Material Safety Data Sheet

Transcription

Keson Industries, Inc. 810 Commerce Street Aurora, IL 60504 Date Prepared: January 1, 2013 MATERIAL SAFETY DATA SHEET SECTION 1 Concentrated (color) indicator Marking Chalk-‐Blue Product Name: For Information Call: 1-‐800-‐345-‐3766 SECTION II-‐Hazardous Ingredients of Mixture Principal Component (s) Ultramarine Blue Calcium Carbonate Silicon Dioxide Boiling Point: N/A Vapor Pressure: N/A % Volatile by weight: N/A Appearance: Odorless Blue Powder CAS # 57455-‐37-‐5 3
471-‐34-‐1 15 mg/m 7631-‐86-‐9 OSHA PEL ACGIH, TLV 3
NA 10 mg/m 3
10 mg/m 3
3
6.00 mg/m 10.00 mg/m SECTION III-‐Physical Data Specific Gravity (H2O=1) 2.4 Solubility in Water: Negligible Vapor Pressure: N/A pH 5-‐8 (5% solution) SECTION IV-‐ Fire and Explosion Data Flash Point: Non-‐Flammable Extinguishing Media: Non-‐Flammable Special Firefighting Procedures: NIOSH Approved respirator and protective clothing should be worn. Use water spray to cool equipment and containers. Unusual Fire Explosion Hazards: None known. SECTION V-‐Health Hazard Data Routes of Entry: Skin-‐Yes, Inhalation-‐Yes, Ingestion-‐Yes, Eyes-‐Yes. Carcinogenicity-‐Calcium Carbonate contains crystalline silica at levels between 0.01-‐2%. There is some evidence that this material may be carcinogenic. Limit exposure to the lowest limit possible. Effects of Overexposure: Eye Contact-‐ Irritating to eyes Skin Contact-‐ None noted Inhalation-‐ May cause irritation to the nose, throat and respiratory tract. Ingestion-‐ Harmful or fatal if swallowed. Emergency First Aid Procedures: Eye Contact: Flush with warm water, lifting the eyelids periodically for 15 minutes. Consult a physician if condition Keson Industries, Inc. 810 Commerce Street Aurora, IL 60504 Date Prepared: January 1, 2013 SECTION VI-‐Reactivity Data Stability: Stable Conditions to avoid: None known. Incompatibility (materials to avoid): Strong acids liberate carbon dioxide. Hazardous Decomposition Products: Combustion will produce toxic oxides of carbon and calcium oxide. Hazardous Polymerization: Will not occur. SECTION VII-‐Spill or Leak Procedures Vacuum or scoop material into approved containers for reclamation or disposal. If excessive dust is generated, wear NIOSH approved respirator for mineral dust. SECTION VIII-‐Special Protection Information Respiratory Protection: An approved NIOSH respirator should be worn when TWA limits are exceeded. Ventilation: Use local ventilation to keep dust levels below recommended exposure limits. If exposure limits are exceeded, a NIOSH approved respirator for mineral dust should be worn. Protective Clothing: Employees must wear gloves. Eye Protection: Chemical safety goggles or safety glasses with splash guards. Other Protective equipment: Eye bath and safety shower should be available. SECTION IX-‐ Special Precautions Precautions to be taken in handling and storage: Do not store near acids. Follow normal good housekeeping procedures. Other Precautions: Wash hands thoroughly after handling. Wash contaminated clothing before reuse. SECTION X-‐ Regulatory Status TSCA Inventory Status: This material is a mixture, the ingredients of which are on TSCA inventory. RCRA: This material, when disposed of, is not specifically listed as a hazardous waste according to federal regulations unless it meets the USEPA definitions for being toxic, corrosive, ignitable or reactive, or it is mixed with or comes in contact with a listed hazardous waste. Consult local, state and federal regulations. California Proposition 65: See Section XI SECTION XI-‐Other Regulatory Information CHEMICAL NAME/ CAS NUMBER CONCENTRATION STATE CODE Arsenic/7440-‐38-‐2 <30 ppm * CA, MA Cadmium/7440-‐43-‐9 <5 ppm* CA,MA Lead/7439-‐92-‐1 <30 ppm * CA Keson Industries, Inc. 810 Commerce Street Aurora, IL 60504 Date Prepared: January 1, 2013 HMIS CODE: Health Flammability Reactivity 1 0 0 MATERIAL SAFETY DATA SHEET
Klean Strip Easy Liquid Sander
Flammability
Instability
1
1
1
1
0
0
Health
PPE
X
Special
1. Product and Company Identification
HEALTH
FLAMMABILITY
PHYSICAL HAZ.
Product Code:
Product Name:
Manufacturer Information
Company Name:
Phone Number:
Emergency Contact:
Information:
Web site address:
Preparer Name:
Intended Use:
Synonyms
Page: 1
Printed: 04/29/2010
Revision: 04/23/2010
Supercedes Revision: 07/31/2003
515.1
W. M. Barr
2105 Channel Avenue
Memphis, TN 38113
(901)775-0100
3E 24 Hour Emergency Contact
(800)451-8346
W.M. Barr Customer Service
(800)398-3892
www.wmbarr.com
W.M. Barr EHS Dept
(901)775-0100
Paint Adhesion Product
QWN285
2. Hazards Identification
Emergency Overview
Caution! Harmful if swallowed. Eye irritant. Avoid contact with eyes, skin, and mucous membranes. Do not
take internally. Use only with adequate ventilation.
OSHA Regulatory Status:
This material is classified as hazardous under OSHA regulations.
Health Hazards (Acute and Chronic)
This product has not been tested to determine health effects. The health effects listed below are associated with
the individual ingredients listed in Section 3.
EYES: Can cause eye irritation. Symptoms include stinging, tearing, redness, swelling of the eyes, and blurred
vision.
SKIN: Can cause skin irritation. Prolonged or repeated contact may dry the skin or cause discomfort and
redness. Symptoms include redness, burning, drying and cracking of the skin. Burns may be possible from
prolonged contact, especially if contact with the skin is under clothing or personal protective equipment.
Individuals with sensitive skin may be more likely to develop skin irritation from contact.
INHALATION: Breathing small amounts during normal handling is not likely to cause harmful effects.
Breathing large amounts may be harmful. Symptoms usually occur at air concentrations higher than the
MATERIAL SAFETY DATA SHEET
Page: 2
Printed: 04/29/2010
This product contains ~ 5% crystalline silica in the form of quartz. In respirable form, chronic overexposure can
cause lung disease and silicosis. The silica in this product is not in respirable form. The silica is encapsulated,
which should present no health hazard due to inhalation exposure.
TARGET ORGANS: liver, stomach/intestines, lungs
PRIMARY ROUTES OF ENTRY: inhalation, absorption
Signs and Symptoms Of Exposure
See Potential Health Effects.
Medical Conditions Generally Aggravated By Exposure
None known.
3. Composition/Information on Ingredients
Hazardous Components (Chemical Name)
CAS #
1.
Dimethyl glutarate
1119-40-0
Concentration
5.0 -10.0 %
2.
Dimethyl adipate
627-93-0
1.0 -5.0 %
3.
Dimethyl succinate
4.
Ethylene glycol monopropyl ether {(a glycol
106-65-0
1.0 -5.0 %
2807-30-9
7.0 -13.0 %
9036-19-5
1.0 -5.0 %
14808-60-7
3.0 -7.0 %
ether)}
5.
Octylphenoxypolyethoxyethanol
6.
Quartz {Silica-crystalline; Cistobalite;
Tridymite}
4. First Aid Measures
Emergency and First Aid Procedures
INHALATION:
If user experiences breathing difficulty, move to air free of vapors. Administer oxygen or artificial respiration
until medical assistance can be rendered.
SKIN CONTACT:
Immediately wash with soap and water. Seek medical attention if irritation from contact persists.
EYE CONTACT:
Immediately flush with water, remove any contact lens, and continue flushing with water for at least 15 minutes.
Get medical attention immediately.
INGESTION:
Do not induce vomiting, unless directed to by medical personnel. Call your poison control center, hospital,
emergency room, or physician immediately for instructions. Do not give anything by mouth to an unconscious
person.
Note to Physician
Page: 3
Printed: 04/29/2010
Unusual Fire and Explosion Hazards
Ethylene glycol monopropyl ether may form peroxides of unknown stability when involved in a fire.
Hazardous Combustion Products
Oxides of carbon
Suitable Extinguishing Media
Non-combustible liquid - use extinguishing media for underlying cause of fire.
Unsuitable Extinguishing Media
None known.
6. Accidental Release Measures
Steps To Be Taken In Case Material Is Released Or Spilled
Isolate the immediate area. Prevent unauthorized entry. Stay upwind, out of low areas, and ventilate closed
spaces before entering. Do not touch or walk through spilled material. Stop leak if you can do so without risk.
Prevent entry into waterways, sewers, or confined areas. A vapor suppressing foam may be used to reduce
vapors. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to compatible
containers. For large spills, dike ahead of the spill.
7. Handling and Storage
Precautions To Be Taken in Handling
Read carefully all cautions and directions on product label before use. Since empty container retains residue,
follow all label warnings even after container is empty. Dispose of empty container according to all waste
regulations. Do not reuse this container.
Avoid contact with eyes, skin, and mucous membranes. Do not take internally.
Precautions To Be Taken in Storing
Keep container tightly closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated
temperatures.
8. Exposure Controls/Personal Protection
CAS #
OSHA PEL
ACGIH TLV
Other Limits
1.
1119-40-0
No data.
No data.
No data.
Dimethyl glutarate
2.
Dimethyl adipate
627-93-0
No data.
No data.
No data.
3.
Dimethyl succinate
106-65-0
No data.
No data.
No data.
4.
2807-30-9
No data.
No data.
No data.
ether)}
5.
6.
9036-19-5
14808-60-7
No data.
No data.
No data.
8825 ppm/(%SiO2+5)
0.05 mg/m3 (R)
No data.
Tridymite}
Respiratory Equipment (Specify Type)
For consumer use, use only with adequate ventilation. If strong odor is noticed or you experience slight dizziness
- STOP - ventilation is inadequate. Leave area immediately.
For OSHA controlled workplace and other regular users - Use only with adequate ventilation under engineered air
Page: 4
Printed: 04/29/2010
Other Protective Clothing
Various application methods can dictate use of additional protective safety equipment, such as impermeable
aprons, etc., to minimize exposure. Before reuse, thoroughly clean any clothing or protective equipment that has
been contaminated by prior use. Discard any clothing or other protective equipment that cannot be
decontaminated, such as gloves or shoes.
Ventilation
Use only with adequate ventilation to prevent build-up of vapors. Open all windows and doors. Use only with a
cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight
dizziness, headache, nausea, or eye-watering - STOP - ventilation is not adequate. Leave area immediately and
move to fresh air.
Work/Hygienic/Maintenance Practices
Wash hands thoroughly after use and before eating, drinking, or smoking.
Do not eat, drink, or smoke in the work area.
Facilities storing or handling this material should be equipped with an emergency eyewash and safety shower.
9. Physical and Chemical Properties
Physical States:
Melting Point:
Boiling Point:
Autoignition Pt:
Flash Pt:
Explosive Limits:
Specific Gravity (Water = 1):
Density:
Bulk density:
Vapor Pressure (vs. Air or mm Hg):
Vapor Density (vs. Air = 1):
Evaporation Rate (vs Butyl
Acetate=1):
Solubility in Water:
Percent Volatile:
Heat Value:
Particle Size:
Corrosion Rate:
pH:
Appearance and Odor
[ ] Gas
[ X ] Liquid
No data.
> 212.00 F
No data.
No data.
LEL: No data.
No data.
8.6 LB/GL
No data.
No data.
>1
<1
[ ] Solid
UEL: No data.
No data.
92.8 % by weight.
No data.
No data.
No data.
No data.
milky emulsion
10. Stability and Reactivity
Stability:
Unstable [
]
Stable [ X ]
Possibility of Hazardous Reactions: Will occur [
Conditions To Avoid - Hazardous Reactions
]
Page: 5
Printed: 04/29/2010
Will not occur [ X ]
No data available.
11. Toxicological Information
This product has not been tested as a whole. Information below will be for individual ingredients.
Chronic Toxicological Effects
This product has not been tested as a whole. Information below will be for individual ingredients.
Carcinogenicity/Other Information
No data available.
CAS #
NTP
IARC
ACGIH
OSHA
1.
1119-40-0
n.a.
n.a.
n.a.
n.a.
Dimethyl glutarate
2.
Dimethyl adipate
627-93-0
n.a.
n.a.
n.a.
n.a.
3.
Dimethyl succinate
106-65-0
n.a.
n.a.
n.a.
n.a.
4.
2807-30-9
n.a.
n.a.
n.a.
n.a.
9036-19-5
n.a.
n.a.
n.a.
n.a.
Known
2B
A2
n.a.
ether)}
5.
6.
14808-60-7
Tridymite}
12. Ecological Information
No information available for this product as a whole.
13. Disposal Considerations
Waste Disposal Method
Dispose of in accordance with local, state, and federal laws.
Do not place material in general trash.
Do not allow material to enter bodies of water or sewers.
14. Transport Information
LAND TRANSPORT (US DOT)
DOT Proper Shipping Name
Additional Transport Information
Paint Related Material
For D.O.T. information, contact W.M. Barr Technical Services at 1-800-398-3892.
The shipper/supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity,
Limited Quantity, Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat
Regulations. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these
exceptions.
15. Regulatory Information
Page: 6
Printed: 04/29/2010
CAS #
Sec.302 (EHS)
Sec.304 RQ
Sec.313 (TRI)
Sec.110
5.
9036-19-5
No
No
No
No
6.
14808-60-7
No
No
No
No
Tridymite}
US EPA CAA, CWA, TSCA
CAS #
EPA CAA
EPA CWA NPDES
EPA TSCA
CA PROP 65
1.
Dimethyl glutarate
1119-40-0
HAP, ODC ()
No
Inventory, 4 Test,
No
2.
Dimethyl adipate
627-93-0
HAP, ODC ()
No
12(b)
Inventory, 4 Test,
No
12(b)
3.
Dimethyl succinate
106-65-0
HAP, ODC ()
No
Inventory, 4 Test,
No
12(b)
4.
2807-30-9
HAP, ODC ()
No
Inventory
No
9036-19-5
HAP, ODC ()
No
Inventory, 8A PAIR
No
14808-60-7
HAP, ODC ()
No
Inventory
No
ether)}
5.
6.
Tridymite}
SARA (Superfund Amendments and
Reauthorization Act of 1986) Lists:
Sec.302:
EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000
LB TPQ if not volatile.
Sec.304:
EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. **
indicates statutory RQ.
Sec.313:
EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a
chemical category.
Sec.110:
EPA SARA 110 Superfund Site Priority Contaminant List
TSCA (Toxic Substances Control
Act) Lists:
Inventory:
Chemical Listed in the TSCA Inventory.
5A(2):
Chemical Subject to Significant New Rules (SNURS)
6A:
Commercial Chemical Control Rules
8A:
Toxic Substances Subject To Information Rules on Production
8A CAIR:
Comprehensive Assessment Information Rules - (CAIR)
8A PAIR:
Preliminary Assessment Information Rules - (PAIR)
8C:
Records of Allegations of Significant Adverse Reactions
8D:
Health and Safety Data Reporting Rules
8D TERM:
Health and Safety Data Reporting Rule Terminations
12(b):
Notice of Export
Other Important Lists:
CWA NPDES:
EPA Clean Water Act NPDES Permit Chemical
CAA HAP:
EPA Clean Air Act Hazardous Air Pollutant
CAA ODC:
EPA Clean Air Act Ozone Depleting Chemical (1=CFC, 2=HCFC)
CA PROP 65:
California Proposition 65
International Regulatory Lists:
Page: 7
Printed: 04/29/2010
16. Other Information
Company Policy or Disclaimer
The information contained herein is presented in good faith and believed to be accurate as of the effective date
shown above. This information is furnished without warranty of any kind. Employers should use this information
only as a supplement to other information gathered by them and must make independent determination of
suitability and completeness of information from all sources to assure proper use of these materials and the safety
and health of employees. Any use of this data and information must be determined by the user to be in
accordance with applicable federal, state and local laws and regulations.
4291
13 00
DATE OF PREPARATION
May 24, 2013
SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
4291
PRODUCT NAME
KRYLON® Camouflage Paint, Khaki
MANUFACTURER'S NAME
Krylon Products Group
Cleveland, OH 44115
Telephone Numbers and Websites
Product Information
(800) 247-3268
www.krylon.com
Regulatory Information (216) 566-2902
Medical Emergency (216) 566-2917
Transportation Emergency* (800) 424-9300
*for Chemical Emergency ONLY (spill, leak, fire, exposure, or
accident)
page 1 of 6
4291
SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS
% by Weight
17
8
4
12
0.5
3
35
1
CAS Number
74-98-6
106-97-8
64742-89-8
108-88-3
100-41-4
1330-20-7
67-64-1
108-10-1
2
112926-00-8
3
13463-67-7
Ingredient
Units
Propane
ACGIH TLV
1000 PPM
OSHA PEL
1000 PPM
Butane
ACGIH TLV
1000 PPM
OSHA PEL
800 PPM
V. M. & P. Naphtha
ACGIH TLV
300 PPM
OSHA PEL
300 PPM
OSHA PEL
400 PPM STEL
Toluene
ACGIH TLV
20 PPM
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
Ethylbenzene
ACGIH TLV
20 PPM
OSHA PEL
100 PPM
OSHA PEL
125 PPM STEL
Xylene
ACGIH TLV
100 PPM
ACGIH TLV
150 PPM STEL
OSHA PEL
100 PPM
OSHA PEL
150 PPM STEL
Acetone
ACGIH TLV
500 PPM
ACGIH TLV
750 PPM STEL
OSHA PEL
1000 PPM
Methyl Isobutyl Ketone
ACGIH TLV
50 PPM
ACGIH TLV
75 PPM STEL
OSHA PEL
50 PPM
OSHA PEL
75 PPM STEL
Amorphous Precipitated Silica
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
6 mg/m3 as Dust
Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
5 mg/m3 Respirable Fraction
Vapor Pressure
760 mm
760 mm
12 mm
22 mm
7.1 mm
5.9 mm
180 mm
16 mm
SECTION 3 — HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
INHALATION of vapor or spray mist.
EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSURE
EYES: Irritation.
SKIN: Prolonged or repeated exposure may cause irritation.
INHALATION: Irritation of the upper respiratory system.
HMIS Codes
Health 2*
Flammability 3
Reactivity 0
May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.
Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems:
the liver
the urinary system
the cardiovascular system
the reproductive system
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
None generally recognized.
CANCER INFORMATION
For complete discussion of toxicology data refer to Section 11.
page 2 of 6
4291
SECTION 4 — FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:
Flush eyes with large amounts of water for 15 minutes. Get medical attention.
Wash affected area thoroughly with soap and water.
Remove contaminated clothing and launder before re-use.
If affected, remove from exposure. Restore breathing. Keep warm and quiet.
Do not induce vomiting. Get medical attention immediately.
SECTION 5 — FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
EXTINGUISHING MEDIA
Propellant < 0 °F
0.9
12.8
Carbon Dioxide, Dry Chemical, Foam
UNUSUAL FIRE AND EXPLOSION HAZARDS
Containers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.
During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately
apparent. Obtain medical attention.
SPECIAL FIRE FIGHTING PROCEDURES
Full protective equipment including self-contained breathing apparatus should be used.
Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure
build-up and possible autoignition or explosion when exposed to extreme heat.
SECTION 6 — ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition. Ventilate the area.
Remove with inert absorbent.
SECTION 7 — HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off
stoves, electric tools and appliances, and any other sources of ignition.
Consult NFPA Code. Use approved Bonding and Grounding procedures.
Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children.
SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USE
Use only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.
Wash hands after using.
This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous
levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts
are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may
cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other
hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper
containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your
local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure
limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this
product, underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear
chemical resistant gloves.
EYE PROTECTION
Wear safety spectacles with unperforated sideshields.
page 3 of 6
4291
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.
SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES
6.36 lb/gal
761 g/l
0.77
<0 - 325 °F
<-18 - 162 °C
Not Available
90%
Faster than
ether
VAPOR DENSITY Heavier than air
SOLUBILITY IN WATER Not Available
pH 7.0
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)
Volatile Weight 46.81%
Less Water and Federally Exempt Solvents
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
SECTION 10 — STABILITY AND REACTIVITY
STABILITY — Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
HAZARDOUS DECOMPOSITION PRODUCTS
By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION
Will not occur
SECTION 11 — TOXICOLOGICAL INFORMATION
CHRONIC HEALTH HAZARDS
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.
Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient
evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in
certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals
exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans.
IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No
significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such
as paint."
page 4 of 6
4291
TOXICOLOGY DATA
CAS No.
74-98-6
106-97-8
64742-89-8
108-88-3
100-41-4
1330-20-7
67-64-1
108-10-1
112926-00-8
13463-67-7
Ingredient Name
Propane
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
4000 ppm
5000 mg/kg
LC50 RAT
LD50 RAT
4HR
Not Available
3500 mg/kg
LC50 RAT
LD50 RAT
4HR
5000 ppm
4300 mg/kg
LC50 RAT
LD50 RAT
4HR
Not Available
5800 mg/kg
LC50 RAT
LD50 RAT
Amorphous Precipitated Silica
LC50 RAT
LD50 RAT
Titanium Dioxide
LC50 RAT
LD50 RAT
4HR
Not Available
2080 mg/kg
4HR
Not Available
4999. mg/kg
4HR
Not Available
Not Available
Butane
V. M. & P. Naphtha
Toluene
Ethylbenzene
Xylene
Acetone
SECTION 12 — ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
No data available.
SECTION 13 — DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.
SECTION 14 — TRANSPORT INFORMATION
Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping
description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of
transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport.
US Ground (DOT)
May be classed as LTD. QTY. OR ORM-D
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)
Canada (TDG)
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)
IMO
May be shipped as Limited Quantity
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D)
IATA/ICAO
UN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY
page 5 of 6
4291
SECTION 15 — REGULATORY INFORMATION
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
108-88-3
Toluene
12
100-41-4
Ethylbenzene
0.5
1330-20-7
Xylene
3
108-10-1
1
CALIFORNIA PROPOSITION 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.
SECTION 16 — OTHER INFORMATION
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the
MSDS contains all of the information required by the CPR.
The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other
additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no
warranties, express or implied, and assume no liability in connection with any use of this information.
page 6 of 6
KDQ5223
17 00
DATE OF PREPARATION
May 24, 2013
PRODUCT NUMBER
KDQ5223
PRODUCT NAME
KRYLON® Chalkboard Paint
MANUFACTURER'S NAME
Cleveland, OH 44115
Product Information
(800) 247-3268
www.krylon.com
accident)
% by Weight
2
20
2
CAS Number
111-77-3
14808-60-7
1333-86-4
Ingredient
Units
2-(2-Methoxyethoxy)-ethanol
ACGIH TLV
OSHA PEL
Quartz
ACGIH TLV
0.025
OSHA PEL
0.1
Carbon Black
ACGIH TLV
3.5
OSHA PEL
3.5
Vapor Pressure
Not Available
Not Available
1 mm
mg/m3 as Resp. Dust
mg/m3 as Resp. Dust
MG/M3
MG/M3
ROUTES OF EXPOSURE
EYES: Irritation.
HMIS Codes
Health 2*
Flammability 0
Reactivity 0
In a confined area vapors in high concentration may cause headache, nausea or dizziness.
CANCER INFORMATION
EYES:
SKIN:
INHALATION:
INGESTION:
page 1 of 4
KDQ5223
FLASH POINT
Not Applicable
LEL
UEL
FLAMMABILITY CLASSIFICATION
Not
Not
Not Applicable
Applicable
Applicable
EXTINGUISHING MEDIA
Carbon Dioxide, Dry Chemical, Alcohol Foam
Closed containers may explode (due to the build-up of pressure) when exposed to extreme heat.
STORAGE CATEGORY
Not Applicable
Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally.
Keep out of the reach of children.
VENTILATION
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection against materials in Section 2.
EYE PROTECTION
page 2 of 4
KDQ5223
9.89 lb/gal
1184 g/l
1.19
212 - 382 °F
100 - 194 °C
Not Available
72%
Slower than
ether
pH 9.0
1.20 lb/gal 144 g/l Less Water and Federally Exempt Solvents
0.38 lb/gal
45 g/l Emitted VOC
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
Crystalline Silica (Quartz, Cristobalite) is listed by IARC and NTP. Long term exposure to high levels of silica dust, which can occur only when
sanding or abrading the dry film, may cause lung damage (silicosis) and possibly cancer.
Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is
insufficient evidence in humans for its carcinogenicity.
TOXICOLOGY DATA
CAS No.
Ingredient Name
111-77-3
2-(2-Methoxyethoxy)-ethanol
LC50 RAT
4HR
Not Available
LD50 RAT
5500 mg/kg
14808-60-7
Quartz
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
1333-86-4
Carbon Black
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
No data available.
Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.
Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local
regulations regarding pollution.
page 3 of 4
KDQ5223
US Ground (DOT)
Not Regulated for Transportation.
Canada (TDG)
IMO
IATA/ICAO
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
Glycol Ethers
2
TSCA CERTIFICATION
page 4 of 4
51301
06 00
DATE OF PREPARATION
Jul 17, 2013
PRODUCT NUMBER
51301
PRODUCT NAME
KRYLON® ColorMaster™ with Covermax™ Technology Acrylic Crystal Clear, Gloss
MANUFACTURER'S NAME
Cleveland, OH 44115
Product Information
(800) 247-3268
www.krylon.com
accident)
% by Weight
14
13
17
3
0.4
41
4
CAS Number
74-98-6
106-97-8
108-88-3
64742-94-5
91-20-3
67-64-1
763-69-9
Ingredient
Units
Propane
ACGIH TLV
1000 PPM
OSHA PEL
1000 PPM
Butane
ACGIH TLV
1000 PPM
OSHA PEL
800 PPM
Toluene
ACGIH TLV
20 PPM
OSHA PEL
100 ppm (Skin)
OSHA PEL
150 ppm (Skin) STEL
Medium Aromatic Hydrocarbons
ACGIH TLV
Not Available
OSHA PEL
Not Available
Naphthalene
ACGIH TLV
10 PPM
ACGIH TLV
15 PPM STEL
OSHA PEL
10 PPM
OSHA PEL
15 PPM STEL
Acetone
ACGIH TLV
500 PPM
ACGIH TLV
750 PPM STEL
OSHA PEL
1000 PPM
Ethyl 3-Ethoxypropionate
ACGIH TLV
Not Available
OSHA PEL
Not Available
Vapor Pressure
760 mm
760 mm
22 mm
0.12 mm
1 mm
180 mm
1.11 mm
ROUTES OF EXPOSURE
EYES: Irritation.
HMIS Codes
Health 2*
Flammability 4
Reactivity 0
page 1 of 4
51301
the liver
the urinary system
CANCER INFORMATION
EYES:
SKIN:
INHALATION:
INGESTION:
FLASH POINT
LEL
UEL
EXTINGUISHING MEDIA
Propellant < 0 °F
0.8
12.8
STORAGE CATEGORY
Not Available
VENTILATION
page 2 of 4
51301
PROTECTIVE GLOVES
EYE PROTECTION
OTHER PRECAUTIONS
6.07 lb/gal
727 g/l
0.73
<0 - 415 °F
<-18 - 212 °C
Not Available
94%
Faster than
ether
pH 7.0
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
Naphthalene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence
in laboratory animals.
TOXICOLOGY DATA
CAS No.
Ingredient Name
74-98-6
Propane
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
106-97-8
Butane
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
108-88-3
Toluene
LC50 RAT
4HR
4000 ppm
LD50 RAT
5000 mg/kg
64742-94-5
Medium Aromatic Hydrocarbons
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
91-20-3
Naphthalene
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
67-64-1
Acetone
LC50 RAT
4HR
Not Available
LD50 RAT
5800 mg/kg
763-69-9
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
page 3 of 4
51301
No data available.
US Ground (DOT)
Canada (TDG)
IMO
UN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U
IATA/ICAO
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
108-88-3
Toluene
17
91-20-3
Naphthalene
0.3
TSCA CERTIFICATION
page 4 of 4
2338
08 00
DATE OF PREPARATION
Jul 23, 2013
PRODUCT NUMBER
2338
PRODUCT NAME
KRYLON® Fusion for Plastic® Metallic Shimmer, Nickel Shimmer
MANUFACTURER'S NAME
Cleveland, OH 44115
Product Information
(800) 247-3268
www.krylon.com
accident)
% by Weight
17
CAS Number
74-98-6
8
5
106-97-8
64742-89-8
14
108-88-3
0.5
3
100-41-4
1330-20-7
35
2
67-64-1
108-10-1
Ingredient
Propane
ACGIH TLV
OSHA PEL
Butane
ACGIH TLV
OSHA PEL
V. M. & P. Naphtha
ACGIH TLV
OSHA PEL
OSHA PEL
Toluene
ACGIH TLV
OSHA PEL
OSHA PEL
Ethylbenzene
ACGIH TLV
OSHA PEL
OSHA PEL
Xylene
ACGIH TLV
ACGIH TLV
OSHA PEL
OSHA PEL
Acetone
ACGIH TLV
ACGIH TLV
OSHA PEL
ACGIH TLV
ACGIH TLV
OSHA PEL
OSHA PEL
Units
Vapor Pressure
1000 PPM
1000 PPM
760 mm
1000 PPM
800 PPM
760 mm
300 PPM
300 PPM
400 PPM STEL
12 mm
20 PPM
100 ppm (Skin)
150 ppm (Skin) STEL
22 mm
20 PPM
100 PPM
125 PPM STEL
7.1 mm
100
150
100
150
PPM
PPM STEL
PPM
PPM STEL
5.9 mm
500 PPM
750 PPM STEL
1000 PPM
180 mm
50
75
50
75
PPM
PPM STEL
PPM
PPM STEL
16 mm
ROUTES OF EXPOSURE
page 1 of 5
2338
EYES: Irritation.
HMIS Codes
Health 2*
Flammability 3
Reactivity 1
the liver
the urinary system
CANCER INFORMATION
EYES:
SKIN:
INHALATION:
INGESTION:
FLASH POINT
LEL
UEL
EXTINGUISHING MEDIA
Propellant < 0 °F
0.9
12.8
STORAGE CATEGORY
Not Available
page 2 of 5
2338
VENTILATION
PROTECTIVE GLOVES
EYE PROTECTION
OTHER PRECAUTIONS
6.18 lb/gal
740 g/l
0.74
<0 - 325 °F
<-18 - 162 °C
Not Available
91%
Faster than
ether
pH 7.0
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
page 3 of 5
2338
TOXICOLOGY DATA
CAS No.
74-98-6
106-97-8
64742-89-8
108-88-3
100-41-4
1330-20-7
67-64-1
108-10-1
Ingredient Name
Propane
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
4000 ppm
5000 mg/kg
LC50 RAT
LD50 RAT
4HR
Not Available
3500 mg/kg
LC50 RAT
LD50 RAT
4HR
5000 ppm
4300 mg/kg
LC50 RAT
LD50 RAT
4HR
Not Available
5800 mg/kg
LC50 RAT
LD50 RAT
4HR
Not Available
2080 mg/kg
Butane
V. M. & P. Naphtha
Toluene
Ethylbenzene
Xylene
Acetone
No data available.
US Ground (DOT)
Canada (TDG)
IMO
IATA/ICAO
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
108-88-3
Toluene
14
100-41-4
Ethylbenzene
0.5
1330-20-7
Xylene
3
108-10-1
2
page 4 of 5
2338
TSCA CERTIFICATION
page 5 of 5
2410
10 00
DATE OF PREPARATION
Jul 23, 2013
PRODUCT NUMBER
2410
PRODUCT NAME
KRYLON® OSHA Colors, Safety Orange
MANUFACTURER'S NAME
Cleveland, OH 44115
Product Information
(800) 247-3268
www.krylon.com
accident)
% by Weight
15
7
1
8
38
11
6
0.3
CAS Number
74-98-6
106-97-8
100-41-4
1330-20-7
67-64-1
78-93-3
108-65-6
13463-67-7
Ingredient
Units
Propane
ACGIH TLV
1000 PPM
OSHA PEL
1000 PPM
Butane
ACGIH TLV
1000 PPM
OSHA PEL
800 PPM
Ethylbenzene
ACGIH TLV
20 PPM
OSHA PEL
100 PPM
OSHA PEL
125 PPM STEL
Xylene
ACGIH TLV
100 PPM
ACGIH TLV
150 PPM STEL
OSHA PEL
100 PPM
OSHA PEL
150 PPM STEL
Acetone
ACGIH TLV
500 PPM
ACGIH TLV
750 PPM STEL
OSHA PEL
1000 PPM
Methyl Ethyl Ketone
ACGIH TLV
200 PPM
ACGIH TLV
300 PPM STEL
OSHA PEL
200 PPM
OSHA PEL
300 PPM STEL
1-Methoxy-2-Propanol Acetate
ACGIH TLV
Not Available
OSHA PEL
Not Available
Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
Vapor Pressure
760 mm
760 mm
7.1 mm
5.9 mm
180 mm
90.6 mm
1.8 mm
ROUTES OF EXPOSURE
page 1 of 5
2410
EYES: Irritation.
HMIS Codes
Health 2*
Flammability 3
Reactivity 0
the liver
the urinary system
the hematopoietic (blood-forming) system
CANCER INFORMATION
EYES:
SKIN:
INHALATION:
INGESTION:
FLASH POINT
LEL
UEL
EXTINGUISHING MEDIA
Propellant < 0 °F
1.0
13.1
STORAGE CATEGORY
Not Available
page 2 of 5
2410
VENTILATION
PROTECTIVE GLOVES
EYE PROTECTION
OTHER PRECAUTIONS
6.29 lb/gal
753 g/l
0.76
<0 - 302 °F
<-18 - 150 °C
Not Available
93%
Faster than
ether
pH 7.0
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
Methyl Ethyl Ketone may increase the nervous system effects of other solvents.
as paint."
page 3 of 5
2410
TOXICOLOGY DATA
CAS No.
74-98-6
106-97-8
100-41-4
1330-20-7
67-64-1
78-93-3
108-65-6
13463-67-7
Ingredient Name
Propane
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
Not Available
Not Available
LC50 RAT
LD50 RAT
4HR
Not Available
3500 mg/kg
LC50 RAT
LD50 RAT
4HR
5000 ppm
4300 mg/kg
LC50 RAT
LD50 RAT
4HR
Not Available
5800 mg/kg
RAT
RAT
4HR
Not Available
2740 mg/kg
RAT
RAT
4HR
Not Available
8500 mg/kg
RAT
RAT
4HR
Not Available
Not Available
Butane
Ethylbenzene
Xylene
Acetone
Methyl Ethyl Ketone
LC50
LD50
LC50
LD50
Titanium Dioxide
LC50
LD50
No data available.
US Ground (DOT)
Canada (TDG)
IMO
IATA/ICAO
UN1950, AEROSOLS, 2.1, LIMITED QUANTITY
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
100-41-4
Ethylbenzene
1
1330-20-7
Xylene
8
TSCA CERTIFICATION
page 4 of 5
2410
page 5 of 5
SCS-036
08 00
DATE OF PREPARATION
May 24, 2013
PRODUCT NUMBER
SCS-036
PRODUCT NAME
KRYLON® SHORT CUTS™ Spray Paint, Sun Yellow
MANUFACTURER'S NAME
Cleveland, OH 44115
Product Information
(800) 247-3268
www.krylon.com
accident)
% by Weight
16
15
10
9
29
6
CAS Number
74-98-6
106-97-8
64742-89-8
64742-88-7
67-64-1
13463-67-7
Ingredient
Propane
ACGIH TLV
OSHA PEL
Butane
ACGIH TLV
OSHA PEL
V. M. & P. Naphtha
ACGIH TLV
OSHA PEL
OSHA PEL
Mineral Spirits
ACGIH TLV
OSHA PEL
Acetone
ACGIH TLV
ACGIH TLV
OSHA PEL
Titanium Dioxide
ACGIH TLV
OSHA PEL
OSHA PEL
Units
Vapor Pressure
1000 PPM
1000 PPM
760 mm
1000 PPM
800 PPM
760 mm
300 PPM
300 PPM
400 PPM STEL
12 mm
100 PPM
100 PPM
2 mm
500 PPM
750 PPM STEL
1000 PPM
180 mm
10 mg/m3 as Dust
10 mg/m3 Total Dust
ROUTES OF EXPOSURE
EYES: Irritation.
HMIS Codes
Health 2*
Flammability 4
Reactivity 0
the liver
the urinary system
page 1 of 4
SCS-036
CANCER INFORMATION
EYES:
SKIN:
INHALATION:
INGESTION:
FLASH POINT
LEL
UEL
EXTINGUISHING MEDIA
Propellant < 0 °F
0.9
12.8
STORAGE CATEGORY
Not Available
VENTILATION
page 2 of 4
SCS-036
PROTECTIVE GLOVES
EYE PROTECTION
OTHER PRECAUTIONS
6.14 lb/gal
735 g/l
0.74
<0 - 395 °F
<-18 - 201 °C
Not Available
90%
Faster than
ether
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
as paint."
TOXICOLOGY DATA
CAS No.
Ingredient Name
74-98-6
Propane
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
106-97-8
Butane
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
64742-89-8
V. M. & P. Naphtha
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
64742-88-7
Mineral Spirits
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
67-64-1
Acetone
LC50 RAT
4HR
Not Available
LD50 RAT
5800 mg/kg
13463-67-7
Titanium Dioxide
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
No data available.
page 3 of 4
SCS-036
US Ground (DOT)
Canada (TDG)
IMO
IATA/ICAO
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification.
TSCA CERTIFICATION
page 4 of 4
1601
03 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
1601
14-JAN-08
PRODUCT NAME
KRYLON® Interior/Exterior Paint, Glossy Black
HMIS CODES
Health
Flammability
Reactivity
2*
3
0
MANUFACTURER'S NAME
THE SHERWIN-WILLIAMS COMPANY
KRYLON Products Group
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 832-2541
Regulatory Information
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
14
6
1
8
39
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
100-41-4 Ethylbenzene
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
1330-20-7 Xylene
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL
67-64-1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
1601
page 2
6
108-65-6
0.4
1333-86-4
ACGIH TLV Not Available
OSHA PEL Not Available
Carbon Black
ACGIH TLV
3.5 mg/m3
OSHA PEL
3.5 mg/m3
1.8 mm
Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
EYES: Irritation.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, blood forming and reproductive
systems.
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
CANCER INFORMATION
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:
Flush eyes with large amounts of water for 15 minutes.
Get medical attention.
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
13.1
EXTINGUISHING MEDIA
1601
page 3
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if the exposure to
1601
page 4
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
6.30 lb/gal
754 g/l
SPECIFIC GRAVITY
0.76
BOILING POINT
<0 - 302 F
<-18 - 150 C
MELTING POINT
Not Available
VOLATILE VOLUME
93 %
EVAPORATION RATE
Faster than ether
VAPOR DENSITY
Heavier than air
SOLUBILITY IN WATER
N.A.
pH
7.0
Volatile Weight 51.08% Less Water and Federally Exempt Solvents
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
1601
page 5
Section 11 -- TOXICOLOGICAL INFORMATION
Methyl Ethyl Ketone may increase the nervous system effects of other
solvents.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
Ethylbenzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals. Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and liver tumors in mice.
These effects were not observed in animals exposed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
Carbon Black is classified by IARC as possibly carcinogenic to humans
(group 2B) based on experimental animal data, however, there is
TOXICOLOGY DATA
CAS No.
Ingredient Name
74-98-6
Propane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
106-97-8
Butane
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
100-41-4
Ethylbenzene
LC50
RAT
4HR
Not Available
LD50
RAT
3500
mg/kg
1330-20-7
Xylene
LC50
RAT
4HR
5000
ppm
LD50
RAT
4300
mg/kg
67-64-1
Acetone
LC50
RAT
4HR
Not Available
LD50
RAT
5800
mg/kg
78-93-3
Methyl Ethyl Ketone
LC50
RAT
4HR
Not Available
LD50
RAT
2740
mg/kg
108-65-6
LC50
RAT
4HR
Not Available
LD50
RAT
8500
mg/kg
1333-86-4
Carbon Black
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
Section 12 -- ECOLOGICAL INFORMATION
No data available.
1601
page 6
Section 13 -- DISPOSAL CONSIDERATIONS
Waste from this product may be hazardous as defined under the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
May be classed as Consumer Commodity, ORM-D
Canada (TDG)
IMO
Section 15 -- REGULATORY INFORMATION
CAS No.
CHEMICAL/COMPOUND
1330-20-7 Xylene
% by WT
1
8
% Element
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
and is based on the information available at this time. Addition of
51608
03 00
DATE OF PREPARATION
May 24, 2013
PRODUCT NUMBER
51608
PRODUCT NAME
KRYLON® ColorMaster™ with Covermax™ Technology, Gloss Smoke Gray
MANUFACTURER'S NAME
Cleveland, OH 44115
Product Information
(800) 247-3268
www.krylon.com
accident)
% by Weight
14
13
18
0.1
34
2
CAS Number
74-98-6
106-97-8
108-88-3
100-41-4
67-64-1
13463-67-7
Ingredient
Propane
ACGIH TLV
OSHA PEL
Butane
ACGIH TLV
OSHA PEL
Toluene
ACGIH TLV
OSHA PEL
OSHA PEL
Ethylbenzene
ACGIH TLV
OSHA PEL
OSHA PEL
Acetone
ACGIH TLV
ACGIH TLV
OSHA PEL
Titanium Dioxide
ACGIH TLV
OSHA PEL
OSHA PEL
Units
Vapor Pressure
1000 PPM
1000 PPM
760 mm
1000 PPM
800 PPM
760 mm
20 PPM
100 ppm (Skin)
150 ppm (Skin) STEL
22 mm
20 PPM
100 PPM
125 PPM STEL
7.1 mm
500 PPM
750 PPM STEL
1000 PPM
180 mm
10 mg/m3 as Dust
10 mg/m3 Total Dust
ROUTES OF EXPOSURE
HMIS Codes
Health 2*
51608
CANCER INFORMATION
EYES:
SKIN:
INHALATION:
INGESTION:
FLASH POINT
LEL
UEL
EXTINGUISHING MEDIA
Propellant < 0 °F
1.0
12.8
STORAGE CATEGORY
Not Available
51608
PROTECTIVE GLOVES
EYE PROTECTION
OTHER PRECAUTIONS
6.24 lb/gal
748 g/l
0.75
<0 - 238 °F
<-18 - 114 °C
Not Available
88%
Faster than
ether
pH 7.0
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
as paint."
TOXICOLOGY DATA
CAS No.
Ingredient Name
74-98-6
Propane
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
106-97-8
Butane
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
108-88-3
Toluene
LC50 RAT
4HR
4000 ppm
LD50 RAT
5000 mg/kg
100-41-4
Ethylbenzene
51608
No data available.
US Ground (DOT)
Canada (TDG)
IMO
IATA/ICAO
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
108-88-3
Toluene
18
100-41-4
Ethylbenzene
0.1
TSCA CERTIFICATION
1501
03 00
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER
DATE OF PREPARATION
1501
14-JAN-08
HMIS CODES
Health
Flammability
Reactivity
PRODUCT NAME
KRYLON® Interior/Exterior Paint, Glossy White (OSHA White)
2*
3
0
MANUFACTURER'S NAME
KRYLON Products Group
Cleveland, OH 44115
TELEPHONE NUMBERS and WEBSITES
Product Information
(800) 832-2541
(216) 566-2902
www.paintdocs.com
Medical Emergency
(216) 566-2917
Transportation Emergency
for Chemical Emergency ONLY (spill, leak,
(800) 424-9300
fire, exposure, or accident)
% by WT
14
6
1
7
36
Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
CAS No. INGREDIENT
UNITS
VAPOR PRESSURE
74-98-6 Propane
ACGIH TLV
2500 ppm
760 mm
OSHA PEL
1000 ppm
106-97-8 Butane
ACGIH TLV
800 ppm
760 mm
OSHA PEL
800 ppm
ACGIH TLV
100 ppm
7.1 mm
ACGIH TLV
125 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
125 ppm STEL
1330-20-7 Xylene
ACGIH TLV
100 ppm
5.9 mm
ACGIH TLV
150 ppm STEL
OSHA PEL
100 ppm
OSHA PEL
150 ppm STEL
67-64-1 Acetone
ACGIH TLV
500 ppm
180 mm
ACGIH TLV
750 ppm STEL
OSHA PEL
1000 ppm
1501
page 2
6
108-65-6
6
13463-67-7
ACGIH TLV Not Available
1.8 mm
OSHA PEL Not Available
Titanium Dioxide
ACGIH TLV
10 mg/m3 as Dust
OSHA PEL
10 mg/m3 Total Dust
OSHA PEL
Section 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSURE
EYES: Irritation.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death.
Prolonged overexposure to solvent ingredients in Section 2 may cause
adverse effects to the liver, urinary, blood forming and reproductive
systems.
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists.
Redness and itching or burning sensation may indicate eye or excessive
skin exposure.
CANCER INFORMATION
Section 4 -- FIRST AID MEASURES
EYES:
SKIN:
INHALATION:
INGESTION:
If affected, remove from exposure. Restore breathing.
Keep warm and quiet.
Do not induce vomiting.
Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT
LEL
UEL
Propellant < 0 F
1.0
13.1
EXTINGUISHING MEDIA
1501
page 3
During emergency conditions overexposure to decomposition products may
cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
Full protective equipment including self-contained breathing apparatus
should be used.
Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent
pressure build-up and possible autoignition or explosion when exposed to
extreme heat.
Section 6 -- ACCIDENTAL RELEASE MEASURES
Section 7 -- HANDLING AND STORAGE
STORAGE CATEGORY
Not Available
Keep away from heat, sparks, and open flame. Vapors will accumulate
readily and may ignite explosively.
During use and until all vapors are gone: Keep area ventilated - Do not
smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves,
electric tools and appliances, and any other sources of ignition.
Contents under pressure. Do not puncture, incinerate, or expose to
temperature above 120F. Heat from sunlight, radiators, stoves, hot water,
and other heat sources could cause container to burst. Do not take
internally. Keep out of the reach of children.
1501
page 4
Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
This coating may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels
only during sanding or abrading of the dried film. If no specific dusts
are listed in Section 2, the applicable limits for nuisance dusts are ACGIH
TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3
(total dust), 5 mg/m3 (respirable fraction).
Removal of old paint by sanding, scraping or other means may generate
dust or fumes that contain lead. Exposure to lead dust or fumes may cause
brain damage or other adverse health effects, especially in children or
pregnant women. Controlling exposure to lead or other hazardous substances
requires the use of proper protective equipment, such as a properly fitted
respirator (NIOSH approved) and proper containment and cleanup. For more
information, call the National Lead Information Center at 1-800-424-LEAD
(in US) or contact your local health authority.
VENTILATION
materials in Section 2 is maintained below applicable exposure limits.
Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
ventilation, wear a properly fitted organic vapor/particulate respirator
When sanding or abrading the dried film, wear a dust/mist respirator
approved by NIOSH/MSHA for dust which may be generated from this product,
underlying paint, or the abrasive.
PROTECTIVE GLOVES
None required for normal application of aerosol products where minimal
skin contact is expected. For long or repeated contact, wear chemical
resistant gloves.
EYE PROTECTION
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal.
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
VAPOR DENSITY
6.58 lb/gal
788 g/l
0.79
<0 - 302 F
<-18 - 150 C
Not Available
92 %
Faster than ether
Heavier than air
1501
page 5
Section 10 -- STABILITY AND REACTIVITY
STABILITY -- Stable
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
Section 11 -- TOXICOLOGICAL INFORMATION
Methyl Ethyl Ketone may increase the nervous system effects of other
solvents.
Reports have associated repeated and prolonged overexposure to solvents
with permanent brain and nervous system damage.
Ethylbenzene is classified by IARC as possibly carcinogenic to humans
(2B) based on inadequate evidence in humans and sufficient evidence in
laboratory animals. Lifetime inhalation exposure of rats and mice to high
ethylbenzene concentrations resulted in increases in certain types of
cancer, including kidney tumors in rats and lung and liver tumors in mice.
These effects were not observed in animals exposed to lower concentrations.
There is no evidence that ethylbenzene causes cancer in humans.
IARC's Monograph No. 93 reports there is sufficient evidence of
carcinogenicity in experimental rats exposed to titanium dioxide but
inadequate evidence for carcinogenicity in humans and has assigned a Group
2B rating. In addition, the IARC summary concludes, "No significant
exposure to titanium dioxide is thought to occur during the use of products
in which titanium is bound to other materials, such as paint."
TOXICOLOGY DATA
1501
page 6
CAS No.
Ingredient Name
74-98-6
Propane
106-97-8
100-41-4
1330-20-7
67-64-1
78-93-3
108-65-6
13463-67-7
Butane
Ethylbenzene
Xylene
Acetone
LC50
LD50
RAT
RAT
4HR
Not Available
Not Available
LC50
LD50
RAT
RAT
4HR
Not Available
Not Available
LC50
LD50
RAT
RAT
4HR
Not Available
3500
mg/kg
LC50
LD50
RAT
RAT
4HR
LC50
RAT
4HR
LD50
RAT
Methyl Ethyl Ketone
LC50
RAT
4HR
LD50
RAT
LC50
RAT
4HR
LD50
RAT
Titanium Dioxide
LC50
RAT
4HR
LD50
RAT
5000
4300
ppm
mg/kg
Not Available
5800
mg/kg
Not Available
2740
mg/kg
Not Available
8500
mg/kg
Not Available
Not Available
Section 12 -- ECOLOGICAL INFORMATION
No data available.
Section 13 -- DISPOSAL CONSIDERATIONS
Waste from this product may be hazardous as defined under the Resource
Waste must be tested for ignitability to determine the applicable EPA
hazardous waste numbers.
Do not incinerate. Depressurize container. Dispose of in accordance
with Federal, State/Provincial, and Local regulations regarding pollution.
1501
page 7
Section 14 -- TRANSPORT INFORMATION
US Ground (DOT)
Canada (TDG)
IMO
Section 15 -- REGULATORY INFORMATION
CAS No.
CHEMICAL/COMPOUND
1330-20-7 Xylene
% by WT
1
7
% Element
WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt from listing,
on the TSCA Inventory.
Section 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazard criteria
of the Canadian Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
The above information pertains to this product as currently formulated,
Lamplight Farms
4900 N. Lilly Road
Menomonee Falls, WI 53051
1-800-645-5267
(262) 781-9590
LAMPLIGHT ULTRA-PURE LAMP OIL
Filename:
MSDS Ultra Pure
Revision Date: 03/03
Printed on: 04/11/03
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME:
SYNONYMS:
ULTRA PURE LAMP OIL
LINPAR 1416-V NORMAL PARAFFIN, Mixture of
Tetradecane, Pentadecane, and Hexadecane.
EINECS # 265-233-4
MANUFACTURER:
ADDRESS:
Lamplight Farms
4900 North Lilly Road, Menomonee Falls, WI 53051
(800) 645-5267 262-781-9590 (8:00 AM- 4:30 PM CST) M-F
EMERGENCY NUMBER: 1-800-308-7141 (Prosar)
For non-emergency and all other information call: 1-800-645-5267
2. COMPOSITION / INFORMATION ON INGREDIENTS
Components
CAS Number
C14-C16 Paraffins
90622-46-1
Weight %
100
See Section 8 for Exposure Guidelines and Section 15 for OSHA Classification
3. HAZARDS IDENTIFICATION
Emergency Overview
Water white, oily liquid. Mild hydrocarbon odor.
HEALTH HAZARD: MAY CAUSE EYE OR SKIN IRRITAION. High vapor concentrations may cause
headache, stupor, dizziness, or irritation of throat and eyes
Potential Health Effects
EYES:
Irritation may occur with exposure to concentrated vapors or contact with product.
SKIN:
Repeated or prolonged contact can cause redness, irritation, and scaling of the skin
(dermatitis). Normal care and personal hygiene should prevent skin effects.
INHALATION: Exposure to high concentration of vapors may result in headache and stupor.
INGESTION:
Lung exposure to this product either by prolonged breathing of a mist or vomiting following
ingestion, can lead to serious lung injury and possibly death.
(See section 11 for Toxicological Information).
-1-
Lamplight Farms
4900 N. Lilly Road
1-800-645-5267
(262) 781-9590
Filename:
MSDS Ultra Pure
4. FIRST AID MEASURES
EYES:
Immediately flush eyes with plenty of water for at least 15 minutes. If irritation persists, seek
medical attention.
SKIN:
Immediately flush skin with plenty of water. Remove contaminated clothing and shoes.
Wash affected area with mild soap. Call a physician if irritation occurs.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration and seek medical attention
immediately. Oxygen should only be administered by trained personnel.
INGESTION:
DO NOT INDUCE VOMITING. Seek medical advice immediately.
5. FIRE FIGHTING MEASURES
Flammable Properties
FLASH POINT / METHOD:
250°F (121° C) / PM
AUTOIGNITION TEMPERATURE:
420°F (216° C)
FLAMMABLE LIMITS IN AIR % BY VOLUME:
None Expected.
FIRE AND EXPLOSION HAZARD:
None Expected.
FIRE FIGHTING INSTRUCTIONS:
Water spray, carbon dioxide,, dry chemical, or alcohol compatible foam is recommended.
6. ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE OF A SPILL OR LEAK:
Evacuate the area and eliminate all sources of ignition. Contain the spill if possible. Material may be
picked up with a solid sorbent. Dispose of only in accordance with local, state, and federal regulations.
CERCLA HAZARDOUS SUBSTANCE:
Component
CERCLA RQ
Contains no chemicals on the CERCLA Hazardous Substance List.
-2-
Maximum Wt. %
Lamplight Farms
4900 N. Lilly Road
1-800-645-5267
(262) 781-9590
Filename:
MSDS Ultra Pure
7. HANDLING AND STORAGE
ELECTROSTATIC ACCUMULATION HAZARD:
Yes – ground all equipment.
USUAL SHIPPING CONTAINERS:
Tank cars, tank trucks.
STORAGE / TRANSPORT TEMPERATURE:
Ambient. (Product will freeze at 47° F (8° C))
STORAGE / TRANSPORT PRESSURE:
Ambient. (Product will freeze at 47° F (8° C))
LOAD / UNLOAD TEMPERATURE:
Ambient, above freezing point. (Product will freeze at 47° F (8° C))
STORAGE AND HANDLING MATERIALS:
Carbon steel is suitable.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls
Air contaminant levels should be controlled below the PEL or TLV for this product (see Exposure
Guidelines of this section). Mechanical ventilation may be necessary if working with this product in
enclosed areas and at elevated temperatures.
Personal Protective Equipment
EYES:
When contact with liquid is possible, use a face shield and chemical goggles. Otherwise use safety
glasses or goggles.
SKIN:
Chemical gloves should be worn to prevent repeated contact. If potential for significant exposure to
liquid exists, use full protective clothing and chemical boots.
RESPIRATORY PROTECTION:
NIOSH-approved organic vapor air-purifying respirator, self contained breathing apparatus, or airsupplied respirators dependent on concentration.
-3-
Lamplight Farms
4900 N. Lilly Road
1-800-645-5267
(262) 781-9590
Filename:
MSDS Ultra Pure
Exposure Guidelines:
No exposure limit has been set for exposure to vapors for this product. However, Lamplight and its suppliers
recommend the ACGIH/OSHA/NIOSH – recommended limit of 5 mg/m3 (8-hour TWA) fir exposure to mists
of this product.
OSHA PEL
Component
ACGIH TLV
None Established.
PEL = Permissible Exposure Limits
TLV = Threshold Limit Value
TWA = Time Weighted Average ( 8hr.)
STEL = Short Term Exposure Limit (15 min.)
Carcinogenicity
No carcinogenic ingredients.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE:
Water white, oily liquid
VISCOCITY:
2.5 – 2.7 cSt @ 104° F (40° C).
ODOR:
PHYSICAL STATE:
Liquid.
Mild hydrocarbon odor.
VAPOR PRESSURE (mm Hg.).
0.05 @ 68° F (20° C).
BOILING POINT:
490 - 592° F (254 – 283° C).
VAPOR DENSITY (Air=1).
7-8
MELTING POINT:
48 - 50° F (8 - 10° C).
SOLUBILITY IN WATER:
Negligible
SPECIFIC GRAVITY (H2O = 1):
0.773 @ 60°F/60°F (16°C/16°C).
10. STABILITY AND REACTIVITY
CONDITIONS TO AVOID:
High Temperatures.
INCOMPATIBILITY WITH OTHER MATERIALS:
Strong Oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS:
Combustion products include carbon dioxide, carbon monoxide and possibly other unidentified organic
compound.
HAZARDOUS POLYMERIZATION:
Stable.
-4-
Lamplight Farms
4900 N. Lilly Road
1-800-645-5267
(262) 781-9590
Filename:
MSDS Ultra Pure
11. TOXICOLOGICAL INFORMATION
EYES:
Primary Eye Irritation Index (Rabbits): 5.7 for nonwashed eyes after 1 hour, 6 for washed eyes
after 1 hour. (Maximum score is 110).
SKIN:
Acute Dermal LD50 (Rabbits): >2 g/kg
Primary Skin Irritation Index (Rabbits): 4.4 (Maximum score is 8.0)
INHALATION:
LC50 (Rats): >5.8 mg/l (nominal) with four-hour exposure.
INGESTION:
Acute Oral LD50 (Rat): > 5 g/kg.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION:
Not Available.
CHEMICAL FATE INFORMATION:
Not Available.
13. DISPOSAL CONSIDERATIONS
SPECIAL INSTRUCTIONS:
Evacuate the area and eliminate all sources of ignition. Contain the spill is possible. Material may be
picked up with solid sorbent. Dispose of only in accordance with local state, and federal regulations.
WASTE CLASSIFICATION:
If discarded in its purchased form, this product is not a RCRA hazardous waste. Re-evaluation of the
product may be required by the user at the time of disposal, since the product uses, transforms, and
mixtures may change the classification.
EMPTY CONTAINERS:
Empty containers retain product residue (liquid and/or vapor) can be dangerous. DO NOT
PRESSURIZE, CUT WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES
OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should
be completely drained, properly bunged and promptly returned to a drum reconditioner, or properly
disposed of.
(See Section 6 for CERCLA Reporting Requirements).
-5-
Lamplight Farms
4900 N. Lilly Road
1-800-645-5267
(262) 781-9590
Filename:
MSDS Ultra Pure
14. TRANSPORT INFORMATION
DOT DESCRIPTION:
This product is not a hazardous material according to DOT regulations for ground transportation.
ICAO / IATA DESCRIPTION:
This product is not a dangerous good as defined by IATA for air transportation.
IMO DESCRIPTION (IMDG CODE):
This product is not a dangerous good as defined by IMO in the IMDG Code for water transportation.
15. REGULATORY INFORMATION
U.S. Federal Regulations
OSHA HAZARD COMMUNICATION STANDARD CLASSIFICATION:
Nonhazardous as defined by the OSHA Hazard Communication Standard.
TSCA INVENTORY LISTING:
Component
CAS Number
Alkanes (C14-C16)
90622-46-1
SARA 302 STATUS
Component
CAS Number
Maximum Wt. %
Contains no chemicals subject to SARA 302 reporting.
SARA 311/312 CLASSIFICATION:
Nonhazardous according to SARA 311/312.
SARA 313 CHEMICALS:
CAS Number
Component
Contains no chemicals subject to SARA 313 reporting.
(See Section 6 for CERCLA Reporting Requirements.)
-6-
Maximum Wt. %
Lamplight Farms
4900 N. Lilly Road
1-800-645-5267
(262) 781-9590
Filename:
MSDS Ultra Pure
International Regulations
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS) CLASSIFICATION:
This material is not a controlled product as defined by Canada's Workplace Hazardous Materials
Information System (WHMIS).
CANADIAN DOMESTIC SUBSTANCE LIST (DSL) INVENTORY LISTING:
CAS Number
Chemical Name
C14 Tetradecane
C15 Pentadecane
C16 Hexadecane
629-59-4
629-62-9
544-76-3
EUROPEAN INVENTORY OF EXISTING COMMERCIAL SUBSTANCES (EINECS) LISTING:
EINECS Number
Chemical Name
C14 Tetradecane
C15 Pentadecane
C16 Hexadecane
2110960
2110981
2088789
JAPANESE MINISTER OF INTERNATIONAL TRADE AND INDUSTRY (MITI) INVENTORY LISTING:
Section Structure #
Chemical Name
Alkane (C10-29)
2-10
AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS) LISTING:
CAS Number
Chemical Name
C14 Tetradecane
C15 Pentadecane
C16 Hexadecane
629-59-4
629-62-9
544-76-3
State Regulations
CALIFORNIA SAFE DRINKING WATER ACT (PROP 65) LISTING:
Component
CAS Number
**No ingredients listed in this section**
CALIFORNIA AIR RESOURCES BOARD Title 17, Article 2, Section 94510 Consumer Products:
This product is VOC exempt by 94510 (d)(1) as it has a vapor pressure below 0.1 mm Hg at 20°C.
-7-
Lamplight Farms
4900 N. Lilly Road
1-800-645-5267
(262) 781-9590
Filename:
MSDS Ultra Pure
16. OTHER INFORMATION
Hazard Ratings
Health:
FLAMMABILITY:
REACTIVITY:
NFPA
HMIS
1
1
0
1
1
0
Revision Summary
Date
Description
Jan 10, 2002
June 28, 2002
Document created.
Added Emergency numbers (Prosar) and Non emergency contact number.
THE DATA AND INFORMATION CONTAINED HEREIN ARE BEING FURNISHED FOR INFORMATIONAL PURPOSES ONLY. UPON
TH E EXPRESS CONDITION THAT EACH CUSTOMER SHALL MAKE ITS OWN ASSESMENT OF APPROPRIATE USE AND
APPROPRIATE SHIPPING, TRANSFER, AND STORAGE MATERIALS AND PROCEDURES FOR LAMPLIGHT FARMS PRODUCTS.
LAMPLIGHT DISCAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH MAY RESULT FROM THE USE OF THE ABOVE DATA,
AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY, (INCLUDING WARRANTY OF
MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABLITY) BY LAMPLIGHT WITH RESPECT
TO THE DATA, THE PRODUCTS DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS
KNOWN TO LAMPLIGHT.
PREPARED BY:
PHONE NUMBER:
LAMPLIGHT FARMS Engineering Department.
(800) 645-5267 (262) 781-9590
-8-
1 of 4
http://hazard.com/msds/f2/ccf/ccfmw.html
GLIDDEN COMPANY -- 1008001-CA-80 LIQUID NAILS ADHESIVES CONTACT CEMENT -- 8040-00F051677
=====================
Product Identification
=====================
Product ID:1008001-CA-80 LIQUID NAILS ADHESIVES CONTACT CEMENT
MSDS Date:04/08/1996
FSC:8040
NIIN:00F051677
MSDS Number: CCFMW
=== Responsible Party ===
Company Name:GLIDDEN COMPANY
Address:925 EUCLID AVENUE
City:CLEVELAND
State:OH
ZIP:44115-5000
Country:US
Info Phone Num:216-344-8000/800-634-0015
Emergency Phone Num:800-634-0015/216-344-8049
CAGE:01PD6
=== Contractor Identification ===
Company Name:GLIDDEN PAINT, ICI PAINTS NORTH AMERICA
Address:925 EUCLID AVE
Box:City:CLEVELAND
State:OH
ZIP:44115
Country:US
Phone:800-545-2643/216-344-8207
CAGE:01PD6
=============
Composition/Information on Ingredients
Ingred Name:TOLUENE (IARC CARC- GROUP 3)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 10-20%
Other REC Limits:375 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
=============
*96-3*
Ingred Name:STYRENE, ALPHA-METHYLSTYRENE, VINYLTOLUENE,
DICYCLOPENTADIENE, INDENE POLYMER
CAS:68240-01-7
Ingred Name:METHYL ETHYL KETONE, 2-BUTANONE
CAS:78-93-3
RTECS #:EL6475000
Other REC Limits:590 MG/CUM
OSHA PEL:200 PPM
ACGIH TLV:200 PPM
*96-3*
7/16/13 6:13 PM
2 of 4
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE
CAS:64742-89-8
OSHA PEL:300 PPM
* 96-3 *
Ingred Name:NEOPRENE, 2 CHLORO-1, 3-BUTADIENE HOMOPOLYMER, CHLOROPRENE
POLYMER
CAS:9010-98-4
RTECS #:EI9640000
=====================
Hazards Identification
=====================
LD50 LC50 Mixture:ORAL LD50(RAT): 636.00 MG/KG TOLUENE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO
IARC:NO
OSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF RESPIRATORY
TRACT, CNS DEPRESSION, ANESTHETIC EFFECT, NEUROTOXICITY,
ASPHYXIATION/DEATH. SKIN: IRRITATION/DERMATITIS & ABSORPTION. EYES:
SEVERE IRRITATION & CORNEAL INJURY. I NGESTION: CAUSES LUNG
INFLAMMATION & DAMAGE DUE TO ASPIRATION OF MATEIRAL INTO LUNGS,
MOUTH & THROAT IRRITATION. (SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, FATIGUE, DROWSINESS, DIZZINESS,
LIGHTHEADEDNESS, HEADACHE, UNCOORDINATION, NAUSEA, VOMITING, CHEST
PAIN, DIFFICULTY W/SPEECH, APATHY, METALLIC TASTE, CONFUSION,
NARCOSIS, LOSS OF CONSCIOUS NESS, DEFATTING, BLURRED VISION,
TEARING, REDNESS, DIARRHEA, GI DISTURBANCES, ABDOMINAL PAIN,
APATHY.
Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS,
NERVOUS SYSTEM DISORDERS.
=======================
First Aid Measures
=======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED
BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. SKIN:
FLUSH W/WATER. THEN WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH
IMMEDIATELY W/LARGE AMOUNTS OF WATER. OBTAIN MEDICAL ATTENTION IN
ALL CASES.
=====================
Fire Fighting Measures
=====================
Flash Point Method:SCC
Flash Point:20F
Lower Limits:1
Upper Limits:12
Extinguishing Media:DRY CHEMICAL/FOAM, WTAER FOG, CO2.
Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED
CONTAINERS. USE FULL PROTECTIVE CLOTHING, EYE PROTECTION & SCBA.
7/16/13 6:13 PM
3 of 4
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPLODE TO EXTREME
HEAT. VAPORS IGNITE EXPLOSIVELY AT AMBIENT TEMPS & ARE > THAN AIR &
TRAVEL LONG DISTANCE TO SOURCE OF IGNITION/FLASHBACK.
==================
Accidental Release Measures
Spill Release Procedures:LARGE: SHUT OFF
PUMP TO STORAGE/SALVAGE VESSELS. USE
RESIDUE. KEEP SALVAGEABLE MATERIAL &
WATER COURSES. SMALL: USE ABSORBENT
PROPERLY.
======================
==================
LEAK SAFELY. DIKE & CONTAIN.
ABSORBNET TO PICKUP EXCESS
RINSE WATER OUT OF SEWERS &
TO PICKUP RESIDUE & DISPOSE OF
Handling and Storage
======================
Handling and Storage Precautions:STORE BELOW 80F. KEEP AWAY FROM HEAT,
SPARKS & OPEN FLAME. USE ONLY W/ADEQUATE VENTILATION. KEEP
CONTAINERS TIGHLTY CLOSED & UPRIGHT WHEN NOT IN USE.
Other Precautions:DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
AVOID CONTACT W/SKIN, EYES & BREATHING OF VAPORS. EMPTY CONTAINERS
MAY CONTAIN HAZARDOUS RESIDUES. GROUND EQUIPMENT WHEN TRANSFERRED
TO PREVENT AC CUMULATION OF STATIC CHARGE. (SEE SUPP)
=============
Exposure Controls/Personal Protection
=============
Respiratory Protection:WHERE RESPIRATORY PROTECTION IS REQUIRED, USE
ONLY NIOSH/MSHA APPROVED RESPIRATORS IAW/OSHA STANDARD.
Ventilation:DILUTION/LOCAL EXHAUST TO PREVENT BUILD UP OF VAPORS. USE
EXPLOSION PROOF EQUIPMENT/NON SPARKING EQUIPMENT.
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GLASSES/GOGGLES
Other Protective Equipment:EYE WASH, SAFETY SHOWER, IMPERVIOUS
CLOTHING.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS THOROUGHLY AFTER HANDLING/BEFORE EATING/SMOKING.
Supplemental Safety and Health
HLTH HZRD CONT'D: CNS DEPRESSION, PULMONARY EDEMA, TOXICITY TO
LIVER/KIDNEY, CNS, BLOOD, HEART. OVEREXPOSURE TO SOLVENTS MAY CAUSE
PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. PRECAUTIONS: INTENTIONAL
MIS USE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MAY
BE HARMFUL/FATAL.
==================
Physical/Chemical Properties
==================
Boiling Pt:B.P. Text:172-527F
Spec Gravity:0.854
Appearance and Odor:YELLOW LIQUID
Percent Volatiles by Volume:87.25
=================
Stability and Reactivity Data
=================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, BASES, ALDEHYDES, AMINES, AMMONIA, NITRIC ACID,
7/16/13 6:13 PM
4 of 4
CAUSTICS, MINERAL ACIDS.
Stability Condition to Avoid:ELEVATED TEMPS, SPARKS, OPEN FLAME,
IGNITION SOURCES.
Hazardous Decomposition Products:CO, CO2, HYDROGEN CHLORIDE.
====================
Disposal Considerations
====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
7/16/13 6:13 PM
MSDS for: LN-604
Revised:
18-May-2012
SECTION 1:
PRODUCT IDENTIFIER:
DATE OF PREPARATION:
PRODUCT USE:
LN-604 LATEX PROJECT & FOAM ADHESIVE
MAY 18, 2012
ADHESIVE
MANUFACTURED BY:
AKZO NOBEL
15885 WEST SPRAGUE ROAD
STRONGSVILLE, OHIO 44136, U.S.A.
AKZO NOBEL (CANADA)
8200 KEELE STREET
CONCORD, ONTARIO L4K 2A5, CANADA
EMERGENCY AND MSDS TELEPHONE NUMBER:
MSDS PREPARED BY:
1-800-545-2643
PRODUCT SAFETY AND COMPLIANCE DEPARTMENT
AKZO NOBEL NORTH AMERICA
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT
WT. %
CHEMICAL NAME:
COMMON NAME:
CAS NUMBER:
ACRYLIC RESI
ACRYLIC RESIN
CONFIDENTIAL
10-20
CHEMICAL NAME:
COMMON NAME:
CAS NUMBER:
1,2-ETHANEDIOL
ETHYLENE GLYCOL
107-21-1
0.1-1.0
CHEMICAL NAME:
COMMON NAME:
CAS NUMBER:
LIMESTONE
LIMESTONE
1317-65-3
30-40
CHEMICAL NAME:
COMMON NAME:
CAS NUMBER:
KAOLIN
CLAY
1332-58-7
10-20
CHEMICAL NAME:
COMMON NAME:
CAS NUMBER:
TITANIUM OXIDE
TITANIUM DIOXIDE
13463-67-7
0.1-1.0
CHEMICAL NAME:
CRISTOBALITE
0.1-1.0
CHEMICAL NAME:
COMMON NAME:
CAS NUMBER:
PROPANOL, OXYBIS-, DIBENZOATE
DIPROPYLENE GLYCOL DIBENZOATE
27138-31-4
1-5
CHEMICAL NAME:
COMMON NAME:
CAS NUMBER:
WATER
WATER
7732-18-5
30-40
SECTION 3: HAZARDS IDENTIFICATION
PRIMARY ROUTE(S) OF EXPOSURE:
INHALATION, SKIN CONTACT, EYE CONTACT,
INGESTION
INHALATION:
IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION
MAY LEAD TO HEADACHE, NAUSEA, DIFFICULTY OF BREATHING,
PNEUMOCONIOSIS.
SKIN CONTACT:
IRRITATION OF SKIN. PROLONGED OR REPEATED CONTACT CAN
CAUSE DEFATTING.
EYE CONTACT:
IRRITATION OF EYES. PROLONGED OR REPEATED CONTACT CAN
CAUSE TEARING OF EYES, REDNESS OF EYES.
INGESTION:
INGESTION MAY CAUSE MOUTH AND THROAT IRRITATION,
NAUSEA, GASTRO-INTESTINAL DISTURBANCES, ABDOMINAL PAIN.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
EYE, SKIN, RESPIRATORY DISORDERS, LUNG DISORDERS
SECTION 4: FIRST-AID MEASURES
INHALATION:
REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED
BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE
TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL
HELP FOR ANY BREATHING DIFFICULTY.
SKIN CONTACT:
WASH THOROUGHLY WITH SOAP AND WATER. IF ANY PRODUCT
REMAINS, GENTLY RUB PETROLEUM JELLY, VEGETABLE OR
MINERAL/BABY OIL ONTO SKIN. REPEATED APPLICATIONS MAY BE
NEEDED. REMOVE CONTAMINATED CLOTHING. WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
EYE CONTACT:
FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER,
ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF
SECTION 5: FIRE-FIGHTING MEASURES
FLASH POINT (SETA): ABOVE 200F/93C
LOWER EXPLOSIVE LIMIT: NOT AVAILABLE
UPPER EXPLOSIVE LIMIT: NOT AVAILABLE
FIRE EXTINGUISHING MEDIA: DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE
CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE.
FIRE FIGHTING PROCEDURES
WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. FIREFIGHTERS
SHOULD USE FULL PROTECTIVE CLOTHING, EYE PROTECTION, AND SELF-CONTAINED
BREATHING APPARATUS.
HAZARDOUS DECOMPOSITION OR COMBUSTION PRODUCTS
CARBON MONOXIDE, CARBON DIOXIDE, ACRYLIC MONOMERS,
OXIDES OF CALCIUM
SECTION 6: ACCIDENTAL RELEASE MEASURES
COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS.
VENTILATE AREA. PLACE COLLECTED MATERIAL IN PROPER CONTAINER. SPILLED
MATERIAL IS EXTREMELY SLIPPERY.
LARGE SPILLS: SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN SPILL. PUMP TO
STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP EXCESS
RESIDUE. KEEP SALVAGEABLE MATERIAL AND RINSE WATER OUT OF
SEWERS AND WATER COURSES.
SMALL SPILLS: USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY.
SECTION 7: HANDLING AND STORAGE
STORE BELOW 100F (38C). KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP
FROM FREEZING.
OTHER PRECAUTIONS
USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. KEEP OUT OF
REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES, AND BREATHING OF
VAPORS. WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
COMMON NAME:
CAS NUMBER:
ACGIH(TWA):
LIMESTONE
1317-65-3
10 MG/M3
OSHA(TWA):
5 MG/M3
COMMON NAME:
CAS NUMBER:
ACGIH(TWA):
CLAY
1332-58-7
2 MG/M3
OSHA(TWA):
5 MG/M3
COMMON NAME:
CAS NUMBER:
ACGIH(TWA):
TITANIUM DIOXIDE
13463-67-7
10 MG/M3
OSHA(TWA):
10 MG/M3
COMMON NAME:
CAS NUMBER:
ACGIH(TWA):
CRYSTALLINE SILICA, CRISTOBALITE
14464-46-1
0.025 MG/M3
OSHA(TWA): 0.05 MG/M3
COMMON NAME:
CAS NUMBER:
ACGIH(TWA):
QUARTZ
14808-60-7
0.025 MG/M3
OSHA(TWA):
0.1 MG/M3
CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE EXPOSURE
STANDARDS WHEN USING THIS MATERIAL. WHENRESPIRATORY PROTECTION IS
DETERMINED TO BE NECESSARY, USE A NIOSH/MSHA (CANADIAN Z94.4) APPROVED
ELASTOMERIC SEALING-SURFACE FACEPIECE RESPIRATOR OUTFITTED WITH ORGANIC
VAPOR CARTRIDGES AND PAINT SPRAY (DUST/MIST) PREFILTERS. DETERMINE THE
PROPER LEVEL OF PROTECTION BY CONDUCTING APPROPRIATE AIR MONITORING.
CONSULT 29CFR1910.134 FOR SELECTION OF RESPIRATORS (CANADIAN Z94.4).
VENTILATION
PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP OF
VAPORS.
PERSONAL PROTECTIVE EQUIPMENT:
EYE WASH, SAFETY SHOWER, SAFETY GLASSES OR GOGGLES,
IMPERVIOUS GLOVES, IMPERVIOUS CLOTHING
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
VAPOR PRESSURE:
BOILING RANGE (F/C):
APPEARANCE:
PHYSICAL STATE:
NOT AVAILABLE
212-212/100-100
WHITE
PASTE
SPECIFIC GRAVITY:
WEIGHT PER GALLON:
%VOLATILE BY VOLUME:
SOLUBLE IN WATER:
1.492
12.43/14.93 IMP
53.23
YES
MATERIALS TO AVOID:
OXIDIZERS, ACIDS, BASES, AMMONIUM SALTS,
STYRENE MONOMER
CONDITIONS TO AVOID:
FREEZING
HAZARDOUS POLYMERIZATION:
WILL NOT OCCUR
SECTION 11: TOXICOLOGICAL INFORMATION
COMMON NAME:
LIMESTONE
CAS NUMBER:
1317-65-3
CARCINOGENICITY LISTED BY: NTP NO
LD50: 6450.00 MG/KG ORL RAT
COMMON NAME:
CLAY
CAS NUMBER:
1332-58-7
COMMON NAME:
TITANIUM DIOXIDE
CAS NUMBER:
13463-67-7
CARCINOGENICITY LISTED BY: NTP YES 2B
LD50: 24.00 GM/KG ORL RAT
LC50: 6820.00 MG/M3/4HR IHL RAT
IARC NO
OSHA NO
ACGIH NO
IARC NO
OSHA NO
ACGIH NO
IARC YES 2B
OSHA NO
ACGIH NO
COMMON NAME:
CRYSTALLINE SILICA, CRISTOBALITE
CAS NUMBER:
14464-46-1
CARCINOGENICITY LISTED BY: NTP YES
IARC YES 1
OSHA NO
ACGIH YES A2
COMMON NAME:
QUARTZ
CAS NUMBER:
14808-60-7
CARCINOGENICITY LISTED BY: NTP YES
ACGIH YES A2
IARC YES 1
OSHA NO
COMMON NAME:
DIPROPYLENE GLYCOL DIBENZOATE
CAS NUMBER:
27138-31-4
IARC NO
OSHA NO
LD50: > 2000.00 MG/KG SKN RBT
LD50: 4673.00 MG/KG ORL RAT
LC50: > 200.00 GM/M3/4HR IHL RAT
ACGIH NO
SUPPLEMENTAL HEALTH INFORMATION
THE MANUFACTURER OF DIPROPYLENE GLYCOL DIBENZOATE CONDUCTED TOXICITY
TESTS AND FOUND DECREASED BODY WEIGHT GAIN, AND BLOOD, LIVER AND CAECUM
EFFECTS IN RATS GIVEN UP TO 2500 MG/KG/DAY IN THE DIET FOR 13 WEEKS. ALL
TREATMENT RELATED CHANGES SHOWED EVIDENCE OF, OR COMPLETE, RECOVERY
AFTER 4 WEEKS WITHOUT TREATMENT. RELEVANCE TO HUMANS IS UNKNOWN.
CRYSTALLINE SILICA AS A KNOWN HUMAN CARCINOGEN.
IN A LIFETIME INHALATION STUDY, EXPOSURE TO 250
MG/M3 TITANIUM DIOXIDE RESULTED IN THE
DEVELOPMENT OF LUNG TUMORS IN RATS. THESE TUMORS
OCCURRED ONLY AT DUST LEVELS THAT OVERWHELMED
THE ANIMALS' LUNG CLEARANCE MECHANISMS AND WERE
DIFFERENT FROM COMMON HUMAN LUNG TUMORS IN
BOTH TYPE AND LOCATION. THE RELEVANCE OF THESE
FINDINGS TO HUMANS IS UNKNOWN BUT QUESTIONABLE.
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
(IARC) HAS CLASSIFIED TITANIUM DIOXIDE AS POSSIBLY
CARCINOGENIC TO HUMANS (GROUP 2B) BASED ON
INADEQUATE EVIDENCE OF CARCINOGENICITY IN HUMANS
AND SUFFICIENT EVIDENCE OF CARCINOGENICITY IN
EXPERIMENTAL ANIMALS.
REPRODUCTIVE EFFECTS:
NO REPRODUCTIVE EFFECTS ARE ANTICIPATED
MUTAGENICITY:
NO MUTAGENIC EFFECTS ARE ANTICIPATED
TERATOGENICITY:
NO TERATOGENIC EFFECTS ARE ANTICIPATED
SECTION 12: ECOLOGICAL INFORMATION
NO ECOLOGICAL TESTING HAS BEEN DONE BY AKZO NOBEL PAINTS LLC
ON THIS PRODUCT AS A WHOLE.
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
SECTION 14: TRANSPORT INFORMATION
DOT:
IMDG:
IATA:
TDG:
ADHESIVE
NOT AVAILABLE
NOT AVAILABLE
NOT AVAILABLE
SECTION 15: REGULATORY INFORMATION
SARA SARA CERCLA
302
313
302.4
HAZ AIR
POLLUTANT
MARINE
POLTNT
THIS PRODUCT CONTAINS NO SARA 302, CERCLA 302.4 OR HAZARDOUS AIR POLLUTANT
CHEMICALS. IT ALSO CONTAINS NO CHEMICALS WHICH ARE SUBJECT TO THE
SECTION 16: OTHER INFORMATION
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA AVAILABLE AT THE TIME OF
PREPARATION OF THIS DATA SHEET AND WHICH AKZO NOBEL PAINTS LLC BELIEVES TO
BE RELIABLE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE
ACCURACY OF THIS DATA. AKZO NOBEL PAINTS LLC SHALL NOT BE RESPONSIBLE FOR
THE USE OF THIS INFORMATION, OR OF ANY PRODUCT, METHOD OR APPARATUS
MENTIONED AND YOU MUST MAKE YOUR OWN DETERMINATION OF ITS SUITABILITY
AND COMPLETENESS FOR YOUR OWN USE, FOR THE PROTECTION OF THE ENVIRONMENT,
AND THE HEALTH AND SAFETY OF YOUR EMPLOYEES AND USERS OF THIS MATERIAL.
COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29CFR1910.1200.
Revision Number: 003.3
Issue date: 01/17/2012
1. PRODUCT AND COMPANY IDENTIFICATION
Product name:
Product type:
Loctite Super Glue Gel Control
Cyanoacrylate
IDH number:
234790
Item number:
30379
Region:
United States
Contact information:
Telephone: 800.624.7767
MEDICAL EMERGENCY Phone: Poison Control Center
1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com
Company address:
Henkel Corporation
One Henkel Way
Rocky Hill, Connecticut 06067
Physical state:
Color:
Odor:
gel, Liquid
Colorless
Irritating
WARNING:
EMERGENCY OVERVIEW
HMIS:
HEALTH:
FLAMMABILITY:
PHYSICAL HAZARD:
Personal Protection:
2
2
1
See MSDS Section 8
BONDS SKIN IN SECONDS.
MAY CAUSE EYE AND RESPIRATORY TRACT IRRITATION.
COMBUSTIBLE LIQUID AND VAPOR.
Relevant routes of exposure:
Skin, Inhalation, Eyes
Inhalation:
Exposure to vapors above the established exposure limit results in respiratory irritation, which
may lead to difficulty in breathing and tightness in the chest.
Bonds skin in seconds. May cause skin irritation. Cyanoacrylates have been reported to cause
allergic reaction but due to rapid polymerization at the skin surface, an allergic response is rare.
Cyanoacrylates generate heat on solidification. In rare circumstances a large drop will burn the
skin. Cured adhesive does not present a health hazard even if bonded to the skin.
Irritating to eyes. Causes excessive tearing. Eyelids may bond.
Not expected to be harmful by ingestion. Rapidly polymerizes (solidifies) and bonds in mouth. It
is almost impossible to swallow.
Skin contact:
Eye contact:
Ingestion:
Existing conditions aggravated by
exposure:
Eye, skin, and respiratory disorders.
This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
See Section 11 for additional toxicological information.
Hazardous components
CAS NUMBER
%
Ethyl 2-cyanoacrylate
Treated fumed silica
7085-85-0
67762-90-7
60 - 100
5 - 10
Inhalation:
Move to fresh air. If symptoms persist, seek medical advice.
IDH number: 234790
Product name: Loctite Super Glue Gel Control
Page 1 of 5
Skin contact:
Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart
using a blunt instrument. If skin is burned due to the rapid generation of heat
by a large drop, seek medical attention. If lips are bonded, apply warm water
to the lips and encourage wetting and pressure from saliva in mouth. Peel or
roll lips apart. Do not pull lips apart with direct opposing force.
Eye contact:
Immediately flush with plenty of water for at least 15 minutes. Get medical
attention. If eyelids are bonded closed, release eyelashes with warm water by
covering with a wet pad. Do not force eye open. Cyanoacrylate will bond to
eye protein and will cause a lachrymatory effect which will help to debond the
adhesive. Keep eye covered until debonding is complete, usually within 1-3
days. Medical attention should be sought in case solid particles of polymerized
cyanoacrylate trapped behind the eyelid caused abrasive damage.
Ingestion:
Ensure breathing passages are not obstructed. The product will polymerize
rapidly and bond to the mouth making it almost impossible to swallow. Saliva
will separate any solidified product in several hours. Prevent the patient from
swallowing any separated mass.
Notes to physician:
Surgery is not necessary to separate accidentally bonded tissues. Experience
has shown that bonded tissues are best treated by passive, non-surgical first
aid. If rapid curing has caused thermal bums they should be treated
symptomatically after adhesive is removed.
Flash point:
80 - 93.4 °C (176°F - 200.12 °F) Tagliabue closed cup
Autoignition temperature:
485 °C (905°F)
Flammable/Explosive limits - lower:
Not available.
Flammable/Explosive limits - upper:
Not available.
Extinguishing media:
Dry powder. foam Carbon dioxide.
Special firefighting procedures:
Fire fighters should wear positive pressure self-contained breathing apparatus
(SCBA).
Unusual fire or explosion hazards:
Not available.
Hazardous combustion products:
Trace amounts of toxic and/or irritating fumes may be released and the use of
breathing apparatus is recommended.
Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.
Environmental precautions:
Do not allow product to enter sewer or waterways.
Clean-up methods:
Do not use cloths for mopping up. Flood with water to complete
polymerization and scrape off the floor. Cured material can be disposed of as
non-hazardous waste.
Handling:
Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists of
this product. Wash thoroughly after handling. Avoid contact with fabric or
paper goods. Contact with these materials may cause rapid polymerization
which can generate smoke and strong irritating vapors, and cause thermal
burns.
IDH number: 234790
Page 2 of 5
Storage:
Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.
For information on product shelf life, please review labels on container or check the Technical Data Sheet.
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.
ACGIH TLV
OSHA PEL
AIHA WEEL
OTHER
None
None
None
None
0.2 ppm TWA
None
10 mg/m3 TWA
15 mg/m3 TWA
Inhalable dust.
Total dust.
3 mg/m3 TWA
5 mg/m3 TWA
Respirable fraction. Respirable fraction.
Engineering controls:
Use positive down-draft exhaust ventilation if general ventilation is insufficient
to maintain vapor concentration below established exposure limits.
Respiratory protection:
Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).
Eye/face protection:
Safety goggles or safety glasses with side shields.
Skin protection:
Use nitrile gloves and aprons as necessary to prevent contact. Do not use
PVC, nylon or cotton.
Physical state:
Color:
Odor:
Odor threshold:
pH:
Vapor pressure:
Boiling point/range:
Melting point/ range:
Vapor density:
Flash point:
Evaporation rate:
Solubility in water:
Partition coefficient (n-octanol/water):
VOC content:
gel, Liquid
Colorless
Irritating
1 - 2 ppm
Not available.
< 0.2 mm hg
> 149 °C (> 300.2 °F)
Not available.
Approximate 3
80 - 93.4 °C (176°F - 200.12 °F) Tagliabue closed cup
Not available.
Not available.
485 °C (905°F)
Not available.
Polymerises in presence of water.
Not available.
< 2 %; < 20 g/l (California SCAQMD Method 316B) (Estimated)
Stability:
Stable under recommended storage conditions.
Hazardous reactions:
Rapid exothermic polymerization will occur in the presence of water, amines,
alkalis and alcohols.
Hazardous decomposition products:
None
Incompatible materials:
Water, Amines, Alkalis, Alcohols.
Conditions to avoid:
Spontaneous polymerization.
Acute oral product toxicity:
LD50 (rat) > 5,000 mg/kg (Estimated)
IDH number: 234790
Page 3 of 5
Acute dermal product toxicity:
LD50 (rabbit) > 2,000 mg/kg (Estimated)
NTP Carcinogen
IARC Carcinogen
No
No
No
No
OSHA Carcinogen
(Specifically Regulated)
No
No
Health Effects/Target Organs
Irritant, Allergen, Respiratory
Irritant
Ecological information:
Not available.
Information provided is for unused product only.
Recommended method of disposal:
Dispose of according to Federal, State and local governmental regulations.
Hazardous waste number:
Not a RCRA hazardous waste.
The shipping classification in this section are for bulk packaging only. Shipping classification may be different for non-bulk packaging
as exceptions may apply. Refer to shipping documents for package specific transportation classification.
U.S. Department of Transportation Ground (49 CFR)
Proper shipping name:
Combustible liquid, n.o.s. (Ethyl cyanoacrylate)
Hazard class or division:
Combustible Liquid
Identification number:
NA 1993
Packing group:
III
Exceptions:
(Not more than 450 Liters), Unrestricted
International Air Transportation (ICAO/IATA)
Packing group:
Exceptions:
Aviation regulated liquid, n.o.s. (Ethyl cyanoacrylate)
9
UN 3334
None
(Not more than 500ml) Unrestricted
Water Transportation (IMO/IMDG)
Packing group:
Not regulated
None
None
None
United States Regulatory Information
TSCA 8 (b) Inventory Status:
TSCA 12(b) Export Notification:
CERCLA/SARA Section 302 EHS:
All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
None above reporting de minimus
CERCLA/SARA Section 311/312:
CERCLA/SARA 313:
Hydroquinone (CAS# 123-31-9). Sulfur dioxide (CAS# 7446-09-5). Boron trifluoride
dihydrate (CAS# 13319-75-0). Boron trifluoride (CAS# 7637-07-2).
Immediate Health, Delayed Health, Fire, Reactive
California Proposition 65:
No California Proposition 65 listed chemicals are known to be present.
IDH number: 234790
Page 4 of 5
Canada Regulatory Information
CEPA DSL/NDSL Status:
WHMIS hazard class:
Contains one or more components listed on the Non-Domestic Substances list. All other
components are listed on or are exempt from listing on the Domestic Substances List.
B.3, D.2.B
This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet
format.
Prepared by: Karim Nasr, Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.
IDH number: 234790
Page 5 of 5
Revision Number: 001.2
Issue date: 01/17/2012
Product name:
Product type:
Loctite® Threadlocker Red 271 Heavy
Duty
Thread sealing
Company address:
Henkel Corporation
One Henkel Way
Rocky Hill, Connecticut 06067
IDH number:
209741
Item number:
27100
Region:
United States
Contact information:
Telephone: 800.624.7767
MEDICAL EMERGENCY Phone: Poison Control Center
1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Physical state:
Color:
Odor:
EMERGENCY OVERVIEW
HMIS:
HEALTH:
FLAMMABILITY:
PHYSICAL HAZARD:
Personal Protection:
Liquid
Red
Mild
WARNING:
*2
1
1
Not available.
CAUSES EYE IRRITATION.
MAY CAUSE SKIN IRRITATION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
Relevant routes of exposure:
Skin, Inhalation, Eyes
Inhalation:
Skin contact:
Eye contact:
Ingestion:
May cause respiratory tract irritation.
May cause allergic skin reaction. May cause skin irritation.
Contact with eyes will cause irritation.
Not expected to be harmful by ingestion.
Existing conditions aggravated by
exposure:
Eye, skin, and respiratory disorders.
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).
See Section 11 for additional toxicological information.
CAS NUMBER
%
Polyglycol dimethacrylate
Bisphenol A fumarate resin
Saccharin
Cumene hydroperoxide
25852-47-5
39382-25-7
81-07-2
80-15-9
60 - 100
10 - 30
1-5
1-5
Inhalation:
Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. If symptoms develop and persist, get medical attention.
IDH number: 209741
Product name: Loctite® Threadlocker Red 271 Heavy Duty
Page 1 of 5
Skin contact:
Wash with soap and water. Remove contaminated clothing and footwear.
Wash clothing before reuse. If symptoms develop and persist, get medical
attention.
Eye contact:
Flush with copious amounts of water, preferably, lukewarm water for at least
15 minutes, holding eyelids open all the time. Get medical attention.
Ingestion:
Do not induce vomiting. Keep individual calm. Never give anything by mouth
to an unconscious person. Get medical attention.
Flash point:
> 93.3 °C (> 199.94 °F) Tagliabue closed cup
Not available.
Not available.
Not available.
Extinguishing media:
Foam, dry chemical or carbon dioxide.
Special firefighting procedures:
Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear.
Unusual fire or explosion hazards:
None
Hazardous combustion products:
Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic
vapours.
Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.
Environmental precautions:
Remove all sources of ignition. Do not allow product to enter sewer or
waterways.
Clean-up methods:
Store in a partly filled, closed container until disposal. Soak up with inert
absorbent material (e.g. sand, silica gel, acid binder, universal binder,
sawdust). Ensure adequate ventilation.
Handling:
Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling. Use only with adequate ventilation. Keep
container closed.
Storage:
For safe storage, store at or below 38 °C (100.4 °F)
Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.
For information on product shelf life, please review labels on container or check the Technical Data Sheet.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.
IDH number: 209741
Page 2 of 5
ACGIH TLV
OSHA PEL
AIHA WEEL
OTHER
Saccharin
None
None
None
None
None
None
None
None
None
None
None
None
None
None
1 ppm (6 mg/m3)
TWA
(SKIN)
None
Engineering controls:
Local exhaust ventilation is recommended when general ventilation is not
sufficient to control airborne contamination below occupational exposure
limits.
Respiratory protection:
Use a NIOSH approved air-purifying respirator with an organic vapor cartridge.
Eye/face protection:
Safety goggles or safety glasses with side shields.
Skin protection:
Use impermeable gloves and protective clothing as necessary to prevent skin
contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves.
Physical state:
Color:
Odor:
Odor threshold:
pH:
Vapor pressure:
Boiling point/range:
Melting point/ range:
Specific gravity:
Specific gravity:
Vapor density:
Flash point:
Evaporation rate:
Solubility in water:
Partition coefficient (n-octanol/water):
VOC content:
Liquid
Red
Mild
Not available.
Not applicable
< 5 mm hg (26.7 °C (80.1 °F))
> 148.9 °C (> 300°F)
Not available.
1.07 at 26.70 °C (80.06 °F)
1.1
Not available.
> 93.3 °C (> 199.94 °F) Tagliabue closed cup
Not available.
Not available.
Not available.
Not available.
Slight
Not available.
0.82 %; 7.81 g/l
Stability:
Stable
Hazardous reactions:
Will not occur.
Hazardous decomposition products:
Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic
vapours. Phenolics.
Incompatible materials:
Rust. Strong oxidizing agents. Reducing agents. Strong acids. Copper.
Conditions to avoid:
Keep away from heat, ignition sources and incompatible materials. See
"Handling and Storage" (Section 7) and "Incompatibility" (Section 10).
Saccharin
NTP Carcinogen
IARC Carcinogen
No
No
No
No
No
No
No
No
IDH number: 209741
OSHA Carcinogen
(Specifically Regulated)
No
No
No
No
Page 3 of 5
Health Effects/Target Organs
Saccharin
Irritant, Allergen
No Target Organs
No Target Organs
Allergen, Central nervous system, Corrosive, Irritant, Mutagen
Ecological information:
Not available.
Information provided is for unused product only.
Recommended method of disposal:
Follow all local, state, federal and provincial regulations for disposal.
Hazardous waste number:
It is the responsibility of the user to determine if an item is hazardous as
defined in the Resource Conservation and Recovery Act (RCRA) at the time of
disposal. Product uses, transformations, mixtures, processes, etc., may
render the resulting material hazardous, under the criteria of ignitability,
corrosivity, reactivity and toxicity characteristics of the Toxicity Characteristics
Leaching Procedure (TCLP) 40 CFR 261.20-24.
U.S. Department of Transportation Ground (49 CFR)
Not regulated
None
None
Packing group:
None
International Air Transportation (ICAO/IATA)
Packing group:
Not regulated
None
None
None
Water Transportation (IMO/IMDG)
Packing group:
Not regulated
None
None
None
United States Regulatory Information
TSCA 8 (b) Inventory Status:
TSCA 12(b) Export Notification:
CERCLA/SARA Section 302 EHS:
CERCLA/SARA Section 311/312:
CERCLA/SARA 313:
California Proposition 65:
All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
Immediate Health, Delayed Health
This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Saccharin (CAS# 81-07-2). Cumene hydroperoxide (CAS# 80-15-9).
This product contains a chemical known in the State of California to cause cancer.
Canada Regulatory Information
CEPA DSL/NDSL Status:
All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
IDH number: 209741
Page 4 of 5
WHMIS hazard class:
D.2.B
This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet
format.
Prepared by: Karim Nasr, Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.
IDH number: 209741
Page 5 of 5
Page 1 of 5
__________________________________________________________________________________________
SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
LUBRIPLATE Lubricants Co.
129 Lockwood St.
Newark, NJ 07105
Emergency Telephone Number:
1-800-255-3924-CHEM-TEL (24 hour)
Telephone Number for information:
1-973-589-9150
SUBSTANCE: LUBRIPLATE® Air Tool Lubricant
MSDS No. – 0892150713054
TRADE NAMES/SYNONYMS:
PRODUCT USE: Petroleum lubricating oil
CREATION DATE: 02/13/2008
REVISION DATE: 07/22/2011
__________________________________________________________________________________________
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENT: Hydrotreated naphthenic distillates
CAS NUMBER: 64742-52-5/64742-53-6
EC NUMBER (EINECS): 265-155-0/265-156-6
PERCENTAGE: 90-95
COMPONENT: Soy methyl ester
CAS NUMBER: 67784-80-9
EC NUMBER (EINECS): 267-055-2
PERCENTAGE: 2-5
COMPONENT: Proprietary additive package
CAS NUMBER: NA
EC NUMBER (EINECS): NA
PERCENTAGE: 0-2
NOTE: The IP 346 value of the mineral oil is less than 3%
__________________________________________________________________________________________
SECTION 3 HAZARDS IDENTIFICATION
Page 2 of 5
EYE CONTACT:
SHORT TERM EXPOSURE: Irritation
LONG TERM EXPOSURE: No information available
INGESTION:
SHORT TERM EXPOSURE: Diarrhea, difficulty breathing
LONG TERM EXPOSURE: no information on significant adverse effects
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS):
Health – 1
Flammability – 1
Reactivity – 0
Not a Controlled Product under (WHMIS) – Canada
Special Protection: See Section 8
__________________________________________________________________________________________
SECTION 4 FIRST AID MEASURES
INHALATION: Remove to fresh air. See a physician if irritation persists.
SKIN CONTACT: Remove any contaminated clothing and wash with soap and warm water.
EYE CONTACT: Flush with clear water for 15 minutes or until irritation subsides. If irritation persists,
consult a physician.
INGESTION: If ingested, call a physician immediately. Do not induce vomiting.
__________________________________________________________________________________________
SECTION 5 FIRE FIGHTING MEASURES
FIRE AND EXPLOSION HAZARDS: Slight fire hazard
EXTINGUISHING MEDIA: Foam, Dry Chemical, Carbon Dioxide or Water Spray (Fog)
SPECIAL FIRE FIGHTING PROCEDURES: Cool exposed containers with water. Use air-supplied
breathing equipment for enclosed or confined spaces.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Do not store or mix with strong oxidants. Empty
containers retain residue. Do not cut, drill, grind, or weld, as they may explode.
__________________________________________________________________________________________
SECTION 6 ACCIDENTAL RELEASE MEASURES
Page 3 of 5
__________________________________________________________________________________________
SECTION 7 HANDLING AND STORAGE
STORAGE: Store at temperatures below 100°F. Store in a cool, dry area in tightly closed containers. Use
adequate ventilation. Avoid excessive heat, sparks, or open flames. Avoid prolonged or repeated skin contact.
__________________________________________________________________________________________
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE LIMITS:
OIL MIST IN AIR (Not Encountered in Normal Usage):
5 mg/m3 UK OES TWA
10mg/m3 UK OES STEL
VENTILATION: Provide local exhaust ventilation system. Ensure compliance with applicable exposure
limits.
EYE PROTECTION: Wear splash resistant safety goggles. Provide an emergency eye wash fountain and
quick drench shower in the immediate work area.
CLOTHING: Wear appropriate chemical resistant clothing.
GLOVES: Wear appropriate chemical resistant (nitrile) gloves.
RESPIRATOR: Consider the need for appropriate protective equipment, such as self-contained breathing
apparatus, adequate masks and filters.
__________________________________________________________________________________________
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: liquid
APPEARANCE: transparent
COLOUR: amber
PHYSICAL FORM: oil
ODOR: mineral oil odor
BOILING POINT: >288 C
FREEZING POINT: Not available
FLASH POINT: 196 C (COC)
LOWER FLAMMABLE LIMIT: 0.9% by volume
UPPER FLAMMABLE LIMIT: 7.0% by volume
AUTO IGNITION: not available
VAPOUR PRESSURE: <5 mm Hg
Page 4 of 5
EVAPORATION RATE: not available
VISCOSITY: 5 mm2/s @ 100 C
COEFFICIENT OF WATER/OIL DISTRIBUTION: not available
__________________________________________________________________________________________
SECTION 10 STABILITY AND REACTIVITY
REACTIVITY: Stable at normal temperatures and pressures
CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition. Avoid contact with
incompatible materials.
INCOMPATIBLES: Oxidising materials, chlorine
HAZARDOUS DECOMPOSITION:
Thermal decomposition products or combustion: oxides of carbon, oxides of sulphur
POLYMERISATION: Will not polymerise.
__________________________________________________________________________________________
SECTION 11 TOXICOLOGICAL INFORMATION
Hydrotreated naphthenic distillates:
TOXICITY DATA:
Greater than 5 g/kg oral-rat LD50
Soy methyl ester:
TOXICITY DATA:
No data available
Proprietary additive package:
TOXICITY DATA:
No data available
____________________________________________________________________________________________________________
SECTION 12 ECOLOGICAL INFORMATION
Not available
__________________________________________________________________________________________
SECTION 13 DISPOSAL CONSIDERATIONS
Page 5 of 5
LAND TRANSPORT RID: No classification assigned.
AIR TRANSPORT IATA: No classification assigned.
AIR TRANSPORT ICAO: No classification assigned.
MARITIME TRANSPORT IMDG: No classification assigned.
__________________________________________________________________________________________
SECTION 15 REGULATORY INFORMATION
EUROPEAN REGULATIONS:
EC CLASSIFICATION (CALCULATED): Not classified as dangerous.
SARA/TITLE III, Section 313 Status – Zinc compounds <1%
__________________________________________________________________________________________
SECTION 16 OTHER INFORMATION
The above information is furnished without warranty, expressed or implied, except that it is accurate to
the best knowledge of LUBRIPLATE Lubricants Company. The data on these sheets relates only to the
specific material designated herein. LUBRIPLATE Lubricants Company assumes no legal responsibility
for use or reliance upon this data.
22-3101
20 00
DATE OF PREPARATION
Apr 26, 2013
PRODUCT NUMBER
22-3101
PRODUCT NAME
BRIGHT LIFE® Interior Latex Satin Gloss Enamel, White
MANUFACTURER'S NAME
MARTIN SENOUR PAINTS
101 Prospect Avenue N.W.
Cleveland, OH 44115
Product Information
www.martinsenour.com
(216) 566-2902
www.paintdocs.com
accident)
% by Weight
2
1
0.1
5
12
CAS Number
112-34-5
107-21-1
14464-46-1
471-34-1
13463-67-7
Ingredient
Units
2-(2-Butoxyethoxy)-ethanol
ACGIH TLV
OSHA PEL
Ethylene Glycol
ACGIH TLV
100
OSHA PEL
50
Cristobalite
ACGIH TLV
0.025
OSHA PEL
0.05
Calcium Carbonate
ACGIH TLV
10
OSHA PEL
15
OSHA PEL
5
Titanium Dioxide
ACGIH TLV
10
OSHA PEL
10
OSHA PEL
5
Vapor Pressure
Not Available
Not Available
0.06 mm
MG/M3 CEILING (aerosol)
PPM CEILING
0.12 mm
mg/m3 as Resp. Dust
mg/m3 as Resp. Dust
mg/m3 as Dust
mg/m3 Total Dust
mg/m3 Respirable Fraction
mg/m3 as Dust
mg/m3 Total Dust
ROUTES OF EXPOSURE
EYES: Irritation.
HMIS Codes
Health 2*
Flammability 0
Reactivity 0
the liver
the urinary system
page 1 of 4
22-3101
CANCER INFORMATION
EYES:
SKIN:
INHALATION:
INGESTION:
FLASH POINT
Not Applicable
LEL
UEL
Not
Not
Not Applicable
Applicable
Applicable
EXTINGUISHING MEDIA
STORAGE CATEGORY
Not Applicable
VENTILATION
PROTECTIVE GLOVES
EYE PROTECTION
page 2 of 4
22-3101
9.93 lb/gal
1189 g/l
1.19
212 - 448 °F
100 - 231 °C
Not Available
62%
Slower than
ether
pH 9.5
0.72 lb/gal
86 g/l Less Water and Federally Exempt Solvents
0.30 lb/gal
36 g/l Emitted VOC
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
as paint."
Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given in
drinking water or by gavage. There is no evidence to indicate it causes birth defects in humans.
TOXICOLOGY DATA
CAS No.
Ingredient Name
112-34-5
LC50 RAT
4HR
Not Available
LD50 RAT
5660 mg/kg
107-21-1
Ethylene Glycol
LC50 RAT
4HR
Not Available
LD50 RAT
4700 mg/kg
14464-46-1
Cristobalite
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
471-34-1
Calcium Carbonate
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
13463-67-7
Titanium Dioxide
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
No data available.
page 3 of 4
22-3101
US Ground (DOT)
Canada (TDG)
IMO
IATA/ICAO
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
107-21-1
Ethylene Glycol
1
Glycol Ethers
2
TSCA CERTIFICATION
page 4 of 4
72-3101
45 00
DATE OF PREPARATION
Mar 26, 2013
PRODUCT NUMBER
72-3101
PRODUCT NAME
PRO LINE® Interior Latex Semi-Gloss Finish, White
MANUFACTURER'S NAME
Cleveland, OH 44115
Product Information
(216) 566-2902
www.paintdocs.com
accident)
% by Weight
0.1
6
10
CAS Number
14464-46-1
471-34-1
13463-67-7
Ingredient
Cristobalite
ACGIH TLV
OSHA PEL
Calcium Carbonate
ACGIH TLV
OSHA PEL
OSHA PEL
Titanium Dioxide
ACGIH TLV
OSHA PEL
OSHA PEL
Units
Vapor Pressure
0.025 mg/m3 as Resp. Dust
0.05 mg/m3 as Resp. Dust
10 mg/m3 as Dust
15 mg/m3 Total Dust
10 mg/m3 as Dust
10 mg/m3 Total Dust
ROUTES OF EXPOSURE
EYES: Irritation.
HMIS Codes
Health 1*
Flammability 0
Reactivity 0
CANCER INFORMATION
page 1 of 4
72-3101
EYES:
SKIN:
INHALATION:
INGESTION:
FLASH POINT
Not Applicable
LEL
UEL
Not
Not
Not Applicable
Applicable
Applicable
EXTINGUISHING MEDIA
STORAGE CATEGORY
Not Applicable
VENTILATION
PROTECTIVE GLOVES
EYE PROTECTION
page 2 of 4
72-3101
9.78 lb/gal
1171 g/l
1.18
212 - 213 °F
100 - 100 °C
Not Available
66%
Slower than
ether
pH 9.5
0.50 lb/gal
60 g/l Less Water and Federally Exempt Solvents
0.17 lb/gal
21 g/l Emitted VOC
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
as paint."
TOXICOLOGY DATA
CAS No.
Ingredient Name
14464-46-1
Cristobalite
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
471-34-1
Calcium Carbonate
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
13463-67-7
Titanium Dioxide
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
No data available.
page 3 of 4
72-3101
US Ground (DOT)
Canada (TDG)
IMO
IATA/ICAO
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
TSCA CERTIFICATION
page 4 of 4
22-3100
12 00
DATE OF PREPARATION
Apr 26, 2013
PRODUCT NUMBER
22-3100
PRODUCT NAME
BRIGHT LIFE® Interior Latex Satin Gloss Enamel, Bright White
MANUFACTURER'S NAME
Cleveland, OH 44115
Product Information
(216) 566-2902
www.paintdocs.com
accident)
% by Weight
2
2
0.1
2
22
CAS Number
112-34-5
107-21-1
14464-46-1
471-34-1
13463-67-7
Ingredient
Units
ACGIH TLV
OSHA PEL
Ethylene Glycol
ACGIH TLV
100
OSHA PEL
50
Cristobalite
ACGIH TLV
0.025
OSHA PEL
0.05
Calcium Carbonate
ACGIH TLV
10
OSHA PEL
15
OSHA PEL
5
Titanium Dioxide
ACGIH TLV
10
OSHA PEL
10
OSHA PEL
5
Vapor Pressure
Not Available
Not Available
0.06 mm
MG/M3 CEILING (aerosol)
PPM CEILING
0.12 mm
mg/m3 as Resp. Dust
mg/m3 as Resp. Dust
mg/m3 as Dust
mg/m3 Total Dust
mg/m3 as Dust
mg/m3 Total Dust
ROUTES OF EXPOSURE
EYES: Irritation.
HMIS Codes
Health 2*
Flammability 0
Reactivity 0
the liver
the urinary system
page 1 of 4
22-3100
CANCER INFORMATION
EYES:
SKIN:
INHALATION:
INGESTION:
FLASH POINT
Not Applicable
LEL
UEL
Not
Not
Not Applicable
Applicable
Applicable
EXTINGUISHING MEDIA
STORAGE CATEGORY
Not Applicable
VENTILATION
PROTECTIVE GLOVES
EYE PROTECTION
page 2 of 4
22-3100
10.58 lb/gal
1267 g/l
1.27
212 - 448 °F
100 - 231 °C
Not Available
66%
Slower than
ether
pH 9.0
0.39 lb/gal
47 g/l Emitted VOC
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
as paint."
Ethylene Glycol is considered an animal teratogen. It has been shown to cause birth defects in rats and mice at high doses when given in
drinking water or by gavage. There is no evidence to indicate it causes birth defects in humans.
TOXICOLOGY DATA
CAS No.
Ingredient Name
112-34-5
LC50 RAT
4HR
Not Available
LD50 RAT
5660 mg/kg
107-21-1
Ethylene Glycol
LC50 RAT
4HR
Not Available
LD50 RAT
4700 mg/kg
14464-46-1
Cristobalite
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
471-34-1
Calcium Carbonate
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
13463-67-7
Titanium Dioxide
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
No data available.
page 3 of 4
22-3100
US Ground (DOT)
Canada (TDG)
IMO
IATA/ICAO
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
107-21-1
Ethylene Glycol
2
Glycol Ethers
2
TSCA CERTIFICATION
page 4 of 4
U.S. Department of Labor
May be used to comply with
OSHA’s Hazard Communication Standard,
29 CFR 1910.1200. Standard must be
consulted for specific requirements.
Occupational Safety and Health Administration
(Non-Mandatory Form)
Form Approved
OMB No. 1218-0072
Page 1 of 2
IDENTITY (As used on label and list)
Master Appliance Ultratane Butane Fuel
Note:
Blank spaces are not permitted. If any item is not applicable, or no
information is available, the space must be marked to indicate that.
SECTION I.
MANUFACTURER’S NAME
ADDRESS
Master Appliance Corp.
2420 18
TH
Street
EMERGENCY TELEPHONE NO. 1-800-535-5053 (Infotrac)
TELEPHONE NO. FOR INFORMATION
1-262-633-7791
PO BOX 68
DATE PREPARED
January 2, 2013
RACINE WI 53401
SIGNATURE OF PREPARER
(optional)
SECTION II. HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
HAZARDOUS COMPONENTS
(Specific Chemical Identity: Common Name(s))
OSHA PEL
ACGIH TLV
Isobutane (CAS 75-28-5)
NE
800ppm
Propane
(CAS 74-98-6)
1000ppm
NE
Butane
(CAS 106-97-8)
800ppm
800ppm
Other Limits Recommended % (optional)
SECTION III. SHIPPING INFORMATION
PROPER SHIPPING NAME
Petroleum Gases, Liquefied
CLASS AND DIVISION NUMBER
2.1 (Flammable Gas)
UN NUMBER
UN-1075
REQUIRED LABELS
Flammable Gas label on each non-bulk package
PACKING GROUP
Not Listed
SECTION IV. PHYSICAL/CHEMICAL CHARACTERISTICS
BOILING POINT
11°F
SPECIFIC GRAVITY (H20 = 1)
.571
VAPOR PRESSURE @70°F (psig)
30 ± 2
MELTING POINT
-138c
VAPOR DENSITY (air = 1)
1
EVAPORATION RATE (Butyl Acetate = 1)
1
SOLUBILITY IN WATER
Negligible
APPEARANCE AND ODOR
Clear gas with light ethereal odor
SECTION V. FIRE AND EXPLOSION HAZARD DATA
FLAMMABLE LIMITS
LEL: 1.4
UEL: 9.5
FLASH POINT (METHOD USED)
-100°F Estimated
EXTINGUISHING MEDIA
Dry chemical, foam, carbon dioxide
Use water spray to cool containers. Avoid rocketing containers.
Containers generate pressure when heated causing violent bursting and
dangerous propelling of containers.
Material Safety Data Sheet For Master Appliance Ultratane Butane Fuel
January 2, 2013
Page 2 of 2
SECTION VI. REACTIVITY DATA
STABILITY
Stable:
Yes
Unstable:
CONDITIONS TO AVOID
Not established
INCOMPATIBILITY (Materials to Avoid)
Oxygen and strong oxidizing materials
HAZARDOUS DECOMPOSITION OR BYPRODUCTS Carbon oxides formed when burned
May occur:
CONDITIONS TO AVOID
Not established
Will not occur: Yes
SECTION VII. HEALTH HAZARD DATA
ROUTE(S) OF ENTRY
Inhalation?
HEALTH HAZARDS (Acute and Chronic)
Yes (A)
Skin? Yes (B)
Ingestion?
N/A
(A) Simple asphyxiant, dizziness, disorientation, headache, excitation, central
nervous system depression, anesthesia.
(B) Liquid contact with exposed skin can cause frostbite.
CARCINOGENICITY? N/A
NTP?
SIGNS AND SYMPTOMS OF EXPOSURE
N/A
IARC MONOGRAPHS? N/A
OSHA REGULATED? N/A
Dizziness, headache, ect.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
EMERGENCY AND FIRST AID PROCEDURES
None
Remove from exposure. If irritation develops seek medical attention.
SECTION VIII. PRECAUTIONS FOR SAFE HANDLING AND USE
Protect from ignition. Ventilate area
thoroughly.
WASTE DISPOSAL METHOD Treatment, storage, transportation and disposal must be in accordance with applicable
Federal, State and Local regulations.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store below 120°F. In case of accidental puncturing with
forklift, shut off forklift and any other possible source of
ignition. Ventilate area.
OTHER PRECAUTIONS
Use with adequate ventilation.
SECTION IX. CONTROL MEASURES
RESPIRATORY PROTECTION (Specific Type)
N/A
VENTILATION
Adequate
LOCAL EXHAUST
For small enclosed work areas
MECHANICAL (General)
Adequate for storage
PROTECTIVE GLOVES
Not required for normal handling
EYE PROTECTION
Safety Glasses
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
Not required for normal handling
WORK/HYGIENIC PRATICES
N/A
SECTION X. NFPA HAZARD CODES – HMIS RATING
HEALTH:
1
FIRE:
4
REACTIVITY: 0
U.S. Department of Labor
May be used to comply with
OSHA’s Hazard Communication Standard
29 CFR 1910.1200. Standard must be
consulted for specific requirements.
Occupational Safety and Health Administration
(Non-Mandatory Form)
Form Approved
OMB No. 1218-0072
Identity (As Used on Label and List)
Note: Blank spaces are not permitted. If any item is not applicable, or
no information is available, the space must be marked to indicate
that.
PROPANE
SECTION 1
Supplier’s Name
Emergency Telephone Number
Bernz-O-matic
716-798-4949
Address
Number, Street, City, State and ZIP Code
Telephone Number for Information
716-798-4949
Date Prepared
One BernzOmatic Drive
Medina, NY 14103
January 12, 2000
Signature of Preparer (Optional)
SECTION II - Hazardous Ingredients / Identity Information
Hazardous Components
Specific Chemical Identity, Common Name(s)
PROPANE CAS #74-98-6
NFPA HAZARD RATINGS
OSHA PEL
ACGIH TLV
Other Limits
Recommende
d
% (optional)
1000PPM
1000PPM
NA
100
HMIS RATINGS
Health -1
Health -0
Flammability -4
Flammability -4
Reactivity -0
Reactivity -0
Note: When propane fuel is burned efficiently, the normal by-products of combustion are CO2 and H20.
Inefficient burning may add CO to the by-products of combustion.
SECTION III - Physical / Chemical Characteristics
Boiling Point
Specific Gravity (H20 - 1)
-44º F
Liquid @ 60º F
Vapor Pressure (mm Hg)
.51
Melting Point
@ 100º F
197 psig
Vapor Density (AIR=1)
N/A
Evaporation Rate
@ 1 ATM @ 60º F
1.56
Butyl Acetate -1)
N/A
Solubility in Water
Not Soluble
Appearance and Odor
Colorless - Rotten Egg Odor
SECTION IV - Fire and Explosion Hazard Data
Flash Point (Method Used)
Flammable Limits
-156º F Closed Cup
LEL
UEL
2.1
9.5
Extinguishing Media
Stop flow of gas or oxygen
Special Fire Fighting Procedures
Use water to cool tanks
Auto Ignition temp. 842º F Heavier than air (vapor density 1.5).
Unusual Fire and Explosion Hazards
May travel a considerable distance to a source of ignition and flashback.
SECTION V - Reactivity Data
Stability Ë
Unstable
Stable X
Conditions to Avoid
N/A
Incompatibility (Materials to Avoid)
N/A
Hazardous Decomposition or Byproducts
None
Hazardous
Polymerization Ë
May Occur
Will Not Occur X
Conditions to Avoid
N/A
SECTION VI - Health Hazard Data
Routes of Entry Ë
Inhalation?
Skin?
Ingestion?
YES
YES
NO
Health Hazards (Acute and Chronic)
Contact with liquid propane may cause frost burns
Carcinogenicity Ë
NTP?
IARC Monographs?
OSHA Regulated?
N/A
N/A
N/A
Signs and Symptoms of Exposure
High concentrations may cause headaches and drowsiness.
Medical Conditions Generally Aggravated by Exposure
N/A
Emergency and First Aid Procedures
Remove exposed person from contaminated area.
Warning
This fuel, and byproducts of combustion of this fuel, contain chemicals
known to the State of California to cause cancer, birth defects, and
other reproductive harm.
SECTION VII - Precautions for Safe Handling and Use
Steps to be Taken in Case Material is Released or Spilled
Remove ignition sources and ventilate area.
Waste Disposal Method
Vent gas to atmosphere in flame free, spark free area outdoors.
Precautions to be Taken in Handling and Storing
Store at temperatures below 120º F in well ventilated, spark free, flame
free area.
Other Precautions
None
SECTION VIII - Control Measures
Respiratory Protection (Specify Type)
Not required with normal use.
Ventilation Ë
Local Exhaust
Mechanical (General)
Special
Other
N/A
N/A
N/A
N/A
Protective Gloves
Not required
Eye Protection
Not required
Other Protective Clothing or Equipment
Not required
Work / Hygienic Practices
N/A
SECTION IX - Shipping Information
WHMIS Classification: A - Compressed Gas & B1-Flammable Gas
DOT
Proper Shipping Name
Petroleum Gas, Liquefied
Class: 2.1
Hazard Classification
Flammable Gas
UN. No.
1075


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
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







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
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
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










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


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










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




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

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

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




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

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
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


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
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
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
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
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
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


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
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
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
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Tuesday, October 06, 2009
Page 1 of 5
MSDS - Material Safety Data Sheet
Product Name: Thread Cutting Oil
MSDS No.: 016035
Part Numbers Covered:
016035
016036
016050
016055
016060
016070
016100
016101
016102
016105
016110
016115
016120
016150
016151
016153
016154
016155
016157
016160
016165
016170
016190
016205
016215
016261
016264
016265
016266
016267
016272
016273
016276-W
016277
016278
016279
016281
016320
016321
016322
016324
016325
016326-W
016327
016328
016330
016331
016332
016333
016334
016336
016337
016338
016341
016342
016343
016348
016350
016351
016353
016365
016366
016390
016391
248674
403766
403774
Premier 461020
Premier 461020
Premier 461023
Premier 461024
1. Basic Information:
Manufacturer: William H. Harvey Company
1
Address: 4334 South 67th Street
City, ST Zip: Omaha, NE 68117-1019
1
0
Emergency Contact: CHEMTREC
Emergency Telephone Number: (800)424-9300
Contact: Information Telephone Number
Information Telephone Number: (800)228-9681
Last Update: 02/06/2009
Chemical State:
X
Chemical Type:
1
1
Expiration Date:
Liquid
Pure
Gas
X
0
Solid
B
Mixture
2. Ingredients:
Trade Secret
EHS
CAS No.
Chemical Name
% Range
64742-65-0
HIghly Refined Petroleum Oil
90 - 100
IARC
NTP
SARA
313
OSHA
SUB Z
PEL
5 mg/m3
ACGIH
TLV
Other
Limits
5 mg/m3
NI
3. Hazardous Identification:
Hazard Category:
X Acute
Chronic
Fire
Pressure
Reactive
Hazardous Identification Information:
Product has a low order of oral and dermal toxicity. Possible aspiration hazard. Induced vomiting may cause aspiration of
product into lungs.
4. First Aid Measures:
Route(s) of Entry:
SKIN, EYES, INHALATION, INGESTION
Health Hazards (Acute and Chronic):
Acute: Ingestion may cause gastric disturbance. Chronic: Not known to have chronic toxic effects.
Signs and Symptoms:
Page 2 of 5
MSDS No.: 016035
EYE CONTACT:
Lubricating oils are generally considered no more than minimally irritating to the eyes.
SKIN CONTACT:
Brief contact is not irritating. Lubricating oils are generally considered no more than mildly irritating to the skin. Because of its
defatting properties, prolonged and repeated contact may aggravate an existing or result in various skin disorders (dermatitis,
folliculitis, etc.).
INHALATION:
Inhalation of vapor or oil mist (generated at high temperatures) may result in mild irritation of the upper respiratory tract, including
irritation of the nose and throat, headache, nausea and drowsiness.
INGESTION:
No adverse effects expected. If more than several mouthfuls are swallowed, abdominal discomfort, nausea and diarrhea may
occur.
Medical Conditions Generally Aggravated by Exposure:
None known in normal usage concentrations.
Emergency and First Aid Procedures:
EMERGENCY FIRST AID CALL: 1-303-623-5716 COLLECT
EYES: Flush with water for 15 minutes. Get medical attention if effects persist.
SKIN: Wash thoroughly with soap and water. Get medical attention if irritation persists.
INHALATION: Move to fresh aire and provide oxygen if difficulty in breathing. Get medical attention.
INGESTION: Do not induce vomiting. Get medical attention
Other Health Warnings:
Avoid breathing of oil mists.
5. Fire Fighting Measures:
Flash Point: >370F
Lower Explosive Limit: NE
Upper Explosive Limit: NE
F.P. Method: COC
Fire Extinguishing Media: According to the NFPA guide, used water fog, foam, dry chemical or CO2. Do not use a direct stream of water.
Product will float and can be reignited on the surface of water. Use water to cool containers.
Special Fire Fighting Procedures:
Material will not burn unless preheated. Don not enter confined fire-space without proper protective equipment including a
positive-pressure, NIOSH approved self-contained breathing apparatus. Use water to keep fire exposed containers cool.
Unusual Fire and Explosion:
Exposing containers to high heat may cause container to rupture.
6. Accidental Release Measures:
Steps to be Taken in Case Material is Released or Spilled:
LARGE SPILLS: evacuate area and remove ignition sources. Dike and contain. Take up spills with sand, dirt, or other absorbent.
Clean surfaces so they do not remain slippery. Treat as an oil spill. Pump excess to storage tanks. Use absorbent for remaining
liquid and place in closed container for disposal according to local, state and federal regulations.
SMALL SPILLS: follow directions above but do not evacuate area unless the potential to slip and fall due to the spill is possible.
.
Page 3 of 5
MSDS No.: 016035
7. Handling and Storage:
Precautions to be Taken:
Store in a cool dry place. Store away from flames, heat, oxidizing agents, and strong alkalies. Keep containers tightly closed when
not in use.
KEEP OUT OF REACH OF CHILDREN AND ANIMALS.
Other Precautions:
Oily metal cuttings should be handled with the same precautions as for the cutting oil. Keep away from ignition sources.
Do not take internally. Avoid skin contact. Avoid eye contact. Avoid breathing vapors. Wash thoroughly after skin contact.
8. Exposure Controls/Personal Protection:
Ventilation Requirements:
Use with adequate ventillation. Mechanical exaust is reccomended for areas of concentrated mists, fumes or vapors.
Personal Protective Equipment:
EYES: wear splash proof goggles
SKIN: wear oil resistant gloves. Wash hands and arms after use. Remove contaminated clothing promptly and wash before
reuse. Treat contaminated clothing as a fire hazard .
INHALATION: ( if no mechanical exaust is available or in small enclosed areas) wear mist and/or organic vapr respirator when
mists or fumes are present. A well ventilated work area is the best engineering ppe.
INGESTION: avoid swallowing.
9. Physical and Chemical Properties:
Boiling Point: > 680º F
Melting Point: NA
Evaporation Rate (Butyl Acetate = 1): < 1.0
Vapor Pressure (mm Hg.): < .01
Specific Gravity (H20 = 1): 0.90000
Vapor Density (AIR = 1): NDA
Solubility In Water: Negligible
Appearance and Odor: Light amber to dark brown liquid / Sulfur
Other Information: VOC Content: < 20 grams/L
10. Stability and Reactivity:
Stability:
Stable
Incompatibility (Materials to Avoid):
High heat, open flame, strong oxidizers.
Decomposition/By Products:
May form carbon monoxide and other unidentified organic compounds upon combustion.
Hazardous Polymerization:
Will not occur
Page 4 of 5
MSDS No.: 016035
11. Toxicological Information:
Median Lethal Dose (LD50 LC50) (Species)
Oral: Believed to be >5 g/kg (rat); practically non-toxic
Inhalation: Not Determined
Dermal: Believed to be 5 g/kg (rabbit); no appreciable effect
Irritation Index, estimate of Irritation (Species)
Skin: Believed to be <0.5 / 8.0 (rabbit); no appreciable effect
Eyes: Believed to be <15 / 110 (rabbit); no appreciable effect
Sensitization: Not Determined
Other:
This product and its components are not classified as carcinogens by the IARC or OSHA. Used gasoline motor oils have
been shown to cause skin cancer when repeatedly applied to mouse skin without any effort to remove the material between
applications. There is no evidence of a causal relationship between skin cancer in humans and exposure to used motor oil.
12. Ecological Information:
No data available, but based on similar compounds, this product may have toxic effects to aquatic life.
13. Disposal Considerations:
This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in its
purchased form. Under RCRA, it is the responsibility of the user of the product to determine at the time of disposal, whether the
product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures, processes, etc. may
render the resulting materials hazardous.
Dispose in accordance with all local, state and federal regulations.
REMARKS: Recycle all used oils. Recycling used oils may provide exemptions related to hazardous waste regulations.
14. Transport Information:
DOT PROPER SHIPPING NAME: NA
DOT LABEL: NA
DOT NUMBER: NA
UN NUMBER: NA
IMCO CLASS: NA
DOT HAZARD CLASSIFICATION: NA
This product is considered an oil under 49 CFR (DOT) Part 130. If shipped by rail or highway in a tank with a capacity of 3,500
gllons or more, it is subject to the requirements of Part 130.
15. Regulatory Information:
NI
16. Other Information:
Page 5 of 5
MSDS No.: 016035
ABBREVIATIONS:
~ =
< =
> =
ACGIH
AIHA
C =
Deg =
EPA
F =
HMIS
IARC
NA =
NDA
NE =
NFPA
NI =
NIOSH
NTP
OSHA
Approximately
Less Than
Greater Than
= American Conference of Governmental Industrial Hygienists
= American Industrial Hygiene Association
Degrees Celcius
Degrees
= Environmental Protection Agency
Degrees Farenheit
= Hazardous Materials Information System
= International Agency for Research on Cancer
Not Applicable
= No Data Available
Not Established
= National Fire Protection Association
Not Indicated
= National Institure of Occupational Safety and Health
= National Toxicology Program
= Occupational Safety and Health Administration
The information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided by the
William H. Harvey Company without any warranty, expressed or implied regading its correctness. Some information presented and
conclusions drawn herein are from sources other than direct test data on the substance itself. This MSDS was prepared and is to be
used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Users should make their own investigations to determine the suitability of the information or products for their particular purpose.
The conditions or methods of handling, storage, use, and disposal of the product are beyond our control and may be beyond our
knowledge. For this and other reasons, the William H. Harvey company does not assume responsibility and expressly disclaims
liability for loss, damage or expense arising out of or in any way connected with handling, storage, use or disposal of the product.
Polycrylic/MW
Document Code: Polycrylic/MW
Version: 03
Date of Preparation
March 14, 2003
Section 1 - Product and Company Identification
PRODUCT NAME & NUMBERS
MINWAX® POLYCRYLIC® Protective Finish
3333 Satin
Rockler SKUs:
4444 Semi-Gloss
31895, 32135, 33821, 34701, 35455, 39863
5555 Gloss
MANUFACTURER'S NAME
MINWAX Company
10 Mountainview Road
Upper Saddle River, NJ
07458
Section 2 – Composition/Information on Ingredients
HMIS CODES
Health
Flammability
Reactivity
2
0
0
EMERGENCY TELEPHONE NO.
(216) 566-2917
INFORMATION TELEPHONE NO.
(800) 523-9299
% WT.
CAS No.
Ingredient Name
Vapor Pressure
---------------------------------------------------------------------------1
34590-94-8
2-Methoxymethylethoxypropanol
ACGIH
TLV 100
ppm (skin)
0.4 mm
ACGIH
TLV 150
ppm (skin) STEL
OSHA
PEL 100
ppm (skin)
OSHA
PEL 150
ppm (skin) STEL
2
29911-28-2
1-(2-Butoxymethylethoxy)-propanol
ACGIH
TLV
Not Available
0.06 mm
OSHA
PEL
Not Available
4
5131-66-8
Butoxypropanol
ACGIH
TLV
Not Available
0.6 mm
OSHA
PEL
Not Available
3
107-21-1
Ethylene Glycol
ACGIH
TLV
50
ppm CEILING
0.12 mm
OSHA
PEL
50
ppm CEILING
1
9014-85-1
Decylpoly(ethyleneoxy)ethanol
ACGIH
TLV
Not Available
OSHA
PEL
Not Available
2
872-50-4
1-Methyl-2-Pyrrolidone
ACGIH
TLV
Not Available
1 mm
OSHA
PEL
Not Available
Section 3 – Hazards Identification
ROUTES OF EXPOSURE
Exposure may be by INHALATION and/or SKIN or EYE contact, depending on
conditions of use. To minimize exposure, follow recommendations for proper use,
ventilation, and personal protective equipment.
Page 2 of 4
Polycrylic/MW
Section 4 – First Aid Measures
If INHALED:
If on SKIN:
If in EYES:
If SWALLOWED:
If affected, remove from exposure. Restore breathing. Keep warm
and quiet.
Wash affected area thoroughly with soap and water. Remove
contaminated clothing and launder before re-use.
Section 5 – Fire Fighting Measures
FLASH POINT
LEL
UEL
>200 °F PMCC
N.A.
N.A.
FLAMMABILITY CLASSIFICATION – Not Applicable
EXTINGUISHING MEDIA - Carbon Dioxide, Dry Chemical, Alcohol Foam
Closed containers may explode (due to the build-up of pressure) when exposed to
extreme heat. During emergency conditions overexposure to decomposition products
may cause a health hazard. Symptoms may not be immediately apparent. Obtain
medical attention.
Full protective equipment including self-contained breathing apparatus should
be used. Water spray may be ineffective. If water is used, fog nozzles are
preferable. Water may be used to cool closed containers to prevent pressure
Section 6 – Accidental Release Measures
Remove all sources of ignition. Ventilate the area. Remove with inert
absorbent.
Section 7 – Handling and Storage
STORAGE CATEGORY – DOL Storage Class IIIB
Keep container closed when not in use. Transfer only to approved containers
with complete and appropriate labeling. Do not take internally. Keep out of the
reach of children.
Section 8 – Exposure Controls/Personal Protection
Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid
breathing vapor and spray mist. Wash hands after using.
These coatings may contain materials classified as nuisance particulates
(listed "as Dust" in Section 2) which may be present at hazardous levels only
during sanding or abrading of the dried film. If no specific dusts are listed in
Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg./m3 (total
dust), 3 mg./m3 (respirable fraction), OSHA PEL 15 mg./m3 (total dust), 5 mg./m3
(respirable fraction).
Removal of old paint by sanding, scraping or other means may generate dust or
Page 3 of 4
Polycrylic/MW
Section 8 – Exposure Controls/Personal Protection (continued)
VENTILATION
materials in Section 2 is maintained below applicable exposure limits. Refer to
OSHA Standards 1910.94, 1910.107, 1910.108.
ventilation, wear a properly fitted organic vapor/particulate respirator approved
by NIOSH/MSHA for protection against materials in Section 2.
When sanding or abrading the dried film, wear a dust/mist respirator approved
by NIOSH/MSHA for dust which may be generated from this product, underlying paint,
or the abrasive.
PROTECTIVE GLOVES
Wear gloves which are recommended by glove supplier for protection against
materials in Section 2.
EYE PROTECTION
Section 9 – Physical and Chemical Properties
PRODUCT WEIGHT
8.51–8.55 lb/gal
EVAPORATION RATE
SPECIFIC GRAVITY
1.02-1.03
VAPOR DENSITY
BOILING POINT
212-449 °F
MELTING POINT
VOLATILE VOLUME
71 %
SOLUBILITY IN WATER
VOLATILE ORGANIC COMPOUNDS (VOC Theoretical)
2.5 lb/gal
Less Federally Exempt Solvents
1.0-1.1 lb/gal
Emitted VOC
Slower than Ether
Heavier than Air
Not Available
Not Available
Section 10 – Stability and Reactivity
STABILITY - Stable
CONDITIONS TO AVOID - None known.
INCOMPATIBILITY - None known.
HAZARDOUS DECOMPOSITION PRODUCTS - By fire: Carbon Dioxide, Carbon Monoxide
HAZARDOUS POLYMERIZATION - Will not occur
Section 11 – Toxicological Information
No ingredient in these products is an IARC, NTP or OSHA listed carcinogen.
Ethylene Glycol is considered an animal teratogen. It has been shown to cause
birth defects in rats and mice at high doses when given in drinking water or by
gavage. There is no evidence to indicate it causes birth defects in humans.
Prolonged overexposure to solvent ingredients in Section 2 may cause adverse
effects to the liver and urinary systems.
TOXICOLOGY DATA
CAS No.
Ingredient Name
---------------------------------------------------------------------------34590-94-8
2-Methoxymethylethoxypropanol
LC50
RAT
4HR
Not Available
Page 4 of 4
Polycrylic/MW
TOXICOLOGY DATA (continued)
CAS No.
Ingredient Name
---------------------------------------------------------------------------107-21-1
Ethylene Glycol
LC50
RAT
4HR
Not Available
LD50
RAT
4700
mg/kg
9014-85-1
Decylpoly(ethyleneoxy)ethanol
LC50
RAT
4HR
Not Available
LD50
RAT
Not Available
872-50-4
LC50
RAT
4HR
Not Available
LD50
RAT
4200
mg/kg
Section 12 – Ecological Information
ECOTOXICOLOGICAL INFORMATION - No data available.
Section 13 – Disposal Considerations
Waste from these products is not hazardous as defined under the Resource
Incinerate in approved facility. Do not incinerate closed container. Dispose
of in accordance with Federal, State/Provincial, and Local regulations regarding
pollution.
Section 14 – Transport Information - No data available.
Section 15 – Regulatory Information
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
107-21-1
Ethylene Glycol
3
872-50-4
2
WARNING: These products contain chemicals known to the State of California to
cause cancer and birth defects or other reproductive harm.
TSCA CERTIFICATION
All chemicals in these products are listed, or are exempt from listing, on the
TSCA Inventory.
Section 16 – Other Information
CANADIAN DISTRIBUTOR:
Consumer Brands Canada Inc.
200 Confederation Parkway
Vaughn, ON L4K 4T8
NOTE: These products have been classified in accordance with the hazard
criteria of the CPR and the MSDS contains all of the information required by the
CPR.
2716
11 00
DATE OF PREPARATION
May 24, 2013
PRODUCT NUMBER
2716
PRODUCT NAME
MINWAX® WOOD FINISH®, Dark Walnut
MANUFACTURER'S NAME
MINWAX Company
10 Mountainview Road
Upper Saddle River, NJ 07458
Product Information
(800) 523-9299
www.minwax.com
www.paintdocs.com
accident)
% by Weight
3
55
0.2
CAS Number
64742-88-7
64742-88-7
1333-86-4
Ingredient
Units
Med. Aliphatic Hydrocarbon Solvent
ACGIH TLV
Not Available
OSHA PEL
Not Available
Mineral Spirits
ACGIH TLV
100 PPM
OSHA PEL
100 PPM
Carbon Black
ACGIH TLV
3.5 MG/M3
OSHA PEL
3.5 MG/M3
Vapor Pressure
2 mm
2 mm
ROUTES OF EXPOSURE
EYES: Irritation.
HMIS Codes
Health 2*
Flammability 2
Reactivity 0
the liver
the urinary system
CANCER INFORMATION
page 1 of 4
2716
EYES:
SKIN:
INHALATION:
INGESTION:
FLASH POINT
LEL
UEL
105 °F PMCC
1.0
6.0
Combustible, Flash above 99 and below 200 °F
EXTINGUISHING MEDIA
Closed containers may explode when exposed to extreme heat.
STORAGE CATEGORY
DOL Storage Class II
Contents are COMBUSTIBLE. Keep away from heat and open flame.
To minimize the possibility of spontaneous combustion: control the accumulation of overspray; soak wiping rags and waste immediately after
use in a water-filled, closed metal container; air dry filters outside, far from any combustible material and separated by bricks or other noncombustible spacers; dispose of all contaminated materials and waste properly. Consult OSHA 29 CFR 1910.107(b)(5) and NFPA 33,
Chapter 8 (8-9) for the proper procedures.
VENTILATION
page 2 of 4
2716
PROTECTIVE GLOVES
EYE PROTECTION
OTHER PRECAUTIONS
7.07 lb/gal
846 g/l
0.85
300 - 425 °F
148 - 218 °C
Not Available
66%
Slower than
ether
4.25 lb/gal 509 g/l Emitted VOC
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is
TOXICOLOGY DATA
CAS No.
Ingredient Name
64742-88-7
Med. Aliphatic Hydrocarbon Solvent
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
64742-88-7
Mineral Spirits
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
1333-86-4
Carbon Black
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
No data available.
page 3 of 4
2716
US Ground (DOT)
May be Classed as a Combustible Liquid for U.S. Ground.
UN1263, PAINT, 3, PG III, (ERG#128)
Bulk Containers may be Shipped as:
UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128)
Canada (TDG)
May be Classed as a Combustible Liquid for Canadian Ground.
UN1263, PAINT, CLASS 3, PG III, (ERG#128)
IMO
5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity.
UN1263, PAINT, CLASS 3, PG III, (41 C c.c.), EmS F-E, S-E, ADR (D/E)
IATA/ICAO
UN1263, PAINT, 3, PG III
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
TSCA CERTIFICATION
page 4 of 4
Product Name: MOBIL SHC 634
Revision Date: 23May2007
Page 1 of 8
______________________________________________________________________________________________________________________
SECTION 1
PRODUCT AND COMPANY IDENTIFICATION
PRODUCT
Product Description: Synthetic Base Stocks and Additives
Product Code: 201560500570, 602912-00, 970321
Intended Use: Circulating/gear oil
COMPANY IDENTIFICATION
Supplier:
EXXON MOBIL CORPORATION
3225 GALLOWS RD.
FAIRFAX, VA. 22037 USA
24 Hour Health Emergency
609-737-4411
Transportation Emergency Phone
800-424-9300
ExxonMobil Transportation No.
281-834-3296
MSDS Requests
713-613-3661
Product Technical Information
800-662-4525, 800-947-9147
MSDS Internet Address
http://www.exxon.com, http://www.mobil.com
SECTION 2
COMPOSITION / INFORMATION ON INGREDIENTS
No Reportable Hazardous Substance(s) or Complex Substance(s).
SECTION 3
HAZARDS IDENTIFICATION
This material is not considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
POTENTIAL HEALTH EFFECTS
Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure
injection under skin may cause serious damage.
NFPA Hazard ID:
HMIS Hazard ID:
Health:
Health:
0
0
Flammability: 1
Flammability: 1
Reactivity: 0
Reactivity: 0
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.
Page 2 of 8
______________________________________________________________________________________________________________________
mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the
body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by
a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be
minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent
of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5
FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.
Inappropriate Extinguishing Media: Straight Streams of Water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent runoff from fire control or dilution from entering streams,
sewers, or drinking water supply. Firefighters should use standard protective equipment and in enclosed
spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
protect personnel.
Hazardous Combustion Products: Smoke, Fume, Oxides of carbon, Aldehydes, Incomplete combustion
products, Sulfur oxides
FLAMMABILITY PROPERTIES
Flash Point [Method]: >210C (410F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9
Autoignition Temperature: N/D
SECTION 6
UEL: 7.0
ACCIDENTAL RELEASE MEASURES
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
Page 3 of 8
______________________________________________________________________________________________________________________
Land Spill: Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.
Water Spill: Stop leak if you can do it without risk. Confine the spill immediately with booms. Warn other
shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.
SECTION 7
HANDLING AND STORAGE
HANDLING
Prevent small spills and leakage to avoid slip hazard.
Static Accumulator: This material is a static accumulator.
STORAGE
Do not store in open or unlabelled containers.
SECTION 8
EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols
can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL, 5 mg/m³ - OSHA PEL.
NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION
Page 4 of 8
______________________________________________________________________________________________________________________
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapor warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Work conditions can greatly affect glove durability; inspect and replace worn or damaged
gloves. The types of gloves to be considered for this material include:
No protection is ordinarily required under normal conditions of use.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional
data.
GENERAL INFORMATION
Physical State: Liquid
Color: Orange
Odor: Characteristic
Odor Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C ): 0.869
Flash Point [Method]: >210C (410F) [ ASTM D-92]
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0
Autoignition Temperature: N/D
Boiling Point / Range: > 316C (600F)
Page 5 of 8
______________________________________________________________________________________________________________________
Viscosity: 460 cSt (460 mm2/sec ) at 40 C
Oxidizing Properties: See Sections 3, 15, 16.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Pour Point:
-30°C (-22°F)
SECTION 10
STABILITY AND REACTIVITY
STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.
MATERIALS TO AVOID: Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
SECTION 11
ACUTE TOXICITY
Route of Exposure
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3
Irritation: No end point data.
Ingestion
Toxicity (Rat): LD50 > 2000 mg/kg
Skin
Toxicity (Rabbit): LD50 > 2000 mg/kg
Irritation (Rabbit): Data available.
TOXICOLOGICAL INFORMATION
Conclusion / Remarks
Minimally Toxic. Based on test data for structurally similar
materials.
Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.
materials.
materials.
Negligible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.
Eye
Irritation (Rabbit): Data available.
CHRONIC/OTHER EFFECTS
Contains:
May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials.
Page 6 of 8
______________________________________________________________________________________________________________________
The following ingredients are cited on the lists below: None.
1 = NTP CARC
2 = NTP SUS
SECTION 12
--REGULATORY LISTS SEARCHED-3 = IARC 1
5 = IARC 2B
4 = IARC 2A
6 = OSHA CARC
ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.
Material -- Not expected to demonstrate chronic toxicity to aquatic organisms.
MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.
SECTION 13
DISPOSAL CONSIDERATIONS
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.
DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed as hazardous wastes. It
does not exhibit the hazardous characteristics of ignitability, corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However, used
product may be regulated.
Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and
can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be
completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken
for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
Page 7 of 8
______________________________________________________________________________________________________________________
LAND (TDG) : Not Regulated for Land Transport
SEA (IMDG) : Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA) : Not Regulated for Air Transport
SECTION 15
REGULATORY INFORMATION
OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
NATIONAL CHEMICAL INVENTORY LISTING: IECSC, DSL, EINECS, KECI, TSCA
EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
SARA (313) TOXIC RELEASE INVENTORY: This material contains no chemicals subject to the supplier notification
requirements of the SARA 313 Toxic Release Program.
The Following Ingredients are Cited on the Lists Below:
Chemical Name
CAS Number
PHENOL, 4,4118-82-1
METHYLENEBIS(2,6-BIS(1,1DIMETHYLETHYL)1 = ACGIH ALL
2 = ACGIH A1
3 = ACGIH A2
4 = OSHA Z
5 = TSCA 4
List Citations
5, 9
--REGULATORY LISTS SEARCHED-6 = TSCA 5a2
11 = CA P65 REPRO
7 = TSCA 5e
12 = CA RTK
8 = TSCA 6
13 = IL RTK
9 = TSCA 12b
14 = LA RTK
10 = CA P65 CARC
15 = MI 293
Code key: CARC=Carcinogen; REPRO=Reproductive
SECTION 16
OTHER INFORMATION
N/D = Not determined, N/A = Not applicable
16 = MN RTK
17 = NJ RTK
18 = PA RTK
19 = RI RTK
Page 8 of 8
______________________________________________________________________________________________________________________
----------------------------------------------------------------------------------------------------------------------------------------------------This warning is given to comply with California Health and Safety Code 25249.6 and does not constitute an admission
or a waiver of rights. This product contains a chemical known to the State of California to cause cancer.
----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief, accurate
and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most current
available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly or indirectly hold any interest.
----------------------------------------------------------------------------------------------------------------------------------------------------Internal Use Only
MHC: 0, 0, 0, 0, 0, 0
PPEC: A
DGN: 2007946XUS (547900)
----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Exxon Mobil Corporation, All rights reserved
The Procter & Gamble Company
P&G Household Care
Fabric & Home Care Innovation Center
5299 Spring Grove Avenue
Cincinnati, OH 45217-1087
MSDS #: FH/H/2003/TWTA-5HRJZ8
Supersedes:
Issue Date: 7/2007
Issue Date: 5/2006
SECTION I - PRODUCT IDENTIFICATION
Identity: Mr Clean Magic Eraser (Original, Duo, Extra Strength, Auto) Finished Product
Brands: 1-800-248-1612 or call your Poison Control Center or your physician
P&G Telephone Number:
1-800-248-1612 or call your Poison Control Center or your physician .
SECTION II - HAZARDS IDENTIFICATION
Potential Health Hazards (Acute and Chronic): (See Section 11 for more information)
Ingestion: Blockage of the gastrointestinal tract may occur if swallowed. Do not ingest.
Eye Contact: Irritating to eyes.
Skin Contact: Moderately irritating to the skin. Prolonged / repeated contact may result in skin
sensitization.
Inhalation: Ensure adequate ventilation.
Signs and Symptoms of Exposure:
Ingestion:
May cause irritation and/or blockage of the gastrointestinal track.
Eye Contact: Dust from foam may cause mechanical irritation.
Skin:
Dust from foam may cause mechanical irritation.
Inhalation: Dust from foam may cause irritation of the respiratory track.
Medical Conditions Generally Know to be Aggravated by Exposure: None
Potential Environmental Effects: (See Section 12 for more information)
MrClean MagicEraser OrginalDuoExtraAuto (2).doc
SECTION III - COMPOSITION AND INGREDIENTS
Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA:
CAS No.
Composition
LD50/LC50
Chemical Name Common Name
Range
NONE
SECTION IV – FIRST AID INFORMATION
First Aid Procedures:
Ingestion: If foam is ingested, contact a physician or veterinarian immediately. Intestinal
blockage may be life threatening to some household pets..
Eye Contact: In case of eye irritation, flush thoroughly with water for 15 minutes. If irritation
persists, seek medical advice.
Skin:
In case of skin irritation, flush affected area thoroughly with water and apply a cold
compress. If irritation persists, seek medical advice. Remove any contaminated
clothing.
Inhalation: If respiratory irritation occurs, moving from the site of exposure to an area with
fresh air. If irritation persists, seek medical advice.
Note to Physician: (if applicable)
Other: Consumer product package has the following precautionary statement: Consumer product
package has the following precautionary statement: “Caution: keep out of reach of children. Keep out
of reach of toddlers and pets to avoid accidental ingestion. Do not use on skin or other parts of the
body. Using on skin will likely cause abrasions.”
SECTION V - FIRE FIGHTING INFORMATION
Flash Point (Method Used): Closed Cup FP
Flashpoint: 1076ºF (5806ºC)
This product does not sustain combustion when exposed to an open flame.
Flammable Properties:
Upper Flammable Limit: unknown
Lower Flammable Limit: unknown
Explosive Limits:
UEL:
unknown
LEL:unknown
Auto-ignition Temperature: Unknown
Hazardous Combustion Products: Unknown
Explosion Data (Sensitivity to Mechanical Impact): NA
Explosion Data (Sensitivity to Static Discharge):NA
Extinguishing Media:
Suitable: Regular dry chemical, carbon dioxide, water, regular foam. For large fires use regular foam or
flood with fine water spray.
Unsuitable:
Protection of Firefighters:
Specific Hazards Arising from the Material: None known
Protective Equipment and Precautions for Firefighters:
SECTION VI - ACCIDENTAL RELEASE MEASURES
Personal Precautions: None known
Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH
ALL FEDERAL, STATE, PROVINCIAL AND LOCAL REGULATIONS.
Methods for Containment: Collect spilled material in an appropriate container for disposal.
Methods for Cleanup: Keep out of water supplies and sewer.
Other Information: (if applicable) NA
SECTION VII – HANDLING AND STORAGE
Precautions To Be Taken in Handling: None known
Precautions To Be Taken in Storage:: None known
SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines: Workplace should have sufficient general.
Engineering Controls: Provide local ventilation.
Personal Protective Equipment (PPE):
Eye/Face Protection: Provide emergency eyewash fountain and quick drench shower in the work area.
Skin Protection: Do not rub on skin, foam can cause abrasion to skin
Respiratory Protection: Under conditions of frequent use or heavy exposure, respiratory protection may
be needed. (Any chemical cartridge respirator with an organic vapor cartridge, dust and mist filter(s)).
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Flash Point (Method Used): This material does
Appearance (color, physical form, shape):
not sustain combustion in open flame testing.
Original, Duo, Extra Strength, Auto – white foam
Duo - white and blue foam
Odor: None
Reserve Alkalinity: NK
Solubility in Water: NK
Odor Threshold: Not applicable
Decomposition Temperature: NK
Physical State: Liquid
Vapor Pressure (mm Hg): Below 2 mm Hg
Evaporation Rate (nBuOAc=1): NK
Vapor Density (Air=1): NK
Specific Gravity/Density: NK
Melting/Freezing Point: NK
Boiling Point:NK
Partition Coefficient (n-octanol/water): NK
pH ( ): NK
Volatile Organic Compound (VOC): Not applicable - Product not regulated for VOC Content at State
or Federal level.
SECTION X - STABILITY AND REACTIVITY
Chemical Stability: Stable at normal temperatures and pressures
Conditions to Avoid: Avoid heat, flames, sparks, and other sources of ignition. Avoid contact with
incompatible materials.
Incompatible Materials: Avoid contact with strong oxidizers.
Hazardous Decomposition Products: Oxides of carbon, oxides of sulfur, aromatic compounds,
formaldehyde, hydrogen cyanide.
Possibility of Hazardous Reactions: No systemic effects expected.
SECTION XI - TOXICOLOGICAL INFORMATION
Chronic Effects: No chronic health effects reported.
Target Organs: No target organs reported.
Carcinogenicity: This finished consumer product is not carcinogenic.
NTP: No
IARC: No
SECTION XII - ECOLOGICAL INFORMATION
This product is expected to be safe at relevant environmental concentrations. It is intended for dispersive
use and should not be disposed of directly into the environment. The article, packaging, or container is
compatible with municipal solid waste systems and will not pose a hazard to the environment when the
waste is properly handled.
SECTION XIII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: Disposal is to be performed in compliance with federal, state/provincial and
local regulations.
Non-Household Setting (US Federal):
Product covered by this MSDS, in their original form, when disposed as waste, are considered non
hazardous waste according to the federal RCRA Regulation (40CFR261). Disposal should be in
accordance with the local, state and federal regulations.
Non-Household Setting (California): No
Household Use:
Product used in household may be disposed of in refuse.
SECTION XIV - TRANSPORT INFORMATION
Ground Transport (US DOT): Not regulated
Air Transport (IATA): Not regulated
Marine/Water Transport (IMDG): Not regulated
SECTION XV - REGULATORY INFORMATION
United States
All intentionally-added components of this product are listed on the US TSCA Inventory.
EPA Registration Number: Not Applicable
SARA 313/302/304/311/312 chemicals: None
California: This product has been evaluated and does not require warning labeling under California
Proposition 65.
California Registration Number: Not Applicable
State Right-to-Know and CERCLA:
The following ingredients present in the finished product are listed on state right-to-know lists or state
worker exposure lists
Ingredient
CAS #
Level
CERCLA
RQ
IL
MA
State
NJ
PA
RI
NONE
Canada
All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been
classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR)
and this MSDS contains all information required by the Controlled Products Regulations.
SECTION XVI - OTHER INFORMATION
Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance.
P&G Hazard Rating:
*N/A. - Not Applicable
Health:
1
Flammability: 2
Reactivity:
1
4=EXTREME
3=HIGH
2=MODERATE
1=SLIGHT
0=NOT SIGNIFICANT
*N/K. - Not Known
Data supplied is for use only in connection with occupational safety and health.
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance
regarding the use of this material. The information contained here has been compiled from sources
considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s
knowledge. It is not meant to be an all-inclusive document on worldwide hazard communication
regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of
use and design the appropriate protective mechanisms to prevent employee exposures, property damage
or release to the environment. Procter & Gamble assumed no responsibility for injury to the recipient or
third persons, or for any damage to any property resulting from misuse of the product.
Murphy® Oil Soap Liquid
1.
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
COLGATE-PALMOLIVE COMPANY
Institutional Products Division
191 East Hanover Avenue
Morristown, NJ 07960-3151
ACUTE HEALTH. . . 1
FIRE. . . . . . . . . . . . . 0
REACTIVITY. . . . . . 0
Least=0
HMIS HAZARD RATING
Slight=1
Moderate=2
High=3
Extreme= 4
®
PRODUCT NAME: Murphy Oil Soap Liquid
LABEL CODE:
01101 (16 oz), 01106 (32 oz), 01103 (1 gal)
CAS NUMBER:
Not applicable - product is a mixture
GENERAL USE:
A specially formulated, mild, multi-purpose
cleaner.
2.
For consumer information: Call (800) 432-8226
EMERGENCY TELEPHONE NUMBER: For emergency involving
spill, leak, fire, exposure or accident, call CHEMTREC:
(800) 424-9300, day or night.
THE PITTSBURGH POISON CENTER HAS BEEN PROVIDED
SPECIFIC INFORMATION FOR USE IN MEDICAL
EMERGENCIES INVOLVING THIS PRODUCT:
CALL COLLECT: (412) 692-5596.
COMPOSITION/INFORMATION ON INGREDIENTS
OSHA REGULATED COMPONENTS (present at a concentration
> or = 1%):
Component
Potassium
Hydroxide
CAS #
1310-58-3
%
1-5
PEL
None
TLV
2 mg/m3
The following components, present at a concentration > or =
0.1%, are listed as carcinogens or potential carcinogens by either
the National Toxicology Program (NTP), the International Agency
for Research on Cancer (IARC) or OSHA:
Component
CAS #
%
PEL
TLV
None - not applicable
POTENTIAL HEALTH EFFECTS:
EYE CONTACT:
Direct exposure to large amounts may cause eye irritation, but no permanent eye injury is expected.
SKIN CONTACT: No skin irritation is expected with normal use. However, skin irritation may occur with prolonged or excessive
contact.
INGESTION:
Repeated overexposure may be harmful.
INHALATION:
No adverse effects expected with normal use.
EYE CONTACT: Flush eye with large amounts of warm water for 15 minutes. Get medical attention if irritation persists.
SKIN CONTACT: Flush skin with large amounts of water for 15 minutes. Get medical attention if irritation occurs.
INGESTION:
Drink 2-4 ounces of a clear liquid. Get medical attention.
INHALATION:
Not applicable.
Flash Point (Method):
Extinguishing Media:
SPECIAL FIRE FIGHTING PROCEDURES:
Not established.
Water spray, CO2, All-purpose dry chemical
Self-contained breathing apparatus and protective clothing should be worn when fighting
chemical fires.
Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of water.
7. HANDLING AND STORAGE:
Store in a cool dry place (40 – 125 degrees F).
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
GENERAL CONTROLS:
Avoid contact with skin and eyes.
PROTECTIVE CLOTHING: Under normal conditions of use, no special precautions or control measures are required. In processing
and packaging operations where repeated skin or eye contact are possible, the use of safety goggles and
rubber gloves is recommended.
SPECIAL PRECAUTIONS: Keep out of the reach of children.
9.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance and odor:
Specific Gravity:
Amber, viscous liquid. Citrus odor.
Approximately 1.0
pH:
11.0 ± 0.6 (1% Solution)
GENERAL:
INCOMPATIBLE MATERIALS:
HAZARDOUS DECOMPOSITION:
This product is stable. Hazardous polymerization will not occur.
Avoid contact with strong oxidizing and reducing agents, acids, alkalis, organic peroxides and
easily ignitable materials. Avoid prolonged contact with reactive metals (e.g. aluminum, brass,
bronze, etc.).
May produce irritating or poisonous gases upon thermal decomposition.
This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety
Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration
available safety-related information including information on individual ingredients, similar ingredients, similar formulas and potential
ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the
MSDS.
12. ECOLOGICAL INFORMATION:
Not Available.
Small quantities generated by consumer use may be disposed of in a sanitary sewer with large quantities of water. Empty containers
generated by consumer use may be disposed of as conventional waste.
Any disposal practice must be in compliance with local, state, and federal laws and regulations (contact local or state government
agency for specific rules). Do not dump into sewers, any body of water, or onto the ground.
14. TRANSPORTATION
This product is not regulated as a DOT hazardous material.
RCRA (40 CFR 261, Subpart D): Not Applicable.
CLEAN WATER ACT:
Contains potassium hydroxide which is a Section 311 material.
CLEAN AIR ACT:
Contains ethanol which is a Section 111 material.
SARA:
Sections 301-304 (Threshold planning quantity – TPQ)
40 CFR 355:
The TPQ for this product is 10,000 lbs.
Acute health hazard: Irritant
Section 313 (Toxic chemical release reporting)
40 CFR 372: The following chemicals must be reported under
SARA 313:
Not Applicable.
CERCLA:
Section 102 (Reportable Quantity – RQ)
40 CFR 302:
The RQ for this product to the environment is 32,258 lbs. based
on the presence of potassium hydroxide (3.1%). Releases
greater than or equal to 32,258 lbs. must be reported to The
National Response Center (NRC) immediately: 800-424-8802.
TSCA Section 8(b) INVENTORY STATUS:
All ingredients in this product are listed on the TSCA Inventory or
are not required to be listed on the TSCA Inventory.
NEW JERSEY RIGHT TO KNOW HAZARDOUS SUBSTANCE
LIST:
This product contains the following components
subject to reporting requirements:
Potassium hydroxide, ethanol
PENNSYLVANIA HAZARDOUS SUBSTANCE LIST:
Potassium hydroxide
MASSACHUSETTS SUBSTANCE LIST:
Potassium hydroxide, ethanol
CALIFORNIA SAFE DRINKING WATER AND TOXIC
ENFORCEMENT ACT (PROPOSITION 65):
subject to reporting requirements: None
CANADA:
Workplace Hazardous Materials Information System
(WHMIS)-listed material.
Potassium hydroxide
Effective Date: June 29, 2000
Supersedes MSDS dated April 28, 1997
MSDS Status: Revised sections 1, 8, 11
The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based
on its knowledge and information as of the date noted. Colgate-Palmolive makes no representation, guarantee or warranty, expressed
or implied, as to the accuracy, reliability or completeness of the information and assumes no responsibility for injury, damage or loss
resulting from the use of the material.
Prepared in accordance with ISO 11014-1/ANSI standard Z400.1-2004
Print Date Mar-08-2013
Revision Date Mar-08-2013
Product code
Product name
5512
Opaque White
Product category
5500 Series Flat Poster Screen Ink
Manufacturer or supplier's details
UNITED STATES
Nazdar Company
8501 Hedge Lane Terrace
Shawnee, KS 66227
Tel: 1-913-422-1888
Tel: 1-800-677-4657
Fax: 1-913-422-2294
UNITED KINGDOM
Nazdar Limited
Barton Road
Heaton Mersey
Stockport, England SK4 3EG
Tel: +44 161 442 2111
Emergency Telephone Number
USA:
Chemtrec: 1-800-424-9300
Outside USA: Chemtrec: 1-703-527-3887
Website: www.nazdar.com
MSDS Information: 1-913-422-1888 ext 2305
MSDS Contact: Regulatory Compliance
email: [email protected]
This product is a preparation. Health hazard information is based on its components.
Appearance
Emergency Overview
Colored liquid
FLAMMABLE LIQUID AND VAPOR.
Aspiration hazard. Harmful: may cause lung damage if swallowed. Irritant. May cause
drowsiness and dizziness.
Eyes
Skin
Inhalation
Moderately irritating to the eyes.
Causes skin irritation.
May cause irritation of respiratory tract. Inhalation of high vapour concentrations may
cause symptoms like headache, dizziness, tiredness, nausea and vomiting.
Harmful if swallowed. Potential for aspiration if swallowed. Risk of serious damage to the
lungs (by aspiration).
Ingestion
3. COMPOSITION/INFORMATION ON INGREDIENTS
Component
Titanium dioxide
Kaolin
Stoddard solvent
Petroleum naphtha, light aromatic
Ethylene glycol monopropyl ether
1,2,4-Trimethylbenzene (contaminant)
Solvent naphtha (petroleum), medium aliphatic
Silicon Dioxide
Cumene (contaminant)
CAS-No
13463-67-7
1332-58-7
8052-41-3
64742-95-6
2807-30-9
95-63-6
64742-88-7
7631-86-9
108-67-8
98-82-8
Weight %
10 - 30
10 - 30
10 - 30
10 - 30
5 - 10
5 - 10
5 - 10
1-5
1-5
<1
the ingredient and cannot be separated. The percentage listed for the contaminant is as contained in the Hydrocarbon ingredient. (Example: 100%
Hydrocarbon, 10% Contaminant A, 3% Contaminant B)
Eye Contact
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. Get medical attention immediately if irritation
develops and persists.
______________________________________________________________________________________________
Page 1 / 7
Product code 5512 - Opaque White
______________________________________________________________________________________________
Skin Contact
Wash off immediately with soap and plenty of water. Use a mild soap if available. Rinse
immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. If
irritation develops, get medical attention.
Inhalation
If breathed in, move person into fresh air. If breathing is irregular or stopped, administer
artificial respiration. Get medical attention immediately.
Ingestion
If swallowed, DO NOT induce vomiting. Call a physician or Poison Control Centre
immediately. Never give anything by mouth to an unconscious person.
5. FIRE-FIGHTING MEASURES
FLAMMABLE LIQUID AND VAPOR.
Suitable Extinguishing Media
Foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures
that are appropriate to local circumstances and the surrounding environment.
Protective Equipment and
Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear. Keep away from fire, sparks and heated
surfaces. Cool containers / tanks with water spray. Fire or intense heat may cause violent
rupture of packages.
Specific Hazards Arising from the
Chemical
Thermal decomposition can lead to release of irritating gases and vapours. Burning
produces obnoxious and toxic fumes. Keep product and empty container away from heat
and sources of ignition. Risk of ignition.
Personal Precautions
Remove all sources of ignition. Ventilate the area. Avoid breathing dust or vapor. Avoid
contact with skin, eyes and clothing. Evacuate personnel to safe areas. Keep people away
from and upwind of spill/leak.
Methods for Cleaning Up
Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth,
diatomaceous earth, vermiculite) and transfer to a container for disposal according to local /
national regulations (see section 13). Do not use sparking tools.
Environmental Precautions
Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If
the product contaminates rivers and lakes or drains inform respective authorities.
Handling
Avoid contact with skin, eyes and clothing. Ensure adequate ventilation. Remove and
wash contaminated clothing before re-use. Discard contaminated shoes. When using do
not smoke. Do not take internally. Harmful or fatal if swallowed. Take notice of the
directions of use on the label.
Storage
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep container
closed when not in use. Keep out of the reach of children. Keep away from heat and
sources of ignition.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure limits
Component
ACGIH TLV
OSHA PEL
NIOSH IDLH
Ontario TWAEV
Mexico OEL (TWA)
______________________________________________________________________________________________
Page 2 / 7
______________________________________________________________________________________________
Titanium dioxide
TWA: 10 mg/m3
Kaolin
TWA: 2 mg/m3
(respirable fraction)
Stoddard solvent
TWA: 100 ppm
TWA: 10 mg/m3 (total
dust)
dust)
dust)
TWA: 5 mg/m3
(respirable fraction)
dust)
TWA: 100 ppm
TWA: 525 mg/m3
TWA: 500 ppm
TWA: 2900 mg/m3
5000 mg/m3
TWA: 2 mg/m3
(respirable)
20000 mg/m3
Ethylene glycol monopropyl
ether
TWA: 525 mg/m3
TWA/LMPE-PPT: 10
mg/m3 (as Ti)
STEL/LMPE-CT: 20 mg/m3
(as Ti)
TWA/LMPE-PPT: 10
mg/m3
STEL/LMPE-CT: 20 mg/m3
TWA/LMPE-PPT: 100 ppm
TWA/LMPE-PPT: 523
mg/m3
STEL/LMPE-CT: 200 ppm
STEL/LMPE-CT: 1050
mg/m3
TWA: 25 ppm
TWA: 110 mg/m3
Skin
TWA: 525 mg/m3
Solvent naphtha
(petroleum), medium
aliphatic
Silicon Dioxide
dust)
TWA: 50 ppm
TWA: 6 mg/m3
3000 mg/m3
TWA: 50 ppm
TWA: 245 mg/m3
Skin
900 ppm
(10% LEL)
TWA: 50 ppm
TWA/LMPE-PPT: 50 ppm
TWA/LMPE-PPT: 245
mg/m3
STEL/LMPE-CT: 75 ppm
STEL/LMPE-CT: 365
mg/m3
Use ventilation adequate to keep exposures below recommended exposure limits. In case
of insufficient ventilation, wear suitable respiratory equipment.
Engineering Measures
Personal Protective Equipment
Respiratory Protection
Eye Protection
Skin Protection
General Hygiene Considerations
Use the indicated respiratory protection if the occupational exposure limit is exceeded
and/or in case of product release (dust). Respirator with a vapour filter.
Ensure that eyewash stations and safety showers are close to the workstation location.
Avoid contact with eyes. Safety glasses with side-shields. Goggles. Face-shield.
Wear protective gloves/clothing. Solvent-resistant apron and boots.
Handle in accordance with good industrial hygiene and safety practice. Wash hands before
eating, drinking, or smoking. Remove and wash contaminated clothing before re-use.
Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection.
Regular cleaning of equipment, work area and clothing is recommended.
Appearance
Odor
pH
Boiling point/Boiling Range
Freezing Point/Range
Evaporation Rate
Colored liquid
Characteristic
No information available
>149 °C / >300 °F
Vapour Pressure
Flammability (solid, gas)
Physical State
Odor Threshold
Autoignition Temperature
Melting Point/Range
Solubility
Partition Coefficient
(n-octanol/water)
Vapour Density
Liquid
Heavier than air
Flammability Limits in Air
Upper No information available
Lower No information available
______________________________________________________________________________________________
Page 3 / 7
______________________________________________________________________________________________
Flash Point
Method
29 °C / 85 °F
Pensky Martens Closed Cup (PMCC)
Photochemically Reactive
11.16
Weight Per Gallon (lbs/gal)
VOC by weight % (less water) 41.46
4.63
VOC lbs/gal (less water)
Yes
1.34
Specific Gravity
VOC by volume % (less water) 64.6
VOC grams/liter (less water) 554.96
Chemical Stability
Stable under normal conditions.
Conditions to Avoid
Heat, flames and sparks.
Incompatible Products
Strong acids. Strong bases. Strong oxidizing agents. Reducing agents.
Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapours. Carbon dioxide
(CO2). Carbon monoxide.
Possibility of Hazardous Reactions None under normal processing.
Acute Toxicity
Component
Titanium dioxide
LD50 Oral
>10000 mg/kg ( Rat )
LD50 Dermal
LC50 Inhalation
8400 mg/kg ( Rat )
>2000 mg/kg ( Rabbit )
3400 ppm ( Rat ) 4 h
>5.2 mg/L ( Rat ) 4 h
3089 mg/kg ( Rat )
960 µL/kg ( Rabbit )
1,2,4-Trimethylbenzene
(contaminant)
Solvent naphtha (petroleum),
medium aliphatic
Silicon Dioxide
(contaminant)
3400 mg/kg ( Rat )
18 g/m3 ( Rat ) 4 h
>5000 mg/kg ( Rat )
3000 mg/kg ( Rabbit )
>5.28 mg/L ( Rat ) 4 h
>5000 mg/kg ( Rat )
5000 mg/kg ( Rat )
>2.2 mg/L ( Rat ) 1 h
24 g/m3 ( Rat ) 4 h
1400 mg/kg ( Rat )
39000 mg/m3 ( Rat ) 4 h
Chronic Toxicity
Component
Titanium dioxide
ACGIH
IARC
Group 2B
Group 2B
IARC: (International Agency for Research on Cancer)
OSHA: (Occupational Safety & Health Administration)
Sensitisation
Mutagenic Effects
Reproductive Effects
Developmental hazard
Teratogenicity
Chronic Effects
Target Organ Effects
NTP
OSHA
X
X
Group 2B - Possibly Carcinogenic to Humans
X - Present
Exposure to component solvent vapour concentrations in excess of the stated occupational
exposure limit may result in adverse health effect, such as mucous membrane and
respiratory system irritation and adverse effect on kidney, liver and central nervous system.
Blood, Central nervous system, Eyes, Kidney, Respiratory system, Skin.
______________________________________________________________________________________________
Page 4 / 7
______________________________________________________________________________________________
Ecotoxicity
We have no quantitative data concerning the ecological effects of this product. Should not be released into the environment.
Component
Petroleum naphtha, light
aromatic
(contaminant)
Solvent naphtha (petroleum),
medium aliphatic
Silicon Dioxide
(contaminant)
Algae
96h EC50 Pseudokirchneriella
subcapitata: 450 mg/L
subcapitata: 440 mg/L
subcapitata: 2.6 mg/L
Persistence and Degradability
Bioaccumulation
Mobility in Environmental Media
Fish
96h LC50 Oncorhynchus mykiss:
9.22 mg/L
96h LC50 Pimephales promelas:
7.19 - 8.28 mg/L [flow-through]
800 mg/L [static]
96h LC50 Brachydanio rerio: 5000
mg/L [static]
3.48 mg/L
6.04 - 6.61 mg/L [flow-through]
2.7 mg/L [semi-static]
4.8 mg/L [flow-through]
96h LC50 Poecilia reticulata: 5.1
mg/L [semi-static]
Water Flea
48h EC50 Daphnia magna: 6.14 mg/L
48h EC50 Daphnia magna: >100 mg/L
48h EC50 Ceriodaphnia dubia: 7600
mg/L
24h EC50 Daphnia magna: 50 mg/L
48h EC50 Daphnia magna: 7.9 - 14.1
mg/L [static]
48h EC50 Daphnia magna: 0.6 mg/L
Component
log Pow
3.63
3.55
Waste Disposal Methods
Dispose of contents/container in accordance with local regulation.
Contaminated Packaging
Empty containers should be taken to an approved waste handling site for recycling or
disposal.
DOT
UN1210, Printing Ink, 3, III
ICAO/IATA
IMDG/IMO
International Inventories
Listed on TSCA. For further information, please contact: Manufacturer, importer, supplier
U.S. Federal Regulations
SARA 313
The following components are subject to reporting levels established by SARA Title III, Section 313
Component
CAS-No
Weight %
SARA 313 - Threshold
Values
______________________________________________________________________________________________
Page 5 / 7
______________________________________________________________________________________________
2807-30-9
95-63-6
5 - 10
5 - 10
1.0
1.0
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
Component
CAS-No
2807-30-9
Weight %
5 - 10
U.S. State Regulations
Component
Titanium dioxide
Kaolin
Stoddard solvent
Silicon Dioxide
California Prop. 65
Massachusetts
Right To Know
X
X
X
Not Listed
X
Not Listed
X
X
X
Minnesota
Right To Know
X
X
X
Not Listed
X
Not Listed
X
Not Listed
X
New Jersey
Right To Know
X
X
X
X
X
X
X
Not Listed
X
Pennsylvania
Right To Know
X
X
X
X
X
Not Listed
X
Not Listed
X
WARNING! This product contains a chemical known in the State of California to cause
cancer and / or WARNING! This product contains a chemical known in the State of
California to cause birth defects or other reproductive harm
Component
Titanium dioxide
CAS-No
13463-67-7
98-82-8
Weight %
10 - 30
<1
Canada
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required
by the CPR
Component
Titanium dioxide
Kaolin
Stoddard solvent
Silicon Dioxide
WHMIS Classifications of Components
D2A
D2A
B3,D2B
B3,D2B
B3,D1B,D2B
B3
B3
Uncontrolled product according to WHMIS classification criteria
B3
B2,D2A
Component
Stoddard solvent
NPRI - National Pollutant Release Inventory
Part 5 Substance
Part 5, Other Groups and Mixtures
Part 5 Substance
Part 4 Substance
Part 4 Substance
Part 1, Group 1 Substance
Part 5, Individual Substance
Part 5 Substance
Part 4 Substance
Part 5, Isomer Groups
Part 4 Substance
Part 1, Group 1 Substance
______________________________________________________________________________________________
Page 6 / 7
______________________________________________________________________________________________
Regulation (EC) No. 1907/2006 (REACH), Article 57
This product does not contain substances of very high concern (Regulation (EC) No. 1907/2006 (REACH), Article 57)
HMIS:
Health
Flammability
Reactivity
PPE
2*
3
0
X
Revision Date
Mar-08-2013
Revision Note
New MSDS format
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text
End of MSDS
______________________________________________________________________________________________
Page 7 / 7
MSDS
1 of 3
http://www.nevrdull.com/MSDS.htm
[What is it?] [Where do I get it?] [Who uses it?] [How good is it?]
[Material Safety Data Sheet] [Contact Us] [Home Page]
NEVR-DULL MAGIC WADDING POLISH
May be used to comply with OSHA's Hazard Communication Standard,
29CFR 1910. 1200. Standard must be consulted for specific requirements.
QUICK INDENTIFIER
Common Name: (used on label and list)
TRADE SECRET (Proprietary)
SECTION 1 Manufacturer's
Name
THE GEORGE BASCH CO., INC.
Address
19 HANSE AVE - P.O. BOX 188
Emergency
Telephone No.
516-378-8100
City, State, and ZIP
FREEPORT, N.Y. 11520
Other
Information
Calls
same
Date
Prepared
1-1-2013
Signature of Person
Responsible for Preparation (Optional)
SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY
Hazardous Component(s) (chemical & common name(s))
OSHA
PEL
ACGIII
TLV
Other Exposure
Limits
%
(optional)
CAS
NO.
Mineral Spirits – Petroleum Hydrocarbon
This product is C.A.R.B. , V.O.C. Compliant
SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS
Boiling
Point
Specific
Gravity (H2O =
1)
343 F
Vapor
Density (Air = 1)
0.805 @60
F
Vapor
Pressure (mm
Hg)@20c
0.6
5.8
7/22/13 2:32 PM
MSDS
2 of 3
Solubility
in Water
Stable under normal
conditions
Appearance
and Odor
cotton wadding
Impregnated with liquid
chemical
Reactivity in
Water
None
Melting
Point
NA
SECTION 4 - FIRE & EXPLOSION DATA
Flash
Point
145 F.
63 C.
Method
Used
Open cup
Auto-Ignition
Temperature
490 F
Extinguisher
Media
Fire Extinguisher- type-Monoamnonium Phosphate
(class ABC - Dry Chemical)
Flammable Limits
in Air % by Volume
Special Fire
Fighting Procedures
Keep away from open flame-
Unusual Fire and
Explosion Hazards
None
LEL
Lower
0.9
UEL
Upper
NA
SECTION 5 - PHYSICAL HAZARDS (REACTIVITY DATA)
Stability
Unstable [ ]
Stable [x]
Conditions
to Avoid
Incompatibility
(Materials to Avoid)
Isolate from strong oxidizers such as permanganates,
chromates & peroxides
Hazardous
Decomposition Products
Carbon monoxide, Carbon Dioxide from burning
Hazardous
Polymerization
Will Not Occur
Isolate from strong oxidizers,
heat and open flame
SECTION 6 - HEALTH HAZARDS
Eye Contact Slightly irritating but does not injure eye tissue
Skin Contact Low order of toxicity. Skin contact may irritate or cause an existing dermatitis condition
Inhalation
Low vapor concentrations may cause dizziness, headaches, drowsiness
Ingestion
May cause local irritation, vomiting, respiratory irritation, headache, dizziness, nausea
SECTION 7 – First Aid Measures
Eye Contact
Flush eyes with large amounts of water until irritation subsides
Skin Contact
Recommend rubber gloves to use. Wash hands with soap and water
Inhalation
Remove to fresh air. Give artificial respiration if necessary
7/22/13 2:32 PM
MSDS
3 of 3
If swallowed DO NOT induce vomiting. Seek medical attention
Ingestion
SECTION 8 – PRECAUTIONS FOR SAFE HANDLING AND USE
Precautions to be Taken in
Store at room temperature. Keep away from open flames
SECTION 9 – STABILITY AND REACTIVITY
Stability
Stable
Conditions to Avoid
Instability
N/A
Hazardous
Polymerization
Will Not Occur
Conditions to Avoid
Hazardous
Polymerization
N/A
Materials &
Conditions to avoid
Incompatibility
Oxidizers
Hazardous
Decomposition
Products
None
SECTION 10 – HAZARD RATING SYSTEM
NPCA-HMIS
Nat’l Paint & Coating Assoc./ Hazardous indent. Systems
HEALTH
FLAMMABILITY
REACTIVITY
1
2
0
NFPA 704
National Fire Protection Association
0
2
0
KEY
4 = Severe
3 = Serious
2 = Moderate
1 = Slight
0 = Minimal
7/22/13 2:32 PM
MSDS
1 of 3
NEVR-DULL MAGIC WADDING POLISH
May be used to comply with OSHA's Hazard Communication Standard,
29CFR 1910. 1200. Standard must be consulted for specific requirements.
QUICK INDENTIFIER
Common Name: (used on label and list)
TRADE SECRET (Proprietary)
SECTION 1 Manufacturer's
Name
THE GEORGE BASCH CO., INC.
Address
19 HANSE AVE - P.O. BOX 188
Emergency
Telephone No.
516-378-8100
City, State, and ZIP
FREEPORT, N.Y. 11520
Other
Information
Calls
same
Date
Prepared
1-1-2013
Signature of Person
Responsible for Preparation (Optional)
SECTION 2 - HAZARDOUS INGREDIENTS/IDENTITY
Hazardous Component(s) (chemical & common name(s))
OSHA
PEL
ACGIII
TLV
Other Exposure
Limits
%
(optional)
CAS
NO.
Mineral Spirits – Petroleum Hydrocarbon
This product is C.A.R.B. , V.O.C. Compliant
SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS
Boiling
Point
Specific
Gravity (H2O =
1)
343 F
Vapor
Density (Air = 1)
0.805 @60
F
Vapor
Pressure (mm
Hg)@20c
0.6
5.8
7/16/13 5:42 PM
MSDS
2 of 3
Solubility
in Water
Stable under normal
conditions
Appearance
and Odor
cotton wadding
Impregnated with liquid
chemical
Reactivity in
Water
None
Melting
Point
NA
SECTION 4 - FIRE & EXPLOSION DATA
Flash
Point
145 F.
63 C.
Method
Used
Open cup
Auto-Ignition
Temperature
490 F
Extinguisher
Media
Fire Extinguisher- type-Monoamnonium Phosphate
(class ABC - Dry Chemical)
Flammable Limits
in Air % by Volume
Special Fire
Fighting Procedures
Keep away from open flame-
Unusual Fire and
Explosion Hazards
None
LEL
Lower
0.9
UEL
Upper
NA
SECTION 5 - PHYSICAL HAZARDS (REACTIVITY DATA)
Stability
Unstable [ ]
Stable [x]
Conditions
to Avoid
Incompatibility
(Materials to Avoid)
Isolate from strong oxidizers such as permanganates,
chromates & peroxides
Hazardous
Decomposition Products
Carbon monoxide, Carbon Dioxide from burning
Hazardous
Polymerization
Will Not Occur
Isolate from strong oxidizers,
heat and open flame
SECTION 6 - HEALTH HAZARDS
Eye Contact Slightly irritating but does not injure eye tissue
Skin Contact Low order of toxicity. Skin contact may irritate or cause an existing dermatitis condition
Inhalation
Low vapor concentrations may cause dizziness, headaches, drowsiness
Ingestion
May cause local irritation, vomiting, respiratory irritation, headache, dizziness, nausea
SECTION 7 – First Aid Measures
Eye Contact
Flush eyes with large amounts of water until irritation subsides
Skin Contact
Recommend rubber gloves to use. Wash hands with soap and water
Inhalation
Remove to fresh air. Give artificial respiration if necessary
7/16/13 5:42 PM
MSDS
3 of 3
If swallowed DO NOT induce vomiting. Seek medical attention
Ingestion
SECTION 8 – PRECAUTIONS FOR SAFE HANDLING AND USE
Precautions to be Taken in
Store at room temperature. Keep away from open flames
SECTION 9 – STABILITY AND REACTIVITY
Stability
Stable
Conditions to Avoid
Instability
N/A
Hazardous
Polymerization
Will Not Occur
Conditions to Avoid
Hazardous
Polymerization
N/A
Materials &
Conditions to avoid
Incompatibility
Oxidizers
Hazardous
Decomposition
Products
None
SECTION 10 – HAZARD RATING SYSTEM
NPCA-HMIS
Nat’l Paint & Coating Assoc./ Hazardous indent. Systems
HEALTH
FLAMMABILITY
REACTIVITY
1
2
0
NFPA 704
National Fire Protection Association
0
2
0
KEY
4 = Severe
3 = Serious
2 = Moderate
1 = Slight
0 = Minimal
7/16/13 5:42 PM
140-0597
12 00
DATE OF PREPARATION
Jul 23, 2013
PRODUCT NUMBER
140-0597
PRODUCT NAME
SUPERACRYLIC® Controls Rust Spray Enamel, Wr. Iron Flat White
MANUFACTURER'S NAME
Cleveland, OH 44115
(216) 566-2902
www.paintdocs.com
accident)
% by Weight
14
13
18
29
2
7
7
CAS Number
74-98-6
106-97-8
108-88-3
67-64-1
763-69-9
14807-96-6
13463-67-7
Ingredient
Units
Propane
ACGIH TLV
1000
OSHA PEL
1000
Butane
ACGIH TLV
1000
OSHA PEL
800
Toluene
ACGIH TLV
20
OSHA PEL
100
OSHA PEL
150
Acetone
ACGIH TLV
500
ACGIH TLV
750
OSHA PEL
1000
ACGIH TLV
OSHA PEL
Talc
ACGIH TLV
2
OSHA PEL
2
Titanium Dioxide
ACGIH TLV
10
OSHA PEL
10
OSHA PEL
5
Vapor Pressure
PPM
PPM
760 mm
PPM
PPM
760 mm
PPM
ppm (Skin)
ppm (Skin) STEL
22 mm
PPM
PPM STEL
PPM
180 mm
Not Available
Not Available
1.11 mm
mg/m3 as Resp. Dust
mg/m3 as Resp. Dust
mg/m3 as Dust
mg/m3 Total Dust
ROUTES OF EXPOSURE
EYES: Irritation.
HMIS Codes
Health 2*
Flammability 3
Reactivity 0
page 1 of 4
140-0597
the liver
the urinary system
CANCER INFORMATION
EYES:
SKIN:
INHALATION:
INGESTION:
FLASH POINT
LEL
UEL
EXTINGUISHING MEDIA
Propellant < 0 °F
1.0
12.8
STORAGE CATEGORY
Not Available
VENTILATION
page 2 of 4
140-0597
PROTECTIVE GLOVES
EYE PROTECTION
OTHER PRECAUTIONS
6.70 lb/gal
803 g/l
0.81
<0 - 342 °F
<-18 - 172 °C
Not Available
90%
Faster than
ether
pH 7.0
PRODUCT WEIGHT
SPECIFIC GRAVITY
BOILING POINT
MELTING POINT
VOLATILE VOLUME
EVAPORATION RATE
CONDITIONS TO AVOID
None known.
INCOMPATIBILITY
None known.
Will not occur
as paint."
TOXICOLOGY DATA
CAS No.
Ingredient Name
74-98-6
Propane
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
106-97-8
Butane
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
108-88-3
Toluene
LC50 RAT
4HR
4000 ppm
LD50 RAT
5000 mg/kg
67-64-1
Acetone
LC50 RAT
4HR
Not Available
LD50 RAT
5800 mg/kg
763-69-9
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
14807-96-6
Talc
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
13463-67-7
Titanium Dioxide
LC50 RAT
4HR
Not Available
LD50 RAT
Not Available
page 3 of 4
140-0597
No data available.
US Ground (DOT)
Canada (TDG)
IMO
IATA/ICAO
CAS No.
CHEMICAL/COMPOUND
% by WT
% Element
108-88-3
Toluene
18
TSCA CERTIFICATION
page 4 of 4

Material Safety Data Sheet

Transcription

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