Essie Professional - Four Star Salon Services

Essie Professional
Product
Product Category
Accessories
Corrector Pen
Cuticle Pen
White Bright Nail Pen
Nail
All In One Three Way Glaze
Apricot Cuticle Oil
Essie Gel
Essie Nail Color
Fill The Gap
First Base Base Coat
Gel Base Coat
Gel Cleanser
Gel Remover Liquid
Gel Top Coat
Good To Go
Grow Faster Base Coat
Grow Stronger Base Coat
Instant Dry Oil
Luxeffects Top Coat
Man E Cure
Matte About You
Millionails Treatment
Naturally Clean Purifying Nail Polish Remover
No Chips Ahead Top Coat
Protein Base Coat
Quick E
Ridge Filler
Ridge Filling Base Coat
Sensitivity
Shine E
Sleek Sticks Nail Stickers
Super Duper Top Coat
MSDS
11-073
NON-HAZ
99-020
99-022
NON-HAZ
ESSIE GEL
99-022
99-022
99-022
EP Base-Top
EP Cleanser
11-073
EP Base-Top
99-022
99-022
99-022
NON-HAZ
99-022
99-022
99-022
99-022
11-073
99-022
99-022
99-022
99-022
99-022
99-022
99-022
NON-HAZ
99-022
T:\OTC - Safety - Ingredients\MSDS\MSDS CLASSIFICATION\PROFESSIONAL - CURRENT\Essie Professional.xls
Material Safety Data Sheet
U.S. Department of Labor
May be used to comply with
OSHA’s Hazard Communication Standard
29 CFR 1910.1200. Standard must be
consulted for specific requirements
Occupation Safety and Health Administration
(Non-Mandatory Form)
Form Approved
OMB No. 1218-0072
IDENTITY
Note: Blank spaces are not permitted. If any item is not applicable, or no
#99-020
information is available, the space must be marked to indicate that.
Alcohol-Based Fragrance & Skin Treatment
Products
Section I
Manufacturer’s Name
Emergency Telephone Number
L'Oreal USA Products, Inc.
(800) 535-5053 (Int’l 352-323-3500)
Address (Number, Street, City, State, and ZIP Code)
Telephone Number For Information
111 Terminal Avenue
(732) 499-2745
Date Prepared
Clark, NJ
07066
June 20, 2005
Signature of Preparer (optional)
GCD
Section II - Hazardous Ingredients/Identity Information
Hazardous Components (Specific Chemical Identity;Common Name(s))
Ethyl Alcohol
OSHA PEL
ACGIH
TLV
Other Limits
Recommended
1000 ppm
% (optional)
25-92%
Section III - Physical/Chemical Characteristics
B oi l i ng P oi nt
Specific Gravity (H2O = 1)
~170°F
Vapor Pressure (mm Hg)
~0.9
M e l ti n g P o i n t
N/A
Vapor Density (AIR = 1)
N/A
Evaporation Rate
>1
(Butyl Acetate = 1)
~3
S o l u b i l i ty i n W a te r
Miscible
Appearance and Odor
Colored, perfumed, water-thin liquid. (non-aerosol)
Section IV - Fire and Explosion Hazard Data
Flash Point (Method Used)
Flammable Limits
LE L
UEL
60-90°F (closed cup)
Ethyl Alcohol
3.3%
19%
Extinguishing Media
Carbon dioxide, dry chemical, foam and/or water spray.
Special Fire Fighting Procedures
For small fires, use carbon dioxide, dry chemical, or foam.
For larger fires, use ample quantities of water.
Unusual Fire and Explosion Hazards
None; however, observe usual precautions for handling of flammable liquids.
For manufacturing, minimize airborne vapor levels through engineering controls.
Forms published by ChemSW (707)864-0845
#99-020
Section V - Reactivity Data
S ta b i l i ty
Unstable
Conditions to
A v oi d
S ta b l e
Avoid fire, flame, heat, and other sources
of ignition.
X
Incompatibility (Materials to Avoid)
Oxidizing agents and nitric acid.
Hazardous Decomposition or Byproducts
None known.
Hazardous
May Occur
Polymerization
Will Not Occur
Conditions to
A v oi d
None known.
X
Section VI - Health Hazard Data
Route(s) of Entry:
In h a l a ti o n ?
S k i n?
In g e s ti o n ?
Yes
Yes
Not likely
Health Hazards (Acute and Chronic)
Causes eye irritation. May cause skin irritation or sensitization in sensitive
individuals. May be harmful if swallowed.
Carcinogenicity:
NTP?
IARC Monographs?
OSHA Regulated?
No
NO
No
Signs and Symptoms of Exposure
Overexposure and/or ingestion may produce signs and symptoms of alcohol intoxication.
Medical Conditions Generally Aggravated by Exposure
None known.
Emergency and First Aid Procedure
INGESTION: Give one or two glasses of water or milk and consult physician.
EYE CONTACT: Flush thoroughly with water for at least 15 minutes and get medical
attention.
SKIN CONTACT: Flush with water, then wash with soap and plenty of water.
Section VII - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled
Eliminate all sources of ignition. Dike and contain the free liquid and absorb with
vermiculite or spill pillows. Containerize absorbed material in UN specification drums
for disposal. Wash spill area with water.
Waste Disposal Method
Alcohol-based products are ignitable (D001) RCRA hazardous wastes when intended for
disposal. Incineration is the required method of treatment and disposal.
Precautions to be Taken in Handling and Storage
Store bulk quantities in a cool, well-ventilated room. Limit quantities on hand to the
extent possible. Store away from possible sources of ignition. Observe usual
precautions relative to static electricity. Avoid oxidizing agents and nitric acid.
Other Precautions
Avoid contact with eyes.
For external use only.
Use only as directed.
#99-020
Section VIII - Control Measures
Respiratory Protection (Specify Type)
For manufacturing/filling, wear a NIOSH approved organic vapor respirator if alcohol
TLV is exceeded. For spills, wear an approved self-contained operating apparatus.
V e n ti l a ti o n
Local Exhaust
S pec i al
Explosion-Proof
Mechanical(General)
Other
Explosion-Proof
Protective Gloves
Plastic or rubber for bulk quantities.
Other Protective Clothing or Equipment
Safety glasses for bulk quantities.
Protective clothing for manufacturing operations.
Work/Hygienic Practices
OSHA hazard classification: Flammable, eye irritant
DOT classification: Bulk - Perfumery products, with flammable solvents, 3 UN 1266 PGII
Finished product - Consumer Commodity, ORM-D.
Forms published by ChemSW (707)864-0845
SAFETY DATA SHEET
SDS #99-022
DATE: June 29, 2012
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Emergency Telephone Number:
Number
800-535-5053
5053 (International: 352-323-3500)
352
L’Oreal USA Products, Inc.
111 Terminal Avenue
Clark, NJ 07066
For further information:
732-499-2741
Product Name: Nail Enamels
Recommendations on use: Liquid lacquer painted on the nails to create temporary coloring effect.
Restrictions on use: Please read the labeling on the consumer package for proper use of this material.
material For external use
only. Use only as directed.
SECTION 2: HAZARDS IDENTIFICATION
Signal word: DANGER
Symbol
Classification
Flammable Liquids –
Category 2
Hazard Statement
Highly flammable
liquid and vapor
Prevention Statements
•
•
•
•
•
•
•
Eye Irritation –
Category 2A
Causes serious eye
irritation
•
•
Keep away from heat, sparks, open
flames and hot surfaces. Do not use
while smoking.
Keep container tightly closed.
Ground/bond container and receiving
equipment.
Use explosion-proof
proof electrical, ventilating,
lighting, manufacturing and packaging
equipment.
sparking tools.
Use only non-sparking
Take precautionary
cautionary measures against
static discharge.
Wear plastic or rubber gloves. Eye
protection
appropriate
for
the
manufacturing operation being performed
should be used (goggles or face shield).
Wash hands and face thoroughly after
handling.
Wear eye protection/face protection; eye
protection appropriate for the
manufacturing operation being performed
should be used (goggles or face shield).
Nail Enamels
Symbol
Classification
Specific Target Organ
Toxicity (Single
Exposure) –
Category 3
Hazard Statement
May cause
drowsiness or
dizziness
Prevention Statements
•
•
Avoid breathing mist/vapors.
Use only in a well-ventilated area.
This material is considered hazardous by the US Occupational Safety and Health Administration Hazard Communication
Standard (29 CFR 1910.1200)
General Precautionary Statements: Keep out of reach of children. Read label before use.
Hazards Not Otherwise Classified: Over-exposure may cause skin dryness or slight irritation.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Only hazardous constituents associated with the product are listed below
INGREDIENT:
CAS NO.
% WT
Ethyl Acetate
n-Butyl Acetate
Propyl Acetate
Tosylamide/formaldehyde resin (not present in all formulations)
Nitrocellulose
Isopropyl Alcohol
141-78-6
123-86-4
109-60-4
25035-71-6
9004-70-0
67-63-0
<60 %
<30 %
<30 %
<15 %
<12 %
<10 %
SECTION 4: FIRST AID MEASURES
Response Statements:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue
rinsing for at least 20 minutes or until material is sufficiently removed from the eye. If eye irritation persists: Get
medical advice/attention if irritation or other symptoms occur.
IF ON SKIN OR HAIR: Remove immediately all contaminated clothing. Rinse skin with water in an appropriate
emergency shower. If irritation symptoms appear and persist, get medical attention.
IF SWALLOWED:
unwell.
Do not induce vomiting. Consult a physician immediately. Call a Poison Control Center if you feel
IF INHALED: Remove victim to fresh air and keep in a rest position comfortable for breathing. Call a Poison Control
Center if you feel unwell.
NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: Consult product labeling. No special advice.
SYMPTOMS/EFFECTS: Eye irritation upon contact, possible skin dryness/irritation if over-exposed, drowsiness or
dizziness if over-exposed by inhalation.
Issue Date: June 29, 2012
PAGE 2 OF 10
Supersedes Date: September 12, 2011
Nail Enamels
SECTION 5: FIRE-FIGHTING MEASURES
Notes for Non-Emergency Personnel:
EXTINGUISHING MEDIA: In case of fire use carbon dioxide, dry chemical and/or foam for extinction. Water spray may
be used to soak other materials surrounding the product, to prevent the spread of the fire. Selection of a fire extinguisher
should also be appropriate to address the location of the fire and equipment involved. Please review the tools available at
your location to ensure proper availability of equipment.
Notes for those trained to participate in an emergency:
SPECIAL FIRE FIGHTING PROCEDURES: Treat as flammable liquid. Follow National Fire Protection Association
Guidelines or local guidelines appropriate for emergency response. Minimize all sources of static electricity.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Observe all appropriate precautions for handling flammable materials.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide/carbon dioxide, nitrogen oxides.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Notes for non-emergency personnel:
Consult trained response personnel for clean-up of large spills or locations where providing preliminary control of the
chemical release is hazardous. Hazardous locations include areas where ignition sources cannot be controlled. It is vital
that sections 2, 5, 7 and 8 of this document be consulted before an accident occurs, to control any risks in handling
flammable liquids.
If the location is not hazardous and only a small amount of material is spilled, control the spill using absorbent pads and
protective equipment as noted below. Prohibit discharge to drains, soil, surface and ground waters. Dispose in
accordance with section 13 of this document.
PERSONAL PROTECTIVE EQUIPMENT: Plastic or rubber gloves, apron may be required for clean-up of large spills.
Respiratory protection may need to be utilized, depending upon the size of the spill. Respiratory protection may include
the use of organic vapor cartridges. Protective goggles or face shield is recommended for the control of liquid. See also
Section 8 of this document.
Notes for those trained to participate in an emergency:
ACCIDENTAL RELEASE MEASURES: Eliminate all sources of ignition. Dike and contain the free liquid and absorb on
vermiculite or spill pillows/pads. Place spent absorbents in UN specification drums for disposal. All precautions associated
with controlling a flammable liquid should be employed during clean-up. Prohibit discharge to drains, soil, surface and
ground waters.
Recommendations for personal protective equipment selection are noted above. Non-sparking tools should be utilized in
all clean-up associated with flammable liquids. Dispose in accordance with section 13 of this document.
Issue Date: June 29, 2012
PAGE 3 OF 10
Supersedes Date: September 12, 2011
Nail Enamels
SECTION 7: HANDLING AND STORAGE
Storage precautions for unpackaged product (manufacturing environment): Store in a well-ventilated place. Keep
cool. Minimize inventory. Keep container tightly closed. It is suggested that this material be “locked up” or stored in an
area where production inventory may be controlled by authorized personnel. Use only non-sparking tools. Use
explosion-proof electrical/ventilating/lighting equipment.
Take precautionary measures against static discharge.
Appropriate fire suppression and detection equipment should be utilized. Store on spill pallets or other locations where
spill containment will be easily accessible.
Keep away from open drains and access to the environment.
General notes on storage:
Incompatible materials: Oxidizers, acids, bases. Store away from incompatible materials.
Maintain a clean work environment which includes use of properly functioning containers, proper housekeeping practices.
General notes on handling:
Employees should not eat, drink or smoke while working with flammable materials. Employees should be advised to wear
appropriate protective equipment in the manufacturing environment. See section 8 of this document for protective
equipment selection. All manufacturing should be performed indoors, in an enclosed environment free from uncontrolled
ignition sources. Employees should be advised not to handle flammable products in close proximity to incompatible
materials.
Please refer to section 8 of this document for recommended equipment to be used in a manufacturing environment.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters – these criteria have been published by the referenced authority to establish exposure limits in the
work environment. Employee work areas should be monitored to ensure that permissible limits are not exceeded during
the work day. These references do not coincide with product use. These references are meant to be in association with
the manufacturing environment.
Occupational Exposure Values (where available from the listed agencies):
Component Name (CAS-No.)
Ethyl Acetate (141-78-6)
Component Name (CAS-No.)
n-Butyl Acetate (123-86-4)
Issue Date: June 29, 2012
Reference
OSHA PEL
ACGIH TLV
NIOSH REL
Reference
OSHA PEL
ACGIH TLV
NIOSH REL
ppm
400
400
400
ppm
150
150
150
PAGE 4 OF 10
TWA
3
mg/m
1400
-1400
TWA
3
mg/m
710
710
710
ppm
---ppm
--200
STEL/CEILING
3
mg/m
---STEL/CEILING
3
mg/m
--950
Supersedes Date: September 12, 2011
Nail Enamels
Component Name (CAS-No.)
Propyl Acetate (109-60-4)
Component Name (CAS-No.)
Reference
OSHA PEL
ACGIH TLV
NIOSH REL
Reference
OSHA PEL
ACGIH TLV
NIOSH REL
Isopropyl Alcohol (67-63-0)
ppm
200
200
200
ppm
400
400
400
TWA
3
mg/m
840
840
840
TWA
3
mg/m
980
980
980
ppm
--250
ppm
--500
STEL/CEILING
3
mg/m
--1050
STEL/CEILING
3
mg/m
--1225
WORK HYGIENIC PRACTICES: Ensure all work surfaces are maintained, to prevent contamination.
ENGINEERING CONTROLS: None required for product use. For handling large quantities of material, such as in the
manufacturing of product, ventilation should be utilized. This ventilation should be compatible with the control of
flammable materials. Exhaust ventilation should be utilized to maintain air concentrations of material below the
occupational exposure guidelines noted above.
Local exhaust ventilation is not typically required for product use. For handling large quantities of material, such as in the
manufacturing of product -- Local Exhaust: Explosion proof. Mechanical (general): Explosion proof.
Personal Protective Equipment: Consistent with good hygiene practices, personal protective equipment (PPE) should
be used in conjunction with other control measures including engineering controls, ventilation and isolation. See also
Section 5 of this document for PPE advice, in the event of an emergency.
RESPIRATORY PROTECTION (NON-EMERGENCY): Respiratory protection is not required for product use. For
manufacturing of product, respiratory protection may be considered. Ensure that the respirator meets current local
occupational health and safety standards. Organic vapor cartridges should be utilized with filtering respiratory protection.
EYE/FACE PROTECTION (NON-EMERGENCY): None required for product use. For handling of large quantities of
liquid material, safety glasses with side shields/goggles are recommended.
SKIN PROTECTION (NON-EMERGENCY): None required for product use. For handling large quantities of material,
such as in product manufacturing, plastic or rubber gloves should be considered for use. Tyvek clothing may also be
suitable for handling large quantities of material in the manufacturing environment.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Colored or clear, shiny liquid material. Dries after contact with air.
ODOR: The product has a solvent odor associated with it (butyl acetate or ethyl acetate odor).
ODOR THRESHOLD: The fragrance of the material will be noticeable when very little product has been dispensed.
pH: Not available (non-aqueous)
MELTING POINT: F: N/A
BOILING POINT:
FLASH POINT:
F: 125-175
C: N/A
FREEZING POINT: F: N/A
C: N/A
C: 51.7 – 79.4
F: 14-45; C: -10 – 7.3 METHOD USED: Closed Cup
Issue Date: June 29, 2012
PAGE 5 OF 10
Supersedes Date: September 12, 2011
Nail Enamels
EVAPORATION RATE: >1 for product
(Butyl acetate = 1)
FLAMMABILITY: flammable liquid
FLAMMABLE LIMITS IN AIR (% BY VOLUME):
ETHYL ACETATE: 11.5% UEL; 2.0% LEL
n-BUTYL ACETATE: 7.6% UEL; 1.7% LEL
PROPYL ACETATE: 8% UEL; (@100F) 1.7% LEL
ISOPROPYL ALCOHOL: (@200F) 12.7% UEL; 2.0% LEL
NO OTHERS LISTED
VAPOR PRESSURE (mm Hg):
@ 70F ; 21 C: 44 – 73
VAPOR DENSITY (AIR = 1):
@ 70F; 21 C: >1
RELATIVE DENSITY/SPECIFIC GRAVITY (H2O = 1) : >1
SOLUBILITY IN WATER: Insoluble
PARTITIION COEFFICIENT: not available
AUTOIGNITION TEMPERATURE: F: 797 C: 425 (ethyl acetate)
DECOMPOSITION TEMPERATURE: Not available
VISCOSITY: 100-1000 cps
SECTION 10: STABILITY AND REACTIVITY
REACTIVITY: This material is not considered reactive under typical handling and storage conditions.
STABILITY: Product is stable under standard pressure and temperature.
POSSIBILITY OF HAZARDOUS REACTIONS: None known. Hazardous polymerization is not expected to occur.
CONDITIONS TO AVOID: Heat, fire, flame and other sources of ignition.
INCOMPATIBILITY (MATERIAL TO AVOID): Oxidizing agents and acids/bases.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide/carbon dioxide, nitrogen oxides.
SECTION 11: TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS:
SKIN CORROSION/IRRITATION: Overexposure may cause skin irritation or dryness
SERIOUS EYE DAMAGE OR IRRITATION: Serious eye irritation upon contact
RESPIRATORY OR SKIN SENSITIZATION: None expected
INGESTION: Harmful if swallowed
INHALATION: May cause drowsiness/dizziness
Issue Date: June 29, 2012
PAGE 6 OF 10
Supersedes Date: September 12, 2011
Nail Enamels
CARCINOGENICITY:
OSHA:
NTP:
ACGIH:
IARC:
Not recognized as carcinogenic
Not recognized as carcinogenic
Not recognized as carcinogenic
Not recognized as carcinogenic
ROUTES OF EXPOSURE: Inhalation, eyes, skin
SYMPTOMS: Symptoms may include unsteady gait, nausea, and dizziness. Skin redness, dryness or itchiness may occur with overexposure to the product. Watering, stinging or itching eyes may occur with direct contact.
CHRONIC HEALTH EFFECTS: None anticipated
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known.
MATERIAL
Ethyl Acetate
n-Butyl Acetate
Propyl Acetate
Nitrocellulose
Isopropyl Alcohol
T/F Resin
LC 50 (RAT)
LD 50 Oral (RAT)
200 g/m3
390 ppm
Unavailable
Unavailable
16000 ppm
Unavailable
5620 mg/kg
10768 mg/kg
9370 mg/kg
5000 mg/kg
5045 mg/kg
Unavailable
SECTION 12: ECOLOGICAL INFORMATION
Contact with the environment should be avoided. Spills and leaks should be immediately cleaned up and removed. All precautions
should be taken to prevent contact with the environment. Published information regarding ingredients listed on this document area
found below; where data is not listed, documentation was unavailable.
Contact with the environment should be avoided. Spills and leaks should be immediately cleaned up and removed. All
precautions should be taken to prevent contact with the environment.
ACUTE AND PROLONGED TOXICITY TO FISH
INGREDIENT NAME
Ethyl Acetate
RESULT
SPECIES
EXPOSURE
LC50 = 270-333 mg/l
Golden Orfe
48 h
n-Butyl Acetate
LC50 = 18 mg/l
Pimephas promelas
96 h
Propyl Acetate
LC50= 56-64 ppm
Pimephas promelas
96 h
Pimephas promelas
96 h
Isopropyl Alcohol
Issue Date: June 29, 2012
50
LC
= 11,130 mg/l
PAGE 7 OF 10
Supersedes Date: September 12, 2011
Nail Enamels
ACUTE TOXICITY TO AQUATIC INVERTEBRATES
INGREDIENT NAME
RESULT
SPECIES
EXPOSURE
Ethyl Acetate
EC50= 3090 mg/l
Daphnia Magna
24 h
n-Butyl Acetate
Propyl Acetate
Isopropyl Alcohol
EC50 = 205 mg/l
EC50 = 318-511 ppm
LC50 = 903 mg/l
Daphnia Magna
Daphnia Magna
Daphnia Magna
24 h
24 h
96 h
TOXICITY TO AQUATIC PLANTS
INGREDIENT NAME
RESULT
SPECIES
EXPOSURE
Ethyl Acetate
EC50 = 3300 mg/l
Scenedesmus subspicatus (algae)
48h
n-Butyl Acetate
EC50 = 675 mg/l
Scenedesmus subspicatus (algae)
72 h
Propyl Acetate
EC50 = >1000 mg/l
Planktonalgen
24 h
Isopropyl Alcohol
EC50 = >1000 mg/l
Scenedesmus subspicatus (algae)
96 h
TOXICITY TO MICROORGANISMS
INGREDIENT NAME
Ethyl Acetate
n-Butyl Acetate
Propyl Acetate
Isopropyl Alcohol
RESULT
EC50 = 1500 mg/l
EC50 = 959 mg/l
TGK = 97-1123 mg/l
EC50 = 41,676 mg/l
SPECIES
Bacteria (Pseudomonas fluorescens)
Pseudomonas putida
Protozoa
Bacteria (activated sludge)
EXPOSURE
15 min
18 h
48-72 h
30 days
This product is readily biodegradable and shows a low bioaccumulation potential.
SECTION 13: DISPOSAL CONSIDERATIONS
Those responsible for the performance of disposal, recycling or reclamation activities should refer to section 8 of
this document for advice on personal protective equipment and exposure controls.
WASTE DISPOSAL CONTAINERS: Appropriate US DOT containers should be utilized which may include cardboard
boxes for products, metal or plastic drums for liquids. These containers should meet the packaging specifications
required for DOT compliance.
WASTE DISPOSAL METHOD: Nail enamel remover products are ignitable (D001) RCRA hazardous wastes when
intended for disposal. Controlled incineration at a hazardous waste facility is the recommended technology for treatment
and disposal. This material must not be disposed through sewage.
RCRA HAZARD CLASS: D001 Follow all local governmental requirements intended for disposal.
Issue Date: June 29, 2012
PAGE 8 OF 10
Supersedes Date: September 12, 2011
Nail Enamels
SECTION 14: TRANSPORT INFORMATION
North American Ground Transportation
The classification represented below is based upon 49 CFR 171.150 SP 198 in affiliation with
Nitrocellulose, solution, flammable with not more than 12.6 percent nitrogen, by mass, and not more
than 55% nitrocellulose UN 2059 PGII:
•
In Consumer Packaging: Limited Quantity/Consumer Commodity
•
PACKAGED IN OTHER THAN CONSUMER PACKAGING:
ID NUMBER: UN 1266
PROPER SHIPPING NAME: Perfumery Products
HAZARD CLASS: 3
PACKING GROUP: II
LABEL STATEMENTS: Flammable Liquid
Transport Via Water
The classification represented below is based upon IMDG code SP 198 in affiliation with Nitrocellulose,
solution, flammable with not more than 12.6 percent nitrogen, by mass, and not more than 55%
nitrocellulose UN 2059 PGII:
•
In Consumer Packaging: Limited Quantity
ID NUMBER: UN 1266
PROPER SHIPPING NAME: Perfumery Products
HAZARD CLASS: 3
PACKING GROUP: II
LABEL STATEMENTS: None
•
PACKAGED IN OTHER THAN CONSUMER PACKAGING:
ID NUMBER: UN 1266
PROPER SHIPPING NAME: Perfumery Products
HAZARD CLASS: 3
PACKING GROUP: II
LABEL STATEMENTS: Flammable Liquid
Issue Date: June 29, 2012
PAGE 9 OF 10
Supersedes Date: September 12, 2011
Nail Enamels
Transport Via Air Domestic/International
The classification represented below is based upon 49 CFR 171.150 SP 198 and IATA DGR SP A91 in
affiliation with Nitrocellulose, solution, flammable with not more than 12.6 percent nitrogen, by mass,
and not more than 55% nitrocellulose UN 2059 PGII:
•
In Consumer Packaging: Limited Quantity/Consumer Commodity ID 8000
•
PACKAGED IN OTHER THAN CONSUMER PACKAGING:
ID NUMBER: UN 1266
PROPER SHIPPING NAME: Perfumery Products
HAZARD CLASS: 3
PACKING GROUP: II
LABEL STATEMENTS: Flammable Liquid
Please be aware of carrier transport variations before shipping hazardous materials
SECTION 15: REGULATORY INFORMATION
National Fire Protection Association Codes: Health: 2 Fire: 3 Reactivity: 0 Other: None
Workplace Hazardous Materials Identification System (as acetone): Class B Flammable Material; D2B Poisonous
and infectious material - Toxic
US DOT/IATA//IMDG: See section 14 above
This regulatory information represents the product, in its consumer packaging.
SECTION 16: OTHER INFORMATION
PREPARATION INFORMATION: Formatting change to accommodate changes to OSHA 29CFR1910.1200 Hazard Communication
regulations.
Author: Chandra L. Jennings
Issue Date: June 29, 2012
PAGE 10 OF 10
Supersedes Date: September 12, 2011
SAFETY DATA SHEET
SDS # 11-073
DATE: June 5, 2012
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Emergency Telephone Number:
Number
800-535-5053
5053 (International: 352-323-3500)
352
L’Oreal USA Products, Inc.
111 Terminal Avenue
Clark, NJ 07066
For further information:
732-499-2741
Product Name: Acetone Nail Enamel Removers (Bottles and Pen Dispensers)
Recommendations on use: Applied on the nails to remove temporary coloring effects produced by nail lacquer.
Restrictions on use: Please read the labeling on the consumer package for proper use of this material.
material For external use
only. Use only as directed.
SECTION 2: HAZARDS IDENTIFICATION
Signal word: DANGER
Symbol
Classification
Flammable Liquids –
Category 2
Hazard Statement
Highly flammable
liquid and vapor
Prevention Statements
•
•
•
•
•
•
•
Eye Irritation –
Category 2A
Causes serious eye
irritation
•
•
Keep away from heat, sparks, open
flames and hot surfaces. Do not use
while smoking.
Keep container tightly closed.
Ground/bond container and receiving
equipment.
Use explosion-proof
proof electrical, ventilating,
lighting, manufacturing and packaging
equipment.
sparking tools.
Use only non-sparking
Take precautionary
cautionary measures against
static discharge.
Wear plastic or rubber gloves. Eye
protection
appropriate
for
the
manufacturing
turing operation being performed
should be used (goggles or face shield).
Wash hands and face thoroughly after
handling.
Wear eye protection/face protection; eye
protection appropriate for the
manufacturing operation being performed
should be used (goggles or face shield).
Acetone Nail Enamel Removers
(Bottles and Pen Dispensers)
Symbol
Classification
Specific Target Organ
Toxicity (Single
Exposure) –
Category 3
Hazard Statement
May cause
drowsiness or
dizziness
Prevention Statements
•
•
Avoid breathing mist/vapors.
Use only in a well-ventilated area.
This material is considered hazardous by the US Occupational Safety and Health Administration Hazard Communication
Standard (29 CFR 1910.1200)
General Precautionary Statements: Keep out of reach of children. Read label before use.
Hazards Not Otherwise Classified: Over-exposure may cause skin dryness or slight irritation.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Only hazardous constituents associated with the product are listed below
INGREDIENT:
CAS NO.
% WT
Acetone
64-67-1
<99 %
SECTION 4: FIRST AID MEASURES
Response Statements:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue
rinsing for at least 20 minutes or until material is sufficiently removed from the eye. If eye irritation persists: Get
medical advice/attention if irritation or other symptoms occur.
IF ON SKIN OR HAIR: Remove immediately all contaminated clothing. Rinse skin with water in an appropriate
emergency shower. If irritation symptoms appear and persist, get medical attention.
IF SWALLOWED:
unwell.
Do not induce vomiting. Consult a physician immediately. Call a Posion Control Center if you feel
IF INHALED: Remove victim to fresh air and keep in a rest position comfortable for breathing. Call a Poison Control
Center if you feel unwell.
NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: Consult product labeling. No special advice.
SYMPTOMS/EFFECTS: Eye irritation upon contact, possible skin dryness/irritation if over-exposed, drowsiness or
dizziness if over-exposed by inhalation.
Issue Date: June 5, 2012
PAGE 2 OF 8
Supersedes Date: Initial Document
Acetone Nail Enamel Removers
(Bottles and Pen Dispensers)
SECTION 5: FIRE-FIGHTING MEASURES
Notes for Non-Emergency Personnel:
EXTINGUISHING MEDIA: In case of fire use carbon dioxide, dry chemical and/or foam for extinction. Water spray may
be used to soak other materials surrounding the product, to prevent the spread of the fire. Selection of a fire extinguisher
should also be appropriate to address the location of the fire and equipment involved. Please review the tools available at
your location to ensure proper availability of equipment.
Notes for those trained to participate in an emergency:
SPECIAL FIRE FIGHTING PROCEDURES: Treat as flammable liquid. Follow National Fire Protection Association
Guidelines or local guidelines appropriate for emergency response. Minimize all sources of static electricity.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Observe all appropriate precautions for handling flammable materials.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide/carbon dioxide, nitrogen oxides.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Notes for non-emergency personnel:
Consult trained response personnel for clean-up of large spills or locations where providing preliminary control of the
chemical release is hazardous. Hazardous locations include areas where ignition sources can not be controlled. It is vital
that sections 2, 5, 7 and 8 of this document be consulted before an accident occurs, to control any risks in handling
flammable liquids.
If the location is not hazardous and only a small amount of material is spilled, control the spill using absorbent pads and
protective equipment as noted below. Prohibit discharge to drains, soil, surface and ground waters. Dispose in
accordance with section 13 of this document.
PERSONAL PROTECTIVE EQUIPMENT: Plastic or rubber gloves, apron may be required for clean-up of large spills.
Respiratory protection may need to be utilized, depending upon the size of the spill. Respiratory protection may include
the use of organic vapor cartridges. Protective goggles or face shield is recommended for the control of liquid. See also
Section 8 of this document.
Notes for those trained to participate in an emergency:
ACCIDENTAL RELEASE MEASURES: Eliminate all sources of ignition. Dike and contain the free liquid and absorb on
vermiculite or spill pillows/pads. Place spent absorbents in UN specification drums for disposal. All precautions associated
with controlling a flammable liquid should be employed during clean-up. Prohibit discharge to drains, soil, surface and
ground waters.
Recommendations for personal protective equipment selection are noted above. Non-sparking tools should be utilized in
all clean-up associated with flammable liquids. Dispose in accordance with section 13 of this document.
Issue Date: June 5, 2012
PAGE 3 OF 8
Supersedes Date: Initial Document
Acetone Nail Enamel Removers
(Bottles and Pen Dispensers)
SECTION 7: HANDLING AND STORAGE
Storage precautions for unpackaged product (manufacturing environment): Store in a well-ventilated place. Keep
cool. Minimize inventory. Keep container tightly closed. It is suggested that this material be “locked up” or stored in an
area where production inventory may be controlled by authorized personnel. Use only non-sparking tools. Use
explosion-proof electrical/ventilating/lighting equipment.
Take precautionary measures against static discharge.
Appropriate fire suppression and detection equipment should be utilized. Store on spill pallets or other locations where
spill containment will be easily accessible.
Keep away from open drains and access to the environment.
General notes on storage:
Incompatible materials: Oxidizers, acids, bases. Store away from incompatible materials.
Maintain a clean work environment which includes use of properly functioning containers, proper housekeeping practices.
General notes on handling:
Employees should not eat, drink or smoke while working with flammable materials. Employees should be advised to wear
appropriate protective equipment in the manufacturing environment. See section 8 of this document for protective
equipment selection. All manufacturing should be performed indoors, in an enclosed environment free from uncontrolled
ignition sources. Employees should be advised not to handle flammable products in close proximity to incompatible
materials.
Please refer to section 8 of this document for recommended equipment to be used in a manufacturing environment.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters – these criteria have been published by the referenced authority to establish exposure limits in the
work environment. Employee work areas should be monitored to ensure that permissible limits are not exceeded during
the work day. These references do not coincide with product use. These references are meant to be in association with
the manufacturing environment.
Occupational Exposure Values:
OSHA PEL-TWA :
OSHA PEL-STEL/CEILING:
ACGIH TLV-TWA:
ACGIH STEL/CEILING:
Acetone – 1000 ppm
None established
Acetone: 500 ppm
Acetone: 750ppm
WORK HYGIENIC PRACTICES: Ensure all work surfaces are maintained, to prevent contamination.
ENGINEERING CONTROLS: None required for product use. For handling large quantities of material, such as in the
manufacturing of product, ventilation should be utilized. This ventilation should be compatible with the control of
flammable materials. Exhaust ventilation should be utilized to maintain air concentrations of material below the
occupational exposure guidelines noted above.
Local exhaust ventilation is not typically required for product use. For handling large quantities of material, such as in the
manufacturing of product -- Local Exhaust: Explosion proof. Mechanical (general): Explosion proof.
Issue Date: June 5, 2012
PAGE 4 OF 8
Supersedes Date: Initial Document
Acetone Nail Enamel Removers
(Bottles and Pen Dispensers)
Personal Protective Equipment: Consistent with good hygiene practices, personal protective equipment (PPE) should
be used in conjunction with other control measures including engineering controls, ventilation and isolation. See also
Section 5 of this document for PPE advice, in the event of an emergency.
RESPIRATORY PROTECTION (NON-EMERGENCY): Respiratory protection is not required for product use. For
manufacturing of product, respiratory protection may be considered. Ensure that the respirator meets current local
occupational health and safety standards. Organic vapor cartridges should be utilized with filtering respiratory protection.
EYE/FACE PROTECTION (NON-EMERGENCY): None required for product use. For handling of large quantities of
liquid material, safety glasses with side shields/goggles are recommended.
SKIN PROTECTION (NON-EMERGENCY): None required for product use. For handling large quantities of material,
such as in product manufacturing, plastic or rubber gloves should be considered for use. Tyvek clothing may also be
suitable for handling large quantities of material in the manufacturing environment.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Colored or clear, free-flowing liquid dispensed from bottle or pen.
ODOR: The product has a solvent odor associated with it (acetone odor).
ODOR THRESHOLD: The fragrance of the material will be noticeable when very little product has been dispensed.
pH: Not available (non-aqueous)
MELTING POINT:
F: N/A C: N/A
FREEZING POINT:
F: ~ -140
BOILING POINT:
F: ~133
FLASH POINT:
F: -4 C : -20
C: ~ -95.6
C: ~ 56.1
METHOD USED: Closed Cup
EVAPORATION RATE: >6 for product
(Butyl acetate = 1)
FLAMMABILITY: flammable liquid
FLAMMABLE LIMITS IN AIR (% BY VOLUME): ACETONE: 12.8% UEL; 2.5% LEL;
VAPOR PRESSURE ( mmHg):
@ 70F ; 21 C: 180
VAPOR DENSITY (AIR = 1):
@ 70F; 21 C: approximately 2
RELATIVE DENSITY/SPECIFIC GRAVITY (H2O = 1): approximately 0.79
SOLUBILITY IN WATER: Soluble in cold water
PARTITIION COEFFICIENT: Octanol/Water: 0.58 (calculated); Water/Air: 334 (Measured)
AUTOIGNITION TEMPERATURE: F: 869 C: 465 (as acetone)
DECOMPOSITION TEMPERATURE: Not available
VISCOSITY: < 1cps; free-flowing like water
Issue Date: June 5, 2012
PAGE 5 OF 8
Supersedes Date: Initial Document
Acetone Nail Enamel Removers
(Bottles and Pen Dispensers)
SECTION 10: STABILITY AND REACTIVITY
REACTIVITY: This material is not considered reactive under typical handling and storage conditions.
STABILITY: Product is stable under standard pressure and temperature.
POSSIBILITY OF HAZARDOUS REACTIONS: None known. Hazardous polymerization is not expected to occur.
CONDITIONS TO AVOID: Heat, fire, flame and other sources of ignition.
INCOMPATIBILITY (MATERIAL TO AVOID): Oxidizing agents and acids/bases.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide/carbon dioxide, nitrogen oxides.
SECTION 11: TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS:
SKIN CORROSION/IRRITATION: Overexposure may cause skin irritation or dryness
SERIOUS EYE DAMAGE OR IRRITATION: Serious eye irritation upon contact
RESPIRATORY OR SKIN SENSITIZATION: None expected
INGESTION: Harmful if swallowed
INHALATION: May cause drowsiness/dizziness
CARCINOGENICITY:
OSHA: Not recognized as carcinogenic
NTP:
Not recognized as carcinogenic
ACGIH: Acetone has been denoted to have a carcinogencity category of TLV-A4. This reference indicates that the material is a
“Probably Not Carinogenic to Humans. This category is used for agents or mixtures for which there is very little evidence suggesting
lack of carcinogencity in humans and in experimental animals. In some instances, agents or mixtures for which there is inadequate
evidence of carcinogenicity in humans but evidence suggesting lack of carcingoenicty in experimental animals, consistently and
strongly supported by a broad range of other relevant data, may be classified in this group”.
IARC: Not recognized as carcinogenic
ROUTES OF EXPOSURE: Inhalation, eyes, skin
SYMPTOMS: Symptoms may include unsteady gait, nausea, and dizziness. Skin redness, dryness or itchiness may occur with overexposure to the product. Watering, stinging or itching eyes may occur with direct contact.
CHRONIC HEALTH EFFECTS: None anticipated
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known.
Acute Oral Toxicity (LD50) acetone: 8400 mg/kg (Rat)
Acute Toxicity of the vapor (LC50) acetone: 50,000 mg/m3; 8 hr (Rat)
Skin Irritation acetone: Non-Irritating (Rabbit)
Eye Irritation acetone: Highly Irritating (Draize test; Rabbit)
Respiratory Irritation acetone (RD50): Weakly Irritating (Mouse)
Sensitization acetone: Not sensitizing
Repeated Dose Toxicity (OECD 408) acetone: NOEL: 1% (900 mg/kg/day) Rat: male
Developmental Toxicity/Teratogencity (OECD 414) acetone: NOEL: teratogencity: >26, 1110 mg/m3 (Rat)
NOEL: developmental 5330 mg/m3 (rat)
Issue Date: June 5, 2012
PAGE 6 OF 8
Supersedes Date: Initial Document
Acetone Nail Enamel Removers
(Bottles and Pen Dispensers)
SECTION 12: ECOLOGICAL INFORMATION
Contact with the environment should be avoided. Spills and leaks should be immediately cleaned up and removed. All precautions
should be taken to prevent contact with the environment. Published information regarding ingredients listed on this document area
found below; where data is not listed, documentation was unavailable.
ACUTE AND PROLONGED TOXICITY TO AQUATIC ORGANISMS
INGREDIENT NAME
Acetone
Acetone
RESULT
SPECIES
LC50 7400 mg/l
LC50 15,800 mg/L
Rainbow Trout
Daphnia magna
EXPOSURE
96 h
8h
Acetone is noted to volatilize, leach and biodegrades fairly rapidly in soil and water by both aerobic and anaerobic means.
Significant accumulation in sediment is not expected after release. Acetone is miscible is water and does not hydrolyze.
Bioconcentration acetone: Atlantic Cod BCF 0.65
Oxygen demand acetone: Theorectical (ThOD): 2.20 g O2/g/ Chemical (COD): 2.00 g O2/g
SECTION 13: DISPOSAL CONSIDERATIONS
Those responsible for the performance of disposal, recycling or reclamation activities should refer to section 8 of
this document for advice on personal protective equipment and exposure controls.
WASTE DISPOSAL CONTAINERS: Appropriate US DOT containers should be utilized which may include cardboard
boxes for products, metal or plastic drums for liquids. These containers should meet the packaging specifications
required for DOT compliance.
WASTE DISPOSAL METHOD: Nail enamel remover products are ignitable (D001) RCRA hazardous wastes when
intended for disposal. Controlled incineration at a hazardous waste facility is the recommended technology for treatment
and disposal. This material must not be disposed through sewage.
RCRA HAZARD CLASS: D001 Follow all local governmental requirements intended for disposal.
SECTION 14: TRANSPORT INFORMATION
North American Ground Transportation
•
In Consumer Packaging: Limited Quantity/Consumer Commodity
•
PACKAGED IN OTHER THAN CONSUMER PACKAGING:
ID NUMBER: UN 1266
PROPER SHIPPING NAME: Perfumery Products
HAZARD CLASS: 3
PACKING GROUP: II
LABEL STATEMENTS: Flammable Liquid
Issue Date: June 5, 2012
PAGE 7 OF 8
Supersedes Date: Initial Document
Acetone Nail Enamel Removers
(Bottles and Pen Dispensers)
Transport Via Water
•
In Consumer Packaging: Limited Quantity
ID NUMBER: UN 1266
PROPER SHIPPING NAME: Perfumery Products
HAZARD CLASS: 3
PACKING GROUP: II
LABEL STATEMENTS:
•
PACKAGED IN OTHER THAN CONSUMER PACKAGING:
ID NUMBER: UN 1266
PROPER SHIPPING NAME: Perfumery Products
HAZARD CLASS: 3
PACKING GROUP: II
LABEL STATEMENTS: Flammable Liquid
Transport Via Air Domestic/International
•
In Consumer Packaging: Limited Quantity/Consumer Commodity ID 8000
•
PACKAGED IN OTHER THAN CONSUMER PACKAGING:
ID NUMBER: UN 1266
PROPER SHIPPING NAME: Perfumery Products
HAZARD CLASS: 3
PACKING GROUP: II
LABEL STATEMENTS: Flammable Liquid
Please be aware of carrier transport variations before shipping hazardous materials
SECTION 15: REGULATORY INFORMATION
National Fire Protection Association Codes: Health: 2 Fire: 3 Reactivity: 0 Other: None
Workplace Hazardous Materials Identification System (as acetone): Class B Flammable Material; D2B Poisonous
and infectious material - Toxic
US DOT/IATA//IMDG: See section 14 above
This regulatory information represents the product, in its consumer packaging.
SECTION 16: OTHER INFORMATION
PREPARATION INFORMATION: This is the first issuance of this document.
Author: Chandra L. Jennings
Issue Date: June 5, 2012
PAGE 8 OF 8
Supersedes Date: Initial Document
Material Safety Data Sheet
U.S. Department of Labor
Products associated with this document are exempt from
OSHA’s Hazard Communication Standard
29 CFR 1910.1200, due to low presence or no presence of
hazardous materials. Standard must be
consulted for specific requirements and reporting thresholds.
Occupation Safety and Health Administration
(Non-Mandatory Form)
Form Approved
Non-Haz
OMB No. 1218-0072
IDENTITY
Note: Blank spaces are not permitted. If any item is not applicable, or no
information is available, the space must be marked to indicate that.
L’Oreal Non-Hazardous hair styling, cosmetic
and/or skin care products
Section I
Manufacturer’s Name
Emergency Telephone Number
L'Oreal USA Products, Inc.
(800) 535-5053 (Int’l 352-323-3500)
Address (Number, Street, City, State, and ZIP Code)
Telephone Number For Information
111 Terminal Avenue
(732) 499-2745
Date Prepared
Clark, NJ
07066
May 10, 2005
Signature of Preparer (optional)
CLJ/GCD
Section II - Hazardous Ingredients/Identity Information
Hazardous Components (Specific Chemical Identity;Common Name(s))
OSHA PEL
ACGIH
TLV
Other Limits
Recommended
% (optional)
Not applicable
Section III - Physical/Chemical Characteristics
B oi l i ng P oi nt
(Liquids)
Specific Gravity (H2O = 1)
varies
Vapor Pressure (mm Hg)
>1
M e l ti n g P o i n t
N/A
Vapor Density (AIR = 1)
(Solids)
varies
Evaporation Rate
>1
(Butyl Acetate = 1)
<1
S o l u b i l i ty i n W a te r
Generally soluble or miscible
Appearance and Odor
May have a mild to moderate fragrance
Section IV - Fire and Explosion Hazard Data
Flash Point (Method Used)
Flammable Limits
LE L
UEL
>200°F
Not applicable
N/A
N/A
Extinguishing Media
Carbon dioxide, dry chemical, foam, and/or water spray.
Special Fire Fighting Procedures
Fires involving bulk product may be extinguished with carbon dioxide, dry chemical,
and/or foam. Water spray may be used to soak corrugated shipping containers of finished
product if involved in a fire.
Unusual Fire and Explosion Hazards
None; however, observe usual precautions for handling of combustible materials. For
manufacturing, minimize airborne vapor levels through engineering controls.
Forms published by ChemSW (707)864-0845
Non-Haz
Avoid heat, fire, and other sources of
ignition.
Section V - Reactivity Data
S ta b i l i ty
Unstable
Conditions to
A v oi d
S ta b l e
X
Incompatibility (Materials to Avoid)
Oxidizing agents and nitric acid.
Hazardous Decomposition or Byproducts
Silicon dioxide, carbon monoxide, carbon dioxide.
Hazardous
May Occur
Polymerization
Will Not Occur
Conditions to
A v oi d
X
None known.
In h a l a ti o n ?
S k i n?
In g e s ti o n ?
Yes
Yes
Yes
Section VI - Health Hazard Data
Route(s) of Entry:
Health Hazards (Acute and Chronic)
No health hazards anticipated.
Carcinogenicity:
NTP?
IARC Monographs?
OSHA Regulated?
No
No
No
Signs and Symptoms of Exposure
No health hazards anticipated.
Medical Conditions Generally Aggravated by Exposure
None known.
Emergency and First Aid Procedure
If in eyes, flush with plenty of water for at least 15 minutes. Get medical attention
if irritation occurs. If swallowed, drink one or two glasses of water or milk and
consult a physician. If on skin, wash with soap and water.
Section VII - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled
Eliminate all sources of ignition. Dike and contain the free liquid, if any, and absorb
on vermiculite, spill pillows, or other absorbants. Containerize spent absorbants in
suitable containers for disposal. Wash spill area with detergent solution as necessary.
Waste Disposal Method
Non-hazardous products are not regulated as hazardous wastes when intended for
disposal. However, incineration is the recommended method of treatment and disposal for
such products.
Precautions to be Taken in Handling and Storage
Store bulk quantities in a cool, well-ventilated room. Limit quantities on hand to the
extent possible. Store away from possible sources of ignition. Observe usual
precautions relative to static electricity. Avoid oxidizing agents and nitric acid.
Other Precautions
For external use only. Use only as directed.
Section VIII - Control Measures
For routine manufacturing/filling operations, none generally required. For spills, wear
an approved self-contained breathing apparatus.
V e n ti l a ti o n
Local Exhaust
S pec i al
Explosion-Proof
Mechanical(General)
Other
Explosion-Proof
Non-Haz
Protective Gloves
Rubber or plastic gloves for bulk quantities.
Other Protective Clothing or Equipment
Safety glasses and protective clothing for bulk quantities.
Work/Hygienic Practices
OSHA hazard classification: Non-Hazardous
DOT classification: Bulk - Not regulated
Finished Product - Not regulated.
Forms published by ChemSW (707)864-0845