VihtaVuori

Vihta Vuori
VihtaVuori Ni00 & N300 Series
MATERIALSAFETYDATASHEET
April 2009
The following Ni00, N300, 2N and 3N series powders are manufactured by VihtaVuori
and distributed by Hodgdon Powder Company.
20N29
3N37
3N38
Ni0S
Nll0N133-
~
N135
-
N140
-
N150
-
N160 "-
N165N310
-
N320 N340 '
N350-
6231 Robinson Street'
Shawnee Mission, KS 66202 * Phone (913) 362-9455 . Fax (913-362-1307
www.Hodgdon.com
* www.lMRpowder.com
~ www.WWpowder.com
@
Fonner date: 26.4.2007
Date: 17.11.2008
Trade name
N-Powder
Code of the preparation
Ni00-, N300-,2N-,3N-series, N32C, 20N29 and
24N41, B7T-and B19T-propellants
The intended uses of the chemical
Propel!ant for ammunition.
24610
1.2.2
1.2.3
Standard industrial classification (SIC)
Use categories (UC62)
TOli: 296 KT1:36
1.2.4
The chemical can be used by the general public
1.2.5
The chemical is used by the general public only
0
0
1.3.2
Contact infonnation:
Street address
EURENCOVihtavuoli Oy
Ruutitehtaantie 80
FI- 41330 Vihtavuori
Postcode and post office
Post-office box
Postcode and post office
Telephone number
Telefax
Y code
+358-14-3779211
+358-14-3771 460
FI14922233
Ta!ephone number +358-14-3779211
Te!efax +358-14-3771643
EURENCOVihtavuoriOy, FI-41330 V!HTAVUORI
FINLAND
ler
code
ingredient
.1 CASnumber
or 2.1.2Nameof
the
603-037-00-6 !nd
!Nitrocellulose
!
122-39-4
IDiphenylamine
!
!
!
-98-3
Diethyidiphenylurea
,centraiit~.J.L._...._..._._.-
2.1.3
Concentration
90-99%
max. 2.0 %
max. 6.0 %
2.1.4
E; R3;R1
T; R23/24/25; R33;N; R50-53
EY -nro: 204-539-4
HTP 8 h= 5 mgfm3 (skin),
HTP 15min= 10 mglm~ (skin),
LD50=300 mg/kg (oral
Xn; R22-52/53.
LD50=420 !J:)J
2.1.5
There
2.1.6
2.1.7
according to Annex 3 of the decree
A substance not dangerous has been indicated as confidential
Other information
......-...-..........--.--.
has been a request for confidentialityof a substance
.-.---...--..-..-
.....--...-..-..-.
Warning symbol, R phrases and
other data on the ingredient
0
0
---...-----.
Page 1
Trade
name: N-POWDER
Date: 17.11.2008
Former date: 26.4.2007
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,,,,..,,-","-",,,,,,,,.,,,,,,,,,.,,,,,,"
Risk of explosion
,",._",,,,,,,,,,,,,,,,..,,,
".",
shock, friction,fire or other sources of ignition. Harmful
""",,,,,,,.,,,,,,.,,,,,,.,,,,,,-,,-~
if
swallowed. Danger of cumulative effects. Harmful to aquatic organisms, may cause longterm adverse effects in the aouatic environment.
4.1
Special instructions
4.2
Inhalation
4.3
4.4
Move patients to fresh air.
Heating can release hazardous gases, nitrogen oxides (NOx). In case of fire and/or
explosion do not breathe fumes. Remove from exposure, lie down. Oxygen or artificial
respiration if needed. Seek medical advice.
Skin contact
contact
Avoid skin contact Wash off Immediately with soap and plenty of water.
Rinse thoroughly with plenty of water, also under the eyelids,
4.5
Ingestion
4.5
information to doctor or other trained pemons giving fimt aid
Induce repeated vomiting. (only if the victim is conscious)
Exposuring to
5.1
oxides (NO,) may cause symptoms of poisoning after several
Suitable extinguishing media
Recommended extinguil1hingmedia, water. Also other endothermic extinguishing media
are posslb!e.
0.2
Extinguishing media which must not be used for safety reasons
5.3
Speciai exposure hazards in a TIre
In case of fire and/or explosion do not breathe fumes which may contains nitrogen
oxides (NOxl. Evacuate
to safe areas.
for
and protective suit.
Wear self..contained breathing
5.4
5.5
Other instructions
Can only be extinguished by effective cooling. Bums without auxiliary oxygen. Very fast,
deflagration like
may turn to explosion. At risk of fire peopk?shali evacuated to
a safe distance.
6.1
ft2
Pemonai precautions
in casesomeof the powderhasrunout of the package:Removeall sourcesof ignition
Usenon-sparkyequipment,seekprofessionaladvice.
Environmentaiprecautions
6.4
Risk of explosion.
up
in case some of the powder has run out of the package .use non-sparky equipment,
seek
advice.
Other instructions
1.1
Handling
6.3
Methods for
Keep out of children. Keep away from heat and sources of ignition. Handle and open
containers with care. Do not smoke. Take precautionary measures against static
discharges. Ensure adequate ventilation. Wear suitable protective clothing and gloves.
Avoid exposuring to the product and read the instructions before use.
1.2
7.3
Specific
Store in original containers. Keep in a
Incompatible with acids and bases.
uss(s)
cool place.
Trade name: N-POWDER
Date: 17.11.2008
Former date: 26.4.2007
",..>m ~",,,,.>m>m,,'-~,,'~>m
",.",
""-"'
>m~
8:1.1
HT? values
iL1.2
Organic dust 5 mg/m2
Other limit values
8.1.3
Limit values in other countries
8.2.1
Occupational exposure controls
~.......
10 mg/m2(15min)
Ensure adequate ventilation.Wear personal protective equipment
8.2.1.1
Respiratory
dust or continious skin
protection
>m-'''''-..................................
contact.
in risk of inhalation of
Wear half mask witha partide filter P2 (European Norm EN 143 ::: former DIN3181) in
3.2.1.2
risk of dust
Hand protection
8.2.1.3
Eye protection
8.2.1.4
Skin
8.2.2
Protective clothing. recommended antistatic and non-flammable material.
Environmental exposure controls
Wear suitable protective gloves in risk of direct skin contact
Wear protective
9.2.2
poinilbomng range
9.2.3
Flash
9.2.4
flammability (solid, gas
min 165°C
Extreme risk of i
9.2.5.1
Lowerexplosive limit
-
9.2.EL2 Upper
limit
9.2.6
Oxidising
9.2.1
Vapour pressure
9.2.8
Relativedensity
1
9.2.9.1
Water solubility
Insofuble
9.2.!:L2
Fat solubmty (solvent-oil to be
9.2.10
Partition coefficient n..octanolfwater
9.2.11
-
Organic dissolvents:
esters (e.g. acetonitrile)
-Trade name; N-PQWDER
Former date: 26.4.2007
Date; 17.11.2008
~"""-"'"""""'
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""",,,,,_,,,,,m,. mm.m..""~,,,,''''''''~-"_'_--"''""''"''''-'''
9,2,12
density
\3.2,13
Evaporation rate
9.3
Other information
Ex
'!G.'!
Conditions to avoid
Stable at norma! conditions, long -time heat exposure decreases stability.
Materials to avoid
Incompatiblewithacids and bases, Degradation can cause explosion.
Hazardous decomposition proch.Jcts
Nitrogen oxides
10.2
10.3
11.2
No data avai!able,
Irritation and corrosiveness
11.3
Sem.itisation
11,4
Sub-acute, sub-chmnic and prolonged
May cause skin and eye irritation.
No data available.
No data avaiiable.
11.5
data on effects on humans
May cause skin irritation.
cause irritation of the mucous membranes,
11J)
Other inforrnaticm on health effects
12.1.1
Aquatic toxicity
2.1.2
12.2
Harmful to aquatic organisms, may cause !ongmtermadverse effects in the aquatic
environment
Toxicity to omer organisms
No data available.
Mobility
12.3.1
Biodegradation
12.3.2
Chemical degradation
No data available.
Incompatib!e with acids and bases:may cause degradation.
decreases stability.
12.4
Bioaccumulativepotential
12.5
Other adverse effects
Dlsposa! of unused products, waste and contaminated
accordance with local and national regulations.
14.1
UN number
14.2
Packing group
Long -time
packages must
heat exposure
be done
in
0161
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.-.,,
m._._Page 4
Trade name: N-POWDER
Former date: 26.4.2007
Date: 17.11.2008
_''''''"""m"""
""""..""m__''W__~''m"""."",,.m''''''_._m''''""''''-'''''''''''--''.''''_''~'m_''''
code
""
ADR 1.3C
Packing instructions:
14.3.2
Risk
14.3.3
Name
14.3.4
Other information
"m""""""-"'''''''''''-'''''--'.'''.'''''''''''''...,.".""""."..---
P114 (b), special packing provisions PP50 andPP52
according to bm of freight
Powder, smokeless
14.4.1
14.4.2
14.4.3
14.5.1
1.3C
Packing instructions:
Correct technical name
Powder, smokeless
Other information
P 114(b), special packing provisions PP50 and PP52
14.5.2
ICAOIIATA class
FORBIDDEN
Correct technical name
14.5.3
Other information
15.1.1
Letter code of the warning symbol and indications of danger for the preparation
E
- Explosive
Xn
-
Harmful
15.1.2
Names of the ingredients given on the warning label
Nitroce!lulose, Diphenylamine, Diethyldiphenylurea
15.1.3
R phrases
R2 Risk of explosion by shock, friction, fire or other sources of ignition.
R22 Harmful if swallowed.
R33 Danger of cumulative effects.
R52153 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
15.1.4
S phrases
81/2 Keep locked-up and out of reach of children.
835 This material and its container must be disposed of in a safe way.
15.1.5
Special regulations on certain preparations
15.2
Nationalregulations
16.1
List of the relevant R phrases
R1 Explosive when dry.
R3 Extremerisk of explosion by shock, friction,fire or other sources of ignition.
R22 Harmful if swallowed.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R33 Danger of cumulative effects.
R50 Very
toxic to aquatic organisms.
R52153 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquaticenvironment
R53 May cause long-term adverse effects in the aquatic environment.
Trade name: N-POWOER
Date; 17.11.2008
""mm"."."m,
~m'~"m"'m.""....
Former date: 26.4.2007
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,
16.2
Training advice
16,3
Restrictions on use
16A
Further information
16.5
16.6
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The information provided in this Safety Data Sheet is correct to the best of our
knowledge at the date of its publication, The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification, since the conditions of the
operations mentioned are beyond our control, The information relates only to the specific
materia! designated and may not be valid for such materia! used in combination with any
other materials or in any process unless specified in the text EURENCO Vihtavuori Oy
discJaims any liability for loss or damage resulting from the use of these data,
information or suggestions,
Sources of key dam 1.I$8d
information
which has been added, deleted or revised
1.1.
87T- and 8 19T-propeHantsadded
2.1.3. NitroceHulose concentration 80-98 % revised-> 90-99%