Pebax ® Rnew

Pebax® Rnew
Biobased Engineering Elastomer
生物基尼龙弹性体
www.pebax.com
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What are Pebax® and Pebax® Rnew ?
Thermoplastic Elastomer – TPE
热塑性弹性体 TPE
Poly Ether Block Amide (eXtreme)
聚醚聚酰胺
Two phases structure两种结构
两种结构
● Polyamide – Rigid Block 硬段- 聚酰胺
● Polyether – Soft Chain 软缎- 聚醚
Polyamide 12
Polyether
Polyamide 11
Polyether
Molten state polycondensation 熔融缩聚
PE / PA ratio Flexibility 不同比例决定柔韧性
Pebax® Rnew – 基于蓖麻原的
PA11为硬段聚酰胺
2
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Pebax® Rnew
First engineering thermoplastic Elastomer
range made from Renewable resources
第一个生物基的工程弹性体
Vegetal Oil
植物
Petroleum
石油
- renewable resource -
- fossil resource -
MONOMER SYNTHESIS
MONOMER SYNTHESIS
Polyamide 11
Polyether
- hard block -
- soft block -
20 to 95%
5 to 80%
BLOCK POLYMERIZATION
Pebax® Rnew
- Polyether Block Amide -
3
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Hardness硬度范围
硬度范围
广泛适用的硬度范围及牌号:
Styrenics
TPO
NEW!
NEW!
NEW!
2 transparent
grades
7 biobased
grades
NEW!
2 rigid
grades
1 soft
grade
PolyEther Block Esters (COPE)
Thermoplastic
Polyurethane (TPU)
Caoutchouc / Rubber
Polyamides
Shore D 80D
72D 70D 63D
55D
Shore A
40D 35D
90A 85A
25D
75A
66A
4
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50A
10A
Flexibility 柔韧性
BEST PERFORMANCE AT LOW-TEMPERATURE
最佳的表现：
最佳的表现： 低温下韧性
拉伸模量:
低温表现:
800
600
According to standard
ISO 527 at 23°
°C
Modulus of rigidity (MPa)
600
385
400
260
200
According to standard
ASTM D 1043
660
150
80
TPU
400
COPE
200
17
9
0
0
25R53
35R53
40R53
55R53
63R53
70R53
72R53
-40
RUBBER - BEHAVIOR OF THE MATERIAL - POLYAMIDE
5
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-20
0
20
40
Temperature °C
60
80
Density 密度
Lightest weight among
Thermoplastic Elastomer
Save 20% weight
相对于其他弹性体，
相对于其他弹性体，质轻约20%
质轻约
COPE
TPU
Polyester Elastomers
Thermoplastic Urethanes
1.18 ~ 1.20
1.21 ~ 1.25
1.22 ~ 1.26
1.25 ~ 1.26
Soft grades
(<shore D 64)
Rigid grades
1.03
(>shore D 64 )
6
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Energy Return 能量回复
Pebax® Rnew
has lower energy loss factor than TPU
低于TPU的能量损失
BEST Energy Return*
理想状态 (theoretical)
Pebax® Rnew (80 shore A)
TPU (80 shore A)
能量损失因子 = 0
能量损失因子 = 0.1~0.2
能量损失因子= 0.4~0.5
Extension
Relaxation
Extension
Relaxation
Elongation
Load
Load
Load
NO
ENERGY
LOSS
Extension
Relaxation
LOW
ENERGY
LOSS
Elongation
HIGH
ENERGY
LOSS
Elongation
* Capacity of a material to retain a maximum of energy during extension phase and to deliver back a maximum of it (“return”)
during
relaxation phase.
7
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Weather resistance耐候性
耐候性
Pebax® Rnew
LONGEST LIFE-TIME
1. UV test- UV 老化测试
Ross flex 耐疲劳测试
Samples = 150x25x2mm
2. Ross flex test 耐疲劳测试
- 30ºC, angle 90º, 100cycles/min
2 weeks （2周
周）
150,000 cycles
60C, 0.68W/m2 at 340nm
150,000
Number of cycles
until breaking
Hytrel® 6356
100,000
断裂样条的数量
TPU 64D
70R53
NO
BREAK
50,000
不断裂
Clear 400
2
900
0
8
Hytrel®
TPU
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Pebax® Clear 400
Pebax® Rnew 70R53
Productivity
Excellent processability of Pebax® Rnew
绝佳的加工特性
●
●
●
Injection molding 注塑加工
Extrusion (cast film, blown film, sheet, tube...) 挤出加工（流延，吹膜，挤板，管材）
Assembly process : overmolding and co-extrusion 双色射出
Productivity increase by Pebax® Rnew
生产率的提高
●
●
●
●
●
Wide processing window among TPE (TPU) 加工窗口宽泛
Good flowability 流动性好
Possibility to inject extremely thin part (0.8mm) 薄壁成型 0.8mm
Shorter cycle time than TPU 成型周期小于TPU
Higher recyclability than TPU 回收能力好于TPU
Time cycles reduced by 10 to 30 %*
可以节省10~30% 成型周期
可以节省
9
* Compare to TPU & COPE, according to our major customers on sports, automotive & industrial markets
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Renewable Resources* Carbons
可再生碳在材料成分中的比例
19%
Pebax® RNew 25R53
31%
Pebax® RNew 35R53
46%
Pebax® RNew 40R53
65%
Pebax® RNew 55R53
79%
Pebax® RNew 63R53
89%
Pebax® RNew 70R53
95%
Pebax® RNew 72R53
0%
20%
40%
60%
80%
10* This calculation follows the guideline of the ASTM 6866 norm. The real amount of C from renewable sources can be measured by isotopic analysis of the
14C / 12C ratio and will have to be determined experimentally. This real value may be slightly different (probably by a few %) for the industrial grades.
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100%
Pebax® Rnew soft grades
GENERAL PROPERTIES
Renewable carbon content
Density
Melting Point
25R53
SP 01 35R53
SP 01 40R53
SP 01
ASTM 6866
%
17-21
24-28
44-48
ISO 1183
g/cm3
1.03
1.03
1.03
ISO 11357
°C
136
146
148
ISO 868
Shore D
26
32
42
22
25
39
MPa
NC
NC
> 25
%
NC
NC
> 600
MPa
9
17
80
Hardness
Instantaneous
After 15 s.
Tensile
Stress at break
ISO 527
Elongation at break
Tensile modulus
ISO 527
11
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Pebax® Rnew hard grades
GENERAL PROPERTIES
55R53
01
SP 63R53
SP 01
70R53
SP 01
72R53
SP 01
Renewable carbon content
ASTM 6866
%
62-66
77-81
87-91
93-97
Density
ISO 1183
g/cm3
1.03
1.03
1.03
2.03
Melting Point
ISO 11357
°C
167
180
186
186
ISO 868
Shore D
53
62
68
71
41
57
60
65
MPa
46
56
55
55
%
> 500
> 450
> 350
> 300
MPa
150
260
385
660
Hardness
Instantaneous
After 15 s.
Tensile
Stress at break
ISO 527
Elongation at break
Tensile modulus
ISO 527
12
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Injection conditions
Drying
Injection Temperature
Mold Temperature
Pebax® 25R53
4-8 hours / 55 - 65°
°C
180°
°C / 210 °C /
240°
°C
10 - 30°
°C
Pebax® 35R53
4-8 hours / 55 - 65°
°C
180°
°C / 210 °C /
240°
°C
10 - 30°
°C
Pebax® 40R53
4-6 hours / 60 - 70°
°C
200°
°C / 240 °C /
270°
°C
10 - 30°
°C
Pebax® 55R53
4-6 hours / 65 - 75°
°C
200°
°C / 240 °C /
270°
°C
25 - 60°
°C
Pebax® 63R53
4-8 hours / 55 - 65°
°C
230°
°C / 260 °C /
290°
°C
25 - 60°
°C
Pebax® 70R53
5-7 hours / 70 - 80°
°C
230°
°C / 260 °C /
290°
°C
25 - 60°
°C
Pebax® 72R53
5-7 hours / 70 - 80°
°C
230°
°C / 260 °C /
290°
°C
25 - 60°
°C
Rilsan® unfilled - BMNO
4-1 night / 80 - 90°
°C
230°
°C / 260 °C /
290°
°C
20 - 40°
°C
Rilsan® filled - AZM 30
4-1 night / 80 - 90°
°C
240°
°C / 280 °C /
310°
°C
40 - 60°
°C
13
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滑雪镜
太阳镜应用
滑雪镜-太
镜应用
PEBAX Rnew
与Rilsan Clear 双射成型
PEBAX Rnew
14
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Winter Sports – Scarpa
冬季滑雪靴
Posters and flyers on the booth
Hangtags on the boots
15
Visit our website
www.pebaxpowered.com !
Scarpa booth at ISPO 09 (Munich Feb 1st - 4th 2009)
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Pebax® Rnew
户外运动应用案例
16
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Nike
Air Zoom Rage
Air Zoom Apocalypse
Air Zoom Barracuda
III
17
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IV
Under Armour
Metal D Series
Metal Power
Metal Power Mid
Metal Speed
Metal Power High
Metal Speed Low
Dual plate (Pebax® forefoot)
18
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Metal Speed Mid
Dual plate (Pebax® forefoot)