Pflege- und Maßnahmenkonzert für Bronzen im Freien Cm Beisriel

Transcription

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45.4"
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2.39"
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2.85
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2.83"
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"""
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347
Aceton MSDS (UK)
ACETONE
origin: GROS
1 Identification
formula:
gross formula:
form:
colour:
odour:
type:
CAS-nr:
concentration:
mass molecule:
classification:
EEC-nr:
EINECS-nr:
hazard identification:
UN nr:
NFPA-code:
KCA-codes:
BAGA-code:
RTECS-code:
labeling:
note:
EC-list:
CH3COCH3
Liquid
Grey
Characteristic
Pure substance
67-64-1
100 %
606-001-00-8
2006622
33
1090
1-3-0
III
D 4190
AL 3150000
F
--Yes
Suppliers
name:
address:
residence:
telephonenr:
fax-nr:
Manufacturer
Merck Nederland b.v.
Postbus 8198
Amsterdam
020-5811511
020-6149641
name:
address:
residence:
telephonenr:
fax-nr:
Mobil Oil B.V.
Westblaak 163
Rotterdam
010-4175911
010-4175449
Names
CAS-name
UN name
EC-name
IUPAC-name
ACETONE
ACETONE
ACETON
2-PROPANON
Synonyms
2-PROPANON
2-PROPANONE
ACETON
ACETON-D-EEG
ACETONE
AZETON
DIMETHYL FORMALDEHYDE
DIMETHYL KETONE
DIMETHYLKETON
KETONE PROPANE
METHYL KETONE
RS-phrases
R11
S16
smoking.
S2
S23
dust.
S33
discharges.
S9
Highly flammable.
Keep away from sources of ignition-No
Keep out of reach of children.
Do not breath gas/ fumes/ vapour/ spray/
Take precautionary measures against static
Keep container in a well ventilated place.
2 Composition
-
3 Hazards
Vapour is heavier than air and spreads at ground level.
Risk of ignition at a distance.
Do not use compressed air when filling,emptying or processing.
The substance forms readily explosive mixtures.
See: Reactivity.
The substance can enter the body by inhalation and ingestion.
Harmful concentrations build up fairly rapidly at room temperature.
Harmful concentrations of aerosols build up rapidly.
The substance tickles the eyes,the skin and the respiratory tract.
The liquid destroys the natural oils of the skin.
The substance affects the nervous system.
4 First-aid measures
Symptoms:
After inhalation:Sore throat,cough,headache,dizziness,drowsiness.
Skin contact :Redness,pain.
After ingestion :Sore throat,headache,dizziness,drowsiness.
Eye complaints :Redness,pain.
First aid:
After inhalation:Fresh air.Rest.Call a doctor.
Skin contact :Remove clothing,flush skin with water or shower.
Eye complaints :Flush thoroughly with water,take to a doctor.
After ingestion :Rinse mouth with water.Take to a doctor.
Alcohol consumption increases toxic effects.
5 Fire-fighting measures
Extremely flammable.
Extinguishing agents:
- Powder,alcohol-resistant foam,large amount of water,carbon dioxide,halons.
Keep tanks and drums cool by spraying with water.
6 Accidental release measures
Collect leakage in sealable containers.
Remove to a safe place.
Flush away remainder with water.
Additional individual protection: breathing apparatus.
7 Handling and storage
Handling
Keep away from naked flames/heat.
Spark- and explosionproof appliances and lighting system.
Storage
Fireproof storeroom.
Packaging
Storage together
KEEP SUBSTANCE AWAY FROM:
oxidizing agents
8 Personal protection
ventilation,local exhaust or respiratory protection.
gloves,safety glasses.
face shield:
goggles:
+
shoes:
protective clothing:
goggles:
:
respirator with filter:
breathing apparatus:
Gas suit:
helmet:
ear protection:
gloves:
+
butyl rubber:
+
natural rubber:
neoprene:
neoprene/SBR:
neoprene/natural rubber
PVC:
nitrile rubber:
nitrile/PVC:
-
polyethylene: ?
CPE:
?
polyurethane: PVA:
SBR:
viton:
?
-
9 Physical properties
boiling-point:
melting point:
freezing point:
Pa.sec
56
-95
decomposition temperature:
sublimation temperature:
viscosity:
vapor pressure:
relative density:
absolute density:
1.2
ph:
solubility in water:
solubility in ether:
solubility in alcohol:
solubility in actone:
233
0.8
flash point:
explosive limit:
mJ
explosive limit:
pS/m
-19
2.3/13
hPa
kg/m3
relative vapor density:
2.0
relative gas density:
rel. dens. sat. mixt. vapor/air:
g/100ml
g/100ml
g/100ml
g/100ml
infinite
vol
auto-ignition temperature:
min. ignition energy:
1.15
g/m3
specific conductivity:
490000
10 Stability and reactivity
Reacts with strong oxidants.
Reacts viontly with chloroform in basic environment.
Forms peroxides.
Attacks many plastics.
11 Toxicology
ACUTE TOXITY
Recommendation: MAC-C 5ppm,25 mg/m3
Components have a MAC-value.
Slightly toxic if swallowed.
Slightly toxic in contact with skin.
Slightly toxic by inhalation.
Substance is absorbed through the skin.
Slightly irritant to the skin.
Slightly toxic to respiratory organs.
Slightly toxic to eyes.
Narcotic in high concentrations.
CHRONIC TOXICITY.
Not listed in mutagenicity class (EEC,MAK).
No cumulative effect.
Not listed in carcinogenicity class (IARC,EEC,TLV,MAK).
Not listed in teragenicity class (EEC,MAK).
MAC - TGG:
MAC - stel:
MAC - ceiling:
skin absorption:
750
ppm
ppm
ppm
1780
mg/m3
mg/m3
mg/m3
MAK:
1000
MAK - mutagenicity:
MAK - carcinogenicity:
skin absorption/sensibility:
pregnancy:
ppm
2400
mg/m3
TLV - TWA:
TLV - stel:
TLV - ceiling:
skin absorption:
ppm
1780
ppm
2380
ppm
TLV - carcinogenicity:
mg/m3
mg/m3
mg/m3
750
1000
LD50 oral rat:
LD50 dermal rat:
LD50 dermal rabbit:
LC50 inhalation rat:
9750
2000
mg/kg
mg/kg
mg/kg
mg/L/4H
ppm/4H
repro.
39
EC carc. category:
IARC-group:
EEL:
TRK:
ppm
muta.
ppm
mg/m3
mg/m3
12 Ecology
Water
Nitrification of activated sludge is inhibited at 840 mg/litre, 75%.
Bioaccumulation: not applicable.
Toxic to algae.
According to literature (highly) toxic to fishes.
Not water pollutant (surface water).
Danger of drinking-water pollution (ground water).
Slightly harmful to algae.
Slightly harmful to bacteria.
Slightly harmful to fishes.
Slightly harmful to aquatic organisms.
Bioaccumulation: not applicable.
Soil
Readily biodegradable.
Air
According to literature air pollutant.
13 Waste
Collect in closeable containers.
Recycle by distillation.
Remove to an authorised waste treatment plant.
Use appropriate containment to avoid environmental contamination.
14 Transport
ADR-name:
ACETON
hazard identification: 33
UN nr:
1090
Road
ADR class:
3
ADR item no:
3b)
forbidden:
ADR marginal:
2301
forbidden:
ADR label(s) on tanks:
1.4
ADR label(s) on packages:
Transport Emergency Card: TEC(R)-30
routing:
In case of fog/slipperiness tanker lorries
in case of fog/slipperiness all transport
Transport in tanks allowed:
Transport in loading kettle allowed:
Rail
RID class:
RID-itemno:
RID marginal:
3
3b)
301
1.4
Inland navigation
ADNR class:
ADNR-item no
IIIA
ADNR-item no:
ADNR marginal:
5
6301
1.4
Sea freight
UN number:
UN class:
UN sub risks:
UN packaging-group:
labels:
1090
3
II
IMDG class:
IMDG page:
EMS-number:
MFAG number:
marine pollutant:
3.1
3102
3-06
300
-
Air freight
UN number:
UN class:
UN sub risks:
UN packaging-group:
labels:
1090
3
II
ICAO class:
3
ICAO sub hazards:
ICAO instruction 1:
305/Y305
ICAO instruction 2:
307
15 Regulatory information
16 Other information
file:///D|/Projekte/Hochschularbeiten/Downloads%20%20Dipl%20Arbeiten/kolmanitsch/Anlagen/Aceton%20MSDS%20(UK).htm [13.02.2004 08:06:40]
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1. STOFF-/ZUBEREITUNGS- UND FIRMENBEZEICHNUNG(1) [Bit1]
/Firmenbezeichn.
Stoff-/Zubereitungs-
Produktinformation
Handelsname
:
AEROSIL® R 974
Firma
:
Degussa AG, Aerosil & Silanes
Produktsicherheit AS-FA-PS
Postfach 1345
D-63403 Hanau
Telefon
Telefax
:
:
+49 (0)6181 59-4787
+49 (0)6181 59-4205
Notrufnummer
:
+49 (0)89 455 60-273
2. ZUSAMMENSETZUNG/ANGABEN ZU BESTANDTEILEN(2)
zu Bestandt.
Zusammensetzung/Ang.
Sonderfall Reinstoff
Ende Sonderfall Reinstoff
Gefährliche Inhaltsstoffe
Stoffliste vorhanden ???
Angaben zu Bestandteilen / Gefährliche Inhaltsstoffe
Gefährliche Inhaltsstoffe
• Silan, Dichlordimethyl-,
Reaktionsprodukte mit Siliciumdioxid
CAS-Nr.
68611-44-9
EG-Nr.
271-893-4
3. MÖGLICHE GEFAHREN(3)
Mögliche Gefahren
Das Produkt ist aufgrund uns vorliegender Daten kein gefährlicher Stoff im Sinne des
Chemikaliengesetzes beziehungsweise der Gefahrstoffverordnung in der zur Zeit gültigen Fassung.
4. ERSTE-HILFE-MASSNAHMEN(4) Erste-Hilfe-Massnahmen
Einatmen
Bei Freisetzung von Produktstaub:
Mögliche Beschwerden: Husten, Niesen
Betroffene an die frische Luft bringen.
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Hautkontakt
Keine besonderen Erste-Hilfe Maßnahmen erforderlich.
Augenkontakt
Mögliche Beschwerden durch Fremdkörpereffekt bedingt.
Bei geöffnetem Lidspalt gründlich mit viel Wasser spülen.
Bei anhaltenden Beschwerden
Augenarzt vorstellen.
Verschlucken
Mund ausspülen.
Hinweise für den Arzt
03EHS_L_TEXT(DH-E04.00590030)
Keine besonderen Erste-Hilfe Maßnahmen erforderlich.
5. MASSNAHMEN ZUR BRANDBEKÄMPFUNG(5)
Behandlung
Massnahmen zur Brandbekämpfung
Geeignete LöschmittelGeeignete Löschmittel
alle Löschmittel geeignet
Ungeeignete LöschmittelGefährdung bei BrandbekämpfungBesondere Gefahren bei der
Brandbekämpfung
Im Brandfall können freigesetzt werden: Kohlenmonoxid und Kohlendioxid.
Zusätzl. Hinweise – BrandbekämpfungWeitere Angaben
Löschwasser darf nicht in die Kanalisation, Untergrund oder Gewässer gelangen.
Für ausreichende Löschwasserrückhaltemöglichkeiten sorgen.
Löschwasserrückhaltung in Deutschland: siehe Löschwasserrückhalterichtlinie "LöRüRL".
Brandrückstände und kontaminiertes Löschwasser müssen entsprechend den örtlichen behördlichen
Vorschriften entsorgt werden.
6. MASSNAHMEN BEI UNBEABSICHTIGTER FREISETZUNG(6)
Freisetzung
Maßnahmen bei unbeabs.
Personenbez. VorsichtsmaßnahmenPersonenbezogene Vorsichtsmaßnahmen
Persönliche Schutzausrüstung tragen.
UmweltschutzmaßnahmenUmweltschutzmaßnahmen
Nicht in Abwasser, Erdreich, Gewässer, Grundwasser, Kanalisation gelangen lassen.
Verfahren zur Reinigung oder AufnahmeVerfahren zur Reinigung
Mechanisch aufnehmen und in geeigneten Behältern zur Entsorgung bringen.
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Zusätzliche HinweiseZusätzliche Hinweise
Staubbildung vermeiden.
7. HANDHABUNG UND LAGERUNG(7)
Handhabung und Lagerung
HandhabungHandhabung
Hinweise für sichere HandhabungHinweise für sichere Handhabung
Gegebenenfalls Objektabsaugung.
Hinweise Brand- und ExplosionsschutzHinweise zum Brand- und Explosionsschutz
Maßnahmen gegen elektrostatische Aufladungen treffen.
LagerungLagerung
Anforderung an Lagerräume und Behälter
Trocken aufbewahren.
Anforderungen Lagerung
8. EXPOSITIONSBEGRENZUNG UND PERSÖNLICHE SCHUTZAUSRÜSTUNG(8)
Expositionsbegrenz. u. pers. Schutz.
Bestandteile mit arbeitsplatzbezogenen, zu überwachenden GrenzwertenBestandteile mit
Arbeitsplatzgrenzw.
Ende Luftgrenzwerte
Bestandteile mit Arbeitsplatzgrenzwerten
Komponentenschleife
Instanzenschleife Arbeitsplatzgrenzwerte
• Siliciumdioxid, auf chemischem Wege gewonnen
CAS-Nr.
7631-86-9
Grenzwerte
4 mg/m3
einatembare Fraktion
Sonstige Hinweise (Stoffliste)
SDB(P27) / 16.01.2003 11:44
EG-Nr.
231-545-4
MAK(TRGS 900)
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Persönliche SchutzausrüstungPersönliche Schutzausrüstung
Atemschutz
Atemschutz
Keine besondere Schutzausrüstung erforderlich.
Beim Auftreten von Staub: Staubmaske mit Partikelfilter P2
Bei Überschreitung der arbeitsplatzbezogenen Grenzwerte und / oder bei Freisetzung größerer
Mengen (Leckagen, Verschütten, Staub) ist der angegebene Atemschutz zu verwenden.
Handschutz
Handschutz
Schutzhandschuhe aus folgenden Materialien tragen: Stoff, Gummi,Leder.
Augenschutz
Augenschutz
Schutzbrille mit Seitenschutz
Beim Auftreten von Staub: Korbbrille
Körperschutz
Haut- und Körperschutz
Keine besondere Schutzausrüstung erforderlich.
Vorbeugender Hautschutz
Hygienemaßnahmen
Hygienemaßnahmen
Bei der Arbeit nicht essen, trinken, rauchen, schnupfen.
Beschmutzte Kleidung vor Wiedergebrauch waschen.
Pers. Schutzmaßnahmen
Schutzmaßnahmen
Die beim Umgang mit Chemikalien üblichen Vorsichtsmaßnahmen sind zu beachten.
Bei Möglichkeit des Kontaktes der Haut / Augen ist der angegebene Handschutz / Augenschutz /
Körperschutz zu verwenden.
9. PHYSIKALISCHE UND CHEMISCHE EIGENSCHAFTEN(9) Physikal. u. chem. Eigenschaften
Erscheinungsbild1. Erscheinungsbild
Form
Form
FarbeFarbe
GeruchGeruch
Pulver
weiß
geruchlos
Sicherheitsrelevante Daten2. Sicherheitsrelevante Daten
pH-WertpH-Wert
3,7 - 4,7
Medium:
(40 g / l)
(20 °C)
Wasser / Methanol
1:1 in Suspension
n.a.
Phasenüberg.
fest/flüssigSchmelzpunkt/Schme
lzbereich
Phasenübergang
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flüssig/gasförmigSiedepunkt/S
iedebereich
FlammpunktFlammpunkt
n.a.
EntzündlichkeitEntzündlichkeit n.a.
ZündtemperaturZündtemperat
ur
> 400 °C
Methode:
DIN 51794
SelbstentzündlichkeitSelbsten
tzündungstemperatur
Untere
ExplosionsgrenzeUntere
Explosionsgrenze
Obere
ExplosionsgrenzeObere
Explosionsgrenze
DampfdruckDampfdruck
n.a.
DichteDichte
ca. 2 g/cm3 (20 °C)
StampfdichteStampfdichte
ca. 50 g / l
nicht bestimmt
nicht bestimmt
n.a.
Methode:
DIN / ISO 787/11
Löslichkeit in
unlöslich
WasserWasserlöslichkeit
VerteilungskoeffizientVerteilun n.a.
gskoeffizient (nOktanol/Wasser)
Viskosität,
n.a.
dynamischViskosität,
dynamisch
10. STABILITÄT UND REAKTIVITÄT(10)
Stabilität und Reaktivität
Zu vermeidende Bedingungen
Zu vermeidende Bedingungen Bei Temperaturen > 300 °C geht die Hydrophobie verloren.
Zersetzungsprodukte
Gefährliche
Zersetzungsprodukte
Kohlenmonoxid, Kohlendioxid (CO2)
11. ANGABEN ZUR TOXIKOLOGIE(11)
Akute orale Toxizität
Akute orale Toxizität
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Angaben zur Toxikologie
LD50 Ratte: > 5.000 mg/kg
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Methode: Literatur
Akute inhalative Toxizität
Akute inhalative Toxizität
Hautreizung
Hautreizung
Augenreizung
Augenreizung
LC50 Ratte: > 0,477 mg/l / 4 h
Methode: analog OECD
(experimentell maximal erreichbare Konzentration)
Kaninchen / Literatur
nicht reizend
Kaninchen / Literatur
nicht reizend
Toxizität bei wiederholt. Verabreichung
Toxizität bei wiederholter
Oral
Verabreichung
keine negativen Effekte
Toxizität bei wiederholt. Verabreichung
inhalativ
keine irreversiblen Veränderungen und keine Anzeichen von Silikose
festgestellt
Gentoxizität in vitro
Gentoxizität in vitro
Ames-Test S. typhimurium / E. coli
negativ
Methode: Literatur
Kanzerogenität
Cancerogenität
Reproduktionstoxizität
Reproduktionstoxizität
Erfahrungen am
MenschenErfahrung am
Menschen
SDB(P27) / 16.01.2003 11:44
Silikose oder andere produktspezifische Erkrankungen der Atemwege
wurden beim Umgang mit dem Produkt nicht beobachtet.
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12. ANGABEN ZUR ÖKOLOGIE(12) Angaben zur Ökologie
Angaben zur Elimination (Persistenz und Abbaubarkeit)1. Angaben zur Elimination (Pers....)
Verhalten in Umweltkompartimenten2. Verhalten in Umweltkompartimenten
Ökotoxische Wirkungen3. Ökotoxische Wirkungen
Fisch-ToxizitätFischToxizität
LC50 (Brachydanio rerio): > 10.000 mg/l / 96 h
Methode:
OECD 203
Invertebraten-Toxizität
Daphnientoxizität
EC50 Daphnia magna: > 10.000 mg/l / 24 h
Methode:
OECD 202
Algentoxizität Algentoxizität
IC 50 scenedesmus subspicatus: > 10.000 mg/l / 72 h
Methode:
OECD 201
13. HINWEISE ZUR ENTSORGUNG
(13)
Entsorgung des Stoffes
Produkt
Kann unter Beachtung der notwendigen technischen Vorschriften nach Rücksprache mit dem
Entsorger und der zuständigen Behörde mit Hausmüll zusammen abgelagert werden.
Entsorg. ungereinigter Verpackungen
Verunreinigte Verpackungen
Gereinigte Verpackungsmaterialien den örtlichen Wertstoffkreisläufen zuführen.
Andere Länder: Nationale Regelungen beachten.
Abfallschlüssel Nr.Abfallschlüssel
Abfallschlüssel EU Für dieses Produkt kann keine Abfallschlüsselnummer gemäß europäischem
Abfallkatalog (EAK) festgelegt werden, da erst der Verwendungszweck durch den Verbraucher eine
Zuordnung erlaubt.
Abfallschlüssel EU Die Abfallschlüsselnummer ist in Absprache mit dem Entsorger / Hersteller / der
Behörde festzulegen.
14. ANGABEN ZUM TRANSPORT(14)
Nicht Gefahrgut Voll-/Leertransport
Gefahrgutvorschriften ADR
Gefahrgutvorschriften IMDG
Gefahrgutvorschriften IATA
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Gefahrgutvorschrift ADNR
Verladehinweise/Bemerkungen (Gefahrgutfreitexte)
Gefahrenhinweise/Vorschriftenübergreifende Verladetexte
Transport/weitere Angaben
Kein Gefahrgut im Sinne der Transportvorschriften.
Weitere Angaben für Transport
15. VORSCHRIFTEN(15)Vorschriften
Kennzeichnung gemäß EG-RichtlinienKennzeichnung gem. EG-Richtlinien
Kennzeichn.-Gesetzl. Grundlage/Liste
Gefahrensymbole
R-Sätze
S-Sätze
Zusatzinformationen
Weitere Angaben
Das Produkt ist aufgrund uns vorliegender Daten kein gefährlicher Stoff im
Sinne des Chemikaliengesetzes beziehungsweise der
Gefahrstoffverordnung in der zur Zeit gültigen Fassung.
Nationale VorschriftenNationale Vorschriften
Wassergefährdungsklasse
Wassergefährdungsklasse
nicht wassergefährdend Kenn-Nummer: 849
Einstufung durch Kommission zur Bewertung wassergefährdender Stoffe
(KBwS).
Ende Instanzenschleife TA Luft (Kompon.)
16. SONSTIGE ANGABEN(16)
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Weitere InformationWeitere Informationen
Abänderungen von der letzten Ausgabe werden am Rand hervorgehoben werden. Diese Version
ersetzt alle früheren Ausgaben.Änderungsmarkierungen
Mit den vorstehenden Angaben, die dem heutigen Stand unserer Kenntnisse und Erfahrungen
entsprechen, wollen wir unser Produkt im Hinblick auf etwaige Sicherheitserfordernisse beschreiben.
Wir verbinden damit jedoch keine Eigenschaftszusicherungen und
Qualitätsbeschreibungen.Schlußformel
SDB(P27) / 16.01.2003 11:44
file:///D|/Projekte/Hochschularbeiten/Downloads%20%20Dipl%20Arbeiten/kolmanitsch/Anlagen/carbopol.htm
63812 Carbopol EZ 2
(Ersatz für 63810 und 63811: Carbopol 980 und 954)
Carbopol EZ 2 kreuzvernetzt Polymere auf der Basis von modifizierter Acrylsäure.
Das Carbopol EZ 2 ist sehr leicht in Wasser dispergierfähig, ohne Klumpenbildung.
Lösungsempfehlung:
Man streut 20 - 50 g Carbopol EZ 2 in einen Liter warmes Wasser ohne Rühren ein, nach 2 bis max. 5 Minuten ist das Produkt
benetzt. Durch einfaches Umrühren erhält man gleichmässige Verteilung.
Angabe der Viskosität:
●
●
0,2%-ige Lösung mindestens 10.000, maximal 30.000 cP
0,5%-ige Lösung mindestens 50.000, maximal 70.000 cP
file:///D|/Projekte/Hochschularbeiten/Downloads%20%20Dipl%20Arbeiten/kolmanitsch/Anlagen/carbopol.htm [13.02.2004 08:06:38]
file:///D|/Projekte/Hochschularbeiten/Downloads%20%20Dipl%20Arbeiten/kolmanitsch/Anlagen/ethomeen%20c12.htm
780804 Ethomeen C/12, Kokosalkyl(dihydroxyethyl)amin
INCI-Name:
PEG-2 Cocamine
CAS-Nummer:
61791-31-9
Standardspezifikation
Analysenmethode
Aussehen bei 25° C:
flüssig
-
Äquivalentgewicht:
275 - 295
VV/3.001
Gewalt prim.u.sek.Amin(MG = 240/244):
< 3%
VV/1.001
Wassergehalt:
< 1%
VE/4.003
Farbzahl nach Gardner:
2
SC/2.001
Typische Daten
Trübungspunkt (ASTM D 2500):
4° C
Fliesspunkt (ASTM D 97):
0° C
Dichte bei 20° C:
870 kg/m3
Flammpunkt (Pensky-Martens c.c.):
> 200° C
HLB-Wert:
10
Alkylkettenverteilung:
C8
5%
C10
6%
C12
50%
C14
19%
C16
10%
C18
10%
Anwendungsgebiete:
Emulgator
file:///D|/Projekte/Hochschularbeiten/Downloads%20%20Dipl%20Arbeiten/kolmanitsch/Anlagen/ethomeen%20c12.htm [13.02.2004 08:06:38]
Sicherheitsdatenblatt
Version 002
Seite: 1/6
gemäß 91/155/EWG
B E N Z I N DAB*
überarbeitet am: 29.06.00
1 Stoff-/Zubereitungs- und Firmenbezeichnung
Angaben zum Produkt
Handelsname:
B E N Z I N DAB* (W U N D B E N Z I N)
Petrolether
Lieferant:
AUG. HEDINGER GmbH & Co.
Heiligenwiesen 26
D-70327 Stuttgart
Tel.: 0711/402050
Notfallauskunft:
Gemeinsames Giftinformationszentrum (GGIZ) Erfurt
c/o Klinikum Erfurt, Nordhäuser Str. 74, 99089 Erfurt
Tel.: 0361 / 730 730
2 Zusammensetzung/Angaben zu den Bestandteilen
Chem. Gruppen-Bezeichnung:
Allgemeine Bezeichnung:
Synonyme:
CAS-NR.:
Aliphatischer Kohlenwasserstoff
SBP
Special boiling point spirit 40/65
64742-49-0
Gefahrenbestimmende
Komponenten
n-Hexan
CAS-NR.
Sonstige Angaben:
EG-Gefahren- R-Sätze
symbol(e)
Gehalt
110-54-3
nach 25. ATP: F, Xn ,N
< 3 % (m/m)
R11-38-48/20-6265-66-67-−51/53
[vor der 25.ATP F,Xn
R11-R48/20]
Basierend auf Daten für dieses Produkt. Die Gefahrenmerkmale
der gefährlichen Bestandteile ändern nicht die Klassifizierung
oder die Ratschläge für die Handhabung aus diesem
Sicherheitsdatenblatt.
3 Mögliche Gefahren
Gefahren für die
menschliche Gesundheit:
Sicherheitsrisiken:
Gefahren für die Umwelt:
Beim Verschlucken mit anschließendem Erbrechen kann
Aspiration in die Lunge erfolgen, was zum Ersticken oder zu
toxischem Lungenödem führt. Führt bei hohen Dampfkonzentrationen zur Bewußtlosigkeit. Reizt die Haut
Leichtentzündlich. Bei Gebrauch Bildung explosionsfähiger /
leichtentzündlicher Dampf-Luftgemische möglich. Während
der Handhabung kann elektrostatische Aufladung erfolgen.
Giftig für Wasserorganismen. Kann in Gewässern längerfristig
schädliche Wirkungen haben.
4 Erste-Hilfe-Maßnahmen
Symptome und Effekte:
Erste Hilfe - Einatmen:
Erste Hilfe - Haut:
Erste Hilfe - Augen:
Erste Hilfe - Verschlucken:
Hinweise für den Arzt:
Kopfschmerzen, Schwindelgefühl, Übelkeit, Bewußtlosigkeit,
Trockene Haut. Hautkontakt kann Reizung verursachen.
Betroffenen an die frische Luft bringen. Wenn keine rasche
Erholung eintritt, Arzt hinzuziehen.
Haut mit Wasser und Seife abwaschen.
Augen mit Wasser ausspülen.
Kein Erbrechen herbeiführen. Nichts zu trinken geben. Sofort
Arzt hinzuziehen !
Langanhaltende oder wiederholte Exposition kann Hautentzündung (Dermatitis) verursachen. Beim Verschlucken mit anschließendem Erbrechen kann Aspiration in die Lunge erfolgen,
was zu toxischem Lungenödem führt. Verursacht Depression
des Zentralnervensystems.
*) Deutsches Arzneibuch in seiner gültigen Fassung
**) Umsetzung der 25. ATP (das Produkt als solches ist jedoch in der 25. ATP nicht gelistet)
Version 002
Seite: 2/6
gemäß 91/155/EWG
B E N Z I N DAB*
5 Maßnahmen zur Brandbekämpfung
Spezielle Gefahren:
Löschmittel:
Ungeeignete Löschmittel:
Schutzausrüstung:
Sonstige Angaben:
Bei unvollständiger Verbrennung kann Kohlenmonoxid
freigesetzt werden. Schwimmt auf und kann sich an der
Wasseroberfläche wieder entzünden. Dämpfe sind schwerer als
Luft und verbreiten sich am Boden. Entzündung über größere
Entfernung möglich.
Schaum, Sprühwasser oder Wassernebel.
Trockenlöschpulver, Kohlendioxid, Sand oder Erde sind nur bei
kleinen Bränden einsetzbar.
Keinen scharfen Wasserstrahl verwenden.
Vollschutzanzug und Preßluftatemschutzgerät
Gefährdete Behälter mit Wassersprühstrahl kühlen.
6 Maßnahmen bei unbeabsichtigter Freisetzung:
Personenbezogene
Vorsichtsmaßnahmen:
Kontakt mit Haut und Augen vermeiden. Dämpfe nicht einatmen. Offene Flammen auslöschen. Zündquellen entfernen.
Nicht rauchen ! Funken vermeiden. Alle Personen, deren Anwesenheit nicht erforderlich ist, aus dem Gefahrengebiet entfernen. Vorsichtsmaßnahmen gegen elektrostatische
Aufladung treffen. Lecks schließen, möglichst ohne ein persönliches Risiko einzugehen.
Schutzausrüstung:
Handschuhe aus Nitrilkautschuk, Stulpenhandschuh, Jacke und
Hose aus Nitrilkautschuk, Sicherheitsstiefel aus Gummi,
knielang tragen.
Hinweise zum Atemschutz in Kapitel 8.
Umweltschutzmaßnahmen:
Kontamination von Wasser und Boden verhindern. Eindringen
in das Abwassersystem, in Flüsse oder Oberflächengewässer
durch Errichten von Sperren aus Sand bzw. Erde oder durch
andere geeignete Absperrmaßnahmen verhindern.
Maßnahmen nach Verschütten:
– kleine Mengen
– große Mengen
Weitere Angaben:
Mit Sand, Erde oder saugfähigem Material aufnehmen bzw.
eindämmen. In einen gekennzeichneten und verschließbaren
Behälter überführen und anschließend sicher deponieren.
Undichte Behälter in ein gekennzeichnetes Faß oder Bergungsfaß hineinstellen. Verunreinigte Oberfläche mit Reinigungsmittel
säubern. Waschflüssigkeit als Sondermüll behandeln.
Zwecks Aufarbeitung oder Deponie in einen gekennzeichneten,
verschließbaren Behälter überführen. Behandlung von
Rückständen wie beim Verschütten kleiner Mengen.
Explosionsgefahr. Feuerwehr und Wasserschutzbehörden informieren, wenn die Flüssigkeit in die Kanalisation eindringt.
Dämpfe können mit Luft ein explosives Gemisch bilden.
Kapitel 13 für Hinweise zur Entsorgung beachten.
7 Handhabung und Lagerung
Handhabung:
Verarbeitungstemperatur:
Längeren oder wiederholten Kontakt mit Haut vermeiden.
Dämpfe, Sprühnebel, Nebel nicht einatmen. Alle offenen
Flammen auslöschen, Zündquellen beseitigen, Funkenbildung
vermeiden. Nicht rauchen. Maßnahmen gegen elektrostatische
Aufladung treffen. Alle Vorrichtungen erden. Nicht in die
Kanalisation gelangen lassen.
Umgebungstemperatur.
Version 002
Seite: 3/6
gemäß 91/155/EWG
B E N Z I N DAB*
Lagerung:
Lagertemperatur:
Umfüllen:
Empfohlene Materialien:
Ungeeignete Materialien:
Behälter fest verschlossen halten und an einem gut belüfteten
Ort aufbewahren. Von direkter Sonneneinstrahlung und anderen
Wärme- oder Zündquellen fernhalten. Im Lagerbereich nicht
rauchen.
Umgebungstemperatur.
Vorsichtsmaßnahmen gegen elektrostatische Aufladung treffen.
Alle Vorrichtungen erden. Nicht im freien Fall befüllen. Keine
Druckluft zum Befüllen, Entladen oder Handhaben benutzen.
Verdrängungspumpen müssen mit Sicherheitsventil ausgerüstet
sein. Strömungsgeschwindigkeit beim Pumpen begrenzen, um
elektrostatische Aufladung zu vermeiden. Weitere Hinweise zur
Verladung auf Anfrage.
Als Werkstoffe für Behälter oder zur Innenauskleidung unlegierter Stahl, Edelstahl benutzen. Als Anstrichfarbe für die Innenauskleidung von Behältern geeignet: Zinksilikat, Epoxidharz.
Längeren Kontakt mit Natur-, Butyl- oder Nitrilkautschuk
vermeiden.
8 Expositionsbegrenzung und persönliche Schutzausrüstung
Grenzwert nach TRGS 900/901:
Kohlenwasserstoffgermische, additivfrei, Gruppe5: (Stand 2000)
3
MAK = 600 mg/m
MAK = 170 ppm
Technische Schutzmaßnahmen:
Nur in gut gelüfteten Bereichen verwenden.
Atemschutz:
Wenn technische Kontrollen die Luftschadstoffkonzentration
nicht unter dem für den Atemschutz kritischen Wert halten
können, ist der geeignete Atemschutz unter Berücksichtigung
der speziellen Arbeitsbedingungen und der jeweiligen gesetzlichen Vorschriften auszuwählen und mit den Herstellern von
Atemschutzgeräten abzuklären.
Wenn normale Filtersysteme geeignet sind, unbedingt die geeignete Kombination von Filter und Maske auswählen und einen
Filter für organische Gase und Dämpfe (Siedepunkt < 65°C)
verwenden.
Atemschutzgeräte dann anlegen, wenn normale Filtersysteme
ungeeignet sind, z.B. bei hohen Luftkonzentrationen, bei Risiko
von Sauerstoffmangel oder in abgeschlossenen Räumen.
Handschuhe aus Nitrilkautschuk
Korbbrille
Chemikalienbeständige Sicherheitsschuhe oder -stiefel.
Standard-Arbeitskleidung
Handschutz:
Augenschutz:
Körperschutz:
9 Physikalische und chemische Eigenschaften
Aggregatzustand:
Farbe:
Geruch:
Siedepunkt/Siedebereich:
Fließpunkt (‚Pour Point‘)
Flammpunkt:
Selbstentzündungstemperatur:
Explosionsgrenzen:
Dampfdruck:
Relative Verdunstungszahl :
Flüssig
Farblos
Paraffinisch
typisch 44 - 62 °C (ASTM D−1078)
typisch −150 °C (ASTM D−97)
typisch -43 °C (IP 170)
392 °C (ASTM E−659) und 280 °C (DIN 51794)
untere: 1,1 % (v/v) obere: 7,5 % (v/v)
33000 Pa bei 20 °C
115 kPa bei 50°C
9,6 (ASTM D 3539, n-Butylacetat = 1)
Version 002
Seite: 4/6
gemäß 91/155/EWG
B E N Z I N DAB*
Dichte:
Wasserlöslichkeit:
Verteilungskoeffizient:
Kinemat. Viskosität:
Oberflächenspannung:
Mittleres Molekulargewicht:
Gehalt an organ. Kohlenstoff:
3
658 kg/m bei 15 °C (ASTM D−4052)
3
645 - 660 kg/m bei 15 °C (ASTM D−1298)
Unlöslich.
2,9 - 4 (geschätzt) [n-Octanol/Wasser (log pow)]
2
typisch 0,41 mm /s bei 25 °C (ASTM D−445)
typisch 16,8 mN/m bei 20°C (ASTM D−971)
82
84 % (m/m)
10 Stabilität und Reaktivität
Stabilität:
Zu vermeidende Bedingungen:
Zu vermeidende Materialien:
Gefährliche Zersetzungsprodukte:
Stabil unter normalen Bedingungen.
Wärme, Flammen und Funken.
Keine bekannt.
Keine bekannt.
11 Angaben zur Toxikologie
Grundlagen der Bewertung:
Die Angaben basieren auf den Daten der Einzelkomponenten
und der Toxikologie ähnlicher Produkte.
Akute Toxizität (LD 50) Oral:
praktisch nicht giftig; LD5O > 2000 mg/kg (geschätzt)
Akute Toxizität (LD 50) Dermal:
praktisch nicht giftig; LD5O > 2000 mg/kg (geschätzt).
Akute Toxizität (LC 50) Einatmung: praktisch nicht giftig; LC5O > 5 mg/l (geschätzt).
Hautreizung:
Kein Reizstoff gemäß den EU−Richtlinien
Augenreizung:
Keine Reizwirkung.
Hautsensibilisierung:
Keine Sensibilisierung durch Hautkontakt.
Mutagenität:
Keine Mutagenität (geschätzt).
Reproduktionstoxizität:
Keine Beeinträchtigung der Fruchtbarkeit zu erwarten.
Erfahrungen am Menschen:
Langanhaltender oder wiederholter Kontakt kann die Haut entfetten und zu Hautentzündung (Dermatitis) führen. Beim Verschlucken mit anschließendem Erbrechen kann Aspiration in die
Lunge erfolgen, was zum Ersticken oder zu toxischem Lungenödem führt.
12 Angaben zur Ökologie
Grundlagen der Bewertung:
Für dieses Produkt stehen nur unvollständige ökotoxikologische
Daten zur Verfügung. Die folgenden Informationen basieren
teilweise auf Erkenntnissen der Komponenten sowie ökotoxikologischen Eigenschaften vergleichbarer Produkte.
Mobilität:
Schwimmt auf der Wasseroberfläche. Verdunstet innerhalb
eines Tages von Wasser- oder Bodenoberflächen.
Persistenz / Abbaubarkeit:
Biologisch potentiell abbaubar.
Schnelle photochemische Oxidation in der Luft.
Halbwertszeit in der Umwelt: 1 – < 10 Tagen (geschätzt).
Bioakkumulation:
Bioakkumulation potentiell möglich.
Akute Toxizität (Fisch):
Giftig (geschätzt), 1 < LC/EC/IC < 10 mg/l
Akute Toxizität (wirbellose Tiere): Giftig (geschätzt), 1 < LC/EC/IC < 10 mg/l
Akute Toxizität (Algen):
Akute Toxizität (Bakterien):
Verhalten in Kläranlagen:
Sonstige Angaben:
Wassergefährdungsklasse:
Wegen der schnellen Verdunstung des Lösemittels stellt das
Produkt keine signifikante Gefahr für Wasserlebewesen dar.
1 (schwach wassergefährdend) nach VwVwS, Anh. 2, Nr. 27.
Version 002
Seite: 5/6
gemäß 91/155/EWG
B E N Z I N DAB*
13 Hinweise zur Entsorgung
Vorsichtsmaßnahmen:
Abfall−Entsorgung, Ent−
sorgung von Restmengen:
Entsorgung von Behältern:
Nationale Vorschriften:
Vor Handhabung des Produktes oder Behälter Kapitel 7
beachten.
Rückgewinnung oder Recycling, wenn möglich.
Anderenfalls Verbrennung.
Behälter vollständig entleeren. Nach dem Entleeren an
sicherem Platz belüften, außer Reichweite von Funken und
Feuer. Rückstände können eine Explosionsgefahr darstellen.
Ungereinigte Behälter nicht durchlöchern, zerschneiden oder
schweißen. Behälter einer Rekonditionierung oder Aufarbeitung
zuführen.
Diese Empfehlungen sind für eine sichere Entsorgung angemessen. Es gelten aber in jedem Fall die behördlichen Vorschriften. Europäischen Abfallkatalog beachten. Der
Abfallerzeuger ist für die richtige Verschlüsselung und
Bezeichnung seiner Abfälle verantwortlich
14 Angaben zum Transport
Landtransport ADR/RID/GGVS/GGVE:
Klasse:
3
Ziffer/Buchstabe:
2(B)
Gefahrenzettel:
3 (Feuergefährlich, entzündbare flüssige Stoffe)
Techn. Bezeichnung:
Kohlenwasserstoffe, flüssig, n.a.g., (Solvent Naphtha)
Kemler-Zahl:
33
UN-Nr.:
3295
Seeschifftransport IMDG/GGVSee
UN-Nr.:
3295
Klasse:
3.1
PG:
II
Gefahrenzettel:
3 (Feuergefährlich, entzündbare flüssige Stoffe)
Marine pollutant
Nein
Techn. Bezeichnung
HYDROCARBONS, LIQUID, N.O.S (SOLVENT NAPHTHA)
Lufttransport ICAO/IATA
UN-NR.:
Klasse:
PG:
Gefahrenzettel:
Techn. Bezeichnung:
3295
3
II
Flammable Liquid
HYDROCARBONS, LIQUID, N.O.S (SOLVENT NAPHTHA)
15 Vorschriften
Stoffname gemäß EG-Richtl.:
EG-Einstufung:
EG-Gefahrensymbole:
Naphtha (Erdöl), hydrogeniert, leicht
Leicht Entzündlich, Gesundheitsschädlich, Umweltgefährlich
F
Leichtentzündlich
Xn
Gesundheitsschädlich
N
Umweltgefährlich
R-Sätze:
11
38
51/53
65
67
Leichtentzündlich.
Reizt die Haut bei großflächiger/ständiger Berührung.**
Giftig für Wasserorganismen, kann in Gewässern
längerfristig schädliche Wirkungen haben.
Gesundheitsschädlich: kann beim Verschlucken
Lungenschäden verursachen.
Dämpfe können Schläfrigkeit und Benommenheit ver−
ursachen. **
Version 002
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gemäß 91/155/EWG
B E N Z I N DAB*
S-Sätze:
02
09
16
23
24
33
61
62
Hinweis zur Einstufung:
Darf nicht in die Hände von Kindern gelangen
Behälter an gut belüfteten Orten aufbewahren.
Von Zündquellen fernhalten. - Nicht rauchen.
Dämpfe nicht einatmen.
Großflächige/ständige Berührung mit der Haut vermeiden
Maßnahmen gegen elektrostatische Aufladung treffen.
Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen / Sicherheitsdatenblatt zu Rate ziehen.
Bei Verschlucken kein Erbrechen herbeiführen. Sofort
ärztlichen Rat einholen und Verpackung oder dieses
Etikett vorzeigen.
nach 94/69/EG (21. ATP): Der Benzolgehalt des
Produktes ist < 0,1%. Es gilt die Anmerkung P, die
Einstufung und Kennzeichnung als krebserzeugend
(R45) ist somit nicht notwendig.
TSCA:
AICS (Australien):
DSL(Canada):
EINECS / ELINCS (EU):
EU-Nr. (gemäß Anhang 1):
MITI-Nr.:
TCCL (Korea):
PICCS (Philippinen):
Verzeichnet.
Verzeichnet.
Verzeichnet.
265-151-9
649-328-00-1
9-1694
9206-739
Verzeichnet.
Wassergefährdungsklasse:
1 (schwach wassergefährdend)
nach VwVwS, Anh. 2, Nr. 27.
Störfallverordnung:
Stoffgruppe 2 (leichtentzündliche Flüssigkeiten)
Mengenschwellen beachten.
AI.
VbF:
BG-Merkblatt:
Hommel:
Handbuch der gefährlichen Güter:
Kühn-Birett:
Merkblätter gefährliche Arbeitsstoffe:
M017.
38c
K O32.
16 Sonstige Angaben:
Die Angaben stützen sich auf den heutigen Stand unserer Kenntnisse und dienen dazu, das
Produkt im Hinblick auf die zu treffenden Sicherheitsvorkehrungen zu beschreiben. Sie stellen
jedoch keine Zusicherung von Produkteigenschaften dar und begründen kein vertragliches
Rechtsverhältnis.
Wesentliche Änderungen: sind durch Kursivschrift gekennzeichnet
Änderungen in dieser Ausgabe:
Abschnitt 2:
für den Bestandteil n−Hexan: Einstufung nach der 25. ATP
Abschnitt 3:
Verschlucken: Erbrechen, Aspirationsgefahr
Abschnitt 8:
Schutzausrüstung
Abschnitt 15: Hinweis auf die ab 1.7.2000 verbindliche 25. ATP (vergleiche Fußzeile!).
Wassergefährdungsklasse nach VwVwS.
Änderungen in der vorhergehenden Ausgabe:
Abschnitt 8:
MAK-Wert nach TRGS 900/901
Basis: DSC 05/2000
Ansprechpartner: Dr. E. Haug
Sh ell Ch em ica ls
Da ta Sh eet
IS 2 .3 .2
Issued July 2001, 8 th Edition
Product name
Description
Specification items
SHELLSO L T
SHELLSOL T is an isoparaffinic hydrocarbon solvent with a characteristically low
odour.
CAS Registry Number
64741-65-7
EINECS Number
265-067-2
Property
Unit
Test method
Typical
___________________________________________________________________
Density at 15°C
kg/ L
Colour (Saybolt)
Typical properties
ASTM D4052
0.761
ASTM D156
+30
Initial boiling point
°C
ASTM D1078
187
Dry point
°C
ASTM D1078
213
Flash point (PMCC)
°C
ASTM D93
60
Benzene
mg/ kg
G.C.
<5
Aromatics
% v/ v
SMS 2728
0.01
Property
Unit
Test method
Value
___________________________________________________________________
Paraffins
% m/ m
>98
Naphthenics
% m/ m
1
Sulphur content
mg/ kg
SMS 1897
< 0.5
Water content
%
ASTM D1744
< 0.005
Bromine index
mgBr/ 100g
ASTM D2710
500
1
Non-volatile matter
mg/ 100ml
ASTM D1353
Copper corrosion,
3h/ 100°C
ASTM D130
1
Doctor test
°C
ASTMD4952
negativee
Typical
properties
physical Property
Unit
Test method
Value
___________________________________________________________________
Density at 15°C
kg/ L
ASTM D4052
0.761
Initial boiling point
°C
ASTM D1078
187
Dry point
°C
ASTM D1078
213
Flash point (PMCC)
°C
ASTM D93
60
ASTM D1218
1.424
Refractive index
Vapour pressure at 0°C
kPa
0.03
Vapour pressure at 20°C
kPa
0.11
Antoine constant A
6.71506
(1)
Antoine constant B
2009.16
Antoine constant C
241.89
Temperature limits for the
°C
+40 to +140
Antoine equation
Pour point
°C
ASTM D97
<-30
Coefficient of cubic expansion
10 -4/ °C
8
Thermal conductivity
W/ m/ °C
0.13
Specific heat
kJ/ kg/ °C
2.0
Heat of combustion
kJ/ kg
-43835
Electrical conductivity
pS/ m
ASTM D4308
Dielectric constant
<0.15
2.0
Surface tension
mN/ m
ASTM D971
23.5
Kinematic viscosity at 25°C
mm2/ s
ASTM D445
1.85
Average molecular weight
172
All properties at 20°C unless otherwise stated.
(1)
The vapour pressure, between the specified temperature limits, can be calculated using the
Antoine equation: log 10 P = A - B , where P is the vapour pressure in kPa and T is the
temperature
Solvent properties
in
°C
T+C
T+C
Property
Unit
Test method
Value
___________________________________________________________________
Kauri-butanol value
Aniline point
°C
Hildebrand solubility parameter
(cal/ cm³)½
ASTM D1133
26
ASTM D611
85
7.35
Hydrogen bonding index
0
Fractional polarity
0
Relative evaporation rate (nBuAc=1)
Relative evaporation rate (ether=1)
ASTM D3539
DIN 53170
110
0.09
Safety data
Property
Unit
Test method
Value
___________________________________________________________________
Flash point (PMCC)
°C
Lower explosion limit in air
% v/ v
0.6
Upper explosion limit in air
% v/ v
6.0
Autoignition temperature
°C
Saturated vapour concn. At 20°C g/ m³
ASTM D93
ASTM E659
430
Calculated
7
Transport:
ADR/ RID class/ item/ label
IMO UN number/ label
class/ packing group
EC user label:
Symbol
Risk phrases
Safety phrases
Test methods
60
3/ 31©/ 3
3295/ 3
3.3/ III
Xn
65,66
23, 24, 62
ASTM methods are published by the American Society for Testing and Materials,
1916 Race Street, Philadelphia, Pa 19103, USA, and are available in Europe from
ASTM European Office, 27-29 Knowl Piece, Wilbury Way, Hitchin, Herts, SG4
OSX, UK.
DIN methods are published by Beuth Verlag GmbH., Burggrafenstrasse 4-7, D1000,
Berlin, Germany.
SMS methods are issued by Shell International Chemicals B.V., Shell Research and
Technology Centre, Amsterdam, The Netherlands, and are available through your
local Shell Chemicals company.
The test methods mentioned above are not necessarily those used for routine quality
control analysis, but such methods have been validated against them.
Specifications
SHELLSOL T can be supplied to meet the requirements of the US Food and Drug
Adminstration (FDA) specifications published in the code of Federal Regulations
Chapter 21, Subchapter B, Parts 172.882, 178.3530, 172.884, 178.3620 (b)
(1) (ii)y, 178.3650, and the medical use requirements of the German DAB.10.
Users of SHELLSOL T should make their own assessment of compliance with the
relevant regulation.
Composition
SHELLSOL T is manufactured to the highest standards. It does not contain detectable
quantities of polycyclic aromatics, heavy metals or chlorinated compounds.
Applications
SHELLSOL T is used in applications where its low odour is of value. These include
household products (cleaners, lighter fuels, waxes and polishes), surface coatings,
printing inks, industrial and textile cleaning, photocopier toner dispersants, cosmetics,
pesticide formulations, wallpaper manufacture etc.
Storage and handling
Provided proper storage and handling precautions are taken we would expect
SHELLSOL T to be stable for at least 12 months.
Advice on storage and handling may be obtained from your local Shell Chemicals
company. SHELLSOL T is available from Shell in bulk and drums; details available
on request.
Hazard information
SHELLSOL T is not considered hazardous.
For advice please refer to Safety Data Sheet IS 2.3.2.
Warranty
Shell companies have their own separate identities, but in this publication the
collective expressions “ Shell” and “ Group” are sometimes used for convenience in
contexts where the reference is to companies of the Royal Dutch/ Shell Group in
general or where no useful purpose is served by identifying the particular Shell
company or companies.
The information contained in this publication is, to the best of our knowledge, true
and accurate, but any recommendations or suggestions which may be made are
without guarantee, since the conditions of use are beyond our control. Furthermore,
nothing contained herein shall be constructed as a recommendation to use any
product.
Product code
Q7412
New Template is a Shell trade mark.
The expression ‘Shell Chemicals’ refers to the companies of the Royal Dutch / Shell Group which are
engaged in chemical businesses. Each of the companies which make up the Royal Dutch / Shell
Group of companies is an independent entity and has its own separate identity.
The information contained in this publication is to the best of our knowledge, true and accurate, but
any recommendations or suggestions which may be made are without guarantee, since the conditions
of use are beyond our control. Furthermore, nothing contained herein shall be construed as a
recommendation to use any product in conflict with existing patents covering any material or its use.
DIGGERS AUSTRALIA PTY LTD
7 Marmalade way
Maddington WA 6109
Tel: 08 9452 5200
Fax: 08 9493 1214
MATERIAL SAFETY DATA SHEET
This MSDS supersedes MSDS dated 12 November, 1996
IDENTIFICATION
PRODUCT NAME:
WHITE SPIRIT
UN Number:
Class:
Subsidiary Risk:
Packaging Group:
EPG:
Hazchem Code:
Poison Schedule:
1300
3
n/a
III
3A1
3[Y]
5
OTHER NAMES: Turpentine Substitute
HAZARDOUS ACCORDING TO CRITERIA OF WORKSAFE AUSTRALIA
PRODUCT CODE:
WHS
USE:
Product is for use as a solvent.
PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Water white liquid with a slight kerosene odour
BOILING POINT: 147ºC - 196ºC
MELTING POINT: No data available
VAPOUR PRESSURE: 6mmHg
VAPOUR DENSITY: >1
SPECIFIC GRAVITY: 0.79
SOLUBILITY (WATER): Negligible (<0.1% mass)
FLASH POINT: 37ºC
EXPLOSION LIMITS: LEL: 0.9% UEL: 7.0%
VOLATILES: 100%
pH: Not pertinent
INGREDIENTS
Medium aliphatic petroleum solvent
64742-88-7
>60%
Light aromatic petroleum solvent
64742-95-6
10-30%
HEALTH HAZARD INFORMATION
ACUTE
INGESTION
Irritating. May cause symptoms of stomach pain, nausea and vomiting. Ingestion of large doses may cause
unconsciousness. If vomiting occurs after ingestion, small droplets of the liquid may enter the lungs (aspiration) with
the risk of chemical pneumonia being induced.
EYE
Liquid may cause moderate to severe eye irritation, vapour is irritating.
SKIN
Irritating. Contact with the product may defat the skin and contribute to dermatitis.
white spirit.doc
Revised: 6 October, 2000
Page 1 of 4
Date Issued: 19 October, 2000
WHITE SPIRIT
Health Hazard Information continued
INHALATION
Irritating. Inhalation may cause headache, nausea and dizziness. Higher concentrations may cause unconsciousness
and coma. Death may result from severe and continued over-exposure.
CHRONIC
Inhalation and ingestion are the routes of entry into the body. The product defats the skin and prolonged or repeated
contact may contribute to dermatitis.
Medium aliphatic petroleum solvent: TCLo (inhaled, human): 600mg/m3/8H; LC50 (inhaled, rat): 3400ppm/4H; Eye
(human): 800ppm/15min: irritant effects.
Light aromatic petroleum solvent: LD50 (oral, rat): 8400mg/Kg..
ADVICE TO DOCTOR
Because of the risk of aspiration, gastric lavage should only be undertaken after endotracheal intubation.
FIRST AID PROCEDURES
INGESTION
NEVER GIVE AN UNCONSCIOUS PERSON ANYTHING TO DRINK NOR ATTEMPT TO INDUCE VOMITING. If person is
conscious, rinse mouth out with water ensuring that mouth wash is not swallowed. Give about 250mL (2 glasses) of
water to drink. DO NOT attempt to induce vomiting. Seek URGENT medical attention.
EYE
Hold eyelids open and rinse the eye continuously with a gentle stream of clean running water for at least fifteen
minutes. Seek medical attention.
SKIN
Remove contaminated clothing and wash thoroughly with soap and water. Use water alone, if soap is unavailable.
Apply a moisturising hand cream, if available. Seek medical attention if any soreness or inflammation of the skin
persists or develops later. Launder affected clothing before re-use.
INHALATION
Remove to fresh air. Keep warm and at rest. If breathing is laboured, hold in a half upright position (this assists
respiration). Apply artificial respiration if breathing has stopped. Seek URGENT medical attention for all but the most
minor cases of over-exposure.
PRECAUTIONS FOR USE
ENGINEERING CONTROL
Exhaust ventilation may be required to maintain vapour levels below the appropriate exposure standard. Otherwise,
the work area should be very well ventilated.
PERSONAL PROTECTION
Safety goggles, overalls and polyvinyl chloride (PVC) gloves. A respirator with organic vapour filter will be required
unless the work area is well ventilated. In confined or poorly ventilated areas use air supplied breathing apparatus.
N.B. TAKE THE LIMITS OF ABSORPTION CAPACITY INTO ACCOUNT. CHANGE FILTERS REGULARLY.
FLAMMABILITY
Flammable. Solvent vapours can form flammable mixtures with air. May evolve toxic fumes if heated or burned. The
product may react with strong oxidising agents such as liquid or powdered chlorine.
white spirit.doc
Page 2 of 4
WHITE SPIRIT
EXPOSURE STANDARDS
Oil mist E.S. TWA: 5mg/m3.
SAFE HANDLING PROCEDURES
STORAGE
Class 3 Flammable Liquids should not be transported or stored with goods of: Class 1 (Explosives), Class 2.1
(Flammable Gases, where both flammable liquid and flammable gases are in bulk), Class 2.3 (Poisonous Gases), Class
4.2 (Spontaneously Combustible Substances), Class 5.1 (Oxidising Agents), Class 6 (Poisonous (toxic) Substances,
where the flammable liquid is nitromethane), Class 7 (Radioactive Substances).
Store in a flammable liquids area: designated no smoking, away from all sources of ignition, out of direct sunlight in a
cool well ventilated area below 25ºC. Higher temperatures may cause pressure build up inside containers. Protect
containers against physical damage. Ventilation along the floor is advised for bulk storage.
SPILLS & DISPOSAL
SPILLS: Ensure that there are no sources of ignition present. Remove unnecessary personnel from the affected area.
Wear protective equipment as specified for handling. If possible, dam the spill. Cover with an absorbent such as earth,
sand or a commercial oil absorber. Sweep up and collect in sealable containers. Dispose to approved land-fill.
DISPOSAL: If possible, return to supplier. Otherwise, dispose by controlled incineration or to approved land-fill.
FIRE EXPLOSION
Flammable. Solvent vapours can form explosive mixtures with air in poorly ventilated conditions. Containers may
explode if heated. Vapour is heavier than air and may travel along the ground, distant ignition is possible.
Wear self contained breathing apparatus. If possible remove containers from the vicinity of the fire. Otherwise keep
containers as cool as possible by spraying with water, from a protected position. Water is not effective for fire fighting
and direct contact with water should be avoided. Extinguish using foam, powder (bicarbonate or ammonium phosphate
based) or carbon dioxide.
OTHER INFORMATION
HAZARD CLASSIFICATION
Xn
Harmful
RISK PHRASES
R65
Harmful: May cause lung damage if swallowed.
SAFETY PHRASES
S2
Keep out of reach of children.
S23
Do not breathe vapour.
S24
Avoid contact with skin.
S62
If swallowed, do not induce vomiting; seek medical advice immediately and show this container or
label
white spirit.doc
Page 3 of 4
WHITE SPIRIT
CONTACT POINT
Customer Service
(08) 9452 5200
Emergency Advice
(08) 9452 5200
8.00 - 5.30 Mon – Fri
(08) 9242 3311
All Other Times
white spirit.doc
Western Standard Time
Page 4 of 4

Pflege- und Maßnahmenkonzert für Bronzen im Freien Cm Beisriel

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