Molding compounds product portfolio
Transcription
Molding compounds product portfolio
Molding compounds product portfolio ACRYLITE® • ACRYMID® • CYROLITE® • XT® polymer • CYREX® Table of contents General Remarks 4 Product Overview Overview of applications 6 ACRYLITE® molding compounds 7 ACRYLITE® Resist (impact-modified) 8 ACRYLITE® Heatresist and ACRYMID® (high heat) 9 ACRYLITE® Satinice (light-diffusing) 10 ACRYLITE® LED 11 ACRYLITE® Optical 12 ACRYLITE® Hi-Gloss 13 ACRYLITE® MD (medical diagnostics) 14 CYROLITE® molding compounds (medical devices) 15 XT® polymer (packaging and appliances) 16 CYREX® acrylic-polycarbonate alloy (high impact resistance) 17 Special Grades 18 ACRYLITE® Heatstop (infrared-reflecting) (previously CoolTouch) Molding compounds with special additives Vu-Stat® static dissipative acrylic multipolymer ACRYLITE® cf (Coverform®) Colors and delivery 19 Properties of selected molding compounds 20 Optical, rheological, mechanical and physical properties 3 General Remarks ACRYLITE® molding compounds ACRYLITE® molding compounds are thermoplastics based on polymethyl methacrylate (PMMA), standardized to ASTM D788, DIN 7745/ISO 8257. ACRYLITE® molding compounds are characterized by a number of chemical, physical and technical properties that are indispensable for manufacturing high-quality parts by injection molding, injection blow molding and extrusion. Absolutely clear ACRYLITE® molding compound grades are so highly transparent that molded parts and semifinished products manufactured from them provide the maximum possible light transmission of 92%. It shows only the physically unavoidable reflection loss of 4% at each surface where light enters and exits. This unique clarity makes it possible to obtain particularly pure colors with an outstanding degree of precision. Convincing longevity As confirmed by tests in all of the world’s climates, ACRYLITE® molding compounds show unsurpassed resistance to weathering and aging. They do not turn yellow or wear away under chemical attack, show no deterioration of their properties and are not subject to decay. Therefore, ACRYLITE® makes a major contribution to resource conservation. That was also one of the outstanding points in its favor in the Life Cycle Assessment (LCA) performed in accordance with DIN ISO 14040ff. Recyclable Due to their chemical composition, ACRYLITE® molding compounds are uniquely suitable for chemical recycling and material recovery. Tough surface In addition to their pleasant feel and sound, molded parts and semifinished products made from ACRYLITE® (PMMA) present the greatest surface hardness and thus the best scratch resistance of all thermoplastics. This enables them to preserve their high gloss even after prolonged use. 4 Food contact approvals The crystal-clear molding compounds ACRYLITE®, ACRYLITE® Resist and ACRYLITE® Satinice conform to FDA Regulation 21CFR177.1010, Commission Regulation (EU) No. 10/2011 repealing Commission Directive 2002/72/EC, as well as to Recommendation XXII of the German Federal Institute for Risk Assessment (BfR, formerly BgVV). They also comply with the German Consumer Goods Ordinance (December 23, 1997). Please consult us with regard to other grades and colored molding compounds. All clear grades of CYROLITE® (except CYROLITE® Med2 and CYROLITE® Protect: both of which have not been tested) , CYREX 200-8005 and clear grades of XT®polymer conform to FDA Regulations for food contact requirements in 21CFR177.1010, 21CFR180.22 and 21CFR177.1580 as appropriate to the specific product. Certified quality The Performance Polymers Business Unit of Evonik Industries maintains high standards for its management systems. All manufacturing processes for ACRYLITE® molding compounds are subjected to a continuous improvement process. All sites are certified in accordance with ISO 14001:2004, and RC 14001:2008. Additionally, each manufacturing site is certified in accordance with ISO 9001:2008. Antimicrobial grades CYROLITE® Protect and CYREX® Protect antimicrobial grades meet FDA Class I or Class II medical devices covered by 510(k) PMN submission. 5 Product overview Overview of applications We encounter ACRYLITE® or one of our other molding compounds every day in a multitude of applications and in different market segments. Market applications Product Automotive & Transportation * Electronic & Communication Lighting Technologies ACRYLITE® • • • ACRYLITE® Heatresist • • • ACRYLITE® Heatstop • ACRYLITE® Hi-Gloss • • ACRYLITE® LED • • • • • ACRYLITE® Optical ACRYLITE® Resist • ACRYLITE® Satinice • • Solar Applications Industrial Construction & Architecture Home & Garden • • • • • • Furniture, Exhibit Booths & Store Fixtures • • • • • • • • • • • • CYROLITE® • XT®polymer • CYREX® • • • • *Note on the Automotive & Transportation market segment There are increasing demands from the automotive industry for material data to be entered in the International Material Data System (IMDS). The IMDS archives and manages all materials used in vehicle manufacture. This is one way to fulfill the obligations imposed on automobile manufacturers, and consequently on suppliers, by national and international norms, standards, laws and directives. Our material data sheets are published in IMDS and are therefore accessible to all IMDS participants. Contact our technical service department at +1 203 284-4290 for assistance in obtaining IMDS information for ACRYLITE molding compounds. 6 • • • ACRYLITE® Solar ACRYMID® Health & Wellness • • • ACRYLITE® basic molding compounds Depending on the grade, our general molding compounds differ in their physical properties such as flow and heat deflection temperature under load. They can be processed by all conventional thermoplastic processing methods. ACRYLITE® L40 • molding compound with maximum flow and a low heat deflection temperature under load • application: injection molding of thin-walled parts with long flow paths ACRYLITE® M30 • molding compound with high flow and a medium heat deflection temperature under load • application: injection molding of optical and technical items such as optical lens and lighting louvers, nameplates and magnifying glasses ACRYLITE® H12 • molding compound with medium flow and a medium heat deflection temperature under load • application: injection molding of technical items to satisfy higher demands on heat deflection temperature under load (e.g. lighting industry, automotive industry taillights, etc.) ACRYLITE® H15 • less flow than ACRYLITE H12, with high heat deflection temperature and high mechanical properties • application: injection molded automotive taillights and extrusion of profiles and sheets for overhead lighting ACRYLITE® 8N • improved flow over H15, with high heat deflection and high mechanical properties • application: injection molded automotive taillights and extrusion of profiles and sheets for overhead lighting ACRYLITE® 8H • variant of ACRYLITE® 8N with higher molecular weight and improved stress crack resistance. Somewhat tougher than ACRYLITE® 8N at the same heat deflection temperature under load. • application: extrusion of profiles and sheets for overhead lighting 7 Product overview ACRYLITE® Resist – impact-modified (zk) ACRYLITE® Resist acrylic polymers are specially formulated to offer enhanced impact resistance and toughness. They offer clarity similar to standard PMMA. ACRYLITE® Resist acrylic polymers are resistant to the adverse affects of outdoor weathering and they are chemical resistant. ACRYLITE® Resist grades can easily be blended with ACRYLITE® acrylic polymers to optimize impact properties and processability. Decreasing impact strength ACRYLITE® Resist zk6 This grade offers maximum impact strength, low flow and a balanced property spectrum. The product is found in a wide variety of applications. ACRYLITE® Resist zkD This product has maximum impact resistance and medium flow characteristics. It is used in applications that require a higher level of processability than what ACRYLITE® zk6 can provide. ACRYLITE® Resist zk6SR This grade offers maximum impact resistance, low flow and is specially formulated to provide high melt strength for extrusion applications. ACRYLITE® Resist zkM It offers medium impact strength and medium flow. Often used for electronic instrumentation windows and security camera housing applications. ACRYLITE® Resist zkX This material provides medium impact strength with low flow. Frequently used in sheet and profile extrusion applications. ACRYLITE® Resist zk5BR The material provides medium impact strength with medium flow. It has the highest heat deflection temperature of any ACRYLITE® Resist grade. ACRYLITE® Resist zkF The product provides medium impact strength with maximum flow. It is the most processable ACRYLITE® Resist grade. ACRYLITE® Resist zkP It is a medium impact grade with medium flow characteristics. Found in appliance applications. 8 ACRYLITE® Heatresist and ACRYMID® – high heat deflection temperature under load Products of the ACRYLITE® Heatresist and ACRYMID® groups are crystal-clear molding compounds with higher heat deflection temperatures under load than other grades of ACRYLITE®. ACRYLITE® Heatresist FT15 ACRYLITE® Heatresist FT15 is a new molding compound based on PMMA with a higher heat deflection temperature under load combined with improved flow. ACRYLITE® Heatresist FT15 is particularly suitable for injection-molding and extrusion applications with stringent requirements in terms of heat deflection temperature and flow. The special property profile offers benefits particularly when it comes to designing moldings with challenging wall thickness/flow path ratios (e.g. multicomponent injection molding). ACRYLITE® Heatresist hw55 ACRYLITE® Heatresist hw55 is particularly suited for injection-molded technical parts subjected to high thermal stress. ACRYLITE® Heatresist hw55 is a copolymer based on methyl methacrylate (MMA) with comonomer constituents. These provide a high heat deflection temperature under load for a PMMA molding compound, combined with high chemical resistance and ease of processing. ACRYMID® TT50 and TT70 Polymethyl methacrylimide (PMMI) with high heat deflection temperature that is suitable for high-temperature applications such as headlamp lenses, drum lenses and built-in furniture lighting. Besides their high transmission and clarity and excellent strength and rigidity, these specialty molding compounds offer extremely stable optical values after long-term exposure to heat. 9 Product overview ACRYLITE® Satinice – light-diffusing (df) Bead-shaped polymer particles impart light-diffusing properties to products made from ACRYLITE® Satinice, with minimal loss of transmitted light. Furthermore, in extrusion processes, matte surfaces can be obtained. Increasing light diffusion ACRYLITE® Satinice df20 – 23 • ACRYLITE® Satinice df20 • ACRYLITE® Satinice df21 • ACRYLITE® Satinice df22 • ACRYLITE® Satinice df23 ACRYLITE® Satinice zd23 and zd24 • ACRYLITE® Satinice zd23 This is a specially formulated maximum impact strength and medium flow product that offers the highest light diffusion characteristics. It is typically used in lighting as well as in automotive interior applications. • ACRYLITE® Satinice zd24 This product is specially formulated with maximum impact resistance and medium flow that offers medium light diffusion characteristics. It is designed for extrusion applications. ACRYLITE® Satinice zd24 impact-modified light-diffusing acrylic polymer complies with requirements in IEC 60598-1 IEC:2008 Luminaires sections 4.15 and 13.3.2 for thermoplastic translucent covers, shades, and similar parts not having an insulation function as tested following IEC 60695 -2-12 flammability test procedures using a glow-wire. Testing was performed by a UL certified laboratory for flammability in thicknesses of 1.5 mm (0.059 inch), 2.0 mm (0.079 inch) and 3.0 mm (0.118 inch). Test values of this product are all greater than 650°C (1,292°F). Temperatures equal to and greater than 650°C (1,202°F) are required. 1.5 mm thick zd24 exceeds 750° C (1,382°F). 10 ACRYLITE® LED – for LED lighting Specialty molding compounds for efficient lighting engineering applications in combination with LEDs. There is a choice of products either for edge lighting with maximum transmission or for backlighting to eliminate disturbing hot spots. For edge lighting Components made from the molding compounds of the LD range appear clear and transparent when unlit. These molding compounds have been optimized for edge lighting and for guiding light across differently sized areas. No additional diffusion films or microstructures are required on the component surface in order to achieve uniform light output over the entire surface. Light guiding over large area with light input from both sides ACRYLITE® LED LD • ACRYLITE® LED LD12 • ACRYLITE® LED LD24 • ACRYLITE® LED LD48 • ACRYLITE® LED LD96 Formulated using ACRYLITE® 8N molding compounds. For backlighting Molding compound colors developed for uniform light distribution when backlit with strong LED light. Combined with high transmission, the products eliminate disturbing hotspots (spots of light). These properties make it possible to reduce the spacing required between the cover and the LED light source, and to optimize the wall thickness of the component. ACRYLITE® LED White • ACRYLITE® LED White 0V606 molding compounds made from this special color appear white in incident light. • ACRYLITE® LED White 0V200 Special color for higher transmission, while retaining light-diffusing properties. 11 Product overview ACRYLITE® Optical Specialty crystal-clear molding compounds that provide high optical purity for applications that require high transmission efficiency in long light paths. One example is the manufacture of optical light guides for backlight units in TFT-LCD displays. The products in the ACRYLITE® Optical POQ grade portfolio differ in their flow properties, which are adjusted to optimize the results for different processing methods. ACRYLITE® Optical POQ66 Suitable for extrusion: • balanced combination of melt elasticity and flow properties • high heat deflection temperature under load • good mechanical properties for post-treatment of extruded sheets ACRYLITE® Optical POQ64 Suitable for injection molding and injection-compression molding: • excellent flow properties • optimized de-molding behavior • accurate reproduction of mold surfaces ACRYLITE® Optical POQ62 Suitable for injection molding, injection-compression molding and co-extrusion: • outstanding flow properties • highly accurate reproduction of microstructures ACRYLITE® Optical SuPure® ACRYLITE® Optical SuPure® is produced with a process designed to deliver an end-product of extreme purity and clarity that has no visible defects. The product that is produced is then packaged in premium Gaylord boxes and super sacks to further ensure that the product maintains its purity in transport. ACRYLITE® Optical SuPure® is typically available in 8N, additional grades upon request. 12 ACRYLITE® Hi-Gloss – for opaque high gloss surfaces Molding compounds of the ACRYLITE® Hi-Gloss family are particularly suitable for injection-molded applications. The high brilliance of ACRYLITE® Hi-Gloss makes it possible to manufacture high-gloss, Class A surfaces. They are usually provided in opaque colors. The color Black 9V022 was specially developed for “piano black” applications. Applications: add-on automotive body parts (e.g. pillar panels, spoilers, roof elements), decorative trim in car interiors and exteriors, mirror housings etc. ACRYLITE® Hi-Gloss FT8 • molding compound with high heat deflection temperature under load • good flow and melt viscosity ACRYLITE® Hi-Gloss FT15 • highest heat deflection temperature under load combined with good flow ACRYLITE® Hi-Gloss NTA-1 • slightly impact-modified molding compound with high heat deflection temperature under load ACRYLITE® Hi-Gloss NTA-3 • molding compound with higher heat deflection temperature under load 13 Product overview ACRYLITE® MD ACRYLITE® MD polymers are specially designed for medical diagnostic applications. They offer exceptional ultra-violet light transmittance and optical clarity while providing maximum flow properties and high dimensional stability. Both grades are suitable for diagnostic test packs, rotors and cuvettes as well as for any container or accessory requiring USP Class VI , ISO 10993-1, and food contact FDA 21CFR177.1010 compliance. ACRYLITE® MD L40 • extremely high flow with lower heat deflection temperature under load • suitable for fast cycles and multi-cavity tooling ACRYLITE® MD H12 • medium flow with medium heat deflection temperature under load 14 CYROLITE® molding compounds CYROLITE® is a MMA/styrene/ethyl acrylate terpolymer with an added impact modifier. Highly transparent and tough, these compounds are specially engineered to support the medical device industry. They are resistant to lipids, alcohol and the plasticizers found in PVC tubing. They can be sterilized by a variety of techniques and can be processed by all conventional thermoplastic processing methods. CYROLITE® is used in a wide variety of medical devices including luer connectors, Y-sites, filter housings and blood collection devices. Not recommended for outdoor or implantable applications. All clear grades of CYROLITE® passed Class VI United States Pharmacopoeia tests for determining the suitability of a plastic material intended for use in fabricating containers or accessories thereto, for parenteral preparations. Most grades of CYROLITE® have been found to be in compliance with Tripartite and ISO 10993-1 (CYROLITE® Protect has not been tested) and found to be non-hemolytic, non-cytotoxic, non-pyrogenic, non-sensitizing and non-mutagenic. USP, Tripartite and ISO tested in 001 tint only. CYROLITE® G-20 • medium flow and a high heat deflection temperature under load • can be sterilized via gamma irradiation, E-beam or ethylene oxide gas • provides for excellent bonding to PVC tubing and other mating plastics. CYROLITE® G-20 HIFLO® • highest flow, a high heat deflection temperature under load and offers most of the other features that CYROLITE® G20 provides • used extensively in devices that are molded with very high mold cavitation CYROLITE® GS-90 • high flow and a medium heat deflection temperature under load • best appearance directly following exposure to gamma sterilization • can be sterilized via gamma irradiation, E-beam or ethylene oxide gas CYROLITE® CG-97 • medium flow with medium heat deflection temperature • excellent lipid resistance and excellent appearance directly following exposure to gamma sterilization • can be sterilized via gamma irradiation, E-beam or ethylene oxide gas CYROLITE® Med 2 • medium flow with medium heat deflection temperature • CRYOLITE Med 2 is highly resistant to lipid and alcohol attack • can be sterilized via gamma irradiation, E-beam or ethylene oxide gas CYROLITE® Protect • specifically designed for FDA Class I or Class II medical devices covered by 510(k) PMN submission. • provides antimicrobial capabilities* against a variety of microorganisms commonly found in healthcare facilities. • can be sterilized via gamma irradiation, E-beam or ethylene oxide gas *as tested by the JIS Z 2801 protocol. 15 Product overview XT® polymer XT® polymer is a MMA/styrene/acrylonitrile terpolymer with an added impact modifier. Highly transparent and tough these compounds are used in a wide variety of applications ranging from medical and food packaging to appliance parts and paper towel dispenser covers. They are resistant to the plasticizers found in PVC. In thin sheet form they can be sterilized by gamma radiation and in any form by EtO gas. The material has excellent cold temperature impact resistance. It can be processed by all conventional thermoplastic processing methods. Not recommended for outdoor or implantable applications. All grades of XT® polymer passed Class VI United States Pharmacopoeia tests for determining the suitability of a plastic material intended for use in fabricating containers or accessories thereto, for parenteral preparations. Most grades of XT® polymer have been found to be in compliance with Tripartite and ISO 10993 and found to be non-hemolytic, non-cytotoxic, non-pyrogenic, non-sensitizing and non-mutagenic. USP, Tripartite and ISO tested in natural and 301 tint only. XT® 250 polymer • medium flow and a high heat deflection temperature under load • high impact strength XT® 375 polymer • medium flow and a high heat deflection temperature under load • highest impact strength at either room or cold temperature • high chemical resistance XT® X800RG polymer • highest flow and a high heat deflection temperature under load • high impact strength • designed for use in large tools such as the tooling needed to make paper towel dispensers 16 CYREX® acrylic-polycarbonate alloy CYREX® is an opaque, acrylic-polycarbonate alloy. When the two components are combined with a proprietary compatabilizer, a synergistic effect is produced. The result is a material with extremely high impact strength. The alloy’s notched impact resistance is much higher than polycarbonate’s yet it can be processed using conditions similar to that of an acrylic. Used in tool boxes, furniture, appliances and medical devices. Not recommended for outdoor or implantable applications. CYREX® 200-8005 and CYREX® Protect passed Class VI United States Pharmacopoeia tests for determining the suitability of a plastic material intended for use in fabricating containers or accessories thereto, for parenteral preparations. CYREX® 200-8005 has been found to be in compliance with Tripartite and ISO 10993-1 and found to be non-hemolytic, non-cytotoxic, non-pyrogenic, non-sensitizing and non-mutagenic. USP, Tripartite and ISO tested in 8005 color only. It is used in luer connectors, Y-sites, filter housings and blood collection devices. CYREX® 200 – 8000 • medium flow and a high heat deflection temperature under load • extremely high impact resistance almost double that of polycarbonate • general purpose grade CYREX® 200 – 8005 • medium flow and a high heat deflection temperature under load • specially formulated for the medical industry – exhibits little color change after exposure to gamma radiation sterilization CYREX® 953 • designed for thin-walled applications and has a high heat deflection temperature under load CYREX® Protect • specifically designed for FDA Class I or Class II medical devices covered by 510(k) PMN submission • provides antimicrobial capabilities* against a variety of microorganisms commonly found in healthcare facilities • medium flow and a high heat deflection temperature under load • specially formulated for the medical industry – exhibits little color change after exposure to gamma radiation sterilization *as tested by the JIS Z 2801 protocol. 17 Special grades ACRYLITE® Heatstop (formerly CoolTouch) Specialty opaque molding compound that reflects heat rays directly at the surface. ACRYLITE® Heatstop is suitable for all thermoplastic processing methods, including coextrusion. Vu-Stat® static dissipative acrylic multipolymer Vu-Stat compounds have outstanding ESD properties and an excellent balance of mechanical, thermal and flow properties. Vu-Stat Y-20 compound was developed for medical device applications that are sensitive to static charge discharge. Vu-Stat provides permanent ESD protection even after many washings. The product can be processed in all types of molding equipment. Molding compounds with special additives Standard molding compounds with special properties are available on request. These include: • increased UV absorption • UV transmission • easy mold release, for particularly complex molding shapes to minimize the risk of de-molding fractures. The mold release agent causes no haze. ACRYLITE® cf (CoverForm®) The specialty molding compound ACRYLITE cf is a component of the CoverForm® system solution. Together with a solvent-free multi-component reactive system on an acrylate base, PMMA components can be coated directly inside the injection mold. The surfaces obtained in this way are highly resistant to scratching and wear, as well as to a large number of chemicals. CoverForm® is a new surface technology developed by Evonik and KraussMaffei to meet particularly stringent requirements. The innovative system solution enables the application of a thin functional layer to PMMA moldings directly during the injection molding process, with no need for subsequent coating. 18 Colors and delivery Colors ACRYLITE® colors Special colors Standard colors are identified by a five-digit number after the color name. The 1st digit stands for the main color (in analogy to RAL): 0 = white 5 = blue 1 = yellow 6 = green 2 = orange 7 = gray 3 = red 8 = brown 4 = purple 9 = black and clear We offer a variety of special colors. Among others, these include colors for signaling applications and lighting engineering, as well as ones with good hiding power for coextrusion. Further information on the availability of special colors is available on request. (email: [email protected]) AMECA*-listed colors are available that can be employed for automotive signal purposes. They meet the requirements of SAE J 576. * Automotive Manufacturers Equipment Compliance Agency Delivery Physical Forms ACRYLITE®, ACRYMID®, CYROLITE®, XT®polymer and CYREX® molding compounds are supplied in injection molding and extrusion quality as pellets of uniform size. Packaging • 1500 pound Gaylord box packages • 300 pound drums (CYROLITE®, XT® polymer and CYREX®) or 375 pound drums (ACRYLITE®) or sample box packages • Further forms of packaging, such as silos, on request Inspection and other certificates An inspection certificate can be provided on request. Availability • ACRYLITE® molding compound in crystal-clear and standard colors is normally available on short notice • All other molding compounds are manufactured to order, subject to certain minimum quantities • Color matching and new colors are available on request, at a charge 19 Properties of selected molding compounds ACRYLITE® – Properties Property ASTM Method ACRYLITE MD L40* ACRYLITE M30 ACRYLITE MD H12* ACRYLITE H15 ACRYLITE 8N ACRYLITE 8H D-1003 92 92 92 92 92 92 OPTICAL Light Transmission, % Light Transmission, % @ 340 nm D-1003 min 87.7 – min 87.7 – – – Haze, % D-1003 <1 <1 <1 <1 <1 <1 Refractive Index D-542 1.49 1.49 1.49 1.49 1.49 1.49 Yellowness Index D-1925 <1 <1 <1 <1 <1 <1 D-1238 26 24 7 2.2 3.3 0.7 RHEOLOGICAL Melt Flow Rate, g/10 min @ 230°C & 3.8 kg MECHANICAL Tensile Strength, psi (MPa) D-638 8800 (60.7) 9,200 (63.4) 9500 (65.5) 9,800 (67.6) 11,300 (77.9) 11300 (77.9) Tensile Modulus, x106 psi (GPa) D-638 0.47 (3.2) 0.47 (3.2) 0.47 (3.2) 0.47 (3.2) 0.47 (3.2) 0.49 (3.3) Tensile Elongation @ Yield, % D-638 2-4 2-4 4 -6 4-6 4 -6 6-8 Tensile Elongation @ Break, % D-638 2-4 2-4 4-6 4-6 4 -6 6-8 Flexural Strength, psi (MPa) D-790 14,200 (97.9) 15,500 (106.9) 17,000 (117.2) 17,000 (117.2) 16,200 (111.7) 17,900 (123) Flexural Modulus, x106 psi (GPa) Notched Izod, ft-lb/in (J/m) ¼ bar @23°C Notched Izod, ft-lb/in (J/m) ¼ bar @0°C D-790 0.44 (3.0) 0.46 (3.2) 0.49 (3.4) 0.49 (3.4) 0.50 (3.5) – D-256 0.36 (19) 0.36 (19) 0.36 (19) 0.36 (19) 0.36 (19) 0.53 (28) D-256 – – – – – – Rockwell Hardness, M scale D-785 84 89 94 95 95 98 DTL, °F (°C) @ 264 psi, annealed D-648 165 (74) 180 (82) 201 (95) 203 (96) 212 (100) 212 (100) Vicat Softening Point, °F (°C) D-1525 180 (82) 194 (90) 221 (105) 221 (105) 226 (108) 226 (108) PHYSICAL Specific Gravity D-792 1.19 1.19 1.19 1.19 1.19 1.19 Water Absorption, % max D-570 0.3 0.3 0.3 0.3 0.3 0.3 Mold Shrinkage, in/in, mm/mm D-955 0.003-0.006 0.003-0.006 0.004-0.006 0.004-0.007 0.004-0.007 0.004-0.006 Coefficient of Linear Expansion in/in/°F, 32 - 212°F (mm/mm °C, 0-100°C) D-696 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) UL 94 HB (f1) UL 94 HB (f1) UL 94 HB (f1) UL 94 HB (f1) UL 94 HB (f1) UL 94 HB PMMA 0112V7 PMMA 0130V4 PMMA 0130V4 PMMA 0140V2 PMMA 0140V3 PMMA0132V1 UL Flammability Class CLASS *also available in standard grade 20 D-788 ACRYLITE Resist zk6 ACRYLITE Resist zkD ACRYLITE Resist zk6SR ACRYLITE Resist zkM ACRYLITE Resist zkX ACRYLITE Resist zk5BR ACRYLITE Resist zkF ACRYLITE Resist zkP 91.5 91.5 91 91.5 91.5 >90 92 92 – – – – – – – – 1 1 1 1 1 <2 1 1 1.49 1.49 1.49 1.49 1.49 1.49 1.49 1.49 0.3 0.3 0.2 0.3 0.3 0.3 0.3 0.3 1.7 5.8 1.3 3.5 1 3.4 13 4.5 6,300 (43.4)) 6,400 (44.1)) 6,000 (41) 8,500 (58.6) 9,300 (64.1) 9000 (62) 8,200 (56.2) 10500 (72.4) 0.22 (1.5) 0.23 (1.6) 0.23 (1.6) 0.32 (2.2) 0.37 (2.5) 0.36 (2.5) 0.33 (2.3) 0.40 (2.8) 5 5 5 5 5 5 5 5 55 40 60 30 25 30 25 20 8,600 (59.3)) 9,400 (64.8)) 8,000 (55.2) 13,000 (89.6) 15,000 (103.4) 12,900 (88.7) 10,000 (68.9) 15,700 (72.4) 0.22 (1.5) 0.23 (1.6) 0.2 (1.4) 0.32 (2.2) 0.35 (2.5) 0.33 (2.3) 0.29 (2.0) 0.40 (2.8) 1.1 (58.1) 1.1 (58.1) 1.1 (58.1) 0.85 (44.9) 0.85 (44.9) 0.80 (41.6) 0.75 (39.6) 0.60 (31.5) 0.70 (36.8) 0.65 (34.1) 0.8 (43) 0.50 (26.3) 0.60 (31.7) 0.50 (26.3) 0.45 (23.9) 0.35 (18.5) 40 33 40 68 70 70 65 80 194 (90) 190 (88) 181 (83) 196 (91) 200 (93) 210 (99) 196 (91) 198 (92) 201 (94) 201 (94) 196 (91) 210 (99) 230 (110) 217 (103) 208 (98) 219 (104) 1.16 1.16 1.16 1.18 1.16 1.18 1.17 1.18 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.004 - 0.007 0.003 - 0.006 0.004 - 0.007 0.003 - 0.006 0.004 - 0.007 0.004 - 0.007 0.003 - 0.006 0.003 - 0.006 0.00004 (0.000072) 0.000052 (0.0000936) 0.00005 (0.00009) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) UL 94 HB (f1) UL 94 HB UL 94 HB (f1) UL 94 HB (f1) UL 94 HB (f1) UL 94 HB UL 94 HB UL 94 HB (f1) PMMA 0231V1 PMMA 0221V3 PMMA 0231V1 PMMA 0221V3 PMMA 0221V1 PMMA 0221V3 PMMA 0221V5 PMMA 0221V3 21 Properties of selected molding compounds ACRYLITE® – Properties Property ASTM Method ACRYLITE Heatresist hw55 ACRYLITE Satinice df20 8N ACRYLITE Satinice df21 8N ACRYLITE Satinice df22 8N ACRYLITE Satinice df23 8N OPTICAL Light Transmission, % D-1003 91 90 90 88 86 Light Transmission, % @ 340 nm D-1003 – – – – – Haze, % D-1003 <1 50 83 94 96 Refractive Index D-542 1.512 1.492 1.496 1.498 1.498 Yellowness Index D-1925 <2 <1 <2 <4.5 <6.5 D-1238 1.3 3.2 3.1 3 2.9 Tensile Strength, psi (MPa) D-638 12,500 (86) 11,350 (78.3) 11,500 (79.3) 11,500 (79.3) 11,500 (79.3) Tensile Modulus, x106 psi (GPa) D-638 0.55 (3.8) 0.54 (3.7) 0.55 (3.8) 0.55 (3.8) 0.55 (3.8) Tensile Elongation @ Yield, % D-638 2-4 4 4 4 4 Tensile Elongation @ Break, % D-638 2-4 4 4 4 4 RHEOLOGICAL Melt Flow Rate, g/10 min @ 230°C & 3.8 kg MECHANICAL Flexural Strength, psi (MPa) D-790 19,800 (136.5) 19,000(131) 20,000 (138) 20,000 (138) 19,000 (131) Flexural Modulus, x106 psi (GPa) Notched Izod, ft-lb/in (J/m) ¼ bar @23°C Notched Izod, ft-lb/in (J/m) ¼ bar @0°C D-790 0.50 (3.5) 0.50 (3.5) 0.50 (3.5) 0.50 (3.5) 0.50 (3.5) D-256 0.25 (13) 0.3 (16) 0.3 (16) 0.3 (16) 0.3 (16) D-256 – – – – 0.5 (26.3) Rockwell Hardness, M scale D-785 100 95 95 95 95 D-648 223 (106) 221 (105) 221 (105) 221 (105) 221 (105) PHYSICAL DTL, °F (°C) @ 264 psi, annealed Vicat Softening Point, °F (°C) D-1525 246 (119) 243 (117) 246 (119) 246 (119) 246 (119) Specific Gravity D-792 1.19 1.19 1.19 1.19 1.19 Water Absorption, % max D-570 0.3 0.3 0.3 0.3 0.3 Mold Shrinkage, in/in, mm/mm Coefficient of Linear Expansion in/in/°F, 32 - 212°F (mm/mm °C, 0-100°C) D-955 0.009-0.010 0.003 – 0.006 0.003 – 0.006 0.003 – 0.006 0.003 – 0.006 D-696 0.000056 (0.000094) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) UL 94 HB UL 94 HB (f1) UL 94 HB (f1) UL 94 HB (f1) UL 94 HB (f1) PMMA 0140V1 PMMA 0122V7 PMMA 0122V7 PMMA 0140V2 PMMA 0140V2 UL Flammability Class CLASS 22 D-788 ACRYLITE Satinice zd23 ACRYLITE Satinice zd24 ACRYLITE LED LD12 ACRYLITE LED LD24 ACRYLITE LED LD48 ACRYLITE LED LD96 85 87 90 91 91 92 – – – – – – 96 97 <8 <4 <2 <1 1.49 1.49 1.49 1.49 1.49 1.49 5.5 – <1 <1 <1 <1 3.1 0.8 3.1 3.1 3.1 3.1 6,400 (44.1) 7,330 (51) 11,600 (80) 11,600 (80) 11,600 (80) 11,600 (80) 0.25 (1.7) 0.33 (2.3) 0.47 (3.2) 0.47 (3.2) 0.47 (3.2) 0.47 (3.2) 4 4-3 4-6 4-6 4-6 4-6 20 43 4-6 4-6 4-6 4-6 10,000 (69.5) 18,700 (128.9) 18,700 (128.9) 18,700 (128.9) 18,700 (128.9) 18,700 (128.9) 0.26 (1.8) 0.30 (2.1) 0.42 (2.9) 0.42 (2.9) 0.42 (2.9) 0.42 (2.9) 1.0 (52.5) 0.62 (32.3) 0.33 (17.3) 0.33 (17.3) 0.33 (17.3) 0.33 (17.3) 0.5 (26.3) – – – – – 44 63 101 101 101 101 185 (85) 182 (83) 198 (92) 198 (92) 199 (93) 210 (99) 226 (108) 208 (98) 226 (108) 226 (108) 226 (108) 226 (108) 1.15 1.15 1.18 1.18 1.18 1.18 0.3 0.3 0.3 0.3 0.3 0.3 0.003 – 0.006 0.003-0.006 0.004-0.007 0.004-0.007 0.004-0.007 0.004-0.007 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) 0.00004 (0.000072) UL 94 HB UL 94 HB UL 94 HB (f1) UL 94 HB (f1) UL 94 HB (f1) UL 94 HB (f1) PMMA 0231V2 PMMA 0221V3 PMMA 0140V3 PMMA 0140V3 PMMA 0140V3 PMMA 0140V3 23 Properties of selected molding compounds CYROLITE® /Vu-Stat®/ XT Polymer®/CYREX® – Properties Property ASTM Method CYROLITE G-20 CYROLITE G-20 HIFLO CYROLITE GS-90 CYROLITE CG-97 CYROLITE Med 2 CYROLITE Protect OPTICAL Light Transmission, % D-1003 89 89 89 87 85 40 Haze, % D-1003 5.0 6.0 3.0 5.0 7.0 48 Refractive Index D-542 1.515 1.515 1.515 1.515 1.515 1.518 Yellowness Index D-1925 -0.3 -0.3 -0.3 -0.3 -1.0 45 D-1238 2.6 10 6.5 1.8 2.1 10 6,850 (47.2) RHEOLOGICAL Melt Flow Rate, g/10 min @ 230°C & 5.0 kg MECHANICAL Tensile Strength, psi (MPa) D-638 6,800 (46.9) 7,000 (48.3) 6,300 (43.4) 5,270 (36.3) 5,320 (36.7) Tensile Modulus, x106 psi (GPa) D-638 0.32 (2.2) 0.37 (2.6) 0.43 (3.0) 0.27 (1.9) 0.25 (1.7) 0.33 (2.3) Tensile Elongation @ Yield, % D-638 4.0 3.6 3.6 3.8 3.9 3.0 Tensile Elongation @ Break, % D-638 9.5 9.5 6.7 13.9 22 8.0 Flexural Strength, psi (MPa) D-790 10,500 (72.4) 9,400 (64.8) 10,800 (74.5) 9,800 (67.6) 8,590 (59.2) 10,200 (70.3) Flexural Modulus, x10^6 psi (GPa) D-790 0.34 (2.3) 0.31 (2.1) 0.33 (2.3) 0.27 (1.8) 0.24 (1.6) 0.325 (2.2) Notched Izod, ft-lb/in (J/m) @23°C D-256 1.9 (101) 1.9 (101) 2.0 (107) 2.3 (122) 2.2 (117) 1.3 (69) Notched Izod, ft-lb/in (J/m) @0°C D-256 1.1 (59) 1.1 (59) 0.8 (43) – – 1.0 (53) Compressive Strength, psi (MPa) D-695 11,500 (79.3) 11,500 (79.3) 8,190 (56.5) 6,200 (42.8) – 11,500 (79.3) Rockwell Hardness, M scale D-785 39 27 30 L47 33 40 DTL, °F (°C) @ 264 psi, annealed D-648 186 (86) 186 (86) 163 (73) 158 (70) 163 (73) 167 (75) Vicat Softening Point, °F (°C) D-1525 214 (101) 214 (101) 210 (99) 194 (90) 201 (94) 212 (100) Specific Gravity D-792 1.11 1.11 1.11 1.08 1.08 1.11 PHYSICAL Water Absorption, % max D-570 0.30 0.30 0.30 0.40 0.38 0.30 Mold Shrinkage, in/in, mm/mm D-955 0.004-0.007 0.004-0.007 0.004-0.006 0.005-0.007 0.005-0.007 0.004-0.007 Coefficient of Linear Expansion in/in/°F, 32 212°F (mm/mm °C, 0-100°C) D-696 0.0000514 (0.0000925) 0.0000514 (0.0000925) 0.00004 (0.000072) 0.000053 (0.000095) 0.000048 (0.000086) 0.0000514 (0.0000925) UL 94 HB UL 94 HB UL 94 HB UL 94 HB UL 94 HB – UL Flammability Class 24 Vu-Stat Y-20 XT polymer 250 XT polymer 375 XT polymer X800RG CYREX 200-8000 CYREX 200-8005 CYREX 953 CYREX Protect 85 90 86 86 Opaque Opaque Opaque Opaque 7.0 2.5 2.5 5.0 – – – – 1.515 1.515 1.515 1.515 – – – – -0.3 4 -1.0 -1.0 – – – – 9.0 4.2 2.6 11 3.9* 3.5* 1.9* 3.0* 5,700 (39.3) 8,000 (55.2) 7,000 (48.3) 6,300 (43.4) 8,850 (61.0) 8,000 (55.2) 7,860 (54.2) 7,900 (54.5) 0.31 (2.1) 0.43 (3.0) 0.37 (2.6) 0.43 (3.0) 0.35 (2.4) 0.32 (2.2) 0.30 (2.1) 0.31 (2.14) 3.0 4.0 4.0 4.0 4.7 4.3 4.2 4.0 18 15 28 28 58 57 88 25 8,300 (57.2) 13,000 (89.6) 11,000 (75.8) 9,700 (66.9) 12,500 (86.2) 11,300 (78.9) 12,500 (86.2) 13,400 (92.4) 0.24 (1.7) 0.40 (2.8) 0.35 (2.4) 0.32 (2.2) 0.35 (2.4) 0.32 (2.2) 0.30 (2.1) 0.30 (2.1) 1.3 (69) 1.2 (64.0) 2.0 (107.0) 1.9 (101.0) 30.0 (1600) 26.0 (1387) 26.1 (1392) 12 (641) 0.5 (26.2) 0.9 (48) 1.6 (85) 1.2 (64) 4.0 (213) – 17.1 (913) – – 11,500 (79.3) 9,500 (65.5) 11,500 (79.3) – – – – 54 56 45 22 46 49 44 45 194 (90) 189 (87) 186 (86) 186 (86) 214 (101) 214 (101) 217 (103) 205 (96) 217 (103) 214 (101) 217 (103) 201 (94) 277 (136) 286 (141) 275 (135) 266 (130) 1.13 1.11 1.11 1.11 1.15 1.15 1.15 1.16 0.30 0.30 0.30 0.30 0.26 0.26 0.26 0.26 0.004-0.007 0.004-0.007 0.004-0.007 0.004-0.007 0.004-0.008 0.004-0.008 0.004-0.008 0.004-0.008 0.0000514 (0.0000925) 0.00004 (0.000072) 0.00005 (0.00009) 0.000048 (0.000086) 0.000052 (0.0000936) 0.000052 (0.0000936) 0.000052 (0.0000936) 0.000052 (0.0000936) – UL 94 HB UL 94 HB UL 94 HB UL 94 HB UL 94 HB UL 94 HB – * Melt Flow Rate, g/10 min @ 230°C & 3.8 kg 25 Properties of selected molding compounds ACRYLITE® / ACRYMID® – Properties by ISO test method Property ISO Method ACRYLITE 8N ACRYLITE Optical POQ66 ACRYLITE Hi-Gloss FT8 ACRYLITE Hi-Gloss FT15 OPTICAL Luminous transmittance D65 % 13468-2 92 92 Opaque Opaque Refractive Index 489 1.49 1.49 Opaque Opaque 1133 3 2.9 3 4.5 Tensile Modulus @ 1mm / min MPa 527 3,300 3,200 3,300 3,500 Stress @ Break @ 5 mm / min MPa 527 77 69 77 50 RHEOLOGICAL PROPERTIES Melt Volume Rate, 230°C & 3.8kg cm3 / 10min MECHANICAL Strain @ Break @ 5 mm / min , % 527 5.5 4 5.5 3.1 Charpy Impact Strength, kJ/m2 179 / 1eU 20 20 20 18 PHYSICAL Deflection Temperature Under Load @ 0.45 MPa °C 75 103 – 103 107 Deflection Temperature Under Load @ 1.8 MPa °C 75 98 – 98 105 Vicat Softening Point, B / 50°C 306 108 104 108 115 Glass Transition Temperature °C IEC 10006 117 108 117 121 Density g / cm3 1183 1.19 1.19 1.19 1.19 Water Absorption 23°C / 50% RH 62 – – – – Water Absorption, Sat / 23°C, % 62 >3 >3 >3 >3 Mold shrinkage, mm / mm 294 – – – – Coefficient of Linear Thermal Expansion (0 - 50°C), E-5 /°K 11359 8 8 8 – Fire Rating DIN 4102 B2 B2 B2 B2 Flammability (1.6 mm), Class IEC 707 UL 94 HB UL 94 HB UL 94 HB UL 94 HB All listed technical data are typical values intended for your guidance. They are given without obligation and do not constitute materials specification. 26 ACRYLITE Hi-Gloss NTA-1 ACRYLITE Hi-Gloss NTA-3 ACRYLITE Heatresist hw55 ACRYLITE Heatresist FT15 ACRYMID TT50 ACRYMID TT70 Opaque Opaque 91 91 91 91 Opaque Opaque 1.51 1.502 1.53 1.54 3 2 1.2 4.5 (2) 5 (1) 1.7 (1) 2,700 2,900 3,600 3,500 4,000 4,000 68 (2) 60 80 50 80 80 10 (2) 2.6 3.5 3.1 3 3 33 16 20 18 20 20 103 106 109 107 140 158 102 106 106 105 132 149 110 116 120 115 150 170 120 126 – 121 151 – 1.18 1.18 1.19 1.19 1.21 1.21 – – 0.6 0.46 0.63 0.54 >3 >3 2.2 2 4 6 – – 0.002 - 0.006 0.002 - 0.005 0.002 - 0.005 0.001 - 0.004 – – 6.4 6.6 5.3 5.7 B2 B2 B2 B2 B2 B2 UL 94 HB UL 94 HB UL 94 HB UL 94 HB UL 94 HB UL 94 HB (1) Melt Volume Rate, 260°C & 10.0kg cm2 / 10min (2) Stress at break and strain at break at 50 mm/min 27 ® = registered trademark ACRYLITE®, ACRYMID®, CYROLITE®, XT® polymer, CYREX®, and Vu-Stat® and are registered trademarks of Evonik Cyro LLC. Evonik Industries is a worldwide manufacturer of PMMA products sold under the PLEXIGLAS® trademark on the European, Asian, African and Australian continents and under the ACRYLITE® trademark in the Americas. Important Notice: This information and all technical and other advice are based on Evonik’s present knowledge and experience. However, Evonik assumes no liability for such information or advice, including the extent to which such information or advice may relate to third party intellectual property rights. Evonik reserves the right to make any changes to information or advice at any time, without prior or subsequent notice. EVONIK DISCLAIMS ALL REPRESENTATIONS AND WARRANTIES, WHETHER EXPRESS OR IMPLIED, AND SHALL HAVE NO LIABILITY FOR, MERCHANTABILITY OF THE PRODUCT OR ITS FITNESS FOR A PARTICULAR PURPOSE (EVEN IF EVONIK IS AWARE OF SUCH PURPOSE), OR OTHERWISE. EVONIK SHALL NOT BE RESPONSIBLE FOR CONSEQUENTIAL, INDIRECT OR INCIDENTAL DAMAGES (INCLUDING LOSS OF PROFITS) OF ANY KIND. It is the customer’s sole responsibility to arrange for inspection and testing of all products by qualified experts. Reference to trade names used by other companies is neither a recommendation nor an endorsement of the corresponding product, and does not imply that similar products could not be used. Product Portfolio and technical data subject to alteration. ©2012 Evonik Cyro LLC. All rights reserved. Printed in USA. Evonik Cyro LLC 299 Jefferson Road Parsippany, NJ 07054 United States 3790-1112-1BM phone +1 800 631-5384 [email protected] www.acrylite-polymers.com www.evonik.com