Lithofacies and Petrophysical Properties of Mesaverde Tight
Transcription
Lithofacies and Petrophysical Properties of Mesaverde Tight
Lithofacies and Petrophysical Properties of Mesaverde Tight-Gas Sandstones in Western U.S. Basins: a short course Alan P. Byrnes formerly Kansas Geological Surveynow Chesapeake Energy Robert M. Cluff John C. Webb Daniel A. Krygowski Stefani D. Whittaker The Discovery Group, Inc 2009 AAPG Annual Convention Short course #1 6 June 2009, Denver, Colorado Cluff: Introduction and Overview Lithofacies and Petrophysical Properties of Mesaverde TightTight-Gas Sandstones in Western U.S. Basins: a short course Alan P. Byrnes formerly Kansas Geological Survey Survey-now Chesapeake Energy Robert M. Cluff John C. Webb Daniel A. Krygowski Stefani D. Whittaker The Discovery Group, Inc 2009 AAPG Annual Convention Short course #1 6 June 2009, Denver, Colorado AAPG ACE 2009: Denver Colorado 1 Denver, Colorado Short course agenda 8:00-8:30 8:008:30--10:00 8:30 Project overview, Bob Cluff Lithofacies and geology of the Mesaverde Group, John Webb 10:0010 10:00 00-10:15 10 15 b break eak 10:1510:15-noon Porosity & permeability of Mesaverde tight gas sands, Alan Byrnes noon--1:00p lunch noon 1:00--2:30 1:00 Pc, resistivity, and relative perm of Mesaverde, Alan Byrnes 2:30--2:45 2:30 break 2:452:45-4:15 Log evaluation of the Mesaverde, Mesaverde Dan Krygowski, Stefani Whittaker, & Bob Cluff 4:15--4:30 4:15 discussion, Q&A period AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 2 1 of 217 Cluff: Introduction and Overview Project title: Analysis of Critical Permeability, Capillary and Electrical Properties for Mesaverde Tight Gas Sandstones from Western U.S. Basins US DOE # DE-FC26-05NT42660 website: http://www.kgs.ku.edu/mesaverde AAPG ACE 2009: Denver Colorado 3 Project overview ¾ ¾ Project proposal submitted on 21 March 2005 in response to DOE solicitation DEDE-PS26 PS26--04NT42720 DOE award DEDE-FC26 FC26--05NT42660 in October 2005 z z ¾ ¾ ¾ for $411K DOE funds/$103K industry coco-share Discovery Group inin-kind contribution of manpower and facilities 2 ½ year study with nono-cost extension Alan P. Byrnes, Principal Investigator University of Kansas Center for Research was the umbrella contracting organization z Kansas Geological Survey and The Discovery Group, cocoparticipating research contractors AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 4 2 of 217 Cluff: Introduction and Overview Team Members University of Kansas Kansas--Kansas Geological Survey Alan P. Byrnes (Principal Investigator) Support Team Members: John Victorine, Ken Stalder, Daniel S. Osburn, Andrew Knoderer, Owen Metheny, Troy Hommertzheim, Joshua P. Byrnes The Discovery Group, Inc. Robert M. Cluff (co(co-Principal Investigator) John C. Webb, Daniel A. Krygowski, Stefani Whittaker AAPG ACE 2009: Denver Colorado 5 Future Gas Supply Lower 48 unconventional gas sources will meet nearly 50% of US demand (Caruso, EIA, 2008) AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 6 3 of 217 Cluff: Introduction and Overview Future Gas Supply While tight gas sandstones represent over half of unconventional supply (Caruso, EIA, 2008) 7 AAPG ACE 2009: Denver Colorado Annual Gas Production (Tcf) Production Projected to Increase from Rocky Mountain Region Date AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 (US EIA, 2004) 8 4 of 217 Cluff: Introduction and Overview Natural Gas Type Lower 48 Technically Recoverable Resources Tcf (US EIA, 2004) 9 AAPG ACE 2009: Denver Colorado PGC Rocky Mountain Gas Resources Kmv Shallow Resources (0(0-15,000 ft) Deep Resources (15,000(15,000-30,000 ft) Total Traditional Resources Coalbed Gas Resources Total Recoverable Resources 99,167 Bcf 24,429 Bcf 123,596 Bcf 63,273 Bcf 186,869 Bcf Data source: Potential Gas Committee (2003) AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 10 5 of 217 Cluff: Introduction and Overview Why pick the Mesaverde? ¾ Tight gas sandstones (TGS) represent z z z z ¾ 72% (342 TCF) of the projected unconventional gas resource (474 TCF). Rocky Mountain TGS are 70% of the total TGS resource base (241 Tcf; USEIA USEIA, 2004) and the Mesaverde Group represents the main gas productive sandstone unit in the Rocky Mtn. TGS basins and the largest shallow (<15,000 ft) target. Understanding of reservoir properties and accurate tools for formation evaluation are needed for: z z z z assessment of the regional gas resource projection j ti off ffuture t gas supply l exploration programs optimizing development programs AAPG ACE 2009: Denver Colorado 11 Project objectives ¾ The project provides petrophysical tools that address fundamental questions concerning z z z z z z gas flow, flow critical gas saturation saturation, Sgc=f Sgc= Sgc f (lithofacies, (lithofacies Pc, architecture) capillary pressure, Pc=f Pc=f (P), Pc=f Pc=f (lithofacies, k, φ, architecture) electrical properties, m* & n* facies and upscaling issues wireline log interpretation algorithms providing a webweb-accessible database of advanced rock properties. AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 12 6 of 217 Cluff: Introduction and Overview Specific research objectives ¾ ¾ ¾ ¾ ¾ explore nature of critical gas saturation, capillary pressure, and electrical properties of Mesaverde tight gas sandstones h how d do th these vary with ith porosity, it permeability, bilit and d lithofacies? better understanding of minimum gas saturation required for gas flow improve log calculations through better corrections for conductive solids/surface effects address the lack of adequate public domain databases covering petrophysics of tight gas sandstones z lots of proprietary data out there, numerous publications with partial datasets, but nothing integrated to work with AAPG ACE 2009: Denver Colorado 13 Tasks ¾ ¾ ¾ Task 1. Research Management Plan Task 2. Technology Status Assessment Task 3. Acquire Data and Materials z z z ¾ Task 4. Measure Rock Properties p z z z z z z ¾ z z Subtask 6 6.1. 1 Compare log and core properties Subtask 6.2. Evaluate results and determine loglog-analysis algorithm inputs Task 7. Simulate ScaleScale-dependence of Relative Permeability z z ¾ Subtask 5.1. Compile published and measured data into Oracle database Subtask 5.2. Modify existing webweb-based software to provide GUI data access Task 6. Analyze WirelineWireline-log Signature and Analysis Algorithms z ¾ Subtask 4.1. Measure basic properties (k, φ, GD) and select advanced population Subtask 4.4. Measure critical gas saturation Subtask 4.3. Measure inin-situ and routine capillary pressure Subtask 4.4. Measure electrical properties Subtask 4.5. Measure geologic and petrologic properties Subtask 4.6. Perform standard logs analysis Task 5. Build Database and WebWeb-based Rock Catalog z ¾ Subtask 3.1. Compile published advanced properties data Subtask 3.2. Compile representative lithofacies core and logs from major basins Subtask 3.3. Acquire logs from sample wells and digitize Subtask 7.1. Construct basic bedform architecture models Subtask 7.2. Perform numerical simulation of flow for basic bedform architecture Task 8. Technology Transfer AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 14 7 of 217 Cluff: Introduction and Overview Research strategy ¾ compile all available published advanced rock properties (Pc, FRF, Krg, compressibility, etc.) ¾ collect 300+ core plug samples from 20 to 25 wells across 5 major basins ¾ sample full range of rock types, porosity and permeability found in Mesaverde throughout the Rockies z Kmv is widespread, lots of core available, representative example for most TGS problems 15 AAPG ACE 2009: Denver Colorado Sampling ¾ ¾ ¾ ¾ 44 wells in 6 basins described 7000 ft core (digital) 2200 core samples 120 120--400 advanced properties ti samples Powder River Wind River Wyoming Green River N Washakie Utah Colorado Uinta AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 Piceance 16 8 of 217 Cluff: Introduction and Overview Number of wells by basin Number of W Wells 12 10 Industry-contribution USGS Core Library 8 6 4 2 Wind Riverr Washakie (Sand Wash) Washakie Uinta Powder River Piceance Green n River 0 Basin 17 AAPG ACE 2009: Denver Colorado Core Plugs by Basin Number of Core e Plugs 700 600 500 400 300 200 100 Powderr River Wind R iverr Piceance e Uinta a Washakie e Greater Green Riverr 0 Basin AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 18 9 of 217 Cluff: Introduction and Overview Sampling by depth 0.20 0.18 0 16 0.16 0.14 0.12 0.10 0.08 0.06 0.04 0 02 0.02 0.00 100% 90% 80% 70% 60% 50% 40% 30% 20% 10% 0% 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000 11000 12000 13000 14000 15000 16000 17000 Fraction Depth Histogram Depth (ft) 19 All Green River Piceance Powder River Sand Wash Uintah Wind River Washakie 40 35 30 25 20 15 10 5 10-100 100-1,000 1-10 0.1-1 0.01-0.1 0.001-0.01 0.0001-0.001 0 1E-5 - 1E-4 ¾ Petrophysical property distributions are generally normal or loglog-normal SubS b-distributions Sub di t ib ti =f (basin, lithofacies, marine/non--marine, etc.) marine/non 45 1E-6 - 1E-5 ¾ 50 1E-7 - 1E-6 Property distributions Percent of Population (%) P AAPG ACE 2009: Denver Colorado Green River Piceance Powder River Uintah Wind River Washakie Sand Wash 50 40 30 20 10 0 40 Percent of Popu ulation (%) All Green River Piceance Powder River Sand Wash Uintah Wind River Washakie 35 30 25 20 15 10 5 Grain Density (g/cc) AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 22-24 20-22 18-20 16-18 2.722.74 14-16 2.702.72 12-14 2.682.70 10-12 2.662.68 8-10 2.642.66 6-8 2.622.64 4-6 2.602.62 2-4 0 2.582.60 0-2 Percent of Bas sin Population In situ Klinkenberg Permeability (mD) 45 60 In situ Porosity (%) 20 10 of 217 Cluff: Introduction and Overview Core description ¾ ¾ ¾ ¾ ¾ rock typing at 0.5 ft frequency q y to match log data resolution lithology, color, grain size, sed structures sample locations important cements d depositional iti l environments 21 AAPG ACE 2009: Denver Colorado Digital core description ¾ To provide lithologic input to equations and predict lithology from logs used 5 digit system z z z z z ¾ ¾ AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 1 basic type (Ss, Ls, coal) 2 grain size/sorting/texture 3 consolidation 4 sedimentary structure 5 cement mineralogy P Property t continuum ti - nott mnemonic or substitution cipher Similar to system used in our 1994 and subsequent studies 22 11 of 217 Cluff: Introduction and Overview Petrography ¾ 40X ¾ ¾ ~150 advanced properties smpls were petrographically characterized representative photos at several magnifications point counts Williams PA 424, 6148.8’ 15276 9.9% 2.66 g/cc Ka=0.0237 mD AAPG ACE 2009: Denver Colorado 100X 23 Core analysis program ¾ ¾ ¾ Geologic description of cores and rock types (Webb) Wire--line log analysis of all project wells over Kmv Wire (Krygowski and Whittaker) Collect plugs for basic properties (minimum 300 samples, we actually collected ~2200) (Byrnes) z z z ¾ routine porosity and permeability porosity and permeability at reservoir stress grain density Select a subsub-set of 120120-400 samples for advanced core analyses (Byrnes) AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 24 12 of 217 Cluff: Introduction and Overview “Routine” core analysis ¾ Routine porosity and permeability ¾ In In--situ porosity and permeability ¾ Pore P volume l compressibility ibilit (113 smpls) l ) z ¾ 200 200--4000 psi NCS determined new equations for z z z Klinkenberg correction stress dependent porosity stress t dependent d d t permeability bilit 25 AAPG ACE 2009: Denver Colorado Prior work In n situ Klinkenberg Perrmeability (md) 100 10 Council Grove Mesaverde/Frontier 1 0.1 0.01 0.001 0.0001 0.00001 0.001 0.01 0.1 1 10 Routine Air Permeability (md) 100 logkik = 0.0588 (logkair)3 –0.187 (logkair)2 +1.154 logkair - 0.159 AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 26 13 of 217 Cluff: Introduction and Overview SCAL work ¾ ¾ routine and in situ mercury capillary pressure investigate Pc as function of lithology, φ, K z ¾ investigate stress sensitivity of Pc z z z ¾ sample span range of basins, K, lithology most MICP curves are run under lab conditions we expect Pc to be confining stress sensitive 120 “high “high--low” pairs of plugs run using highly similar plugs selected from φ-K data look at relationship between initial saturation and residual gas saturation (“scanning curves”) z z only published data are for conventional rocks ran mercury curves for this project 27 AAPG ACE 2009: Denver Colorado Mesaverde, Frontier capillary pressure vs. permeability 10 md ~Heightt above Free Waterr (ft) 350 1 md 0.1 md 300 0.01 md 0.001 md 250 200 150 100 50 0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Water Saturation (fraction) AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 28 14 of 217 Cluff: Introduction and Overview Pc hysteresis 4 ¾ ¾ Non-wetting residual Nonsaturation to imbibition Snwr = f (Snwi) this was a “freebie” added to the project plan Drainage-Imbibition Cycles 5 3 2 1 Midale Dol φ = 23% AAPG ACE 2009: Denver Colorado 29 (after Larson & Morrow, 1981) SCAL work ¾ routine and in situ mercury capillary pressure ¾ drainage critical gas saturation AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 30 15 of 217 Cluff: Introduction and Overview Why is Sgc important? Gas Relative Permeability 1 P = 1.7 Sgc = f (kik) 0.1 P = f (kik) Sgc = 10% 0.01 0.001 0.0001 0.00001 0 10 20 30 40 50 60 70 80 90 100 Water Saturation ¾ 2 alternative views of what happens at high Sw, which is correct? 31 AAPG ACE 2009: Denver Colorado Saturation at capillary equilibrium for breakthrough pressure (Hg experiment) Saturation at Breakthrough in Pc Equilibrium (%) 60 50 40 30 20 10 0 0 10 20 30 40 50 60 Critical Saturation at Breakthrough (%) proof of concept dataset, 2005 AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 32 16 of 217 Cluff: Introduction and Overview SCAL work ¾ routine and in situ mercury capillary pressure ¾ drainage critical gas saturation ¾ cementation and saturation exponents ¾ cation exchange capacity using multimulti-salinity method 33 AAPG ACE 2009: Denver Colorado When F and φ are plotted loglog-log m= 2 1000 m= 3 but not this! F 100 m= 1 10 We’ve seen this before, 1 0.01 0.1 log F = -m log φ φ AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 1 34 17 of 217 Cluff: Introduction and Overview Products ¾ web-based database with output as XLS files, webgraphical output, reports and presentations z z z ¾ ¾ ¾ organized by data type and by area, well htt // http://www.kgs.ku.edu/mesaverde/ k k d / d / http://www.discovery--group.com/projects_doe.htm http://www.discovery methods for improved log calculations industry talks, short courses, & forthcoming publications so here we go.......... AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 35 18 of 217 Webb: Lithofacies and Reservoir Quality Influence of Lithofacies and Diagenesis on Reservoir Quality of the Mesaverde Group, Piceance Basin, Colorado John Webb Disco er Gro Discovery Group, p Den Denver, er CO AAPG Short Course no. 1, Denver, CO June 6, 2009 1 Denver, Colorado Outline ¾ ¾ ¾ ¾ ¾ ¾ ¾ ¾ ¾ Data collection procedures and methods Di it l rock Digital k classification l ifi ti system t Thin section preparation and petrography Example from the Piceance basin Paleogeography and depositional environments Lithofacies and porosity/permeability relationships Detrital composition and diagenesis Porosity distribution Influence of diagenesis on reservoir quality 2 AAPG ACE Short Course 1: 06.06.2009 19 of 217 Webb: Lithofacies and Reservoir Quality Acknowledgements Industry Partners: Bill Barrett Corporation - Steve Cumella EnCana USA, Piceance Teams - Brendan Curran, Mike Dempsey, Danielle Strickler ExxonMobil, Piceance Basin Team Don Yurewicz, Yurewicz, Hollie Kelleher Williams Production - Lesley Evans 3 Acknowledgements Contractors and Government: Elitigraphics – Peter Hutson Triple O Slabbing - Butch Oliver USGS Personnel - Phil Nelson, Mark Kirschbaum USGS Core C Research R h Center C t Tom Michalski, Betty Adrian (current director) Jeannine Honey, John Rhodes, Josh Hicks, Terri Huber, Richard Nunn, Devon Connely 4 AAPG ACE Short Course 1: 06.06.2009 20 of 217 Webb: Lithofacies and Reservoir Quality Core sampling and description ¾ ¾ ¾ ¾ ¾ Cut 1” diameter plugs from butt portions of slabbed core, using water cooled diamond drill bit Location of core plugs to 0.1 foot Digital rock typing of each core plug (lithology, grain size, porosity, sedimentary structures, cementation) Scanned core slab images and handhand-held digital photos for core plug locations and documentation of lithology t o ogy and a d sedimentary sed e ta y structures st uctu es Core descriptions from slabbed core when possible 5 Core sampling and description ¾ ¾ ¾ ¾ Logged lithology, grain size, matrix porosity, sedimentary structures, fractures, trace fossils, contact relationships and digital rock type at minimum ½ foot intervals Comparator for grain size determination HCl for identification of calcareous cements Legacy core analysis data and whole core photographs on file at USGS CRC or from current well operators 6 AAPG ACE Short Course 1: 06.06.2009 21 of 217 Webb: Lithofacies and Reservoir Quality Barrett Last Dance 43C – Typical Core Chart 7 Digital Core Description ¾ ¾ Sampling designed to sample across all lithofacies 5 digit system z z z z z ¾ basic type (Ss, Ls, coal) grain size/sorting/texture Consolidation/porosity sedimentary structure cement mineralogy Provides lithology log traces and quantitative variables for multivariate analysis 8 AAPG ACE Short Course 1: 06.06.2009 22 of 217 Webb: Lithofacies and Reservoir Quality Digital Rock Types Grain size/sorting/ shaliness Visible porosity 10xxx 11xxx 12xxx xx0xx xx1xx xx2xx 2 xx3xx xx4xx xx5xx xx6xx xx7xx xx8xx 19xxx Shale Silty shale V shaly sandstone, sandstone siltstone Shaly sandstone VF sandstone F sandstone M sandstone C sandstone VC/Matrix supported pp cgl. g Conglomerate 05000 2xxxx 30000 Volcanic ash Limestone Coal 13xxx 14xxx 15xxx 16xxx 17xxx 18xxx xx9xx 0-2%, unfractured 0-2% fractured 3 10% unfrac’d 3-10%, f ’d 3-10%, frac’d 3-10%, highly frac >10%, unfrac’d >10%, frac’d >10%, unfrac’d V high, weak consolidation Unconsolidated Porosity/ Resistivity logs GR/Porosity/ Resistivity logs 9 Digital Rock Types, cont. Sedimentary struc’s xxx0x Vertical dike xxx1x Bioturbated xxx2x Contorted xxx3x Discontinuous laminations xxx4x Continuous laminations xxx5x Flaser bedded xxx6x Ripple laminated xxx7x Trough & planar tabular crossbeds xxx8x Planar laminated, low angle cross bedded xxx9x Massive bedded Shaliness, vertical and lateral permeability Cement xxxx0 Pyrite xxxx1 1 Siderite Sid i xxxx2 Phosphate xxxx3 Anhydrite xxxx4 Dolomite xxxx5 Calcite xxxx6 Quartz xxxx7 Authigenic clay xxxx8 Carbonaceous xxxx9 No pore filling Density/ Resistivity/ PE logs 10 AAPG ACE Short Course 1: 06.06.2009 23 of 217 Webb: Lithofacies and Reservoir Quality 15277 - Medium sandstone with moderate porosity, not fractured, trough cross bedded, clay cemented 11 Utility of digital rock typing, continued ¾ ¾ ¾ ¾ ¾ ¾ Excellent match with GR log traces, core gamma Precise depth shifting of core analysis data D Demonstrates t t iinfluence fl off grain i size i and d shaliness h li on porosity and permeability Allowed improvement of equations used to calculate Archie Sw Sw,, total and effective porosity and significantly improved estimates of permeability Rock types are not restricted to a specific depositional environment Log analysis identified detrital shale component, but failed to identify details of grain size and sedimentary structures 12 AAPG ACE Short Course 1: 06.06.2009 24 of 217 Webb: Lithofacies and Reservoir Quality Correlation of lithofacies and core analysis data to wireline logs 13 Utility of digital rock typing ¾ ¾ ¾ Track statistical distribution of lithofacies for sampling and core analysis data Provides quantitative variables for multivariate analysis The simple variation in grain density from basin to basin indicates that differences in detrital composition of sediment, depositional environment, burial history and diagenesis among basins requires separate treatment of basins for assessment of reservoir quality 14 AAPG ACE Short Course 1: 06.06.2009 25 of 217 Webb: Lithofacies and Reservoir Quality Percent of Basin Popula ation Grain densities of the Mesaverde Group 60 Green River Piceance Powder River Uintah Wind River Washakie Sand Wash 50 40 30 20 10 0 2.582.60 2.602.62 2.622.64 2.642.66 2.662.68 2.682.70 2.702.72 2.722.74 Grain Density (g/cc) 15 Thin section preparation ¾ ¾ ¾ ¾ ¾ ¾ Blue-dyed epoxy, low viscosity, slow cure BlueVacuum and pressure impregnation in warm oven Polished surfaces of billet and mounted slide Dual carbonate stained for nonferroan (red) and ferroan carbonate (various shades of blue) Stained for potassium feldspar (K(K-spar is yellow) Cover slips 16 AAPG ACE Short Course 1: 06.06.2009 26 of 217 Webb: Lithofacies and Reservoir Quality Thin section petrography ¾ Nikon and Leitz petrographic microscopes ¾ Conventional film and digital photography, representative magnifications and detailed features ¾ 300 point counts per sample, automated point count stage ¾ Calculations in Excel, g graphic p p plots in Quattro Pro and Excel spreadsheets 17 Utility of thin section petrography ¾ Detrital composition z z z ¾ Cements z ¾ Provenance Radioactive components for GR match Bulk density of constituent grains Bulk density of constituent cement (calcite, dolomite, pyrite, clay) Distribution of clay z z z Detrital - laminated, structural, dispersed (burrowing) Clay cements – pore pore--lining, porepore-bridging or dispersed Clay mineralogy (visual morphology) AAPG ACE Short Course 1: 06.06.2009 18 27 of 217 Webb: Lithofacies and Reservoir Quality Utility of thin section petrography ¾ Diagenesis z z ¾ Porosity distribution z z ¾ Assess the effect of compaction and pressure solution Document changes in detrital grains or rock fabric Mesoporosity, microporosity, moldic and intragranular porosity Compare relative abundance of Meso vs. Micro Fractures z z Assess the importance of microfractures Identify fracture cements 19 Paleogeography of Mesaverde Group, Uinta and Piceance Basins Early Clagget time, Middle Judith River time, Mancos Shale Iles Formation (Rollins, Cozette and Corcoran Ss) Middle Bear Paw time, Williams Fork Formation approx 80 mya approx 73 mya McGookey, et al., 1972 AAPG ACE Short Course 1: 06.06.2009 approx 70 mya 20 28 of 217 Webb: Lithofacies and Reservoir Quality Depositional environments of the Mesaverde ¾ ¾ ¾ ¾ ¾ ¾ Shallow marine and shoreline environments, including lagoonal lagoonal, bay bay--fill and coastal marsh Tidal delta, tidal channel, mudflat and tidally influenced coastal streams Coal swamps (raised mire) and coastal plain Fluvial Fl i l channel, h l iincluding l di tid tidally ll iinfluenced fl d Abandoned channel and overbank/splay Paleosols,, rooted horizons, air fall ash and Paleosols lacustrine to shallow marine limestone 21 Example: The Piceance Basin ¾ Core analysis: z Routine - 629 samples, SCAL - 46 samples ¾ Mercury invasion and imbibition curves for 8 samples ¾ Core description and petrography : z ¾ 6 wells, 2 shallow bore holes, 1168’ core, 46 thin section point counts L analysis: Log l i z Modern log suites for 5 wells, various vintages and format for 1 older well and 2 shallow bore holes 22 AAPG ACE Short Course 1: 06.06.2009 29 of 217 Webb: Lithofacies and Reservoir Quality Mesaverde Group cores, Piceance Basin W Fuels 21011-5 Moon Lake White River Dome FR M30-2-96W WRD Love Ranch EM WR T63X-2G RulisonMamm Creek Grand Valley Chevron 33-34 Parachute MWX-2 BBC LD 43C-3-792 USGS BC 1 Wms PA 424-34 23 Stratigraphic distribution of samples, Piceance Basin 33-34 3,500 ft 4,600 ft 5700 ft 10,500 ft USGS Coal Resources, #1 Book Cliffs outcrop core 250 ft 6,500 ft 6,600 ft 8200 ft 6,300 ft 8,100 ft 24 AAPG ACE Short Course 1: 06.06.2009 30 of 217 Webb: Lithofacies and Reservoir Quality Barrett Last Dance 43C – Shallow Marine/Coastal 25 Barrett Last Dance 43C – Coastal Mudstones 26 AAPG ACE Short Course 1: 06.06.2009 31 of 217 Webb: Lithofacies and Reservoir Quality Barrett Last Dance 43C – Fluvial 27 Lithofacies - Influence of grain size and shaliness on porosity and permeability Phi/K Crossplot Mesaverde Group, Piceance Basin Amb bient Permeability, in mD 100 10 1 11XXX 12XXX 13XXX 0.1 14XXX 15XXX 0.01 16XXX 17XXX 0.001 0.0001 0 5 10 15 20 Ambient Porosity, percent 28 AAPG ACE Short Course 1: 06.06.2009 32 of 217 Webb: Lithofacies and Reservoir Quality Phi/K Crossplot Mesaverde Group, Piceance Basin 100 Ambient Permeability, in m mD 10 1 0.1 11XXX 0.01 0.001 0.0001 0 5 10 15 20 Ambient Porosity, percent 29 Phi/K Crossplot Mesaverde Group, Piceance Basin 100 Ambient Permeability, in m mD 10 1 0.1 12XXX 0.01 0.001 0.0001 0 5 10 15 20 Ambient Porosity, percent 30 AAPG ACE Short Course 1: 06.06.2009 33 of 217 Webb: Lithofacies and Reservoir Quality Phi/K Crossplot Mesaverde Group, Piceance Basin 100 Ambient Permeability, in m mD 10 1 0.1 13XXX 0.01 0.001 0.0001 0.0 5.0 10.0 15.0 20.0 Ambient Porosity, percent 31 Phi/K Crossplot Mesaverde Group, Piceance Basin 100 Ambient Permeability, in m mD 10 1 0.1 14XXX 0.01 0.001 0.0001 0 5 10 15 20 Ambient Porosity, percent 32 AAPG ACE Short Course 1: 06.06.2009 34 of 217 Webb: Lithofacies and Reservoir Quality Phi/K Crossplot Mesaverde Group, Piceance Basin Ambient Permeability, in m mD 10 1 0.1 15XXX 0.01 0.001 0.0001 0 5 10 15 20 Ambient Porosity, percent 33 Phi/K Crossplot Mesaverde Group, Piceance Basin Ambient Permeability, in m mD 10 1 0.1 16XXX 17XXX 0.01 0.001 0.0001 0 5 10 15 20 Ambient Porosity, percent 34 AAPG ACE Short Course 1: 06.06.2009 35 of 217 Webb: Lithofacies and Reservoir Quality Phi/K Crossplot Mesaverde Group, Piceance Basin Ambient Permeability, in m mD 10 1 0.1 16XXX 17XXX 0.01 0.001 0.0001 0 5 10 15 20 Ambient Porosity, percent 35 Influence of burial on porosity and permeability of lithofacies Phi/K Crossplot Mesaverde Group, Piceance Basin Fine Grained Ss (15xxx) Amb bient Permeability, in mD 100 10 1 250 ‐ 3999 ft 4000 ‐ 6999 ft 7000 ‐ 10,000 ft 0.1 0.01 0.001 0 5 10 15 20 25 Ambient Porosity, percent 36 AAPG ACE Short Course 1: 06.06.2009 36 of 217 Webb: Lithofacies and Reservoir Quality Influence of burial on porosity and permeability of lithofacies Phi/K Crossplot Mesaverde Group, Piceance Basin Medium Grained Ss (16xxx) 100 Ambient Permea ability, in mD 10 1 250 ‐ 3999 ft 4000 ‐ 6999 ft 7000 ‐ 10,000 ft 0.1 0.01 0.001 0 5 10 15 20 25 Ambient Porosity, percent 37 Detrital Composition of Sandstones in the Mesaverde Group ¾ Why do we care? Because detrital composition has an effect on diagenesis and porosity preservation. ¾ In the Mesaverde, quartzose sandstones are preferentially subject to pressure solution compaction and quartz overgrowth cementation (clay cementation may retard overgrowths) ¾ Feldspathic sandstones suffer compaction by grain rearrangement and brittle deformation, accompanied by clay cement. 38 AAPG ACE Short Course 1: 06.06.2009 37 of 217 Webb: Lithofacies and Reservoir Quality Detrital Composition of Sandstones in the Mesaverde Group ¾ Other alterations include dissolution of framework grains ((Kg (K-spar p and carbonate rock fragments), resulting in moldic porosity. ¾ Ductile deformation of shale, carbonaceous material, volcanic rock fragments and micaceous grains, brittle deformation of feldspars 39 Detrital Composition of Sandstones in the Mesaverde Group ¾ ¾ ¾ ¾ Composition ranges from litharenite to feldspathic litharenite lithic arkose, litharenite, arkose sublitharenite sublitharenite, subarkose and quartzarenite Rock fragments include volcanic, sedimentary and metamorphic grains Volcanic rock fragments are commonly altered, resulting in replacement by clay silicification and partial to complete dissolution clay, Sedimentary rock fragments include shale/mudstone, chert and carbonate grains 40 AAPG ACE Short Course 1: 06.06.2009 38 of 217 Webb: Lithofacies and Reservoir Quality 41 42 AAPG ACE Short Course 1: 06.06.2009 39 of 217 Webb: Lithofacies and Reservoir Quality 43 Detrital Composition, Barrett Last Dance 43C 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% Williams Fork Fm 3544.9 3555.4 3577.6 4004.3 4013.3 Top Gas 4363 ft 4393.6 4416.6 5715.4 6042.4 Cameo Coal zone 6337.1 Quartz Feldspar Lithic 44 AAPG ACE Short Course 1: 06.06.2009 40 of 217 Webb: Lithofacies and Reservoir Quality Detrital Composition, MWX‐2 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% Williams Fork Fm 5734.1 5838.6 5852.3 6536.3 6542.2 6550.3 7085.5 7133.5 7264.5 7272.8 7276.2 Cozette Ss Cozette Ss 7851.3 7877.5 7880.1 Corcoran Ss 8106.9 8117.9 Quartz Feldspar Lithic 45 SRF – Sedimentary rock fragments VRF – Volcanic V l i rock k ffragments t PRF – Plutonic rock fragments QM – Quartzose metamorphic MRF – Micaceous metamorphic 46 AAPG ACE Short Course 1: 06.06.2009 41 of 217 Webb: Lithofacies and Reservoir Quality Lithic Population, Barrett Last Dance 43C 0.0 5.0 10.0 15.0 20.0 25.0 Williams Fork Fm 3544.9 3555.4 3577.6 4004.3 4013.3 Top Gas 4363 ft 4393.6 4416.6 5715.4 6042.4 Cameo Coal zone 6337.1 Chert Shale Dolostone Volcanic 47 Lithic Population, MWX‐2 0 Williams Fork Fm 5 10 15 20 25 5734.1 5838.6 5852.3 6536.3 6542.2 6550.3 7085.5 7133.5 7264.5 7272.8 7276.2 Cozette Ss 7851.3 7877.5 7880.1 Corcoran Ss 8106.9 8117.9 Chert Shale Limestone Dolostone Volcanic 48 AAPG ACE Short Course 1: 06.06.2009 42 of 217 Webb: Lithofacies and Reservoir Quality Cement Distribution in the Mesaverde Group ¾ Pore--lining clay cements Pore z z ¾ Chlorite (common to abundant) Mixed--layer illite Mixed illite--smectite (sparse to moderate) Pore--filling cements Pore z z z z z z z Siderite (trace) Pyrite (trace to sparse) Non--ferroan calcite (sparse) Non Quartz overgrowth (trace to abundant) Ferroan calcite and ferroan dolomite (sparse to common) Albite (grain replacement and moldmold-filling) Kaolinite (sparse in one sample in Book Cliff outcrop) 49 Cement Types, Barrett Last Dance 43C 0 5 10 15 20 25 Williams Fork Fm 3544.9 3555.4 3577.6 4004.3 4013.3 Top Gas 4363 ft 4393.6 4416.6 5715.4 6042.4 Cameo Coal zone 6337.1 Quartz Og Fe Calcite Chlorite and ML/IS 50 AAPG ACE Short Course 1: 06.06.2009 43 of 217 Webb: Lithofacies and Reservoir Quality Cement Types, MWX‐2 0 5 10 15 20 25 30 35 Williams Fork Fm 5734.1 5838.6 5852.3 6536.3 6542.2 6550.3 7085.5 7133.5 7264.5 7272.8 7276.2 Cozette Ss 7851.3 7877.5 7880.1 Corcoran Ss 8106.9 8117.9 Quartz Og Fe Calcite Chlorite and ML/IS 51 Porosity Distribution in the Mesaverde Group ¾ Mesoporosity z z z ¾ Pore throat apertures <2 micron, > 0.5 micron radius Intergranular pores, primary and secondary Moldic pores (partly and completely dissolved feldspars, carbonate and volcanic rock fragments (large aspect ratio, pore body/pore throat) Microporosity z z z Pore throat apertures <0.5 micron, >0.1 micron radius P -lilining PorePore i and d porepore-filling filli clay l cementt Intragranular micropores (altered VRF, clay pellets, shale rock fragments, clay and carbonaceous matrix) 52 AAPG ACE Short Course 1: 06.06.2009 44 of 217 Webb: Lithofacies and Reservoir Quality Porosity Distribution in the Mesaverde Group ¾ Nanoporosity z z ¾ Pore throat apertures <0.1 micron radius Typical of mudstones, clayclay-sized intergranular, common in d t it l clay detrital l or carbonaceous b material t i l Fractures z z Macroscopic Microscopic (primarily crushed feldspars or chert, partings or separations at quartz overgrowth boundaries) 53 Interparticle and intercrystalline Mesoporosity AAPG ACE Short Course 1: 06.06.2009 Interparticle and intraparticle Microporosity 54 45 of 217 Webb: Lithofacies and Reservoir Quality Porosity Distribution, Barrett Last Dance 43C 0 5 10 15 20 25 Williams Fork Fm 3544.9 3555.4 3577.6 4004.3 4013.3 Top Gas 4363 ft 4393.6 4416.6 5715.4 6042.4 Cameo Coal zone 6337.1 BP sBP Mo clfBP 55 Porosity Distribution, MWX‐2 0 2 4 6 8 10 12 Williams Fork Fm 5734.1 5838.6 5852.3 6536.3 6542.2 6550.3 7085.5 7133.5 7264.5 7272.8 7276.2 Cozette Ss 7851.3 7877.5 7880.1 Corcoran Ss 8106.9 8117.9 BP sBP Mo clfBP 56 AAPG ACE Short Course 1: 06.06.2009 46 of 217 Webb: Lithofacies and Reservoir Quality 57 Porosity Networks in the Mesaverde Group ¾ Type z z z z Conventional porosity – Primary intergranular and modified intergranular (e.g. quartz overgrowth cement, secondary intergranular) Lacking clay cement Mesoporosity >> Microporosity Phi=high, K=high, low Swi, efficient drainage, low to moderate Pc entry pressure ¾ Type z z z z I II Intergranular and moldic – May include primary intergranular and secondary intergranular Trace to absent clay cement Mesoporosity >> Microporosity Phi=high, K=moderate , low to moderate Swi, elevated Srg,, moderate Pc entry pressure Srg AAPG ACE Short Course 1: 06.06.2009 58 47 of 217 Webb: Lithofacies and Reservoir Quality Porosity Networks in the Mesaverde Group ¾ Type z z z z Restricted intergranular – ClayClay-lined pores and pore throats, some moldic and clayclay-filled intergranular microporosity moderate to common clay cement Microporosity > Mesoporosity Phi=moderate, K=low, moderate to high Swi, elevated Srg,, increased Pc entry pressure Srg ¾ Type z z z z III IV Microintergranular – ClayClay-filled intergranular pores Moderate to common clay cement Microporosity >> Mesoporosity High Swi, Phi=moderate to low, K=low to extremely low, elevated Srg Srg,, increased Pc entry pressure 59 Porosity Networks in the Mesaverde Group ¾ Type z z z V Nanointergranular– Typical of mudstones, clayNanointergranular– clay-sized intergranular, common clay or carbonaceous material Microporosity only Phi=moderate to low, K=low to extremely low, high Swi, extremely high pore entry pressure 60 AAPG ACE Short Course 1: 06.06.2009 48 of 217 Webb: Lithofacies and Reservoir Quality Type I (shallow burial) Porosity consists of well connected primary and secondary intergranular mesopores, sparse moldic pores, quartz overgrowth cement. Quartz cement is sparse. 40X 100X Lack of pore-lining clay cement reduces Swi and improves relative permeability. USGS CB #1 Book Cliffs, 255.8’ Rock type 15567 Porosity 24.8% amb., Rhob2.64 g/cc Ka=137.62 mD Kins=112.2 mD 61 Type I (moderate burial) Porosity consists of moderately connected primary and secondary intergranular mesopores and traces of pore-lining chlorite clay containing microporosity microporosity. 40X Quartz cement and ferroan calcite are sparse. Lack of pore-lining clay cement reduces Swi and improves relative permeability. 100X Barrett Last Dance 43C, 3544.9’ Rock type 16277 Porosity 11.4% Rhob 2.65 g/cc Ka=0.8716 mD Kins=0.4287 mD 62 AAPG ACE Short Course 1: 06.06.2009 49 of 217 Webb: Lithofacies and Reservoir Quality Type II Porosity consists of poorly to moderately connected moldic and secondary intergranular mesopores with traces of pore-lining ML/IS(?) clay, containing microporosity. 40X Quartz cement is prominent, ferroan calcite is sparse. Pore-lining clay cement begins to increase Swi and reduce relative permeability. 100X Williams PA 424, 6148.8’ Rock type 15276 Porosity 9.9% Rhob 2.66 g/cc Ka=0.0237 mD Kins=0.0076 mD 63 Type III Porosity consists of clay-lined intergranular pores, pore throats are occluded by clay cement, causing elevated Swi, reduced relative permeability and i increased dP Pc entry t pressure. 40X Cements include chlorite or ML-IS clay, traces of nonferroan or ferroan calcite, traces of quartz overgrowths. Inhomogeneous packing and over sized intergranular pores over-sized indicate the development of secondary intergranular porosity. Williams PA 424, 4600.3’ Rock type 15297 Porosity 12.2% Rhob 2.65 g/cc Ka=0.0178 mD Kins=0.0019 mD 100X AAPG ACE Short Course 1: 06.06.2009 64 50 of 217 Webb: Lithofacies and Reservoir Quality Type III Porosity consists of clay-lined intergranular pores, pore throats are occluded by clay cement, which causes elevated Swi, reduced relative permeability and d iincreased dP Pc entry t pressure 400X Cements include chlorite or ML-IS clay, traces of nonferroan or ferroan calcite, traces of quartz overgrowths. Inhomogeneous packing and over-sized over sized intergranular pores indicate the development of secondary intergranular porosity. 400X, XP Williams PA 424, 4600.3’ .Rock type 15297 Porosity 12.2% Rhob 2.65 g/cc Ka=0.0178 mD Kins=0.0019 mD 65 Type IV Porosity consists almost entirely of sparse, poorly connected, clay-filled intergranular microporosity. Quartz cement is prominent prominent, ferroan calcite is sparse. 40X Pore-filling clay cement causes elevated Swi, reduced relative permeability and increased Pc entry pressure. Williams PA 424, 4686.4’ Rock type 15286 Porosity 7.9% Rhob 2.65 g/cc Ka=0.0211 mD Kins=0.0031 mD 100X AAPG ACE Short Course 1: 06.06.2009 66 51 of 217 Webb: Lithofacies and Reservoir Quality Type V Porosity consists entirely of sparse, poorly connected microporosity within interparticle voids of mudstone and shale matrix. 64X Cements include siderite, ferroan calcite and pyrite. Organic matter is locally common. Abundant clay causes highly elevated Swi, severely reduced permeability and elevated Pc entry pressure. p 160X CER MWX-2, 7085.5’ Rock type 11299 Porosity 2.4% Rhob 2.70 g/cc Ka=0.0020 mD Kins=0.00004 mD 67 P Permeability, ambient, in n mD Porosity types, Mesaverde, Piceance basin 100 10 Type I 1 Type II Type III Type IV 0.1 Type V 0.01 0.001 0 5 10 15 20 25 Porosity, ambient, in percent 68 AAPG ACE Short Course 1: 06.06.2009 52 of 217 Webb: Lithofacies and Reservoir Quality Pe ermeability, ambient, in m mD Porosity types, Mesaverde, Piceance basin 250 ‐ 3999 ft minimum burial 100 10 Type I 1 Type II Type III Type IV 0.1 Type V 0.01 0.001 0 5 10 15 20 25 Porosity, ambient, in percent 69 Pe ermeability, ambient, in m mD Porosity types, Mesaverde Group, Piceance basin 4,000 ‐ 6,999 ft minimum burial 100 10 Type I 1 Type II Type III Type IV 0.1 Type V 0.01 0.001 0 5 10 15 20 25 Porosity, ambient, in percent 70 AAPG ACE Short Course 1: 06.06.2009 53 of 217 Webb: Lithofacies and Reservoir Quality Pe ermeability, ambient, in m mD Porosity types, Mesaverde Group, Piceance basin 7,000 ‐ 10,000 ft minimum burial 100 10 Type I 1 Type II Type III Type IV 0.1 Type V 0.01 0.001 0 5 10 15 20 25 Porosity, ambient, in percent 71 Diagenetic alterations in the Mesaverde ¾ ¾ ¾ ¾ ¾ ¾ ¾ ¾ Compaction, ductile and brittle deformation Clay cements, primarily chlorite and MLML-IS Quartz overgrowths Nonferroan calcite Dissolution of calcite or other precursor cements Ferroan calcite and ferroan dolomite cements Replacement of KK-spar by ferroan calcite and albite formation of moldic porosity albite, Dissolution of carbonate rock fragments 72 AAPG ACE Short Course 1: 06.06.2009 54 of 217 Webb: Lithofacies and Reservoir Quality Brittle deformation of K-spar and Pore-lining clay cement – Chlorite, ferroan calcite pore fill Pore-filling chlorite cement with continued burial AAPG ACE Short Course 1: 06.06.2009 73 74 55 of 217 Webb: Lithofacies and Reservoir Quality Pore-lining clay cement – ML/IS Pore-lining clay cement – ML/IS AAPG ACE Short Course 1: 06.06.2009 75 76 56 of 217 Webb: Lithofacies and Reservoir Quality Pore-lining clay cement – ML/IS Inhomogeneous packing and relics of calcite cement indicate secondary intergranular porosity AAPG ACE Short Course 1: 06.06.2009 77 78 57 of 217 Webb: Lithofacies and Reservoir Quality Relic of calcite cement and adjacent secondary intergranular porosity Secondary intergranular pores mimic size and shape of neighboring cement-filled areas AAPG ACE Short Course 1: 06.06.2009 79 80 58 of 217 Webb: Lithofacies and Reservoir Quality Secondary porosity, created by dissolution of framework grains 81 Secondary porosity, created by dissolution of framework grains 82 AAPG ACE Short Course 1: 06.06.2009 59 of 217 Webb: Lithofacies and Reservoir Quality Secondary porosity, created by dissolution of carbonate framework grains Alteration of potassium feldspar AAPG ACE Short Course 1: 06.06.2009 83 84 60 of 217 Webb: Lithofacies and Reservoir Quality Alteration of potassium feldspar and VRF’s Alteration of potassium feldspar AAPG ACE Short Course 1: 06.06.2009 85 86 61 of 217 Webb: Lithofacies and Reservoir Quality Alteration of plagioclase feldspar Alteration of plagioclase feldspar AAPG ACE Short Course 1: 06.06.2009 87 88 62 of 217 Webb: Lithofacies and Reservoir Quality Alteration of volcanic rock fragments 89 Influence of depositional environment on detrital composition AAPG ACE Short Course 1: 06.06.2009 90 63 of 217 Webb: Lithofacies and Reservoir Quality Influence of depositional environment on detrital composition Influence of depositional environment on diagenesis AAPG ACE Short Course 1: 06.06.2009 91 92 64 of 217 Webb: Lithofacies and Reservoir Quality Pore-filling chlorite in a quartzose sandstone Pore-filling chlorite in a quartzose sandstone AAPG ACE Short Course 1: 06.06.2009 93 94 65 of 217 Webb: Lithofacies and Reservoir Quality Conclusions ¾ ¾ ¾ ¾ Rock typing is useful tool for lithofacies analysis and directing statistical sampling. Grain size and shale content are the primary influences on reservoir quality Compaction and cementation by clay (primarily chlorite and MLML-IS), quartz and ferroan calcite further reduce porosity and permeability Matrix porosity in the Mesaverde Group consists of both primary and secondary intergranular, moldic and clayclay-filled microporosity 95 Conclusions, continued ¾ ¾ ¾ Mesofractures, microfractures on the scale of individual grains grains, and overgrowth partings are also present Porosity type and distribution of clay cements help explain the variation of permeability for a given value of porosity Log g analysis y is complicated p by y the p presence of chlorite clay cement (more on that later…) 96 AAPG ACE Short Course 1: 06.06.2009 66 of 217 Webb: Lithofacies and Reservoir Quality Analysis of Critical Permeability, Capillary Pressure and Electrical Properties for Mesaverde Tight Gas Sandstones from Western U.S. Basins DOE Contract DE-FC26-05NT42660 http://www.kgs.ku.edu/mesaverde http://www.discovery-group.com 97 AAPG ACE Short Course 1: 06.06.2009 67 of 217 Byrnes: Porosity, Permeability, and Compressibility Analysis of Critical Permeability, Capillary and Electrical Properties for Mesaverde Tight Gas Sandstones f from W Western t U.S. US B Basins i http://www.kgs.ku.edu/mesaverde US DOE # DE-FC26-05NT42660 Core Analysis • Porosity & Grain Density – – – – • • – – – – – – – – Lithologic and other controls Routine helium In situ Pore Volume Compressibility p y Permeability – – – – – – Routine Air Klinkenberg Crack & Capillary Liquid In situ Effective & Relative • • • • • Gas oil Oil Gas-oil, Oil-water, water Gas Gas-water water Drainage, imbibition Steady-state, unsteady-state Single-phase stationary Parameters influencing kr – T, Poverburden, wettability, pore architecture, capillary number – Fluid Sensitivity Saturation & Capillary Pressure • Enhanced Oil Recovery – Chemical (polymer, surfactant, caustic) – Miscible (CO2, N2, Enriched Gas) – Thermal (Steam, Combustion) • Electrical & Acoustic Properties – Archie Electrical Properties • Cementation & Saturation Exponent, Cation Exchange – Vp & Vs • Rock Mechanics – – AAPG ACE Short Course 1: 06.06.2009 Routine Analysis (retort, Dean-Stark) Air-brine, oil-brine, air-mercury Drainage, imbibition Centrifuge, Porous-plate, Hg intrusion I t f i l Tension Interfacial T i Contact Angle Wettability Threshold Pressure Young’s Modulus, Poisson’s Ratio, Bulk Modulus Fracture Pressure 68 of 217 Byrnes: Porosity, Permeability, and Compressibility PVTXt • All petrophysical properties are physical-chemical in nature and dependent on: • P – Pressure – Confining/pore • V- Volume/Scale • T – Temperature • t – time/history (hysteresis) • X - Composition (broad definition) – Classification (sandstone, limestone, etc.) – Compositional (mineralogy) – Textural (sorting-grain size distribution, roundness, angularity) – Sedimentologic (bedding, heterogeneity, architecture) – Porosity/ pore size distribution – Fluid Always consider at what conditions a property was measured and over what range of conditions the measured property value is valid Porosity AAPG ACE Short Course 1: 06.06.2009 69 of 217 Byrnes: Porosity, Permeability, and Compressibility Core Analysis • – – – – – – • • Porosity Classification Lithologic & other controls Routine helium In situ Pore volume l compressibility ibili Wireline-log Analysis – – – – – – – – Permeability – – – – – – Routine Air Klinkenberg Crack & Capillary Liquid In situ Effective & Relative • • • • • Gas-oil, Oil-water, Gas-water Drainage, imbibition Steady-state, unsteady-state Single-phase stationary Parameters influencing kr – T, Poverburden, wettability, pore architecture, capillary number – Fluid Sensitivity Saturation & Capillary Pressure • Enhanced Oil Recovery – Chemical (polymer, surfactant, caustic) – Miscible (CO2, N2, Enriched Gas) – Thermal ((Steam,, Combustion)) • Electrical & Acoustic Properties – Archie Electrical Properties • Cementation & Saturation Exponent, Cation Exchange – Vp & Vs • Rock Mechanics – – AAPG ACE Short Course 1: 06.06.2009 Routine Analysis (retort, Dean-Stark) Air-brine, oil-brine, air-mercury Drainage, imbibition Centrifuge, Porous-plate, Hg intrusion Interfacial f i l Tension i Contact Angle Wettability Threshold Pressure Young’s Modulus, Poisson’s Ratio, Bulk Modulus Fracture Pressure 70 of 217 Byrnes: Porosity, Permeability, and Compressibility Porosity Types - Classifications Various Porosity Nomenclature – genesis, size distribution, flow contribution Intraparticle φ Vuggy φ Secondary φ Transparticle φ F t Fracture φ Nano <0.1 μm Micro 01.-0.5 μm Meso 0.5-2 μm Macro 2-10 μm Mega 10-100 μm Micro φ Ineffective φ Interparticle φ Primary φ Effective φ Porosity Definition Porosity, n. The ratio of void space to the bulk volume of rock containing that void space φ = Vp/(Vp+Vg) Isolated φ (minor) Connected φ micro φ φi=isolated φc=connected = φcmicro+φcmacro+φbound φcmacro= connected, d >0.5μm 0 φcmicro= connected, <0.5μm, not bound bound- φ = connected, bound to clay or water φ bound surface, water of hydration • Total φtotal = φc+φi= φcmacro+φcmicro+φbound+φi • Effective1 φeff = φc (excludes φi) • Effective2 φeff = φcmacroi+φmicro (exc φi, φbound) • Effective3 φeff = φcmacro+φi+φcmicro (exc φbound) • Effective4 φeff = φcmacro (exc φi,φcmicro,φbound) AAPG ACE Short Course 1: 06.06.2009 71 of 217 Byrnes: Porosity, Permeability, and Compressibility Packing & Sorting Control on Porosity (after Bear , 19 Porosity independent of size Highly dependent on sorting & packing Secondary Porosity - Transfer • Feldspar grain dissolution creates t secondary d porosity but removed material often reprecipitates in nearby pore space as kaolinite k li i or smectite AAPG ACE Short Course 1: 06.06.2009 72 of 217 Byrnes: Porosity, Permeability, and Compressibility Porosity Measurement • Core Analysis – Helium Boyle’s law - Dry sample, measure bulk volume, injected gas measures grain volume - measures φc, does not measure φi and may not measure some φbound – Crushed sample He pycnometer – dry crushed sample material is measured by Boyle’ss Law technique, Boyle technique measures φt – Liquid Resaturation – dry sample is weighed,saturated with liquid of know density and weighed saturated, weight difference measures φc, does not measure φi and may not measure some φbound – Summation of Fluids – two pieces of native core, one is weighed, crushed, retorted for oil&water content, and weighed; second has bulk volume measured and mercury injected into gas pore space, fluid saturations and porosity calculated for combined volumes – measures combination of φt and φc – Nuclear Magnetic Resonance – integrated NMR signal is measured on saturated t t d sample l – measures φt • Wireline Logs – – – – – Core Analysis Data Density (ρma- ρb)/ (ρma- ρliq) Sonic (Δt- Δtma)/(Δtfluid- Δtma) ResistivityF = a/φm NMR Core Analysis Data Neutron Helium Porosimeter Precision • Vg = (Vr +Vc) -P1g/P2gVr Properly performed error in grain volume measurement should be < +0.001 cc (after Ruth & Pohjoisrinne AAPG ACE Short Course 1: 06.06.2009 73 of 217 Byrnes: Porosity, Permeability, and Compressibility Porosity Error Interlaboratory Calibration • Dotson et al (1951) Avg φ Error = + 0.5 • Thomas and Pugh (1988) Maximum “acceptable” deviation = + 0.5; 0 5; 65% of labs in 1987 met that quality assurance criteria • Quality reviewed data in TGS +0.25 pu (Hunt & Luffel, 1988) Xmean std dev Xmean std dev Xmean std dev 1-inch diameter 1.5 -inch diameter Porosity (%) Porosity (%) Permeability Permeability to air, md Ambient Overburden to air, md Ambient Overburden Berea Sandstone Samples 248 19.0 18.5 261 18.7 18.2 24 0.5 0.4 22 0.4 0.1 Alundum Samples 111 18.9 18.6 120 19.1 19.2 24 0.8 0.6 22 0.8 0.4 Bedford Limestone Samples 3.2 14.0 13.8 3 13.8 13.7 0.9 0.6 0.5 0.7 0.7 0.7 Interlaboratory comparison - 25 labs (Sprunt et al , 1990) Routine Porosity Distribution Routine Porosity Histogram 0.18 Fraction of Popula ation 0.16 0.14 0.12 0.10 0.08 0.06 0.04 0.02 0.00 0-2 2-4 4-6 6-8 8-10 10-12 12-14 14-16 16-18 18-20 20-22 22-24 Routine Helium Porosity (%) AAPG ACE Short Course 1: 06.06.2009 74 of 217 Byrnes: Porosity, Permeability, and Compressibility Porosity Distribution by Basin Al l B asins Greater Green River Washakie Ui nta Pi ceance Wind River Powder River 0.45 Fraction of Popula ation 0.40 0.35 0 30 0.30 0.25 0.20 0.15 0.10 0.05 0.00 0-2 2-4 4-6 6-8 8-10 10-12 12-14 14-16 16-18 18-20 20-22 22-24 Routine Helium Porosity (%) • Distribution influenced by sampling – not normally distributed Porosity Statistics by Basin All Basins Mean ea Median St Dev Minimum Maximum Kurtosis Skewness Count 7.1 6.2 5.1 0.0 24.9 0.7 1.0 2209 AAPG ACE Short Course 1: 06.06.2009 Greater Green River 7.3 3 4.6 6.4 0.0 23.6 -0.4 1.0 568 Wind Powder Washakie Uinta Piceance River River 9.5 9 5 8.7 5.4 0.0 23.8 -0.4 0.5 395 6.1 6 5.9 4.2 0.0 22.2 1.1 0.9 539 6.1 6 6.1 3.8 0.0 24.9 4.5 1.4 596 5.8 5 8 5.5 3.3 0.0 13.2 -0.8 0.1 83 13.2 3 15.1 4.5 2.6 16.9 1.0 -1.5 28 75 of 217 Byrnes: Porosity, Permeability, and Compressibility Statistics of Paired Samples Porosity Histogram 1.0 0.45 0.40 0.9 0.8 0.35 0.30 0.7 0.6 0.25 0.5 0.20 0.15 0.4 0.3 0.10 0.05 0.2 0.1 0.00 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 Fraction of Popula ation 0.50 Paired Plugs Porosity Ratio • Histogram of ratio of paired plug porosities to mean porosity of plug pair. n = 652 x2= 1304 Grain Density Grain Density Histogram Fraction of Popullation 0.30 0.25 0.20 0.15 0.10 0.05 0.00 <2.56 2.562.58 2.582.60 2.602.62 2.622.64 2.64266 2.662.68 2.682.70 2.702.72 > 2.72 Grain Density (g/cc) • Mesaverde grain density is normally distributed for entire population (n=2200) AAPG ACE Short Course 1: 06.06.2009 76 of 217 Byrnes: Porosity, Permeability, and Compressibility Mesaverde Grain Density All Basins Mean Median St Dev D Minimum Maximum Kurtosis Skewness Count 2.653 2.654 0 040 0.040 2.30 2.84 15.1 -2.00 2184 Greater Green Washakie River 2.648 2.660 2.645 2.662 0 029 0.029 0 034 0.034 2.50 2.47 2.77 2.79 2.6 3.7 0.28 -0.18 566 393 Uinta Piceance Wind River Powder River 2.639 2.649 0 052 0.052 2.30 2.80 13.2 -2.82 532 2.660 2.661 0 038 0.038 2.35 2.84 14.0 -1.19 583 2.673 2.673 0 029 0.029 2.51 2.73 10.2 -1.87 82 2.679 2.674 0 026 0.026 2.60 2.75 3.9 -0.28 28 • Statistically meaningful differences exist among basins • Low density minerals: carbonaceous fragments (1.2-1.4 g/cc), K-feldspar (2.57 g/cc), Illite/smectite (2.60 g/cc) Grain Density by Basin Grain Density Histogram Fraction of Popullation 0.60 0.50 All Basins Greater Green River Washakie Uinta Piceance Wind River Powder River 0.40 0.30 0.20 0.10 0.00 <2.56 2.562.58 2.582.60 2.602.62 2.622.64 2.64266 2.662.68 2.682.70 2.702.72 > 2.72 Grain Density (g/cc) AAPG ACE Short Course 1: 06.06.2009 77 of 217 Byrnes: Porosity, Permeability, and Compressibility Generic Porosity vs Confining Pressure (after Byrnes, 1994) Crack Compressibility • Crack porosity is far more compressible than normal intergranular porosity • Walsh & Grosenbaugh (1979) developed a model for fracture compressibility ibili that h matches h ddata well ll and can be expressed, as shown by Ostersen for low-k sandstones, by a linear porosity change with logarithmic change in stress (after Walsh & Grosenba (after Ostensen, 1983) AAPG ACE Short Course 1: 06.06.2009 78 of 217 Byrnes: Porosity, Permeability, and Compressibility Stress-Dependence of Porosity Fraction of Iinitial Porrosity 1.0 0.9 0.8 0.7 0.6 0.5 0.4 10 100 1000 Net Confining Pressure (psi) 10000 • Crossplot of fraction of initial pore volume versus net confining stress for 113 Mesaverde samples. Every sample exhibits a log-linear relationship though slopes and intercepts differ. Pore Volume Compressibility σz σy σx Cformation = ΔVpore/Vpore Δp Stress field defined by σx, σy, σz Effective stress equation: σhydro = K1σz – K2Pinital + K3 (Pinitial-P) Cformation f ti = K3 Chydro h d (after Yale et al, 1993) AAPG ACE Short Course 1: 06.06.2009 K1 = (σx+σy+σz)/3σz; lithostatic stresses K2 = (1 (1-C Cb/Cgr); Biot α – effect of pore pressure K3 = K2 ((1+ν)/(3-3ν)); effect of pore pressure change, “uniaxial correction”; ν=Poisson’s ratio Rock Type Consolidated Sandstone Friable Sandstone Unconsolidated Sandston Carbonate K1 0.85 0.90 0.95 0.85 K2 0.80 0.90 0.95 0.85 K3 0.45 0.60 0.75 0.55 79 of 217 Byrnes: Porosity, Permeability, and Compressibility Type Compressibility Curves Unconsolidated Friable Consolidated -0.00002805 0.0001054 -0.00002399 300 500 300 0.1395 -0.225 0.0623 0.0001183 -0.00001103 0.00004308 Pore Volum me Compressibility (psi/10^6) A B C D Cf = A(σ-B)C + D σ=K1Pover-K2Pi+K3(Pi-P) 60 50 Unconsolidated Friable Consolidated 40 30 20 10 0 0 2,000 4,000 6,000 8,000 10,000 Effective Lab Stress (psi) (after Yale et al, 1993) Rellative Pore Volume Chan nge Slope ( 1/psi) Pore Volume Compressibility 0.00 -0.05 -0.10 -0.15 -0.20 -0.25 -0.30 0 2 4 6 8 10 12 14 16 18 20 22 24 Routine Helium Porosity (%) • Crossplot of slope of log-linear curves in Figure 4.1.6 with porosity. • The relationship between the slope and porosity can be expressed: • Slope = -0.00549 -0.155/φ0.5 AAPG ACE Short Course 1: 06.06.2009 80 of 217 Byrnes: Porosity, Permeability, and Compressibility Pore Volume Compressibility Relative Pore Volume C Change Intercept (1/psii) 1.35 1.30 1.25 1.20 1.15 1.10 1.05 1.00 0 2 4 6 8 10 12 14 16 18 20 22 24 Routine Helium Porosity (%) • Crossplot of intercept of log-linear curves in Figure 4.1.6 with porosity. The relationship between the intercept and porosity can be expressed: • Intercept = 0.013 φ + 1.08 Pore Volume Compressibility • The above equations result in a power-law relationshipp between ppore volume compressibility and net effective confining pressure of a form: log10 β = C log10 Pe + D • The slope and intercept of the pore volume compressibility relations can be predicted using: C = -1.035 + 0.106/φ0.5 D = 4.857 φ-0.038 AAPG ACE Short Course 1: 06.06.2009 81 of 217 log Pore Volum e Compressibility Pressure Intercept log Pore Volume C Compressibility Pressure Sl ope (1/psi) Byrnes: Porosity, Permeability, and Compressibility -0.95 -0.96 -0.97 -0.98 -0.99 -1.00 -1.01 -1.02 0 5 10 15 20 25 4.80 4.75 4.70 4.65 4.60 4.55 4.50 4.45 4.40 4.35 4.30 4.25 0 Routine Porosity (%) 5 10 15 20 25 Routine Porosity (%) log10 β = C log10 Pe + D • Where: C = -1.035 + 0.106/φ0.5 D = 4.857 φ-0.038 Porre Volume Compressibility y (10^6/psi) Pore Volume Compressibility 1000 100 10 1 100 φ = 21% φ = 18% φ = 15% φ = 12% φ = 8% φ = 6% φ = 4% φ = 2% 1000 Net Effective Confining Stress (psi) 10000 β =10^[(-1.035+0.106/φ0.5)*log10 Pe+(4.857φ-0.038)] AAPG ACE Short Course 1: 06.06.2009 82 of 217 Byrnes: Porosity, Permeability, and Compressibility In situ vs. Routine Porosity • φi/φo = A logPe + B φi/φo Slope = A = -0.00549 – 0.155/φ0.5 φi/φo Intercept = B = 1.045 + 0.128/φ Where: φi = porosity at defined effective in situ stress Pe, φo = reference initial porosity Pe = effective confining stress A and B are empirical constants that vary with rock properties i Porosity at Pe = 4,0 000 psi (%) In situ vs. Routine Porosity 24 22 20 18 16 14 12 10 8 6 4 2 0 Mesaverde Study T ravis Peak Mesaverde/Frontier Clinton/Medina Linear (Mesaverde Study) 0 2 4 6 8 10 12 14 16 18 20 22 24 Routine Porosity (%) All Studies: Mesaverde Study: φi = A φroutine + B φi = 0.96 φroutine – 0.73 Travis Peak: Mesavrd/Frontier Clinton/Medina: φi = 0.95 φroutine – 0.3 φi = 0.998 φroutine – 0.8 φi = 0.966 φroutine + 0.02 AAPG ACE Short Course 1: 06.06.2009 A> B> Routine Porosity 2.0 24.0 Travis Mesaverde/ Clinton/ Mesaverde Medina Study Peak Frontier 0.950 0.998 0.966 0.960 -0.300 -0.800 0.020 -0.734 In situ Porosity (%) 1.6 1.2 2.0 1.2 22.5 23.2 23.2 22.3 83 of 217 Byrnes: Porosity, Permeability, and Compressibility Porosity from Wireline Logs e s y • Density • Neutron • Sonic • NMR Permeability AAPG ACE Short Course 1: 06.06.2009 84 of 217 Byrnes: Porosity, Permeability, and Compressibility Core Analysis • Porosity & Grain Density – – – – • • Permeability – – – – – – Routine Air Klinkenberg Crack & Capillary Liquid In situ Effective & Relative • • • • • Gas-oil, Oil-water, Gas-water Drainage, imbibition Steady-state, unsteady-state Single-phase stationary Parameters influencing kr – T, Poverburden, wettability, pore architecture, capillary number – Fluid Sensitivity Saturation & Capillary Pressure – – – – – – – – Lithologic & other controls Routine helium In situ Pore volume compressibility • Routine Analysis (retort, Dean-Stark) Air-brine, oil-brine, air-mercury Drainage, imbibition Centrifuge, Porous-plate, Hg intrusion Interfacial f i l Tension i Contact Angle Wettability Threshold Pressure Enhanced Oil Recovery – Chemical (polymer, surfactant, caustic) – Miscible (CO2, N2, Enriched Gas) – Thermal (Steam, Combustion) • Electrical & Acoustic Properties – Archie Electrical Properties • Cementation & Saturation Exponent, Cation Exchange – Vp & Vs • Rock Mechanics – – Young’s Modulus, Poisson’s Ratio, Bulk Modulus Fracture Pressure Original Darcy Flow Measurement Q = k A dP µ dh Analogs in Electric and heat flow i= 1 A dV d dx dQ = KH A dT dx AAPG ACE Short Course 1: 06.06.2009 85 of 217 Byrnes: Porosity, Permeability, and Compressibility Evolution of Permeability Modeling k=fr2/8 K=Φ/(FsAs2) x (L/La)2 (after Dullien, 1992) (after CoreLab, 1978) Current Permeability Modeling • Permeability controlled by: y – – – – – pore body size pore throat size distribution connectivity larger-scale architecture AAPG ACE Short Course 1: 06.06.2009 86 of 217 Byrnes: Porosity, Permeability, and Compressibility Comparison of Sandstone Pore Volume Distribution Measured by Hg Porosimetry and Photomicroscopy (after Dullien & Dhawan, 1974) Liquid Permeability Q = k A dP µ dL (liquid) Q = Volumetric Flow rate (cc/sec) K = Permeability (Darcies) A = Cross-sectional area (cm2) dP = Pressure differential (atm) m = fluid viscosity (centipoise) dL = Length (cm) Q = k A (P12-P22) µ 2PbzdL (gas) AAPG ACE Short Course 1: 06.06.2009 (after CoreLab, 1978) 87 of 217 Byrnes: Porosity, Permeability, and Compressibility Permeability Definitions • Absolute Permeability (k) – Permeability of rock 100% saturated with fluid of interest • Effective Permeability (keg, keo, kew) – Permeability to fluid of interest when other fluids are also present in pore space • Relative Permeability (krg, kro, krw) – ke/k, Ratio of effective to absolute permeability (reference for absolute may be effective at some condition, e.g. keo,Sw/keo,Swi) • In situ – under reservoir conditions • Klinkenberg – Corrected for low pressure gas slippage effects • Air – Permeabilityy to air uncorrected for Klinkenbergg effect • Routine – Air permeability, generally measured with a confining stress of less than ~500 psi Permeability Determination • Full-diameter – Influenced by microfractures – Averages response of individual beds – Possible drilling mud invasion – Less biased • Plug – Precisely accurate – Possible sampling bias – May ay miss ss important po ta t beds • Drilled Sidewall – Greater sampling uncertainty – Similar to plug AAPG ACE Short Course 1: 06.06.2009 • Probe mini-permeability – Fast – Allows high sampling densityy – Accurate for k > 1md • Chip – Low accuracy – Severe sampling bias • Percussion Sidewall – Shattered – Under- and over-estimates properties • Cuttings – Rarely used – Surface-to volume issues – Sever sampling bias 88 of 217 Byrnes: Porosity, Permeability, and Compressibility Klinkenberg Gas Slip kgas = kliq (1+4cl/r) = kliq (1+b/P) Gas measurable fluid velocity at wall Where; Liquid c = proportionality factor ~ 1 l = mean free path at P r = radius of capillary b = proportionality constant =f(r,l,kliq) ( ) P = ppressure (atm) Since b is a function of pore radius, mean free path at P, and liquid permeability it can vary from one low k sample to another but values are generally consistent with the Heid et al (1950) graph shown Klinkenberg b factor (psi) Zero fluid velocity at wall 100 Heid et al, 1950 Jones & Owens, 1981 - low k 10 b = 0.777 kliq0.39 1 0.1 b = 0.867 kliq-0.33 0.01 1E-04 0.001 0.01 0.1 1 10 100 1000 Klinkenberg Permeability (md) (after Heid et al, 1950) Klink kenberg b factor (psi) General Correlation of Klinkenberg b Factor and Permeability 100 Heid et al, 1950 Jones & O w ens , 1981 - low k 10 b = 0.777 kliq-0.39 1 0 .1 0.33 b = 0.867 0 867 kliq-0.33 0 .0 1 1 E -0 4 0 .0 0 1 0 .0 1 0 .1 1 10 100 1000 K linkenberg P erm eability (m d) AAPG ACE Short Course 1: 06.06.2009 89 of 217 Byrnes: Porosity, Permeability, and Compressibility Correlation between Gas Slip-factor, b, and Permeability (after Sampath & Keighin, 1982) In situ Klinkenberg Permeability Klinkenberg b factor (atm) 1000 100 10 1 0.1 1E-08 1E-07 1E-06 1E-05 0.0001 0.001 0.01 0.1 1 10 100 1000 In situ Klinkenberg Permeability (mD) kgas = kliquid (1 + 4 4cL/r) L/ ) = kliquid (1+b/P) Gas kgas = gas permeability at pore pressure kliquid is liquid permeability and = Klinkenberg permeability kklink Liquid c = proportionality constant (~ 1) L = mean free path of gas molecule at pore pressure b = 0.851 kik-0.34 (Present Study) r = pore radius b = proportionality constant (=f(c, L, r)) b = 0.867 kliq-0.33 (Jones & Owens) P = pore pressure (atm) b = 0.777 kliq-0.39 (Heid) AAPG ACE Short Course 1: 06.06.2009 90 of 217 Byrnes: Porosity, Permeability, and Compressibility Measured Insitu Klinkenberg vs Air Permeability In situ u Klinkenberg Perm meability (md) 100 Sandstone 10 Carbonate 1 0.1 0.01 kik =0.685kia 2 R = 0.98 0.001 0.0001 0.0001 1.12 0.001 0.01 0.1 1 10 In situ Air Permeability (md) 100 (after Byrnes, 2003) Comparison of Klinkenberg Prediction Models 1 Klinkenberg Permeability (m md) Byrnes, 2003 Jones & Owens, 1981 0.1 0.01 kklink = 0.685 kair1.12 0.001 0.0001 0.00001 0.00001 0.0001 0.001 0.01 0.1 1 Air Permeability (md) J&O (1980): kklink = 10^(-0.0398 logkair2+1.067logkair-0.0825) valid for upstream pressure = 100 psi AAPG ACE Short Course 1: 06.06.2009 91 of 217 Byrnes: Porosity, Permeability, and Compressibility Effect of Partial Water Saturation on Gas Slip (after Sampath & Keighin, 1982) “Averaging” Permeability Data • Permeability is a vector • Pseudo-Permeability is direction dependent • Pseudo-Permeability “averaging” is a function of flow model (3-D arrangement) assumed – Dependent on geomodel and assumptions of smaller scale permeability distribution AAPG ACE Short Course 1: 06.06.2009 • End-member models – – – – Series Flow Parallel Flow Random Flow Vertical flow constraint • Permeability is frequently scale dependent 92 of 217 Byrnes: Porosity, Permeability, and Compressibility Typical distributions of Porosity and Permeability Permeability Architecture End Members Series Flow No vertical cross-flow Vertical crossflow kv=0, kv=Ckh Parallel Flow AAPG ACE Short Course 1: 06.06.2009 Heterogeneous Flow 93 of 217 Byrnes: Porosity, Permeability, and Compressibility • In parallel flow the high perm drives the system • In series flow the low perm drives the system • Cross-flow influences parallel flow in closed systems (see Simulation Section) 0.01 md 100 md 100 ft Karith = 1.010 md Kgeom = 0.011 md 100 md 1 ft Karith = 99.000 md Kgeom = 91.201 md 0.01 md 0.01 md 100 md 100 md 0.01 md 100 md 0.01 md 100 md Kharm = 0.010 md Kgeom = 0.011 md 0.01 md Flow Kharm = 0.990 md Kgeom = 91.201 md Core Plug Sampling with Bedding C - Suitable C Bedding Planes AAPG ACE Short Course 1: 06.06.2009 A - Unsuitable B – Possibly suitable 94 of 217 Byrnes: Porosity, Permeability, and Compressibility Model of Measured vs Composite Permeability for Layered Samples Permeability-Porosity Equation : k = 3.65 x 10-5 e(0.68 Φ) Fraction of Upper Layer Thickness to Total hickness = 0.3 Upper Base Porosity Upper Base Average Permeability Measured Ratio Layer Layer Difference Layer Layer Porosity for Average Permeability Measured/ Porosity Porosity Permeability Permeability Porosity Composite (%) (%) (%) (md) (md) (%) (md) (md) Permeability 0 14 14 0.0000365 0.497 9.8 0.0286 0.348 12.2 2 14 12 0.000142 0.497 10.4 0.0430 0.348 8.1 4 14 10 0.000554 0.497 11.0 0.0646 0.348 5.4 6 14 8 0.00216 0.497 11.6 0.0972 0.349 3.6 8 14 6 0.00841 0.497 12.2 0.146 0.350 2.4 10 14 4 0.0327 0.497 12.8 0.220 0.358 1.6 12 14 2 0.128 0.497 13.4 0.331 0.386 1.2 14 14 0 0.497 0.497 14.0 0.497 0.497 1.0 16 14 -2 1.94 0.497 14.6 0.747 0.929 1.2 18 14 -4 7.54 0.497 15.2 1.124 2.61 2.3 20 14 -6 29.4 0.497 15.8 1.690 9.16 5.4 21 14 -7 58.0 0.497 16.1 2.072 17.7 8.6 22 14 -8 114 0.497 16.4 2.541 34.7 13.6 23 14 -9 226 0.497 16.7 3.116 68.1 21.9 24 14 -10 446 0.497 17.0 3.821 134.1 35.1 Parallel Beds and Sampling 1 Measured or Calc culated Permeability (md) 40 Measured Permeability - Kmeas Calculated Permeability - Kcalc 35 Ratio Kmeas/Kcalc Upper Bed Porosity 10 30 25 1 20 15 0.1 10 5 40 Measured Permeability - Kmeas Calculated Permeability - Kcalc Ratio Kmeas/Kcalc Upper Bed Porosity 35 30 25 20 0.1 15 0.01 10 5 0.001 Ratio Kmeas/Kcalc & Up pper Bed Porosity (%) Measured or Calculate ed Permeability (md) 10 100 0.01 Ratio Kmeas/Kcalc & Upper Bed Porosity (%) • When sample contains parallel beds of different k the measured k at the average porosity is always greater than the k calculated for the composite of the individual beds 0 9 10 11 12 13 14 15 16 17 Average Porosity (%) 0 7 8 9 10 11 12 13 Average Porosity (%) AAPG ACE Short Course 1: 06.06.2009 95 of 217 Byrnes: Porosity, Permeability, and Compressibility General Lithologic Controls on the Effect of Overburden Pressure on Permeability Effect of Confining Pressure on Permeablity • Early work by Thomas and Ward (1972) Shows the characteristic decrease in permeability with increasing confining pressure exhibited by low-permeability sandstones Samples from Gas buggy well, Pictured Cliffs Fm Rio Arriba Co., NM and Wagon Wheel well, Ft. Union Fm, Sublette Co., WY 1.0 Fraction of Initial Permeabiility • 0.9 0.8 0.7 0.6 0.5 0.4 0.3 02 0.2 0.1 0.0 0 1000 2000 3000 4000 5000 6000 Confining Pressure (psi) AAPG ACE Short Course 1: 06.06.2009 96 of 217 Byrnes: Porosity, Permeability, and Compressibility Effect of Confining Pressure on Spirit River and Cotton Valley Permeability (after Walls, 1982) Permeability Response to Confining Stress for Varying Crack Aspect Ratios (after Brower & Morrow, 1983) k/ki = {1-(16(1-n2)cLc)/(9(1-2n)pwi)s}3 AAPG ACE Short Course 1: 06.06.2009 97 of 217 Byrnes: Porosity, Permeability, and Compressibility Models of Stress Dependent Permeability Model Type Noncrack Noncrack Crack Crack Asperity Asperity Asperity Model Capillary tube Gangi, grain, 1978 Jones &Owens, 1980 Brower & Morrow, 1983 Gangi, bed of nails, 1978 Walsh, exp. dist., 1981 Ostensen, Gauss.,1983 Mesaverde & Frontier (after Ostensen, 1983) Equation . k/ki = (1-2s/E)4 k/ki = {1-2{3p(1-n2)s/4E}2/3}4 k/ki = {1-Slog(Pk/1000)}3 k/ki = {1-(16(1-n2)cLc)/(9(1-2n)pwi)s}3 k/ki = {1-(s/lE)e}3 k = Ls3/12 {ln[(nE(prcs3)1/2)/(2(1-n2)s)]}3 k = 0.76Ls3/12 {ln[(2.48E(s/rc)1/2)/(3p1.5(1-n2)s)]}2 Council Grove Limestones (after Byrnes et al, 2001) (after Jones &* Owens, 1980) Sheet-like Pores in Travis Peak Sandstone Transmitted light, 100X Fluorescent epoxy 8,275 ft, k = 0.007 md; SFE Well 2, Waskom Field, Harrison Co., TX AAPG ACE Short Course 1: 06.06.2009 (after Soeder & Chowdiah, 1990) 98 of 217 Byrnes: Porosity, Permeability, and Compressibility Pore e Size Freque ency (%) Pressure and Pore Throats 25 High P 20 Low P 15 10 5 0 0.01 0.1 1 Pore Throat Diameter (um) In situ vs Routine Permeability In situ K Klinkenberg Perme eability (md) 100 10 Council Grove Mesaverde/Frontier 1 0.1 0.01 logkik = 0.0588 (logkair)3 –0.187 (logkair)2 +1.154 logkair - 0.159 0 001 0.001 0.0001 0.00001 0.001 AAPG ACE Short Course 1: 06.06.2009 0.01 0.1 1 10 Routine Air Permeability (md) 100 99 of 217 Byrnes: Porosity, Permeability, and Compressibility log g In situ Klinkenberg Permeability (mD) Stress dependence of permeability 3 y = -0.0088x3 - 0.0716x2 + 1.3661x - 0.4574 2 R2 = 0.9262 1 0 -1 -2 -3 -4 -5 -6 -7 -7 -6 -5 -4 -3 -2 -1 0 1 2 3 log Routine Air Permeability Ppore = 100 psi (mD) Known for many years that lowlow-K sandstones are stress sensitive Generalized = f (Ppore, Lith) 1997 Byrnes equation: kik = 10^[1.34 (logkair) - 0.6] This study: kik = 10^[0.0088 (logkair)3 - 0.072 (logkair)2+ 1.37 logkair +0.46] Statistically similar except for k > 1 mD no meaningful stress dependence over 10 mD Permeablity Distribution Fraction of Pop pulation 0.35 0.30 0.25 0.20 0.15 0.10 0.05 100-1 1000 10--100 1-10 1 0.1-1 0 0.01 1-0.1 0.001-0 0.01 0.00 0010.0 001 0.000 0010.00 001 0.0000 0010.000 001 0.00000 0010.0000 001 0.00 In situ Klinkenberg Permeability (mD) Distribution of in situ Klinkenberg permeability measured at 26.7 MPa (4,000 psi) net effective stress for all samples AAPG ACE Short Course 1: 06.06.2009 100 of 217 Byrnes: Porosity, Permeability, and Compressibility In situ Klinkenberg Permeability Histogram Fraction of Pop pulation 0.60 All Basins Greater Green River Washakie Uinta Piceance Wind River Powder River 0.50 0 40 0.40 0.30 0.20 0.10 100--1000 10 0-100 1-10 0.1-1 0.0 01-0.1 0.001-0.01 0.0 00010.001 0 0.00 00010.0 0001 0.000 00010.00 0001 0.0000 00010.000 0001 0.00 In situ Klinkenberg Permeability (mD) Distribution of in situ Klinkenberg permeability measured at 26.7 MPa (4,000 psi) net effective stress by basin Permeability Statistics All Basins Greater Green Washakie Uinta River Mean logk -2.60 -2.49 -2.03 -2.66 Median logk -2.93 -3.15 -2.46 -2.86 St Dev log 1.58 1.94 1.78 1.36 Minimum logk -6.19 -6.19 -5.66 -5.33 Maximum logk 2.31 2.31 2.08 1.88 Kurtosis 0.62 -0.54 -0.39 0.17 Skewness 1.05 0.79 0.76 0.74 Count 2143 555 373 529 Mean 0.0025 0.0032 0.0094 0.0022 Median 0.0012 0.0007 0.0035 0.0014 St Dev 37.9 87.4 59.9 23.0 Minimum 0.000001 0.000001 0.000002 0.000005 a u 206.0 06 0 206.0 06 0 121.0 0 76.2 6 Maximum Kurtosis 0.62 -0.54 -0.39 0.17 Skewness 1.05 0.79 0.76 0.74 Count 2143 555 373 529 AAPG ACE Short Course 1: 06.06.2009 Piceance Wind River Powder River -2.95 -3.44 -1.88 -3.03 -3.36 -2.21 1.13 0.69 1.39 -5.23 -5.11 -4.29 2.05 -1.98 0.55 4.02 -0.49 -0.38 1.48 -0.01 0.50 577 81 28 0.0011 0.0004 0.0133 0.0009 0.0004 0.0062 13.4 4.9 24.5 0.000006 0.000008 0.000051 112.2 0.010 0 0 0 3.53 3 53 4.02 -0.49 -0.38 1.48 -0.01 0.50 577 81 28 101 of 217 Byrnes: Porosity, Permeability, and Compressibility Permeability Histogram 1.0 0.18 0.9 0.16 0.8 0 14 0.14 07 0.7 0.12 0.6 0.10 0.5 0.08 0.4 0.06 0.3 0.04 0.02 0.2 0.1 0 00 0.00 00 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 3.0 4.0 5.0 >6 Fraction of Popu lation 0.20 Paired Plugs Permeability Ratio • Histogram of ratio of paired plug in situ Klinkenberg permeabilities to mean permeability of plug pair. n = 634 x2 = 1268 Permeability vs Porosity • Permeability a function of: Grain size Shale bed architecture Pore-throat size Porosity g alteration ((includingg cementation)) Diagenetic • Porosity is optimal predictor parametric with lithofacies AAPG ACE Short Course 1: 06.06.2009 102 of 217 Byrnes: Porosity, Permeability, and Compressibility Permeability as a Function of Grain Size and Sorting (after Jonas & McBride, 1977) Influence of Grain Size on Permeability (from Shanley, 2004) AAPG ACE Short Course 1: 06.06.2009 103 of 217 Byrnes: Porosity, Permeability, and Compressibility Permeability vs. Porosity by Grain Size Klinkenberg Permeability (4,000 psi, mD) K 1000 100 10 1 0.1 0.01 0.001 0.0001 X(4-9)XXX 0.00001 X3XXX 0.000001 X(0-2)XXX 0.0000001 0 2 4 6 8 10 12 14 16 18 20 22 24 In situ calc Porosity (%) • Generally subparallel trends increasing in porosity range and permeability at porosity with increasing grain size • Influence of other variables significant Dispersed Clay Types in Sandstones Affecting Flow Discrete Particle Kaolinite Pore-Lining Chlorite Montmorillonite Pore-Bridging Illite Mixed-Layer (after Neasham, 1977) AAPG ACE Short Course 1: 06.06.2009 104 of 217 Byrnes: Porosity, Permeability, and Compressibility Influence of Clay types on Permeability Discrete-particle, porelining and porebridging Kaolinite, Chlorite, and Illite can each result in permeability decrease by a factor of 1-0.03, 0.2-0.01, and 0.06-0.003, respectively (after Wilson, 1981) Discrete Particles-Pore Lining Kaolinite American Hunter Old Road 8360’ AAPG ACE Short Course 1: 06.06.2009 (courtesy John Webb) 105 of 217 Byrnes: Porosity, Permeability, and Compressibility Pore Lining Clays Mixed-Layer Illite-Smectite Chlorite American Hunter Old Road 5490 ft (courtesy John Webb) Illite - Pore Bridging AAPG ACE Short Course 1: 06.06.2009 106 of 217 Byrnes: Porosity, Permeability, and Compressibility Permeability vs Porosity • Generalized trend kik = 10[0.3φi-4.75] with 10X error • Different k-φ trends among basins due to lithologic variation • Beyond common k↑ with grain size↑, lithologic influence changes with porosity nonlinear Klinkenberg Perrmeability (4,000 psi, mD) 1000 100 10 1 0.1 Green River Piceance Powder River Uintah Washakie Wind River logK=0.3Phi-3.7 logK=0.3Phi-5.7 0.01 0.001 0.0001 0.00001 0.000001 0.0000001 0 2 4 6 8 10 12 14 16 18 20 22 24 In situ calc Porosity (%) 1000 • logkik = 0.282φi + 0.182RC25.13 (+4.5X MLRA) • logkik = 0.034φi2-0.00109φi3 + 0.0032RC2 - 4.13 ((+4.1X MNLRA)) • Artificial Neural Network +3.3X 100 10 X9XXX X8XXX X7XXX X6XXX X5XXX X4XXX X3XXX X2XXX X1XXX 1 0.1 0.01 0.001 0.0001 0.00001 0.000001 1000 0.0000001 0 2 4 6 8 10 12 14 16 18 20 22 24 In situ calc Porosity (%) in situ Klinkenberg Permeab bility (mD) 1000 100 10 1 Predicted in situ Klinkenberg Permeability (mD) Klinkenberg Permeability (4,000 psi, mD) Permeability vs Porosity 100 10 1 0.1 0.01 0.001 0.0001 0.00001 0.00001 0.1 0.0001 0.001 0.01 0.1 1 10 100 1000 Measured in situ Klinkenberg Permeability (mD) 0.01 1XX9X 1XX8X 1XX7X 1XX6X 1XX5X 1XX4X 1XX3X 1XX2X 1XX1X 1XX0X 0.001 0.0001 0.00001 0.000001 0.0000001 0 2 4 6 8 10 12 14 16 18 20 22 24 hidden layer: 1 Hidden layer nodes: 10 Mean> 8.239 4.280 6.294 hidden layerStd Dev> 5.260 1.335 2.527 to-output Input-to-hidden layer weights weights Node Constant Phii RC2 RC4 Constant -0.388 1 -0.760 2.946 -2.027 -6.438 -0.885 2 -2.155 4.637 1.279 0.895 2.323 3 -4.999 7.901 0.957 3.167 -2.583 4 -1.484 -0.307 -1.695 6.175 -0.154 5 -4.597 4.582 1.568 0.730 4.022 6 -2.609 0.320 -2.201 -2.257 -2.495 7 -1.765 -1.843 -1.122 0.145 -3.859 8 2.839 -3.146 -9.237 0.264 0.789 9 -1.566 1.029 -1.588 -3.390 2.400 10 2.951 0.778 3.316 0.179 -2.136 Calculated in situ Porosity (%) AAPG ACE Short Course 1: 06.06.2009 107 of 217 Byrnes: Porosity, Permeability, and Compressibility Permeability vs Porosity • • • Overall trend allows prediction of Kik from porosity with 10X error Multivariate linear equations using: 1) porosity, 2) rock class (1 (1--3), and for each of three porosity classes separately (0(0-12%, 1212-18%, >18%), performed separately for each basin, exhibit an average standard error of prediction of: 00-12%: 3.6+ 3.6+2.4X; 12 12--18%: 3.3+ 3.3 +3.6X; >18%: 3.1X (for all basins undifferentiated for this high porosity class); where the range of error for each standard error of prediction indicates the range of standard error among basins Beyond common k↑ k↑ with grain size↑, lithologic influence changes are complex and nonlinear Klinkenberg Permeab bility (4,000 psi, mD) 1000 100 10 1 0.1 Green River Piceance Powder River Uintah Washakie Wind River logK=0.3Phi-3.7 logK=0.3Phi-5.7 0 01 0.01 0.001 0.0001 0.00001 0.000001 0.0000001 0 2 4 6 8 10 12 14 16 18 20 22 24 In situ calc Porosity (%) Berea Cotton Valley Chacra Cleveland Wilcox Travis Peak (from Dutton et al, 1993) AAPG ACE Short Course 1: 06.06.2009 Canyon Frontier-Moxa Comparison of Tight Gas Sand k-f Trends 108 of 217 Byrnes: Porosity, Permeability, and Compressibility Generalized Tight Gas Sandstone Permeability vs Porosity Trends In situ Permeability (md) 100 logki = 0.32+0.10 Φi - 5.05+1.48 10 1 0.1 Berea Cotton Valley Canyon Frontier-Moxa Arch Wilcox Chacra Cleveland Travis Peak Mesaverde-GGRB Medina Mesaverde-Uinta 0.01 0.001 0.0001 0 5 10 15 20 25 In situ Porosity (%) Data from various sources including Dutton et al, 1993; Byrnes, 2003; Castle and Byrnes, 2005) Stressed Permeability Hysteresis • Loading cycles approach similar values near original reservoir stress • Successive loading cycles cease to exhibit further hysteresis after second loading cycle (after Thomas & Ward, 1968) AAPG ACE Short Course 1: 06.06.2009 (after Warpinski & Teufel, 1990) 109 of 217 Byrnes: Porosity, Permeability, and Compressibility Calculating Directional Permeability in Festoon Cross-Bed Sets (after Weber, 1982) Shale Bed Continuity Distribution in Sandstone p Environments Depositional (after Weber, 1980) AAPG ACE Short Course 1: 06.06.2009 110 of 217 Byrnes: Porosity, Permeability, and Compressibility Conclusions • Grain density, porosity, and permeability measured on ~1500 unique samples and 700 duplicates (5X original proposal) • Core plugs obtained from 44 wells representing approximately 7,000 feet of described core • Average grain density for 2200 samples is 2.654+0.033 g/cc (±1sd) – but grain density distributions differ slightly among basins & lithofacies.. lithofacies • Porosity variance with 11--2 inches (2.5 (2.5--5 cm) = +10% (1sd) • Pore volume compressibility shows a loglog-linear relationship characteristic of sheet like pores and cracks log10 β = C log10 Pe + D where C = -1.035 + 0.106/φ 0.5 D = 4.857 φ-0.038 • Lower porosity rocks exhibit greater pore volume compressibility than high porosity rocks consistent with observed φi vs φroutine trends Conclusions • Klinkenberg slip term “b” consistent with prior trends to 1 μD • Geometric mean permeability = 0.0025 mD, mD, median = 0.0012 mD • Stress dependence of permeability is consistent with prior work ((Byrnes, y 1997)) • PorosityPorosity-permeability data exhibit two subtrends with permeability prediction approaching 5X within each – Adding rock types or using an ANN model improves perm prediction to 3.3X – 4X • Multivariate linear equations using: 1) porosity, 2) rock class (1 (1-3), and for each of three porosity classes separately (0(0-12%, 12 12-18%, >18%), performed separately for each basin, exhibit an average standard error of prediction of: 00-12%: 3.6 3.6+ +2.4X; 121218%: 3.3+ 3.3+3.6X; >18%: 3.1X (for all basins undifferentiated for this high porosity class); where the range of error for each standard error of prediction indicates the range of standard error among basins AAPG ACE Short Course 1: 06.06.2009 111 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Saturation & Capillary Pressure Water Saturation • Water saturations in reservoir determined using three basic methods – Wireline Wi li logs l • Electric logs • NMR logs – Fluid saturations from core • • • • Routine core p g core Sponge High-pressure core Oil- & low-invasion and water-based mud – Capillary pressure measurements on core AAPG ACE Short Course 1: 06.06.2009 112 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Influence of Core Flushing with Water-based Mud on Saturations (after CoreLab, 1982) “Averaging” Saturation Data i=n • Saturation is a scalar but is dimensionless • Sw should not be Swaverage averaged • BVW is averaged and then converted back to Sw AAPG ACE Short Course 1: 06.06.2009 Σ i=1 = Swi φi •hi i=n Σ φh i=1 i i (Averaging for a well by thickness) 113 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Buckles Plot – Piceance Basin Ro outine Core Water Satura aiton (%) 100 MWX-1 MWX-2 MWX-3 Buckles 600 Buckles 300 Buckles 240 Buckles 180 90 80 70 60 50 40 30 20 10 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 Routine Core Porosity (%) Trendlines shown represent Sw = Aφ-1.1 where A = 180. 240. and 300, respectively. Differences in trends can be postulated to be due to differences in grainsize and/or clay type/content. Buckles Plot – Piceance Basin Routine Core Water Saturraiton (%) R 100 480 0-4 935 547 5-5 485 570 0-5 845 90 80 642 0-6 555 708 0-7 180 723 0-7 360 780 0-7 890 810 0-8 120 70 60 Buckle s 78 52 -7 86 3 Buckle s 78 48 -7 87 7 Buckle 78 73 -788 6 50 40 30 20 10 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 Routine Core Porosity (%) • Routine core analysis porosity versus water saturation for the Piceance Basin MWX-2well. Saturation versus porosity trends exhibit commonly observed Buckles power-law relationship. Trendlines for depth intervals 7852-7886 shown represent Sw = Aφ-1.1 where A = 180. 240. and 300, respectively. Differences in trends can be postulated to be due to differences in grainsize and/or clay type/content. AAPG ACE Short Course 1: 06.06.2009 114 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Drop Cohesive Forces σ P1 σ P2 Forceout = π r2 ΔP Forcein = 2π r σ At equilibrium: Fout=Fin π r2 ΔP = 2π r σ rearranging ΔP = 2σ/r Where : σ=interfacial tension (dyne/cm) r = radius (cm) Capillary Pressure rcap Pnw rliq Pw AAPG ACE Short Course 1: 06.06.2009 rliq = rcap/cosθ Pc = Pnw-Pw Pnw Pw = 2σ/rliq = 2σcosθ/rcap q 115 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Capillary Pressure in Uniformly Variable Capillary • Pc = 2τ cosθ/r (after Lake, 2005) Pc = capillary pressure τ = interfacial tension θ = contact angle r = pore radius Capillary Rise Pnw r Pnw Pw Pnw h Pw Pw h h Pw* Pw* Free Water Level Pnw=Pw Pw* Water Pw-Pnw = (ρw-ρnw) h g AAPG ACE Short Course 1: 06.06.2009 116 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Capillary Pressure Equations • H= • Pc = 2τ cosθ/r where: Where: H = height above free water level Pcres = reservoir capillary pressure Pcair-Hg = air-mercury Pc σbrine = specific density of brine (g/cc) σoil,gas = specific density of oil or gas (g/cc) 0.433 = conversion from density (g/cc) to pressure gradient (psi/ft) Pc = capillary P ill pressure τ = interfacial tension θ = contact angle r = pore radius Pcres = Pcair-Hg τcosθres Pcres . (σbrine-σoil,gas) x 0.433 τcosθair-hg water P H Pw r = 2τ cosθ/Pc PhH oil PhB PwB rH H rB Capillary Pressure Equations • Pc = 2τ cosθ/r • r = 2τ cosθ/Pc where: h Pc = capillary pressure τ = interfacial tension θ = contact angle r = pore radius AAPG ACE Short Course 1: 06.06.2009 • H= Pcres . (σbrine-σoil,gas) x 0.433 • Pcres = Pcair-Hg air Hg τcosθres τcosθair-hg 117 of 217 Depth Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability (after Doveton, 1999) Capillary Pressure Measurement Mercury Injection Porous Plate Centrifuge • • • • Air-mercury Air-brine Oil-brine Gas-oil AAPG ACE Short Course 1: 06.06.2009 • Drainage • Imbibition 118 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Mercury Capillary Pressure (after Jennings, 1981) Capilary Pressure Measurement In situ Mercury Intrusion high-P fluid • Drainageg imbibition (n=37) • Drainage only (n=90) • NES = 4000 psi AAPG ACE Short Course 1: 06.06.2009 hi h -P high P core holder electric insulator Pressure transducer Core Plug Core Plug – Unconfined (n=150) – In situ Resistance Reference Cell • Three different air-Hg i H measurements Unconfined (routine) Mercury Intrusion hi h -P high P core holder Pressure transducer mercury in mercury in 119 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability 10000 Unconfined Capillary Pressure 9000 8000 6000 5000 4000 3000 Air-Hg Capillary Pressure (psia) 7 7000 • C Capillary ill Pressure P Varies with Lithofacies and associated pore size distribution and permeability 2000 1000 0 100 90 80 70 60 50 40 30 20 10 0 Wetting Phase Saturation (% ) Capillary Pressure Varies with Lithofacies and associated pore size distribution Me ercury Injection Pres ssure (psia) 10000 1000 0.00025md 0.00049md 0.0012md 0.0017md 0.0018md 0.0030md 0.0040md 0.0057md 0.0085md 0.012md 0.013md 0.032md 0.046md 0.085md 0.25md 0.41md 0.56md 0.84md 2.24md 100 10 0 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) AAPG ACE Short Course 1: 06.06.2009 120 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Normalizing Capillary Pressures • Capillary pressure curves change with permeability and porosity • To predict water saturation from capillary pressure it is necessary to either – Know the specific conditions at a given point and use a appropriate measured capillary pressure – Construct a synthetic capillary pressure curve for the conditions at the point – Develop a relation between a normalized capillary pressure function and saturation • Two principal approaches for normalization or synthetic curve construction: i – Leverett “J” function (Leverett, 1941) – Unpublished normalization of Brooks-Corey l function (Brooks and Corey, 1964) • Fractal model extension of B-C Leverett J function • J(Sw) = CPc (k/φ)0.5/τcosθ – J = dimensionless Pc function, function of Sw – C = conversion constant = 0.2166 – Pc = capillary pressure (psi) τcosθ = interfacial tension (dyne/cm) X cosine of the contact angle (degrees) – k = permeability (md) – –φ AAPG ACE Short Course 1: 06.06.2009 = porosity (fraction) 121 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Basic Leverett J Function • At its simplest a Leverett J function is constructed by plotting taking a series of capillary pressure curves for samples of different porosity and permeability and plotting the J value versus the water saturation • From the cross-plot a curve is constructed that honors th data the d t • For some formations Sw = -Alog10J + B • Valid J<1; For J>1 then Sw=Swi •A problem with the Leverett J function is the wide variance in saturation that occurs near the “irreducible” water saturation which is the saturation of principal interest for many analyses Leverett J Adjustment for Swi • Because of the problem that Leverett J functions can have near the “irreducible” water saturation (Swi) aspects of the Brooks-Corey method have been adopted to improve the JS correlation Sw l ti bby normalizing li i ffor S Swii • Water saturation is normalized using: – Swe = (Sw-Swi)/(1-Swi) where Swe = effective water saturation, Sw = water saturation at any given Pc and Swi = “irreducible” water saturation – Method is dependent on criteria for defining Swi • Plot of J versus log Swe is generally linear with a constant slope, λ, and an intercept, J*, related to the J function normalized threshold entry pressure. • The calculation of water saturation requires knowledge or back-calculation of Swi: J = J* Swe(1/λ) AAPG ACE Short Course 1: 06.06.2009 122 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Normalization: Leverett J Function 9 0.00025md 8 0.00049md 0.0012md 0 0017md 0.0017md 7 Leverett J Function • J function works poorly for mixed lithofacies and between basins • Does work OK for single lithofacies in a small area 0.0018md 0.0030md 6 0.0040md 0.0057md 5 0.0085md 0.012md 4 0.013md 0.032md 0.046md 3 0.085md 0 25md 0.25md 2 0.41md 0.56md 1 0.84md 2.24md 0 0 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) Normalized Brooks-Corey • Brooks and Corey (1966) showed that a log-log plot of Pc versus Swe often exhibits a linear trend with slope, slope λ, λ and intercept equal to the threshold entry pressure • logSwe = -λlogPc + λlogPce for Pc>Pce – – – – Pc=capillary pressure Pce = threshold entry pressure Swe = (Sw-Swi)/(1-Swi) λ = slope of log-log plot Capillary pressure parameters, λ and Pce, are correlated with permeability and/or porosity to develop Pc curves AAPG ACE Short Course 1: 06.06.2009 123 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Air-Hg Capillary Pressure (psia) 10000 Normalization: BrooksCorey Capillary Pressure 9000 8000 7000 • Transform taking logarithm of Pc and Sw • λ represents pore throat size distribution • Standard unimodal curves can be reduced to intercept (Pce = extrapolated threshold entry) and slope (λ) 6000 5000 4000 3000 2000 1000 0 0 10 20 30 40 50 60 70 80 90 100 10000 Air-Hg Capillary y Pressure (psia) Wetting Phase Saturation (%) Air-Hg Capillary Pres ssure (psia) 10000 1000 -2.05 Pc = 1.54E+07Sw 2 R = 0.997 Pce λ 1000 100 100 0 10 20 30 40 50 60 70 80 90 100 10 Wetting Phase Saturation (%) 100 Wetting Phase Saturation (%) Change in Methane Density with Pressure and Temperature Meth hane Density (g/cc) ρ=0.03861-0.0003331T+5.943*10-5P-4.287*10-9P2+1.226*10-13P3 0.32 0.30 0.28 0.26 0.24 0.22 0.20 0.18 0.16 0.14 0.12 0.10 0 08 0.08 0.06 0.04 0.02 0.00 Pressure (psia) 12000 11000 10000 9000 8000 7000 6000 5000 4000 3000 2000 1000 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 Temperature (deg F) AAPG ACE Short Course 1: 06.06.2009 124 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Brine Density vs P-T-X Bw = (1 +ΔVwp)x(1-ΔVwT); Bw =FVFw γw = 1+ 6.95x10-6 XTDS; γw = specific gravity, X mg/l ΔVwT = -1.0001x10-2 + 1.339x10-4T+5.5065x10-7T2 ΔVwp = -1.953x10-9pT-1.7283x10-13p2T-3.5892x10-7p-2.2534x10-10p2 De ensity (g/cc) 1.30 65 F, 15 psi 1.25 65 F 1000 psi 1.20 65 F, 10000 psi 1.15 100 F, 1000 psi 1.10 100 F, 10000 psi ρw = γw/Bw 65 F, 5000 psi 100 F, 15 psi 100 F, 5000 psi 200 F, 15 psi 200 F, 1000 psi 1.05 200 F,, 5000 psi p 200 F, 10000 psi 1.00 300 F, 15 psi 300 F, 1000 psi 0.95 300 F, 5000 psi 300 F, 10000 psi 0.90 0 50 100 150 200 250 300 Total Dissolved Solids (mg/l/1000) Discrepancy in High P,T MethaneWater Interfacial Tension AAPG ACE Short Course 1: 06.06.2009 80 J&N M Modeled IFT (dyne/cm) • IFT data of Hough, Raza, and Wood (1951) exhibits hibi IFT <30 dyne/cm at higher P,T • Data of Jennings & Newman (1971) exhibit higher values • J&N data more consistent, HRW may have had unknown problem with system elastomer seal contamination 70 60 50 40 30 20 10 0 0 10 20 30 40 50 60 70 80 HRW Measured IFT (dyne/cm) 125 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Relationship Between Pore Throat Diameter and Permeability by Lithology Principal Po ore Throat Diameter (μm) 100 0 445 y = 2.61x0.445 R² = 0.9259 10 1 0.1 Ss lithic Ss arkosic Ss quartzose Ls interparticle Ls chalk Ls moldic Ls oomoldic 0.01 0.001 0.000001 0.00001 0.0001 0.001 0.01 0.1 1 10 100 1000 10000 Insitu Klinkenberg Permeability (md) Relationship Between Pore Throat Diameter and Permeability by Lithology Principal Pore Throat Diameter (μm)) 100 10 Dp = 7.17(k/φ)0.49 R2 = 0.83 1 0.1 Lithology Ss lithic Ss arkosic Ss quartzose Ls interparticle Ls chalk Ls moldic Ls oomoldic 0.01 0.001 0.000001 0.00001 0.0001 0.001 0.01 0.1 1 10 100 1000 Porosity Normalized Permeability (kik/φa, md/%) AAPG ACE Short Course 1: 06.06.2009 126 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Relationship Between Pore Throat Diameter and Permeability by Lithology Princip pal Pore Throat Diameter (μm m) 100 Dp = 7.17(k/φ)0.49 R2 = 0.83 10 Lithology Ss lithic 1 Ss arkosic Ss quartzose Ls interparticle 0.1 Ls chalk Ls moldic Ls oomoldic Mesaverde Hi 0.01 Mesaverde Lo Power (Lithology) 0.001 0.000001 0.00001 0.0001 0.001 0.01 0.1 1 10 100 1000 Porosity Normalized Permeability (kik/φa, md/%) Relationship Between Threshold Entry Pressure and Permeability Air-Mercury Threshold Entrry Pressure (psi) 10000 kak kmk kik 1000 100 10 -0.44 y = 64.66x 2 R = 0.82 1 1E-06 0.00001 0.0001 0.001 0.01 0.1 1 10 100 Klinkenberg Permeability (mD) AAPG ACE Short Course 1: 06.06.2009 127 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability 1000 100 10 1 R091 255.9 ft 0 k = 113 m D φ = 24.5% 113 mD 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 100 10 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 100 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 20 30 40 50 60 70 80 90 100 8 mD 90 100 0.2 mD Wetting Phase Saturation (%) 100 10 10 20 30 40 50 60 70 80 Wetting Phase Saturation (%) 1000 100 10 B029 1 11460.6 ft k = 0.02550mD 10 φ = 4.4% 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 0.02 mD 1000 100 10 PA424 1 4606.5 ft 0 m D10 k = 0.00107 φ = 12.7% 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 1000 100 10 B029 1 13672.5 ft 0 m D10 k = 0.000065 φ = 2.6% 20 30 40 50 60 70 • no significant difference in high-low pairs at high K • increasing Pce separation with decreasing K • merging of curves at 35-50% Sw • smaller pores are in protected pore space • users of Winland R35 need to adjust for confining stress 10000 Air-Hg Capillary Pressure (psia) 10000 Air-Hg Capillary Pressure (psia) 10 1000 LD43C 1 4013.25 ft 0 k = 0.190 mD φ = 12.9% Air-Hg Capillary Pressure (psia) A Ai r-Hg Capillary Pressure (psia) 1000 E946 1 6530.3 ft k = 0.04160mD 10 φ = 9.5% 0.001 mD 10 10000 10000 0.04 mD 100 10000 1000 E946 1 6486.4 ft 0 k = 0.637 mD φ = 12.2% 1000 R780 1 2729.9 ft 0 k = 7.96 mD φ = 19.2% Air-Hg Capillary Pressu ure (psia) Air-Hg Capillary Pressu ure (psia) 10000 0.6 mD Stress effect on Pc 10000 Air-Hg Capillary Pressure (psia) Air-Hg Capillary Pressure (psia) 10000 80 90 100 Wetting Phase Saturation (%) 0.00007 mD Thresho old Entry Pore Diame ter (μ m) 100 0.50 y = 11.77x 2 R = 0.77 10 1 y = 11.28x0.50 R2 = 0.93 01 0.1 A 0.01 1E-06 0.00001 0.0001 0.001 0.01 0.1 1 10 100 Klinkenberg Permeability/Porosity (mD/%) Threshold Entry Gas Column Height (ft)) 10000 C 1000 y = 6.75x 6 75x-0.50 R2 = 0.93 100 10 1 1E-06 y = 6.48x-0.50 2 R = 0.77 1E-05 0.0001 0.001 0.01 0.1 1 10 • threshold entry pressure is predictable from √K/φ at any confining pressure • correct unconfined Pce to insitu Pce based on perm change with stress 100 Klinkenberg Permeability/Porosity (mD/%) AAPG ACE Short Course 1: 06.06.2009 128 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Threshold Entry Pore Diame ter (μ m) 100 Stress effect on Pc 1000 100 10 R091 1 255.9 ft 0 k = 113 mD φ = 24.5% 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 0.6 mD 100 10 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 100 10 E946 1 6530.3 ft k = 0.04160mD 10 φ = 9.5% 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) A 8 mD 0.01 1E-06 0.00001 0.0001 0.001 0.01 0.1 1 10 100 Klinkenberg Permeability/Porosity (mD/%) 100 10 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 0.2 mD 1000 100 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 1000 20 30 40 50 60 70 80 90 100 0.02 mD 90 100 0.00007 mD Wetting Phase Saturation (%) 1000 100 10 B029 1 13672.5 ft 0 mD10 k = 0.000065 φ = 2.6% 20 30 40 50 60 70 80 Wetting Phase Saturation (%) y = 6.48x-0.50 10 C 10 y = 6.75x-0.50 R2 = 0.93 100 100 10000 1000 PA424 1 4606.5 ft 0 mD10 k = 0.00107 φ = 12.7% 10000 1000 B029 1 11460.6 ft k = 0.02550mD 10 φ = 4.4% Air-Hg Capillary Pressure (psia) Air-Hg Capillary Pressure (psia) 10 LD43C 1 4013.25 ft 0 k = 0.190 mD φ = 12.9% Air-Hg Capillary Pressure (psia) Air-Hg Capil lary Pressure (psia) 1000 10000 0.001 mD 100 10000 10000 0.04 mD y = 11.28x0.50 R2 = 0.93 10000 1000 E946 1 6486.4 ft 0 k = 0.637 mD φ = 12.2% 1 0.1 R780 1 2729.9 ft 0 k = 7.96 mD φ = 19.2% Air- Hg Capillary Pressure ( psia) Air-Hg Capillary Pressure (psia) 10000 1000 Threshold Entry Gas Column Height (ft) 113 mD 10000 Air-Hg Capillary Pressure (psia) Air-Hg Capillary Pressure (psia) 10000 0.50 y = 11.77x 2 R = 0.77 10 2 R = 0.77 1 1E 06 1E-06 1E 05 0.0001 1E-05 0 0001 0.001 0 001 0 01 0.01 01 0.1 1 10 100 Klinkenberg Permeability/Porosity (mD/%) • threshold entry pressure is entirely predictable from √K/φ √K/φ ratio at any P Brooks-Corey Slope • PSD expressed by Pcslope • Pcslope = f (k) • Pcslope ↓ with P ↑ Leverett J(Sw) = Pc (k/φ)0.5/τcosθ Poor fit because Pcslope ≠ C = f(k, lith) 5 Brooks-C Corey Capillary Pressure Slope Implicitly assumes Pcslope = Constant in situ unconfined y = -0.0304Ln(x) + 1.87 2 R = 0.0216 4 y = -0.037Ln(x) + 1.256 2 3 R = 0.052 2 1 0 1E-05 0.0001 0.001 0.01 0.1 1 10 100 1000 In situ Klinkenberg Permeability (mD) AAPG ACE Short Course 1: 06.06.2009 129 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Height a above free water (ft) Modeled Pc curves 1000 900 Modeled Pc Curves k=0.0001 mD k=0.001 mD 800 700 600 k=0.01 mD k=0.1 mD k=1 mD k=10 mD 500 400 300 200 100 0 Modeled Pc curves Water Saturation (fraction) Pc properties evolve over time as diagenesis changes porosity and pore architecture Height above frree water (ft) 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1000 100 k=0.0001 mD k=0.001 mD k=0.01 mD 10 k=0.1 mD k=1 mD k=10 mD 1 0.0 0.1 1.0 Water Saturation (fraction) Hysteresis of Capillary Pressure • Non-wetting residual saturation to imbibition S Snwr = f(Snwi) f(S i) 4 Drainage-Imbibition Cycles 3 5 2 1 Midale Dol φ = 23% (after Larson & Morrow, 1981) AAPG ACE Short Course 1: 06.06.2009 130 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Capillary Pressure Hysteresis in Coarse Sand Pack (after Klute, 1967) Drainge-Imbibition • what is the residual trapped gas when a reservoir leaks or along a gas migration path? Approx. Height above Free Waterr Level (ft) 10000 0000 Primary Drainage First Imbibition Secondary Drainage Second Imbibition Tertiary Drainage Third Imbibition 1000 100 10 1 0.1 0 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) AAPG ACE Short Course 1: 06.06.2009 131 of 217 10000 10000 Primary Drainage First Imbibition Secondary Drainage Second Imbibition Tertiary Drainage Third Imbibition kik 1000 Air-Hg Capillary Pressure (psia) Air-Hg C apillary Pressure (psia) Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability 100 10 1 E393 7001.1ft φ = 17.4% = 28.9 mD 0 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) Air-Hg Capil lary Press sure (psia) Air-Hg Capillary Press sure (psia) 100 10 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 100 10 Airr-Hg Capilla ry Pressure (psia) Airr-Hg Capillary Pressure (psia) 100 10 1 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 100 10 1 S685 6991.2 ft (B)0 φ = 8.6% = 0.0063 mD 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 10000 10000 Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 Air-Hg Capillary Pressure (psia ) Air-Hg Capillary Pressure (psia) 20 10000 Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 100 10 1 E458 6404.8 ft (A) 0 φ = 9.5% = 0.0019 mD 10 1000 1 R829 5618.3 ft (B)0 φ = 9.2% = 0.287 mD 10000 B646 8294.4 ft (B) 0 φ = 7.6% = 0.022 mD 10 10000 Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 1 E393 7027.2 ft 0 φ = 15.0% = 1.93 mD 100 1 B049 9072.1 ft (A) 0 φ = 12.3% = 6.74 mD 10000 Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 10 20 30 40 50 60 70 80 Wetting Phase Saturation (%) 90 100 Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 100 10 KM360 1 8185.7 ft (B)0 φ = 5.9% = 0.00070 mD 10 20 30 40 50 60 70 80 Wetting Phase Saturation (%) 90 100 Capillary Pressure Hysteresis • Composite primary drainage trend consistent with single--cycle drainage single • Imibition curves exhibit hibi high hi h trapping i • Trapped saturation increases with increasing initial saturation Trapping increases with increasing initial saturation (after Lake 2005) AAPG ACE Short Course 1: 06.06.2009 132 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Residual Non-wetting Phase Saturation Residual N Nonwetting Phase Saturation (S Snwr) 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Initial Nonwetting Phase Saturation (Snwi) Residual Gas Saturation C = 1/[(Snwr-Swi)-1/(Snwi-Swi)] Snwr = 1/[C + 1/Snwi] C = 0.55 (min ε); Swi = 0 all unconfined hysteresis confined all unconfined hysteresis confined all unconfined hysteresis confined Swirr definition Swirr = 1-Snwmax Swirr = 1-Snwmax Swirr = 1-Snwmax Swirr = 1-Snwmax Swirr = 0 Swirr = 0 Swirr = 0 Swirr = 0 Swirr = 0, Snwi<70% Swirr = 0, Snwi<70% Swirr = 0, Snwi<70% Swirr = 0, Snwi<70% Land C C Land C Snwr Snwr Average Standard Minimum Standard Std Error Error Error Error C=0.55 0.57 0.329 0.53 0.077 0.077 0.61 0.294 0.59 0.087 0.088 0.61 0.383 0.51 0.056 0.057 0.44 0.249 0.45 0.088 0.085 0.73 0.443 0.63 0.073 0.073 0.78 0.360 0.71 0.080 0.081 0.75 0.562 0.59 0.057 0.057 0.61 0.316 0.54 0.078 0.078 0.70 0.054 0.053 0.83 0.062 0.061 0.70 0.052 0.051 0.50 0.038 0.039 Residual Nonwetting g Phase Saturation (Snwr) 1.0 Sample Condition unconfined Snwi= 1-Snwmax unconfined hysteresis Land C =0.59, Swirr=0 Land C=0.71, Swirr=0 Land C =0.55, Swirr=0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Initial Nonwetting Phase Saturation (Snwi) AAPG ACE Short Course 1: 06.06.2009 133 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Residual Saturation C = 1/[(Snwr-Swi)-1/(Snwi-Swi)] Snwr = 1/[C + 1/Snwi] C = 0.55 (min ε); Swi = 0 Residual Non nwetting Phase Saturation (Snwr) 1.0 unconfined 0.9 confined Land C=0.66, Swi=0 0.8 Land C =0.54, Swi=0 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Primary Drainage First Imbibition Secondary Drainage Second Imbibition Tertiary Drainage Third Imbibition 1000 100 10 1 0 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) Air-Hg Capil lary Pressurre (psia) Air-Hg Capillary Pressurre (psia) 100 10 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 30 40 50 60 70 80 90 • Snwi and Snwr are ~ = for Sw > 80% • e.g., e g for Swi of 30% 30%, Swr is ~50% 100 Wetting Phase Saturation (%) Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 100 10 Air-Hg g Capilla ry Pressure (psia) Air-Hg g Capillary Pressure (psia) 100 10 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 1.0 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 100 10 1 S685 6991.2 ft (B)0 φ = 8.6% = 0.0063 mD 10 20 30 40 50 60 70 80 90 100 Wetting Phase Saturation (%) 10000 10000 Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 Air-Hg Capillary Pressure (psia ) Air-Hg Capillary Pressure (psia) 20 10000 Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 100 10 1 E458 6404.8 ft (A) 0 φ = 9.5% = 0.0019 mD 10 1000 1 R829 5618.3 ft (B)0 φ = 9.2% = 0.287 mD 10000 1 B646 8294.4 ft (B) 0 φ = 7.6% = 0.022 mD 10 10000 Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 1 E393 7027.2 ft 0 φ = 15.0% = 1.93 mD 100 1 B049 9072.1 ft (A) 0 φ = 12.3% = 6.74 mD 10000 Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 10 20 30 40 50 60 70 80 90 Wetting Phase Saturation (%) AAPG ACE Short Course 1: 06.06.2009 100 Primary Drainage Primary Imbibition Second Drainage Second Imbibition Third Drainage Third Imbibition 1000 100 unconfined 0.9 confined Land C=0.66, Swi=0 0.8 Land C =0.54, Swi=0 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 10 KM360 1 8185.7 ft (B)0 φ = 5.9% = 0.00070 mD Residual Nonwetting Phase Saturation (Snwr) E393 7001.1ft φ = 17.4% = 28.9 mD Residual Gas Saturation 10000 10000 kik Air-Hg Capillary Pressure (psia) Air-Hg C apillary Pressure (psia) Initial Nonwetting Phase Saturation (Snwi) 0.0 10 20 30 40 50 60 70 80 90 100 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Initial Nonwetting Phase Saturation (Snwi) Wetting Phase Saturation (%) 134 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability • Trapping constant, C consistent with cemented sandstone 1.0 Complete trapping, C=0 Vuggy, isolated moldic, C=0.3 Mesaverde high C =0.35 Mesaverde Ss, C=0.55 Mesaverde low, C=0.9 Cemented Ss, C=0.7 Berea, C=1.7 Unconsolidated sucrosic Unconsolidated, sucrosic, oolitic oolitic, C=3 C 3 0.9 Residu ual Nonwetting Phase Saturattion (Snwr) Residual gas saturation 0.8 07 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 Initial Nonwetting Phase Saturation (Snwi) Electrical Properties AAPG ACE Short Course 1: 06.06.2009 135 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Wireline log analysis tools unkn 1000 Timur : Constant Exponent 0.001 MD 1000 Timur : Variable Exponent 0.001 md 1000 1:240 MD in F Permeability - 1 Core 0.001 0.4 0.4 0.4 0.4 0 Reservoir Components Porosity V/V PHIX V/V Oil V/V Water V/V Shale V/V Permeability - 2 Core 0 0.0 0 0.001 0.001 0.001 unkn Timur : Sw-Sw(Density) unkn Timur : Sw/Sw(Density) 1000 unkn 1000 1000 0 2 CPHI 0 unkn 0 Water Oil 6400 0 0 1 6425 6450 • Lithofacies identification • Accurate porosity calculation • Water saturation calculations Gas 6475 6500 6525 6550 MWX2 Resistivity of a simple rock model with straight pores Porosity 1 (Φ) Resistivity Rw (Ro) The ‘formation factor’ (F) is defined as the ratio Ro/Rw 8 0 F = 1/φ AAPG ACE Short Course 1: 06.06.2009 136 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability For a rock with a tortuous pore network .... m F = 1/φ This is the first Archie equation, where ‘m’ is known as the ‘cementation exponent’ The resistivity of hydrocarbonbearing rocks 1 8 Ro 0 Water saturation (Sw) Resistivity (Rt) The ‘resistivity index’ (I) is defined as the ratio Rt/Ro n I = 1/Sw AAPG ACE Short Course 1: 06.06.2009 137 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Putting it all together ... the Archie equation F= Ro Rw = a Φm I = Rt Ro a Rw m = Sw φ * R t ( = 1 n Sw 1/n ) Core measurement of the formation factor, F core p plug g A ro Rw Φ L AAPG ACE Short Course 1: 06.06.2009 138 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability When F and φ are plotted on logarithmic graph paper ... 1 Φ m= 3 0.1 m= 2 m= 1 0.01 1 10 F 100 1000 Regional Water Chemistry Database DOE Contract DE-FC-02NT41437 Billingsley et al Advanced Resources International • Historical Hi t i l D Data t • 3200 Well Locations –Greater Green River Basin and Wind River Basin • 8000 Chemical Analyses • Access/Excel Formats AAPG ACE Short Course 1: 06.06.2009 139 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability m in sandstones Archie (1942) observed the range in value of m in sandstones: 1.3 unconsolidated sandstones 1.4 - 1.5 very slightly cemented 1.6 - 1.7 slightly cemented 1.8 - 1.9 moderately cemented 2.0 - 2.2 g y cemented highly Guyod gave the name “cementation exponent” to m, but noted that the pore geometry controls on m were more complex and went beyond simple cementation m variability Core measurements of formation factor and porosity in a Cherokee sandstone sample, with a computed value of cementation exponent m for each core sample from: m F = 1/φ AAPG ACE Short Course 1: 06.06.2009 140 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Archie Cementation Exponents 35 30 Mesaverde Frontier Mesaverde-Frontier 25 20 Medina 15 10 2.1-2.2 2.0-2.1 1.9-2.0 1.8-1.9 1.7-1.8 1.6-1.7 1.5-1.6 0 1.4-1.5 5 1.3-1.4 Percent of Populatio on (%) 40 Archie Cementation Exponent (m, a=1) Water Saturation Calculations • • • • • Archie Simandoux Fertl Dual-Water Waxman-Smits AAPG ACE Short Course 1: 06.06.2009 141 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Simandoux • Developed theoretically primarily for Gulf Coast application Where φ = effective porosity • Rw = water resistivity • Rt = formation true resistivity • Rsh = shale or clay resistivity • Vsh = volume of shale Fertl • Developed for shaly sandstones in Rocky Mountains Where φ = effective porosity • Rw = water resistivity • Rt = formation true resistivity • Vsh = volume of shale • A = Constant AAPG ACE Short Course 1: 06.06.2009 142 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Dual-Water/Waxman-Smits • (Clavier, Coats, and Dumanoir, 1984) Swt - Swb Sw = 1 - Swb Where φt = total porosity • Rwf = formation water resistivity • Rt = formation true resistivity • Rwb = bound water resistivity (Rwa in shales) • Swt = total water saturation • Swb = bound water saturation (various methods for determination – e.g., Swb = α vq Qv; vq = 0.28 cc/meq25oC, α(XNaCl) ≈ 1 Clay Surface Area & Cation Exchange Capacity Clay Type Cation Exchange Morphology Specific Surface Pure Clay Clay in Sandstone Capacity (Meq/100g) Kaolinite 15-18 0.05-0.20 3-15 Books Fans Smectite 85-100 0.5-2.0 80-150 Honeycomb Illite 90-115 1.5-10 10-40 SmectiteIllite (mixedlayer) 85-115 0.5-10 10-150 Curled flakes with projecting and fibrous mat Similar to Smectite & Illite Chlorite 40-60 0.5-2.0 10-40 Cardhouse, rosette (after Grim, 1968; Gaida et al, 1973) AAPG ACE Short Course 1: 06.06.2009 143 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Waxman and Smits (1969) Calculated Water Saturation • Redefined the Archie equation including the influence of conductive clays Co = (1/F*) (Cw + BQv) • Co = core conductivity at Sw=100% (mho/m) Cw = water conductivity (mho/m) F* = salinity/clay conductivity independent formation factor Qv = cation exchange capacity of the core (meq/cc) B = specific counter-ion activity [(equiv/l)/(ohm-m)] • F*/F = (1 + BQv/Cw) Waxman-Smits Water Saturation Calculations • Sw = [(F*Rw) Rt(1+ RwBQv/Sw)]1/n* • F* = salinity/clay conductivity independent formation factor Qv = cation exchange capacity of the core (meq/cc) B = specific counter-ion activity [(equiv/l)/(ohm-m)] • Qv ≈ CEC(1-φ)ρ ( φ)ρma/100φ φ AAPG ACE Short Course 1: 06.06.2009 144 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Waxman-Smits-Thomas Sw = n * a* φm * Rw ⎛ ⎞ R BQ ⎜ ⎟ w v Rt ⎜⎜1+ Sw ⎟⎟⎠ ⎝ F* = a*/φm* Intrinsic Formation Factor; free of excess conductivity m* p ; free of excess conductivityy Intrinsic cementation exponent; n* Intrinsic saturation exponent; free of excess conductivity Rw Resistivity of brine at temperature (ohm-m) B Equivalent counterion conductance at temperature (1/ohm-m)/(equiv / liter) Qv Cation exchange capacity per ml pore space (meq/ml) Qv Lab Methods • Wet Chemistry – Utilizes crushed rock with high surface area – Requires sample porosity & grain density to compute Qv – Crushing can improperly exposes Qv sites not present in native pores • Multiple Salinity (Co vs Cw) – Flow-through Fl th h off multiple lti l salinity li it bbrines i on core – Preserves distribution of clays and Qv – time – intensive AAPG ACE Short Course 1: 06.06.2009 145 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Multiple-salinity Analysis Core Conductivity (CO), 1/Ro Bmax Q v F* CO = Cw B Qv + F* F* Slope @ Bmax brines = 1/F* Clay-rich sandstone Excess conductivity CO = Clean sandstone 1 C ⋅ CW = W F F 0 BmaxQv Brine Conductivity (CW), 1/Rw Porosity dependence of “m” Empirical: m = 0.234 ln φ + 1.33 Dual porosity: m = log[(φ log[(φ-φ2)m1 + φ2m2]/log φ φ2 = 0.35% m1=2, m2=1; SE both = 0.11 rock behaves like a mixture of matrix p porosityy and cracks or fractures both models fit data φ = bulk porosity φ2 = fracture porosity m1 = matrix cementation exponent m2 = fracture cementation exponent In situ Archie C Cementaiton Exponent (m, a=1, X brrine=40KppmNaCl) 2.2 2.1 2.0 1.9 1.8 1.7 1.6 15 1.5 1.4 1.3 1.2 1.1 1.0 0 2 4 6 8 10 12 14 16 18 20 22 In situ Porosity (%) AAPG ACE Short Course 1: 06.06.2009 146 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Archie Cementation Exponent • Empirical: m = 0.95 - 9.2φ + 6.35φ0.5 • Dual porosity: m = log[(φ-φ2)m1 + φ2m2]/logφ • • • • φ = bulk porosity φ2 = fracture or touching vug porosity m1 = matrix cementation exponent m2 = fracture or touching vug cementation exponent Archie Ceme ntation Exponent (m, A=1) 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 m1 = 2.1, 2 1 φ2 = 0.0005 0 0005 m1 = 2.0, φ2 = 0.001 m1 = 1.8, φ2 = 0.002 m2 = 1 High: Int: Low: 15 1.5 1.4 1.3 1.2 1.1 1.0 0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 0.2 0.22 0.24 Porosity (fraction) Archie porosity (cementation) exponent Nearly all cores exhibit some salinity dependence tested plugs with 20K, 40K, 80K, and 200K ppm brines 1.0 Core C Conductivity (mho/m) 0.9 n=335 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0 2 4 6 8 10 12 14 16 18 20 22 Brine Conductivity (mho/m) AAPG ACE Short Course 1: 06.06.2009 147 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Archie Cementation Exponent vs. Rw In situ Arrchie Cementation Ex xponent, (m, A=1) 2.3 Nearly all cores exhibit some salinity dependence tested p plugs g with 20K, 40K, 80K, and 200K ppm brines 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.01 0.1 1 Brine Resistivity (ohm-m) Multi-salinity Archie m Archie e Cementaiton Expo onent (m, a=1) 2.4 2.2 2.0 1.8 1.6 1.4 200K 1.2 80K 40K 1.0 20K 0.8 0 2 4 6 8 10 12 14 16 18 20 22 In situ Porosity (%) • Archie m decreases with decreasing salinity AAPG ACE Short Course 1: 06.06.2009 148 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability In situ Archie m vs log Rw w Slope Slopem-logRwvs Porosity Each core exhibits a highly linear m vs logRw Mean value for all cores: 0.2 0.1 0.0 -0.1 Average Slopem-Rw = -0.27+0.32 (2 -0.2 standard deviations) -0.3 where Slopem-Rw = slope of mRw versus logRw. -0.4 -0.5 -0.6 y = 0.0118x - 0.3551 R2 = 0.1198 -0.7 -0.8 0 2 4 6 8 10 12 14 16 18 20 22 In situ Porosity (%) Slopes exhibit a weak correlation with porosity . This correlation can be used to improve the prediction of m at any salinity: Slopem-Rw = 0.00118 φ – 0.355 (φ - %). Estimation of Archie m • Each core exhibits a highly linear m vs logRw • Mean value for all cores: – Average Slopem-Rw = -0.27+0.32 (2 standard deviations) – where h Slope Sl m-Rw = slope l off mRw versus logRw. l R • Slopes exhibit a weak correlation with porosity . This correlation can be used to improve the prediction of m at any salinity: – Slopem-Rw = 0.00118 φ – 0.355 (φ - %). • Combining the above equations the Archie cementation exponent at any given porosity and reservoir brine salinity can be predicted using: – mX = m40 + Slopem-Rw (log RwX + logRw40K) – mX = (0.676 logφ + 1.22) + (0.0118 φ-0.355) x (logRwX + 0.758); – mX = 1.95 + (0.0118 φ-0.355) x (logRwX + 0.758); • • • φ<14% φ>14% where mx = m at salinity X m40 = m at 40K ppm NaCl, log RwX = log10 of resistivity of brine at salinity X logRw40K = log10 of resistivity of 40K ppm NaCl = 0.758 AAPG ACE Short Course 1: 06.06.2009 149 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Salinity dependence of “m” 20K ppm 2.50 y = 0.2267Ln(x) + 2.2979 2 R = 0.6619 Axis Title 2 00 2.00 1.50 Series1 Log. (Series1) 1.00 40K ppm 0.50 3.00 0.00 0.000 y = 0.2328Ln(x) + 2.409 0.050 0.100 0.150 0.200 2 R = 0.6547 2.50 0.250 • m = a ln φ + b • a, b = f (salinity) • low porosity rocks hold more gas than we thought insitu porosity (%) Axis Title 2.00 Series1 1.50 80K ppm Log. (Series1) 1.00 3.00 y = 0.2149Ln(x) + 2.4354 0.50 2 R = 0.5132 2.50 0.050 0.100 0.150 insitu porosity (%) 0.200 0.250 2.00 Axis Title 0.00 0.000 200K ppm Series1 1.50 Log. (Series1) 3.00 1.00 y = 0.1621Ln(x) + 2.3222 2 R = 0.3633 2.50 0.50 2.00 0.050 0.100 0.150 insitu porosity (%) 0.200 0.250 Axis Title 0.00 0.000 Series1 1.50 Log. (Series1) 1.00 0.50 0.00 0.000 0.050 0.100 0.150 0.200 0.250 insitu porosity (%) Critical Gas Saturation AAPG ACE Short Course 1: 06.06.2009 150 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Overview – little krg data at Sw > 65% : Does p varyy or Sgc vary or both? – little Swc data: how is Swc = f (kik)? Or what is krw exponent ? Ga as Relative Permeability 0.1 0.01 0 10 20 30 40 50 60 70 80 90 100 Water Saturation 1 Relative Permeability (fraction) • Previous work indicated that krg could be modeled using: Corey q with p=1.7 p & Sgc ~ eqn 0.15-0.05*log10kik • Swc ~ Swi600 • Issues Western Sandstones 1 g-10 md w -10 md g-1 md w -1 md g-0.1 md w -0.1 md g-0.01 md w -0.01 md g-0.001 md w -0.001 md 0.1 0.01 0.001 0.0001 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Water Saturation (fraction) Swc>Swi AAPG ACE Short Course 1: 06.06.2009 0 0 Swi krg krw Swc Sgc 1 0 0 gas-only production Heightt above Free Water Level Pc drainage curve ater water-only gas&wa production production • At Sg<Sgc no gas flow only water flow • At Swc<Sw<(1-Sgc) transition zone both gas & water flow • At Sw<Swc no measurable water flow only gas flow Rela ative Permeability • Krg - relative permeability to gas • Krw - relative permeability to water • Sgc - critical gas saturation (Sg necessary for f connective ti gas path) th) • Swc - critical water saturation (Sw below which water relative permeability is zero or less than measurable threshold • Swi - “irreducible” water saturation (Sw at which further increase in Pc, hydrocarbon column height, results in S decrease Sw d lless th than some criteria it i 1 Capillarry Pressure Relative Permeability and Capillary Pressure Sgc Transition zone Free water level 1 Water Saturation 151 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Relative Permeability Scaling Linear Relative Permeability Relative Perm meability Logarithmic 1 0.1 0.01 0 0 0.001 0.0001 0.00001 0.000001 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Water Saturation Water Saturation • A As saturations t ti approachh the th critical iti l saturation t ti for f eachh phase h the th relative permeability for that phase changes by orders of magnitude • At saturations above critical saturations the relative permeability to the remaining flowing phase changes less than an order of magnitude Relative Permeability Reference Frame • krg = kreg/kr? • Relative permeability is the ratio of the effective permeability of one phase to a baseline permeability bili - traditional di i l references f are: – kr = ke/kabsolute; where kabs may be kair,kwater, koil kklink – kr = ke/kenw,Swc or kr = ke/kenw,Swi • kabs is the absolute permeability – – – – In high k rocks kwater ~ kklink ~ kabs (~ kair) In high k rocks kenw,Swc Swii en S c ~ kabs and Swcc~S In low k rocks kwater<kklink In low k rocks keg,Swi < kklink • User must choose reference frame - (carefully) AAPG ACE Short Course 1: 06.06.2009 152 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Relative Permeability Reference Frame Selection of – – – Relative Perm meability • For most reservoir simulation programs kr cannot exceed 1 In reservoir Swi can be < Swc but it achieved the low Sw by water flow at krw << krw,Swc 1 0.1 0.01 0.001 0.0001 0.00001 0.000001 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 kref = kwater Water Saturation 10 1 Relative Perme eability • kreference = kwater kref = keg,Swc results in krg > 1 at Sw < Swc Relativ ve Permeability 10 • 0.1 0.01 0 0 0.001 0.0001 0.00001 0.000001 1 0.1 0.01 0.001 0.0001 0.00001 0.000001 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 kref = kklink Water Saturation 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 kref = keg,Swc Water Saturation Generalized Drainage & Imbibition Relative Permeability Curves Generalize Drainage Curves Generalized Imbibition Curves (after Sahimi, 1994) AAPG ACE Short Course 1: 06.06.2009 153 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Gas Relative Permeability of LowPermeability Tight Gas Sandstone • Referenced to kklink • Measurements performed at Sw <Swi by evaporation • Note shift to lower krg at a given Sw with decreasing ki (after Thomas & Ward, 1972) Effect of Confining Pressure on Relative Permeability for Tight Gas Sandstone • • • • • Note data points showing little effect of significant g change g in confining pressure on krg Ward & Morrow (1987) data indicate that krg under pressure may be 10% less than at low pressure Referenced to kklink,P Measurements performed at Sw <Swi by evaporation Note shift to lower krg at a given Sw with decreasing ki (after Thomas & Ward, 1972) AAPG ACE Short Course 1: 06.06.2009 154 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Gas Relative Permeability is Similar using different techniques to obtain water saturation (after Walls, 1982) Influence of Confining Pressure on Gas Permeability with Core at Different Water Saturations (after Walls, 1982) AAPG ACE Short Course 1: 06.06.2009 155 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Effect of Confining Pressure on Relative Permeability for Tight Gas Sandstone Data of Randolph (1983) show moderate effect of confining stress on kr at low water saturation but increasing effect with increasing Sw (after Randolph, 1983) Single-phase Stationary krg Curves • Relative gas permeability data, representing krg values obtained at several saturations, saturations were compiled from published studies (Thomas and Ward, 1972; Byrnes et al , 1979; Sampath and Keighin, 1981; Walls, 1981; Randolph, 1983; Ward and Morrow, 1987) AAPG ACE Short Course 1: 06.06.2009 156 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Gas Relative Permeability Western Sandstones Gas Relative Permeab bility 1 Bounding curves consistent with single-point data 0.1 0.01 0 10 n=43 20 30 40 50 60 70 80 90 100 Water Saturation Single-point krg,Swi Data • Relative gas permeability data, data representing krg values obtained at a single Sw and krg values obtained for a single sample at several saturations, were compiled from published studies (Thomas and Ward, 1972; Byrnes et al , 1979; Jones and p and Keighin, g 1981; Walls, Owens, 1981; Sampath 1981; Randolph, 1983; Ward and Morrow, 1987; Byrnes, 1997; Castle and Byrnes, 1997; Byrnes and Castle, 2001) AAPG ACE Short Course 1: 06.06.2009 157 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Single-Sw Gas Relative Permeability All Tight Gas Sandstones Gas R Relative Permeab bility 1.0 1-10 md 0.1-1 md 0.05-0.1 md 0 01 0 05 md 0.01-0.05 d 0.005-0.01 md 0.001-0.005 md 0.0001-0.001 md 1 md 0.1 md 0.01 md 0.001 md 0.0001 md 0.9 08 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0 10 20 30 40 50 60 70 80 90 100 Water Saturation (%) Relative Permeability to Gas – at Stress Multiple reservoir intervals – GGRB (n = 583) Relative Permeability 1.0 0.8 Krg/4000 Byrnes data 0.6 0.4 0.2 0 0 10 20 30 40 50 60 Water Saturation (%) AAPG ACE Short Course 1: 06.06.2009 70 80 90 100 (Shanley et al, 2003) 158 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Single-Sw Gas Relative Permeability All Tight Gas Sandstones Gas R Relative Permeab bility 1 0.1 1-10 md 0.1-1 md 0.05-0.1 md 0.01-0.05 md 0.005-0.01 md 0.001-0.005 md 0.0001-0.001 md 1 md 0.1 md 0.01 md 0.001 md 0.0001 md 0.01 0.001 0 10 20 30 40 50 60 70 80 90 100 Water Saturation (%) Relative Permeability Modeling • Early workers (e.g., Burdine, 1953) modeled kr based on KozenyCarmen equation and capillary pressure curves and associated pore size distribution where kr was expressed as a function of the fraction of ppore space p occupied p and the relative size occupied p • Example: Wyllie & Spangler (1958) Sw krw = [(Sw-Swc)/(1-Swc)]2 Tortuosity Term Gates and Lietz (1950) 1 ∫0 krg = [1-(Sw-Swc)/(1-Sgc-Swc)]2 AAPG ACE Short Course 1: 06.06.2009 dSw Pc2 dSw Pc2 ∫0 1 ∫S w 1 ∫0 Mean Hydraulic Radius Term Burdine (1953) dSw Pc2 dSw Pc2 159 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Corey (1954) Equation • Corey (1954) making the approximation that 1/Pc2 = C(Sw-Swc)/(1-Swc), i.e., is linear with ΔSw over a range of saturations, simplified the BurdineP Purcell ll ddrainage i ttype equations ti tto: Sw-Swc (1- 1-S krg = gc-Swc Sw-S Swc 1-Swc ( krw = Sw-Swc 2 2 ) (1- ( 1-S ) ) wc 4 ) •Exponents often modified to adjust for different pore size distribution Key Features of Krg Sw-Swc,g 1.7 Sw-Swc,g 2 11-Swc,g gc-Swc,g Swc decreases with decreasing ki Swc krg = (1- 1-S )( ( All Tight Gas Sandstones 1 Gas Relative Permeability )) 1-10 md 0.1-1 md 0.05-0.1 md 0.01-0.05 md 0.005-0.01 md 0.001-0.005 md 0.0001-0.001 md 1 md d 0.1 md 0.01 md 0.001 md 0.0001 md 0.001 0 10 20 30 40 50 60 (where<0 then 0) Scg = 0.15 - 0.05*log10kik krg, at any given Sw increases with increasing ki krg,Sw 0.1 0.01 Swc,g = 0.16 + 0.053*log10kik 70 Water Saturation (%) 80 90 100 Krg curve shapes are approximately identical for widely different lithofacies Sgc Sgc increases with decreasing ki AAPG ACE Short Course 1: 06.06.2009 160 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Key Features of Gas Relative Permeability in Low Permeability Rocks Swc,g decreases with decreasing ki Swc,g All Tight Gas Sandstones Gas Relative Permeability 1 krg, at any given Sw increases with increasing ki krg,Sw 0.1 1-10 md 0.1-1 md 0.05-0.1 md 0.01-0.05 md 0.005-0.01 md 0.001-0.005 md 0.0001-0.001 md 1 md d 0.1 md 0.01 md 0.001 md 0.0001 md 0.01 0.001 0 10 20 30 40 50 60 70 80 90 100 Water Saturation (%) Krg curve shapes are approximately identical for widely different lithofacies Sgc Sgc increases with decreasing ki Why is Sgc Important? Gas Relative Permeability 1 P = 1.7 Sgc = f (kik) 0.1 0.01 P=f (kik) Sgc = 10% 0.001 0.0001 0.00001 0 10 20 30 40 50 60 70 80 90 100 Water Saturation AAPG ACE Short Course 1: 06.06.2009 161 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Definitions • Critical-gas saturation has been defined variously as – minimum gas saturation at which the gas phase flows freely (Firoozabadi et al., 1989) – maximum gas saturation before any gas flow occurs (Moulo and Longeron, 1989) – gas saturation at which gas freely flows to the top of a reservoir (Kortekaas and Poelgeest, 1989) – gas saturation at which gas is produced at the outlet of a core (Li and Yortsos, 1991) – Li andd Yortsos Y (1993) appropriately i l clarified l ifi d a robust b definition as the gas saturation at which the gas forms a system-spanning cluster (and consequently flows freely). This definition is consistent with the critical percolation threshold at which the gas is connected to all parts of the system and not just flowing in a subset of the system. Measured Sgc • 0.006 < Sgc < 0.38 – Solution-gas laboratory-measured (Hunt and Berry, 1956; Handy, 1958; Moulu and Longeron, 1989; Kortekaas and Poelgeest, 1989; Firoozabadi et al., 1989; and Kamath and Boyer, 1993) • 0.03 < Sgc < 0.11 – 0.0008 mD < kik < 0.031 mD, n =11, Chowdiah (1987) • Sgc=0.01 – k = 0.10 mD, Colton sandstone sample, Kamath and Boyer (1993) • Sgc = 0.10 – solution gas drive, k = 0.10 mD, Colton sandstone sample, Kamath and Boyer (1993) • Sgc=0.02 – Torpedo sandstone, k = 413 mD, Closmann (1987) • 0.045 < Sgc < 0.17 – Schowalter (1979) , n=10, 0.01 mD < k < 30.09 mD AAPG ACE Short Course 1: 06.06.2009 162 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Published Single-Saturation Gas Relative Permeablity G as Realtive Permeability y 1.00000 0 10000 0.10000 0.01000 Thomas & Ward, 1972 Byrnes et al, 1979 Jones & Owens, 1980 Sampath & Keighin, 1981 Walls, 1981 Chowdiah, 1990 Morrow et al, 1991 Byrnes, 1992 Byrnes, 1997 Byrnes & Castle, 2000 0.00100 0.00010 0.00001 0 10 20 30 40 50 60 70 80 90 100 Water Saturation (%) Measurement of Snwc (Sgc) – Percolation threshold of Hg detected by resistivity drop of >200x105 to <5 ohm – Able to determine Pc equilibrium saturation after non-equilibrium q breakthrough g – Determine pore throat size difference between entry threshold and percolation threshold AAPG ACE Short Course 1: 06.06.2009 ΔV Hg in Core • Confined mercury intrusion with electrical conductivity • Advantages oil High P Vessel Pnetconfining = 4,000 psi 163 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Critical Non-wetting Phase Saturation Critical Non-wetting g Phase Saturation 0.22 0.20 MICP-inflection 0.18 Electrical Resistance 0.16 0.14 0.12 0.10 0.08 0.06 0.04 0 02 0.02 0.00 0.00001 0.0001 0.001 0.01 0.1 1 10 100 1000 In situ Klinkenberg Permeability (mD) • Electrical conductivity and Pc inflection indicate 0% < Snwc < 22% • Higher Snwc in complex bedding lithofacies Measurement of Snwc (Sgc) AAPG ACE Short Course 1: 06.06.2009 N2 in micropipette gas bubble Core • Confined gas injection • Advantages – Sample water wet – Expulsion l i off first fi gas bubble b bbl is i highly sensitive – Sgc from both Vgas and weight change • Disadvantages – Potential saturation gradient g – Solution gas development at high pressure – Pore volume change with stress and possible hysteresis oil High P Vessel Pconfining = 4,000 psi 164 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability 50 45 40 35 30 25 20 15 10 5 0 Sgc Histogram 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0.0 00 0.0 04 0.0 08 0.12 0.16 20 0.2 0.2 24 0.2 28 0.3 32 0.3 36 0.4 40 0.4 44 0.4 48 Frequency Critical Gas Saturation Critical Gas Saturation • Sgcavg = 0.066+0.13 (2 stdev) • Wide variance Critical Gas Saturation Critical Gas Satu uration 0.50 0.45 0.40 0.35 0.30 0.25 0.20 0.15 0.10 0.05 0.00 0 00 0.0001 0.001 0.01 0.1 1 10 100 In situ Klinkenberg Permeability (mD) • Sgc is low for high permeability samples and fraction of population shows increasing Sgc with decreasing permeability AAPG ACE Short Course 1: 06.06.2009 165 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability How does Sgc get so high? • In cross-bedded sandstone series intrusion requires Pc=threshold of lowest k facies • Sgc = f(Pc1&Pc2, V1/V2, Sgc1&Sgc2, Pc equilibrium, architecture) 1 Gas-Water Capillary P Pressure (psi) 140 0.1 md 0.01 md 0.001 md 120 100 1 80 60 40 2 20 0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Water Saturation (fraction) 2 Sgc=5% 1 1 2 Sgc=5% Sgc=75% Sgc=75% Sgc vs bedding Corey and Rathjens (1956) AAPG ACE Short Course 1: 06.06.2009 166 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Invasion direction Sgc and Percolation • Sgc (L) = A LD−E (Wilkinson and Willemsen, 1983) 1) Percolation Network (Np) - Macroscopically homogeneous, random distribution of bond sizes, e.g., Simple Cubic Network (z=6) – L is network dimension – A is a numerical constant (for simple cubic network A = 0.65) – D is the mass fractal dimension of the percolation cluster – E is the Euclidean dimension 3) Series network (N ) - preferential samplespanning orientation of pore sizes or beds of different Np networks perpendicular to the invasion direction. • As L → ∞ Sgc → 0 – Sgc = 21.5% for L = 10 – Sgc = 2.4% for L = 1000 – Sgc = 0.8% for L = 10000) Gas-Water Capillary Pressurre (kPa) 1000 2) Parallel Network (NII) preferential orientation of ppore sizes or beds of different Np networks parallel to the invasion direction. 4) Discontinuous series network (N d) ppreferential non-sample-spanning p p g orientation of pore sizes or beds of different Np networks perpendicular to the invasion direction. Represents continuum between N and Np. • Experimental results can be explained using four - pore network architecture models 0.001 md 900 0.1 md 800 700 600 A B 500 400 300 200 100 0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Water Saturation Sgc and percolation theory Invasion direction 1) Percolation Network (Np) - Macroscopically homogeneous, random distribution of bond sizes, e.g., Simple Cubic Network (z=6) 3) Series network (N ) - preferential samplespanning orientation of pore sizes or beds of different Np networks perpendicular to the invasion direction. • critical gas saturation strongly controlled by sedimentary structures/rock f bi fabric • any bedding parallel laminations result in low Sgc 2) Parallel Network (NII) preferential orientation of pore sizes or beds of different Np networks parallel to the invasion direction. 4) Discontinuous series network (N d) preferential non-sample-spanning orientation of pore sizes or beds of different Np networks perpendicular to the invasion direction. Represents continuum between N and Np. • experimental results can be explained using four - pore network architecture models Gas-Water Capillary Press sure (kPa) 1000 0.001 md 900 0.1 md 800 700 600 500 A B 400 300 200 100 0 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 Water Saturation AAPG ACE Short Course 1: 06.06.2009 167 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Prediction of Sgc • Four pore network architecture models: – – – – • • • • percolation (Np) parallel (N//) series (N⊥) discontinuous series (N⊥d) Analysis suggests that Sgc is scale- and bedding-architecture dependent in cores and in the field. Sgc is likely to be very low in cores with laminae and laminated reservoirs (N//)) and low (e.g., Sgc < 0.03-0.07 at core scale and Sgc < 0.02 at reservoir scale) in massive-bedded sandstones of any permeability (Np) In cross-bedded lithologies exhibiting series network properties (N⊥), Sgc approaches a constant reflecting the capillary pressure property differences and relative l ti pore volumes l among th the bbeds d iin series. i For F th these networks t k Sgc can range widely but can reach high values (e.g., Sgc < 0.6) Discontinuous series networks, representing lithologies exhibiting series network properties but for which the restrictive beds are not sample-spanning (N⊥d), exhibit Sgc intermediate between Np and N⊥ networks. CMG IMEX Single 1-ft thick HighPermeability Layered Reservoir Simulation Model AAPG ACE Short Course 1: 06.06.2009 • • • • 1ft – 0.01, 0.1, 1, 10, 100 md keg=0.004,0.04,0.4,4,40 md Swc= 0.34, krg = 0.38 kbase= 0.004 md, kvert = 0.0004md 168 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Base Model – keg=0.004 md Cumulative Gas (scf) 1.E+09 1.E+08 1.E+07 1.E+06 J-01 J-02 J-03 J-04 Time (m-yr) J-05 J-06 khigh = 4 md, kbase = 0.004 md Cumulative Gas (scf) 1.E+10 1.E+09 1.E+08 1.E+07 J-01 J-02 J-03 J-04 Time (m-yr) J-05 AAPG ACE Short Course 1: 06.06.2009 J-06 169 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Effect of highk thin-bed on recovery relative to recovery without bed Influence of Vertical Permeability AAPG ACE Short Course 1: 06.06.2009 170 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Bioturbation Lenticular bedded isolated lenses Lenticular bedded thick connected lenses Wavy bedded Shaly Sandstone core • Core through g non-bioturbated interval would indicate ggood k in lenses • Series flow indicates long-range permeability would be reduced to permeability of shale k < 1μd • Bioturbation decreases k of lenses by 5-10X but preserves average k • Beneficial effect of bioturbation decreases with increasing sand:shale ratio but amount of k decrease also decreases Plug Permeability Scales DST-Well Test Wireline- log Establish role of Heterogeneities & Fractures Lease-Reservoir Establish role of Heterogeneities & Fractures F t FullDiameter Core AAPG ACE Short Course 1: 06.06.2009 171 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Conclusions • Drainage capillary pressure (Pc) can be modeled using equations for threshold entry pressure (Pte) and Brooks-Corey λ slopes. • Capillary pressure (Pc) exhibits a log-log threshold entry pressure (Pte) (Pt ) versus kik/φi trend t d andd variable i bl Brooks-Corey B k C slopes. • Snwr ↑ with Snwi ↑ Land-type relation: 1/Snwr-1/Snwi = 0.55 • Capillary pressure (Pc) is stress sensitive as expected – threshold entry pressure is predictable from √K/ φ at any confining pressure g ppores consistent with • Confiningg ppressure decreases largest permeability decrease but has little influence on smaller pores (pores largely protected by matrix) • Residual gas saturation increases with increasing initial gas saturation – Land Land--type relation: (1/Snwr (1/Snwr))-(1/ (1/Snwi Snwi)) = 0.55 Conclusions • Multi-salinity measurements of Archie cementation exponent, m, have been completed on 408 samples at various salinities for each sample – 20,000 ppm NaCl, 40,000 ppm, 80,000 ppm, and 200,000 ppm – Three times the number proposed • Nearly all core exhibit some dependence of conductivity and cementation exponent on salinity • The salinity dependence of m is weakly negatively correlated with porosity • Using equations developed the Archie cementation exponent can be predicted for any given porosity and formation brine salinity • Archie cementation exponent (m) decreases with decreasing porosity below approximately 6% – Can C be b modeledd l d empirical i i l or by b a duald l porosity it model d l AAPG ACE Short Course 1: 06.06.2009 172 of 217 Byrnes: Capillary Pressure, Electrical Properties, Relative Permeability Conclusions • Analysis suggests that Sgc is scale- and bedding-architecture dependent in cores and in the field. • Sgc is likely to be very low in cores with laminae and laminated reservoirs ( //)) andd low (N l ((e.g., Sgc < 0.03-0.07 0 03 0 0 at core scale l andd Sgc < 0.02 0 02 at reservoir i scale) in massive-bedded sandstones of any permeability (Np) • In cross-bedded lithologies exhibiting series network properties (N⊥), Sgc approaches a constant reflecting the capillary pressure property differences and relative pore volumes among the beds in series. For these networks Sgc can range widely but can reach high values (e.g., Sgc < 0.6) • Discontinuous series networks, representing lithologies exhibiting series network t k properties ti but b t for f which hi h th the restrictive t i ti beds b d are nott samplel spanning (N⊥d), exhibit Sgc intermediate between Np and N⊥ networks. AAPG ACE Short Course 1: 06.06.2009 173 of 217 Krygowski: Log Responses in Tight Shaly Gas Sands Lithofacies and Petrophysical Properties P ti off Mesaverde M d Ti Tight Tightht-Gas G Sandstones in Western U.S. Basins: Log Responses in Tight Shaly Gas Sands Dan Krygowski AAPG ACE 2009: Denver Colorado 1 Denver, Colorado The geologic environment ¾ Complicated lithology/mineralogy z z z ¾ Quartz Mixture of clays clays, maybe diagenetic products (Vcl/Vsh) Low porosity, <15% (Phi) Fluids z z z ¾ Quantities of interest Gas (water saturation, Sw < 1) Relativelyy fresh waters High irreducible water saturation Permeability z (Sw) ((Rw)) (Swirr) (k) Low, and of interest AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 2 174 of 217 Krygowski: Log Responses in Tight Shaly Gas Sands A Mesaverde example 2.65 ExxonMobil Willow Ridge T63X-2G Rio Blanco county, CO Piceance Basin AAPG ACE 2009: Denver Colorado 3 Environmental effects on the logs ¾ Complicated lithology/mineralogy z Presence of clay • Ga Gamma a ray, ay, SP: S decreased dec eased response espo se as co compared pa ed to nearby shales. z GR may also be affected by radioactive KK-feldspar. • Porosity measurements z Density porosity: slightly lower z Neutron porosity: higher z Sonic porosity: higher • Resistivity: lower, from additional clay conductivity. z May make water saturation calculations higher than actual saturations. AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 4 175 of 217 Krygowski: Log Responses in Tight Shaly Gas Sands Environmental effects II ¾ Fluids z Gas • • • • z Gamma ray: no change. SP: decreased response Density porosity: slightly higher Neutron porosity: lower Sonic porosity: variable Relatively fresh water • Clay conductivity will be a larger percentage of the total conductivity than in a salt water case. • Resistivityy decreased from equivalent q clean case; z Shaly sand version of Archie needed? z High irreducible water • WaterWater-free production even with elevated water saturations. AAPG ACE 2009: Denver Colorado 5 Environmental effects III ¾ Permeability z Low, but of interest • Logs,even ogs,e e NMR logs, ogs, do don’tt measure easu e pe permeability, eab ty, but we can infer permeability from log response. • Many equations; functions of porosity and irreducible water saturation. ⎛ Phi 6 ⎞ ⎟ z An example: Timur: KT = 62500 ∗ ⎜ ⎜ Sw 2 ⎟ irr ⎠ ⎝ • We can get Swirr from BVWirr, irreducible bulk volume water: BVW = Phi Phi*Sw Sw, and BVWirr = Phi* Phi Swirr z and BVW can give us some indication of fluids that will be produced (water vs no water). AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 6 176 of 217 Krygowski: Log Responses in Tight Shaly Gas Sands Quantities, parameters of interest ¾ Clay/shale volume z Density/neutron: problematic because of gas effects on the neutron. z SP: hydrocarbon effects will make Vsh too high. Gamma ray: probably p y the best. Use linear unless other data indicates otherwise. Shale volume, Vsh • In general, neutron porosity has issues in the Rockies. z Vsh may be needed for the following quantities... AAPG ACE 2009: Denver Colorado BakerAtlas, 1984 Radioactivity Index, IRA Gamma Ray Index, IGR 7 More quantities of interest ¾ Porosity, Phi z Need matrix and fluid parameters • Variable a ab e matrix at pa parameters a ete s are a e not ot uncommon. u co o PHID = RHOma − RHOB RHOma − RHOfl PHIS = z DT − DTma 2 DT − DTma or = * DTfl − DTma 3 DT May need shale/clay parameters: Vsh, shale values for specific measurements: density, neutron, t … • Effective porosity from total porosity, Vsh, and shale response. PHIDeff = PHID − Vsh ∗ PHIDSH AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 8 177 of 217 Krygowski: Log Responses in Tight Shaly Gas Sands Porosity in a gas zone ¾ Single porosity measurement z Can the matrix and fluid parameters in the volume of investigation g be sufficiently y estimated to produce a reasonable porosity? • Most porosity measurements are in the flushed zone. ¾ Porosity measurement combinations: density and neutron z If the neutron is good, this is actually a good estimate ti t off hydrocarbonhydrocarbon h d b -corrected t d crossplot l t porosity. 1 ⎛ PHIDe 2 + PHINe 2 ⎞ 2 ⎟ PHIE = ⎜ ⎜ ⎟ 2 ⎝ ⎠ 9 AAPG ACE 2009: Denver Colorado More quantities, for saturation ¾Water z saturation, Sw Water resistivity, Rw • Produced waters yield Rw values that are much too fresh (water of condensation in the gas). • NOT SP! Rwa vs GR • Pickett plot or Rwa, 150 apparent water resistivity GRshale Rwb 125 Archie parameters, a, m (variable), n • Local knowledge; Pickett plot z Which form of Archie’s equation? • Vsh & Rsh; or Rwf & Rwb AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 100 GR z 75 50 data 25 GRclean 0 0.1 Rw, Rwf 1 10 100 Rwa If Rwf = Rwb, use Archie. 10 178 of 217 Krygowski: Log Responses in Tight Shaly Gas Sands Rwa in the Mesaverde Rwb Rw, Rwf 11 AAPG ACE 2009: Denver Colorado Another saturation parameter method ¾“Super BVWirr can also be estimated from a log plot. Slope = f(saturation exponent,n) Pickett plot Rw increasing BVW BVWirr 1 Porosity z Getting a number of parameters. decrreasing Sw z Pickett” plot data 0.1 Slope = -1/cementation exponent, m Sw = 1 0.01 1 10 100 1000 Resistivity AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 12 179 of 217 Krygowski: Log Responses in Tight Shaly Gas Sands Pickett with Mesaverde data From slope, saturation exponent, n = 2.0 Rw = 0.064 Sw = 1 BVW = 0.1 06 0.6 04 0.4 02 0.2 0.04 0.05 BVWirr = 0.026 From slope, cementation exponent, m = 1.85 13 AAPG ACE 2009: Denver Colorado Which saturation equation to use? ¾ The most commonly used in the Rockies: z Archie 1 ⎞2 ⎛ a ∗ Rw Sw = ⎜ ⎟ ⎝ Phi m ∗ Rt ⎠ z In conductivity space (Ct = 1000/Rt): Ct = a ∗ Sw n ∗ Phi m ∗ Cw Dual Water Sw = [a number of versions are published…] ⎡⎛ Swb ⎞ ⎤ Swb Ct = Sw n ∗ Phi m ∗ ⎢⎜1 − ∗ Cwb ⎥ ⎟ ∗ Cwf + Sw Sw ⎠ ⎣⎝ ⎦ AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 14 180 of 217 Krygowski: Log Responses in Tight Shaly Gas Sands Mesaverde data again What about permeability? ¾ Timur (and other equations) requires Swirr. • Swirr is a proxy for surface area. z We can get Swirr from BVWirr: Swirr = BVWirr / PHI z But the permeability numbers are suspect (at best). • Core data is needed to calibrate the permeability calculation, calibration being done by modifying the porosity and saturation exponents. z NMR logs can provide permeability • They measure both Phi and BVWirr. • But they still need calibration to core for quantitative values. AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 16 181 of 217 Krygowski: Log Responses in Tight Shaly Gas Sands …and bulk volume water, BVW… ¾ If Sw < 1, and BVW is a constant, the zone has a good chance of producing waterwater-free. z z But we can can’tt determine the production volumes volumes. If BVW > 0.05, there’s a good chance that the well will produce no fluids at all. • Pore throats are blocked by water. AAPG ACE 2009: Denver Colorado 17 Mesaverde with permeability and BVW AAPG ACE Short Course 1: 06.06.2009 182 of 217 Krygowski: Log Responses in Tight Shaly Gas Sands Conclusions ¾ The combination of gas, shaly formations, and low porosity has adverse affects on all the logging measurements. z z ¾ Some of the effects counteract each other; i.e., gas and clays on neutron porosity. Generally, the difference between wet zones and pay is more subtle. So, what specifically have we learned about the Mesaverde in the Rockies? z The story continues… AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 19 183 of 217 Whittaker: Standard Log Analysis Lithofacies and Petrophysical Properties of Mesaverde Tight Tight--Gas Sandstones in Western U.S. Basins: Standard Analysis Stefani Whittaker AAPG ACE 2009: Denver Colorado 1 Denver, Colorado OUTLINE ¾ DATA PREPARATION z z z z z z Gather Data and Initial Clean up Calc. In situ Core Data Import corrected core data, rock type numbers, and point count numbers Shifting: Core data, point count data and rock type data Pick tops and zones Setting up zone parameters AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 2 184 of 217 Whittaker: Standard Log Analysis ¾ CALCULATION: z z z z z z Calculate Vsh Total and Effective Porosities Calculate Sw Look at a Pickett Plot Calculate SWI Calculate perm AAPG ACE 2009: Denver Colorado 3 Gathering WellWell-Log Data ¾ Required Curves ¾ Depth p Matching g ¾ Merging Multiple Runs ¾ Tool Pick Pick--up ¾ Neutron Matrix Conversion ¾ Normalization AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 4 185 of 217 Whittaker: Standard Log Analysis Calculating In In--situ Core Data Klinkenberg Corrected Porosity CPHIinsitu = CPHI − 0.008 Permeability log Kinsitu = 1.341(log kroutine ) − 0.6 *Note: Alan Byrnes equation from The Mountain Geologist; Volume 34; Number 1; “Reservoir Characteristics of Low-Permeability Sandstones in the Rocky Mountains”; pg. 42. There is a mistype in the publication, the above equation is the CORRECT equation. AAPG ACE 2009: Denver Colorado 5 Importing Data 1) In Situ Core Data ● ● 2) Rock Type Data • • 3) Conventional Core Data KGS analyzed Core Data (Appended _KGS) Core description 5 digit rock type code 5 digit code can be compared to GR Point Count Data • • Thin Section Point Count Data The total radiation term (VRAD_TS) can be compared to the Vsh curve in the logs. AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 6 186 of 217 Whittaker: Standard Log Analysis VANHCMT_TS VCCMT_TS VCO3CMT_TS VKSP_TS Volume of anhydrite in thin section Volume of clay cement in thin section Volume of carbonate cement in thin section Volume of Potassium Feldspar in thin section VKVRF_TS Volume of Potassium rich volcanic rock fragments in thin section VOSRF_TS Volume of of other sedimenary rock fragments in thin section VOVRF_TS Volume of other volcanic rock fragments in thin section VPLAG_TS Volume of Plagioclase Feldspars in thin section VQTZ_TS VQTZ TS VQTZCMT_TS VRAD_TS VSSRF_TS VVISPOR_TS Volume of quartz in thin section Volume of quartz cement in thin section Volume of Radioactive Elements in thin section (VRAD_TS = VKSP_TS + VKVRF_TS + VSSRF_TS + VCCMT_TS + VOVRF_TS) Volume of Shaley sedimentary rock fragments in thin section Volume of Visible Porosity in thin section Depth Shifting Core Data ¾ Rock Type Number was compared to the GR. ¾ Data Shifted together: • • • • Conventional Core Data KGS analyzed Core Data Point Count Data Rock Type Data AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 8 187 of 217 Whittaker: Standard Log Analysis Picking Tops and Zones 1 1. PI Dwights scout tickets for formation tops tops. 2. Zones were chosen based on changes in petrophysical properties to “tighten the log/core correlation • • • GR Porosity Induction AAPG ACE 2009: Denver Colorado 9 Standard Discovery Group Shaly Sand Process 1. 2 2. 3. 4. 5. 6. Set up Parameters Calculate Vshale Calculate Porosity (Total, Effective, Cross Cross--Plot) Calculate Water Saturation Calculate Bulk Volume Water and Bulk Volume Water Irreducible and Calculate Irreducible Water Saturation Calculate Permeability AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 10 188 of 217 Whittaker: Standard Log Analysis Setting up zone Parameters ¾ Deep Resistivity Rt = Rdeep ¾ Rho Matrix From Header Data ¾ Neutron Matrix From Header Data ¾ Vshale Model Linear using GR ¾ Water Sat. Model Archie’s (m=1.85, n=2, a=1) ¾ BVW Model Effective Porosity ¾ Permeability Model Timur Model Parameters for Permeability were varied by zone: •Permeability Porosity Exponent [KPHIEXP] (Ranged from 5.0 - 9.25) •Permeability Irreducible Water Saturation Exponent [KSWIEXP] (Ranged from 1.5 - 2.0) 11 AAPG ACE 2009: Denver Colorado Calculate Vsh ¾ Used the GR with the Linear method to calculate Vsh. V sh = ¾ GR log − GR clean GR sh − GR clean Rockyy Mountain Region g Suggestions: gg GR_CLEAN = 1010-15 API GR_SHALE = 9090-100 API (Will vary from well to well) AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 12 189 of 217 Whittaker: Standard Log Analysis Total Porosity ¾ Total Porosity z PHIN = Converted from LS units to desired output lithology units. z PHID = z PHIS = RHOMA − RHOB RHOMA − RHOFL (Wyllie Time Average Equation) Δt log − DTMA DTF − DTMA 13 AAPG ACE 2009: Denver Colorado Cross-Plot Porosities •Take RHOB and Neutron Φ and cross plot them to get a PHIDN PROS: -Corrects for grain density -Eliminates most of the gas effect CONS: -Requires a good NPHI log AAPG ACE Short Course 1: 06.06.2009 190 of 217 Whittaker: Standard Log Analysis Effective Porosity PHINE = PHIN − (Vsh * PHINSH ) PHIDE = PHID − (Vsh * PHIDSH ) PHISE = PHIS − (Vsh * PHISSH ) PHIDNE = PHIDN − (Vsh * PHIDNSH ) (Diminish the effect of Shale) 15 AAPG ACE 2009: Denver Colorado Total Φ AAPG ACE Short Course 1: 06.06.2009 Diminishes Shale Volume Diminishes 1. Grain Density Differences 2. Gas Effect 3. Shale Volume 191 of 217 Whittaker: Standard Log Analysis Calculate Sw Archie’s Water Saturation equation z z z z a=1; n=2; m=1.85 (Rocky Mountain Suggestion) Rw = Zoned (Pickett Plot or Rwa plot) Used Neutron/Density crossplot Effective Porosity Rt = Deep Resistivity Sw = n aRw φ m Rt AAPG ACE 2009: Denver Colorado 17 BVW, BVWI and SWI Two ways to find BVW, BVWI, and SWI 1) Calculate and visual estimation 2) Graphically using Pickett Plot Calculate: BVWT = PHIX * S w BVWe = PHIE * S w Then look at a consistently flat part on the BVW and visually pick the BVWI SWI = BVWI / PHI AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 18 192 of 217 Whittaker: Standard Log Analysis 100% Water Sat. when a=1 Pickett Plot Iso BVW lines BVWI AAPG ACE Short Course 1: 06.06.2009 193 of 217 Whittaker: Standard Log Analysis Calculate Permeability ¾ Used the Timur Model for permeability K coef = 62500 K KPHIEXP ~ 5.0 − 9.25 (Determined by zone) K KSWIEXP ~ 1.5 − 2.0 (Determined by zone) K log = K coef PHIX KPHIEXP SWI KSWIEXP 21 AAPG ACE 2009: Denver Colorado Piceance Basin Error introduced = Vshale Φ, m&n Φ, SWI Kexp. Left to right more error introduced AAPG ACE Short Course 1: 06.06.2009 194 of 217 Whittaker: Standard Log Analysis Green River Basin Washakie Basin AAPG ACE Short Course 1: 06.06.2009 195 of 217 Whittaker: Standard Log Analysis Uinta Basin Wind River Basin AAPG ACE Short Course 1: 06.06.2009 196 of 217 Cluff: Advanced Log Models Lithofacies and Petrophysical Properties of Mesaverde Tight Tight--Gas Sandstones in Western U.S. Basins: Advanced Log Analysis Bob Cluff The Discovery Group Inc. Inc 2009 AAPG Annual Convention Short course #1 6 June 2009, Denver, Colorado AAPG ACE 2009: Denver Colorado 1 Denver, Colorado Outline rock typing ¾ variable m model for Sw ¾ z ¾ as an alternative to obtuse shaly sand models permeability modeling AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 2 197 of 217 Cluff: Advanced Log Models Advanced rock typing ¾ most rock typing methods follow some form of φ-K separation or BVW separation z z z ¾ Winland R35 isoiso-lines K/ K/φ φ ratios BVW classes or, some kind of statistical relationship with logs is sought z z z single variate comparsions (e.g. GR vs grain size) multivariate comparisons, cluster analysis, etc. neural networks (a fancy form of multivariate nonnon-linear regression) AAPG ACE 2009: Denver Colorado 3 Winland equation ¾ ¾ ¾ ¾ Developed by Amoco in 1970’s Empirically derived eqn from a large Pc dataset, Weyburn field in Canada Eqn published by Kolodzie, 1980 (SPE 9382) Rock types defined by “equi“equi-pore throat size” classes, or “port” sizes, as determined from Pc at 35% Snw z z z z ¾ macroports = 22-10 μm mesoports p = 0.5 – 2 μm microports = 0.1 – 0.5 μm nanoports < 0.1 μm implicit is pore throat sizes control hydrocarbon entry and relate to pay quality AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 4 198 of 217 Cluff: Advanced Log Models Winland R35 “port” size classes log R35 = 0.732 + 0.588 log Kair – 0.864 log φ (%) in-situ Klin nkenberg gas permeability (MD D) 1000 R35 “macroports” 100 2 10 0.5 “microports” 1 0.1 0.1 “nanoport” 0.01 0.02 0.001 0.0001 Note: essentially all Kmv TGS fall into the nanoport rock type 0.00001 0.000001 0.0 5.0 10.0 15.0 20.0 25.0 in-situ porosity (%) 5 AAPG ACE 2009: Denver Colorado K/ K/φ φ ratio isoiso-lines K/phi ratio = Ka (mD) / φ (v/v) in-situ Klinkenberg gas permeability ((MD) 1000 K/phi 100 50 10 5 1 0.5 0.1 0.01 0.05 0.005 0.001 0.0001 Note: most smpls are at K/f < 0.5 and would fall into 3 or 4 classes, but without natural breaks 0.00001 0.000001 0.0 5.0 10.0 15.0 20.0 25.0 in-situ porosity (%) AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 6 199 of 217 Cluff: Advanced Log Models K/phi methods ¾ you can compute K/phi ratio from ambient or in in--situ core data, or from log K and phi z z ¾ compute Winland R35 from standard eqn or cook your own eqn from our dataset! z z ¾ divide it into classes that make sense for your area no natural divisions in the overall database we have NOT done this for you LOTS of ways to slice and dice this large a database basic Winland classes have limited utility in very tight rocks like these, almost everything falls into the “nanoport” size range AAPG ACE 2009: Denver Colorado 7 Rock types from logs we have digital rock types from core description depth shifted to log data ¾ seems like we should be able to pull rock types out of the log data by xx-plots or statistical analysis ¾ Well, maybe its not so easy......... ¾ AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 8 200 of 217 Cluff: Advanced Log Models Digital core database @ 0.5 ft resolution GR log plot vs rock # ¾ GR to rock # correlation is outstanding! AAPG ACE Short Course 1: 06.06.2009 201 of 217 Cluff: Advanced Log Models GR vs Rock number but over the entire database, the rock type classes broadly overlap Why is that? ¾ GR logs are not normalized z z z it looks good on a single well basis, but gets smeared out over multiple p cores/wells uncorrected environmental effects all vendors GR tools are not alike the 13000 rock class will always be a problem, by nature of the definition they span p a broad range g of Vsh ¾ only the higher rock classes (1st 2 or 3 digits) are likely to fall out in the best of cases ¾ AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 12 202 of 217 Cluff: Advanced Log Models ILD vs. GR xplot colored by major rock # 11000 to 12999’s separate cleanly from 15000’s, but the 13000’s overlap all NPHI--RHOB by major rock # NPHI again the 15000’s split cleanly from 12000’s, while 13000’s overlap the entire field AAPG ACE Short Course 1: 06.06.2009 203 of 217 Cluff: Advanced Log Models DT - RHOB colored by major rock # nothing separates on this, because DT and RHOB are too similar in their lithology response Rock typing summary there is a lot of data here, we didn’t push the boundaries of what could be done by any means ¾ BUT, from our analysis, the results do not look promising ¾ very, very difficult to pull out subtle rock type signatures from a limited suite of open hole measurements if the base lithology does not change much ¾ only grain size comes out cleanly, but with a broad overlap between classes ¾ AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 16 204 of 217 Cluff: Advanced Log Models Saturation model basic model assumes Archie with TGS average m, n values ¾ Shaly sand models (e (e.g. g Dual Water) all yield similar results because fm. waters are saline and shales are not highly conductive ¾ core data suggests m varies as a function of both porosity and average salinity ¾ 17 AAPG ACE 2009: Denver Colorado When F and φ are plotted loglog-log 1000 m= 2 m= 3 100 m= 1 F 10 1 0.01 0.1 φ AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 1 log F = -m log φ 18 205 of 217 Cluff: Advanced Log Models Salinity dependence of “m” tested plugs with 20K, 40K, 80K, and 200K ppm brines Nearly all cores exhibit some salinity dependence ¾ ¾ 1.0 In situ Arc chie Cementation Exponent, (m, A=1) 2.3 0.9 Core e Conductivity (mho/m) n=335 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0 2 4 6 8 10 12 14 16 18 20 22 22 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.01 Brine Conductivity (mho/m) 0.1 1 Brine Resistivity (ohm-m) 19 AAPG ACE 2009: Denver Colorado All data, all salinities Archie C Cementaiton Exponent (m m, a=1) 2.40 2.20 2.00 1.80 1.60 1.40 1.20 200K 80K 1.00 40K 20K 0.80 0 2 4 6 8 10 12 14 16 18 20 22 In situ Porosity (% ) AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 20 206 of 217 Cluff: Advanced Log Models Salinity dependence of “m” 20K ppm 2.50 ¾ y = 0.2267Ln(x) + 2.2979 2 R = 0.6619 Axis Title 2.00 ¾ 1.50 Series1 Log. (Series1) 1.00 40K ppm 0.50 0.00 0.000 3.00 0.100 0.050 0.150 0.200 ¾ m = a log φ + b intercept b drops with decreasing salinity slope is ~ constant 0.250 insitu porosity (%) y = 0.2328Ln(x) + 2.409 2 R = 0.6547 2.50 Axis Title 2.00 Series1 1.50 Log. (Series1) 1.00 80K ppm 200K ppm 0.50 3.00 0.00 0.000 3.00 y = 0.2149Ln(x) + 2.4354 0.050 0.100 0.150 2.50 0.200 y = 0.1621Ln(x) + 2.3222 y 0.1621Ln(x) + 2.3222 2 R = 0.5132 0.250 2 R = 0.3633 2.50 insitu porosity (%) 2.00 Series1 1.50 Log. (Series1) Axis Title Axis Title 2.00 Log. (Series1) 1.00 0.50 0.50 0.00 0.000 0.050 0.100 0.150 insitu porosity (%) 0.200 0.250 Series1 1.50 1.00 0.00 0.000 0.050 0.100 0.150 0.200 0.250 insitu porosity (%) AAPG ACE 2009: Denver Colorado 21 Simple procedure to compute Sw ¾ determine Rw @ Tf conventionally z z z ¾ Pickett plots – focus on the lower porosity, wetter sandstones produced waters your best guess....... convert Rw to 75 75°°F by chart lookup or Arps equation AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 22 207 of 217 Cluff: Advanced Log Models Pickett Plot example Rw = 0.306 pick m at low porosity end, where BVWirr ~ BVW Williams PA 424424-34 Piceance basin Kmv above “top gas” Pickett plot Rw 0.306 ohmm @ 160 160°°F = 0.7 @ 75° 75°F (9K ppm) AAPG ACE Short Course 1: 06.06.2009 208 of 217 Cluff: Advanced Log Models Our new procedure ¾ compute m at 40K ppm from RMA regression: m40k = 0.676 log φ + 1.22 e.g. for 10% φ : m = 0.676 + 1.22 = 1.896 ¾ correct m for salinit salinity effect b by m = m40k + ((0.0118 φ – 0.355) * (log Rw + 0.758)) ¾ e.g. for 10% φ, Rw = 0.7 @ 75° 75°F m = 1.896 + ((0.0118 * 10 – 0.355) * (log 0.7 + 0.758)) m = 1.896 + ((--0.237 * 0.603) = 1.753 ¾ ¾ cap m at 1.95 (~12% porosity) this corrects for variation in both porosity and fm salinity space AAPG ACE 2009: Denver Colorado 25 Practical impact Nominally, most of us use an m close to 2, but usually slightly less, for tight gas sand evaluations (e.g. (e.g. 1.85, 1.90) ¾ Variable m that DECREASES with decreasing porosity leads to lower Sw’s ¾ Therefore, there is more gas in the tight rocks than we thought. ¾ Above 10% porosity there is very little difference ¾ AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 26 209 of 217 Cluff: Advanced Log Models Example: Low porosity, wet zone Moderate porosity, wet AAPG ACE Short Course 1: 06.06.2009 210 of 217 Cluff: Advanced Log Models “High” porosity gas zone m is HIGHER than base case, so Sw is higher! 20Kppm example, Natural Buttes improvement in HCPV in shoulders AAPG ACE Short Course 1: 06.06.2009 211 of 217 Cluff: Advanced Log Models 30K ppm example, Wamsutter no change Sw summary 335 Kmv samples run at multiple salinities ¾ Archie porosity exponent m varies with ¾ z z ¾ porosity salinity m ↓ as porosity ↓ m ↓ as salinity ↓ behavior is consistent with increasing electrical efficiency with decreasing porosity, whatever the pore scale architecture z z very likely that the surface conductivity is highly connected with low effective m pore--pore throat conductivity is Archie with m pore close to 2 AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 32 212 of 217 Cluff: Advanced Log Models Capillary tube model for m m 1.0 >1 ~2 m=1 >2 Herrick & Kennedy, 1993, SPWLA Paper HH 33 AAPG ACE 2009: Denver Colorado E0 vs porosity, 40K ppm data TableCurve 2D v5.01 AAPG ACE Short Course 1: 06.06.2009 213 of 217 Cluff: Advanced Log Models ¾ ¾ ¾ ¾ variable m Archie model can be implemented with a simple equation relating m to porosity and formation water salinity m is constant above ~12% 12% porosity at 1 1.95 95 lowering m at 5 5--12% φ increases GIP see no impact below ~5% porosity z z z ¾ BVWirr is typically 3 3--5% no longer calculate Sw’s >> 1 Sw = 1 at low φ validates Rw much simpler than Dual Water or WW-S formulations for TGS, easier to implement, and it gets you the same answer 35 AAPG ACE 2009: Denver Colorado Permeability permeability has historically been a problem to estimate from log data ¾ dynamic property that we are trying to correlate with static properties ¾ z ¾ problem is there are no 1:1 functional relationships between any of the static properties, like porosity, and permeability. so, we fudge.... g AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 36 214 of 217 Cluff: Advanced Log Models Permeability from logs ¾ Porosity--permeability cross Porosity cross--plots z z z z regression equations developed for each basin and p presented p previously y with an accurate log porosity, you can predict K within a SE of about 4X to 5X if you add information such as grain size or rock type, you can do even better only a fraction of what is possible to do has been done done, but basic eqn’s eqn s by basin are presented in the project data store 37 AAPG ACE 2009: Denver Colorado Klinkenb berg Permeability (4,000 ps si, mD) 1000 100 10 1 0.1 Green River Piceance Powder River Uintah Washakie Wind River logK=0.3Phi-3.7 logK=0.3Phi-5.7 0.01 0.001 0.0001 0 00001 0.00001 0.000001 0.0000001 0 2 4 6 8 10 12 14 16 18 20 22 24 In situ calc Porosity (%) AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 38 215 of 217 Cluff: Advanced Log Models Kozeny & TimurTimur-type eqn’s ¾ Kozeny equation K = A * φ3 / S2, where S = surface area/bulk volume ¾ Timur eqn (and its derivatives) are of this general form, but use Swi as a proxy for the internal surface area term K = 0.136 * φ4.4 / Swi2 K = 62,500 * φ6 / Swi2 K = A * φB / SwiC ¾ ¾ (original Timur eqn) (Schlumberger eqn) (general form) We treat A, B, C as local variables and fit p parameters by y trial and error or using a multivariate solver (e.g. Excel Solver) note: NMR eqn’s (e.g. Coates & SDR or T2GM) are basically the general Timur eqn, but use Swi and φ from NMR instead of indirect estimates AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 39 216 of 217 Cluff: Advanced Log Models 41 AAPG ACE 2009: Denver Colorado Thank you! ¾ Q&A period (if (if time available) available) Visit our project website portals: http://www.kgs.ku.edu/mesaverde or http://www.discovery--group.com/projects_doe.htm http://www.discovery AAPG ACE 2009: Denver Colorado AAPG ACE Short Course 1: 06.06.2009 42 217 of 217
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