Invincible. The next generation of thermoset matrix resins

Comments

Transcription

Invincible. The next generation of thermoset matrix resins
Invincible.
The next generation of
thermoset matrix resins
CALIDUR® polyetheramide resins
CALIDUR® is a new class of thermoset matrix resins that combines the high flame
retardancy of phenolic resins with the mechanical properties of high TG epoxy resins.
Benefits
CALIDUR® provides much greater design flexibility for carbon fiber and glass fiber
composite structures in aircraft and other transportation interior applications.
Properties
• Intrinsic FST performance
• High TG
• Excellent surface quality
Processing
• Rapid processing and curing
• Formaldehyde-free
• Thermoformable
• Storage-stable at 8°C
CALIDUR® is supplied as a resin solution or in powder form. Prepregs with
various fiber reinforcements are available via our partner c-m-p GmbH.
Prepreg production
Drying
Dry fabric
Resin solution
Impregnated fabric
Dry prepreg
Parts production
Autoclave
Compression molding press
Our Partner
2
In addition to enabling short production
cycles, CALIDUR® does not require binders
while providing greater flexibility across a
wide range of curing temperatures.
With a very low shrinkage of < 0.5 % and
superior characteristics compared to stateof-the-art phenolic compounds, CALIDUR®
also demonstrates very good mechanical
properties.
Prepreg characteristics
Tackiness
No tack
Storage stability
Stable for at least 6 months at 8°C
Curing cycle
Wide range of curing conditions possible
TG after curing (30 mins at 150°C)*
DSC 152°C
TG after curing (10 mins at 180°C)
DSC 163°C
*
TG after curing (45 mins at 180°C)
*
*
DSC 187°C
1 layer glass fiber prepreg (300gsm, E-Glass HexForce 07781, 8H satin)
3
CALIDUR® meets both Airbus FST (ABD0031) and FAA
requirements, and is competitive with phenolic resin.
Vertical Bunsen burner test (AITM 2.0002 A)
Burn length [mm]
After flame time [s]
0
0
0
0
0
0
After flame time
of drips [s]
1
CALIDUR®
100
10
Phenolic resin
Epoxy resin
Airbus & FAA limits
Heat release rate, heat release (AITM 2.0006)
HRR max *
[kW/sqm]
HR **
[kW min/sqm]
0
CALIDUR® ***
5
10
15
Phenolic resin
20
25
Epoxy resin
* Max heat release rate within 5 minutes;
** Total heat release at 2 minutes;
*** Values are measured with 1 h 160 °C post curing
4
30
35
40
45
50
55
Airbus & FAA limits
60
65
70
Specific optical density of smoke (AITM 2.0007A; flaming model)
Max. specific
optical density
0
CALIDUR® ***
20
40
Phenolic resin
60
80
Epoxy resin
100
120
140
160
Airbus & FAA limit
*** Values are measured with 1 h 160 °C post curing
Epoxy resin fulfills the requirements of FAR25.853; phenolic resin fulfills the requirements of DAN 407-08.
Fiber: 300gsm, E-Glass HexForce 07781, 8H satin; two prepreg plies
5
CALIDUR® shows superior composite properties compared
to phenolic resin and is competitive with epoxy resin.
CALIDUR® vs. state-of-the-art prepreg resins for aerospace interior applications
Tensile strength*
EN 2747
Tensile modulus*
EN 2747
In-plane shear strength*
AITM 1-0002
In-plane shear modulus*
AITM 1-0002
Compression strength*
EN 2850
Compression modulus*
EN 2850
Compression strength
after 30 J impact
0
20
40
60
80
100
Data normalized [%]
CALIDUR®
Epoxy resin
Phenolic resin
Epoxy resin fulfills the requirements of FAR25.8533; phenolic resin fulfills the requirements of DAN 407-08.
Fiber: 300 gsm, E-Glass HexForce 07781, 8 H satin.
* Data normalized on 50 % fiber volume content.
6
The exceptional properties of CALIDUR® make it ideal
for applications that require both superior resistance to
flammability, especially smoke density, and outstanding
mechanical strength.
7
Technical contact:
Dr. Silke Witzel
Evonik Industries AG
Paul-Baumann-Straße 1
45772 Marl
Germany
 +49 2365 49-84878
 +49 2365 49-8084878
[email protected]
Marketing:
Kirsten Alting
Evonik Industries AG
Paul-Baumann-Straße 1
45772 Marl
Germany
 +49 2365 49-2259
 +49 2365 49-802259
[email protected]
Prepreg inquiries:
This information and all further technical
advice is based on our present knowledge
and experience. However, it implies no
liability or other legal responsibility on
our part, including with regard to existing
third party intellectual property rights,
especially patent rights. In particular, no
warranty, whether express or implied,
or guarantee of product properties in the
legal sense is intended or implied. We
reserve the right to make any changes
according to technological progress or
further developments. The customer
is not released from the obligation to
conduct careful inspection and testing
of incoming goods. Performance of the
product described herein should be
verified by testing, which should be
carried out only by qualified experts in
the sole responsibility of a customer.
Reference to trade names used by other
companies is neither a recommendation,
nor does it imply that similar products
could not be used.
CALIDUR® is a registered trademark of
Evonik Industries or its subsidiaries.
c-m-p gmbh
Industrieparkstraße 15
52525 Heinsberg
Germany
 +49 2452 15721–0
 +49 2452 15721–44
[email protected]
300-09.14
Evonik Industries AG
Agrochemicals & Polymer Additives
Paul-Baumann-Straße 1
45764 Marl
Germany
www.evonik.com/composites

Similar documents

Phenolic Resins Market Analysis Forecast to 2020 by P&S Market Research

Phenolic Resins Market Analysis Forecast to 2020 by P&S Market Research The key drivers behind the growing demand of global phenolic resins include growing demand from construction and transports application, and increased usage of fire retardant materials in automotive and aircraft components. However, the volatility in crude oil prices is expected to restrain the growth of the global phenolic resins market, as crude oil is a major raw material needed for the manufacturing of phenolic resins.

More information