong-Jo Chang,
Hongchan An
11:00 – 1770. Toward a systematized approach of applying the information-rich
content of natural products to chemical
genomics. Daniel Romo*
7:30 – 1746. Engineering of enzymes for glycoside synthesis by design and by
chance. Stephen G. Withers*,
Amir Aharoni, Guangyu Yang,
Jamie Rich, Hongming Chen, Roman Kitl,
Susan Hancock, Natalie Strynadka
8:15 – 1747. Regio- and stereoselective
lipase-catalyzed reactions on sugars and
carbasugars. Manabu Hamada,
Yuji Ueda, Nobuyuki Chishima,
Jordi Calveras, Toshinori Higashi,
Mitsuru Shoji, Takeshi Sugai*
9:00 – 1748. Whole-cell biotransformations
with organic solvent-tolerant Kocuria rhizophila strain DC2201 in biphasic systems. Akinobu Matsuyama*,
Eitaro Matsumura
9:45 – 1749. Recognition of remote chiral
centers in the course of lipase-catalyzed
resolution and its application to both enantiomers of TBMB acid.
Toshinori Higashi, Chika Abe,
Mitsuru Shoji, Takeshi Sugai*
10:10 – 1750. New recombinant Baeyer-Villiger monooxygenases from the camphor
degradation pathway: Comparison of
Type I and II BVMOs in organic synthesis.
Peter C. Lau*, Hannes Leisch,
Stephan Grosse, Helene Bergeron,
Hiroaki Iwaki, Yoshie Hasegawa
10:35 – 1751. Actinobacteria, a treasure box
of P450s: How we can use them in biocatalysis? Byung-Gee Kim*,
Kwon-Young Choi, Nahum Lee,
Chang-Min Sung, Da-Hae Jeong,
Eun-Ok Chung
11:00 – 1752. Development of an efficient
method for producing optically pure alcohols using an asymmetric hydrogentransfer biocatalysis: Application of engineered enzymes in a polar organic
solvent-water medium. Nobuya Itoh*,
Yoshihide Makino
Hilton
Coral V
Total Synthesis of Natural Products and
Related Compounds (#134)
Organized by: K. Tanino, S.H. Kang,
R. Williams
Presiding: R. Williams
Hilton
South Pacific II
Molecular Probes and Fluorophores for
Cellular Imaging (#157)
Organized by: C. Fahrni, Y. Chang,
S. Kelley, K. Kikuchi
Presiding: C. Fahrni
7:30 – 1771. In situ imaging of trace metals.
Christoph Fahrni*
8:00 – 1772. Recent progress on fluorescent
chemosensors and their applications for
cellular imaging and zebrafish imaging.
Juyoung Yoon*
8:30 – 1773. Fluorescent indicators for zinc
ion based on 1,2,3-triazole coordination
chemistry and heteroditopic ligand platforms. Lei Zhu*
8:50 – 1774. Development of caged-complexes for studying Zn2⫹ signaling and
homeostasis. Shawn C. Burdette,
Daniel P. Kennedy, Dhammika Bandara,
Celina Gwizdala, Hannah Mbatia,
Timothy Walsh, Daniel Brown, Elif Akin
9:10 – 1775. Two-photon fluorescent probes
for dual color bioimaging.
Hwan Myung Kim*
9:30 – 1776. Chemical approaches to studying the cell biology of metals by molecular imaging. Christopher J. Chang*
10:00 – 1777. Two-photon probes for bioimaging. Bong Rae Cho*, Chang Su Lim,
Ji Hee Han, Min Young Kang
10:30 – 1778. Developing highly selective
fluorescent sensors for the detection of
peroxynitrite and hypochlorite in cells.
Dan Yang*, Tao Peng, Zhen-Ning Sun,
Hua-Li Wang
11:00 – 1779. Novel fluorescent probes for
visualizing reactive oxygen species in the
lipid membranes of live cells.
Gonzalo Cosa*, Katerina Krumova
Hilton
South Pacific IV
Boronic Acids: Synthetic and Biological
Applications (#199)
Organized by: B. Wang, P. Duggan,
D. Hall, M. Suginome
Presiding: B. Wang, E. Anslyn
7:50 Welcoming remarks
7:55 – 1780. Mechanistic studies on and
uses of boronic acids. Eric V. Anslyn*
8:25 – 1781. Boronic acid based optical saccharide sensor: Continuous glucose
sensing and beyond. Bakthan Singaram
8:55 – 1782. Divergent fluorescent response
boronolectins for sugar acid sensing applications. Todd A. Houston*,
Stephan M. Levonis, Milton J. Kiefel
9:25 – 1783. Wood protection properties of
organic spiroborates. Peter Duggan*,
Jenny Carr, David Humphrey,
Edward Tyndall, James Platts
9:55 – 1784. Indicators combining covalent
and supramolecular interactions to aid
disease detection. Robert Strongin*
10:25 – 1785. Design and synthesis of boron
containing novel heteroarotinoids to
study Retinoic acid signaling pathways.
Bhaskar C. Das*, Sabita Nayak,
Seetaram Mohapatra, Philip D. Campbell
10:45 – 1786. Molecular imaging approaches to studying peroxide biology.
Christopher J. Chang*
8:30 – 1789. Supramolecular chemistry
based on arene-perfluoroarene interaction: Gel and liquid crystalline phase formation. Yuguo Ma*, Ben-Bo Ni,
Huixian Wu
8:55 – 1790. Temperature-dependent
change of extraction performance of soft
cadmium(II) ion with TPEN-NIPA gel.
Tetsuya Maekawa, Wataru Watanabe,
Tatsuya Kida, Yuji Miyazaki,
Yusuke Inaba, Atsunori Mori,
Kenji Takeshita
9:10 – 1791. Multiple logic fluorescent
switching copolymers. Zhiqian Guo,
Weihong Zhu, He Tian
9:35 – 1792. Quad click! Construction of tetrakis(5-triazolylmethyl)ethylenediamine
(TTzEN) as a selective chelating agent.
Wataru Watanabe*, Tatsuya Kida,
Tetsuya Maekawa, Yuji Miyazaki,
Atsunori Mori, Yusuke Inaba,
Kenji Takeshita
9:50 – 1793. Syntheses of novel water-soluble phthalocyanines and their aggregation behavior in aqueous and non-aqueous media. Hiroaki Isago*,
Yutaka Kagaya, Harumi Fujita,
Tamotsu Sugimori
10:10 – 1794. Electrostatic effects on the
stability and kinetics of pseudorotaxanes.
Jorge Tiburcio*,
Anayeli P. Carrasco-Ruiz
10:30 – 1795. Molecular machine based on a
U-shaped conformation of alkyl chains
bound to a host. Young Ho Ko*,
Ilha Hwang, Hyunuk Kim,
Youngkook Kim, Kimoon Kim
10:50 – 1796. Design and synthesis of synthetic hydrogen bonded double helices.
James A. Wisner*
11:10 – 1797. Molecular configuration for the
methanol-water mixture in sub- and supercritical states via MD. Takumi Ono,
Shunsuke Kobayashi, Taka-aki Hoshina,
Masaki Ota, Yoshiyuki Sato,
Hiroshi Inomata*
Hilton
Honolulu II
Transition Metal Catalysis: Mechanism and
Practice (#283)
Organized by: K. Nozaki, J. Stryker,
F.D. Toste
Presiding: K. Nozaki
8:10 – 1798. Pd-catalyzed aerobic oxidative
amination of alkenes: New catalysts, synthetic applications, enantioselective
methods and mechanistic insights.
Shannon S. Stahl*
8:45 – 1799. Palladium-catalyzed oxidative
functionalization at the ␤-position of alkyl
ketones. Satoshi Ueno*, Ryohei Maeda,
Ryoichi Kuwano
9:00 – 1800. Efficient synthesis of amines via
hydroaminoalkylation and hydroamination with early transition metal catalysts.
Philippa R. Payne*, Patrick Eisenberger,
Laurel L. Schafer
9:15 – 1801. Access to molecular complexity
via gold- and platinum-catalyzed carbocyclization of alkynes. Rai-Shung LIu*
9:50 – 1802. Alkyne metathesis: Catalyst design and synthetic applications.
Jyothish Kuthanapillil, Qi Wang,
Chenxi Zhang, Wei Zhang*
Hilton
Honolulu I
Molecular Complex Systems: Reversible
Aggregation/Disaggregation of Organic
Molecules (#216)
Organized by: M. Yamaguchi, B. Kim,
D. Zhang
Presiding: A. Zengian
7:50 – 1787. Reversible double-helix formation of ethynylhelicene oligomers.
Masahiko Yamaguchi*
8:10 – 1788. Responsive molecular gels:
Bridging the gap between rationale design and serendipity. Anne J. McNeil*
* Principle Author
Photographing of presentations
and/or taping of talks is
prohibited unless permission is
obtained from the symposia
organizers and individual
presenters. Final Pacifichem
2010 program online at:
http://pacifichem.abstractcentral
.com/planner.jsp
TECH–141
04-ORGN
10:05 – 1803. Highly modular P-OP ligands
for asymmetric catalysis.
Anton Vidal-Ferran*,
Héctor Fernández-Pérez,
José L. Núñez-Rico, Armen Panossian,
Pablo Etayo
10:20 – 1804. New reaction pathways for organic synthesis: Mechanistically novel
cyclization and ring expansion processes.
Jeffrey M. Stryker*
10:55 – 1805. Chain-walking strategy for
synthesis of cyclic organic molecules:
Palladium-catalyzed cycloisomerization
of 1,n-dienes. Takuya Kochi*,
Yuka Aoyama, Junichi Kawasaki,
Taro Hamasaki, Fumitoshi Kakiuchi
Convention Center
Kamehameha Halls II and III
Asymmetric Organocatalysis (#62)
Organized by: K. Maruoka, L. Deng,
L. Gong
Presiding: K. Maruoka
Poster Session
10:00 – 12:00
1806. Asymmetric addition reactions using
chiral phosphoric acids as a Brønsted acid-base bifunctional catalyst.
Veda P. Billakanti, Wei Huang,
Satoaki Onitsuka, Hiroshi Furuno,
Junji Inanaga*
1807. Construction of contiguous quaternary
stereocenters by intramolecular crossed
benzoin reaction catalyzed by N-heterocyclic carbene. Tadashi Ema*,
Kumiko Akihara, Yoshitaka Oue,
Yuki Miyazaki, Toshinobu Korenaga,
Takashi Sakai
1808. C3-symmetric chiral trisimidazoline:
Design and application to organocatalyst.
Kenichi Murai*, Shunsuke Fukushima,
Shoko Hayashi, Yusuke Takahara,
Hiromichi Fujioka*
1809. Practical enantioselective synthesis of
optically active 1,1-disubstituted tetrahydro-␤-carbolines by phase-transfer-ctalyzed alkylation. Kun Liu, Seiji Shirakawa,
Keiji Maruoka
1810. Development of direct asymmetric
bromination reaction catalyzed by a
binaphthyl-based amine.
Fumitaka Shirozu, Taichi Kano,
Keiji Maruoka
1811. Stereoselective construction of sevenmembered rings with an all-carbon quaternary center by direct
Tiffeneau⫺Demjanov-type ring expansion. Yuki Naganawa,
Takuya Hashimoto, Keiji Maruoka
1812. ␣-Chiral acetylenes having an all-carbon quaternary center: Phase transfer
catalyzed enantioselective ␣ alkylation of
␣-alkyl-␣-alkynyl esters and ␣-alkynyl
crotonates. Kazuki Sakata*,
Takuya Hashimoto, Keiji Maruoka
1813. Enantioselective direct aldol reaction
catalyzed by phosphine oxide.
Shunsuke Kotani*, Masaharu Sugiura,
Makoto Nakajima*
1814. Development of a base-free chiral
phase-transfer reaction system.
Seiji Shirakawa, Lijia Wang, Rongjun He,
Keiji Maruoka
1815. Metal-free direct asymmetric aminoxylation of aldehydes catalyzed by a
binaphthyl-based chiral amine.
Taichi Kano, Haruka Mii, Keiji Maruoka*
1816. Stereoselective synthesis of trisubstituted aziridines with N-␣-diazoacyl camphorsultam. Hiroki Nakatsu,
Takuya Hashimoto, Shogo Watanabe,
Keiji Maruoka*
1817. Enantioselective inverse-electron demand 1,3-dipolar cycloaddition of C,Ncyclic azomethine imines catalyzed by
axially chiral dicarboxylic acid.
Masato Omote, Takuya Hashimoto,
Keiji Maruoka
1818. Catalytic enantioselective construction
of all-carbon quaternary stereocenters by
an organocatalytic Diels-Alder reaction of
␣-substituted ␣,␤-unsaturated aldehydes. Taiga Yurino, Youhei Tanaka,
Kenta Osawa, Taichi Kano, Keiji Maruoka
142–TECH
TECHNICAL PROGRAM
1819. Recyclable montmorillonite-entrapped
N-(2-Thiophenesulfonyl)prolinamide for
asymmetric aldol reaction.
Noriyuki Hara*, Shuichi Nakamura,
Norio Shibata, Takeshi Toru
1820. Direct asymmetric benzoyloxylation of
aldehydes catalyzed by 2-tritylpyrrolidine.
Sunhwa Song, Haruka Mii, Taichi Kano,
Keiji Maruoka
1821. Organocatalytic asymmetric one-pot
double Mannich reactions.
Ryu Sakamoto, Yukako Yamaguchi,
Taichi Kano, Keiji Maruoka
1822. Asymmetric allylation of arylaldehydes
with allyltrichlorosilane by using chiral cyclohexanediamine derivatives as Lewis
bases. Yuya Tanimura, Kaori Ishimaru*
1823. Highly enantioselective synthesis of
␣,␣-dialkylmalonates by direct ␣-alkylations of malonates. Suckchang Hong,
Jihye Lee, Minsik Kim, Young Ju Lee,
Sang-sup Jew, Hyeung-geun Park*
1824. Asymmetric nitro Michael addition and
aldol reaction catalyzed by novel chiral
azacrown ethers as organocatalysts.
Mio Ueda*, Masato Nishitani,
Kazushige Hori, Keita Tani
1825. E-selective monoacylation of 2-Alkylidenepropane-1,3-diols by PPY catalysts
with functional chains. Keisuke Yoshida,
Takumi Furuta, Takeo Kawabata
1826. Catalytic stereoselective aziridination
of electron-deficient olefins using
N-haloamides. Yuta Murakami,
Satoshi Minakata*
1827. Synthesis of biaryl DMAP derivatives
with an internal carboxylate.
Reiko Nishino*, Takumi Furuta,
Takeo Kawabata
1828. Direct aldol reaction promoted by trichlorosilyl triflate. Shohei Aoki,
Shunsuke Kotani*, Masaharu Sugiura,
Makoto Nakajima*
1829. Asymmetric synthesis of 3,4- and
2,3,4-substituted 1,4-dihydropyridines by
using co-catalysts of Brønsted acid and
aminothiourea. Kohzo Yoshida,
Tsubasa Inokuma, Kiyosei Takasu,
Yoshiji Takemoto*
1830. Asymmetric aldol reaction and related
reactions using chiral phenoxide as a catalyst. Tomonori Ichibakase,
Makoto Nakajima*
1831. Enantioselective double aldol reaction
catalyzed by chiral phosphine oxide.
Yasushi Shimoda, Shunsuke Kotani*,
Masaharu Sugiura, Makoto Nakajima*
1832. Enantioselective catalytic allylation of
N-acylhydrazones using a protonated
chiral amine. Doo Ok Jang*,
Sung Jun Kim
1833. New umpolung catalysts: reactivity
and selectivity of fenchole-based lithium
phosphonates in enantioselective benzoin type couplings. Anca Gliga*,
Bernd Goldfuss
1834. Catalytic asymmetric formal [4⫹1] annulation leading to optically active cisisoxazoline N-oxides. Zugui Shi*,
Guofu Zhong*
1835. Chiral Brønsted acid-catalyzed asymmetric Friedel-Crafts alkylation reaction
of indoles with ␣,␤-unsaturated ketones:
Rapid access to optically active 2- and
3-substituted indole derivatives.
Tsubasa Sakamoto, Keiji Mori,
Takahiko Akiyama*
1836. Synthesis and properties of substituted 2,3-dihydro-4H-pyrimido[2,3b]benzothiazoles as acyltransfer catalysts. Baby Viswanbharan,
Chikashi Matsuno, Sentaro Okamoto*
1837. Catalytic enantioselective reactions
based on a Lewis base-catalyzed conjugate reduction of ␣,␤-unsaturated carbonyl compounds with trichlorosilane.
Masaharu Sugiura*, Norimasa Sato,
Mako Kumahara, Yuko Sonoda,
Shunsuke Kotani, Makoto Nakajima*
1838. Stereoselective synthesis of nitrogencontaining compounds by a tandem C-C
bond formation/reduction using Lewis
base catalysts. Takeru Kashiwagi,
Shunsuke Kotani, Masaharu Sugiura*,
Makoto Nakajima*
1839. Organocatalytic enantioselective synthesis of nitrogen-substituted dihydropyran-2-ones, a key synthetic intermediate
of 1␤-methylcarbapenems.
Shoji Kobayashi*, Tatsuhiro Kinoshita,
Hisatoshi Uehara, Tomoko Sudo,
Araki Masuyama, Ilhyong Ryu
1840. Theoretical study of neutral Lewis
base catalyzed allylation of aldehydes.
Ken Sakata
1841. Development of a solid phase proline
organocatalysis on gold nanoparticles.
Haruo Yamada*, Tatsuya Arizono
1842. Synthetic approach of a tertiary amine
containing [6]helicene for asymmetric catalysis. Kazuteru Usui*,
Toshitaka Kogiso, Kosuke Yamamoto,
Hiroshi Suemune*
1843. Enantioselective Friedel-Crafts alkylation of indoles, pyrroles, and furans with
trifluoropyruvate catalyzed by chiral
phosphoric acid. Wataru Kashikura,
Junji Itoh, Keiji Mori, Takahiko Akiyama*
1844. Asymmetric synthesis of tetra-substituted biaryl compounds by chiral phosphoric acid-catalyzed enantioselective
bromination. Yuki Ichikawa, Keiji Mori,
Takahiko Akiyama*
1845. Enantioselective Mannich-type reaction of aliphatic imine catalyzed by chiral
phosphoric acid. Kohei Ogawa,
Keiji Mori, Takahiko Akiyama*
1846. Chiral diamine-catalyzed asymmetric
Robinson-type annulation application to
the short synthesis of (⫹)-sporochnol A.
Niiha Sasakura, Yogo Inokoishi,
Hiyoshizo Kotsuki*
1847. Highly enantioselective phase-transfer
catalytic mono-␣-alkylation of malonamic
esters: Application to the total synthesis
of (-)-paroxetine. Jiwon Park,
Mi-hyun Kim, Young Ju Lee,
Sang-sup Jew, Hyeung-geun Park*
1848. Enantioselective synthesis of sixmembered oxacycles via organocatalyzed oxa-Michael cyclizations.
Andrew Duncan*, Michael Harris,
Nicholas Babij, Charlotte Osborne,
Craig Sather, Sarah Lindstrom,
Rich G. Carter
1849. Highly enantioselective and diastereoselective [4⫹2]cycloaddition reaction of
alpha,beta-unsaturated amide and alphachloroaldehyde catalyzed by N-heterocyclic carbene. Limin Yang, Guofu Zhong*
1850. Michael addition reaction of ␤-ketoesters in water using DMAP-related organocatalysts. Kyungmin Ko,
Maya Moritaka, Hiyoshizo Kotsuki*
1851. Organocatalytic 3⫹2 cycloaddition reactions. Fei Wang*
1852. Planar-chiral terpyridine N-oxide for
catalytic asymmetric allylation of aldehyde. Norihiko Akutsu,
Nobuhiro Kanomata*
1853. Enantio-selective epoxidation and
aziridination via the Corey-Chaykovsky
type reaction using a camphor-derived
chiral sulfide mediator. Kota Shibuya,
Noriki Kutsumura, Takao Saito*
1854. High-pressure organic chemistry:
Chiral thiourea-catalyzed asymmetric
hetero-Diels-Alder reaction of activated
ketones. Kaori Mori,
Tomoyuki Yamauchi, Hiyoshizo Kotsuki*
1855. Theoretical study on kinetic resolution
in chiral phosphoric acid catalyzed Robinson-type annulation. Masaya Hoshino,
Masahiro Yamanaka*, Keiji Mori,
Takahiko Akiyama*
1856. Asymmetric synthesis of optically active quaternary ␣-amino phosphonic acids. Masashi Hayashi,
Shuichi Nakamura*, Yuichi Hiramatsu,
Norio Shibata, Takeshi Toru
1857. Regioselective iodination of 2,2’-dimethoxy-1,1’-binaphthyl with N,N’-diiodo5,5-dimethylhydantoin catalyzed by
Lewis acid. Makoto Sako,
Hiroshi Shibaguchi, Toshiyuki Kamei,
Toyoshi Shimada*
1858. Glucose-specific acylation with a nucleophilic organocatalyst via fine molecular recognition. Kenji Mishiro*,
Wataru Muramatsu, Takumi Furuta,
Takeo Kawabata
1859. Enantioselective Robinson-type annulation reaction catalyzed by a chiral phosphoric acid. Shinya Ichikawa,
Takuya Katoh, Keiji Mori,
Takahiko Akiyama*
Convention Center
Kamehameha Halls II and III
Marine Natural Products: Isolation, Biology,
Ecology, and Synthesis (#80)
Organized by: J. Rainier, R. Anderson,
M. Murata
Presiding: J. Rainier
Poster Session
10:00 – 12:00
1860. Novel long-chain polyamine (LCPA)
associated peptides toxins from the
sponge Axinyssa aculeata.
Satoko Matsunaga, Mitsuru Jimbo,
Martin B. Gill, Geoffrey T. Swanson,
Ryuichi Sakai
1861. Anti-inflammatory meroterpenoids
from the New Zealand ascidian Aplidium
scabellum: Isolation, synthesis, and biology. Brent R. Copp*, Susanna T. Chan,
Iman M. Khalil, David Barker,
Jacquie L. Harper, Victoria L. Webb
1862. Bisebromoamide, a potent cytotoxic
peptide from the marine cyanobacterium
Lyngbya sp. Hiroaki Sasaki,
Toshiaki Teruya, Kiyotake Suenaga*
1863. Determination of the absolute configurations of chiral amines by NMR method.
Hiroki Fukui*, Yukiharu Fukushi
1864. Isolation and structure of a novel macrolide glycoside from the marine cyanobacterium Leptolyngbya sp.
Maho Morita, Toshiaki Teruya,
Kiyotake Suenaga
1865. Phytochemical screening of Cyperus
platycaulis for antituberculosis agents:
Part II. Echeme O. JohnBull*,
Muluh E. Khan
1866. Anti-inflammatory activity of furan fatty
acid. Toshiyuki Wakimoto, Ikuro Abe*
1867. Synthetic study of biselides A and B.
Yosuke Satoh*, Dai Kawamura,
Yumi Ochiai, Masashi Yamaura,
Ichiro Hayawaka, Hideo Kigoshi
1868. Total synthesis of auripyrones A and B
by using a novel diastereoselective aldoltype reaction of a 4-pyrone.
Takuma Takemura, Emi Fukasawa,
Yuta Ebihara, Natsuki Sato,
Takayasu Nakamura, Kiyotake Suenaga,
Ichiro Hayakawa, Hideo Kigoshi*
1869. Isolation and structure elucidation of
bioactive compounds from Sada Cape.
Makoto Kuramoto*, Yoshitaka Yokoo,
Norimichi Miyake, Hidemitsu Uno
1870. Exploration of skeletal structure-activity relationships of gambierol. Yuto Suga,
Tomomi Goto, Yuya Ogata,
Haruhiko Fuwa, Makoto Sasaki*
1871. Biselyngbyaside, a macrolide glycoside from the marine cyanobacterium lyngbya sp. Toshiaki Teruya*,
Hiroaki Sasaki, K

Similar documents

cv-david crich - Institut de Chimie des Substances Naturelles

cv-david crich - Institut de Chimie des Substances Naturelles Academic qualifications - BSc 1981 Chemistry with French, University of Surrey, England. - Doctorat ès Sc 1984, Supervisor DHR Barton Université de Paris XI, Orsay, France. Postes occupés : Positio...

More information

Universités Universities

Universités Universities JEFFREY MOHAMED ANTENEH W. A. TANSU MARTHA L. LISA NICOLAS DARLENE COLLEEN PATRICK D. RODGER SANDRA KATHRYN WALID HICHEM SHEILA M. MICHAEL GREGORY KATHRYN MICHAEL ERNEST FIONA EDWARD IRENE R. TERRA...

More information