hammonds fuel additives, inc. - Technology Lubricants Corporation
Transcription
hammonds fuel additives, inc. - Technology Lubricants Corporation
HAMMONDS FUEL ADDITIVES, INC. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. “BUGS IN MY FUEL” Answers to the Most Frequently Asked Questions on Microbial Growth in Fuel What are microorganisms, or bugs? The scientific names for the types of organisms that live in petroleum products are Cladosporium Resinae and Pseudomonas Aeruqinosa. The organisms are either air or water borne and contaminate fuel systems be entering through vents, standing water in sump bottoms, dissolved “free water” or trash incurred during transport or delivery. They grow at incredible rates with some varieties having the ability to double in size every 20 minutes. What do these bugs do? These slimy bugs live and multiply in the fuel / water interface. They actually exist in the water and feed off the hydrocarbons in the fuel. They are referred to as Hydrocarbon Utilizing Microorganisms, commonly known as HUM-Bugs. As they grow, they form mats that are dark in color and appear gel-like. Their waste produces water, sludge, acids and other harmful by-products. Microorganisms will also consume rubber gaskets, o-rings, hoses or tank linings and coatings for their mineral contents. How do I know I have bugs? The signs of microbial growth can vary. Some of the obvious signs are clogged filters, loss of engine power due to fuel starvation because of plugged lines, contamination on tank bottoms, fuel with a sulfur smell and tank access lids with green or brown slimy formations. A more definite appraisal may be made with the use of a microbe detector kit. An easy-to-use test kit is the HUM-Bug Detector® Kit available through Hammonds Fuel Additives, Inc. Why do I need to control microbes in fuel systems? A sterile fuel system is one with lower maintenance costs. That translates to reduce equipment disruptions, or downtime due to fuel system complications. The elimination of bugs in both storage and equipment tanks will also produce the chances of leaking tanks due to corrosion from microorganisms’ acid waste products. Isn’t good fuel management and proper “housekeeping” enough to avoid problems? Keeping petroleum products dry and clean is essential to any well-maintained storage operation. The monitoring of water bottoms and removal of trash and particulate matter is very important. However, the highest standards of housekeeping will not ensure the absence of microbial infestations and associated problems. Microbial spores can exist in a dormant stage for extended periods of time, waiting for trace amounts of water or improved growing conditions. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. What should I do if I find I have a bug problem? Blend BIOBOR® JF into your fuel tank at the recommended 270 PPM by weight. Allow the tanks to be uninterrupted for at least 24 hours. Depending on the severity of the infestation, results may be seen in as little as 16 hours but can require as much as 72 hours in order to provide a complete kill. Place tank back in operation and monitor filters for residual build up. Once BIOBOR® JF has done its job of exterminating the infestation, the remains might appear as coffee grains in the bottom of the tank. Once I have a sterile tank and fuel system, how can I prevent these problems from happening again? The use of BIOBOR® JF at a rate of 135 PPM is a preventative measure and will deter any future infestations. BIOBOR® JF Fuel Additive will correct and prevent microorganism contamination in petroleum products. Periodic fuel testing with the Hum-bug Detector® Kit will also verify the effectiveness of the BIOBOR® JF additive. Aren’t there other products on the market that can cure the problem and do other things in addition? Yes, there are other products on the market, some that have a list of problems that they propose to cure. However, when a product is formulated, it can have many different ingredients designed to do many different things. When this is done, it is difficult to get enough of any one ingredient to perform any job well. BIOBOR® JF is specifically designed to do one job, and do it very effectively without being harmful to the user, the fuel or the environment. Why is Biobor® JF so effective? As you may have noted from the can label, BIOBOR® JF is registered with the EPA as a pesticide. Any additive which has the proper amount of the effective ingredients with dosages strong enough to truly “kill” or eliminate a growing organism, must have its contents and label approved and registered by the EPA. How can I find out more about Biobor® JF? Call or write Hammonds Fuel Additives, Inc. at: HAMMONDS FUEL ADDITIVES, INC. 15760 WEST HARDY ROAD, SUITE 400 HOUSTON TEXAS 77060-3147 PHONE: 281 820 5674 OR TOLL FREE 800 548 9166 FAX: 281-847 5129 We will be glad to send you additional technical data, or have our Marketing Technical Services Department visit with you to discuss your particular problem and solution. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. GENERAL INSTRUCTIONS FOR THE USE OF BIOBOR® JF BIOBOR® JF is best used with a fuel management plan. Included in this regular maintenance schedule should be daily inspection routines. The plan for BIOBOR® JF use includes correct dosage, frequency and method of applications. Maintenance includes the care of the fuel and the fuel system. Of prime importance is the frequent and regular removal of water from both the storage tank and vehicles. Check tanks for uneven bottoms which cannot be drained. Inspect fuel for quality. Check storage tanks, fuel systems and vehicle’s operational tanks for microbes. Early detection prevents damage, and allows for easier treatment with BIOBOR® JF. Proper fuel management is necessary to control microbial growth, but as with the use of preservatives to prevent food spoilage, some other insurance is needed. BIOBOR® JF is that insurance. BIOBOR® JF is a powerful, safe, and effective biocide for fuel. When used correctly, it will bring a fuel system to sterility and keep it that way. The necessary information and steps are outlined below. 1. 2. 3. 4. Correct dosage. Careful addition injection to the system. Suitable contact time. Frequency of use. There are two (2) levels of addition; a shock dose for contaminated or at risk systems, and the maintenance dose for clean, less risky systems. The meaning of a contaminated system is obvious. Microorganisms have been identified or contamination is highly suspected because one or more of the following exist: 1. Slime has been found on the filters. 2. Slime has been found on the surfaces. 3. A problem has developed with fuel lines plugging. Once one of these preliminary symptoms is noticed, a fuel sample should be taken and tested. One of the industry wide, recognized tests for the existence of harmful Hydrocarbon Utilizing Microorganisms is the HUM-Bug Detector® Kit, also available through Hammonds Fuel Additives, Inc., Houston, Texas. A system is at risk if one or more of the following conditions exist: 1. The fuel will be stored or the vehicle is not in constant use. 2. Fuel quality is suspect. (Some fuels are heavily contaminated due to improper handling). 3. The vehicle operates in warm, humid areas. 4. Past history of the vehicle or sip indicates a continuing potential for problems. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. 5. Condensation with side variations in day / night temperature, spring and fall may be higher risk times. Systems can be a lower risk under the following conditions; 1. Fuel is bought with good quality assurance and is maintained carefully with frequent inspections. 2. Vehicles are used frequently (this only lowers the risk slightly). 3. Tanks are sumped frequently and regularly, and / or have water removal systems. 4. Past history indicates problems of contamination are rare. 5. Winter will slow the growth rate (most microorganisms slow their growth rate in the cold). Note: Microorganisms are not killed by cold, only put into a dormant state. Assessing risk is a judgment matter. Manufactures have to be taken into account, and are necessarily different for each case. The highest dosage level of BIOBOR® JF ever recommended is 270 parts per million (PPM). This level is approximately equal to one gallon of BIOBOR® JF for 5,000 gallons of fuel. The 135 PPM dose may not be strong enough to clean a contaminated system. There are two (2) factors of consideration when using BIOBOR® JF. 1. BIOBOR® JF must reach all areas of a system to be effective. 2. The fuel / water BIOBOR® JF system is a complex one, and BIOBOR® JF needs to be distributed evenly throughout. The most reliable way to get BIOBOR® JF into the fuel is by metered injection. With proper metered injection, BIOBOR® JF is blended instantly to the correct dose so there are no areas in the tank that get high of low levels, and the problem of solids formation is avoided. (The subject of solids formation is discussed at length in the Hammonds’ Service Bulletin 980 and Service Bulletin 982). There are several manufactures of metering systems who can be consulted on the details of the equipment available. Hammonds Technical Services, Inc. in Houston, Texas, manufactures fluid injector systems which are compatible with this product and are operated independently of any other equipment. If the use of an injection system is not possible, there are other options. A batch may be made to predilute the BIOBOR® JF. The batch should not exceed 1,000 PPM, so something as large as a tank truck may be needed to perform batch blending. Some operators have been making a much more concentrated blend, several ounces of BIOBOR® JF in two or five gallons of fuel. This method is definitely not recommended! Fuel will ordinarily contain enough water to react with the highly concentrated BIOBOR® JF. This may appear as haze, precipitate, or through the formation of separate liquid layers. Limiting the blend to 1,000 PPM avoids the problem of precipitate and loss of BIOBOR® JF activity. A second method is direct addition to the top of the tank. If this method is used, check to see if there is fuel under the access hold. BIOBOR® JF should never be poured into an empty tank or into a thin layer of fuel. If possible, dribble it in the tank which is being filled. If pouring in from the top, make sure there is at least half a tank full and add while fuel is flowing in. This will blend and dilute it to get the desired results. Treating the storage tank instead of the vehicle is the most efficient way to batch-blend BIOBOR® JF. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. Everything in the system (pipes, trucks, filters and meters) will be kept free of contamination. Also, if a mistake in under-dosage is made, it can be corrected before the fuel reaches the vehicle or ship. BIOBOR® JF is a metabolic poison for microorganisms. That is, it has its effect on the metabolism and / or multiplication of the individual cells. Before is can kill them, it has to cross the exterior walls and membranes of each cell. This takes a few hours. A few more hours are needed for the metabolic activity. Therefore, a certain contact time is needed for a complete kill. Depending on the severity of the infestation, results may be seen in as little as 16 hours but can require as much as 72 hours in order to provide a complete kill. This is of no matter for storages tanks that are idle, but it becomes a problem for vehicles in active use. In order to reach the desired contact time, many possibilities have to be considered, and a careful plan worked out. Factors in the plan include: 1. Treating after the last use of the day, so that evening hours are available for contact. 2. Treating during scheduled maintenance, when the vehicle is idle for a day or two. 3. Treating at two or more successive stops on the schedule to ensure the necessary time. Frequency of treatment is perhaps the most difficult aspect of BIOBOR® JF treatment. Many operators use BIOBOR® JF more or less continually, but this option is not open to all users. The system has to be treated often enough to keep microorganisms in check. The goal is to never allow microorganisms to grow long enough to cause any damage. Determining how often this is, is based on may factors: 1. 2. 3. 4. 5. 6. The limit of risk for the system. Historical incidence of contamination. Level of maintenance. Source of fuel. Weather in the operating area. Use pattern of the vehicle or ship. Again, this is a judgment situation. Frequency may become individualized to a system, location, or even to a single tank on any individual piece of equipment. A new schedule may at first be arbitrary. Experience will show whether or not the treatments are frequent enough. Should inspection show signs of growth contamination, then the system must be treated more often. A tank going into storage should be treated. No second treatment will be needed until the fuel is burned off or drained. Service Bulletin No. 982, for aircraft use, and No. 980 for general use, should be consulted before using BIOBOR® JF. Material Safety Data Sheets are also available. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. BIOBOR JF microbicide ® TECHNICAL DATA SHEET-TD-9610 BIOBOR® JF is a liquid fuel additive that combats fungus and other microbial life in hydrocarbon fuels such as diesel and jet fuels. BIOBOR® JF eliminates growth of harmful slime producing fungi that clog filters and pipelines, attack rubber fuel systems components and whose waste products aid in the corrosion of metal surfaces. BIOBOR® JF is simple to use and harmless to the wide variety of fuel system parts, top coatings, sealants and elastomeric materials tested. It does not adversely affect fuel performance in any way. BIOBOR® JF is an effective microbicide because of its equilibrium solubility in both fuel and water under conditions of fuel storage. BIOBOR® JF is used by a large number of aircraft operators, airlines, ships boats, trucking fleets, railroads, bulk storage terminals, fuel suppliers and by other users of hydrocarbon fuels exposed to the possibility of contamination by fungus and bacteria. GENERAL USAGE If a system is badly contaminated, drain water bottoms thoroughly. Water bottoms in storage tanks should be kept to a minimum. Good housekeeping is important in treating slime problems, but it is not a cure. BIOBOR® JF is used at 270* PPM in fuel to effect sterilization, and subsequently at 135* PPM to maintain fungus-free fuel. Ideally, BIOBOR® JF should be injected to ensure proportionality and even distribution throughout the fuel tank. However, in the absence of metering equipment, BIOBOR® JF may be manually batch-blended. If batch-blending, as in tank trucks or small aircraft wing tanks, BIOBOR® JF should be introduced while the tank is being filled, after the tank is approximately ½ full. This will ensure faster and more complete dispersion. *See Chart on Reverse. PRODUCT DATA Chemical Composition Active Ingredients 2,2’-oxybis (4,4,6-trimethyl-1, 3,2- dioxaborinane) 2,2-(1-methyltrimethylenedioxy) bis-(4-methyl-1, 3,2-dioxaborinane) Inert Ingredients Petroleum Naphtha Inerts 95.0% 4.5% 0.5% 100.0% 7.3% Total Boron Content Physical Properties (typical) Flash Point, Tag Closed Cup 104 + 2° F. Pour Point -27° F. Appearance Clear Liquid Instructions for Storage and Handling All BIOBOR® JF container must be kept closed from the atmosphere. Protect BIOBOR® JF from any water contamination. The solvent action of BIOBOR® JF will attack coatings on paper linings of caps and lids, therefore, polyethylene liners or closures are recommended for storage of BIOBOR® JF. EPA REG. NO. 65217-1 EPA EST. 61897-TX-0001 CANADIAN P.C. P REG. NO. 10301 CAS NO. 8063-89-6 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 TECHNICAL DATA SHEET CONTINUED HAMMONDS FUEL ADDITIVES, INC. BIOBOR JF ® microbicide BIOBOR® JF ADDITIONS FOR LARGE JET FUEL TANKS JET FUEL Lbs. Gals. 670 100 1,340 200 2,010 300 2,680 400 3,350 500 6,700 1,000 13,400 2,000 16,750 2,500 33,500 5,000 67,000 10,000 134,000 20,000 335,000 50,000 SHOCK TREATMENT @ 270 PPM Gals. Fl. Ozs. 0.02 2.63 0.04 5.26 0.06 7.89 0.08 10.53 0.10 13.16 0.21 26.46 0.41 52.92 0.52 66.08 1.03 132.16 2.07 264.47 4.14 528.94 10.35 1,322.35 MAINTENANCE LEVEL @ 135 PPM Gals. Fl. Ozs. 0.01 1.32 0.02 2.63 0.03 3.95 0.04 5.26 0.05 6.58 0.10 13.16 0.21 26.46 0.26 33.04 0.52 66.08 1.03 132.31 2.06 264.62 5.15 661.55 To determine the fluid ounces of BIOBOR® JF required to give a concentration of 270 PPM, multiply pounds of fuel by 0.004 and for 135 PPM by 0.002 Density of Jet Fuel: 1 gallon weighs 6.714 pounds. BIOBOR® JF METRIC CONVERSIONS FOR VARIOUS FUELS SHOCK TREATMENT AT 270 PPM Oz. of ml of Fuel Density at BIOBOR® JF BIOBOR® JF 15° C / 59° F per 1000 per 1000 FUEL g / ml lbs / gal kg / L gal. fuel liters fuel JP-4 0.7601 6.343 .762 25.37 198.27 Kerosene (Turbine Fuel) 0.8045 6.714 .806 26.86 209.57 Diesel #1 0.8180 6.827 .820 27.31 214.50 Diesel #2 0.8484 7.080 .850 28.32 220.99 Bunker “C” 0.9952 8.305 .997 33.22 259.26 To determine the fluid ounces of BIOBOR® JF required to give a concentration of 270 PPM, multiply pounds of fuel by 0.004 and for 135 PPM by 0.002 To determine milliliters of BIOBOR® JF required to give a concentration of 270 PPM, multiply kilograms of fuel by .26 and for 135 PPM by .13 BIOBOR® JF is manufactured and sold for prevention and elimination of microbial growth in all hydrocarbon fuels such as aviation jet fuels, kerosene, no.1 and no.2 diesel fuels, home heating oil, marine diesel and bunker “C” fuel. HAMMONDS FUEL ADDITIVE, INC. 15760 West Hardy Road, Suite 400 Houston, Texas 77060-3147 281/820-5674 Fax: 281/847-5129 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 800-548-9166 ©1996 All Rights Reserved BIOBOR JF Service Bulletin ® HAMMONDS FUEL ADDITIVES, INC. BIOBOR® JF AVIATION FUEL ADDITIVE No. 982 I. INTRODUCTION The following discussion and tables are presented on the subject of fungal growth in aircraft fuel systems and how to eliminate it with the help of BIOBOR® JF. It is simple to use and compatible with a wide variety of fuel system parts and top coatings, sealants and elastomeric materials. It does not adversely affect fuel performance. Chemical and physical properties are listed in Table I, blending data in Tables II, III and IV, and compatibility fuel system components in Table V. Due to the critical nature of fuel supply to an aircraft engine, it is important that this information be carefully read, particularly the section on blending, before attempting to use BIOBOR® JF. This product is a special formulation of glycol borates designed for maximum biocidal effectiveness in hydrocarbon fuels and oils. In addition BIOBOR® JF is authorized by the FAA and recommended by both airframe manufacturers and engine manufacturers. BIOBOR® JF works in both fuel and water. However, BIOBOR® JF must be kept from direct contact with excessive amounts of water to prevent hydrolysis of active ingredients into fuel insoluble materials. A complete discussion is given for proper handling and use. Should more information be needed, contact the technical service representative at Hammonds Fuel Additives, Inc. Office addresses and telephone numbers are listed at the end of this service bulletin. BIOBOR® JF is registered with the EPA as a pesticide (EPA Reg. No. 65217-1) BIOBOR® JF is recognized by a military specification number (MIL-S-53021) II. FUEL CONTAMINATION IN AIRCRAFT A. Occurrence of the Problem Surprisingly, several forms of fungi can survive and multiply in hydrocarbon fuels, especially the fuels consumed by jet aircraft. The microscopic growth occurs in al components of the fuel handling system – storage tanks, pumps, filters, delivery lines and ultimately, the jet aircraft fuel tanks. These microbes grow into long strings and form large mats or globules. The growth appears slimy, and usually black, green or brown, although it may be any color. It may grow throughout the fuel, or at the interface area between the fuel and water bottom layer. As the fuel is agitated – for instance during filling – microbial growth is distributed throughout the fuel system, where it will cling tenaciously to walls and supporting structures. The organism most commonly found in contaminated systems is Cladosporium resinae. It grows rapidly under widely varying conditions, needing only trace amounts of water and minerals to sustain itself. As it grows, it chemically alters the fuel to produce water, sludge, and acidic by-products. It can attack and destroy fuel tank linings and hoses, and pit metals to the point where holes are formed. Other problems can also arise. Fuel tank gauging systems are favorite places for microbial growth and the adhering slime interfaces with the operation of the indicating system to cause erratic readings. Filters also are affected, as 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. the slimy material is very difficult to remove by the usual fuel filtering methods. The slime very quickly clogs filters, sometimes to the point of fuel starvation. B. Detection of the Problem Evidence of contamination may be seen on filters, tank surfaces, and pipelines as a dark slimy mass. The fuel may develop a smell of sulphur, similar to rotten eggs. Where there is no clear evidence but contamination is suspected, there are biological methods for testing fuel. Among the most convenient of these is the Hum-Bug Detector® Kit available from Hammonds Fuel Additives, Inc., Houston, Texas. Whenever fuel tanks are opened for a maintenance inspection, a visual examination should be made to determine the presence of slime on interior surfaces and particularly in sump area where slime proliferates. Water, routinely drawn from sump areas, should also be inspected for slimy debris. Erratic readings from fuel quantity probes may be due to an accumulation of slime deposits. Physical cleaning of the fuel probes may reduce the problem temporarily but re-growth very likely will occur resulting in faulty readings and further damage because of corrosion. Positive findings of slime require immediate action to prevent further damage. C. Prevention of the problem The problem of microbial contamination in fuels can be alleviated by a two-step procedure: 1. Use of a microbicide, such as BIOBOR® JF, following the instructions below. 2. Proper maintenance of the fuel handling system. This is a key step because the effectiveness of even the most efficient fungicide can be reduced if the fuel is allowed to retain fungal debris and high excesses of water. Proper maintenance therefore requires regular removal of accumulated water bottoms and drainage of sump areas in addition to proper filtering to remove debris. Filters and screens should be inspected regularly. Storage tanks must be included in regular cleaning and inspection schedules. In some instances, good housekeeping may be all that is needed to prevent fungal growth. However, contamination occurs very easily, and even the best maintained system may need the assurance of BIOBOR® JF. III. INSTRUCTIONS FOR USE OF BIOBOR® JF A. General Prepare the system before using BIOBOR® JF by checking the condition of the entire system. If microbial growth contamination has already occurred, there may have been damage that should be repaired. In badly contaminated systems, as BIOBOR® JF kills the microbes, water, chemical and physical debris can be released that my further damage or clog the fuel system. When adding BIOBOR® JF, consult the dosage charts (Tables II, III and IV), or calculate the amount of BIOBOR® JF necessary to treat the fuel. For contaminated systems, or tanks prone to microbial attack, 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. use the higher “shock” treatment level. This is calculated at 270 PPM BIOBOR® JF in fuel, or approximately one gallon of BIOBOR® JF for 5,000 gallons of turbine fuel. For maintenance in new or previously treated tanks, a level of 135 PPM BIOBOR® JF or one gallon BIOBOR® JF in 10,000 gallons of turbine fuel, may be used. Exact usage will vary due to variations in weather, movement of fuel, and aircraft type. In general, use the lower level as long as the system is free of microbial growth. If contamination occurs, use the 270 PPM addition, or treat more often, or both. In no instance should BIOBOR® JF be used at more than 270 PPM in the fuel. Also, consult your aircraft manufactures’ operations manual for recommended frequency of usage. When using BIOBOR® JF, check the filters frequently at first. Dying microorganisms will release specks of dirt and rust that have been caught in the mats. Also, the slime itself may come off walls and structures as it is killed. Once dead, the slimy nature of the growth will disappear, and it should become more filterable. Once BIOBOR® JF is applied to fuel, it begins to work immediately. However, when large infestations exist, it is important to allow sufficient time for the BIOBOR® JF to provide a thorough kill. The concern is that BIOBOR® JF treated fuel in a contaminated tank will begin to break up large mats of growth into smaller ones which, once dislodged, could cause filter or line plugging. It is important that treated fuel be allowed to kill an infestation completely. Even still, when large, visual infestations exist, once killed, carcass remains and particulate matter which may have been trapped in large mats of microbial growth will need to be removed manually or by filtration. Also, tanks that are not completely filled with treated fuel, may not get protection above the fuel line. Therefore, it is also recommended that BIOBOR® JF treated fuel be used to fill tanks completely to ensure total sterilization. B. Blending CAUTION: Turbine fuel, by its nature contains some water. Always be sure fuel has been properly maintained and filtered to remove water and debris. BIOBOR® JF is a mixture of glycol borates, and under certain conditions (high BIOBOR® JF concentrations), will hydrolyze in fuel-water systems to form solid crystalline products. To avoid the possibility of solids formation, care must be taken to avoid adding BIOBOR® JF to fuel containing excess moisture, and to avoid using BIOBOR® JF above a concentration of 1,000 PPM (equivalent to 0.1%, or about 3.8 gallons of BIOBOR® JF to 5,000 gallons of fuel) even when preparing BIOBOR® JF fuel concentrates. Glycol borates are soluble in both the water and fuel phases of the system. For practical purposes, a partition coefficient of 250:1 fuel to water distribution can be assumed. In the presence of very low concentrations of water in fuel, BIOBOR® JF is essentially contained in the fuel phase. With BIOBOR® JF at its recommended level of 270 PPM, there will be no problem of solids formation. However, in the presence of excess water, either through direct dilution of BIOBOR® JF with water, of by adding BIOBOR® JF to “wet” fuel, i.e., fuel from a sump area, formations of solids may occur. If BIOBOR® JF concentration in fuel is maintained below 1,000 PPM, it has been shown that solid formation will not occur, even in “wet” fuel. However, above 1,000 PPM of BIOBOR® JF in fuel, water concentration becomes a factor and in laboratory tests, amounts of water in excess of 1,000 PPM added to the fuel treated with BIOBOR® JF caused formation of solids. ASTM standards note the maximum recommended limit for water in jet fuel not exceed 30 PPM. For reasons noted above, we strongly recommend the use of a metered injection system for BIOBOR® JF addition to aviation turbine fuel. Metered injection eliminates problems associated with batch15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. blending and over-the-wing addition. Also, it ensures continuous dilution at the correct level in a flowing stream of fuel. Complete dispersion is obtained immediately, which is especially important in wing tanks with baffles and in aircraft where fuel cannot be re-circulated to promote mixing. Over the wing treatment in aircraft that do not have re-circulation devices may lead to chronic under treatment, or lack of treatment, in some areas of the fuel tank. This will result in lack of fungal control in those areas. Therefore, a Hammonds Additive Injection System is highly recommended. Contact Hammonds Technical Services, Inc. at (713) 999-2900, Fax (713) 847-1857, for an additive injection system distributor near you. If metered injection is not possible, and the only alternatives are batch-blending or over-the-wing addition, further precautions should be taken. When batch-blending, calculate the amount of BIOBOR® JF needed for treatment, and prepare a batch that does not exceed the 1,000 PPM concentration. Use a large container and be sure that it is free of dirt, water and other contaminants. Fill the container one-half full with fuel first, then continue adding fuel and BIOBOR® JF at the same time to ensure proper dispersion. To insure proper dilution below 1,000 PPM, a tank truck may be required for mixing. When adding BIOBOR® JF over the wing, fill the wing tank about half-full with fuel first, then add BIOBOR® JF slowly during addition of the remaining fuel. This will help bring about dispersion, and avoid areas of high concentration. Never add BIOBOR® JF to an empty tank. Table II will serve ass an aid in calculating the amount of BIOBOR® JF to blend with turbine fuel to obtain concentrations of 270 and 135 PPM. For jet fuel, a density of 6.7 pounds per gallon is used as a basis for the calculation. Density of BIOBOR® JF is 8.75 pounds per gallon. C. Storage Tank Treatment BIOBOR® JF may be added to storage tanks following the same precautions as outlined above. Again, metered injection into the incoming stream of fuel is the preferred method. BIOBOR® JF should never be added directly into water bottom areas nor should it be used as a tank wall cleaning agent. It is designed for use as a fuel additive only. When treating storage tanks, be sure that all aircraft to receive fuel from that tank have approval for BIOBOR® JF use. D. Storage and Handling of BIOBOR® JF Containers BIOBOR® JF containers should be protected from water. Containers must be capped tightly when not in use, as prolonged exposure to atmospheric moisture can cause formation of solids and loss of effectiveness. To avoid prolonged storage of containers that have been opened, choose a size most suitable to your needs. Before use, clean the lid area of dust and dirt. Discard if product is discolored or contains solids. DO NOT TRANSFER BIOBOR® JF TO OTHER CONTAINERS FOR STORAGE. BIOBOR® JF is presently available in 16 ounce, one quart, one gallon, five gallon and fifty-five gallon non-returnable containers. 16 ounce Easy Squeeze containers are sold twelve bottles per case. Quarts are sold six per case. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. TABLE I BIOBOR® JF PRODUCT DATA Chemical Composition Active Ingredients 2,2’—oxybis (4, 4, 6-trimethyl – 1, 3, 2-dioxaborinane) 2,2’—(1-methyltrimethylenedioxy) bis-(4-methyl 1-1, 3, 2-dioxaborinane) 95.0% Inert Ingredients Petroleum Naptha Inerts TOTAL: Boron Content 4.5% 0.5% 100% 7.3% Physical Properties (typical) Flash Point, TCC (Tag Closed Cup) Density Pour Point Color (ASTM) 104 ± 2° F. 1.05g/cc @ 68° F. -27° F. 0.5. TABLE II BIOBOR® JF DOSAGE LEVELS (FUEL = U.S. GALLONS) JET FUEL Lbs. Gals. 670 1,340 2,010 2,680 3,350 6,700 13,400 16,750 33,500 67,000 134,000 335,000 100 200 300 400 500 1,000 2,000 2,500 5,000 10,000 20,000 50,000 SHOCK TREATMENT @ 270 PPM Gals. Fl. Ozs. 0.02 0.04 0.06 0.08 0.10 0.21 0.42 0.52 1.0 2.1 4.2 10.3 2.6 5.3 8.0 10.7 13.4 26.8 53.6 67.0 134.0 268.0 536.0 1340.0 MAINTENANCE LEVEL @ 135 PPM Gals. Fl. Ozs. 0.01 0.02 0.03 0.04 0.05 0.10 0.21 0.26 0.52 1.04 2.09 5.23 1.3 2.6 4.0 5.3 6.7 13.4 26.8 33.5 67.0 134.0 268.0 670.0 To determine the fluid ounces of BIOBOR® JF required to give a concentration of 270 PPM, multiply pounds of fuel by 0.004 and for 135 PPM by 0.002 Density of Jet Fuel: 1 Gallon weighs 6.714 pounds. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. TABLE III BIOBOR® JF DOSAGE LEVELS METRIC EQUIVALENTS TURBINE FUEL* U.S. GAL. LITERS 100 300 625 1250 BIOBOR® JF (270 PPM)** BIOBOR® JF (135 PPM)** 80 ml 236 ml 473 ml 946 ml 40 ml 118 ml 236 ml 473 ml 378.5 1135.5 2365.6 4731.3 * Assuming fuel density of 0.804g/ml ** BIOBOR® JF density = 1.05g/ml TABLE IV BIOBOR® JF METRIC CONVERSIONS FOR VARIOUS FUELS “SHOCK TREATMENT” AT 270 PPM Fuel JP-4 Kerosine (Turbine Fuel) Diesel #1 Diesel #2 Bunker “C” g/ml Fuel Density at 15° C / 59° F. lbs. gal* kg/L 0.7601 0.8045 0.8180 0.8484 0.9952 6.343 6.714 6.827 7.080 8.305 .762 .806 .820 .850 .997 Oz. of ml of ® BIOBOR JF BIOBOR® JF Per 1000 Per 1000 gal. fuel liters fuel 25.37 26.86 27.31 28.32 33.22 198.27 209.57 214.50 220.99 259.26 To determine the fluid ounces of BIOBOR® JF required to give a concentration of 270 PPM, multiply pounds of fuel by 0.004 and for 135 PPM by 0.002. To determine milliliters of BIOBOR® JF required to give a concentration of 270 PPM, multiply kilograms of fuel by .26 and for 135 PPM by .13 *Computed from fuel densities as surveyed by the American Petroleum Institute. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. TABLE V BIOBOR® JF COMPATIBILITY WITH FUEL SYSTEM COMPONENTS* BIOBOR® JF IS COMPATIBLE WITH: I. Top Coatings and Sealants 1. 2. 3. 4. 5. 6. 7. 8. 9. Buna-N (EC-7765-R) Polyurethane PR-1560 PR-1422 (Thiokol type) PR-703 Products Research Corporation PR1422 Products Research Corporation PR-9021 Product Research Corporation Pro Seal-719 Coast Pro Seal Company Pro Seal-890 Coast Pro Seal Company Z9-0048 Dow Corning Corporation II. Fuel Cell Materials 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. Estane 580029 BTC-17-10 BTC-12-3 BTC-49 BTC-54A BTC-67 BTC-85 BTC-86 10740SR LS-53 Silicone MIL R-6855 US-566R/RL US-943 B.F. Goodrich Goodyear Goodyear Goodyear Goodyear Goodyear Goodyear Goodyear Firestone Dow Corning Corporation Precision Components UNIROYAL (nitrile materials) UNIROYAL (nitrile materials) III. Metal Alloys 1. SAE 1010 2. AZ92 3. 2024 4. 4015 5. 7178 6. 7075 7. Cad plated steel Steel Magnesium Aluminum Aluminum Aluminum Aluminum 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. III. Metal Alloys 1. SAE 1010 2. AZ92 3. 2024 4. 4015 5. 7178 6. 7075 7. Cad plated steel Steel Magnesium Aluminum Aluminum Aluminum Aluminum IV. Fuel Tank Gauging Systems 1. 2. 3. 4. Approved by Minneapolis Honeywell Approved by Simmonds Precision Products Approval by Liquidometer Corporation Approval by Consolidated Airborne Systems BIOBOR® JF is not compatible with Lexan polycarbonate. BIOBOR® JF at full strength may not be compatible with some polymeric materials. TEFLON is recommended for gaskets and / or O-rings where exposure to neat BIOBOR® JF is anticipated. *Testing was done at recommended use dilution or two times use dilution. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. COMPANIES WHICH RECOMMEND THE USE OF BIOBOR® JF AIRCRAFT MANUFACTURERS de Havilland, Inc. Gulf Stream Aerospace Corp. Boeing Aircraft Beechcraft Aircraft Corp. Dassault Falcon Jet Bell Helicopter Fokker Aircraft Corp. LearJet Corporation Lockheed Aircraft Company Sikorsky Helicopter British Aerospace Aircraft McDonnell Douglas Aircraft Saberliner Aircraft Corp. AirBus Industries ENGINE ACCESSORIES AND FUEL MONITORING EQUIPMENT MANUFACTURERS Dahl Filter Corporation Velcon Filters, Inc. Stanadyne Filter/Fuel Injector Systems Airborne Fuel Filters Consolidated Airborne Systems Liquidometer Corporation Minneapolis Honeywell Simmonds Precision Products Facet Filter Fleetguard Filter Corporation FUEL SERVICE COMPANIES AIRCRAFT ENGINE MANUFACTURERS Rolls Royce Engines Lycoming Engine Corporation Pratt & Whitney Engines Allison Industries Garrett Aircraft Engines General Electric Engines Division Allied Signal Aerospace Corp. DIESEL ENGINE MANUFACTURERS Detroit Diesel Corp. Caterpillar Tractor Corp. International Harvester Tractor Co. Waukesha/Dresser Engines Cummins Engine Co., Inc. General Motors – Diesel Engine Division Mercedes Benz John Deere Tractor Paulsen Industries Fuel Tank Maintenance Fuel Tank Cleaners of Florida Fuel Pure TANK MANUFACTURERS Uniroyal Tank and Plastic Production Division Goodyear Aerospace U.S. Steel Tank Firestone Tank Division Dow Corning Tanks A.O. Smith Fiberglass Tank Corp. BF Goodrich Aerospace The OEM’s listed above suggest the use of Biobor® JF as part of their standard maintenance programs. This endorsement appears in the Equipment Maintenance Manuals under Engine Airframe or Fuel System Care. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129 HAMMONDS FUEL ADDITIVES, INC. HAMMONDS FUEL ADDITIVES, INC. 15760 WEST HARDY ROAD, SUITE 400 • HOUSTON, TEXAS 77060-3147 800 548 9166 • FAX: 281 847 5129 NOTICE: THERE ARE NO WARRANTIES, EXPRESS OR IMPLIED INCLUDING ANY WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE, WHICH EXTEND BEYOND THE DESCRIBED USES IN THIS BULLETIN. WARNING: ON ALL PRODUCTS, AVOID PROLONGED INHALATION OR PROLONGED SKIN CONTACT. NOT FOR FOOD OR DRUG USE. READ ALL INSTRUCTIONS RELATING TO THE PRODUCTS BEFORE USE. If possible uses of these products have been mentioned herein, it is not intended that the above products be used to practice any applicable patent, whether mentioned in this Bulletin or not, without procurement of a license, if necessary, from the owner, following investigation by the user. ©1992 All Rights Reserved. 15760 WEST HARDY ROAD, SUITE 400 •HOUSTON, TEXAS 77060-3147 • (281) 999-2900 • (800) 584-9166 • FAX: (281) 847-5129
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