Vol. 14, No 4
Transcription
Vol. 14, No 4
Polish Academy of Sciences University of Engineering and Economics in Rzeszów University of Life Sciences in Lublin Faculty of Production Engineering TEK A COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE AN INTERNATIONAL QUARTERLY JOURNAL ON MOTORIZATION, VEHICLE OPERATION, ENERGY EFFICIENCY AND MECHANICAL ENGINEERING Vol. 14, No 4 LUBLIN–RZESZÓW 2014 Editor-in-Chief: Eugeniusz Krasowski Assistant Editor: Andrzej Kusz Associate Editors 1. Motorization and vehicle operation: Kazimierz Lejda, Rzeszów, Valentin Mohyła, Lugansk 2. Mechanical engineering: Paweł Nosko, Lugańsk, Adam Dużyński, Częstochowa 3. Energy efficiency: Witold Niemiec, Rzeszów, Stepan Kovalyshyn, Lviv 4. Mathematical statistics: Andrzej Kornacki, Lublin Editorial Board Dariusz Andrejko, Lublin, Poland Andrzej Baliński, Kraków, Poland Volodymyr Bulgakow, Kiev, Ukraine Karol Cupiał, Częstochowa, Poland Aleksandr Dashchenko, Odessa, Ukraine Kazimierz Dreszer, Lublin, Poland Valeriy Dubrowin, Kiev, Ukraine Valeriy Dyadychev, Lugansk, Ukraine Dariusz Dziki, Lublin, Poland Sergiey Fedorkin, Simferopol, Ukraine Jan Gliński, Lublin, Poland Bohdan Hevko, Ternopil, Ukraine Jerzy Grudziński, Lublin, Poland Aleksandr Hołubenko, Lugansk, Ukraine L.P.B.M. Jonssen, Groningen, Holland Józef Kowalczuk, Lublin, Poland Volodymyr Kravchuk, Kiev, Ukraine Elżbieta Kusińska, Lublin, Poland Janusz Laskowski, Lublin, Poland Nikołaj Lubomirski, Simferopol, Ukraine Andrzej Marczuk, Lublin, Poland Jerzy Merkisz, Poznań, Poland Ryszard Michalski, Olsztyn, Poland Aleksandr Morozov, Simferopol, Ukraine Leszek Mościcki, Lublin, Poland Janusz Mysłowski, Szczecin, Poland Ilia Nikolenko, Simferopol, Ukraine Paweł Nosko, Lugansk, Ukraine Gennadij Oborski, Odessa, Ukraine Yurij Osenin, Lugansk, Ukraine Marian Panasiewicz, Lublin, Poland Sergiey Pastushenko, Mykolayiv, Ukraine Iwan Rohowski, Kiev, Ukraine Marek Rozmus, Lublin, Poland Povilas A. Sirvydas, Kaunas, Lithuania Wołodymyr Snitynskiy, Lviv, Ukraine Stanisław Sosnowski, Rzeszów, Poland Ludvikas Spokas, Kaunas, Lithuania Jarosław Stryczek, Wrocław, Poland Michaił Sukach, Kiev, Ukraine Aleksandr Sydorchuk, Kiev, Ukraine Wojciech Tanaś, Lublin, Poland Viktor Tarasenko, Simferopol, Ukraine Giorgiy F. Tayanowski, Minsk, Bielarus Andrey Tevyashev, Kharkiv, Ukraine Henryk Tylicki, Bydgoszcz, Poland Denis Viesturs, Ulbrok, Latvia Dmytro Voytiuk, Kiev, Ukraine Janusz Wojdalski, Warszawa, Poland Anatoliy Yakovenko, Odessa, Ukraine Tadeusz Złoto, Częstochowa, Poland All the articles are available on the webpage: http://www.pan-ol.lublin.pl/wydawnictwa/Teka-Motrol.html All the scientific articles received positive evaluations by independent reviewers Linguistic consultant: Małgorzata Wojcieszuk Typeset: Adam Niezbecki Cover design: Hanna Krasowska-Kołodziej © Copyright by Polish Academy of Sciences 2014 © Copyright by University of Engineering and Economics in Rzeszów 2014 © Copyright by University of Life Sciences in Lublin 2014 In co-operation with Volodymyr Dahl East-Ukrainian National University of Lugansk 2014 Editorial Office address Polish Academy of Sciences Branch in Lublin Pałac Czartoryskich, Plac Litewski 2, 20-080 Lublin, Poland e-mail: [email protected] Printing elpil Artyleryjska Str. 11, 08-110 Siedlce, Poland e-mail: [email protected] ISSN 1641-7739 Edition 60+16 vol. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 3–6 Drying Faba Bean Seeds in a Silo with a Vertical Air Circulation System Janusz Bowszys*, Teresa Bowszys** * Department of Agricultural Process Engineering, University of Warmia and Mazury in Olsztyn, Katedra Inżynierii Systemów, Uniwersytet Warmińsko-Mazurski w Olsztynie ul. Heweliusza 14,10-718 Olsztyn, e-mail: [email protected] ** Department of Agricultural Chemistry and Environmental Protection, University of Warmia and Mazury in Olsztyn, Katedra Chemii Rolnej i Ochrony Środowiska, Uniwersytet Warmińsko-Mazurski w Olsztynie, e-mail: [email protected] Received December 03.2014; accepted December 17.2014 Summary. Legume seeds harvested by combine harvesters in the fall are characterized by a high moisture content. In this study, faba bean seeds were dried at low temperatures in a silo with a vertical air circulation system. Low temperature and long drying time of 90 hours minimized thermal stress in seeds. The objective of the study was to describe the drying process of faba EHDQVHHGVLQDVLORZLWKYHUWLFDODLUÀRZVOLJKWO\KHDWHGE\D kW electric heater. The results of the study have indicated that WKHDPRXQWRIDLUSXPSHGLQWRWKHVLORE\D:3IDQUDQJHV IURPP3·Mg-1·h-1WRP3·Mg-1·h-1, subject to the degree of VLOR¿OOLQJZLWKIDEDEHDQVHHGV$YHUWLFDODLUFLUFXODWLRQV\VWHP with a ventilation cone facilitates the process of drying faba bean seeds. Faba bean seeds are dried most rapidly along the silo’s axis of symmetry, whereas the drying rate is lowest along the silo’s outer walls. Seeds are dried faster in the lower part of the silo, therefore, a two-phase drying process is recommended in SODQHV::DQG:6HHGVGULHGLQWKHORZHUSDUWRIWKHVLOR should be removed upon the achievement of the optimal moisture content for storage. The remaining seeds should be dried in the second stage of the process. Key words: silos, drying, storage, faba beans. attempts have been made to dry faba bean seeds at low WHPSHUDWXUHVLQVLORVZLWKUDGLDORUYHUWLFDODLUÀRZ> @/RZWHPSHUDWXUHDQGORQJGU\LQJWLPHRIKRXUV PLQLPL]HGWKHUPDOVWUHVVLQVHHGV>@7KHSRVLWLYH results of experiments where cereal seeds were dried in silos [2] prompted the current attempt to dry faba bean seeds in a silo with a vertical air circulation system. The objective of this study was to describe the drying process RIIDEDEHDQVHHGVLQDVLORZLWKYHUWLFDODLUÀRZVOLJKWO\ KHDWHGE\DN:HOHFWULFKHDWHU7KHVLOR¶VYHQWLODWLRQ HI¿FLHQF\DQGWKHDPRXQWRIDLUVXSSOLHGWRWKHVLORVXEject to the height of the seed layer inside the silo, were determined to evaluate the drying process. 0$7(5,$/6$1'0(7+2'6 $ GU\LQJ VLOR ZLWK D YHUWLFDO DLU FLUFXODWLRQ V\VWHP was designed at the former Department of Process DeYLFHVSUHVHQWO\WKH'HSDUWPHQWRI$JULFXOWXUDO3URFHVV (QJLQHHULQJRIWKH8QLYHUVLW\RI:DUPLDDQG0D]XU\LQ 2OV]W\Q$SDWHQWDSSOLFDWLRQZDVVXEPLWWHGWRWKH3ROLVK INTRODUCTION 3DWHQW2I¿FHZKLFKLVVXHGFRS\ULJKW1RIRUWKH VLOR>@7KHGHYLFHZDVGHVLJQHGIRUGU\LQJDQGVWRULQJ New low-tannin faba bean varieties with a determi- FHUHDOJUDLQ$GLDJUDPRIWKHVLORXVHGLQWKLVH[SHULPHQW nate growth habit, containing a minimal amount of tannins LVSUHVHQWHGLQ)LJXUH PJSHUJ'0FRXOGFRQWULEXWHWRWKHSRSXODULW\ The silo is a steel structure. The cylindrical section of faba beans grown for fodder, in particular, if imports of ZLWKDGLDPHWHURIPLVPDGHRIJDOYDQL]HGVWHHOFRDWHG JHQHWLFDOO\PRGL¿HGVR\EHDQPHDOVDUHOLPLWHG7KHIDED ZLWKSODVWLFRQERWKVLGHV$LULVSXPSHGLQWRWKHVLORE\ EHDQLVDOHJXPHSODQWRIJUHDWHQYLURQPHQWDOVLJQL¿FDQFH DIDQ7KHYHQWLODWLRQFRQHZLWKDEDVHGLDPHWHURI that plays an important role in crop rotation schemes with PLVPDGHRISHUIRUDWHGVWHHOZLWKYHQWRSHQLQJV7KH a predominance of cereals. Legume seeds harvested by slant height of the cone is parallel to the slant height of the combine harvesters in the fall are characterized by a high discharge tube. The cone is separated from the discharge moisture content. Intensive drying of faba bean seeds in tube by a distance of 0.7 m. Research results indicate that roof dryers leads to thermal stress, which damages the the designed ventilation system permits air movement embryo and causes seeds to develop microcracks [8, 9]. throughout the entire bulk [2]. For the needs of this exRoof dryers are not suitable for drying crop seeds. Several SHULPHQWLQVSHFWLRQRSHQLQJVPDUNHG:::DQG -$186=%2:6=<67(5(6$%2:6=<6 Fig. 1. $GLDJUDPRIWKHH[SHULPHQWDOVLORZLWKDYHUWLFDODLUFLUFXODWLRQV\VWHPDQGDYHQWLODWLRQFRQH±VLOR±PLFURSUHVVXUH JDXJHIRUPHDVXULQJSUHVVXUHLQVLGHWKHVXFWLRQSLSHOLQH±SUHVVXUHJDXJH±WRSVXUIDFHRIWKHVHHGOD\HU±YHQWLODWLRQFRQH ±VXFWLRQSLSHOLQH±IDQ±HOHFWULFKHDWHU:W2, W W±VDPSOLQJSODQHV±WKHVLOR¶VD[LVRIV\PPHWU\±DWPLGUDGLXV ±E\WKHZDOO:, W, W±VDPSOLQJSRLQWVZKHUHVHHGWHPSHUDWXUHZDVPHDVXUHGFRQWLQXRXVO\ :ZHUHGULOOHGDORQJWKHVLOR¶VIRXUORQJLWXGLQDOSODQHV DWWKHGLVWDQFHVJLYHQLQ)LJXUH7KHVLORZDVHTXLSSHG ZLWKDN:KHDWHU:3IDQDQGPLFURJDXJHV IRUPHDVXULQJWKHWRWDOSUHVVXUHDQGVWDWLFSUHVVXUHRI pumped air. Pressure was measured to the nearest Pa. Inspection openings were used to collect samples from various locations in the bulk. Total airstream pressure and static SUHVVXUHZHUHPHDVXUHGWRFDOFXODWHIDQHI¿FLHQF\DQGWKH DPRXQWRIDLUSXPSHGLQWRWKHVLOR7KH¿UVWPHDVXUHPHQW ZDVSHUIRUPHGIRUDQHPSW\VLOR+ DQGVXFFHVVLYH measurements were performed when seeds were added in OD\HUVRIPXQWLOWKHKHLJKWRIWKHVHHGEHGLQVLGHWKH VLORUHDFKHGP7KHWKLFNQHVVRIWKHVHHGOD\HUVKRXOG QRWH[FHHGPGXHWRWKHULVNRIVHHGGDPDJHXQGHUWKH H[HUWHGORDG>@7KHPHDVXUHPHQWVZHUHXVHGWRFDOFXODWH YHQWLODWLRQHI¿FLHQF\DQGWKHDPRXQWRIDLUVXSSOLHGWRWKH VLORLQOLQHZLWKWKHSUHVHQWHGPHWKRG>@)DEDEHDQ VHHGVZHUHKDUYHVWHGIURPWKHVDPH¿HOGLQ¿YHEDWFKHV 6HHGSXULW\UDQJHGIURPWRZLWKWR FRQWHQWRIXVDEOHLPSXULWLHVDQGWR content of non-usable impurities. Total seed weight was deWHUPLQHGDW0J6DPSOHVIRUWKHGHWHUPLQDWLRQRIVHHG moisture content were collected at various points along IRXUVDPSOLQJSODQHVWKHVLOR¶VD[LVRIV\PPHWU\: ::DWWKHGLVWDQFHRIPIURPWKHD[LVRI V\PPHWU\::::DQGDORQJWKHVLORZDOO ::::7KHPRLVWXUHFRQWHQWRIVHHGV was determined by the drying method with the accuracy of 6HHGVZHUHGULHGIRUKRXUVE\FLUFXODWLQJKHDWHG air throughout the silo. The parameters of circulating air DUHJLYHQLQ)LJXUH6DPSOHVIRUHYDOXDWLQJVHHGPRLVWXUH content were collected eight times, approximately every KRXUV7KHWHPSHUDWXUHDQGPRLVWXUHFRQWHQWRIGU\LQJ air were determined upon sample collection. 5(68/76 The results of calculations revealed that the total area of vents in the ventilation cone is larger that cross-sectional area of the pipeline connecting the fan with the silo. ThereIRUHDLUÀRZZDVQRWWKURWWOHGLQVLGHWKHVLOR&KDQJHVLQ YHQWLODWLRQHI¿FLHQF\DVDIXQFWLRQRIWKHKHLJKWRIWKHVHHG OD\HUDUHSUHVHQWHGLQ)LJXUH,QLWLDOO\DW+ DLUZDV SXPSHGE\WKHIDQLQWRWKHVLORDWDUDWHRIP3·h-1. 9HQWLODWLRQHI¿FLHQF\ZDVUHGXFHGWRP3·h-1 when the WKLFNQHVVRIWKHVHHGOD\HUUHDFKHGP)DEDEHDQVHHGV ZHUHDGGHGLQVXFFHVVLYHOD\HUVRIPXQWLOWKHKHLJKW RIWKHVHHGEHGLQVLGHWKHVLORUHDFKHGP7KHIDQZDV active and pressure was measured every time a new batch of seeds was added to the silo. The results of ventilation HI¿FLHQF\FDOFXODWLRQVDUHSUHVHQWHGLQ)LJXUH7KHFXUYH '5<,1*)$%$%($16(('6,1$6,/2:,7+$9(57,&$/$,5&,5&8/$7,216<67(0 LQGLFDWHVWKDWIDQHI¿FLHQF\UHDFKHGP3·h-1 when the silo was full. This is a constant value at which faba been seeds were dried for 90 hours. The correlation between YHQWLODWLRQHI¿FLHQF\DQGWKHKHLJKWRIWKHVHHGOD\HUZDV GHVFULEHGE\DUHJUHVVLRQHTXDWLRQ)LJ&KDQJHVLQ the amount of air pumped into the silo as the height of WKHVHHGOD\HULQFUHDVHGIURPWRPDUHSUHVHQWHGLQ )LJXUH7KHVHHGOD\HUZLWKWKHKHLJKWRIPZDVDLUHG DWP3·Mg-1·h-1. When the height of the seed layer inFUHDVHGWRPWKHDPRXQWRIDLUSXPSHGLQWRWKHVLOR Fig. 5. $FWXDOGU\LQJSURFHVVLQWKHVLORLQVDPSOLQJSODQH: ZDVUHGXFHGWRP3·Mg-1·h-1, and the drying process was FRQGXFWHGDWWKLVDLUÀRZUDWHIRUKRXUV&KDQJHVLQWKH amount of air supplied to the silo as the thickness of the VHHGOD\HULQFUHDVHGIURPWRPZHUHGHVFULEHGZLWK DUHJUHVVLRQHTXDWLRQ)LJ5HJUHVVLRQHTXDWLRQVFDQEH XVHGWRFDOFXODWHYHQWLODWLRQHI¿FLHQF\DQGWKHDPRXQWRI air supplied at any thickness of the seed layer (Figs. 2 and 6HHGGU\LQJLQVLGHDVLORLVGHWHUPLQHGE\YHQWLODWLRQ HI¿FLHQF\DLUWHPSHUDWXUHDQGUHODWLYHPRLVWXUHFRQWHQW> Fig. 6. $FWXDOGU\LQJSURFHVVLQWKHVLORLQVDPSOLQJSODQH: Fig. 2. &KDQJHVLQYHQWLODWLRQHI¿FLHQF\VXEMHFWWRWKHKHLJKWRI the seed layer in the silo. Fig. 7. $FWXDOGU\LQJSURFHVVLQWKHVLORLQVDPSOLQJSODQH: Fig. 8. $FWXDOGU\LQJSURFHVVLQWKHVLORLQVDPSOLQJSODQH: Fig. 3. Changes in the amount of air supplied to faba bean seeds in the silo. Fig. 4. Temperature and relative moisture content of air as a function of drying time. @,QWKLVVWXG\GU\LQJDLUKDGVWDEOHSDUDPHWHUVZLWK WHPSHUDWXUHRIWRDQGUHODWLYHPRLVWXUHFRQWHQWRI WR&KDQJHVLQDLUSDUDPHWHUVDVDIXQFWLRQRIWLPH DUHSUHVHQWHGLQ)LJXUH ,QSODQH:VDPSOHVZHUHFROOHFWHGDWWZRSRLQWV: DQG:EHWZHHQWKHGLVFKDUJHWXEHDQGWKHYHQWLODWLRQ FRQH)LJ9HQWLODWLRQHI¿FLHQF\FXUYHVLQGLFDWHWKDWGU\LQJLQSODQH:SURFHHGHGDWWKHKLJKHVWUDWHDIWHUKRXUV DQGUHODWLYHPRLVWXUHFRQWHQWZDVGHWHUPLQHGDWDQG UHVSHFWLYHO\7KHGU\LQJUDWHDWSRLQWV:DQG: was very high because seeds were dried by air with the lowest moisture content. The initial moisture content of seeds in plane W2 was )LJ$WWKHHQGRIGU\LQJWKHKLJKHVWGURSLQPRLV- -$186=%2:6=<67(5(6$%2:6=<6 WXUHFRQWHQWWRZDVQRWHGDORQJWKHD[LVRIV\PPHWU\ ZKHUHDVWKHORZHVWGURSWRZDVREVHUYHGE\WKHVLOR ZDOO7KHDERYHUHVXOWVFDQEHDWWULEXWHGWRLQFUHDVHGDLUÀRZ resistance due to seed segregation along the silo wall [2, 7]. 7KHGU\LQJSURFHVVZDVPRVWVWDEOHLQSODQH:DQG changes in air moisture content were similar at all points. 7KHGU\LQJSURFHVVZDVVORZHVWLQSODQH:)LJ$IWHU 90 hours of drying, moisture content was determined at LQSRLQW:LQ:DQGLQ:$LU passing through the thickest seed layer is more moist than at WKHEHJLQQLQJRIWKHSURFHVVSODQHV:DQG:9HQWLODtion curves indicate that seeds were dried most rapidly along the silo’s axis of symmetry. The seed bulk was characterized by the highest porosity along the axis of symmetry, which PLQLPL]HGDLUÀRZUHVLVWDQFHLQVLGHWKHVLOR>@ ]SURPLHQLRZ\PXNáDGHPZLHWU]HQLDF],02752/ 0RWRU\]DFMDL(QHUJHW\ND5ROQLFWZDYRO1R %RZV]\V-&\G]LN56LORV]ERĪRZ\GRGRVXV]DQLD ]LDUQDQUSDWHQWX Bowszys J., Grabowski J., Tomczykowski J. 2004. Temperatures in seed mass stored in a metallic immeGLDWHO\WDIWHUKDUYHVW7HFKQ6F 7. Bowszys J., Tomczykowski J. 2007. Self-segregation of maize kernels during gravitational discharge from a silo. 7(.$.RP0RW3RZHU,QG$JULFXOW9,, 8. Figiel A. Konieczna M. 2001. Fizyczne i biologiczne ZVNDĨQLNLSRGDWQRĞFLQDVLRQERELNXQDXV]NRG]HQLD ZSURFHVLHVXV]HQLDLQDZLOĪDQLD$FWD$JURSK\VLFD 9. Grzesiuk S., Górecki R. 1994. Fizjologia plonów. WproZDG]HQLHGRSU]HFKRZDOQLFWZD:\G$572OV]W\Q .XVLĔVND($QLQÀXHQFHRIRXWHUHQHUJ\RQPRCONCLUSIONS isture content distribution in grains stoned in a model VLOR7(.$.RP0RW3RZHU,QG$JULFXOW9, 7KHDPRXQWRIDLUVXSSOLHGWRWKHVLORE\WKH:3IDQ 1DGXOVNL5.XVLĔVND(*X]7.REXV= UDQJHVIURPP3·Mg-1·h-1WRP3·Mg-1·h-1, subject :Sá\ZZLOJRWQRĞFL]LDUQLDNyZLQDFLVNXSLRQRZHJRQD WRWKHGHJUHHRIVLOR¿OOLQJZLWKIDEDEHDQVHHGV LFKHQHUJLĊL]GROQRĞüNLHáNRZDQLD,QĪ\QLHULD5ROQLF]D $YHUWLFDODLUFLUFXODWLRQV\VWHPZLWKDYHQWLODWLRQFRQH facilitates the process of drying faba bean seeds. 6]ZHG*.XVLĔVND(=PLDQDFHFKJHRPHWU\F] )DEDEHDQVHHGVDUHGULHGPRVWUDSLGO\DORQJWKHD[LV nych ziarniaków pszenicy w wyniku niekorzystnych of symmetry, whereas the drying rate is lowest by the warunków przechowywania. MOTROL Motoryzacja silo’s outer wall. L(QHUJHW\ND5ROQLFWZD )DEDEHDQVDUHGULHGIDVWHULQWKHORZHUSDUWRIWKHVLOR therefore, a two-phase drying process is recommended 352&(66686=(1,$1$6,21%2%,.8:6,/26,( =3,212:<035=(3à<:(032:,(75=$ LQSODQHV::DQG:6HHGVGULHGLQWKHORZHU part of the silo should be removed upon the achievement of the optimal moisture content for storage. The Streszczenie. 1DVLRQDURĞOLQVWUąF]NRZ\FK]HEULQHSU]\XĪ\remaining seeds should be dried in the second stage FLXNRPEDMQXMHVLHQLąFKDUDNWHU\]XMąVLĊZ\VRNą]DZDUWRĞFLą wilgoci. W tym badaniu, nasiona bobiku suszono w niskich of the process. 5()(5(1&(6 Bowszys J. 2003. 5R]NáDGWHPSHUDWXUZPDVLH]LDUna pszenicy przechowywanej w metalowych silosach ]ERĪRZ\FK3URFHHGLQJVRIWKH1DWLRQDO$JULFXOWXUDO 8QLYHUVLW\RI8NUDLQH³0HFKDQL]DWLRQRI$JULFXOWXUDO 3URGXFWLRQ´.\LY 2. Bowszys J. 2006. Doskonalenie technologii suszenia LSU]HFKRZ\ZDQLDZF\OLQGU\F]Q\FKVLORVDFK]ERĪRZ\FK=HV]\W:\G]LDá,QĪ\QLHULL3URGXNFML$5 Lublin. Bowszys J. 2013. :Sá\ZJUXERĞFLZDUVWZ\QDVLRQVNáDGRZDQ\FKZVLORVDFK]SLRQRZ\PXNáDGHPZLHWU]HQLD QDSDUDPHWU\SU]HSá\ZXSRZLHWU]D02752/0RWRU\]DFMDL(QHUJHW\ND5ROQLFWZDYRO1R Bowszys J., Bowszys T. 2013. Przebieg procesu suV]HQLD RUD] ]PLDQ\ MDNRĞFL QDVLRQ ERELNX Z VLORVLH WHPSHUDWXUDFKZVLORVLH]SLRQRZ\PSU]HSá\ZHPSRZLHWU]D 1LVNDWHPSHUDWXUDLGáXJLF]DVVXV]HQLDZ\QRV]ąF\JRG]LQ ]PLQLPDOL]RZDá\VWUHVFLHSOQ\ZQDVLRQDFK&HOHPEDGDQLD E\áRRSLVDQLHSURFHVXVXV]HQLDQDVLRQERELNXZVLORVLH]SLRQRZ\PSU]HSá\ZHPSRZLHWU]DOHNNRRJU]HZDQ\PSU]H] N:JU]HMQLNHOHNWU\F]Q\:\QLNLWHJREDGDQLDZVND]XMąĪH LORĞüSRZLHWU]DSRPSRZDQHJRGRVLORVXSU]H]ZHQW\ODWRU:3 Z\QRVLRGP3·Mg-1·h-1GRP3·Mg-1·h-1]DOHĪQLHRG VWRSQLDZ\SHáQLHQLDVLORVXQDVLRQDPLERELNX3LRQRZ\RELHJ SRZLHWU]D]HVWRĪNLHPZHQW\ODF\MQ\PXáDWZLDSURFHVVXV]HQLD QDVLRQERELNX%RELNVXV]\VLĊQDMV]\EFLHMZ]GáXĪRVLV\PHWULLVLORVXQDWRPLDVWV]\ENRĞüVXV]HQLDMHVWQDMQLĪV]DZ]GáXĪ ]HZQĊWU]Q\FKĞFLDQVLORVX1DVLRQDVXV]ąVLHV]\EFLHMZGROQHMF]ĊĞFLVLORVX]DWHP]DOHFDVLĊGZXID]RZ\SURFHVVXV]HQLD ZSáDV]F]\]QDFK::L: 1DVLRQDVXV]RQHZGROQHMF]ĊĞFLVLORVXQDOHĪ\XVXZDüSR RVLąJQLĊFLXRSW\PDOQHM]DZDUWRĞFLZLOJRFLZFHOXSU]HFKRZ\ZDQLD3R]RVWDáHQDVLRQDSRZLQQ\E\üVXV]RQHZGUXJLPHWDSLH procesu. 6áRZDNOXF]RZHsilosy, suszenie, przechowywanie, bobik. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 7–14 Application of Generalized Method of Lines for Solving the Problems of Thick Plates Thermoelasticity Part 1. Construction of resolving equations Valery Chybiryakov, Anatoly Stankevich, Dmitry Levkivskiy, Vladimir Melnychuk Kyiv National University of Construction and Architecture Povitroflotskyy Prosp., 31, Kyiv, Ukraine, 03680, e-mail: [email protected] Received December 07.2014; accepted December 17.2014 Summary. The authors proposed a new version of lowering dimensionality in the application of the method of lines. The EDVLFLGHDLVORZHULQJWKHGLPHQVLRQDOLW\RILQSXWHTXDWLRQV per the spatial coordinate by projection method, including the %XEQRY*DOHUNLQPHWKRG Key words: PHWRGRIOLQHV%XEQRY*DOHUNLQ3HWURYWKHUPRHlasticity method, thick plates, structural mechanics. INTRODUCTION The authors proposed a new version of lowering dimensionality in the application of the method of lines. It is greatly expanding the capabilities of method of lines. The proposed generalized method of lines may be used for calculating the plates of variable thickness, and also problems of dynamics. The basic idea of generalized method of lines LVORZHULQJWKHGLPHQVLRQDOLW\RILQSXWHTXDWLRQVSHUWKH spatial coordinate by projection method. The projection PHWKRGLQFOXGHVWKH%XEQRY*DOHUNLQPHWKRGJHQHUDOL]HG E\3HWURY>@ 385326(2):25. One of the most effective methods of solving multidimensional problems of structural mechanics is the combination approach. In this approach a problem is solved in two stages: GHFUHDVLQJWKHGLPHQVLRQRIWKHLQSXWHTXDWLRQVE\RQH or two coordinates; WKHUHGXFHGSUREOHPLVVROYHGDQDO\WLFDOO\RUQXPHULcally. Traditionally in structural mechanics, lowering dimenVLRQDOLW\RILQSXWHTXDWLRQVLVEDVHGRQFHUWDLQK\SRWKHVHV $FFRUGLQJO\WKH¿UVWVWDJHRIWKHPHWKRGZDVH[FOXGHG in a separate research: theory of rods, plates and, shells. $SSOLHGK\SRWKHVHVZHUHVWURQJHQRXJKEXWOHVVDFFXUDWH It lead to creation of various theories of plates and shells. Currently, lowering dimensionality is performed using mathematical methods (for example, the theory of shells ,19HNXD>@:LWKWKHQH[WVROXWLRQRIUHGXFHGHTXDtions, lowering the dimension creates a combined method for solving problems of mathematical physics. Such methods include Vlasov-Kantorovich’s method. These combined methods are alternative, compared to the general numerical PHWKRGVVXFKDV¿QLWHHOHPHQWPHWKRG¿QLWHGLIIHUHQFHDQG variation-difference method. Mathematical methods of lowering dimensionality are associated with the geometrical characteristics of the considered objects. It greatly restricts the geometry of the problems, for which it is possible to use the combined methods. +RZHYHUOLPLWLQJWKHFRPSOH[LW\RIWKHJHRPHWU\DOORZVWKH DSSOLFDWLRQRIYHU\HI¿FLHQWQXPHULFDOPHWKRGV,WLQFUHDVHV the accuracy and stability of numerical calculation. It also VLJQL¿FDQWO\UHGXFHVFRPSXWHUWLPHXVLQJ One of the known methods of lowering dimensionality LQSXWHTXDWLRQVLVWKH³PHWKRGRIOLQHV´,QWKLVPHWKRGWKH ¿QLWHGLIIHUHQFHPHWKRGLVXVHGIRURQHRIWKHWZRFRRUGLQDWHV7KLVPHWKRGZLOOEHHIIHFWLYHLIWKHLQSXWHTXDWLRQV DUHV\VWHPVRIRUGLQDU\GLIIHUHQWLDOHTXDWLRQV,QWKHFDVH RIFRQVWDQWFRHI¿FLHQWVLQWKHVHHTXDWLRQVLWLVSRVVLEOHWR XVHDQDO\WLFDOVROXWLRQRIV\VWHPRIHTXDWLRQV9LQRNXURY >@6KNHORY/7>@,QWKLVUHJDUGWKHPHWKRGRIOLQHVLV used for the solution of static problems for plates and shells of constant thickness. The authors proposed a new version of lowering dimensionality in the application of the method of lines. It is greatly expanding the capabilities of method of lines. The proposed generalized method of lines may be used for calculating the plates of variable thickness, and also problems of dynamics. The basic idea of generalized method of lines LVORZHULQJWKHGLPHQVLRQDOLW\RILQSXWHTXDWLRQVSHUWKH spatial coordinate by projection method. The projection 8 9&+<%,5<$.29$67$1.(9,&+'/(9.,96.,<90(/1<&+8. PHWKRGLQFOXGHVWKH%XEQRY*DOHUNLQPHWKRGJHQHUDOL]HG E\3HWURY>@ In the case of thick plates with constant thickness for HTXDWLRQVRISODWHGHIRUPDWLRQVSHUWKLFNQHVVORFDOO\EDVLF UHVWULFWHGGLVFUHWHOLQHDUIXQFWLRQVDUHFKRVHQ)LJ QHQWVLVSHUIRUPHGGLIIHUHQWO\+HUHZLWKZHJHWWZREDVLF PDWULFHV± G and B , which are recorded in an index form as: gij Mi M j , bij of two functions: Mi Mi M j dM j dy . This is the scalar product ³ M y M y dy h i j 0 Conversion of components with derivative y of the function n -type displacement and stresses-type functions is formed in different ways. This is the use of lowering dimension of a plane problem using the theory of elasWLFLW\ The peculiarity of this functional basis is that this basis is not orthogonal, and thus there exist two types of index values, f i and fi . These magnitudes are different by rules )LJ%DVLVIXQFWLRQV of conversion at transition on another basis. Contravariant magnitudes denoted by upper index and covariant mag$VLQWKHWUDGLWLRQDOYHUVLRQRIWKHPHWKRGRIOLQHV QLWXGHV±ORZHULQGH[$FFRUGLQJO\ ^ gij ` ±WZRLQGH[HV DFURVVVHFWLRQRIWKHSODWHLVGLYLGHGLQWRLQÀLFWn lines magnitude is twice covariant metric tensor and the inverse LQFOXGLQJWZRERXQGDU\OLQHVZLWKDQHTXDOUDQJHǻ+RZ- matrix ^ gij ` ^g ij ` is twice contravariant metric tensor. ever, in order to reduce dimensionality, we do not use method Metric tensor provides a transition from covariant to conRI¿QLWHGLIIHUHQFHVEXWWKHJHQHUDOL]HGPHWKRGRI%XE- travariant components and vice versa: QRY*DOHUNLQ3HWURY%\FRRUGLQDWHy the unknown functions f x y is approximated in this manner: fi gij f j , f i g ij f j f x y | f i x Mi y The constructed algorithm of lowering dimensionality formally resembles algebraic transformations of tensor calculus. In this connection, the generalized method of lines essentially tensor symbols and relevant rules are used. For example, by repeated indexes is assumed summation. 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Therefore in mathematics covariant and contravariant function magnitudes have an LGHQWL¿HGQDPH%HFDXVHWKHFRYDULDQWPDJQLWXGHVDSSHDU LQWKHGHFRPSRVLWLRQE\EDVLV¿JWKH\DUHFDOOHGFRHI¿FLHQWV&RYDULDQWPDJQLWXGHVDSSHDUDVDVFDODUSURGXFW of the basis elements: f x y f x y Mi y ³ f x y M ydy , h i 0 WKH\DUHFDOOHG±PRPHQWV 7KHUHIRUH UHGXFHG HTXDWLRQV FDQ EH ZULWWHQ LQ IRXU ways: ± ,QPRPHQWVLIGLVSODFHPHQWDQGVWUHVVHVLQWKHPRPHQWV ± ,QFRHI¿FLHQWVLIDOOXQNQRZQVDUHZULWWHQLQFRHI¿FLHQWV ± 7ZRYHUVLRQVRIFRPELQHGUHFRUGGLVSODFHPHQWLQWKH PRPHQWVVWUHVVHVLQWKHFRHI¿FLHQWVRUGLVSODFHPHQWLQ FRHI¿FLHQWVWUHVVHVLQWKHPRPHQWV wu x y ³0 wy Mi ydy h u x ³ Mi y M cj y dy bij u x , ³ h 0 w u j xM j y wy Mi y dy h j j 0 wV x x y Mi y wy h wV x x y Mi y dy V x x y Mi y _ ³ V x x y Mic y dy wy 0 0 0 ³ h h V x x h M n h V x x M ³ V x j x M j y Mic y dy h V x x h Mn h V x x M b jiV x j x 0 wV wW wW w w w w w w wW wV wW w W wW wV w w w w w w wW wW wV P 9w w Vw w O P w P w when x 0 : $IWHUIRUPXODWLQJWKHFRQVWUXFWLQJHTXDWLRQVZHQHHGWR O O w P V w when x 0 : IRUPXODWHWKHUHGXFHGERXQGDU\YDOXHDQGLQLWLDO±ERXQGDU\ O P w 0 0 0 w O q x (0, y, z , t D xT (TxC Tx q xC (0, y, z , t value problem in index form. w w W w O P 7KHGHVFULEHGWHFKQLTXHFDQEHDSSOLHGWRVROYHWKH when x l : w w problem of thermal stresses in a rod of rectangular cross-secwhen: x l ,: DD w w ( , y, z , t W w w when x l : WLRQ)LJZKLFKRFFXSLHVDWKUHHGLPHQVLRQDOUHJLRQ w w W l w q x (l , y, z , t D xT (Txl TxCl q xC (l , y, z , t w [0 d x d l ] u [0 d y d hy ] u [0 d z d hz ] . w 7KH HTXDWLRQV w W The temperatures and heat flows of exterw w z 7KHWHPSHUDWXUHVDQGKHDWÀRZVRIH[WHUQDOHQYLURQPHQW c 7KH HTXDWLRQV from the side of relevant part of boundary surface of beam hz are marked asc “ cǁŚĞŶ ”: ǁŚĞŶ ǁŚĞŶ when: y ǁŚĞŶ 0 :, ǁŚĞŶ D 0 coordinates. 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The initial conditions are in the ZHQHHGWRVSHFLI\WKHLQLWLDODQGERXQG X q y Ory w W V W w w ZHQHHGWRVSHFLI\WKHLQLWLDODQGERXQG T x y z w w w w w w ry wconditions. The initial conditions are in wthe ° ZHQHHGWRVSHFLI\WKHLQLWLDODQGERXQG wwwV y wwWW wwW yzwW y wwWwxy wwV ZHQHHGWRVSHFLI\WKHLQLWLDODQGERXQG wW Y , w wxyV VwwwWV ° w w W W w w W ZHQHHGWRVSHFLI\WKHLQLWLDODQGERXQG y yz w w w W V W wT ɯ \ ] 7 ɯ \ ] wwW ww wwV w Yw,,wW ww Y , ° w Y qz O w w w W V W here ɯ \ ] 7 ɯ \ ] T ɯɯ \ ] 7 ɯ \ ] x y w z w w w w w \ \] ]ɯ7\ ɯ] \ 7] ɯ \ ] w wz ɯ ¯° wz wwWW wWww wwWW wwWw wwV wV ɯ \ ]] 7 ɯ temperature \ ] w distribution wZ , wWWw w wwVwW wVwV w W w W ɯ \ ] 7 ɯ \ ] ɯɯ \\ ]]ɯɯ \\ w wW ] ɯ \temperature wZ Zw,,wV z wZ , wwVwW yz wwW xz w ] 7 ɯ \ ]distribution ɯ \ ] w W W w w V q Z , where T T x y z ±WHPSHUDWXUHIXQFWLRQ , , q w w w w w q w ɯthe \ volume ] x z y of the w throughout body at the inir wwwx wwWW wPwy wwWW wz wwV w O ] ±FRPSRQHQWVRIWKHKHDWÀX[ q x y z ɯ, U\ ±GHQVLW\RI w wP VO w VwvO*** P w w * w w w w * wwuP OVPP VO Ow vO* P ww the material, c ±VSHFL¿FKHDW OTThe ±FRHI¿FLHQWRIWKHUPDO w w w V P P O PO VO P Owv P w u boundary conditions of the problem O w w Ow wP OVxwPOP POOwP P w The boundary conditions of the problem w O conductivity. Q ±WKHTXDQWLW\RIKHDWJHQHUDWHGE\LQWHUQDO V wy DO w P wO (P wx O (O w2wO OP2OP ww will be set as conditions of convective heat O P V O P w O P x 0 : heat sources. O OwwO *P wwOO P w D PPO D P OOD P x 0 : x 0 : wO*2PPO P D O O PPOwwww PO(OO x 0 : x 0D: (0, y, z , t O 7RHQVXUHXQLW\RIVROXWLRQRIWKHV\VWHPZHQHHG wP O DT(OP P0 T T w w u w O P x 0D : y, z , t( 0, y, z , t D D The ((0, 0, ** O(wOu * ,w O P D 2P to specify the initial and boundary conditions. x l :D initial y, z , t(0, y, z , tww (O W2wwP wwwuuWWz*O, D * (O P 2wwP D (0, y, z , t u ,wz *, O P conditions are in the form: zv,*t W w wuW*O xx ll :: xx llD:: D ( , y, z(0, wP * ,wwu * , t yw,w w v W , D w w w w u x l : D ( , y , z , t D ( , y , z , t t T(x, y, z) T0(x, y, z), D w * W * w , xD l : ( , y, z , t ( , y, z , t www w wwwwuuxW** Wwxyu* . wy D ( , y, z , t w wW*.. wwu . wy W where: w W D ( , y, zww, t w wuW w . * EH VHSDUDWHO\ D ( , y, zw, t w *HTXDWLRQV W w 7KH . w wuFDQ FRQVL T0(x, y, z)±WHPSHUDWXUHGLVWULEXWLRQWKURXJKRXWWKHYROXPH * WFDQ . EH VHSDUDWHO\ www HTXDWLRQV wuFDQ 7KH HTXDWLRQV FDQEH EH VHSDUDWHO\ FRQVL FRQVL The temperatures and heat flows of 7KH exter-HTXDWLRQV VHSDUDWHO\ FRQVL W . of the body at the initial time. c The temperatures and heat flows ofw7KH exter- 7KH w HTXDWLRQV w FDQ EH VHSDUDWHO\ FRQVL xz 7KH HTXDWLRQV EH FRQVL wx7KH FDQ wz VHSDUDWHO\ c c nal environment from the side of relevant The boundary conditions of the problem will be set as HTXDWLRQV FDQ EH VHSDUDWHO\ FRQVL c c 7KH HTXDWLRQV FDQ EH VHSDUDWHO\ FRQVL c transfer. part of boundary surface of beam are marked conditions of convective heat 7KHHTXDWLRQVFDQEHVHSDUDWHO\FRQVLGHUHG c ered: c ZHQHHGWRVSHFLI\WKHLQLWLDODQGERXQG ɯ \ ] 7 ɯ \ ] ɯ \ ] ɯ \ ] 7 ɯ \ ] ɯ \ ] $33/,&$7,212)*(1(5$/,=('0(7+2'2)/,1(6 9&+<%,5<$.29$67$1.(9,&+'/(9.,96.,<90(/1<&+8. O wu * (O 2P wv* P wx P wy Vy O ww* (O 2P D T (T T0 P wz P O wu * O wv* Vz P wx P wy (O 2P ww* O 2P DT (T T0 P P wz 7 § ww* wv* · ¸, ¨¨ 8 wz ¸¹ © wy where: f * P f . %RXQGDU\ FRQGLWLRQV RI VWUHVV-strain state in general are written by the analogy of work [7] (-( For construction of the boundary condiWLRQV 9-( ZH ZULWH WKH VXP RI SURMHctions of all power factors that act on the boundary contour, on corresponding axis. In )LJ . RQ WKH SODQH x0 y , the magnitudes which act on area x 0 are shown. The first index —signifies the number of the axis which is perpendicular to the area. The second index shows the direction of displacement or stress. W yz when: x 0 , V x0 (k 0 2 xx (k 0 xy (k 0 xz when: x W0 2 xy W xz0 2 l, where: f 0 (k l 2 xx (k l 2 xy (k l xz V l x W l xy Wl 2 xz f (0, y, z fl u0 k xx0 (k 0 2 xx v0 k xy0 (k 0 2 xy k xz0 (k 0 2 xz w0 k xxl (k l 2 xx k xyl (k l 2 xy k xzl (k l 2 xz u l v l wl f (l , y, z . Fig. 3. Modeling of the boundary conditions uc , vc — displacement of points of the external environment, u, v — horizontal and vertical displacement of points of object, q xx , q xy — external load on object, V x , W xy — QRUPDO DQG WDQJHQWLDO VKHDU stresses along the contour inside the object, k xx , k xy — spring stiffness. (k 0 2 xx q xx0 (k 0 2 xy (k 0 2 xz (k l 2 xx (k l 2 xy (k l 2 xz qxy0 q xz0 q l xx q l xy q xzl k xx0 (k 0 2 xx uc0 0, 9 vc0 0, (20 wc0 0, ( ucl 0, (22 vcl 0, ( wcl 0. ( k xy0 (k 0 2 xy k xz0 (k 0 2 xz k xxl (k l 2 xx k xyl (k l 2 xy k xzl (k l 2 xz $33/,&$7,212)*(1(5$/,=('0(7+2'2)/,1(6 %\ FKDQJLQJVWLIIQHVV ZHFDQVSHFLI\ DQ\ 7KH ILUVW HTXDWLRQ RI V\VWHP LV PXOWistandard conditions of interaction of the ob- plied as a scalar by {Mi Mi ( y` where ject with the external environment. i n , and than integrated by coordi)RU HTXDWLRQV -( WKH SURFHGXUH RI nate y : lowering dimension is performed by coordinates y, z . $WILUVW— reduction by y %DVLF (( wq x wq y wq z Uc wT Q( x, y, z, t 0, M ( y i wt wx wy wz {Mi Mi ( y` , functions are applied (2 i n , where the following rules are tak- wq xi G ni q y i ( x, z, t G i q y i ( x, z, t w x en into account: wq wT f ( x, y, z , t f i ( x, z , t Mi ( y , b ji g jD q yD ( x, z, t zi Uc i Qi ( x, z, t 0;. ³ f ( x, y, z, t M ( ydy ( f ( x, y, z , t Mi ( y hy i 0 f i ( x, z, t ³ · § wf ( x, y, z, t , Mi ( y ¨ x w ¹̧ © wf ( x, y, z, t Mi ( ydy wx hy 0 w w f ( x, y, z, t Mi ( ydy f i ( x, z, t ³ wx wx 0 Where f is a factor of stress, then hy ³ § wf ( x, y, z, t · ¨¨ , Mi ( y ¸ wy © ¹̧ f ( x, y, z , t Mi ( y _ hy 0 y hy y 0 wf ( x, y, z, t Mi ( ydy wy ³ f ( x, y, z , t Mic( y dy wz wt In the next step we perform the reduction by z RIHTXDWLRQ wq i i ( xi G ni q y ( x, z , t G i q y ( x, z , t wx wq wT b ji g jD q yD ( x, z , t zi U c i wz wt Qi ( x, z , t 0, M k ( z > > b pk g ps q zis ( x, t Uc wTik Qik ( x, t 0, wt hy f ( x, hy , z, t Mi (hy f ( x,0, z , t Mi 0 ³ f j ( x, z, t M j ( y Mic( y dy +HUH ª¬G ni q y i k G i q y i k º¼ hy f ( x, hy , z, t G f ( x,0, z , t G 0 n i i i i b ji g jD fD ( x, z, t When: f is a factor of temperature and displacement ( T , u , v, w then: · § wf ( x, y, z, t ¨¨ , Mi ( y ¸ wy ¹̧ © ³ hy i 0 ³ hy wf ( x, y, z, t Mi ( ydy wy w( f j ( x, z, t M j ( y Mi ( ydy wy ³M ( yM c ( y f 0 hy j j @ wq xik i i G ni q y k ( x, t G i q y k ( x, t wx k k b ji g jD q yDk ( x, t G mk q z i ( x, t G k q z i ( x, t (2 0 ( x, z, t dy bij g jD fD ( x, z, t ª¬G mk qzi k G k qzi k º¼ @ ª q y k º « » « 0 » », « « » « 0 » « q n » ¬ y k ¼ ª qzi º « » « 0 » « », » « « 0 » « q m » ¬ zi ¼ n – number of lines along the axis y , m number of lines along the axis z . Indexes i, j , D , E , J - are related to reduction by coordinate y ; indexes k , p, s, I , H reduction by coordinate z . Taking into account the boundary condiWLRQV- 9&+<%,5<$.29$67$1.(9,&+'/(9.,96.,<90(/1<&+8. ª¬G ni q y i k G i q y i k º¼ ª¬G im qzi k G i qzi k º¼ The substitution: ªD yT ªD yT Ty k º « » « « 0 » « « » T D i ͕ « y k « » « 0 « » « « hy « hy n » ¬D yT Ty k ¼ ¬D yT ªD yT Ty k º ªD yT TyC k º ª q yC k º « » « » « » 0 « 0 » « » « 0 » »« « »« » » « « » « » 0 « 0 » « » « 0 » « hy « hy n » n » « q n » ¬D yT Ty k ¼ ¬D yT TyC k ¼ ¬ yC k ¼ ª D zT Tzi º ª D yT TzCi º ª qzCi º « » « » « » 0 « 0 » « » « 0 » »« « »« » « » « » « » 0 « 0 » « » « 0 » «D hz T m » «D hz T m » « q m » ¬ yT zi ¼ ¬ yT zCi ¼ ¬ zCi ¼ TyC k º ª q yC k º » « » 0 » « 0 » » TC i ͕ « » y k » » « 0 » « 0 » » « q n » TyC nk ¼ ¬ yC k ¼ D zT TzC i ª D zT Tzi º « » « » 0 0 « » « » k » » T D zi ͕ « « « » » « 0 « 0 » « » «D hz T m » h m z «D T » ¬ zT zi ¼ ª ¬ zT zC i ª qzC i º « » « 0 » » T TC zi k ͕ « » « « 0 » « q m » ¬ zC i ¼ ¼ Similarly, the reduction of remaining HTXDWLRQVRIV\VWHPLVGRQH wTik , wx OT bij g jD TDk ( x, t , qxik q yik qzik OT OT bkp g psTis ( x, t . (27 º Taking into account the boundary conditions (27-(28LQHTXDWLRQ0 wq ( xik ª¬ g iD T D yD k g kH TC y iH g iD q yCD k º¼ wx b ji g jD q yD k ª¬ g kH T D ziH giD TCzD k g kH q yCiH º¼ wT bpk g ps qzis U c ik Qik wt q yC i k ͕ ( ( ( Substituting (-( LQ 9 HTXation (LVIRUPHG qzC i k ͘ (28 w 2Tik ª g iD T D yD k g kH TC y iH g iD q yCD k º¼ wx 2 ¬ OT b ji g jD bDE g EJ TJ k OT ª¬ g kH T D ziH g iD TC zD k g kH q yCiH º¼ wT OT bpk g ps bsI g IH TiH U c ik Qik wt The reduced initial conditions will look like Tik ( x T0ik ( x 7KHQH[WVWHSLVWKHUHGXFWLRQRIHTXDWLRQV of system (-( ,Q WKLV V\VWHP WKH SUocess of reduction expressions are substituted for V y , V z , W yz -8 XVLQJ WKH DERYH mentioned operations: $33/,&$7,212)*(1(5$/,=('0(7+2'2)/,1(6 P du *ik dx (O 2P dV xik dx dW xyik V xik O (O 2P bij g jD v*Dk O (O 2P bkp g ps w*is dv*ik W xyik bij g jD u *Dk , dx dw*ik W xzik bkp g psu *is , dx > O 2P DT (Tik T0ik , (O 2 P O @> > @> > k k ( O P b ji g jD bDE g EJ v* xJk O 2P 2(O 2 P w*Ds b ji g jD D T (TDk T0Dk O 2P b ji g jD V xDk O 2P dx 2O b g jD bkp g ps O 2 P ji i @ @> @ > > @> ( ( @ ( b ji g jDW xyDk b pk g psW xzis G ni W xy k G iW xy k G mk W xy i G kW xy i X ik , i @> ( 8 @ b pk g psbsI g IH v*iH b pk g ps bij g jD w*Ds G ni V y k G i V y k G mk W xz i G k W xz i Yik , i i k > k @> @ dW xzik O (O P 2O b pk g psV xis bpk g psbsI g IH w* xiH b pk g ps bij g jD v*Ds dx O 2P O 2P OP 2(O 2P D T bpk g ps (Tis T0is b ji g jD bkp g ps v*DH b ji g jD bDE g EJ w*Jk O 2P > @> @ @ G ni W yz k G iW yz k G mk V z i G kV z i Z ik i i P k k P k xx0 k xx0 *0 *0 0 ucik u q ik xxik 0 2 0 2 *0 2 (k xx (k xx (k xx (9 The reduced boundary conditions of stress-strain state will look like: (k xx0 P 0 V xik 2 (k P 0 2 xy (k xz0 2 P W 0 xyik W 0 xzik (k xxl P (k 0 2 xy l 2 xy (k xzl 2 v *0 ik P (k 0 2 xy q 0 xyik k xy0 (k 0 2 xy *0 vcik P k xz0 k xz0 *0 *0 0 wcik wik qxzik 0 2 0 2 0 2 (k xz (k xz (k xz l V xik 2 (k P k xy0 W l xyik W l xzik P k xxl k xxl *l *l l ucik u q xxik ik l 2 l 2 l 2 (k xx (k xx (k xx k xyl (k l 2 xy v *l ik P (k l 2 xy q l xyik k xyl (k l 2 xy *l vcik P k xzl k xzl *l *l l wcik wik qxzik l 2 l 2 l 2 (k xz (k xz (k xz 0, 0, 0, 0, ( 0, 0. The next step — the problem numerically on the geometryCONCLUSIONS and initial-boundary condi7KHQH[WVWHS±WKHSUREOHPQXPHULFDOO\LVVLPXODWHG XVLQJWKHPHWKRGRIGLVFUHWHRUWKRJRQDOL]DWLRQE\6.+RGXQRY>@'LIIHUHQWLDOHTXDWLRQVLQSDUWLDOGHULYDWLYHVDUH 7KHVXJJHVWHGPRGL¿FDWLRQRIWKHPHWKRGRIOLQHVVLJWKRJRQDOL]DWLRQE\6.+RGXQRY>@'LIIH solved using the method of This probHQWLDO HTXDWLRQV LQRunge-Kutta-Merson. SDUWLDO GHULYDWLYHV DUH QL¿FDQWO\LQFUHDVHVWKHDFFXUDF\RIFDOFXODWLRQ7KHSUREOHP lem is programmed by the Fortran programming language. of setting boundary function is solved and this allows the Depending on the geometry and initial-boundary conditions; solution of problem of dynamics and thermoelasticity. temperature, displacement and stress are determined at certain points of the construction. 9&+<%,5<$.29$67$1.(9,&+'/(9.,96.,<90(/1<&+8. LWHRUɿ\DVSRUXG´±3UHYLHZ,VVXHʋ±S± LQ8NUDLQLDQ Vekua I.N., 1982. Some common methods of con- 8. Godunov S.K., 1961. On the numerical solution of structing different versions of the theory of shells. M boundary value problems for systems of linear ordinary 6FLHQFH+RPH(GLWRULDOSK\VLFDODQGPDWKHPDWLFDO GLIIHUHQWLDOHTXDWLRQV$GYDQFHV0DWKHPDWLFDO6FLHQFOLWHUDWXUHSLQ5XVVLDQ HV±Y±1R±3±LQ5XVVLDQ Vinokurov L.P., 1956. Direct methods for solving spatial and contact problems for arrays and foundations. ɉɊɂɆȿɇȿɇɂȿɈȻɈȻɓȿɇɇɈȽɈɆȿɌɈȾȺɉɊəɆɕɏ ɄɁȺȾȺɑȺɆɌȿɊɆɈɍɉɊɍȽɈɋɌɂɌɈɅɋɌɕɏɉɅɂɌ .KDUNLY3XEO.KDUNRY8QLYSLQ5XVVLDQ ɋɈɈȻɓȿɇɂȿɉɈɋɌɊɈȿɇɂȿɊȺɁɊȿɒȺɘɓɂɏ 6KNHOɺY L.T., Stankevich A.N., Poshivach D.V., 2004. ɍɊȺȼɇȿɇɂɃ $SSOLFDWLRQRIWKHPHWKRGRIOLQHVIRUWKHGHWHUPLQDWLRQ of the stress and strain states of the spatial and plate VWUXFWXUDOHOHPHQWV0RQRJUDSK±..18&$ ȺɧɧɨɬɚɰɢɹȺɜɬɨɪɚɦɢɞɚɧɧɨɣɪɚɛɨɬɵɩɪɟɞɥɨɠɟɧɧɨɜɵɣ ɜɚɪɢɚɧɬɩɨɧɢɠɟɧɢɹɪɚɡɦɟɪɧɨɫɬɢɦɟɬɨɞɨɦɩɪɹɦɵɯɱɬɨɫɭSLQ5XVVLDQ ɳɟɫɬɜɟɧɧɨɪɚɫɲɢɪɢɥɨɟɝɨɜɨɡɦɨɠɧɨɫɬɢɈɛɨɛɳɟɧɧɵɣɦɟɬɨɞ Mikhlin S.M., 1957. Variational methods in matheɩɪɹɦɵɯɩɪɢɦɟɧɢɦɞɥɹɩɥɢɬɩɟɪɟɦɟɧɧɨɣɬɨɥɳɢɧɵɚɬɚɤɠɟ matical physics // State-ing because of technical and ɜɡɚɞɚɱɚɯɞɢɧɚɦɢɤɢɈɫɧɨɜɧɚɹɢɞɟɹɫɨɫɬɨɢɬɜɩɨɧɢɠɟɧɢɢ WKHRUHWLFDOOU\0±SLQ5XVVLDQ ɪɚɡɦɟɪɧɨɫɬɢɩɨɩɪɨɫɬɪɚɧɫɬɜɟɧɧɨɣɤɨɨɪɞɢɧɚɬɟɫɩɨɦɨɳɶɸ Kovalenko A.D., 1970. Fundamentals of thermoelastic- ɩɪɨɟɤɰɢɨɧɧɨɝɨɦɟɬɨɞɚɤɩɪɨɟɤɰɢɨɧɧɨɦɭɦɟɬɨɞɭɨɬɧɨɫɢɬɫɹ LW\1DXNRYD'XPND±LQ5XVVLDQ ɦɟɬɨɞȻɭɛɧɨɜɚ±ȽɚɥɟɪɤɢɧɚɨɛɨɛɳɟɧɧɵɣȽɂɉɟɬɪɨɜɵɦ Kovalenko A.D.,1975. Thermoelasticity. Textbook. To >@ȼɪɚɛɨɬɟɦɟɬɨɞɢɤɚɩɨɧɢɠɟɧɢɹɪɚɡɦɟɪɧɨɫɬɢɢɫɩɨɥɶɡɭ9LVKFKD6FKRRO±SLQ5XVVLDQ ɟɬɫɹɞɥɹɪɟɞɭɤɰɢɢɭɪɚɜɧɟɧɢɣɬɟɪɦɨɭɩɪɭɝɨɫɬɢ 6WDQNHYLFK$0&KLEɿU\DNRY9.6NHOH/7 ɄɥɸɱɟɜɵɟɫɥɨɜɚɦɟɬɨɞɩɪɹɦɵɯɦɟɬɨɞȻɭɛɧɨɜɚȽɚɥɺɪɤɢ7KHPHWKRGRIOLQHVLQSURVWRURYɿ\]DGDFKɿWHRUɿʀSUX- ɧɚɉɟɬɪɨɜɚɬɟɪɦɨɭɩɪɭɝɨɫɬɶɬɨɥɫɬɵɟɩɥɚɫɬɢɧɵɫɬɪɨɢɬɟɥɶ]KQRVWɿ1DXNRYDWHKQɿFKQ\]EɿUQLN³2SɿUPDWHUɿDOɿY ɧɚɹɦɟɯɚɧɢɤɚ 5()(5(1&(6 2. 7. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 15–18 Assessment of The Mechanical Properties of Fresh Soil-grown Cucumber Fruits Józef Gorzelany, Natalia Matłok, Dagmara Migut Department of Food and Agriculture Production Engineering of the University of Rzeszów Received December 01.2014; accepted December 17.2014 Summary. The handling, storage, and transportation of fresh FXFXPEHUVDIIHFWWKHZDWHUFRQWHQWLQWKHIUXLWDQGFRQVHTXHQWO\ LWV¿UPQHVVDQGWKHTXDOLW\RI¿QDOSURGXFWV7KLVFRQFHUQV the raw material intended for both direct consumption and processing. The water losses resulting from too long storage VXEVWDQWLDOO\DIIHFWWKH¿QDOSDUDPHWHUVRIWKHSURGXFW7KHDLP of this study was the determination of water content impact on the selected mechanical properties of fresh cucumbers, analysis RIFXFXPEHUVHFWLRQLPDJHDQGDVVHVVPHQWRISHHODQGÀHVK resistance in fresh fruits of the tested cucumber varieties to mechanical damages caused at the process of their puncturing ZLWKDPPGLDPHWHUSXQFK Key words: soil-grown cucumbers, mechanical properties, puncture force of peel and tissue, water content. INTRODUCTION &XFXPEHU&XFXPLVVDWLYXV/EHORQJVWRDQQXDOSODQWV RIKLJKWHPSHUDWXUHDQGVRLOUHTXLUHPHQWV,WUHSUHVHQWV pumpkin vegetables of Cucurbitales order. Their distinguished varieties are those for sowing in soil and those for FXOWLYDWLRQXQGHUFRYHUV>@ The production of soil-grown cucumbers regularly increases due to their high popularity and a wide range RI FXFXPEHU IUXLW XVH ,Q WKH FURS ZDV WRQV DQG LW ZDV FORVH WR WKDW RI ,Q FRPSDULVRQ ZLWKWKHDYHUDJHSURGXFWLRQLQWKHSHULRGWKH SURGXFWLRQRIVRLOJURZQYHJHWDEOHVLQZDVORZHU E\>@ $SDUWIURPWKHPDVVFRQVXPSWLRQRIFXFXPEHUVLQWKH form of fresh fruit, a great part of the total crop is used as a popular processing product used for the production of pickled and conserved cucumbers, gherkins, and pickles. Cucumber fruit intended for processing should have small seed chamber, appropriate chemical composition, sugar FRQWHQWDERYHUHVLVWDQFHWRWKHIRUPLQJDQGSUHVHQFH of voids, high yield in the production at industrial scale, DQGKLJKUHVLVWDQFHWRSHVWV%HVLGHVLWLVLPSRUWDQWWKDW cucumber fruit is of uniform shape and appropriate, regular DQGHTXDOFRORXU>@ %LRORJLFDOPDWHULDOVLQJHQHUDODUHVXEMHFWHGWRYDUious both static and dynamic loads which are connected with the harvest, handling, trans-ship, transport, sorting DQGVWRUDJH$VWKHUHVXOWRIWKHVHWHFKQRORJLFDOSURFHVVHV cucumber fruit undergoes mechanical damages manifesting themselves with both external and internal disturbances of WKHLUWLVVXHFHOOVWUXFWXUH>@0HFKDQLFDOGDPDJHVPDNH the commercial value of the raw material lower so they UHGXFHLWVSURFHVVLQJYDOXH%HVLGHVWKH\FRQWULEXWHWRWKH softening of the cucumber by damaging its peel, which is DVSHFL¿FSURWHFWLRQEDUULHUVXSSRUWLQJWKHFRKHVLYHQHVV of the raw material. The process of cucumber softening favours the formation of next damages and the developPHQWRISXWUHIDFWLYHEDFWHULD>@7KHZD\LQZKLFKIUHVK cucumbers are handled, stored, and transported affect the FRQWHQWRIZDWHULQWKHIUXLWDVZHOODVLWV¿UPQHVVDQGWKH TXDOLW\RIWKH¿QDOSURGXFWV7KLVFRQFHUQVWKHUDZPDWHULDO intended for direct consumption as well as for processing. 7KHORVVHVRIZDWHUFRQWHQWVLJQL¿FDQWO\DIIHFWWKH¿QDO parameters of the product and the mechanical properties of the raw material. The investigation of mechanical properties is the basic measurement instrument of the texture and elasticity of the tested biological material [8]. It includes a series of mechanical tests where compressive, shearing, and tensile IRUFHVDUHXVHG>@7KHGHIRUPDWLRQUDWHGHSHQGVRQWKH value of the used force, rate of the tested material forming, shape and size of the investigated sample as well as such factors as the plant variety, maturity/ripeness degree, raw ¿EUHFRQWHQWZDWHUFRQWHQWDQGWKHPDWHULDO¶VVSHFL¿F density [2, 7, 9]. -Ï=()*25=(/$1<1$7$/,$0$7à2.'$*0$5$0,*87 0(7+2'6$1'0($685,1*$33$5$786 7ZRVL]HIUDFWLRQVWKHVWRQHWRFPDQGWKH QGRQH±FPRI¿YHYDULHWLHVRIVRLOJURZQFXFXPEHU were investigated: Polan FĝUHPVNL)ĝUHPLDQLQ) and WZRFXFXPEHUJHQRW\SHVDVUHIHUHQFHVWDQGDUGVPDWHULDO The samples of the soil-grown cucumber were taken from three farms engaged in the production of vegetables in the YLOODJHRI&LV]\FDĝZLĊWRNU]\VNLH3URYLQFHDQGWKHVWDWLRQRI.UDNRZVND+RGRZODL1DVLHQQLFWZR2JURGQLF]H ³32/$1´(Cracow Plant Breeding and Seed Production “POLAN”) with their seat in Kraków (Raciborowice testing JURXQGV The water content measurement in fresh cucumbers was FRQGXFWHGLQWKH¿UVWVWDJHRIGU\LQJDWWKHWHPSHUDWXUHRI 700&IRUKUVE\PHDQVRIODERUDWRU\LQFXEDWRUDQGWKHQ in the second stage of the drying up of the samples in the WHPSHUDWXUHRI0 C with the use of scale incubator. The tests for the content of water were performed on the samples cut out in three places i.e. at the leaf stalk base, in the middle and in the bottom part of the cucumber fruit for two selected fruit fractions. The investigation of the mechanical properties in the SURFHVVRIWKHSXQFWXULQJRIWKHSHHODQGÀHVKRIIUHVKDQG SLFNOHGFXFXPEHUVZHUHSHUIRUPHGE\PHDQVRI=ZLFN Roell machine for strength testing with the use of the punch RIWKHGLDPHWHURIPP7KHPHDVXUHPHQWZDVSHUIRUPHG in three places, i.e. at the leaf stalk base, in the middle and in the bottom part of the cucumber fruit. The tests were conducted on the whole fruits of soilJURZQFXFXPEHUZLWKUHSHWLWLRQVIRUHDFKRIWKHWKUHH measurement places. The measurement was conducted sepaUDWHO\IRUHDFKVL]HIUDFWLRQ$IWHUHYHU\PHDVXUHPHQWVHULHV WKHDYHUDJHIRUFHUHTXLUHGWRSXQFWXUHFXFXPEHUSHHODQG ÀHVKWKHLUGHIRUPDWLRQDQGWKHHQHUJ\RISXQFWXUHZDV measured. 5(68/762)7+(,19(67,*$7,21 Ta b l e 1 . The average water content of the analyzed varieties of fresh cucumbers Variety and fraction 3RODQVWIUDFWLRQ Polan, 2nd fraction Average ĝUHPLDQLQVWIUDFWLRQ ĝUHPLDQLQQGIUDFWLRQ Average ĝUHPVNLVWIUDFWLRQ ĝUHPVNLQGIUDFWLRQ Average JHQRW\SHVWIUDFWLRQ JHQRW\SHQGIUDFWLRQ Average JHQRW\SHVWIUDFWLRQ JHQRW\SHQGIUDFWLRQ $9(5$*(727$/ Fruit stalk 95.3 95.1 95.1 94.5 94.9 Water content [%] Fruit Fruit $YHUcentre end age 95.4 95.3 95.3 95.0 95.0 95.0 94.8 94.8 94.9 94.6 94.3 94.4 94.8 94.8 94.8 $1$/<6,62)7+(6(&7,21,0$*( 2)7+()5(6+)58,762)6(/(&7(' &8&80%(59$5,(7,(6 The average sizes of the seed chamber surface areas and WKHDUHDRIWKHÀHVKLQWKHPLGGOHSDUWRIWKHLQYHVWLJDWHG varieties of fresh cucumber fruits for two size fractions are presented in Table 2. On the basis of the obtained results it ZDVH[SOLFLWO\IRXQGRXWWKDWWKHVWIUDFWLRQRIWKHĝUHPLDQLQ variety was characterized by the highest percentage share of WKHVHHG]RQH7KHORZHVWSHUFHQWDJHVKDUHRIWKHVHHG zone was found out for the 2nd fraction of the Polan variety, DQGLWDPRXQWHGWR)RUWKHVWIUDFWLRQRIWKHJHQRW\SHWKHVHFWLRQVXUIDFHDUHDZDVZLWKLQWKHUDQJHRI mm2ZKHUHDVIRUWKHJHQRW\SHLWZDVXSWRPP2, DQGIRUWKHQGIUDFWLRQRIWKHJHQRW\SHWKHVHFWLRQVXUIDFH DUHDZDVIURPPP2 WR mm2 for the Polan variety. The average content of water in the fresh cucumber fruits of the investigated varieties was within the range of Ta b l e 2 . 6XUIDFHDUHDVRIWKHVHHGFKDPEHUVDQGÀHVKLQWKH XSWR7KHKLJKHVWZDWHUFRQWHQWZDVIRXQG middle part of the investigated varieties of cucumber fresh fruits in the fruit of the Polan variety, the 2nd fraction size, and for the two size fractions. LWDPRXQWHGWRUHJDUGOHVVIURPZKLFKSODFHWKH Cucumber Seed chamber Flesh surface Fracsection surface area area VDPSOHZDVWDNHQ7KHJHQRW\SHRIWKHVWVL]HIUDFWLRQ Variety tion surface area was featured by the lowest water content in the fruit. The 2 [mm ] [%] [mm2] [%] [mm2] lowest value was found at the fruit stalk base of the variety VW 222.8 UHIHUUHGWRDERYHDQGLWDPRXQWHGWR)URPDPRQJ Polan Polan 2nd the tested varieties the highest content of water was found ĝUHPLDQLQ VW LQWKH3RODQYDULHW\IRUERWKWKHVL]HIUDFWLRQV$QDO\]LQJ ĝUHPLDQLQ 2nd the investigation place, the differences in the average water ĝUHPVNL VW FRQWHQWZHUHLQVLJQL¿FDQW7KHKLJKHVWDYHUDJHZDWHUFRQĝUHPVNL 2nd WHQWZDVREVHUYHGDWWKHIUXLWVWDONDQGLWDPRXQWHGWR 7KHDYHUDJHZDWHUFRQWHQWLQWKHIUHVKIUXLWRIVRLOJURZQ Genotype 44 VW Genotype 44 2nd FXFXPEHUZDV The average water content levels in the fresh fruits of Genotype 54 VW the investigated varieties of soil-grown cucumbers are pre- Genotype 54 2nd VHQWHGLQ7DEOH $66(660(172)7+(0(&+$1,&$/3523(57,(6 $66(660(172)7+()25&(5(48,5(' 72381&785(7+(3((/$1')/(6+2))5(6+ &8&80%(56 7KHIRUFH)>1@UHTXLUHGWRSXQFWXUHWKHSHHODQGÀHVKRI fresh cucumbers and their deformation L [mm] depends on the fruit size, variety, the place of puncturing and the water FRQWHQWLQWKHLQYHVWLJDWHGPDWHULDO,Q)LJWKHDYHUDJH IRUFHUHTXLUHGWRSXQFWXUHWKHSHHODQGÀHVKRIWKHIUHVK fruits of the investigated cucumber varieties in three places, i.e. at the leaf stalk base, in both the middle and the bottom part of the cucumber fruit is presented. Fruit leaf stalk base Fig. 1 $YHUDJHIRUFHUHTXLUHGWRSXQFWXUHWKHSHHODQGÀHVKRI the fresh fruits of the selected varieties of cucumbers with the SXQFKRIWKHGLDPHWHURIPPLQWKUHHSXQFWXUHSODFHV )RUWKHDQDO\]HGYDULHWLHVWKHKLJKHVWIRUFHUHTXLUHG to puncture the peel and flesh of cucumber was observed at the base of the leaf stalk, and the lowest one at the ERWWRPSDUWRIWKHIUXLW7KHKLJKHVWIRUFHV)>1@UHTXLUHG to puncture the peel and flesh were found out for the FXFXPEHUV RI WKH ĝUHPVNL YDULHW\ ZKHUHDV WKH ORZHVW UHVLVWDQFHWRSXQFWXUHZDVREVHUYHGIRUWKHJHQRW\SH The obtained results of the resistance to puncture justify the fact that this genotype has been marked out by Polan company as the standard of the worst technology properties for pickling. In Fig. 2 the lines of the puncture force trend for the SHHODQGÀHVKRIWKHVHOHFWHGYDULHWLHVRIIUHVKFXFXPEHU fruits versus their deformation for three measuring places are presented. The differentiated average values of the IRUFHVUHTXLUHGWRSXQFWXUHWKHSHHODQGÀHVKRIIUHVKFXcumbers versus their deformation for the analyzed varieties were observed. The curve of the relation of the peel and ÀHVKSXQFWXUHIRUFHLQWKHIXQFWLRQRIWKHLUGHIRUPDWLRQ LVGHVFULEHGE\WKHTXDGUDWLFIXQFWLRQRIVHFRQGGHJUHH \ D[2 + bx + c. On the basis of the obtained and presented results )LJDYHU\VWURQJUHODWLRQEHWZHHQWKHIRUFHRIWKH SXQFWXUHRISHHODQGÀHVKDQGWKHGHIRUPDWLRQRFFXUULQJ in the process of the puncturing with a punch at the base of the leaf stalk was found out. The determination coef¿FLHQWVZHUH52 DQG52 IRUWKHVWIUDFWLRQ VPDOOFXFXPEHUVDQGQGIUDFWLRQELJFXFXPEHUVUHspectively. For the middle and the end part of the fresh fruits of selected cucumber varieties the observed relations EHWZHHQWKHSHHODQGÀHVKSXQFWXUHIRUFHDQGWKHGHIRUmation were smaller and differentiated. The determination FRHI¿FLHQWVZHUH Middle part of the fruit End part of the fruit Fig. 2. /LQHVRIWKHWUHQGRIWKHDYHUDJHIRUFH)>1@UHTXLUHGWR SXQFWXUHWKHSHHODQGÀHVKRIWKHIUHVKFXFXPEHUVRIVHOHFWHG YDULHWLHVZLWKWKHSXQFKRIWKHGLDPHWHURIPPYHUVXVWKHLU deformation L [mm] in three puncture places. 7KHPLGGOHSDUWRIFXFXPEHUIUXLWVWIUDFWLRQ±52 QGIUDFWLRQ±52 7KHHQGSDUWRIFXFXPEHUIUXLW VWIUDFWLRQ±52 QGIUDFWLRQ±52 The average deformation L [mm] values until the fresh cucumber fruits were punctured had been within the range IURPPPXSWRPP7KHELJJHVWGHIRUPDWLRQZDV REVHUYHGIRUWKH3RODQYDULHW\WKHVWVL]HIUDFWLRQDQGLW DPRXQWHGWRPPZKHUHDVWKHVPDOOHVWRQH±LQWKH JHQRW\SHDOVRIRUWKHVWVL]HIUDFWLRQDQGLWZDVPP 7KHDYHUDJHSXQFWXUHHQHUJ\UDWHIRUSHHODQGÀHVKDV ZHOODVWKHSHHODQGÀHVKEUHDNLQJVWUHVVIRUWKHDQDO\]HG fresh cucumber varieties versus their size fraction is preVHQWHGLQ7DEOH -Ï=()*25=(/$1<1$7$/,$0$7à2.'$*0$5$0,*87 Ta b l e 3 . $YHUDJHUDWHRIWKHSXQFWXUHHQHUJ\IRUWKHFXFXPEHU SHHODQGÀHVKDQGWKHEUHDNLQJVWUHVVHV Variety and fraction (QHUJ\:>-@ Breaking stress [MPa] 3RODQVWIUDFWLRQ Polan, 2nd fraction ĝUHPLDQLQVWIUDFWLRQ ĝUHPLDQLQQGIUDFWLRQ ĝUHPVNLVWIUDFWLRQ ĝUHPVNLQGIUDFWLRQ 89,8 *HQRW\SVWIUDFWLRQ *HQRW\SQGIUDFWLRQ *HQRW\SVWIUDFWLRQ *HQRW\SQGIUDFWLRQ Average – 1st fraction 66,1 1,45 Average – 2nd fraction 79,5 1,61 %DVHGRQWKHREWDLQHGUHVXOWVLWZDVIRXQGRXWWKDWWKH DYHUDJHEUHDNLQJVWUHVVYDOXHVZHUH03DDQG03D IRUWKHVWDQGQGVL]HIUDFWLRQUHVSHFWLYHO\7KHDYHUDJH YDOXHVRIWKHHQHUJ\QHHGHGWRSXQFWXUHWKHSHHODQGÀHVK IRUWKHDQDO\VHGVWDQGQGIUDFWLRQVZHUH-DQG- respectively. The highest energy needed to puncture the peel DQGÀHVKRIWKHDQDO\VHGIUHVKFXFXPEHUIUXLWVZDVREVHUYHG IRUWKHĝUHPLDQLQYDULHW\WKHQGIUDFWLRQDQGWKHVPDOOHVW RQHIRUWKHJHQRW\SH±WKHVWVL]HIUDFWLRQ7KRVHYDOXHV ZHUH-DQG-UHVSHFWLYHO\7KHORZHVWEUHDNLQJ VWUHVVZDVREVHUYHGIRUWKHJHQRW\SHWKHVWIUDFWLRQ±LW DPRXQWHGWR03DZKHUHDVWKHKLJKHVWRQHV±IRUWKH ĝUHPLDQLQYDULHW\WKHQGVL]HIUDFWLRQDQGWKHĝUHPVNL YDULHW\WKHVWIUDFWLRQ±ZHQWXSWR03D CONCLUSIONS 7KHDYHUDJHFRQWHQWRIZDWHUIRUWKHDQDO\]HGFXFXPEHU varieties was slightly differentiated and it was in the UDQJHIURPIRUWKHJHQRW\SHWKHVWIUDFWLRQ WRIRUWKH3RODQYDULHW\WKHQGIUDFWLRQ 2. In the middle part of the cucumber fresh fruits of the tested varieties the highest percentage share of the seed ]RQHZDVREVHUYHGIRUWKHĝUHPLDQLQYDULHW\WKHVWVL]H fraction, and the lowest one for the Polan variety, the QGIUDFWLRQDQGWKH\DPRXQWHGWRDQG respectively. 7KHDYHUDJHIRUFH)>1@QHHGHGWRSXQFWXUHWKHSHHODQG ÀHVKRIWKHDQDO\]HGYDULHWLHVRIIUHVKFXFXPEHUIUXLWV ZDVZLWKLQWKHUDQJHRI±1DQGWKHKLJKHVW UHVLVWDQFHWRSXQFWXULQJZDVVKRZQE\WKHĝUHPLDQLQ YDULHW\ZKHUHDVWKHJHQRW\SHVKRZHGWKHORZHVWRQH 7KHDYHUDJHUDWHVRIGHIRUPDWLRQ/>PP@WRWKHPRPHQW ZKHQWKHSHHODQGÀHVKZHUHSXQFWXUHGKDGEHHQZLWKLQ WKHUDQJHRIXSWRPP 7KHDYHUDJHHQHUJ\:>-@UHTXLUHGWRSXQFWXUHWKHSHHO DQGÀHVKRIWKHIUHVKFXFXPEHUVRIWKHWHVWHGYDULHWLHV DQGWKHEUHDNLQJVWUHVVı>03D@ZHUHWKHVWDQGWKH QGVL]HIUDFWLRQ±-DQG-UHVSHFWLYHO\DQG WKHVWDQGWKHQGVL]HIUDFWLRQ±03DDQG MPa, respectively. 5()(5(1&(6 Bargel H., Neinhuis C., 2005: Tomato fruit growth and ripening as related to the biomechanical properties of IUXLWVNLQDQGLVRODWHGFXWLFOH-RXUQDORI([SHULPHQWDO %RWDQ\ 2. Bohdziewicz J., Czachor G., 2010: :Sá\ZREFLąĪHQLD QDSU]HELHJRGNV]WDáFHQLDZDU]\ZRNV]WDáFLHNXOLVW\P ,QĪ\QLHULD5ROQLF]D &LXSDN$*áDG\V]HZVND%:áDĞFLZRĞFLPHFKDQLF]QHVNyUNLRZRFyZSRPLGRUDZUyĪQ\FKWHPSHUDWXUDFKSU]HFKRZ\ZDQLD$FWD$JURSK\VLFD *áyZQ\8U]ąG6WDW\VW\F]Q\:\QLNRZ\V]DFXQHNSURGXNFMLJáyZQ\FK]LHPLRSáRGyZUROQ\FKLRJURGQLF]\FK ZURNX,QIRUPDFMDV\JQDOQD '\QDPLF]QHPHWRG\SRPLDUXZáDVQRĞFLPHFKDQLF]Q\FK RZRFyZLZDU]\Z$FWD$JURSK\VLFD Brickell, C. D.; Alexander, C.; David, J. C.; Hetterscheid, W. L. A.; Leslie, A. C.; Malecot, V.; XiaoBai Jin; Cubey, J. J., 2009: ,QWHUQDWLRQDO6RFLHW\IRU+RUticultural Science. International code of nomenclature for cultivated plants. 7. -DNXEF]\N(/HZLFNL33:áDĞFLZRĞFLPHFKDQLF]QHWNDQNLMDEáNDZRGQLHVLHQLXGRMHMVWUXNWXU\ $FWD$JURSK\VLFD 8. -DNXEF]\N(8]LDN'Charakterystyka instruPHQWDOQ\FKPHWRGEDGDQLDZáDĞFLZRĞFLPHFKDQLF]Q\FK Z\EUDQ\FKRZRFyZLZDU]\Z,QĪ\QLHULD5ROQLF]D 9. Marzec A., Pasik S., 2008: :Sá\ZPHWRG\VXV]HQLDQD ZáDĞFLZRĞFLPHFKDQLF]QHLDNXVW\F]QHVXV]\PDUFKZLRZ\FK,QĪ\QLHULD5ROQLF]D 6]F]ĊĞQLDN$6Texture is a sensory property. )RRG4XDOLW\DQG3UHIHUHQFH Wrzodak A., Korzeniowski M., 2012:-DNRĞüVHQVRryczna ogórków kwaszonych z owoców traktowanych IXQJLF\GDPLZXSUDZLHSRORZHM1RZRĞFL:DU]\ZQLF]H 2&(1$:<%5$1<&+:à$ĝ&,:2ĝ&, 0(&+$1,&=1<&+ĝ:,(ĩ<&+2:2&Ï: 2*Ï5.$*58172:(*2 Streszczenie. 6SRVyESRVWĊSRZDQLDSU]HFKRZ\ZDQLDLWUDQVSRUWXĞZLHĪ\FKRJyUNyZPDZSá\ZQD]DZDUWRĞüZRG\ZRZRFX ZNRQVHNZHQFMLQDMHJRMĊGUQRĞüLMDNRĞüSURGXNWyZ¿QDOQ\FK 'RW\F]\WRVXURZFDSU]H]QDF]RQHJREH]SRĞUHGQLRGRVSRĪ\FLD MDNUyZQLHĪGRSU]HWZyUVWZD8E\WNLZRG\Z\QLNDMąFH]H]E\W GáXJLHJRSU]HFKRZ\ZDQLDPDMąLVWRWQ\ZSá\ZQDSDUDPHWU\ NRĔFRZHSURGXNWX&HOHPSUDF\E\áR RNUHĞOHQLHZSá\ZX]DZDUWRĞFLZRG\QDZ\EUDQHFHFK\PHFKDQLF]QHĞZLHĪ\FKRJyUNyZ DQDOL]DREUD]XSU]HNURMXRUD]RFHQDRGSRUQRĞFLVNyUNLLPLąĪV]X ĞZLHĪ\FKRZRFyZEDGDQ\FKRGPLDQRJyUNyZQDXV]NRG]HQLD PHFKDQLF]QHSRZVWDáHZSURFHVLHSU]HELFLDVWHPSOHPRĞUHGQLF\PP 6áRZDNOXF]RZHRJyUNLJUXQWRZHZáDĞFLZRĞFLPHFKDQLF]QH VLáDSU]HELFLDVNyUNLLWNDQNL]DZDUWRĞüZRG\ TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 19–22 Quality of Dill Pickled Cucumbers Depending on The Variety And Chemical Composition of Pickle Brine Józef Gorzelany1, Natalia Matłok1, Dagmara Migut1, Tomasz Cebulak2 Department of Food and Agriculture Production Engineering of the University of Rzeszów 2 Department of Technology and Assessment of Plant Products 1 Received December 11.2014; accepted December 19.2014 Summary. Dill pickled cucumbers is the product obtained from fresh cucumbers with the addition of taste-aromatic seasonings poured with a water solution of table salt and subjected to lactic acid fermentation. There are many kinds of pickling technology, and many types of pickle brines. 7KLVLVWKHUHDVRQRXUZRUNZDVDLPHGDWWKHTXDOLWDWLYHDVsessment of dill pickled cucumbers depending on the pickle brine chemical composition. On the basis of organoleptic DVVHVVPHQWDGLYHUVL¿HGVHQVRU\TXDOLW\DVVHVVPHQWRIWKH tested dill pickled cucumbers was carried out depending on pickle brine chemical composition. Key words: dill pickled cucumbers, pickle brines, organoleptic assessment INTRODUCTION Dill pickled cucumbers are very popular in our country and they win over larger and larger group of connoisseurs and FXVWRPHUVIURPDEURDG$SDUWIURPWKHFKDUDFWHULVWLFWDVWH they have many pro-health properties, and that is why they are often recommended by dieticians as an item of a well-balDQFHGGLHW>@7KHODFWLFDFLGIRUPHGE\WKHIHUPHQWDWLRQSURFHVVDQGFRQWDLQHGLQVLODJHVORZHUVWKHS+YDOXHVLQLQWHVWLQHV DQGE\WKLVLWIDYRXUVWKHSUROLIHUDWLRQRIWKHLQWHVWLQDOÀRUD The endogenic strains of lactic acid bacteria, when present in a ready product, contribute to the formation of the characteristic taste of ensilaged products [7]. Dill pickled cucumbers FRQWDLQDOVRYLWDPLQ&DQGWKH%JURXSYLWDPLQV 7KHTXDOLW\RIWKH¿QDOSURGXFWLVVLJQL¿FDQWO\DIIHFWHG by both the cucumber variety and the components of the SLFNOHEULQHXVHG$QDSSURSULDWHVHOHFWLRQRIUDZPDWHULDOV and their share in the ready pickle brine allow obtaining an optimum taste-smell effect. The important aspect is the use RIZDWHURIDSSURSULDWHTXDOLW\FRQIRUPLQJWRWKHUHTXLUH- ments for drinking water and its hardness, which may be increased by adding calcium carbonate. The pickle brine is a water based solution of table salt enriched with natural taste-aromatic additives, the most common of which are dill and horseradish. They create a characteristic, strong aroma of dill pickled cucumbers [2]. Sodium chloride added to the brine enables an initial selection of microorganisms and faster growth of lactic acid mesophilic bacteria such as L. paracasei, L. casei, L. plantarum, L. rhamnosus>@ $GGLWLRQRISURELRWLFVWDUWHUFXOWXUHVWRWKHSLFNOHEULQH DOORZVWRREWDLQDKLJKTXDOLW\SURGXFWGXHWRWKHLUDQWDJRnistic reactions to detrimental moulds or yeasts, The essential hazard arising during spontaneous fermentation process is the risk of infection by Geotrichum candidum or Picha manshurica \HDVWVZKLFKE\UDLVLQJWKHHQYLURQPHQWDOS+ due to the oxidation of organic acids enable the development RISXWUHIDFWLYHEDFWHULD>@ Salt, as a component of pickle brine reduces the osmotic pressure and by this the brine gets enriched in nutritional components and becomes an appropriate environment for WKHGHYHORSPHQWRIWKHIHUPHQWDWLRQPLFURÀRUD'LIIXVLRQ processes proceed slowly, and that it is why the fermentation in the anaerobic environment is a lengthy process [8]. Sensory assessment carried out by predisposed tasters, i.e. those without changes in the felt taste and disorders such as the so called taste daltonism manifesting itself as a lack of sense of taste and feeling no differences between the four basic tastes, in appropriate concentration is an important element while introducing the product to the market as well as during laboratory tests aimed at the improvement of technological processes. Changes in taste perception may be caused by too low content of zinc in the human organism, which can be often observed in people RQYHJHWDULDQGLHWV>@ -Ï=()*25=(/$1<1$7$/,$0$7à2.'$*0$5$0,*87720$6=&(%8/$. 20 Sensory assessment, apart from physical-chemical one, is a supplementary method of the assessment of SURGXFWTXDOLW\6XFKDVVHVVPHQWVSURYLGHLQIRUPDWLRQ on the reaction of the senses to the consumption of a product [9]. 0$7(5,$/$1'0(7+2'2/2*< The tested material were the fruits of three varieties of soil-grown cucumbers (Polan FĝUHPVNL)DQGĝUHPLDQLQ FDQGWKHJHQRW\SHVXEMHFWHGWRWKHSLFNOLQJSURFHVV The cucumbers of the selected varieties were pickled in large glass jars with the pickle brines of three different FKHPLFDOFRPSRVLWLRQV7KHJHQRW\SHVLQJOHGRXWE\ WKH.UDNRZVND6WDFMD+RGRZOLL1DVLHQQLFWZDÄ3RODQ´ (Cracow Plant Breeding and Seed Production “POLAN”) as a standard of the variety non-predisposed to pickling was subjected to this process in one type of pickle brine LQRUGHUWRFRQ¿UPLWVZRUWKOHVVQHVVWRWKHWHFKQRORJLFDO SURFHVVLQTXHVWLRQ8QWLODQLQWHQVLYHIHUPHQWDWLRQVWDUWHG the jars were stored in the room temperature, and after that WKH\ZHUHWUDQVIHUUHGWRDURRPZLWKWKHWHPSHUDWXUHRI0 C. The chemical composition of pickle brines is presented LQ7DEOH The tests included the organoleptic assessment of the TXDOLW\IHDWXUHVVXFKDVJHQHUDODSSHDUDQFHFRORXUFRQsistency, taste, and smell. The organoleptic assessment ZDVFDUULHGRXWE\WKHVFRUHPHWKRGSRLQWPHWKRG FRQVLVWLQJLQWKHGHWHUPLQDWLRQRIWKHTXDOLW\OHYHOVRI LQGLYLGXDOTXDOLW\IHDWXUHVGHWHUPLQDQWVE\PHDQVRI QXPHULFDOYDOXHVDQGH[SUHVVLQJWKHWRWDOTXDOLW\RIWKH Ta b l e 1 . Chemical composition of the pickle brines used for the pickling of the tested varieties of soil-grown cucumbers. Component 3,&./(%5,1(&+(0,&$/&20326,7,21 A B Addition for 100 kg of Addition for 100 kg Component Component cucumbers (%) of cucumbers (%) C Addition for 100 kg of cucumbers (%) Water solution of NaCl Water solution of NaCl Water solution of NaCl Fresh dill +RUVHUDGLVKURRW Mustard *DUOLF 0.2 Fresh dill +RUVHUDGLVKURRW *DUOLF Mustard 0.2 Fresh dill +RUVHUDGLVKURRW *DUOLF Mustard 0.2 Currant leaves %D\OHDYHV Oak tree leaves %D\OHDYHV %D\OHDYHV %D\OHDYHV *UHHQPDUMRUDP 0.02 %D\OHDYHV Whole grain dark pepper 3URELRWLF(0 Ta b l e 2 . Card of the assessment by score method for tested dill pickled cucumbers 48$/,7<)($785(62)',//3,&./('&8&80%(56 Scale of score points Quality de- Weightiness terminant FRHI¿FLHQWV 5 points 4 points 3 points 2 points very hard, crispy, medium hard, no soft, with small VRIWVLJQL¿FDQW Consistency no void cavities void cavities inside void cavities inside void cavities inside inside very salty, very too salty and sour, medium salty and sour, typical for Taste too little-salty and salty, sour sour dill pickled cutoo little cumbers intense, aromatic, slightly perceptible medium perceptitypical for dill hardly perceptible with no perceptible pickled cucumbers ble with medium Smell with faint aroma of 0.2 aroma of additives aroma of additives with perceptible additives and herbs and herbs smell of herbs and and herbs other additives good, close to typiwith well visible very good, fullcal for dill pickled with not numerous large brown, dark dark green colourColour cucumbers, lighter discolouration brown or white ing, typical for dill spots at the ends spots along the spots at the ends pickled cucumbers whole length medium, minimal- minimal indicavery good, typical good, close to typiGeneral ly differing from tions of rooting 0.2 for dill pickled cal for dill pickled appearance typical for dill and getting cucumbers cucumbers pickled cucumbers mouldy 1 point very soft, large void cavities inside oversalted, too sour, no perceptible taste of salt non-sour not perceptible, musty brown, dark brown or white indicating rooting mouldy, spoiled 48$/,7<2)',//3,&./('&8&80%(56 product being assessed on the basis on those values. The score assessment was based on the comparison of the TXDOLW\RIVXEVHTXHQWSURGXFWIHDWXUHVZLWKWKHTXDOLW\ GH¿QLWLRQVVSHFL¿HGLQWKHVFRUHDVVHVVPHQWFDUG7DEOH DQGZULWLQJWKHREWDLQHGGDWDGRZQLQWRDVSHFLDOUHSRUW form. The obtained data were multiplied by appropriate ZHLJKWLQHVVFRHI¿FLHQWVRITXDOLW\GHWHUPLQDQWVRIWKH ¿QDOSURGXFW7KHSDUWLFLSDQWVLQWKHSURFHGXUHRIGLOO SLFNOHG FXFXPEHUV DVVHVVPHQW ZHUH HPSOR\HHV RI the University of Rzeszów, having appropriate sensory sensitivity. The organoleptic assessment of dill pickled cucumbers was carried out in the Laboratory of OrganoOHSWLF$VVHVVPHQWRI3URGXFWVRIWKH)DFXOW\RI%LRORJ\ DQG$JULFXOWXUHDWWKH8QLYHUVLW\RI5]HV]yZ To determine the possible usefulness for the processing of the analyzed varieties of cucumbers some photographs of the cross-sections of soil-grown cucumbers were taken during the pickling process. The pictures were taken in three places: at the leaf stalk base, in the central and in the end part of the cucumber fruit. The pictures were taken for two size fractions: I-fraction, i.e. small fruits, II-fraction. i.e. large fruits. The views of the surfaces of the cross-sections were obtained by the view scanning method by scanning slices cut off from the eatable part of the fruits of the analysed varieties. tic assessment of the dill pickled cucumbers versus the variety and the chemical composition of pickle brine are SUHVHQWHGLQ)LJ The lowest score, irrespectively of the pickle brine FKHPLFDOFRPSRVLWLRQZDVREWDLQHGE\WKHĝUHPVNL)vaULHW\SRLQWVZKHUHDVWKHORZHVWRQHSRLQWVZDV given to the Polan F variety. On the basis of the results of the organoleptic assessment of dill pickled soil-grown cucumber it can be stated that from among the tested varieties WKHPRVWXVHIXOIRUGLOOSLFNOLQJYDULHW\LVWKHĝUHPVNL), while the least useful one is the Polan F. The results of the usefulness of the tested cucumber varieties for dill pickling are presented in Fig. 2. 5(68/762)7(676$1'',6&866,21 Fig. 1. $VVHVVPHQWRIWKHWHVWHGTXDOLW\IHDWXUHVRIGLOOSLFNOHG cucumbers as the function of variety and chemical composition of pickle brine. )LJSUHVHQWVWKHUHVXOWVRIWKHDVVHVVPHQWRILQGLYLGXDO TXDOLW\ IXWXUHV JHQHUDO DSSHDUDQFH FRQVLVWHQF\ WDVWHFRORXUDQGVPHOORIWKHIUXLWVRIWKHWHVWHGYDULHties of soil-grown cucumbers dill pickled in three pickle brines of different chemical composition. Irrespective of the cucumber variety and the brine chemical composition, the assigned tasters assessed the general appearance of dill pickled cucumbers as the highest (appraisal arithmetic mean ZDVDQGWKHWDVWHDVWKHORZHVWDULWKPHWLFPHDQ The arithmetic mean values for the consistency, smell, and FRORXURIWKHWHVWHGGLOOSLFNOHGFXFXPEHUVZHUH DQG±UHVSHFWLYHO\7KHKLJKHVWVFRUHDPRXQWLQJWR was given by the assessing persons to the general appearance RIWKHFXFXPEHUVRIWKHĝUHPLDQLQ) variety pickled in the SLFNOHEULQH$ZKHUHDVWKHORZHVWVFRUHZDVREWDLQHGE\ WKHFRQVLVWHQF\RIWKHFXFXPEHUVRIWKHĝUHPVNL) variety SLFNOHGLQWKHEULQH% The organoleptic assessment of dill pickled cucumbers was conditioned by both the cucumber variety and the pickle brine chemical composition. The highest score, in WKHVFDOHRIWRZDVJLYHQWRWKHIUXLWVRIVRLOJURZQ FXFXPEHURIWKHĝUHPVNL) variety pickled in the brine %7KHORZHVWRQHRQO\SRLQWVZDVREWDLQHGE\WKH cucumbers of the Polan F variety pickled in the brine % 'XULQJ WKH RUJDQROHSWLF DVVHVVPHQW RI WKH FXFXPEHUIUXLWVVLQJOHGRXWE\WKH.UDNRZVND6WDFMD+RGRZOL L1DVLHQQLFWZDÄ3RODQ´LHWKHJHQRW\SHDVWKHYDULHW\ useless for the dill pickling process, this variety obtained DYHUDJHVFRUHSRLQWV7KHUHVXOWVRIWKHRUJDQROHS- Fig. 2. 0HDQVFRUHVRIWKHWHVWHGTXDOLW\IHDWXUHVRIGLOOSLFNOHG soil-grown cucumbers with regard to their usefulness for dill pickling. Regardless of the variety of soil-grown cucumbers, the best score was given to the cucumbers subjected to pickling in the pickle brine C. The mean value for all the tested YDULHWLHVLQWKLVEULQHZDVSRLQWV7KHORZHVWVFRUH SRLQWVREWDLQHGWKHFXFXPEHUVSLFNOHGLQWKHEULQH%DQG WKHFXFXPEHUVSLFNOHGLQWKHEULQH$ZHUHJLYHQSRLQWV On the basis of the obtained results it was found out that, regarding chemical composition, the C brine is the most VXLWDEOHIRUSLFNOLQJFXFXPEHUVZKHUHDVWKH%EULQH±WKH least suitable. The results of the assessment of pickle brines of three different chemical compositions with regard to WKHLUXVHIXOQHVVIRUSLFNOLQJDUHSUHVHQWHGLQ)LJEHORZ 22 -Ï=()*25=(/$1<1$7$/,$0$7à2.'$*0$5$0,*87720$6=&(%8/$. 5()(5(1&(6 &DSOLFH()LW]JHUDOG* Food fermentation: role of microorganisms in food production and preserYDWLRQ,QW-)RRG0LFURELRO± 2. &KDEáRZVND%3LDVHFND-yĨZLDN.5R]PLHUVND -6]NXG]LĔVND5]HV]RZLDN(Initiated lactic acid fermentation of cucumbers from organic farm by application of selected starter cultures of lactic acid bacWHULD-5HV$SSO$JULF(QJ± Franco W., Perez-Diaz I., Johanningsmeier S., McFeeters R., 2012: Characteristic of spoilage-associated Fig. 3. Mean values of the assessment of brines of different HFRQGDU\FXFXPEHUIHUPHQWDWLRQ$SSO(QYLURQ0LFURchemical composition with regard to their usefulness for pickling ELRO cucumbers. *DMHZVND-%áDV]F]\N0Probiotyczne bakWHULH IHUPHQWDFML POHNRZHM /$% 3RVW 0LFURELRO ± *DOLĔVNL**DZĊFNL-$QLRáD-(IIHFWRI VHQVRULO\YDULHGIRRGVWXIIVRQVHQVRU\VSHFL¿FVDWLHW\ LQ\RXQJDGXOWVGHSHQGLQJRQWKHLUVH[±DVKRUWUHSRUW 3RO-)RRG1XWU6FL± *DOLĔVNL*:DONRZLDN-:yMFLDN5:*DZĊFNL -.UHMSFLRO=Stan wysycenia organizmu cynNLHPDZUDĪOLZRĞüVPDNRZDLZ\VWĊSRZDQLH]MDZLVND V\WRĞFLVHQVRU\F]QLHVSHF\¿F]QHMXPáRG\FKZHJHWDULDQ %URPDW&KHP7RNV\NRO;/,9± 7. +DQVHQ( Commercial bacterial starter cultures for femented foods of the future. Int. J. Food Microbiol. ± Fig. 4. Cross-sections of the tested varieties of dill pickled soil ±JURZQFXFXPEHU 8. 3LDVHFND-yĨZLDN.&KDEáRZVND%5R]PLHVND- 2013:=DVWRVRZDQLHEDNWHULLIHUPHQWDFMLPOHNRZHMMDNR The examples of the views of the cross-sections of cuNXOWXUVWDUWHURZ\FKZNLV]HQLXZDU]\Z3U]HP\VáIHUFXPEHUVRIWKHWHVWHGYDULHWLHVRQWKHWKGD\RISLFNOLQJ PHQWDF\MQ\LRZRFRZRZDU]\ZQ\± SURFHVVDUHVKRZQLQ)LJ:KHQDQDO\VLQJWKHYLHZRIWKH 9. Wrzodak A., Korzeniowski M., 2012:-DNRĞüVHQVRcross-sections of the tested pickled cucumber fruits, the largryczna ogórków kwaszonych traktowanych fungicydami est air spaces were found for the Polan Fvariety, which conZXSUDZLHSRORZHM1RZ:DU]± VHTXHQWO\DIIHFWHGWKHJHQHUDOVHQVRU\DVVHVVPHQWRIWKH¿QDO =DUĊED'=LDUQR0$OWHUQDW\ZQHSURELRSURGXFWUHVXOWVRIWKHFDUULHGRXWRUJDQROHSWLFDVVHVVPHQW W\F]QHQDSRMHZDU]\ZQHLRZRFRZH%URPDW&KHP 7RNV\NRO;/,9± CONCLUSIONS 7KHTXDOLW\RIWKH¿QDOSURGXFWREWDLQHGWKURXJKWKHSURcess of dill pickling of soil-grown cucumbers is conditioned by both the variety and the chemical composition of the pickle brine. 2. From among the varieties of soil-grown cucumbers being WHVWHGWKHĝUHPVNL)YDULHW\SURYHGWREHWKHPRVWXVHIXO for pickling, and the least useful was the Polan F. Regardless of the chemical composition of the brine used in the pickling process, the cucumbers of the varieties referred to above obtained the following organoleptic assessment VFRUHVĝUHPVNL)±SRLQWV3RODQ)SRLQWV %DVHGRQWKHRUJDQROHSWLFDVVHVVPHQWLWZDVIRXQGRXW that the pickle brines of the chemical composition C and $DUHWKHPRVWXVHIXOIRUGLOOSLFNOLQJRIWKHDQDO\]HG varieties of soil-grown cucumber fruits. -$.2ĝû2*Ï5.Ï:.:$6=21<&+ :=$/(ĩ12ĝ&,2'2'0,$1< ,6.à$'8&+(0,&=1(*2=$/(:< Streszczenie. 2JyUNLNZDV]RQHWRSURGXNWRWU]\PDQ\]HĞZLHĪ\FKRJyUNyZ]GRGDWNLHPSU]\SUDZVPDNRZRDURPDW\F]nych, zalanych roztworem soli kuchennej i poddanych procesowi IHUPHQWDFMLPOHNRZHM,VWQLHMHEDUG]RGXĪDOLF]EDWHFKQRORJLL NZDV]HQLDDWDNĪHURG]DMyZ]DOHZ'ODWHJRWHĪFHOHPSUDF\ E\áDRFHQDMDNRĞFLRZDRJyUNyZNZDV]RQ\FKZ]DOHĪQRĞFLRG VNáDGXFKHPLF]QHJR]DOHZ\1DSRGVWDZLHSU]HSURZDG]RQHM RFHQ\RUJDQROHSW\F]QHMVWZLHUG]RQR]UyĪQLFRZDQąMDNRĞüVHQVRU\F]QąEDGDQ\FKRGPLDQRJyUNyZNZDV]RQ\FKZ]DOHĪQRĞFL RGRGPLDQ\LVNáDGX]DOHZ\ 6áRZDNOXF]RZHogórki kwaszone, zalewy, ocena organoleptyczna. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 23–30 Research on the Frost Resistance of Concretes Modified with Fly Ash Jacek Halbiniak, Bogdan Langier Department of Technology of Building Processes and Materials Czestochowa University of Technology, Faculty of Civil Engineering Akademicka 3, 42-200 Częstochowa, [email protected];[email protected] Received December 04.2014; accepted December 17.2014 Summary. 7KHSDSHUSUHVHQWVWKHLQÀXHQFHRIDGGLQJÀ\DVKHV and air-entraining admixture on the frost resistance of concrete tested by the direct method and on the characteristics of air pores. 7KHIURVWUHVLVWDQFHWHVWZDVGRQHIRUIUHH]HWKDZF\FOHV7KH porosity structure of concrete composites was tested by means of a device for automatic image analysis that uses the computer program Lucia Concrete. The analysis involved control concrete DQGFRQFUHWHZLWKWKHDGGLWLRQRIÀ\DVK±KDOIWKHPD[LPXP SHUPLVVLEOHTXDQWLW\±WKDWZDVDLUHQWUDLQHGZLWKYDULRXVGRVHV of air-entraining admixture. Key words: FRQFUHWHÀ\DVKHVDLUSRUHVFKDUDFWHULVWLFVIURVW resistance. INTRODUCION Concrete durability is a set of designed properties that the material retains for the longest possible usage period of the engineering construction. The basic factor that determines the usefulness of concrete for a construction is its compresVLYHVWUHQJWK+RZHYHUWKHUHDUHRWKHUIDFWRUVWKDWLQÀXHQFH concrete durability in a construction besides its strength, like for example proper selection of ingredients and their approSULDWHTXDOLW\SURSHUPRXOGLQJFXULQJDQGSURFHVVLQJWKH LQÀXHQFHRIFRUURVLYHHQYLURQPHQWVDVZHOODVFHPHQWVOXUU\ microstructure and the structure of the aggregate-cement VOXUU\WUDQVLWRU\OD\HU>@ Concrete is a composite whose features can be shaped E\DGGLWLYHVPLFUR¿OOHUVDQGDGPL[WXUHV7KH\PDNHLW possible to obtain concretes with special properties, but to REWDLQKLJKIURVWUHVLVWDQFHRIFRQFUHWHVZLWKDODUJHTXDQWLW\ RIDGGLWLYHVDSURSHUDLUHQWUDLQPHQWLVQHFHVVDU\>@ 7KHQRUP31(1LQWURGXFHVFRQFUHWHH[SRVXUH FODVVHVIURP;)WR;)GHSHQGHQWRQWKHLQÀXHQFHRIIURVW RQFRQFUHWH7KH;)FODVVLQFOXGHVFRQFUHWHVYHUWLFDOHOHPHQWVWKDWDUHPRGHUDWHO\VDWXUDWHGZLWKZDWHUZLWKRXWDQti-icing agents. Vertical concrete elements exposed to weather conditions and anti-icing agents should be made with the ;)FODVVFRQFUHWH+RUL]RQWDOFRQFUHWHHOHPHQWVKLJKO\ saturated with water without anti-icing agents, exposed to IURVWVKRXOGEHPDGHZLWKWKH;)FODVVFRQFUHWH&RQFUHWH surfaces of roads and bridges, exposed to high saturation with water and anti-icing with chemical agents should be PDGHZLWKWKH;)FODVVFRQFUHWH7KH;);)DQG;) FRQFUHWHVUHTXLUHDLUHQWUDLQPHQWRIWKHFRQFUHWHPL[&RQcretes that belong to the above-mentioned exposure classes VKRXOGPHHWWKHIROORZLQJUHTXLUHPHQWVSUHVHQWHGLQ7DEOH The content of air in road surface concretes presented in the Polish catalogue [8] depends on the maximal diameter of aggregate grains. The values are shown in Table 2. $FFRUGLQJWR*HUPDQUHTXLUHPHQWVWKHPLQLPDOFRQWHQW RIDLULQURDGVXUIDFHFRQFUHWHVVKRXOGEHIRUFRQFUHWHV ZLWKRXWSODVWLFL]HUVDQGIRUFRQFUHWHVZLWKSODVWLFL]HUV according to [20]. $FFRUGLQJWR)UHQFKUHTXLUHPHQWVWKHPLQLPDODPRXQW RIDLULQVXUIDFHFRQFUHWHVVKRXOGEHDQGWKHPD[LPDO ±DFFRUGLQJWR>@ $LUHQWUDLQLQJDGPL[WXUHVDUHXVHGWRIRUPPLFURVFRSLF DLUEXEEOHVZLWKDGLDPHWHURIDSSUR[LPDWHO\P7KHDLU bubbles are distributed in the cement slurry and they break the continuity of capillaries, which leads to higher resistance of concrete to freeze-thaw cycles. When water in saturated FRQFUHWHWXUQVIURPDOLTXLGVWDWHWRDVROLGVWDWHLWVYROXPHLQFUHDVHVDQGWKHLFHVTXHH]HVLQWRHPSW\DLUEXEEOHV $LUHQWUDLQLQJPDNHVFRQFUHWHPRUHIURVWUHVLVWDQWDQGWKH concrete mixture becomes more workable. $LUHQWUDLQLQJDGPL[WXUHVFKDQJHWKHVWUXFWXUHRIWKH FHPHQWVOXUU\IURPPLFURFDSLOODU\WRPLFURSRURXV)LJ The admixture has a foaming effect and forms enclosed air EXEEOHVZLWKWKHGLDPHWHURIDSSUR[LPDWHO\PZKLFK DUHHYHQO\GLVWULEXWHG$VWKHFRQFUHWHKDUGHQVWKHVXUIDFH of the air bubbles undergoes mineralization and becomes the phase of the hardened concrete. They break the capillary QHWZRUNDQGUHGXFHWKHULVHRIZDWHU>@ -$&(.+$/%,1,$.%2*'$1/$1*,(5 Ta b l e 1 . &RQFUHWHPL[FRPSRVLWLRQUHTXLUHPHQWVDFFRUGLQJWR31(1 +D]DUGW\SH ([SRVXUHFODVV $JJUHVVLRQFDXVHGE\ freezing and thawing ;) ;) ;) ;) 0LQLPDOTXDQWLW\RI cement [kg/m3] Maximal W/C ratio Minimal strength class of concrete & & & & Ta b l e 2 . 5HTXLUHGFRQWHQWRIDLULQWKHFRQFUHWHPL[DFFRUGLQJWR>@ &RQWHQWRIDLULQWKHFRQFUHWHPL[>@ Without a plasticizing admixture With a plasticizing admixture $YHUDJH Minimal $YHUDJH Minimal Maximal diameter of aggregate grains [mm] Up to 8 8SWR 8SWR Fig. 1. 7KHGLVWULEXWLRQRIDLUEXEEOHVLQFRQFUHWH±FDSLOODULHV ±PLFURSRUHV $GGLQJDLUHQWUDLQLQJDGPL[WXUHVWRWKHFRQFUHWHPL[ can also have unwanted effects. It leads to higher porosity RIFRQFUHWHDQGORZHUVWUHQJWK>@ -DPURĪ\>@FODLPVWKDWWKHFRPSUHVVLRQVWUHQJWKRI concrete can be raised after air-entraining if the cement FRQWHQWLVEHORZNJP3. If the [cement content is over NJP3, FRQFUHWHVWUHQJWKLVORZHUHGE\DERXWIRU HYHU\DGGLWLRQDORIDLU$FFRUGLQJWR5XVLQ>@IRU FRQFUHWHVZLWKWKH:&UDWLRRI·WKHDYHUDJHGURS RIVWUHQJWKFDQEHHYHQIRURIDGGLWLRQDODLULQWKH mix after air-entraining. $LUHQWUDLQLQJWKHFRQFUHWHPL[GRHVQRWJXDUDQWHHIXOO frost-thaw resistance of the concrete. What is important in air-entraining the concrete mix is the distribution of air pores LQKDUGHQHGFRQFUHWHDQGWKHGLVWDQFHEHWZHHQWKHP$ODUJH distance between the spots where ice is formed and the nearest void leads to higher hydraulic pressure. Small distances between pores are the effect of excessive air-entraining of the concrete mix, which leads to a large drop of compression strength. What determines the proper air-entraining of the concrete mix is the spacing factor L of pores in concrete. The factor determines the average largest distance from a UDQGRPVSRWLQWKHFHPHQWVOXUU\LQWKHFRQFUHWHWRWKH nearest air pore. 7KHQRUPV31(1DQG31(1GRQRW determine the porosity structure of hardened concrete. It is universally assumed that in order to obtain frost resistant FRQFUHWHWKHSURSHUVSDFLQJIDFWRUVKRXOGEH/PP and the content of micropores with the diameter smaller WKDQPFODVV$!&RQFUHWHVZLWK/ PPDQG$!DUHFRQVLGHUHGWRJXDUDQWHHDYHU\KLJK OHYHORIIURVWUHVLVWDQFH+RZHYHUVRPHDXWKRUVFODLPWKDW WKHHYDOXDWLRQRIIURVWUHVLVWDQFHRIÀ\DVKFRQFUHWHVEDVHG RQWKHYDOXHV/DQG$ are of little use because of air pores LQWKHJUDLQVRIDVK>@ Concrete durability is also determined by proper moulding, maintenance and processing of the concrete composite [7, 9]. 7+(5(6($5&+21&21&5(7(6 The research program aimed at determining the inÀXHQFHRIÀ\DVKHVDQGDQDLUHQWUDLQLQJDGPL[WXUHRQ WKHTXDQWLW\DQGTXDOLW\SDUDPHWHUVRIFRQFUHWHDQGWKH characteristics of the concrete mix. The base concrete PDUNHGDV³´ZDVPDGHIURPQDWXUDODJJUHJDWHZLWK JUDLQVL]HXSWRPPDQGWKHVDQGSRLQW±FHPHQW &(0,5DQGSODVWLFL]LQJDGPL[WXUHEDVHGRQSROLcarboxylates. Ta b l e 3 . Composition of the tested series of concretes Ingredient [kg/m3] Cement Water $JJUHJDWH Plasticizer Fly ash $LUHQWUDLQLQJ admixture 0-0 - 0-2 - - - 0.772 Series of tested concretes 0-8 - 0.772 5(6($5&+217+()52675(6,67$1&(2)&21&5(7(602',),(':,7+)/<$6+ 7KHPRGL¿FDWLRQVRIWKHEDVHYHUVLRQFRQVLVWHGLQDGGLQJDQDLUHQWUDLQLQJDGPL[WXUHLQWKHDPRXQWRI VHULHVVHULHVDQGVHULHVLQUHODWLRQ to the mass of cement. 1H[WWKHEDVHVHULHVZDVPRGL¿HGE\DGGLQJKDOIWKH PD[LPXPSHUPLVVLEOHTXDQWLW\RIÀ\DVKVHULHV7KHQ DQDLUHQWUDLQLQJDGPL[WXUHZDVDGGHGWRÀ\DVKFRQFUHWHLQ the amounts corresponding to the control series. 7KLVUHVXOWHGLQFRQFUHWHVHULHVPDUNHGDV 7DEOHSUHVHQWVWKHFRPSRVLWLRQRIDOOWHVWHGVHULHVRI concrete mixes and concretes. $OOFRQFUHWHVZHUHWHVWHGIRUDLUFRQWHQWLQWKHFRQFUHWH mix, consistency by the concrete slump method, compressive strength after 28 days of curing, saturation, depth of ZDWHUSHQHWUDWLRQDQGUHVLVWDQFHWRIUHH]HWKDZF\FOHV The porosity structure of selected concrete series was tested by determining: the total amount of air in hardened concrete $WKHVSDFLQJIDFWRU)WKHPLFURSRUHVFRQWHQW$, and the distribution of air pores. The tests were done with cubical VDPSOHVZLWKDQHGJHRIPPWKDWZHUHGHPRXOGHG hours after they had been made, and then they were kept for GD\VLQZDWHUDWWKHWHPSHUDWXUHRI& 7+(5(68/762)7(676)25&216,67(1&< $1'$,5&217(17 The tested concrete mixes were mixed in a paddle concrete mixer for 70 seconds and then the following was determined: consistency by the concrete slump method in DFFRUGDQFHZLWK31(1DQGDLUFRQWHQWE\WKH SUHVVXUHPHWKRGDFFRUGLQJWR31(1 7KHUHVXOWVDUHSUHVHQWHGLQ7DEOH The result of the slump test for the control series conFUHWHPL[ZDVPP6FRQVLVWHQF\FODVVDQGDLU FRQWHQWWHVWVKRZHGWKHDPRXQWRI$VWKHDPRXQW RIWKHDLUHQWUDLQLQJDGPL[WXUHZDVUDLVHGWKHOLTXLGLW\RI concrete mixes also grew together the air content. Concrete PL[HVZLWKRXWÀ\DVKDQGZLWKPD[LPDOTXDQWLW\RIWKH DLUHQWUDLQLQJDGPL[WXUHRIWKHFHPHQWPDVVKDG WKHDLUFRQWHQWRI$WWKHVDPHWLPHWKLVFRQFUHWHPL[ KDVWKHKLJKHVWOHYHORIOLTXLGLW\DQGLWVFRQVLVWHQF\FODVV ZDVPDUNHGDV6 7KHSUHVHQFHRIÀ\DVKVHULHVLQÀXHQFHGFRQVLVWHQF\ WKHOLTXLGLW\ZDVFRQVLGHUDEO\KLJKHU7KHPHDVXUHGDPRXQW RIDLULQÀ\DVKPL[HVZDVDOVRKLJKHUZLWKWKHVDPHDPRXQW of the air-entraining admixture. $GGLQJÀ\DVKWRFRQFUHWHLQVWHDGRIFHPHQWUDLVHGWKH DLUFRQWHQWE\:LWKWKHDGGLWLRQRIWKHDLUHQWUDLQLQJ DGPL[WXUHLQWKHDPRXQWRIDQGWKHREVHUYHGLQFUHDVHRIWKHWHVWHGFKDUDFWHULVWLFVZDVE\DERXWLQÀ\ ash mixes. The greatest difference in air content was noticed IRUWKHDLUHQWUDLQLQJDGPL[WXUHLQWKHDPRXQWRI7KH DLUFRQWHQWLQWKHÀ\DVKPL[ZDVKLJKHUE\ 7+(5(68/762)7(676)25&2035(66,9( 675(1*7+$1'7+(3(1(75$7,21'(37+ 2)35(6685,=(':$7(5 The compressive strength test was done after 28 days of curing the samples in laboratory conditions. The saturation WHVWZDVGRQHRQWKHEDVLVRIWKH31%QRUP7KH UHVXOWVDUHSUHVHQWHGLQ7DEOH The series 0-0 control concrete had the average compressive strength fcm 03D7KHWHVWUHVXOWVFODVVL¿HG WKHFRQWUROVHULHVWRWKH&VWUHQJWKFODVV8VLQJÀ\DVK as a cement substitute resulted in the drop of compressive VWUHQJWKE\7KLVFKDQJHGWKHFRQFUHWHVWUHQJWKFODVV WR& 7KH PRGL¿FDWLRQ RI WKH WHVWHG FRQFUHWHV E\ XVLQJ DQ air-entraining admixture lowered the average values of compressive strength. The greatest drop was noted in the series ZKHUHWKHDPRXQWRIDGGHGDLUHQWUDLQLQJDGPL[WXUHZDV RIWKHFHPHQWPDVVDQGVHULHV7KLVUHVXOWHGLQFODVVLI\LQJERWKWKHVHULHVWRDVWLOOORZHUVWUHQJWKFODVV& Figure 2 presents the comparison of average compresVLYHVWUHQJWKRIFRQFUHWHVZLWKDQGZLWKRXWÀ\DVK The average compressive strength of the concrete conWDLQLQJKDOIWKHPD[LPDOSHUPLVVLEOHDPRXQWRIÀ\DVKZDV lower in every tested sample. The largest strength drop FDXVHGE\WKHXVHRIÀ\DVKZDVQRWLFHGLQWKHVHULHVZLWKRXWDQDLUHQWUDLQLQJDGPL[WXUHDQGZLWKWKHODUJHVW DPRXQWRIWKHDLUHQWUDLQLQJDGPL[WXUH )LJXUHSUHVHQWVFRPSUHVVLYHVWUHQJWKGURSWRJHWKHU with the increasing amount of the air-entraining admixture. Ta b l e 4 . Concrete mix test results Characteristics of concrete mixes Slump test [mm] Consistency class $LUFRQWHQW 0-0 S2 0-2 80 S2 2.8 0-5 90 S2 Series of tested concretes 0-8 1-0 6 6 1-2 6 1-5 6 1-8 200 6 Ta b l e 5 . $YHUDJHYDOXHVRIFRPSUHVVLYHVWUHQJWKDQGWKHSHQHWUDWLRQGHSWKRISUHVVXUL]HGZDWHURIFRQFUHWHGPRGL¿HGZLWK À\DVKDQGDLUHQWUDLQLQJDGPL[WXUH Characteristics of concretes Compressive strength fcm [MPa] Strength class Depth of water penetration [mm] 0-0 & 0-2 & 0-5 & 70 82 Series of tested concretes 0-8 1-0 1-2 & & & 98 90 90 1-5 & 1-8 & 80 VWUHQJWKFODVVWR& ZDVRIWKHFHPHQWPDVV DQG VHULHV WKHVHULHVWRDVWLOOORZHUVWUHQJWKFODVV& -$&(.+$/%,1,$.%2*'$1/$1*,(5 Average compressive strength fcm [MPa] 56 54 52 50 concretes without fly ash 48 46 44 42 fly shs concretes 7KHXVHRIÀ\DVKDVDFHPHQWVXEVWLWXWHFDXVHGDQLQcrease in the depth of water penetration in concretes both with and without the air-entraining admixture. Similarly, the amount of the air-entraining admixture increased together with the depth of water penetration. 7+(5(68/762)7+()52675(6,67$1&(7(67 &<&/(6 7KHQRUP31(1GRHVQRWPHQWLRQDQ\PHWKod for determining the frost-thaw resistance of concretes. 0 0,2 0,5 0,8 Amount of air entraining admixture [%] +RZHYHUWKHFRQFUHWHVWKDWEHORQJWRWKH;)DQG;) Fig. 2. 7KHLQÀXHQFHRIDQDLUHQWUDLQLQJDGPL[WXUHRQFRP- exposure classes must contain an air-entraining admixture. pressive strength $WSUHVHQWDOOFRQFUHWHVH[SRVHGWRIURVWWKDZF\FOHVDUH tested for frost resistance according to the 100 31%QRUP Air entraining DQGZLWK The tested series of concrete underwent 95 admixture content IUHH]HWKDZF\FOHV7KHUHVXOWVDUHSUH0% )LJXUHSUHVHQWV FRPSUHVVLYHVWUHQJWK GURSWRJHWKHUZLWK WKHLQFUHDVLQJDPRXQWRI 90 VHQWHGLQ7DEOH 0,20% 85 None of the tested series had any 0,50% PDVVORVVDIWHUF\FOHV7KHFRPSUHV80 0,80% sive strength drop for the control concrete 75 ZDV $FFRUGLQJ WR WKH 31 concretes without fly ash fly ash concretes %QRUPPD[LPDOVWUHQJWKGURS Fig. 3. 7KHLQÀXHQFHRIWKHDPRXQWRIWKHDLUHQWUDLQLQJDGPL[- FDQQRWH[FHHG7KHFRQFUHWHVHULHVZLWKRXWÀ\DVK )LJ7KHLQIOXHQFHRIWKH ture on the compressive strength percentage of concretes with the control one 0-0 and the one with minimal amount of the DQGZLWKRXWÀ\DVK air-entraining admixture 0-2 didn’t have frost resistance after $GGLQJ IUHH]HWKDZF\FOHV)O\DVKFRQFUHWHVDQGWKHRQHV HTXDOWRRIWKHFHPHQWPDVVUHVXOWHGLQORZHULQJ ZLWKPLQLPDODPRXQWRIWKHDLUHQWUDLQLQJDGPL[WXUH $GGLQJDQDLUHQWUDLQLQJDGPL[WXUHUHVXOWHGLQORZWKHDYHUDJHFRPSUHVVLYHVWUHQJWKWR03D7DEOH7KHLQFUHDVHLQWKHDPRXQWRI er strength of the tested concretes. The amount of the GLGQ¶WKDYHIURVWUHVLVWDQFHDIWHUIUHH]HWKDZF\FOHVHLWKHU FDXVHV ORZHULQJWKHFRPSUHVVLYHVWUHQJWK ZKLFKGURSSHGWR ZLWK DLUHQWUDLQLQJDGPL[WXUHHTXDOWRRIWKHFHPHQWPDVV The remaining series of tested concretes with the amount RIWKHDGPL[WXUH$VLPLODUUHVXOWZDVREVHUYHGLQIO\DVKFRQFUHWH7KH FRPSUHVVLYHVWUHQJWKGURSSHGIURP03DLQWKHVHULHVZLWKRXWWKHDGPL[WXUHWR03D resulted in lowering the average compressive strength RIWKHDLUHQWUDLQLQJDGPL[WXUHRIDQGKDGWKH WR03D7DEOH7KHLQFUHDVHLQWKHDPRXQWRIWKH IURVWUHVLVWDQFH) )LJ7KHLQIOXHQFHRIWKH (1 air-entraining admixture causes lowering the compressive DUHSUHVHQWHGLQILJXUH VWUHQJWKZKLFKGURSSHGWRZLWKWKHPD[LPDODPRXQW 7+(5(68/762)7(676&21&(51,1* $GGLQJ RIWKHDGPL[WXUH$VLPLODUUHVXOWZDVREVHUYHGLQÀ\ 7+(&+$5$&7(5,67,&62)$,5325(6 HTXDOWRRIWKHFHPHQWPDVVUHVXOWHGLQORZHULQJ ash concrete. The compressive strength dropped from ,1+$5'(1('&21&5(7( WKHDYHUDJHFRPSUHVVLYHVWUHQJWKWR03D7DEOH7KHLQFUHDVHLQWKHDPRXQWRI 03DLQWKHVHULHVZLWKRXWWKHDGPL[WXUHWR03D FDXVHV ORZHULQJWKHFRPSUHVVLYHVWUHQJWK ZKLFKGURSSHGWR ZLWK in the series with the maximal amount of the air-entraining The air pores characteristics tests were done in acRIWKHDGPL[WXUH$VLPLODUUHVXOWZDVREVHUYHGLQIO\DVKFRQFUHWH7KH admixture. cordance with the research procedure described in the FRPSUHVVLYHVWUHQJWKGURSSHGIURP03DLQWKHVHULHVZLWKRXWWKHDGPL[WXUHWR03D The water penetration test was done in accordance with 31(1QRUP7KHWHVWZDVGRQHZLWKWKHXVHRIDQ WKH31(1QRUP7KHUHVXOWVDUHSUHVHQWHGLQ¿Jautomatic system for analysing the image of air pores in (1 XUH FRQFUHWH)LJDQGWKHFRPSXWHUSURJUDP/XFLD&RQFUHWH DUHSUHVHQWHGLQILJXUH For all tested concrete series, the following parameters deter100 mining concrete structure were obtained: the total amount of 90 DLULQFRQFUHWH$WKHVSDFLQJIDFWRU)WKHPLFURSRUHFRQWHQW 80 $FODVVWKHGLVWULEXWLRQRIFKRUGVLQSDUWLFXODUVL]H concretes 70 )LJ7KHLQIOXHQFHRIWKHDPRXQWRI without fly classes of pores. 60 ash The obtained results are presented in Table 7. 50 fly ash $OOWKHVHULHVKDGWKHVSDFLQJIDFWRU/PPZKLFK 40 concretes is recommended to obtain frost resistance of concrete. 30 )LJXUHSUHVHQWVWKHFXPXODWHGDLUFRQWHQWLQSDUWLFXODU 20 SRUHFODVVHVIRUFRQFUHWHVZLWKRXWÀ\DVKGHSHQGHQWRQWKH 10 0 amount of the air-entraining admixture. (1 GRHVQRWPHQWLRQDQ\PHWKRGIRUGHWHUPLQLQJWKHIURVW 00,2 0,5 0,8 WKDW EHORQJ WR WKH ;) DQG Figure UHVLVWDQFH RI FRQFUHWHV +RZHYHU WKH FRQFUHWHV ;) H[SRVXUH 7 presents cumulated air content in particular pore Amount of air entraining admixture [%] FODVVHGIRUÀ\DVKFRQFUHWHVGHSHQGHQWRQWKHDPRXQWRI Fig. 4. 7KHLQÀXHQFHRIWKHDPRXQWRIWKHDLUHQWUDLQLQJDGPL[- the air-entraining admixture. ture on the penetration depth by pressurized water in concretes Fly ash concretes had considerably higher cumulated )LJ7KHLQIOXHQFHRIWKHDPRXQWRI ZLWKDQGZLWKRXWÀ\DVK DLUFRQWHQWWKDQFRQFUHWHVZLWKRXWÀ\DVK7KHREWDLQHG Depth of water penetration [mm] Percent of compressive strength in relation to control concretes [%] 40 5(6($5&+217+()52675(6,67$1&(2)&21&5(7(602',),(':,7+)/<$6+ 27 Ta b l e 6 . &RPSUHVVLYHVWUHQJWKGURSDQGPDVVORVVDIWHUIUHH]HWKDZF\FOHV Characteristics of concretes Compressive strength drop afWHUIUHH]HWKDZF\FOHV>@ 0DVVORVV>@ )URVWUHVLVWDQFH) Series of tested concretes 0-8 1-0 0-0 0-2 0-5 0 NO 0 NO 0 <(6 0 <(6 1-2 1-5 1-8 8.0 0 NO 0 NO 0 <(6 0 <(6 1-5 1-8 20.8 Ta b l e 7 . The results of tests concerning the characteristics of air pores Characteristics of air pores 7RWDODLUFRQWHQWLQFRQFUHWH$>@ Spacing factor L [mm] 0LFURSRUHFRQWHQW$>@ 0-0 0-2 Series of tested concretes 0-8 1-0 1-2 7.9 0-5 8.9 )LJ$ZRUNVWDWLRQIRUWHVWLQJWKHSRUHVWUXFWXUHLQKDUGHQHGFRQFUHWH $>@ $ >@ 7KH REWDLQHG YDOXHV RI WKH WRWDO SRUH FRQWHQW LQ KDUGHQHG FRQFUHWH $ DUH TXLWH FOHDUO\ KLJKHU WKDQ WKH DLU FRQWHQW REWDLQHG LQ WKH SUHVVXUH PHWKRG WHVWV RI FRQFUHWH $OO WKH VHULHV KDG WKH VSDFLQJ IDFWRU / PP ZKLFK LV UHFRPPHQGHG WR REWDLQ IURVW RSLQLRQVH[SUHVVHGLQ>@WKDWIO\DVKFDQLQFUHDVHWKH$S )LJXUHSUHVHQWVWKHFXPXODWHG Cumulated air content [%] 10 8 Tested series 6 0-0 0-2 4 0-5 2 0-8 0 1 2 3 4 5 6 7 8 9 10111213141516171819202122232425262728 Percentage amount of chords in a class [%] Fig. 5. $ZRUNVWDWLRQIRUWHVWLQJWKHSRUHVWUXFWXUHLQKDUGHQHGFRQFUHWH 25 20 Tested series 15 0-0 10 0-2 0-5 5 0-8 0 1 2 3 4 5 6 7 8 9 10111213141516171819202122232425262728 Pore classes Pore classes Cumulated air content [%] 21 18 Tested series 15 12 1-0 9 1-2 6 1-5 1-8 3 0 1 2 3 4 5 6 7 8 9 10111213141516171819202122232425262728 Pore classes Percentage amount of chords in a class [%] Fig. 6. 7KHLQÀXHQFHRIDQDLUHQWUDLQLQJDGPL[WXUHRQFXPX- Fig. 8. $KLVWRJUDPRIDLUSRUHVGLVWULEXWLRQLQFRQFUHWHVZLWKRXW )LJ7KHLQIOXHQFHRI )LJ$KLVWRJUDPRIDLUSRUHVGLVWULEXWLRQLQFRQFUHWHVZLWKRXWIO\DVK À\DVK ODWHGDLUFRQWHQWLQFRQFUHWHVZLWKRXWÀ\DVKGHSHQGHQWRQWKH pore class 25 20 Tested series 15 1-0 1-2 10 1-5 5 1-8 0 1 2 3 4 5 6 7 8 9 10111213141516171819202122232425262728 Pore classes Fig. 7. 7KHLQÀXHQFHRIDQDLUHQWUDLQLQJDGPL[WXUHRQFXPXODW- Fig. 9. $KLVWRJUDPRIDLUSRUHVGLVWULEXWLRQLQÀ\DVKFRQFUHWHV HGDLUFRQWHQWLQÀ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pressure method tests of concrete mixes. Particularly large GLIIHUHQFHVZHUHQRWLFHGLQÀ\DVKFRQFUHWHV7KLVFRQ¿UPV WKHRSLQLRQVH[SUHVVHGLQ>@WKDWÀ\DVKFDQ LQFUHDVHWKH$SDUDPHWHU Figures 8 and 9 present histograms of the percentage distribution of air pores in all size classes. 7KHFRQWHQWRIPLFURSRUHV$ obtained in the test UDQJHGIURPLQWKHVHULHVDQGWRLQWKH VHULHV7DEOH$OOWKHWHVWHGVHULHVKDGWKHIDFWRU$, UHTXLUHGIRUFRQFUHWHIURVWUHVLVWDQFHZLWKWKHYDOXHDERYH WKHPLQLPDO It is commonly assumed that in order to obtain frost UHVLVWDQWFRQFUHWHWKHSURSHUVSDFLQJIDFWRUVKRXOGEH/ 0.20mm and the content of micro-pores with the diameter VPDOOHUWKDQPFODVV$!&RQFUHWHVZLWK /PPDQG$!DUHFRQVLGHUHGWRJXDUDQWHHD very high level of frost resistance. In a direct frost resistance test, despite having obtained proper parameters in the porosity structure test, in the series WKHUHZHUHQRFRQFUHWHVWKDWFRXOGEH LQFOXGHGLQWKH)IURVWUHVLVWDQFHFODVV CONCLUSIONS The paper presents the results of research on the characteristics of air pores, compressive strength, the depth of penetration by pressurized water, and frost resistance after F\FOHVLQFRQFUHWHVPRGL¿HGE\À\DVKDQGDQDLUHQtraining admixture. The research that was carried out has led to the following conclusions: ± À\DVKUDLVHVWKHHIIHFWLYHQHVVRIDLUHQWUDLQLQJWKHFRQcrete mix and it helps to increase air content, ± DQDLUHQWUDLQLQJDGPL[WXUHLPSURYHVIURVWUHVLVWDQFHRI FRQFUHWHLQFUHDVHVWKHOLTXLGLW\RIWKHFRQFUHWHPL[DQG improves its workability, ± DLUHQWUDLQLQJDGPL[WXUHVUHVXOWLQDFRQVLGHUDEOHGURS RIFRPSUHVVLYHVWUHQJWKXSWRLQFRPSDULVRQZLWK concrete without the admixture. It can lead to lowering the strength class of concrete by even 2 degrees, ± DGGLWLRQDODLULQWKHFRQFUHWHPL[FDQDOVROHDGWRLQcreasing the depth of water penetration, which is rarely mentioned by the admixture manufacturers. Therefore, the composition of concrete must be corrected at the designing stage, ± WKHFKDUDFWHULVWLFVRIDLUSRUHVGLVWULEXWLRQLVDQHIIHFWLYH tool to estimate the frost resistance of concrete composites. 5()(5(1&(6 Chaussées en béton, 2000:*XLGHWHFKQLTXH/&3& 6(75$ 2. Czarnecki L., 2003:'RPLHV]NLGREHWRQX±PRĪOLZRĞFL LRJUDQLF]HQLD3ROVNL&HPHQW±%XGRZQLFWZR7HFKQRORJLH$UFKLWHNWXUDQXPHUVSHFMDOQ\ Halbiniak J., 2010: Optymalizacja stosunku cementowo-wodnego w napowietrzanych mieszankach beWRQRZ\FK:=ZLĊNV]HQLHHIHNW\ZQRĞFLSURFHVyZ EXGRZODQ\FKLSU]HP\VáRZ\FK3RGUHG0DUOHQ\5DMF]\N5R]G]LDáZPRQRJUD¿L:\G3RO&]ĊVWRFKRZskiej. Halbiniak J., Pietrzak A., 2007:%HWRQQDSRZLHWU]DQ\ 'URJRZQLFWZR0LHVLĊF]QLN1DXNRZR±7HFKQLF]Q\ 6WRZDU]\V]HQLD,QĪ\QLHUyZLWHFKQLNyZ.RPXQLNDFML Halbiniak J., 2004::DUVWZDSU]HMĞFLRZDNUXV]\ZR ± ]DF]\Q FHPHQWRZ\ Z NRPSR]\WDFK EHWRQRZ\FK =ZLĊNV]HQLHHIHNW\ZQRĞFLSURFHVyZSU]HP\VáRZ\FK LEXGRZODQ\FK:\G3RO&]ĊVWRFKRZVNLHM&]ĊVWRchowa. -DPURĪ\=%HWRQLMHJRWHFKQRORJLH:\GDZnictwo Naukowe PWN, Warszawa. 7. .DOLVW\00DáDV]NLHZLF]'Metody badania PUR]RRGSRUQRĞFLEHWRQyZ2FHQDPUR]RRGSRUQRĞFLEHWRQX]FHPHQWHPKXWQLF]\P%XGRZQLFWZRL,QĪ\QLHULD ĝURGRZLVND 8. Katalog typowych konstrukcji nawierzchni sztywnych, :*''3:DUV]DZD 9. .XUGRZVNL:6]HOąJ+%RFKHQHN$ CzynQLNLZSá\ZDMąFHQDRGSRUQRĞüEHWRQXQDG]LDáDQLHPUR]X;;9,.RQIHUHQFMD1DXNRZR7HFKQLF]QD$ZDULH EXGRZODQH àDĨQLHZVND3LHNDUF]\N%7KHLQÀXHQFHRI selected new generation admixtures on the workability, air-voids parameters and Frost-resistance of self-comSDFWLQJFRQFUHWH&RQVWUXFWLRQDQG%XLOGLQJ0DWHULDOV 0DáROHSV]\-., 2000::\EUDQH]DJDGQLHQLD]WUZDáRĞFL EHWRQyZ%HWRQQDSURJXQRZHJRPLOHQLXP.UDNyZ Neville A.M., :áDĞFLZRĞFLEHWRQX3ROVNL&Hment, Kraków. Nowak – Michta A., 2008:,GHQW\¿NDFMDSRURZDWRĞFL QDSRZLHWU]RQ\FKEHWRQyZ]GRGDWNLHPSRSLRáXORWQHJR Dni betonu. Powers T.C., 1945:$ZRUNLQJK\SRWKHVLVIRUIXUWKHU VWXGLHVRIIURVWUHVLVWDQFH-RXUQDORIWKH$PHULFDQ&RQFUHWH,QVWLWXWH Rajczyk J., Halbiniak J., 2012:,QÀXHQFHRI0LFURVLOLFVVDQG$LU(QWUDLQLQJ$GGLWLYHVRQ3DUWLFXODU)HDWXUHVRI&RQFUHWH&RPSRVLWH:3URFHHGLQJVRIWK International Conference on Contemporary Problems LQ$UFKLWHFWXUHDQG&RQVWUXFWLRQ6XVWDLQDEOH%XLOGLQJ ,QGXVWU\RIWKH)XWXUH6HSWHPEHU:\G 3RO&]ĊVWRFKRZVNLHM Rajczyk J., Halbiniak J., Langier B., 2012: Technologia kompozytów betonowych w laboratorium i w prakW\FH:\G3RO&]ĊVWRFKRZVNLHM&]ĊVWRFKRZD 5XVLQ=., 2002: Technologia betonów mrozoodpornych, Polski Cement, Kraków. :DZU]HĔF]\N-0ROHQGRZVND$., 2011: Struktura SRUyZDPUR]RRGSRUQRĞüEHWRQyZQDSRZLHWU]RQ\FK ]DSRPRFąPLNURVIHU&HPHQW:DSQR%HWRQQU :DZU]HĔF]\N-0ROHQGRZVND$, 2014: MrozoodSRUQRĞüEHWRQyZQDSRZLHWU]RQ\FK]DSRPRFąPLNURVIHU SROLPHURZ\FK'QL%HWRQX 5(6($5&+217+()52675(6,67$1&(2)&21&5(7(602',),(':,7+)/<$6+ 29 UyZSRZLHWU]Q\FK%DGDQLHPUR]RRGSRUQRĞFLSU]HSURZDG]RQR 20. =79%HWRQ±6W%=XVlW]OLFKH7HFKQLVFKH GODF\NOL]DPURĪHĔLUR]PURĪHĔ'ODEHWRQyZZ\NRQDQR 9HUWDJVEHGLQJXQJHQXQG5LFKWOLQLHQIĦUGHQ%DXYRQ EDGDQLHVWUXNWXU\SRURZDWRĞFLNRPSR]\WyZEHWRQRZ\FKNWy)DKUEDKQGHFNHQDXG%HWRQ UHSU]HSURZDG]RQRSU]\XĪ\FLXXU]ąG]HQLDGRDXWRPDW\F]QHM %$'$1,$75:$à2ĝ&,052=2:(-%(721Ï: 02'<),.2:$1<&+'2'$7.,(0323,2à8 /271(*2 Streszczenie. :SUDF\SU]HGVWDZLRQRZSá\ZGRGDWNXSRSLRáyZORWQ\FKLGRPLHV]NLQDSRZLHWU]DMąFHMQDPUR]RRGSRUQRĞü EHWRQXEDGDQąPHWRGąEH]SRĞUHGQLąRUD]FKDUDNWHU\VW\NĊSR- analizy obrazu z wykorzystaniem programu komputerowego /XFLD&RQFUHWH$QDOL]LHSRGGDQREHWRQNRQWUROQ\RUD]EHWRQ ]GRGDWNLHPSRSLRáXORWQHJRZLORĞFLSRáRZ\PDNV\PDOQHMGRSXV]F]DOQHMQRUPRZRLORĞFLQDSRZLHWU]DQHUyĪQ\PLGDZNDPL GRPLHV]NLQDSRZLHWU]DMąFHM 6áRZDNOXF]RZHEHWRQSRSLRá\ORWQHFKDUDNWHU\VW\NDSRUyZ SRZLHWU]Q\FKPUR]RRGSRUQRĞü TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 31–36 Assessment of Monthly Mean Total Ozone Distribution Changes With Regard to Atlantic Ocean Surface Temperatures Variations Alexander Holoptsev1, Alexander Bolshikh1, Valeriya Bekirova2, Mariya Nikiforova2 Sevastopol Maritime Academy Rybakov Str., 5A, Sevastopol, Crimea, 299014; e-mail: [email protected] 2 Sevastopol National Technical University Universitetskaya Str., 33, Sevastopol, Crimea, 299053; e-mail: [email protected] 1 Received December 03.2014; accepted December 17.2014 Summary: Taking into account monthly average surface temSHUDWXUHVFKDQJHVRI$WODQWLFZDWHUDUHDVZKLFKKDYHDVWURQJ LQÀXHQFHRQPRQWKO\PHDQWRWDOR]RQHGLVWULEXWLRQDERYH3RODQG allows to imply their effective modeling and forecasting for several years. Prediction errors are at the maximum in June and rise as the forecast period increases. Nevertheless, when forecast is PDGHIRU±\HDUVWKHLUOHYHOVPRGXORGRQRWH[FHHGDEVRlute error of total ozone measurements instrumentally based on WKHPRVWH[DFWRIH[LVWLQJGHYLFHV±'REVRQVSHFWURSKRWRPHWHU Key words: variability of total ozone distribution over Poland, VXUIDFHWHPSHUDWXUHVVLJQL¿FDQWRFHDQDUHDVPRGHOLQJIRUHcasting, statistical relationship, interaction of the troposphere and stratosphere. INTRODUCTION 9DULDELOLW\RIWRWDOR]RQHFRQWHQW72&GLVWULEXWLRQLQ WKHDWPRVSKHUHLQÀXHQFHVFKDQJHVRI89VRODUUDGLDWLRQ ÀX[HVZKLFKWDNHSDUWLQFUHDWLQJWURSRVSKHULFDQGVXUIDFH ozone, growth of all land plants, animals and microorganisms, and affect human health as well. Therefore, improvePHQWRIWKHWHFKQLTXHVRILWVPRQLWRULQJLVDWRSLFDOSUREOHP of physical geography, meteorology and ecology. 1RZDGD\VVLQFH-DQXDU\YDULDELOLW\DQGGLVWULbution of daily mean and monthly mean TOC have been researched by the means of global monitoring system. TOC values for different regions of the Planet which are not in the area of a pole night are measured by spectrophotometers 7206WLOODQG20,±SUHVHQWGD\6XFKGDWD JRWRWKH:RUOGR]RQHDQGXOWUDYLROHWGDWDFHQWUH7RURQWR and are presented in the Internet for free access. Possibilities of these tools and data processing procedures provide resoluWLRQRI'REVRQXQLWV'8ZLWKVSDWLDOJULGɯ>@ *URXQGEDVHG72&PHDVXULQJVWDWLRQVDUHORFDWHGLQGLIferent cities; the most accurate device in use here is Dobson VSHFWURSKRWRPHWHUZLWKPHDVXUHPHQWHUURUDURXQG'8 This allows to study the process peculiarities in more detail. 1HYHUWKHOHVVGHYHORSLQJDOWHUQDWLYHPRQLWRULQJWHFKQLTXHV of TOC variability is of a great interest. It has been established that changes of ozone depleting VXEVWDQFHVÀX[HVHQWHULQJGLIIHUHQWDWPRVSKHUHVHJPHQWV is one of the essential factors, causing TOC distribution changes in terrestrial atmosphere [2]. Such species of technogenic and natural origin are formed on ground surface and can be delivered by air streams to stratosphere, where mainly ozone is located. Within troposphere their transport is carried out by streams, which arise at various convectionDODQGV\QRSWLFSURFHVVHV>@7KHPHFKDQLVPVWKDWDOORZ such substances to enter stratosphere are not yet known ZLWKDVVXUDQFH$FFRUGLQJWR+33RJRV\DQ>@WKHPDLQ role here is played by advection of tropospheric air through tropopause breakdowns, which are located above subtropical jet streams. Nevertheless, this mechanism does not explain how exactly such substances, which have gotten to the lower VWUDWRVSKHUHDUHGLVWULEXWHGLQVWHDGLO\VWUDWL¿HGXSSHUOD\ers, where ozone destruction occurs. ($=KDGLQ>@VXJJHVWHGWKDWWKHHVVHQWLDOUROHLQWKLV process is carried out by planetary and gravity waves, which arise as a result of various interactions of atmosphere and the (DUWK¶VVXUIDFH7KH\DOVRFDQEHJHQHUDWHGE\PRYHPHQW of cyclones and anticyclones, interaction of jet streams and RURJUDSKLFRUSUHVVXUHLUUHJXODULWLHV>@%HLQJQRQOLQHDU and large-scale, such waves break at some distance from WKHVRXUFHDVWKHLUZDYHSUR¿OHWUDQVIRUPVZKLOHVSUHDGLQJ [8]. This results in turbulent rising air currents, which can transfer air to any heights in stratosphere. $QLPSRUWDQWUROHLQJHQHUDWLQJSUHVVXUHLUUHJXODULWLHVLV played by exposure of the atmosphere to heat and water vaSRUÀX[HVZKLFKDULVHIURPWKH:RUOGRFHDQVXUIDFH+HQFH a relation between surface temperature changes of some water areas and TOC over many world regions can exist. 7KHDGHTXDF\RIVXFKDVVXPSWLRQVKDVEHHQFRQ¿UPHG by many researchers [9]. This suggests a possibility of using $+2/2376(9$%2/6+,.+9%(.,529$01,.,)2529$ surface temperature measurement results of some World ocean areas in the monitoring of TOC variations over the majority of the planet regions. 7KH$WODQWLF2FHDQLVWKHELJJHVWDQGZDUPHVWSDUWRI the world oceans. This suggests a possibility of existence of such regions within it, whose surface temperature changes LQÀXHQFHWKHR]RQRVSKHUHVWDWHRYHU3RODQG 7KHRFFXUUHQFHZDVHVWDEOLVKHGRIVLJQL¿FDQWVWDWLVtic relationships on coinciding time periods between TOC changes in the majority of atmosphere and surface temperDWXUHYDULDWLRQVRIPDQ\$WODQWLFZDWHUDUHDV2QDYHUDJH connections between these processes are weaker when the WHPSRUDU\VKLIWEHWZHHQWKHPJURZV>@ Observations of surface temperature changes for the PDMRULW\RI$WODQWLF2FHDQDUHDVKDYHEHHQPDGHIRURYHU \HDUV7KHLUUHVXOWVLQWLPHVHULHVIRUPDUHSUHVHQWHGLQ the Internet. The data present the values of monthly mean anomalies calculated as an average of a segment, limited by SDUDOOHOVDQGPHULGLDQVGLIIHULQJRQ>@ 7KHGLVSRVLWLRQRIZDWHUDUHDVLQÀXHQFLQJ72&GLVWULbution variations over one or other world region the most, ZKLFK ZH ZLOO IXUWKHU FDOO µVLJQL¿FDQW¶ LV QRW FOHDUO\ understood. It does not allow to use connections between the mentioned processes in modeling and forecasting TOC changes over such regions. On this basis, the object of the research was monthly mean TOC distribution changes over Poland and monthly PHDQVXUIDFHWHPSHUDWXUHVRIYDULRXV$WODQWLF2FHDQDUHDV The subject of the research was elaboration of monthly mean TOC distribution changes monitoring with regard WRVXUIDFHWHPSHUDWXUHVYDULDWLRQVRIWKH$WODQWLF2FHDQ VLJQL¿FDQWDUHDVRQWKHH[DPSOHRI3RODQG 7KHSXUSRVHRIWKHZRUNZDVWRLGHQWLI\WKH$WODQWLF 2FHDQVLJQL¿FDQWDUHDVPRGHOLQJDFFXUDF\DVVHVVPHQWDQG TOC distribution variations forecasting over Poland. To attain these ends the following tasks were solved: ,GHQWL¿FDWLRQRI$WODQWLF2FHDQDUHDVZKRVHPRQWKO\ PHDQVXUIDFHWHPSHUDWXUHLQWHUDQQXDOFKDQJHVVLJQL¿FDQWO\LQÀXHQFHLQFRLQFLGLQJWLPHSHULRGVPRQWKO\PHDQ TOC variations over the majority of Poland’s regions. ,GHQWL¿FDWLRQRILQWHUDQQXDO72&FKDQJHVSUHGLFWLYH models over the Poland’s territory. 'HYHORSLQJ72&GLVWULEXWLRQFKDQJHVIRUHFDVWVRYHUWKH 3RODQG¶VWHUULWRU\DQGWKHLUDGHTXDF\DVVHVVPHQW does not guarantee its practicality in the forecasting tasks. %XWWKHSRVVLELOLW\LVWKHKLJKHUWKHVWURQJHUWKHVWDWLVWLFDO FRQQHFWLRQVFRQVLGHUHGLQPRGHOLQJDUH+HQFHWKHDSSOLFDWLRQRIWKLVPHWKRGLQGHYHORSLQJIRUHFDVWLQJWHFKQLTXHV of studied process was accepted as admissible. 7KHPHQWLRQHGWHFKQLTXHLQFOXGHGWZRVWDJHV $WWKH¿UVWVWDJHWKH¿UVWWDVNZDVVROYHGZLWKWKHXVH RIFRUUHODWLRQDQDO\VLV$PRQJDOOWKH$WODQWLF2FHDQDUHDV [WKHRQHVZHUHLGHQWL¿HGZKRVHVXUIDFHWHPSHUDWXUH LQWHUDQQXDOFKDQJHVZHUHVLJQL¿FDQWO\FRUUHODWHGZLWK72& LQRQHRURWKHUDWPRVSKHUHVHJPHQW[RYHU3RODQG¶V WHUULWRU\$VDTXDQWLW\PHDVXUHRIFRQQHFWLRQEHWZHHQWKH VWXGLHGSURFHVVHVDSDLUFRUUHODWLRQFRHI¿FLHQWZDVXVHG7KH latter, with due regard to freedom degrees of correspondLQJWLPHVHULHVZDVDFFHSWHGVLJQL¿FDQWZKHQH[FHHGLQJ E\6WXGHQW¶VWWHVW)XUWKHUDPRQJVXFKZDWHUDUHDV WKHVLJQL¿FDQWRQHVZHUHHVWDEOLVKHG7KHLUWHPSHUDWXUH FKDQJHVZHUHVLJQL¿FDQWO\FRQQHFWHGZLWK72&YDULDWLRQVDW FRLQFLGLQJWLPHSHULRGVLQQRWOHVVWKDQRIDWPRVSKHUH segments over the studied territory. $WWKHVHFRQGVWDJHWKHPRGHOV¶PRQWKO\PHDQ72& inter-annual changes , corresponding to each atmosphere VHJPHQWRYHU3RODQGZHUHLGHQWL¿HG Linear multiple regression was used as a predictive model: 8 t c0 c x t c 2 x 2 t ... c N x N t here: ci±FRQVWDQWVZKLFKZHUHFKRVHQVRWKDWWKHVXPRI GHYLDWLRQVTXDUHV z t Y t y t for all the time periods t was minimal; y t ±WLPHVHULHVIRUHDFKSUHGLFWDEOHSURFHVVGXULQJWKH ±SHULRG Y t ±LWVPRGHO xi t ±VWDWHLQDWLPHPRPHQW t of some process, which is VLJQL¿FDQWO\VWDWLVWLFDOO\FRQQHFWHGZLWK y t . $VPRGHODUJXPHQWVWKHWLPHVHULHVRIPRQWKO\PHDQ VXUIDFHWHPSHUDWXUHVRIVLJQL¿FDQWZRUOGRFHDQVDUHDVZHUH XVHG7KH\FRUUHVSRQGWRWKH±SHULRGLQVRPH time moments t coinciding with the studied processes. )RUHFDVWLQJZDVPDGHIRUDQGVLQFHWKHUH are results of satellite TOC monitoring for these years over Poland so their comparison can be made. It was suggested that the number of model arguments ZDVHTXDOWRWKHQXPEHURIVLJQL¿FDQWDUHDV± N . Time series for each of them contained M members ( M 2 N 0(7+2'2/2*<$1''$7$ 7KHQPRGHOFRHI¿FLHQWVZHUHFDOFXODWHGDVFRPSRQHQWV of ( N YHFWRU Ñ , which is a solution to vector-matrix One of the most universal mathematical modeling meth- HTXDWLRQ ods of stochastic processes is a multiple regression method B A C >@,WLVDOVRDSSOLHGIRUWKHLUSUHGLFWLRQLIWKHIDFWRUV where: considered as arguments, are connected with the studied Ñ N -vector process. Proving existence of stochastic connections be½ M ° ¦ yi ° tween such natural process as TOC changes over Poland ° ° Mi and other natural processes is really hard, in many cases ° ° ° ¦ y i xi , ° B ®i ±LPSRVVLEOH,WLVPXFKHDVLHUWRHVWDEOLVKDQH[LVWHQFHRI ¾, ° ... ° statistical connection between them. ° °M The application of factors, connected statistically with °¦ y i xi , N ° ° ° ¿ ¯i the studied process, as factors in multiple regression model, $66(660(172)0217+/<0($1727$/2=21(',675,%87,21&+$1*(6 A ±PDWUL[ N u N A ° M °M ° x i , °¦ ° iM ® ° ¦ xi , 2 °i ° M ... ° x i,N °¯¦ i ¦x M ¦x i i , M ¦x i M i ¦x M i ¦x M ¦x i i,2 ... M x i , i , x i , i , 2 ... ¦x i M i ¦x M x i , i , N i i,2 xi , ... i,2 xi , 2 ... ... i,2 ¦x ½ ° i ° M xi , N xi , ° ¦ ° i ° M ¾ x x ¦ i,N i,2 ° i ° ... ° M ° x x ¦ i,N i,N °¿ i M ... xi , N ... i,N Ta b l e 1 . &RRUGLQDWHVRIWKHUHJLRQV¶FHQWHUVRI$WODQWLF2FHDQ ZKLFKZHUHVLJQL¿FDQWLQPRGHOLQJ72&FKDQJHVDERYH3RODQG in June # ʋ 2 latitude 1 1 1 1 1 longitude : : : : : # ʋ 7 8 9 latitude 1 1 1 1 1 longitude : : : : : # ʋ latitude (ɨ 1 1 1 1 1 longitude (ɨ ( : : ( : The mentioned solution would look like: C A B here: A is an inverse matrix to A . Vector C was identified for each considered Poland’s region. The foreFDVWLQJ ZDV PDGH E\ VXEVWLWXWLRQ LQ HTXDWLRQ WLPH VHULHV RI DUJXPHQWV FRUUHVSRQGLQJ WR DQG yy. TOC values were calculated for each month and each Poland’s region. For each of them prediction accuracy was estimated. $VGDWDWLPHVHULHVRIPRQWKO\PHDQVXUIDFHWHPSHUDWXUHVDQRPDOLHVRIDOOWKH$WODQWLF2FHDQDUHDV[ZHUH XVHG7KH\ZHUHREWDLQHGIURP>@,QGRLQJVRRQO\WLPH VHULHVZLWKQRJDSVGXULQJ±ZHUHXVHG$VR]RQH variability data, time series were taken of monthly mean 72&YDOXHVRYHUHDFK(DUWKVXUIDFHVTXDUHɯOLPLWHG E\SDUDOOHOV1DQG1DQGPHULGLDQVȿDQGȿ UHFHLYHGIURP>@6XFKDWPRVSKHUHVHJPHQWFRPSOHWHO\ covers the whole Poland’s territory and some regions of *HUPDQ\8NUDLQHDQG%HODUXV 5(68/76$1'',6&866,21 :LWKWKHXVHRIWKHPHQWLRQHGWHFKQLTXHVLJQL¿FDQW DUHDVRI$WODQWLF2FHDQIRUDOOWKHPRQWKVZHUHLGHQWL¿HG 7KHVPDOOHVWDPRXQWRIVXFKUHJLRQVRFFXUUHGLQ-XQH &RRUGLQDWHVRIWKHHVWDEOLVKHGVLJQL¿FDQWDUHDVRI$WODQWLF 2FHDQDUHWDEXODWHGLQ7DEOH /RFDWLRQVRIVXFKUHJLRQVDUHSUHVHQWHGLQ)LJXUH $VLVVHHQIURP7DEOHDQG)LJXUHWKHPHQWLRQHG regions are located in the area where a strong interaction RI*XOI6WUHDPDQG/DEUDGRU&XUUHQWLVIRXQG6RKHUH the most contrastive pressure gradients are observed. Their interplay with jet streams makes the last ones vertically oscillate. This arises planetary and gravitation waves, tropopause breakdown and allows ozone depleting species enter the stratosphere. When solving the second task for each month, the TOC FKDQJHVPRGHOVZHUHLGHQWL¿HGIRUDOOWKHFRQVLGHUHG atmosphere segments. With the use of these models, TOC values were preGLFWHGIRUYDULRXVSDUWVRI3RODQGLQ-XQHDQG These forecasts, as well as the fact values of TOC over various regions of Poland in June 2009 are tabulated in Table 2. Fig. 1. /RFDWLRQRIWKHUHJLRQV¶FHQWHUVRI$WODQWLF2FHDQZKRVH VXUIDFHWHPSHUDWXUHFKDQJHVZHUHVLJQL¿FDQWLQPRGHOLQJ72& changes above Poland in June Ta b l e 2 . Fact and forecasted TOC values over the Poland regions in June 2009 Fact oN oN oN oN o( oN oN oN oN oN oN oN oN 2.7 o( o( 20 o( Outlook Forecast error 2.9 0.2 -2.0 22 o( o( 8.9 -0.9 -2.0 $+2/2376(9$%2/6+,.+9%(.,529$01,.,)2529$ $VLVVHHQIURP7DEOHWKHPD[LPXPIRUHFDVWHUURUV WHUULWRU\IRUDRQH\HDUIRUHFDVWPHDVXUHV'8ZKLFK '8FRUUHVSRQGWR3RODQGUHJLRQZLWKFHQWHUFRRUGL- is less than TOC measurement error, obtained on Dobson QDWHV1($YHUDJHHUURUYDOXHRYHUWKHZKROH3RODQG spectrophotometer. 5HODWHGFRPSDULVRQVIRUKDYHVKRZQWKDWSUHGLFWLRQPHDQHUURUPDGHIRU\HDUVPHDVXUHV'8,IWKH A) IRUHFDVWIRULVPDGHZLWKWKHXVHRIPRGHOIDFWRU FKDQJHVLQ±SHULRGLHWKHIRUHFDVWIRURQH\HDU PHDQHUURUYDOXHPHDVXUHV'8,QRWKHUPRQWKVWKH DPRXQWRIVLJQL¿FDQW$WODQWLF2FHDQDUHDVLVJUHDWHUDQG the TOC forecasts mistakes over Poland are fewer. CONCLUSIONS B) 7KHUHDUH$WODQWLF2FHDQDUHDVZKRVHVXUIDFHWHPSHUDWXUHLQWHUDQQXDOFKDQJHVVLJQL¿FDQWO\LQÀXHQFHWKH TOC variations over Poland in coinciding time periods. ,WVXSSRUWVWKHDGHTXDF\RIK\SRWKHVLVDERXWZDYHQDture of the distribution mechanism in the stratosphere of ozone depleting substances. 2. Prediction errors of TOC distribution changes over Poland are maximal in June and increase when forecast is made on greater time shifts. Nevertheless, when forecast LVPDGHIRU±\HDUVWKHLUOHYHOVPRGXORGRQRW exceed absolute error of total ozone measurements instrumentally based on the most exact of existing devices ±'REVRQVSHFWURSKRWRPHWHU7KLVUHLQIRUFHVDSSOLFDWLRQ HI¿FLHQF\RISUHGLFWLQJWHFKQLTXHLQWKHVWXGLHGIRUHFDVWing process. 5()(5(1&(6 :RUOGR]RQHDQGXOWUDYLROHWGDWDFHQWHUKWWSZZZ woudc.org 2. $OH[DQGURY(/<$,]UDHO,/.DURO$++UJLDQ 1992.2]RQLFVKLHOGRIWKH(DUWKDQGLWVFKDQJHV63HWHUVEXUJ*LGURPHWHRL]GDW &KNROQ\(3Physics of the atmosphere. Odessa, Poghosyan H. P., 1972.*HQHUDOFLUFXODWLRQRIWKHDWC) mosphere. Leningrad. -DGLQ($,QÀXHQFHRILQWHUDQQXDOWHPSHUDWXUH variations of the surface of the ocean circulation of the atmosphere and the ozone layer. The dissertation for VFLHQWL¿FGHJUHHRIWKHGRFWRURISK\VLFDODQGPDWKematical Sciences. Dolgoprudny, Moscow Institute of SK\VLFV +ROWRQ-53++D\QHVDQG0(0F,QW\UH 6WUDWRVSKHUH WURSRVSKHUH H[FKDQJH 5HY *HRSK\V 7. Salby M.L., 1996. )XQGDPHQWDOVRI$WPRVSKHULF3K\VLFV1HZ<RUN$FDGHPLF3UHVV 8. Lighthill, M.J., 1970. Nonlinear theory of wave propDJDWLRQ0RVFRZ³:RUOG´ 9. Mohanakumar, K., 2011. Interaction of the stratoVSKHUH DQG WURSRVSKHUH 7UDQVODWLRQ IURP (QJOLVK Ɋ8 /XN\DQRYD HGLWHG E\ *9$OH[HHY 0RVFRZ Pic. 2. 'LVWULEXWLRQRYHU3RODQGWHUULWRU\RIIRUHFDVWHG$DQG IDFW%72&YDOXHVLQ-XQHDQGSUHGLFWLRQHUURUV& ),=0$7/,7 $66(660(172)0217+/<0($1727$/2=21(',675,%87,21&+$1*(6 Holoptsev, A.V., 2013. The geographic position of the ZDWHUVRIWKH3DFL¿FRFHDQDVDIDFWRURIVLJQL¿FDQWLQÀXence of changes of surface temperature on the state of the ozone layer. The Karazin Kharkiv national University, “Man and environment. The problem of neo-ecology WUHQG´ʋ 2YHUYLHZRIFXUUHQWRFHDQUHDQDO\VHVUHDQDO\VHVRUJ ocean. Draper, N., H, Smith, 2007. $SSOLHGUHJUHVVLRQDQDO\VLV0XOWLSOHUHJUHVVLRQ0RVFRZ³'LDOHFWLF´ 2&(1$=0,$10,(6,ĉ&=1(-ĝ5('1,(- &$à.2:,7(-'<675<%8&-,2=212:(- :$63(.&,(:$+$ē7(03(5$785<:Ï' 32:,(5=&+1,2:<&+2&($18$7/$17<&.,(*2 Streszczenie: %LRUąFSRGXZDJĊĞUHGQLHPLHVLĊF]QH]PLDQ\ WHPSHUDWXU\SRZLHU]FKQLZZRGDFK$WODQW\NXNWyUHPDMąVLOQ\ ZSá\ZQDPLHVLĊF]QąĞUHGQLąFDáNRZLWHMG\VWU\EXFMLR]RQRZHM QDG3ROVNąPRĪQDVXJHURZDüLFKVNXWHF]QHPRGHORZDQLHLSURJQR]RZDQLHSU]H]NLONDODW%áĊG\SU]HZLG\ZDQLDVąQDMZ\ĪV]H ZF]HUZFXLURVQąZUD]]HZ]URVWHPRNUHVXSURJQR]RZDQLD 1LHPQLHMMHGQDNJG\SURJQR]DMHVWURELRQDQD±ODWDLFKSR]LRPPRGXORQLHSU]HNUDF]DEáĊGXDEVROXWQHJRVXP\SRPLDUyZ R]RQXZRSDUFLXRQDMEDUG]LHMGRNáDGQH]LVWQLHMąF\FKXU]ąG]HĔ ±VSHNWURIRWRPHWU'REVRQD 6áRZDNOXF]RZH]PLHQQRĞüFDáNRZLWHJRUR]NáDGXR]RQXQDG 3ROVNąWHPSHUDWXU\SRZLHU]FKQLRZH]QDF]ąFHREV]DU\RFHDQLF]QHPRGHORZDQLHSURJQR]RZDQLHVWDW\VW\F]Q\]ZLą]HN interakcja troposfery i stratosfery. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 37–40 Dynamic Viscosity of Water and Milk Suspensions of Extruded Corn Porridge Magdalena Klimek, Leszek Mościcki, Agnieszka Wójtowicz, Tomasz Oniszczuk, Maciej Combrzyński, Marcin Mitrus Department of Food Process Engineering, Lublin University of Life Sciences Doświadczalna 44, 20-236 Lublin, Poland Received December 01.2014; accepted December 17.2014 Abstract: The purpose of this study was to determine the effect of temperature and the content of extruded corn porridge RQWKHG\QDPLFYLVFRVLW\RIZDWHUDQGPLONVXVSHQVLRQV([trusion-cooking process was carried out using a single extruVLRQFRRNHU76'XULQJWKHPHDVXUHPHQWVLWZDVQRWHGWKDW the viscosity of the suspensions was affected by the kind of OLTXLGXVHGWKHWHPSHUDWXUHRIWKHVXVSHQVLRQDQGWKHFRQWHQW of porridge in the mixture. The highest viscosity was found in DPLON\VXVSHQVLRQWHVWHGDW& Key words: extruded, extrusion-cooking, corn porridge, suspensions, viscosity, food in appropriate conditions allows to obtain a new type of products different in relevant properties, texture, appearance DQGTXDOLW\RIKHDOWK>@4XDOLWDWLYHO\EHWWHUSURGucts are derived from harder maize, which is caused by the KLJKHUDP\ORVHFRQWHQWLQFRPSRVLWLRQ>@&RUQSURGXFWV and dishes are hypoallergenic and gluten-free. Due to the different composition of protein compared to other cereals, corn products are recommended for people suffering from FHOLDFGLVHDVH>@ 0$7(5,$/6$1'0(7+2'6 INTRODUCTION Current trends show an increase in consumption of conYHQLHQFHIRRGZKLFKGRHVQRWUHTXLUHDORQJWLPHWRSUHSDUH Nowadays the consumers attach more and more importance to healthy eating, which is a challenge for manufacturers of functional foods for direct consumption. Innovations used in food processing, i.e. extrusion-cooking, micronization, expanding and combining plant additives call for the replacement of popular snacks with a new type of healthy SURGXFWV>@ ([WUXVLRQFRRNLQJLVSURFHVVLQJRIYHJHWDEOHUDZPDWHrials under high pressure and high temperature, which causes VLJQL¿FDQWFKDQJHVLQWKHLUSK\VLFDODQGFKHPLFDOSURSHUWLHV During processing the material is mixed, compacted, comSUHVVHGPHOWHGDQGSODVWLFL]HGLQWKH¿QDOH[WUXGHU]RQH %DURWKHUPDOWUHDWPHQWFDQEHSHUIRUPHGLQFRQGLWLRQVRI XSWR&DQGSUHVVXUHVXSWR03D([WUXVLRQFRRNLQJ technology is used in the food industry for the production of various types of food products such as snacks, instant cereal baby food, breakfast cereals, texturized vegetable protein, FULVSEUHDGHWF>@ Corn grits is one of the most popular material used in the SURGXFWLRQRIH[WUXVLRQFRRNHGIRRG>@3URFHVVLQJ The main raw material used in our experimental study ZDVFRPPHUFLDOFRUQJULWV9HJHWXV/XEDUWyZ3RODQG ZLWK D PRLVWXUH FRQWHQW RI GP ([WUXVLRQ ZDV FDUULHG RXW LQ D VLQJOH VFUHZ H[WUXVLRQFRRNHU76 =0&K0HWDOFKHP*OLZLFH3RODQGXVLQJDVLQJOHGLH RIPPGLDPHWHU7KHUPDOWUHDWPHQWZDVDW& DWWKHFRQVWDQWVFUHZURWDWLRQ±USP7KHREWDLQHG corn extrudates were grounded in a laboratory mill type /017HVW&KHP5DGOLQWRWKHSDUWLFOHVL]HRIPP >@ Moisture was determined by a drying chamber method, LQDFFRUGDQFHWRVWDQGDUG±31$>@ :DWHUDQGPLONVXVSHQVLRQVRIDQGVKDUHRI extrudates were studied. 6DPSOHVZHUHPL[HGIRUPLQXWHVWRREWDLQDXQLIRUP consistency. The values of dynamic viscosity were measured DWWZRWHPSHUDWXUHV&DQG&0HDVXUHPHQWVZHUH registered six-times. Samples with hot distilled water and milk were prepared as follows: a weighed sample of the extrudate was mixed ZDWHURUPLONDWDWHPSHUDWXUHRI&(YHU\VLQJOHVDPSOHZDVPL[HGIRUPLQWKHQFRROHGWR&DWZKLFK measurement was taken. The measurements carried out at &GLGQRWUHTXLUHDGGLWLRQDOKHDWLQJ 0./,0(./02ĝ&,&.,$:Ï-72:,&=721,6=&=8.0&20%5=<ē6.,00,7586 Fig. 2. (IIHFWRIFRUQJULWVDQGWHPSHUDWXUHRQWKHYLVFRVLW\RI DTXHRXVVROXWLRQVRIFRUQJULWV )LJVKRZVWKHYLVFRVLW\RIPLONVXVSHQVLRQDW&DQG &UHVSHFWLYHO\'XULQJWKHPHDVXUHPHQWVLWZDVIRXQG out that milky suspension was characterized by higher levels of dynamic viscosity compared to the water solutions. For example the viscosity of the milk suspension containing H[WUXGHGFRUQZDVDOPRVWWZLFHDVKLJKDVWKDWRIWKH ZDWHUVXVSHQVLRQDQGDPRXQWHGXSWR3DāVDW0C. $OVRLQWKDWFDVHZHFDQVD\WKDWWKHWHPSHUDWXUHRIWKH VXVSHQVLRQVSOD\HGDQLPSRUWDQWUROH+LJKHUWHPSHUDWXUH decreased the viscosity value. The highest viscosity valFig. 1. 7HVWLQJ0DFKLQH=ZLFNW\SHRI%'2)%7+ZLWK XH3DāVZDVREWDLQHGIRUPLONVXVSHQVLRQDW mounted “back-extrusion” snap &)RUWKHVDPHVXVSHQVLRQDW&WKHG\QDPLFYLVFRVLW\ ZDV3DāV Changes in viscosity of suspensions were measured using DXQLYHUVDOWHVWLQJPDFKLQH=ZLFN5RHOO%'2)%7+ =ZLFN*PE+&R*HUPDQ\)LJHTXLSSHGZLWK a back extrusion snap. During measurements were used: DFKDPEHURIPPKHLJKWDQGLQWHUQDOGLDPHWHURIPP DQGDSOXQJHURIPPGLDPHWHUDQGDKHLJKWRIPP Resistance force was recorded during movement of the piston through the slurry in two measuring cycles: down and XSZKLFKZDVFRQYHUWHGWRWKHYDOXHRIWKHFRHI¿FLHQWRI YLVFRVLW\3UR¿OHVRIWKHG\QDPLFYLVFRVLW\DYHUDJHGHFUHDVH in shear strength, and the standard distance were recorded. 7KHWHVW;SHUWYZDVXVHGIRUWKHSURSHUPHDVXUHPHQWV Fig. 3. 9LVFRVLW\RIFRUQJULWV±PLONVXVSHQVLRQ SURFHGXUH>@ 5(68/76$1'',6&866,21 CONCLUSIONS 7KH VWXG\ FRQ¿UPHG WKH SRVVLELOLW\ RI XVLQJ H[WUXsion-cooking technology in the production of safe inThe moisture content of the extruded corn porridge has a great importance during storage, for maintaining the senstant corn porridge. The average moisture content of the VRU\TXDOLWLHVDVZHOODVWKHPLFURELRORJLFDOVDIHW\>@ H[WUXGHGSURGXFWVZDV Taking all these aspects into account we can say that our 2. Increased temperature decreased the dynamic viscosity of the suspensions. The highest dynamic viscosity was products were very safe, their moisture content was less PHDVXUHGIRUWKHPLON\VXVSHQVLRQDW& WKDQDWDYHUDJH Dynamic viscosity of water suspensions made from the ,QFUHDVLQJDPRXQWRIWKHH[WUXGHGFRUQSRUULGJHLQWKH mixture resulted in the increasing of the dynamic visH[WUXGHGFRUQSRUULGJHVLJQL¿FDQWO\FKDQJHGZLWKLQFUHDVLQJ cosity of the suspension. its percentage share. The increase of the extrudate in the suspension resulted in higher values. Viscosity of water VXVSHQVLRQDW&UHDFKHG3DāVDWWKHFRQFHQWUDWLRQ 5()(5(1&(6 RI$WWKHGRXEOHFRQFHQWUDWLRQ±WKHREWDLQHG YDOXHZDV3DāV+HDWLQJRIWKHVXVSHQVLRQXSWR& resulted in the lowering of viscosity index, which varied $6$(6WDQGDUG$6$(6 Wafers, pellet IURP3DāVDWFRQFHQWUDWLRQIRUFRUQSRUULGJHWR DQGFUXPEOHV±GH¿QLWLRQVDQGPHWKRGVIRUGHWHUPLQLQJ 3DāVDWFRQFHQWUDWLRQIRUFRUQJULWVVHH)LJ density, durability and moisture content. '<1$0,&9,6&26,7<2):$7(5$1'0,/.6863(16,216 2. Bhattacharya S., Sudha M.L., Rahim A., 1999: Pasting characteristics of an extruded blend of potato and ZKHDWÀRXUV-RXUQDORI)RRG(QJLQHHULQJ Chaunier L., Valle G.D., Lourdin D., 2007: Relationships between texture, mechanical properties and VWUXFWXUHRIFRUQÀDNHV)RRG5HVHDUFK,QWHUQDWLRQDO &]HUZLĔVND'3U]HWZRU\]NXNXU\G]\±URG]DMH FKDUDNWHU\VW\NDZ\NRU]\VWDQLH3U]HJOąG=ERĪRZR± 0á\QDUVNL *RQGHN(-DNXEF]\N(:LHF]RUHN%:áDĞFLZRĞFL¿]\F]QHEH]JOXWHQRZHJRSLHF]\ZDFKUXSNLHJR =HV]\W\3UREOHPRZH3RVWĊSyZ1DXN5ROQLF]\FK Gujral H.S., Sodhi N.S., 2002:%DFNH[WUXVLRQSURSHUWLHVRIZKHDWSRUULGJH'DOLD-RXUQDORI)RRG(QJLQHHULQJ 7. Guy R.([WUXVLRQ&RRNLQJ7HFKQRORJLHVDQG $SSOLFDWLRQV&5&3UHVV,QF%RFD5DWRQ)/86$ 8. Harper J.M., 1981:([WUXVLRQRI)RRGVYRO,L,,&5& 3UHVV,QF)ORU\GD86$ 9. Jurga R. 3U]HWZRU\ ] NXNXU\G]\ X]\VNDQH PHWRGąHNVWUX]ML3U]HJOąG=ERĪRZR0á\QDUVNL Jurga R., 2012:3U]HWZyUVWZRNXNXU\G]\±PRĪOLZRĞFL Z\NRU]\VWDQLD3U]HJOąG=ERĪRZR0á\QDUVNL Kunachowicz H., Przygoda B., 2008::]ERJDFDüĪ\ZQRĞüF]\QLHZ]ERJDFDü"3U]HP\Vá6SRĪ\ZF]\ /HH6</XQD*X]PDQ,&KDQJ6%DUUHWW'0 Guinard J-X., 1999: Relating descriptive analysis and instrumental texture data of processed diced tomatoes. )RRG4XDOLW\DQG3UHIHUHQFH Mercier C., Linko P., Harper J.M., 1998:([WUXVLRQ FRRNLQJ 6W 3DXO $PHULFDQ $VVRFLDWLRQ RI &HUHDO Chemists, Inc 0LWUXV02QLV]F]XN70RĞFLFNL0 Changes RIVSHFL¿FPHFKDQLFDOHQHUJ\GXULQJH[WUXVLRQFRRNLQJ RISRWDWRVWDUFK7(.$.RP0RW,(QHUJ5ROQ±2/ 3$1F Mitrus M., Wójtowicz A., 2011:([WUXVLRQFRRNLQJ RIZKHDWVWDUFK7(.$.RP0RW,(QHUJ5ROQ±2/ 3$1F Mouquet C., Salvignol B., Hoan N.V., Monvois J., Treche S., 2003:$ELWLW\RID³YHU\ORZFRVWH[WUXGHU´WR SURGXFHLQVWDQWLQIDQWÀRXUVDWDVPDOOVFDOHLQ9LHWQDP )RRG&KHPLVWU\ 0RĞFLFNL/0LWUXV0:yMWRZLF]$ Technika HNVWUX]MLZSU]HP\ĞOHUROQRVSRĪ\ZF]\P:DUV]DZD PWRiL 0RĞFLFNL / (NVWUX]MD Z SU]HWZyUVWZLH UROQRVSRĪ\ZF]\P&],,6XURZFHVWRVRZDQHZSURGXNFML Z\UREyZHNVWUXGRZDQ\FK3U]HJOąG=ERĪRZR±0á\QDUVNL 0RĞFLFNL/0LWUXV0:yMWRZLF]$2QLV]F]XN T., Rejak A., Janssen L., 2012:$SSOLFDWLRQRIH[WUXsion-cooking for processing of thermoplastic starch 736)RRG5HVHDUFK,QWHUQDWLRQDO9ROSS 299. 20. Naz S., Siddigi R., Sheikh H., Sayeed S.A., 2005: Deterioration of olive, corn and soybean oils due to air, OLJKWKHDWDQGGHHSIU\LQJ)RRG5HV,QWHUQDW 2QLV]F]XN7:yMWRZLF]$0LWUXV00RĞFLFNL/ &RPEU]\ĔVNL05HMDN$*áDG\V]HZVND% %LRGHJUDGDWLRQRI736PRXOGLQJVHQULFKHGZLWKQDWXUDO ¿OOHUV7HND&RPPLVLRQRI0RWRUL]DWLRQDQG(QHUJHWLFV LQ$JULFXOWXUH3ROLVK$FDGHP\RI6FLHQFHV%UDQFKLQ /XEOLQYRO1RSS 22. PN-A-888034: 1998&KUXSNL0HWRG\EDGDĔ 5DPLUH]-LPHQ] $ *XHUUD+HUQDQGH] ( *DUcia-Villanowa B., 2003:(YROXWLRQRIQRQHQ]\PDWic browning during storage of infant rice cereal. 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COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 41–44 The Note on Application of Logistic Model in Agriculture Research Andrzej Kornacki Department of Applied Mathematics and Computer Science University of Life Sciences in Lublin Akademicka 12, 20-950 Lublin, e-mail: [email protected] Received December 10.2014; accepted December 19.2014 Summary. In the study an example was presented when the DSSOLFDWLRQRIWKHFRHI¿FLHQWRIGHWHUPLQDWLRQ52, a commonly XVHGJRRGQHVVRI¿WPHDVXUHRIWKHPRGHOWRWKHHPSLULFDOUHVXOWV leads to wrong conclusions. It is an example of a logistic model. Theoretical considerations were applied to the model describing the germination of seeds which underwent laser biostimulation prior to sowing. Moreover, the origin of problems that appears in the described situation was explained. Key words: ORJLVWLFPRGHOFRHI¿FLHQWRIGHWHUPLQDWLRQ52, laser biostimulation prior to sowing. RIWKHPRGHORUUHJUHVVLRQIXQFWLRQWRH[SHULPHQWDOGDWD ZKHUHDVWKRVHFORVHWRLQGLFDWHSRRU¿W0RUHRYHUYDOXH R2 determines which part of variability of the experimental UHVXOWVLVH[SODLQHGE\WKHPRGHORUUHJUHVVLRQIXQFWLRQ +RZHYHULQFDVHRIVRPHQRQOLQHDUPRGHOVYDOXH52 can be negative. In such a case the application of this coef¿FLHQWLVLQFRUUHFW 7+(2%-(&7,9($1'6&23(2)678'< The objective of the study was to demonstrate that the FRHI¿FLHQWRIGHWHUPLQDWLRQ52 for some nonlinear models can take on negative values. This study describes such a case Describing processes by mathematical models is a prob- regarding a logistic model. Theoretical considerations were lem of interest to a number of researchers in various areas of applied to the model describing the germination process of VFLHQFH+RZHYHUWKHPRGHOVKDSHDOVRUHTXLUHVWKHYHUL¿FD- seeds that underwent laser biostimulation prior to sowing. tion of its correctness based on empirical data. The measure 0RUHRYHULWZDVH[SODLQHGZK\WKHXVHRIDFRHI¿FLHQWRI RIWKHJRRGQHVVRI¿WRIWKHPRGHOWRHPSLULFDOGDWDWKDWLV determination is incorrect in this situation. RIWHQXVHGLVWKHFRHI¿FLHQWRIGHWHUPLQDWLRQ52>@ 7KLVFRHI¿FLHQWIRUFKDUDFWHULVWLFyLVGH¿QHGDV>@ 0$7(5,$/$1'0(7+2'6 SSE R2 SST $WWKH'HSDUWPHQWRI3K\VLFVRIWKH8QLYHUVLW\RI/LIH Sciences in Lublin the research was conducted aiming at the where: n SST ¦ ( yi y 2 LVWRWDOVXPRIVTXDUHIRUJLYHQIHDWXUH determination of the germination process of tomato seeds i and the impact of the laser biostimulation of the sowable n PDWHULDORQWKLVSURFHVV>@,QWKHUHVHDUFKWKHVHHGVRI SSE ¦ ( yi f i 2 LVHUURUVXPRIVTXDUH i Promyk variety were used. In laser biostimulation the adjustable doses of energy method were used assuming the dose and HTXDOWRP-)RUFRPSDUDWLYHUHDVRQVDFRQWUROVDPSOH yi±GHQRWHVHPSLULFDOGDWD fi±GHQRWHVWKHYDOXHVRIDIXQFWLRQGHVFULELQJWKHPRGHO RIVHHGVQRQELRVWLPXODWHGZDVWDNHQ7KHWHVWJURXSZDV &RHI¿FLHQW52 works perfectly in case of linear mod- represented by 700 seeds sown on Petri plates with tissue els and some nonlinear ones which are brought to linear SDSHUOLQLQJLQVDPSOHVVHHGVSHUVDPSOH7KHSODWHV models using the relevant transformations (i.e. nonlinear were placed in an electrostatic furnace, ensuring temperature LQWHUQDOOLQHDUPRGHOV>@,WWDNHVRQWKHYDOXHVIURPWKH stabilisation with the accuracy to 0C. The seeds germinatUDQJH!9DOXHVFORVHWRSURYHWKHJRRGQHVVRI¿W HGZLWKRXWDFFHVVRIOLJKW(YHU\IHZKRXUVWKHJHUPLQDWLQJ INTRODUCTION $1'5=(-.251$&., $WWKH'HSDUWPHQWRI3K\VLFVRIWKH8QLYHUVLW\RI/LIH6FLHQFHVLQ/XEOLQWKHUHVHDUFK LPSDFWRIWKHODVHUELRVWLPXODWLRQRIWKHVRZDEOHPDWHULDORQWKLVSURFHVV>@,QWKHUHVHDUFK seeds were counted. The seed was considered germinated Ta b l e 2 . 7KHYDOXHVRIVXPVRIVTXDUHVDQGWKHFRHI¿FLHQW if it formed a germ which was at least 2 mm long. During of determination R2 for germinated seeds of Promyk variety HUH XVHG DVVXPLQJ WKH GRVH HTXDO WR P- )RU FRPSDUDWLYH UHDVRQV D FRQWURO the experiment the constant moisture content of the tissue WRPDWRHVVWLPXODWHGZLWKWKHGRVHRIP-DWWHPSHUDWXUH0C. ELRVWLPXODWHGZDVWDNHQ7KHWHVWJURXSZDVUHSUHVHQWHGE\VHHGV paper was maintained by dosing distilled water. SST LQVDPSOHVVHHGVSHUVDPSOH7KH 66( R &7KHVHHGVJHUPLQDWHGZLWKRXWDFFHVVRIOLJKW(YHU\IHZKRXUVWKHJHUPLQDWLQJVHHGV 0$7+(0$7,&$/02'(/ 2)7+(*(50,1$7,21352&(66 Ta b l e 3 . 7KHYDOXHVRIVXPVRIVTXDUHVDQGWKHFRHI¿FLHQWRI determination R2 for nonstimulated germinated seeds of Promyk 2)720$726(('6 2 YDULHW\WRPDWRHVDWWHPSHUDWXUH& The germination process of tomato seeds undergoing laSST ELRVWLPXODWLRQ ZLWK WKH GRVH RI P- DW WHPSHU ser biostimulation before sowing can be described by means ELRVWLPXODWHG VHHGV DW66( WHPSHUDWXUH of a mathematical model which is expressed by means WHPSHUDWXUH of &DUHSUHVHQWHGLQ7DEOHVDQGDVZHOODV7DEOH R2 WKHORJLVWLFIXQFWLRQ>@LQWKHIRUPRI IXQFWLRQ>@LQWKHIRUPRI Ta b l e 4 . 7KHYDOXHVRIVXPVRIVTXDUHVDQGWKHFRHI¿FLHQW nk n(t of determination R2 for germinated seeds of Promyk variety 7DEOH D p nk ( t t0 (nk e D WRPDWRHVVWLPXODWHGZLWKWKHGRVHRIP-DWWHPSHUDWXUH& 7DEOH where: SST $V7DEOHV VKRZLQWKHFRQVLGHUHGFDV nk±¿QDOQXPEHURIJHUPLQDWHGVHHGV 66( QHJDWLYHYDOXHV,QVXFKDVLWXDWLRQLWGRHVQRWKDYHDQ\LQWHUSUHWDWLRQDWDOODQGFRQVHTXHQWO\ QW±QXPEHURIVHHGVJHUPLQDWHGDIWHUJLYHQWLPHW QW R2 D p ±FRHI¿FLHQWRIJHUPLQDWLRQVSHHG>K@ D VSHHG>K@ @ WKDW LQ WKH OLQHDU UHJUHVVLRQ PRGHO VRPH EDVLF LGHQWLW\ WDNHV t0±WLPHJHUPLQDWLRQRIWKH¿UVWVHHGVVRZQ>K@ ,WLVGHPRQVWUDWHG>@WKDWLQWKHOLQHDUUHJUHVVLRQPRGValues D p and t0 are determined on an experimental el some basic identity takes place. basis. n n n ( y i yÖ 2 ¦ ( y i f i 2 ¦ ( f i y 2 so SST SSE SSR In a general case the D logistic curve can be described by ¦ i i i a formula with three parameters n three parameters In a general case the logistic curve can be described by a formula with SSR 2¦ ( f i y 2 where A ¦ ( y i f (t Be Ct GHQRWHVUHJUHVVLRQVXPRIVTXDUH GHQRWHVUHJUHVVLRQVXPRIVTXDUH 7KHSURRIRIWKHLGHQWLW\LVEDVHGRQWKHOLQHDULW\RI LV EDVHGRQWKHOLQHDULW\RIWKHUHJUHVVLRQPRGHO DQGWKH Results and discussion WKHUHJUHVVLRQPRGHODQGWKHHYDOXDWLRQRILWVFRHI¿FLHQWV HYDOXDWLRQRILWVFRHIILFLHQWVXVLQJWKHOHDVWVTXDUHPHWKRG&RQVHTXHQWO\LGHQWLW\LVWUXH 8VLQJ IRUPXOD WKH QXPEHU RIIRU JHUPLQDWHG VHHGV ZDV FDOFXODWHG WKH VTXDUH PHWKRG 7KH UDQJH RI 5(68/76$1'',6&866,21 XVLQJWKHOHDVWVTXDUHPHWKRG&RQVHTXHQWO\LGHQWLW\ OLQHDU PRGHOV ZLWKQW FRHIILFLHQWV HYDOXDWHG DQG XVLQJWKHQ WKH OHDVW VXPVRIVTXDUHV667DQG66(DQGILQDOO\IURPIRUPXODWKHYDOXHRIWKHFRHIILFLHQWRI !UHVXOWVLQDQREYLRXVZD\IURPLGHQWLW\ LVWUXHIRUOLQHDUPRGHOVZLWKFRHI¿FLHQWVHYDOXDWHGXVLQJ IRUZKLFKLGHQWLW\GRHVQRWRFFXU,WLVSURYHGE\WKH 8VLQJIRUPXODWKHQXPEHURIJHUPLQDWHGVHHGVQW WKHOHDVWVTXDUHPHWKRG7KHUDQJHRIYDOXHRIFRHI¿FLHQW VXPVRIVTXDUHVLQ7DEOHV ,WLVWKLVSDUWLFXODUIDFWWKDWLVWKHVRX XQGHUZHQWODVHUELRVWLPXODWLRQZLWKP-GRVHDWWHPSHUDWXUH &DUHSUHVHQWHGLQ7DEOH 2 ZDVFDOFXODWHGDQGWKHQWKHVXPVRIVTXDUHV667DQG66( R !UHVXOWVLQDQREYLRXVZD\IURPLGHQWLW\7KH 7DEOH DQG¿QDOO\IURPIRUPXODWKHYDOXHRIWKHFRHI¿FLHQWRI logistic model is an example of a non-linear model for determination R2. The results for germinated seeds of Promyk ZKLFKLGHQWLW\GRHVQRWRFFXU,WLVSURYHGE\WKHVXPV RIVTXDUHVLQ7DEOHV,WLVWKLVSDUWLFXODUIDFWWKDWLVWKH variety tomatoes which underwent laser biostimulation with Ϯ P-GRVHDWWHPSHUDWXUH0&DUHSUHVHQWHGLQ7DEOH VRXUFHRIQHJDWLYHYDOXHVRIWKHFRHI¿FLHQWRIGHWHUPLQDWLRQ Ta b l e 1 . 7KHYDOXHVRIVXPVRIVTXDUHVDQGWKHFRHI¿FLHQW of determination R2 for germinated seeds of Promyk variety WRPDWRHVVWLPXODWHGZLWKWKHGRVHRIP-DWWHPSHUDWXUH0C. -0,90 CONCLUSIONS To sum up the considerations contained in the study, the following conclusions can be formulated: >@'RERV]0&RPSXWHUDLGHGVWDWL $NDGHPLFND2ILF\QD &RHI¿FLHQWRIGHWHUPLQDWLRQ52 is a very good measure :\GDZQLF]D([LW:DUV]DZD>LQ3ROLVK@ RIJRRGQHVVRI¿WRIlinear models and some nonlinear >@%LDáREU]HVNL,0\KDQ5&\G]LN5(IIHFWLYHZDWHUGLIIXVLRQFRHIILFLHQWLQ)DED EHDQVHHGVGXULQJGU\LQJ3DUW,,$QDO\VLVRIHVWLPDWLRQHUURUV(OHFWURQLF-RXU but internal linear ones to empirical data. Similar results for germinated seeds of Promyk vari$JULFXOWXUDO8QLYHUVLWLHV9RO,VVXH ety tomatoes which underwent laser biostimulation with ,WLVQRWUHFRPPHQGHGWKDWWKHFRHI¿FLHQWRIGHWHUPLQDWLRQ WKHGRVHRIP-DWWHPSHUDWXUH0C, the control sample R2EHXVHGDVDJRRGQHVVRI¿WFULWHULRQIRUDORJLVWLFPRGHO 0 ϯ QRQELRVWLPXODWHGVHHGVDWWHPSHUDWXUH C and the sam0 SOHVRIELRVWLPXODWHGVHHGVDWWHPSHUDWXUH C are presentHGLQ7DEOHVDQGDVZHOODV7DEOH 5()(5(1&(6 $V7DEOHVVKRZLQWKHFRQVLGHUHGFDVHVWKHFRHI¿FLHQWRIGHWHUPLQDWLRQWDNHVRQQHJDWLYHYDOXHV,QVXFK Dobosz M., 2001: Computer aided statistical analysis RIWHVWUHVXOWV$NDGHPLFND2¿F\QD:\GDZQLF]D([LW a situation it does not have any interpretation at all and Warszawa.[in Polish], FRQVHTXHQWO\LWFDQQRWEHXVHGDVDPHDVXUHRIJRRGQHVV RI¿WRIWKHPRGHOWRHPSLULFDOGDWD/HWXVGHPRQVWUDWHWKH 2. %LDáREU]HVNL,0\KDQ5&\G]LN5(IIHFWLYH source of the existing situation. ZDWHUGLIIXVLRQFRHI¿FLHQWLQ)DEDEHDQVHHGVGXULQJ SST 66( R2 7+(127(21$33/,&$7,212)/2*,67,&02'(/,1$*5,&8/785(5(6($5&+ GU\LQJ3DUW,,$QDO\VLVRIHVWLPDWLRQHUURUV(OHFWURQLF -RXUQDORI3ROLVK$JULFXOWXUDO8QLYHUVLWLHV9RO,Vsue 2, http://www.ejpau.media.pl//volume8/issue2/art29.html, *áDG\V]HZVND%(YDOXDWLRQRIWKHLPSDFWRI pre-laser bio-stimulation of seeds of tomatoes on the process of germination. The doctoral dissertation. Uniwersytet Przyrodniczy w Lublinie.[In Polish], Molenda M. Lukaszuk J., Horabik J., 2005: $LUÀRZ resistance of wheat as affected by grain density and PRLVWXUHFRQWHQW(OHFWURQLF-RXUQDORI3ROLVK$JULFXOWXUDO8QLYHUVLWLHV9RO,VVXHKWWSZZZHMSDXPHGLD SOYROXPHLVVXHDUWKWPO Królczyk J., Matuszek D., Tukiendorf M., 2010: ModHOOLQJRITXDQWLW\FKDQJHVLQDPXOWLFRPSRQHQWJUDQXODU PL[WXUHGXULQJPL[LQJ(OHFWURQLF-RXUQDORI3ROLVK$JULFXOWXUDO8QLYHUVLWLHV9RO,VVXHKWWSZZZHMSDX PHGLDSODUWLFOHVYROXPHLVVXHDUWSGI 2QLV]F]XN70RĞFLFNL/(IHFWRI¿OOHUVDGGLWLRQRQ60(RIH[WUXVLRQFRRNLQJRIWKHUPRSODVWLF ZKHDWVWDUFK7HND.RP0RW(QHUJ5ROQ2/3$1 7. 2QLV]F]XN70RĞFLFNL/ Production of biodegradable packaging materials by extrusion-cooking 7HND.RP0RW(QHUJ5ROQ2/3$1 8. Ryan T.P. 1997: Modern regression methods. John :LOH\6RQV1HZ<RUN 9. Seber G.A.F., 1977: Linear regression analysis. John :LOH\6RQV1HZ<RUN Seber G.A.F., Wild C.J. 1989: Nonlinear regression, -RKQ:LOH\6RQV1HZ<RUN 127$2=$67262:$1,802'(/8 /2*,67<&=1(*2:%$'$1,$&+52/1,&=<&+ Streszczenie. :SUDF\RSLVDQRSU]\NáDGNLHG\XĪ\FLHZVSyáczynnika determinacji R2, powszechnie stosowanej miary dobroci dopasowania modelu do wyników eksperymentu prowadzi do QLHZáDĞFLZ\FKZQLRVNyZ-HVWWRSU]\SDGHNPRGHOXORJLVW\F]QHJR5R]ZDĪDQLDWHRUHW\F]QH]DVWRVRZDQRGRPRGHOXRSLVXMąFHJR SURFHVNLHáNRZDQLDQDVLRQSRGGDQ\FKSU]HGVLHZQHMODVHURZHM ELRVW\PXODFML3RQDGWRZ\MDĞQLRQRFRMHVWĨUyGáHPSUREOHPyZ SRMDZLDMąF\FKVLĊZRSLVDQHMV\WXDFML 6áRZDNOXF]RZHPRGHOORJLVW\F]Q\ZVSyáF]\QQLNGHWHUminacji R2, przedsiewna biostymulacja nasion. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 45–52 An Analysis of Pressure Distribution in Water and Water Emulsion In a Front Gap of a Hydrostatic Bearing Konrad Kowalski, Tadeusz Zloto Institute of Mechanical Technologies, Czestochowa University of Technology Al. Armii Krajowej 21, 42-201 Czestochowa, [email protected], [email protected] Received December 05.2014; accepted December 18.2014 &]Ċ Summary. The paper presents pressure distributions for water and water emulsion in a variable-height gap of a hydrostatic thrust bearing with a rotating upper wall. On the basis of the Navier-Stokes equations and the continuity equation a formula is established for obtaining pressure in the gap. The paper also analyses the influence of geometrical parameters and exploitation conditions on the distribution of circumferential pressure around the smallest height of the gap. Key words: pressure distribution, variable-height gap, hydrostatic thrust bearing, water, water emulsion. INTRODUCTION The problem of gap flow concerns a number of hydraulic devices and machines in which contact parts are separated by liquid-filled gaps of very small height. For gap flow of working liquids the Reynolds number is small and the flow is laminar [13, 26]. There are gaps of various shapes and dimensions. Since each gap in a hydraulic system is a source of loss [5, 6, 13, 21], it is important to examine phenomena that occur in them [14]. Losses are essentially dependent on the gap height: the greater the gap height the smaller the mechanical losses and the greater the volumetric losses [22]. Hydrostatic bearings are applied in popular hydrostatic drive systems [3, 4, 10, 16, 18, 19, 20]. In the case of axial pumps with a flat swash plate, a front gap can be found between slipper and swash plate and between cylinder block and valve. The smallest gap height between the slipper and swash plate is much greater than that between the cylinder block and valve plate [2]. The working liquid used in a hydraulic system is of crucial the slipper and swash plate is much greater than that between the cylinder block and valve plate [2]. The working liquid used in a hydraulic system is of crucial importance, too. The liquid is responsible for transferring large forces and torques of the system’s elements. Selecting a working liquid has therefore economic and often environmental consequences. Over the centuries, the discipline of fluid mechanics, including broadly conceived hydraulics, was developed by a number of prominent scientists, such as Thales of Miletus, Aristotle, Ktesibios, Archimedes, Da Vinci, Stevin, Torricelli, Pascal, Boyle, Newton, Bernoulli, Euler, Armstrong or Bramah [27]. In 1795, Bramah designed, patented and constructed the first hydraulic water press [11]. It was however observed that water as working liquid caused corrosion of metal elements and at the beginning of the 20th century American scientists Harvey Williams and Reynolds Janney came up with the idea of using mineral oil instead of water. They were the first to construct a hydrostatic piston axial gear with a swing swash plate [14]. This invention marks the beginning of the rapid development of oil hydraulics, which continues until today. In hydraulic systems various liquids are used as working agents (Fig. 1). At present the one most frequently used is mineral oil [7, 23]. In places under the risk of fire, such as mines, non-flammable liquids are used. The liquids applied are not perfect. With the multitude of industrial applications, it is necessary to search for liquids meeting the requirements as closely as possible. Because of that, studies are conducted on the application of plant oils in hydraulic systems. New opportunities seem Fig. 1. Working liquids used in hydraulic drives The liquids applied are not perfect. With the multitude .215$'.2:$/6.,7$'(86==/272 liquids meeting the requirements as closely as possible. Because of that, studies are conducted on the application of plant oils in hydraulic systems. New opportunities seem to be offered by what is known as intelligent fluids, including electro-rheological and magneto-rheological fluids. Besides, in the recent years there has been a revival of interest in water. Its applicability as a working agent in hydraulic systems is expected to rise due to the fact that it is environment-friendly and much cheaper than the other liquids currently used [11, 12, 17]. Following intensive research on water hydraulics [12], many producers and suppliers offer parts for modern water systems. OBJECTIVES OF THE STUDY The present study aims to examine the influence of exploitation parameters and dimensions on pressure distributions in the area surrounding the smallest height of the front gap in a hydrostatic thrust bearing with water and with a water emulsion. The study assumes an analytic model of pressure distribution in a front gap of the hydrostatic thrust bearing with a rotating upper wall. GU UGij G] A MODEL BASED ON THE NAVIER-STOKES EQUATIONS AND THE CONTINUITY EQUATION OF LIQUID PRESSURE DISTRIBUTION IN A FRONT GAP OF A HYDROSTATIC BEARING Pressure distribution in the front gap of a hydrostatic thrust bearing (Fig. 2) can be best described analytically by means of a system of equations consisting of the Navier-Stokes equation and the continuity equation represented in a cylindrical system of coordinates U, ij, ] [8, 15, 25]. A fluid element ABCDEFGH of dimensions GU UGij, G] is presented in Fig 3. To solve the system of equations (1- 4) analytically, it is necessary to adopt the following simplifying assumptions: The gap is of micrometre high and is completely filled with incompressible liquid of constant viscosity; Surfaces are rigid; Liquid flow is laminar, uniform, steady and isothermal; Tangent stress is Newtonian; U ij ] Liquid particles directly adjacent to the rotating wall surface have the same velocity as the rotating wall; Inertia is negligible. Fig. 2. Front gap of a hydrostatic thrust bearing [25] The base system of equations is [8, 15, 25]: The base system of equations is [8, 15, 25]: U ] (1) , (5) (2) , , . (3) (4) (9) To solve the system of equations (1- 4) analytically, it is necessary to adopt the ] FRQGLWLRQV $1$1$/<6,62)35(6685(',675,%87,21,1:$7(5$1':$7(5(08/6,21 Inertia is negligible. , (12) and after substituting (11) and (12) into equation (10): . (13) After integrating equation (6) twice with respect to the variable ], the velocity vijwas obtained: . (14) The boundary conditions used for computing the integration constants & and & are presented in Table 2. Table 2. Boundary conditions for computing the integration constants & and & Fig. 3. A fluid element in a cylindrical coordinate system [1] Besides, if vr = vr(U, ]) and vz = 0, equations (1 - 4) become: , (5) %RXQGDU\ FRQGLWLRQV 1R 9DULDEOH] 9HORFLW\vij z=0 vij = 0 z=h vij = Ȧr Hence: , , (6) , (7) (15) , (16) and after substituting (15) and (16) into equation (14): . . (17) (8) When (14) and (17) are substituted into (8): Equation (5) can be transformed and represented as: . (18) . (9) To obtain the velocity vr, it is necessary to integrate equation (9) twice with respect to the variable ]. Then, the result is: . (10) The integration constants & and & were obtained for the boundary conditions presented in Table 1. Integrating equation (18) with respect to the variable ] in the interval from 0 to K and performing some transformations yields: . To obtain a formula describing the pressure S in a front gap, it is necessary to integrate equation (19) twice with respect to the variable U. This leads to : . Table 1. Boundary conditions for computing the integration constants & and & %RXQGDU\ FRQGLWLRQV 1R 9DULDEOH] 9HORFLW\vr z=0 vr = 0 z=h vr = 0 (20) The integration constants & and & were computed for the boundary conditions specified in Table 3. Table 3. Boundary conditions for computing integration constants & and & Then, it follows: , (19) (11) (12) %RXQGDU\ FRQGLWLRQV Hence: 1R 5DGLXVU 3UHVVXUH p r = r1 p = p1 r = r2 p=0 & & & & ZDWHU ZDWHUHPXOVLRQ 1R 5DGLXVU 3UHVVXUH 5DGLXVU 3UHVVXUH %RXQGDU\ .215$'.2:$/6.,7$'(86==/272 FRQGLWLRQV 1R %RXQGDU\ FRQGLWLRQV Hence: . İ Substituting integration constants (21, 22) into equation (20) ultimately leads to S(21) K . Ȧ (22) UU . (23) ij RESULTS OF SIMULATIONS OF PRESSURE DISTRIBUTION IN THE FRONT GAP OF A HYDROSTATIC BEARING – AN ANALYSIS Pressure was calculated in the front gap of a hydrostatic thrust bearing with water and with water emulsion AQUACENT LT 68. The basic physical parameters of these working liquids are presented in Table 4. Table 4. Parameters of the working liquids Parameter Unit Liquid ZDWHU ZDWHUHPXOVLRQ density kg/m 3 988,1 930 kinematic viscosity mm2/s 0,548 68 water contents % 100 41 The following input data were assumed in the computational model: Compression pressure S = 20 Mpa, The smallest front gap height hmin = 0.6·10-6 m in the hydrostatic thrust bearing, Inclination angle of the upper wall with respect to the lower one İ = 0.02º, Angular velocity of the upper wall Ȧ = 150 rad/s, Ratio of the external radius to the internal radius of the hydrostatic bearing UU = 3. The height K of the front gap was obtained from the following formula [24]: where: r ij į į angle measured with respect to the horizontal axis, –for this angle the height of the front gap is the smallest (in the xy plane). In variable-height gaps there are two zones near the point of the smallest height: the confusor zone and the diffuser zone. In the confusor zone the gap height decreases along the gap and overpressure occurs. In the diffuser zone, on the other hand, the gap height increases along the gap and negative pressure occurs, which is partly limited by the cavitation phenomenon [9]. An example of pressure distribution for water and the radius r = 0.011 [m] near the smallest height point in a hydrostatic bearing is presented in Fig. 4. Fig. 4. Circumferential pressure distribution of water near the smallest-height point at the radius r = 0.011 m A key parameter affecting the pressure of working liquids in a front gap is the kinematic viscosity factor. This can be seen very clearly in Fig. 5, where the values of the , (24) circumferential pressure in the hydrostatic bearing front gap are presented for water Ȟ mm2/s, ȡ kg/m3) and for water emulsion AQUACENT LT Ȟ mm2/s, ȡ kg/m3), i.e. for working liquids any radius within the plane of the point under which differ significantly with respect to kinematic – consideration, viscosity. It can be observed that the values of the circumferential pressure increase as the viscosity of the –current rotation angle, working liquid increases. angle measured with respect to the horizontal axis, –for this angle the height of the front gap is the ȡ ȡ Ȟ Ȟ ȡ ȡ $1$1$/<6,62)35(6685(',675,%87,21,1:$7(5$1':$7(5(08/6,21 Fig. 5. Circumferential pressure distribution of water and water emulsion near the smallest-height point at the radius r = 0.011 m In the interest of readability, in the graphs presented In the interest of readability, in the graphs presented below different scales are used on the vertical axis for water and for water emulsion. Fig. 6 presents circumferential pressure of water (Fig. 6a) and of water emulsion (Fig. 6b) in a confusor- water and for water emulsion. Fig. 6 presents circumferential pressure of water (Fig. 6a) and of water emulsion (Fig. 6b) in a confusorshaped gap of the hydrostatic bearing for various minimal gap heights. The Koverpressure peaks occurring in the gap PLQ are the greater, the smaller the gap is. Fig. 7 presents circumferential pressure of water (Fig. 7a) and water emulsion (Fig. 7b) in a front gap of the hydrostatic thrust bearing depending on the angle İof the upper wall inclination. İThe pressure drops in the gap with increase in the angle İ. Fig. 8 presents circumferential pressure of water (Fig. 8a) in a front gap of the hydrostatic thrust bearing and of water emulsion (Fig. 8b) depending on the angular velocity of the bearing upper wall. Here the pressure increases with increase in the angular velocity of the upper wall. KPLQ İ İ Fig. 6. Circumferential pressure distributions at the radius İ for various values of the smallest gap r = 0.011 m in a front gap height KPLQ for a) water, b) water emulsion Fig. 7 presents circumferential pressure of water İ İ Fig. 7. Circumferential pressure distributions at the radius r = 0.011 m in a front gap for various values of the upper wall inclination angle İfor a) water, b) water emulsion Fig. 8 presents circumferential pressure of water İ Fig. 8. Circumferential pressure distributions at the radius r = 0.011 m in a front gap for various values of the angular velocity Ȧ of the upper wall for a) water, b) water emulsion In the case of hydrostatic bearing with water as .215$'.2:$/6.,7$'(86==/272 Ȧ Fig. 9. Circumferential pressure distributions at the radius r = 0.011 m in a front gap for various values of the feeding pressure S1of the hydrostatic bearing for a) water, b) water emulsion The value of the circumferential pressure depends U U UU U U Fig. 10. Circumferential pressure distributions at the radius r = 0.011 m in a front gap for various dimensions of the hydrostatic bearing for: a) water, b) water emulsion Ȧ In the case of hydrostatic bearing with water as working liquid, the circumferential pressure in a front gap is significantly affected by the feeding pressure of the bearing. As the feeding pressure grows, the circumferential S pressure grows, too (Fig. 9 a). For water emulsion, however, the influence of the feeding pressure is negligible (Fig. 9 b). The value of the circumferential pressure depends also to a large extent on the dimensions of the hydrostatic bearing. Fig. 10 presents the circumferential pressure of water (Fig. 10a) and of water emulsion (Fig. 10b) in a front gap depending on the ratio of the external radius to the internal radius of the bearing. More specifically, in this study the external radius U was assumed to be constant and only the internal radius U varied to alter the size of the feeding chamber. For water, as the radius of the feeding chamber increases (so that the ratio UU decreases), the pressure grows in the gap. For water emulsion the opposite occurs: the greater the ratio UU, the greater the value of the pressure in the gap. suitable for determining liquid pressure distribution in a front gap of a hydrostatic bearing with a rotating upper wall. In the confusor zone near the smallest-height point the circumferential pressure increases. Its value depends on the dimensions and exploitation parameters of the bearing. The pressure is higher for water emulsion than for water due to higher viscosity of the former. In the confusor zone of the front gap there is an additional relief of the bearing caused by pressure increase. REFERENCES Hydraulika i &]HWZHUW\ĔVNL ( hydromechanika. PWN, Warszawa. 2. ([QHU+L LQ.HPSI+RSUDFRZDQLHLUHGDNFMD 0HFQHU : WáXPDF]HQLH Hydraulika. 3RGVWDZ\ HOHPHQW\ NRQVWUXNF\MQH L SRG]HVSRá\ Vademecum hydrauliki, Tom 1, Wydanie 3 poprawione. Bosch Rexroth Sp. z o.o., Polska. &]HWZHUW\ĔVNL ( *UHF]DQLN 7 6WU\F]HN - The concept of the S bus fluid power system of the mining machine. Polska CONCLUSIONS ([QHU+L LQ.HPSI+RSUDFRZDQLHLUHGDNFMD Akademia Nauk, Teka Komisji Motoryzacji 0HFQHU : WáXPDF]HQLH i Energetyki Rolnictwa, Tom V, 72-79, Lublin. The analyses presented above3RGVWDZ\ lead to theHOHPHQW\ followingNRQVWUXNF\MQH L SRG]HVSRá\ +DPD7.XULVX.0DWVXVKLPD.)XMLPRWR+ conclusions: 7DNXGD + Outflow Characteristics of a The computational model adopted in the study is Pressure Medium during Sheet Hydroforming, ISIJ suitable for determining liquid pressure distribution in - *UHF]DQLN 7 6WU\F]HN International, Vol. 49, Nr. 2, 239-246. a front gap of a hydrostatic bearing with a rotating ,YDQW\V\Q - ,YDQW\V\QRYD 0 Hydrostatic upper wall. U U +DPD7.XULVX.0DWVXVKLPD.)XMLPRWR+ 7DNXGD + UU *UHF]DQLN 7 6WU\F]HN - +DPD7.XULVX.0DWVXVKLPD.)XMLPRWR+ 7DNXGD + $1$1$/<6,62)35(6685(',675,%87,21,1:$7(5$1':$7(5(08/6,21 7. 8. 9. 20. 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Stryczek S. 1984:1DSĊGK\GURVWDW\F]Q\(OHPHQW\L XNáDG\:17:DUV]DZD Watton J. 2009: )XQGDPHQWDOV RI )OXLG 3RZHU &RQWURO&DPEULGJH8QLYHUVLW\3UHVV1HZ<RUN Zloto T. 2009:0RGHOOLQJWKHSUHVVXUHGLVWULEXWLRQLQ RLO ILOP LQ WKH YDULDEOH KHLJKW JDS EHWZHHQ WKH YDOYH SODWH DQG F\OLQGHU EORFN LQ WKH $ULDO SLVWRQ SXPS 3ROVND$NDGHPLD 1DXN 7HND .RPLVML 0RWRU\]DFML L (QHUJHW\NL5ROQLFWZD9RO 91U 11418-/XEOLQ Zloto T., Kowalski K. 2012:3UHVVXUHGLVWULEXWLRQVLQ RLO ILOP LQ WKH IURQW JDS RI D K\GURVWDWLF WKUXVW EHDULQJ 3ROLVK $FDGHP\ RI 6FLHQFHV %UDQFK LQ /XEOLQ 7HND &RPPLVVLRQ RI 0RWRUL]DWLRQ DQG (QHUJHWLFV LQ $JULFXOWXUH 9RO 12 1U 2 257- /XEOLQ Zloto T., Kowalski K. 2013: 2LO OHDNV LQWHQVLW\ LQ YDULDEOH-KHLJKW JDSV 3ROLVK $FDGHP\ RI 6FLHQFHV %UDQFK LQ /XEOLQ7HND &RPPLVVLRQ RI 0RWRUL]DWLRQ DQG(QHUJHWLFVLQ$JULFXOWXUH9RO 131U 2113- /XEOLQ 27. 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COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 53–58 Exploitation and Repair of Hydraulic Cylinders Used in Mobile Machinery Konrad Kowalski, Tadeusz Zloto Institute of Mechanical Technologies, Czestochowa University of Technology Al. Armii Krajowej 21, 42-201 Czestochowa, [email protected], [email protected] Received December 05.2014; accepted December 18.2014 Summary. +\GUDXOLFF\OLQGHUVDUHFRPPRQO\DSSOLHGLQPRbile machinery. They are prone to mechanical damage and wear due to atmospheric conditions. The paper presents selected issues related to the exploitation and repair of hydraulic cylinders. On the basis of practical experience, it offers an algorithm of actions to be undertaken in case of damage of a hydraulic cylinder. Key words: hydraulic cylinder, exploitation, repair, seals, mobile hydraulics machinery. INTRODUCTION 5HOLDEOHDQGÀDZOHVVRSHUDWLRQRIPDFKLQHVDQGGHvices depends on many factors, such as their technological advancement, conditions and type of operation, age, DVZHOODVIUHTXHQF\RIRYHUKDXOVDQGPDLQWHQDQFH>@ $QXPEHURIK\GUDXOLFV\VWHPVLQFOXGHK\GUDXOLFF\OLQders, whose function is to transform the energy of presVXUHLQWRPHFKDQLFDOHQHUJ\$W\SLFDOK\GUDXOLFF\OLQGHU performs a back-and-forth linear movement of a limited VWURNH>@+\GUDXOLFF\OLQGHUVKDYHQXPHURXVDSSOLFDWLRQVLQLQGXVWU\>@DQGLQPRELOHPDFKLQHV>@ such as excavators, loaders, backhoe loaders, dump cars, extension arms, cranes, tractors, refuse collection trucks, KDUYHVWHUVDQGRWKHUV)LJ+\GUDXOLFF\OLQGHUVDUH KRZHYHUSURQHWREUHDNGRZQV>@HVSHFLDOO\WKRVHXVHG in harsh and changeable working conditions. 2%-(&7,9(62)7+(678'< The aim of this paper is to offer some practical remarks concerning the exploitation of hydraulic cylinders with pistons and to present an algorithm of actions related to the repair of hydraulic cylinders used in mobile machinery. 7<3(6$1'&$86(62)%5($.'2:16 2)+<'5$8/,&&</,1'(56 2QHRIWKHPRVWIUHTXHQWO\HQFRXQWHUHGSUREOHPVLQ the exploitation of hydraulic cylinders is the loss of tightQHVVFDXVLQJOHDNVRXWVLGHDQGLQVLGHWKHF\OLQGHU>@7KH worn or damaged seals do not protect the interior of the cylinder from being contaminated by dirt, which increases the risk of a breakdown. It is thus of crucial importance to use appropriate wiper seals, with a wiper ring being in direct contact with the piston rod in order to collect all dirt accumulating on it as well as to collect dirt from the DLU%HFDXVHRIWKDWLWLVQHFHVVDU\WRWDNHLQWRDFFRXQWWKH UHTXLUHGFRQWDFWEHWZHHQWKHZLSHUVHDODQGWKHSLVWRQURG In order to ensure that the cylinder is leakage-tight inside, it is necessary to apply appropriate piston and piston rod seals, depending on the cylinder type (unidirectional or ELGLUHFWLRQDO +\GUDXOLFF\OLQGHUVDUHRSHUDWHGLQYDULRXVH[WHUQDOFRQditions. The part which is especially prone to breakdowns is the piston rod, which is directly exposed to atmospheric factors, such as water, snow, changing temperature and to GLUWSDUWLFOHVDQGVRRW>@DVZHOODVWRPHFKDQLFDOIDFWRUV When a long break in the cylinder operation is planned, the piston rod should be protected from the above mentioned IDFWRUV>@$GGLWLRQDOO\LWKDVWREHNHSWLQPLQGWKDW hydraulic cylinders are not suitable for transferring lateral ORDGV>@ +\GUDXOLFF\OLQGHUVDYDLODEOHRQWKHPDUNHWKDYHWKHLU strength parameters calculated with a certain safety margin. In some cases, however, it is advisable to check the piston rod against buckling, especially in the case of hydraulic cylinders with long strokes. The critical load level above which the piston rod undergoes buckling is obtained from (XOHU¶VIRUPXOD>@ ( ( -V V .215$'.2:$/6.,7$'(86==/272 Fig. 1. +\GUDXOLFF\OLQGHUVLQPRELOHPDFKLQHU\ గమ ா ܨ ൌ గమమா ܨ ൌ మೞ ೞ where: E ±<RXQJ PRGXOH RI WKH SLVWRQ URG PDWHULDO IRU VWHHO ( ā5 N/mm2 J±PRPHQWRILQHUWLDIRUWKHSLVWRQURGFURVVVHFWLRQ Q ) ls±IUHHEXFNOLQJOHQJWK Q ) $VVXPLQJWKHVDIHW\FRHI¿FLHQWDVn >@WKHPD[imal force F that can be transferred by the piston rod is: ி ೖೝ ܨൌ ிೖೝ ܨൌ Typicalofbreakdowns of hydraulic cylinders are presented Typical breakdowns hydraulic cylinders are presented in Fig. 2 in Fig. 2. Damaged parts of hydraulic cylinders are those that have cracks, cavities, deformations, seizures, and may be corroded to various extent. Fig. 2. Possible types of breakdowns of hydraulic cylinders (;3/2,7$7,21$1'5(3$,52)+<'5$8/,&&</,1'(5686(',102%,/(0$&+,1(5< 6($/6,1+<'5$8/,&&</,1'(56 sides, seals can contain components made of other materials to enhance their performance and applicability conditions $QXPEHURIW\SHVRIVHDOVDUHDSSOLHGLQK\GUDXOLFF\O- HJ3203(8+0:37)(EURQ]H $SDUWIURPWKDWZHDUEDQGVDUHXVHGLQK\GUDXOLFF\Oinders. They include wiper seals, piston seals, piston rod VHDOVJODQGVHDOVDQGVWDWLFVHDOV([DPSOHVRIW\SLFDOVHDOV inders to keep the piston and piston rod precisely along the LQK\GUDXOLFF\OLQGHUVDUHSUHVHQWHGLQ)LJ cylinder axis and to prevent contact between the metallic The main purpose of using seals is to ensure leak tight- VXUIDFHVRIWKHSLVWRQDQGF\OLQGHU>@:HDUEDQGV ness inside the cylinder and to protect it from external dirt DUHPDGHRISRO\R[\PHWK\OHQHSODVWRPHUHV320FKDUDFZLSHUV%HVLGHVVHOHFWLQJWKHVKDSHPDWHULDODQGWLJKW- WHUL]HGE\YHU\ORZJULQGLQJDELOLW\DQGVHOIOXEULFDWLRQ>@ ness of seals affects the magnitude of friction loss between the piston and the cylinder barrel and between the piston rod and the gland. If the seals are inappropriately chosen or 5(3$,5$1'5(129$7,212)+<'5$8/,& &</,1'(56 PRXQWHGWKHHQHUJ\ORVVFDQEHVLJQL¿FDQWXSWR>@ :KHQWKHORVVLVNHSWDWWKHPLQLPXPOHYHOWKHWRWDOHI¿FLHQ)LJSUHVHQWVDEORFNGLDJUDPRIUHSDLUVRIK\GUDXOLF F\RIDK\GUDXOLFF\OLQGHUFDQEHDWWKHOHYHORI·>@ The most popular static seals are O-rings, with V-rings cylinders. The user of the cylinder, referred to as “customer”, DQG;ULQJVIROORZLQJFORVHO\$PRQJG\QDPLFVHDOVIRU notices a breakdown and commissions the repair to a speSLVWRQVDQGSLVWRQURGVWKHPRVWSRSXODUDUHSDFNVHDOV cialised service. The servicing company accepts the com(chevron rings, including highly wear-resistant rubber-fabric mission and undertakes repair as agreed with the customer. VHDOVVHDOVZLWKDQWLH[WUXVLRQULQJVDVZHOODVVHDOVZLWK $IWHUWKHK\GUDXOLFF\OLQGHULVWUDQVSRUWHGWRWKHVHUYLFHLWLV wear rings and support rings. UHJLVWHUHGDQGSUHSDUHGIRUUHSDLU$WWKLVVWDJHWKHFXVWRPHU When selecting the right seals, one has to take into ac- VKRXOGEHQRWL¿HGDERXWWKHSUHGLFWHGGXUDWLRQRIUHSDLU FRXQWWKHNLQGRIZRUNLQJOLTXLGPLQHUDORLOQRQÀDPPDEOH OLTXLGVVRWKDWLWLVQHXWUDOWRZDUGVWKHVHDOPDWHULDO%H0($685(0(176$1'',$*126,6 sides, the seal has to be suitable for the operating pressure 2)7+(7(&+1,&$/&21',7,21 DQGWHPSHUDWXUH>@ Seals come in different cross-section and can be made of When the hydraulic cylinder is disassembled, its parts GLIIHUHQWPDWHULDOV>@VXFKDVSRO\XUHWKDQH and seals have to be diagnosed. It is recommended that all 738+38*38638ÀXRULQHUXEEHU)30VLOLFRQH measurements and tests should be performed twice, by two 094PHWK\OYLQ\OVLOLFRQHUXEEHUDQGHWK\OHQHSURS\OHQH different service workers. On the basis of the test results, the GLHQHUXEEHU(3'00RVWRIWHQKRZHYHUWKHPDWHULDOLV technical condition of the hydraulic cylinder can be assessed QLWULOHUXEEHU±1%5DFU\ORQLWULOHEXWDGLHQHUXEEHU%H- on the basis of the following criteria: Fig. 3. 6HDOVDSSOLHGLQK\GUDXOLFF\OLQGHUVDVWDWLFVHDOVEZLSHUVHDOVFSLVWRQURGVHDOVGSLVWRQVHDOV .215$'.2:$/6.,7$'(86==/272 ± :KHWKHULWLVIHDVLEOHWRUHSDLUWKHK\GUDXOLFF\OLQGHU depends on economic and technological considerations. ± &RPSRQHQWVPDGHRIFDVWLURQRUVWHHOFDVWLQJPD\KDYH FUDFNVZKLFKPDNHVWKHPXQVXLWDEOHIRUUHSDLU>@ ± +\GUDXOLFF\OLQGHUVGLVSOD\LQJKLJKGHJUHHRIZHDURU damage, with such symptoms as seizing, deep corrosion, deep cracks, deformations, cavities, etc. are considered QRWVXLWDEOHIRUUHSDLU$QH[FHSWLRQFDQEHPDGHIRU untypical designs, in which case the repair cost will be lower than the cost of producing a replacement cylinder. For instance, in the case of cast hydraulic cylinders with extensive damages, a solution preferred to producing a new cylinder on economic and technological grounds ZLOOEHEXVKLQJ>@ ± 5HSDLULVWKHRSWLPXPVROXWLRQIRUK\GUDXOLFF\OLQGHUV with low degree of damage (scratches, small traces of FRUURVLRQ ± +LJKO\GDPDJHGSLVWRQURGVDUHW\SLFDOO\UHSODFHGE\ new ones. ± 7KH¿QDOGHFLVLRQRQZKHWKHUDK\GUDXOLFF\OLQGHULV VXLWDEOHIRUUHSDLURUQRWLVWDNHQE\TXDOL¿HGSHUVRQQHO on the basis of technical and economic considerations. ,IDFXVWRPHUUHTXHVWVWREHFRQVXOWHGDIWHUWKHK\GUDXlic cylinder is diagnosed, they should be informed about the technical condition and recommendations concerning the repair. With the customer’s acceptance, the servicing company can undertake work. 5(3$,52)$+<'5$8/,&&</,1'(5 7KH¿UVWVWHSLVWRUHPRYHGLUWIURPDOOVXUIDFHV7KH hydraulic cylinder is rinsed with a cleaning agent at a special stand, with a container to collect the used agent. The cleaning agent is petroleum ether, which is sprayed with an airbrush. Then, the hydraulic cylinder is wiped with a soft, white cotton cloth. It is essential that the cloth must not leave DQ\¿EUHVRQWKHF\OLQGHU$IWHUWKDWWKHSDUWVVKRXOGEH moved to the place allocated for the repair. Then, depending on the diagnosis, the piston and/or piston rod can undergo grinding, chromium plating, and polishing. Similarly, the cylinder surface can be subject to chromium plating and honing. The next stage is making grooves for wear bands DQGSURFHVVLQJWKHFROODULIQHFHVVDU\$IWHUWKDWDSSURSULDWH seals and wear bands have to be selected. $66(0%/< $IWHUWKHUHSDLULVFRPSOHWHDQGWKHVHDOVDQGZHDUEDQGV are chosen, the hydraulic cylinder is to be reassembled from its parts. It is essential that no dirt or other contaminants get into the cylinder. The piston, piston rod, and cylinder have WREHOXEULFDWHGZLWKDWKLQ¿OPRIK\GUDXOLFRLO6HDOVDUH PRXQWHGE\PHDQVRIVSHFLDOSOLHUV)LJZLWKVPRRWK surfaces. Still, special care has to be taken not to damage the VHDOVRUVFUDWFKWKHVHDOHGVXUIDFHV$OD\HURIPHWDOERQG- Fig. 4. $OJRULWKPIRUUHSDLURIDK\GUDXOLFF\OLQGHUE\DVSHFLDOLVHGFRPSDQ\ (;3/2,7$7,21$1'5(3$,52)+<'5$8/,&&</,1'(5686(',102%,/(0$&+,1(5< LQJJOXHHJ/RFWLWHLVWKHQDSSOLHGRQWKHSLVWRQ rod-piston screw joint. Depending on the construction, DOD\HURIUHWDLQHUHJ/RFWLWHVKRXOGEHDSSOLHGRQ co-axial joints. The piton has to be screwed on the piston rod and the joint is to be protected with a lock-nut. Then, WKHSLVWRQSLWRQURGFRXSOHLVLQVHUWHGLQWKHF\OLQGHU$IWHU the assembly, a pressure test should be performed with great care. Optionally, the external surface can be coated with paint to improve its appearance. used within a limited period of time, typically up to two years. otherwise rubber hardens and loses its sealing properties. With appropriate machines and practical experience at one’s disposal, it is possible to repair hydraulic cylinders without hiring a professional help. This is feasible, however, when the repair involves a minor issue, such as replacing seals. In the case of major overhauls and repairs, it is much more advisable to hire a specialised company. 5()(5(1&(6 Cundiff J.S. 2002: Fluid Power Circuits and Controls. )XQGDPHQWDOV DQG$SSOLFDWLRQV &5& 3UHVV %RFD Raton. 2. Greczanik T., Stryczek J. 2005: The concept of the EXVÀXLGSRZHUV\VWHPRIWKHPLQLQJPDFKLQH3ROVND $NDGHPLD1DXN7HND.RPLVML0RWRU\]DFMLL(QHUJHW\NL Rolnictwa; V, 7279, Lublin. Kotnis G. 2008:%XGRZDLHNVSORDWDFMDXNáDGyZK\GUDXOLF]Q\FKZPDV]\QDFK:\GDZQLFWZR.D%H.URVQR .UyO5=LPUR]56WRODUF]\Nà$QDOL]DDZDU\MQRĞFLXNáDGyZK\GUDXOLF]Q\FKVDPRMH]GQ\FKPDV]\Q URERF]\FKVWRVRZDQ\FKZ.*+03ROVND0LHGĨ6$ Fig. 5. Pliers for mounting seals 3UDFH1DXNRZH,QVW\WXWX*yUQLFWZD3ROLWHFKQLNL:URFáDZVNLHM6WXGLDLPDWHULDá\ 75$163257,1*7+(5(3$,5('&</,1'(5 Lipski J. 1981:1DSĊG\LVWHURZDQLDK\GUDXOLF]QH:\GDZQLFWZD.RPXQLNDFMLLàąF]QRĞFL:DUV]DZD If the hydraulic cylinder passes the pressure test, the 2NXODUF]\N:5HJHQHUDFMDVLáRZQLNyZSQHXPDW\F]Q\FK+\GUDXOLNDL3QHXPDW\ND RUL¿FHVKDYHWREHSURWHFWHGE\SOXJVDQGWKHK\GUDXOLFF\Oinder can be prepared for transport. It is necessary to provide 7. 2VLHFNL$+\GURVWDW\F]Q\QDSĊGPDV]\Q:\dawnictwa Naukowo-Techniczne, Warszawa. a packaging that protects it from damage during transport. Together with a repaired hydraulic cylinder, the customer 8. Rabie M.G. 2009:)OXLG3RZHU(QJLQHHULQJ0F*UDZshould also be provided with instructions for storing the +LOO1HZ<RUN hydraulic cylinder. 9. Rusin A., Wojaczek A. 2007: Selection of Maintenance When the customer does not intend to use the repaired 5DQJHIRU3RZHU0DFKLQHVDQG(TXLSPHQWLQ&RQVLGhydraulic cylinder within a short period of time, it is advisHUDWLRQRI5LVN(NVSORDWDFMDL1LH]DZRGQRVF±0DLQWHQDQFHDQG5HOLDELOLW\ DEOHWRSURWHFWLWIURPFRUURVLRQE\¿OOLQJLWZLWKK\GUDXOLF oil and by covering the piston rod with a thick grease. Ryzhakov$Nikolenko I., Dreszer K. 2009: Selection of discretely adjustable pump parameters for hydraulic GULYHVRIPRELOHHTXLSPHQW3ROVND$NDGHPLD1DXN CONCLUSIONS 7HND.RPLVML0RWRU\]DFMLL(QHUJHW\NL5ROQLFWZD7RP ,;/XEOLQ The algorithms of actions to be undertaken in case of ĩDELFNL''REyULHNVSORDWDFMDVLáRZQLNyZK\hydraulic cylinder breakdowns and repairs is universal and GUDXOLF]Q\FK8WU]\PDQLHUXFKX can be applied for any hydraulic cylinder, including those ĩDELFNL'8V]F]HOQLHQLD,QĪ\QLHULDL8WU]\DSSOLHGLQLQGXVWU\HJLQK\GUDXOLFSUHVVHV PDQLH5XFKX=DNáDGyZ3U]HP\VáRZ\FKKWWSZZZ If the operating temperature of the hydraulic cylinder is utrzymanieruchu.pl/menu-gorne/artykul/article/uszczelKLJKWKHHIIHFWRIWHPSHUDWXUHRQWKHZRUNLQJOLTXLGDQG QLHQLD>DFFHVV@ on other parts, especially rubber seals, has to be taken into KWWSZZZKHQQOLFKSOXSORDGV.DWDORJB8V]F]HOQLHaccount. QLDBSGI>DFFHVV@ The parts that are worn or damaged should be repaired, KWWSZZZK\GURFRPSOUHVGRFBEB if possible. If not, such parts must be replaced by new ones. .DWDORJBXV]F]HOQLHBBBBSGI>DFFHVV@ Whenever a hydraulic cylinder undergoes repair, all seals KWWSZZZVNIFRPELQDU\B(1 must be replaced by new ones. +\GUDXOLFVHDOVSGI>DFFHVV@ Rubber seals mounted in a hydraulic cylinder can work for years, whereas seals stored in inventories have to be .215$'.2:$/6.,7$'(86==/272 (.63/2$7$&-$,5(*(1(5$&-$6,à2:1,.Ï: +<'5$8/,&=1<&+:02%,/1<&+0$6=<1$&+ 52%2&=<&+ Streszczenie. 6LáRZQLNLK\GUDXOLF]QHVąSRZV]HFKQLHVWRVRZDQHZPDV]\QDFKK\GUDXOLNLPRELOQHM=HZ]JOĊGXQDSUDFĊ Z]PLHQQ\FKZDUXQNDFKQDUDĪRQHVąRQHQDXV]NRG]HQLDPH- FKDQLF]QHRUD]G]LDáDQLHF]\QQLNyZDWPRVIHU\F]Q\FK:SUDF\SU]HGVWDZLRQRDVSHNW\]ZLą]DQH]LFKXĪ\WNRZDQLHPRUD] UHJHQHUDFMą:RSDUFLXRSUDNW\F]QHGRĞZLDGF]HQLDSU]HGVWDZLRQRDOJRU\WPSRVWĊSRZDQLD]XV]NRG]RQ\PLVLáRZQLNDPL hydraulicznymi. 6áRZDNOXF]RZHVLáRZQLNK\GUDXOLF]Q\HNVSORDWDFMDUHJHneracja, uszczelnienia, hydraulika mobilna, maszyna robocza. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 59–64 Application of the Computation Procedure in Bayesian Network in Estimation of Total Cost of Natural Stone Elements Production Andrzej Kusz, Jacek Skwarcz, Mateusz Gryczan Department of Technology Fundamentals, University of Life Sciences, ul. Doświadczalna 50A, 20-280 Lublin, Poland, e-mail: [email protected] Received December 01.2014; accepted December 17.2014 Summary. In the course of data collection and processing, an essential role is played by computation processes which can be performed automatically. Moreover, these processes should naturally allow for uncertainties. The article presents such a process UHDOL]HGZLWKWKHDLGRI%D\HVQHWZRUNWHFKQLTXH7KHPRGHO enables the user to monitor the total production cost of elements which are made of natural granite stone. Inference mechanisms built into the system make it possible to retrieve the information necessary for a rational production management. The basis for estimation is an approach based on a probability distribution GH¿QHGRYHUDVHWRIYDOXHVRIGHFLVLRQYDULDEOHVUHSUHVHQWLQJ parameters of the production process. It has been shown how to carry out a simulation research in a range of situations where inference mechanisms are applied. Key words: production process, natural stone, granite, compuWDWLRQSURFHVVHVSURGXFWLRQFRVWV%D\HVLDQQHWZRUNV INTRODUCTION *UDQLWHPDFKLQLQJSURFHVVFRQVLVWVRIPDQ\RSHUDWLRQV affecting the overall course of the process as well as the ¿QDOHIIHFW(DFKRSHUDWLRQLVDQLQWHJUDOSDUWRIWKHHQWLUH process, having an impact on the other stages of the process, or it is determined by them. It is not possible to determine causal links without the knowledge of proper complete FRXUVHRIWKHSURFHVV>@6WUXFWXUDOQRQKRPRJHQHLW\ high variability of process parameters burdened with randomness, justify treating the process components as random variables and a probabilistic model as a natural way of representing them. The necessity of taking uncertainty present in the proFHVVLQWRFRQVLGHUDWLRQPDNHV%D\HVLDQQHWZRUNDXVHIXO system of knowledge representation, when it is needed to clearly encode an uncertainty factor and understanding issue in terms of nondeterministic cause-effect relations. These network capabilities can be employed in creating production process predictability. The possibility of automation of data collection process, DVZHOODVRIGDWDSURFHVVLQJLVDQHVVHQWLDODVSHFW> 9] whereas the computation processes are performed automatically basing on advanced cognitive modelling systems. The process stages and the states of objects used in specific processes are known within the accuracy of probability GLVWULEXWLRQ&RJQLWLYHPRGHOOLQJFDQEHEDVHGRQ%D\HVLDQ QHWZRUNWHFKQLTXH $QLPSRUWDQWFRPSXWDWLRQSURFHVVLQWHFKQLFDOV\VWHPV engineering, which needs to be embedded in the system, is the possibility of monitoring production costs. It is a multidimensional process, which refers to entire systems, their FRPSRQHQWVVXEV\VWHPVDQG¿QDOO\VSHFL¿FJURXSVDQG machine types. Production cost optimization forms the JURXQGZRUNIRUHIIHFWLYHWHFKQLFDOV\VWHPVXWLOL]DWLRQ(Qtire production cost estimation, based on the information obtained from database, allows comparing the technology of a particular production process to other production technologies. Computational procedures are based on a deterministic DSSURDFKLQFOXGLQJ¿QDQFLDOUDWLRPHWKRGV $QDOWHUQDWLYHDSSURDFKLVWKHDSSURDFKEDVHGRQ%D\HVLDQQHWZRUN6XFKDQDSSURDFKLVMXVWL¿HGE\WKHXQFHUWDLQW\ factor which is integrally related to production process. The essence of the offered approach is that each cost component and the factors which determine its size are represented by random variables. %D\HVLDQQHWZRUNKDVPDQ\DSSOLFDWLRQVZKHUHLWLV QHHGHGWRH[SOLFLWO\HQFRGHXQFHUWDLQW\FRHI¿FLHQWDQGUHDVRQLQJLQWHUPVRIQRQGHWHUPLQLVWLFFDXVDOOLQNUHODWLRQV> @7KH\DUHWKHUHIRUHDXVHIXOWRROWRPRGHOXQFHUWDLQWLHVLQSURGXFWLRQSURFHVVHV>@SUHGLFWDELOLW\RIWHFKQLFDOREMHFWVEHKDYLRU>@FRPSXWHUDLGHG GHFLVLRQPDNLQJSURFHVVHV>@DQGWRH[SUHVVUHOLDELOLW\ NQRZOHGJHERWKLQWHUPVRISUDFWLFDODSSURDFK>@DV ZHOODVIRUWKHRUHWLFDODQDO\VHVSXUSRVHV>@ $QRWKHU¿HOGRIDSSOLFDWLRQRIWKH%D\HVLDQQHWZRUNLV WKHSUREOHPRIFRPSOH[ÀRZFKDUWPDQDJHPHQW>@ $1'5=(-.86=-$&(.6.:$5&=0$7(86=*5<&=$1 The aim of this study is to present a conceptualization method of computation process realizing a problem LQ%D\HVLDQQHWZRUNODQJXDJHE\LOOXVWUDWLQJLWZLWKDQ example of estimation of the total cost of natural stone JUDQLWH HOHPHQWV PDFKLQLQJ SURFHVV$Q DVVXPSWLRQ has been made during designing the model, according to which the process components are represented as random YDULDEOHV%D\HVLDODESURJUDPZDVXVHGLQEXLOGLQJWKH model. This environment has built-in inference mechanisms allowing the model to operate as a prognostic and explanatory system. 02'(/&21&(37,21$1'6758&785( Natural stone machining process modelling is based on the analysis of the granite features which are important in terms of modelling, and the machining process elements ZKLFKLQÀXHQFHGLIIHUHQWFRVWVDVZHOODVRSHUDWLQJVXSHUYLVLQJWLPH)DFWRUVZKLFKLQÀXHQFHWKHFRVWDQGRSerating-supervising time have been presented as variables DQGWKHLUYDOXHVLPSOHPHQWHGLQ%D\HVLDODEHQYLURQPHQW >@7KHYDULDEOHVDUHUHSUHVHQWHGE\QRGHVDQGWKHLUODbels correspond to the process component represented by DVSHFL¿FQRGH,WKDVEHHQDVVXPHGWKDWYDULDEOHVYDOXHV can be continuous within a given range or they can be of a discrete type. Cause-effect relations are represented by DUFV7KH\UHÀHFWUHODWLRQVZKLFKWDNHSODFHLQWKHPRGHOOHG SURFHVV6XEVHTXHQWO\DSULRULSUREDELOLW\GLVWULEXWLRQVKDYH EHHQDVVLJQHGRYHUWKHUDQJHRIYDULDEOHYDOXHVGH¿QLQJ distribution type and its values. Nodes can be divided into certain groups representing GLIIHUHQWDVSHFWVRIWKHPRGHOOHGSURFHVV$OOPRGHOHOHments have values and probability distributions assigned to them and basing on those, values of other variables are determined by arithmetic operations or logical operators. $OD\HUGHVFULELQJWKHIHDWXUHVRIWKHZRUNSLHFHLVGLVtinguished in the network. Variables representing density, WKLFNQHVVDQGOHQJWKRIPDFKLQHGPDWHULDOJUDQLWHDVZHOO DVPDFKLQLQJTXDOLW\EHORQJWRWKLVOD\HU7KHPDFKLQHG material density is an essential variable in natural stone machining process. It depends on the percentage of each mineral which the natural stone is composed of. The main minerals which granite consists of are: orthoclase, plagiRFODVHTXDUW]ELRWLWHDQGDZKROHVHULHVRIRWKHUPLQHUDOV LQWUDFHDPRXQWV*UDQLWHGHQVLW\KDVDQLPSDFWRQXQLWDU\ cutting tool consumption cost and feed rate. In the model, density is represented by a discrete random variable, which can have three values: low, average and high. Low density LVZLWKLQWKHLQWHUYDOIURPNJP3XSWRPD[NJ m3HJ.DVKPLU:KLWHJUDQLWHZKRVHGHQVLW\LVNJ m37KHDYHUDJHGHQVLW\EHJLQVIURPDERYHNJP3 up to 2800 kg/m3. This interval contains most granite, including: ,PSDODNJP36WU]HJRPNJP39DQJDNJ m3. The high density category ranges from 2800 kg/m3 up WRNJP3. This density group consists of the following JUDQLWHV$]XO3ODWLQRNJP3, New Impal Red 2820 kg/ m36WDU*DOD[\NJP3. These intervals include almost all granite densities. Thickness of the machined granite workpiece is another continuous variable which was considered in the model. The workpiece thickness is based on a client’s own taste, as well as on assembly and design capabilities. It was assumed that WKLVYDULDEOHUDQJHVIURPPPWRPP The variable length of the workpiece represents the sum of its side lengths. This variable is used to estimate the cycle time of machining the workpiece surface. It is DFRQWLQXRXVYDULDEOHDQGLWFDQKDYHYDOXHVIURPPP WRPP 7KHTXDOLW\RIWKHPDFKLQLQJSURFHVVLVDYDULDEOHZKLFK UHSUHVHQWVDFOLHQW¶VH[SHFWDWLRQVFRQFHUQLQJWKH¿QDOSURGXFWTXDOLW\0DFKLQLQJSDUDPHWUHVDQGUHTXLUHGQXPEHU RIF\FOHVDUHGHWHUPLQHGE\GH¿QLQJDTXDOLW\FODVV,WLV DVVXPHGLQWKHPRGHOWKDWWKHYDULDEOHUHSUHVHQWLQJTXDOLW\ is a discrete variable and it can take three different values: high, average and economic. The cutting disc feed rate is FKRVHQDFFRUGLQJWRWKHUHTXLUHGTXDOLW\6ORZFXWWLQJGLVF feed decreases labour consumption during the process of polishing. The workpiece surface is a continuous-type variable and its values are found as the product of length and thickness variables. This variable can take values from the interval from 0,2 m2PLQLPDOYDOXHWRP2PD[LPDOYDOXH The value of this variable impacts on intensity of cutting tool consumption. The machined surface, after polishing, must XQGHUJRSUHVHUYDWLRQDQGJORVV¿QLVKWUHDWPHQW )HHGUDWHLVGHWHUPLQHGE\WKHTXDOLW\UHTXLUHGDVZHOO as by density of the workpiece. Its precise value is found using a logical formula. It was assumed that the values of the variable have normal distributions, an expected value of distribution corresponds to a particular rate and standard GHYLDWLRQLV)HHGUDWHLVDYDULDEOHZKLFKGHWHUPLQHV cycle time. $QRWKHUSURFHVVSDUDPHWHULVWKHQXPEHURIF\FOHV,W GHSHQGVRQWKHGHFODUHGTXDOLW\DQGLWLVF\FOHVIRUHFRQRPLFTXDOLW\IRUDYHUDJHTXDOLW\DQGLQFDVHRIKLJK TXDOLW\ Water consumption in machining process is evaluated in the model as the product of unitary water consumption per minute related to the machining time. It was assumed that the variable of unitary water consumption per minute LVDFRQWLQXRXVYDULDEOHDQGLWUDQJHVIURPOPLQ Other variables enable estimation of operation time and their costs. They are continuous variables which represent: unitary machining cycle time, workpiece machining time, cutting tool exchange time and worker’s work WLPH8QLWDU\PDFKLQLQJF\FOHWLPHHTXDOVDFRPSOHWH F\FOHWLPHRISROLVKLQJPDFKLQHRSHUDWLRQ$ZRUNSLHFH machining time is estimated on the basis of information represented by nodes: workpiece length, cutting disc feed rate. In this manner, we obtain probability distributions over a set of estimated possible machining time values. ([WHQGLQJPDFKLQLQJWLPHKDVDVLJQL¿FDQWLPSDFWRQ WKH¿QDOFRVWVLQFHZRUNORDGZDWHUDQGHOHFWULFLW\FRQsumption increase. Cutting tool exchange time is a variable whose values depend on the worker’s experience, abilities, manual and motor coordination skills. In the model, this time $33/,&$7,212)7+(&20387$7,21352&('85(,1%$<(6,$11(7:25. LVUHSUHVHQWHGE\DFRQWLQXRXVYDULDEOHRIPLQ $ZRUNHU¶VZRUNWLPHLVDYDULDEOHHYDOXDWHGE\WKHVXP RIDZRUNSLHFHPDFKLQLQJWLPHDQGWKHWLPHUHTXLUHGIRU FXWWLQJWRROVH[FKDQJH7KLVYDULDEOHFDQUDQJHIURP WRPLQXWHV The last group of variables considered in the model, are the variables which represent costs. Costs represent TXDQWLWDWLYHH[SHQGLWXUHFRUUHVSRQGLQJWRWKHUHDOL]DWLRQ RIDVSHFL¿FYHUVLRQRIVWRQHPDFKLQLQJSURFHVV7KH\LQclude: unitary cutting tool consumption cost, preservation DQGJORVV¿QLVKFRVWDVZHOODVHYDOXDWHGFRQVXPSWLRQFRVWV RIFXWWLQJWRROV¿QLVKLQJHOHPHQWVZDWHUHQHUJ\XWLOLWLHV and labour. The range of each variable was either assigned or evaluated, according to possible versions of the process and current prices. 7KH¿QDOYDULDEOHLQWKHPRGHOLVDFRQWLQXRXVYDULDEOH representing the total cost of machining a single workpiece. The total cost is evaluated as the sum of values of three QRGHV¿QLVKLQJHOHPHQWVFRVWXWLOLWLHVFRVWDQGODERXUFRVW The node shows probability distribution over a set of cost values which can be reached during the machining process of natural stone. $JUDSKLFDOIRUPRIWKHFRQFHSWXDOL]DWLRQSUHVHQWHG above, and at the same time, the structure of a network allowing for the estimation of a single workpiece machining FRVWLQ%D\HVLDQQHWZRUNWHFKQLTXHKDVEHHQVKRZQLQ WKH)LJ7KHYDULDEOHVXVHGLQFRPSXWDWLRQVUHSUHVHQWing machined pieces features, machining parameters, times DQGDOOFRQVWLWXHQWFRVWVDUHUHSUHVHQWHGE\HTXDOO\QDPHG variables in the network. Probability distributions over sets of the variables considered in the model are illustrated in a graphical form in the Fig. 2. (67,0$7,212)727$/*5$1,7((/(0(176 PRODUCTION COST )RUWKHSXUSRVHRIYHUL¿FDWLRQRIWKHPRGHODFRPSXWDtion concerning machining process of natural granite stone elements has been carried out. Inference mechanisms, typLFDOLQ%D\HVLDQQHWZRUNVZHUHDSSOLHGLQWKHYHUL¿FDWLRQ The standard mechanism of the network working (preGLFWLRQRIWKHFRQVHTXHQFHVRIGHFLVLRQVSURYLGHVWKHSURFHVVWRWDOFRVWDFFRUGLQJWRWKHZRUNSLHFHIHDWXUHVTXDOLW\ UHTXLUHPHQWVDQGRSHUDWRU¶VFRPSHWHQFH In the analyzed problem, it has been assumed that the YDULDEOHVWKHZRUNSLHFHOHQJWK±RIPPDFKLQLQJ TXDOLW\±DYHUDJHFXWWLQJWRROH[FKDQJHWLPHRIPLQ ZDJHUDWHDFFRUGLQJWRFDWHJRU\HTXDOV]áSHUPLQXWH the number of cycles is 27, and unitary water consumption KDVEHHQ¿[HGDWOLWUHVSHUPLQ7KHWRWDOFRVWKDVEHHQ HYDOXDWHGIRUWKHZRUNSLHFHWKLFNQHVVRIPDQGYDULRXV GHQVLW\YDOXHVORZ$DYHUDJH%KLJK&&RPSXWDWLRQ results as probability distribution over a set of total cost YDOXHVKDYHEHHQSUHVHQWHGLQWKH)LJ The above calculations were repeated, assuming the ZRUNSLHFHWKLFNQHVVWRHTXDOP&DOFXODWLRQVUHVXOWV DUHSUHVHQWHGLQWKH)LJ,QWKH¿UVWFDVHWKLFNQHVVRI PWKHORZHVWWRWDOFRVWZDVREWDLQHGIRUWKH low density of the workpiece, and the highest for the high GHQVLW\DQGDPRXQWVWR]á,WVKRXOGEHQRWHGWKDW LQFDVHRIORZGHQVLW\ZLWKSUREDELOLW\RIDSRVVLEOH RXWFRPHRIFRVWVFDQUDQJHIURPWR]á:KHUHDV in case of high density, the total cost can take values from LQWHUYDOV]áSUDFWLFDOO\ZLWKHTXDOSUREDELOLW\UHVSHFWLYHO\ )RUDYHUDJHZRUNSLHFHGHQVLW\WKHWRWDOFRVWLV]á Fig. 1. Network structure used for estimation of natural stone machining process cost $1'5=(-.86=-$&(.6.:$5&=0$7(86=*5<&=$1 Fig. 2. Probability distributions over random variable values $ % & $ % & Fig. 3. 7RWDOFRVWWKLFNQHVVGHSHQGLQJRQWKHGHQVLW\RIWKHPDFKLQHGVWRQH Fig. 4. 7RWDOFRVWWKLFNQHVVGHSHQGLQJRQWKHGHQVLW\RIPDFKLQHGVWRQH $33/,&$7,212)7+(&20387$7,21352&('85(,1%$<(6,$11(7:25. For the variable ‘workpiece thickness’ at the value of WKHWRWDOFRVWREWDLQHGZDVIRUORZGHQVLW\ IRUWKHDYHUDJHDQGIRUWKHKLJK,QWKLVFDVH the knowledge of probability distribution allows for estimating the chance of getting a desired value of the total cost. The diagnostic inference mechanism available in the network is useful in a situation when we want to determine FRQGLWLRQVWKDWPXVWEHVDWLV¿HGLQRUGHUWRDFKLHYHWKH DVVXPHGOHYHORIWKHWRWDOFRVW)LJVKRZVSRLQWVZKLFK FRUUHVSRQGWRFRQVWDQWWRWDOFRVWV.B DQG.B GHSHQGLQJRQWKLFNQHVVDQGOHQJWKRIWKHZRUNSLHFH Fig. 5. Points corresponding to constant total costs of machining process depending on thickness and length of the workpiece The working scheme of the model shown above can be applied to estimation of other cost components. Information possible to obtain by simulation experiments is of a great practical importance and can be used in the natural stone element production management. CONCLUSIONS The procedure of estimating the total cost of natural VWRQHPDFKLQLQJZKLFKLVLPSOHPHQWHGLQ%D\HVLDQQHWwork, is an example of a computation process which can be entirely automated by virtue of embedded inference mechanisms. The convenience of input data which can be formed arbitrarily basing on available resources and predicted proGXFWLRQFRQGLWLRQVDFFRXQWIRULWVVLJQL¿FDQWLPSRUWDQFH at the stage of design, planning, monitoring and analysis of production process with reference to natural stone elements LQVSHFL¿FFRQGLWLRQRIUHDOL]DWLRQ Prognostic inference allows for analysing all possible YHUVLRQVGHSHQGLQJRQPRGHOLQSXWYDULDEOHV$VHWRIDFceptable solutions can be determined, accurate to probability distribution. For expected values of the terminal variable (in WKLVFDVHIRUWRWDOSURGXFWLRQFRVWK\SRWKHWLFRGHGXFWLYH LQIHUHQFHWHPSRUDOEDFNZDUGSURMHFWLRQIDFLOLWDWHVZLWK an accuracy of probability distribution, determination of UHTXLUHPHQWVUHJDUGLQJYDULDEOHVUHSUHVHQWLQJHDFKFRVW component and variables describing features of the workpiece, as well as machining process parameters. Machine learning mechanisms which are available in WKHV\VWHP>@IDFLOLWDWHDGDSWDELOLW\RIWKHPRGHOERWK LQWHUPVRIWRSRORJ\DGMXVWLQJWKHPRGHOWRREMHFWW\SHV as well as in determination of a priori probability distributions. 5()(5(1&(6 %DUORZ5(8VLQJLQÀXHQFHGLDJUDPV,Q&ODURWWL &$/LQGOH\'9HGLWRUV$FFHOHUDWHGOLIHWHVWLQJDQG H[SHUWV¶RSLQLRQVLQUHOLDELOLW\ 2. Bartnik G., Kalbarczyk G. and Marciniak A. W.2011. $SSOLFDWLRQRIWKHRSHUDWLRQDOUHOLDELOLW\PRGHOWRWKH risk analysis in medical device production. Teka, Vol. ;,& Bartnik G., Kusz A. and Marciniak A. 2006. Dynamiczne sieci bayesowskie w modelowaniu procesu HNVSORDWDFMLRELHNWyZWHFKQLF]Q\FK,QĪ\QLHULD:LHG]\ L6\VWHP\(NVSHUWRZH2¿F\QD:\GDZQLF]D3ROLWHFKQLNL:URFáDZVNLHMW,, Bartnik G. and Marciniak A. W. 2011. Operational UHOLDELOLW\PRGHORIWKHSURGXFWLRQOLQH7HND9RO;,& Berners-Lee T., Karger D.R., Stein L.A., Swick R.R., Weitzner D.J. Proposal: Semantic Web Development 5HWULHYHGIURP:& %HUQHUV/HH+HQGOHU-/DVVLOD2The SemanWLF:HE6FLHQWL¿F$PHULFDQ 7. Chmielecki A. 2004. Konceptualne podstawy kogniW\ZLVW\NL±NU\W\NDLSURSR]\FMHZáDVQH6]F]HFLQ9,, =MD]G)LOR]R¿F]Q\ 8. &KXQ6X<HTXQ)X5HOLDELOLW\$VVHVVPHQWIRU :LQG7XUELQHV&RQVLGHULQJWKH,QÀXHQFHRI:LQG6SHHG 8VLQJ%D\HVLDQ1HWZRUN(NVSORDWDFMDL1LH]DZRGQRVF ±0DLQWHQDQFHDQG5HOLDELOLW\± 9. Cost S., Finin T., Joshi A. 2002$&DVH6WXG\LQWKH 6HPDQWLF:HEDQG'$0/2,/,(((,QWHOOLJHQW6\Vtems. 'RNXPHQWDFMDSURJUDPX%D\HVLD/DEKWWSZZZED\HVLDFRP 'RJXF2DQG5DPLUH]0DUTXH]-($JHQHULF PHWKRGIRUHVWLPDWLQJV\VWHPUHOLDELOLW\XVLQJ%D\HVLDQ QHWZRUNV5HOLDELOLW\(QJLQHHULQJDQG6\VWHP6DIHW\ +DOSHUQ-< Reasoning about uncertainty. The MIT Press Cambridge, Massachusetts, London. +RáDM+.XV]$0DNV\P30DUFLQLDN$: Modelowanie problemów decyzyjnych w integrowaQ\PV\VWHPLHSURGXNFMLUROQLF]HM,QĪ\QLHULD5ROQLF]D .RFLUD6.XERĔ0The operating costs machines and general type of farming. Roczniki Naukowe 6WRZDU]\V]HQLD(NRQRPLVWyZ5ROQLFWZDL$JUREL]QHVX 6(5L$7RP;,,,=HV]\W Kusz A., Maksym P., Marciniak A. W. 2011.%D\HVLDQ networks as knowledge representation system in domain RIUHOLDELOLW\HQJLQHHULQJ7HND9RO;,& .XV]$0DNV\P36NZDUF]-*UXG]LĔVNL- The representation of actions in probabilistic networks. 7HND9RO;,, $1'5=(-.86=-$&(.6.:$5&=0$7(86=*5<&=$1 Kusz A., Marciniak A.W. 2010. Modelowanie niezaZRGQRĞFL]áRĪRQ\FKV\VWHPyZELRDJURWHFKQLF]Q\FK ,QĪ\QLHULD5ROQLF]D Maksym P. 2011. Podstawowe zasady modelowania SURFHVXSURGXNFMLUROQLF]HM,QĪ\QLHULDUROQLF]D, Maksym P., Marciniak A. W., Kostecki R. 2006. =DVWRsowanie sieci bayesowskich do modelowania rolniczego SURFHVXSURGXNF\MQHJR,QĪ\QLHULD5ROQLF]D 20. Maksym P., Marciniak A. W., Kusz A. 2011. ModeloZDQLHV\QWH]\G]LDáDĔRFKURQQ\FKZUROQLF]\PSURFHVLH SURGXNF\MQ\P,QĪ\QLHULD5ROQLF]D Marciniak A. 2005. Projektowanie systemu reprezentacji wiedzy o rolniczym procesie produkcyjnym. RozpraZ\QDXNRZH$NDGHPLL5ROQLF]HMZ/XEOLQLH:\G]LDá ,QĪ\QLHULL3URGXNFML]HV]\W 22. 2QLĞNR$0DUHN-'UX]G]HO0-:DV\OXN+ /HDUQLQJ%D\HVLDQQHWZRUNSDUDPHWHUVIURPVPDOOGDWD VHWV$SSOLFDWLRQRIQRLV\RUJDWHV,QWHUQDWLRQDO-RXUQDO RI$SSUR[LPDWH5HDVRQLQJ Pearl J. 1986. Fusion, Propagation, and Structuring in %HOLHI1HWZRUNV$UWL¿FLDO,QWHOOLJHQFH Pearl J. 1988. Probabilistic Reasoning in Intelligent Systems: Network of Plausible Inference. Morgan Kaufmann. Tchangani A.P. 2001. 5HOLDELOLW\DQDO\VLVXVLQJ%D\HVLDQQHWZRUNV6WXG,QIRUP&RQWURO =$67262:$1,(352&('85<2%/,&=1,:(- :6,(&,%$<(62:6.,(-'2:<=1$&=$1,$ .26=7Ï:&$à.2:,7<&+352'8.&-, (/(0(17Ï:=.$0,(1,$1$785$/1(*2 Streszczenie: W Proces gromadzenie danych oraz ich przeWZDU]DQLDLVWRWQDUROĊRGJU\ZDMąSURFHV\REOLF]HQLRZHNWyUH PRJąE\üUHDOL]RZDQHDXWRPDW\F]QLHDSRQDGWRZQDWXUDOQ\VSRVyESRZLQQ\XPRĪOLZLDüXZ]JOĊGQLHQLHQLHSHZQRĞFL :DUW\NXOHSU]HGVWDZLRQRSU]\NáDGWDNLHJRSURFHVXUHDOL]RZDQHJRZWHFKQRORJLLVLHFLED\HVRZVNLFK0RGHOXPRĪOLZLD PRQLWRURZDQLHNRV]WyZFDáNRZLW\FKSURGXNFMLHOHPHQWyZ wykonanych z kamienia naturalnego granitu. 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COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 65–70 S The Analysis of Oil Balance in Crank Bearing Khachatur Kyureghyan1, Wiesław Piekarski2 1 S Department of Applied Mathematics and Computer Science, University of Life Sciences 20-950 Lublin, Akademicka 13, e-mail: [email protected] RSWLPDORSHUDWLRQDIWHUPWK 2 Department of Energy and Transportation, University of Life Sciences 20-959 Lublin, Poniatowskiego 1, e-mail: [email protected] Received December 09.2014; accepted December 19.2014 '> @ ¦f K Summary. The paper presents an analytical calculation of the balance of oil flowing through the dynamically loaded main and crank bearing. 7KHRUHWLFDO FRQVLGHUDWLRQV DUH EDVHG RQ VROYLQJ WKH 5H\QROGV HTXDWLRQ (analytical distribution of oil pressure in the FURVV VOLGH EHDULQJ ZLWK boundary conditions that characterize the working conditions in the bearings used in motors s- DJULFXOWXUDO WUDFWRUV7KH TXDQWLWDWLYHDQGYROXPHWULFHYDOXDWLRQVRIOXEULFDQWIOXLGIORZLQJWKURXJK the bearing are presenWHG DGHTXDWHO\ WR WKH FRQVWUXFWLRQ RI D GLDJQRVWLF signal, which allows for a dynamic comparative analysis carried out for the model bearings, the new ones as well as the ones with a particular classification of wear. Key words: hydrodynamic lubrication, cross slide bearing, Reynolds HTXDWLRQGLDJQRVWLFDQDO\VLVGLDJQRVWLFVLJQDOSDUDPHWHUV Physical values: - thickness of the wedge [mm], H - relative bearing eccentricity [-], c - bearing clearance [mm], K - coefficient of dynamic oil viscosity [ Pa s ], V - peripheral speed of crankshaft [m/s], e - eccentricity [mm], P(x,z) oil pressure inside bearing [Pa], L L [mm], x,z – coordinat variables, x 0,2SR , z , 2 2 L – the width of the pan [mm], p w , p0 supply pressure ambient pressure [Pa], h p z - supply pressure [Pa], a - cord diameter [mm], Q - oil intensity passing through the crank bearing [dm3/min], Q1 ,Q2 - partial intensity[dm3/min], S0,Sgr values for Q1 ,Q2from experiment[dm3/min], h0 min hx - the minimum thickness of oil wedge [mm], x 0, 2SR cdot c0 clearance after getting proper association (at RSWLPDORSHUDWLRQDIWHUPWK [mm], c gr - critical value of clearance [mm], Dp - coefficent of dynamic passing [-], dp - experimenthal value of Dp determined as a parametr of the diagnostic signal Mathematical solutions b '> f @a f (a f (b - RSHUDWRUUyĪQLFRZ\ >f @ ¦f - suming operator, k, K N, F]ĊĞüFDáNRZLWDZ\UDĪHQLD 5H\QROGV HTXDWLRQ FRQVWDQWV GHWHUPLQHG E\ fK RSHUDWRUUyĪQLFRZ\ - suming operator, k, K N, > f @ - F]ĊĞüFDáNRZLWDZ\UDĪHQLDf, - 5H\QROGV HTXDWLRQ FRQVWDQWV GHWHUPLQHG E\ C1,C11,C1K boundary conditions k k INTRODUCTION The parameters of diagnostic signals defining the course of change in the tightness of slide bearings are a very important factor in assessing the technical state of engines examined in this study on the example of farm tractors. It should be noted that in the lubrication subsystem the main slide bearings and the crank ones of the crankshaft determine the technical condition of the engine, and its ability to perform useful functions. Increased clearances in the bearings make the lubricant oil flow freely through the gaps between the pivots and the cups, which in turn is manifested by an increase in oil flow and pressure drop in the engine lubrication system. In diagnostic considerations, the evaluation of work behavior of a dynamically loaded slide bearing is based on the simplified model of a standard cross slide bearing and is based mostly on the minimum thickness of oil gap and the value of the maximum pressure and maximum temperature of the oil film. +RZHYHU DV QRWHG E\ VHYHUDO DXWKRUV >@ LQ diagnostic tests, particularly in predicting the technical state of emergency crank system operation, application of a singleparameter diagnostic signal based solely on the measurement of relative drop in oil pressure at selected points of the bearing, is not sufficient to assess the degree of bearing wear. >@ SUHVHQWHG D PXOWLYDULDWH VWDWLVWLFDO DQDO\VLV (curvilinear regression model for the associated random vDULDEOHVRIWKHGLDJQRVWLFVLJQDObased on measurements of four parameters, where the measurement of the relative pressure drop and loss of lubricant in the bearings were considered as associated variables. The purpose of this study is to analyze the theoretical value of the diagnostic signal parameter described by an analytical balance of oil in the cross slide bearing. In diagnostic studies of changes in oil flow through the crankshaft bearing and at the constant supply pressure in RLOJDS$QGDFFRUGLQJWRWKHUHODWLRQ H cosT DULDEOHVRIWKHGLDJQRVWLFVLJQDO .+$&+$785.<85(*+<$1:,(6à$:3,(.$56., cross slide bearing. In diagnostic studies of changes in oil flow through the crankshaft bearing and at the constant supply pressure in static conditions, the oil flow rate depends mainly on the size of RLOJDS$QGDFFRUGLQJWRWKHUHODWLRQ: h Lt H cosT , p 0 for z P p w x for z § wPx, z · ¨ © wz ¹̧W r the gap value depends on oil bearing clearance (L tDQG FRQVLGHUDWLRQV relative bearing eccentricity (İ LQ IXUWKHU ZH use a simplified designation: S § w · ¨ Lt c . ¹̧ © w K H r P L , 2 0, Sa p z pw c KL H cos x R , for z 0 where: ambient pressure [Pa], p0 - the pz - supply pressure [Pa], Determination of this value in the experimental way is pw - oil pressure at the inlet to the placenta [Pa], OXEULFDWLRQ VXEV\VWHP EHDULQJ VHD based on measurements of diagnostic parameters, the a - cord diameter [mm], commonest of which are oil pressure or relative drop of oil L - the width of the pan [mm]. $FFRUGLQJ WR >@ >@, the analytical EDVHG RQ WKHdistribution HTXDWLRQV inRIthe K\GURG\QDPLF pressure in the OXEULFDWLRQ VXEV\VWHP 2 EHDULQJ VHDOVXEV\VWHP %\ ZD\ EHDULQJ VHDO %\ ZD\ OXEULFDWLRQ of contrast, the theoretical determination of the oil gap is EHDULQJ RLO SUHVVXUH DV WKH VROXWLRQ RI HTXDWLRQ FDQ EH written as follows: EDVHG RQ WKH HTXDWLRQVEDVHG RI K\GURG\QDPLFs for aRIviscous K\GURG\QDPLF RQ WKH HTXDWLRQV K\GURG\QDPLF substance. e 0$7+(0$7,&$/02'(/2)%($5 ª H cos x º H L § · $FFRUGLQJ WR >@ R » $1' « $668037,216 Px, z p0 C ¨ z EHDULQJ RLO SUHVVXUH DV WKH VROXWLRQ RI HTXDWLRQ FDQ EH 0$7+(0$7,&$/02'(/2)%($5,1* 2 ¹̧ « H » © 0$7+(0$7,&$/02'(/2)%($5,1* ¬ ¼ $VVHVVPHQWRIZRUN $1' $668037,216 $1' $668037,216 f Kz K L z 2 ) RK x R <RKV x R , ¦ CK e e $VVHVVPHQWRIZRUNof loaded crank bearing K $VVHVVPHQWRIZRUN dynamically $VVHVVPHQWRIZRUN H ª H º is one of the most important tasks of§ the crank · « subsystem In this paper,» engines. ¨ diagnostics in internal combustion » where © ¹̧ « H ¬ ¼ theoretical considerations and the resulting mathematical R 2 K 2 2 x § cos x · W\SH RI LQWHUQDO FRPEXVWL f sin calculations are shown on the basis of a cross slide bearing R¨ R¸ , parameters ) ) RK x model, characterizing ¦ the operating of <crank ¸ R ¨ 2 ¹ © bearing in S- FRPEXVWLRQ W\SH RI LQWHUQDO W\SHHQJLQHV RI LQWHUQDO FRPEXVWLRQ HQJLQHV In the process of exploitation, the growing bearing clearance 2 2 2 ª x · § cos x · § 2 2 § 2SRK · >R K @ «§ R K V · ¨ cos R ¸ R¸ values cause an increase in the impact of oil flowing fromthe x ¨¨ ¸¸ ln ¨ < RKV R ¨ ¦ ¸ ¨ ¸ ¨ « x · nV i i 2 bearing, causing a decrease in tightness of the§bearings. ¹̧ © cos i © ¹ © ¸ ¨ R¹ ¹ © ¬« ) a dynamically The balance of oil flowing through loaded ¸ ¨ HTXDWLRQ using crank bearings can be determined analytically ¹ a © e º i pressure distribution which is the solution of the Reynolds ª H x x x § · · § · § > @ cos H V cos cos ·¨ HTXDWLRQ: · § S HTXDWLRQ «§¨ w § w · w HTXDWLRQ R ¸ ln ¨ R ¸ ¨ R ¸ » , w § w · ¸ < ¨ » ¨ ¸ ¦ ¨ ¸ ¨ ¸ ¨ ¸ ¨ ¸ « ¨ ¸ ¨¨ K w ¸¸ w 2 S e V ¹̧ © © cos x w w w K ¹ © ¹ © ¹ R¹ © ¹ © © ¹ »» w § h wP · w § h wP ·w «¬§ wwh · w § w · ¼ ¨¨ ¸¸ ¨¨ ¸¸ ¨V . ¸ ¨ ¸ w wx © K wx ¹ wz © K wz ¹w ¨© K wwx ¸¹ w ¨© K w ¸¹ $IWHUFRQVLGHULQJWKHFRQVWDQWFRHIILFLHQWRIG w e º 'L H DV ZHOO § H · DV pz p0 K, C cos ¸ » L $IWHUFRQVLGHULQJWKHFRQVWDQWFRHIILFLHQWRIG\QDPLFoil ¨ $IWHUFRQVLGHULQJWKHFRQVWDQWFRHIILFLHQWRIG\QDPLF $IWHUFRQVLGHULQJWKHFRQVWDQWFRHIILFLHQWRIG\QDPLF » 'L ¨ S ¸ viscosity ( K const DV ZHOO DV© the » DV 2 >@ DV¹simplified ZHOO K following » expressions for the functions describing the thickness ¼of the wedge and the bearing wear >@ >@ H ' p h h( x c H cosx ,' H R w w H e sin x wh( x R ,w h( x wx Rc H cos x w H HTXDWLRQFDQEHZULWWHQDV R > > @ HTXDWLRQFDQEHZULWWHQDV: HTXDWLRQFDQEHZULWWHQDV HTXDWLRQFDQEHZULWWHQDV @ H Kexsin x Ke sin x e sin R R P' ' xx x, z P' ' zz x,z V 0 P' x x, z H cos Rc H H xR Rc H cos x R with the boundary conditions: , with the boundary conditions: K r S K ^ ` ® ¯ « ¬ 7+($1$/<6,62)2,/%$/$1&(,1&5$1.%($5,1* H H V H H H H H » H H ¼ ½ ¾ ¿ RPLWWHG HOHPHQWV RI WKH H ' L *L p z p0 ' * , , e ª º 'H º ª e º ª H H H H § § · · 2 S » < S » H H»20H «¨ ) ) S< < ) S « H ) < §¨ HH ·H «) S ) ¨2 <0S< 2 » « © H» ¹̧ ' » « © H ¹̧ « H © H ¹̧ ¬ H ¼ 2 ¼ ¼ ¬ ¬ § · e ¨ Sa ¸ K K Sa ' L ¸ Sa L ª H º H ¨ ' ' 'L , C C p C , K K ¦ k ¦ ¨ 0K 2 «¬ H »¼ 2c KL § KL · ¸ k k ¨ SC ¨ ¸ ¹̧ ¹ © © H H H 2 L ' e * ' * e *L ' L e . H where: H H ' *C ª§ R · 2 º $1$/<7,&$/%$/$1&(2)2,/ $1$/<7,&$/%$/$1&(2)2,/ K ,2,..., «¨ ». $1$/<7,&$/%$/$1&(2)2,/ ¬«© e ¹̧ ¼» $QDO\WLFDO $QDO\WLFDO GHWHUPLQDWLRQ of the amount of GHWHUPLQDWLRQ oil flowing$QDO\WLFDO GHWHUPLQDWLRQ LV EDVHG RQ WKH VROXWLRQ EDVHG HTXDWLRQ WKH VROXWLRQ Lstreams RI 4 HTXDWLRQ L DueLV toRI -RQ , oil through bearing LV EDVHG RQ WKH VROXWLRQ RI HTXDWLRQ L.e. 42 can be written as ]GHVFULELQJWKHGLVWULEXWLRQRIS ]GHVFULELQJWKHGLVWULEXWLRQRIS function P (x, ]GHVFULELQJWKHGLVWULEXWLRQRISressure in the follows: @ DOXHRIWKHLQWHQVLW\RI4SDVVLQ @ DOXHRIWKHLQWHQVLW\RI4SDVVLQ crank bearing [9,@The vDOXHRIWKHLQWHQVLW\RI4SDVVLQg e through the crank bearing can be represented as two partial º ª H c CK exp^KL` « 44flow caused by 44 § H · » § H · streams 442, where Q1 is part of the stream ¨ Q ( H ¨ , 4 «4 KRK the rotation of the crankshaft, while 42 is part of a stream of © H ¹̧ © 2 ¹̧ » ¼ ¬ 4 %\ YLUWXH RI WKH 4 DERYH %\ YLUWXH RI WKH DERYH pressurized forced power 42. %\ YLUWXH RI WKH DERYH considerations, the dependencies representing the partial e C e H KS exp ^KL` ª streams of flowing oil can be written as follows: H H º» . Q2 2C K « e 2H K ¼ ¬ S S RS L 2 w w ª ª º º ª wP º ' « » dzS ' « » dz Q Q, x 0 Q, x RS h' « » dz S K ³ )LQDOO\E\HTXDWLRQWKHEDODQFHRIRLOIORZLQJ K ³ ¬w ¼ ¬w ¼ K ³L 2 ¬ wx ¼ 0 through the crank bearing can be written as the following L L relationship: ªw º º ªw º ª w ªw º 2 ª wP º 2 ª wP º , h dz h dz ³ ³³ «¬ w«¬ w »¼ »¼ S dz K ³ «¬ w »¼ S dz « » ³ ³ » « » « K K K w ¬ ¼ K L 2 ¬ wx ¼ x 0 K L 2 ¬ wx ¼ x RS c exp^KL` ª ·º § : Q Q Q2 . «2C CK ¨ RK KS: 2 » , K ¹̧¼ © ¬ L r r S S r 2S 2 ªw º ªw º ª wP º ' ' Q2 Q2, z 0 Q h ' « » dx «¬ w »¼ «¬ w »¼ L r r where: K³ K ³ 2, z r K ³0 ¬ wz ¼ 0 2 e S S S S 2S 2S ª w ªºw º § ªHw· Hº § H · ªw º ª wP º ª wP º dx dx dx³ , « w dx h h , K ³K ³«¬ w «¬»¼w:r»¼ ( HK ¨³ «¬Hw »¼ r ¨ 2 ¬ »¼ K ³ «¬ wz »¼ z 0 K ³ «¬ wz »¼ z rLK © ¹̧ © ¹̧ 0 0 2 c CK exp ^KL` H §¨ H · KRK © H ¹̧ where: Q, x 0 e H ,K ^ 3(5)250$1&($1$/<6,62)',$*1267,&6,*1$/ ^ ` H ^ ` H K In Sthe crank Q, x RS bearings of the engine type S- K (agricultural tractors C- , the maximum value of bearing clearance is characterized by accelerated wear of crank mechanism (the boundary condition of the bearing e CK e H c KS exp^KL` ª º Q2, z 0 can be derived from the average «2C e 2H H H » , crank is 0.2 mm, which K ¬ ¼ dependence given by KozáRZLHFNL DQG 3U]XVWND >@ DV ZHOO as 7KXP> @ e CK e H c KS exp ^KL` ½ H H ¾ . Q ®2C L 2 2, z r e 2H K ¿ ¯ C dot 2 C gr , h0 The relationshipV - RPLWWHG HOHPHQWV RI WKH order o( H and used the following indications: using the classical formula Vogelpohl: c CK exp ^KL` HS , KRK C ¦ § ¨ ¦ ¨¨ ¨ © 'L p z p0 , L 'L 2 ª H º « ¬ H »¼ ª§ · 2 H º · ¸ ' ¸ ·¸ § S ¨ ¸ ¹̧ ¹ © e e H H H . e : 2 e ` H § H ·^H `e 2H H § H · H ¨ ¨ H ¹̧ ©K © H ¹̧ Cdot 0.92 V , where: C dot - clearance after getting proper association (at optimal operation aIWHUPWK h0 - the minimum thickness of oil wedge, EHDULQJ¶V RSHUDWLRQ .+$&+$785.<85(*+<$1:,(6à$:3,(.$56., operation aIWHUPWK h0 - the minimum thickness of oil wedge, V - the peripheral speed of crankshaft. CONCLUSIONS In the boundary conditions of dynamically loaded crank EHDULQJ¶V RSHUDWLRQ, the diagnostic signal parameters describing the relative decline in the oil pressure inside the bearing and its flow through the bearing score significantly higher values than when working under optimal conditions, ZKLFKSRLQWVWRDFFHOHUDWHGZHDURIWKHFUDQN3LHNDUVNL>@ applied the model to assess the value of diagnostic signal parameters based on measurements of the relative pressure drop and oil flow d\QDPLFVDWWKHPHDVXUHPHQWQDUURZLQJ$s an indicator of the dynamics, the following value describing oil flow through the bearing was accepted: dp S gr S 0 S0 , $nalytical interpretation of the above relation, using the average value of clearance limit (at the speed of the shaft min C gr 2, V , C0 FDQEHREWDLQHGE\HTXDWLRQDVIROORZV 7 Dp § c gr ¨ ¨c © 0 · ¸ ¸ ¹ · § :gr 2C CK ¨¨ KS: 2 gr ¸¸ RK ¹ © § : · 2C CK ¨ KS: 20 © RK ¹̧ ) gr 2, , )0 5()(5(1&(6 c gr , i=1;2, )0 ) gr §: · 2C0 CK ¨ KS: 20 , © RK ¹̧ · § :gr 2C gr CK ¨¨ KS: 2 gr ¸¸ , RK ¹ © K for c c0 ° 2 c0 , c gr for c ® °̄ for c c gr . %DáXFLĔVNL-6WĊSLĔVNL- Wykorzystanie metod oceny stanu technicznego silników przy kwalifikowaniu LFKGRQDSUDZ\7HFKQ0RWR- 2. %ĊGNRZVNL / Elementy ogólnej teorii GLDJQRVW\NLWHFKQLF]QHM%LXO:$7 Cislikowski B., Pedryc N., 2009: Koncepcja nadzoru QDG PDV]\QDPL SU]H] FRPSXWHU SRNáDGRZ\ FLąJQLND Z czasie rzeczywistym z wykorzystaniem magistrali LQIRUPDW\F]QHM/,1,QĪ\QLHULD5ROQLF]D- Das S., Guha S.K., Chattopadhyay A.K., 2005: Linear stability analisis od hydrodynamic journal bearings under micropolar lubricatioQ7U\ERORJ\,QWHUQDWLRQDO- Hebda M., Wachal A., 1980: Trybologia, WNT, Warszawa. -XĞFLĔVNL 6 3LHNDUVNL : =DU]ąG]DQLH ORJLVW\F]QH DXWRU\]RZDQ\P VHUZLVHP FLąJQLNyZ L masz\Q UROQLF]\FK (NVSORDWDFMD L 1LH]DZRGQRĞü – 0DLQWHQDQFHDQG5HOLDELOLW\- 7. Mienann G., 1980: Mashinenelemente. Springer Verlag, %HUOLQ 8. Niewczas A., 1991: Zastosowanie pomiarów SU]HGPXFKyZ VSDOLQ GR SURJQR]RZDQLD WUZDáRĞFL silników spalinowych. Krajowa Konf. Naukowo – 7HFKQLF]QD.LHNU]- 9. .R]áRZLHFNL + àRĪ\VND WáRNRZ\FK VLOQLNyZ spalinowych. WKiL, Warszawa. .R]áRZLHFNL + 3U]XVWHN - :VSyáF]HVQH PHWRG\REOLF]DQLDSDUDPHWUyZSUDF\áRĪ\VNPHFKDQL]PX korbowego silników spalinowych. Silniki Spalinowe, 2, - Krasowski P., 2006: =PLDQD FLĞQLHQLD Z SRSU]HF]Q\P áRĪ\VNX ĞOL]JRZ\P SU]\ ODPLQDUQ\P QLHVWDFMRQDUQ\P where: :i 0 - TXDQWLW\FDOFXODWHGIURPVROXWLRQV, IRU c c0 , i=1;2, : igr - TXDQWLW\ FDOFXODWHG IURP VROXWLRQV IRU c Knowledge of the dynamics of steam friction (pivot FXS LQ D FUDQN system, expressed by escalation of clearance between its elements, allows to determine the probability of reliable operation of the considered friction SDLU $ SURSHU technical maintenance of the engine operation is necessary, provided the information is available on its properties. This information can be known only by the changes of bearing clearance and course changes in the dynamics of the diagnostic signal. The terms of co-operation of the functional subsystem crank pivot - cup decide on the reliable operation of the 8 engine. The worsening conditions for cooperation of these subsystems as a result of processes of consumption lead to premature engine wear, and even more to significant increase in fuel and oil consumption and increased difficulty in starting. 5HTXLUHPHQWV IRU RSHUDWLRQDO SURJUHVV DUH EHFRming PRUHIUHTXHQWO\UHFRJQL]HGDQGIRUPXODWHG,W has been noted that the effectiveness of the management of technical objects in many cases reduces the high operating expenses, which may even get higher than expenses associated with designing and manufacturing. The high operating expenses can be UHGXFHGE\LPSURYLQJWKHTXDOLW\RIWHFKQLFDOREMHFWVDVZHOO as conditions of their use and handling. For this purpose, the pursuit is necessary of rational, science-based exploitation of technical objects. In diagnostic tests, the dynamic of determined signal changes should be as high as possible. It is assumed that the determined change induced by an increase in consumption occurring in the crank subsystem is the relative increase in oil pressure drop, which is treated as a diagnostic signal. CONCLUSIONS 9 FXS LQ D FUDQN SDLU $ SURSHU 3URJQR]RZDQLH WUZDáRĞFL SDU WUąF\FKVLĊQDSU]\NáDG]LHáRĪ\VNZDáXNRUERZHJRVLOQLND &=HV]\W\1DXNRZH$56]F]HFLQ JQRVW\ND SRMD]GyZ UROQLF]\FK:\G$5/XEOLQ hEHU GHQ 9HUODXI GHV 6FKPLHUILOPGUXFNHV LQ 7+($1$/<6,62)2,/%$/$1&(,1&5$1.%($5,1* G\QDPLVFK EHDQVSUXFKWHQ *OHLWODJHUQ :LVV = 7HFKQ +RFKVFK0DJGHEXUJ VPDURZDQLX =HV]\W\ 1DXNRZH $NDGHPLL 0RUVNLHM Z Thum H., 1985: =XU %HVWLPPXQJ GHU 9HUVFKOHLVV6]F]HFLQLH-298. EHGLQJXQJHQ /HEHQVGDXHU YRQ :llzlagern bei verschieKurowski W., 1978: 6\VWHP\ GLDJQRVW\F]QH XU]ąG]HĔ GHQHQ hEHUOHEHQZDKUVFKHLQOLFKNHLWHQ 6FKLPUXQJVmechanicznych. DUM, Ossolineum. WHFKQLN- Kyureghyan Kh., 2002: Theoretical calculation of size 20. Vogelpohl G., 1969: hEHU GLH 8UVDFKHQ GHU 8Q]Xon an oil slit in a transverse sliping bering, Mathematical UHLFKHQGHQ %HZHUWXQJ YRQ 6FKHPLHUXQJVIUDJHQ LP 0HWKRGVLQ$JULFXOWXUH- 9RULJHQIDKUXQGHUW6FKPLHUWHFKQLN Kyureghyan Kh., Kornacki A., Piekarski W., 2006: $QDOLW\F]QD ]DOHĪQRĞü GR Z\]QDF]DQLD FLĞQLHQLD Z $1$/,=$%,/$1682/(-8:à2ĩ<6.8.25%2:<0 K\GURVWDW\F]Q\P áRĪ\VNX SRSU]HF]Q\P ĞOL]JRZ\P ,QĪ\QLHULD5ROQLF]D Kyureghyan Kh., Piekarski W., 2008: $QDOLVLV RI Streszczenie 3UDFD SU]HGVWDZLD DQDOLW\F]Qą NDONXODFMĊ ELODQVX ROHMX SU]HSá\ZDMąFHJRSU]H]G\QDPLF]QLHREFLąĪRQHáRĪ\VNRJáyZQHLNRUERZH detetermining pressure distribution in crank bearing, 7HRUHW\F]QH UR]ZDĪDQLD ED]XMą QD UR]ZLą]DQLX UyZQDQLD 5H\QROGVD (NVSORDWDFMD L 1LH]DZRGQRĞü – Maintenance and DQDOLW\F]Q\ UR]NáDG FLĞQLHQLD ROHMX Z áRĪ\VNX SRSU]HF]Q\P ĞOL]JRZ\P 5HOLDELOLW\- o ZDUXQNDFK EU]HJRZ\FK FKDUDNWHU\]XMąF\FK ZDUXQNL SUDF\ ZZ áRĪ\VN Piekarski W., 1993: 3URJQR]RZDQLH WUZDáRĞFL SDU zastosowanych w silnikach S- FLąJQLNL UROQLF]H ,ORĞFLRZRWUąF\FKVLĊQDSU]\NáDG]LHáRĪ\VNZDáXNRUERZHJRVLOQLND REMĊWRĞFLRZą RFHQĊ FLHF]\ VPDUXMąFHM SU]HSá\ZDMąFHM SU]H] áRĪ\VNR przedstawiono adekwatnie do WHRUHW\F]QHM ZDUWRĞFL V\JQDáX S – &=HV]\W\1DXNRZH$56]F]HFLQ- GLDJQRVW\F]QHJR FR SR]ZDOD QD G\QDPLF]Qą DQDOL]Ċ SRUyZQDZF]ą Piekarski W. i inni., 1988: DiaJQRVW\ND SRMD]GyZ SU]HSURZDG]RQą GOD Z]RUFRZ\FK QRZ\FK MDN UyZQLHĪ GOD áRĪ\VN UROQLF]\FK:\G$5/XEOLQ o XVWDORQHMNODV\ILNDFMLVWRSQLD]XĪ\FLD Thum H.: hEHU GHQ 9HUODXI GHV 6FKPLHUILOPGUXFNHV LQ 6áRZD NOXF]RZH VPDURZDQLH K\GURG\QDPLF]QH áRĪ\VNR SRSU]HF]ne G\QDPLVFK EHDQVSUXFKWHQ *OHLWODJHUQ :LVV = 7HFKQ ĞOL]JRZHUyZQDQLH5H\QROGVDDQDOL]DGLDJQRVW\F]QDSDUDPHWU\V\JQDáX diagnostycznego. +RFKVFK0DJGHEXUJ Thum H., 1985: =XU %HVWLPPXQJ GHU 9HUVFKOHLVVEHGLQJXQJHQ /HEHQVGDXHU YRQ :llzlagern bei verschieGHQHQ hEHUOHEHQZDKUVFKHLQOLFKNHLWHQ 6FKLPUXQJV WHFKQLN hEHU GLH 8UVDFKHQ GHU 8Q]X UHLFKHQGHQ %HZHUWXQJ YRQ 6FKHPLHUXQJVIUDJHQ LP 9RULJHQIDKUXQGHUW6FKPLHUWHFKQLN $1$/,=$%,/$1682/(-8:à2ĩ<6.8.25%2:<0 3UDFD SU]HGVWDZLD DQDOLW\F]Qą NDONXODFMĊ ELODQVX ROHMX SU]HSá\ZDMąFHJRSU]H]G\QDPLF]QLHREFLąĪRQHáRĪ\VNRJáyZQHLNRUERZH 7HRUHW\F]QH UR]ZDĪDQLD ED]XMą QD UR]ZLą]DQLX UyZQDQLD 5H\QROGVD DQDOLW\F]Q\ UR]NáDG FLĞQLHQLD ROHMX Z áRĪ\VNX SRSU]HF]Q\P ĞOL]JRZ\P ZDUXQNDFK EU]HJRZ\FK FKDUDNWHU\]XMąF\FK ZDUXQNL SUDF\ ZZ áRĪ\VN FLąJQLNL UROQLF]H ,ORĞFLRZR REMĊWRĞFLRZą RFHQĊ FLHF]\ VPDUXMąFHM SU]HSá\ZDMąFHM SU]H] áRĪ\VNR WHRUHW\F]QHM ZDUWRĞFL V\JQDáX GLDJQRVW\F]QHJR FR SR]ZDOD QD G\QDPLF]Qą DQDOL]Ċ SRUyZQDZF]ą SU]HSURZDG]RQą GOD Z]RUFRZ\FK QRZ\FK MDN UyZQLHĪ GOD áRĪ\VN XVWDORQHMNODV\ILNDFMLVWRSQLD]XĪ\FLD 6áRZD NOXF]RZH VPDURZDQLH K\GURG\QDPLF]QH áRĪ\VNR SRSU]HF] ĞOL]JRZHUyZQDQLH5H\QROGVDDQDOL]DGLDJQRVW\F]QDSDUDPHWU\V\JQDáX TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 71–80 The Development of New Technologies for Processing and Disposal of the Oil Containing Wastes Enterprises of Railway Infrastructure Anna Leshchyns’ka, Yuliya Zelen’ko, Marina Bezovs’ka, Michael Sandowski Dnipropetrovsk National University of Railway Transport Named after Academician V. Lazaryan Academician Lazaryan st., 2, Dniepropetrovsk, Ukraine, 49010 e-mail: [email protected], [email protected] Received December 11.2014; accepted December 19.2014 activity; railway facilities in Ukraine occupy approximately KHFWDUHVZLWKGUDZQIURPDJULFXOWXUDOVHFWRU>@ /DUJHSDUWRIHPLVVLRQVDERXWLVSURGXFHGE\IXHO combustion during operation of diesel mainline and shunting rolling stock, refrigerated trains. 7KHTXDOLW\RIZDVWHZDWHURIWKHUDLOZD\XQGHUWDNLQJV varies widely. Water pollution by industrial wastewaters creates a potential threat to public health, restricts the use of water reservoirs for household, drinking, cultural and GRPHVWLFSXUSRVHVFDXVHVJUHDWGDPDJHWR¿VKHULHVDQG DJULFXOWXUH>@ The sources of wastes in railway transport are all its INTRODUCTION subdivisions. Major transport companies, which include, in particular, locomotive, railcar depots, railway stations, rail7KHFUHDWLRQDQGGHYHORSPHQWRIKLJKHI¿FLHQWWHFKQROR- way machinery repair plants and bases supporting them, tend gies subject to demands on resource and energy conservation to form and accumulate processing wastes, oil-contaminated DVZHOODVHQYLURQPHQWDOVDIHW\DUHSUHUHTXLVLWHVIRUWKH RQHVEHLQJWKHPRVWFRPPRQRIWKHP7DEOH production development at the present stage. The railway infrastructure is one of the largest con- Ta b l e 1 . Processing wastes of railway undertakings sumers of valuable material resources such as petroleum, Waste Technological process that because the environmental safety of the railways is one of Type of waste volume per forms wastes annum WKHSULRULWLHV>@ Summary. In article traditional methods of utilization and reQHZDORIWKHIXO¿OOHGFRROLQJOXEULFDQWVDQGZDVWHFRPSUHVVRU oils of separate brands are considered. In developing the scheme RIUHFRYHU\RIRSHUDWLQJTXDOLW\RIWKHRLOFRQWDLQLQJZDVWHVIRU WKHSXUSRVHRIIRUPLQJDQGFDOFXODWLQJWKHSURFHVVÀRZGLDJUDP suggested, the process optimization, namely temperature, reagent amount, and time of its contact with oil was conducted. The new technologies with use of surface-active substances are offered. Key words: ZDVWHFRPSUHVVRURLOVFRROLQJOXEULFDQWVFRRODQWV surface-active substances, environmental safety, utilization. Oil sludge 0$7(5,$/6$1'0(7+2'6 To reduce the negative impact of railway transport in all parts of the biosphere during regular operation, the degree of its impact should be constantly monitored and regulated. $QDO\VLVRIWKHDQQXDODFWLYLWLHVRIWKHUDLOZD\XQGHUWDNLQJV VXJJHVWVWKDWPRUHWKDQRIZDWHUFRQVXPHGLVGLVFKDUJHG into surface water reservoirs in the form of wastewater contaminated with oil products, salts of heavy metals, synthetic VXUIDFHDFWLYHVXEVWDQFHVHWFRYHUWRQVRIKDUPIXOVXEstances are emitted into the atmosphere from stationary sourcHVRQO\DERXWRIWKHPDUHUHFDSWXUHGDQGGHWR[L¿HG PRUHWKDQWRQVRIZDVWHDUHIRUPHGDVDUHVXOWRILQGXVWULDO Washing machinery sludge 3XUL¿FDWLRQRIZDVWHZDWHUV up to 200 thous. t Washing of bearings, bearing boxes, four-wheel trucks and carriage up to 2000 m3 bodies of rolling stock, various details before repair works 3XUL¿FDWLRQRIZDVKLQJZDWHUV up to 20 t of galvanic sections *DOYDQLF sludge Dry-cleaning machinery Work wear cleaning subsidence Cleaning of bearing boxes beScavenge oils fore repair, scavenge oil change Scavenge diesel oils change Scavenge during rolling stock maintediesel oils nance and repair P3 WKRXV7 2YHU thous. T 72 $11$/(6+&+<16¶.$<8/,<$=(/(1¶.20$5,1$%(=296¶.$0,&+$(/6$1'2:6., Type of waste Technological process that forms wastes Cleaning of industrial sites, Contaminated midpoint pump station, sleeper impregnation plant, railside soil territories of depots, plants etc. Replacement of used Cross-sleepers cross-sleepers during repair works Replacement of defective lamps Fluorescent in administrative premises and lamps workshops of the undertakings MechaniReplacement of brake shoes cal-rubber during repair works, of battery wastes jars and other rubber pieces Waste volume per annum XSWRPOQ T POQ pcs. XSWR thous. pcs. W $PRXQWRIPDQDJHGZDVWHRIDOOJUDGHVLVQHJOLJLEOH due to the general economic trend of decline in production, which in turn is a condition for reducing the volume of ¿QDQFLQJHQYLURQPHQWDOPHDVXUHVDLPHGDWLQFUHDVLQJWKH level of waste utilization not only in railway transport, but also in all industries in Ukraine. Storage and disposal of waste in railway transport, as in RWKHULQGXVWULHVGRQRWRIWHQPHHWVDQLWDU\UHTXLUHPHQWV leading to contamination of groundwater, soil and atmosphere. The most effective approach to minimizing the negative environmental impact is to develop eco-protection technologies based on the monitoring data, which allows for taking into account the peculiarities of the objects. $WWKHUDLOZD\XQGHUWDNLQJVRLOFRQWDPLQDWHGDQGRLO\ waste (waste oils, cooling lubricants, contaminated soils, JUHDVHWHFKQRORJ\VOXGJHSHWUROHXPVOLPHHWFFRQVWLWXWHDVLJQL¿FDQWSDUWRIWKHWRWDOYROXPHRIDOOZDVWHV7KLV follows, for example, from the analysis of the dynamics of the formation of different types of waste that were formed at the undertakings of different railway departments. In particular, the major contributors to the formation of such waste are the undertakings of locomotive department, VR)LJSUHVHQWVWKHGDWDRQWKHIRUPDWLRQRIDOOW\SHVRI waste at the undertakings of that department of the PrydniSURYVNDUDLOZD\LQ>@ )LJFOHDUO\VKRZVWKDWLQJHQHUDOIRUWKHXQGHUWDNLQJV of the railway locomotive department it is scavenge oils that constitute the main group of waste; process sludge comes third after accumulator batteries. $FFRUGLQJWRWKHSXEOLFPDQDJHPHQWSROLF\LQWKH¿HOG of waste treatment, all processing waste for which the methods for recycling and rational use in the national economy are developed, are to be used as secondary raw material and VKRXOGQRWEHWUDQVSRUWHGWRODQG¿OOV Disposal of exhausted petroleum and oil-containing ZDVWHVLVDQLPSRUWDQWVFLHQWL¿FDQGWHFKQLFDOFKDOOHQJH EHFDXVHWKH\DUHFODVVL¿HGDVKD]DUGRXVZDVWHZKLFKDGYHUVHO\DIIHFWDOOREMHFWVRIWKHHQYLURQPHQW±DLUVRLODQG water. For instance, water pollution by petroleum products LVRIWKHWRWDOPDQPDGHFRQWDPLQDWLRQ>@ In most developed countries the relevant laws, environmental standards and economic conditions regulate the collection and disposal of exhausted oils. Increased attention to meeting these laws is stipulated by large amounts of waste oils, high environmental risk they lead to and also the valuable properties of oils as hydrocarbon-containing raw >@$ZHOODGMXVWHGPHFKDQLVPRIUHF\FOLQJZDVWHRLOVSURvides the return them to production or consumption sector as secondary products or intermediates, which provides real VDYLQJWKHUHVRXUFHVLQRLOLPSRUWLQJFRXQWULHV>@ )RUH[DPSOHLQ*HUPDQ\PRUHWKDQPLOOLRQWRQVRI WKHH[KDXVWHGRLOVLVFROOHFWHGDQQXDOO\ZKLOHLQWKH86$± FDPLOOLRQWRQV'HVSLWHWKHVWDELOL]DWLRQRISURGXFWLRQ DQGXVHRIOXEULFDQWVDWWKHOHYHORIPLOOLRQWRQVSHU year, in the coming years, according to experts’ forecasts, the steady amount growth in the collection of waste oils is expected. This is due to the improvement of the legal and economic mechanisms of managing the turnover of commodity and waste oils, the development of technologies for collecting and recycling the latter, strengthening the state and public control over the handling of hazardous wastes and other factors [7]. ([SHUWVHVWLPDWHWKDWWRGD\WKHJOREDOSURGXFWLRQYROXPHRIOXEULFDWLQJRLOVRIGLIIHUHQWEUDQGVLVDERXW POQWRQVSHU\HDU$QLQVLJQL¿FDQWSDUWWKHUHRI is irrevocably lost in the course of use due to evaporation, VSLOOVEXUQRXWDQGOHDNRIIV7KHLUELJJHUSDUWLV gradually contaminated by various metal, mineral and organic impurities, is thermally decomposed through interaction Fig. 1. )RUPDWLRQRIZDVWHDWWKHXQGHUWDNLQJVRIORFRPRWLYHGHSDUWPHQWRIWKH3U\GQLSURYVNDUDLOZD\LQW\HDU 7+('(9(/230(172)1(:7(&+12/2*,(6)25352&(66,1*$1'',6326$/ ZLWKKRWSDUWVRIWKHHTXLSPHQWR[LGL]HGE\DWPRVSKHULF oxygen, exposed to such environmental factors as pressure, HOHFWULF¿HOGDQGQDWXUDOOLJKWLQJ$VDUHVXOWVFDYHQJHRLO completely changes its properties and turns into very thick, ooze-like black or dark-brown substance, thick mixture of YDULRXVNLQGVRIOLTXLGVZLWKDGGLWLRQRIVROLGV±PHWDOR[ides, wear debris. Regeneration of waste oils for railway companies is virtually non-existent, except for certain physical methods (settling DQGFHQWULIXJDWLRQZKLFKGRQRWHQVXUHWKHIXOOHIIHFW>@ $WSUHVHQWZDVWHRLOVDUHRIWHQXVHGZLWKRXWUHJHQHUDtion as heating and boiler fuel directly at railway enterprises or transferred for further use or regeneration to other busiQHVVHVWKDWOHDGVWRVLJQL¿FDQWUHSHDWHGHFRQRPLFH[SHQVHV >@(JWKHUHJHQHUDWLRQRIZDVWHRLOVLVRIWHQFRQGXFWHG LQSHWUROHXPUH¿QHULHVE\DIXOOWHFKQRORJLFDOVFKHPH,WLV a well-known fact that with proper organization of process WKHFRVWRIUHFRYHUHGRLOVLVOHVVE\WKDQWKHFRVWRI WKHIUHVKRLODWDOPRVWWKHVDPHTXDOLW\>@ In the operation, physical and chemical properties of oils vary but experiments have shown that in the main the JURXSFKHPLFDOFRPSRVLWLRQRIWKHRLOYDULHVVOLJKWO\>@ Fig. 2. Diagram of scavenge oil disposal/recycling technologies Products of physicochemical transformations of oils as well as harmful impurities, which get from outside and make the RLOXQ¿WIRUIXUWKHUZRUNDUHRQO\DVPDOOSDUWRIWKHLUWRWDO mass and by means of using special processing methods WKH\FDQEHUHPRYHG$IWHUUHPRYDORIFRQWDPLQDQWVWKH original properties of oils are recovered therefore they can EHUHXVHGLQDPL[WXUHZLWKIUHVKRLOV>@ $MRLQWSURFHVVLQJLQDPL[WXUHZLWKSHWUROHXPDWRLOUH¿QHULHVDQGWKHLUWDUJHWSURFHVVLQJZLWKREWDLQLQJWKHJUHDVH FRPSRQHQWVUHJHQHUDWLRQDUHWKHPDLQDUHDVRISURFHVVLQJ the exhausted oils. *HQHUDOO\UHJHQHUDWLRQPHWKRGVDUHGLYLGHGLQWRSK\Vical, chemical, physical and chemical, biological and comSOH[+HUHLVDVFKHPDWLFGLDJUDPRIDFRPSDUDWLYHDQDO\VLV RIVFDYHQJHRLOGLVSRVDOUHF\FOLQJWHFKQRORJLHV)LJ>@ To physical belong such methods that provide for removal of only mechanical impurities, i.e, dust, sand, metal particles, water, tarry, asphaltum-like substances and carbon blacks, as well as fuel, without affecting the chemical base RIRLOVWREHUH¿QHG7KHVHLQFOXGHVHGLPHQWDWLRQ¿OWUDWLRQ VHSDUDWLRQÀXVKLQJZLWKZDWHUDOVRLIQHFHVVDU\OLJKWIUDFtions recovery is carried out. $11$/(6+&+<16¶.$<8/,<$=(/(1¶.20$5,1$%(=296¶.$0,&+$(/6$1'2:6., 6HGLPHQWDWLRQLVWKH¿UVWDQGPDQGDWRU\RSHUDWLRQRI the regeneration process. Mechanical impurities and water, VXVSHQGHGLQWKHRLOVHGLPHQWDWWKHRLOVWLOOVWDQGE\IRU hours depending on the heating temperature and the height RIWKHOLTXLGFROXPQ6HGLPHQWDWLRQLVEDVHGRQWKHSULQFLSOH of particle settling by gravity. The greater the particles’ sedLPHQWDWLRQUDWHIURP6WRNHVHTXDWLRQWKHELJJHUWKHLUVL]H DQGVSHFL¿FJUDYLW\DQGWKHORZHUWKHÀXLGYLVFRVLW\>@ 6HSDUDWLRQDOORZVIRUGHHSHUSXUL¿FDWLRQRIVFDYHQJHG oil. This is a centrifugation process when products, affected by centrifugal effort, are separated according to their density: the heaviest contaminating impurities are pushed to the walls of the container, forming an annular layer of sediments; the next annular layer is made up of water that is released, and WKHWKLUGRQHORFDWHGQHDUWKHD[LVRIURWDWLRQLVUH¿QHGRLO Filtration is a process of separation of heterogeneous systems through porous walls that block some phases of these systems and let through others. These processes inFOXGHVHSDUDWLRQRIVXVSHQVLRQVLQWRSXUHOLTXLGDQGZHW sediment, such as separation of mechanical impurities or EOHDFKLQJFOD\IURPRLO)LOWHULQJLVRQHRIWKHPRVWHI¿FLHQW methods of regeneration, because it can be used directly in the operation, when the lubrication systems of engines and WRROVLQFOXGHWDLORUPDGH¿OWHUV 7KHGLVDGYDQWDJHRIWKLVPHWKRGLVORZFOHDQLQJHI¿FLHQcy due to the fact that contaminant particulates as small as PLFURQSDVVWKURXJKWKHSRUHVRIWKH¿OWHUV$GGLWLRQDOO\ ¿OWUDWLRQRQO\UHPRYHVPHFKDQLFDOLPSXULWLHVDQGKDVQR effect on the processes that lead to changes in the physical DQGFKHPLFDOSURSHUWLHVRIWKHRLODQGWKHUHIRUHUHTXLUHV IXUWKHUSURFHVVLQJZLWKFKHPLFDOUHDJHQWV>@ In addition to the above-mentioned methods, which refer to the list of physical ones, one should also note thermal methods that allow for getting the heat, but constitute additional challenges due to the installation of expensive HTXLSPHQWDQGDX[LOLDU\PDFKLQHU\IRUFOHDQLQJWKHFRPbustion products [8]. Physical and chemical methods include coagulation and adsorption. During the coagulation the particles of colloidal system coalesce and grow to form loose aggregates, thereby H[DFHUEDWLQJVHGLPHQWDWLRQRIFRQWDPLQDQWV$GVRUEHQWVWDNH LQDQGUHWDLQRQLWVVXUIDFHDVLJQL¿FDQWDPRXQWRIDVSKDOW pitch, acidic compounds, ethers and other products of aging. )RUUHFRYHU\RIRLOVWKDWDUHQRW¿OWHUHGGLIIHUHQWGHWHUJHQWVDQGVXUIDFWDQWVDUHXVHGDVFRDJXODQWV>@ 7KHGLVDGYDQWDJHVRIWKHPHWKRGDUHWKHGLI¿FXOWLHVLQ ¿QGLQJFRDJXODQWVDQGFRQGLWLRQVXQGHUZKLFKWKHFRDJulation process is successful (temperature, necessity and LQWHQVLW\RIPL[LQJ $QLPSRUWDQWFRQGLWLRQIRUDGVRUSWLRQSXUL¿FDWLRQLV the intensity and time of contact of oil with an adsorbent ZKLFKLVXVXDOO\DFKLHYHGE\WZRPHWKRGV,QWKH¿UVWPHWKod an adsorbent is fed into the oil with vigorous stirring of USPZKLFKODVWVIRUDWOHDVWKDOIDQKRXUWKHQ the used adsorbent is separated by sedimentation. The second PHWKRGLVD¿OWUDWLRQWKURXJKDOD\HURIFRDUVHDGVRUEHQW>@ $FRPPRQGLVDGYDQWDJHRIWKHDGVRUSWLRQPHWKRGLV the need for removal of waste adsorbents and sludge, which will no longer be recycled, but simply thrown away, which leads to contamination of the environment. In addition, some DGVRUEHQWVGXHWRLQVXI¿FLHQWO\KLJKPHFKDQLFDOSURSHUWLHV VWUHQJWKUHVLVWDQFHWRDEUDVLRQGHJUDGH¿OWHUSHUIRUPDQFH generally complicating the cleaning process. 4XLWHRIWHQFKHPLFDOPHWKRGVRIUHJHQHUDWLRQDUHXVHG Sulfuric acid, alkaline sodium silicate solutions are used more often than others, but there is a more effective method of chemical treatment , which provides for the use of different selective solvents and their mixtures (phenol, propane, PL[WXUHVRISKHQROZLWKSURSDQHXVHGIRUWUHDWPHQWRIUHsidual oil that belonged to irreversibly lost ones. The disadvantage of the use of sulfuric acid is the presence of residual acid and sulpha compounds that adversely affect the physical and chemical properties of oil and inFUHDVHLWVFRUURVLRQDFWLYLW\$OVRIRUPHGLVDFLGLFVOXGJH ZKLFKLVGLI¿FXOWWRGLVSRVH5HPRYDORIDFLGLFFRPSRXQGV UHTXLUHVDVLJQL¿FDQWLQYHVWPHQWRIWLPHDQGPRQH\DQG LVDFFRPSDQLHGE\DORVVRIXSWRRIRLO$OVRWRJHW a neutral reaction, alkaline agents should be added to the oil. ,QVXI¿FLHQWGHJUHHRIVFDYHQJHRLOSXUL¿FDWLRQE\DOkaline treatment method is associated with the presence in PDQ\RLOVRIGLIIHUHQWW\SHVRIDGGLWLYHVWKDWVLJQL¿FDQWO\ LPSDLUFRDJXODWLRQDQGÀRFFXODWLRQIXQFWLRQVRIDONDOLQH agents. Therefore, for successful regeneration one should FKRRVHVSHFL¿FFRQGLWLRQVIRUHDFKW\SHRIRLO>@ In practice, for better effect the combined methods best VXLWHGWRSURYLGHKLJKTXDOLW\FOHDQLQJDQGUHFRYHU\RI waste oils are applied. 5(68/76',6&866,21 $WWKHUDLOZD\EXVLQHVVHVWKHSHUVRQQHODSSOLHVFRPSUHVVRURLORIPDUN&6DVDOOVHDVRQDOOXEULFDQWIRUIULFWLRQ XQLWVRIFRPSUHVVRUVRIGLHVHOVDQGGLHVHOWUDLQV>@ In the operation, chemical engineering laboratories at each depot investigate oil on suitability for further use, comSDULQJWKHUHVXOWVRIDQDO\]HVZLWKVFUDSLQGLFHV>@QXPHULFYDOXHVRITXDOLW\SDUDPHWHUVZKHQWKHOXEULFDQWVORVH WKHLUIXQFWLRQDOSURSHUWLHV:KHQVDPSOLQJIRUUHMHFWLRQRQ the results of laboratory analysis, the full replacement of oils in compressors is conducted. The analysis of current technologies and schemes of regeneration of waste oils led to drawing the conclusion that the physical-and-chemical methods are the most promising >@LQSDUWLFXODUWKHXVHRIGLIIHUHQWW\SHVRIDGYDQFHG VXUIDFHDFWLYHVXEVWDQFHVVXUIDFWDQWV In the operation, chemical engineering laboratories at each depot investigate oil on suitability for further use, comparing the results of analyzes with scrap indices (numeric YDOXHVRITXDOLW\SDUDPHWHUVZKHQWKHOXEULFDQWVORVHWKHLU IXQFWLRQDOSURSHUWLHV:KHQVDPSOLQJIRUUHMHFWLRQRQWKH results of laboratory analysis, the full replacement of oils in compressors is conducted. The analysis of current technologies and schemes of regeneration of waste oils led to drawing the conclusion that the physical-and-chemical methods are the most promising, in particular the use of different types of advanced VXUIDFHDFWLYHVXEVWDQFHVVXUIDFWDQWV 7+('(9(/230(172)1(:7(&+12/2*,(6)25352&(66,1*$1'',6326$/ $VWKHDERYHWDEOHVKRZVWKHPDLQRSHUDWLQJLQGLFHVRI SXUL¿HGRLOH[FHHGHGWKHUHMHFWLRQLQGLFHVLHLWLVSRVVLEOH to draw the conclusion that the use of this technology gives a positive result. <LHOGRISXUL¿HGSURGXFWZLWKXVLQJWKLVVFKHPHLVDERXW ZKLOHIRUWUHDWPHQWLWZDV 7KHDQDO\VLVRIWKHG\QDPLFVRIIRUPDWLRQ7DEOH of the oil-contaminated waste at the Prydneprovska railZD\VKRZVWKDW±WRQVRIWKHSURFHVVVOXGJHDUHDQQXDOO\ formed at the undertakings of various departments. If you ORRNDWSHUFHQWDJHV\RXFDQVHHWKDWWKH\WDNHXSDVLJQL¿FDQWVKDUHDERXWRIWKHWRWDOYROXPHRIWKHSDVVHQJHU GHSDUWPHQWZDVWH>@ In appearance processing waste represented by process sludge are brown mass, having crumby structure. Often process sludge refers to the third class of hazard and are moderately hazardous. Oil sludge of the operating units of the railways are acTa b l e 2 . &RPSDULVRQRINH\SDUDPHWHUVRIWKHIXO¿OOHGDQG cumulated in wastewater of the undertakings after washing cleared oil with rejection indicators of cars, locomotives and their parts, that is why most of them are formed in the railcar and passenger car de-pots of Parameter Physico-chemical Rejection Rejected the railways, as it is here where washing of the rolling stock valueafter properties index oil cleaning during repair works is made. –1 DFWLYHVXEVWDQFHVVXUIDFWDQWV &RQWDPLQDWLRQIJFP One of the most common ways of disposing oil sludge Flash point in open LVDWKHUPDOPHWKRGVXFKDVLQFLQHUDWLRQ+RZHYHUSURFHVV %HORZ FUXFLEOHɋ sludges are limited combustible substances, for this reason 9LVFRVLW\DWɋ their incineration can be performed only by using additional %HORZ mm2/s TXDQWLWLHVRIIXHO)RUH[DPSOHIRUUDLOZD\XQGHUWDNLQJVLWLV TXDOLW\ SDUDPHWHUV ZKHQ WKH OXEULFDQWV ORVH WKHLU $ONDOLQHQXPEHU IXQFWLRQDOSURSHUWLHV:KHQVDPSOLQJIRUUHMHFWLRQ offered to incinerate them when mixed with solid fuel in the 0.72 PJɄɈɇJ furnaces of stationary steam engines located in the territory Traces Traces :DWHUSHUFHQWDJH of the depot. The ash that remains after burning is recom PHQGHGWRFKHFNIRUWKHSUHVHQFHRIKHDY\PHWDOV>@ We conducted the laboratory studies to recover the properties of waste compressor oils with a wide range of VXUIDFHDFWLYHVXEVWDQFHVVXUIDFWDQWV6SHFL¿FDOO\VRPH TXDQWLW\RIVXUIDFWDQWVWHVWHGDPRQJZKLFKHWK\OR[LGH VRGLXPODXU\OVXOIDWH(PDOGJDYHWKHEHVWUHVXOW ,QGHYHORSLQJWKHVFKHPHRIUHFRYHU\RIRSHUDWLQJTXDOity of waste compressor oils for the purpose of forming and FDOFXODWLQJWKHSURFHVVÀRZGLDJUDPVXJJHVWHGWKHSURFHVV optimization, namely temperature, reagent amount, and time of its contact with oil was conducted. ,Q)LJWKHUHVXOWLVSUHVHQWHGDVWKHTXDOLW\UHFRYHU\ VFKHPHIRUDZDVWHFRPSUHVVRURLO&6GHYHORSHGDQG proposed for railway usage. 7KHREWDLQHGUHVXOWVRIYHUL¿FDWLRQRINH\RSHUDWLRQDO indices of waste compressor oil and comparison of them WRWKHLQGLFHVRIUH¿QHGRLODQGUHMHFWLRQSDUDPHWHUVDUH RITXDOLW\SDUDPHWHUVZKHQWKHOXEULFDQWVORVHWKHLU given in Table 2. IXQFWLRQDOSURSHUWLHV:KHQVDPSOLQJIRUUHMHFWLRQ Ta b l e 3 . $QDO\VLVRIWKHIRUPDWLRQRIRLOFRQWDPLQDWHGZDVWHDWWKH3U\GQLSURYVNDUDLOZD\W\HDU Department or division HOHFWUL¿FDWLRQ water supply passenger Total - 0,08 0,90 - - - - - - - No. Type of waste VXUIDFWDQWV 6SHFLILFDOO\ VRPH TXDQWLW\ RI VRGLXP ODXU\O VXOIDWH (PDO G J 8VHGRLO¿OWHUV 0,08 2 TXDOLW\ Scavenge engine oils RSHUDWLQJ RI ZDVWHFRPSUHVVRU RLOVIRU WKH Oil sludge Oily rags Wastewater residual oils Oil-contaminated soil TXDOLW\UHFRYHU\VFKHPHIRUDZDVWHFRPSUHVVRURLO freight commercial Railway tracks public facilities - car service locomotive DFWLYHVXEVWDQFHVVXUIDFWDQWV GHYHORSHGDQGSURSRVHGIRUUDLOZD\XVDJH Collecting and making waste compressor oil homogeneous +HDWLQJ exhausted oil Sedimentation Centrifugation Fig. 3. Recovery scheme for waste compressor oil Fig. 3. Recovery scheme for waste compressor oil $GGLtion of reagent (mal 270d Mixing Collecting recovered compressor oil $11$/(6+&+<16¶.$<8/,<$=(/(1¶.20$5,1$%(=296¶.$0,&+$(/6$1'2:6., +RZHYHUWKHVHWHFKQRORJLHVDUHORZSURGXFWLRQHQHUJ\ DQG¿QDQFLDOO\FRVWO\EHFDXVHRIWKHKLJKSULFHRIERLOHUV EHVLGHVRQHKDVWRLQVWDOODGGLWLRQDOH[SHQVLYHHTXLSPHQW to purify atmospheric emissions; they do not allow the complete recycling and disposal of oil sludge and do not ensure the environmental safety. When choosing a technology of process sludge disposal, RQHVKRXOGWDNHLQWRDFFRXQWWKHIUHTXHQF\RIIRUPDWLRQRI WKHVHZDVWHVWKHLUOLPLWHGDPRXQWVLJQL¿FDQWFRQVXPSWLRQRI additional fuel to support the combustion process. Therefore, to account for these characteristics of the railway sludge, we offer to apply much cheaper mechanical methods. For example, to install in the depots decanters of different design depending on the overall composition of the sludge and composition of each of its major components: hydrocarbon-bearLQJSDUWLFOHVZDWHUDQGPHFKDQLFDOLPSXULWLHV>@ Decanters provide for oil product incineration in standard containers, the possibility of waste disposal directly at the place of their formation at a special site of any depot. 6LQJOHGRXWVKRXOGEHDEHWWHUTXDOLW\RILQFLQHUDWLRQFRPpared to open burning, high explosive hazard rate as a result of combustion chamber blow-down. $VUDLOZD\RLOVOXGJHVDUHVXI¿FLHQWO\ZDWHUHGEHLQJ the wastes of rolling stock washing, they do not need to be further diluted with water to reduce the percentage of mechanical impurities. It is recommended to use decanters with a screw that is covered with special protection, such as ceramics or tungsten carbide. Such measures are caused by the presence in process sludges of so-called “hard” mechanical impurities (sand, IRUJHVODJPHWDOFKLSVDQGVRRQZKLFKFDQFDXVHSUHPDWXUHZHDURIWKHZRUNLQJSDUWVRIWKHHTXLSPHQW$GGLWLRQally, to prevent ingress of large mechanical impurities into decanter, it is advisable to in-stall strainer screens of various ¿QHQHVVRIWUHDWPHQWRUYLEUDWRU\VHSDUDWRUV The effectiveness of the decanter depends on the parameters of raw materials, such as their homogeneity and WHPSHUDWXUH7KH¿UVWSDUDPHWHUZLOODOORZWKHGHFDQWHUWR run in continuous operation and eliminate the constant human control over the parameters of its operation; indeed, it takes PLQLPXPPLQXWHVIRUWKHHPSOR\HHZKRVHUYLFHVWKH GHFDQWHUWRVHWLWIRUWKHQHFHVVDU\SDUDPHWHUV$QRWKHUSDrameter provides the necessary viscosity of the material and is XVXDOO\&KLJKHUWHPSHUDWXUHVFDQOHDGWRRYHUKHDWLQJ of the device. Typically, this heating is carried out directly in the repository for the oil sludge (by heating intermediate FRQWDLQHUVRU³RQWKHJR´ZLWKVSHFLDOKHDWH[FKDQJHUVZKHQ oil sludge is heated while passing through them. %HORZLQ)LJVKRZQLVWKHJHQHUDOVFKHPHRIVOXGJH processing using a centrifuge-decanter and heat exchanger. Practical research shows that for optimum separation of WKUHHSKDVHVRISURFHVVVOXGJHVUHTXLUHGDUHGLIIHUHQWW\SHV RIÀRFFXODQWVIRUHDFKFDVH'HSHQGLQJRQWKHW\SHRIWKH HTXLSPHQWXVHGIRUWKHWUHDWPHQWRIRLOVOXGJHFHQWULIXJHV ¿OWHUSUHVVHVYDFXXP¿OWHUVVHOHFWHGLVWKHPRVWDSSURSULDWH type of reagent to be used in further processing. )URPWKHH[SHULHQFHRIXVLQJFDWLRQLFÀRFFXODQWVPRVW HIIHFWLYHO\WKH\LQÀXHQFHRUJDQLFFRPSRXQGVZKLOHDQLRQLF ones are more suitable for inorganic substances. Due to the diversity of the structure and properties of sludges, the seOHFWLRQRIHIIHFWLYHÀRFFXODQWVLQHDFKFDVHVKRXOGEHPDGH with prior laboratory and industrial tests. )RUH[DPSOHZLGHO\NQRZQDUHVXFKÀRFFXODQWVDV)7 37=HWDJÀRFFXODQWVLQGXVWULDOSRO\DFU\ODPLGH 3$$DQGRWKHUV7KXVZDWHUEDVHGFDWLRQLFÀRFFXODQW =HWDJPDQXIDFWXUHGE\6ZLVVFRPSDQ\&LED6SHFLDOW\ &KHPLFDOVLVXVHGLQWKHRLOUH¿QHU\LQGXVWU\LQWKHSURFHVV of oil sludge dehydration at the consumption rate of 2 kg per ton of dry residue. Known are the results of studies into the opportunity of VOXGJHWUHDWPHQWLQWKHSUHVHQFHRI=HWDJDQG3UDHVWRO ÀRFFXODQWVDQGSRO\DFU\ODPLGHDWWKHFRQVXPSWLRQUDWH RIJUDPVSHURQHWRQRIVOXGJH7KHUHVXOWVVKRZHGWKDWDW ORZFRQVXPSWLRQRIWKHÀRFFXODQWRQHFDQFOHDUO\VHSDUDWH mechanical impurities from oil products. The content of oil SURGXFWVLQWKHORZHUOD\HUVHGLPHQWZKHQXVLQJ=HWDJ DQG3UDHVWROÀRFFXODQWVZDVDQGLQWKHVHGLPHQW ZLWKRXWÀRFFXODQWV±>@ Fig. 4. 6FKHPDWLFGLDJUDPRIWKHUHDJHQWVOXGJHSURFHVVLQJXVLQJDGHFDQWHUDQGDKHDWH[FKDQJHU±WKHRLOVOXGJHVWRUDJHWDQN ±WKHSXPSV±WKHFRDUVH¿OWHU±WKHKHDWH[FKDQJHU±WKHGHFDQWHUFHQWULIXJH±WKHFRQWDLQHUIRUFROOHFWLQJZDWHU± WKHFRQWDLQHUIRUFROOHFWLQJFHQWUDWHK\GURFDUERQV±WKHFRQWDLQHUIRUFROOHFWLQJVHGLPHQW±WKHFRQWDLQHUIRUSUHSDUDWLRQRI UHDJHQWV±WKHGRVLQJSXPSIRUIHHGLQJUHDJHQWV 7+('(9(/230(172)1(:7(&+12/2*,(6)25352&(66,1*$1'',6326$/ To get rid of wasted mechanical impurities, several RSWLRQVDUHXVXDOO\RIIHUHGWKHLUGLVSRVDODWWKHODQG¿OO burning; gradual decomposition using biologically active sorbents at the specially prepared sites. Under the conditions of the depot it would be reasonable to make gradual accumulation and exportation of wastes to WKHODQG¿OOIRUGLVSRVDO The water that remains after oil sludge treatment is fed IRUWKHSRVWWUHDWPHQWDQGVXEVHTXHQWO\FDQEHXVHGDV already mentioned above, for preparing solution of reagents and included in the production cycle of the enterprise as technical water or the discharged into water bodies. $VUHDJHQWVUHFRPPHQGHGIRUXVHDVÀRFFXODQWVDUH VXUIDFWDQWV6\QWKDQRODQG1HRQRO 6LJQL¿FDQWFRQWULEXWLRQWRWKHKXPDQSUHVVXUHRQWKH environment make metalworking shop of numerous companies, such as machine-building and rail companies (wagon, ORFRPRWLYHGHSRWVHWF>@ ,QWHQVL¿FDWLRQRISURFHVVHVRIPHWDOPHFKDQLFDOWUHDWTXDQWLW\RIGLVFKDUJHVRIH[KDXVWHGSURFHVVOLTXLGV PHQWLPSOHPHQWLQJKLJKSHUIRUPDQFHHTXLSPHQWDXWRPDWed processes, extensive use of structural materials lead to the fact that metal cutting becomes impossible without the XVHRIHI¿FLHQWFRROLQJOXEULFDQWVFRRODQWV Coolants are a water emulsion of mineral oil stabilized by surfactants and various organic additives aimed at preDTXDWLFHQYLURQPHQW5HSHDWHGXVHRIZDVWHZDWHU venting the premature emulsion aging. In the process of use, GRHV QRW UHTXLUH WKHLU GHHS SXULILFDWLRQ LW LV HYHQ the coolant loses its technological properties and needs to EHUHSODFHGZLWKIUHVKRQH$QH[KDXVWHGFRROLQJOXEULFDQW KDYH D QHJDWLYH LPSDFW RQ WKH TXDOLW\ RI SURGXFWV FRRODQWUHIHUVWRKD]DUGFODVV>@ During the use of coolants, they are prone to contamination with: ± VPDOOHVWPHFKDQLFDOSDUWLFOHVLPSXULWLHVHPLWWHGIURP theFRROLQJOXEULFDQWVLQFOXGLQJ(PXOVRO69.XVLQJ oxidized metal layer, sludge after pickling and products of metal wear during pickling and cold rolling; VXUIDFWDQWV (J VXUIDFWDQWV VXFK DV D ± IUHHQRQHPXOVL¿HGRLOVH[WUDFWHGIURPWKHHPXOVLRQ as a result of separation; PRQRDON\OSKHQ\OLF DFLG QHRQRO $) ± RLOVIDOOLQJLQWRDQHPXOVLRQV\VWHPDVDUHVXOWRIOHDNHWKR[\ODWHG VRGLXP ODXU\O VXOIDWH components (PDO G age from the mechanical and hydraulic and FRFDPLGRSURS\ODPLQR[LGH6$2<HYURNVLG652 RWKHUPHWDOWUHDWPHQWHTXLSPHQWDQGVRRQ>@ VWHDUR[ 6\QWDQRO $/0 VXOSKRQRO SDVWD RI 7KHZDVWHFRRODQWHPXOVLRQLVDVSHFLDOW\SHRIVHZDJH PDUNWHFKQLFDOZHUHILUVWWHV water that is very dangerous for the environment, since it FRQWDLQVDODUJHQXPEHURIVWDEOHHPXOVL¿HGSHWUROHXPSURGucts and heavy metals. In this regard, a complex of measures $%6$ZDVLQYHVWLJDWHG$VDUHVHDUFKUHVXOWWKH IRUQHXWUDOL]DWLRQRIZDVWHFRRODQWLVQHFHVVDU\>@ FRPELQDWLRQ RI QHRQRO $) DQG $%6$OHGWR The spent coolant is subject to obligatory rendering safe IURPWKHPRVWWR[LFFRPSRQHQWV([LVWLQJPHWKRGVRIQHX tralizing the emulsions of the kind of coolant-containing sewage water can be divided into three main groups: Collecting and making the waste coolant homogeneous Settling ± WKHUPDO ± SK\VLFRFKHPLFDO ± ELRORJLFDO +RZHYHUQRQHRIWKHVHJURXSVDORQHFDQPHHWWKHPRGHUQUHTXLUHPHQWVFRQFHUQLQJWKHTXDOLW\RIZDWHUDIWHULWV SXUL¿FDWLRQDQGWKHDPRXQWRIZDVWHPDWHULDOVJHQHUDWHG The use of common chemical and physicochemical methods leads to secondary contamination due to the formation of various wastes. Most methods of neutralization of coolDQWFRQWDLQLQJZDVWHZDWHUDUHHLWKHUHFRQRPLFDOO\LQHI¿FLHQWRUHQYLURQPHQWDOO\XQDFFHSWDEOH>@7KHUHIRUHWKH problem of neutralization of coolants remains urgent. Local cleaning the wastewater of various compositions, HOLPLQDWLQJRUUHGXFLQJWKHWRWDOTXDQWLW\RIGLVFKDUJHVRI H[KDXVWHGSURFHVVOLTXLGVGXHWRWKHLUUHJHQHUDWLRQDQG UHXVHRISXUL¿HGVHZDJHZDWHUVLQFORVHGV\VWHPVRIZDWHU turnover and technical water supply in companies can be considered as the most appropriate ways to reduce the harmful effects of contaminated sewage waters of metalworking VKRSVRIYDULRXVLQGXVWULHVRQWKHDTXDWLFHQYLURQPHQW5HSHDWHGXVHRIZDVWHZDWHUGRHVQRWUHTXLUHWKHLUGHHSSXUL¿FDWLRQLWLVHYHQHQRXJKWRUHPRYHRQO\WKRVHVXEVWDQFHV ZKLFKKDYHDQHJDWLYHLPSDFWRQWKHTXDOLW\RISURGXFWVWR be manufactured, and to set their MPC values in the water XQGHUXVDJH>@ :HFRQGXFWHGUHVHDUFKLQWKH¿HOGRIUHQGHULQJVDIH and neutralization of exhausted cooling lubricants, includLQJ³(PXOVRO69.´XVLQJGLIIHUHQWW\SHVRIVXUIDFHDFWLYH VXEVWDQFHVVXUIDFWDQWV(JVXUIDFWDQWVVXFKDVDVSDUDO F, cocamidopropylbetain, oxyethylated monoalkylphenylic DFLGQHRQRO$)HWKR[\ODWHGVRGLXPODXU\OVXOIDWH (PDOGFRFDPLGRSURS\ODPLQR[LGH6$2<HYURNVLG 652VWHDUR[6\QWDQRO$/0VXOSKRQROSDVWDRIPDUN ³WHFKQLFDO´ZHUH¿UVWWHVWHG7RLQWHQVLI\WKHSURFHVVRI sediment loss, the possibility of using an acidic agent such DVDON\OEHQ]HQHVXOIXULFDFLGV$%6$ZDVLQYHVWLJDWHG $VDUHVHDUFKUHVXOWWKHFRPELQDWLRQRIQHRQRO$)DQG $%6$OHGWRWKHEHVWUHVXOW ,Q)LJWKHUHVXOWLVSUHVHQWHGDVVFKHPHIRUQHXWUDOLzation of waste cooling lubricants developed and proposed for railway usage. The use of the technology suggested provides the folORZLQJLQGLFHVWKHGHJUHHRISXUL¿FDWLRQLVWKH\LHOG RISXUL¿HGZDWHULVWKH\LHOGRIRLODQGSHWUROHXP SURGXFWVLV The oil and petroleum products obtained can be offered DVFRPPRGLWLHVWRYDULRXVSHWUROHXPUH¿QHULHVDQGFRPpanies producing concrete constructions, asphalt. +HDWLQJ the waste coolant Percolating through an adsorbent layer Fig. 5.Fig. 1HXWUDOL]DWLRQVFKHPHIRUZDVWHFRROLQJOXEULFDQWFRRODQW 5. Neutralization scheme for waste cooling lubricant FRRODQW 77 $GGing a mixture of reagents Mixing Collecting the purified water 78 $11$/(6+&+<16¶.$<8/,<$=(/(1¶.20$5,1$%(=296¶.$0,&+$(/6$1'2:6., 7KHZDWHUSXUL¿HGFDQEHXVHGLQLQGXVWULDOWXUQRYHUIRU internal consumption or for the preparation of new cooling OXEULFDQWRUZKLOHPDLQWDLQLQJWKHVDQLWDU\UHTXLUHPHQWVLW can be dropped into urban sewer network and even into the water basins. The water after regeneration of the adsorbent can be used for washing a railway rolling stock. The given technology can be applied in metalworking shops of railway enterprises, machine-building, metallurgical and other industries, where coolant-containing drainage is a part of wastewater complex generated. One of the most promising examples of using this technology for recycling DZDVWHFRRODQWLVLWVLQWURGXFWLRQDWORFDOSXUL¿FDWLRQVWDtions of locomotive and wagon depots, as well as railway stations of complex neutralization. CONCLUTIONS 7KHVFKHPHIRUDZDVWHFRPSUHVVRURLO&6GHYHORSHGDQGSURSRVHGIRUUDLOZD\XVDJH<LHOGRISXUL¿HG SURGXFWZLWKXVLQJWKLVVFKHPHLVDERXWZKLOH IRUWUHDWPHQWLWZDV 2. The proposed scheme sludge processing using centrifuge-decanter and heat exchanger. 7KHVFKHPHIRUQHXWUDOL]DWLRQRIZDVWHFRROLQJOXEULcants that proposed for introduction at local treatment plants and locomotive depots, as well as comprehensive utilization railway stations. 7KHWHFKQRORJ\IRUQHXWUDOL]DWLRQRIZDVWHFRROLQJOXEULcants ensures a double effect: the environmental effect (owing to minimizing the amount of waste belonging to the IIIrd class of danger, and rational use of water UHVRXUFHVDQGWKHHFRQRPLFLPSDFWGXHWRUHXVLQJWKH water in the circulating system of water supply as well DVRLODQGSHWUROHXPSURGXFWV 5()(5(1&(6 $QVHURY<X0'XUQHY9'(QJLQHHULQJDQG environmental protection, Leningrad, Mashinostroenie, 2. Bannov P.G., 2005: Principles of analysis and standard PHWKRGVIRUTXDOLW\FRQWURORIRLOSURGXFWV0RVFRZ 7V1,,7(QHIWHKLP %H]RYVND06=HOHQNR<X9 New eco-model himmotolohichni treatment of waste oils railways, 1DWLRQDOVFLHQWL¿FDQGWHFKQLFDOMRXUQDO©4XHVWLRQVRI chemistry and chemical technology», Dnepropetrovsk ©1HZLGHRORJ\ªʋ %H]RYVND06=HOHQNR<X9<DULVKN,QD/2 :DVWHRLOVIRUPDWLRQVWRUDJHUHJHQHUDWLRQ6FLHQWL¿F MRXUQDO©5DLOZD\7UDQVSRUWRI8NUDLQHª.LHY9LGYR '1'7V8=ʋ %H]RYVND 06 =HOHQNR <X9 <DULVKN,QD /2 %DEHQNR2% Utilization of oil sludge and oil JHQHUDWHGLQWKHVWUXFWXUDOXQLWVRIUDLOZD\V6FLHQWL¿F MRXUQDO©5DLOZD\7UDQVSRUWRI8NUDLQHª.LHY9LGYR '1'7V8=ʋ %H]RYVND 06 =HOHQNR <X9 <DULVKN,QD /2 Shevchenko L.V., 2011: Development of a common scheme of regeneration of waste oils railways, Vestnik +178ʋ 7. Boychenko S.V., Ivanov S.V., Burlaka V.G., 2005: MoWRUIXHOVDQGRLOVIRUDPRGHUQWHFKQLTXH0RQRJUDSK .LHY1$8 &KD\ND2+3UHYHQWLRQRI(QYLURQPHQWDO3ROOXWLRQVSHQWPRWRURLO$EVWUDFWIRUWKHGHJUHHRIFDQGLGDWH6F6FLHQFHV6XP\6XP'8 (YGRNLPRY$<X)XNV,*6KDEDOLQD71%DJdasarov L.N., 2000: Lubricating materials and problems RIHFRORJ\0RVFRZ*83,]GYR1HIWLJD]5*8QHIWL LJD]DLP,0*XENLQD 10. Koganovskiy A.M. and others, 1989:3XUL¿FDWLRQRI ZDVWHZDWHUDQGLQGXVWULDO0RVFRZ+LPL\D 11. Kostyuk V.I., Karnauh G.S., 1990: Waste water treatPHQWHQJLQHHULQJFRPSDQLHV.LHY7HKQLND /HVKFK\QVND\D$/ =HOHQ¶NR<9 %H]RYVND\D M.S., 2012:7HFKQRORJ\RIUHVWRUDWLRQRIWKHIXO¿OOHG FRPSUHVVRURLOVRIWKHUDLOZD\HQWHUSULVHV=ELUQLNQDXNRYLKSUDWV'RQ,=7ʋ /HVKFK\QVND\D $/ =HOHQ¶NR <9 %H]RYVND\D M.S., 2013: The use of surfactants to recover waste RLOV1DWLRQDOVFLHQWL¿FDQGWHFKQLFDOMRXUQDO³4XHVWLRQV of chemistry and chemical technology”, Dnepropetrovsk ³1HZLGHRORJ\´ʋ /HVKFK\QVND\D$/=HOHQ¶NR<X96DQGRZVNL0 2013: Development of resource-saving technologies of XWLOL]DWLRQRIWKHIXO¿OOHGOXEULFDQWFRROLQJÀXLGV6FLHQWL¿FMRXUQDO©5DLOZD\7UDQVSRUWRI8NUDLQHª.LHY 9LGYR'1'7V8=ʋ 1LNXOLQ)(Recycling and treatment of indusWULDOZDVWH/HQLQJUDG6XGRVWURHQLH 3ODKRWQLN91<DU\LVKNLQD/$6LUDNRY9,DQG others, 2001: (QYLURQPHQWDODFWLYLWLHVDWWKHUDLOZD\ transport of Ukraine: problems and solutions, Kiev, 7UDQVSRUW8NUDLQ\L 17. Proskuryakov V.A., Shmidt L.I., 1997: Wastewater WUHDWPHQWLQWKHFKHPLFDOLQGXVWU\0RVFRZ+LPL\D 6KDVKNLQ<,%UD\,9 The regeneration of ZDVWHRLOVɛ0RVFRZ+LPL\D 19. Shkolnikov V.M., 1999: Fuels, lubricating materials, WHFKQLFDOOLTXLGV$VVRUWPHQWDQGDSSOLFDWLRQ5HIHUHQFH ERRN0RVFRZ7HKLQIRUP 20. Smetanin V.I., 2003: Protecting the environment from waste production and consumption: a training manual, 0RVFRZ.RORVV 6PLUQRY'1*HQNLQ9(&OHDQLQJRIHIÀXents is in the processes of treatment of metals, Moscow, 0HWDOOXUJL\D 22. Sultan Ramazanov, Anna Voronova, 2014:(FRQRPic-mathematical modeling of rational water use and minimization engineering enterprise’s negative impact RQ WKH HQYLURQPHQW7(.$ &RPPLVVLRQ RI 0RWRU 7+('(9(/230(172)1(:7(&+12/2*,(6)25352&(66,1*$1'',6326$/ DQG(QHUJLQDJULFXOWXUH±/XEOLQ±/XJDQVN± 9RO 23. TsT–0060: Instructions for use of lubricants for tracWLRQUROOLQJVWRFNRIUDLOZD\VRI8NUDLQH, Kiev, 6WDQGDUW =HOHQNR<X96FLHQWL¿FEDVHVRIHFRORJLFDOVDIHty of technology of transporting and use of oil products on a railway transport: Monograph, Dn-vsk, Vid-vo MaNRYHWVNL\ =HUNDORY'9(FRQRP\RIRLOSURGXFWV.LHY 729Ä0,]KQDUI,QDJHQWV,\D´ =HUNDORY'9(FRORJL]DWLRQRIHQHUJ\FRQVXPSWLRQ.LHY729Ä0L]KQDU¿QDJHQWVL\D´ 79 ɊȺɁɊȺȻɈɌɄȺɇɈȼȿɃɒɂɏɌȿɏɇɈɅɈȽɂɃ ɉȿɊȿɊȺȻɈɌɄɂɂɍɌɂɅɂɁȺɐɂɂ ɇȿɎɌȿɋɈȾȿɊɀȺɓɂɏɈɌɏɈȾɈȼɉɊȿȾɉɊɂəɌɂɃ ɀȿɅȿɁɇɈȾɈɊɈɀɇɈɃɂɇɎɊȺɋɌɊɍɄɌɍɊɕ Ⱥɧɧɨɬɚɰɢɹȼɫɬɚɬɶɟɪɚɫɫɦɨɬɪɟɧɵɬɪɚɞɢɰɢɨɧɧɵɟɦɟɬɨɞɵ ɭɬɢɥɢɡɚɰɢɢɢɪɟɝɟɧɟɪɚɰɢɢɨɬɪɚɛɨɬɚɧɧɵɯɫɦɚɡɨɱɧɨɨɯɥɚɠɞɚɸɳɢɯɠɢɞɤɨɫɬɟɣɢɤɨɦɩɪɟɫɫɨɪɧɵɯɦɚɫɟɥɉɪɢɪɚɡɪɚɛɨɬɤɟɫɯɟɦɪɟɝɟɧɟɪɚɰɢɢɧɟɮɬɟɫɨɞɟɪɠɚɳɢɯɨɬɯɨɞɨɜɫɰɟɥɶɸ ɮɨɪɦɢɪɨɜɚɧɢɹɢɪɚɫɱɟɬɚɩɪɟɞɥɨɠɟɧɧɵɯɬɟɯɧɨɥɨɝɢɱɟɫɤɢɯ ɫɯɟɦɛɵɥɚɩɪɨɜɟɞɟɧɚɨɩɬɢɦɢɡɚɰɢɹɬɟɯɧɨɥɨɝɢɱɟɫɤɨɝɨɩɪɨɰɟɫɫɚɚɢɦɟɧɧɨɬɟɦɩɟɪɚɬɭɪɵɤɨɥɢɱɟɫɬɜɚɪɟɚɝɟɧɬɚɢɜɪɟɦɟɧɢ ɤɨɧɬɚɤɬɚɉɪɟɞɥɨɠɟɧɵɧɨɜɵɟɬɟɯɧɨɥɨɝɢɢɫɢɫɩɨɥɶɡɨɜɚɧɢɟɦ ɩɨɜɟɪɯɧɨɫɬɧɨɚɤɬɢɜɧɵɯɜɟɳɟɫɬɜ Ʉɥɸɱɟɜɵɟ ɫɥɨɜɚ ɨɬɪɚɛɨɬɚɧɧɵɟ ɤɨɦɩɪɟɫɫɨɪɧɵɟ ɦɚɫɥɚ ɫɦɚɡɨɱɧɨɨɯɥɚɠɞɚɸɳɢɟɠɢɞɤɨɫɬɢɩɨɜɟɪɯɧɨɫɬɧɨɚɤɬɢɜɧɵɟ ɜɟɳɟɫɬɜɚɷɤɨɥɨɝɢɱɟɫɤɚɹɛɟɡɨɩɚɫɧɨɫɬɶɭɬɢɥɢɡɚɰɢɹ TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 81–86 Strength Properties of Horse Bean Seeds (Vicia faba L. var. minor) Rafał Nadulski1, Jacek Skwarcz2, Grzegorz Łysiak3, Ryszard Kulig3 Department of Food Engineering and Machines, Department of Equipment Operation and Maintenance in the Food Industry University of Life Sciences, Doświadczalna 44, 20-280 Lublin, Poland, e-mail: [email protected] 2 Department of Technology Fundamentals, University of Life Sciences, ul. Doświadczalna 50A, 20-280 Lublin, Poland 1 3 Received December 02.2014; accepted December 17.2014 Summary. The research results of the seed strength properties concerning three horse bean varieties are presented here. The LQYHVWLJDWLRQZDVFDUULHGRXWXQGHUTXDVLVWDWLFFRQGLWLRQVE\ PHDQVRIWKHDSSDUDWXV,QVWURQ,QGLYLGXDOKRUVHEHDQVHHGV were placed with their cotyledons parallel to the apparatus base and loaded with plate, slat or penetrator. The maximum force values and corresponding to them deformation values capable of transporting a seed to the destruction moment have been read off from the obtained force-deformation characteristics. In the course of investigations, it was found out that the hardness features depended to a great extent on a given variety. It has been stated additionally that the increase of seeds moisture content causes a considerable decrease of their hardness. Key words: horse bean, variety, strength properties. INTRODUCTION (Vicia faba L. var. minorKDUGQHVV7KHLQYHVWLJDWLRQVRQ this subject have been carried out only by few researches >@2QO\IHZSDSHUVGHDOZLWKLQYHVWLJDWLRQV of mechanical properties of (Vicia faba L. var. major> 8]. Taking into consideration the fact that the knowledge of horse bean seeds hardness is indispensable in working out technological processes and preservation of machines necessary in their processing and allows to characterize the TXDOLW\RIPDWHULDODQGWKHUHIRUHLWLVZHOOPRWLYDWHGWR carry out the research work whose results aim at establishing the characteristics of horse bean seeds (Vicia faba L. var. minor,QPHDVXULQJVHHGUHVLVWDQFHORDGLQJE\PHDQVRI penetrators with different endings /in the shape of cylinder, cone, or semicircle/ has been used. Taking into account fact that in processing seed material into feed there is a wide use of a beater in which a working element differs in its shape from loading elements used in resistance measurements, it has been decided to carry out such investigations using DORDGLQJVODWZLWKEOXQWHGJH±DQHOHPHQWVLPLODULQLWV shape to beater. The seed of loading plays an important role in all investigations concerning seed resistance that aim at UHÀHFWLQJWKHFRQGLWLRQVDSSUR[LPDWLQJWKHVHLQUHDOOLIH while to carry out any investigations under such conditions LVYHU\GLI¿FXOWWKHUHIRUHPHDVXUHPHQWVSUHVHQWHGKHUHKDYH EHHQFDUULHGRXWXQGHUTXDVLVWDWLFORDGLQJFRQGLWLRQV The goal of this research work has been to determine hardness features of horse bean seeds having different moisWXUHFRQWHQWXQGHUTXDVLVWDWLFORDGLQJRIVHHGVZLWKSODWH VODWDQGSHQHWUDWRU$GGLWLRQDOO\WKHUHVXOWVREWDLQHGHQDEOHG to comparison of the values of seed resistance measured by three different methods. ,Q3RODQGZKHUHDQLPDOIHHGLQJLV,QEDVHGRQ LPSRUWHGVR\DJULWVWKHFUXFLDOSUREOHPLV¿QGLQJWKHDOWHUQDWLQJVRXUFHRISURWHLQLQDQLPDOIHHGLQJ>@2LOLQGXVWU\ SURGXFWVUDSHVHHGRLOFDNHDQGSUHVVFDNHDVZHOODVVHHGV RIOHJXPLQRXVSODQWVHJOXSLQHKRUVHEHDQDQGSHDDUH the domestic products which can replace soya bean having FRPSDUDEOHSURWHLQFRQWHQW>@+RUVHEHDQVHHGVFRQWDLQLQJ IURPWRRIWKHSURWHLQFRQVWLWXWHDJRRGFRPSRQHQW IRUWKHSURGXFWLRQRIWKHIHHGPL[WXUH>@7KHSURWHLQIURP horse bean seeds is characterized by the high biological value and the wide usefulness for feeding. The interest in horse bean (Vicia faba SPP. minorFXOWLYDWLRQDVDYDOXDEOH feeding has developed in Poland and other countries with VLPLODUFOLPDWHFRQGLWLRQV>@ The physical properties of seeds are to be known for 0$7(5,$/$1'0(7+2'6 design and improve of relevant machines and facilities for KDUYHVWLQJVWRULQJKDQGOLQJDQGSURFHVVLQJ> The research work has been carried out on horse bean @$ZLGHVXUYH\RIOLWHUDWXUHVKRZVVPDOOQXPEHURISXElications in the research work concerning horse bean seeds VHHGVRI'ĊEHN1DGZLĞODĔVNLDQG-DVQ\YDULHWLHV,QRUGHUWR ĊEHN DGZLĞODĔVNL ĊEHN DGZLĞODĔVNL 82 5$)$à1$'8/6.,-$&(.6.:$5&=*5=(*25=à<6,$.5<6=$5'.8/,* DGZLĞODĔVNL &͕E &͕E &͕E &͕E HVWDEOLVKWKHLQÀXHQFHRIVHHGVPRLVWXUHFRQWHQWDQGVL]HRQ E\SHQHWUDWRU,QWKLVFDVHPD[LPXPIRUFHVDUHQHDUO\ the investigated hardness features, the input material was hu- times higher than the minimum ones. Much smaller differ- DGZLĞODĔVNL PLGL¿HGLQWRHLJKWPRLVWXUHFRQWHQWOHYHOVLQWKHUDQJHIURP ences between the maximum and minimum forces were % WR% every ca 2 %, and then it was divided according observed in case of seeds loaded with a plate. to thickness. The seeds moisture contents were determined The changes of the values of deformation forces dependusing the oven-drying method. Selected fractionVKRZQLQ)LJDQG of seeds with LQJRQVHHGPRLVWXUHFRQWHQWZHUHVKRZQLQ)LJDQG thickness from 7.0 to 8.0 mm was used for the compression The increase of seed moisture content causes a considerable VKRZQLQ)LJDQG ϳϬϬ of their hardness. H[SHULPHQWV)RUHDFKPRLVWXUHUHSHWLWLRQVZHUHGRQH decrease their hardness. &Ŷсϭϭϱϯ͕ϯĞͲϬ͕ϬϴǁZϸсϬ͕ϵϰϴ The measurements of hardness features have been carried ϲϬϬ ϳϬϬ &ĐсͲϭϬ͕ϴϭǁнϯϭϴ͕ϭϴZϸсϬ͕ϵϲϯ RXWE\PHDQVRI,QVWURQDSSDUDWXVHTXLSSHGZLWKKHDG &Ŷсϭϭϱϯ͕ϯĞͲϬ͕ϬϴǁZϸсϬ͕ϵϰϴ ϱϬϬ ϲϬϬ ZLWKDORDGLQJUDQJHN1,QGLYLGXDOVHHGVKDYHEHHQ &ƉсϭϮϴϬ͕ϰĞͲϬ͕ϭϳϮǁZϸсϬ͕ϵϴϵ &ĐсͲϭϬ͕ϴϭǁнϯϭϴ͕ϭϴZϸсϬ͕ϵϲϯ ϰϬϬ placed with their cotyledons parallel to the lower stationary ϱϬϬ &Ŷ &ƉсϭϮϴϬ͕ϰĞͲϬ͕ϭϳϮǁZϸсϬ͕ϵϴϵ plate, and then, they were loaded by means of a disc, cutting ϯϬϬ ϰϬϬ &Đ VODWPPWKLFNRUDSHQHWUDWRUZLWKDF\OLQGHUHQGZLWKGL&Ŷ ϮϬϬ &Ɖ ϯϬϬ DPHWHUPPWKLFN/RDGLQJHOHPHQWVKDYHEHHQPRYLQJ &Đ -1 ϭϬϬ LQDOOFDVHVZLWKDFRQVWDQWVSHHGY PPÂPLQ according ϮϬϬ &Ɖ WRWKHVWDQGDUGSURSRVLWLRQSUHVHQWHGE\)UąF]HNHWDO>@ Ϭ ϭϬϬ The loading force operated along the seed thickness. The ϭϬ ϭϱ ϮϬ Ϯϱ Ϭ ǁ͕й measurements have been carried out to the seed destruction ϭϬ ϭϱ ϮϬ Ϯϱ moment i. e. splitting, cutting, or puncturing of seed coat. ǁ͕й $IWHUWKDWWKH\HQGHG7KHIRUFHFXUYHDVGHIRUPDWLRQIXQF)LJ7KHLQIOXHQFHRIPRLVWXUHFRQWHQW tions were recorded. Then, the values of deformation forces Fig. 1. 7KHLQÀXHQFHRIPRLVWXUHFRQWHQWRQGHIRUPDWLRQ SHQHWUDWRU DQGVODW ĊEHN )LJ7KHLQIOXHQFHRIPRLVWXUHFRQWHQW for the seeds loaded with plate Fn, slat Fc or penetrator Fp IRUFHIRUKRUVHEHDQVHHGYDULHW\'ĊEHNORDGHGE\SODWHF n (FpDQGVODWFc were read from the obtained graphs together with the relative penetrator ĊEHN SHQHWUDWRU DQGVODW deformation values (en, ec, epFRUUHVSRQGLQJWR these forces. ϳϬϬ The deformation work for seeds loaded with plate (WnVODW &Ŷсϭϰϱϱ͕ϰĞͲϬ͕ϭϬdžZϸсϬ͕ϵϴϲ ϲϬϬ (WcDQGSHQHWUDWRUWpZDVGHWHUPLQHGDVWKHDUHDEHORZ ϳϬϬ &ĐсͲϭϲ͕ϭϴϭǁнϰϯϴ͕ϳϰZϸсϬ͕ϵϵϮ WKHFXUYHLQWKHIRUFH±GHIRUPDWLRQUHODWLRQ>@ &Ŷсϭϰϱϱ͕ϰĞͲϬ͕ϭϬdžZϸсϬ͕ϵϴϲ ϱϬϬ ϲϬϬ &ƉсϮϱϱϯ͕ϵĞͲϬ͕ϮϬǁZϸсϬ͕ϵϵϮ Statistical analysis of the data was performed with Sta&ĐсͲϭϲ͕ϭϴϭǁнϰϯϴ͕ϳϰZϸсϬ͕ϵϵϮ ϰϬϬ ϱϬϬ WLVWLFDVRIWZDUH6WDWLVWLFD6WDW6RIW,QF7XOVD2. &Ŷ &ƉсϮϱϱϯ͕ϵĞͲϬ͕ϮϬǁZϸсϬ͕ϵϵϮ ϯϬϬ 86$XVLQJDQDO\VLVRIYDULDQFHIRUIDFWRULDOGHVLJQV7KH ϰϬϬ &Đ &Ŷ VLJQL¿FDQFHRIGLIIHUHQFHVEHWZHHQPHDQYDOXHVZDVGHϮϬϬ &Ɖ ϯϬϬ &Đ WHUPLQHGXVLQJ)LVKHU¶VH[DFWWHVWDWDOHYHORIS ϭϬϬ ϮϬϬ The investigation parameters have been made to depend &Ɖ Ϭ on moisture content and the obtained relations have been ϭϬϬ ϭϬ ϭϱ ϮϬ Ϯϱ GHVFULEHGE\PHDQVRIUHJUHVVLRQHTXDWLRQ Ϭ ϭϬ ,Q7DEOHWKHPLQLPDODQGPD[LPXPIRUFHYDOXHVREtained by means of different methods of horse bean seed loading has been presented. The highest hardness value of seeds loaded by plate, slat and penetrator is characteristic of dry horse bean seed of Jasny variety. The lowest hardness value of seeds loaded by plate, slat and penetrator is charDFWHULVWLFRIGU\KRUVHEHDQVHHGRI'ąEHNYDULHW\ ǁ͕й ϮϬ Ϯϱ Fig. 2. 7KHLQÀXHQFHRIPRLVWXUHFRQWHQWRQGHIRUPDWLRQ ǁ͕й RQGHIRUPDWLRQI IRUFHIRUKRUVHEHDQVHHGYDULHW\1DGZLĞODĔVNLORDGHGE\SODWH (FnSHQHWUDWRUFpDQGVODWFc SHQHWUDWRU DQGVODW 1DGZLĞODĔVNL RQGHIRUPDWLRQI ϳϬϬ &Ŷсϭϳϱϳ͕ϴĞͲϬ͕ϭϭǁZϸсϬ͕ϵϲϲϭ ϲϬϬ &ĐсͲϭϰ͕ϰϰǁнϰϯϳ͕ϳϱZϸсϬ͕ϵϵϴ ϱϬϬ &͕E 5(68/7$1'',6&866,21 ϭϱ &ƉсϮϵϲϴ͕ϰĞͲϬ͕ϭϵǁZϸсϬ͕ϵϴϭ ϰϬϬ &Ŷ ϯϬϬ &Đ ϮϬϬ Ta b l e 1 . Deformation force F values for horse bean seeds loaded by plate, slat and penetrator Moisture Variety content, 'ĊEHN 1DGZLĞODĔVNL Jasny ([WUHPHYDOXHRIIRUFHV)1 penetrator plate loading slat loading loading )LJ7KH &Ɖ ϭϬϬ Ϭ ϭϬ ϭϱ ϮϬ Ϯϱ ǁ͕й Fig. 3. 7KHLQÀXHQFHRIPRLVWXUHFRQWHQWRQGHIRUPDWLRQ force for horse bean seed variety Jasny loaded by plate (Fn penetrator (FpDQGVODWFc SHQHWUDWRU DQGVODW The greatest difference of force values occur in the case In Table 2 the relative deformation values corresponding RIKRUVHEHDQVHHGVRI1DGZLĞODĔVNLL-DVQ\YDULHW\ORDGHG to the deformation force values obtained by seed loaded with FDVHVKDYHEHHQREWDLQHGIRUKRUVHEHDQVHHGVZLWKDERXW 675(1*7+3523(57,(62)+256(%($16(('6 ϯϬ ϮϬ ĞŶ ϭϱ ĞĐ ϭϬ Ta b l e 2 . Relative deformation e values for horse bean seeds loaded by plate, slat and penetrator Min-max value of relative deformation e Variety penetrator plate slat loading loading loading 'ĊEHN 1DGZLĞODĔVNL Jasny ĞŶсͲϬ͕ϬϵdžϮнϰ͕ϰϳǁͲϯϬ͕ϵϳϯZϸсϬ͕ϵϵϲ Ϯϱ Ğ͕й plate, slat and penetrator have been presented. It has been stated that deformation values depend moisture content and horse bean variety. The highest deformation values in all loading cases have been obtained for horse bean seeds with DERXW% moisture content of Jasny variety. ĞĐсϭ͕ϯϱǁͲϲ͕ϱϮZϸсϬ͕ϵϴϴ ϱ Moisture content, ĞƉ ĞƉсϬ͕ϳϰǁͲϬ͕ϲϭZϸсϬ͕ϵϵϭ Ϭ ϭϬ ϭϱ ϮϬ Ϯϱ ǁ͕й Fig. 6. 7KHLQÀXHQFHRIPRLVWXUHFRQWHQWRQUHODWLYHGHIRUmation e for horse bean seed variety Jasny loaded by plate (en slat (ecDQGSHQHWUDWRUep VODW DQGSHQHWUDWRU For all the varieties, the increase of seed moisture content ,Q7DEOHWKHZRUNRIGHIRUPDWLRQYDOXHVREWDLQHG ,Q7DEOHWKHZRUNRIGHIRUPDWLRQYDOXHVREWDLQHGE\VHHGORDGHGZLWKSODWH causes the increase of deformation values and the maxi- by seed loaded with plate, slat and penetrator have been PDOYDOXHVDUHWLPHVKLJKHUWKDQPLQLPDO7KHORZHVW presented. It has been stated that the work of deformation values of the relative deformation were obtained for seeds values depend on moisture content of seeds and horse bean loaded with the penetrator. The changes of the values of variety. The biggest differences between the minimum and relative deformation depending on seed moisture content maximum values of the deformation work were observed 7DEOH ZHUHVKRZQLQ)LJDQG,QHDFKFDVHWKHLQFUHDVHLQ in case of the penetrometric test. value of work of deformation moisture content of seeds causes the increase in the relative Moisture deformation values. Ta b l e 3 . Work of deformation W values for horse bean seeds penetrator loading slat loading loadedFRQWHQW by plate, slat and penetrator ϯϬ ϯϬ Ϯϱ Ϯϱ Ğ сͲϬ͕ϭϭǁϮнϱ͕ϭϰǁͲϯϲ͕ϲϯZϸсϬ͕ϵϵϰ ĞŶŶсͲϬ͕ϭϭǁϮнϱ͕ϭϰǁͲϯϲ͕ϲϯZϸсϬ͕ϵϵϰ ĊEHN Ğ͕й Ğ͕й ϮϬ ϮϬ ϭϱ ϭϱ ϭϬ ϭϬ Ğ сϭ͕ϮϳǁͲϳ͕ϭϭZϸсϬ͕ϵϴϯ ĞĐĐсϭ͕ϮϳǁͲϳ͕ϭϭZϸсϬ͕ϵϴϯ ϱ ϱ ĞŶ ĞĐ ĞĐ ĞƉ ĞƉ Ğ сϬ͕ϲϵǁͲϭ͕ϵϰZϸсϬ͕ϵϳϯ ĞƉƉсϬ͕ϲϵǁͲϭ͕ϵϰZϸсϬ͕ϵϳϯ The changes of the values of relative deformation depending on the seed moisture content were shown in Fig. 7, 8 and 9. In case of seeds loaded with plate and slat the value ǁ͕й ǁ͕й of deformation work gradually increases with the increase Fig. 4. 7KHLQÀXHQFHRIPRLVWXUHFRQWHQWRQUHODWLYHGHIRU- in moisture content of seeds and after reaching the maxi mation ĊEHN eIRUKRUVHEHDQVHHGYDULHW\'ĊEHNORDGHGE\SODWHe VODW DQGSHQHWUDWRU n mum it slightly decreases. In case of the penetrometric test ĊEHN slat (ecDQGSHQHWUDWRUep VODW DQGSHQHWUDWRU the increase in seed moisture causes the constant gradual decrease in work deformation value. Ϭ Ϭ Min-max value - - 0.007 of work of deformation W, J penetrator plate -0.292 - slat loading loading loading - - 0.022 1DGZLĞODĔVNL Jasny Moisture - Variety content, DGZLĞODĔVNL - ĞŶ 'ĊEHN- ϭϬ ϭϬ ϯϬ ϯϬ ϭϱ ϭϱ ϮϬ ϮϬ Ϯϱ Ϯϱ ĞŶсͲϬ͕ϭϭǁϮϮнϱ͕ϯϬǁͲϯϳ͕ϲϮZϸсϬ͕ϵϵϱ ĞŶсͲϬ͕ϭϭǁ нϱ͕ϯϬǁͲϯϳ͕ϲϮZϸсϬ͕ϵϵϱ Ϯϱ Ϯϱ ϯϬ Ϯϱ ϭϬ ϭϬ ĞĐсϭ͕ϮϵǁͲϲ͕ϮϲZϸсϬ͕ϵϴϵ ĞĐсϭ͕ϮϵǁͲϲ͕ϮϲZϸсϬ͕ϵϴϵ ϱ ϱ Ϭ Ϭ ϮϬ Ğ͕й ĞŶ ĞŶ ĞĐ ĞĐ ĞƉ ĞƉ ϭϱ ϭϱ ĞƉсϬ͕ϲϲǁͲϬ͕ϵϵZϸсϬ͕ϵϳϮ ĞƉсϬ͕ϲϲǁͲϬ͕ϵϵZϸсϬ͕ϵϳϮ ϭϬ ϭϬ ϭϱ ϭϱ ǁ͕й ǁ͕й ϮϬ ϮϬ ĞĐ ĞĐсϭ͕ϮϳǁͲϳ͕ϭϭZϸсϬ͕ϵϴϯ ϱ Ϯϱ Ϯϱ Fig. 5. 7KHLQÀXHQFHRIPRLVWXUHFRQWHQWRQUHODWLYHGHIRU)LJ7KHLQIOXHQFHRIPRLVWXUHFRQWHQW mation eIRUKRUVHEHDQVHHGYDULHW\1DGZLĞODĔVNLORDGHGE\ )LJ7KHLQIOXHQFHRIPRLVWXUHFRQWHQW 1DGZLĞODĔVNL VODW DQGSHQHWUDWRU 1DGZLĞODĔVNL VODW DQGSHQHWUDWRU plate (enVODWecDQGSHQHWUDWRUe p ĞŶ ϭϱ ϭϬ ĞƉ ĞƉсϬ͕ϲϵǁͲϭ͕ϵϰZϸсϬ͕ϵϳϯ Ϭ ϭϬ ϭϱ ϮϬ Ϯϱ ǁ͕й Fig. 7. 7KHLQÀXHQFHRIPRLVWXUHFRQWHQWRQWKHZRUNRI GHIRUPDWLRQIRUKRUVHEHDQVHHGYDULHW\'ĊEHNORDGHGE\SODWH ĊEHN VODW DQGSHQHWUDWRU (WnSHQHWUDWRUWpDQGVODWW c ϯϬ Ϯϱ ĞŶсͲϬ͕ϭϭǁϮнϱ͕ϯϬǁͲϯϳ͕ϲϮZϸсϬ͕ϵϵϱ ϮϬ Ğ͕й Ğ͕й Ğ͕й ϮϬ ϮϬ ĞŶсͲϬ͕ϭϭǁϮнϱ͕ϭϰǁͲϯϲ͕ϲϯZϸсϬ͕ϵϵϰ ϭϱ ĞŶ ϭϬ ϭϱ ϮϬ Ϯϱ ǁ͕й ĊEHN ϯϬ VODW DQGSHQHWUDWRU 5$)$à1$'8/6.,-$&(.6.:$5&=*5=(*25=à<6,$.5<6=$5'.8/,* between the relative deformation and seed moisture was GHVFULEHGZLWKWKHOLQHDUHTXDWLRQLQFDVHRIVHHGVORDGHG ZLWKWKHVODWDQGSHQHWUDWRUDQGZLWKTXDGUDWLFHTXDWLRQV ϮϬ in case of loading the seeds with the slat. ,QFDVHRIVHHGORDGHGZLWKWKHSODWHDQGVODWHWKHLQĞŶ ϭϱ crease in seed moisture causes the gradual increase in ĞĐ ϭϬ deformation work and after reaching the maximum the ĞƉ ĞĐсϭ͕ϮϵǁͲϲ͕ϮϲZϸсϬ͕ϵϴϵ decrease in its value. In case of the penetrometric test ϱ ĞƉсϬ͕ϲϲǁͲϬ͕ϵϵZϸсϬ͕ϵϳϮ increase of seeds moisture content causes a considerable Ϭ decrease of deformation force. The dependence between ϭϬ ϭϱ ϮϬ Ϯϱ the deformation work and seed moisture was described ǁ͕й E\TXDGUDWLFHTXDWLRQVLQFDVHRIVHHGORDGHGZLWKWKH SODWHDQGVODWDQGE\H[SRQHQWLDOHTXDWLRQVLQFDVHRI Fig. 8. 7KHLQÀXHQFHRIPRLVWXUHFRQWHQWRQWKHZRUNRI )LJ7KHLQIOXHQFHRIPRLVWXUHFRQWHQW GHIRUPDWLRQIRUKRUVHEHDQVHHGYDULHW\1DGZLĞODĔVNLORDGHG penetrometric test. 1DGZLĞODĔVNL VODW DQGSHQHWUDWRU by plate (WnSHQHWUDWRUWpDQGVODWWc 7KHFKRLFHRIVWUHQJWKWHVWLQÀXHQFHVWKHVFRSHDQG dynamics of changes of seed resistance for mechanical ϯϬ loading. Thus, to describe fully the changes of seed reϮ ĞŶсͲϬ͕Ϭϵdž нϰ͕ϰϳǁͲϯϬ͕ϵϳϯZϸсϬ͕ϵϵϲ sistance for mechanical loading it is advisable to use the Ϯϱ results obtained in different strength tests. ĞŶсͲϬ͕ϭϭǁϮнϱ͕ϯϬǁͲϯϳ͕ϲϮZϸсϬ͕ϵϵϱ Ğ͕й Ϯϱ Ğ͕й ϮϬ ĞŶ ϭϱ ϭϬ ĞĐ ĞĐсϭ͕ϯϱǁͲϲ͕ϱϮZϸсϬ͕ϵϴϴ ĞƉ 5()(5(1&(6 $OWXQWD(<ÕOGÕ]0(IIHFWRIPRLVWXUHFRQWHQW on some physical and mechanical properties of faba bean Ϭ (Vicia faba LJUDLQV-RXUQDORI)RRG(QJLQHHULQJ ϭϬ ϭϱ ϮϬ Ϯϱ ± ǁ͕й 2. ']LNL ' &DFDN3LHWU]DN * %LHUQDFND % -RĔ F]\N . 5yĪ\áR 5 *áDG\V]HZVND % The Fig. 9. 7KHLQÀXHQFHRIPRLVWXUHFRQWHQWRQWKHZRUNRI seed variety Jasny loaded by plate deformation for horse bean grinding energy as an indicator of wheat milling value. VODW (WnSHQHWUDWRUWpDQGVODWW DQGSHQHWUDWRU 7(.$&RPPLVVLRQRI0RWRUL]DWLRQDQG(QHUJHWLFVLQ c $JULFXOWXUH9RO ,Q7DEOHWKHZRUNRIGHIRUPDWLRQYDOXHVREWDLQHGE\VHHGORDGHGZLWKSODWH The carried out analysis shows that using only one test in )UąF]HN-.DF]RURZVNL-ĝOLSHN=+RUDELN- seed strength tests may not be enough. It is essential especially Molenda M. 2003. Standarization of methods for the in case of the measurement of deformation work of loaded measurement of the physico-chemical properties of plant seeds. Different relationship between deformation work and JUDQXODUPDWHULDOVLQ3ROLVK$FWD$JURSK\VLFD seed moisture is observed depending on the test. In case of Gorzelany, J., Puchalski, C. 1994. The effect of load7DEOH deformation strength and relative deformation, however, difing-force direction and magnitude on mechanical damferent scope and dynamics of the change with the increase in value of work of deformation DJHWRKRUVHEHDQVHHGV=HPƟGƟOVND7HFKQLND seed moisture depending on the used strength test was noticed. Moisture penetrator Grochowicz J., Andrejko D. 2006.(IIHFWRIWKHPRLVFRQWHQW loading slat loading ture content on energy consumption at grinding of lupine CONCLUSIONS VHHGV7(.$&RPPLVVLRQRI0RWRUL]DWLRQDQG(QHUJHW- - 0.007 ĊEHN - LFVLQ$JULFXOWXUH9RO -0.292 - DGZLĞODĔVNL Grochowicz J., Nadulski R. 1984. 7KH,QÀXHQFH+XThe- carried out investigations concerning hardness allow to formulate the following conclusions: PLGLW\DQG+RUVH%HDQ6L]HRQ7KHLU6WUHQJWK&KDU- - 0.022 - 'HIRUPDWLRQIRUFHUHODWLYHGHIRUPDWLRQDQGZRUNRI DFWHULVWLFV&RQIHUHQFHPDWHULDOV9,,*ROORąXLXP*DWH ±3$1$JULFXOWXUDO8QLYHUVLW\*RGROOR+XQJDU\ deformation depend on horse bean variety. 2. In the case of the all used tests the increase of seeds 7. Grochowicz J., Nadulski R. 1985. The Mechanical moisture content causes a considerable change of their Properties of Some Leguminous Plant Seeds. Conferstrength properties. HQFH PDWHULDOV UG ,QWHUQDWLRQDO &RQIHUHQFH &,*5 7KHLQFUHDVHLQVHHGPRLVWXUHFDXVHVWKHVLJQL¿FDQW ³3K\VLFDO3URSHUWLHVRI$JULFXOWXUDO0DWHULDOV´3UDJD Czechoslovakia, 289-292. decrease in the value of deformation strength. The dependence between the deformation strength and seed 8. +DFÕVHIHURJXOODUÕ + *H]HU , %DKWL\DUFD < PRLVWXUHZDVGHVFULEHGE\H[SRQHQWLDOHTXDWLRQVLQFDVH 0HQJH+2Determination of some chemical and of loading the seeds with the plate and penetrator and by SK\VLFDOSURSHUWLHVRI6DNÕ]IDEDEHDQVicia faba L. Var. OLQHDUHTXDWLRQVLQFDVHRIVHHGVORDGHGZLWKWKHVODW major-RXUQDORI)RRG(QJLQHHULQJ± 7KHLQFUHDVHLQVHHGPRLVWXUHFDXVHVWKHVLJQL¿FDQWLQ- 9. +DQF]DQRZVND(.VLĊĪDN-.UDMRZHĨUyGáD crease in relative deformation value. The dependence ELDáNRZ\FKSDV]URĞOLQQ\FKMDNR]DPLHQQLNLĞUXW\VRMRϱ ĞƉсϬ͕ϳϰǁͲϬ͕ϲϭZϸсϬ͕ϵϵϭ 675(1*7+3523(57,(62)+256(%($16(('6 ZHM*02ZĪ\ZLHQLXĞZLĔLQ3ROLVK5RF]QLNL1DXN =RRWHFKQLNL± -HU]DN 0$ &]HUZLĔVND.D\]HU ' )ORUHN - ĝPLJODN.UDMHZVND0 Determinanty produkcji URĞOLQVWUąF]NRZ\FKMDNRDOWHUQDW\ZQHJRĨUyGáDELDáND± w ramach nowego obszaru polityki rolnej w Polsce (in 3ROLVK5RF]QLNL1DXN5ROQLF]\FK6HULD*W] Kulig B., Pisulewska P., Sajdak A. 2007.:Sá\ZLORĞFLZ\VLHZXQDSORQRZDQLHRUD]ZLHONRĞüSRZLHU]FKQL DV\PLODF\MQHMZ\EUDQ\FKRGPLDQERELNXLQ3ROLVK =HV]\W\3UREOHPRZH3RVWĊSyZ1DXN5ROQLF]\FK] .XĨQLDU3-DUHFNL:%REUHFND-DPUR' :áDĞFLZRĞFL PHFKDQLF]QH QDVLRQ Z\EUDQ\FK URĞOLQ VWUąF]NRZ\FKDLFKPDVDLJUXERĞü,QĪ\QLHULD5ROQLF]D Laskowski J., Skonecki S. 2006. :Sá\ZZLHONRĞFL NRPRU\LPDV\PDWHULDáXQD]DJĊV]F]DQLHQDVLRQERELNX ,QĪ\QLHULD5ROQLF]D à\VLDN*/DVNRZVNL- Investigation of mechanical properties of faba bean for grinding behavior SUHGLFWLRQ$FWD$JURSK\VLFD Mohsenin N. N. 1986. Physical Properties of Plant and $QLPDO0DWHULDOV6WUXFWXUH3K\VLFDO&KDUDFWHULVWLFV DQG0HFKDQLFDOQG(GQ*RUGRQDQG%UHDFK1HZ <RUN86$ 1DGXOVNL5.XVLĔVND(.REXV=*X]7(Ifect of selected factors on grain mass creep test under VLPXODWHGORDGFRQGLWLRQV7(.$&RPPLVVLRQRI0RWRUL]DWLRQDQG(QHUJHWLFVLQ$JULFXOWXUH9RO 3UXVLĔVNL-3RVWĊSELRORJLF]Q\ZKRGRZOLLXSUDZLHJURFKXVLHZQHJRLERELNX)UDJPHQWD$JURQRPLFD 8. Sosnowski, S. 1991.'HWHUPLQLQJRIWKHLQÀXHQFHRI the direction of loading forces on mechanical damage RIEHDQVHHGV=HV]\W\3UREOHPRZH3RVWĊSyZ1DXN 5ROQLF]\FK :à$ĝ&,:2ĝ&,:<75=<0$à2ĝ&,2:(1$6,21 %2%,.8VICIA FABA L. VAR. MINOR Streszczenie. :SUDF\SU]HGVWDZLRQRZ\QLNLGRW\F]ąFHEDGDĔZáDĞFLZRĞFLZ\WU]\PDáRĞFLRZ\FKQDVLRQWU]HFKRGPLDQ ERELNX%DGDQLDSU]HSURZDG]RQRZZDUXQNDFKREFLąĪHĔTXDVLVWDW\F]Q\FKSU]\XĪ\FLXPDV]\Q\Z\WU]\PDáRĞFLRZHM,QWURQ 1DVLRQDXPLHV]F]DQROLĞFLHQLDPLUyZQROHJOHGRSRGVWDZ\XU]ąG]HQLDDQDVWĊSQLHREFLąĪDQRSU]\SRPRF\Sá\W\ QRĪDLSHQHWUDWRUD=Z\NUHVXVLáDSU]HPLHV]F]HQLHZ\]QDF]RQR PDNV\PDOQąVLáĊSURZDG]ąFąGR]QLV]F]HQLDQDVLRQDRGSRZLDGDMąFąMHMSU]HPLHV]F]HQLHLSUDFĊGHIRUPDFML:\ND]DQRĪH Z\WU]\PDáRĞüQDVLRQLVWRWQLH]DOHĪ\RGRGPLDQ\6WZLHUG]RQR ĪHZ]URVWZLOJRWQRĞFLQDVLRQSRZRGXMHZ\UDĨQ\VSDGHNLFK Z\WU]\PDáRĞFLPHFKDQLF]QHM 6áRZDNOXF]RZHERELNRGPLDQDZáDĞFLZRĞFLZ\WU]\PDáRĞFLRZH TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 87–92 Comparative Analysis of The Variability of Daily Electric Power Loads Krzysztof Nęcka, Małgorzata Trojanowska Department of Power Engineering and Agricultural Processes Automation, Agricultural University of Cracow Balicka Str. 116B, 30-149 Cracow, Poland e-mail: [email protected]; [email protected] Received December 02.2014; accepted December 17.2014 Summary. This publication analyses the variability of loads in rural medium and low voltage distribution networks compared to the variability of energy demand in the national power grid. Values of standard indicators used to characterise power demand, such as load factors and balancing factors, have been LGHQWL¿HGDQGFRPSDUHG7KLVDQDO\VLVZDVFDUULHGRXWEDVHG RQGDWDUHFRUGHGDWPDLQVXSSO\VWDWLRQVDQGN9 transformer stations. Key words: power grid, distribution networks, load variability. INTRODUCTION One of the important problems of power system engineering is to optimise the time curves of electrical loads, which practically boils down to balancing them and reducing peak power. This is why it is so important to correctly analyse power demand curves. In order to characterise their YDULDELOLW\YDULRXVPHDVXUHVIXQFWLRQVDQGFRHI¿FLHQWV are used, whose examples can be found in the literature of WKHVXEMHFW>@7KHPDMRULW\RI these measures come from classical methods of analysing SRZHUV\VWHPORDGV>@7KHVHPDNHLWSRVVLEOHWR FKDUDFWHULVHORDGVGXULQJKRXUVDZHHNDPRQWKDQGD year, at various supply voltages, caused by individual consumers, groups of consumers or all consumers in total. The total of loads of all consumers constitutes the load on the QDWLRQDOSRZHUJULG³QDWLRQDOJULG´,QSUDFWLFHLWLVQRW only analyses of the curves themselves that are important, but also their comparisons. This publication presents the results of a comparative DQDO\VLVRIWKHYDULDELOLW\RIORDGVLQUXUDOPHGLXP09 DQGORZYROWDJH/9GLVWULEXWLRQQHWZRUNVFRPSDUHGWR the variability of energy demand in the national power grid. 6LQFHLWLVRQO\WKHYDULDELOLW\RIORDGRYHUKRXUVWKDWLV VLJQL¿FDQWIRUSRZHUV\VWHPPDQDJHPHQWWKLVSXEOLFDWLRQ LVOLPLWHGWRDQDO\VLQJWKHKYDULDELOLW\RISRZHUGHPDQG which has been described using standard indicators characterising electrical power loads. 0$7(5,$/6$1'0(7+2'6 This analysis is based on the results of power measurements taken at the main supply stations on the medium voltage side and in MV/LV transformer-distribution stations RQWKHORZYROWDJHVLGH,QWRWDOUHVHDUFKZRUNFRYHUHG PDLQVXSSO\VWDWLRQVRYHUDWOHDVW\HDUDQG09/9 stations. Figures on national grid loads were taken from Monthly reports on the operation of the National Power Grid and the Balancing Mechanism. 5(68/76 For the purpose of this comparative analysis, reduced load graphs were drawn, with mainly relative indicators used to characterise load curves. The reference value was either peak load Ps and indicators thus calculated are referred to as load factors m, or the average load Psr, with balancing factors lEHLQJFDOFXODWHG'HWDLOHGGH¿QLWLRQVRIORDGDQG balancing factors can be found, inter alia, in the collective SXEOLFDWLRQ>@DQGLQ*yUD¶VSXEOLFDWLRQ>@ 7KHKYDULDELOLW\RIORDGVLVPRVWIUHTXHQWO\SUHVHQWHG graphically, usually as a calendar graph. The comparison of individual power values to the peak power produces the reduced graph of loads. These were the graphs plotted for WKHDQDO\VHGV\VWHPV,QWHUQDODQDO\VHVFRQ¿UPHGRWKHU DXWKRUV¶REVHUYDWLRQVWKDWWKHKFXUYHRISRZHUFRQVXPStion is mainly driven by the rhythm and intensity of human DFWLYLWLHVDQGWKHVHDVRQRIWKH\HDU)LJ&RQVHTXHQWO\ when presenting the variability of power demand, averaged SUR¿OHVRIORDGVFRQWUDVWHGZLWKWKHDQQXDOSHDNSRZHUPsr were presented separately for different seasons, split into .5=<6=72)1ĉ&.$0$à*25=$7$752-$12:6.$ 7R FKDUDFWHULVH ORDGV RYHU KRXUV PHDQ YDOXHV 7R FKDUDFWHULVH ORDGV RYHU KRXUV PHDQ YDOXHV EXVLQHVVGD\VDQGKROLGD\V)LJ)LJXUHVDDQGD ±DYHUDJHORDGIDFWRU 7R FKDUDFWHULVH ORDGV RYHU KRXUV PHDQ YDOXHV - average load factor present graphs of national grid loads in the form of averaged P m = sr ORDGFXUYHVIRU\HDUVWKXVVLJQL¿FDQWO\UHGXFLQJWKHUDQ Ps GRPIDFWRU7KHUHPDLQLQJLOOXVWUDWLRQVDUHKVFKHGXOHVRI - base load factor ORDGVRQV\VWHPVVXSSO\LQJUXUDOFRQVXPHUV$FKDUDFWHULVWLF ±EDVHORDGIDFWRU - base load P factor feature of these curves is the smooth, low load during the Po mo PRUQLQJSHDNVWDUWLQJDURXQGDPUHJDUGOHVVRIWKHVHDVRQ Ps and type of day, and a general lack of an afternoon trough. - balancing factor of the base load P Changes in the shape of load curves are mainly caused by ±EDODQFLQJIDFWRURIWKHEDVHORDG = Po - balancing factor of the base load o WKHFKDQJLQJOHQJWKRIWKHGD\LQÀXHQFLQJWKHWLPHDWZKLFK = P lo = o the evening peak load materialises. In winter, the evening UHSUHVHQWWKHEDVHORZHVWP Psr UHSUHVHQWWKHEDVHORZHVWP SHDNVWDUWVDURXQGSPEXWLQVXPPHUDVODWHDVDWSP where: Po, P UHSUHVHQWWKHEDVHORZHVWP DQGODVWVDOPRVWWLOOSP7KHVHDVRQDOVRLQÀXHQFHVWKH where: Po, Psr, PsUHSUHVHQWWKHEDVHORZHVWPHDQDQGSHDN LQ 7DEOH ZKLOH WKHLU YDOXHV IRU D VHOHFWHG Z level of power demand, which is much greater in winter power, respectively. LQ 7DEOH ZKLOH WKHLU YDOXHV IRU D VHOHFWHG Z DWLRQDOJUL than in summer. LQ 7DEOH ZKLOH WKHLU YDOXHV IRU D VHOHFWHG Z DWLRQDOJUL Mean values of these indicators for business days and D DWLRQDOJUL KROLGD\VVSOLWE\VHDVRQDUHSUHVHQWHGLQ7DEOHZKLOHWKHLU D values for a selected winter and summer week for exemplary D transformer-distribution stations and the nationalD grid are VKRZQLQ)LJXUH D 88 E E E E E F )LJ$YHUDJHGORDGSURILOHVGXULQJDEXVLQHVVK )LJ$YHUDJHGORDGSURILOHVGXULQJDEXVLQHVVK )LJ$YHUDJHGORDGSURILOHVGXULQJDEXVLQHVVK F Fig. 1. ([DPSOHFXUYHVRIWKHSRZHUGHPDQGYDULDELOLW\LQVHOHFWHGSHULRGVRIWKH\HDUDQDWLRQDOJULGE09F/9 7RFKDUDFWHULVHORDGVRYHUKRXUVPHDQYDOXHVRI daily load and balancing factors were determined for the analysed systems. In particular, the following were calcu- Fig. 2. $YHUDJHGORDGSUR¿OHVGXULQJDEXVLQHVVKSHULRG DQDWLRQDOJULGE09F/9 ODWHG>@ &203$5$7,9($1$/<6,62)7+(9$5,$%,/,7<2)'$,/<(/(&75,&32:(5/2$'6 89 D D E E F F Fig. 3. $YHUDJHGORDGSUR¿OHVIRUDKKROLGD\SHULRGDQDWLRQDOJULGE09F/9 Fig. 4. Daily load and balancing factor values in a selected winter and summer week for the national power grid and for exemplary WUDQVIRUPHUGLVWULEXWLRQVWDWLRQVDQDWLRQDOJULGE09F/9 Ta b l e 1 . Mean values of daily load and balancing factors 1DWLRQDO*ULG m mo lo spring 0,88 0,70 0,80 summer 0,87 0,78 autumn 0,77 winter 0,78 +ROLGD\ %XVLQHVV day Period spring m 0,70 MV mo lo 0,72 m LV mo 0,29 lo 0,72 0,20 summer 0,89 autumn 0,72 winter average 0,87 0,72 0,82 FRHI¿FLHQWRI YDULDWLRQ>@ The lowest values of the analysed indicators, and their greatest variabilities, characterise the curves of power demand recorded on the low voltage of a MV/LV transformer VWDWLRQDQGFRQ¿UPDVLJQL¿FDQWLQHTXDOLW\RISRZHUGH- mand. The mo indicator is best suited for assessing the load LQHTXDOLW\,WVORZHVWYDOXHVIRUKORDGVFDXVHGE\FRQsumers supplied at low voltage are observed in the spring, on 0RQGD\V6DWXUGD\VDQG6XQGD\V/RDGLQHTXDOLW\DVVHVVHG by the value of mo on medium voltage is, on average, one third lower than on the low voltage, and approx. one third greater than in the national grid. 7KHLQGLFDWRUPRVWIUHTXHQWO\XVHGIRUDQDO\VLQJWKH variability of loads in Poland and abroad is the average load factor m>@,WLVDOVRXVHGWRFODVVLI\FRQVXPHUORDG schedules and predict the electrical capacity and energy GHPDQG)LJXUHVDQGVKRZWKHYDOXHVRIWKLVLQGLFDWRU for individual days of the week and individual months of the year. $VJUDSKVIRUWKHHQWLUHSRZHUJULGDQGPHGLXPYROWDJH grids show, neither the season of the year nor the type of GD\LQÀXHQFHVWKHDYHUDJHYDOXHVRIWKHm indicator. The impact of the season is observable only for the low voltage grid, in which the mean value of m changed in the studied SHULRGIURPLQ1RYHPEHUWRLQ-XO\ .5=<6=72)1ĉ&.$0$à*25=$7$752-$12:6.$ 90 D 0,92 0,90 m 0,88 0,86 0,84 0,82 0,80 Monday Wednesday Friday Sunday Tuesday Thursday Saturday Day of the week E F 0,95 Average Average ±Standard deviation Average ±2*Standard deviation Coming off Extreme 1,0 0,9 0,85 0,8 0,80 0,7 0,75 0,6 m m 0,90 0,70 0,5 0,65 0,4 0,60 0,3 0,55 0,2 0,1 0,50 Monday Wednesday Friday Sunday Tuesday Thursday Saturday Monday Wednesday Friday Sunday Tuesday Thursday Saturday Day of the week Day of the week Fig. 5. Weekly variability of the mLQGLFDWRUDQDWLRQDOJULGE09F/9 7KHJUHDWHVWLQHTXDOLW\LVQRWHGLQORDGVRIFRQVXPHUV UHFRUGHGRQORZYROWDJH7KHLUYDULDELOLW\LVVLJQL¿FDQWUHgardless of the type of day and the season. The variability of rural consumer loads recorded at main supply stations is ORZHURQDYHUDJH Characterising the variability of electrical power loads using indicators such as load and balancing factors makes the comparative analysis easier and can be used by distriEXWLRQFRPSDQLHVZKHQGH¿QLQJW\SLFDOORDGVFKHGXOHVRI consumers and modelling the demand for electrical power and energy. Fig. 6. Monthly variability of the m indicator 5()(5(1&(6 CONCLUSIONS Daily schedules of rural consumer loads recorded on the low and medium voltage are characterised by a low load during the morning peak, which is good for the national grid, but the evening peak load in rural areas coincides with the peak load on the entire power grid. $QDOL]DLSURJQR]DREFLąĪHĔHOHNWURHQHUJHW\F]Q\FK 3UDFD]ELRURZD:17:DUV]DZD 2. %LHOLĔVNL:7\SRZHZ\NUHV\REFLąĪHĔHOHNWURHQHUJHW\F]Q\FKZ\EUDQ\FKRGELRUFyZ0DWHULDá\9 .RQIHUHQFML1DXNRZR±7HFKQLF]QHMÄ5\QHNHQHUJLL HOHNWU\F]QHM5((¶´1DáĊF]yZ± &203$5$7,9($1$/<6,62)7+(9$5,$%,/,7<2)'$,/<(/(&75,&32:(5/2$'6 &KRMQDFNL$à$QDOL]DGRERZHMW\JRGQLRZHM LURF]QHM]PLHQQRĞFLREFLąĪHĔHOHNWURHQHUJHW\F]Q\FK ZVLHFLDFKZLHMVNLFKRUD]PLHMVNLFK3U]HJOąG(OHNWURWHFKQLF]Q\± Dudek G. 2004. Wybrane metody analizy szeregów F]DVRZ\FKREFLąĪHĔHOHNWURHQHUJHW\F]Q\FK0DWHULDá\ VII Konferencji Naukowej Prognozowanie w elektroenergetyce&]ĊVWRFKRZD± Ferreira A.M.S., Cavalcante C.A., FontesC.H., Marambio J. 1012.$1HZSURSRVDORIW\SL¿FDWLRQRIORDG SUR¿OHVWRVXSSRUWWKHGHFLVLRQPDNLQJLQWKHVHFWRURI electric energy distribution. Internacional Industrial ConIHUHQFHRQ(QJLQHHULQJDQG2SHUDWLRQV0DQDJHPHQW ±-XO\*XLPDUmHV3RUWXJDOLD,'±,' Góra S. 1975.*RVSRGDUNDHOHNWURHQHUJHW\F]QDZSU]HP\ĞOH3:1:DUV]DZD 7. 'HUHFND0%LHOLĔVNL: Nowe charakterystyki ]PLHQQRĞFLPRF\SRELHUDQHMSU]H]RGELRUFyZ0DWHULDá\ VI Konferencji Naukowej Prognozowanie w elektroenergetyce PE’2002&]ĊVWRFKRZD± 8. .DĨPLHUF]DN$&KRMQDFNL$à$QDOL]DGRERZHMLW\JRGQLRZHM]PLHQQRĞFLREFLąĪHĔPRFąF]\QQą LELHUQąHOHNWURHQHUJHW\F]Q\FKVLHFLG\VWU\EXF\MQ\FK 61PLHMVNLFKRUD]WHUHQRZ\FK(QHUJHW\ND± 9. 1ĊFND.$QDOL]DV]HUHJyZF]DVRZ\FKREFLąĪHĔ HOHNWURHQHUJHW\F]Q\FKQDREV]DUDFKZLHMVNLFK,QĪ\QLHULD5ROQLF]D± 3URJQR]RZDQLHZHOHNWURHQHUJHW\FH=DJDGQLHQLDZ\EUDQHUHG,'REU]DĔVND:\GDZQLFWZR3ROLWHFKQLNL&]ĊVWRFKRZVNLHM&]ĊVWRFKRZD Trojanowska M. 2003. :\]QDF]HQLHREFLąĪHĔZLHMVNLFKVLHFLQLVNLHJRQDSLĊFLD,QĪ\QLHULD5ROQLF]D ± Trojanowska M. 2010. $QDOL]D]DSRWU]HERZDQLDQD PRFLHQHUJLĊHOHNWU\F]QąZ]DNáDG]LHPOHF]DUVNLP -RXUQDORI5HVHDUFKDQG$SSOLFDWLRQVLQ$JULFXOWXUDO (QJLQHHULQJ± 7URMDQRZVND01ĊFND. Determination of W\SLFDOHOHFWULFSRZHUORDGVIRUUXUDOHQGXVHUV7(.$ .RPLVML0RWRU\]DFMLL(QHUJHW\NL5ROQLFWZD9RO,; ± =DOHZVNL:6WDW\VW\F]QDDQDOL]D]PLHQQRĞFL REFLąĪHĔZVLHFLDFKUR]G]LHOF]\FK(FRQRP\DQG0DQDJHPHQW± $1$/,=$325Ï:1$:&=$=0,(112ĝ&, '2%2:<&+2%&,Ąĩ(ē (/(.752(1(5*(7<&=1<&+ Streszczenie. 3U]HGVWDZLRQR DQDOL]Ċ ]PLHQQRĞFL REFLąĪHĔ Z ZLHMVNLFK VLHFLDFK G\VWU\EXF\MQ\FK ĞUHGQLHJR L QLVNLHJRQDSLĊFLDQDWOH]PLHQQRĞFL]DSRWU]HERZDQLDQDHQHUJLĊ w krajowym systemie elektroenergetycznym. Wyznaczono LSRUyZQDQRZDUWRĞFLVWDQGDUGRZ\FKZVNDĨQLNyZZ\NRU]\stywanych do charakteryzowania zapotrzebowania na moc, WDNLFKMDNVWRSQLHREFLąĪHQLDLVWRSQLHZ\UyZQDQLD$QDOL]D ]RVWDáDSU]HSURZDG]RQDZRSDUFLXRGDQH]DUHMHVWURZDQHZ JáyZQ\FKSXQNWDFK]DVLODMąF\FKLZVWDFMDFKWUDQVIRUPDWRURZ\FKN9 6áRZDNOXF]RZHsystem elektroenergetyczny, sieci dystrybuF\MQH]PLHQQRĞüREFLąĪHĔ TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 93–98 Short-Term Forecasting of Natural Gas Demand by Rural Consumers Using Regression Models Krzysztof Nęcka, Małgorzata Trojanowska Department of Power Engineering and Agricultural Processes Automation, Agricultural University of Cracow Balicka Str. 116B, 30-149 Kraków, Poland e-mail: [email protected]; [email protected] Received December 02.2014; accepted December 17.2014 Under the progressing liberalization of the natural gas market, short-term forecasts are becoming increasingly important. In recent years, an increasing number of studies KDYHHPHUJHGDLPHGDWLPSURYLQJWKHTXDOLW\RIWKLVW\SH of forecast. The short-term prediction of demand for natural gas uses both traditional methods and methods based RQDUWL¿FLDOLQWHOOLJHQFHDVZHOODVFRPELQHGPHWKRGV >@ Traditional forecasting methods can be divided into WKRVHZKLFKXVHOLQHDU>@DQGQRQOLQHDUPRGHOVORJLVWLFPRGHOH[SRQHQWLDOPRGHO*RPSHUW] PRGHODQGWKHOLNH>@RUPRGHOVRIDXWRUHJUHVVLRQ and means (ARIMAX, SARIMAX, recursive autoregression models RARX>@,QUHFHQW\HDUVWKHUHKDV INTRODUCTION been an increase in the number of published studies which For natural gas companies, like for other enterprises XVHQHXUDOQHWZRUNV>@UHFXUVLYH in the energy sector, the forecasting of demand for energy QHXUDOQHWZRUNV>@IX]]\QHXUDOQHWZRUNV>@DQGQHXFDUULHUVLVRQHRIWKHEDVLFDFWLYLWLHVUHTXLUHGE\WKHPDQ- UDOQHWZRUNVRSWLPL]HGE\XVLQJJHQHWLFDOJRULWKP>@WR DJHPHQWRIWKHVHEXVLQHVVHVDQGWKHTXDOLW\RIIRUHFDVWV forecast the daily consumption of natural gas. directly affects the energy security of consumers as well as $PRQJ3ROLVKSXEOLFDWLRQVLQWKLV¿HOGPRVWVWXGLHV WKHSUR¿WVRIWKHVHHQWHUSULVHV,QQDWXUDOJDVFRPSDQLHV deal with long-term forecasts of the demand for gas. Pubforecasts of demand for natural gas are prepared for various OLFDWLRQVGHDOLQJZLWKVKRUWWHUPIRUHFDVWVDUHIHZ>@ The objective of this study was to use various types of time horizons. The short-term forecast of demand for gas includes regression models to predict the daily demand for natural hourly and daily forecasts for a maximum of seven days gas by rural consumers, and to carry out comparisons in in advance. These activities facilitate the operational man- this area. agement of an enterprise, and, in particular, serve to plan daily purchases of gas. 0$7(5,$/6$1'0(7+2'6 Medium-term forecasts are daily and monthly with a time horizon of between one week and a year. These are used for planning purchases of gas in longer periods, and The consumer demand for natural gas depends on a numfor planning gas transmission operations. ber of factors. For this reason, multiple regression models Long-term forecasts are annual predictions with the are very suitable for such forecasts. The regression function SHUVSHFWLYHRIDIRUHFDVWRIEHWZHHQWR\HDUV7KHVH can be given not only in the form of a mathematical formula, are used by gas companies in the long-term planning of but also as an algorithm. In the study, the construction of gas purchases, and for planning the development of gas forecasting models was performed using standard linear infrastructure. regression models, but also using algorithms in the form of Summary. The study used various kinds of multiple regression PRGHOVVWDQGDUGDQGQRQSDUDPHWULFWRSUHGLFWWKHGDLO\GHmand for natural gas by rural consumers. The construction of forecasting models was performed in the workspace of STATISTICA Data MinerXVLQJWKHGDWDPLQLQJWHFKQLTXH7KHDQDO\VLV of forecast errors showed that all models applied in the study i.e. standard regression models, neural networks, regression trees, models based on the MARS, SVM and k-Nearest Neighbours PHWKRGVJHQHUDWHJRRGTXDOLW\IRUHFDVWVZKLOHDUWL¿FLDOQHXUDO networks turned out to be the most effective method. Key words: short-term forecasts, multiple regression, data mining. .5=<6=72)1ĉ&.$0$à*25=$7$752-$12:6.$ neural networks, regression trees, as well as applying MARS, SVM and k-Nearest Neighbours methods. The construction of the models was carried out in the workspace of STATISTICA Data Miner, using data mining methodologies. Developing models was preceded by a corUHODWLRQDQDO\VLVDLPHGDW¿QGLQJWKHIDFWRUVRIJUHDWHVW effect on the daily usage of natural gas by rural consumers. The calculations and analyses were carried out on the basis of hourly measurements of gas usage by consumers from rural areas of southwestern Poland, who are supplied by a low-pressure network via a selected gas pressure reduction station. Data from the 2008–SHULRGZDVXVHG 'DWDIURPZDVXVHGDVDWUDLQLQJVHWZKHUHDV GDWDIURPZDVXVHGDVDWHVWLQJVHW7KHTXDOLW\RI the models was evaluated on the basis of values for ex-post forecast errors, using the following formula: Gt Gtp Z Z2 Z Gt p n Gt Gt ¦ n t Gt ¦G n t t Gtp Gc where: Gt±DFWXDOGDLO\FRQVXPSWLRQRIJDV Gtp ±IRUHFDVWRIGDLO\JDVFRQVXPSWLRQ, Gc±DFWXDOFRQVXPSWLRQRIJDVGXULQJn days of observation. 5(68/76 $PRQJRWKHUIRUHFDVWVQDWXUDOJDVHQWHUSULVHVLQ3RODQG are obliged to make forecasts of daily gas consumption one GD\LQDGYDQFH$GD\RIFRQVXPSWLRQLVGH¿QHGDVKUV IURP$0WR$0WKHQH[WGD\ The course of hourly and daily natural gas consumption by rural consumers within the study period is presented in )LJVDQG Meteorological and time factors were considered among the factors affecting gas consumption. The meteorological factors taken into account included: temperature (daily –PHDQPD[LPXPPLQLPXPKXPLGLW\GDLO\– mean, PD[LPXPPLQLPXPZLQGYHORFLW\GDLO\–PHDQZLQG direction (daily –PHDQSUHVVXUHGDLO\–PHDQZLWKWKHVH values taken with delay to the day of analyzed gas consumption. Time factors include the correlation between the values for daily gas consumption with the values of the variable GHOD\HGZLWKWKHWLPHDQGWKHGD\RIWKHZHHN$WRWDORI YDULDEOHVZHUHFRQVLGHUHGLQWKHFRUUHODWLRQDQDO\VLV It was found that the greatest effect on the value of daily gas consumption by rural consumers was exerted by this val- ue delayed by one day, the mean temperature of the previous day, and the day of the week. In further statistical analyses, these values were adopted as the variables explaining the daily demand for natural gas. ,QRUGHUWRGHYHORSSUHGLFWLRQPRGHOVZKLFKSHUPLW¿QGing the daily demand for natural gas, a project was created in the graphic environment of Statistica 10 Data Miner (Fig. . $PRQJRWKHUHOHPHQWVWKHQRGHVZHUHSODFHGWKHUHWR permit drawing forecasts based on: Neural Networks (NN &ODVVL¿FDWLRQDQG5HJUHVVLRQ7UHHV&$57Multivariate Adaptive Regression Splines (MARS), Support Vector Machine (SVMk Nearest Neighbours (k-NNDVZHOODV standard Multiple Regression (MR 6WDQGDUGPXOWLSOHUHJUHVVLRQUHTXLUHVPHHWLQJPDQ\ assumptions pertaining to sample size, explained and explaining variables, residuals of the model, although in data mining these assumptions are tested less restrictively than in traditional statistics. The other procedures used in this VWXG\DUHQRQSDUDPHWULFSURFHGXUHVZKLFKGRQRWUHTXLUH meeting any initial assumptions. $PRQJWKHODWWHUSURFHGXUHVWKHROGHVWDQGEHVWGHVFULEHGLVWKHPHWKRGRIDUWL¿FLDOQHXUDOQHWZRUNV,WKDV been dynamically developing for several decades and it is QRZUHJDUGHGDVDYHU\UH¿QHGPRGHOOLQJWHFKQLTXHFDSDEOH of mapping very complex relationships. &ODVVL¿FDWLRQDQG5HJUHVVLRQ7UHHVare other advanced prediction tools of Data Mining. The tree is a graphical model created as a result of the recurrent division of a set of observations into n of disjoint subsets. In most general terms, the objective of the analysis with the applied CART DOJRULWKPLVWR¿QGWKHVHWRIORJLFDOFRQGLWLRQVIRUGLYLVLRQ of the if-so, OHDGLQJWRWKHXQDPELJXRXVFODVVL¿FDWLRQRI objects. The MARS method can be regarded as an extension of regression trees and multiple regression. The Multivariate Adaptive Regression Splines algorithm utilises the method of the recurrent division of trait space in the nodes of basic functions to construct the regression model in the form of spline curves. The relationship between variables is modHOOHGZLWKWKHXVHRIDVHWRIEDVLFFRHI¿FLHQWVDQGIXQFWLRQV generated on the basis of data. The SVM method is the next one implemented in the Statistica software, which serves to VROYHUHJUHVVLRQDQGFODVVL¿FDWLRQSUREOHPV,WFRQVLVWVRI constructing non-linear decision borders, separating areas in the space of predictors, corresponding to different values of the dependent variable. K Nearest Neighbours is a method where instead of matching the model, similar objects are sought. The basis of the method is an intuitive conviction that similar objects will fall into the same class. The predictions of the k-NN method are determined on the basis of k objects from the training set which are most similar to the object for which the value of the dependent variable is determined. Mean errors were calculated for the training set (Table DQGWHVWLQJVHW7DEOHIRUIRUHFDVWVIRXQGZLWKWKHXVH of particular methods. The most accurate method turned out to be the neural networks, whereas the standard regression was the least accurate. VWXG\SHULRGLVSUHVHQWHGLQ)LJVDQG 6+2577(50)25(&$67,1*2)1$785$/*$6'(0$1'%<585$/&21680(56 ϲϬ ϱϬ ϰϬ ϯϬ ϮϬ ϭϬ Ϭ ϭ Ϯ ϯ ϰ ϱ ϲ ϳ ϴ ϵ ϭϬ ϭϭ ϭϮ ϭ Ϯ ϯ ϰ ϱ ϲ ϳ ϴ ϵ ϭϬ ϭϭ ϭϮ ϭ Ϯ ϯ ϰ ϱ ϲ ϳ ϴ ϵ ϭϬ ϭϭ ϭϮ ϭ Ϯ ϯ ϰ ϱ ϲ ϳ ϴ ϵ ϭϬ ϭϭ ϭϮ ,ŽƵƌůLJŐĂƐĐŽŶƐƵŵƉƚŝŽŶŵϯ ϳϬ ϮϬϬϴ ϮϬϬϵ ϮϬϭϬ ϮϬϭϭ ͘ zĞĂƌ Fig. 1. +RXUO\QDWXUDOJDVFRQVXPSWLRQ ϭϬϬϬ ϴϬϬ ϲϬϬ ϰϬϬ ϮϬϬ Ϭ ϭ Ϯ ϯ ϰ ϱ ϲ ϳ ϴ ϵ ϭϬ ϭϭ ϭϮ ϭ Ϯ ϯ ϰ ϱ ϲ ϳ ϴ ϵ ϭϬ ϭϭ ϭϮ ϭ Ϯ ϯ ϰ ϱ ϲ ϳ ϴ ϵ ϭϬ ϭϭ ϭϮ ϭ Ϯ ϯ ϰ ϱ ϲ ϳ ϴ ϵ ϭϬ ϭϭ ϭϮ ĂŝůLJ ŐĂƐ ĐŽŶƐƵŵƉƚŝŽŶŵϯ )LJ+RXUO\QDWXUDOJDVFR ϭϮϬϬ ϮϬϬϴ ϮϬϬϵ ϮϬϭϬ HTXLUH PHHWLQJ DQ\ LQLWLDO ϮϬϭϭ ͘ zĞĂƌ Fig. 2. Daily natural gas consumption PHDQ PD[LPXP PLQLPXP PHDQ PD[LPXP PLQLPXP DEOH GHOD\HG ZLWK WKH WLPH DQG WKH GD\ RI WKH ZHHN $ WRWDO RI Fig. 3. View of models constructed in the workspace of Data Miner )LJ9LHZRIPRGHOVFRQVWUXFWHGLQWKHZRUNVSDFHRI Data Miner $PRQJ WKH ODWWHU SURFHGXUHV WKH ROGHVW DQG EHVW GHVFULEHG LV WKH PHWKRG RI DUWLILFLDO )LJ .5=<6=72)1ĉ&.$0$à*25=$7$752-$12:6.$ Ta b l e 1 . Forecast errors found for training set Model (UURU Z2 >@ Z>@ NN CART MARS SVM k±NN MR Ta b l e 2 . Forecast errors found for testing set Model (UURU Z2 >@ Z>@ NN CART MARS SVM k±NN MR For the purpose of analyzing daily gas consumption forecasts, the distribution functions of relative errors w were determined and their courses for the testing set are SUHVHQWHGLQ)LJ$VVKRZQLQWKH¿JXUHLUUHVSHFWLYHRI the method used, the proportion of smallest errors is similar *UHDWHUGLIIHUHQFHVEHWZHHQWKHw IUHTXHQFLHV of occurrence for the studied models were seen when this proportion increased. In the k–NN model, the proportion of HUURUVDPRXQWLQJWROHVVWKDQZDVRIREVHUYDWLRQV whereas for the NNPRGHOLWZDV7KHDGYDQWDJHRI the NN model over the other models is also visible in the proportion of highest observed errors. They did not exceed LQDVPDQ\DVRIWKHREVHUYDWLRQV )LJ(PSLULFDOGLVWULEXWLRQIXQFWLRQVRIZ forecast errors Fig. 4. (PSLULFDOGLVWULEXWLRQIXQFWLRQVRIZ forecast errors CONCLUSIONS The greatest effect on the value of daily gas consumption by rural consumers was exerted by this value delayed YLHZday, RI WKH UHTXLUHPHQWV RI WKH TXDOLW\ by,Qone mean temperature of RI theVKRUW previous day, and the day of the week. ,QYLHZRIWKHUHTXLUHPHQWVRIWKHTXDOLW\RIVKRUWWHUP Z DQGDFFXUDWHZ forecasts posed by gas enterprises, the forecasts determined on the basis of multiple regression models, both standard and non-parametric i.e. NN, CART, MARS, SVM, and k–NN FDQEHFRQVLGHUHGDGPLVVLEOHZ2 DQG DFFXUDWHZ2 The analysis of forecast errors proved that the most effective methods are the neural networks, whereas the greatest errors in forecasts are generated in standard regression. 5()(5(1&(6 Azadeh A., Asadzadeh S.M., Ghanbari A. 2010:$Q adaptive network-based fuzzy inference system for shortterm natural gas demand estimation: Uncertain and comSOH[HQYLURQPHQWV(QHUJ\3ROLF\ 2. Azari A.; Shariaty-Niassar M., Alborzi M. 2012: Short-term and medium-term gas demand load forecasting by neural networks. Iranian Journal of Chemistry DQG&KHPLFDO(QJLQHHULQJ %UDEHF0.RQDU23HOLNDQ(0DO\0 $QRQOLQHDUPL[HGHIIHFWVPRGHOIRUWKHSUHGLFWLRQRI natural gas consumption by individual customers. InterQDWLRQDO-RXUQDORI)RUHFDVWLQJ %UDEHF0.RQDU20DO\03HOLNDQ(9RQdracek J. 2008:$ VWDWLVWLFDO PRGHO IRU QDWXUDO JDV VWDQGDUGL]HGORDGSUR¿OHV-5R\6WDWLVW6RF6HULHV& $SSOLHG6WDWLVWLFV &KHQ46KH<;X; Combination model for VKRUWWHUPORDGIRUHFDVWLQJ7KH2SHQ$XWRPDWLRQDQG &RQWURO6\VWHPV-RXUQDO 'LWWPDQ36]DEHOD3DVLHUELĔVND( Short-term sales forecasts in management of natural gas distributing ZRUNV0DQDJHPHQW 7. Kelner J.M. 2003: Prognozowanie krótkoterminowe SRERUyZJD]X]VLHFLSU]HV\áRZ\FKPHWRGąV]WXF]Q\FK VLHFLQHXURQRZ\FK*D]:RGDL7HFKQLND6DQLWDUQD 8. Kizilaslan R., Karlik B.2008: Comparison neural networks models for short term forecasting of natural gas FRQVXPSWLRQLQ,VWDQEXO,Q$SSOLFDWLRQVRIGLJLWDOLQIRUPDWLRQDQGZHEWHFKQRORJLHV,&$',:7 $XJXVW 9. 3RWRFQLN 3 *RYHNDU ( Practical results of forecasting for the natural gas market. http://www. intechopen.com/books/natural-gas/practical-results-of-forecasting-for-the natural-gas market. 3RWRFQLN3*RYHNDU(*UDEHF,Short-term natural gas consumption forecasting. In: Proceedings of WKHWK,$67(',QWHUQDWLRQDO&RQIHUHQFHRQ$SSOLHG 6LPXODWLRQDQG0RGHOOLQJ±$60 Potocnik P., Soldo B., Simunovic G., Saric T., JeURPHQ$*RYHNDU( Comparison of static and adaptive models for short-term residential natural gas IRUHFDVWLQJLQ&URDWLD$SSOLHG(QHUJ\ 6DER.6FLWRYVNL59D]OHU,=HNLF6XVDF0 0DWKHPDWLFDOPRGHOVRIQDWXUDOJDVFRQVXPSWLRQ(QHUJ\&RQYHUVLRQDQG0DQDJHPHQW 6LPXQHN03HOLNDQ( Temperatures data preprocessing for short-term gas consumption forecast. In: ,(((,QWHUQDWLRQDO6\PSRVLXPRQ,QGXVWULDO(OHFWURQLFV Smith P., Husejn S. 1996: Forecasting short term reJLRQDOJDVGHPDQGXVLQJDQH[SHUWV\VWHP([SHUW6\VWHPVZLWK$SSOLFDWLRQV 6+2577(50)25(&$67,1*2)1$785$/*$6'(0$1'%<585$/&21680(56 Soldo B. 2012: Forecasting natural gas consumption. $SSOLHG(QHUJ\ Soldo B., Potocnik P., Simunovic G., Saric T., GoveNDU( Improving the residential natural gas consumption forecasting models by using solar radiation. (QHUJ\DQG%XLOGLQJV Suganthi L., Anand A. Samuelb A.A. 2012:(QHUJ\ PRGHOVIRUGHPDQGIRUHFDVWLQJ$UHYLHZ5HQHZDEOH DQG6XVWDLQDEOH(QHUJ\5HYLHZV 7DVSÕQDU)&HOHEL17XWNXQ1 Forecasting of daily natural gas consumption on regional basis in 7XUNH\XVLQJYDULRXVFRPSXWDWLRQDOPHWKRGV(QHUJ\ DQG%XLOGLQJV <X);X;$VKRUWWHUPORDGIRUHFDVWLQJPRGHO of natural gas based on optimized genetic algorithm and LPSURYHG%3QHXUDOQHWZRUN$SSOLHG(QHUJ\ 20. =KRX+6X*/L* Forecasting daily gas load ZLWK2,+)(OPDQ1HXUDO1HWZRUN3URFHGLD&RPSXWHU 6FLHQFH 97 352*12=2:$1,(.5Ï7.22.5(62:( =$3275=(%2:$1,$2'%,25&Ï::,(-6.,&+ 1$*$==,(01<=:<.25=<67$1,(002'(/, 5(*5(6<-1<&+ Streszczenie. :SUDF\Z\NRU]\VWDQRUyĪQHJRURG]DMXPRGHOH UHJUHVMLZLHORUDNLHMVWDQGDUGRZHLQLHSDUDPHWU\F]QHGRSUHdykcji dobowego zapotrzebowania odbiorców wiejskich na gaz ]LHPQ\%XGRZĊPRGHOLSUHG\NF\MQ\FKSU]HSURZDG]RQRZSU]Hstrzeni roboczej STATISTICA Data MinerSU]\XĪ\FLXPHWRG data mining$QDOL]DEáĊGyZSURJQR]Z\ND]DáDĪHZV]\VWNLH zastosowane w pracy modele tj. standardowej regresji, sieci neuronowych, drzew regresyjnych, oparte na metodzie MARS, ZHNWRUyZQRĞQ\FKRUD]N–QDMEOLĪV]\FKVąVLDGyZJHQHUXMąSURJQR]\GREUHMMDNRĞFLSU]\F]\PPHWRGąQDMEDUG]LHMHIHNW\ZQą RND]Dá\VLĊV]WXF]QHVLHFLQHXURQRZH 6áRZDNOXF]RZHprognozy krótkookresowe, regresja wieloraka, data mining. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 99–104 Evaluation of Physical Properties in Briquettes Made from Selected Plant Materials Ignacy Niedziółka1, Wojciech Tanaś1, Mariusz Szymanek1, Beata Zaklika1, Józef Kowalczuk2, Jarosław Tatarczak2, Janusz Zarajczyk2 Department of Agricultural Machines, Department of Horticultural and Forestry Machines, University of Life Sciences, 28 Głęboka Street, 20-612 Lublin 1 2 Received December 12.2014; accepted December 19.2014 potential of this material which has not found any rational use. Its use as an energy source has become the solution to WKLVVLWXDWLRQ>'UHV]HUHWDO)LV]HU.RáRG]LHM DQG0DW\ND1LHG]LyáNDDQG6]\PDQHN=DUDMF]\N@ To enhance plant biomass use for energy production, efforts have been made to improve its physical properWLHV>:XHWDO@/RZHULQJWKHPRLVWXUHDOORZVIRU long-term storage, while increasing the concentration of mass and energy per unit volume makes the transport, storage and dispensing easier. These favourable characteristics can be achieved by concentration of biomass in WKHIRUPRIEULTXHWWHVWKXVJDLQLQJDIXHOZKLFKLVFRPpetitive with conventional ones [Komorowicz et al. 2009, /HZDQGRZVNLDQG5\PV1LHG]LyáND6]\PDQHN DQG.DFKHO-DNXERZVND@ INTRODUCTION %LRPDVVEULTXHWWLQJPHDQVWKHLQFUHDVLQJRIHQHUJ\GHQsity and improving the milling properties of the raw material. (QHUJ\IURPIRVVLOIXHOUHVRXUFHVKDVEHHQJHWWLQJPRUH 7KHPRVWFRPPRQO\XVHGEULTXHWWLQJSUHVVHVDUHWKHSLVWRQ and more expensive due to their depleting reserves. More screw and cylindrical ones. They can be used as separate and more attention has been paid to the problems of environ- devices or within an in-line process for the manufacture of mental protection. These phenomena have been encouraging compact fuel. Construction of the line is dependent on the research into alternative energy sources, among others, bi- volume of production, properties of the raw material used omass. The greatest hopes are connected with the biomass DQGVSHFL¿FUHTXLUHPHQWVIRUWKHREWDLQHGSURGXFW>+HMIW of plant origin and this group includes the straw of cereals )UąF]HN.DOO\DQDQG0RUH\@7KHUHIRUH DQGRWKHUFURSV>%RUNRZVND'HQLVLXN*U]\EHN the production process may be more or less complicated, depending on the initial parameters of the processed mate1LHG]LyáNDHWDO6WRODUVNL@ Virtually any type of straw from cereal, oilseed rape ULDOVDVZHOODVWKHLU¿QDOGHVWLQDWLRQ and buckwheat can be used for energy purposes. Due to The aim of this study was to evaluate the physical proptheir properties, the most often used straw is that of rye, HUWLHVRIEULTXHWWHVPDGHRIVHOHFWHGSODQWUDZPDWHULDOV wheat, rape and buckwheat. It is assumed that “straw” is ripe or dried plant stalks, having a high dry matter content 0$7(5,$/6$1'0(7+2'6 RIXSWRDQGWKHFDSDFLW\RIZDWHUDQGJDVDEVRUSWLRQ $VDZDVWHSURGXFWLWKDVDZLGHUDQJHRIDSSOLFDWLRQVLQ crop production, horticulture, construction and energy. Wheat straw, maize stover and Sida stalks were used for Despite the different applications of straw in agriculture WKHSURGXFWLRQRIEULTXHWWHV7KHUHODWLYHPRLVWXUHRIUDZ it should be noted that there still remains a considerable materials was determined by the weight-drier method acSummary. The purpose of this study was to evaluate the physical SURSHUWLHVRIEULTXHWWHVPDGHIURPVHOHFWHGSODQWUDZPDWHULDOV The research was carried out on three kinds of raw materials, i.e. wheat straw, maize stover and Sida stalks. It was found out that WKHSODQWPDWHULDOVXVHGIRUWKHSURGXFWLRQRIEULTXHWWHVZHUH FKDUDFWHUL]HGE\ORZPRLVWXUHDQGKLJKFDORUL¿FYDOXHDQGWKH\ FRXOGZHOOXQGHUJRDSURFHVVRIFRPSDFWLRQ$OVRWKHSURGXFHG EULTXHWWHVZHUHFKDUDFWHUL]HGE\IDYRXUDEOHSURSHUWLHVFRQFHUQing the studied parameters, i.e. length, mass, proper density and bulk density. The best results for the studied properties were REWDLQHGIRUWKHEULTXHWWHVPDGHIURPPDL]HVWRYHUDQGVOLJKWO\ ZRUVHIRUWKHEULTXHWWHVPDGHIURPZKHDWVWUDZDQG6LGDVWDONV Key words: SODQWELRPDVVEULTXHWWLQJSK\VLFDOSURSHUWLHVRI EULTXHWWHV ,1,('=,Ïà.$:7$1$ĝ06=<0$1(.%=$./,.$-.2:$/&=8.-7$7$5&=$. FRUGLQJWRWKH31(1VWDQGDUG0HDVXUHPHQW 3KRWRVKRZVWKHK\GUDXOLFSLVWRQEULTXHWWLQJPDFKLQH of moisture content in the raw materials was performed in -81,25XVHGWRSURGXFHEULTXHWWHV WULSOLFDWHDQGGHWHUPLQHGE\WKHIRUPXOD W mo m mo where: W±KXPLGLW\RIWKHWHVWHGPDWHULDO mo±PDVVRIWKHVDPSOHEHIRUHGU\LQJJ m±PDVVRIWKHVDPSOHDIWHUGU\LQJJ 7KHQHWFDORUL¿FYDOXHZDVFDOFXODWHGEDVHGRQWKHJURVV FDORUL¿FYDOXHGHWHUPLQHGXVLQJDFDORULPHWHU./0QLQ DFFRUGDQFHZLWK31(17KHEULTXHWWLQJSODQW materials were pulverized using a chopper drum substation and universal hammer mill, powered by electric motors with WKHFDSDFLW\RIUHVSHFWLYHO\DQGN:7KHGHYLFH used for the compaction process of the shredded plant maWHULDOVZDVWKHK\GUDXOLFSLVWRQEULTXHWWLQJPDFKLQH-XQLRU RIWKH325'(7$FRPSDQ\3RODQG $IWHUWKHSURGXFWLRQRIEULTXHWWHVWKHLUJHRPHWULFDO characteristics were determined: diameter and length usLQJFDOLSHUVZLWKDFFXUDF\RIPPDQGPDVVXVLQJ DODERUDWRU\VFDOH:37ZLWKDFFXUDF\RIJ %XONGHQVLW\RIWKHSHOOHWVZDVGHWHUPLQHGE\IUHHO\GURSping them into the measuring cylinder with the volume of GP3LQDFFRUGDQFHZLWK31(1$IWHU ¿OOLQJWKHF\OLQGHUDQGUHPRYLQJWKHH[FHVVVWULSDOOWKH EULTXHWWHVZHUHZHLJKHGRQWKHVFDOHV:3(ZLWKDFFXUDF\RIJ%XONGHQVLW\YDOXHZDVFDOFXODWHGDVWKH TXRWLHQWRIWKHGLIIHUHQFHLQPDVVRIWKHF\OLQGHUZLWKDQG without fuel pellets and the cylinder’s volume, according WRWKHIRUPXOD U mL mO V where: ȡ±EXONGHQVLW\RISHOOHWVNJāP-3 mL±PDVVRIF\OLQGHUZLWKSHOOHWVJ mO±PDVVRIWKHHPSW\F\OLQGHUJ V±F\OLQGHU¶VYROXPHGP3 3KRWR VKRZV WKH WHVWHG SODQW PDWHULDOV DIWHU WKHLU shredding. D E Photo. 2. 7KHK\GUDXOLFSLVWRQEULTXHWWLQJPDFKLQH-81,25 7DEOHSUHVHQWVWKHWHFKQLFDODQGRSHUDWLRQDOSDUDPHWHUV RIWKHK\GUDXOLFSLVWRQEULTXHWWLQJPDFKLQH-81,25 Ta b l e 1 . The technical and operational parameters of the K\GUDXOLFSLVWRQEULTXHWWLQJPDFKLQH-81,25 MeasureData ment unit 7\SHRIEULTXHWWLQJGHYLFH JUNIOR Diameter of pellets mm 0D[LPXPOHQJWKRIEULTXHWWHV mm %ULTXHWWLQJSHUIRUPDQFH kg·h-1 (OHFWULFPRWRUSRZHU kW Maximum working pressure MPa Oil tank capacity dm3 %ULTXHWWLQJGHYLFHGLPHQVLRQV mm îî OHQJWK[ZLGWK[KHLJKW %ULTXHWWLQJGHYLFHZHLJKW kg 6SHFL¿FDWLRQ F Photo 1. 7KHWHVWHGSODQWPDWHULDOVDIWHUVKUHGGLQJDZKHDWVWUDZEPDL]HVWRYHUF6LGDVWDONV (9$/8$7,212)3+<6,&$/3523(57,(6,1%5,48(77(6 3KRWRVKRZVWKHEULTXHWWHVPDGHIURPWKHWHVWHGSODQWPDWHULDOV D E F Photo 3. %ULTXHWWHVSURGXFHGIURPWKHWHVWHGSODQWUDZPDWHULDOVDZKHDWVWUDZEPDL]HVWRYHUF6LGDVWDONV 5(68/76 )LJXUHVKRZVWKHDYHUDJHPRLVWXUHFRQWHQWRISODQW PDWHULDOVXVHGIRUWKHSURGXFWLRQRIEULTXHWWHV7KHORZHVW PRLVWXUHZDVUHFRUGHGIRUZKHDWVWUDZDQGWKH KLJKHVWIRUPDL]HVWRYHU7KHVWDWLVWLFDODQDO\VLV VKRZHGWKDWVLJQL¿FDQWGLIIHUHQFHVRFFXUUHGLQWKHPRLVWXUH of all the tested materials. )LJXUHVKRZVWKHUHVXOWVRIPHDVXUHPHQWVRIWKHOHQJWK RIEULTXHWWHVPDGHRIYDULRXVSODQWPDWHULDOV7KHVKRUWHVW EULTXHWWHVZHUHREWDLQHGIURPZKHDWVWUDZPPZKLOH WKHORQJHVWIURP6LGDVWDONVPP7KHDQDO\VLVRI WKHUHVXOWVVKRZHGWKDWVWDWLVWLFDOO\VLJQL¿FDQWGLIIHUHQFHV RFFXUUHGEHWZHHQWKHOHQJWKRIEULTXHWWHVSURGXFHGIURP ZKHDWVWUDZDQGPDL]HVWRYHUDQGWKHOHQJWKRIEULTXHWWHV PDGHIURP6LGDVWDONV7KHUHZHUHQRVWDWLVWLFDOO\VLJQL¿FDQW GLIIHUHQFHVLQWKHOHQJWKRIEULTXHWWHVIURPZKHDWVWUDZDQG maize stover. Fig. 1. $YHUDJHPRLVWXUHRIWKHFRPSDFWHGSODQWUDZPDWHULDOV )LJXUHVKRZVWKHDYHUDJHFDORUL¿FYDOXHRIWKHSODQWPDWHULDOVXVHGLQWKHPDQXIDFWXUHRIEULTXHWWHV7KHORZHVWFDORUL¿FYDOXHRFFXUUHGIRUZKHDWVWUDZ0-āNJ-1VOLJKWO\ KLJKHUYDOXHVZHUHUHFRUGHGIRU6LGDVWDONV0-āNJ-1 DQGWKHKLJKHVWIRUPDL]HVWRYHU0-āNJ-17KHDQDO\VLV VKRZHGQRVWDWLVWLFDOO\VLJQL¿FDQWGLIIHUHQFHVLQWKHFDORUL¿F value of all the compacted materials. Fig. 2. $YHUDJHFDORUL¿FYDOXHRIFRPSDFWHGSODQWPDWHULDOV Fig. 3. $YHUDJHOHQJWKRIEULTXHWWHVPDGHIURPSODQWPDWHULDOV )LJXUHVKRZVWKHUHVXOWVRIPHDVXULQJWKHPDVVRI pellets made from the tested materials. The lowest average PDVVFKDUDFWHUL]HGWKHEULTXHWWHVIURPZKHDWVWUDZ JVOLJKWO\KLJKHUEULTXHWWHPDVVZDVIRXQGIRU6LGDVWDONV JDQGWKHKLJKHVWIRUPDL]HVWRYHUJ7KHVWDWLVWLFDODQDO\VLVLQGLFDWHGWKDWVLJQL¿FDQWGLIIHUHQFHVRFFXUUHGEHWZHHQWKHPDVVRIEULTXHWWHVPDGHIURPZKHDW VWUDZRU6LGDVWDONVDQGWKDWRIWKHEULTXHWWHVPDGHIURP PDL]HVWRYHU,QFRQWUDVWQRVWDWLVWLFDOO\VLJQL¿FDQWGLIIHUences occurred between the mass of wheat straw and Sida VWDONVEULTXHWWHV )LJXUHVKRZVWKHGHQVLW\RIEULTXHWWHVGHSHQGLQJRQ the type of plant raw materials used. The lowest proper GHQVLW\FKDUDFWHUL]HGWKHEULTXHWWHVIURP6LGDVWDONV kg.m-3DQGWKHKLJKHVWWKHEULTXHWWHVIURPPDL]HVWRYHU NJ.m-3%DVHGRQWKHVWDWLVWLFDODQDO\VLVLWZDV IRXQGRXWWKDWVLJQL¿FDQWGLIIHUHQFHVRFFXUUHGEHWZHHQWKH SURSHUGHQVLW\RIEULTXHWWHVSURGXFHGIURPZKHDWVWUDZRU 6LGDVWDONVDQGWKHSURSHUGHQVLW\RIEULTXHWWHVIURPPDL]H ,1,('=,Ïà.$:7$1$ĝ06=<0$1(.%=$./,.$-.2:$/&=8.-7$7$5&=$. Fig. 4. $YHUDJHPDVVRIEULTXHWWHVPDGHIURPSODQWPDWHULDOV Fig. 6. $YHUDJHEXONGHQVLW\RIEULTXHWWHVSURGXFHGIURPSODQW materials VWRYHU+RZHYHUQRVWDWLVWLFDOO\VLJQL¿FDQWGLIIHUHQFHVZHUH found in the density of the pellets produced from wheat $PRQJWKHFRPSDFWHGPDWHULDOVWKHORZHVWPRLVWXUH straw and Sida stalks. DQGKHDWLQJYDOXH0-āNJ-1ZDVIRXQGRXW for the wheat straw, and the highest for the maize stover, DQG0-āNJ-1UHVSHFWLYHO\ $IWHUWKHDQDO\VLVRIWKHUHVXOWVRIPHDVXUHPHQWVRI OHQJWKDQGPDVVRIWKHSURGXFHGEULTXHWWHVLWZDVIRXQG RXWWKDWWKHVKRUWHVWEULTXHWWHVZHUHREWDLQHGIURPZKHDW VWUDZPPDQGWKHORQJHVWIURP6LGDVWDONV PP,QFRQWUDVWWKHORZHVWPDVVZDVUHFRUGHGIRUWKH EULTXHWWHVPDGHIURPZKHDWVWUDZJZKHUHDVWKH KLJKHVWIRUWKHEULTXHWWHVSURGXFHGIURPPDL]HVWRYHU J %DVHGRQWKHDQDO\VLVWKHORZHVWYDOXHVRISURSHUDQG bulk density were found out for the pellets produced IURP6LGDVWDONV±DQGNJ.m-3UHVSHFWLYHO\ DQGWKHKLJKHVWYDOXHVIRUWKHEULTXHWWHVPDQXIDFWXUHG IURPPDL]HVWRYHU±DQGNJ.m-3UHVSHFFig. 5. $YHUDJHGHQVLW\RIEULTXHWWHVSURGXFHGIURPSODQWPDterials tively. The results of measurements of the average bulk density 5()(5(1&(6 depending on the kind of raw materials used are shown in )LJXUH7KHORZHVWEXONGHQVLW\FKDUDFWHUL]HGWKHEULTXHWWHVSURGXFHGIURP6LGDVWDONVNJ.m-3DQGWKH Borkowska H., 2006: 3HOHW\]HĞOD]RZFDSHQV\OZDĔVNLHKLJKHVWWKRVHSURGXFHGIURPPDL]HVWRYHUNJ.m-3 JRQDWOHQRUP\',1&]\VWD(QHUJLD %DVHGRQWKHVWDWLVWLFDODQDO\VLVLWZDVIRXQGRXWWKDWVLJ- 2. Denisiuk W., 2007:%U\NLHW\SHOHW\]HVáRP\ZHQHUJHW\FH,QĪ\QLHULD5ROQLF]D QL¿FDQWGLIIHUHQFHVRFFXUUHGEHWZHHQWKHEXONGHQVLW\RI EULTXHWWHVPDGHIURPZKHDWVWUDZRU6LGDVWDONVDQGWKH 'UHV]HU . 0LFKDáHN 5 5RV]NRZVNL $ (QHUJLD RGQDZLDOQD ± PRĪOLZRĞFL MHM SR]\VNLZDQLD EXONGHQVLW\RIEULTXHWWHVPDGHRIPDL]HVWRYHU7KHUHZHUH QRVWDWLVWLFDOO\VLJQL¿FDQWGLIIHUHQFHVLQWKHEXONGHQVLW\RI LZ\NRU]\VWDQLDZUROQLFWZLH(G37,5.UDNRZ±/XEEULTXHWWHVPDGHIURPZKHDWVWUDZDQG6LGDVWDONV OLQ±:DUVDZ Fiszer A., 2008:%DGDQLDSRUyZQDZF]HZVSyáF]\QQLND WUZDáRĞFLEU\NLHWyZ]HVáRP\-RXUQDORI5HVHDUFKDQG $SSOLFDWLRQVLQ$JULFXOWXUDO(QJLQHHULQJ CONCLUSIONS )UąF]HN-HGPrzetwarzanie biomasy na cele enerThe results of research and statistical analysis allow for JHW\F]QH(G37,5.UDNyZ,6%1 the following conclusions: Grzybek A. (ed.)., 2012: 6áRPD ± Z\NRU]\VWDQLH 7KHWHVWHGSODQWPDWHULDOVXVHGIRUWKHSURGXFWLRQRI ZHQHUJHW\FHFLHSOQHM(G,73)DOHQW\,6%1 EULTXHWWHVZHUHFKDUDFWHUL]HGE\ORZPRLVWXUHDQG KLJKFDORUL¿FYDOXHDQGZHUHYXOQHUDEOHIRUWKHSURFHVV 7. Hejft R., 2013:,QQRZDF\MQRĞüZJUDQXORZDQLXELRPDV\&]\VWD(QHUJLD RIFRPSDFWLRQ$OVRWKHSURGXFHGEULTXHWWHVZHUH characterized by favourable parameters of the studied 8. Kallyan N., Morey R.V., 2009: Factors affecting properties, i.e. length, mass proper density and bulk VWUHQJWKDQGGXUDELOLW\RIGHQVL¿HGELRPDVVSURGXFWV density. %LRPDVVDQG%LRHQHUJ\ (9$/8$7,212)3+<6,&$/3523(57,(6,1%5,48(77(6 9. .RáRG]LHM%0DW\ND0HGOdnawialne ĨUyGáDHQHUJLL5ROQLF]HVXURZFHHQHUJHW\F]QH3:5L/ 6S]RR3R]QDĔ,6%1 .RPRURZLF]0:UyEOHZVND+3DZáRZVNL- 6NáDGFKHPLF]Q\LZáDĞFLZRĞFLHQHUJHW\F]QHELRPDV\ ]Z\EUDQ\FKVXURZFyZRGQDZLDOQ\FK2FKURQDĝURGRZLVNDL=DVREyZ1DWXUDOQ\FK Lewandowski W. M., Ryms M., 2013:%LRSDOLZD3URHNRORJLF]QHRGQDZLDOQHĨUyGáDHQHUJLL:17:DUV]DZD ,6%1 1LHG]LyáND,HGTechnika produkcji brykieWyZ]ELRPDV\URĞOLQQHM7RZ:\G1DXN/,%5232/,6,6%1 1LHG]LyáND,6]\PDQHN0$QHVWLPDWLRQRI SK\VLFDOSURSHUWLHVRIEULTXHWWHVSURGXFHGIURPSODQW ELRPDVV7HND.RPLVML0RWRU\]DFMLL(QHUJHW\NL5ROQLFWZD; 1LHG]LyáND,6]\PDQHN0=XFKQLDU]$ (QHUJHWLFHYDOXDWLRQRISRVWKDUYHVWFRUQPDVVIRUKHDWLQJSXUSRVHV7HND.RPLVML0RWRU\]DFMLL(QHUJHW\NL 5ROQLFWZD9,$ 31(1±2]QDF]DQLH]DZDUWRĞFLZLOJRFL PHWRGąVXV]DUNRZą±&]ĊĞü:LOJRüZRJyOQHMSUyEFH analitycznej. 31(1±%LRSDOLZDVWDáH±2]QDF]DQLH ZDUWRĞFLRSDáRZHM 31(1±%LRSDOLZDVWDáH±2]QDF]DQLH JĊVWRĞFLQDV\SRZHM Stolarski M., Szczukowski S., Tworkowski J., 2008: %LRSDOLZD]ELRPDV\ZLHOROHWQLFKURĞOLQHQHUJHW\F]Q\FK(QHUJHW\ND Szymanek M., Kachel-Jakubowska M., 2010:(VWLPDWLRQDQGDQDO\VLVRIFKRVHQIDFWRUVRIWKHLQÀXHQFH RQTXDOLW\DQGHQHUJ\FRQVXPSWLRQDWWKHSURFHVVLQJ of plant materials for energy purposes. Teka Komisji 0RWRU\]DFMLL(QHUJHW\NL5ROQLFWZD 20. Wu M.R., Schott D.L., Lodewijks G., 2011: Physical SURSHUWLHVRIVROLGELRPDVV%LRPDVVDQG%LRHQHUJ\ =DUDMF]\N- Uwarunkowania techniczne i techQRORJLF]QHSURGXNFMLSHOHWX]ELRPDV\URĞOLQQHMQDFHOH HQHUJHW\F]QH,QĪ\QLHULD5ROQLF]D0RQRJUD¿HLUR]SUDZ\7VV 2&(1$:à$ĝ&,:2ĝ&,),=<&=1<&+%5<.,(7Ï: :<.21$1<&+=:<%5$1<&+0$7(5,$àÏ: 52ĝ/,11<&+ Streszczenie. &HOHPWHJREDGDQLDE\áDRFHQDZáDĞFLZRĞFL¿]\F]Q\FKEU\NLHWyZZ\NRQDQ\FK]Z\EUDQ\FKVXURZFyZURĞOLQQ\FK %DGDQLDSU]HSURZDG]RQRQDWU]HFKURG]DMDFKVXURZFyZVáRPLH SV]HQQHMVáRPLHNXNXU\G]LDQHMLáRG\JDFKĞOD]RZFDSHQV\OZDĔVNLHJR6WZLHUG]RQRĪHPDWHULDá\URĞOLQQHVWRVRZDQHGRZ\WZDU]DQLDEU\NLHWyZFKDUDNWHU\]XMHQLVNDZLOJRWQRĞüLZ\VRND ZDUWRĞüRSDáRZDLPRJąRQH]SRZRG]HQLHPE\üSRGGDZDQH SURFHVRZL ]DJĊV]F]DQLD 3RQDGWR Z\SURGXNRZDQH EU\NLHW\ FKDUDNWHU\]RZDá\VLĊNRU]\VWQ\PLZáDĞFLZRĞFLDPLZ]DNUHVLH EDGDQ\FKSDUDPHWUyZF]\OLGáXJRĞFLPDV\JĊVWRĞFLZáDĞFLZHM LJĊVWRĞFLQDV\SRZHM1DMOHSV]HZ\QLNLGODEDGDQ\FKZáDĞFLZRĞFL X]\VNDQRGODEU\NLHWyZ]HVáRP\]NXNXU\G]\DQLHFRJRUV]HGOD EU\NLHWyZ]HVáRP\SV]HQQHMLáRG\JĞOD]RZFDSHQV\OZDĔVNLHJR 6áRZDNOXF]RZHELRPDVDURĞOLQEU\NLHWRZDQLHZáDĞFLZRĞFL ¿]\F]QHEU\NLHWyZ TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 105–112 TXDQWLW\ TXDOLW\ Increase of Reverse Water Supply Systems Effectiveness in Production of Construction Materials Ilya Nikolenko, Ervin Karimov TXDOLW\ Crimean Federal V.I. Vernadsky University 181, Kievskaya Street, Simferopol, Crimea, e-mail: [email protected] Received December 02.2014; accepted December 17.2014 Summary. In the DUWLFOHWKHTXHVWLRQVRIPRGHOLQJRIK\GURG\QDPLF filtering in systems of reverse water supply in production of construction materials are considered. The scheme of experimental installation is provided for realization of pilot research of the K\GURG\QDPLF ILOWHU DQG DOVR WKH WHFKQLTXH RI SLORW UHVHDUFKHV LV given. The plan of three-IDFWRULDO H[SHULPHQW RI *') RI 3&0 wastewaters is developed, researches are conducted and the regression HTXDWLRQ FKDUDFWHUL]LQJ WKH UHPRYDO SURFHVV RI WKH VXspended materials is received. Dependences for calculation of the residual content of the suspended materials depending on initial concentration of impurities, the ratio of a useful and slime expense on the filter and the consumption of the processed fluid are established. It is established that in the production of construction materials the installation of reverse water supply systems with application of hydrodynamic filtering allows using effectively its advantages and providing more rational use of energy and natural resources. Key words: Productions of construction materials, industrial wastewaters, reverse water supply, hydrodynamic filtering, concentration, expense, residual concentration of impurity, refinement effectiveness INTRODUCTION Water in industrial production is essential for ensuring primary and secondary technological processes, as well as fire-fighting, domestic and drinking needs of enterprises. The TXDQWLW\ and TXDOLW\ of technical water which is necessary in any production is defined by the scale and nature of its technological processes. Properties of utilized water, cost of water supply systems and water disposals substantially define TXDOLW\ and prime cost of products and also conditions of the rational use of natural resources. Reserve for water resources saving at any production is the use of circulating water supply where much depends on the technology of wastewaters refinement. With the installation of recycling systems for industrial water supply there are additional reserves on consumption of fresh water and reduction of wastewaters into reservoirs. Industrial wastewaters refinement represents an important technological and methodical problem in developing effective ways for recycling refined water in industrial processes. Fluids’ refinement from various types of impurities that they contain is a widespread problem. It is constantly > @ ,Q WHFKQRORJLFDO SURFHVVHV RI SURGXFWLRQ PDWHULDOV 3&0 ODUJH YROXPHV RI ZDWHU DUH XVHG ZKLFK processes. Fluids’ refinement from various types of impurities that they contain is a widespread problem. It is constantly faced not only in communal services and on the domestic level but also in all the branches of industrial production > @ ,Q WHFKQRORJLFDO SURFHVVHV RI SURGXFWLRQ processing and also the production of construction PDWHULDOV 3&0 ODUJH YROXPHV RI ZDWHU DUH XVHG ZKLFK become soiled generally by mineral insoluble impurity. For the majority of PCM, in the technological processes water is the main working medium. The use of polluted ZDWHUWRDQ\H[WHQWLVH[SRVHGWRUHILQHZLWKLWVVXEVHTXHQW dumping in water objects or in reverse schemes with the VXEVHTXHQW DSSOLFDWLRQ LQ WHFKQRORJLFDO SURFHVV RHTXLUHPHQWVTXDOLW\RILQGXVWULDOZDVWHZDWHUVUHILQHPHQW at their outlet in reservoirs DQG DOVR DW WKH VXEVHTXHQW application causes broad use of various refinement methods and technologies. While choosing a method of impurities refinement not only their structure in ZDVWHZDWHUV LV FRQVLGHUHG EXW DOVR UHTXLUHPHQWV ZKLFK have to satisfy waters refinement: when disposing in a reservoir, and at a reuse of the refined wastewaters in production - WKRVH UHTXLUHPHQWV ZKLFK DUH QHFHVVDU\ IRU realization of actual technological processes. The current situation is characterized by increasing DWWHQWLRQ RI VRFLHW\ WR TXHVWLRQV RI SRZHU DQG UHVRXUFH VDYLQJ WKDW LV GLUHFWO\ FRQQHFWHG ZLWK TXDOLW\ DQG DQ H[SHQVH XVHG LQ WHFKQRORJLFDO ZDWHU SURFHVVHV >@ 7KH condition of the surrounding water medium, the developed level of understanding of environmental problems demand restriction of unjustified expenses of water resources and industrial wastes disposing in natural reservoirs. Despite the increased scientific and technical capabilities, the problem of water surface protection and in particular sanitary protection of water objects from impurity remains valid DQGVWLOOGHPDQGVWKHHIIHFWLYHGHFLVLRQV>@7KH choice of optimized technological schemes of industrial water supply refinement is a complex challenge that is caused by a variety of the water impurities and great GHPDQGV PDGH RI UHILQHPHQW TXDlity. The technoeconomic rating of the ways of water preparation has a great significance for the preparation of industrial water from industrial wastewaters or insuring conditions of the EXW GXUL DQGVWLOOGHPDQGVWKHHIIHFWLYHGHFLVLRQV>@7KH ,/<$1,.2/(1.2(59,1.$5,029 GHPDQGV PDGH RI UHILQHPHQW TXD economic rating of the ways of water preparation has a inclined baffle plates 47 … 70%. For IW wastewaters refinement from suspended great significance for the preparation of industrial water from industrial wastewaters or insuring conditions of the materials hydrocyclone machines are used in which the disposal refinement wastewaters of reservoirs. Reverse centrifugal force effecting on particles with a higher systems of industrial water supply usually have got density than that of water is used. They successfully replace settlers having a number of advantages: they economic advantage. The solution of this problem for PCM in many cases occupy small space, have high extent of refinement up to is connected with the organization of the closed water KLJK HIILFLHQF\ KDYH QR PRYLQJ HOHPHQWV WKHLU supply cycles. This task cannot be solved successfully operation can be completely automated. In most cases filtering is used for integrated without effective refinement of the circulating reverse wastewater treatment of IW after all the preliminary water from impurities. treatment methods. It can be surface filtering through filter baffle plates or volume through grained loading. In case of additional reactant treatment of wastewaters, treatment of $1$/<6,6 OF 38%/,&$7,216 IW with coagulant and flocculant on the score In PCM water is used both as the main and the of suspended particles agglomeration and other alterations secondary technological process. Conventionally, these solid particles emission during filtering improves. Reduction of pressure drop on filtering element, increase waters can be divided into the following groups [8,9]. Technological waters are working medium in of refinement precision of power fluid, its preservation technological processes. These technological processes from blinding and therefore self-regeneration support can include: water concentration of nonmetallic minerals, be provided under conditions which will pass the particles hydro-mining, hydro-transport, hydro-washing. These through units of surface filtering element the size of which is much lesser than “in light” units size. These conditions ZDWHUVDUHKHDYLO\SROOXWHGDQGUHTXLUHUHILQHPHQW Cooling waters are formed during cooling the are created on hydrodynamic filters. +\GURG\QDPLF )LOWHULQJ +) LV RQH RI WKH PRGHUQ HTXLSPHQW machines and devices which are used in the main technological process. These waters generally have effective methods of fluid refinement from impurities. the so-called pollution "temperature". Therefore, they are )OXLG UHILQHPHQW RI +) LV EDVHG RQ WKH K\GURG\QDPLF called conditionally clean. They need only cooling and can WKHRU\RI=/)LQNHOVWHLQDERXWWKHPRYHPHQWRILPSXULW\ particles in a fluid flow near the filtering element. In this be reused in processes. Washing and de-dusting waters are formed as a theory it LV DFFHSWHG WKDW WKH ILOWHULQJ HOHPHQW )( washing result of aggregates, machines and HTXLSPHQW and represents the plate covered with regularly located holes also for dust control on PCM. These waters are heavily XQLWVRIDFHUWDLQVL]H>@ In case of the standard refinement scheme of the polluted and need to be cleaned. $OO industrial engineering wastewaters in their use and discharge into water bodies polluted fluid flow it goes perpendicularly WRWKH)(Slane. Only those particles whose linear size is lesser that the size genHUDOO\UHTXLUHUHILQHPHQW $ large number of various impurities in the IW of filtering unit do not linger on it. Particles of the bigger industrial wastewaters is determined by numerous size cumulate from the incident flux and gradually "clog" methods, WHFKQLTXHV and technological scheme used while )(RSHQLQJV7KHUHIRUHGXULQJWKHZRUNRI)(LQDIOX[RI refining them. Ways of industrial wastewaters refinement the polluted fluid its capacity decreases, drop of pressure of insoluble impurities are divided into three groups: on it increases and finally it becomes soiled and loses mechanical refinement – separation of impurities while working capacity. )(LVFRQVLGHUHGFORJJHGLIWKHFUHDWHG going through the passage media; physical refinement – pressure losses on it overrun allowable maximum separation of impurities when fluid stays in force fields; provided by its desiJQ$IWHUWKDWLWLVQHFHVVDU\WRWUDQVIHU combined refinement – separation of impurities from fluid the clogged filter to an initial state by replacement or at a joint mechanical and physical refinement. Mechanical effective flushing which is defined by type of the filter and refinement of fluid is divided into the following types: nature of the detained substances in it. Running time of the surface, volume and mixed. The last type combines filter between two consecutive flashings is called a features of the two first types. Defecation and clarification filtering cycle. 7RUHVWRUHWKH)(LVVXEMHFWWRIOXVKZLWKDSXUHZDWHU of the polluted water in PCM is based on particles on sedimentation of impurities with a higher density than the backwash, replacement or regeneration. To increase density of water at its moving with low speed. Such water contaminant capability RI)(DQGLWV VHUYLFHOLIHWLPHLWLV refinement is made in tank clarifications or settlers of necessary to increase its surface and volume considerably. various designs. Tank clarifications are constructed as one, Therefore such way of fluid refinement is far from perfect two and multiple-stage ones and for keeping water long- in terms of technical and economic indicators as for the term. Effectiveness of clarification in ponds reaches 50 … SHULRGRIUHILQHPHQW RU)(UHSODFHPHQWLWLV QHFHVVDU\WR EXW GXULng winter period their operation is poorer . SURYLGH DGGLWLRQDO UHVHUYH )( LWV SHULRGLF RSHUDWLRQ Ponds need to be cleaned regularly, they occupy a big without refinement. $W+)WKHSROOXWHGIOXLGIORZJRHVSDUDOOHOWRWKH)( surface area and pollute the environment. The effectiveness of horizontal settles refinement with the plane. Thus, hydrodynamic features of system are such regulating perforated baffle plates reaches 39 … 49%, that through filter units together with fluid penetrate only with the system of dispersed water abstraction surface - those particles, which linear size in 3…10 times less than … 69%, and for settlers with thin layer elements from XQLWVL]H%LJSDUWLFOHVDUHZDVKHGDZD\IURP)(VXUIDFH by a fluid flow. TherHIRUH )( RI VXFK NLQG DUH QHYHU inclined baffle plates 47 … 70%. For IW wastewaters refinement from suspended FORJJHG ZLWK SDUWLFOHV RI WKH ELJJHU VL]H %LJ SDUWLFOHV materials hydrocyclone machines are used in which the PRYLQJ LQ D IOXLG IORZ DUH UHPRYHG IURP )( XQLWV DQG VXFK NLQG RI )( ZLWKRXW UHSODFHPHQW ZRUN IURP WR KLJK HIILFLHQF\ KDYH QR PRYLQJ HOHPHQWV WKHLU SRVVLELOLWLHV RI +) LQVWDOODWLRQ LQ 3&0 RI UHYHUVH ZDWHU SURYLGH DGGLWLRQDO UHVHUYH )( LWV SHULRGLF RSHUDWLRQ )(PDW $W+)WKHSROOXWHGIOXLGIORZJRHVSDUDOOHOWRWKH)( ,1&5($6(2)5(9(56(:$7(56833/<6<67(06())(&7,9(1(66 XQLWVL]H%LJSDUWLFOHVDUHZDVKHGDZD\IURP)(VXUIDFH by a fluid flow. TherHIRUH )( RI VXFK NLQG DUH QHYHU >@ FORJJHG ZLWK SDUWLFOHV RI WKH ELJJHU VL]H %LJ SDUWLFOHV – Fluid is incompressible, homogeneous and isothermal; PRYLQJ LQ D IOXLG IORZ DUH UHPRYHG IURP )( XQLWV DQG – Particles are globule and homogeneous; provide its continuous cleaning. The filtering systems with – Thickness influence of walls and interaction of moving VXFK NLQG RI )( ZLWKRXW UHSODFHPHQW ZRUN IURP WR particles on velocity distribution isn't considered; years without technical servicing and repair. – Inertia of particles in a longitudinal flux isn’t The purpose of the work consists in studying the considered; SRVVLELOLWLHV RI +) LQVWDOODWLRQ LQ 3&0 RI UHYHUVH ZDWHU – 2SHQLQJVLQ)(DUHDFFHSWHUURXQG supply to increase its effectiveness in the way of energy We will use the principle of superposition. We will and natural resource saving in the process of refinement consider a vector of absolute participle velocity v as a industrial water from impurities. vector sum of flux velocities v0 through a large number of RSHQLQJV LQ)(DQGVSHHGRIDORQJLWXGLQDOIOX[ vm$V D SUHVVXUH ORVVHV RI D IOX[ SUHVVXUH PRYLQJ OHQJWKZD\V )( 67$7(0(172)7+(352%/(0 are insignificant it is possible to consider sizes of volume H[SHQVHV WKURXJK VHSDUDWH RSHQLQJV HTXDO 6XPPDUL]LQJ The theory of hydrodynamic refinement is based on these speed components in a certain point of space we consideration of the particle movement located in the receive sizes of longitudinal and transverse velocities SROOXWHG ]RQH LQ DQ RSHQLQJ ]RQH >@ :H ZLOO XQGHU WKH LQIOXHQFH RI SUHVVXUH GURS RQ )( For FRQVLGHUWKH+)VFKHPHLQSLF7KHFRPSOH[PRYHPHQW determination of the maximum particle diameter which RISROOXWLRQSDUWLFOHVUHODWLYHO\WR)(FDQEHSUHVHnted as a FDQ SDVV WKURXJK )( RSHQLQJ ZH ZLOO FRQVLGHU D FULWLFDO sum of two movements: longitudinal and transverse. case. Thee particle with diameter d and center of gravity in 3DUWLFOHVZKLFKDUHLQWKHIOXLGOD\HUVFORVHVWWR)(VXUIDFH a point O LVSODFHGRQWKHSLF For calculation we accept the following parameters: have maximum likelihood to get into an opening. The EDVLV RI +) WKHRU\ LV D PRGHO RI SDUWLFOH PRYHPHQW Q – VXSSO\ RI WKH SROOXWHG IOXLG RQ )( Q1 – part of relatively to FF with the certain ratio of longitudinal and supply which is refined; ' p - pressure drop which is transverse velocity. If the angle of slope tangent to particle allowed from operation conditions RQ)( We will determine the parameter of a cross flux: trajectory D arctg §¨ vo ·¸ is greater than the diagonal section ¨v ¸ © m¹ of the unit in the longitudinal plane, the particle of pollution has an ability to pass in a unit space. Restriction of polluted particle detention in units is represented as the speed ratio: v d ! o . 2c vm Q , kF q where: k S c 2 , coefficient of flow section, F – )(VTXDUH 2c m 2 Q2c m . q Therefore, depending on the trajectory angle D , FS c 2 dimension ratio of particle diameter d and diameter of the unit opening 2c . the particle can pass in the space under $WWKHVHWvelocity v0 RIFURVVIOX[IURPZHGHILQH )( XQGHU WKH DFWLRQ RI D FURVV IOX[ RU EH GLVSODFHG E\ D QHFHVVDU\)(VTXDUH ORQJLWXGLQDOIOX[DORQJ)( q v0 S c 2 F 2 . We determine the velocity of a longitudinal flux from the condition: Fig. 1. Scheme of hydrodynamic filtering c – unit radius; m – the minimum distance between cells; d – particle diameter; vm– longitudinal flux velocity v0 – cross flux velocity; v – absolute velocity of particle balance center; l – )(PDWerial thickness For engineering practice development calculation a set of assumptions was accepted, which not significantly change the nature of hydrodynamic filtering process >@ – Fluid is incompressible, homogeneous and isothermal; – Particles are globule and homogeneous; Q Q , Q2 where: Q2 – flow rate of the impure IOXLGOHDYLQJ)( )URPFRQVWUXFWLYHUHDVRQVZHFKRRVH)(OHQJWK L on ZKLFKZHILQG)(ZLGWK: F. L B &RQVLGHULQJ)(F\OLQGULFDOLWVGLDPHWHU: Dɤɪ B, S 7KHDUHDRIDFUDFNEHWZHHQ)(DQGWKHILOWHUERG\DW 2SHQLQJVLQ)(DUHDFFHSWHUURXQG RSHQLQJV LQ)(DQGVSHHGRIDORQJLWXGLQDOIOX[ $V D Q X &RQVLGHULQJ)(F\OLQGULFDOLWVGLDPHWHU ɤɪ S ,/<$1,.2/(1.2(59,1.$5,029 X 7KHDUHDRIDFUDFNEHWZHHQ)(DQGWKHILOWHUERG\DW the end of a longitudinal flux: ɫɪ Q . Xm ¦X d ª Q Q 2 2c m º « » , 2 2 2 S q l ¬ SXm ¼ 0. ª Q Q Q 2c m º « » S 2 q 2l 2 ¼ ¬ SXm 2 Dk X For realization of this condition diameters of conical part of the body: Dɧ Xm $WWKHEHJLQQLQJRIDIOX[: Sɧ Thus, despite the preservations average longitudinal velocity constant along the filter length the local velocity LQWKHJDSIURPWKHVXUIDFHRI)(GHSHQGVRQWKHULQJJDS height. The received velocity X m for necessary filtration degree LQWKLVFDVHZRQ WEHHTXDOWRDYHUDJHDQGWKHUHIRUH it is impossible directly to determine Q2 $WODPLQDUIORZVLWLVQHFHVVDU\WRZULWHGRZQ: Q Q . Sk . Critical diameter of a particle after substitutions and transformations is defined in the following manner: d 0, Ugd 2 P . 2c z h z Q2 X ¦ m S h2 0 § cUg · d 2 ¨¨ h ¸ dX 0 2cX m 2h 2 © P ¹̧ 0. The last formula can be solved in final coefficients with Cardano's method however it is much simpler to find its Thus, at a given supply the certain geometrical YDOXH ZKLFK LV DSSURDFKHG RQ WKH DYDLODEOH (&0 SDUDPHWHUV RI WKH )( DQG ERG\ DUH GHILQHG VSHHGV RI D algorithms. Further calculations don't undergo changes. longitudinal and cross flux on which specifies the fineness of filtration. If the velocity of a longitudinal flux is accepted by a 0(7+2'2)7+((;3(5,0(17 constant gap section, it corresponds to the assumption of WKH WXUEXOHQW PRGH RI WKH IOX[ PRYHPHQW DORQJ )( 7KH ([SHULPHQWDO LQVWDOODWLRQ ZKLFK VFKHPH GLDJUDP LV acceptability of such assumption can be proved only by shown on pic.2 is developed for physical modeling of existence of local flux resistance on an entrance to the process of PCM wastewater refinement from impurities ILOWHU ZKLFK LV UDWKHU VPDOO LQ )( OHQJWK LQ FRPSDULVRQ ZLWK DSSOLFDWLRQ RI +') ,QVWDOODWLRQ FRQVLVWV RI WKUHH with diameter of rather high longitudinal fluxes. FDSDFLWLHV ZLWK LQLWLDO ZDWHU ZLWK FOHDred 2 and $W WKH VHW JHRPHWULFDO SDUDPHWHUV DQG IOXLG YLVFRVLW\ FDSDFLWLHVIRUSROOXWHGZDWHUVWRUDJHWKHGUDLQDJHSXPS the mode movement depends only on flux rate. Therefore, WKH K\GURG\QDPLF ILOWHU – WKH ).'- W\SH DW D FHUWDLQ H[SHQVHV RI WKH SROOXWHG IOXLG RQ )( LW LV IORZPHWHUVPDQRPHWHUVDQGWKHUHJXODWLQJILWWLQJV possible to provide the laminar flow movement. In case of DQGWKHE\SDVVOLQH:DWHULVVXSSOLHGE\GUDLQDJHSXPS a laminar flow in a ring crack of velocities in a gap are WKURXJKDIORZPHWHUWKHPDQRPHWHUWKHFRFNLQ distributed under the parabolic law. We will determine gap the hydrodynamic filter 9 where the flow is divided into VL]HRYHU)(DWWKHEHJLQQLQJRIWKHILOWHU: two components: the cleared water which is flushed via the pipeline with a flowmeter 8 and the manometer 7 in Dɧ Dɫɪ , FDSDFLW\ DQG WKH VOLPH IORZLQJ WR FDSDFLW\ 7KH hɧ 2 consumption of the initial polluted water varies the degree of closing of the valve RQ WKH VXSSO\ SLSH 2WKHU In the end of the filter: expense through the bypass line PHUJHVLQWKHWDQN %DVHGRQWKHDQDO\VLVRIZDVWHZDWHUIRUH[SHULPHQWDO Dk Dɫɪ . studies of refinement installation process of partial flow hk 2 hydrodynamic filter which is intended for refinement of various fluids from insoluble impurity at supply of the )URP D FRQGLWLRQ RI DYHUDJH YHORFLWLHV HTXDOLW\ RQ SROOXWHG OLTXLG WR OPLQ LV SURYLGHG )RU FUHDWLQJ D VHFWLRQDORQJ)(: ORQJLWXGLQDO IOX[ RI WKH IOXLG LQ FLUFXODWLRQ bypassing the reILQHG IORZ 7KH SURFHVV RI +') ZDV Q2 . Q modeled on artificial wastewaters. Knowing wastewaters X m.ɫɪ S Dɧ2 Dɮ2 S impurity of PCM, which comes to clean, water for H[SHULPHQW LV PRGHOHG $V WKH SROOXWLQJ VXEVWDQFH WKH Therefore, velocity on height ring gap is distributed selected tests of slime from slime pit which operate on PCM are applied. on dependence: Xm z h z X m.ɫɪ . h2 Thus, despite the preservations average longitudinal LQWKHJDSIURPWKHVXUIDFHRI)(GHSHQGVRQWKHULQJJDS X LQWKLVFDVHZRQ WEHHTXDOWRDYHUDJHDQGWKHUHIRUH Q2 ,1&5($6(2)5(9(56(:$7(56833/<6<67(06())(&7,9(1(66 ɫ Fig. 2. Scheme of experimental installation The composition of production wastewaters of SharkhinskSLWV SLWV$OXVKWD&ULPHD $OXVKWD&ULPHDZKLFK ZKLFKDUH DUHIRUPHG IRUPHGE\ E\ washing crushed stone is presented in TDEOH DEOH DEOH7KH 7KH increased image of impurities containing in wastewaters from crushed stone after washing has been received by a micro-SKRWRPHWKRGLVVKRZQLQSLF,QWKLVIDFWRIGDWD SKRWRPHWKRGLVVKRZQLQSLF,QWKLVIDFWRIGDWD SKRWRPHWKRGLVVKRZQLQSLF,QWKLVIDFWRIGDWD ).'-ILOWHU IUDFWLRQDOVWUXFWXUHRILPSXULWLHVIRUWKH IUDFWLRQDOVWUXFWXUHRILPSXULWLHVIRUWKH).' ).' ILOWHU ILOWHU DV DV)( )(WKH WKHPHWDO PHWDOJDX]H JDX]HZLWK ZLWKDDVL]H VL]HRI RIXQLWV XQLWVRI RI [[ microns was accepted therefore the expected fineness of the detained firm mineral particles will make 15 … 20 microns. Table 1. Fractional composition of slimes in the total remains Total mass content, Size of fraction, mm 1,25…0,63 0,63…0,315 0,315…0,15 0,15…0,08 0,08…0,05 0,05…0,01 0,01…0,005 0,005…0,002 0,002…0,001 aa DJHIRUPLQ For receiving artificial wastewater slime is previously dried up to the constant weight in a drying cabinet. Then slime is crushed for the purpose of receiving homogeneous PDVV DQG HOLPLQDWLRQ IURP VOLPH OXPSV )RU +') parameters process research the kinetics of sedimentation of the suspended materials of artificial wastewaters is previously studied. For this purpose dependence graphic of optical density on weighed substances concentration are under construction. The graphic is under construction according to indications of optical density of the tests ZKLFK DUH VHOHFWHG DIWHU VW PLQXWH RI VHGLPHQWDWLRQ DV during this period large particles are drop out and they will QRW LQIOXHQFH RQ WKH SURFHVV RI +') :H ZLOO GHWHUPLQH WKH +') SDUDPHWHUV E\ WKH DFWXDO FRQcentration of impurities. For its determination we use samples of the impure water on PCM slime tests with concentration 1 … JO DIWHU PLQXWH GHVLOWLQJ 7KHQ WHVWV ZKLFK DUH UXQ through specially prepared paper filters are selected. Further filters are dried up in a drying cabinet. The actual concentration of polluted PCV of artificial wastewater is determined by a difference of mass of the dry filter before filtration and the dry filter with the suspended materials after filtration carried to the volume of the filtered test. Tests of artificial wastewaters are being prepared and their light transmittance on the photo-colorimeter is FKHFNHG %HFDXVH RI D KLJK WXUELGLW\ RI WHVWV LQ WKH DFFHSWHGUDQJHRIKLJKFRQFHQWUDWLRQPRUHWKDQJOWKH selected tests are diluted several times. On the received values the dependence graphic of optical density on the actual concentration of the suspended materials on which WKH+')SDUDPHWHUVDUHHVWLPDWHGLVXQGHUFRQVWUXFWLRQ .(<),1',1*6 7KH DQDO\VLV RI +') SURcess allowed allocating three major factors which influence on refinement effectiveness: initial concentration of the suspended materials; a consumption of in-taking wastewater which is regulated by a throttle on filter entrance; a ratio of a useful and slime expense on the filter which are provided with adjustment of a throttle on the bypass line. The method of rotatable design of experiment which allows receiving more exact mathematical description of a surface response IDFWRULDO+')UHVHDUFKHV in comparison with orthogonal central composite planning ZDV DSSOLHG WR SURFHVVLQJ RI H[SHULPHQWDO GDWD RQ +') > @ ,W LV UHDFKHG WKDQNV WR LQFUHDVH LQ QXPEHUĮRI experiences in the center of the plan and a special size choice of a star shoulder a. The main characteristic of a matrix of rotatable design of three-factorial experiment is provided in table 2. $WURWDWDEOHFHQWUDO FRPSRVLWHGHVLJQIRUFRHIILFLHQWV calculation of regression and the corresponding estimates of dispersion constants are defined: bb DIWHU+') cc )LJ0LFUR-photos )LJ0LFUR-photos )LJ0LFUR ofofwastewaters wastewatersimpurities impuritiesreceived receivedfrom from crushed stone washing: a, – before refinement; b – after slime stDJHIRUPLQ ɫ – DIWHU+') Ⱥ B For receiving artificial wastewater slime is previously PDVV DQG HOLPLQDWLRQ IURP VOLPH OXPSV )RU +') , 2 ȼ>n 2B n@ n 2N N 0 nN N , UHJUHVVLRQ RI +') DV UHVLGXDO FRQFHQWUDWLRQ IXQFWLRQV RI IDFWRULDO+')UHVHDUFKHV ,/<$1,.2/(1.2(59,1.$5,029 Į Ta b l e 2 . 7KHFKDUDFWHULVWLFRIURWDWDEOHFHQWUDOFRPSRVLWHGHVLJQIRUWKUHHIDFWRULDO+')UHVHDUFKHV UHJUHVVLRQHTXDWLRQE\)LVFKHU VFULWHULRQ)RUWKHHTXDWLRQ Total number of Number of factors Number of factorial Number of experiences Number of experiences Į FDOFXODWHG design experiences in star points in plan centre experiences Ɋɞ > @ >@7KHYDOLGLW\FKHFN Ta b l e 3 . $FWXDOH[SHULPHQWDOFRQGLWLRQV LV VDWLVILHG WKHUHIRUH WKH UHJUHVVLRQ HTXDWLRQ d> @ Number of factors n Value of factors at plan code values DGHTXDWHO\GHVFULEHVDVXUIDFHUHVSRQVHIRUWKHFRQVLGHUHG Designation of +') SURFHVV 7KH DQDO\VLV RI WKH Variation interval 0 UHFHLYHG UHJUHVVLRQ Name of variation factors Ⱥ variation factors HTXDWLRQDOORZVGUDZLQJDFRQFOXVLRQRQH[LVWHQFHRIWKH ȼ> @ 8 $WURWDWDEOHFHQWUDO FRPSRVLWHGHVLJQIRUFRHIILFLHQWV Initial conc. of suspended materials Consumption of in-taking water, l/min Ratio of useful and slime expense C N , N N0 ; ; ; 70,2 HTXDWLRQ FKDUDFWHUL]HV 7KH UHJUHVVLRQ WKH 20 removal process of the suspended materials on the hydrodynamic filter and allows estimating influence of three considered factors on residual concentration of impurity, and also describes a surface response. For HYDOXDWLRQ RI UHILQHPHQW HIIHFWLYHQHVV RI +') ZH ZLOO enter function of the following type: ZDVWHZDWHUVDIWHU+')IRURWKHUYDOXHVRIWKHFRQVLGHUHG SDUDPHWHUV RQ SLF WKHxFDOFXODWLRQ LV FDUULHG RXW RQ Y Z . x where: n - number of factors; N - total number of rotatable central composite design experiences; N0 number of experiences in the plane center. For three-factorial experiment of a constant for coefficients calculation of regression and the § · ¨ corresponding estimates of dispersions; A 0, ; ȼ 0, ; © ¹̧ 7KH FDOFXODWLRQ UHVXOWV RI +') UHILQHPHQW HIIHFɋ ,. tiveness IURPWKHFRQVLGHUHGIDFWRUVDUHJLYHQLQSLFˈϯсϭ͕Ϯϱ %DVHGRQWKHUHVXOWVRISUHOLPLQDU\H[SHULPHQWranges ˈϯсϭ From the analysis of the received results obtained and points in vicinities which the plan of three-factorial DSSOLFDWLRQ RI +') IRU WKH DFFHSWHG VL]H RI XQLWV RI )( experiment is determined: ϵϬ ;– initial concentration of the weighed substances, and fractional composition of ϵϬ slimes can provide ϴϬ UHILQHPHQW HIIHFWLYHQHVV WR 7DNLQJ LQWR DFFRXnt ͕й ϮϬ ϴϬ ϳϬ 2 … 4 g/l. Ϯϱ fractional composition of slimes in ͕йsize of the total ϮϬ ϳϬ ϯϬ ϲϬ ϯϱ ; – supply of wastewater on the filter, 20 … 70 Ϯϱ ϰϬ ϯϬ ϲϬ ϰϱ ϱϬ UHPDLQVWDEWKHPDLQWHQDQFHRISDUWLFOHVOHVVWKDQ ϯϱ ϱϬ ϰϬ l/min. ϰ ϰϱ ϱϬ ϱϱ ϯ͕ϱ microns in size contains in tests of artificial wastewaters to ϲϬ ϱϬ ϯ ϰ Y̛͕̣̥̦ͬ ; – a ratio of a useful and slime expense on the ϱϱ Ϯ͕ϱ ϯ͕ϱ ϲϬ DQG SDUWLFOHV OHVV WKDQ PLFURQV - WRϲϱ Ϯ ϳϬ ϯ Y̛͕̣̥̦ͬ ϲϱ filter, 1 … 2 K. Ϯ͕ϱ Ϯ ϳϬ sizes of impurity particles ĞŶ͕̣̐ͬ The actual conditions for the accepted rotatable Therefore, in this range of theĞŶ͕̣̐ͬ ϱϬͲϲϬ ϲϬͲϳϬ RI +') ϳϬͲϴϬ ϴϬͲϵϬ WKH DFFHSWHG SDUDPHWHUV RI RSHUDWLQJ SURFHVV central composite design of experiment are presented in ϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ ϴϬͲϵϬ SURYLGH WKHLU IXOO UHPRYDO DFFRUGLQJ WR WKH VL]H RI )( WDEOH LQ WKH IRUP RI YDOXHV RI IDFWRUV DQG LQWHUYDOV RI ɚ units. their variation. ˈϯсϮon the Change of a ratio ˈofϯсϭ͕ϱ a useful and slime expense $V D UHVXOW RI FDUU\LQJ RXW DFFRUGLQJ WR WKH FKRVHQ filter in the range d x d 2 significantly influences on $FWXDOH[SHULPHQWDOFRQGLWLRQV SODQRIH[SHULPHQWDOVWXGLHVWKHVXEVHTXHQWSURFHVVLQJRI refinement in the relation of a LWVNumber UHVXOWV WKH HTXDWLRQ RI UHILQHPHQW HIIHFWLYHQHVV of factors Value of factors at plan code valueseffectiveness. With increase ϵϬ filter the residual UHJUHVVLRQ RI +') DV UHVLGXDO FRQFHQWUDWLRQ IXQFWLRQV RI useful and slime expense onϮϬ the ϵϬ ϴϬ Designation ϮϬ concentration almost depends ϯϬless on the size of ͕й ϴϬ ϳϬ rather Name accepted of variationfactors is received:Variation Ϯϱ ͕й ϯϬ ϳϬ ϯϱ wastewaters supply on the filterϲϬ ϰϬand is defined by ϰϬ ϰϱ ϱϬ ϲϬ ϱϬ generally initial concentration of impurities. On the ϱϬ Y 0, 0, x 0, x2 0, x ϰ ϱϱ Initial conc. of ϯ͕ϱY̛͕̣̥̦ͬ ϱϬ ϲϬ ϲϬ of this residual 2 Y̛͕̣̥̦ͬ ϯ contrary at reduction concentration relation ϰ ϲϱ Ϯ͕ϱ 0, x 0, x 0, x 0suspended , xmaterials ϯ͕ϱ Ϯ ϳϬ ϯ ϳϬ almost depends less from initial concentrationϮ͕ϱ of Consumption of inϮ ĞŶ͕̣̐ͬ . x22 0l/min 0taking ,water, , x2 0, x impurities but generally defined by the size of wastewatersĞŶ͕̣̐ͬ ϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ ϴϬͲϵϬ Ratio of useful and on the filter. supply ϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ ϴϬͲϵϬ slime expense We will execute validity check of the received For finding the residual concentration in the refined UHJUHVVLRQHTXDWLRQE\)LVFKHU VFULWHULRQ)RUWKHHTXDWLRQ ZDVWHZDWHUVDIWHU+')IRURWKHUYDOXHVRIWKHFRQVLGHUHG 'HSHQGHQFHRIUHILQHPHQWHIIHFWLYHQHVVRI+')IURPLQLWLDO FDOFXODWHG value of Fischer's criterion made Fp , . SDUDPHWHUV RQ SLF WKH FDOFXODWLRQ LV FDUULHG RXW RQ dependence: Tabular value of Fischer's criterion at confidence Z ·. § coefficient Ɋɞ - >F @ >@7KHYDOLGLW\FKHFN ɚ Y x ¨ © ¹̧ FP d >F @ LV VDWLVILHG WKHUHIRUH WKH UHJUHVVLRQ HTXDWLRQ DGHTXDWHO\GHVFULEHVDVXUIDFHUHVSRQVHIRUWKHFRQVLGHUHG 7KXVWKH+')SDUDPHWHUVZKLFKFDQIRUPDEDVLVIRU ˈϯсϭ͕Ϯϱ ˈϯсϭ +') SURFHVV 7KH DQDO\VLV RI WKH UHFHLYHG UHJUHVVLRQ development of modern technological graphics of reverse HTXDWLRQDOORZVGUDZLQJDFRQFOXVLRQRQH[LVWHQFHRIWKH water supply of PCM are experimentally established. The ϵϬ actual values of factors which provide optimum conditions residual concentration of the suspended materials received ϵϬ ϴϬ of wastewaters refinement from impurities. DIWHU +') LV VXIILFLHQW WR UHXVH UHILQHG ZDVWHZDWHUV LQ ͕й ϮϬ ϴϬ ϳϬ Ϯϱ 7KH UHJUHVVLRQ HTXDWLRQ FKDUDFWHUL]HV WKH PCM and to reuse separated impurities. Installation in ϮϬ ϳϬ ϯϬ ͕й ϲϬ ϯϱ Ϯϱ ϰϬ ϱϬ removal process of the suspended materials on the PCMϯϬthe with application ϯϱ systems of reverse waterϲϬsupply ϰϱ ϱϬ ϰϬ ϰ ϰϱ ϱϬ ϱϱ ϯ͕ϱ hydrodynamic filter and allows estimating influence of RI +') DOORZ XVLQJ HIIHFWLYHO\ WKHLU DGYDQWDJHV WKDt ϲϬ ϱϬ ϯ ϰ Y̛͕̣̥̦ͬ ϱϱ ϲϱ Ϯ͕ϱ ϯ͕ϱ ϲϬ three considered factors on residual concentration of provide more rational use of ϯenergy and natural resources. Ϯ ϳϬ Y̛͕̣̥̦ͬ ϲϱ Ϯ ϳϬ HYDOXDWLRQ RI UHILQHPHQW HIIHFWLYHQHVV RI +') ZH ZLOO ϱϬͲϲϬ ϲϬͲϳϬ Ϯ͕ϱ ϳϬͲϴϬ ĞŶ͕̣̐ͬ ĞŶ͕̣̐ͬϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ ϴϬͲϵϬ ɚ ˈϯсϭ͕ϱ ˈϯсϮ +\GURG\QDPLFILOWHUVDUHLQWHUPHGLDWHEHWZHHQPLFUR ϴϬͲϵϬ ˈϯсϭ͕Ϯϱ ˈϯсϭ͕Ϯϱ ˈϯсϭ ˈϯсϭ ϵϬ ϵϬ ϮϬ ϴϬ ϮϬ Ϯϱ ϴϬ Ϯϱ ϯϬ ͕й ϳϬ ϯϱ ϳϬ ϯϬ ͕й ϯϱ ϰϬ ϲϬ ϰϬ ϰϱ ϲϬ ϰϱ ϱϬ ϱϬ ϱϱ ϱϬ ϱϬ ϲϬ ˈ3ϱϱ =1,25 ϰ ϲϬ ϯ͕ϱ ϰ Y̛͕̣̥̦ͬ Y̛͕̣̥̦ͬ ϯ͕ϱ RIWKHVXVSHQGHGPDWHULDOVZLWKWKHVL]HVIURPPLFURQV WR ϵϬ PP 7KH H[LVWLQJ JULGV WKDW DUH FRPPHUFLDOO\ ϵϬ ϴϬ DYDLODEOH KDYH WKH PLQLPXP XQLW VL]H RI ɯ PLFURQV ϴϬ ϳϬ ͕й ͕й ϳϬ ,1&5($6(2)5(9(56(:$7(56833/<6<67(06())(&7,9(1(66 ϲϬ ϲϬ PLQHUDO SDUWLFOHV ZLOO PDNH « PLFURQV 6XFK ϱϬ ϱϬ ϰ VXEWOHW\ RI UHILQHPHQW LV TXLWH DFFHSWDEOH DW SUHOLPLQDU\ ϯ͕ϱ ϰ ϯ ϯ͕ϱ ϲϱ Ϯ͕ϱ ϯ stages of mechanical water and wastewaters refinement, ϲϱ ϳϬ Ϯ͕ϱ Ϯ ϯ Ϯ ϲϱ ϳϬ Ϯ͕ϱ ϯ ĞŶ͕̣̐ͬ Y̛͕̣̥̦ͬ ϲϱ ϳϬ and it is sufficient for a number of reverse systems of the Ϯ Ϯ͕ϱ ĞŶ͕̣̐ͬ Ϯ ϳϬ ĞŶ͕̣̐ͬϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ ϴϬͲϵϬ industrial enterprises for refinement of technological ĞŶ͕̣̐ͬϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ ϴϬͲϵϬ Z, % ϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ Z, % ϴϬͲϵϬ ZDVWHZDWHUV IRU WHFKQLFDO QHHGV +') QHHG WR EH ϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ ϴϬͲϵϬ ɚɚ considered as a preliminary stage of mechanical refinement for firm mineral particles removal more than Q,̛̣̥̦ͬ ˈϯсϭ͕ϱ ˈ ϯ сϮ Q,̛̣̥̦ͬ ˈϯсϭ͕ϱ ˈϯсϮ Cen͕̣̐ͬ 20 microns in size. Cen͕̣̐ͬ The plan of three-factoriaO H[SHULPHQW RI +') ɚ b ϵϬ wastewaters of PCM is developed, researches are ϵϬ ϵϬ ϴϬ ˈ =2 ˈ =1,5 ϮϬ ϵϬ FRQGXFWHG DQG WKH UHJUHVVLRQ HTXDWLRQ FKDUDFWHUL]LQJ WKH ϴϬ ϮϬ ϮϬ ͕й ϴϬ ϳϬ ϯϬ ϮϬ Ϯϱ ͕й ϴϬ ͕й of the suspended materials removal is received. ϳϬ ϯϬ process Ϯϱ ϯϬ ϲϬ ϰϬ ϳϬ ͕й ϯϬ ϯϱ ϲϬ ϰϬ ϳϬ ϯϱ ϰϬ Dependences are established which help to calculate the ϰϬ ϰϱ ϱϬ ϲϬ ϱϬ ϰϱ ϱϬ ϱϬ ϲϬ ϱϬ ϰ ϱϬ ϱϱ residual content of the suspended material depending on ϯ͕ϱ ϱϬ ϰ Z, % Z, % Y̛͕̣̥̦ͬ ϲϬ ϱϱ ϲϬ ϯ ϯ͕ϱY̛͕̣̥̦ͬ Y̛͕̣̥̦ͬ ϱϬ ϲϬ ϲϬ ϲϱ ϰ Y̛͕̣̥̦ͬ Ϯ͕ϱ ϯ ϯ͕ϱinitial concentration of impurity, a ratio of a useful and ϰ ϲϱ ϳϬ Ϯ͕ϱ Ϯ ϯ ϳϬ ϯ͕ϱ Ϯ ϳϬ Q,̛̣̥̦ͬ Ϯ͕ϱ ϯ ϳϬ Ϯ Ϯ͕ϱ ĞŶ͕̣̐ͬ slime expense on the filter and a consumption of the ĞŶ͕̣̐ͬ Ϯ ĞŶ͕̣̐ͬ Q,̛̣̥̦ͬ ĞŶ͕̣̐ͬ SURFHVVHGIOXLGRQWKHK\GURG\QDPLFILOWHU$VDUHVXOWRI ϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ ϴϬͲϵϬ Cen͕̣̐ͬ ϱϬͲϲϬ ϲϬͲϳϬ Cen͕̣̐ͬ ϳϬͲϴϬ ϴϬͲϵϬ ϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ ϴϬͲϵϬ experimental studies on the simulated composition of ϱϬͲϲϬ ϲϬͲϳϬ ϳϬͲϴϬ ϴϬͲϵϬ 3&0 ZDVWHZDWHUV WKH UHJUHVVLRQ HTXDWLRQ RI UHILQHPHQW c d c d effectiveness which characterizes the removal process of Fig. 3. 'HSHQGHQFHRIUHILQHPHQWHIIHFWLYHQHVVRI+')IURPLQLWLDO 'HSHQGHQFHRIUHILQHPHQWHIIHFWLYHQHVVRI+')IURPLQLWLDO suspended materials on the hydrodynamic filter is concentration of the suspended materials and from wastewater supply on the filter at various values of a useful and slime expense ratios on established and allows estimating influence of three the filter: : ɚɚ - x ,0 ; b - x , ; c - x , ; d- x 2,0 considered factors on residual impurity concentration. +')SURYLGHKLJKH[WHQWRIUHILQHPHQWDWZDVWHZDWHUV refinement of PCM technological capabilities which 7KXVWKH+')SDUDPHWHUVZKLFKFDQIRUPDEDVLVIRU 7KXVWKH+')SDUDPHWHUVZKLFKFDQIRUPDEDVLVIRU allows using them effectively in systems of reverse water development of modern technological graphics of reverse supply of such industry. water supply of PCM are experimentally established. The ϮϬ ϮϬ Ϯϱ Ϯϱ ϯϬ ϯϬ ϯϱ ϯϱ ϰϬ ϰϬ ϰϱ ϰϱ ϱϬ ˈ3=1 ϱϬ ϱϱ ϱϱ ϲϬ ϲϬ Y̛͕̣̥̦ͬ 90 90 80 80 20 25 20 70 30 35 25 70 30 60 35 60 40 45 40 45 50 55 3,5 60 50 50 4 55 3,5 60 3 65 3 65 50 4 2,5 2 70 2,5 2 70 50-60 50-60 60-70 70-80 60-70 70-80 80-90 80-90 3 3 90 90 20 80 20 25 70 30 35 60 40 45 50 55 3,5 60 80 30 70 40 60 3 65 60 50 50 4 70 2,5 2 2 70 50-60 60-70 70-80 80-90 50-60 60-70 2,5 70-80 3 3,5 50 4 80-90 residual concentration of the suspended materials received DIWHU +') +') LV LV VXIILFLHQW VXIILFLHQW WR WR UHXVH UHXVH UHILQHG UHILQHG ZDVWHZDWHUV ZDVWHZDWHUV LQ LQ DIWHU PCM and to reuse separated impurities. Installation in PCM the systems of reverse water supply with application RI +') +') DOORZ DOORZ XVLQJ XVLQJ HIIHFWLYHO\ HIIHFWLYHO\ WKHLU RI WKHLU DGYDQWDJHV DGYDQWDJHV WKD WKDt provide more rational use of energy and natural resources. CONCLUSIONS +\GURG\QDPLFILOWHUVDUHLQWHUPHGLDWHEHWZHHQPLFUR +\GURG\QDPLFILOWHUVDUHLQWHUPHGLDWHEHWZHHQPLFURFORQHV $W $W REVHUYDQFH REVHUYDQFH RI RI QHFHVVDU\ QHFHVVDU\ filters and hydro-FORQHV speeds of a flow fineness of the detained particles hydrodynamic filters ZLOO EH WLPHV OHVV WKDQ PLFURfilters, at the identical sizes of units of grids which will be established in them. Fineness of the detained particles in the hydrodynamic filter is smaller than fineness of the particles detained in a hydro-clone at identical velocity of a flow. Thus it should be noted that micro-filters and hydro-clones at installation in working conditions have showed good technical and economic indicators. +\GURG\QDPLF ILOWHUV DUH GHSULYHG RI PLFUR-filters shortcomings - they do not demand flushing, and are deprived of hydro-clones shortcomings – they don't have increased mechanical wear. It provides high technical and HFRQRPLFUDWHVDW+')LQVWDOODWLRQLQV\VWHPVRILQGXVWULDO wastewaters refinement. In practice of water conditioning and purification, wastewaters refinement it is necessary to delete particles RIWKHVXVSHQGHGPDWHULDOVZLWKWKHVL]HVIURPPLFURQV WR PP 7KH H[LVWLQJ JULGV WKDW DUH FRPPHUFLDOO\ DYDLODEOH KDYH WKH PLQLPXP XQLW VL]H RI ɯ PLFURQV therefore the expected fineness of the detained firm PLQHUDO SDUWLFOHV ZLOO PDNH « PLFURQV 6XFK VXEWOHW\ RI UHILQHPHQW LV TXLWH DFFHSWDEOH DW SUHOLPLQDU\ stages of mechanical water and wastewaters refinement, and it is sufficient for a number of reverse systems of the ZDVWHZDWHUV IRU WHFKQLFDO QHHGV +') QHHG WR EH 2. 7. 8. 9. 5()(5(1&(6 Sokolov L.I., 1997. Resursosberegayushchiye tekhnologii v sistemakh vodnogo khozyaystva promyshlennykh predpriyatiy/L.I.Sokolov – 0$69 – Alferova L.A., Nachayev A.P., 1984. =DPNQXW\\H sistemy vodnogo khozyaystva promyshlennykh predpriyatiy, kompleksov i rayonov./ L.$$OIHURYDL dr. - M.: Stroyizdat. - Koganovskiy A.M., 1983. Ochistka i ispol'zovaniye stochnykh vod v promyshlennom vodosnabzhenii. M.: Khimiya. - Gromov B. V., Laskorin B. N., 1985. Problemy razvitiya bezotkhodnykh proizvodstv. - M.: Stroyizdat. – =KXNRY$,0RQJD\W,/5RG]LOOHU,' Metody ochistki proizvodstvennykh stochnykh YRG$,=KXNRYLGU- M.: Stroyizdat. - 1LNROHQNR,6DOLHY<H The feasibility report on maintainability of the water supply and sewerage system// MOTROL. – 9ROʋ– - 6DOLHY ( (FRORJRORJLFDO DQG (FRQRPLF Problems of Power Saving up Technologies’ Introduction in Ukraine// MOTROL. - ʋ%– %D]KHQRY <80 $OLPRY /$ 9RURQLQD 99 Treskeva N.V., 2005. Proyektirovaniye predpriyatiy po proizvodstvu stroitel'nykh materialov i izdeliy./ <80%D]KHQRYLGU– 0$69- Bogdanov V.S., Borshchevskiy A.A., Il'in A.S., 2000. Tekhnologicheskiye kompleksy i linii dlya proizvodstva stroitel'nykh materialov i izdeliy./ V.S. %RJGDQRYLGU06WUR\L]GDW– Nikolenko I.V., Skidan V.V., 2011. Perspektivy primeneniya gidrodinamicheskikh fil'trov dlya PDWHULDORY, 9 1LNROHQNR 8FKHQ\\H ]DSLVNL 9ROʋ7HNKQQDXNL %D]KHQRY <80 $OLPRY /$ 9RURQLQD 99 <80%D]KHQRYLGU 0$69 ʋ $GOHU<810DUNRYD<H9*UDQRYVNL\<89 ,/<$1,.2/(1.2(59,1.$5,029 RSWLPDO Q\NK XVORYL\ <8 1 $GOHU L GU %RJGDQRYLGU06WUR\L]GDW– Nauka. – . %RJGDQRYLGU06WUR\L]GDW Nikolenko I.V., Skidan V.V., 2011. Perspektivy Ruzinov L. P., 1972. Staticheskiye metody primeneniya gidrodinamicheskikh fil'trov dlya optimizatsii khimicheskikh protsessov. - M.: Khimiya. obespecheniya ratsional'nogo ispol'zovaniya – prirodnykh resursov (pri proizvodstve stroitel'nykh Tikhomirov V. B., 1970. Planirovaniye i analiz eksperimenta. - M.: Legkaya industriya. - PDWHULDORY, 9 1LNROHQNR 8FKHQ\\H ]DSLVNL Krymskogo inzhenerno-pedagogicheskogo un-ta. – 9ROʋ7HNKQQDXNL– 9ROʋ7HNKQQDXNL Simferopol'.: NITS KIPU. – – :=5267()(.7<:12ĝ&,6<67(0Ï: 0RFKDOLQ <H 9 .KDODWRY $ $ 0. '267$5&=$1,$:2'<2':5271(-:352'8.&-, *LGURGLQDPLND ]DNUXFKHQQRJR SRWRND Y 0$7(5,$àÏ:%8'2:/$1<&+ URWDWVLRQQ\NK ILO WUDNK <H9 0RFKDOLQ $$ .KDODWRY ,QVWLWXW WHNKQLFKHVNR\ WHSORIL]LNL 1$1 Streszczenie. :DUW\NXOHUR]ZDĪDQHVą]DJDGQLHQLDPRGHORZDUkrainy. – K. - QLD¿OWURZDQLDK\GURG\QDPLF]QHJRZV\VWHPDFKGRVWDUF]DQLD )LQNHO VKWH\Q = / Primeneniye i ochistka ZRG\RGZURWQHMZSURGXNFMLPDWHULDáyZEXGRZODQ\FK3U]HGrabochikh zhidkostey dlya gornykh mashin./ = / VWDZLRQRVFKHPDWLQVWDODFMLGRĞZLDGF]DOQHMGRUHDOL]DFMLEDGDĔ Finkel'shteyn. - M.: Nedra. – SLORWDĪRZ\FK¿OWUDK\GURG\QDPLF]QHJRRUD]RPyZLRQRWHFKQLNL )LQNHO VKWH\Q = / Raschet W\FKEDGDĔ2SUDFRZDQRSODQWUyMF]\QQLNRZHJRHNVSHU\PHQWX JLGURGLQDPLFKHVNLNK ILO WURY = / )LQNHO VKWH\Q *')ĞFLHNyZ3&0SURZDG]RQHVąEDGDQLDLRWU]\PDQRUyZPnevmatika i gidravlika. Privody i sistemy QDQLHUHJUHVMLFKDUDNWHU\]XMąFHSURFHVXVXZDQLD]DZLHV]RQ\FK upravleniya. – Vyp. 7. – M. – – PDWHULDáyZ8VWDORQR]DOHĪQRĞFLREOLF]DQLDUHV]WNRZHM]DZDU%RMNR 1 )LQNHOVWHMQ = <DPNRYD\D 0 WRĞFL]DZLHV]RQ\FKPDWHULDáyZZHGáXJSRF]ąWNRZHJRVWĊĪHQLD Filter for cleaning with running magnetic field// ]DQLHF]\V]F]HĔVWRVXQHNXĪ\WHF]QRĞFLLNRV]WXV]ODPXQD¿OWU]H MOTROL. - ʋ$ ʋ$– RUD]]XĪ\FLHSU]HWZDU]DQHJRSá\QX%H]VSRUQHMHVWĪHZSUR=)LQNHOVWHLQ=9DVLOHFKNR0$VDGL New GXNFMLPDWHULDáyZEXGRZODQ\FKPRQWDĪV\VWHPyZ]DRSDWU]HQLD posibilities for improving reliability of hydraulic ZZRGĊRGZURWQą]]DVWRVRZDQLHP¿OWURZDQLDK\GURG\QDPLF]HTXLSPHQW ZLWK WKH KHOS RI K\GURG\QDPLF FOHDQLQJ QHJRSR]ZDODVNXWHF]QLHZ\NRU]\VW\ZDüMHJR]DOHW\L]DSHZQLü MOTROL. - ʋ-– bardziej racjonalne korzystanie z energii i zasobów naturalnych. Sautin S. N., 1975. Planirovaniye eksperimenta v 6áRZDNOXF]RZH3URGXNFMDPDWHULDáyZEXGRZODQ\FKĞFLHNL khimii i khimicheskoy tekhnologii. - L.: Khimiya. - SU]HP\VáRZHGRVWDUF]DQLHZRG\RGZURWQHM¿OWURZDQLHK\GUR G\QDPLF]HVWĊĪHQLHNRV]WUHV]WNRZHVWĊĪHQLH]DQLHF]\V]F]HĔ $GOHU<810DUNRYD<H9*UDQRYVNL\<89 VNXWHF]QRĞüRF]\V]F]DQLD 1973. Planirovaniye eksperimenta pri poiske RSWLPDO Q\NK XVORYL\ <8 1 $GOHU L GU - M.: Nauka. – . Ruzinov L. P., 1972. Staticheskiye metody optimizatsii khimicheskikh protsessov. - M.: Khimiya. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 113–118 Research on Properties of Bitumen Modified with Polymers Used for Asphalt Concrete Pavement on Bridges Arthur Onischenko, Mykolay Kuzminets, Sergey Aksenov National Transport University, Ukraine, Kyiv, str. Suvorova 1, e-mail: [email protected], [email protected], [email protected] Received December 01.2014; accepted December 17.2014 Summary. There are given the investigation results of bitumen PRGL¿HGZLWKWKHSRO\PHU6%5ODWH[%XWRQDO16GHSHQGing on temperature, time and the modifying agent amount, taking LQWRDFFRXQWWKHPDQXIDFWXULQJFRPSDQ\%$6)UHFRPPHQGDtions. The carried out research has shown the possibility to proGXFHELWXPLQRXVSRO\PHURQWKHSRO\PHUODWH[%XWRQDO16EDVLV WKDWPHHWVWKH8NUDLQHWHFKQRORJLFDOQRUPDWLYHUHTXLUHPHQWV2Q the conducted investigations basis there have been established the rational parameters of bituminous polymer binding agent production process thus allowing for the determination of the UHTXLUHPHQWVIRUWKHSRO\PHUODWH[%XWRQDO16DSSOLFDWLRQ under domestic production conditions. Key words: SDYLQJELWXPHQSRO\PHUODWH[%XWRQDO16ELWXminous polymer preparation process, binding agent properties. of the binding agent physical-mechanical properties depending on the polymer amount. This research allowed to apply WKH%XWDQRO16SRO\PHUDWWKHIROORZLQJKLJKZD\VDQG EULGJHVFRQVWUXFWLRQ.\LY.\LY±2GHVVDNP± NP±NP±.KDUNRY±6LPIHURSRONP ±NP.\LY±&KRSNP±NPDQGWKH RWKHUREMHFWV)LJ INTRODUCTION ,QURDGEXLOGLQJLQGXVWU\ELWXPHQPRGL¿FDWLRQZLWK polymers is one of the most effective ways to extend service life of the road-building materials produced on the organic ELQGLQJDJHQWV>@ The most effective and recognized are the styreneEXWDGLHQHEDVHGSRO\PHUV>@$PRQJWKHSRO\PHUVRI WKLVW\SHWKHSRO\PHUODWH[HVRIWKH%XWRQDO16VHULHV %$6)SURGXFWLRQ86$DGYDQWDJHRXVO\GLIIHUGXHWRWKHLU SURSHUWLHV>@ Taking into consideration the fact that domestic paving ELWXPHQVGLIIHUIURPWKRVHXVHGLQWKH86$DQHFHVVLW\ HPHUJHGWRVWXG\LQÀXHQFHRIVXFKPRGLI\LQJDJHQWVRQWKH properties of the paving bitumens used in Ukraine. Cationic ODWH[%XWRQDO16EHFDPHRQHRIWKH¿UVWPRGLI\LQJODtexes used in Ukraine. On the basis of previous investigations SHUIRUPHGE\WKH'HU]KGRUUHVHDUFKLQVWLWXWHDQG.1$58 research teams the effect was determined of the polymer ODWH[%XWRQDO16RQWKHSDYLQJELWXPHQSURSHUWLHV> @7KHODERUDWRU\WHVWUHVXOWVFRQ¿UPHGWKHHQKDQFHPHQW Fig. 1. South bridge across the Dnieper in Kiev Recently one more type of polymer latex appeared in 8NUDLQH±%XWRQDO16GHVLJQHGWRHQKDQFHWKHSDYLQJ ELWXPHQVPRGLI\LQJHI¿FLHQF\+RZHYHULWLVREYLRXVWKDW WRDFKLHYHWKHPD[LPXPEHQH¿WRIWKHSRO\PHUXVHDQG WRVWXG\LWVLQÀXHQFHRQWKHELWXPHQSK\VLFDOPHFKDQLFDO properties the preparation process rational parameters should be determined taking into account operating conditions. In WKLVSDSHUWKHLQÀXHQFHLVLQYHVWLJDWHGRIWKHPRGL¿HGZLWK SRO\PHUODWH[%XWRQDO16ELWXPHQSUHSDUDWLRQSDUDPeters on the paving bitumen properties. The experimental investigation was conducted to determine the following: ± UDWLRQDOSRO\PHUFRQVXPSWLRQIRUELWXPHQPRGL¿FDWLRQ ± LQÀXHQFHRIWKHELWXPLQRXVSRO\PHU preparation temperature and time on its main characteristics; $57+8521,6&+(1.20<.2/$<.8=0,1(766(5*(<$.6(129 ± LQÀXHQFHRIWKHSUHSDUDWLRQWHPSHUDWXUHDQGWLPHRQWKH bituminous polymer homogeneity. To perform this work the sample preparation procedures were developed. The experiments were carrying out using VDPSOHVRIELWXPHQZLWKWKHSRO\PHUODWH[%XWRQDO16 SURYLGHGE\WKH%$6)UHSUHVHQWDWLYHV±³,QWHUQDWLRQDO chemical production, Ltd.”. The research was performed in WKH3URI*.6XQ\DODERUDWRU\³7UDQVSRUW&RQVWUXFWLRQ 0DWHULDOVDQG'HVLJQV´RIWKH5RDG%XLOGLQJ0DWHULDOVDQG Chemistry Department at the National Transport University. 352&('85(2)7+(%,780,128632/<0(5 35(3$5$7,21%()25(7(67,1* To determine the influence of the polymer latex %XWRQDO 16 RQ WKH ELWXPLQRXV SRO\PHU¶V SK\VLcal-mechanical properties, during these investigations WKH SHWUROHXP SDYLQJ ELWXPHQ ZDV XVHG DV RQH of the most common in Ukraine. The polymer latex was added to this bitumen to determine its amount and other process-dependent parameters which are relevant to production of the bituminous polymer according to domestic UHTXLUHPHQWV 2XWSXWSDYLQJELWXPHQKDGWKHIROORZLQJRXWSXW GDWD7DEOH %LWXPLQRXVSRO\PHUVDPSOHVZHUHSUHSDUHG containing DQGRIWKH%XWRQDO167HPSHUDWXUHGXULQJ SUHSDUDWLRQYDULHGIURPɨɋWRɨɋ7KHELWXPLQRXV SRO\PHUV¶SUHSDUDWLRQGXUDWLRQYDULHGIURPWRKRXUV Such extended range of the modifying parameters is used also to determine their limit values under the operating conditions. Ta b l e 1 . 7KHRXWSXWGDWDRISDYLQJELWXPHQ 816WUHTXLUHments to petroleum Parameter Parameters description Unit paving bitumen value Needle penetration WR 97 GHSWKDWɨɋ mm Softening temperature ɨ ɋ WR DFFRUGLQJWR5% Stretchability (shortcm PLQLPXP QHVVDWWHPSHUDWXUH RIɨɋ Properties change after heating: PLQLPXP residual penetration ° ɋ PD[LPXP softening temperature change 2 ° Fragility temperature ɋ PD[LPXP -22 ° Flash temperature ɋ PLQLPXP $GKHVLRQ 90 To modify bitumen binding agent, a blade mixer instalODWLRQZDVGHYHORSHG)LJZKLFKDOORZHGIRUSHUIRUPLQJ WKHSURFHVVZLWKWKHVSHFL¿HGWHFKQRORJLFDOPRGHV Fig. 2. /DERUDWRU\EODGHPL[HUVLGHYLHZ 1 ± tripod, 2±FRQWUROXQLW3±HOHFWULFPRWRU4±EODGHDJLWDWRU 5±RLOWKHUPRVWDW6±RLOWDQN7±HOHFWULFWHQVRU8±WKHUPRFRXSOH in the oil thermostat, 9±WKHUPRFRXSOHIRUPRGL¿HGELWXPHQ 10±PHWDOFRQWDLQHUDFFRUGLQJWR'67811 ±ELWXPHQ binder. /$%25$725<5(6($5&+5(68/76 The tests on the output bitumen as well as bitumen mod L¿HGZLWKSRO\PHUZHUHFDUULHGRXWDFFRUGLQJWRDSSOLFDEOH UHJXODWLRQV>@7KHRXWSXWDQGPRGL¿HGELWXPHQWHVW UHVXOWVDUHVKRZQLQ)LJ H qɋ qɋ %LWXPLQRXV SRO\PHU ɨɋ ɨ Fig. 3. %LWXPLQRXVSRO\PHUSHQHWUDWLRQGHSHQGHQFHDW ɋ upon the preparation time at various polymer amounts %LWX DW qɋ Fig. 4. %LWXPLQRXVSRO\PHUSHQHWUDWLRQGHSHQGHQFHDW ɨɋ %LWXPLQRXV upon the preparation timeSRO\PHU at various polymer amounts ɨ ɋ 5(6($5&+213523(57,(62)%,780(102',),(':,7+32/<0(56 On the basis of these results the conclusion can be made that to establish the bituminous polymer viscosity factor it LVVXI¿FLHQWWRPRGLI\WKHELQGLQJDJHQWGXULQJWKUHHKRXUV and after this time period it is possible to determine its grade. While analyzing the bituminous polymer viscosity change LQFDVHRIWKHSUHSDUDWLRQWHPSHUDWXUHFKDQJHIURP°ɋ to 200 °ɋLWLVVHHQWKDWDWLWVLQFUHDVHWKHYLVFRVLW\YDOXH LQFUHDVHVWRR)LJ $VLWPD\EHVHHQDWWKHSUHSDUDWLRQWHPSHUDWXUHRI °ɋZLWKRISRO\PHUWKHREVHUYHGYLVFRVLW\UHGXFWLRQ ɉHTXDOVZLWKRISRO\PHU±ZLWKRI SRO\PHU±$WWKHWHPSHUDWXUHRI°ɋZLWKRI SRO\PHUWKHREVHUYHGYLVFRVLW\UHGXFWLRQHTXDOVZLWK RISRO\PHU±ZLWKRISRO\PHU±DQG at the temperature of 200 °ɋ±UHVSHFWLYHO\DQG 2QWKHEDVLVRIVXFKUHVXOWVLWLVSRVVLEOHWRDVVXPH that while preparing the bituminous polymer at the temperDWXUHRI °ɋWKHPRGLI\LQJSURFHVVGLGQRWWDNHSODFH FRPSOHWHO\ZKLFKFRUUHVSRQGVWR%$6)UHFRPPHQGDWLRQV WKHUHFRPPHQGHGUDQJHLV°ɋ Fig. 5. %LWXPLQRXVSRO\PHUSHQHWUDWLRQGHSHQGHQFHDW °ɋ upon the preparation temperature at various polymer amounts Decrease of the penetration value of the bituminous SRO\PHUSUHSDUHGDWWHPSHUDWXUHVRI °ɋDQG °ɋ is virtually the same, however it can also be assumed that under such conditions simultaneously with the binding agent modifying process the intensive processes of its deterioration occurs. It is important also to note that at the preparation temperature increase and especially at polymer amount LQFUHDVHXSWRWKHELWXPLQRXVSRO\PHUPD\WUDQVIHU to a more viscose state. This feature of the produced bituminous polymer should be taken into consideration during preparation, placement and consolidation of polymer road concrete mix. The results of determination of the bituminous polymer softening temperature dependence upon the preparation temSHUDWXUHDQGWLPHVKRZHGLWVFKDQJHDEOHFKDUDFWHU)LJ similar to the penetration changeability. ,QFDVHRISRO\PHUFRQFHQWUDWLRQDOUHDG\DIWHUWKH ¿UVWKRXURIELWXPLQRXVSRO\PHUEHQGLQJDJHQWSUHSDUDWLRQ)LJWKHKHDWUHVLVWDQFHYDOXHLQFUHDVHGE\°ɋDQG remained virtually constant at its further maturing in the UHDFWRU)LJ ,QFDVHRISRO\PHUFRQFHQWUDWLRQWKHPDLQLQFUHDVH LQWKHKHDWUHVLVWDQFHYDOXHWRRNSODFHGXULQJWKH¿UVWKRXU of bituminous polymer bending agent preparation and corUHVSRQGHGWR°ɋ$IWHUKRXUVRIWKHELWXPLQRXVSRO\PHU EHQGLQJDJHQWSUHSDUDWLRQWKLVLQFUHDVHZDVHTXDOWR°ɋ Fig. 6. %LWXPLQRXVSRO\PHUVRIWHQLQJWHPSHUDWXUHGHSHQGHQFH upon the preparation time at various polymer amounts ,QFDVHRISRO\PHUFRQFHQWUDWLRQWKHVHSDUDPHWHUV ZHUHHTXDOWR °ɋDQG °ɋ,WLVQHFHVVDU\WRQRWHWKDW the bituminous polymer bending agent was prepared at the WHPSHUDWXUHRI°ɋDFFRUGLQJWR%$6)UHFRPPHQGDWLRQV In case of the bituminous polymer bending agent preparation at the temperature reduction from 200 °ɋWR°ɋ)LJ the softening temperature value respectively increased by °ɋDQGGHFUHDVHGE\°ɋ Fig. 7. %LWXPLQRXVSRO\PHUVRIWHQLQJWHPSHUDWXUHGHSHQGHQFH upon the preparation temperature at various polymer amounts ,WFRQ¿UPVWKHSUHYLRXVDVVXPSWLRQWKDWWKHELWXPLQRXV SRO\PHUEHQGLQJDJHQWSUHSDUDWLRQWHPSHUDWXUHRI °ɋ LVLQVXI¿FLHQWIRUTXLFNSRO\PHULQWHJUDWLRQWRJHWWKHKRmogeneous mixture, and the heat resistance slow increase at the preparation temperature of 200 °ɋHQVXUHVWKDWWKH deterioration processes do not develop. To examine the possible bituminous polymer bending agent deterioration at too high temperatures, the bituminous polymer bending agent elasticity change in a range of the temperatures and preparation time periods was measured. The following results were obtained: The elasticity occurrence even at the small amount of pol\PHUDQGPRGLI\LQJWLPHDWDIWHUKRXURISUHSDUDWLRQ )LJFRQ¿UPVWKHSRVVLELOLW\RIWKHELWXPLQRXVSRO\PHU bending agent elastic properties considerable enhancement. Fig. 8. %LWXPLQRXV SRO\PHU HODVWLFLW\ GHSHQGHQFH XSRQ WKH preparation temperature at various polymer amounts %LWXPLQRXV SRO\PHU %LWXPLQRXVSRO\PHU $W $57+8521,6&+(1.20<.2/$<.8=0,1(766(5*(<$.6(129 ,QFDVHRISRO\PHUFRQFHQWUDWLRQDIWHUWKH¿UVWKRXU RISUHSDUDWLRQWKHHODVWLFLW\IDFWRUZDVHTXDOWRDIWHU KRXUV±DQGLWUHPDLQHGFRQVWDQWDWWKHPD[LPXP WLPHRIWKHELWXPLQRXVSRO\PHUEHQGLQJDJHQW±KRXUV Similar increase of the elasticity factor was found at modiTXDOLW\ polyI\LQJRISRO\PHUUHVSHFWLYHO\E\DQGDQG after heatDWRISRO\PHU±DQG7KXVWKHSRO\PHU tegration during storage. Therefore, DPRXQWLQFUHDVHHYHQXSWRYLUWXDOO\GLGQRWLQÀXHQFH WKHLQFUHDVHRIWKHHODVWLFLW\IDFWRUZKLFKLVDOVRVXI¿FLHQWO\ were conducted and high at a smaller amount ofwhich the polymer. confirmed the very It is especially note that the value slight change important of such to properties at elasticity given modiat the high temperatures of the bituminous polymer bending DJHQWSUHSDUDWLRQUHPDLQHGYLUWXDOO\LQYDULDEOH)LJDV compared with the preparation at low temperatures. polyThese factor UHVXOWVFRQ¿UPWKHSUHYLRXVVWDWHPHQWVFRQFHUQLQJWKHQHZ binding agent deterioration resistance. polymer amounts and time of its modifying is very VOLJKW $IWHU WKH ILUVW KRXU RI PRGLI\LQJ DW SUHSDUDWLRQ WHPSHUDWXUH RI qɋ qɋ PRGLILHG EHQGLQJ DJHQW ZKLOH DIWHU KRXUV q ɋ TXLU Fig. 9. %LWXPLQRXV SRO\PHU HODVWLFLW\ GHSHQGHQFH XSRQ WKH $W ORZHULQJ WKH ELWXPLQRXV SRO\PHU EHQGLQJ DJHQW q SUHSDUDWLRQWHPSHUDWXUHWR°ɋWKLVSDUDPHWHUUHPDLQHG ɋ ° the same, and at the temperature up to 200 ɋLWV ° qɋ increase PD[LPXPYDOXHZDV ɋ)LJZKLFKDOVRPHWWKH WKHUHTXLUHPHQWV UHTXLUHPHQWV>@ Fig. 11. %LWXPLQRXVSRO\PHUVRIWHQLQJWHPSHUDWXUHFKDQJHGHpendence upon the preparation temperature at various polymer %LWXPLQRXV SRO\PHU amounts Dependence of the bituminous polymer bending agent disintegration factor during storage (according to penetraWLRQIDFWRURQWKHSRO\PHUDPRXQWWKHSUHSDUDWLRQWLPH and temperature showed its slight change during modifying ERWKDWORZWHPSHUDWXUHVDQGDWKLJKRQHVGHJUHHVRI SHQHWUDWLRQ)LJ preparation time at various polymer amounts The bituminous polymer bending agent important parameters which characterize its processability, usability in production conditions, and also determine the produced ELQGLQJDJHQWTXDOLW\DUHWKHELWXPLQRXVSRO\PHUEHQGLQJ agent properties changes after heating and disintegration during storage. Therefore, in this work, investigations were FRQGXFWHGDQGWKHUHVXOWVREWDLQHGZKLFKFRQ¿UPHGWKH very slight change of such properties at given modifying temperatures. It may be seen that the bituminous polymer bending agent heat resistance factor change after heating at various polymer amounts and time of its modifying is very slight. $IWHUWKH¿UVWKRXURIPRGLI\LQJDWSUHSDUDWLRQWHPSHUDWXUH RI°ɋWKLVSDUDPHWHUZDVKLJKHUE\°ɋDVFRPSDUHG to the output bituminous polymer bending agent, which is H[SODLQHGE\WKHQRQPRGL¿HGEHQGLQJDJHQWZKLOHDIWHU KRXUVRIPRGLI\LQJWKLVSDUDPHWHUGLGQRWH[FHHG °ɋ )LJLHLWPHWWKHDSSOLFDEOHUHTXLUHPHQWV Fig. 10. %LWXPLQRXVSRO\PHUVRIWHQLQJWHPSHUDWXUHFKDQJHGHpendence upon the preparation time at various polymer amounts qɋ ZDVHTXDOWR Fig. 12. %LWXPLQRXVSRO\PHUGLVLQWHJUDWLRQGXULQJVWRUDJHDFFRUGLQJWRSHQHWUDWLRQIDFWRUGHSHQGHQFHXSRQWKHSUHSDUDWLRQ Fig. 12. %LWXPLQRXV SRO\PHU time various polymer amounts LQJatVWRUDJH DFFRUGLQJ WR SHQHWUDWLRQ IDFWRU G $OWKRXJKWKLVSDUDPHWHULVQRWUDWHGWKHREWDLQHGUHVXOWV VKRZWKHVXI¿FLHQWKRPRJHQHLW\RISURGXFHGELQGLQJDJHQW after $OWKRXJK modifying. Dependence of the bituminous polymer bending agent disintegration factor during storage (accordLQJWRVRIWHQLQJWHPSHUDWXUHXSRQWKHSRO\PHUDPRXQWDQG its preparation time showed slight change of this parameter WKDWDGGLWLRQDOO\FRQ¿UPHGWKHREWDLQHGELWXPLQRXVSRO\PHU bending agent homogeneity as well as the ability to be proFHVVHG+RZHYHULWLVQHFHVVDU\WRQRWHWKDWDWWKHSRO\PHU amount increase, the disintegration factor value increases too, although remaining within the allowable limits. $WWKHSRO\PHUFRQFHQWUDWLRQRIWKH.L.IDFWRU difference depending on the preparation time varied from WR °ɋZKLOHDWWKHSRO\PHUFRQFHQWUDWLRQRIWKLV GLIIHUHQFHZDVHTXDOWR°ɋ)LJ Such results are observed in the entire range of the bi+RZHYHULWLV QHFHVVDU\WR QRWHWKDW tuminous polymer bending agent preparation temperature change. %LW %LW 5(6($5&+213523(57,(62)%,780(102',),(':,7+32/<0(56 Fig. 13. %LWXPLQRXVSRO\PHUGLVLQWHJUDWLRQGXULQJVWRUDJHDFFRUGLQJWRSHQHWUDWLRQIDFWRUGHSHQGHQFHXSRQWKHSUHSDUDWLRQ temperature at various polymer amounts Fig. 14. %LWXPLQRXVSRO\PHUGLVLQWHJUDWLRQGXULQJVWRUDJHDFFRUGLQJWRVRIWHQLQJWHPSHUDWXUHGHSHQGHQFHXSRQWKHSUHSDration time at various polymer amounts Fig. 15. %LWXPLQRXVSRO\PHUGLVLQWHJUDWLRQGXULQJVWRUDJHDFFRUGLQJWRVRIWHQLQJWHPSHUDWXUHGHSHQGHQFHXSRQWKHSUHSDration temperature at various polymer amounts CONCLUSIONS 7KHELWXPLQRXVSRO\PHUEHQGLQJDJHQWRQWKHEDVLVRI WKH%XWDQRO16SRO\PHUODWH[LQFRPSOLDQFHZLWKDOO VWDQGDUGSDUDPHWHUVPHHWVWKHUHTXLUHPHQWVWRELWXPHQ PRGL¿HGZLWKSRO\PHUV 2. The bituminous polymer bending agent physical-mechanLFDOSURSHUWLHVFKDQJHLQWKHZLGHOLPLWVE\ depending on the polymer amount and the preparation process parameters shows the possibility of its properties active regulation under the particular operating conditions. 7KHELWXPLQRXVSRO\PHUEHQGLQJDJHQWSURSHUWLHVUHVLVWance and stability under the high process temperatures LQÀXHQFHVKRZVWKHSRVVLELOLW\RILWVVXI¿FLHQWO\ORQJ term storage under the production conditions with the original properties retained. 6KRUWWLPHRIWKLVELWXPLQRXVSRO\PHUEHQGLQJDJHQW SUHSDUDWLRQRQDYHUDJHKRXUVDOORZVIRUWKHVDYLQJ of the considerable energy resources and advantageously distinguishes it from the bituminous polymer bending DJHQWVSURGXFHGZLWKWKHRWKHUPRGL¿HUV 7KH%XWDQRO16SRO\PHUODWH[UDWLRQDODPRXQWIRU PRGLI\LQJWKHELWXPHQRIWKLVJUDGHFRQVWLWXWHV WKHSUHSDUDWLRQWLPHLVZLWKLQWKHOLPLWVRIKRXUV DQGWKHRSWLPDOSUHSDUDWLRQWHPSHUDWXUHLVFORVHWR °ɋ 5()(5(1&(6 628±³%LWXPHQPRGL¿HG using laboratory blade mixer. Methods for process conWUROPRGL¿FDWLRQV 2. =RORWDUHY9$., 2009.3RO\PHUPRGL¿HGELWXPHQDQG DVIDOWSROLPHUFHPHQWV'RUR]KQDLDWHKQLND =RORWDUHY9$., 2003. 3URSHUWLHVRIELWXPHQ6%6SRO\PHUPRGL¿HGW\SH$YWRVKO\DKRYLNRI8NUDLQH±,VVXH .\LY King G.N., Radovskii B.S., 2004. Properties of polymer bitumen binders in the U.S. and methods of testing // 6FLHQWL¿FDQG7HFKQLFDO,QIRUPDWLRQ.LW1RYRVWLYGRUR]KQRPGHOH±,VVXH0RVFRZ King G.N., Radovskii B.S., 2004. Materials and technology company Koch Materials for the construction DQGUHSDLURIURDGVXUIDFHV6FLHQWL¿FDQG7HFKQLFDO ,QIRUPDWLRQ .LW 1RYRVWL Y GRUR]KQRP GHOH ± ,VVXH 0RVFRZ Hochman L. M., 2004. Complex organic binders based RQEORFNFRSRO\PHUV6%6W\SH±0RVFRZ³(NRQLQIRUP´-6&± 7. Kirichek <$'HP¶\DQHQNR996XKRUHEU\\2$ 2008.([SHULPHQWDOVWXG\RIWKHSURSHUWLHVRIPRGL¿HG ELWXPHQXVHGLQURDGFRQVWUXFWLRQ%XOOHWLQRI3U\GQLSURYVND6WDWH$FDGHP\RI&RQVWUXFWLRQDQG$UFKLWHFWXUH±'QHSURSHWURYVN36$%$ʋ 8. 2QLVKFKHQNR $0 Improving durability of asphalt layers by the use of polymer latexes. 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COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 119–124 Characteristics of Selected Rheological Properties of Water Suspensions of Maize TPS Biocomposites Tomasz Oniszczuk, Agnieszka Wójtowicz, Leszek Mościcki, Andrzej Rejak, Maciej Combrzyński Department of Food Process Engineering, Lublin University of Life Sciences Doświadczalna 44, 20-236 Lublin, Poland e-mail: [email protected] Received December 07.2014; accepted December 18.2014 Summary. 7KHUHVHDUFKFRYHUHGWKHDTXHRXVVROXWLRQVRI PDL]HWKHUPRSODVWLFVWDUFK7367KHWKHUPRSODVWLFVWDUFK granules were produced from mixtures of maize starch, glycHURODQGDQDGGLWLYHRI¿OOHUVLQWKHIRUPRIQDWXUDO¿EUHV,Q WKHVWXG\DPRGL¿HGVLQJOHVFUHZH[WUXVLRQFRRNHU76 ZDVXVHGZLWK/' DQG/' ZLWKDQH[WUDFRROLQJRI the end part of the barrel. The research focused on the effect of the extruder screw speed, the plasticizing system and the W\SHRI¿OOHUXVHGIRUDSSDUHQWYLVFRVLW\RISXOYHUL]HGJUDQXOHV of maize starch. During the measurements, the top values of apparent viscosity were reported for the maize TPS containing DQDGGLWLRQRIFHOOXORVH¿EUHH[WUXGHGZLWKWKHSODVWLFL]LQJ V\VWHP/' Key words: viscosity, thermoplastic starch, extrusion, biocomposites. consumers until tests prove the non-carcinogenic effect of %3$RQKXPDQV>@7KHUHDUHPDQ\PRUHH[DPSOHVRI similar concerns. Therefore, the general public puts more and more attention to the growing problem of plastics and their recycling. In order to protect the environment, and above all, protect human health, developed countries undertake research into the manufacture of environmentally friendly polymers. The primary focus is on natural materials, includLQJWKRVHPDGHRIGLIIHUHQWW\SHVRIVWDUFK%LRSRO\PHUV are obtained after mixing starch with a plasticizer (often JO\FHUROVRDVWRDOORZWKHOLTXHIDFWLRQRIWKHPDWHULDODW a temperature lower than the decomposition temperature of the starch. Such starch is referred to as thermoplastic VWDUFK736DQGLVUHJDUGHGDVDELRGHJUDGDEOHELRSRO\PHU>@%LRGHJUDGDEOHSRO\PHUVOLNHSHWUROHXP INTRODUCTION SRO\PHUVPXVWPHHWFHUWDLQUHTXLUHPHQWVLQWHUPVRI SK\VLFDOSURSHUWLHV%LRSRO\PHUSURGXFWLRQLVGRQHRQ The recent decades have seen a growing application WKHPDFKLQHVDQGHTXLSPHQWXVHGIRUWKHSURGXFWLRQRI of plastics in all the areas of human activity. Today, it is synthetic polymers. These materials can be an option in GLI¿FXOWWRLPDJLQHOLIHZLWKRXWSODVWLFVLQSDFNDJLQJWR\V WKHSODVWLFVPDUNHWRIIHULQJ>@ The aim of the study was to determine the viscosity of FDUVPHGLFDOSURGXFWVHWF+RZHYHUEHVLGHVWKHXQTXHVWLRQDEOHEHQH¿WVWKHUHDUHDOVRVRPHQHJDWLYHFRQVHTXHQFHV thermoplastic maize starch water solutions with an addition RIWKHLUXELTXLW\7KHPHWKRGRISURFHVVLQJDQGGLVSRVDO RIQDWXUDO¿EUHRIGLIIHUHQWRULJLQGHSHQGLQJRQWKHSURof different types of plastic after their life cycle has a tre- duction parameters. mendous impact on the natural environment, including KXPDQKHDOWK>@,WKDVEHHQDVVHUWHGWKDWVRPH 0$7(5,$/6$1'0(7+2'6 chemical compounds used in plastics processing for the SURGXFWLRQRIIRRGSDFNDJLQJELRVSKHQRO$±%3$FDQ affect the human endocrine system and are ranked among The basic raw material used in the study was maize cancer-causing substances. The U.S. companies represent- VWDUFKRIWKHW\SH0(5,=(7SURGXFHGE\6HJH]KD LQJWKHSODVWLFVLQGXVWU\GHFLGHGWRZLWKGUDZ%3$IURP ,UHODQG$OVRÀD[¿EUHZDVXVHGIURPD3ROLVKSURGXFthe process of manufacturing packaging for food storage, HUFHOOXORVH¿EUH9LYDSXUW\SH-56IURPD*HUPDQ and the U.S. government declared amendments to the rel- producer and ground pine bark. The basic characteristics evant law on food safety that are expected to eliminate any RIWKHJURXQGEDUNFHOOXORVH¿EUHDQGÀD[¿EUHDUHJLYHQ SURGXFWVFRQWDLQLQJ%3$WKDWDUHOLNHO\WREHGHWULPHQWDOWR LQ7DEOH 721,6=&=8.$:Ï-72:,&=/02ĝ&,&.,$5(-$.0&20%5=<ē6., Ta b l e 1 . %DVLFFKDUDFWHULVWLFVRIFHOOXORVH¿EUHÀD[¿EUH and bark. *URXQGSLQH bark Feature Determination results .± Particle size [m] .±. .±. . %XONGHQVLW\ ± ± [kg/m] +XPLGLW\>@ ± ± ± &HOOXORVH¿EUH )OD[¿EUH From among a considerable group of auxiliary substancHVXVHGDVSODVWLFL]HUVDQGDGGLWLYHVLPSURYLQJWKHTXDOLW\ Photo 1. 6LQJOHVFUHZH[WUXGHU76PDGHE\=0&K0HWDOof obtained material, the study used technical glycerol of FKHPLQ*OLZLFH3RODQG SXULW\LQWKHDPRXQWRIRIGU\PDVVRIVWDUFK>@ mm and a height of 20 mm with a conical bottom surface. 7KHIROORZLQJVHWWLQJVZHUHXVHGLQWKHVWXG\N1KHDG 35(3$5$7,212)7360,;785(6 IRUFHPPPHDVXULQJJDSWKHWRWDOWHVWOHQJWKPP KHDGVSHHGPPPLQ-1. During the study, the resistance 6WDUFKZLWKRIPRLVWXUHFRQWHQWFHOOXORVH¿EUHV force of the suspension was recorded during the movement ÀD[¿EUHVJURXQGEDUNDQGJO\FHUROZHUHXVHGWRSUHSDUH of the plunger in one bottom-up measurement cycle, which PDWHULDOPL[WXUHV7KHJO\FHURODFFRXQWHG736IRURI ZDVQH[WFRQYHUWHGLQWRWKHDSSDUHQWYLVFRVLW\FRHI¿FLHQW WKHPL[WXUHZHLJKWDQGWKHSURSRUWLRQRI¿EUHVZDV 7KHPHDVXUHPHQWVZHUHPDGHXVLQJWKHWHVW;SHUWY DQG6DPSOHVZHUHPL[HGXVLQJDODERUDWRU\PL[HU SURJUDP7KHUHZHUH¿YHUHSOLFDWLRQVWKH¿QDOUHVXOWEHLQJ ribbon. Through repeated trials, the effective mixing time WKHDULWKPHWLFPHDQRIWKHPHDVXUHPHQWV>@ ZDVHVWDEOLVKHGDWPLQXWHV$IWHUPL[LQJWKHVDPSOHV ZHUHOHIWLQVHDOHGSODVWLFEDJVIRUKRXUVWRKRPRJHQL]H 5(68/76 Immediately before extrusion, the samples were mixed again IRUPLQXWHVWRREWDLQDORRVHDQGSRZGHUHGVWUXFWXUHRI the mixture. The use of the back extrusion chamber allowed the exDPLQDWLRQRIWKHDSSDUHQWYLVFRVLW\RI¿QHWKHUPRSODVWLF VWDUFKJUDQXOHVDQGRIWKHGHJUHHRIERQGLQJRIWKH¿OOHUV (;7586,21 FHOOXORVH¿EUHÀD[¿EUHDQGJURXQGEDUN7KHVHSDUDPHWHUV are crucial in determining the processing properties of therTPS biocomposite granules were made by a single-screw PRSODVWLFVWDUFK7KHDGGLWLRQRIQDWXUDO¿OOHUVLQWKHIRUP H[WUXVLRQFRRNHUHTXLSSHGZLWKWZRNLQGVRISODVWLFL]HU of granules is intended to stabilize the shape and improve V\VWHPVZLWKWKHVFUHZOHQJWKGLDPHWHUUDWLRRI/' the performance of rigid forms of packaging. DQG/' 3KRWR$VWHHOGLHZDVXVHGZLWKDKROHRI PPLQGLDPHWHU*UDQXOHVZHUHSURGXFHGDWWKHH[WUXGHU VFUHZVSHHGRIDQGUSP7KHH[WUXVLRQSDUDPHWHUVZHUHVHWLQWKHWHPSHUDWXUHUDQJH&DQGPDLQWDLQHGE\DSSURSULDWHO\DGMXVWLQJWKHÀRZLQWHQVLW\RIWKH FRROLQJOLTXLG7KHH[WUXGHUZDVHTXLSSHGZLWKDPDWHULDO feeder, a plasticizing system made up of the screw linked to the drive and housing, a preheating device and a cooling V\VWHP>@ 0($685(0(172)$33$5(179,6&26,7< $=ZLFNWHVWLQJPDFKLQHZDVXVHGLQWKHVWXG\HTXLSSHG with a back extrusion chamber. The obtained extrudate was ground in a laboratory mill to the grain size below 0.8 mm. )URPWKHJURXQGH[WUXGDWHDQGGLVWLOOHGZDWHUDW& suspensions were prepared by continuous mixing. The viscosity measurement of the suspensions was carried out after PLQXWHVRIPL[LQJ7KHPHDVXUHPHQWVZHUHPDGHLQ WKHEDFNH[WUXVLRQFKDPEHUPPLQKHLJKWDQGPP RILQQHUGLDPHWHUXVLQJDSOXQJHUZLWKDGLDPHWHURI Fig. 1. 7KHLQÀXHQFHRIFHOOXORVH¿EUHVDQGWKHH[WUXGHUVFUHZ speed on the apparent viscosity of maize starch solutions (exWUXGHUSODVWLFL]LQJV\VWHPRI/' )LJVKRZVWKHGHSHQGHQFHRIWKHYLVFRVLW\RIDTXHRXV solutions of thermoplastic maize starch upon the applied &+$5$&7(5,67,&62)6(/(&7('5+(2/2*,&$/3523(57,(62):$7(56863(16,216 VFUHZVSHHGRIWKH/' YHUVLRQH[WUXGHUDQGXSRQWKH FRQWHQWRIFHOOXORVH¿EUHLQWKHPL[WXUH,WZDVREVHUYHG that the viscosity of the solution increased along with the increasing extruder screw speed and a higher addition of FHOOXORVH¿EUH7KLVGHSHQGHQF\LVFRUURERUDWHGWKURXJK WKHSRVLWLYHYDOXHVRIWKHVORSHFRHI¿FLHQWVRISRO\QRPLDO WUHQGOLQHVIRUDOOWKHDSSOLHGVFUHZVSHHGV7DEOH$OVR WKHPRVWVLJQL¿FDQWGLIIHUHQFHVZHUHLQGLFDWHGEHWZHHQWKH PHDQVS The highest viscosity values were obtained for granuODWHGPDWHULDOSURGXFHGDWWKHH[WUXGHUVFUHZVSHHGRI rpm-17KLVWHVWL¿HVWRDJRRGERQGEHWZHHQWKH¿EUHVDQG biopolymer matrix. Fig. 2. 7KHLQÀXHQFHRIFHOOXORVH¿EUHVDQGWKHH[WUXGHUVFUHZ speed on the apparent viscosity of maize starch solutions (exWUXGHUSODVWLFL]LQJV\VWHPRI/' The solution of the granulated material obtained using WKHSODVWLFL]LQJV\VWHPRIWKHH[WUXGHUZLWK/' GHPRQstrated lower apparent viscosity values compared with the UHVXOWVREWDLQHGIRUWKHVKRUWHUYHUVLRQ$VLPLODUWUHQGZDV observed: viscosity increased along with the increasing exWUXGHUVFUHZVSHHGDQGDKLJKHUDGGLWLRQRIWKH¿OOHU$OVR LQWKLVFDVHVLJQL¿FDQWGLIIHUHQFHVZHUHUHSRUWHGEHWZHHQ WKHPHDQV7DEOH $QDGGLWLYHRIÀD[¿EUHFDXVHGDVOLJKWLQFUHDVHLQWKH YLVFRVLW\RIVROXWLRQV)LJ7KHKLJKHVWYLVFRVLW\YDOues were obtained for granulated maize starch produced DWWKHH[WUXGHUVFUHZVSHHGRIUSP-1$ORQJZLWKWKH ULVLQJFRQWHQWRIÀD[¿EUHLQDOOWKHWHVWHGPDWHULDOVYLVFRVLW\LQFUHDVHGRQO\VOLJKWO\7KHDGGLWLRQRIRIÀD[ ¿EUHVFDXVHGDGHFUHDVHLQWKHYLVFRVLW\RIVROXWLRQVZKLFK GHPRQVWUDWHVDZHDNERQGEHWZHHQWKHÀD[¿EUHVDQGWKH biopolymer matrix. Fig. 3. 7KHLQÀXHQFHRIÀH[¿EUHVDQGWKHH[WUXGHUVFUHZVSHHG on the apparent viscosity of maize starch solutions (extruder SODVWLFL]LQJV\VWHPRI/' During the examination of the solution of extrudates produced on the longer version of the plasticizing system, Ta b l e 2 . 7KHUHVXOWVRIWKHVWDWLVWLFDODQDO\VLVRIYLVFRVLW\RIDTXHRXVVROXWLRQVRIWKHUPRSODVWLFVWDUFKGHSHQGLQJRQWKHDGGLtives used. L/D Screw rotation version [rpm-1] 80 &HOOXORVH¿EUH 80 80 )OD[¿EUH 80 80 *URXQGSLQH bark 80 $GGLWLYH 3RO\QRPLDOUHJUHVVLRQHTXDWLRQ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ F test values 9.807 2.029 72.707 P value 0.0000008 0.0000009 0.0000 0.00002 0.0000 0.0000 0.00000002 0.0000 721,6=&=8.$:Ï-72:,&=/02ĝ&,&.,$5(-$.0&20%5=<ē6., some problems emerged with maintaining the homogeneity of solutions which began to delaminate. Friction rose in the SODFHVRI¿EUHVHWWOHPHQWKHQFHWKHFRQVLGHUDEOHGLIIHUHQFHV LQWKHWKHYLVFRVLW\RIVROXWLRQVZKLFKLVYLVLEOHLQ)LJ showing the results of measurements of the viscosity of solutions of biopolymers obtained by using the extruder SODVWLFL]LQJV\VWHPRI/' 7KHUHZHUHQRVLJQL¿FDQW differences reported between the means for these granules S!7DEOH was caused by resistance occurring during the study. TPS granule solutions containing ground bark obtained by using WKHSODVWLFL]LQJV\VWHPRIWKHH[WUXGHUZLWK/' VKRZHG KLJKHUDSSDUHQWYLVFRVLW\YDOXHV)LJ7KHWRSYDOXHV ZHUHUHFRUGHGIRUWKHDGGLWLRQRIRIJURXQGEDUNWR the thermoplastic starch extruded at the screw speed of 80 rpm-1P3DV The lowest viscosity values were demonstrated by the PL[WXUHVRIPDL]HVWDUFKDQGJO\FHUROFRQWDLQLQJD addition of ground bark in the whole range of extruder screw speeds. Fig. 4. 7KHLQÀXHQFHRIÀH[¿EUHVDQGWKHH[WUXGHUVFUHZVSHHG on the apparent viscosity of maize starch solutions (extruder SODVWLFL]LQJV\VWHPRI/' Fig. 6. 7KHLQÀXHQFHRIJURXQGEDUNDQGWKHH[WUXGHUVFUHZVSHHG on the apparent viscosity of maize starch solutions (extruder $QRWKHU W\SH RI WKHUPRSODVWLF VWDUFK ELRFRPSRVLWHV SODVWLFL]LQJV\VWHPRI/' subjected to analysis were maize starch granules with the DGGLWLRQRIJURXQGEDUN)LJDQGVKRZWKHPHDVXUHPHQW results of the apparent viscosity depending on the version CONCLUSIONS of the plasticizing system used. The viscosity values of the thermoplastic starch solutions with the addition of ground ± ,WZDVREVHUYHGWKDWWKHDSSDUHQWYLVFRVLW\RIWKHVROXbark were lower than the viscosity of TPS solutions with tions of thermoplastic maize starch was determined by WKHFHOOXORVH¿EUHFRQWHQW'XULQJWKHVWXG\DVLQWKHFDVH the rotational speed of the extruder used for the producRIÀD[¿EUHVROXWLRQVWKHVXVSHQVLRQVZHUHGHODPLQDWHG tion of the granulated matter. ± 7KHKLJKHVWDSSDUHQWYLVFRVLW\YDOXHVZHUHUHSRUWHGIRU solutions of maize TPS with the addition of cellulose ¿EUH ± 7KHDTXHRXVVROXWLRQVRIJUDQXOHVREWDLQHGZLWKWKH H[WUXGHUSODVWLFL]LQJV\VWHPDW/' VKRZHGKLJKHU apparent viscosity values. ± 7KHDGGLWLRQRI¿OOHUVVXFKDVQDWXUDO¿EUHVLQFUHDVHG YLVFRVLW\LQWKHPDMRULW\RIH[DPLQHGDTXHRXVVROXWLRQV of extruded maize starch. 5()(5(1&(6 Averous L., Moro L., Dole P., Fringant C., 2000: PropHUWLHVRIWKHUPRSODVWLFEOHQGVVWDUFK±SRO\FDSURODFWRQH Fig. 5. 7KHLQÀXHQFHRIJURXQGEDUNDQGWKHH[WUXGHUVFUHZVSHHG 3RO\PHU on the apparent viscosity of maize starch solutions (extruder 2. Bledzki A.K., Gassan J., 1999: Composites reinforced SODVWLFL]LQJV\VWHPRI/' ZLWKFHOOXORVHEDVHG¿EUHV3URJ3RO\PHU6FLHQFH 7KHDGGLWLRQRIRIJURXQGEDUNWRPDL]HVWDUFK Dyadychev V., Pugacheva H., Kildeychik A., 2010: JUDQXOHVH[WUXGHUSODVWLFL]LQJV\VWHPRI/' FRQWULECo-injection molding as one of the most popular injecuted to the dispersion of the apparent viscosity values, which tion molding Technologies for manufacture of polymeric &+$5$&7(5,67,&62)6(/(&7('5+(2/2*,&$/3523(57,(62):$7(56863(16,216 GHWDLOVIURPVHFRQGDU\UDZPDWHULDOV7(.$&RPPLVLRQ RIPRWRUL]DWLRQDQG3RZHU,QGXVWU\LQ$JULFXOWXUH3$1 9ROXPH;F Gujral H.S., Sodhi N.S., 2002:%DFNH[WUXVLRQSURSerties of wheat porridge (Dalia). -RXUQDORI)RRG(QJLQHHULQJ -DQVVHQ/3%00RVFLFNL/(GVThermoSODVWLF6WDUFK:LOH\9&+9HUODJ*PE+&R.*D$ :HLQKHLP /HH6</XQD*X]PDQ,&KDQJ6%DUUHWW'0 Guinard J-X., 1999:Relating descriptive analysis and instrumental texture data of processed diced tomatoes. )RRG4XDOLW\DQG3UHIHUHQFH 7. Mitrus M., 2006: Investigations of thermoplastic starch H[WUXVLRQFRRNLQJSURFHVVVWDELOLW\7(.$&RPPLVVLRQ RIPRWRUL]DWLRQDQG3RZHU,QGXVWU\LQ$JULFXOWXUH3$1 9ROXPH9,D 8. 0LWUXV 0 2QLV]F]XN 7 :Sá\Z REUyENL FLĞQLHQLRZR±WHUPLF]QHMQDZáDĞFLZRĞFLPHFKDQLF]QH VNURELWHUPRSODVW\F]QHM:áDĞFLZRĞFLJHRPHWU\F]QH mechaniczne i strukturalne surowców i produktów VSRĪ\ZF]\FK:\G1DXN)51$/XEOLQ 9. 0RĞFLFNL/(G([WUXVLRQ&RRNLQJ7HFKQLTXHV :LOH\9&+9HUODJ*PE+&R.*D$:HLQKHLP 0RĞFLFNL/0LWUXV0:yMWRZLF]$Technika HNVWUX]MLZSU]HP\ĞOHUROQR±VSRĪ\ZF]\P3:5L/ Warszawa. 0RĞFLFNL / 0LWUXV 0:yMWRZLF]$ 2QLV]F]XN T., Rejak A., Janssen L., 2012:$SSOLFDWLRQRIH[WUXsion-cooking for processing of thermoplastic starch 736)RRG5HVHDUFK,QWHUQDWLRQDO9ROSS 2QLV]F]XN73LODZND5:Sá\ZGRGDWNXZáyNLHQFHOXOR]RZ\FKQDZ\WU]\PDáRĞüWHUPLF]QąVNUREL WHUPRSODVW\F]QHM3U]HP\Vá&KHPLF]Q\ 2QLV]F]XN73LODZND52QLV]F]XN$:Sá\Z GRGDWNXPLHORQHMNRU\VRVQRZHMQDZ\WU]\PDáRĞüWHUPLF]QąVNURELWHUPRSODVW\F]QHM3U]HP\Vá&KHPLF]Q\ 2QLV]F]XN7:yMWRZLF]$0LWUXV00RĞFLFNL/ &RPEU]\ĔVNL05HMDN$*áDG\V]HZVND% ,QÀXHQFHRISURFHVFRQGLWLRQVDQG¿OOHUVDGGLWLRQRQ H[WUXVLRQFRRNLQJHI¿FLHQF\DQG60(RIWKHUPRSODVtic potato starch, Teka Commision of Motorization and (QHUJHWLFVLQ$JULFXOWXUH3ROLVK$FDGHP\RI6FLHQFHV %UDQFKLQ/XEOLQYRO1RSS 2QLV]F]XN7:yMWRZLF]$0LWUXV00RĞFLFNL/ &RPEU]\ĔVNL05HMDN$*áDG\V]HZVND% %LRGHJUDGDWLRQRI736PRXOGLQJVHQULFKHGZLWKQDWXUDO ¿OOHUV7HND&RPPLVLRQRI0RWRUL]DWLRQDQG(QHUJHWLFV LQ$JULFXOWXUH3ROLVK$FDGHP\RI6FLHQFHV%UDQFKLQ /XEOLQYRO1RSS Sobczak P., 2006: Sorbitol addition on extrusion proFHVV7(.$&RPPLVVLRQRI0RWRUL]DWLRQDQG3RZHU ,QGXVWU\LQ$JULFXOWXUH3$19ROXPH9,D Thomas D.J., Atwell W.A., 1997: 6WDUFK $QDO\VLV 0HWKRGV,Q6WDUFKHV(DJDQ3UHVV6W3DXO0LQQHVRWD ĩDNRZVND+Opakowania biodegradowalne, &HQWUDOQ\2ĞURGHN%DGDZF]R5R]ZRMRZ\2SDNRZDĔ :DUV]DZD =KDQJ<5:DQJ;/=KDR*0:DQJ<= ,QÀXHQFHRIR[LGL]HGVWDUFKRQWKHSURSHUWLHVRIWKHUPRSODVWLFVWDUFK&DUERK\GUDWH3RO\PHUV± &+$5$.7(5<67<.$:<%5$1<&+&(&+ 5(2/2*,&=1<&+:2'1<&+52=7:25Ï: .8.85<'=,$1<&+%,2.2032=<7Ï:736 Streszczenie. %DGDQLRPSRGGDQRZRGQHUR]WZRU\JUDQXODWyZ NXNXU\G]LDQHMVNURELWHUPRSODVW\F]QHM736*UDQXODW\VNUREL WHUPRSODVW\F]QHM]RVWDá\Z\SURGXNRZDQH]PLHV]DQHNVNURELNXNXU\G]LDQHMJOLFHU\Q\RUD]GRGDWNXZ\SHáQLDF]\ZSRVWDFLZáyNLHQ QDWXUDOQ\FK:EDGDQLDFK]DVWRVRZDQR]PRG\¿NRZDQ\HNVWUXGHU MHGQRĞOLPDNRZ\76R/' L/' ]GRGDWNRZ\PFKáRG]HQLHPNRĔFRZHMF]ĊĞFLF\OLQGUDXU]ąG]HQLD%DGDQRZSá\Z SUĊGNRĞFLREURWRZHMĞOLPDNDHNVWUXGHUD]DVWRVRZDQHJRXNáDGX SODVW\¿NXMąFHJRRUD]URG]DMXVWRVRZDQHJRZ\SHáQLDF]DQDOHSNRĞü SR]RUQąUR]GUREQLRQ\FKJUDQXODWyZVNURELNXNXU\G]LDQHM3RGF]DV SRPLDUyZ]DREVHUZRZDQRĪHQDMZ\ĪV]HZDUWRĞFLOHSNRĞFLSR]RUQHMZ\VWĊSRZDá\ZSU]\SDGNXJUDQXODWyZVNURELNXNXU\G]LDQHM ]DZLHUDMąF\FKGRGDWHNZáyNLHQFHOXOR]RZ\FKHNVWUXGRZDQ\FK SU]\]DVWRVRZDQLXXNáDGXSODVW\¿NXMąFHJRR/' 6áRZDNOXF]RZHOHSNRĞüVNURELDWHUPRSODVW\F]QDHNVWUX]MD biokompozyty. This research work has been supported by the funds for science for the years 2010-2013 as a research project NN313275738. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 125–130 Characteristics of Selected Rheological Properties of Water Suspensions of Potato TPS Biocomposites Tomasz Oniszczuk, Agnieszka Wójtowicz, Leszek Mościcki, Andrzej Rejak, Maciej Combrzyński, Marcin Mitrus Department of Food Process Engineering, Lublin University of Life Sciences Doświadczalna 44, 20-236 Lublin, Poland e-mail: [email protected] Received December 07.2014; accepted December 18.2014 Summary. 7KH UHVHDUFK FRYHUHG WKH DTXHRXV VROXWLRQV RI JUDQXOHVRISRWDWRWKHUPRSODVWLFVWDUFK7367KHWKHUPRplastic starch granules were produced from mixtures of potato VWDUFKJO\FHURODQGDQDGGLWLYHRI¿OOHUVLQWKHIRUPRIQDWXUDO ¿EUHV ,Q WKH VWXG\ WZR FRQ¿JXUDWLRQV RI WKH SODVWLFL]LQJ V\VWHPZHUHXVHG/' DQG/' LQDPRGL¿HGVLQJOHVFUHZH[WUXVLRQFRRNHU76ZLWKDQH[WUDFRROLQJRIWKH end part of the cylinder. The research focused on the effect of the extruder screw speed and the volume and types of XVHG¿OOHUVRQWKHDSSDUHQWYLVFRVLW\RISXOYHUL]HGJUDQXOHV of thermoplastic starch. During the measurements, it was observed that the apparent viscosity of extruded potato starch ZDVLQÀXHQFHGE\WKHW\SHRIWKHSODVWLFL]LQJV\VWHPLQVWDOOHG in the extruder used for the production of TPS granules. The highest viscosity was reported for the solutions of potato TPS ZLWKWKHDGGLWLRQRIÀD[¿EUH Key words: H[WUXGHU¿EUHYLVFRVLW\WKHUPRSODVWLFVWDUFKH[trusion, biocomposites. compared with the corresponding petroleum-based plastic and are less expensive to make [2]. Starch is the most important polysaccharide in plants serving as a reserve and accumulated in the form of grains. Particularly starch-rich are the grains of cereals, potato and manioc tubers, as well as maize cobs. Starch hydrolyses only WRĮ'JOXFRVHEXWLWLVQRWDFKHPLFDOO\XQLIRUPFRPSRXQG in fact, it consists of two fractions: unbranched amylose and branched amylopectin [2]. The main advantages of starch are: biodegradability, broad availability, relatively low cost DQGHDVHRIFKHPLFDOPRGL¿FDWLRQ>@ Pure and dried starch differs materially from synthetic SRO\PHUV>@,WVKRXOGQRWEHUHJDUGHGDVDWKHUPRSODVWLFPDWHULDOVLQFHLWVJODVVWUDQVLWLRQWHPSHUDWXUH7J LVVLJQL¿FDQWO\KLJKHUWKDQWKHGHFRPSRVLWLRQWHPSHUDWXUH ,QUHFHQWGHFDGHVDQH[WUXVLRQFRRNHGPRGL¿HGVWDUFK has appeared on the market. The addition of plasticizers in the process of extrusion results in the lowering of the glass transition temperature of starch below its decomposition INTRODUCTION temperature and transforms it into thermoplastic starch 736ZKLFKOHQGVLWVHOIWRHDV\SURFHVVLQJ>@ The development of procedures for the mass produc- Plasticizers are mostly substances of low molecular weight tion of biodegradable materials has recently been an area which can be easily embedded into the polymer matrix in orof extensive research, both academic and commercial. This der to destroy the hydrogen inter and intra molecular bonds is attributed to the growing scarcity of crude oil resources that occur in starch. This, in the end, leads to the improved and to the fact that petroleum-based materials are non-bi- strength and heat treatment conditions of starch-based maRGHJUDGDEOH>@3RO\PHULFELRGHJUDGDEOHPDWHULDOV WHULDOV>@7KHPRVWFRPPRQO\XVHGSODVWLFL]HUV can be divided into two main groups, depending on the DUHJO\FHURODQGZDWHU>@ $VDX[LOLDU\DGGLWLYHVWKDWHQKDQFHWKHPHFKDQLFDODQG source of raw materials for their production: the polymers produced by the traditional chemical synthesis of natural physical properties of natural polymers, various types of monomers and the polymers produced by microorganisms ¿OOHUVFDQEHXVHGVXFKDVQDWXUDO¿EUHKHPSÀD[MXWH RUPRGL¿HGEDFWHULDWKHVRFDOOHGELRSRO\PHUV$SUDFWLFDO FRFRQXWFHOOXORVHFRWWRQRUZRRGZDVWH>@ alternative replacing the polymers based on petroleum are The aim of the study was to examine the apparent viscosimaterials produced with the use of starch and belonging to ty of water suspensions of pulverized granules of potato therWKHODWWHUJURXS$OVRWKHPL[LQJRIWKLVQDWXUDOFRPSRQHQW PRSODVWLFVWDUFKH[WUXGHGDWVHYHUDOFRQ¿JXUDWLRQVHWWLQJVRI with synthetic polymers is an option. Such mixtures are not the plasticizing system and to determine the impact of the type biodegradable, still, they reveal a lower carbon emission DQGTXDQWLW\RIDGGLWLYHVRQWKHYLVFRVLW\RIVROXWLRQV 721,6=&=8.$:Ï-72:,&=/02ĝ&,&.,$5(-$.0&20%5=<ē6.,00,7586 0$7(5,$/6$1'0(7+2'6 The main raw material used in the research was potato VWDUFKRIWKHW\SH6XSHULRU6WDQGDUG)VXSSOLHGE\Ä3HSHHV´ 6$.URFKPDOQLDàRPĪD$VDQDX[LOLDU\VXEVWDQFHDFWLQJ DVSODVWLFL]HUWHFKQLFDOJO\FHUROZDVXVHGRISXULW\LQ DQDPRXQWRIRIVWDUFKZHLJKW $VDGGLWLYHVRIQDWXUDORULJLQDFWLQJDV¿OOHUVFHOOXORVH ¿EUH9LYDSXUW\SH-56*HUPDQ\ÀD[¿EUHDQGSLQH EDUN3RODQGZHUHXVHGDIWHUEHLQJJURXQGRQDODERUDWRU\ PLOO/017HVW&KHP5DGOLQ 3RWDWRVWDUFKZLWKDPRLVWXUHFRQWHQWRIDQGJO\Ferol were used to prepare TPS raw material mixtures to ZKLFKFHOOXORVH¿EUHÀD[¿EUHDQGJURXQGEDUNZHUHDGGHG LQWKHDPRXQWRIDQGRIWKHPL[WXUHZHLJKW6R prepared raw material was mixed by means of a laboratory ULEERQPL[HUIRUPLQXWHV$IWHUPL[LQJWKHPDWHULDOZDV OHIWLQVHDOHGSODVWLFEDJVIRUKRXUVWRKRPRJHQL]HWKH whole mass of the sample. Directly before extrusion, the PDWHULDOZDVPL[HGDJDLQIRUPLQXWHVLQRUGHUWRORRVHQ the mass before extrusion. 352'8&7,212)*5$18/(6 Potato starch granules with the addition of natural plant ¿OOHUVZHUHH[WUXGHGLQWKHWHPSHUDWXUHUDQJH& and moulded through a die with a single hole of a diameter RIPP,QWKHSURFHVVDPRGL¿HGYHUVLRQRIWKHVLQJOH VFUHZH[WUXVLRQFRRNHU76ZDVXVHG=0&K0HWDOFKHP *OLZLFH3RODQG7KHPRGL¿FDWLRQLQYROYHGWKHDSSOLFDtion of two types of a plasticizing system with the screw/ GLDPHWHUUDWLRRI/' DQG/' HTXLSSHGZLWK a temperature control system and the cooling of the end SDUWRIWKHF\OLQGHU*UDQXOHVZHUHSURGXFHGDWDYDULDEOH H[WUXGHUVFUHZURWDWLRQQDPHO\DQGUSP7KH obtained granules were ground before tests in the laboratory PLOO/017HVW&KHP5DGOLQWRWKHSDUWLFOHVL]HRI PPDQGVWRUHGLQGU\HQYLURQPHQWXQWLOPHDVXUHPHQWV> @ Photo 1. 7HVWLQJPDFKLQH=ZLFN%'2)%7+ZLWKPRXQWHG back extrusion component to measure viscosity SURJUDP7KHUHZHUH¿YHUHSOLFDWLRQVWKH¿QDOUHVXOWEHLQJ WKHDULWKPHWLFPHDQRIWKHPHDVXUHPHQWV>@ 5(68/76 7KHDSSDUHQWYLVFRVLW\RIDTXHRXVVROXWLRQVRISRWDWRWKHUPRSODVWLFVWDUFKZLWKWKHDGGLWLRQRIFHOOXORVH¿EUHH[WUXGHGLQ DSODVWLFL]LQJV\VWHPFRQ¿JXUDWLRQRI/' LQFUHDVHGDORQJ ZLWKWKHLQFUHDVLQJH[WUXGHUVFUHZVSHHG)LJ7KHLQFUHDVH LQWKHFRQWHQWRIFHOOXORVH¿EUHLQWKHPL[WXUHRIUDZPDWHrials caused higher viscosities of potato starch solutions and VLJQL¿FDQWSGLIIHUHQFHVEHWZHHQWKHPHDQV7DEOH 0($685(0(172)$33$5(179,6&26,7< 7RPHDVXUHDSSDUHQWYLVFRVLW\VROXWLRQVZHUHSUHSDUHGRIJURXQGJUDQXOHVDQGGLVWLOOHGZDWHURI&3UHSDUHGVXVSHQVLRQVZHUHPL[HGIRUPLQXWHVDQGVXEMHFWHG WRDYLVFRVLW\WHVWLQJF\FOH$EDFNH[WUXVLRQFRPSRQHQW ZDVPRXQWHGRQWKHWHVWLQJPDFKLQH=ZLFN5RHOO%'2 )%7+HTXLSSHGZLWKDN1IRUFHKHDG)LJ7KH FKDPEHUSDUDPHWHUVZHUHDVIROORZVF\OLQGHUKHLJKW± PPLQQHUGLDPHWHU±PPSOXQJHUGLDPHWHU±PP SOXQJHUKHLJKW±PPWKHSOXQJHUKDYLQJDFRQLFDOERWtom surface. During the test, the head speed was set to PPPLQ-1, the measuring gap was 2 mm, and the total WHVWOHQJWKZDVPP During the test, the value of the apparent viscosity coHI¿FLHQWZDVGHWHUPLQHGEDVHGRQWKHUHFRUGHGUHVLVWDQFH force of the suspension during the movement of the plunger in one bottom-up measurement cycle; the force was next FRQYHUWHGLQWRDSSDUHQWYLVFRVLW\LQWKHWHVW;SHUWY Fig. 1. 7KHLQÀXHQFHRIWKHDGGLWLRQRIFHOOXORVH¿EUHDQGWKH extruder screw speed on the apparent viscosity of potato starch VROXWLRQVH[WUXGHUSODVWLFL]LQJV\VWHPRI/' Fig. 2 illustrates the results of measurements of apparent YLVFRVLW\RIDTXHRXVVROXWLRQVRIJUDQXOHVZLWKWKHDGGL- &+$5$&7(5,67,&62)6(/(&7('5+(2/2*,&$/3523(57,(62):$7(56863(16,216 WLRQRIFHOOXORVH¿EUH7KHXVHRIH[WHQGHGSODVWLFL]LQJV\VWHP RI/' DQGDYDULDEOHH[WUXGHUVFUHZVSHHGGXULQJWKH SURGXFWLRQRISRWDWRVWDUFKJUDQXOHVZLWKWKHDGGLWLRQRI RIFHOOXORVH¿EUHLQWKHUHFLSHGLGQRWHQWDLODQ\VLJQL¿FDQW changes in the viscosity of thermoplastic starch solutions. %RWKWKHLQFUHDVHRIWKHVFUHZVSHHGGXULQJWKHSURGXFWLRQRIJUDQXODWHVDQGWKHKLJKHUFRQWHQWRIQDWXUDOÀD[ ¿EUHVLJQL¿FDQWO\LPSURYHGWKHYLVFRVLW\YDOXHV7DEOH The highest apparent viscosity values were reported for TPS VROXWLRQVFRQWDLQLQJRIÀD[¿EUH+RZHYHULQWKLVFDVH the higher screw speed during extrusion resulted in the lower YDOXHVRIWKHWHVWHGSDUDPHWHU)LJ Fig. 2. 7KHLQÀXHQFHRIWKHDGGLWLRQRIFHOOXORVH¿EUHDQGWKH extruder screw speed on the apparent viscosity of potato starch VROXWLRQVH[WUXGHUSODVWLFL]LQJV\VWHPRI/' Fig. 3. 7KHLQÀXHQFHRIÀH[¿EUHVDQGWKHH[WUXGHUVFUHZVSHHG on the apparent viscosity of potato starch solutions (extruder $YHU\ORZYLVFRVLW\RIWKHH[DPLQHGVROXWLRQVPD\ SODVWLFL]LQJV\VWHPRI/' LQGLFDWHLQVXI¿FLHQWSUHVVXUHDQGWKHUPDOWUHDWPHQWLQWKH cooling conditions and with the application of the extended plasticizing system, which prevented the granules with the DGGLWLRQRIFHOOXORVH¿EUHWRREWDLQDVWDEOHVWUXFWXUH )LJDQGVKRZWKHHIIHFWRIWKHDGGLWLRQRIÀD[¿EUH and the extruder screw speed on the apparent viscosity of DTXHRXVVROXWLRQVRI736H[WUXGHGLQGLIIHUHQWFRQ¿JXUDWLRQVRIWKHSODVWLFL]LQJV\VWHP7KHDTXHRXVVROXWLRQVRI TPS granules obtained with the extruder plasticizing system DW/' GLVSOD\HGKLJKHUYLVFRVLW\YDOXHV $VLPLODUWUHQGZDVREVHUYHGIRUWKHH[WHQGHGSODVWLFL]LQJV\VWHPQDPHO\DORQJZLWKWKHLQFUHDVLQJFRQWHQWRIÀD[ ¿EUHWKHDSSDUHQWYLVFRVLW\RIDTXHRXVVROXWLRQVRIJUDQXOHV rose; yet, the measured viscosity values were slightly lower. Such considerable differences in viscosity measurements were caused by problems occurring during the measurement. During the measurement, the solution began to delaminate, ZKLFK VLJQL¿FDQWO\ DIIHFWHG LWV YLVFRVLW\ 7KLV LQ WXUQ demonstrates an uneven internal structure of potato starch Ta b l e 1 . 7KHUHVXOWVRIWKHVWDWLVWLFDODQDO\VLVRIYLVFRVLW\RIDTXHRXVVROXWLRQVRIWKHUPRSODVWLFSRWDWRVWDUFKGHSHQGLQJRQ the additives used. $GGLWLYH L/D version &HOOXORVH¿EUH )OD[¿EUH *URXQGSLQHEDUN Screw rotation [rpm-1] 80 80 80 80 80 80 3RO\QRPLDOUHJUHVVLRQHTXDWLRQ )WHVWYDOXHV P value y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y ([2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2+0.090x+7.207 y [2[ 2.277 0.0000 0.0000 721,6=&=8.$:Ï-72:,&=/02ĝ&,&.,$5(-$.0&20%5=<ē6.,00,7586 ELRFRPSRVLWHVDQGDZHDNERQGEHWZHHQÀD[¿EUHVDQGWKH ing system with the addition of ground bark changed only starch matrix in the conditions of intense cooling and with VOLJKWO\7KHKLJKHU¿OOHUFRQWHQWDQGWKHH[WUXGHUVFUHZ the application of the extended plasticizing system. speed did not have a noteworthy effect on the value of apparent viscosity in this case. The results indicate only a loose bond between bark and potato starch in the granulated structure, which translates into the low viscosity of SUHSDUHGDTXHRXVVROXWLRQV Fig. 4. 7KHLQÀXHQFHRIÀH[¿EUHVDQGWKHH[WUXGHUVFUHZVSHHG on the apparent viscosity of potato starch solutions (extruder SODVWLFL]LQJV\VWHPRI/' The addition of ground bark to the potato TPS potato VWDUFKUHVXOWHGLQKLJKHUDSSDUHQWYLVFRVLW\RILWVDTXHRXV solutions than in the case of granules without this added content. The lowest viscosity was reported in TPS solutions WKDWFRQWDLQHGQR¿OOHU)LJ7KHKLJKHVWYDOXHRIWKH apparent viscosity was obtained while testing granules with DDGGLWLRQRIJURXQGEDUN5DLVLQJWKHEDUNFRQWHQWWR LQWKHZKROHUDQJHRIDSSOLHGH[WUXGHUVFUHZVSHHGV KDGDVLJQL¿FDQWLQÀXHQFHSRQHWKHGHFOLQHLQWKH apparent viscosity of TPS solutions, as shown by the negaWLYHYDOXHVRIWKHVORSHFRHI¿FLHQWVRIWKHOLQHVRIWKHWUHQG H[SUHVVHGE\DVTXDUHSRO\QRPLDO7DEOH Fig. 6. 7KHLQÀXHQFHRIJURXQGEDUNDGGLWLRQDQGWKHH[WUXGHU screw speed on the apparent viscosity of potato starch solutions H[WUXGHUSODVWLFL]LQJV\VWHPRI/' CONCLUSIONS ± 7KHKLJKHVWDSSDUHQWYLVFRVLW\YDOXHVZHUHUHSRUWHGIRU VROXWLRQVRI736ZLWKWKHDGGLWLRQRIÀD[¿EUH ± 7KHDSSDUHQWYLVFRVLW\RIWKHVROXWLRQVZDVGHWHUPLQHG by the rotational speed of the extruder used for the production of the TPS granulated matter. ± 7KHDTXHRXVVROXWLRQVRI736JUDQXOHVREWDLQHGZLWKWKH /' H[WUXGHUSODVWLFL]LQJV\VWHPGLVSOD\HGKLJKHU apparent viscosity values. ± 7KHDGGLWLRQRI¿OOHUVVXFKDVQDWXUDO¿EUHVLQFUHDVHG YLVFRVLW\LQWKHPDMRULW\RIH[DPLQHGDTXHRXVVROXWLRQV of TPS. 5()(5(1&(6 Bledzki A.K., Gassan J., 1999: Composites reinforced ZLWKFHOOXORVHEDVHG¿EUHV3URJ3RO\PHU6FLHQFH 2. Cerclé C., Sarazinb P., Basil D. Favis B.D. 2013:+LJK performance polyethylene/thermoplastic starch blends WKURXJKFRQWUROOHGHPXOVL¿FDWLRQSKHQRPHQD&DUERK\Fig. 5. 7KHLQÀXHQFHRIJURXQGEDUNDGGLWLRQDQGWKHH[WUXGHU GUDWH3RO\PHUV± screw speed on the apparent viscosity of potato starch solutions Dyadychev V., Pugacheva H., Kildeychik A., 2010: H[WUXGHUSODVWLFL]LQJV\VWHPRI/' Co-injection molding as one of the most popular injection molding Technologies for manufacture of polymeric No explicit effect was observed of the applied screw GHWDLOVIURPVHFRQGDU\UDZPDWHULDOV7(.$&RPPLVLRQ speeds during extrusion; still, the lowest screw speed reRIPRWRUL]DWLRQDQG3RZHU,QGXVWU\LQ$JULFXOWXUH3$1 sulted in the lowest viscosity of granulate solutions pro9ROXPH;F duced in the proposed conditions with the shorter version Gujral H.S., Sodhi N.S., 2002:%DFNH[WUXVLRQSURSof the plasticizing system. The viscosity of solutions of erties of wheat porridge (Dalia). -RXUQDORI)RRG(QJLSRWDWR736JUDQXOHVSURGXFHGZLWKWKH/' SODVWLFL]QHHULQJ &+$5$&7(5,67,&62)6(/(&7('5+(2/2*,&$/3523(57,(62):$7(56863(16,216 -DQVVHQ/3%00RVFLFNL/(GVThermoSODVWLF6WDUFK:LOH\9&+9HUODJ*PE+&R.*D$ :HLQKHLP Labet, M., Thielemans, W., & Dufresne, A. 2007: 3RO\PHUJUDIWLQJRQWRVWDUFKQDQRFU\VWDOV%LRPDFURPROHFXOHV± 7. /HH6</XQD*X]PDQ,&KDQJ6%DUUHWW'0 Guinard J-X., 1999:Relating descriptive analysis and instrumental texture data of processed diced tomatoes. )RRG4XDOLW\DQG3UHIHUHQFH 8. Mitrus M., 2006: Investigations of thermoplastic starch H[WUXVLRQFRRNLQJSURFHVVVWDELOLW\7(.$&RPPLVVLRQ RIPRWRUL]DWLRQDQG3RZHU,QGXVWU\LQ$JULFXOWXUH3$1 9ROXPH9,D 9. 0LWUXV 0 2QLV]F]XN 7 :Sá\Z REUyENL FLĞQLHQLRZRWHUPLF]QHMQDZáDĞFLZRĞFLPHFKDQLF]QH VNURELWHUPRSODVW\F]QHM:áDĞFLZRĞFLJHRPHWU\F]QH mechaniczne i strukturalne surowców i produktów VSRĪ\ZF]\FK:\G1DXN)51$/XEOLQ 0RVFLFNL/(G([WUXVLRQ&RRNLQJ7HFKQLTXHV :LOH\9&+9HUODJ*PE+&R.*D$:HLQKHLP 0RĞFLFNL / 0LWUXV 0:yMWRZLF]$ 2QLV]F]XN T., Rejak A., Janssen L., 2012:$SSOLFDWLRQRIH[WUXsion-cooking for processing of thermoplastic starch 736)RRG5HVHDUFK,QWHUQDWLRQDO9ROSS 2QLV]F]XN73LODZND5:Sá\ZGRGDWNXZáyNLHQFHOXOR]RZ\FKQDZ\WU]\PDáRĞüWHUPLF]QąVNUREL WHUPRSODVW\F]QHM3U]HP\Vá&KHPLF]Q\ 2QLV]F]XN73LODZND52QLV]F]XN$:Sá\Z GRGDWNXPLHORQHMNRU\VRVQRZHMQDZ\WU]\PDáRĞüWHUPLF]QąVNURELWHUPRSODVW\F]QHM3U]HP\Vá&KHPLF]Q\ 2QLV]F]XN7:yMWRZLF]$0LWUXV00RĞFLFNL/ &RPEU]\ĔVNL05HMDN$*áDG\V]HZVND% ,QÀXHQFHRISURFHVFRQGLWLRQVDQG¿OOHUVDGGLWLRQRQ H[WUXVLRQFRRNLQJHI¿FLHQF\DQG60(RIWKHUPRSODVtic potato starch, Teka Commision of Motorization and (QHUJHWLFVLQ$JULFXOWXUH3ROLVK$FDGHP\RI6FLHQFHV %UDQFKLQ/XEOLQYRO1RSS 2QLV]F]XN7:yMWRZLF]$0LWUXV00RĞFLFNL/ &RPEU]\ĔVNL05HMDN$*áDG\V]HZVND% %LRGHJUDGDWLRQRI736PRXOGLQJVHQULFKHGZLWKQDWXUDO ¿OOHUV7HND&RPPLVLRQRI0RWRUL]DWLRQDQG(QHUJHWLFV LQ$JULFXOWXUH3ROLVK$FDGHP\RI6FLHQFHV%UDQFKLQ /XEOLQYRO1RSS 6DUD]LQ3/L*2UWV:-)DYLV%'%Lnary and ternary blends of polylactide, polycaprolactone DQGWKHUPRSODVWLFVWDUFK3RO\PHU± Sobczak P., 2006: Sorbitol addition on extrusion proFHVV7(.$&RPPLVVLRQRI0RWRUL]DWLRQDQG3RZHU ,QGXVWU\LQ$JULFXOWXUH3$19ROXPH9,D Talja R. A., Peura M., Serimaa R., & Jouppila K., 2008:(IIHFWRIDP\ORVHFRQWHQWRQSK\VLFDODQGPHFKDQLFDOSURSHUWLHVRISRWDWRVWDUFKEDVHGHGLEOH¿OPV %LRPDFURPROHFXOHV± 7HL[HLUD('i5y]$&DUYDOKR$&XUYHOR$ 2007: The effect of glycerol/sugar/water and sugar/water mixtures on the plasticization of thermoplasticcassava VWDUFK&DUERK\GUDWH3RO\PHUV± 20. Thomas D.J., Atwell W.A., 1997: 6WDUFK $QDO\VLV 0HWKRGV,Q6WDUFKHV(DJDQ3UHVV6W3DXO0LQQHVRWD Xie, F., Halley, P. J., Ave´ rous, L., 2012: Rheology to understand and optimize processibility, structures and properties of starch polymeric materials. Prog. Polym. 6FL± 22. ĩDNRZVND+Opakowania biodegradowalne, &HQWUDOQ\2ĞURGHN%DGDZF]R5R]ZRMRZ\2SDNRZDĔ :DUV]DZD =KDQJ<5:DQJ;/=KDR*0:DQJ<= ,QÀXHQFHRIR[LGL]HGVWDUFKRQWKHSURSHUWLHVRIWKHUPRSODVWLFVWDUFK&DUERK\GUDWH3RO\PHUV± =KDQJ<5=KDQJ6':DQJ;/&KHQ5< :DQJ<=(IIHFWRIFDUERQ\OFRQWHQWRQWKH properties of thermoplastic oxidized starch. CarbohyGUDWH3RO\PHUV &+$5$.7(5<67<.$:<%5$1<&+&(&+ 5(2/2*,&=1<&+:2'1<&+52=7:25Ï: =,(01,$&=$1<&+%,2.2032=<7Ï:736 Streszczenie. %DGDQLRPSRGGDQRZRGQHUR]WZRU\JUDQXODWyZ ]LHPQLDF]DQHMVNURELWHUPRSODVW\F]QHM736*UDQXODW\VNUREL WHUPRSODVW\F]QHM]RVWDá\Z\SURGXNRZDQHZ]PLHV]DQHNVNUREL]LHPQLDF]DQHMJOLFHU\Q\RUD]GRGDWNXZ\SHáQLDF]\ZSRVWDFL ZáyNLHQQDWXUDOQ\FK:EDGDQLDFK]DVWRVRZDQRGZLHNRQ¿JXUDFMH XNáDGXSODVW\¿NXMąFHJR/' RUD]/' ]PRG\¿NRZDQHJR HNVWUXGHUDMHGQRĞOLPDNRZHJR76]GRGDWNRZ\PFKáRG]HQLHP NRĔFRZHMF]ĊĞFLF\OLQGUD%DGDQRZSá\ZSUĊGNRĞFLREURWRZHM ĞOLPDNDHNVWUXGHUDLORĞFLRUD]URG]DMXVWRVRZDQ\FKZ\SHáQLDF]\ QDOHSNRĞFLUR]GUREQLRQ\FKJUDQXODWyZVNURELWHUPRSODVW\F]QHM 3RGF]DVSRPLDUyZ]DREVHUZRZDQRĪHQDOHSNRĞüSR]RUQąUR]WZRUyZHNVWUXGRZDQHMVNUREL]LHPQLDF]DQHMPLDáZSá\ZURG]DM ]DVWRVRZDQHJRXNáDGXSODVW\¿NXMąFHJRHNVWUXGHUDVWRVRZDQHJRGR SURGXNFMLJUDQXODWyZ7361DMZ\ĪV]ąOHSNRĞFLąFKDUDNWHU\]RZDá\ VLĊUR]WZRU\]LHPQLDF]DQHM736]GRGDWNLHPZáyNLHQOQLDQ\FK 6áRZDNOXF]RZHHNVWUXGHUZáyNQDOHSNRĞüVNURELDWHUPRSODstyczna, ekstruzja, biokompozyty. This research work has been supported by the funds for science for the years 2010-2012 as a research project NN313275738. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 131–136 Characteristics of Selected Rheological Properties of Water Suspensions of Wheat TPS Biocomposites Tomasz Oniszczuk, Agnieszka Wójtowicz, Leszek Mościcki, Andrzej Rejak, Magdalena Klimek, Maciej Combrzyński Department of Food Process Engineering, Lublin University of Life Sciences Doświadczalna 44, 20-236 Lublin, Poland, e-mail: [email protected] Received December 07.2014; accepted December 18.2014 Summary. 7KHUHVHDUFKFRYHUHGWKHDTXHRXVVROXWLRQVRIWKHUPRSODVWLFZKHDWVWDUFK736JUDQXOHV7KHWKHUPRSODVWLFVWDUFK granules were produced from mixtures of wheat starch, glycerol DQGDQDGGLWLYHRI¿OOHUVLQWKHIRUPRIQDWXUDO¿EUHV,QWKHVWXG\ DPRGL¿HGVLQJOHVFUHZH[WUXVLRQFRRNHU76ZDVXVHGZLWK /' DQG/' ZLWKDQH[WUDFRROLQJRIWKHHQGSDUWRIWKH cylinder. The research focused on the effect of the extruder screw rotation speed, the volume and the type of plasticizing system used and on the apparent viscosity of pulverized granules of wheat TPS. During measurements it was observed that higher apparent viscosity values were recorded in those solutions of TPS that were produced with the extended version of the plasticizing V\VWHPRI76H[WUXGHU Key words: H[WUXGHU¿EUHYLVFRVLW\WKHUPRSODVWLFVWDUFKH[trusion, biocomposites. INTRODUCTION The production of biodegradable and environmentally friendly materials has recently come into focus of researchers worldwide. Such a material is expected to replace petroleum-based polymers which are very durable, yet represent DPDMRUHQYLURQPHQWDOLVVXH>@ One of the main natural compounds extensively researched for the use as a biodegradable material is starch. 7KH¿UVWDWWHPSWVWRREWDLQPDWHULDOVEDVHGRQWKLVFRPSRQHQWIRFXVHGRQWKHXVHRIVWDUFKJUDQXOHVDVD¿OOHUIRUV\QWKHWLFSRO\PHUVVXFKDVSRO\HWK\OHQHDQGSRO\SURS\OHQH>@ In order to be further processed as a biodegradable material, natural starch must be transformed into thermoplastic VWDUFK736,QWKLVFDVHWKHJUDQXODUVWUXFWXUHRIVWDUFK is completely degraded by the use of plasticizers in a high WHPSHUDWXUHGXULQJH[WUXVLRQ>@8QIRUWXQDWHO\SXUH thermoplastic starch has several disadvantages. They include ORZPHFKDQLFDOVWUHQJWKIUDJLOLW\DQGKLJKVHQVLWLYLW\WRHQYLURQPHQWDOIDFWRUVHJPRLVWXUH>@,QRUGHUWRRIIVHW these disadvantages, TPS is mixed with other polymers, thus yielding, in a simple, fast and inexpensive manner, mixtures with such properties that are generally not achievable when XVLQJLQGLYLGXDOSRO\PHULFPDWHULDOV>@,QRUGHUWR improve the processing and mechanical properties of TPS, it LVFRPELQHGZLWKHJSRO\HWK\OHQH3(>@SRO\SURS\OHQH33>@DQGSRO\DPLGH3$>@,QDGGLWLRQ in an attempt to obtain completely biodegradable materials, numerous TPS mixtures have been developed with various polymers which undergo complete degradation in the natuUDOHQYLURQPHQW>@$PRQJWKHELRGHJUDGDEOHSRO\PHUV EXW\OHQHSRO\VXFFLQDWH3%6GHVHUYHVVSHFLDODWWHQWLRQQRW RQO\EHFDXVHRILWVH[FHOOHQWELRGHJUDGDELOLW\TXDOLW\EXWDOVR VXI¿FLHQWPHFKDQLFDOVWUHQJWK7KHUHIRUHVRPHUHVHDUFKKDV EHHQFDUULHGRXWRQWKHFRPELQDWLRQRI3%6DQG736>@ *HQHUDOO\VSHDNLQJWKHUPRSODVWLFVWDUFKLVFRQVLGHUHG a promising material for the production of packaging materials due to its reasonable cost, availability, renewability and biodegradability. Recently, its use has spread to many VHFWRUVHJRLOUH¿QLQJJUHDVHPHWDOOXUJ\H[WUDFWLRQRI LPSXULWLHVIURPLURQWH[WLOHUXEEHUDQGSDSHUHQKDQFHPHQWRISDSHUVWUHQJWK>@ The properties of TPS are very much dependent on the QDWXUDORULJLQRIWKHVWDUFKPRUHVSHFL¿FDOO\RQWKHUDWLRRI its main two components: linear amylose and branched amylopectin. The share of amylose chains in starch is determined genetically and generally the same within a particular plant species. In standard starch, the amylose content accounts for RIWKHWRWDOVWDUFKZHLJKWLQVSHFLDOKLJKDP\ORVH VSHFLHVLWUHDFKHV>@7KHUHDUHQXPHURXVVWXGLHV on the effect of amylose and amylopectin content on the ¿QDOSURSHUWLHVRIVWDUFKEDVHGPDWHULDOV>@ TPS obtained from high-amylose starch has been proven to have better thermal and mechanical properties, still their SURFHVVLQJH[WUXVLRQLQSDUWLFXODULVPXFKPRUHGHPDQGLQJ>@,QRUGHUWRHQKDQFHWKHPHFKDQLFDODQG SK\VLFDOSURSHUWLHVRI736YDULRXVW\SHVRI¿OOHUVFDQEH XVHGVXFKDVQDWXUDO¿EUHRUZRRGZDVWH>@ 721,6=&=8.$:Ï-72:,&=/02ĝ&,&.,$5(-$.0./,0(.0&20%5=<ē6., 7KHHIIHFWRIWKHW\SHRIVWDUFKDQGXVHGDGGLWLYHV¿OOHUVSODVWLFL]HUVRQWKHSURSHUWLHVRI736LVFUXFLDOZKHQ selecting raw materials for the production of biodegradable plastics. It also allows the optimization of properties of TPS-based mixtures for the industrial application of TPS SURGXFWV>@ The aim of the study was to examine the apparent viscosity of suspensions of pulverized granules of thermoplastic ZKHDWVWDUFKJUDQXOHVZLWKGLIIHUHQWQDWXUDO¿OOHUV 5(68/76 )LJVKRZVWKHGHSHQGHQFHRIWKHYLVFRVLW\RIDTXHRXV solutions of thermoplastic wheat starch upon the applied VFUHZVSHHGRIWKH/' YHUVLRQH[WUXGHUDQGXSRQWKH FRQWHQWRIFHOOXORVH¿EUHLQWKHPL[WXUH,WZDVREVHUYHGWKDW WKHYLVFRVLW\RIWKHVROXWLRQLQFUHDVHGVLJQL¿FDQWO\S along with the increasing extruder screw speed and a higher DGGLWLRQRIFHOOXORVH¿EUH$VLPLODUWUHQGZDVREVHUYHGIRU maize starch. 0$7(5,$/6$1'0(7+2'6 :KHDWVWDUFKXVHGLQWKHVWXG\ZDV0HUL]HWIURP 6HJH]KD,UHODQGÀD[¿EUHIURPD3ROLVKSURGXFHUFHOOXORVH ¿EUH9LYDSXUW\SH-56IURPD*HUPDQSURGXFHUDQG JURXQGSLQHEDUN7HFKQLFDOJO\FHURORISXULW\ZDV used as a plasticizer. :KHDWVWDUFKJO\FHURODQG¿OOHUVLQWKHIRUPRIÀD[ ¿EUHVDQGJURXQGEDUNZHUHPL[HGIRUPLQXWHVLQDODERUDWRU\ULEERQPL[HU7KHJO\FHURODFFRXQWHGIRURIWKH PL[WXUHZHLJKWDQGWKHSURSRUWLRQRI¿OOHUVLQWKHSUHSDUHG PL[WXUHVZDVDQG$IWHUPL[LQJWKHVDPSOHV ZHUHOHIWLQVHDOHGSODVWLFEDJVIRUKRXUVLQRUGHUIRUWKH PL[WXUHWRKRPRJHQL]H>@ The baro-thermal treatment was carried out on a modL¿HG VLQJOHVFUHZ H[WUXVLRQFRRNHU 76 HTXLSSHG with two kinds of plasticizing systems with the screw OHQJWKGLDPHWHUUDWLRRI/' DQG/' $VWHHO GLHZDVXVHGZLWKDKROHRIPPLQGLDPHWHU*UDQXOHV ZHUHSURGXFHGDWWKHWKUHHH[WUXGHUVFUHZVSHHGV DQGUSP7HPSHUDWXUHYDOXHVZHUHLQWKHUDQJH RI&7KHWHPSHUDWXUHZDVFRQWUROOHGE\DSXUSRVHPDGHFRROLQJV\VWHP7KHH[WUXGHUZDVHTXLSSHG with a material feeder, a plasticizing system made up of the screw linked to the drive and housing, and a preheating device. To measure the temperature of the thermal and pressure treatment, thermocouples were used installed in the extruder cylinder; the results were displayed on the machine control panel. The screw speed during extrusion was monitored using a wireless electronic tachometer, '0$5>@ 7KHYLVFRVLW\RIDTXHRXVVROXWLRQVRIWKHUPRSODVWLF VWDUFKZDVPHDVXUHGRQWKHWHVWPDFKLQH=ZLFN%'2 )%27+ HTXLSSHG ZLWK D EDFN H[WUXVLRQ FKDPEHU The granules were ground using a laboratory mill to REWDLQSDUWLFOHVZLWKDGLDPHWHURIOHVVWKDQPP thermoplastic starch suspensions were prepared with GLVWLOOHGZDWHUDW&7KHYLVFRVLW\PHDVXUHPHQWVZHUH PDGH DIWHU PLQXWHV RI PL[LQJ 'XULQJ WKH WHVW WKH IROORZLQJSDUDPHWHUVZHUHVHWWRWDOWHVWOHQJWKPP DQGWKHKHDGVSHHGPPPLQ-1. During the study, the resistance force of the suspension was recorded during the movement of the plunger in one bottom-up measurement cycle, which was next converted into the apparent viscosity coefficient. The measurements were made usLQJWKHWHVW;SHUWYSURJUDP>@7KHUHZHUHILYH replications, the final result being the arithmetic mean of the measurements. Fig. 1. 7KHLQÀXHQFHRIFHOOXORVH¿EUHVDQGWKHH[WUXGHUVFUHZ speed on the apparent viscosity of wheat starch solutions (exWUXGHUSODVWLFL]LQJV\VWHPRI/' 7KH XVH RI WKH /' SODVWLFL]LQJ V\VWHP )LJ resulted in an increase of apparent viscosity. The highest apparent viscosity values were reported for solutions with DDGGLWLRQRIFHOOXORVH¿EUH,WZDVDOVRUHSRUWHGWKDW ZLWKWKHLQFUHDVLQJ¿EUHFRQWHQWLQWKHPL[WXUHWKHYLVFRVLW\ of the solution decreased. This may be an indication that WKHDGGLWLRQRIFHOOXORVH¿EUHVKDGDQDGYHUVHLPSDFWRQ their bond with the biopolymer matrix, which, in turn, had a negative bearing on the viscosity of the solution. Fig. 2. 7KHLQÀXHQFHRIFHOOXORVH¿EUHVDQGWKHH[WUXGHUVFUHZ speed on the apparent viscosity of wheat starch solutions (exWUXGHUSODVWLFL]LQJV\VWHPRI/' )LJVKRZVWKHHIIHFWRIWKHDGGLWLRQRIÀD[¿EUHRQ the value of apparent viscosity of the solutions of wheat &+$5$&7(5,67,&62)6(/(&7('5+(2/2*,&$/3523(57,(6 thermoplastic starch. It was observed that with increasing extruder screw rotation speed, the viscosity of solutions rose, regardless of the plasticizing system used. Fig. 4. 7KHLQÀXHQFHRIÀH[¿EUHVDQGWKHH[WUXGHUVFUHZVSHHG on the apparent viscosity of wheat starch solutions (extruder SODVWLFL]LQJV\VWHPRI/' Fig. 3. 7KHLQÀXHQFHRIÀH[¿EUHVDQGWKHH[WUXGHUVFUHZVSHHG on the apparent viscosity of wheat starch solutions (extruder SODVWLFL]LQJV\VWHPRI/' +LJKHUYLVFRVLW\YDOXHVZHUHUHSRUWHGIRUWKHVROXWLRQV RIWKHUPRSODVWLFZKHDWVWDUFKZLWKWKHDGGLWLRQRIÀD[¿EUH DWUSP-1 of the extruder screw. During tests, the TPS solutions delaminated, which tesWL¿HVWRDZHDNERQGEHWZHHQÀD[¿EUHDQGZKHDWVWDUFK,Q some cases, there was more resistance between the plunger and and the walls of the machine, which could have led to WKHKLJKVSUHDGRIDSSDUHQWYLVFRVLW\YDOXHV)LJ The apparent viscosity of solutions of wheat starch granules produced on the shorter version of the plasticizing system slightly increased along with the higher bark content in Fig. 5. 7KHLQÀXHQFHRIJURXQGEDUNDGGLWLRQDQGWKHH[WUXGHU WKHJUDQXODWHGPDWWHU)LJ7KHWRSYLVFRVLW\YDOXHZDV screw speed on the apparent viscosity of wheat starch solutions UHSRUWHGDWDFRQWHQWRIJURXQGEDUNDQGIRUWKHVFUHZ H[WUXGHUSODVWLFL]LQJV\VWHPRI/' VSHHGRIUSP-1. Ta b l e 1 . 7KHUHVXOWVRIWKHVWDWLVWLFDODQDO\VLVRIYLVFRVLW\RIDTXHRXVVROXWLRQVRIWKHUPRSODVWLFZKHDWVWDUFKGHSHQGLQJRQWKH additives used. $GGLWLYH L/D version &HOOXORVH¿EUH )OD[¿EUH *URXQGSLQHEDUN Screw rotation [rpm-1] 80 80 80 80 80 80 3RO\QRPLDOUHJUHVVLRQHTXDWLRQ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ y [2[ y80 [2[ y [2[ F test values P value 0.000000009 0.0000002 0.0000 0.00000 0.0000 0.0000008 0.0000 0.0000009 721,6=&=8.$:Ï-72:,&=/02ĝ&,&.,$5(-$.0./,0(.0&20%5=<ē6., No direct effect was noted of the screw speeds during extrusion on the value of the apparent viscosity of TPC ZKHDWVROXWLRQVZLWKJURXQGSLQHEDUN)LJ Fig. 6. 7KHLQÀXHQFHRIJURXQGEDUNDGGLWLRQDQGWKHH[WUXGHU screw speed on the apparent viscosity of wheat starch solutions H[WUXGHUSODVWLFL]LQJV\VWHPRI/' The use of the extended version of the plasticizing system of the extruder for the production of wheat TPS granules with the addition of bark had an impact on the increase in the value of apparent viscosity. The highest apparent viscosity YDOXHVZHUHUHSRUWHGIRUVROXWLRQVZLWKDDQGDGGLWLRQRIJURXQGEDUN$VLPLODUWUHQGZDVREVHUYHGLQWKDW the rising extruder screw speed resulted in the increased viscosity of tested solutions. CONCLUSIONS ± 7KHDTXHRXVVROXWLRQVRIWKHUPRSODVWLFZKHDWVWDUFK JUDQXOHVREWDLQHGZLWKWKHH[WHQGHG/' H[WUXGHU plasticizing system displayed higher apparent viscosity values. ± 7KHDGGLWLRQRI¿OOHUVVXFKDVQDWXUDO¿EUHVLQFUHDVHG YLVFRVLW\LQWKHPDMRULW\RIH[DPLQHGDTXHRXVVROXWLRQV of TPS. ± 7KHDGGLWLRQRIÀD[¿EUHHQKDQFHGWKHYLVFRVLW\RI736 solutions to the greatest extent. ± 7KHULVLQJH[WUXGHUVFUHZURWDWLRQDOVSHHGUHVXOWHGLQ a higher apparent viscosity value in the majority of examined solutions of TPS granules. 5()(5(1&(6 &DUYDOKR$-)-RE$(1$OYHV$$6&XUYHOR A. Gandini., 2003: Thermoplastic starch/natural rubber EOHQGV&DUERK\GUDWH3RO\PHUV± 2. Dyadychev V., Pugacheva H., Kildeychik A., 2010: Co-injection molding as one of the most popular injection molding Technologies for manufacture of polymeric GHWDLOVIURPVHFRQGDU\UDZPDWHULDOV7(.$&RPPLVLRQ RIPRWRUL]DWLRQDQG3RZHU,QGXVWU\LQ$JULFXOWXUH3$1 9ROXPH;F *ULI¿Q*-/863DWHQW Gujral H.S., Sodhi N.S., 2002:%DFNH[WUXVLRQSURSerties of wheat porridge (Dalia). -RXUQDORI)RRG(QJLQHHULQJ +H<6=HQJ-%/L6/:DQJ<= Crystallization behavior of partially miscible biodegradDEOHSRO\EXW\OHQHVXFFLQDWHSRO\HWK\OHQHVXFFLQDWH blends. 7KHUPRFKLP$FWD± -DQVVHQ/3%00RVFLFNL/(GVThermoSODVWLF6WDUFK:LOH\9&+9HUODJ*PE+&R.*D$ :HLQKHLP 7. /HH6</XQD*X]PDQ,&KDQJ6%DUUHWW'0 Guinard J-X., 1999:Relating descriptive analysis and instrumental texture data of processed diced tomatoes. )RRG4XDOLW\DQG3UHIHUHQFH 8. /L0/LX3=RX:<X/HWDO([WUXVLRQ SURFHVVLQJDQGFKDUDFWHUL]DWLRQRIHGLEOHVWDUFK¿OPV ZLWK GLIIHUHQW DP\ORVH FRQWHQWV - )RRG (QJ ± 9. /L-/XR;/LQ;DQG=KRX<ComparDWLYHVWXG\RQWKHEOHQGVRI3%6WKHUPRSODVWLFVWDUFK prepared from waxy and normal corn starches. Starch, ± /LX+;LH)<X/&KHQ//L/Thermal processing of starch-based polymers. Prog. Polym. Sci., ± /LX+<X/6LPRQ*'HDQ.&KHQ/ (IIHFWVRIDQQHDOLQJRQJHODWLQL]DWLRQDQGPLFURVWUXFtures of corn starches with different amylose/amylopecWLQUDWLRV&DUERK\GU3RO\P± Liu, P., Xie, F., Li, M., Liu, X. et al., 2011: Phase transitions of maize starches with different amylose conWHQWVLQJO\FHURO±ZDWHUV\VWHPV&DUERK\GU3RO\P ± Mitrus M., 2006: Investigations of thermoplastic starch H[WUXVLRQFRRNLQJSURFHVVVWDELOLW\7(.$&RPPLVVLRQ RIPRWRUL]DWLRQDQG3RZHU,QGXVWU\LQ$JULFXOWXUH3$1 9ROXPH9,D 0RĞFLFNL/0LWUXV0:yMWRZLF]$2QLV]F]XN T., Rejak A., Janssen L., 2012:$SSOLFDWLRQRIH[WUXsion-cooking for processing of thermoplastic starch 736)RRG5HVHDUFK,QWHUQDWLRQDO9ROSS 299. 0RUDLV7HL[HLUD(5R]$/&DUYDOKR$-) Antonio Curvelo, A., A., S., 2005: Preparation and Characterisation of Thermoplastic Starches from CasVDYD6WDUFK&DVVDYD5RRWDQG&DVVDYD%DJDVVH0DFURPRO6\PS± 2QLV]F]XN73LODZND5:Sá\ZGRGDWNXZáyNLHQFHOXOR]RZ\FKQDZ\WU]\PDáRĞüWHUPLF]QąVNUREL WHUPRSODVW\F]QHM3U]HP\Vá&KHPLF]Q\ 2QLV]F]XN73LODZND52QLV]F]XN$:Sá\Z GRGDWNXPLHORQHMNRU\VRVQRZHMQDZ\WU]\PDáRĞüWHUPLF]QąVNURELWHUPRSODVW\F]QHM3U]HP\Vá&KHPLF]Q\ 2QLV]F]XN7:yMWRZLF]$0LWUXV00RĞFLFNL/ &RPEU]\ĔVNL05HMDN$*áDG\V]HZVND% ,QÀXHQFHRISURFHVFRQGLWLRQVDQG¿OOHUVDGGLWLRQRQ &+$5$&7(5,67,&62)6(/(&7('5+(2/2*,&$/3523(57,(6 H[WUXVLRQFRRNLQJHI¿FLHQF\DQG60(RIWKHUPRSODVtic potato starch, Teka Commision of Motorization and (QHUJHWLFVLQ$JULFXOWXUH3ROLVK$FDGHP\RI6FLHQFHV %UDQFKLQ/XEOLQYRO1RSS 2QLV]F]XN7:yMWRZLF]$0LWUXV00RĞFLFNL/ &RPEU]\ĔVNL05HMDN$*áDG\V]HZVND% %LRGHJUDGDWLRQRI736PRXOGLQJVHQULFKHGZLWKQDWXUDO ¿OOHUV7HND&RPPLVLRQRI0RWRUL]DWLRQDQG(QHUJHWLFV LQ$JULFXOWXUH3ROLVK$FDGHP\RI6FLHQFHV%UDQFKLQ /XEOLQYRO1RSS 20. Pedroso, A. G., Rosa, D. S., 2005: Mechanical, thermal DQGPRUSKRORJLFDOFKDUDFWHUL]DWLRQRIUHF\FOHG/'3( FRUQVWDUFKEOHQGV&DUERK\GU3RO\P± Ramis, X., Cadenato, A., Salla, J. M., Morancho, J. M. et al., 2004: Thermal degradation of polypropylene/starchbased materials with enhanced biodegradabilLW\3RO\P'HJUDG6WDELOLW\± 22. 6KXMXQ:-LXJDR<-LQJOLQ<Preparation and characterization of compatible thermoplastic starch/ pol\HWK\OHQHEOHQGV3RO\P'HJUDG6WDELOLW\± Sobczak P., 2006: Sorbitol addition on extrusion proFHVV7(.$&RPPLVVLRQRI0RWRUL]DWLRQDQG3RZHU ,QGXVWU\LQ$JULFXOWXUH3$19ROXPH9,D Teyssandier, F., Cassagnau, P., Ge´ rard, J. F., Mignard, N., Me´ Lis, F., 2012: Morphology and meFKDQLFDOSURSHUWLHVRI3$SODVWLFL]HGVWDUFKEOHQGV prepared by highshear extrusion. Mater. Chem. Phys. ± Teyssandier, F., Cassagnau, P., Ge´ Rard, J. F., Mignard, N., 2011:5HDFWLYHFRPSDWLELOL]DWLRQRI3$ plasticized starch blends: towards improved mechanical SURSHUWLHV(XU3RO\P-± :DQJ1<X-&KDQJ350D;,QÀXHQFH of citric acid on the properties of glycerol-plasticized GU\VWDUFK'736DQG'736SRO\ODFWLFDFLGEOHQGV 6WDUFK±-/LHWDO6WDUFK ± 27. Xie F., Halley P. J., Ave´ Rous L., 2012: Rheology to understand and optimize processibility, structures and properties of starch polymeric materials. Prog. Polym. 6FL± 28. <X/'HDQ./L/Polymer blends and composites from renewable resources. Prog. Polym. Sci., ± 29. =HQJ-%-LDR//L<'6ULQLYDVDQ0HWDO %LREDVHGEOHQGVRIVWDUFKDQGSRO\EXW\OHQHVXFFLQDWH with improved miscibility, mechanical properties, and reGXFHGZDWHUDEVRUSWLRQ&DUERK\GU3RO\P± =KDQJ<5=KDQJ6':DQJ;/&KHQ5< :DQJ<=(IIHFWRIFDUERQ\OFRQWHQWRQWKH properties of thermoplastic oxidized starch. CarbohyGUDWH3RO\PHUV± =RX:<X//LX;&KHQ/HWDO(IIHFWV of amylose/ amylopectin ratio on starch-based superabVRUEHQWSRO\PHUV&DUERK\GU3RO\P± =XOOR5,DQQDFH6 The effects of different VWDUFKVRXUFHVDQGSODVWLFL]HUVRQ¿OPEORZLQJRIWKHUmoplastic starch: correlation among process, elongational properties and macromolecular structure. Carbohydr. 3RO\P± &+$5$.7(5<67<.$:<%5$1<&+&(&+ 5(2/2*,&=1<&+:2'1<&+52=7:25Ï: 36=(11<&+%,2.2032=<7Ï:736 Streszczenie. %DGDQLRPSRGGDQRZRGQHUR]WZRU\JUDQXODWyZ SV]HQQHMVNURELWHUPRSODVW\F]QHM736*UDQXODW\VNURELWHUPRSODVW\F]QHM]RVWDá\Z\SURGXNRZDQH]PLHV]DQHNVNURELSV]HQQHM JOLFHU\Q\RUD]GRGDWNXZ\SHáQLDF]\ZSRVWDFLZáyNLHQQDWXUDOQ\FK :EDGDQLDFK]DVWRVRZDQR]PRG\¿NRZDQ\HNVWUXGHUMHGQRĞOLPDNRZ\76R/' L/' ]GRGDWNRZ\PFKáRG]HQLHPNRĔFRZHMF]ĊĞFLF\OLQGUDXU]ąG]HQLD%DGDQRZSá\ZSUĊGNRĞFLREURWRZHM ĞOLPDNDHNVWUXGHUDLORĞFLRUD]URG]DMXVWRVRZDQHJRZ\SHáQLDF]DQDOHSNRĞüUR]GUREQLRQ\FKJUDQXODWyZSV]HQQHMVNURELWHUPRSODVW\F]QHM3RGF]DVSRPLDUyZ]DREVHUZRZDQRĪHZ\ĪV]\PLZDUWRĞFLDPL OHSNRĞFLSR]RUQHMFKDUDNWHU\]RZDá\VLĊUR]WZRU\736Z\WZRU]RQHM QDGáXĪV]HMZHUVMLXNáDGXSODVW\¿NXMąFHJRHNVWUXGHUD76 6áRZDNOXF]RZHHNVWUXGHUZáyNQDOHSNRĞüVNURELDWHUPRSODstyczna, ekstruzja, biokompozyty. This research work has been supported by the funds for science for the years 2010-2012 as a research project NN313275738. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 137–142 Vehicle Transport Organization of Food Requiring Refrigeration Halina Pawlak, Piotr Maksym, Jacek Skwarcz University of Life Sciences in Lublin, Department of Technology Fundamentals Doświadczalna 44, 20-236 Lublin, Poland Received December 09.2014; accepted December 19.2014 Summary. 7KHSDSHUSUHVHQWVDGHVFULSWLRQRIWKHOHJDOUHTXLUHPHQWVIRUFDUWUDQVSRUWRIIRRGVWKDWUHTXLUHUHIULJHUDWLRQ:HUH also carried out a survey among drivers involved in this kind of transport, in order to assess the knowledge of drivers about the WUDQVSRUWRISHULVKDEOHIRRGWKDWUHTXLUHVFRROLQJ Key words: perishable foodstuff, vehicle transport, legislation. INTRODUCTION Nowadays the demand is rapidly growing for food with KLJKVHQVRU\TXDOLW\IUHVKDQGULFKLQQXWULHQWV7KLVSKHnomenon is not only the driving force for the development RIDJULIRRGLQGXVWU\EXWDOVRLQWKH¿HOGRIORJLVWLFVDQG transport of refrigerated foods. This progress has resulted in the possibility of provision of even very distant markets IRUSHULVKDEOHIRRGVWXII>@ More and more often, the transport of food products has been using methods of preservation of these products involving the application of the cooling systems. This allows WKHVKRUWWHUPVWRUDJHRIIUHVKIRRGDWDWHPSHUDWXUHIURP WR&RUORQJWHUPVWRUDJHLQDIUR]HQVWDWHDWDWHPSHUDWXUH IURPWR&>@ The advantage of the method of cooling is a complete stop or slowing down of microbial growth in both chilled and frozen foods. Furthermore, foods preserved by this method retain vitamins and organoleptic characteristics of WKHIUHVKIRRG7KHIXO¿OOPHQWRIVXFKFRQGLWLRQVUHTXLUHV compliance with the principles of transport conditions of perishable foodstuffs and the selection of proper means of transport. Special means of transport for perishable food items are: ± LQVXODWHGHTXLSPHQW ± UHIULJHUDWHGHTXLSPHQW ± PHFKDQLFDOO\UHIULJHUDWHGHTXLSPHQW ± KHDWHGHTXLSPHQW Participation in road transport of perishable goods, as well as dangerous goods, has been systematically increasing, ZKLFKUHTXLUHVVWULFWFRPSOLDQFHZLWKWKHUHOHYDQWSURYLVLRQV >@ 3HUVLVWHQFHDQGTXDOLW\RIWUDQVSRUWHGUHIULJHUDWHGIRRG products depends mainly on micro-climatic conditions prevailing in the cargo area. The main parameter is the temperature, which depends on the product being transported. the variations of the temperature should be kept to the minimum >@ During the loading, transport and unloading, the highest temperature of frozen and deep-frozen foods should not H[FHHGWKHWHPSHUDWXUHVJLYHQLQ7DEOH 7DEOH7HPSHUDWXUHUHTXLUHGIRUWKHWUDQVSRUWRIIUR]HQ DQGGHHSIUR]HQIRRGVWXII>@ Type of food article Frozen or deep-frozen cream and fruit juice concentrates )UR]HQDQGGHHSIUR]HQ¿VKHV $Q\RWKHUGHHSIUR]HQIRRGVWXIIV Frozen butter and other fats Frozen offal, egg yolks, poultry and game Frozen meat $Q\RWKHUIUR]HQIRRGVWXIIV 7KHUHTXLUHG transport temperature -20oC oC oC oC oC oC oC This temperature may increase, for example in the evaporator during the defrosting of the means of transport PHFKDQLFDOO\UHIULJHUDWHGHTXLSPHQW,QVXFKFDVHWKH WHPSHUDWXUHLVDOORZHGWRLQFUHDVHQRPRUHWKDQD&ZLWK UHVSHFWWRWKHUHTXLUHGWHPSHUDWXUHV Furthermore, the highest temperature anywhere in cargo during loading, transport and unloading of non-frozen foods should not exceed the temperatures given in Table 2. +$/,1$3$:/$.3,2750$.6<0-$&(.6.:$5&= Ta b l e 2 . 7HPSHUDWXUHUHTXLUHGIRUWKHWUDQVSRUWRIQRQIUR]HQ DQGQRQGHHSIUR]HQIRRGVWXII>@ Type of food article The required transport temperature oC1) oC oC Poultry %XWWHU *DPH 0LONWDQNHUUDZRUSDVWHXULVHGLQWHQGHGIRU oC1) direct human consumption Industrial milk oC1) 0LON\SURGXFWV\RJXUWNH¿UVRXUFUHDP oC1) FRWWDJHFKHHVH )LVKHVVKRXOGDOZD\VEHWUDQVSRUWHGLQLFH2) +2oC Prepared meat products oC 0HDWH[FOXGLQJSRXOWU\ +7oC Poultry and rabbits oC 1) ,QSULQFLSOHWUDQVSRUWWLPHVKRXOGQRWH[FHHGKRXUV 2) :LWKWKHH[FHSWLRQRIVPRNHG¿VKVDOWHGGULHGRUOLYH 3) With the exception of products in the stabilized state by salting, smoking, drying or sterilization. Fig. 1. &HUWL¿FDWLRQSODWHRIFRPSOLDQFHRIWKHHTXLSPHQW±WKH SDUWLFXODUVLQVTXDUHEUDFNHWVDUHJLYHQE\ZD\RIH[DPSOH>@ On the other hand the driver should have the original FHUWL¿FDWHRI$73LQ3ROLVKDQG(QJOLVK6DPSOHJXLGHOLQHV IRUYHUL¿FDWLRQRIWKHHTXLSPHQWLQWKHWUDQVSRUWRIIRRGDUH shown in Figure 2 7KHUHTXLUHPHQWVUHODWHGWRWKHDGPLVVLRQRIYHKLFOHVWR $QRWKHULPSRUWDQWSDUDPHWHURIPHFKDQLFDOO\UHIULJHU- WUDI¿FPXVWEHFRQVLVWHQWZLWKWKHUHTXLUHPHQWVFRQWDLQHGLQ DWHGHTXLSPHQWLVKXPLGLW\ZKLFKVHWVDXWRPDWLFDOO\DQG WKH$73DJUHHPHQW$JUHHPHQWRQWKH,QWHUQDWLRQDO&DUULDJH GRHVQRWUHTXLUHFRQWURO RI3HULVKDEOH)RRGVWXIIVDQGRQWKH6SHFLDO(TXLSPHQWWR Moreover, the interior of transport should be clean in EHXVHGIRUVXFK&DUULDJH order not to lead to the development of miFURRUJDQLVPV%HIRUHORDGLQJLQDFFRUGDQFH with the principles of good transport, refrigeration compartment of the vehicle should be cooled to a temperature appropriate for a given food product. Carriers must be informed (need to NQRZDERXWWKHIDFWWKDWWUDQVSRUWRIIURzen, deep-frozen and unfrozen food must be included as a component of the storage time. Therefore, the drivers carrying food should note that transportation of certain articles of food may be close to the optimum storage time and therefore often vehicles should be WUHDWHGDVDVSHFLDONLQGRIPDJD]LQH>@ Suitable conditions for the transport of food and sanitary safety, as in force in 3RODQG VLQFH $73 $DJUHHPHQW 7WUDQVSRUWDWLRQ 3SHULVKDEOH DJUHHPHQW of the “International Carriage of Perishable IRRGVWXIIVDQGWKHVSHFLDOHTXLSPHQWIRUVXFK FDUULDJH´UHTXLUHDSSURSULDWHLGHQWL¿FDWLRQ RIPHDQVRIWUDQVSRUWDQGWKHUHTXLUHGGRFXPHQWV>@ Means of transport intended for the carriage of perishable food products, which PHHWWKHWHUPVRIWKHDJUHHPHQW$73VKRXOG EHPDUNHGE\VLJQV$73)LJZKLFKLV mounted in a visible location on the wall of the building isothermal for the passenger side. The table contains the marking class RI$73PRQWK\HDUDQGYDOLGLW\RIWKHFHUWL¿FDWH Fig. 2. $73H[DPSOHRIJRRGSUDFWLFH>@ 9(+,&/(75$16325725*$1,=$7,212))22'5(48,5,1*5()5,*(5$7,21 7KH8QLWHG1DWLRQ(FRQRPLF&RPPLVVLRQIRU(XURSH has information about the performing centers (Competent $XWKRULWLHVDQG7HVW6WDWLRQVOLVW>@&2&+SHUIRUPV periodic checks of insulated body in order to extend the SHULRGRIYDOLGLW\RIWKH$73FHUWL¿FDWH)5&)1$ For example, in the context of accreditation for the PolLVK&HQWUHIRU$FFUHGLWDWLRQ&2&+SHUIRUPV ± LQVSHFWLRQVZKLFKDUHWKHEDVLVIRUREWDLQLQJFHUWL¿FDWLRQ RI$73 ± PHDVXUHPHQWVRIWKHRYHUDOOFRHI¿FLHQW³N´RIKHDWWUDQVfer for both the new means of refrigeration transport and WKHLQVHUYLFHRQHDVWKHEDVLVIRUREWDLQLQJFHUWL¿FDWLRQ RI$73 ± FRPSOHWHWHVWLQJRIPHFKDQLFDOO\UHIULJHUDWHGWUDQVSRUW (air-conditioned semi-trailers, refrigerated trailers, reIULJHUDWHGWUXFNVHWFDQGQRWPHFKDQLFDOO\UHIULJHUDWHG WUDQVSRUWLFHKRXVHFDUV ± UHVHDUFKRQWKHHIIHFWLYHUHIULJHUDWLQJFDSDFLW\RIWKH cooling unit, ± PHDVXUHPHQWVRIWKHRYHUDOOFRHI¿FLHQW³N´RIKHDWWUDQVIHUIRUOLTXLGIRRGVWXIIVWDQNWUXFNV>@ 7KHGRPHVWLFDQGLQWHUQDWLRQDOSURYLVLRQVUHTXLUHWKHFDUULHUWRWUDQVSRUWHTXLSPHQWZLWKDPHDVXULQJGHYLFHUHFRUGLQJ the air temperature inside the vehicle. Waveforms obtained from the temperature changes registration, depending on the type of product being transported, must be kept for at least one year.Monitoring and recording of temperature also applies to loading of goods, which should be chilled to the optimum storDJHWHPSHUDWXUHWUDQVSRUWUHIULJHUDQW,WLVDOVRLPSRUWDQWWR FRQWUROWKHWHPSHUDWXUHRIIRRGSURGXFWVEHLQJXQORDGHG>@ 7KHGULYHUHPSOR\HHKDVWREHFRPSHWHQWDQGSRVVHVV WKHNQRZOHGJHRIDOOWKHUHTXLUHPHQWVFRQWDLQHGLQWKHVH regulations. UHTXLUHPHQWV IRU WKH WUDQVSRUW RI IRRG LQ VSHFLDO FRQditions. Ta b l e 3 . *HQHUDOLQIRUPDWLRQ $JH 2. The experience of work in the driver’s SURIHVVLRQLQ\HDUV 7KHH[SHULHQFHRIZRUNLQSHULVKDEOHIRRGVWXII YHKLFOHWUDQVSRUWLQ\HDUV regular 7KHW\SHRIWUDQVSRUWFKDUDFWHU casual Ta b l e 4 . Information on the used type of isothermal transport vehicle ,QVXODWHGHTXLSPHQW 5HIULJHUDWHGHTXLSPHQW 0HFKDQLFDOO\UHIULJHUDWHGHTXLSPHQW 2WKHU Ta b l e 5 . Information on time, temperature and kind of perishable foodstuff $UH\RXDOZD\VLQIRUPHGRQZKDW NLQGRISURGXFWV\RXWUDQVSRUW" 'R\RXNQRZZKDWLVWKHUHTXLUHG temperature during transport RIIRRG" 'R\RXNQRZWKHWLPHUHTXLUHGIRU WKHWUDQVSRUWRIIRRG" 'R\RXNQRZWKHUHTXLUHGWLPH associated with loading and unORDGLQJRIWUDQVSRUWHGIRRG" <HV No I don’tknow <HV No I don’tknow <HV No I don’tknow <HV No I don’tknow Ta b l e 6 . Information on vehicle designation, necessary transport documents and general rules of vehicle transport 7+($,0$1'7+(5$1*(2):25. 7UDQVSRUWDWLRQRIIRRGUHTXLUHVIURPFDUULHUVWKHNQRZOHGJHRIURDGWUDI¿FUHJXODWLRQVDQGVSHFL¿FUHJXODWLRQVFRQcerning the carriage of perishable foods. The main aim of the study was to examine the drivers’ NQRZOHGJHRIWKHUHTXLUHPHQWVUHODWLQJWRWKHWUDQVSRUWRI frozen and perishable food. The study was conducted among drivers transporting food in the Lublin region. 0(7+2'2/2*< 'R\RXNQRZKRZDFDUIRUWKH transporting of food should be PDUNHG" 2. Do you know what document is QHFHVVDU\ZKLOHWUDQVSRUWLQJIRRG" 'R\RXNQRZZKHUHWKH$73UDWLQJSODTXHVKRXOGEHSODFHG" 'R\RXNQRZZKDWWKH¿UVWOHWWHUV RIWKH$73UDWLQJSODTXHDUH" 'R\RXNQRZWKHUXOHVRI³JRRG WUDQVSRUWSUDFWLFH´" <HV No I don’tknow <HV No I don’tknow <HV No I don’tknow <HV No I don’tknow <HV No I don’tknow The survey was conducted in three service companies operating in the transport of food. 7KHVWXG\XVHGDQDXWKRULDOTXHVWLRQQDLUHZLWKEDVLF information about the respondents (age, years of work in 5(68/76 WKHSURIHVVLRQDVDGULYHUHWFDQGRWKHUVSHFL¿FTXHVWLRQV $QDQRQ\PRXVTXHVWLRQQDLUHVKHHWZDVSUHSDUHGLQWKH'Hpartment of Technology Fundamentals. The survey included 7KHVXUYH\ZDVFDUULHGRXWDPRQJGULYHUVEHWZHHQ WKHIROORZLQJTXHVWLRQV WKHDJHVRIWRZKRKDYHEHHQZRUNLQJLQWKHSURfession of driver from 2 to 22 years and have experience 48(67,211$,5(6+((7 LQWKHWUDQVSRUWRIIRRGIURP\HDUWR\HDUV,QIRUmation concerning the type of transport used is shown Please kindly complete a survey, which will be used LQ)LJXUHDQGWKHZRUNH[SHULHQFHLQWKHWUDQVSRUWRI to check the drivers’ knowledge about the knowledge IRRGLQ)LJXUH +$/,1$3$:/$.3,2750$.6<0-$&(.6.:$5&= $SSUR[LPDWHO\RIWKHVXUYH\HGGULYHUVKDYHKDG D\HDURUORQJHUZRUNH[SHULHQFHLQWKHWUDQVSRUWRIIRRG UHVSRQGHQWVIURPDOOWKHPHDQVRIWUDQVSRUWRISHULVKDEOHIRRGVXVHGPHFKDQLFDOO\UHIULJHUDWHGHTXLSPHQW Twenty of all the tested drivers declared that they always have the information as to what kind of food is transported E\WKHP)LJXUHEXWRQO\RIGULYHUVNQRZWKHUXOHV RI³JRRGWUDQVSRUWSUDFWLFH´)LJXUH 2YHURIWKHGULYHUVFDQWHOOZKDWWKHUHTXLUHGWHPperature for the transport of food is. Similarly, the drivers are aware of the time limit, depending on the types of transSRUWHGIRRG$OPRVWDOORIWKHUHVSRQGHQWVNQRZZKHUHWKH $73UDWLQJSODTXHVKRXOGEHSODFHGDQGKRZDFDUVKRXOG be properly marked for the transporting of food. $PRQJWKHVXUYH\HGGULYHUVWKHUHZHUHPDLQO\WKH FDUULHUVRI¿VKDQGIUR]HQRUGHHSIUR]HQSURGXFWV5HTXLUHPHQWVUHODWHGWRWKHDUFKLYLQJRIVKLSSLQJGRFXPHQWDtion, registration and cyclic temperature control in vehicles were met. The problem to which the attention was drawn by the driver was associated with increases in the time of XQORDGLQJRIWKHJRRGV7KHFRQVHTXHQFHRIWKDWVLWXDtion may be a raise of the temperature in the vehicle.This situation is usually caused by the lack of assistance from another person (assistant driver, handling assistant at the FXVWRPHU7KHUHIRUHWKHXQORDGLQJWLPHPD\EHORQJHU due to self-unloading. C B 9% 4% CONCLUSIONS $IRRGFDUULHUVKRXOGUHPHPEHUWKDWKHLVDOVRDFRQsumer. On his knowledge of the procedures followed for the WUDQVSRUWRISHULVKDEOHSURGXFWVWKHLUTXDOLW\GHSHQGV7KH conducted surveys have shown that the examined carriers DUHFRPSHWHQWDVWRWKHUHTXLUHPHQWVIRUWKHWUDQVSRUWRI deep-frozen and frozen food products. D 4% A 9% B 13% C 74% A 87% Fig. 5. $UH\RXDOZD\VLQIRUPHGRQZKDWNLQGRISURGXFWV\RX WUDQVSRUW"$±<HV%±1R&±,GRQ¶WNQRZ A 38% C 46% Fig. 3. ,QIRUPDWLRQDERXWWKHYHKLFOHNLQGXVHG$±LQVXODWHG Fig. 3. Information about the vehicle kind used: HTXLSPHQW%±UHIULJHUDWHGHTXLSPHQW&±PHFKDQLFDOO\UHIULJHUDWHGHTXLSPHQW'±RWKHU A 4% B 9% B 15% Fig. 6. 'R\RXNQRZWKHUXOHVRI³JRRGWUDQVSRUWSUDFWLFH´" $±<HV%±1R&±,GRQ¶WNQRZ C 9% 5()5(5(1&(6 $73$JUHHPHQWYDOLGIURP>RQOLQHDFFHVV@ KWWSZZZXQHFHRUJ¿OHDGPLQ'$0WUDQVPDLQZS ZSGRF$73BHSGI D $73$JUHHPHQWYDOLGIURP>RQOLQHDFFHVV@ 78% KWWSZZZXQHFHRUJ¿OHDGPLQ'$0WUDQVGRF ZS$73BHSGI $73+DQGERRN>RQOLQHDFFHVV@KWWSZZZXQHFHRUJ¿OHFig. 4. 7KHH[SHULHQFHLQ\HDUVRIZRUNLQSHULVKDEOHIRRGVWXII DGPLQ'$0WUDQVGRFZS+DQGERRNHSGI Fig. 4. The experience (in years) of work in YHKLFOHWUDQVSRUW$±EHORZ\HDU%±\HDUV&±\HDUV %ĊF]NRZVND6*UDEDUHN,&KRURPDĔVNL: '±\HDUVDQGPRUH Modelowanie ryzyka w drogowym transporcie towarów 9(+,&/(75$16325725*$1,=$7,212))22'5(48,5,1*5()5,*(5$7,21 QLHEH]SLHF]Q\FK]XZ]JOĊGQLHQLHPF]\QQLNDOXG]NLHJR (UJRQRPLDZZDUXQNDFKJRVSRGDUNLRSDUWHMQDZLHG]\ 5HGDNFMD=áRZRG]NL02JLĔVND+-XOLV]HZVNL7 3DZODN+.RPLWHW(UJRQRPLL3$1.UDNyZ/XEOLQ %LHĔF]DN.=ZLHU]\FNL:6DPRFKRG\FKáRGQLF]HZWUDQVSRUFLHĪ\ZQRĞFL6\VWKHUP3R]QDĔ &HQWUDOQ\2ĞURGHN&KáRGQLFWZD±]DNUHVEDGDĔ$73 >RQOLQHDFFHVV@KWWSZZZFRFKSO%DGDQLD$73EHQ &RPSHWHQW$XWKRULWLHVDQG7HVW6WDWLRQV/LVW>RQOLQH DFFHVV@ KWWSZZZXQHFHRUJ¿OHDGPLQ'$0WUDQV PDLQZSWHVWVWDWLRQVSGI 8. .ZDĞQLRZVNL6=DVDG\GREUXXU]ąG]HĔFKáRGniczych i grzewczych do nadwozi izotermicznych. w.: 3RMD]G\L]RWHUPLF]QHLFKáRGQLF]H2¿F\QD:\GDZQLF]D 3ROLWHFKQLNL:URFáDZVNLHM:URFáDZ 9. àDVNL03DOXFK6 Transport drogowy osób LU]HF]\*UXSD,0$*(:DUV]DZD 2ĞZLDGF]HQLHRSU]\VWąSLHQLXGRXPRZ\RPLĊG]\QDURGRZ\FKSU]HZR]DFKV]\ENRSVXMąF\FKVLĊDUW\NXáyZ Ī\ZQRĞFLRZ\FKLRVSHFMDOQ\FKĞURGNDFKWUDQVSRUWX SU]H]QDF]RQ\FKGRW\FKSU]HZR]yZ$73']8 QUSR]SDĨG]LHUQLND>RQOLQHDFFHVV@ KWWSLVDSVHMPJRYSO'RZQORDG"LG :'8 W\SH 3URFKRZVNL/ĩXFKRZVNL$6DPRFKRG\FLĊĪDURZHLDXWREXV\:\GDZQLFWZD.RPXQLNDFMLLàąF]QRĞFL:DUV]DZD Rydzkowski W., Wojewódzka-Król K. 2005: Transport. Wydawnictwo Naukowe PWN, Warszawa. Steindel M., Schnotale J. 2008:0URĪRQDĪ\ZQRĞüLMHM WUDQVSRUW]JRGQLH]SU]HSLVDPL8QLL(XURSHMVNLHM6DPRFKRGRZ\WUDQVSRUWFKáRGQLF]\'RGDWHNPLHVLĊF]QLND &KáRGQLFWZR.OLPDW\]DFMD(XUR0HGLD:DUV]DZD 8VWDZDRWUDQVSRUFLHGURJRZ\P']81U SR]]GQLDZU]HĞQLDU>RQOLQHDFFHVV@KWWS LVDSVHMPJRYSO'RZQORDG"LG :'8W\ SH 8VWDZDRWUDQVSRUFLHGURJRZ\P']8SR] ]GQLDSDĨG]LHUQLNDU>RQOLQHDFFHVV@KWWSLVDS VHMPJRYSO'RZQORDG"LG :'8W\SH =ZLHU]\FNL : %LHĔF]DN . 5RFKDWND 7 6WDchowiak A., Tyczewski P. 2008: %DGDQLDSRMD]GyZ FKáRGQLF]\FKRUD]NRQWURODWHPSHUDWXU\ZáDGRZQL6DPRFKRGRZ\WUDQVSRUWFKáRGQLF]\'RGDWHNPLHVLĊF]QLND &KáRGQLFWZR.OLPDW\]DFMD(XUR0HGLD:DUV]DZD 25*$1,=$&-$75$16325786$02&+2'2:(*2 ĩ<:12ĝ&,:<0$*$-Ą&(-&+à2'=(1,$ Streszczenie. :DUW\NXOH]DSUH]HQWRZDQRRSLVZ\PDJDĔSUDZQ\FK]ZLą]DQ\FK]WUDQVSRUWHPĪ\ZQRĞFLZ\PDJDMąFHMFKáRG]HQLD3U]HSURZDG]RQRDQNLHWĊZĞUyGNLHURZFyZ]ZLą]DQ\FK ]WDNLPURG]DMHPWUDQVSRUW$QNLHWDPLDáDQDFHOXVSUDZG]HQLH VWDQXZLHG]\NLHURZFyZZ]DNUHVLHSU]HZR]XĪ\ZQRĞFLV]\ENRSVXMąFHMVLĊNWyUDZ\PDJDFKáRG]HQLD 6áRZDNOXF]RZHDUW\NXá\Ī\ZQRĞFLRZHWUDQVSRUWVDPRFKRGRwy, regulacja prawna V\VWHP ZDV GHYHORSHG IRU G\QDPLF RVFLOODWLRQV TXHQFKLQJ WLRQVWRWKHEDVHRIWKHPDFKLQH$QDQDO\VLVZDVSH RVFLOODWLRQV TXHQFKLQJ 7KH PDWKHPDWLFDO TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4,VHTXHQFH 143–150 ZDV TXHQFKHU 7KH SDUDP ZRUNLQJ HTX WLRQVTXHQFKLQJ TXHQFKHU G\QDPLF RVFLOODWLRQV K The Dynamic Vibrations Hydraulic Quencher Leonid Pelevin, Mykola Karpenko QLTXH ZKLFK LV Kyiv National University of Construction Architecture HTXLSSHGand E\ DFWLYH DFWLRQ HQJLQHV DQG XVHG IRU Povitroflotskyy Prosp., 31, Kyiv, Ukraine, 03680, e-mail: [email protected] Received December 01.2014; accepted December 17.2014 Summary. $ UHYLHZ DQG DQDO\VLV ZHUH FDUULHG RXW RI WKH GHYHORSHGK\GUDXOLFV\VWHPIRUTXHQFKLQJG\QDPLFRVFLOOations. The mathematical model was made for determining the time delay in operation of the hydraulic system for dyQDPLFTXHQFKLQJRIRVFLOODWLRQV $FDOFXODWLRQZDVPDGHRI soil cleavage period and operation time delay of dynamic RVFLOODWLRQVTXHQFher, from which it is possible in theory to establish the ability of the hydraulic system for dynamic oscillaWLRQV TXHQFKLQJ WR RSHUDWH LQ WLPH 7KH K\Graulic V\VWHP ZDV GHYHORSHG IRU G\QDPLF RVFLOODWLRQV TXHQFKLQJ inside the working unit to prevent the transmission of vibraWLRQVWRWKHEDVHRIWKHPDFKLQH$QDQDO\VLVZDVSHrformed of the damper’s means and the method of dynamic damping on which the hydraulic system was developed for dynamic RVFLOODWLRQV TXHQFKLQJ 7KH PDWKHPDWLFDO VHTXHQFH ZDV built for the determination of operation time delay of the TXHQFKHU 7KH SDUDPeters have allowed to construct the experimental model of hydraulic system for dynamic oscillaWLRQVTXHQFKLQJ Key words: TXHQFKHU G\QDPLF RVFLOODWLRQV Kydraulic system, time lag response, soil cleavage period. $ UHYLHZ DQG DQDO\VLV ZHUH FDUULHG RXW RI WKH INTRODUCTION GHYHORSHGK\GUDXOLFV\VWHPIRUTXHQFKLQJG\QDPLFRVFLOOamatical model was made for determining construction often works forthat theThe time delay in operation of theincludes hydraulic system dyQDPLFTXHQFKLQJRIRVFLOODWLRQV $FDOFXODWLRQZDVPDGHRI cannot be performed by conventional machines. age period operationtechQLTXH time delay of dynamic In this case, usingand a special ZKLFK LV RVFLOODWLRQVTXHQF er, from which it is possible in theory to HTXLSSHG E\ DFWLYH DFWLRQ HQJLQHV DQG XVHG IRU establish the ability of the hydraulic system for dynamic groundWLRQV operations canWRbe consider as a7KH solution. TXHQFKLQJ RSHUDWH LQ WLPH K\Graulic One of the disadvantages of this special techV\VWHP ZDV GHYHORSHG IRU G\QDPLF RVFLOODWLRQV TXHQFKLQJ inside the working unit to prevent the transmission of nology is the transmission of vibrations fromvibrathe WLRQVWRWKHEDVHRIWKHPDFKLQH$QDQDO\VLVZDVSH formed working body to base machine, accompanied by of the damper’s means and the method of dynamic damping the premature wearing down of the basic machine lic system was developed for dynamic parts whichTXHQFKLQJ do not participate in the ground RVFLOODWLRQV 7KH PDWKHPDWLFDO VHTXHQFHdeZDV built for the determination of operation time delay of the struction. TXHQFKHU 7KH SDUDP ters have allowed to construct the To solve the above-mentioned problem amoramic oscillaWL]DEOH HTXLSPHQW can be used to isolate vibraWLRQVTXHQFKLQJ tions caused TXHQFKHU by the working body movement G\QDPLF RVFLOODWLRQV K draulic from the base machine. *LYHQWKDWWKHFXUUHQWFXVKLRQLQJGHYLFHVDUH WL]DEOH HTXLSPHQW can be used to isolate vibracaused by thePRGHO working body movement –tions $ PDWKHPDWLFDO IRU GHWHUPLQLQJ WKH from the base machine. *LYHQWKDWWKHFXUUHQWFXVKLRQLQJGHYLFHVDUH TXHQF –not$ effective enough, there is demand for the construction of a new hydraulic system for dynamic oscillations TXHQFKLQJ DV ZHOO DV mathematical model for the determination of the main characteristics of the new system, namely: determining the time delay in the operation of the hydraulic system for dynamic oscillations TXHQFKLQJ, its evaluation, timeliness, triggering 7+(0$,10$7(5,$/ of specified dynamic fluctuations. the vibration transmitted to ZRUNLQJ HTXLSPHQW %DVLFDOO\ 385326(2):25. chines with d QDPLFDFWLYHZRUNLQJWRROV$VD result of work, theUHVXOWV vibr RI WKH dynamic analysis %DVHG RQ WKH toofthe machine and destruc the method andcause vibration cushioning devices transmit the work aimed to develop: body – $ PDWKHPDWLFDO PRGHO IRU GHWHUPLQLQJ WKH elements time delay in the operation of the hydraulic tions transmitted to the base machine. The main system for dynamic oscillations TXHQFhing; method of vibration damping is called – $ hydraulic construction developed by the of dynamic viEUDWLRQGDPSLQJ> authors for extinguishing dynamic oscillations that arise inside the working part in order to based on make their transmission to the base machine devices to change the impossible. given object. The LFTXHQFKHULV based on putting out the force transmitted to the REMHFW 7KLV G\QDPLF TXHQFK 7+(0$,10$7(5,$/ other method of reducing vibration, characterized by impos In engineering it is often necessary to damp linka its the vibration transmitted to the machine from ZRUNLQJ HTXLSPHQW %DVLFDOO\, it concerns mamchines with ZKHQ MRLQLQJ D G\QDPLF TXHQFKHU dyQDPLFDFWLYHZRUNLQJWRROV$VD be achieved by the vibrations redistrib can be transmitted result of work, HQHUJ\IURPWKHREMHFWWRWKHTXHQFKHUDQGLQWKH to the machine and cause destruction. To prevent > REMHFW 7KLV m ZK be achieved HQHUJ\IURP direction of fluctuations by changing TXHQFKHU RY excitation by erties of the tacha TXHQFKHUV $ press harmo fluctu range the sec in attaching the object called RI WKH G\QDP elastic ZDVSH 7+(0$,10$7(5,$/ VHTXHQFH ZDV HTXLSPHQW %DVLFDOO\/(21,'3(/(9,10<.2/$.$53(1.2 chines with dyQDPLFDFWLYHZRUNLQJWRROV$VD vibration in the SDUWV ZKHUH WKH TXHQFKHU LV IDstened. Often it may be associated even with the result of work, the vibrations can be transmitted deterioration of the object’s vibration in the other to the machine and cause destruction. To prevent less appropriate places. transmitting the vibrations from the working body to the base machine the so-called springy elements are used, which try to put out the vibrations transmitted to the base machine. The main method of vibration damping is called – a method of dynamic viEUDWLRQGDPSLQJ>, , , ]. The method of dynamic vibration damping is based on the application of additional protective devices to change the vibration properties in a given object. The work of the dynamLFTXHQFKHULV based on putting out the force transmitted to the Fig. 1. The overall look of shock absorbing passive elements: ɚ – VSULQJRIYHKLFOH, b – spring REMHFW 7KLV G\QDPLF TXHQFKing differs from another method of reducing vibration, characterized by imposition of the additional kinematic object linkages, such as fixing some of its points [2, ]. '\QDPLF TXHQFKHU FDQ EH FRQVWUXFWLYHO\ LmChanging the vibrating condition of the base SOHPHQWHGEDVHGRQWKHSDVVLYHHOHPHQWV)LJ machine ZKHQ MRLQLQJ D G\QDPLF TXHQFKHU can PDVVHV VSULQJV VKRFN DEVRUEHUV GDPSHUV DQG be achieved by the redistribution of vibrational the active ones, which have their own power HQHUJ\IURPWKHREMHFWWRWKHTXHQFKHUDQGLQWKH sources. direction of the increasing energy dissipation In the last case we are talking about the use of fluctuations >, 20]. The former is implemented automatic control units that use elements driven by changing the system’s settings of the objectby an electric, hydraulic or pneumatic system. TXHQFKHU RYHU WKH IUHTXHQFLHV RI WKH YLEUDWLRQ Their combination of passive devices is successexcitation by correcting the elastic-inertial propful, an example of which is the shock absorber erties of the system. In this case, the devices atshown in Fig. 2. tachable to the object are called inertial dynamic TXHQFKHUV $Q LQHUWLDO TXHQFKHU LV XVHG WR VXppress harmonic mono or narrowband random fluctuations. During a vibration’s load of the wider frequency range the second method is preferred. It is based on increasing dissipative properties of the system by attaching additional specific damping elements to the object. DynaPLFTXHQFKHUGLVVLSDWLYHW\SHVDUH Fig. 2. *HQHUDOYLHZRIWKHVKRFNDEVRUEHU called vibration absorbers >]. The combined ways The utilization of the active elements expands RI WKH G\QDPLF TXHQFKLQJ XVLQJ ERWK FRUUHFWLRQ the possibilities of dynamic vibration suppreselastic-inertial and dissipative properties of the system system are are also also possible. possible. InIn such such cases cases we we talk talk sion, sion, because because it allows to conduct continuous DGMXVWPHQWRIWKHSDUDPHWHUVRIG\QDPLFTXHQF DERXWWKHG\QDPLFTXHQFKHr DERXWWKHG\QDPLFTXHQFKH of friction [7, ]. ]. DGMXVWPHQWRIWKHSDUDPHWHUVRIG\QDPLFTXHQFh:KHQLPSOHPHQWLQJG\QDPLFTXHQFKHUFRXn:KHQLPSOHPHQWLQJG\QDPLFTXHQFKHUFRXn- ererasasaafunction functionofofexcitation excitationacting, acting,and andthus thus to teraction fluctuations the object is affected fected by by SHUIRUP SHUIRUPTXHQFKLQJ TXHQFKLQJLQ LQFRQGLWLRQV FRQGLWLRQVRI RIFKDQJLQJ FKDQJLQJ reactions that are passed to it from the attached attached YLEUDWLRQORDGV$VLPLODU YLEUDWLRQORDGV$VLPLODUresult can be achieved bodies. For this reason, considerable bleeffects effectswith with sometimes sometimes by by means of passive devices with limited amplitudes of the masses adjusted can canbe be nonl nonlinear characteristics. DFKLHYHGRQO\E\ODUJHPDVVPRPHQWRILQHUWLD DFKLHYHGRQO\E\ODUJHPDVVPRPHQWRILQHUWLD Shock absorber is the device which converts of connected bodies, typicalO\ O\§§ RI RIWKH WKH mechanical mechanical energy energy ininto thermal and is used for reduced mDVVPRPHQWRILQHUWLDSULPDU\V\VWHP DVVPRPHQWRILQHUWLDSULPDU\V\VWHP vibration vibration damping damping and shock absorption. It UDPH 6KRFN with an appropriate appropriateform formofofvibrations vibrationswithin withinthe the bum bumps acting on the casing (fUDPH 6KRFNDDbIUHTXHQF\TXHQFKLQJZKLFKLVSHUformed, IUHTXHQF\TXHQFKLQJZKLFKLVSHU ,respecrespec- sorbers sorbersare areused usedininconjunction conjunctionwith withelastic elasticelelements: WLYHO\>]. WLYHO\> ments:springs springs (ofDYHKLFOH DYHKLFOH, pillows, etc. +\GUDXOLF 7\SLFDOO\ 7\SLFDOO\ DD G\QDPLF G\QDPLF TXHQFKHU TXHQFKHU LV LV XVHG XVHG WR WR +\GUDXOLFVKRFN VKRFNDEVRUEHUV DEVRUEHUV have become the achieve achieveaalocal localeffect: effect:aareduction reductionofofthe theobject’s object’s most most commonly commonly used. used. InIn a hydraulic shock abvibration in the SDUWV SDUWVZKHUH ZKHUHWKH WKHTXHQFKHU TXHQFKHULV LVIDsIDs- sorber sorberthe theresistance resistanceforce forcedepends dependson onthe thespeed speed tened. tened. Often Often itit may may be be associated associated even even with with the the ofof rod movement. Oil is the working medium. deterioration of the object’s vibration tionininthe theother other The Theprinciple principleofofoperation operationofofthe theshock shockabsorber absorber ZRUNLQJ QV K draulic works that achines. XH ZKLFK LV QG XVHG IRU a solution. pecial techns from the panied by sic machine ground de- blem amorolate vibramovement GHYLFHVDUH and for the for dyO DV mathethe main mely: detertion of the oscillations , triggering analysis ing devices IUHTXHQF\TXHQFKLQJZKLFKLVSHU WLYHO\> 7\SLFDOO\ D G\QDPLF TXHQFKHU LV XVHG WR +\GUDXOLF sorber the res of The principle is based on piston shock hol verting mecha tion damping K\GUDXOLF HOH pos ZRUN DQG FDQ tude. )LJV contains an crease the res through the c ing, DFFRUGLQJ /LTXLG hy signed based dampers. blan teristics of sy ticular, the t system perfo various point OLFVKRFNVV transients LV XVHG WR HQFKHU LV IDseven with the n in the other UXFWLYHO\ LmPHQWV)LJ GDPSHUV DQG own power out the use of ments driven ic system. is successock absorber EHU ments expands suppres- UDPH 6KRFN D DYHKLFOH +\GUDXOLF VKRFN DEVRUEHUV 7+('<1$0,&9,%5$7,216+<'5$8/,&48(1&+(5 sorber the resistance force depends on the speed of rod movement. Oil is the working medium. The principle of operation of the shock absorber is based on the reciprocating movement of the piston shock absorber, which through a small hole puts oil from one chamber to another, converting mechanical energy into the heat energy. Today, the generally used solutions for vibration damping devices are those which utilize the K\GUDXOLF HOHPHQWV +\GUDXOLF GDPSHUV DV Rpposed to friction ones, have the longer duration of ZRUN DQG FDQ TXHQFK a small oscillation amplitude. )LJVhows the design of the damper, which contains an adjusting screw. This allows to increase the resistance value of the OLTXLG IORZLQJ through the channel and thus control the damping, DFFRUGLQJWR>, ]. SRZHUVRXUFHFKDUDFWHULVWLFV>]. Total delay time of the system’s response can be defined as a first approximation by the formula: td 'V V , Qh Qb Nowadays, the most promising system is the hydraulic vibration damping one, which is designed based on hydraulic shock absorbers and dampers. In the design of hydraulic systems for blanking the oscillations the dynamic characteristics of systems must be considered, in particular, the transfer speed signals and the total system performance, pressure fluctuations in various points of the system (including hydrauOLFVKRFNVVXsWDLQDELOLW\DQGTXDOLW\RIV\VWHP transients [, ]. Movement of actuating mechanism always Movement of actuating mechanism always comes with some delay in relation to the input o the input signal. The identification of the delay’s amount signal. The identification of the delay’s amount allows to determine the system’s dynamic, the ic, the total response time and the need to introduce total response time and the need to introduce appropriate units to compensate for the delay appropriate units to compensate for the delay calculation, deSHQGLQJ RQ WKH IUHTXHQF\ control SHQGLQJ RQ WKH IUHTXHQF\ control signal and set according to the corresponding corresponding pulses [8, , 9]. To perform the system’s calculations it is necTo perform the system’s calculations it is necessary to know the basic system parameters, inessary to know the basic system parameters, including the size of pipelines, hydraulic and mecluding the size of pipelines, hydraulic and mechanical resistance properties of the working chanical resistance properties of the working fluid and hydraulic machines as well as hydraulic hydraulic SRZHUVRXUFHFKDUDFWHULVWLFV>]. SRZHUVRXUFHFKDUDFWHULVWLFV> Total delay time of the system’s response Total delay time of the system’s response can be defined as a first approximation by the can be defined as a first approximation by the ''V V , where: ǻV – UHGXFHVWKHYROXPHRIOLTXLGLQWKHV\VWHP by increasing the pressure on the value of ǻɪ, m, V – volume of fluid reTXLUHG WR ILOO additional volumes in the system, m, Qb – leak in the system for working pressure, m/s, Qh – the nominal flow rate in the system, m/sǤ In this case Qh and V are determined from the formula: N h , Ph Qh Fig. 3. /LTXLGGDPSHU’s adjusting screw where: Nh – hydraulic drive power, kW, Ph – nominal pressure of hydraulic system MPa. 7KH YROXPH RI WKH IOXLG UHTXLUHG WR ILOO WKH additional volume in the system V LVRI the total volume of fluid in the hydraulic system V, m. The total volume of fluid in the hydraulic system is calculated as follows: V Vc Ve , SSD 2 L , where: where: L L – total length of pipelines, m, D – internal diameter hy ameter hydraulic of the pipeline, m2, calculated by the formula: by the formula: D Qh W , where where: W VSHHG OLTXLG W – VSHHG OLTXLG in the hydraulic system at a prescribed pressure prescribed pressure, m/s. V V $WILUVWDSSURDFKLQJWKHGHOD\RSHUDWLRQRIWKH $WILUVWDSSURDFKLQJWKHGHOD\RSHUDWLRQRIWKH (T ZHREWDLQWKHHTXDWLRQ (T ZHREWDLQWKHHTXDWLRQ ' $WILUVWD system (T where P the coefficie WKHHTXDWLRQ where j measuremen in the sys YDOXHRIǻ where: Ve – the amount of hydraulic fluid that is eTXLSSHG LQ K\GUDXOLF V\VWHP, m, Vc – the amount of hydraulic fluid that is in the pipeline hydraulic system (TZKLFKLVFDOFXODWHGE\ WKHHTXDWLRQ Vc VSHHG prescribed p where į depends on section inn line ’s response tion by the VSHHG OLTXLG WKHV\VWHP e of ǻɪ, m, O ditional k in the systhe nominal $WILUVWDSSURDFKLQJWKHGHOD\RSHUDWLRQRIWKH system (T ZHREWDLQWKHHTXDWLRQ 'V V . Qb Qh 2Qh In the view of that: Qb Kb P , ed from the where: P – operating pressure in the system, MPa, Kb – the coefficient of leakage of liTuid, received from WKHHTXDWLRQ Kb nominal G WR ILOO WKH VRI aulic system he hydraulic uid that is – the the pipeline DOFXODWHGE\ j Nh P2 , short and rigid as possible; 2. Volume losses should be lowered to a minimum; Pump capacity should be significant. In general, the performance of the dynamic oscillations Tuencher is determined for each particular system, provided that the signal can be transmitted with a specific delay, but performance must be such as not to violate the stability of the whole circuit >]. To achieve the stated conditions, we need to find out the time of soil cleavage, i.e. the time at which the dynamic ripper makes one complete cycle of the movement Tc [], which is inverse WR WKH DYHUDJH RVFLOODWLRQ IUHTXHQF\ PD[LPD RI cutting the soil, and is given by: s, nm ( n0 s, Tɫ nm where: j – coefficient of the changes in the units of measurement of l/min in m/s and 0.278 matter. In this case, reduction in WKHYROXPHRIOLTXLG in the system while increasing pressure by the YDOXHRIǻp is calculated as follows: Ww s H nm Finally, after GHWHUPLQLQJ HTXDWLRQV ZLOO JHW GHWHUPLQLQJ HTXDWLRQV ZLOO JHW (T simplified the delay triggering and performance Determine the relationship (T between formance the PLGGOHIUHTXHQF\RVFLOODWLRQFX will look like: the PLGGOHIUHTXHQF\RVFLOODWLRQFXtting forces: GGSSLLVV . Q h Kb P n0 nm s, 2 n0 s. From the dependence it is obvious that to reis obvious that to reduce the time delay triggering it is necessary: sary: Working channels and pipelines should be as orking channels and pipelines should be as The initial data of the hydraulic system for short and rigid as possible; blan N: blanking dynamic oscillations: N N:, P 2. Volume losses should be lowered to a mini0 PV 0 PV mum; T T where: n0 blan 0 H – WKH DYHUDJH RVFLOODWLRQ IUHTXHQF\ RI FXtting soil, m - loosening depth, 'V GSL , Ww – speed of the working body. Let us etermine the dependence of the time of where: delay of triggeriQJ TXHQFKHU G\QDPLF IOXctuations į – coefficient of decrease of the liTuid, which of hydraulic parameters [2, ]. depends on the operating pressure; S – crossSuppose that a dynamic body is working in section inner diameter hydraulic of the piperocky soil at the depth of H , m, in which line, m2. case the rate of dynamic body is Moreover, S is calculated as follows: Ww= 2 m/s. First of all determine the time of soil cleavage SD 22 age: S SD . ɫ Tɫ 0, 09 s. td /(21,'3(/(9,10<.2/$.$53(1.2 V V td that the syste TXHQFKLQJ VS device’s trig the %\FKDQJL tem G\QDPLF the supply reduction of RVFLOODWLRQ FX PLGGOH IUHTXHQF\ sary: should be as ed to a mini- dynamic for each parnal can be but perfore the stability , we need to the time at one complete is inverse \ PD[LPD RI F\ RI FXtting the time of F IOX tuations s working in m, in which FLHQF\RIG\QDPLFTXHQFKLQJ 7+('<1$0,&9,%5$7,216+<'5$8/,&48(1&+(5 2 The initial data of for the hydraulic system blanking dynamic oscillations: Nh N:, Ph 0Pa, P MPa, L m, W PV hydraulic system for Let us carry out the calculation: 0 PV Qh Vcon. which is based on the use of the above- N:, m/s, D mm, s, 2 m, V m, m, 2 S m2, m , ( VXSSO\V\VWHP)LJDQGRQ UHGXFWLRQRIIOXLG)LJ 7KH K\GUDXOLF TXHQFKHU G\QDPLF IOXFWX Kb td kW/MPa2, 2 , s. kW/MPa , From the resulting example we can conclude that the system performance satisfies oscillation s. TXHQFKLQJ VSHFLILHG condition of this dynamic device’s triggering delay is lower WKDQ RI the soil cleavage time. From the resulting example we can syscon%\FKDQJLQJthe parameters of hydraulic clude that the system IOXFWXDWLRQV performance satisfies tem G\QDPLF TXHQFKLQJ – namely RVFLOODWLRQ TXHQFKLQJ VSHFLILHG condition the supply of hydraulic fluid in the system andof reduction of fluid volume ratio, and substituting them in the present calculation, we obtain the dependence of the delay in the operation of the hydraulic system dyQDPLF TXHQFKing oscillation VSHHG RQ the hydraulic fluid supply system (Fig. DQGRQ WKH coefficient reduction of fluid (Fig. . 7KH K\GUDXOLF TXHQFKHU G\QDPLF IOXFWXations were developed to improve the efficiency of dyQDPLF TXHQFKLQJ of oscillations, which is based on the use of the above-mentioned system. The dynamic oscillations TXHQFKHU(Fig. works as follows >0]. Vibrations that are transmitted from the working body to the base machine are blanked with the help of dynamic fluctuaWLRQV TXHQFKHU 1 $W active work, the oscillatory body rod 3 tries to reproduce vibrational motion in the housing 2. +RZHYHU ZKHQ the direction of the vibrational Fig. 4. *UDSK RI WKH WLPH GHOD\ dependence during the operation of hydraulic blanking dynamic fluctuations on hydraulic fluid supply. QDPLF TXHQFK VSHHG RQ DQGRQ WKH 7KH K\GUDXOLF TXHQFKHU G\QDPLF IOXFWX QDPLF TXHQFKLQJ TXHQFKHU > switch WKH Fig. 5. *UDSK RI WKH WLPH GHOD\ dependence signal ceases to be submitted normally during the operation of hydraulic blanking dycontact namic fluctuations on the fluid amount reducWLRQV TXHQFKHU $W ope tion coefficient active work, the oscillatory body rod 3 tries to allowing the hydra reproduce po vibrational motion in LQ theWKH housing 2. additional WLRQV RI WKH OLTXLG SOXQJHU +RZHYHU direction of the vibrational cavity osci ZKHQ ODWLRQVthe TXHQFKHU motionof isreed directed, example, left by movemoval switch for$IWHUH[FOXVLRQRIUHOD\ ment of fluid through the holes throttled 6 plungco er 4, 8 rods switch blocking valve and plunger valve 11 tromagnetic distributor are moving blocking right. Thus blocking rods 8 pos LRQWKHQIHHGDGGLWLRQDOSRUWLRQRIWKHOLTXLG press valve rods washer 7. Meanwhile, blockWR WKHthe TXHQFKHU G\QDPLF IOXFWX ing plunger valve 11 presses the plunger 4, block+\GUDXOLFIOXLGLVIHGWRWKHTXHQFKHUWKURXJKWKH ing throttling holes 6VRWKDWWKHOLTXLGEHJLQVWR pipe flow through passage the holes 12, which extin%HFDXVHRIWKHG\QDPLFIOXFWXDWLRQVTXHQFKHU 1guish the movement of the rod 3 left. Once the plunger 4 reaches the reed switch 14, the magnetchine, during ic field of the magnet constant step 5 shut reed 7KHVLJQDOZLOOJRWRG +HLQWXUQWKHGHOD\UHOD\H[FOXVLRQ $IWHUWKDW LRQWKH WR WKH TXH +\GUDXOLFIO %HFDXVH 1 chine, durin %DVHGRQ 2. %DVHG R RQTXHQF DQG VXSS DQGRQ WKH 7KH K\GUDXOLF TXHQFKHU G\QDPLF IOXFWX works as follows >]. OD TXHQFKHU QDPLF TXHQFKLQJ /(21,'3(/(9,10<.2/$.$53(1.2 reed switch 14, the magnetic field of the > TXHQFKHU LRQWKHQ WR WKH TXHQ +\GUDXOLFIOX WLRQV TXHQFKHU $W %HFDXVHR +RZHYHU ZKHQ WKH QDPLF TXHQFK %DVHGRQ VSHHG RQ DQGRQ WKH Fig. 6. 4XHQFKHU of dynamic fluctuations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ig. 7. The hydraulic circuit control in dynamic oscillations TXHQFKHU a and electrical circuit control distributor b right by moving the working fluid through the guish the movement of the rod 3 left. Once the Vibrations are switch transmitted the throttling magnet constant 5 shut reed contacts 14 holes 6,step 8, rods blocking valve and plunger 4 reachesthat the reed 14, the from magnetbody to constant the basestepmachine are 2.plunger (Fig. 7, valve bWKH 7KH VLJQDO WR GHWHQWLRQ 11 move left. JR Valve blocking 2. %DVHG RQ YDOXHV WKHZLOO icworking field of the magnet 5 shut reed plunger 11 presses washer 10 and valve blocking contacts 14 (Fig. 7, b7KHVLJQDOZLOOJRWRGeWLRQVTXHQFKHU $WDFWLYHZRUN +HLQ WKHGHOD\ UHOD\ H[FOXVLRQ rods 8 pressWXUQ plunger 4 blocking throttling hole 6. tention relay 22, which shut normally open con$VRQTXHQFKLQJFRHII D UHVXOW$IWHUWKDW WKH OLTXLG EHJLQV WR IORZ WKURXJK tact 23+HLQWXUQWKHGHOD\UHOD\H[FOXVLRQ passage 9 , putting the movement of FKDQJLQJ the rod 3 DQG VXSSO\ RI K\GUDXOLF IOXLG %\ is turned on$IWHUWKDW, delay relay exclusion 24 +RZHYHUZKHQWKH right. Once the plunger 4 moves away from the shuts contact 25, which starts the electromagnetic PDJQHWLF FRQWURO 7 reed switch 14 and the magnetic field of the FRQWURO 7KH HOHFWURPDJQHWLF FRQWURO 21 togmagnet constant step 5 stops toSXPS influence the reed gles the distributor 18 LQ WKH OHIW SRVLWLRQ +yOHIW SRVLWLRQ +\GUDXOLF $ QHZ GHVLJQ draulic pump 15 works through thewe variable tion, obtainorithe switch 14 (reed switch contacts open up 14WKH fice with check valve 26, whichoperation regulatesof the the signal ceases to be submitted normally to open supply of hydraulic fluid distributor 18 oscillation and presQDPLF TXHQFKing contact 23. This, in turn, relays switching delay sure line RQ 19 takes an additional portion the open up exclusion 24. It will work for a while, VSHHG supply of system IOXLG LQ WKH SOXQJHU FDYLW\ TXHQFKHU DQGRQ WKH coefficient reductionG\QDPLF of fluid allowing the hydraulic pump 15 to submit several SOXQJHU FDYLW\ G\QDPLF fluctuations 1 ([FHVV IOXLG IORZV RXW RI URGV additional porWLRQVTXHQFKHU RI WKH OLTXLG LQ WKHIOXFWX SOXQJHU WKHOLTXLGEHJLQVWRIORZWKURXJKSDVVDJHWKH ([FHVV IOXLG IORZV RI URGV TXHQFKHU G\QDPLFTXHQFKHU FDYLW\ RVFLOODWLRQV 1 through 7KH K\GUDXOLF G\QDPLF IOXFWXations cavity oscilODWLRQV TXHQFKHU 1-for-4RXW plunger re5()(5(1&(6 the drain line 20 and distributor to the tank of developed to improve the 18 efficiency of dymoval of reed switch 14$IWHUH[FOXVLRQRIUHOD\ hydraulic fluid 16. When plunger 3 movesistobased the QDPLF TXHQFKLQJ contact delay 24, the 25, 21 will control the elecright by moving the working fluid through . the tromagnetic switch distributor 18 in the far right throttling holes 6, 8, rods blocking valve and positLRQWKHQIHHGDGGLWLRQDOSRUWLRQRIWKHOLTXLG TXHQFKHU(Fig. 1$8 plunger valve 11> move left. Valve blocking WR WKH TXHQFKHU G\QDPLF IOXFWXations 1 end. +\GUDXOLFIOXLGLVIHGWRWKHTXHQFKHUWKURXJKWKH $V D UHVXOW WKH OLTXLG EHJLQV WRTXHQFKHU IORZ WKURXJK WLRQV $W 7(.$ %HFDXVHRIWKHG\QDPLFIOXFWXDWLRQVTXHQFKHU (QHUJ5ROQ2/3$1YRO (QHUJ5R J\ +DQ SUHG F IOXFWX . HU(Fig. om the workblanked with XHQFKHU $W tries to e housing 2. e vibrational eft by moveplungnger valve 11 ocking rods 8 , block, blockXLGEHJLQVWR which extineft. Once the , the magnetshut reed ZLOOJRWRGely open conH[FOXVLRQ sion 24 magnetic QWURO togSRVLWLRQ +yvariable oriregulates the and presortion of the KHU G\QDPLF RXW RI URGV QV through tank of moves to the through the ng valve and blocking alve blocking tling hole 6. IORZ WKURXJK of the rod 3 way from the field of the ence the reed WLRQV RI WKH OLTXLG LQ WKH SOXQJHU ODWLRQV TXHQFKHU $IWHUH[FOXVLRQRIUHOD\ QRVWURHQLH 7+('<1$0,&9,%5$7,216+<'5$8/,&48(1&+(5 sian. tromagnetic switch distributor 18 in the far right positLRQWKHQIHHGDGGLWLRQDOSRUWLRQRIWKHOLTXLG 8. Lewis (, Sterh H., 1966. +\GUDXOLF FRQWURO WR WKH TXHQFKHU G\QDPLF IOXFWXations 1 end. system. M.: Mashinostroenie, (in Russian. +\GUDXOLFIOXLGLVIHGWRWKHTXHQFKHUWKURXJKWKH 9. Nagorniy V., Denisov A., 1991. Devices of pipe 13. automation and hydro pneumatic. M.: Mashi%HFDXVHRIWKHG\QDPLFIOXFWXDWLRQVTXHQFKHU nostroenie, (in Russian. 1 reduces dynamic fluctuations in the base ma Patent Ukraine ʋ IURP0D\ (in chine, during the working bodies active action. Ukraine. Popov D., 1987. Dynamics and regulation of hydraulic and pneumatic systems. M.: Mashinostroenie, (in Russian. CONCLUSIONS Schokdemper, 2014 $YDLODEOH DW http://nl.wikipedia.org/wiki/Schokdemper, ac %DVHGRQWKHDQDO\VLVRIG\QDPLFFXVKLRning cessed 20 Jul. (in Nederlands. devices for vibration in the hydraulic system, Shorin V., 1980. (OLPLQDWLRQ RI IOXFWXDWLRQV LQ the mathematical model of the process of deair pipes. M.: Mashinostroenie, (in Russian. termining the delay time of their operation is Vetrov Ju., Vlasov V., 1995. Machines for exworked out, which allows to design these syscavation. Sample calculation: Teach. user.. – tems. .ȱ6'2 (in Russian. 2. %DVHG RQ WKH YDOXHV WKH dependency graphs Vilde Ⱥ., Cesnieks S., Rucins A., 2004. Miniare built of: time delay operation dependence misation of Soil Tillage. 7(.$ NRP 0RW (nof the hydraulic system dynamic oscillations HUJ5ROQ2/3$1YRO- RQTXHQFKLQJFRHIIicients of reduction of fluid Vilde Ⱥ., Rucins A., 2004. The Impact of Soil DQG VXSSO\ RI K\GUDXOLF IOXLG %\ FKDQJLQJ Physical and Mechanical Properties on Draft Rethese parameters the system was designed for sistance of Ploughs. 7(.$ NRP 0RW (QHUJ adjusting the hydraulic damping system dy5ROQ2/3$1YRO- namic oscillations. Vilde Ⱥ, 7DQDĞ W., 2005. Determination of the $ QHZ GHVLJQ was performed of hydraulic blanking of dynamic fluctuations with the soilfriction coefficient and specific adhesion. ability to change the filling parameters. 7(.$ NRP 0RW (QHUJ 5ROQ 2/ 3$1 YRO The design provides adjustable vibration base - machine for vibrations attachments. Walusiak S., DziubiĔski M., Pietrzyk W., 2005. $Q DQDO\VLV RI K\GUDXOLF EUDNLQJ V\stem reliability. 7(.$ NRP 0RW (QHUJ 5ROQ 2/ 5()(5(1&(6 3$1YRO- =DNKDUFKXN%, Telushkin V., 1987. %XOOGR]HU Bud'ko V., 2003. Dynamics and regulation and rippers. M.: Mashinostroenie, (in Rushidropnevmosystem.: K.1$8 (in Ukraine. sian. 2. Cândea I., Popescu S., 2003. Theoretical and 20. =LSNɿQ <D., 1977. Foundations of the theory of experimental study on soil vibrators used for the automatic systems. M.: Mashinostroenie, (in germinal layer preparation. 7(.$: kom. Mot. Russian. (QHUJ5ROQ2/3$1YRO- Chelomej V.N., 1981. Vibrations in TechnoloJ\ +DQGERRN LQ YROXPHV Red. Sovet: SUHG-M.: (in RusȽɂȾɊȺȼɅɂɑȿɋɄɂɃȽȺɋɂɌȿɅɖ (PWVHY Mashinostroenie, 7 mechanics.: sian. ȾɂɇȺɆɂɑȿɋɄɂɏɄɈɅȿȻȺɇɂəɏ ȽɂȾɊȺȼɅɂɑȿɋɄɂɃȽȺɋɂɌȿɅɖ (PWVHY B., 1987. Technical hydromechanics.: +ydraulic drive. ȾɂɇȺɆɂɑȿɋɄɂɏɄɈɅȿȻȺɇɂəɏ M.: Mashinostroenie, (in Russian. Ⱥɧɧɨɬɚɰɢɹ ɉɪɨɜɟɞɟɧ ɨɛɡɨɪ ɢ ɚɧɚɥɢɡ ɫɭɳɟɫɬɜɭɸɳɢɯ ɚɦɨɪɬɢɡɢɪɭɸɳɢɯ ɭɫɬɪɨɣɫɬɜ Gavrilenko B. Minin V., 1958. +ydraulic drive. ɉɪɨɜɟɞɟɧ ɨɛɡɨɪ ɢ ɝɚɲɟɧɢɹ ɚɧɚɥɢɡ ation of Ⱥɧɧɨɬɚɰɢɹ Ɋɚɫɫɦɨɬɪɟɧ ɦɟɬɨɞ ɞɢɧɚɦɢɱɟɫɤɨɝɨ : M.: Mashinostroenie, (in Russian. ɚɦɨɪɬɢɡɢɪɭɸɳɢɯ ɭɫɬɪɨɣɫɬɜ QRVWURHQLH (in ɫɭɳɟɫɬɜɭɸɳɢɯ ɤɨɥɟɛɚɧɢɣ ɋɨɫɬɚɜɥɟɧɚ ɦɚɬɟɦɚɬɢɱɟɫɤɚɹ ɦɨɞɟɥɶ Gijom M., ɦɟɬɨɞ ɡɚɩɚɡɞɵɜɚɧɢɹ ɞɢɧɚɦɢɱɟɫɤɨɝɨ ɝɚɲɟɧɢɹ 1964. Investigation and calculation of Ɋɚɫɫɦɨɬɪɟɧ ɨɩɪɟɞɟɥɟɧɢɹ ɜɪɟɦɟɧɢ ɫɪɚɛɚɬɵɜɚɧɢɹ hydraulic systems.-M.: MashiQRVWURHQLH (in ɤɨɥɟɛɚɧɢɣ ɋɨɫɬɚɜɥɟɧɚ ɦɚɬɟɦɚɬɢɱɟɫɤɚɹ ɦɨɞɟɥɶ draulic ɝɢɞɪɨɚɜɬɨɦɚɬɢɱɟɫɤɨɣ ɫɢɫɬɟɦɵ ɝɚɲɟɧɢɹ Russian. ɜɪɟɦɟɧɢ ɡɚɩɚɡɞɵɜɚɧɢɹ ɫɪɚɛɚɬɵɜɚɧɢɹ ɞɢɧɚɦɢɱɟɫɤɢɯ ɤɨɥɟɛɚɧɢɣ ɡɧɚɱɟɧɢɟ ɤɨɬɨɪɨɝɨ in Rus- ɨɩɪɟɞɟɥɟɧɢɹ 7. Korobochkin B., 1976. dynamics of hydraulic ɝɢɞɪɨɚɜɬɨɦɚɬɢɱɟɫɤɨɣ ɝɚɲɟɧɢɹ ɩɨɡɜɨɥɹɟɬ ɫɨɡɞɚɜɚɬɶ ɫɢɫɬɟɦɵ ɝɢɞɪɨɚɜɬɨɦɚ-ɬɢɱɟɫɤɢɟ ɤɨɥɟɛɚɧɢɣ ɡɧɚɱɟɧɢɟ ɤɨɬɨɪɨɝɨ machines. M.: Mashinostroenie, (in Rus- ɞɢɧɚɦɢɱɟɫɤɢɯ ɫɢɫɬɟɦɵ ɝɚɲɟɧɢɹ ɤɨɥɟɛɚɧɢɣ ɜɨɜɪɟɦɹ ( +\GUDXOLF FRQWURO ɩɨɡɜɨɥɹɟɬ ɝɢɞɪɨɚɜɬɨɦɚ ɬɢɱɟɫɤɢɟ sian. ɪɟɚɝɢɪɭɸɳɢɯɫɨɡɞɚɜɚɬɶ ɧɚ ɞɢɧɚɦɢɱɟɫɤɢɟ ɜɧɟɲɧɢɟ sian. ɝɚɲɟɧɢɹ ɤɨɥɟɛɚɧɢɣ ɜɨɜɪɟɦɹ ɜɨɡɦɭɳɟɧɢɹɉɪɨɜɟɞɟɧɪɚɫɱɟɬɩɟɪɢɨɞɚɫɤɚɥɵɜɚɧɢɹ 8. Lewis (, Sterh H., 1966. +\GUDXOLF FRQWURO ɫɢɫɬɟɦɵ ɪɟɚɝɢɪɭɸɳɢɯ ɧɚ ɞɢɧɚɦɢɱɟɫɤɢɟ ɜɧɟɲɧɢɟ ɝɪɭɧɬɚ ɩɪɢ ɪɚɛɨɬɟ ɪɵɯɥɢɬɟɥɹ ɢ ɜɪɟɦɟɧɢ ɜɨɡɦɭɳɟɧɢɹɉɪɨɜɟɞɟɧɪɚɫɱɟɬɩɟɪɢɨɞɚɫɤɚɥɵɜɚɧɢɹ ɡɚɩɚɡɞɵɜɚɧɢɹ ɫɪɚɛɚɬɵ ɜɚɧɢɹ ɝɚɫɢɬɟɥɹ ɝɪɭɧɬɚ ɩɪɢ ɪɚɛɨɬɟ ɪɵɯɥɢɬɟɥɹ ɢ ɜɪɟɦɟɧɢ ɞɢɧɚɦɢɱɟɫɤɢɯ ɤɨɥɟɛɚɧɢɣ ɧɚ ɨɫɧɨɜɟ ɤɨɬɨɪɵɯ ɡɚɩɚɡɞɵɜɚɧɢɹ ɫɪɚɛɚɬɵ ɜɚɧɢɹ ɝɚɫɢɬɟɥɹ ɭɫɬɚɧɚɜɥɢɜɚɟɬɫɹ ɫɩɨɫɨɛɧɨɫɬɶ ʋ IURP0D\ ɞɢɧɚɦɢɱɟɫɤɢɯ ɤɨɥɟɛɚɧɢɣ ɧɚ ɨɫɧɨɜɟ ɤɨɬɨɪɵɯ ɫɭɳɟɫɬɜɭɸɳ Ɋɚɫɫɦɨɬɪɟɧ ɤɨɥɟɛɚɧɢɣ ɨɩɪɟɞɟɥɟɧɢɹ ɝɢɞɪɨɚɜɬɨɦɚ ɞɢɧɚɦɢɱɟɫɤɢ ɩɨɡɜɨɥɹɟɬ ɫɢɫɬɟɦɵ ɪɟɚɝɢɪɭɸɳɢ ɜɨɡɦɭɳɟɧɢɹ ɝɪɭɧɬɚ ɩɪɢ ɡɚɩɚɡɞɵɜɚɧɢ ɞɢɧɚɦɢɱɟɫɤɢ ɭɫɬɚɧɚɜɥɢɜɚ ɝɢɞɪɨɚɜɬɨɦɚ ɦɢɱɟɫɤɢɯ ɨɛɟɫɩɟɱɢɜɚɹ ɤ ɛɚɡɨ ɝɢɞɪɨɚɜɬɨɦɚ ɦɢɱɟɫɤɢɯ ɤɨ ɨɪɝɚɧɟ ɞɥ ɤɨɥɟɛɚɧɢɣɤ Ʉɥɸɱɟɜɵɟ ɤɨɥɟɛɚɧɢɹ ɡɚɩɚɡɞɵɜɚɧɢ ɝɪɭɧɬɚ Ɋɚɫɫɦɨɬɪɟɧ ɦɟɬɨɞ ɞɢɧɚɦɢɱɟɫɤɨɝɨ ɝɚɲɟɧɢɹ ɝɪɭɧɬɚ ɩɪɢ ɪɚɛɨɬɟ ɪɵɯɥɢɬɟɥɹ ɢ ɜɪɟɦɟɧɢ ɫɪɚɛɚɬɵ ɜɚɧɢɹ ɝɚɫɢɬɟɥɹ ɤɨɥɟɛɚɧɢɣ ɋɨɫɬɚɜɥɟɧɚ ɦɚɬɟɦɚɬɢɱɟɫɤɚɹ ɦɨɞɟɥɶ ɡɚɩɚɡɞɵɜɚɧɢɹ ɞɢɧɚɦɢɱɟɫɤɢɯ ɤɨɥɟɛɚɧɢɣ ɧɚ ɨɫɧɨɜɟ ɤɨɬɨɪɵɯ ɨɩɪɟɞɟɥɟɧɢɹ ɜɪɟɦɟɧɢ ɡɚɩɚɡɞɵɜɚɧɢɹ ɫɪɚɛɚɬɵɜɚɧɢɹ ɝɢɞɪɨɚɜɬɨɦɚɬɢɱɟɫɤɨɣ ɫɢɫɬɟɦɵ ɝɚɲɟɧɢɹ ɭɫɬɚɧɚɜɥɢɜɚɟɬɫɹ ɫɩɨɫɨɛɧɨɫɬɶ ʋ IURP0D\ ɞɢɧɚɦɢɱɟɫɤɢɯ ɤɨɥɟɛɚɧɢɣ ɡɧɚɱɟɧɢɟ ɤɨɬɨɪɨɝɨ ɝɢɞɪɨɚɜɬɨɦɚɬɢɱɟɫɤɨɣ ɫɢɫɬɟɦɵ ɝɚɲɟɧɢɹ ɞɢɧɚ /(21,'3(/(9,10<.2/$.$53(1.2 ɩɨɡɜɨɥɹɟɬ ɫɨɡɞɚɜɚɬɶ ɝɢɞɪɨɚɜɬɨɦɚ ɬɢɱɟɫɤɢɟ ɦɢɱɟɫɤɢɯ ɤɨɥɟɛɚɧɢɣ ɜɨɜɪɟɦɹ ɫɪɚɛɚɬɵɜɚɬɶ and regulation of ɨɛɟɫɩɟɱɢɜɚɹ ɩɪɟɞɨɬɜɪɚɳɟɧɢɟ ɩɟɪɟɞɚɱɢ ɤɨɥɟɛɚɧɢɣ ɫɢɫɬɟɦɵ ɝɚɲɟɧɢɹ Dynamics ɤɨɥɟɛɚɧɢɣ ɜɨɜɪɟɦɹ DXOLF FRQWURO Mashiɛɚɡɨɜɨɣ ɦɚɲɢɧɟ Ɋɚɡɪɚɛɨɬɚɧɚ ɪɟɚɝɢɪɭɸɳɢɯ ɧɚ ɞɢɧɚɦɢɱɟɫɤɢɟ ɜɧɟɲɧɢɟ ɤ sian. ɝɢɞɪɨɚɜɬɨɦɚɬɢɱɟɫɤɚɹ ɫɢɫɬɟɦɚ ɝɚɲɟɧɢɹ ɞɢɧɚɜɨɡɦɭɳɟɧɢɹɉɪɨɜɟɞɟɧɪɚɫɱɟɬɩɟɪɢɨɞɚɫɤɚɥɵɜɚɧɢɹ evices of ɝɪɭɧɬɚ ɩɪɢ ɪɚɛɨɬɟ ɪɵɯɥɢɬɟɥɹ ɢ ɜɪɟɦɟɧɢ ɦɢɱɟɫɤɢɯ ɤɨɥɟɛɚɧɢɣ ɜɨɡɧɢɤɚɸɳɢɯ ɧɚ ɪɚɛɨ-ɱɟɦ $YDLODEOH DW Mashi- ɡɚɩɚɡɞɵɜɚɧɢɹ ɫɪɚɛɚɬɵ-ɜɚɧɢɹ ɝɚɫɢɬɟɥɹ , ac- ɨɪɝɚɧɟ ɞɥɹ ɩɪɟɞɨɬɜɪɚɳɟɧɢɹ ɩɟɪɟɞɚɱɢ ɷɬɢɯ ɞɢɧɚɦɢɱɟɫɤɢɯ ɤɨɥɟɛɚɧɢɣ ɧɚ ɨɫɧɨɜɟ ɤɨɬɨɪɵɯ ɤɨɥɟɛɚɧɢɣɤɛɚɡɨɜɨɣɦɚɲɢɧɟ ɭɫɬɚɧɚɜɥɢɜɚɟɬɫɹ ɫɩɨɫɨɛɧɨɫɬɶ (OLPLQDWLRQ RI IOXFWXDWLRQV LQ Ʉɥɸɱɟɜɵɟ ɫɥɨɜɚ ɝɚɫɢɬɟɥɶ ɞɢɧɚɦɢɱɟɫɤɢɟ \ (in ɤɨɥɟɛɚɧɢɹ ɝɢɞɪɨɚɜɬɨɦɚɬɢɱɟɫɤɚɹ ɫɢɫɬɟɦɚ ɜɪɟɦɹ ɝɢɞɪɨɚɜɬɨɦɚɬɢɱɟɫɤɨɣ ɫɢɫɬɟɦɵ ɝɚɲɟɧɢɹ ɞɢɧɚ in Russian. ɦɢɱɟɫɤɢɯ ɤɨɥɟɛɚɧɢɣ ɜɨɜɪɟɦɹ ɫɪɚɛɚɬɵɜɚɬɶ ɡɚɩɚɡɞɵɜɚɧɢɹ ɫɪɚɛɚɬɵɜɚɧɢɹ ɩɟɪɢɨɞ ɫɤɚɥɵɜɚɧɢɹ Machines for ex- ɝɪɭɧɬɚ regulation of ɨɛɟɫɩɟɱɢɜɚɹ ɩɪɟɞɨɬɜɪɚɳɟɧɢɟ ɩɟɪɟɞɚɱɢ ɤɨɥɟɛɚɧɢɣ ser.. – Mashi- ɤ ɛɚɡɨɜɨɣ ɦɚɲɢɧɟ Ɋɚɡɪɚɛɨɬɚɧɚ .ȱ6'2 ɝɢɞɪɨɚɜɬɨɦɚɬɢɱɟɫɤɚɹ ɫɢɫɬɟɦɚ ɝɚɲɟɧɢɹ ɞɢɧɚ Ⱥ LODEOH DW ɦɢɱɟɫɤɢɯ ɤɨɥɟɛɚɧɢɣ ɜɨɡɧɢɤɚɸɳɢɯ ɧɚ ɪɚɛɨ ɱɟɦ 7(.$ NRP 0RW ( ɨɪɝɚɧɟ ɞɥɹ ɩɪɟɞɨɬɜɪɚɳɟɧɢɹ ɩɟɪɟɞɚɱɢ ɷɬɢɯ ɤɨɥɟɛɚɧɢɣɤɛɚɡɨɜɨɣɦɚɲɢɧɟ HUJ5ROQ2/3$1YRO Ⱥ ɫɥɨɜɚ ɝɚɫɢɬɟɥɶ ɞɢɧɚɦɢɱɟɫɤɢɟ XFWXDWLRQV LQ Ʉɥɸɱɟɜɵɟ ɤɨɥɟɛɚɧɢɹ ɝɢɞɪɨɚɜɬɨɦɚɬɢɱɟɫɤɚɹ ɫɢɫɬɟɦɚ ɜɪɟɦɹ ɡɚɩɚɡɞɵɜɚɧɢɹ ɫɪɚɛɚɬɵɜɚɧɢɹ ɩɟɪɢɨɞ ɫɤɚɥɵɜɚɧɢɹ 7(.$ NRP 0RW (QHUJ ɝɪɭɧɬɚ 5ROQ2/3$1YRO Ⱥ 7DQDĞ RHQLH RP 0RW ( 0RW (QHUJ 2/ 3$1 YRO DNLQJ V\ J 5ROQ 2/ %XOOGR]HU 7(.$ NRP 0RW (QHUJ 5ROQ 2/ 3$1 YRO Ĕ $Q DQDO\VLV RI K\GUDXOLF EUDNLQJ V\ 7(.$ NRP 0RW (QHUJ 5ROQ 2/ 3$1YRO =DNKDUFKXN% %XOOGR]HU =LSNɿQ <D TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 151–160 $ Correlation of Plastic Forming andFKLQH Structure Formation Parameters SDUWV UHTXLUH in Powder Materials VLVWDQFH> Lyudmila Ryabicheva, Dmytro Usatyuk, Yuri Nikitin Volodymyr Dahl East Ukrainian National University, Department of Engineering Mechanics, Chair of Material Science Molodizhny bl., 20a, Lugansk, 91034, Ukraine, e-mail: [email protected] &RQVHTXHQWO\ Received December 04.2014; accepted December 17.2014 S u m m a r y . $ WKHRUHWLFDO DQDO\VLV RI WKH NLQHWLFV RI VRftening processes occurring in the powder porous body during deformation at high temperatures has been conducted. ConstiWXWLYHHTXDWLRQVUHODWLQJWKHGHIRUPDWLRQparameters and structure formation parameters that are characterizing dynamic softening processes during deformation. The linear dependence of the axial stress logarithm and accumulated deformation of hard phase as a function of the reciprocal of the temperature. The activation energy of dynamic softening at uniaxial compression estimated. It has shown that at low deformation temperatures the softening mechanism is dynamic recovery and polygonization while dynamic recrystallization is taking place at elevated temperatures. Porosity decreases the activation energy of dynamic softening. The dynamic softening mechanism in powder material was confirmed by metallographic analysis. K e y w o r d s : mathematical model, recovery, polygonization, recrystallization, activation energy. INTRODUCTION $ wide variety of working conditions of maFKLQH SDUWV UHTXLUH the development of materials with special properties that ensure high wear reVLVWDQFH>, 2]. This problem may be solved by implementation of new materials produced by a combination of heat treatment and plastic forming processes. The power and kinematic parameters of plastic deformation during hot and semi-hot deformation take an influence on structure of powder materials and changing of their operational properties. &RQVHTXHQWO\, investigation of the deformation of powder materials is important for solving problem of interrelation of deformation parameters and structure formation 7KLV TXHVWLRQ has deeply studied for deformation of compact materiDOV > @ It has shown clearly that temperature, strain rate and intensity of deformation take an in- 7KLV TXHVWLRQ deeply studied for deformation of compact materiDOV > @ It has shown clearly that temperature, strain rate and intensity of deformation take an influence on structure formation parameters that are determining the mechanism of softening process >@It has established theoretically and experimentally that increment of material’s plasticity at small degrees of deformation and low temperatures is stipulated by dynamic recovery and polygonization, while it is connected with the kinetics of dynamic recrystallization at increasing of the temperDWXUHDQGGHJUHHRIGHIRUPDWLRQ>@,QFUHDsing of strain rate leads to growing resistance of deformation, decrease in plasticity due to intensification of hardening processes [9]. Obviously, the same dynamic softening processes may be observed into the solid phase of powder material >@+RZHYHUWKHNLQHWLFVRIVRIWHQLQg processes is under the influence of pore phase presented in powder materials. This paper is aimed in theoretical analysis of the kinetics of softening processes taking place in the powder material during plastic deformation at elevated temperatures and determination of dependences between deformation and structure formation parameters. 0$7(5,$/6$1'0(7+2'6 Plastic forming at any conditions, on a basis of dislocation representations, may be characterized by changing of dislocation structure in hard phase of powder material, which causes the development of two mutually balanced processes - hardening and softening. The expression of changing EHZULWWHQDV>@ >@ U KH k U , W 0$7(5,$/6$1'0(7+2'6 >@ /<8'0,/$5<$%,&+(9$'0<75286$7<8.<85,1,.,7,1 phase of powder material, which causes the development of two mutually balanced processes - hardening and softening. The expression of changing the dislocations’ density during plastic deformation may EHZULWWHQDV>@ 1 \ e 2 MJ 2 , 1T W where: \ , M – are porosity functions; e – is the volume changing rate; J – is the shape changing U KH k U , rate. Porosity functions may be calculated by exwhere: U – is the dislocation density; k – is the pressions >@ %ROW]PDQQIXQFWLRQ; H – is the strain rate; K – is the coefficient that characterises the ability of hard 2 ( 1 T )3 2 phase to accumulate dislocations at particular \ , M ( 1T ) , 3 T strain rate. The first term on the right side of the eTXaand assuming of ((Tand ((T WLRQ GHVFULEHV WKH KDUG phase hardening and increment of dislocation density per unit of time W that is growing with the strain rate H . The second 1 Z ³ MJ 2 \ e2 dW . term describes decreasing of strength through dec T 1 0 rementing of dislocation density due to thermally activated processes expressHG E\ WKH %ROW]PDQQ function: The volume changing rate for uniaxial compression may be written as: k0 exp( E / kT ) , k e ez 2er , where: k0 – is the IUHTXHQF\ IDFWRU WKDW LV LQGea shape changing rate may be determined uspendent of temperature; E – is the activation enering the formula: gy of softening processes; T – is the absolute temperature. 7KH HTXDWLRQ has a solution >@ at the 2 J e z er , H ( t ) 9 const constant strain rate and bounda3 ry conditions U ( 0 ) U K9 § ¨ U0 k © U0 : § Z · K9 · , ¸ exp ¨ k ¸ ¹ © 9¹ k FRQVLGHULQJWKHHTXDWLRQ: where: Z – is the accumulated deformation with taking into account the influence of porosity. The accumulated deformation of hard phase is determined by the following expression >@ Z W ³ WdW , er ez r 1 , 2r Q aIWHU VXEVWLWXWLRQ WR (T WKH YROXPH changing rate has transformed to the formula: e 1 2Q ez . $ spherical component of the stress tensor: 0 p 1 Vz, 3 where: W – is the rate of changing the accumulated deformation of powder material; W – is the pethe intensity of shear stress is determined by riod of time. the formula: The rate of changing the accumulated deformation of powder material may be written in the 2 W Vz . following way >@ 3 W \ M T \ e 2 MJ 2 , e Loading surface of powder body with taking Zof K9 W of K9 W V &255(/$7,212)3/$67,&)250,1*$1'6758&785()250$7,213$5$0(7(56 Loading surface of powder body with taking into account pore formation process may be implemented in the form of: D p a 2 EW 2 c2 , where: D , E ,a,c – are coefficients that are dependent on the porosity >@ 7KH IROORZLQJ HTXDWLon that describes dimensional changes during uniaxial compression has obtained in [7] on the basis of the plasticity law ((T ZKile considering ((TDQG(T: r 1D § D · ¨1 3 ¸ 3E© Vz ¹ FRUGLQJWR(TDWthe condition K9 const . The ultimate density of dislocations under the given conditions of deformation goes to the value of K9 k EDVHG RQ WKH H[SUHVVLRQ . The average dislocations’ density for maximum stress reached for this stage of deformation defined simiODUO\WR>@: Uk F K9 k , where: F - is the ratio that is within 0 F . The dependence of the maximum flow stress V z for the certain deformation stage from the dis- location density U k may be assumed in the following way [8]: AU k n , Vz 2 2º ª 1 D « 6DE c D 6 E 6DE a » . where: A and n - are constants. 3 E « D a c 2 D 6 E 6DE a 2 » The expression ((T DIWHU the substitu¬ ¼ tion of ((Tlooks like: The HTXDWion of axial stress under uniaxial compression looks like: Vz 6 c 2 D 6 E 6DEa 2 3Da . D 6E D 6E Vz dZ dH z 1 1T 1 T 1 2Q , 2 1 M \ 1 2Q sign e z . 3 r2 n $IWHU WDNLQJ WKH ORJDULWKP VXEVWLWXWLRQ RI ((TDQGWUDQVIRUPDWLRQVobtained: Therefore, changing of porosity and accumulated deformation during forming operation may be calculated from the expressions: dT dH z § K9 · . A¨ F © k ¹̧ ln V z ª § K9 ·n º nE ln « A ¨ F . ¸ » « © k0 ¹ » RT ¬ ¼ Obviously, the maximum flow stress V z for certain forming stage is corresponding to the accumulated deformation Z k . Then, substituting the H[SUHVVLRQWKHYDOXHRIDFFXPXODWHGVWUDLQDQG HTXDWLQJ DQG DIWHU WUDQVIRUPDWLRQV ZH Rbtain: It is possible to determine the axial stress and accumulated deformation from (T DQG k · 9 ª§ 1 º (T . The right side of ((T contains non Zk ln «¨¨ U0 F 1 » linear functions of porosity, FRQVHTXHQWO\VROXWLRQ k ¬© K9 1 ¸¹̧ ¼ of differential equations’ system was performed numerically by the Newton-Raphson method. The It has assumed from ((TWKDWWKHIDFWRU function ((T describes a decrementing change 1 in case of balance beof dislocations' density U >@ 7KH YDOXH RI U ln U 0 k /( K9 1 )F 1 asymptotically goes to the limiting value K9 k at tween hardening and softening processes tends to a constant value for a certain flow stress. In this Z o f and W o f . The value of K9 k depends case, the rate of changing the dislocation density on the deformation temperature and activation en- goes to zero. 7KHIROORZLQJHTXDWLRQREWDLQHGIrom ergy of thermally activated softening process ac- ((TDWDFRQVWDQW strain rate: FRUGLQJWR(TDWthe condition K9 const . The ultimate density of dislocations under k > K9 k EDVHG RQ WKH H[SUHVVLRQ @ Uɤ K9 7KHIROORZLQJHTXDWLRQREWDLQHGI 5(68/76$1'',6&866,21 (TDWDFRQVWDQW /<8'0,/$5<$%,&+(9$'0<75286$7<8.<85,1,.,7,1 performed for evaluation of the activation energy of dynamic softening processes at uniaxial comU ɤ K9 pression of copper-titanium powder material. SamThen : ples were prepared from charge consists of copper powder PMS– and titanium powder %7–0 with DPDVVIUDFWLRQRIWLWDQLXPDQGDSRURVLW\RI ª§ U ª§ k · · 1 º 1 º ln «¨ U0 1¸ F 1 » ln «¨ 0 1¸ F 1 » - DIWHU VLQWHULQJ DW – 920 ºC during ¬© K9 ¹ ¼ ¬© U ê ¹ ¼ hours into a synthesis gas atmosphere. Samples were deformed on the WHVWLQJ PDFKLQH ='– DW It has accepted that the dislocation density of temperDWXUHV RI DQG ºC with - the hard phase before and after deformation are VWUDLQUDWHV while recording of the indicator GLIIHUHQWE\-WLPHV >@and F | 0 ,8 y 0 ,9 , diagram. The accumulated deformation values were means that the value of ((T may be approxicalculated using ((T D[LDO stress values - by mately determined as ln 10 | 2 ,3 . and ln V z 1 T The eTXDWion ((T was transformed to ((T , dependences the form: ln Zɤ 1 T (Fig have drawn. The obtained dependences are straight lines, 9 9 § E · . H[FHSWIRUWKHSRLQWVDW °C, in which there are Zɤ | 2 ,3 # 2,3 exp¨ k k0 © RT ¹̧ gaps of functions due to deformation aging. Straight lines consist of two branches - low temthan, after taking the logarithm, obtained: perature branch that is characterizing deformation process DW – ºC and high temperature E 9 branch for deformation process DW – ºC. ln Z ɤ ln . V define Zɤ Slopes of these functions the activation enk 0 RT ż Tsoftening a parŸ Tof dynamic ergy passing through ticular mechanism. The degree of deformation (TXDWLRQV(TDQG(TDUHUHODWLRQV characterizes by the stage N . connecting the main parameters of the deformation The low-temperature branch possess the of the porous body flow stress, accumulated delowest DFWLYDWLRQ HQHUJ\ )LJ D with values formation of hard phase, strain rate, temperature within 0.20- H9 DW SRURVLW\ VDPSOHV DQG and structural characteristics of the powder materi-0.28 eV at porosity, which is the result al (K , k , E , Uɤ which characterizes softening of dynamic recovery and polygonisation [9]. process during deformation at the elevated temperThe activation energy at high temperatures atures. $ linear character of dependences of the JURZV PRUH WKDQ WLPHV )LJ E that indicates accumulated deformation and corresponding stress more intensive softening. The greatest increment from the reciprocal temperature follows from these of activation energy - H9 has observed at HTXDWLRQVwith a slope of the OLQHHTXDOWRWKHDFWi- high temperatures during the third stage. In this vation energy of dynamic softening process flow- case, the activation energy of softening comparable ing by one or another mechanism. with the activation energy of self-diffusion of pure $ slope of the function ln Zɤ f 1 T is FRSSHU HTXDO WR H9 >@ VR ZH FDQ DVVXPH E RT and corresponding to ((T . Conse- that softening during the third step carries out by dynamic recrystallization. TXHQWO\ the slope of the function ln V z f 1 T It should be noted that the value of activais nE RT according to ((TTherefore, slopes tion energy of softening process depends on the of these functions different by the value n are initial porosity of samples and takes higher values WHPSHUDWXUHEUDQFKŸ T 0 ż T 0 characterizing a maximum possible density of dis- DWporosity )LJ The presence of pores decelerates the dylocations. namic softening that has confirmed by experiPHQWDO VWXGLHV >@ )RU H[DPSOH E eV at T 0 DQG E eV at T 0 IRU high tem5(68/76$1'',6&866,21 perature deformation when softening takes place by dynamic recrystallization. Verification of the mathematical model has The existence of low-temperature and highperformed for evaluation of the activation energy temperature branches on dependences V 1 T , of dynamic softening processes at uniaxial compression of copper-titanium powder material. Sam- 1 k . %7 DPDVVIUDFWLRQRIWLWDQLXPDQGDSRURVLW\RI 7L &255(/$7,212)3/$67,&)250,1*$1'6758&785()250$7,213$5$0(7(56 a b b a 1. The Tdependences V – 1 T – a, N Z Fig. 1. The dependences ln V z 1 T – a, | ln Zɤ | 1 T – bŸ – T 0Fig. ż– 2 – N ɤ | 1–TN– b: 0 Ÿ T 0 ż T 0 N N a The low-temperature branch possess the N DFWLYDWLRQ HQHUJ\ )LJ D H9 DW SRURVLW\ VDPSOHV DQG JURZV PRUH WKDQ WLPHV )LJ E H9 WHPSHUDWXUHEUDQFKŸ T ż T DFWLYDWLRQ HQHUJ\ )LJ D H9 DW SRURVLW\ VDPSOHV DQG JURZV PRUH WKDQ WLPHV )LJ E H9 FRSSHU HTXDO WR H9V>@ 1 TVR ZH FDQ Zɤ DVVXPH | 1 T ż Ÿ N PHQWDO H[DPSOH N T 0 VWXGLHV >@ T0 )RU a b T IRU T DQG N b FRSSHU HTXDO WR H9 >@ VR ZH FDQ DVVXPH Variation of branch; activation during softeningbranch; pro- Fig. 2. Variation of activation energy during softening process: a – isFig. the 2. low-temperature b –energy is the high-temperature cess: branch; b – is the highŸ – T 0 ż – T 0 . $ a – is the low-temperature LQHTXLJUDQXODULW\ WHPSHUDWXUHEUDQFKŸ ż T 0 with by dynamic recrystallization. 0 connected has been observed. It Thas inhomoge- TheDFWLYDWLRQ presence of pores)LJ decelerates dyD the The existenceHQHUJ\ of low-temperature and highDW )LJ H9 DW SRURVLW\ VDPSOHV temperature branches ondependences ln V z 1 DQG T, PHQWDO VWXGLHV >@ )RU H[DPSOH E characterize softening IRU has been Tthat T mechanism 0 DQG E verified by metallographic 0analysis. The character of structure changes in the powder material with JURZV PRUH WLPHV )LJ Eupon the tem 7L and WKDQ porosity depends perature of deformation and observed at magnifica H9 DQG FRQGLWLRQ V 1 T RI tion x ()LJ *UDLQ VKDSH their boundaries characterize the processes occurring in the powder material during its deformation >@ 7KHVH experiments allowed to explain obFRSSHU HTXDO H9 >@ ZH FDQ DVVXPH 7Lphenomena, WR served establish theVR beginning of dynamic recrystallization and follow the kinetics of WHPSHUDWXUHEUDQFKŸ ż DQG T 0 VKDSH T0 FRQGLWLRQ )LJ *UDLQ RI its development. The starting structure after sintering of the powder material into a synthesis gas atmosphere at >@ E of copPHQWDO VWXGLHV >@ )RU H[DPSOH 900 –7KHVH 920 ºC is characterized by the presence DW )LJ E DQG IRU grains, pores and titanium particles (Fig. a Tper T 0 0 $ considerable LQHTXLJUDQXODULW\ of microstructure has been observed. It has connected with inhomogeneous development of static recrystallization during sintering due to inhomogeneous stress stateVformed 1 Tat >@ neous development of static recrystallization during sintering due to inhomogeneous stress state formed at compaction of >@ charge)RU from copper and titanium PHQWDO VWXGLHV H[DPSOH DW )LJ powders into a closed matrix >@ T 0 DQG T 0 IRU Shapes of deformed copper grains observed on the photo of metallographic section of sample deformed by compression to the degree of deformation 0.69 at temperature 100 °C and strain rate V V- (Fig. EDUHGLIIHUHQWRIHTXLD[HGJUDLQV IRUPHG GXULQJ VLQWHULQJ )LJ D The dynamic recovery does not lead to rebuilding of structure, so distorted boundaries appeared as the conse 7LRI VHvere deformation of hard phase. The TXHQFH refinement of grains has observed near titanium *UDLQ VKDSHofDQG FRQGLWLRQ RI particles due)LJ to a local increase internal stresses around the particles of alloying addition. Deformation at 400 °C leads to formation of >@ 7KHVH complex-shaped ERXQGDULHV )LJ , F WKDW indicates processes associated with the migration of grain boundaries and formation of new ones. New interfaces presented by coherent particles of precipitates have formed at 400 °C as the result of DOV>@ >@ ERXQGDULHV )LJ F WKDW /<8'0,/$5<$%,&+(9$'0<75286$7<8.<85,1,.,7,1 grain boundaries and formation of new ones. New interfaces presented by coherent particles of pre V cipitates have EDUHGLIIHUHQWRIHTXLD[HGJUDLQV formed at 400 °C as the result of IRUPHG GXULQJ VLQWHULQJ )LJ Dsolid solution decomposition of a supersaturated during deformation of the copper-titanium materiDOV>@that promotes the primary recrystallizaTXHQFH RI+RZHYHU VH WLRQ >@ WKH GHYHORSPHnt of dynamic recrystallization inhibited due to blocking of grain boundaries by particles, thus preventing of their migration and resulting in assuming of serpentine shape (Fig. , F 0LFURVWUXFWXUHV RI VDPSOHV ZLWK 7L DQG ERXQGDULHV F WKDW The microstructure of )LJ the sample after de formation at 600 ºC is characterized by the presIRUPDWLRQDWVWUDLQUDWH HQFH RI HTXLD[LDO copper grains formed as the reVXOWRIG\QDPLFUHFU\VWDOOL]DWLRQ)LJG The recrystallized grains have a polygonal shape. Intragranular twins, appeared during dynamic recrystallization, have formed by separation DOV>@ of growing twins from double angle boundaries WLRQ >@ +RZHYHU WKH GHYHORSPHgrain growth. It >@DVWKHUHVXOWRIrecrystallized VKRXOG EH QRWHG WKDW HTXLD[ial structure is formed by the volume of sample. It allows to suggest a uniform and complete flow of dynamic recrystalliF ]DWLRQDW ºC. Increase of titanium content up to 2 LQWKH powder material RI porosity at low temperaHQFH RI HTXLD[LDOleads to growing of the stress and ture deformation VXOWRIG\QDPLFUHFU\VWDOOL]DWLRQ)LJG ultimate degree of deformation that is correspond- ing to changing the activation energy and, conseTXHQWO\ the deformation mechanism. These processes provide grain refinement during compression to various degrees RI GHIRUPDWLRQ )LJ Different barriers like grain boundaries and pores, twin boundaries and titanium particles are places of defects concentration in copper-titanium powder materials, where the most fine- grained structure has been observed )LJ, E*UDLQUHILQHPHQWRQ boundaries of copper and titanium particles during plastic0LFURVWUXFWXUHRIVDPSOHV7LSRURVLW\FRPSUH deformation is a FRQVHTXHQFHRIGLIIHUHQFHV in the plastic and elastic properties of copper and RIGHIRUPDWLRQRI titanium. Formation of finer grain size less than 2 ȝP has been observed near titanium particles )LJ, D DVDUHVXOWRIFRPSUHVVLRQRIVDPSOHVFRQWDLQLQJ RIWLWDQLXPDW&XQWLOWKHGHJUHHRIGHIRUPDWLRQ . +igh values of stresses and deformations in these places promotes to beginning of dynamic recrystallization leading to formation of new grains. +RZHYHU intermediate phases, precipitated as a result of WKHVWUDLQDJLQJ>@ are inhibiting growth of dynamically recrystallized grains [22]. &RQVHTXHQWO\, anisomerous structure near titanium particles preserved up to degree of GHIRUPDWLRQ)LJ, E Further compaction to the degree of deformation IRUPV D KRPRJHQHRXV ILQH-grained structure b 0LFURVWUXFWXUHRIVDPSOHV7LSRURVLW\FRPSUH a RIGHIRUPDWLRQRI c ȝP )LJ D DVDUHVXOWRIFRPSUHVVLRQRIVDPSOHVFRQWDLQLQJ RIWLWDQLXPDW&XQWLOWKHGHJUHHRIGHIRUPDWLRQ + +RZHYHU WKHVWUDLQDJLQJ>@ &RQVHTXHQWO\ 0LFURVWUXFWXUHV RI VDPSOHV ZLWK 7L DQG GHIRUPDWLRQ)LJ E d b d 0LFURVWUXFWXUHV RI VDPSOHV ZLWK 7L DQG Fig. 3 0LFURVWUXFWXUHV RI VDPSOHV ZLWK 7L DQG Fig. 3 0LFURVWUXFWXUHV ZLWK 7L DQG : b VDPSOHV – t =deforming 100ILQH ºC; IRUPDWLRQDWVWUDLQUDWH s RI a – afterDsintering; after to degree of deFig. 3 0LFURVWUXFWXUHV RI VDPSOHV ZLWK DQG de porosity; porosity; a – after sintering; after deforming to 7L degree of porosity;IRUPV a – after KRPRJHQHRXV sintering; after -deforming to degree of de- s : b – t = 100 ºC; porosity; a – after sintering; after sdeforming to degree 400IRUPDWLRQDWVWUDLQUDWH ºC; d – t = 600 ºC. : b – t = 100 ºC; c –oft =deIRUPDWLRQDWVWUDLQUDWH IRUPDWLRQDWVWUDLQUDWH IRUPDWLRQDWVWUDLQUDWH s : b – t = 100 ºC; c – t = 400 ºC; d – t = 600 ºC. c – t = 400 ºC; d – t = 600 ºC. The recrystallized grains have a polygonal )LJ E*UDLQUHILQHPHQWRQ RI DQG FRQVHTXHQFHRIGLIIHUHQFHV &255(/$7,212)3/$67,&)250,1*$1'6758&785()250$7,213$5$0(7(56 ȝ SRZGHU PDWHULDO ZLWK DQG RI WL 0HWDOO RI DQG a a 7LLVDVVRFLDWHGZLW WLRQV)LJ b Fig. 4. 0LFURVWUXFWXUHRIVDPSOHV7LSRURVLW\FRPSUHssion at 100 °C and strain rate of 0.001 s-: a - 0.079 the degree of deformation; b - the degree RIGHIRUPDWLRQRI Formation of finer grain size less than 2 ȝP with the copper grain size 7.28 ȝm by improving )LJ of D completeness of the dynamic recrystallization. DVDUHVXOWRIFRPSUHVVLRQRIVDPSOHVFRQWDLQLQJ Deformation at 600 ºC follows by intensive RIWLWDQLXPDW&XQWLOWKHGHJUHHRIGHIRUPDWLRQ decrease +of copper grain size while increasing degree of deformation, which is typical for copper-titanium SRZGHU PDWHULDO ZLWK DQG RI WLtanium (Fig. 0HWDOOographic studies have shown that ani+RZHYHU somerous structure observed at low deformation deWKHVWUDLQDJLQJ>@ grees RI – DQG caused by inhomogeneous &RQVHTXHQWO\ development of dynamic recrystallization. Formation of a 0LFURVWUXFWXUHRIVDPSOHV7LSRURVLW\FRPSUH homogeneous fine-grained structure due to inGHIRUPDWLRQ)LJ E creasing of dynamic recrystallization rate have ocWKHGHJUHHRI curred, whileWKHGHJUHHRIGHIRUPDWLRQRI of deformation degree to IRUPV Dincreasing KRPRJHQHRXV ILQH . The microstructures of samples ZLWKDQG 7L after compression is characterized by copper grains with serrated boundarieV)LJ7KHVWUXFWXUH RIVDPSOHVZLWK7L is less stable, grain boundaries are extremely tortuous and include a large number of "tips." The reason of serration is local heterogeneity of deformation in the border volumes and the FRQVHTXHQW GLIIHUHQFH LQ WKH GHQVLW\ RI GHIHFWV LQto local volumes on both sides of the original boundary that is stimulating migration of small areas to the volume with higher density of defects. Toothed shape of boundaries indicates the dynamic recrystallization >@ 5HGXFtion of curvature of grain boundaries in &RPPHUFLDOO\ SXUH WLWDQLXP %7 U b WDOOL]HV DW WHPSHUDWXUHV >@ Fig. 50LFURVWUXFWXUHRIVDPSOHV7LSRURVLW\FRPSUHssion at 400 °C at a strain rate of 0.001 s-: a - WKHGHJUHHRI WHPSHUDWXUH UDQJH deformation; b - WKHGHJUHHRIGHIRUPDWLRQRI. The microstructures of samples ZLWKDQG 7L V)LJ7KHVWUXFWXUH RIVDPSOHVZLWK7L FRQVHTXHQW GLIIHUHQFH LQ WKH GHQVLW\ RI GHIHFWV LQ >@ 5HGXF a b Fig. 6. 7KHPLFURVWUXFWXUHRIVDPSOHVRISRURVLW\DIWHUFRmSUHVVLRQVWUDLQUDWHRIV- at a temperature and deformation degree 600 ºC 0.916: and - 7LE- 7L. Obviously, the dynamic recovery does not /<8'0,/$5<$%,&+(9$'0<75286$7<8.<85,1,.,7,1 samples with 2 7LLVDVVRFLDWHGZLWh inhibition of grain boundaries’ migration by pores, titanium particles and disperse precipitaWLRQV)LJ Increasing of the deformation temperature causes softening of hard phase and, as shown by metallographic analysis, softening of copper begins at °C for the account of recovery and above ºC – by the dynamic recrystallization. &RPPHUFLDOO\ SXUH WLWDQLXP %7– UecrysWDOOL]HV DW WHPSHUDWXUHV – 800 ºC >@ 7KHPLFURVWUXFWXUHRIVDPSOHVRISRURVLW\DIWHUFR 7KHPLFURVWUXFWXUHRIVDPSOHVRISRURVLW\DIWHUFR Therefore, we can assume that in the investigated SUHVVLRQVWUDLQUDWHRIV SUHVVLRQVWUDLQUDWHRIV WHPSHUDWXUH UDQJH – 7L ºC softening takes 7LE 7L 7LE place for the account of the dynamic recovery. Obviously, the dynamic recovery does not allow to complete internal release of stresses removal and titanium particles are crushed because of high intensity of plastic deformation. CONCLUSIONS 5()(5(1&(6 2. Theoretical analysis analysis of of the the kinetics kinetics of softening Theoretical processes has been conducted for deformation at high temperatures and based on the dislocation concepts of plastic deformation and plasticity theory of porous powder bodies. ConstituWLYH HTXDWLRQV that are relating the main parameters of the deformation - flow stress, accumulated deformation of hard phase, strain rate, temperature and structural characteristics of the material - ability to accumulate dislocaWLRQV %ROW]PDQQ IXQFWLRQ DFWLYDWLRQ HQHUJ\ density of dislocations, which may be used for evaluation the mechanism of dynamic softening during deformation of porous powder materials at the elevated temperatures. 2. The linear character of the dependencies ln7KHPLFURVWUXFWXUHRIVDPSOHVRISRURVLW\DIWHUFR V z 1 T and ln Zɤ 1 T , which allows to SUHVVLRQVWUDLQUDWHRIV determine the mechanism dynamic softening 7LE of 7L of porous bodies has found. It has established by estimating of activation energy that at low temperatures the deformation mechanism is dynamic softening and recovery polygonization, at high temperatures - dynamic recrystallization. The presence of porosity phase reduces the activation energy of softening and makes its development less intensive. The mechanism of dynamic softening was confirmed by metallographic examination of structure evolution in compression samples from copper-titanium powder materials of different titanium content. 7. 8. 9. 5()(5(1&(6 3LURZVNL = *RĞFLDĔVNL 0 7(.$ &R 3LURZVNL = *RĞFLDĔVNL 0 Casting alloys for agricultural tools operating under the harsh conditions of abrasive wear, 7(.$ &RmPLVVLRQRI0RWRUL]DWLRQDQG(QHUJHWLFVLQ$JULFXlWXUH9RO1RSS– Gromenko, V., Krivonosov, S. and Snizhko A., 2012.: ;-5$<6WUXFWXUDO5HVHDUFKRI3URGXFWVRI &DYLWDWLRQDO (URVLRQ RI 0HWDOV, 7(.$ &RPPLsVLRQRI0RWRUL]DWLRQDQG(QHUJHWLFVLQ$JULFXOWXUH – 9RO1RSS-. Abbod M.F., Sellars C.M., Cizek P., Linkens D.A. and Mahfouf M., 2003.: Modelling the Flow %HKDYLRXU 5HFU\VWDOOL]DWLRQ DQG &U\VWDOORJUDSKLF 7H[WXUH LQ +RW 'eformed Fe- ZW 1L $XVWHnite, $FWD0ater, No. , pp. - Luton M.J., Sellars C.M., 1969.: Dynamic Recrystallization in Nickel and Nickel-,URQ $OOR\V 'XULQJ +LJK 7HPSHUDWXUH 'HIRrmation, $FWD Matallurgica, 9RO, pp- (OZD]UL A.M.(VVDGLTL(<XH6 Kinetics of Metadynamic Recrystallization in MicroalOR\HG +\SHUHXWHFWRLG Steels, ISIJ International, 9RO, No , pp. - Poliak (,, Jones J.J., 2003. Initiation of DynamLF 5HFU\VWDOOL]DWLRQ LQ &RQVWDQW 6WUDLQ 5DWH +RW Deformation, ISIJ International, Vol. , No. , pp- Ryabicheva L.A., 1998.: The Phenomenological $SSURDFK WR (VWLPDWLRQ RI 6WUXFWXUH by Macroscopic Parameters of the, Izvestija vuzov, Ferrous Metallurgy, No. 7, pp. - LQ5XVVLDQ Meyers M.A., Lasalvia J.C., Nestorenko V.F., &KHQ<-DQG Kad B.K., 1996.: Dynamic Recrystallization iQ +LJK 6WDLQ 5DWH 'HIRUPDWLRQ 3URFHVVLQJ RI 5H;C WKH 7KLUG ,QWHUQDWLRQDO Conference on Recrystallization and Related Phenomena, pp. 279– Ryabicheva L.A., 1996.: 7KH %LWPDS FRQWURO RI structure formation processes at hot stamping, (DVW-Ukrainian State University, Luhansk. (in RusVLDQ Bardi F.&DELEER0(YDQJHOLVWD(6LSJDUHlli S. and Vukcevic M., 2003.: $QDQDO\VLVRIKRW GHIRUPDWLRQ RI DQ $O-Cu-Mg alloy produced by powder metallurgy, MateriDOV 6FLHQFH DQG (QJiQHHULQJ$ Vol. , 1R-2, pp. - =RXKDU*, 1974.: %HXUWHLOXQJGHU(UKROXQJV- und Rekristallisationsneigung der Stähle bei der WarmIRUPJHEXQJ PLW +LOIH GHV :DUPWRUVLRQVYHUVXFKV, Neue Hütte, No 7, pp. - LQ*HUPDQ Leshhinskij V.M., Ryabicheva L.A., 1997.: Simulation of the dynamic recrystallization process, Metallovedenie i termoobrabotka, No. , pp. 9- LQ5XVVLDQ Shtern M.B., 1989.: $ PRGHORIWKH SURFHVVHVRI deformation of compressible materials with an allowance made for pore formation II. Uniaxial tension and compression of porous bodies, Powder Metallurgy and Metal Ceramics, Vol. 28, Issue SS 2 HULDOV DW (O 20. 22. LQ5XVVLDQ LQ5XVVLDQ $ PRGHORIWKH SURFHVVHVRI &255(/$7,212)3/$67,&)250,1*$1'6758&785()250$7,213$5$0(7(56 lowance made for pore formation II. Uniaxial tension and compression of porous bodies, Powder Metallurgy and Metal Ceramics, Vol. 28, Issue SS- Frost H.J., Ashby M.F., 1982.: DeformationMechanism Maps, Pergamon Press. Gaponova 2, Ryabicheva L., 2008. Deforming of the Copper-Titanium Powder MatHULDOV DW (Oevated Temperatures, International Conference Deformation and fracture in structural PM materials” DF PM 2008 Proceedings, Stará Lesná, High Tatras, Slovak Republic, pp. 202- Haessner F., 1978.: Recrystallization of metallic materials, Shtuttgart, 'U5LHGHUHU9HUODJ*PE+. .ROHURY 2. Characteristics of primary recrystallization and its role in the sintering of metal powders, Powder Metallurgy and Metal Ceramics, 9RO,VVXHSS. - Lawson C.L., Hanson R.J., 1974: Solving Least 6TXDUHV3UREOHPV3UHQWLFH–+DOO Soffa W.A./DXJKOLQ'( 2004.: +LJK-strength age hardening copper–titanium alloys: redivivus, Progress in Materials Science, No. , pp – McLean D., 1957.: *UDLQ %RXQGaries in Metals, Oxford University Press, London. Beljaev S.P., Lihachev V.A., Myshljaev M.M. and 6HQ NRY 21 Dynamic recrystallization of aluminium, Physics of Metals and Metallography, Vol., No, pp- LQ5XVVLDQ Gorelik S.S., 1978.: Recrystallization of metals and alloys, Moscow, Metallurgy. LQ5XVVLDQ McDonald D.T., Humphreys F.J., Bate P.S., 2007.: Microstructure and texture of dynamically 9RO LQ5XVVLDQ ȼɁȺɂɆɈɋȼəɁɖɉȺɊȺɆȿɌɊɈȼ ɉɅȺɋɌɂɑȿɋɄɈȽɈȾȿɎɈɊɆɂɊɈȼȺɇɂə ɂɋɌɊɍɄɌɍɊɈɈȻɊȺɁɈȼȺɇɂə ȼɉɈɊɈɒɄɈȼɕɏɆȺɌȿɊɂȺɅȺɏ Ɋɟɡɸɦɟ ɉɪɨɜɟɞɟɧ ɬɟɨɪɟɬɢɱɟɫɤɢɣ ɚɧɚɥɢɡ ɤɢɧɟɬɢɤɢ ɪɚɡɭɩɪɨɱɧɹɸɳɢɯ ɩɪɨɰɟɫɫɨɜ ɩɪɨɯɨɞɹɳɢɯ ɜ ɩɨɪɨɲɤɨɜɨɦ ɩɨɪɢɫɬɨɦɬɟɥɟɩɪɢɞɟɮɨɪɦɢɪɨɜɚɧɢɢ ɜɨɛɥɚɫɬɢ ɩɨɜɵɲɟɧɧɵɯ ɬɟɦɩɟɪɚɬɭɪ ɉɨɥɭɱɟɧɵ ɨɩɪɟɞɟɥɹɸɳɢɟ ɭɪɚɜɧɟɧɢɹ ɫɜɹɡɵɜɚɸɳɢɟ ɩɚɪɚɦɟɬɪɵ ɞɟɮɨɪɦɚɰɢɢ ɢ ɩɚɪɚɦɟɬɪɵ ɫɬɪɭɤɬɭɪɨɨɛɪɚɡɨɜɚɧɢɹ ɤɨɬɨɪɵɟ ɯɚɪɚɤɬɟɪɢɡɭɸɬ ɩɪɨɰɟɫɫɵ ɞɢɧɚɦɢɱɟɫɤɨɝɨ ɪɚɡɭɩɪɨɱɧɟɧɢɹ ɩɪɢ ɞɟɮɨɪɦɢɪɨɜɚɧɢɢ ɉɨɤɚɡɚɧɚ ɥɢɧɟɣɧɚɹ ɡɚɜɢɫɢɦɨɫɬɶ ɥɨɝɚɪɢɮɦɚ ɨɫɟɜɨɝɨ ɧɚɩɪɹɠɟɧɢɹ ɢ ɧɚɤɨɩɥɟɧɧɨɣ ɞɟɮɨɪɦɚɰɢɢ ɬɜɟɪɞɨɣ ɮɚɡɵ ɜ ɮɭɧɤɰɢɢɨɛɪɚɬɧɨɣɬɟɦɩɟɪɚɬɭɪɵȼɵɩɨɥɧɟɧɚɨɰɟɧɤɚɷɧɟɪɝɢɢ ɚɤɬɢɜɚɰɢɢ ɞɢɧɚɦɢɱɟɫɤɨɝɨ ɪɚɡɭɩɪɨɱɧɟɧɢɹ ɩɪɢ ɨɞɧɨɨɫɧɨɦ ɫɠɚɬɢɢɉɨɤɚɡɚɧɨɱɬɨɩɪɢɧɢɡɤɢɯɬɟɦɩɟɪɚɬɭɪɚɯɞɟɮɨɪɦɚɰɢɢ ɦɟɯɚɧɢɡɦɨɦɪɚɡɭɩɪɨɱɧɟɧɢɹɹɜɥɹɟɬɫɹɞɢɧɚɦɢɱɟɫɤɢɣɜɨɡɜɪɚɬɢ ɩɨɥɢɝɨɧɢɡɚɰɢɹ ɩɪɢ ɩɨɜɵɲɟɧɧɵɯ ɬɟɦɩɟɪɚɬɭɪɚɯ ɞɢɧɚɦɢɱɟɫɤɚɹ ɪɟɤɪɢɫɬɚɥɥɢɡɚɰɢɹ ɉɨɪɢɫɬɨɫɬɶ ɫɧɢɠɚɟɬ ɷɧɟɪɝɢɸ ɚɤɬɢɜɚɰɢɢ ɞɢɧɚɦɢɱɟɫɤɨɝɨ ɪɚɡɭɩɪɨɱɧɟɧɢɹ Ɇɟɬɚɥɥɨɝɪɚɮɢɱɟɫɤɢɣ ɚɧɚɥɢɡ ɩɨɞɬɜɟɪɠɞɚɟɬ ɦɟɯɚɧɢɡɦ ɞɢɧɚɦɢɱɟɫɤɨɝɨɪɚɡɭɩɪɨɱɧɟɧɢɹɩɨɪɨɲɤɨɜɨɝɨɦɚɬɟɪɢɚɥɚ Ʉɥɸɱɟɜɵɟ ɫɥɨɜɚ ɦɚɬɟɦɚɬɢɱɟɫɤɚɹ ɦɨɞɟɥɶ ɜɨɡɜɪɚɬ ɩɨɥɢɝɨɧɢɡɚɰɢɹɪɟɤɪɢɫɬɚɥɥɢɡɚɰɢɹɷɧɟɪɝɢɹɚɤɬɢɜɚɰɢɢ and alloys, Moscow, Metallurgy. LQ5XVVLDQ McDonald D.T., Humphreys F.J., Bate P.S., 2007.: Microstructure and texture of dynamically recrystallized copper and copper – tin alloys, Materials Science Forum, 9RO, pp- Kapyrin G.I., 1977.: Titanium alloys in machine building, Leningrad, Mashinostroenie. LQ5XVVLDQ ȼɁȺɂɆɈɋȼəɁɖɉȺɊȺɆȿɌɊɈȼ ɉɅȺɋɌɂɑȿɋɄɈȽɈȾȿɎɈɊɆɂɊɈȼȺɇɂə ɂɋɌɊɍɄɌɍɊɈɈȻɊȺɁɈȼȺɇɂə ȼɉɈɊɈɒɄɈȼɕɏɆȺɌȿɊɂȺɅȺɏ Ɋɟɡɸɦɟ ɉɪɨɜɟɞɟɧ ɬɟɨɪɟɬɢɱɟɫɤɢɣ ɚɧɚɥɢɡ ɤɢɧɟɬɢɤɢ ɪɚɡɭɩɪɨɱɧɹɸɳɢɯ ɩɪɨɰɟɫɫɨɜ ɩɪɨɯɨɞɹɳɢɯ ɜ ɩɨɪɨɲɤɨɜɨɦ ɩɨɪɢɫɬɨɦɬɟɥɟɩɪɢɞɟɮɨɪɦɢɪɨɜɚɧɢɢ ɜɨɛɥɚɫɬɢ ɩɨɜɵɲɟɧɧɵɯ ɬɟɦɩɟɪɚɬɭɪ ɉɨɥɭɱɟɧɵ ɨɩɪɟɞɟɥɹɸɳɢɟ ɭɪɚɜɧɟɧɢɹ ɫɜɹɡɵɜɚɸɳɢɟ ɩɚɪɚɦɟɬɪɵ ɞɟɮɨɪɦɚɰɢɢ ɢ ɩɚɪɚɦɟɬɪɵ ɫɬɪɭɤɬɭɪɨɨɛɪɚɡɨɜɚɧɢɹ ɤɨɬɨɪɵɟ ɯɚɪɚɤɬɟɪɢɡɭɸɬ ɩɪɨɰɟɫɫɵ ɞɢɧɚɦɢɱɟɫɤɨɝɨ ɪɚɡɭɩɪɨɱɧɟɧɢɹ ɩɪɢ ɞɟɮɨɪɦɢɪɨɜɚɧɢɢ ɉɨɤɚɡɚɧɚ ɥɢɧɟɣɧɚɹ ɡɚɜɢɫɢɦɨɫɬɶ ɥɨɝɚɪɢɮɦɚ ɨɫɟɜɨɝɨ ɧɚɩɪɹɠɟɧɢɹ ɢ ɧɚɤɨɩɥɟɧɧɨɣ ɞɟɮɨɪɦɚɰɢɢ ɬɜɟɪɞɨɣ ɮɚɡɵ ɜ ɮɭɧɤɰɢɢɨɛɪɚɬɧɨɣɬɟɦɩɟɪɚɬɭɪɵȼɵɩɨɥɧɟɧɚɨɰɟɧɤɚɷɧɟɪɝɢɢ ɚɤɬɢɜɚɰɢɢ ɞɢɧɚɦɢɱɟɫɤɨɝɨ ɪɚɡɭɩɪɨɱɧɟɧɢɹ ɩɪɢ ɨɞɧɨɨɫɧɨɦ ɫɠɚɬɢɢɉɨɤɚɡɚɧɨɱɬɨɩɪɢɧɢɡɤɢɯɬɟɦɩɟɪɚɬɭɪɚɯɞɟɮɨɪɦɚɰɢɢ ɦɟɯɚɧɢɡɦɨɦɪɚɡɭɩɪɨɱɧɟɧɢɹɹɜɥɹɟɬɫɹɞɢɧɚɦɢɱɟɫɤɢɣɜɨɡɜɪɚɬɢ ɩɨɥɢɝɨɧɢɡɚɰɢɹ ɩɪɢ ɩɨɜɵɲɟɧɧɵɯ ɬɟɦɩɟɪɚɬɭɪɚɯ – ɞɢɧɚɦɢɱɟɫɤɚɹ ɪɟɤɪɢɫɬɚɥɥɢɡɚɰɢɹ ɉɨɪɢɫɬɨɫɬɶ ɫɧɢɠɚɟɬ ɷɧɟɪɝɢɸ ɚɤɬɢɜɚɰɢɢ ɞɢɧɚɦɢɱɟɫɤɨɝɨ ɪɚɡɭɩɪɨɱɧɟɧɢɹ Ɇɟɬɚɥɥɨɝɪɚɮɢɱɟɫɤɢɣ ɚɧɚɥɢɡ ɩɨɞɬɜɟɪɠɞɚɟɬ ɦɟɯɚɧɢɡɦ ɞɢɧɚɦɢɱɟɫɤɨɝɨɪɚɡɭɩɪɨɱɧɟɧɢɹɩɨɪɨɲɤɨɜɨɝɨɦɚɬɟɪɢɚɥɚ Ʉɥɸɱɟɜɵɟ ɫɥɨɜɚ ɦɚɬɟɦɚɬɢɱɟɫɤɚɹ ɦɨɞɟɥɶ ɜɨɡɜɪɚɬ ɩɨɥɢɝɨɧɢɡɚɰɢɹɪɟɤɪɢɫɬɚɥɥɢɡɚɰɢɹɷɧɟɪɝɢɹɚɤɬɢɜɚɰɢɢ TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 161–168 Calculation of Deflection of One-Layer and Two-Layer Slabs Supported on Four Sides Dmytro Smorkalov Kyiv National University of Construction and Architecture Povitroflotskyy Prosp., 31, Kyiv, Ukraine, 03680, e-mail: [email protected] Received December 04.2014; accepted December 17.2014 Summary. The article presents the method and results of experimental research of deflection of one-layer and two-layer slabs influenced by short-term lateral load. The proposed method of calculation is based on WKH OLPLW HTXLOLEULXP PHWKRG WKH FDOFXODWLRQ RI VODE defleFWLRQV YDOXHV E\ /,5$-&$' EXQGOHG VRIWZDUH The comparison is carried out of experimental and theoretical results of slabs deflection calculation. Key words: slab, deflection, steel fiber concrete. INTRODUCTION Layered constructions have been increasingly applied in building recently. When appropriate composition of separate layers is selected, multilayer constructions with perfect construction properties may be created [9]. Layers are mostly composed of heavy concrete and effective steel fiber concrete. Such constructive decisions have a widespread use in road and airfield pavements, logistics areas, heavy-weight industrial floors, etc. > @ $PRQJ WKH PRVW SURPLVLQJ trends of reasonable usage of steel fiber concrete is its application in composite structures, as a rule, in combination with concrete or ferroconcrete, with distinct partition of functions of every material. In particular, the steel fiber concrete that is rather thriftily applied along the construction outline, in a thin layer, provides high crack resistance of constructions, as well as its high durability due to high indices of tensile strength, frost resistance, corrosion resistance and high rates of other types of resistance of the steel fiber concrete >@ $WWKHVDPHWLPHWKLV solution provides necessary preconditions for significant reduction of strength and value of the primary concrete and reduction of the number of reinforcement rod. Thus, there are preconditions for obtaining high indices created while their cost drops. PU5326(2)WORK The main purpose of proposed work is the comparison of proposed method of deflection calculation for layered slabs under lateral load with the results of experimental research. (;3(5,0(17$/ 5(6($5&+ $FFRUGLQJ to the set purpose of research, slabs of series were produced, two slabs for each series. The scope and outline of experimental studies is set in Table >]. The total size of single-layer slabs amounts to 800×800× mm; the thickness of each layer of reinforced concrete (concrete and steel fiber FRQFUHWHLQWZR-OD\HUVODEVLV mm. Series I (ɉɎUHSUHVHQWVDVODEPDGHRIVWHHO fiber concrete. Series II (ɉɁ UHSUHVHQWV D VLQJOH-layer reinforced concrete slab with single-layer reinforcement Ø4 %S-I laid at the bottom of the slab ZLWKSURWHFWLYHFRQFUHWHOD\HU mm thick with mm pitch Series III (ɉȻɎ UHSUHVHQWV D WZR-layer concrete slab, the top layer of which is made of unreinforced heavy concrete and the below one – of the steel fiber concrete. Series IV (ɉɁɎRIthe studied samples represents slabs consisting of an upper layer of steel fiber concrete and a heavy concrete layer reinforced with metal reinforcement mesh Ø %S-I VHWZLWK mm pitch. Slab concreting was carried out in two stages. 6ODEV RI ɉɁ JUDGH DQG FRQFUHWH OD\HUV RI ɉɁɎ DQGɉȻɎVODEVZHUHFRQFUHWHGDWWKHILUst stage. Siliceous sand and giaQW JUDYHO RI … mm IUDFWLRQ 3RUWODQG FHPHQW RI 0 JUDGH ZDV used as binding material; water-to-cement ratio '0<7526025.$/29 amounted to W/C 0, 3ODWHV RI ɉɁ DQG ɉɁɎ grade were reinforced with binding wire mesh of %S-, JUDGH PP LQ GLDPHWHU DQG mm pitch in two directions. Concrete protective layer was mm. The surface is bush-hammered while the concrete is immature. $WWKHVHFRQGVWDJHDIWHUGD\VVODEVRIɉɎ grade were concreted and steel fiber concrete layer slabs of ɉɁɎ grade were additionally concreted. Steel fiber concrete contained steel fiber with diameter df = mm and length lf mm; volume percent of reinforcement was f = Fine concrete without coarse aggregate was used as a concrete matrix; water-to-cement ratio HTXDOHGWR:& 0, Table 1. Scope of experimental studies Fig. 1. *HQHUDODSSHDUDQFHRIWHVWLQJEHQFK Series Slab grade I ɉɎ ɉɎ2 ɉɁ- II Section Composition –steel fiber concrete –reinforced concrete ɉɁ-2 ɉȻɎ- III ɉȻɎ-2 ɉɁɎ- IV ɉɁɎ-2 –concrete; 2–steel fiber concrete a –steel fiber concrete; 2–reinforced concrete *HQHUDO appearance of testing bench is showed in Fig. . The same calculation model was applied for both the one- and two-layer slabs exposed by lateral load: a slab is hinge-supported on four sides and influenced by evenly distributed load (Fig. b Fig. 2. Distribution of load (aand support (b upon slab: 1 hinged support, 2 cylinder support ,W LV VXJJHVWHG WKDW FRQFHQWUDWHG IRUFHV evenly allocated on the slabs surface show no significant difference during the operation, as compared to evenly distributed load, that is why in further theoretical study of strength, crack resistance, and deformation of studied slabs a design model was adopted for slabs supported by &$/&8/$7,212)'()/(&7,212)21(/$<(5$1'7:2/$<(56/$%6 hinged bearings on four sides and influenced by evenly distributed load. The load was applied by degrees Pi=2,0 N1ZLWK-minute timing at each stage to take readings from devices. The value of load was fixed by indices of model forcemeter of K\GUDXOLFSXPSLQJVWDWLRQ%HIRUHWHVWLQJWKHKydraulic system consisting of a pumping station, jacks, and model forcemeter was calibrated using model forcemeter of Tokarev system. During the application of load in the center of the slab deflections and deformations over supports were recorded using time indicators with mm scale graduation value. The load was applied by two hydraulic jacks RI kN united by common oil circuit connected to a common pump station. %HIRUH WHVWLQJ WKH VODEV SK\VLFDO DQG Pechanical properties of used materials were determined: those of heavy concrete, steel fiber concrete and reinforcement 7DEOH. $VSURSRVHGE\$ $ *YR]GHY>], it is posVLEOHWRPDNHXVHRIFKDUDFWHULVWLFSRLQWVDQG on the diagram (Fig. Table 2. Physical and mechanical properties of concretes and reinforcement Fig. 3. Design diagram of slab deflection: 1 cracking, 2 appearance of the plastic hinge Type of concrete or fitting concrete Strength, MPa cube prism Steel fiber concrete Reinforcement ȼɪ- – Tensile Starting elasstrength, ticity factor, MPa MPa Deflection values in the areas between fcr and fu are determined by interpolation. The general view of the formula f of slab deflection of slab supported on four sides and bearing a cracks, may be obtained from the following ratio: qu qcr q qcr – $FFRUGLQJ to results of experimental studies with regard to nature of destruction [], all slabs collapsed according to normal sections. &$/&8/$7,212)'()/(CTION 7KHSURSRVHGPHWKRGEDVHGRQWKHOLPLWHTXilibrium method, which may be represented – GXULQJWKHVWDWHRIOLPLWHTXLOLEULXP– by the system of disks united along the lines of fracture with plastic hinges. f u f cr , f f cr where: qu and qɫr – load at destruction and crack formation; fu and fcr – slab deflection at the moment of destruction and crack formation correspondingly. It should look as follows: f f cr q qcr ( f u f cr . qu qcr The value fcr is determined based on elastic system calculation according to load qcr, which in turn may be obtained by bending factor, when first crack appeared in a slab area with the highest tension. The deflections f at the moment of formation of plastic hinges may be determined as follows. Until the conditional yield point of reinforcement achieved along all the lines of fracture, cracks are formed and significantly increased on a VODE$WWKHVDPHWLPHDUHDVZLWKFUDFNVZLOOEH '0<7526025.$/29 especially distorted that will mostly determine the maximum value of slab deflection. If insignificant curvature of slab areas neglected bearing no cracks, but rigidity is high, the slab calculation model may be represented as stiff disks connected by yielding bracing with width ǻ %HQGLQJ ULJLGLW\ RI DOO MRLQWV LV FDOFulated according to V.M. Murashov theory [7], though the coefficient ȥ is taken as a one, as the reinforcements reaches instability the influence of stretched concrete between cracks disappears or becomes insignificant. This assumption substantially simplifies the calculation. For further simplification the angle fracture EHWZHHQGLVFVHTXDOWR ' is assumed as if conr centrated along the lines of fracture. The calculated deflection surface prior to exhaustion of the bearing capacity turns out to be similar to the surface used in calculatLQJ E\ OLPLW HTXLOLEULXP method for the calculation of works on possible movements. Though such likening is not accurate, it allows determining the maximum deflection at a rather decent level. There is a calculation model of VTXDUH slab presented on Fig. and a diagram of angle rotaWLRQ DW VODE FHQWHU GHIOHFWLRQ WKDW LV HTXDO WR fu. Owing to symmetry, the fracture diagram of value ǻ for all plastic hinges is the same. Rigid discs of the slab will turn in relation to supports by angle: M 2 2 fu . l Mutual angle adjacent discs M 2 2 fu l ' l'f ym whereof: 2 2 Es (d x fu , r . where: – curvature-multiplication of which by ǻ r HTXDOVWRUHFLSURFDODQJOHRIURWDWLRQRIDdjacent discs r f ym Es (d x , ( 2 2 – factor derived from geometrical consid- erations, which is transition to the angle of rotation of the disk relative to the support, For fiber reinforced structures (such as fiber FRQFUHWHWKHYDOXHfy and Es at the point of critical steel stress is replaced by the value fctf and elastic modulus Ef suitable to the material. For two-layer slabs the given geometric, strength, deformation properties of two materials are used. %\WKHFRPELQDWLRQRI(T -(ZHFDQGefine a final ratio for the calculation of current deflection of the slab supported by four sides influenced by evenly distributed load: f f cr q qcr ( ' f cr , qu qcr r where: fcr – slab deflection at the moment of of formation of the first cracks in stretched area of the element; qcr – load, when first cracks were created; qu – load corresponding to the limit of the slab bearing capacity; Thus, the calculated width of deformed area ǻ remains unknown in the (T (7DVDUHVXOWLW is not possible to calculate the value f. In order to solve such problem the following method of finding the desired value of deflection f may be proposed. First of all, a boundary value of the slab deflection is set according to the standards for that class of structures fu=[ f ] apply it in the (T (7f=fu=[ f ]. The (T(7LVVHtWOHG ZLWK UHVSHFW WR YDOXH ǻ DQG WKHQ REWDLQHG result is applied to the (T (WKHUHIRUHREWDLning the deflection at the time of formation of plastic hinges with regard to real-specified parameWHUV$WWKHVDPHWLPHWKHUHVXOWRI(T (7 shows the value of current deflection by introducing the calculated value of width of deIRUPHGDUHDǻ &$/&8/$7,212)'()/(&7,212)21(/$<(5$1'7:2/$<(56/$%6 7KHEDVLVRI/,5$-&$'is represented by the calculation of components and structures by finite element method []. The calculation model of a slab (Fig. is built out of tridimensional finite elements (type ɋȿ-The slab is separated into finite elements according to plan. The sectional area of the slab is composed of OD\HUV PP HDFK. The load is applied in the form of concentrated forces. The distribution of load and supports is accepted as in Fig. 2. a b a 7KHYDOXHRIIFUDQGTFUFDQEHFDOFXODWHGLI the combine (T (7 ZLWK WKH IRUPXOD %+*alerkina [2] IRU VTXDUH SODWHV supported on four sides, the deflection at the center of slabs: b Fig. 4. Calculation diagram of VTXDUH slab influenced by evenly distributed load: a – fracture diagram; b – diagram of disc rotation angle rate f 0, ql . Ei h To determine the width of the deformed zone ǻVODEVDVHULHVRILVRODWHGSRLQWVRQVHYHUDOUesearch graphs deflections. Points are usually preVFULEHGLQWKHRSHUDWLRQDOZRUNLQJORDGUDQJH often – is 0,7...0,8 from destructive load. To find WKHYDOXHǻXVLQJ(TDQGWDNLQJLQWRDccount the specific slabs construction. Results of calculation of one- and two-layer VODEVE\WKHOLPLWHTXLOLEUium method are shown in Fig. 7, 8. Considering complexity of mathematical calculations for slab deflection due to analytical methods [] and unsatisfactory precision of results, a decision was made to do calculations on FRPSXWLQJ PDFKLQH ZLWK D KHOS RI /,5$-&$' bundled software [8]. Fig. 5. Calculation model RIVODELQ/,5$-&$': ɚ± general view; b – side view The ɋȿ-finite element is a universal tridimensional eight-node isoparametric finite element, designed for the calculation of tridimensional constructions. There is a diagram represented in Fig (DFK of finite element nodes has three degrees of variance U, V, W defined with regard to global coordinates X, Y, Z and are linear displacements according to axis, whose positive direction coincides with the direction of coordinate axis. $V a result of modeling, there are ,nodes and ,elements '0<7526025.$/29 Fig. 6. Diagram of ɋȿ-finite element The assumed calculation model makes it possible to change the rigidity of materials for both one-layer and two-layer slabs. The slab calculation was performed in linear position for loads corresponding to loading pitches at testing. Non-linear physical-mechanical properties were taken into consideration by means of changing the elasticity modulus. Initial values of elasticity modulus for concrete and steel fiber concrete were assumed according to [], that is Ec = 22,5·10 MPa, Ecf = ,8·10 MPa. In accordance with recommendations [] the nonlinear behavior of construction is recommended to consider by means of introducing decreasing coefficients: 0,2 – in case of any cracks, or 0,– in case no cracks revealed. That is why during the calculations the decreasing coefficient was 0,before appearance of any cracks and 0,2 – after the first cracks appeared. Reduction of slab rigidity as a result of crack was also considered by means of introducing zero rigidity elements in the tensile area within height of the crack. The rigidity of slab supports was not reduced to avoid forcing through the slab thickness $V a result of calculation of one-layer slabs in /,5$ bundled software, diagrams of deflection of the slab center f of the total pressure Ptot=Pi were obtained, which are presented in Fig. 7. ɚ b Fig. 7. Calculation results for deflection of one-layer slabs of series ȱ grade ɉɎ ɚ and slabs of series ȱȱ grade ɉɁb 1 experimental; 2 – calculation by the OLPLW HTXLOLEULXP PHthod; 3 – FDOFXODWHG LQ /,5$ bundled software When calculating the two-layer slabs, relevant elasticity modulus of material was applied for each slab layer. The value of decreasing coefficients and zero elasticity elements were applied similar to the calculation of one-layer slabs. $V a result of calculation of two-layer slabs by means of /,5$ bundled software, diagrams of deflection of the slab center f of the total pressure Ptot=Pi were obtained, which are presented in Fig. 8. &$/&8/$7,212)'()/(&7,212)21(/$<(5$1'7:2/$<(56/$%6 ɚ b Fig. 8. Calculation results for deflection of two-layer slabs of series ȱȱȱgrade ɉȻɎɚand slabs of series ȱV grade ɉɁɎ b 1 experimental; 2 ± calculation by WKH OLPLWHTXLOLEULXP PHWKRG 3 – FDOFXODWHGLQ/,5$ bundled software CONCLUSIONS *LYHQWKDWWRGD\¶VFRQVWUXFWLRQLQGXstry is represented by the vigorous process of increasing the strength of construction materials, particularly concrete and reinforcement, due to achievements in chemistry, there is a strengthenLQJ RI TXDOLW\ LQGLFDWors of buildings and constructions, in particular bearing construction arrangements. Thus, systems making it possible to work in a multi-axial load state (shell structures, slabs, wall-EHDPV HWF DUH JHWWLQJ PRUH SRSular. There is an opportunity to significantly reduce the cost by reduction of cross-section oper- ational overcuts at the expense of increased strength of materials. The new technologies make it possible to perform the most complex design elements made of any materials. Considering the current trends, it should be noted that the issue of performance reliability for buildings DQG VWUXFWXUHV LV QRW DERXW WKH VWUHQJWK UHTXLUements, but the rigidity of elements and buildings in general. Therefore, the study of rigidity (most commonly the deflections RI H[DPLQHG VODEV seems to be a topical issue. $QRWKHU TXHVWLRQ WKLV ZRUN EHDUV DQ Dnswer to is the feasibility of using multi-layer slabs. From the point of view of rigidity (bendLQJ RI VODEV WKH WZR-layer slabs have an adYDQWDJH WKH\ VKRZ OHss deflections, than the one-layer ones. Considering the higher level of crack resistance of tow-layer slabs, the use of two-layer slabs is absolutely justified. &DOFXODWLRQ E\ D FRPSXWHU XVLQJ /,5$ bundled software provides wide opportunities to deterPLQH ULJLGLW\ GHIOHFWLRQ IRU ERWK VLQJOHlayer and multi-layer slabs owing to computing WHFKQRORJLHV+RZHYHUWKH obtained calculation results indicate a deficiency in accuracy, compared to the experimental data. The fact is that compliance with regulatory guidelines, implemented to consider nonlinear structure operation by introduction of decreasing coefficients, sometimes does not match the actual conditions of slab deformation. Furthermore, there are some doubts as to the correctness of defining the depth crack distribution along the slab height, which determines its actual rigidity. . The comparative analysis of experimental and theoretical diagrams of slab deflection evidences good matching of results. Deviations at maximum loads were as follows: for one-layer slabs of VHULHVȱ (ɉɎ – for slabs of VHULHVȱ, (ɉɁ – for two-OD\HU VODEV RI VHULHV ȱ,, (ɉȻɎ – for slabs RIVHULHVȱ9ɉɁɎ – Such deviation in calculations may be explained by complexity of defining the real rigidity of slabs, i.e. the definition of deformation modulus and the height of crack creation to set the zero rigidity elements. 5()(5(1&(6 Barashykov $<D, Smorkalov D.V., 2014. Calculation of solidity of one-layer and twolayer reinforced concrete slabs supported on four sides. Resource efficient materials, structures, WLRQ RI QHZ JHQHUDWLRQ FRQFUHWHV 7(.$ 0RW(QHUJ5ROQ ;% '0<7526025.$/29 , Issue 9, - LQ8NUDLQH 2. 7. 8. 9. buildings, and constructions: Collected studies. Rivne, , Issue 28, - LQ8NUDLQH. Galerkin B.G., 1933. The resilient thin plate. M, *RVVWURLL]GDW (in RusVLDQ Gorodetsky A.S., Schmukler V.S., Bondarev A.V., 2003. Information Technology of calculation and design of builGLQJ NRQVWUXNWVɿ\ 3URF Manual. Kharkiv 178 .3, (in 5XVVLDQ Gvozdev A.A., 1949. Calculation of bearing capacity E\ OLPLW HTXLOLEULXP PHWKRG Moscow, 6WUR\L]GDW9, 280 (in RusVLDQ =KXUDYVN\L 2.D., Smorkalov D.V., 2002. Methodology and results of experimental studies of two-layer slabs. Steel reinforcement concrete constructions. Research, design, construction, operation: Collected research papers, Issue , Kryvyi Rig, KTU, 2002 LQ8NUDLQH Korolyov A.N. Calculation methods for slab deflections supported on four sides at short-term load. Concrete and reinforcedCollected concrete studies. Vol. , LQ8NUDLQH. , 9- (in RusVLDQ ate. M, Murashev V.I., 1950. Crack resistance, stiffness *RVVWURLL]GDW VLDQ and strength of concrete. M, Mashstroyizdat, ndarev (in RusVLDQ Information Technology of calculaLIRA-CAD 2011. 7XWRULDO(OHFWURQLF(Gition , LQ5XVVLDQ GLQJ NRQVWUXNWVɿ\ 3URF 178 .3, (in Rudenko N., 2010. The development of concep5XVVLDQ WLRQ RI QHZ JHQHUDWLRQ FRQFUHWHV 7(.$ Kom. Calculation of bearing ca0RW(QHUJ5ROQ, Vol. ;%, -. E\ OLPLW HTXLOLEULXP PHWKRG Moscow, Smorkalov D.V., 2003. Crack resistance and 6WUR\L]GDW VLDQ fracture modes for two-layer slabs. Resource ef=KXUDYVN\L 2 , 2002. ficient materials, structures, buildings, and constructions: Collected research papers. studies Rivne, concrete , Issue 9, - LQ8NUDLQH construction, Snyder M. 1972. Factors affecting the flexural Issue , strength of steel fibrous concrete. $&, -RXUQDO, LQ8NUDLQH 9RO VLDQ VLDQ $&,-RXUQDO9RO 1R VLDQ 7XWRULDO(OHFWURQLF(G LQ5XVVLDQ WLRQ RI QHZ JHQHUDWLRQ FRQFUHWHV 7(.$ LQ5XVVLDQ 0RW(QHUJ5ROQ ;% %RQG VWUHQJWK LQ VWHHO LQ8NUDLQH 9RO $&, -RXUQDO VLDQ $&,-RXUQDO9RO 1R ɊȺɋɑȿɌɉɊɈȽɂȻɈȼ Snyder M. 1972. Factors affecting the flexural ɈȾɇɈofɂȾȼɍɏɋɅɈɃɇɕɏɉɅɂɌ strength steel fibrous concrete. $&, -RXUQDO, ɈɉȿɊɌɕɏɉɈɄɈɇɌɍɊɍ , 9RO, No. 2, - SP 52-103-2007, 2007. Code of practice on deȺɧɧɨɬɚɰɢɹ ɪɟɡɭɥɶɬɚɬɵ sign and ɉɪɢɜɟɞɟɧɵ construction. ɦɟɬɨɞɢɤɚ Reinforcedɢconcrete castɷɤɫɩɟɪɢɦɟɧɬɚɥɶɧɵɯ ɢɫɫɥɟɞɨɜɚɧɢɣ in-place constructions of buildings. ɩɪɨɝɢɛɨɜ Moscow, ɨɞɧɨɫɥɨɣɧɵɯ ɢ ɞɜɭɯɫɥɨɣɧɵɯ ɩɥɢɬ ɩɨɞ ɞɟɣɫɬɜɢɟɦ 2007 (in RusVLDQ ɩɨɩɟɪɟɱɧɨɝɨ ɤɪɚɬɤɨɜɪɟɦɟɧɧɨɝɨ Stages A., 1981. Ring fiber reinforcedɧɚɝɪɭɡɤɢ concrete. Ɋɚɫɫɱɢɬɚɧɵ ɩɪɨɝɢɛɵ ɩɥɢɬ ɫɩɨɫɨɛɨɦ ɨɫɧɨɜɚɧɧɨɦ $&,-RXUQDO9RO 1R - ɧɚ ɩɪɟɞɟɥɶɧɨɝɨ ɪɚɜɧɨɜɟɫɢɹ ɢ ɦɟɬɨɞɨɦ ɦɟɬɨɞɟ ACI Journal. 1973. State-of-the-art report on fiɤɨɧɟɱɧɵɯ ɷɥɟɦɟɧɬɨɜ ɫ ɩɨɦɨɳɶɸ ɩɪɨɝɪɚɦɧɨɝɨ ber reinforced concrete, , Vol. 70, 729- ɤɨɦɩɥɟɤɫɚ ɅɂɊȺ ɫɪɚɜɧɟɧɢɹ Tarasov V.P., 1974. ȼɵɩɨɥɧɟɧɵ The use of fiber-reinforced ɷɤɫɩɟɪɢɦɟɧɬɚɥɶɧɵɯ ɢ ɬɟɨɪɟɬɢɱɟɫɤɢɯ ɪɟɡɭɥɶɬɚɬɨɜ concrete in construction. Industrial construction. ɪɚɫɱɟɬɚɩɪɨɝɢɛɨɜɩɥɢɬ , Vol. 7, - LQ5XVVLDQ Ʉɥɸɱɟɜɵɟ ɫɥɨɜɚ ɩɥɢɬɚ ɩɪɨɝɢɛ ɫɬɚɥɟɮɢɛɪɨ Tattersall G.H., 1974. %RQG VWUHQJWK LQ VWHHOɛɟɬɨɧ fibre-reinforced concrete. Journal of Concrete Research. Vol No. 87, - ɊȺɋɑȿɌɉɊɈȽɂȻɈȼ ɈȾɇɈ- ɂȾȼɍɏɋɅɈɃɇɕɏɉɅɂɌ ɈɉȿɊɌɕɏɉɈɄɈɇɌɍɊɍ Ⱥɧɧɨɬɚɰɢɹ. ɉɪɢɜɟɞɟɧɵ ɦɟɬɨɞɢɤɚ ɢ ɪɟɡɭɥɶɬɚɬɵ ɷɤɫɩɟɪɢɦɟɧɬɚɥɶɧɵɯ ɢɫɫɥɟɞɨɜɚɧɢɣ ɩɪɨɝɢɛɨɜ ɨɞɧɨɫɥɨɣɧɵɯ ɢ ɞɜɭɯɫɥɨɣɧɵɯ ɩɥɢɬ ɩɨɞ ɞɟɣɫɬɜɢɟɦ ɩɨɩɟɪɟɱɧɨɝɨ ɤɪɚɬɤɨɜɪɟɦɟɧɧɨɝɨ ɧɚɝɪɭɡɤɢ Ɋɚɫɫɱɢɬɚɧɵ ɩɪɨɝɢɛɵ ɩɥɢɬ ɫɩɨɫɨɛɨɦ ɨɫɧɨɜɚɧɧɨɦ ɧɚ ɦɟɬɨɞɟ ɩɪɟɞɟɥɶɧɨɝɨ ɪɚɜɧɨɜɟɫɢɹ, ɢ ɦɟɬɨɞɨɦ ɤɨɧɟɱɧɵɯ ɷɥɟɦɟɧɬɨɜ ɫ ɩɨɦɨɳɶɸ ɩɪɨɝɪɚɦɧɨɝɨ ɤɨɦɩɥɟɤɫɚ ɅɂɊȺ ȼɵɩɨɥɧɟɧɵ ɫɪɚɜɧɟɧɢɹ ɷɤɫɩɟɪɢɦɟɧɬɚɥɶɧɵɯ ɢ ɬɟɨɪɟɬɢɱɟɫɤɢɯ ɪɟɡɭɥɶɬɚɬɨɜ ɪɚɫɱɟɬɚɩɪɨɝɢɛɨɜɩɥɢɬ. Ʉɥɸɱɟɜɵɟ ɫɥɨɜɚ ɩɥɢɬɚ ɩɪɨɝɢɛ ɫɬɚɥɟɮɢɛɪɨɛɟɬɨɧ TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 169–174 Working of Deep-Water Minerals with Sectored Way Mykhailo Sukach Kyiv National University of Construction and Architecture Povitroflotskyy prosp., 31, Kyiv, Ukraine, 03680, e-mail: [email protected] Received December 09.2014; accepted December 19.2014 Summary. The article presents the problems of obtaining the bottom minerals from the depth of water. The sectored way of working mine is suggested and schemes of movement of the bottom mining are proposed. The calculations are done of movement trajectory of the carriage and length of the hose-cable of the mining machine, taking into account the turn inside and outside the sector. Key words: deep-water minerals, sectored way, movement trajectory, hose-cable, concretions. INTRODUCTION The geological investigations performed in the central areas of oceans during the last decades, allowed to made it possible to investigate the promising for industrial developPHQWVDUHDVRISRO\PHWDORUHDFFXPXODWLRQV±FRQFUHWLRQV ±SULPDULO\LQWKHUHJLRQRI&ODULRQ&OLSSHUWRQRQWKH3DFL¿F RFHDQ>@2QWKHUHJLRQDOVWDJHRIWKHJHRORJLFDO survey the deposits with overall density of concretions ocFXUUHQFHDUHLGHQWL¿HGXSWRNJɦ2WKDWFRQWDLQ the industrial concentration of manganese, nickel, copper DQGFREDOW>@ $WWKHVDPHZD\WKHWHFKQRORJ\DQGWHFKQLFDOZD\V needed for the survey and experimental testing stages of works were developed: collection of concretions and lift to watercraft, pre-processing, storage and handling of the H[WUDFWHGPDVVWRWKHRUHWUDQVSRUWLQJVKLS>@ The conditions of concretions occurrence are complex DQGXQLTXH±LWLVWKHGHSWKRIɦORZFDUU\LQJFDSDFLW\RIVHGLPHQWVELJTXDQWLW\RIURFN\H[LWVDQG FDYLWLHV YDULDEOH FRQ¿JXUDWLRQ RI VHGLPHQWDWLRQV 7KH DERYHVSHFL¿HGIDFWRUVVLJQL¿FDQWO\DIIHFWHGWKHRSHUDWLRQ of the survey, pilot-testing machines and machinery at the ERWWRP>@,QVXFKFRQGLWLRQVLWLVUHDVRQDEOHWR SHUIRUPWKHH[SORLWDWLRQZRUNVXVLQJWKH¿[HGRULQDFWLYH mountain reconnaissance complexes, that include the eleva- tion system that interacts with base bottom module of collection aggregate and fast moving gathering working parts. The latter are connected to base unit hose cable which provides transportation of the extracted rock mass and energy supply to drive the carriage of the gathering working ERG\>@ 385326(2)7+($57,&/( The research aimed at the grounding of the possibility of the technological scheme of clearing excavation by sector ways with any predetermined or regulated angle of discloVXUHRIVHFWRU$WWKDWWZRRSWLRQVRIFDUULDJHWUDMHFWRULHV ZHUHRIIHUHG±ZLWKDWXUQLQVLGHWKHVHFWRURUEH\RQGLWV FRQWRXUV)LJ 5(6($5&+$1'&$/&8/$7,216 The carriage can maneuver at some distance from base module, the maximum radius depends on the length of hose-cable that is reeled from the coil. To determine the DPRXQWRIWLPHQHHGHGIRUWKHSURFHVVLQJLWLVUHTXLUHGWR identify the area of sector and the length of the way travelled E\WKHFDUULDJHZKHUHDVIRU¿QGLQJWKHYROXPHRIH[WUDFWLRQ ±WKHDPRXQWRIFRVWVRQWKHXQSURFHVVHGDUHDVRIWKHVHFWRU During the work of carriage with turn inside the sector contours on each operation cycle of the part of circle with width BLQVLGHWKHVHFWRUZLWKDQJOHĮLVSURFHVVHG$WWKH HQGRIWKHVWULSWKHFDUULDJHLVWXUQHGPRUHRYHUWKH hose-cable is reeled to the length B WKDWHTXDOVWKHZLGWKRI FDUULDJHDQGWKHQH[WRSHUDWLRQF\FOHVHH)LJ 7KHLQLWLDOGDWDIRUFDOFXODWLRQĮ±WKHDQJOHRIWXUQRI sector; B±ZLGWKRIFDUULDJHLm±OHQJWKRIKRVHFDEOHRU maximum radius, passed by the carriage; L0±UDGLXVRIWKH base module of collecting aggregate. Needed parameters: 0<.+$,/268.$&+ K±QXPEHURIRSHUDWLRQF\FOHVR0±PLQLPDOUDGLXVVWDUWLQJ age of the developed area; L±ZD\SDVVHGE\WKHFDUULDJH from which the carriage maneuver is possible; S±SURFHVVHG D±VSHFL¿FDUHDLHWKHDUHDUHGXFHGWRWKHXQLWRIZD\ GHYHORSHGDUHDS*±IXOODUHDRIWKHVHFWRUE±SHUFHQW- passed by the carriage. Fig. 1. Calculated scheme of carriage motion trajectory with turns into a sector: I –not processed areas; II - IV – processed zones, from them II – in the first measure, III – on intermediate measures, IV – on the last measure; V –carriage motion trajectory Fig. 2. Calculation scheme of carriage motion trajectory with turns out of sector: I – not processed space; II –carriage motion trajectory; III – superfluous areas; IV – processed areas :25.,1*2)'((3:$7(50,1(5$/6:,7+6(&725(':$< $WHDFKLQWHULPoperation cycle the carriage rotates 180° from point Ai to Ⱥ ɚnd the length of hose-cable increases by width of the S* (DL2m . carriage ȼ; then the carriage moves from point 2 Ⱥ to point Ai , in the result of which the Number of operation cycles of carriage: hose-cable rotates at the angle: Full area of sector: K ' ( Lm L0 B . Mh Į arcsin Minimal radius of carriage turn: R0c B B arcsin , R BR Lm KB . where: R – distance from the carriage to the point of mantling of hose-cable to base module of collecting aggregate. For the full turn of carriage inside the On each operation cycle the center of carsector the following conditions are reTXLUHG riage passes the way: M cr M2 cr d D , where: M cr M2 cr arcsin B ( R0 B , arcsin B ( R0 2BE . Į arcsin B (R0 B) . (R0 B/ 2 )Min , SURFHVVHGGHYHORSHGDUHD: S in > Sh > @ @ $WWhe last step of the operation cycle after the processing of the land, the area of which is determined by (T ( (the hose-cable rotates at the angle: Mc arcsin B . Lm $WWhat the carriage passes the way: Lc Sc (R0 B) 2 R02 M in . 2 2 B (R BE 2 R 2 M h . 2ʌ 2 (Lm B/ 2 ) Mc . $QGWKHODQGLVSURFHVVHG: Center of carriage moves the way: Lin S B 2 ( R0 B / 2 M h . The processed area makes up: $WWKDW R0 R0/ B is used so that to satisfy the condition , in this case K K '[ , where [ safety factor. Note, that with K' 0 processing is not possible, and with K ' only one operation cycle is processed. In the latter case, K is FRQVLGHUHGHTXDO Ʉ , and R0 R0c . In the first operation cycle the carriage is moved from position A0 to position A; +RVH-cable is turned (rotatHGat the angle: Min Lh > @ 2 Lm ( Lm B) 2 M ê . 2 The total way and area (L ɿ S one calculates as sum of corresponding sizes of areas on the initial, all the intermediate ones and the final operation cycle. The percentage of the processed area: E S / S * , 0<.+$,/268.$&+ specific area: D L S / L. ( R0 B / 2D ( R0 B / 2 BD ... [ R0 B / 2 ( K B]D K ( 2 R0 KB . 2D With work of carriage with turn outside the contours of sector with angle Įon each operation cycle the carriage processes the part of the ([WUDZD\RUZD\SDVVHGIRUWKHturn: circle with width ȼ (see Fig. $W WKDW WKH part of the hose-FDEOHWKDWHTXDOVWKHZLGWKRI B ( L K S . the carriage operation cycle is reeled from the 2 coil placed on the base module of collecting carriage. ([WUDZD\, passed by carriage : When you save the similar to the above considered variant output data, you need to L , EL add to thH GHVLUHG VHDUFKHG SDUDPHWHUV WKH L L following: S area, processed by the carriage outside the contours of the sectors (extra area ȿ percentage of extra area; L extra way specific area: and ȿ percentage of extra way. S In this case the full area of sector, the numD . L L ber of operation cycles and minimal radius are accordingly determined with (T ( Mathematical model is doneis fordone collecting that Mathematical model foraggregate collecting Useful area, processed with aggregate,: S 2 ( Lm R02 . 2D ([WUDVSDFHDWWKDWLV: S ( K 2 B . 2S processes with sector scheme the ore deposits with complex FRQ¿JXUDWLRQZLWKELJTXDQWLW\RIREVWDFOHVRQWKHERWWRPOLNH URFN\H[LWVDQGFDYLWLHVHWF%\PHDQVRIFRPSXWHUSURJUDP ZLWK ELJ TXDQWLW\ RI REVWDFOHV RQ WKH ERWWRP the following values are calculated; K, R0, S, S*, S, E, E, L, HWF%\PHDQVRI L, ȿL, D IRUDQJOHVĮ ZLGWKRIFDUULDJHVHL]LQJ ȼ ɦZLWKOHQJWKRIKRVHFDEOHLm ɦ +DQGSURGXFWLYLW\RIPLQLQJFRPSDQ\ZLWKPLOOLRQ ȿ of concretions Į can obtain minerals with minimal losses by using as part of the collection aggregate of lightweight highȼ ɦ speed carriage, that has to be characterized by coordinating ɦ connection with the base module. +DQGSURGXFWLYLW\RIPL Since processing of K operation cycles one needs to perform (K – of turns. The percentCONCLUSIONS age of processed area in the sector is determined with expression ,QWKHGHSWKRIWKHRSHQRFHDQWKHUHDUHELJDUHDVZLWK concretions lying on the bottom surface with increased The percentage of extra areas processed by XSWRNJɦ2GHQVLW\0LQLQJFRQGLWLRQVRIWKHVH the carriage : E S . S S The way passed by the carriage consists of segments of way with useful processing and ways passed for rotation. Useful way is calculated with the formula: deposits are notably hard due to prominence of landforms and the presence of rocky exits. 'XHWRWKHQHFHVVLW\RIFKRRVLQJHTXLSPHQWDQGWHFKnology of sewage treatment works, the organization of excavation works with the scheme with sedentary colOHFWLRQXQLWEDVHPRGXOHDQGIDVWPRYLQJH[FDYDWLRQ XQLWSLFNXSLVVXJJHVWHG 7KHGHWHUPLQDWLRQRISDUDPHWHUVRIPLQHUDOVH[WUDFWLRQ LVJLYHQEDVLQJRQWKHH[WUDFWLRQRIPRUHWKDQPLOORI concretions per year with their minimal losses by means of usage of coordinating connection between the pickup and base module with sector scheme. 7KHPDWKHPDWLFDOPRGHOLVJLYHQDQGNH\SDUDPHWHUVRI sector method of concretions pickup are calculated. :25.,1*2)'((3:$7(50,1(5$/6:,7+6(&725(':$< 5()(5(1&(6 Bakurov G., 1988. Ships for deep-water mountain geoORJLFDOUHVHDUFKHV0RVFRZ6KLSEXLOGLQJʋ 2. Ferromanganese concretions of the central part of WKH3DFL¿FRFHDQ1986.8QGHUHGLWLQJ,2ɆXUGPDD 1ɋ6NRUQLDNRYD0RVFRZ1DXND Fouco I., 1982.0RGHUQVWDWHRIWHFKQLTXHRIERRW\RI GHHSZDWHUIHUULPDQJDQHVHFRQFUHWLRQVȼɐɉʋȿ 0RVFRZLVW)XVHQ9RO 1XURN*%UXMDNLQ<X%XELV<XDQGRWKHU. Mining technology from the bottom of lakes, seas and oceans. 0RVFRZ1HGUD 2JRURGQLNRYɋɉ+\GURPHFKDQL]DWLRQRIGHYHORSPHQWRIVRLOV0RVFRZ6WUR\L]GDW 3DVFKNLQ9,DNRYOHY3ɋRNRORY9. Dredging, ɪɟɮɭɥɟɪɧɵɟDQGɝɢɞɪɨWKHPHFKDQL]HGZRUNVWUDLQDLG 2GHVD$VWURSULQW 7. 6FKQLXNRYȿ=LERURY$ Mineral riches of the %ODFNVHD.\LY1$18 8. Shkaryvsky G., 2014.(VWLPDWLRQRILQÀXHQFHVWUXFWXUally of layout charts of power facilities on completing RIDJJUHJDWHVRQWKHLUEDVH0RWURONRP0RW(QHUJ 5ROQ2/3$19RO1R 9. Sukach M., 2004%RRW\DQGSRUWDJHRIRFHDQPHWDORI containing crusts. Industrial hydraulic and pneumatic, 9RO Sukach M., 2004.:RUNÀRZVRIGHHSPDFKLQHV.\LY 1DXNRYDGXPND Sukach M., 2012'HHSZDWHUWHFKQLTXHDQGWHFKQRORJ\ for development of minerals of the World ocean. Labours 9,,67.³(QHUJLD´6LPIHURSRO$OXSND Sukach M., 2012. Problems of booty of hard minerals from the bottom of the World ocean. Motrol: kom. Mot. (QHUJ5ROQ2/3$19RO Sukach M., 2013.3URVSHFWVRIɪɚɡɪɚɛɨɬɤɢRIPDULQH deposits of mineral raw material. Innovations in science are innovations in education: collection of labours. Ju5*3813,1RYRFKHUNDVVN Sukach M., 2013. Research and development deep-waWHUERRW\WHFKQLTXH.\LY*%'009RO Sukach M., Lysak S., Sosnowski S., 2010. Kinematic DQDO\VLVRIWKHZRUN±LQJSURFHVVRIWUHQFKHU7(.$ NRP0RW(QHUJ5ROQ2/3$19RO; Sukach M., Lytvynenko I., Bondar D., 2009. System of the automated management and measuring of parameters RIWHFKQRORJLFDOSURFHVVHV0RWURONRP0RW(QHUJ 5ROQ2/3$19RO% Technical instructions on the production of the marine dredging, 1986ɊȾ0RVFRZ:60RUWHFKLQIRUPUHNODPD =LERURY$ To obtain or not obtain the black Sea VDSURSHOVLQ8NUDLQH*HRORJ\DQGPLQHUDOVRIWKH:RUOG RFHDQ9RO =LERURY$. 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COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 175–180 Comparison of the Usefulness of Cluster Analysis and Rough Set Theory in Estimating the Rate of Mass Accumulation of Waste in Rural Areas Tomasz Szul, Krzysztof Nęcka Department of Power Engineering and Agricultural Processes Automation, Agricultural University of Cracow Balicka Str. 116B, 30-149 Kraków, Poland, e-mail: [email protected] Received December 01.2014; accepted December 17.2014 Summary. The study shows the comparison between k-means and EM methods of clustering and the rough set theory as far as determining the rate of mass accumulation of waste in rural areas is concerned. Performed comparative analyses reveal that WKHDYHUDJHPHDQDEVROXWHSHUFHQWDJHHUURU±0$3(IRUk-means and EMDOJRULWKPUDQJHGEHWZHHQDQGIRUWKHWUDLQLQJ VHWDQGEHWZHHQDQGIRUWKHWHVWVHW7KHURXJKVHW WKHRU\ZDVFKDUDFWHULVHGE\DPXFKEHWWHUTXDOLW\RISURJQRVLV IRUZKLFK0$3(YDOXHHVWDEOLVKHGIRUWKHWHVWVHWZDV Key words: cluster analysis, households, waste, rough set theory. INTRODUCTION $PHQGPHQWVWRWKH$FWRQ0DLQWDLQLQJ&OHDQOLQHVV DQG2UGHULQWKH0XQLFLSDOLWLHVRI6HSWHPEHUHQWHUHGLQWRIRUFHLQ-DQXDU\DQGZHUHDJDLQDPHQGHGLQ -DQXDU\>FRQVROLGDWHGWH[W-RXUQDORI/DZVRI LWHP@7KHVHFKDQJHVUHYROXWLRQLVHGZDVWHPDQDJHPHQW V\VWHP$FFRUGLQJWRWKHDPHQGPHQWVWKHPXQLFLSDOLWLHV became owners of waste and as such took control over waste PDQDJHPHQWLQWKHLUDUHDV:DVWHPDQDJHPHQWUHTXLUHV FRQVLGHUDEOH¿QDQFLDOUHVRXUFHVZKLFKDUHHVWLPDWHGDW 3/1±PLOOLRQSHU\HDULQ3RODQGZKLFKFRQVWLWXWHV ±RIDOOWKHHQYLURQPHQWDOH[SHQGLWXUHV>.RQLHF]QD .XOF]\FND@$SDUWIURPHFRQRPLFFULWHULDWKHFUHDWLRQ of waste management system has to encompass also the criteria of social acceptability and ecological effectiveness. The basis of rational waste management planning is the rate of waste accumulation, whose proper selection is the PRVWLPSRUWDQWWDVNRIWKHSODQQLQJVWDJH>.HPSD@ 7KHDPRXQWRIJHQHUDWHGZDVWHLVLQÀXHQFHGE\HFRQRPLF social and infrastructural factors. Determining the groups of elements that affect the change in the amount of generated waste is not enough, as it is not known how strong their LQWHUDFWLRQVDUH>0DOLQRZVNLHWDO7DáDáDM6]XO HWDO@,QWKHFKRLFHRIDPHWKRGDOORZLQJWRGHYHORS a model that predicts the amount of generated waste and is the basis of management planning in a given area, a municipality, should take into account a number of features, which ZLOOH[SHFWHGO\KDYHDQHVVHQWLDOHIIHFWRQWKH¿QDORXWFRPH 'XHWRGH¿QLQJDQXPEHURIIHDWXUHVLHPXWXDOO\FRUUHODWHG TXDQWLWDWLYHDQGTXDOLWDWLYHYDULDEOHVLWLVDQLQWHUHVWLQJ alternative to apply methods using cluster analysis and the rough set theory. Methods of cluster analysis are often used in objects and features clustering. This concept was introduced by 7U\RQLQ&XUUHQWO\WKLVWHUPLQFOXGHVPDQ\GLIIHUHQWDOJRULWKPVRIFODVVL¿FDWLRQ>+DUWLJDQ+DUWLJDQ :RQJ1ĊFND6QHDW6RNDO:DUG :LWWHQ)UDQN@DPRQJZKLFKWKHSRSXODURQHVDUH k-means and EMDOJRULWKPV*HQHUDOO\LWFDQEHVDLGWKDW cluster analysis is an exploratory analysis of data, aiming at extracting objects from a large set in such a way that elements belonging to one group are as homogenous as possible within particular groups and as different as possible from objects belonging to other groups. Cluster analysis methods allow to identify structures present in a set, but they do not explain the mechanism of their creation. $FODVVLFk-means clustering algorithm was popularised E\+DUWLJDQ>+DUWLJDQ+DUWLJDQ:RQJ@'XULQJLWVLPSOHPHQWDWLRQDVWKH¿UVWVWHSREVHUYDWLRQVDUH randomly allocated to an established k number of clusters. Next, observations are transferred between the clusters in VXFKDZD\WKDWWKHPHDQVLQWKHFOXVWHUVIRUDOOYDULDEOHV DUHDVGLIIHUHQWIURPRQHDQRWKHUDVSRVVLEOH$VWKHRSWLPDO number of clusters is not known, it has to be determined by an expert or on the basis of the developed algorithms. Usually the number of clusters is selected with the use of v-fold cross validation algorithm. The idea of this method is to divide the whole sample into v subsets, and then, the same analysis is in turn performed on the observations of v-1 subsets, i.e. on the so-called training sample. Next, the results of the analysis are applied to the data of the training 720$6=6=8/.5=<6=72)1ĉ&.$ sample, which had not been so far used in the analysis, and ZHOODVV\VWHPVRIIHDWXUHDQGFODVVL¿FDWLRQUHFRJQLWLRQ the measure of predictive power is determined on its basis. The results of theoretical study within RST involve logics, The results of v repetitions are aggregated and give one VHWWKHRU\NQRZOHGJHUHSUHVHQWDWLRQGDWD¿OWHULQJDOJRULWKassessment of the model’s stability, i.e. its ability to predict mic problems connected with information systems [Nguyen new observations. 6HPHQLXN3ROVNRZVND@$OWKRXJKGHYHORSHG $QRWKHUSRSXODUSURFHGXUHLVEM method cluster anal- a short time ago, rough set theory is used in a number of new ysis, whose detailed description was presented by Witten ¿HOGVRIVWXG\1RZDGD\VLWLVXVHGERWKLQPHGLFLQHSKDUand Frank [2000]. This algorithm calculates the probabil- macology, economics, banking, chemistry, sociology, acousity of cluster membership, with the assumption of one or tics, linguistics, general engineering, neuroengineering as many probability distributions. The aim of the algorithm well as in the diagnostics of machines, geography, land manis to maximise the general probability for a given division DJHPHQWDQGHQYLURQPHQWDOHQJLQHHULQJ±WKHSXEOLFDWLRQV into clusters. The advantage of EM algorithm over k-means RIUHVXOWVFDQEHIRXQGLQWHUDOLDLQ>%RQGDU1RZDNRZVND %RQGDU 1RZDNRZVND'HMD+DFKRá%RQGDU %RQGDU 1RZDNRZVND'HMD+DFKRá%RQGDU DOJRULWKPLVWKHIDFWWKDWLWFDQEHXVHGERWKIRUTXDQWLWDWLYH 'HMD+DFKRá%RQGDU1RZDNRZVNDDQG5HLQ 0UyĪHN 3áRQND 3DZODN %RQGDU 1RZDNRZVND'HMD+DFKRá%RQGDU DQGTXDOLWDWLYHYDULDEOHV KDUG.RPRURZVNLHWDO0UyĪHNDQG3áRQND 0UyĪHN 3áRQND 3DZODN $QRWKHUPHWKRGLVWKHURXJKVHWWKHRU\ZKLFKZDVLQ- 6NRZURQ 3DZODN3RONRZVNLDQG6NRZURQ5HQLJLHU 5HQLJLHU 5HQLJLHU %LáR]RU DQG 0UyĪHN%LáR]RU 3áRQND 3DZODN 6NRZURQ 5HQLJLHU %LáR]RU 5HQLJLHU %LáR]RU DQG WURGXFHGLQWKHVE\SURIHVVRU=G]LVáDZ3DZODN>@ 5HQLJLHU%LáR]RU5HQLJLHU%LáR]RUDQG%LáR]RU %LáR]RU 5HQLJLHU :LĞQLHZVNL %LáR]RU 6áRZLĔVNL %LáR]RU DQG 6NRZURQ %LáR]RU 5HQLJLHUDQG 5HQLJLHU 5HQLJLHU %LáR]RU DQG :LĞQLHZVNL 6áRZLĔVNL It is a relatively new mathematical method of%LáR]RU data analysis. 5HQLJLHU%LáR]RUDQG:LĞQLHZVNL6áRZand %LáR]RU 5HQLJLHU %LáR]RU DQG :LĞQLHZVNL 6áRZLĔVNL It is used as a tool for the synthesis of advanced effec- LĔVNL6]XOHWDO@ tive analyses methods and for the reduction of data sets >0XUXV]NLHZLF]@5RXJKVHWVVHUYHDVDPHWKRGRORJ\ in the process of discovering knowledge in databases. This 0(7+2'2/2*< process is usually both iterative and interactive (a lot of 0(7+2'2/2*< 0(7+2'2/2*< GHFLVLRQVDUHPDGHE\WKHXVHU>6RGáDFNL@7KHURXJK The research was limited to two commonly used meth0(7+2'2/2*< VHWWKHRU\LVYHU\VLJQL¿FDQWLQWKHSURFHVVRIGDWDH[WUDFWLRQ ods of cluster analysis, i.e. k-means and EM methods. In due to the fact that it is one of the fastest developing areas both the methods, calculations began with dividing objects RIDUWL¿FLDOLQWHOOLJHQFH,WLVXVHGWRGHVFULEHLPSUHFLVH into the training and test set, then input variables were standuncertain knowledge, to model decision-making systems ardised and the number of clusters established. V-fold cross DQGDSSUR[LPDWHUHDVRQLQJ>6HPHQLXN3ROVNRZVND@ validation was performed in order to establish an optimal Methodology of deduction that uses rough set theory 1H[W³*HQHUDOLVHGFOXVWHUDQDO\VLV´PRGXOHDYDLODEOHLQ refers QXPEHURIFOXVWHUV1H[W³*HQHUDOLVHGFOXVWHUDQDO\VLV´ 1H[W³*HQHUDOLVHGFOXVWHUDQDO\VLV´PRGXOHDYDLODEOHLQ RQO\WRWKHTXDOLWDWLYHQDWXUHRIWKHREMHFWV¶IHDWXUHV7KLV module available in Statistica 10.0 program was used. It 1H[W³*HQHUDOLVHGFOXVWHUDQDO\VLV´PRGXOHDYDLODEOHLQ FDXVHVOLPLWDWLRQVDQGGLI¿FXOWLHVZKHQZHGHDOZLWKTXDQWLtransferred objects between these clusters in such a way as WDWLYHDQGQRWTXDOLWDWLYHIHDWXUHV,QVXFKDFDVHWKHLQWHJUD- to minimise variability within the clusters and maximise tion of valued tolerance relation proves useful [Stefanowski variability between the clusters. The following distances DQG7VRXNLDV@,WDOORZVWRLQWURGXFHPRUHÀH[LELOLW\ were set while performing analyses with k-means method: to the rough set theory when examining data(XFOLGHDQGLVWDQFH and to analyse (XFOLGHDQGLVWDQFH±JHRPHWULFGLVWDQFHZLWKLQDPXO(XFOLGHDQGLVWDQFH REVHUYDWLRQVH[SUHVVHGLQDTXDQWLWDWLYHIRUP7KLVFRXUVHRI tidimensional space: (XFOLGHDQGLVWDQFH action is aimed at selecting the most important conditional 2 σQ ൫X -Y ൯ attributes which are necessary to make the right decision (XFOLGHDQGLVWDQFH = ට (XFOLGHDQGLVWDQFH ටσQi=1൫ i i ൯ in individual decision-making subgroups [Renigier 2008]. Q ට σ ൫ (XFOLGHDQGLVWDQFH ൯ Standard assumption of the rough set theory is based ondistance the – 0DQKDWWDQGLVWDQFH±VXPRIGLIIHUHQFHVPHDVXUHGDORQJ sum of differences measured along dimensions: LQGLVFHUQLELOLW\UHODWLRQFRQFHSWDVDSUHFLVHHTXLYDOHQFH dimensions: Q Q relation, which means that the objects will be indiscernible ȁ 0DQKDWWDQGLVWDQFH ȁ Q RQO\ZKHQWKH\KDYHVLPLODUDWWULEXWHV±V\VWHP$S 0DQKDWWDQGLVWDQFH = ȁX i -Yi ȁ ȁ 0DQKDWWDQGLVWDQFH ȁ plication of valued tolerance relation to the rough set theory i=1 LWLVXVHGZKHQZHZDQWWRGHILQHWZRREMHFWVDVÄGLIIHUHQW´ZKHQWKH\ allows determination of the upper and lower approxima&KHE\VKHYGLVWDQFH±LWLVXVHGZKHQZHZDQWWRGH¿QH – LWLVXVHGZKHQZHZDQWWRGHILQHWZRREMHFWVDVÄGLIIHUHQW´ZKHQWKH\ tion of a set with different levels of indiscernibility relation WZRREMHFWVDVÄGLIIHUHQW´ZKHQWKH\GLIIHULQRQHGLPHQLWLVXVHGZKHQZHZDQWWRGHILQHWZRREMHFWVDVÄGLIIHUHQW´ZKHQWKH\ >G¶$PDWR@2ZLQJWRWKLVVROXWLRQRQHFDQFRPSDUH sion: ȁ dimension: &KHE\VKHYGLVWDQFH ሺܺǡ ܻሻ PD[ȁ WZRVHWVRIGDWDDQGDFKLHYHDUHVXOWLQWKHUDQJHZKLFK ȁ &KHE\VKHYGLVWDQFH ሺܺǡ ܻሻ PD[ȁ constitutes the level of indiscernibility relation. This range is &KHE\VKHYGLVWDQFH ሺܺǡ ܻሻ PD[ȁXi -Yi ȁ a membership function derived from the assumptions of the $VWKHQH[WVWHSWKHVHPHWKRGVZHUHFRPSDUHGZLWKWKHFDOFXODWLRQVXVLQJWKHURXJK $VWKHQH[WVWHSWKHVHPHWKRGVZHUHFRPSDUHGZLWKWKHFDOFXODWLRQVXVLQJWKHURXJK IX]]\VHWWKHRU\7KHFORVHUWKHUHVXOWWRWKHPRUHVLPLODU $VWKHQH[WVWHSWKHVHPHWKRGVZHUHFRPSDUHGZLWK $VWKHQH[WVWHSWKHVHPHWKRGVZHUHFRPSDUHGZLWKWKHFDOFXODWLRQVXVLQJWKHURXJK DUHWKHREMHFWVLQGLVFHUQLEOHZLWKUHJDUGWRWKHDQDO\VHG the calculations using the rough set theory, whose detailed attribute, and the closer the result to 0, the more discernible methodology alia in the following stud3DZODN %LáR]RUwas presented inter @ 3DZODN LHV>3DZODN5HQLJLHU%LáR]RU6]XOHWDO@ %LáR]RU @ WKH\DUH>5HQLJLHU%LáR]RUD5HQLJLHU%LáR]RU 3DZODN %LáR]RU @ %LáR]RU6WHIDQRZVNL@ In this method, municipalities selected for analysis were The rough set theory is a certain theory of knowledge divided in a way analogous to the analysis of clusters into WKHRU\RILQIRUPDWLRQV\VWHPVDQGVHUYHVDVDWRROIRU two subsets: the training set and the test set. Objects within describing uncertain, imprecise knowledge, for modelling the training set were presented in the form of a decision table approximation reasonings and decision making systems as where the features characterising the municipalities were ¦ &203$5,6212)7+(86()8/1(662)&/867(5$1$/<6,6 p described with condition attributes. The decision attribute n di di MAPE ¦ of the rate of mass accumulation of waste in households, n i di kg·(person·\HDU-1 was also established. Next, the matrix RIÄYDOXHGWROHUDQFHUHODWLRQ´ZDVFDOFXODWHGIRUFRQGLWLRQ where: attributes: di±WKHUDWHRIPDVVDFFXPXODWLRQRIZDVWHLQWKHKRXVH- KROGVNJāSHUVRQā\HDU-1’ · § n p R j ( x, p max¨¨ ¦ R j ( x, p ¸¸ di ±SUHGLFWHGUDWHRIPDVVDFFXPXODWLRQRIZDVWHLQWKH ¹ ©j KRXVHKROGVNJāSHUVRQā\HDU-1. where: 5(68/7 Rj ±YDOXHGWROHUDQFHUHODWLRQ x±DWWULEXWHRIWKHFRQVLGHUHGREMHFW 5(68/76 $QDO\VHV SUHVHQWHG LQ WKH VWXG\ ZHUH SHUIRUPHG RQ WKH EDVLV RI VWDWLVWLFDO GDWD IURP p±DWWULEXWHEHORQJLQJWRWKHFRQGLWLRQDOSDUWRIWKHFRQsidered decision rule, $QDO\VHVSUHVHQWHGLQWKHVWXG\ZHUHSHUIRUPHGRQWKH 0DáRSROVND 9R >*86 'XULQJ WKLV WLPH LQ WKH DQDO\VHG DUHD where EDVLVRIVWDWLVWLFDOGDWDIURP0DáRSROVND9RLYRGHVKLSRI max(0, min(c j ( x c ( y k max((c WKRXVDQG j ( x c ( y 0J RI ZDVWH ZDV JHQHUDWHG ZKLFK FRQVWLWXWHV >*86@'XULQJWKLVWLPHLQWKHDQDO\VHGDUHD R j ( x, y k WKRXVDQG0JRIZDVWHZDVJHQHUDWHGZKLFKFRQVWLwhere: \HDU IRU0DáRSROVND9R\YRGHVKLSDQGLWZDVRQO\VOLJKWO\ORZHU ZDVNJ WXWHVRIWKHZDVWHVWUHDPRQDQDWLRQDOVFDOH7KH Rj(x,y)±LVWKHUHODWLRQEHWZHHQWZRVHWVZLWKDPHPEHUVKLS indicator expressing the amount of waste produced per one WKDQ WKH QDWLRQDOLQKDELWDQWLQZDVNJ DYHUDJH LH NJ DU ,\HDU $Q DYHUDJH KRXVHKROG LQ 0DáRSROVND . -1 IXQFWLRQ>@ (person IRU0DáRSROVND cj(x),cj(y)±YDULDEOHRIWKHDQDO\VHGREMHFW SURGXFHVNJ Voyvodeship \HDU and it was only slightly lower than the national k±FRHI¿FLHQWWDNHQDVDVWDQGDUGGHYLDWLRQLQWKHVHWRI DYHUDJHLHNJ.(person,\HDU-1$QDYHUDJHKRXVHKROG RILQGLYLGXDOPHWKRGV¶HIIHFWLYHQHVVZKLOHGHWHUPLQLQJWK LQ0DáRSROVNDSURGXFHVNJ.(person,\HDU-1, while in the a given attribute of the analysed object. DUHDVZDVGRQHRQWKHH[DPSOHRIWKHVHWRIUDQGRPO\ $IWHU KDYLQJ GHWHUPLQHG LQGLVFHUQLELOLW\ FODVVHV IRU UXUDODUHDVWKLVYDOXHLVORZHUE\DERXW The comparative analysis of individual methods’ effec- RI 0DáRSROVND FRQGLWLRQ DQG GHFLVLRQ DWWULEXWHV TXDOLW\ DQG DFFXUDF\ PXQLFLSDOLWLHV indicators of approximations within individual decisions tiveness while determining the rate of waste accumulation sub-clusters were calculated: IRUUXUDODUHDVZDVGRQHRQWKHH[DPSOHRIWKHVHWRI randomly chosen rural municipalities andWKH rural areas of ur- GLYLGHG LQWR WZR 7KHQ WKH PXQLFLSDOLWLHV FKRVHQ IRU DQDO\VLV ZHUH EDQDQGUXUDOPXQLFLSDOLWLHVRI0DáRSROVND9RLYRGHVKLS card ( POS (U c VXEVHWVWKHWUDLQLQJVHWFRQWDLQLQJREMHFWVDQGWKHWHVWVHWFRPSULVLQJREMHFWV BBBBBBBBBBBBBBBBBB The number of objects within the set was chosen in a way J (X card (O X i WRHQDEOHWKHOHYHORIFRQ¿GHQFHRI7KHQWKHPX nicipalities chosen for the analysis were divided into two where: · F O _ X ±WKHQXPEHURIORZHUDSSUR[LPDWLRQREMHFWVFDUGLQDO- VXEVHWVWKHWUDLQLQJVHWFRQWDLQLQJREMHFWVDQGWKHWHVW set comprising 20 objects. LW\RIWKHORZHUDSSUR[LPDWLRQRI;VHW ƿ;±WKHQXPEHURIXSSHUDSSUR[LPDWLRQREMHFWVFDUGLQDOLW\ Objects within the training set were presented in the form RIWKHXSSHUDSSUR[LPDWLRQRI;VHW RIDGHFLVLRQWDEOH7DEOHZKHUHWKHIHDWXUHVFKDUDFWHUPOSc±WKHQXPEHURIREMHFWVLQWKHLQGLVFHUQLELOLW\FODVVRI ising the municipalities were marked with symbols c·F7, and the rate of mass accumulation of waste in households, a decision attribute. which is a decision attribute was marked with d symbol. card (O X Ec (X B Ta b l e 1 . ,QIRUPDWLRQV\VWHPGHFLVLRQWDEOH card (O X where: Condition attributes Decision attribute Municipality/ O X±WKHQXPEHURIORZHUDSSUR[LPDWLRQREMHFWVFDU- object number F c2 F F F F c7 d GLQDOLW\RIWKHORZHUDSSUR[LPDWLRQRI;VHW ƿ;±WKHQXPEHURIXSSHUDSSUR[LPDWLRQREMHFWVFDUGL- 6RXUFHRZQVWXG\RQWKHEDVLVRI*HQHUDO6WDWLVWLFDO2I¿FH¶VGDWD QDOLW\RIWKHXSSHUDSSUR[LPDWLRQRI;VHW +DYLQJGLVWLQJXLVKHGUHSUHVHQWDWLYHGHFLVLRQUXOHVWKH author determined the rate of mass accumulation of waste. For the aforementioned attributes, domains were deterFor this purpose the municipalities from the test set were mined according to the following assumptions: XVHG$SSO\LQJYDOXHGWROHUDQFHUHODWLRQ975WKHDXWKRU c1±SRSXODWLRQGHQVLW\>SHRSOHāNP-2], checked to which of the decision rules selected above the c2±DYHUDJHDUHDRIDJULFXOWXUDOODQG>KD@ 7KHTXDOLW\RIWKHPDWFK analysed municipality has the highest level of membership. c3±EXLOGLQJ¶VDJHUDWHHVWDEOLVKHGDVDZHLJKWHGDULWKPHWLF 7KHTXDOLW\RIWKHPDWFK 7KHTXDOLW\RIWKHPDWFKEHWZHHQWKHSUHGLFWHGUDWHRI mean of the number of buildings from different periods mass accumulation of waste in households and its real value RIWLPHLHEHIRUH was estimated by determining the value of error: ¦ c4 ±SDUWLFLSDWLRQRIEXLOGLQJVKHDWHGZLWKQDWXUDOJDV n p ME ¦ d i d i c5±PXQLFLSDOLW\W\SH±VXEXUEDQ±WRXULVW±DJn i ULFXOWXUDO c APE d i d ip di ¦ ¦ dp dp c6±SDUWLFLSDWLRQRIKRXVHKROGVGHULYLQJLQFRPHIURPDJ ricultural activity, 720$6=6=8/.5=<6=72)1ĉ&.$ With the purpose of a better presentation of the changes c7±LQFRPHUDWHPXQLFLSDOLWLHV¶RZQLQFRPH±SDUWLFLSDWLRQ in taxes comprising national budget income personal in differences generated for individual methods, empirical GLVWULEXWLRQIXQFWLRQIRU$3(KDVEHHQVKRZQLQ)LJXUH LQFRPHWD[>3/1āSHUVRQā\HDU-1], d±WKHUDWHRIPDVVDFFXPXODWLRQRIZDVWHLQWKHKRXVHKROGV >NJāSHUVRQā\HDU-1]. The values of particular attributes were established on the basis of statistical data included in the Regional Data %DQNRI*HQHUDO6WDWLVWLFDO2I¿FHIRUDQG*HQHUDO$JULFXOWXUDO&HQVXVDYDLODEOHRQWKH*HQHUDO6WDWLVWLFDO 2I¿FH¶VZHEVLWH>*86@ With the use of condition attributes (c±F7WKHWUDLQLQJ set was divided by Statistica 10.0 program into an optimal number of clusters on the basis of v-fold cross validation. Observations from the test set were assigned to different groups. Then, on the basis of the training set, mean values of the decision attribute (dĞU>NJāSHUVRQā\HDU-1@LWVYDULDELOLW\DQG WKHFRHI¿FLHQWV>@ZHUHGHWHUPLQHGIRULQGLYLGXDOFOXVWHUV The results of achieved analyses are presented in Table 2. Fig. 1. &RPSDULVRQRIHPSLULFDOGLVWULEXWLRQIXQFWLRQIRU$3( Ta b l e 2 . Decision attribute’s variability for determined clusters cluster: 2QWKHHPSLULFDOGLVWULEXWLRQIXQFWLRQIRU$3(GLDJUDP )LJZHFDQVHHWKDWWKHURXJKVHWWKHRU\ZDVFKDUDF(0 WHULVHGE\WKHEHVWTXDOLW\RISURJQRVLVRIWKHUDWHRIPDVV accumulation of waste in households for the test set. ParticidĞU V pation of error with the lowest value was similar to k-means FOXVWHULQJPHWKRGDQGLWZDVOHVVWKDQRIWKHREVHUYD2 tions. The advantage of rough set theory for such a small 97 test was very much visible for bigger errors of the prognosis. 0D[LPXP$3(YDOXHGHWHUPLQHGZLWKWKLVPHWKRGGLGQRW JREH\RQGZKHUHDVIRUk-means method it was around $VWKH¿QDOVWHSLQGLYLGXDOFOXVWHUVRIWKHWHVWVHWZHUH 7KHORZHVWTXDOLW\RISURJQRVLVGHVSLWHWKHKLJKHVW attributed with decision algorithm values i.e. the rate of percentage of low value errors was characteristic of EM mass accumulation of waste from households, determined method of clustering. Low value errors accounted for almost on the basis of the training set. The achieved values were RIREVHUYDWLRQVEXWDWWKHVDPHWLPHWKHPD[LPXP compared with real data and the error level was established. YDOXHVRIHUURUVZHUHDVKLJKDV 7KHDFKLHYHGUHVXOWVDUHSUHVHQWHGLQ7DEOH The performed analyses show that the mean value of the CONCLUSIONS rest for all methods of cluster analysis determined for the WUDLQLQJVHWZDV>NJāSHUVRQā\HDU-1]. For the training set it RVFLOODWHGEHWZHHQ±>NJāSHUVRQā\HDU-1] for the rough set The performed comparative analyses show that the avWKHRU\DQG>NJāSHUVRQā\HDU-1] for k-means method, for HUDJHPHDQHUURU±0(IRUDOOPHWKRGVRIFOXVWHUDQDO\VHV ZKLFKWKH(XFOLGHDQGLVWDQFHEHWZHHQREMHFWVZDVFDOFXODWHG GHWHUPLQHGIRUWKHWUDLQLQJVHWZDV>NJāSHUVRQā\HDU-1]. In case of the training set observations, k-means method of )RUWKHWUDLQLQJVHWLWYDULHGIURP±>NJāSHUVRQā\HDU-1] clustering generated underestimated prognoses independent- IRUURXJKVHWWKHRU\WR>NJāSHUVRQā\HDU-1] for k-means ly of the type of distance calculated between objects, contrary PHWKRGIRUZKLFKWKH(XFOLGHDQGLVWDQFHEHWZHHQREMHFWV to EM PHWKRGDQGWKHURXJKVHWWKHRU\7KHDYHUDJH0$3( was calculated. In case of the training set observations, for k-means and EMDOJRULWKPUDQJHGEHWZHHQDQG k-means method of clustering generated underestimated IRUWKHWUDLQLQJVHWDQGEHWZHHQDQGIRUWKHWHVW prognoses independently of the type of distance calculated set. The rough set theory was characterised by a much better between objects, contrary to EM method and the rough TXDOLW\RISURJQRVLVIRUZKLFK0$3(YDOXHZDV set theory. Clustering algorithm: k-means±GLVWDQFHEHWZHHQWKHREMHFWV (XFOLGHDQ Manhattan Chebyshev dĞU V dĞU V dĞU V Ta b l e 3 . Characteristic of the estimation error of the rate of mass accumulation of waste in households Sample: training test (UURUFOXVWHULQJDOJRULWKP k-means±GLVWDQFHEHWZHHQWKHREMHFWV (XFOLGHDQ Manhattan Chebyshev 0( 0$3( 0( 0$3( 0( 0$3( 0 0 0 22 29 20 29 (0 0( 0 Rough set theory 0$3( 0( 0$3( &203$5,6212)7+(86()8/1(662)&/867(5$1$/<6,6 7KHDYHUDJH0$3(RISURJQRVLVIRUk-means and EM 3DZODN = Rough set approach to knowlDOJRULWKPUDQJHGEHWZHHQDQGIRUWKHWUDLQLQJVHW HGJHEDVHGGHFLVLRQVXSSRUW(XURSHDQ-RXUQDORI2SDQGEHWZHHQDQGIRUWKHWHVWVHW7KHURXJKVHW HUDWLRQDO5HVHDUFK WKHRU\ZDVFKDUDFWHULVHGE\WKHEHVWTXDOLW\RISURJQRVLV Polkowski, L. Skowron, A., 2001: Rough mereological IRUZKLFK0$3(YDOXHZDV FDOFXOLRIJUDQXOHV$URXJKVHWDSSURDFKWRFRPSXWDWLRQ The performed analyses have proved that rough set the&RPSXWDWLRQDO,QWHOOLJHQFH ory should be used for estimating the rate of mass accumu- Renigier M., 2006:=DVWRVRZDQLHDQDOL]\GDQ\FKPHlation of waste from rural areas especially when the number WRGą]ELRUyZSU]\EOLĪRQ\FKGR]DU]ąG]DQLD]DVREDPL of objects within the cluster is low. QLHUXFKRPRĞFL6WXGLDL0DWHULDá\7RZDU]\VWZD1DXNRZHJRQLHUXFKRPRĞFL 5HQLJLHU%LáR]RU0%LáR]RU$Opracowanie systemu wspomagania podejmowania decyzji z wyko5()(5(1&(6 rzystaniem teorii zbiorów rozmytych oraz teorii zbiorów SU]\EOLĪRQ\FKZSURFHVLHNV]WDáWRZDQLDEH]SLHF]HĔVWZD %RQGDU1RZDNRZVND(2GG]LDá\ZDQLHUREyW NRQVHUZDF\MQ\FKQDÀRUĊLIDXQĊNRU\WZ\EUDQ\FKFLHSU]HVWU]HQL$FWD6FLHQWLDUXP3RORQRUXP$GPLQLVWUDWLR NyZQL]LQQ\FK=HV]1DXN$5:URFáDZ5R]SUDZ\ /RFRUXP 5HQLJLHU%LáR]RU0$QDOL]DU\QNyZQLHUXFKR&/;;,,,QU 2. Deja R., 2000:=DVWRVRZDQLHWHRULL]ELRUyZSU]\EOLĪRPRĞFL]Z\NRU]\VWDQLHPWHRULL]ELRUyZSU]\EOLĪRQ\FK 6WXGLDL0DWHULDá\7RZDU]\VWZD1DXNRZHJRQLHUXFKRQ\FKZDQDOL]LHNRQÀLNWyZ3UDFDGRNWRUVND,QVW\WXW PRĞFL9RO 3RGVWDZ,QIRUPDW\NL3ROVNLHM$NDGHPLL1DXN *áyZQ\8U]ąG6WDW\VW\F]Q\%DQN'DQ\FK/RNDOQ\FK 5HQLJLHU%LáR]RU0:LĞQLHZVNL57KH(IIHFKWWSVWDWJRYSOEGODSSVWURQDKWPO"SBQDPH LQGHNV WLYHQFHVVRIUHDOHVWHWHPDUNHWYHUVXVHI¿FLHQF\RILWV SDUWLFLSDQWV(XURSHDQ6SDWLDO5HVHDUFKDQG3ROLF\9R +DFKRá-%RQGDU1RZDNRZVND(5HLQKDUG$ QU 2008: 2GG]LDá\ZDQLHZ\EUDQ\FKHOHPHQWyZNRU\WD FLHNXQD]ELRURZLVNDQDF]\QLRZ\FKURĞOLQZRGQ\FK 20. 5HQLJLHU%LáR]RU0%LáR]RU$$SSOLFDWLRQRI ,QIUDVWUXNWXUD L (NRORJLD 7HUHQyZ :LHMVNLFK 1U the rough set theory and the fuzzy set theory in land man3ROVND$NDGHPLD1DXN2GG]LDáZ.UDNRZLH DJHPHQW$SOLFDWLRQMXQHU$QQXDOFRQIHUHQFH 7KH(XURSHDQ5HDO(VWDWH6RFLHW\±(5(6/RQG\Q Hartigan J. A., Wong M. A., 1978:$OJRULWKP ĝOHV]\ĔVNL 3 D 'HOLPLWDFMD REV]DUyZ ZLHMVNLFK R QDMJRUV]\FK ZVNDĨQLNDFK UR]ZRMX VSR$NPHDQVFOXVWHULQJDOJRULWKP$SSOLHG6WDWLVWLFV áHF]QRJRVSRGDUF]HJRE'HOLPLWDFMDREV]DUyZZLHMVNLFKRQDMJRUV]\FKZVNDĨQLNDFKGRVWĊSQRĞFLGRXVáXJ Hartigan, J. A., 1975: &OXVWHULQJDOJRULWKPV1HZ<RUN SXEOLF]Q\FKFRSUDFRZDQLDPDSLNRQVXOWDFMHNDUWRWiley. 7. .HPSD(6*RVSRGDUNDRGSDGDPLPLHMVNLPL JUD¿F]QH,*L3=3$1:DUV]DZDPDS\GOD0L$UNDG\:DUV]DZD nisterstwo Rozwoju Regionalnego (Krajowa Strategia 8. .RPRURZVNL-3DZODN=3RONRZVNL/6NRZ5R]ZRMX5HJLRQDOQHJR ron, A., 1999:5RXJKVHWV$WXWRULDO´5RXJKIX]]\ 22. 6áRZLĔVNL5,QWHOOLJHQWGHFLVLRQVXSSRUW$SSOLK\EULGL]DWLRQ$QHZWUHQGLQGHFLVLRQPDNLQJ cations and advances of the rough sets theory. Kluwer $FDGHPLF3XEOVKHUV'RUGUHFKW 9. Konieczna R., Kulczycka J., 2011: $QDOL]DHNRQRPLF]QDV\VWHPyZJRVSRGDUNLRGSDGDPLF],,,*60L(3$1 Sneath, P. H. A., & Sokal, R. R., 1973: Numerical Karków. WD[RQRP\6DQ)UDQFLVFR:+)UHHPDQ&R 0DOLQRZVNL0.UDNRZLDN%DO$6LNRUD-:RĨ- 6]XO7.QDJD-1ĊFND.$SSOLFDWLRQRI niak A., 2009: ,ORĞFL JHQHURZDQ\FK RGSDGyZ NRrough set theory for establishing the rate of mass accumulation of waste in the households in rural areas. munalnych w aspekcie typów gospodarczych gmin ZRMHZyG]WZDPDáRSROVNLHJR,QIUDVWUXNWXUDL(NROR(FRORJLFDO&KHPLVWU\DQG(QJLQHHULQJ6ZGUXNX JLD7HUHQyZ:LHMVNLFK1U3ROVND$NDGHPLD1DXN 7DáDáDM ,$ :Sá\Z Z\EUDQ\FK F]\QQLNyZ 2GG]LDáZ.UDNRZLH± VSRáHF]QRHNRQRPLF]Q\FKQD]PLDQ\LORĞFLRGSDGyZ 0UyĪHN$3áRQND/$QDOL]DGDQ\FKPHWRGą NRPXQDOQ\FKZZRMHZyG]WZLHSRGODVNLP,QĪ\QLHULD ]ELRUyZSU]\EOLĪRQ\FK$NDGHPLFND2¿F\QD:\GDZ(NRORJLF]QD1U Tryon, R. C., 1939: &OXVWHU$QDO\VLV$QQ$UERU0, nicza PLJ, Warszawa. (GZDUGV%URWKHUV 1ĊFND. Selection of decisive variables for the FRQVWUXFWLRQRIW\SLFDOHQGXVHUSRZHUGHPDQGSUR¿OHV 27. Ward, J. 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COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 181–184 An Analysis of Variability in Demand for Natural Gas at Rural Households Małgorzata Trojanowska, Dorota Lipczyńska Department of Power Engineering and Agricultural Processes Automation, Agricultural University of Cracow Balicka Str. 116B, 30-149 Kraków, Poland, e-mail: [email protected] Received December 11.2014; accepted December 19.2014 Summary. The variability in hourly demand for natural gas in rural households was analyzed at various time intervals. The results enabled the determination of typical daily courses of gas consumption by this group of consumers, separately for workdays and weekends, divided into two periods i.e. high and low gas demand. For the purpose of drawing typical curves of the loads of rural gas networks, the courses of gas consumption ZHUHFODVVL¿HGZLWKWKHXVHRIYDULDQFHDQDO\VLVFOXVWHUDQDO\VLV and based on the principal indicators describing the variability in gas consumption. Key words: JDVPDUNHWW\SLFDOSUR¿OHVRIQDWXUDOJDVFRQVXPSWLRQ analogy, this method can also be used to forecast the demand IRUQDWXUDOJDV>@ The aim of the presented study was to analyse the variability of demand for natural gas in rural households at different time intervals for the purpose of determining the typical daily courses of gas consumption by this group of consumers. This study focused on the daily and weekly variability in gas consumption within the periods of high and low demand for this fuel. 0$7(5,$/6$1'0(7+2'6 INTRODUCTION In this study, a statistical analysis of the consumption RIQDWXUDOJDVE\UXUDOKRXVHKROGVZKLFKDUHDVSHFL¿F customer group of natural gas distribution companies, was FDUULHGRXW,QRUGHUWRREWDLQW\SLFDOSUR¿OHVRIGDLO\JDV usage, the courses of gas consumption were categorised with the use of variance analysis, cluster analysis, particularly the agglomeration and k-means methods, as well as using principal indicators describing gas consumption. Calculations were made on the basis of data of a gas company, pertaining to gas consumption by rural customers supplied via a low-pressure network from a selected grade I gas pressure reduction station located in the province of Lower Silesia. In the study area, the density of the natural gas distribuWLRQQHWZRUNLVNPSHUNP2, and the consumption RIJDVSHUUHVLGHQWLVFDP3. Despite great efforts being made to open up the natural JDVPDUNHWLQ3RODQGLWKDVQRWEHHQIXOO\OLEHUDOLVHG\HW$W WKHHQGRI'HFHPEHUWKHJDVH[FKDQJHZDVODXQFKHG DWWKH3ROLVK3RZHU([FKDQJHDQGDSDUWLDOGHUHJXODWLRQRI JDVSULFHVIRULQGXVWU\RFFXUUHGLQZKLOVWRQ$XJXVW DQHZHQWLW\3*1L*5HWDLO//&ZDVVSXQRIIIURP WKHH[LVWLQJVWUXFWXUHRIWKH3ROLVK2LODQG*DV&RPSDQ\ -RLQW6WRFN&RPSDQ\3*1L*6$$OOWKHWUDGHVHUYLFHVLQ the area of natural gas sales to retail clients were spun off to WKLVQHZFRPSDQ\$WSUHVHQWWKHUHLVQRSRVVLELOLW\WROLEHUalise natural gas prices for retail consumers, but according to experts it will happen within the next couple of years. For business entities involved in sales of natural gas, this near perspective of the liberalisation of gas market means the increasing importance of developed forecasts of demand IRUWKLVIXHOSDUWLFXODUO\VKRUWWHUPIRUHFDVWV> @ 5(68/76 In the energy industry, the most demanding market in WHUPVRIWKHTXDOLW\RIIRUHFDVWVLVWKHHOHFWULFLW\PDUNHW Individual consumers use natural gas for heating buildOne of the ways to predict the demand in the electricity ings, providing domestic hot water and cooking meals. The industry is to determine the demand for electricity on the amount of consumption depends on a number of factors EDVLVRIW\SLFDOORDGSUR¿OHVRIFXVWRPHUV>@%\ >@DPRQJZKLFKDLUWHPSHUDWXUHLV 0$à*25=$7$752-$12:6.$'2527$/,3&=<ē6.$ of the course were determined according to the following formula SDUWLFXODUO\LPSRUWDQW7KHFRUUHODWLRQFRHI¿FLHQWEHWZHHQ the mean daily demand for gas in a given month and the PHDQWHPSHUDWXUHLV([DPSOHVRIWKHFKDQJHVRIWKH WZRFRUUHODWHGYDOXHVDUHSUHVHQWHGLQ)LJ 20 19,2 19,1 16 Gi Gdsr ¦ G j Gdsr , i = 1, 2, …, 24 2 j where: where: KRXU Gi, Gj±ORDGLQLth (jthKRXU ORDGLQKRXUV Gdsr±PHDQORDGLQKRXUV 18,8 18 gi 15,4 14 12,9 m3 12 11 10 8,5 8 6,5 6 4,8 4 2,8 2,7 2 1 0 1 2 3 4 5 6 7 8 9 10 11 %RWKPHWKRGVSURGXFHGWKHVDPHUHVXOWVIRUWKHSHULRG %RWK PHWKRGV SURGXFHG WKH VDPH UHVXOWV IRU WKH SHULRG RI K of high and low consumption alike, which permitted two characteristic days of the week i.e.: workday and weekend day, with respect to the dailyDLO\YDULDELOLW\RIGHPDQGIRUJDV)LJ variability of demand for gas )LJ 12 110 Month mean daily demand for gas in the month mean monthly temperature 100*Distance/Distance max 100 Fig. 1. The mean daily demand for natural gas in particular months of the year vis-à-vis mean monthly air temperature 90 Gas demand [m3] The variance analysis completed in this study showed 80 that the values of average daily gas consumption by rural households over a month-long period did not differ signif70 icantly from one another from November to March, and IURP$SULOWR2FWREHU7KHVHWZRSHULRGVDUHFRQVLGHUHG 60 separately later in the paper and are referred to as periods of high and low consumption of natural gas, respectively. 50 When a large number of consumers are supplied at the Friday Wednesday Monday Sunday Thursday Tuesday Saturday same time, certain regularities can be seen in the timing of gas consumption. These changes are illustrated in Fig. Fig. 3. 'LDJUDPRIDJJORPHUDWLRQRIVLPLODULWLHVRIGDLO\SUR¿OHV 2 where the courses of demand for gas are presented in of gas consumption on particular )LJ days of week particular hours of July and December. Sets of various indicators characterising the variability in 25 loads are often used to classify the daily courses of demand >@$PRQJWKHLQGLFDWRUVPRVWRIWHQXVHGWRGHVFULEH 20 >@$PRQJWKH the variability in demand for electricity are the medium and 15 EDVHOHYHORIORDG>@7KHVHZHUHGH¿QHGIRUQDWXUDO gas in the following way: 10 ±PHGLXPOHYHORIJDVORDG 5 Gsr , Gmax ±EDVHOHYHORIJDVORDG - base level of gas load m 1 25 49 73 97 121 145 169 193 217 241 265 289 313 337 361 385 409 433 457 481 505 529 553 577 601 625 649 673 697 721 0 Hours July December Fig. 2. The courses of demand for gas in particular hours of July and December $VLPLODULW\DQDO\VLVRIGDLO\ORDGVRIJDVQHWZRUNVZDV performed in order to identify the regularity in the courses of changes. For the purposes of the similarity analysis of gas consumption in particular days of the week, normalized YHFWRUVRIGDLO\FRXUVHVFDOOHGQRUPDOL]HGGDLO\SUR¿OHV ZHUHGHWHUPLQHGDQGFODVVL¿HGXVLQJWKHCluster analysis module in the Statistica software package, in particular the agglomeration and k-means methods. 7KHQRUPDOL]HGSUR¿OHVRIGDLO\ORDGVRIJDVQHWZRUNV containing information on the shape of the course were determined according to the following formula [9]: G mo Gmin Gmax where: *VU*PD[*PLQDUHPHGLXPPD[LPXPDQGPLQLPXP * * * levels of gas consumption, respectively. The values of these indicators for daily and weekly peRIWKHVHLQGLFDWRUVIRUGDLO\DQGZH ULRGVZHUHFRPSLOHGLQ7DEOH 7DEOHVKRZVWKDWWKHFRXUVHVRIGHPDQGIRUJDVLQWKH low-consumption-period are characterized by greater unevenness and lesser balanced than in the high-consumption period. The differences are so great that there was a need to develop standard daily load graphs separately for each of these periods. $1$1$/<6,62)9$5,$%,/,7<,1'(0$1')251$785$/*$6$7585$/+286(+2/'6 Ta b l e 1 . Indicators of daily and weekly load of gas network Value Mean Minimum Maximum Period of low gas consumption md mdo mt 0.00 0.28 $VDUHVXOWRIWKHDQDO\VLVSHUIRUPHGIRXUW\SLFDOUHGXFHG SUR¿OHVRIGDLO\JDVFRQVXPSWLRQE\UXUDOFRQVXPHUVLH for a workday and a weekend day during the low-consumption-period, and for a workday and a weekend day during the high-consumption-period, in the form of averaged courses, and corrected, at the same time. The reference value was the respective maximum hourly demand for gas in the low- or KLJKFRQVXPSWLRQSHULRGV7KHSUR¿OHVDUHSUHVHQWHGLQ )LJVDQG mto 0.00 0.00 0.00 Period of high gas consumption md mdo mt 0.07 mto 0.22 for periods of high and low demand for gas. These curves can be used both for the purpose of operating gas distribution networks and in short-term forecasts of gas demand by KRXVHKROGVLQUXUDODUHDV$WSUHVHQWJDVWUDGHUVXVXDOO\XVH the simplest, naive method to predict demand. 5()(5(1&(6 $QDOL]DLSURJQR]DREFLąĪHĔHOHNWURHQHUJHW\F]Q\FK 3UDFD]ELRURZD:17:DUV]DZD 0,8 2. Azadeh A., Asadzadeh S.M., Ghanbari A. 2010:$Q adaptive network-based fuzzy inference system for short0,6 term natural gas demand estimation: Uncertain and com0,4 SOH[HQYLURQPHQWV(QHUJ\3ROLF\ 0,2 %LDQFR96FDUSD)7DJOLD¿FR/$$QDO\VLV and future outlook of natural gas consumption in the 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 ,WDOLDQUHVLGHQWLDOVHFWRU(QHUJ\&RQYHUVLRQDQG0DQHour DJHPHQW Workday Weekend day %UDEHF0.RQDU23HOLNDQ(0DO\0 Fig. 4. 7\SLFDOSUR¿OHVRIGDLO\JDVGHPDQGLQORZJDVFRQ$QRQOLQHDUPL[HGHIIHFWVPRGHOIRUWKHSUHGLFWLRQRI sumption period natural gas consumption by individual customers. InterQDWLRQDO-RXUQDORI)RUHFDVWLQJ± %UDEHF0.RQDU20DO\03HOLNDQ(9RQ1 dracek J. 2008: $ VWDWLVWLFDO PRGHO IRU QDWXUDO JDV 0,8 VWDQGDUGL]HGORDGSUR¿OHV-5R\6WDWLVW6RF6HULHV& 0,6 $SSOLHG6WDWLVWLFV± &KHQ46KH<;X;Combination model for 0,4 VKRUWWHUPORDGIRUHFDVWLQJ7KH2SHQ$XWRPDWLRQDQG 0,2 &RQWURO6\VWHPV-RXUQDO 7. Chicco G. 2012: Overview and performance assess0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 ment of the clustering methods for electrical load pattern Hour JURXSLQJ(QHUJ\ Workday Weekend day 8. Ferreira A.M.S., Cavalcante C.A., Fontes C.H., MaFig. 5. 7\SLFDOSUR¿OHVRIGDLO\JDVGHPDQGLQKLJKJDVFRQrambio J. 2012: $QHZSURSRVDORIW\SL¿FDWLRQRIORDG sumption period SUR¿OHVWRVXSSRUWWKHGHFLVLRQPDNLQJLQWKHVHFWRU of electric energy distribution. Internacional Industrial The studies demonstrated that gas consumption by rural &RQIHUHQFHRQ(QJLQHHULQJDQG2SHUDWLRQV0DQDJHPHQW households on weekend days is slightly higher than on -XO\*XLPDUmHV3RUWXJDOLD,',' ZRUNGD\VLQWKHODVWWZR\HDUV±E\FDWKRXJKLWLV 9. Dudek G. 2004: Wybrane metody analizy szeregów F]DVRZ\FKREFLąĪHĔHOHNWURHQHUJHW\F]Q\FK0DWHULDá\ much more uneven, with clearly marked peaks of consumpKonferencji Naukowej Prognozowanie w elektroenertion in the midday hours. getyce PE ‚04&]ĊVWRFKRZD± Góra S. 1975:*RVSRGDUNDHOHNWURHQHUJHW\F]QDZSU]HCONCLUSIONS P\ĞOH3:1:DUV]DZD Kelner J.M. 2003: Prognozowanie krótkoterminowe poERUyZJD]X]VLHFLSU]HV\áRZ\FKPHWRGąV]WXF]Q\FKVLHFL The demand for gas in rural households shows periodic GDLO\ZHHNO\DQGPRQWKO\ÀXFWXDWLRQV QHXURQRZ\FK*D]:RGDL7HFKQLND6DQLWDUQD Considering the shapes of gas usage curves, four stand- Melikoglu M. 2013: Vision 2023: Forecasting Turkey’s QDWXUDOJDVGHPDQGEHWZHHQDQG5HQHZDEOH DUGSUR¿OHVZHUHGLVWLQJXLVKHGUHSUHVHQWLQJWKHFRQVXPSDQG6XVWDLQDEOH(QHUJ\5HYLHZV tion, i.e. for a workday and a weekend day, respectively G/Gdmax G/Gdmax 1 0$à*25=$7$752-$12:6.$'2527$/,3&=<ē6.$ 1DLPLQJ;&KDRTLQJ<<LQJMLH< ForecastLQJ&KLQD¶VHQHUJ\GHPDQGDQGVHOIVXI¿FLHQF\UDWHE\ JUH\IRUHFDVWLQJPRGHODQG0DUNRYPRGHO(OHFWULFDO 3RZHUDQG(QHUJ\6\VWHPV 3RWRþQLN36ROGR%âLPXQRYLü*âDULü7-HURPHQ$*RYHNDU( Comparison of static and adaptive models for short-term residential natural gas IRUHFDVWLQJLQ&URDWLD$SSOLHG(QHUJ\ 3URJQR]RZDQLHZHOHNWURHQHUJHW\FH=DJDGQLHQLDZ\EUDQHUHG,'REU]DĔVND:\GDZQLFWZR3ROLWHFKQLNL&]ĊVWRFKRZVNLHM&]ĊVWRFKRZD Smith P., Husejn S. 1997: Forecasting short term reJLRQDOJDVGHPDQGXVLQJDQH[SHUWV\VWHP([SHUW6\VWHPVZLWK$SSOLFDWLRQV Soldo B. 2012: Forecasting natural gas consumption. $SSOLHG(QHUJ\ 7DVSÕQDU)&HOHEL17XWNXQ1Forecasting of daily natural gas consumption on regional basis in 7XUNH\XVLQJYDULRXVFRPSXWDWLRQDOPHWKRGV(QHUJ\ DQG%XLOGLQJV 9RQGUiþHN-3HOLNiQ(.RQiU2ýHUPiNRYi- (EHQ.0DOê0%UDEHF0$VWDWLVWLFDOPRGHO IRUWKHHVWLPDWLRQRIQDWXUDOJDVFRQVXPSWLRQ$SSOLHG (QHUJ\ 20. <X);XO;$VKRUWWHUPORDGIRUHFDVWLQJPRGel of natural gas based on optimized genetic algorithm DQGLPSURYHG%3QHXUDOQHWZRUN$SSOLHG(QHUJ\ $1$/,=$=0,(112ĝ&,=$3275=(%2:$1,$ :,(-6.,&+*2632'$567:1$*$==,(01< Streszczenie. 3U]HDQDOL]RZDQR]PLHQQRĞüJRG]LQRZHJRSRERUX JD]X]LHPQHJRSU]H]ZLHMVNLHJRVSRGDUVWZDGRPRZHZUyĪQ\FK LQWHUZDáDFKF]DVRZ\FKLQDWHMSRGVWDZLHRSUDFRZDQRW\SRZH GRERZHSU]HELHJL]XĪ\FLDJD]XSU]H]WĊJUXSĊRGELRUFyZRGdzielnie dla dni roboczych i weekendowych, w rozbiciu na dwa RNUHV\WMGXĪHJRLPDáHJR]DSRWU]HERZDQLDQDJD]'ODSRWU]HE RSUDFRZDQLDW\SRZ\FKNU]\Z\FKREFLąĪHQLDZLHMVNLFKVLHFL JD]RZ\FKSU]HELHJLSRERUXJD]XNODV\¿NRZDQR]Z\NRU]\VWDQLHPDQDOL]\ZDULDQFMLDQDOL]\VNXSLHĔDWDNĪHZRSDUFLX RSRGVWDZRZHZVNDĨQLNLRSLVXMąFH]PLHQQRĞü]XĪ\FLDJD]X 6áRZD NOXF]RZH U\QHN JD]X W\SRZH SUR¿OH ]XĪ\FLD JD]X ziemnego. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 185–190 Determination of the Rheological Properties of Biofuels Containing SBME Biocomponent Grzegorz Wcisło Faculty of Production Engineering and Power Technologies University of Agriculture in Krakow, Poland email: [email protected] Received December 08.2014; accepted December 19.2014 Summary. 6LPLODUO\WRGLHVHORLO%%LRGLHVOD%6%0( dynamic viscosity at positive temperatures in principle increases ZLWKGHFUHDVLQJWHPSHUDWXUH+DYLQJH[FHHGHGoC, it begins to LQFUHDVHUDSLGO\7KHG\QDPLFYLVFRVLW\IRU%6%0(DW& ZDVP3DVIRU%6%0(±P3DVDQGIRU%6%0(± P3DV7KHVWXG\KDVVKRZQWKDW%6%0(FDQQRWEHXVHG in practice as a pure fuel without a package of viscosity-lowering DGGLWLYHV$WWKHVDPHWLPHWKHYLVFRVLW\YDOXHVIRU%DQG% biofuels, in particular at positive temperatures, are close to the viscosity of diesel fuel. Under such conditions one can safely XVH%DQG%ELRIXHOVLQFRPSUHVVLRQLJQLWLRQHQJLQHVHYHQ in those with a state-of-the-art injection apparatus. Key words: diesel HQJLQH%LRGLHVHOELRIXHO6)0(, dynamic viscosity, shearing rate. INTRODUCTION 4XDOLW\VWDQGDUGV31(1IRUGLHVHOIXHODQG (1 ,62 IRU )$0( IXHO GHWHUPLQH RQO\ NLQHPDWLF viscosity. No obligatory norm has been introduced so far for determining dynamic viscosity. Kinematic viscosity is DSDUDPHWHUGHVFULELQJWKHUHVLVWDQFHRIÀXLGÀRZGXHWR gravity forces. In order to determine kinematic viscosity WKHWLPHÀRZIRUFRQVWDQWÀXLGYROXPHWKURXJKDFDSLOODU\WXEHRIDVWDQGDUGYLVFRVLPHWHUXQGHUWKHLQÀXHQFH of gravity forces is measured, under repeatable conditions and at known, strictly controlled temperature. The value of NLQHPDWLFYLVFRVLW\LVFRPSXWHGE\PXOWLSO\LQJWKHÀRZ WLPHE\YLVFRVLPHWHUVWDQGDUGL]DWLRQFRQVWDQW+RZHYHUWKH norm allows three groups of viscosimeters, so the methods of measurements may differ from the described above dependLQJRQWKHNLQGDQGUDQJHRIWKHWHVWHGÀXLGYLVFRVLW\>@ $QDO\VLVRIWKHVXEMHFWOLWHUDWXUHVKRZVYDULRXVYDOXHVRI 50(NLQHPDWLFYLVFRVLW\ZKLFKDFFRUGLQJWRVRPHDXWKRUV at the temperature of e.g. 20o&UDQJHGIURP>@WR >P3DV@>@+RZHYHULWVHHPVWKDWWKHVFDWWHURIUHVXOWVZDV not so wide but was rather due to a measurement error or application of little precise methods. Therefore even a small mistake during measurement may cause a considerable scatWHURIREWDLQHGNLQHPDWLFYLVFRVLW\YDOXHV$GGLWLRQDOO\VXFK error may be multiplied at dynamic viscosity determination >@ In recent years a rapid development of injection apparatus based on pump-injectors or common rail has been observed, where very high pressure occurs. In this situation LWLVPRVWLPSRUWDQWWRGHWHUPLQHWKHÀXLGÀRZUHVLVWDQFH under dynamic, not static conditions. It is the more imporWDQWZKHQW\SH³%´IXHOVZLWKELRFRPSRQHQWVXSSOHPHQWRI KLJKHUYLVFRVLW\DUHXVHGIRU=6HQJLQHIHHGLQJ7KHUHIRUH dynamic, not kinematic viscosity should be determined most precisely. So far dynamic viscosity has not been determined separately, only obtained from kinematic viscosity. It was due to a lack of proper tools which were relatively expenVLYH+RZHYHUDG\QDPLFGHYHORSPHQWRIUKHRPHWHUVLQUHcent years, particularly dynamic types, allowed for a most precise determination of dynamic viscosity. Moreover, for a EHWWHUDVVHVVPHQWRIIXHOPHFKDQLFDOSURSHUWLHVWKHLQÀXHQFH of many rheological parameters on the behaviour of fuels or biofuels may be also tested. The advantages of using rotational rheometers for viscosity determination comprise: small volume of fuel sample DERXWPOLVHQRXJKIXOODXWRPDWLFDQGFRPSXWHUL]HG measurements, possibility of testing both viscous and elastic properties, possible investigation of tixotropy and antitixotropy phenomena. '\QDPLFYLVFRVLW\LVDPHDVXUHRIÀXLG¶VUHVLVWDQFHWR ÀRZRUÀXLGGHIRUPDWLRQ±3ROLVKVWDQGDUG31(1,62 ,WDOVRDIIHFWVWKHLQMHFWLRQFRXUVHVWUHDPUDQJHDQG IXHOVSUD\LQJLQWKHHQJLQHFRPEXVWLRQFKDPEHU,WLQÀXHQFes lubrication properties, which is particularly important in the case of rotational injection pumps because in the pumps of this type the pump elements are lubricated with diesel oil. It may be the reason why one sometimes encounters *5=(*25=:&,6à2 WKHRSLQLRQWKDWVPDOOYLVFRVLW\DQGUHVXOWLQJJRRGÀRZ properties are more important for the engine start up than WKHFHWDQHQXPEHU>@7KHUHLVDOVRDVWULFWUHODWLRQVKLS between viscosity, temperature and shearing rate. There is a serious problem concerning an excessive viscosity of some biofuels, which in recent years has become one of the key issues. It is primarily connected with the use of injection apparatus, which supplies fuel to the engine at G\QDPLFSUHVVXUHUHDFKLQJEDU7KHUHIRUHHYHQDVOLJKW increase in this parameter may negatively affect the work of injection apparatus. The fact that biofuels would enter WKHIXHOPDUNHWVZDVNQRZQLQVRWKHPDQXIDFWXUHUV should adjust the injection systems also for the fuels with a WRKLJKHUYLVFRVLW\%LRGLHVHOTXDOLW\DOVRSRVHVD SUREOHP,WWXUQVRXWWKDWXVXDOO\)$0(KDVPRUHSURGXFWV of incomplete conversion to esters of oil obtained through WUDQVHVWHUL¿FDWLRQSURFHVV(1VWDQGDUGIRU)$0( %LRGLHVHOIXHOVWDWHVWKHPD[LPXPDOORZDEOHDPRXQWRI monoacyloglycerols LQIXHOVDVZKHUHDVGLDF\OJO\FHU\OHWKHUVRQO\PP$QRWKHUSUREOHPLVZURQJ separation of ester from glycerine phase, since even trace amounts of glycerine phase left over lead to a consideraEOHLQFUHDVHLQYLVFRVLW\$VUHVXOWVIURPKH$XWKRU¶VRZQ research, viscosity of properly separated glycerine phase obtained after rapeseed oil methanolysis at 20oC is about >P3DV@ZKHUHDVLQGLHVHOIXHODERXW>P3DV@50(HVWHUVDERXW>P3DV@ZKHUHDVUDSHVHHGRLODERXW>P3DV@ It results from the data given above that at 20oC oil viscosity LVWLPHVKLJKHUDQGYLVFRVLW\RIJO\FHULQHSKDVHE\RYHU WLPHVKLJKHUWKDQ50(YLVFRVLW\>@ 0(7+2'62)5(6($5&+ Measuring set with two coaxial cylinders was applied in WKHUKHRPHWHU%HVLGHWKHFRQHSODWHYLVFRPHWHULWLVRQHRI the most precise devices for measuring dynamic viscosity of IXHOVDQGELRIXHOV)LJXUHVKRZVWKHVFKHPDWLFGLDJUDPRI the measuring set with marked parameters which served to formulate the main relationships: for tangent force, oscillatLQJWRUTXHVKHDULQJIRUFHDQGG\QDPLFYLVFRVLW\ 2S rHW WKHIOXLGWRWKHLQQHUF\OLQGHUFDXVHWKHGHVFULEHGRVFLOODWLQJWRUTXH F GHVFULEHGXVLQJIRUPXOD r r J x M K ȍ 2: S W R2 2 R2 , SKH: , 2 R2 R2 § ·M , ¨¨ 2 2 ¸¸ SH © R R2 ¹ : URWDWLQJIUHTXHQF\RIWKHVSLQQLQJHOHPHQW K J x : § ¨ S ¨© RVFLOODWLQJWRUTXHDFWLQJRQVSLQQLQJHOHPHQWD[LV where: ȍ±URWDWLQJIUHTXHQF\RIWKHVSLQQLQJHOHPHQW $,0$1'6&23(2)5(6($5&+ M±RVFLOODWLQJWRUTXHDFWLQJRQVSLQQLQJHOHPHQWD[LV H±KHLJKWRIELRIXHOVDPSOH 6%0( W\SHELRIXHOV7KUHHNLQGVRIIXHOVZHUHSUHSDUHG21%%% r±GLVWDQFHIURPURWDWLRQD[LV R±RXWHUUDGLXV R2±LQQHUUDGLXVRIF\OLQGHUVOHHYH %LRGLHVHO REWDLQHG IURP 6%0( R2 DOORZVWRXVHXSWR YYRIELRFRPSRQHQWVXSSOHP R1 $,0$1'6&23(2)5(6($5&+ LQ 3RODQG ZH QHHGHG WR FRQVXPH RQ DYHUDJH RI ELRIXHOV DQ R r H $VVXPLQJWKDWWKHWHVWHGVDPSOHKDVWKHKHLJKWH, tanJHQWIRUFHLQWKHÀXLGDWWKHGLVWDQFHr from the rotation axis PD\EHH[SUHVVHGE\WKHIRUPXOD&RQVLGHULQJURWDWLQJ IUHTXHQF\RIWKHVSLQQLQJHOHPHQWDQGRXWHUGLDPHWHURIWKH spinning element Rand inner diameter of cylinder sleeve R2¿OOHGZLWKWKHWHVWHGÀXLGZHPD\GHULYHIRUPXOD describing the relationship for shearing force. If oscillating WRUTXHFDXVHGE\WDQJHQWIRUFHLVHTXDOLWPD\EHJHQHUDOO\ written as M=F·r. On the other hand for the set applied in the rheometer, i.e. measuring set with coaxial cylinders, the RVFLOODWLQJWRUTXHPD\EHVKRZQE\IRUPXOD7DQJHQWIULFWLRQIRUFHVWUDQVIHUUHGE\WKHÀXLGWRWKHLQQHUF\OLQGHUFDXVH WKHGHVFULEHGRVFLOODWLQJWRUTXHM. Considering the above mentioned assumptions the formula for dynamic viscosity XVLQJFRD[LDOF\OLQGHUVHWPD\EHGHVFULEHGXVLQJIRUPXOD R r+dr Fig. 1. Measuring set with coaxial cylinders 7KH VHFRQG FKRVHQ ELRIXHO % E\ D PHDQ ELRFRPS The research aimed at determining theZDV effect ofVLQFH temperaEDODQFHRIIXHOVFRQVXPHGE\WKHWUDQVSRUWZLOOUHDFKDWOHDVW7KH WXUHRQG\QDPLFYLVFRVLW\RI%LRGLHVHO6%0(W\SHELRIXHOV % RU SXUH 6%0( HVWHU 7KUHHNLQGVRIIXHOVZHUHSUHSDUHG21%%%DQG ZHUH SHUIRUPHG RQ WKH FRPPHUFLDO GLHVHO DQG 50( IXHOV IURP D VHUYL %OLVNDVHUYLFHVWDWLRQFKDLQ %7KHYDOXHDWWDFKHGWR³%´OHWWHUGHQRWHVYROXPHWULF 7KH EDVLF IXHO IRU W\SH % DQG % SURSRUWLRQRI6%0(PHWK\OHVWHUVREWDLQHGIURPVR\D PDQXIDFWXUHGE\3.125/(16$FRPSDQ\7KHUHVHDUFKGHWHUPLQHGWK EHDQ¶VRLOLQWKHPL[WXUHZLWKIXHORLO WR These biofuels were selected because of the current atWHPSWVWRFUHDWHDQDOWHUQDWLYHWR%LRGLHVHOREWDLQHGIURP 6%0(VR\DEHDQRLO&XUUHQWO\LQ3RODQGLWLVSRVVLEOHWR RIWKHUKHRPHWHUVSLQGOHZDVFRQVWDQW>V SXUFKDVHVXQÀRZHURLODWDSULFHFRPSHWLWLYHWRVR\DEHDQRLO These biofuel types were selected because, currently passed act on biocomponents and biofuels allows to use up '(7(50,1$7,212)7+(5+(2/2*,&$/3523(57,(6 WRYYRIELRFRPSRQHQWVXSSOHPHQWVLQIXHOVZLWKRXW the obligatory relevant information for the buyer about the supplement. In accordance with the National Index Target, LQLQ3RODQGZHQHHGHGWRFRQVXPHRQDYHUDJH of biofuels and/or bio-components in relation to the total fuel consumption, calculating in energy terms. 7KHVHFRQGFKRVHQELRIXHOZDV%VLQFHE\D mean biocomponent share in the total balance of fuels conVXPHGE\WKHWUDQVSRUWZLOOUHDFKDWOHDVW7KHWKLUG ELRIXHOVHOHFWHGIRUFRPDSDUWLYHWHVWLQJZDV%RUSXUH 6%0(HVWHU,QDGGLWLRQIRUFRPSDULVRQSXUSRVHVWHVWVZHUH SHUIRUPHGRQWKHFRPPHUFLDOGLHVHODQG50(IXHOVIURP DVHUYLFHVWDWLRQEHLQJSDUWRI%OLVNDVHUYLFHVWDWLRQFKDLQ 7KHEDVLFIXHOIRUW\SH%DQG%ELRIHXOVZDVWKH FRPPHUFLDO9(59$21IXHORLOPDQXIDFWXUHGE\3.125/(16$FRPSDQ\7KHUHVHDUFKGHWHUPLQHGWKHYDULDELOLW\ of dynamic viscosity within the temperature range from -20 WRoC. The range of temperatures was assumed because due to the applied thermostatic bath it was impossible to lower the sample temperature below -20oC. On the other hand UDLVLQJWKHXSSHUWHPSHUDWXUHDERYHoC was considered unnecessary because it does not generally affect a change of dynamic viscosity. In the initial part of the test shearing rate RIWKHUKHRPHWHUVSLQGOHZDVFRQVWDQW>V-1]. &+$5$&7(5,=$7,212)0($685,1*67$1' The main device used at the measuring stand was ReRODE4&UKHRPHWHUPDQXIDFWXUHGE\D*HUPDQ$QWRQ3DDU *PE+FRPSDQ\)LJ7KHUKHRPHWHULVDGHYLVHGHVLJQHG for determining mechanical and rheological parameters of ÀXLGVDQGIXHOV7KHGHYLFHPHDVXUHVDPRQJRWKHUVG\QDPLF viscosity, surface tension, shearing forces, shearing rate, VKHDULQJWHQVLRQHWF7KHUKHRPHWHULVDOVRHTXLSSHGZLWK a temperature sensor and integrated system of time measurement. In order to determine the effect of temperature on the above mentioned parameters, the rheometer used at the PHDVXULQJVWDQGZDVDGGLWLRQDOO\HTXLSSHGZLWKWKHUPRVWDW- LFEDWKPDGHE\DQ$XVWULDQ*UDQWFRPSDQ\7KHUHVXOWVRI research using measuring system of the viscosimeter were VHQWWRDFRPSXWHUDQGVDYHGWKHUHWREHVXEVHTXHQWO\SURFHVVHGXVLQJ5+(23/869 7KHUKHRPHWHUZDVHTXLSSHGZLWKLQWHUQDOPHPRU\DQG WKHV\VWHPIRUUHVHDUFKSURJUDPPHJHQHUDWLRQ)LJXUH SUHVHQWVWKHDOJRULWKPRIWKH5HRODE4&UKHRPHWHUH[WHUQDO control. The rheometer may be externally controlled by a computer which allows for creating and editing measuring programmes, which makes possible optional and multiple parameter setting and saving them without the necessity of deleting. 5(68/76$1'',6&866,21 )LJXUHVWKURXJKVKRZWKHUHVXOWVRIUHVHDUFKRQGHtermining the effect of temperature on dynamic viscosity. CONCLUSIONS '\QDPLFYLVFRVLW\RI%6%0(%LRGLHVHOLQWKHWHPSHUDWXUHUDQJHIURPWRoC assumes the values from FDWR>P3DV@'\QDPLFYLVFRVLW\RI%6%0( %LRGLHVHODWoC was 9[mPas]. When the temperature was decreasing its value was increasing and at -20oC reached >P3DV@'\QDPLFYLVFRVLW\IRU%6%0(%LRGLHVHODW o&ZDV>P3DV@EXWZLWKFRROLQJIXHOVDPSOHLWZDV JURZLQJWRUHDFK>P3DV@DWoC. Dynamic viscosity of GLHVHORLO%LQWKHWHPSHUDWXUHUDQJHIURPWRoC DVVXPHVWKHYDOXHVIURPFDWR>P3DV@&RQGXFWHG UHVHDUFKGHPQVWUDWHGWKDWG\QDPLFYLVFRVLW\RI³%´ELRIXHOV is considerably affected by the temperature. Therefore, for DEHWWHUDVVHVVPHQWRIWKHHIIHFWRI6(HQJLQHIHHGLQJZLWK biofuels on the durability and reliability of the injection apparatus, not kinematic but dynamic viscosity should be considered. It is important because the changes of dynamic YLVFRVLW\LOOXVWUDWHWKHDFWXDOFKDQJHVRIWKHÀRZUHVLVWDQFH accompanying engine feeding with biofuels and biocomponents. Currently conducted research focuses on introduction of a proper standard for determining dynamic viscosity of fuels and biofuels. There are standards for rotation rheometers by means of which dynamic viscosity and other parameters, including surface tension, shearing forces, shearing rate or shearing tension may be highly precisely determined, which will make possible a better analysis of rheological properties of fuels and biofuels. 5()(5(1&(6 Fig. 2. The researchers post was furbished with a reometer and tub thermostats &LHĞOLNRZVNL%-XOLV]HZVNL70D]XUNLHZLF]- 2006: /HSNRĞü NLQHPDW\F]QD ELRSDOLZD L ID]\ JOLFHU\QRZHM,QĪ\QLHULD5ROQLF]DYRO 2. &LVHN-0UXN$+ODYĖD9 The properties of D+'9'LHVHOHQJLQHIXHOOHGE\FUXGHUDSHVHHGRLO7HND .RPLVML0RWRU\]DFMLL(QHUJHW\NL5ROQLFWZD9RO;, *5=(*25=:&,6à2 Fig. 3. 7KHDOJRULWKPLFZRUNVFKHPDWDLVXVLQJWKHUHRPHWHU5HRODE4& '(7(50,1$7,212)7+(5+(2/2*,&$/3523(57,(6 Anton Paar GmbH Biodiesel SBME B100 Diesel (B7) 200 dynamic viscosity [mPa s] 180 160 140 120 100 80 60 40 20 0 -20 -15 -12 -10 -5 o temperature C 0 5 10 15 20 30 40 50 Rheoplus Rheoplus )LJ'LDJUDPRI%6%0( 'LHVHO% )LJ'LDJUDPRI%6%0( and 'LHVHO% dynamic viscosity dependence in the function of temperature Fig. 4. 'LDJUDPRI%6%0(DQG'LHVHO%G\QDPLFYLVFRVLW\GHSHQGHQFHLQWKHIXQFWLRQRIWHPSHUDWXUH Diesel (B7) Diesel (B7) SBME B20 SBME B20 Anton Paar GmbH Anton Paar GmbH SBME B50 SBME B50 dynamic viscosity [mPa s] s] dynamic viscosity [mPa 65 55 45 35 25 15 5 -20 -15 -12 -10 -5 0 o temperature C temperature C 5 10 15 20 30 40 50 Rheoplus Rheoplus )LJ'LDJUDPRI%0%0 6%0( and 'LHVHO% dynamic viscosity dependence in the function of Fig. 5. 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COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 191–196 The Determination of Energetic Potential of Waste Wood Biomass Coming from Dębica Forestry Management Area as a Potential Basis for Ethanol Biofuels of II Generation 1 Grzegorz Wcisło, 2Natalia Labak Faculty of Production Engineering and Power Technologies University of Agriculture in Krakow, Poland 2 PhD student at the University of Agriculture in Krakow, Poland 1 Received December 08.2014; accepted December 19.2014 Summary. The goal of this study was to determine the heat of FRPEXVWLRQWRSFDORUL¿FYDOXHDQGWKHGHWHUPLQDWLRQRIIXHO YDOXHERWWRPFDORUL¿FYDOXHRIZDVWHZRRGELRPDVVRISRWHQWLDO raw material for the manufacture of ethanol biofuels of second generation. There determined the energy potential of waste wood biomass, which may be obtained for energy purposes from the WHUULWRU\RI'ĊELFD)RUHVW0DQDJHPHQW$UHD7KHKLJKHVWKHDWRI FRPEXVWLRQDQGFDORUL¿FYDOXHDPRQJWKHVWXGLHG¿YHVSHFLHVRI IRUHVWZRRGSLQHELUFKRDNDVKDQGSRSODUIHDWXUHGSLQH± 0-NJ0-NJDQGWKHORZHVWRDN±0-NJ0- NJ)URPWKHDERYHUHVXOWVWKDWWKHFDORUL¿FYDOXHVLPLODUO\ WRKHDWRIFRPEXVWLRQRISLQHLVDSSUR[7KHIXHOYDOXHRI ZRRGREWDLQHG\HDUO\E\WKH'ĊELFD)RUHVW0DQDJHPHQW$UHD RYHU\HDUVLV3- Key words: biomass, ethanol, biofuels of II generation, heat of FRPEXVWLRQWRSFDORUL¿FYDOXH INTRODUCTION In Poland since 2007 it has been legal to manufacture fuels and introduce them into free circulation. Manufactured are ELRIXHOVRI¿UVWJHQHUDWLRQWKDWLVPDLQO\ELRGLHVHODQGELRHWKanol, and they are introduced as biofuels and fuel additives. In WKHDYHUDJHVKDUHRIELRIXHOVDQGIXHOELRDGGLWLYHVRIWKH WRWDOIXHOFRQVXPSWLRQDPRXQWHGWRDWOHDVWFRQVLGHULQJ energy value in relation to Diesel fuel and petrols. SimultaneRXVO\ZLWKWKHPDQXIDFWXUHRI¿UVWJHQHUDWLRQELRIXHOVZRUNV have been started on new generation biofuels, the so called second generation. One of the objectives of the new biofuels ZDVWRPDQXIDFWXUHWKHPIURPQRQIRRGVRXUFHV%LRHWKDQRO may be manufactured of forestry and agricultural biomasses, ZKLFKLQFOXGHFHOOXORVHDQGOLJQRFHOOXORVH$YHU\LQWHUHVWLQJ idea seems to be the use of forestry wood waste. )RU(XURSHWKHPDLQVRXUFHVRIELRPDVVZLWKFHOOXORVH and lignocellulose content are forests. For that reason it is today important to assess the energy potential of wood waste biomass. This is also of local importance, because at locations with large resources of cellulose biomass in future will be constructed manufacturing facilities of second generation biofuels for transport. The development of the above fuels will cause partial independence from oil supplies and generate new MREVDQGZKDWLVPRVWLPSRUWDQWLWVKDOOIDYRXUDEO\LQÀXHQFH WKHHQYLURQPHQW$WSUHVHQWWKHDUHDRIIRUHVWVLQ3RODQGLV WKRXVDQGKHFWDUHVZKLFKFRUUHVSRQGVDIRUHVWDWLRQ UDWHRI>@,QWKHDUHDRIIRUHVWVLQ3RODQGZDV WKRXVDQGKHFWDUHVDFFRUGLQJWR*863ROLVKQDWLRQDO VWDWLVWLFDODJHQF\±WKHFRQGLWLRQDVRIZKLFK ZDVHTXLYDOHQWWRIRUHVWDWLRQUDWH>@ 7KHTXLFNHFRQRPLFGHYHORSPHQWZKLFKWRRNSODFH in the second half of the twentieth century, brought about DPRGL¿FDWLRQLQWKHXVHRIHQHUJ\UDZPDWHULDOV$QHZ model of global economy was shaped, which is mainly based on oil and earth gas, with decreasing use of black coal. The energy industry has the biggest share in emission of greenhouse gases into the atmosphere. In Poland the manufacture RIHOHFWULFHQHUJ\LVEDVHGPDLQO\RQEODFNFRDOOLJQLWHHDUWKJDVDQGUHQHZDEOHHQHUJ\VRXUFHV LQWRWDO>@8QIRUWXQDWHO\WKHHQHUJ\VHFWRU based on oil and coal causes excessive emissions of the so called greenhouse gases, mainly CO2>@)RUWKDWUHDVRQ 7+(&+$5$&7(5,67,&62)7+(678',(' in recent year more and more emphasis is put on efforts to 'ĉ%,&$)25(670$1$*(0(17$5($ OLPLWWKHHPLVVLRQRIXQGHVLUDEOHJDVHV7KH(XURSHDQ8QLRQ published several documents, that order a gradual replace7KH'ĊELFD)RUHVW0DQDJHPHQW$UHDLVORFDWHGLQ3RGPHQWRIPLQHUDOIXHOVZLWKUHQHZDEOHRQHV7KH &(GLUHFWLYHVWDWHVWKDWXQWLOWKHVKDUHRIUHQHZDEOH NDUSDFNLH3URYLQFH'LVWULFWVRI'ĊELFDDQG6ĊG]LV]yZ± HQHUJ\LQWKHWRWDOEDODQFHRIFRQVXPHGHQHUJ\VKDOOEH 5RSF]\FH7KH)RUHVW0DQDJHPHQW$UHDLQFOXGHVWZRIRUHVW *5=(*25=:&,6à21$7$/,$/$%$. FLUFXLWV±'ĊELFDDQGĩGĪDU\DQGLVGLYLGHGLQWRHOHYHQ IRUHVWULHV7KHWRWDO)RUHVW0DQDJHPHQW$UHDFRPSULVHV KHFWDUHVIRUHVWDUHDKHFWDUHV,QDGGLWLRQWKH 'ĊELFD)RUHVW0DQDJHPHQW$UHDVXSHUYLVHVIRUHVWVZKLFK GRQRWEHORQJWRWKH6WDWH7UHDVXUHRIWRWDODUHDRI KHFWDUHV±)LJ7KHPDLQIRUHVWVSHFLHVDUHSLQH EHHFK¿URDN PDQXIDFWXUHGIURPLWLVEHWZHHQDQG>@7KHORZ YDOXHRIWKLVFRHI¿FLHQWUHVXOWVIURPKLJKHQHUJ\RXWOD\V related to use, forestation, transport and processing of these raw materials. Wood waste biomass features in comparison with other traditional fuels two undoubted advantages: ± WKHXQFHDVLQJUHSURGXFLELOLW\RIZRRGLQIRUHVWV ± LWVDYDLODELOLW\LQRXUJHRJUDSKLFFRQGLWLRQV>@ $FFRUGLQJWRVWXGLHVWKHFDORUL¿FYDOXHRIGU\IRUHVW ZRRGELRPDVVLVRQWKHDYHUDJHORZHUZLWKDSSUR[DV FRPSDUHGZLWKFDORUL¿FYDOXHRIEODFNFRDODQGZLWKDSSUR[ ORZHUWKDQFDORUL¿FYDOXHRIIXHORLO0-NJDQG HDUWKJDV0-P3>@ $YHUDJHKXPLGLW\RIGHFLGXRXVZRRGGLUHFWO\DIWHUFOHDULQJUHDFKHV Wood waste biomass burns easily and is a valuable fuel, if dried properly. Wood dried outdoors in a natural way FRQWDLQVWRWDOKXPLGLW\:KHQEXUQLQJZRRGZLWK excessive content of humidity problems can occur with igniting, that is its ignition time will be longer and it will be PRUHGLI¿FXOWWRUHDFKSURSHUERLOHUHI¿FLHQF\>@,Q)LJ Fig. 1. 7KHQDWXUDODQGJHRJUDSKLFORFDWLRQRIWKH'ĊELFD)RUHVW ZDVSUHVHQWHGWKHUHODWLRQEHWZHHQZRRGFDORUL¿FYDOXHDQG 0DQDJHPHQW$UHD total humidity. &+$5$&7(5,67,&62):22':$67( %,20$66:,7+5()(5(1&( 72,76(1(5*<3523(57,(6 Wood waste biomass displays the most favourable parameters in relation to volume among the types of biomass used for energy purposes. The cost of energy obtained from wood waste biomass is decisively lower as compared with traditional sources. If we adopt the cost of energy obtained IURPZRRGDWWKHOHYHORIJU.:KJU 3/1 DVLQSDUWLFXODUFRQGLWLRQVWKHQWKHFRVWRIHQHUJ\ REWDLQHGIURPEXUQLQJRIFRNHLVRIWKDWYDOXHIURP EXUQLQJRIOLTXLGJDVDQGHDUWKJDVDQG of that value respectively, and from burning of black coal RIWKDWYDOXHZLWKRXWWKHFRVWRIWUDQVSRUW>@ The share of particular components with wood waste ELRPDVVGLIIHUVGHSHQGLQJRQVSHFLHV7DEOH3DUWLFXODUO\ worth noting is the difference when comparing wood of FRQLIHUVDQGGHFLGXRXVWUHHV7KLVDVSHFWLVUHÀHFWHGERWKLQ the cost of transport, effectiveness of wood burning process as well as mineral content of ash remained after burning. Fig. 2. &DORUL¿FYDOXHDVIXQFWLRQRIWRWDOKXPLGLW\FRQWHQWLQ ZRRG9ROW] &+(0,&$/&20326,7,21 2):22':$67(%,20$66 *HQHUDOO\ WKH FKHPLFDO FRPSRVLWLRQ RI SDUWLFXODU ZRRGVSHFLHVLVVLPLODUDQGFRQVLVWVRIGU\PDVVFRDO R[\JHQK\GURJHQQLWURJHQ %HVLGHVZRRGWKHZRRGZDVWHELRPDVVLVFRPSRVHG Ta b l e 1 . Percentage share of wood, green mass and bark with RIJUHHQPDVVOHDYHVEUDQFKHVQHHGOHFRYHUDQGEDUN particular wood waste biomass species [2] $VKHVLQEDUNFRQVWLWXWHDQGLQZRRG $VKHVLQFOXGHQXWULHQWVZKLFKRFFXULQWKHIRUPRIPLFURWood waste :RRG>@ *UHHQPDVV>@ %DUN>@ elements and oxides, like: K20, Na2O, P2O, CaO, MgO. biomass The content of selected microelements is presented in TaDeciduous trees EOH%HVLGHVWKHVSHFL¿HGFRPSRQHQWVWKHZRRGZDVWH Conifers 70-80 biomass includes: resins, tannins, waxes, fats, alkaloids %\XVLQJWKH3(53XUH(QHUJ\5DWLRH[SUHVVHGDV and mineral salts [2]. relations between obtained energy and consumed energy 'XHWRODUJHFRQWHQWRIYRODWLOHSDUWVZRRG we are able to determine the economic value of a particular ignites easily. Most part of volatile components are emitIXHO)RUFRDOWKHYDOXHRIWKLVUDWLRLVLQFOXGHGEHWZHHQ WHGDWWHPSHUDWXUHV&EXWWKHSURFHVVRIWKHUPDO DQGIRURLOLWDPRXQWVWRDQGIRUSK\WRPDVVDQGIXHOV GHFRPSRVLWLRQRIZRRGVWDUWVDWDSSUR[& 7+('(7(50,1$7,212)(1(5*(7,&327(17,$/ 2%-(&7,9($1'6&23(2)7+(:25. The goal of this study was to determine the heat of FRPEXVWLRQWRSFDORUL¿FYDOXHDQGWKHGHWHUPLQDWLRQRI IXHOYDOXHERWWRPFDORUL¿FYDOXHRIZDVWHZRRGELRPDVV of potential raw material for the manufacture of ethanol biofuels of second generation. There will be determined the energy potential of waste wood biomass, which may be REWDLQHGIRUHQHUJ\SXUSRVHVIURPWKHWHUULWRU\RI'ĊELFD )RUHVW0DQDJHPHQW$UHD7KHREWDLQHGUHVXOWVVKDOOEHXVHG LQWKHDERYH)RUHVW0DQDJHPHQW$UHDLQRUGHUWRGHYHORS a long term waste wood management strategy. The wood biomass studied in order to determine energy parameters ZDVGULHGWRUHDFKWKHWHFKQLFDOKXPLGLW\RI $3//,('0(7+2' %LW´FRPSDQ\7KHGLDJUDPRIWKHFDORULPHWHULVSUHVHQWHG LQ)LJ '(7(50,1$7,212)723+($72)&20%867,21 &$/25,),&9$/8( The determination of heat of combustion in the calorimHWHULVEDVHGRQWKHVLPSOL¿HGHTXDWLRQRIWKHUPDOEDODQFH of the calorimeter presented below: Qca mpal 4dmd Pwcwt+mscs¨W .¨W where: 4ac±KHDW RI ZRRG FRPEXVWLRQ UHODWHG WR WKH DQDO\WLFDO sample, mpal±ZHLJKWRIZRRGVDPSOH 4d±KHDWRIFRPEXVWLRQRIVWHHOZLUH md±ZHLJKWRIZLUH mw±ZHLJKWRIZDWHULQFDORULPHWULFYHVVHO cw±VSHFL¿FKHDWRIZDWHU ms±ZHLJKWRIVROLGERGLHVRIFDORULPHWHU±ERPEDQGYHVVHO cs±VSHFL¿FKHDWRIVROLGERGLHV 'W±FRUUHFWHGWHPSHUDWXUHLQFUHDVH .±FRQVWDQWWKHUPDOFDSDFLW\RIFDORULPHWHU The goal of the study was the determination of energy potential of waste wood biomass, which is a potential raw material for the manufacture of ethanol biofuels of II generation of cellulose biomass obtained from wood in the 'ĊELFD)RUHVW0DQDJHPHQW$UHD7KHEDVLVIRUWKHGHWHUmination of these parameters was the determination of heat +HDWRIFRPEXVWLRQZDVGHWHUPLQHGE\WKHFDORULPHWHU of combustion when burning wood samples coming from WKHDERYH)RUHVW0DQDJHPHQW$UHD7KHVWXG\LQFOXGHG using the following relation: WKHIROORZLQJVSHFLHVRIZRRGSUHVHQWLQWKH'ĊELFD)RUHVW K't 0DQDJHPHQW$UHD6FRWVSLQH3LQXVV\OYHVWULVZDUW\ELUFK Qca m pal %HWXODSHQGXOD(QJOLVKRDN4XHUFXVUXEUDDVK)UD[LQXVWUHPXODSRSODU3RSXOXVWUHPXOD7KHPDWHULDOZDV collected without bark from top part of bolt or log. Then &DORUL¿FYDOXHZDVFDOFXODWHGRQWKHEDVLVRIWKHSUHWKHPDWHULDOZDVFRPPLQXWHGDQGGULHGXVLQJ+637 YLRXVO\GHWHUPLQHGKHDWRIFRPEXVWLRQ7KHFDORUL¿FYDOXH 9DFXXP'ULHUWRUHDFKWKHWHFKQLFDOKXPLGLW\RI was referred to the analytical condition and calculated using the formula below: '(7(50,1$7,212)+($72)&20%867,21 $1'&$/25,),&9$/8(2)),9()25(67 :22'63(&,(6 The study was performed in compliance with Polish VWDQGDUGV31&DQG31*6ROLGIXHOV GHWHUPLQDWLRQRIKHDWRIFRPEXVWLRQDQGFDORUL¿FYDOXHLQ IRUFH>@+HDWRIFRPEXVWLRQZDVGHWHUPLQHGXVLQJ DXWRPDWLF./FDORULPHWHUPDQXIDFWXUHGE\Ä3UHF\]MD Qwa Qca mH 2O r , m pal where: +HDW RI HYDSRUDWLRQ U N-NJ 7KH VXP RI ZDWHU weights related to fuel humidity and weight of water from EXUQLQJRIK\GURJHQLQFOXGHGLQIXHOLVWKHTXDQWLW\RIZDWHU after condensing, that is analytical humidity expressed in humidity kg/ wood kg. where: FRQWUROXQLW 2. display of heat of combustion, FRPSXWHUV\VWHPFRPSXWHUV\VWHP GLJLWDOGLVSOD\ DJLWDWRU FDORULPHWULFERPE 7. electric switch, 8. 9. Fig. 3. 6FKHPDWLFGLDJUDPRI./FDORULPHWHU thermometer, signalling diodes, VWDUWRIPHDVXUHPHQW ZDWHUPDQWHOWKHUPRPHWHU DJLWDWRURIZDWHUPDQWHO FRLO. *5=(*25=:&,6à21$7$/,$/$%$. 8VLQJVWRLFKLRPHWULFHTXDWLRQVZHDUHDEOHWRFDOFXODWH gives more energy than oak wood is the fact, that it contains WKDWIURPNJK\GURJHQZHFDQREWDLQNJZDWHUWKDWLVK more volatile oils and resins, which considerably increase LWVFDORUL¿FYDOXH>@ which can be presented using the formula below : 7KHFDORUL¿FYDOXHRIZRRGGHSHQGVRQLWVW\SHKXmH 2 O midity and processing form. Despite the fact, that wood a a kgH 2O 9h W transactions are settled almost exclusively in volume units m pal kgpaliwa ±FXELFPHWHUVJHQHUDOO\LWVFDORUL¿FYDOXHLVGHWHUPLQHGE\ $VDUHVXOWZHREWDLQHGWKHUHODWLRQIRUFDOFXODWLQJFDO- LWVVSHFL¿FPDVV)RUH[DPSOHDFXWGRZQSLQHKDVGHQVLW\ of 700 kg/m3, but in totally dry condition its density falls RUL¿FYDOXHZKHQZHNQRZWKHKHDWRIFRPEXVWLRQ WRNJP3. a a a a For energy purposes it is best to use dry wood, howQw Qc r (9h W ever sometimes the waste wood biomass stored for energy From the above relations results, that in order to deter- SXUSRVHVIHDWXUHVGLIIHUHQWKXPLGLW\$PDWHULDOZKLFKKDV PLQHWKHFDORUL¿FYDOXHLWLVQHFHVVDU\WRNQRZWKHFRQWHQW already been dried, for example in periods with heavy rains of hydrogen and analytical humidity in the studied fuel. or in winter can become moist and will feature a lower FDORUL¿FYDOXH7RLOOXVWUDWHZKDWWKHLQÀXHQFHRQFDORUL¿FYDOXHRIZRRGIURPIRUHVWWUHHVKXPLGLW\FDQKDYH 7(675(68/76 taking into consideration the already obtained test results, WKHRUHWLFDOFDOFXODWLRQVRIFDORUL¿FYDOXHVRISDUWLFXODU ,Q)LJZHSUHVHQWHGWHVWUHVXOWVIRUWKHGHWHUPLQDWLRQ ZRRGVSHFLHVDWDVVXPHGKXPLGLW\RIDQG RIFDORUL¿FYDOXHDQGFDOFXODWLRQRIKHDWRIFRPEXVWLRQRI respectively were performed. The results of calculation VWXGLHGIRUHVWZRRGVSHFLHVDWDEVROXWHKXPLGLW\RI ZHUHSUHVHQWHGLQ7DEOHDQGLQWKH¿JXUHZDVSUHVHQWHG WKHLQÀXHQFHRIKXPLGLW\RQFDORUL¿FYDOXHRIZRRGVSHFLHV DWKXPLGLW\RI Ta b l e 2 . +XPLGLW\LPSDFWRQFDORUL¿FYDOXHRISDUWLFXODU wood species. Type of wood Fig. 4. &RPSDULVRQRIKHDWRIFRPEXVWLRQDQGFDORUL¿FYDOXHRI VWXGLHGIRUHVWWUHHVDWKXPLGLW\RI 7KHKLJKHVWFDORUL¿FYDOXHDPRQJWKHVWXGLHGZRRG ZDVWHELRPDVVVKRZVSLQH3LQXVV\OYHVWULV±0-NJ DQGDORZHURQHRDN4XHUFXVUXEUD±0-NJ)URP WKHDERYHUHVXOWVWKDWWKHFDORUL¿FYDOXHRISLQHDVZHOO DVKHDWRIFRPEXVWLRQLVDSSUR[KLJKHUDVFRPSDUHG ZLWKFDORUL¿FYDOXHRIRDN$SUREDEOHFDXVHWKDWSLQHZRRG Pine %LUFK Oak $VK Poplar DW humidity %RWWRPFDORUL¿FYDOXH>0-NJ@ DW DW DW humidity humidity humidity In compliance with statistical information made availDEOH E\ WKH 'ĊELFD )RUHVW 0DQDJHPHQW$UHD NQRZLQJ the percentage share of particular wood species in the whole waste wood biomass obtained yearly by the above management area was calculated the total calorific value for all species that constitute the forest stand of the above Ta b l e 3 . (QHUJ\SRWHQWLDORIZDVWHZRRGELRPDVVREWDLQHGLQVXEVHTXHQW\HDUVE\WKH'ĊELFD)RUHVW0DQDJHPHQW$UHD (QHUJ\SRWHQWLDORIZRRGREWDLQHGLQVXEVHTXHQW\HDUV 4XDQWLW\RIZRRGRE&DORUL¿FYDOXHRI &DORUL¿FYDOXHRI <HDU WDLQHGLQWKHVXEVHTXHQW wood [MJ] ZRRG>*-@ 3 years [m ] 2007 2008 2009 In total Average yearly result 62 944 5995989766 5995989.77 (OHFWULFHQHUJ\ [MWh] 1665552.7 7+('(7(50,1$7,212)(1(5*(7,&327(17,$/ PDQDJHPHQW DUHD7KH UHVXOWV DUH SUHVHQWHG LQ7DEOH LV *- 7KLV DPRXQW RI HQHUJ\ HTXDOV below. 0:KHOHFWULFHQHUJ\$QDYHUDJHEDVHG )URP7DEOHUHVXOWVWKDWWKHFDORUL¿FYDOXHRIZRRG RQPHGLXP\HDUO\UHVXOWRI0:KLVHTXDO FDOFXODWHGLQ>*-@IURPWKHWRWDORIZRRGREWDLQHG\HDUO\ WR*-HQHUJ\ E\WKH'ĊELFD)RUHVW0DQDJHPHQW$UHDRYHUWKHSHULRGRI 7KHIXHOYDOXHRIDOODVVRUWPHQWVRIZDVWHZRRGREWDLQHG \HDUVLV>*-@DVDUHVXOWRIWKH E\WKH'ĊELFD)RUHVW0DQDJHPHQW$UHDDWWKHH[DPSOH RI\HDUWRWDOOHG*- DVVXPSWLRQWKDW0:K 0-WKHREWDLQHGLQWKLV SHULRGELRPDVVLVHTXDOWRHOHFWULFHQHUJ\RI MWh over a period of six years, and expressed as average 5()(5(1&(6 \HDUO\TXDQWLW\LWLV0:KZKLFKFRQYHUWHGLQWR >*-@\LHOGV\HDUO\HQHUJ\ ,Q7DEOHZHUHVXPPDULVHGWHVWUHVXOWVZKLFKVKRZ %XþNR - 2VYDOG$ : Rozklad dreva teplom ZKDWLVWKHFDORUL¿FYDOXHRIWKHELRPDVVIURPDOOVRUWVRI DRKĖRP78YR=YROHQH ZDVWHZRRGDWWKHH[DPSOHRI\HDU 2. 'RPDĔVNL0LLQQL'UHZQRMDNRPDWHULDáHQHUJHW\F]Q\:\GDZQLFWZR6**::DUV]DZD Ta b l e 4 . (QHUJ\SRWHQWLDORIDOOVRUWVRIZDVWHZRRGREWDLQHG Glijer L., 19993URFHV\VSDODQLDLZDORU\ĞURGRZLVNR\HDUO\E\WKH'ĊELFD)RUHVW0DQDJHPHQW$UHDDWWKHH[DPSOH we wykorzystania drewna do celów grzewczych. Post. RI\HDU 7HFK/HĞQU± /DXUyZ=: Wykorzystanie surowca drzewnego (QHUJ\SRWHQWLDORIZDVWHZRRG GRFHOyZHQHUJHW\F]Q\FK%LEOLRWHF]NDOHĞQLF]HJR=HType of obtained assortment from <HDU &DORUL¿FYDOXH waste wood [m3] >*-@ V]\WQU *862FKURQDĝURGRZLVND:DUV]DZD Dead wood from standing trees *862FKURQDĝURGRZLVND:DUV]DZD Dead wood from lying trees 7. *862FKURQDĝURGRZLVND:DUV]DZD Dead wood from twigs 8. Janowicz L., 2006 %LRPDVD Z 3ROVFH (QHUJHW\ND Dead wood from stumps and roots L(NRORJLD In total 9. àXNDVLN$: Szanse dla robinii w Polsce. Trybuna 7KHFDORUL¿FYDOXHRIDOODVVRUWPHQWVRIZDVWHZRRG /HĞQLNDQU REWDLQHGE\WKH'ĊELFD)RUHVW0DQDJHPHQW$UHDDWWKHH[- RDLP w Katowicach1DGOHĞQLFWZR.RELyU3ODQ DPSOHRI\HDUZDV*- 8U]ąG]DQLD/DVXQDRNUHV 5RPHU(, 1999: Regiony klimatyczne Polski. PWTN, VHU%QU:URFáDZ Trampler T i in., 1990Ä5HJLRQDOL]DFMH3U]\URGQLF]RCONCLUSIONS /HĞQDQDSRGVWDZDFKHNRORJLF]QR¿]MRJUD¿F]Q\FK´ PWRiL, Warszawa. 7KHVWDWHRZQHG1DWLRQDO)RUHVWV/DV\3DĔVWZRZH enterprise is able to deliver wood waste biomass for Wisz J., Matwiejew A., 2005%LRPDVDEDGDQLDZODenergy purposes in the form of different assortments ERUDWRULXPZDVSHNFLHSU]\GDWQRĞFLGRHQHUJHW\F]QHJR such as: small dimensioned wood, rests from clearings, VSDODQLD(QHUJHW\ND ZLQGIDOOZRRGIXHOZRRGDQGORZTXDOLW\SXOSZRRG =DPRURZVNL.:VSyáVSDODQLHELRPDV\ZNRWOH LQFDVHRIQDWXUDOGLVDVWHUVKXUULFDQHVÀRRGVLQVHFW UXV]WRZ\P(QHUJHW\NDQU SHVWLQIHVWDWLRQVZRRGRIKLJKHUTXDOLW\IRUSURWHFWLRQ Voltz K. 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Forest wood waste biomass is a perfect raw material for ODQLDLZDUWRĞFLRSDáRZHM the manufacture of ethanol biofuels of II generation, be- PN-81/G-045133DOLZDVWDáH2]QDF]DQLHFLHSáDVSDODQLDLZDUWRĞFLRSDáRZHM FDXVHLWLVSRVVLEOHWRREWDLQODUJHTXDQWLWLHVRIELRPDVV with cellulose and lignocellulose content. 7KHKLJKHVWKHDWRIFRPEXVWLRQDQGFDORUL¿FYDOXHDPRQJ 2.5(ĝ/(1,(327(1&-$à8(1(5*(7<&=1(*2 '(1'520$6<2'3$'2:(-32&+2'=Ą&(- WKHVWXGLHG¿YHVSHFLHVRIIRUHVWZRRGSLQHELUFKRDN DVKDQGSRSODUIHDWXUHGSLQH±0-NJ0-NJ =1$'/(ĝ1,&7:$'ĉ%,&$-$.2327(1&-$/1(- %$=<'/$%,23$/,:(7$12/2:<&+ DQGWKHORZHVWRDN±0-NJ0-NJ)URP ,,*(1(5$&-, WKHDERYHUHVXOWVWKDWWKHFDORUL¿FYDOXHVLPLODUO\WR KHDWRIFRPEXVWLRQRISLQHLVDSSUR[KLJKHUWKDQ WKHFDORUL¿FYDOXHRIRDN7KHSUREDEOHFDXVHRIWKHIDFW Streszczenie. &HOHP SUDF\ E\áR oznaczenie FLHSáD VSDODQLD ZDUWRĞFLRSDáRZHMJyUQHMRUD]Z\]QDF]HQLHZDUWRĞFLRSDáRthat pine wood has higher energy value than oak wood, ZHMZDUWRĞFLRSDáRZHMGROQHMELRPDV\]GUHZQDRGSDGRZHJR is because pine has more volatile oils and resins which potencjalnego surowca do produkcji biopaliw etanolowych II geFRQVLGHUDEO\LQFUHDVHLWVFDORUL¿FYDOXH QHUDFML1DVWĊSQLH]RVWDQLHRNUHĞORQ\SRWHQFMDáHQHUJHW\F]Q\ 7KHIXHOYDOXHRIZRRGREWDLQHG\HDUO\E\WKH'ĊEL- GHQGURPDV\MDNLPRĪQDSR]\VNDüQDFHOHHQHUJHW\F]QH]WHUHQX FD)RUHVW0DQDJHPHQW$UHDRYHU\HDUV *5=(*25=:&,6à21$7$/,$/$%$. 1DGOHĞQLFWZD'ĊELFD1DMZ\ĪV]\PFLHSáHPVSDODQLDLZDUWRĞFLą RSDáRZąZĞUyGSU]HEDGDQ\FKSLĊFLXJDWXQNyZGU]HZOHĞQ\FK VRVQDEU]R]DGąEMHVLRQLWRSRODFKDUDNWHU\]RZDáDVLĊVRVQD± 0-NJ0-NJQDWRPLDVWQDMPQLHMV]ąGąE± 0-NJ0-NJ:DUWRĞüRSDáRZDGUHZQDSR]\VNLZDQHJR FRURF]QLHSU]H]1DGOHĞQLFWZR'ĊELFDQDSU]HVWU]HQLODW Z\QRVL3- 6áRZDNOXF]RZHELRPDVDHWDQROELRSDOLZD,,JHQHUDFMLFLHSáR VSDODQLDZDUWRĞüRSDáRZD TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 197–200 Determination of the Impact of the Type of Camelina Oil Used for Production of Biofuels on the Fractional Composition of CSME Grzegorz Wcisło, 2Bolesław Pracuch 1,2 Faculty of Production Engineering and Power Technologies, University of Agriculture in Krakow, Poland 2 BioEnergia Małopolska Centre for Renewable Energy Sources, Poland e-mail: [email protected] 1 Received December 08.2014; accepted December 19.2014 Summary. The aim of the study was to determine the impact RIWKHIU\LQJSURFHVVRQWKHIUDFWLRQDOFRPSRVLWLRQRI&60( %LRGLHVHOLQFRPSDULVRQWRWKH&60(REWDLQHGIURPXQXVHG IUHVKFDPHOLQDRLO7KHIUHVKO\SUHVVHGFDPHOLQDRLOZDVGLYLGHG LQWRWZRSRUWLRQV2QHZDVXVHGIRUIU\LQJFKLSVDW&IRU DSHULRGRIKRXUV7KHVWXG\VKRZHGWKH&60(ELRGLHVHO SURGXFHGIURPXQXVHGSXUHFDPHOLQDRLOJHQHUDOO\KDVEHWWHU distillation properties. The temperatures at the start of distillation ZHUHVLPLODUIRUERWKRIWKH&60(V:LWKLQWKHPLG UDQJHWHPSHUDWXUHVWKH&60(SURGXFHGIURPWKHXVHGFRRNLQJ camelina oil was characterized by higher distillation temperatures for the same volume of fuel. The largest differences were REVHUYHGIRUWKHDQGGLVWLOODWLRQWHPSHUDWXUHVDQGWKH ¿QDOWHPSHUDWXUHRIWKHGLVWLOODWLRQSURFHVV7KLVPD\WHVWLI\WR ORZHUSXULW\RIWKH&60(SURGXFHGIURPWKHXVHGFRRNLQJRLO In such a biofuel there may be more less volatile mono- and diglycerides or other chemicals which e.g. remain in the oil after frying. It must be said, though, these are not solid particles, as WKRVHZHUHVHSDUDWHGIURPWKHRLOWKURXJK¿OWUDWLRQ Key words: %LRGLHVHO%LRGLHVHOGLHVHOHQJLQHIUDFWLRQDOFRPposition, temperature distillation. INTRODUCTION ,QDFFRUGDQFHZLWKWKH$FWRQELRFRPSRQHQWVDQGOLTXLGIXHOVDGRSWHGE\WKH3ROLVK6HMPRQ$XJXVW biofuels may be produced and marketed legally in Poland as RI-DQXDU\6RIDUWKHFRXQWU\KDVODXQFKHGPDMRU LQVWDOODWLRQVLQWHQGHGIRUWKHSURGXFWLRQRI)$0(50( biofuels, whose total production capacity is estimated to EHDVKLJKDVPLOOLRQWRQQHVRIHVWHUVD\HDU2QWKHRWKHU hand, the annual national demand for diesel fuel is around PLOOLRQWRQQHVSHU\HDU7KHXVHRIDIXHODGGLWLYHLQWKH IRUPRIYYRIELRFRPSRQHQWQHFHVVLWDWHVSURGXFWLRQ RIDSSUR[WRQQHVRIHVWHUVSHU\HDU Recently, there has been a great interest among individuals, including farmers, as well as companies and institutions EHLQJLQSRVVHVVLRQRIYHKLFOHÀHHWVLQWKHSRVVLELOLW\RI producing biofuels for their own purposes. Under the law currently applicable in Poland, one may legally produce biRIXHOVIRUWKHLURZQSXUSRVHV$PRQJHVSHFLDOO\SULYLOHJHG groups are farmers, who are allowed to produce raw material for the production of biofuels for their purposes, which sigQL¿FDQWO\UHGXFHVWKHSURGXFWLRQFRVWIRUWKLVHQHUJ\FDUULHU )$0(%LRGLHVHOLVREWDLQHGLQWKHSURFHVVRIWUDQVHVWHUL¿FDWLRQ,WVSDUDPHWHUVGHYLDWHVOLJKWO\IURPWKRVHRI WKHGLHVHOIXHOKRZHYHULIWKHWUDQVHVWHUL¿FDWLRQSURFHVV is carried out properly, the resulting biofuel can be used as an additive in the form of a diesel bio-component or used DVDSXUHIXHO%)$0(ELRGLHVHOKDVEHWWHUSDrameters compared to the diesel fuel: higher cetane number, better lubricating properties, higher ignition temperature and ORZVXOIXUFRQWHQW>@ One of the principal parameters used for assessing the VXLWDELOLW\RI)$0(ELRGLHVHOVIRUFRPSUHVVLRQLJQLWLRQHQgines is the fractional composition, which is the reason why this very subject was chosen for investigation by the authors of this paper. The aim of the research presented below was to determine and compare the fractional compositions of WZR&60(ELRIXHOVRQHSURGXFHGIURPSXUHFDPHOLQD canola oil and the other derived from the same oil but used in the process of frying chips in a restaurant for a period of one week. When used in frying, the oil was heated to the WHPSHUDWXUHRI& $JURZLQJGHPDQGIRUELRIXHOVSURGXFHGPDLQO\IURP rape-seed oil makes producers search for new alternative SODQWV*ROGRISOHDVXUH&DPHOLQD6DWLYDDGLFRW\OHGRQ EHORQJLQJWREUDVVLFDVSODQWVRIWKHFDEEDJHIDPLO\EHLQJ RQHRIWKHP>@$VIDUDVVRLOVDUHFRQFHUQHG*ROG of pleasure is undemanding, compared with oilseed rape, DQGFDQEHJURZQRQVRLOVRIWKHthDQGthFODVVHV$URXQG 700dm3RIRLOFDQEHREWDLQHGIURPKHFWDURIODQGZKLOH DSSO\LQJDRQHVWHSPHWKRGRIFROGSUHVVLQJ>@%LRIXHORI WKH&60(%LRGLHVHOW\SH&DPHOLQD6DWLYD0HWK\O(VWHUV *5=(*25=:&,6à2%2/(6à$:35$&8&+ ZDVSURGXFHGLQD*:UHDFWRUFRQVWUXFWHGE\RQHRIWKH 0HWK\ODOFRKROPHWKDQROZDVXVHGIRUWUDQVHVWHUL¿FDWLRQ DXWKRUV*: RI*ROGRISOHDVXUHRLOZLWKDONDOLQHSRWDVVLXPK\GUR[LGH SRWDVVLXPK\GUR[LGHSXUHSDDVDFDWDO\VWLQWKHUHDFWLRQ 7KHSURFHVVRIWUDQVHVWHUL¿FDWLRQZDVFDUULHGRXWLQWZR 352'8&7,212)50(%,2)8(/6,17+( stages and the obtained degree of oil transition into methyl 352&(662)75$16(67(5,),&$7,21)520 HVWHUVZDVHTXDOWRPP7KHUHVXOWKDVSURYHG 385(2,/$1'86('2,/ WKDWWKHREWDLQHG&60(ELRIXHOFRPSOLHVZLWK(1 standards of biofuel for a high pressure engine, as regards %LRIXHO RI WKH &60( %LRGLHVHO W\SH &DOFXODWLQJWKHRSWLPXPVWRLFKLRPHWULFDPRXQWRIUHDF- WKHHVWHUFRQWHQWLQ)$0()DWW\$FLG0HWK\O(VWHUV &DPHOLQD6DWLYD0HWK\O(VWHUVZDVSURGXFHGLQD*: UHDFWRUFRQVWUXFWHGE\RQHRIWKHDXWKRUV*: WDQWVQHHGHGWRFDUU\RXWWKHWUDQVHVWHUL¿FDWLRQSURFHVVXVXDOO\ LQYROYHVWKHXVDJHRIVLPSOL¿HGPRGHOV>@+RZHYHULQ '(7(50,1$7,212)7+(,03$&72)7+( order to determine the appropriate amount of reactants need352'8&7,212)50(%,2)8(/6,17+(352&(662)75$16(67(5,),&$7,21)520385(2,/ 7<3(2)&$0(/,1$2,/86(')25%,2)8(/ HGWRSURGXFH50(WKHDXWKRUVRIWKLVSDSHUXVHGDPRGHO $1'86('2,/ 352'8&7,21217+()5$&7,21$/ developed by one of the co-authors, which makes it possible &20326,7,212)&60(%,2',(6(/ WRRSWLPDOO\GHWHUPLQHWKHTXDQWLWLHVRIPHWK\ODOFRKRODQG WKHFDWDO\VWQHFHVVDU\IRUWKHSURFHVVRIWUDQVHVWHUL¿FDWLRQ &DOFXODWLQJ WKH RSWLPXP VWRLFKLRPHWULF DPRXQW RI UHDFWDQWV QHHGHG WR FDUU\ RXW WKH WUDQVHVWHULILFDWLRQ $YHU\LPSRUWDQWSDUDPHWHUXVHGIRUWKHDVVHVVPHQWRI ±)LJ>@7KHIROORZLQJUDWLRZDVXVHGIRUWKHSXUSRVH OLILHG PRGHOV >@ +RZHYHU LQ RUGHU WR GHWHUPLQH WKH DSSURSULDWH 3 DPRXQWRIUHDFWDQWVQHHGHGWRSURGXFH50(WKHDXWKRUVRIWKLVSDSHUXVHGDPRGHOGHYHORSHGE\RQHRIWKHFR RIWUDQVHVWHUL¿FDWLRQRIFDQRODRLOVIRUHDFKGP of oil, fuel/biofuel operating properties is their fractional composiDXWKRUV ZKLFK PDNHV LW SRVVLEOH WR RSWLPDOO\ GHWHUPLQH PHWK\O on the basis of the temperDPL[WXUHREWDLQHGIURPGLVVROXWLRQRIJRI.2+LQ tion. 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The research determining the fractional compositions RI&60(ELRIXHOVREWDLQHGIURPSXUHDQGXVHGFDQRODRLO ZDVFDUULHGRXWLQWKHELRIXHOVODERUDWRU\RI³%LR(QHUJLD´ 0DORSROVNL&HQWUHIRU5HQHZDEOH(QHUJ\6RXUFHVDWDZRUNVWDWLRQHTXLSSHGZLWKDFDPHUDIRUGHWHUPLQLQJWKHFRPSRsition of the fuels and biofuels with the method of normal GLVWLOODWLRQ±)LJ UHVHDUFKRQWKHGLVWLOODWLRQWHPSHUDWXUHVRI50(%%LRGLHVHOREWDLQHGIURP%/,6.$VHUYLFHVWDWLRQFKDLQRZQHG E\3.125/(1JURXSDQG(NRGLHVHOIXHOREWDLQHGIURP 3.125/(1JURXSVHUYLFHVWDWLRQV Table 2 summarizes the values of the most important SRLQWVRIWKHGLVWLOODWLRQFXUYHIRU50(%LRGLHVHOVREWDLQHG from both of the canola oils, i.e. the temperatures at the start DQGHQGRIWKHGLVWLOODWLRQSURFHVVDQGWKHSHUFHQWDJHYY RIGLVWLOOHGIXHOVDWRUEHORZ&DQG& Ta b l e 1 . Comparison of distillation temperatures for two &60(%LRGLHVHOVDQG50(%LRGLHVHOIURP%/,6.$VHUYLFH stations and diesel fuel >YY@RI &60(%LRGLHVHO &60(%LRGLHVHO 50(%LRGLHVHO ON distillation from pure oil from used oil %/,6.$ 0 202 20 222 270 279 287 70 80 90 Ta b l e 2 . Characteristic distillation curve points for diesel DQG&60(ELRIXHOV Fig. 2. 3KRWREHQFKHTXLSSHGZLWKDGLVWLOOHU+$'E\ +HU]RJ 5(68/76 8SWRWKLVWHPSHUDWXUHYYZDVGLVWLOOHG Start of (QGRI XSWRoC XSWRoC fuel distillation distillation distils distils [oC] YY>@ YY>@ [oC] &60(%LRGLHVHO 0 29 from pure oil &60(%LRGLHVHO 0 27 from used oil 50(%LRGLHVHO 0 %/,6.$ ON CONCLUSIONS 7KHVWXG\KDVVKRZQWKDW&60(%LRGLHVHOSURGXFHG 7DEOHVXPPDUL]HVWKHUHVXOWVRIWKHUHVHDUFKGHWHUPLQ- IURPXQXVHGIUHVKFDPHOLQDRLOLVFKDUDFWHUL]HGE\EHWWHU LQJWKHVHGLVWLOODWLRQSURSHUWLHVRI&60(%%LRGLHVHOV distillation properties. The initial stages of distillation and the For comparison purposes, the table shows the results of the TXDQWLW\RIPLGGOHGLVWLOODWHVLQVDLG&60(VDUHVLPLODU7KH 200 *5=(*25=:&,6à2%2/(6à$:35$&8&+ 7. :FLVáR*: Utilization of used oils and fat for PDQXIDFWXULQJ)$0(ELRIXHOV7HND.RPLVML0RWRU\]DFMLL(QHUJHW\NL5ROQLFWZD9RO;V 8. :FLVáR*: Przetwarzanie biomasy na cele enerJHW\F]QH3UDFD]ELRURZDSRGUHGDNFMą)UąF]HN-8QLZHUV\WHW5ROQLF]\LP+.RááąWDMD.UDNyZ 9. :FLVáR*2NUHĞOHQLHVNáDGXIUDNF\MQHJRELRSDOLZUROQLF]\FK]DZLHUDMąF\FKELRNRPSRQHQW&60( ,QĪ\QLHULD5ROQLF]D9RO Wojtkowiak R. and others. 2009: Production Costs LQD1RYHO0HWKRGRI0DQXIDFWXUHRIWKH0HWK\O(VWHUV)URP)DOVH)OD[&DPHOLQD6DWLYD/2LOIRU)HHG WKH3LVWRQ&RPSUHVVLRQ,JQLWLRQ(QJLQHV-RXUQDORI 5HVHDUFKDQG$SSOLFDWLRQLQ$JULFXOWXUH(QJLQHHULQJ 9RO Wojtkowiak R. and others. 2007: Olej lniankowy jako SDOLZRGR]DVLODQLDVLOQLNyZ]]DSáRQHPVDPRF]\QQ\P 0RQRJUD¿DSRGUHGDNFMą==E\WNDWRP:\EUDQH ]DJDGQLHQLDHNRORJLF]QHZHZVSyáF]HVQ\PUROQLFWZLH 3U]HP\VáRZ\ ,QVW\WXW 0DV]\Q 5ROQLF]\FK 3R]QDĔ Wojtkowiak R. and others. 2007: Koszt produkcji paOLZD]ROHMXOQLDQNRZHJRGRVLOQLNyZ]]DSáRQHPVDPRF]\QQ\P0RQRJUD¿DSRGUHGDNFMą==E\WNDWRP :\EUDQH]DJDGQLHQLDHNRORJLF]QHZHZVSyáF]HVQ\P UROQLFWZLH3U]HP\VáRZ\,QVW\WXW0DV]\Q5ROQLF]\FK 3R]QDĔ 6]ODFKWD==DVLODQLHVLOQLNyZZ\VRNRSUĊĪQ\FK paliwami rzepakowymi, Wydawnictwa Komunikacji LàąF]QRĞFL:.à±:DUV]DZD Biodiesel 2006+DQGOLQJDQG8VH*XLGHOLQHV86'H5()(5(1&(6 SDUWPHQWRI(QHUJ\7KLUG(GLWLRQ6HSWHPEHU 8VWDZD]GQLDVLHUSQLDURELRNRPSRQHQWDFK LELRSDOLZDFKFLHNá\FK']8QUSR] &LVHN-0UXN$+ODYĖD9 The properties of ]SyĨQ]P D+'9'LHVHOHQJLQHIXHOOHGE\FUXGHUDSHVHHGRLO7HND .RPLVML0RWRU\]DFMLL(QHUJHW\NL5ROQLFWZD9RO;, Cisek J., Mruk A. 2012::áDĞFLZRĞFLVLOQLND=6]D2.5(ĝ/(1,(:3à<:852'=$-88ĩ<7(*2 2/(-85=(3$.2:(*2'2352'8.&-,%,23$/,: VLODQHJRQDWXUDOQ\PROHMHPU]HSDNRZ\P=HV]\W\1D1$6.à$')5$.&<-1<&60( ukowe Instytutu Pojazdów Politechniki Warszawskiej ]VHULL0HFKDQLND(NRORJLD%H]SLHF]HĔVWZR0HFKDWURStreszczenie. 3U]HSURZDG]RQHEDGDQLDSRND]Dá\ĪHQLH]DOHĪQLH QLND9RO Jakóbiec J., Ambrozik A. 2009: Procesy starzenia RGURG]DMX]DVWRVRZDQHJRROHMXOQLDQNLGRSURGXNFML50(F]\ HVWUyZPHW\ORZ\FKNZDVyZWáXV]F]RZ\FKROHMXU]HSD- EĊG]LHWRROHMQLHXĪ\W\OXE]XĪ\W\]DNUHV\WHPSHUDWXUGHVW\ODFMLE\á\SRGREQH1LHZLHONLHUyĪQLFH]DQRWRZDQRMHG\QLHGOD NRZHJR,QĪ\QLHULD5ROQLF]DV WHPSHUDWXUNRĔFDGHVW\ODFML&60(Z\SURGXNRZDQH]]XĪ\WHJR 8]GRZVNL0 20060RĪOLZRĞFLZ\NRU]\VWDQLDPLHROHMXOQLDQNLSRWU]HERZDáRZ\ĪV]\FKWHPSHUDWXUGRRGSDURZDQLD szanin paliw tradycyjnych i alternatywnych do zasilania FDáHMREMĊWRĞFL)$0(0RĪHWRĞZLDGF]\üRPQLHMV]HMF]\VWRĞFL VLOQLNyZ=60RWURO9RO$ &60(X]\VNDQHJR]H]XĪ\WHJRROHMX:WDNLPELRSDOLZLHPRĪH Tys J. i in. 2003: Technologiczne i ekonomiczne uwa- ]QDMGRZDüVLĊZLĊFHMPDáRORWQ\FKPRQRLGLJOLFHU\GyZOXE runkowania produkcji biopaliwa z rzepaku. Instytut LQQ\FK]ZLą]NyZNWyUHQSSR]RVWDá\ZROHMXSRSURFHVLHVPD$JUR¿]\NLLP%RKGDQD'REU]DĔVNLHJR3$1Z/XEOLQLH ĪHQLDIU\WHN3U]\F]\PQLHFKRG]LWXRF]ąVWNLVWDáHSRQLHZDĪ :FLVáR* 2011: 7HVWLQJ$)0(DQG50(ELRIXHOVIRU WH]RVWDá\RGG]LHORQHRGROHMXSRGF]DV¿OWUDFML composition of fatty acids. Teka Komisji Motoryzacji 6áRZDNOXF]RZH%LRGLHVHOELRSDOLZRVLOQLNZ\VRNRSUĊĪQ\ VNáDGIUDNF\MQ\WHPSHUDWXU\GHVW\ODFML L(QHUJHW\NL5ROQLFWZD9RO;,& VWDUWRIGLVWLOODWLRQIRUERWKWKH&60(VRFFXUUHGDWDSSUR[ o&$SSUR[YYRI50(ZDVGLVWLOOHGXSWRoC. *UHDWHUGLIIHUHQFHVZHUHREVHUYHGIRUWKHYYGLVWLOlation temperatures and at the end of the distillation process. YY&60(&60(YDSRULVHGXSWRWKHWHPSHUDWXUHRI 270oC, whearas for biufuel derived from used oil the temperature was 282o&&60(REWDLQHGIURPWKHIUHVKFDPHOLQDRLO ZDVHQWLUHO\GLVWLOOHGXSWRWKHWHPSHUDWXUHRIoC, while 50(GHULYHGIURPWKHXVHGFDPHOLQDRLOYDSRULVHGRQUHDFKLQJo&7KLVPD\WHVWLI\WRORZHUSXULW\RIWKH&60( produced from used cooking oil. In such biofuel, there may be more less volatile mono- and diglycerides or other chemicals which result from the lower level of oil-to-biofuel conversion and/or are an effect of residues from the process of frying chips. It must be said, though, these were not solid particles, DVWKRVHZHUHVHSDUDWHGIURPWKHRLOWKURXJK¿OWUDWLRQ $IWHUWKHFRPSDULVRQRIWKHUHVXOWVIRUERWKWKH&60(V ZLWKDFRPPHUFLDO50(ELRIXHOREWDLQHGIURP%/,6.$ service stations, it turned out that biofuels from camelina are characterized by slightly worse distillation properties. 1RWDEOHLVWKHGLIIHUHQFHLQWKHTXDQWLW\RI50(GLVWLOOHGXS WRWKHWHPSHUDWXUHRI&VLQFH%/,6.$VHUYLFHVWDWLRQ ELRIXHOVYDSRUL]HGLQJUHDWHUDPRXQWV±YYPRUHWKDQ WKH&60(SURGXFHGIURPWKHSXUHRLODQGPRUHWKDQ WKH&60(IURPWKHXVHGFRRNLQJFDPHOLQDRLO %RWKWKH&60(VGRQRWFRPSO\ZLWKWKHUHTXLUHPHQWV VHWE\(1IRU)$0(SODQWELRIXHOVGXHWRWKH¿QDO distillation temperature. Under the above-mentioned standDUGWKHWHPSHUDWXUHRI&QHHGVWRYDSRULVHWKHHQWLUH amount of biofuel. 2. TEKA. COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 201–210 Effects of Pre-Sowing Magnetic Stimulation on the Growth, Development and Changes in Physicochemical Properties in Sugar Beet Seedlings Miłosz Zardzewiały, Grzegorz Zaguła, Czesław Puchalski Department of Bioenergy Technologies, University of Rzeszow ul. Rejtana 16C, 35-959 Rzeszow, Poland Received December 02.2014; accepted December 17.2014 Summary. 7KHPDJQHWLF¿HOGLVDSK\VLFDOIDFWRUWRLPSURYHJHUmination and development of plants. The laboratory experiment was conducted to determine the effect of pre-sowing magnetic ¿HOGVWLPXODWLRQRQWKHDELOLW\RIJURZWKDQGGHYHORSPHQWDQG changes in the physicochemical properties of sugar beet seedOLQJV8VHGPDJQHWLF¿HOGRIORZIUHTXHQF\I +]% P7H[SRVXUHWLPHW VHFRQGV7KHQLGHQWL¿HGWKHPRVW favorable induction. In the rest of the experiment the results were compared with a control group, taking into account changes in the basic physical and chemical properties of beet seedlings. The observations carried out during the experiment focused on the growth of plants and determining the basic composition of micro- and macronutrients in the emerging plants. Key words: PDJQHWLF ¿HOGV SK\VLFRFKHPLFDO FRPSRVLWLRQ heavy metals; sugar beet germination. INTRODUCTION 6XJDUEHHW%HWDYXOJDULVVXEVSYXOJDULVFRQYDUFUDVVDSURYDUDOWLVVLPDLVDQLQGXVWULDOSODQWZLWKODUJHFRQWHQWV of sucrose and, after sugarcane, it is the second most important source of sugar produced for consumption, accounting IRUDSSUR[RIJOREDOSURGXFWLRQ>@6XJDUEHHW belongs to the Chenopodiaceae family. It originated from WKHFRDVWVRIWKH0HGLWHUUDQHDQ&DVSLDQDQG%ODFN6HDV ,Q3RODQGDQGRWKHUFRXQWULHVJOREDOO\VXJDUEHHWLV the basic raw material used for production of sugar in the WHPSHUDWHFOLPDWH]RQH>@0RUHRYHUVXJDUEHHWPD\EH a valuable forage crop or raw material for various branches RILQGXVWU\>@ Crop cultivation is indispensable for human existence, for production of food of both plant and animal origin. People must continuously increase food production due to the growing population. In order to provide sustenance IRUSHRSOHLQDGHTXDWHTXDQWLW\DQGTXDOLW\LWLVQHFHVVDU\ WRVLJQL¿FDQWO\LPSURYHIUXLWIXOQHVVLQSODQWV7KLVFDQ be achieved by using two groups of technologies: those necessary for enhancing genotypes of cultivars as well as more effective and environmentally friendly cultivation systems. Until the eighteenth century crops were increased by expanding area designated for cultivation. Starting from WKHQLQHWHHQWKFHQWXU\DSSOLFDWLRQRIVFLHQWL¿FDFKLHYHments became more and more important; these included theoretical basics of soil chemistry and agronomy, initiated production of superphosphate and import of nitrates from &KLOHWRWKH86$DQG(XURSHV\QWKHVLVRIDPPRQLDDQG FRQVWUXFWLRQRIWKH¿UVWDPPRQLDIDFWRU\7KH¿UVWQDWXUDO pesticide was tobacco extract, used from the early eightHHQWKFHQWXU\WRGHVWUR\DSKLGVDQGWKH¿UVWV\QWKHWLFDJHQW ZDVGLQLWURRUWKRFUHVRODWH>@&RQWHPSRUDU\DJULFXOWXUH utilizes large amounts of chemical agents which adversely impact the environment and the condition of soil. Therefore various endeavours are initiated in order to reduce application of chemical substances and restore biodiversity [20]. <HWLQRUGHUWRHQKDQFHVRZLQJPDWHULDOLQWKHWLPHVRI the disturbed natural environment it is necessary to look IRUQHZVDIHPHWKRGVIRUDFKLHYLQJWKLV>@5HFHQW\HDUV have seen a notable increase in the size of farming areas designated for cultivation of crops by means of ecological or integrated methods; there is alsogrowing interest in SURHFRORJLFDOPHWKRGVRILPSURYLQJWKHTXDOLW\DQGKHDOWK of seeds [20]. During the last decade more and more research has focused on effects of pre-sowing electromagnetic radiaWLRQRQVHHG¿HOGSHUIRUPDQFH7KLVW\SHRIVWLPXODWLRQLV cost-effective, and does not adversely impact the plants. +HQFHWKHUHLVDJUHDWQHHGIRUGHYHORSLQJQHZPHWKRGV RIHQKDQFLQJVHHGV>@ 4XDOLW\RIVHHGVXVHGIRUVRZLQJLVDPDMRUIDFWRULPpacting growth and development of plants, and ultimatelythe \LHOG%\DSSO\LQJYDULRXVPHWKRGVRIHQKDQFLQJVRZLQJ material it is possible to considerably improve its germinaWLRQUDWH>@3K\VLFDOIDFWRUVVXFKDVLQIUDUHGXOWUDYLROHW laser, or microwave radiation, ultrasounds or electric, mag- 0,à26==$5'=(:,$à<*5=(*25==$*8à$&=(6à$:38&+$/6., 202 QHWLFDQGHOHFWURPDJQHWLF¿HOGDUHPRUHDQGPRUHIUHTXHQWO\ used to stimulate seeds before sowing. These methods are considered to be safe for the environment; hence they may SURYHXVHIXOIRURUJDQLFIDUPLQJ>@ 3K\VLFDODJHQWVPRVWGH¿QLWHO\ZLOOQRWUHSODFHHIIHFWLYH FKHPLFDOPHWKRGV\HWWKH\PD\EHDEHQH¿FLDOVXSSOHPHQW for the latter. One of the factors which may prove useful for stimulating seed vigour and growth of plants is magnetic ¿HOGEHFDXVHLWVLPSDFWRQVHHGVDQGJURZWKRISODQWVLV QRWLFHDEOHHYHQZLWKORZLQGXFWLRQYDOXHV>@,PSDFW RIPDJQHWLF¿HOGRQSODQWVGHSHQGVRQLWVVL]HDQGQDWXUH Fig. 1a. Multilayer air core inductor. 3ODQWVDUHH[SRVHGWRGLIIHUHQWW\SHVRIPDJQHWLF¿HOG± VWDWLFZLWKFRQVWDQWPDJQHWLFLQGXFWLRQDOWHUQDWLQJ>@ RVFLOODWLQJ>@DQGSXOVHG>@ Numerous studies allow a conclusion that stimulation RIVHHGVZLWKPDJQHWLF¿HOGEHIRUHVRZLQJUHVXOWVLQKLJKer crops without the use of additional mineral fertilizers >@3UHYLRXVUHVHDUFKFRQGXFWHGLQODERUDWRULHVDQGDW PLFUR¿HOGVVKRZKLJKO\SRVLWLYHHIIHFWRIVWLPXODWLRQE\ PHDQVRIPDJQHWLF¿HOGRQJHUPLQDWLRQDQGJURZWKDVZHOO as yield in selected cereals, pulses, root crops, vegetables and ÀRZHULQJSODQWV>@ Ta b l e 1 . 0DJQHWLF¿HOGYDOXHVLQUHVHDUFK> @ Plant Wheat Sugar snap peas Flowering plants Potato Maize 0DJQHWLF¿HOGYDOXH )URPDIHZP7WR7 P7P7P7P7 P7P7 P7P7P7 P7P7 7KHSXUSRVHRIWKHSUHVHQWVWXG\ZDVWRGH¿QHWKHLPSDFWRIVWLPXODWLRQZLWKVORZFKDQJLQJPDJQHWLF¿HOGZLWK LQGXFWLRQYDOXHVRIDQGP7DWIUHTXHQF\RI+] DQGGXUDWLRQRIH[SRVLWLRQVHFRQGVRQWKHHPHUJHQFH and growth of sugar beet seedlings; additionally after the PRVWEHQH¿FLDOPDJQHWLF¿HOGZDVLGHQWL¿HGFKDQJHVLQ physicochemical properties of sugar beet seedlings were also investigated. 0$7(5,$/$1'0(7+2'6 7HQFXOWLYDUVRIVXJDUEHHW%HWDYXOJDULV/ZHUHVHlected for the study. Seeds of each cultivar were divided LQWRJURXSVHDFKFRPSULVLQJVHHGV(DFKFXOWLYDU ZDVH[SRVHGWRDOWHUQDWLQJPDJQHWLF¿HOGRIDQG P7DWIUHTXHQF\RI+]LQRUGHUWRGHWHUPLQHWKH¿HOG ZLWKWKHPRVWEHQH¿FLDOLPSDFWRQWKHVSHHGRIJHUPLQDWLRQ DQGJURZWKRIVHHGV7KHSUHVRZLQJVHFRQGPDJQHWLF stimulation was conducted by means of air core inductor ±VROHQRLGRIFRSSHUZLUHPPFRLOV¿JXUHDE ,QGXFWRUSDUDPHWHUV/HQJWK±P'LDPHWHU±P 1XPEHURIFRLOV±LQZLQGLQJOD\HUV One group, i.e. control seeds, was not subjected to stimulation. The laboratory experiment was carried out in SK\WRWURQZLWKFRQVWDQWFRQGLWLRQVLHWHPSHUDWXUH& Fig. 1b. 6LPXODWHGKRPRJHQHLW\RIWKHVXUURXQGLQJ¿HOGGLVtribution. &KXPLGLW\DQGFRQVWDQWLOOXPLQDWLRQ6HHGVLQ JURXSVRIZHUHSODQWHGLQSRWV¿OOHGZLWKVRLO7KHWRWDO RISRWVZHUHSODFHGLQWKHSK\WRWURQIRUHDFKFXOWLYDU WKHUHZHUHIRXUYDULDQWV±P7P7P7DWIUHTXHQF\ RI+]DQGWKHFRQWUROVDPSOH 7KHH[SHULPHQWZDVFRQWLQXHGIRUGD\V(DFKGD\DW the same time the seeds were watered with distilled water, POSHUHDFKSRW7KHQXPEHURIHPHUJLQJVKRRWVZDV recorded and the lengths of seedlings were compared during WKHFRQVHFXWLYHGD\VRIWKHH[SHULPHQW$WWKHHQGRIWKHH[periment the results were entered into a summary table and, based on that, graphs were complied to show the effects of PDJQHWLF¿HOGRQJHUPLQDWLRQUDWHLQWKHVSHFL¿FFXOWLYDUV ¿QDOO\WKHPRVWEHQH¿FLDOPDJQHWLF¿HOGZDVLGHQWL¿HGIRU IXUWKHUSK\VLFRFKHPLFDOWHVWV$QDO\WLFDOPHDVXUHPHQWVRI the control sample and the sprouts from seeds stimulated ZLWKWKHRSWLPXPPDJQHWLF¿HOGZHUHSHUIRUPHGXVLQJWKH IROORZLQJHTXLSPHQW ± 7*$/HFRWKHUPRJUDYLPHWULFDQDO\]HUWRGHWHUmine the contents of water, ash, and volatile substances; ± 7UXH6SHF&+1/HFRHOHPHQWDOGHWHUPLQDWRUWRLGHQtify the contents of basic building elements; ± ,&32(6L&$3'XDO7KHUPRWRGHWHUPLQHFRQcentrations of selected micro and macro elements, with the use of microwave mineralization. $QDO\WLFDO PHDVXUHPHQWV RI WKH FRQWURO VDPSOH DQG WKH IROORZLQJHTXLSPHQW x ())(&762)35(62:,1*0$*1(7,&67,08/$7,21 x 7UXH 6SHF &+1 x ,&32(6L&$3'XDO 5(68/76 )LJXUH SUHVHQWV FRQFHQWUDWLRQV RI VHOHFWHG KHDY\ metals in shoots of prestimulated plants in comparison to Findings of the experiment allow a conclusion that seedlings which had not been exposed to magnetic stimulaSUHVRZLQJVWLPXODWLRQRIVHHGVZLWKDPDJQHWLF¿HOGVLJ- tion. The graph shows decreased tendency for accumulating QL¿FDQWO\LPSDFWHGWKHDELOLW\RIVXJDUEHHWVWRJHUPLQDWH harmful metals following magnetic prestimulation of the ERWKGXULQJWKHLQLWLDOVHYHQGD\V)LJXUHPHDQUHVXOWV sowing material, in particular for such elements as zinc, IRUWKHFXOWLYDUVDQGWKURXJKRXWWKHHQWLUHH[SHULPHQW nickel and lead. On average thedifference in the overall G days. The speed of germination in the seeds stimulated with DPRXQWRIDFFXPXODWHGKDUPIXOHOHPHQWVUHDFKHVSHU PDJQHWLF¿HOGZDVVLJQL¿FDQWO\KLJKHU a cultivar and the standard deviation between results for VSHFL¿FFXOWLYDUVGRHVQRWH[FHHG 40 EƵŵďĞƌŽĨƐĞĞĚůŝŶŐƐĞĂĐŚ 35 120% seeds witout stimulation 30 seeds with 40mT prestimulation 100% 25 0 mT 20 80% 10 mT 15 20 mT 10 60% 40 mT 5 40% 0 1 2 3 4 6 7 ƚĚĂLJƐ Fig. 2. (IIHFWVRISUHVRZLQJVWLPXODWLRQZLWKPDJQHWLF¿HOGRQ PHDQYDOXHVIRUFXOWLYDUV the speed of germination in the seeds of sugar beets during the LQLWLDOVHYHQGD\VRIWKHH[SHULPHQW±PHDQYDOXHVIRUFXOWLYDUV Figure 2.(IIHFWVRISUH-sowing stimulation with magnetic field on the speed of germination in the seeds of 20% 0% Al Cd Cr Ni Pb Zn Fig. +HDY\PHWDOVFRQFHQWUDWLRQLQVHHGOLQJVVXEMHFWHGDQGQRWVXEMHFWHGWRPDJQHWLFVWLPXODWLRQ 3. +HDY\PHWDOVFRQFHQWUDWLRQLQVHHGOLQJVVXEMHFWHGDQG P7 QRWVXEMHFWHGWRPDJQHWLFVWLPXODWLRQ±PHDQUHVXOWVIRUWKH 7KHUHVXOWVRIWKHVWXG\VXJJHVWWKDWP7PDJQHWLF cultivars. P7 P7 ŵĂĐƌŽĞůĞŵĞŶƚƐĐŽŶĐĞŶƚƌĂƚŝŽŶŵŐͬŐ ŵĂĐƌŽĞůĞŵĞŶƚƐĐŽŶĐĞŶƚƌĂƚŝŽŶŵŐͬŐ ¿HOGKDGWKHPRVWEHQH¿FLDOLPSDFWRQWKHVSURXWLQJYLJRXU +HDY\PHWDOVFRQFHQWUDWLRQLQVHHGOLQJVVXEMHFWHGDQGQRWVXEMHFWHGWRPDJQHWLFVWLPXODWLRQ DFFXPXODWHJUHDWHUTXDQWLWLHVRI LQVXJDUEHHWVRIDOOWKHPDJQHWLF¿HOGYDOXHVDSSOLHGLQ )LJXUHVKRZVWKHWHQGHQF\RISODQWVHPHUJLQJIURP DQG GRHV QRW GHSHQG RQ WKH FXOWLYDU ZKLFK FDQ EH VHHQ LQ WKH VPDOO PD[LPXP WKHH[SHULPHQWLHP7DQGP7DQGP7)LJXUH VHHGVVWLPXODWHGPDJQHWLFDOO\WRDFFXPXODWHJUHDWHUTXDQ Therefore, sprouts which emerged from seeds stimulated tities of macroelements. The tendency is visible for each DFFXPXODWHJUHDWHUTXDQWLWLHVRI ZLWKP7PDJQHWLF¿HOGZHUHVHOHFWHGIRUIXUWKHUDQDO\WLFDO element and does not depend on the cultivar, which can DQG GRHV QRW GHSHQG RQ WKH FXOWLYDU ZKLFK FDQ EH VHHQ LQ WKH VPDOO PD[LPXP tests. Presented below, the results provide comparative data EHVHHQLQWKHVPDOOPD[LPXPVWDQGDUGGHYLDWLRQLQ for the contents of microelements, macroelements, heavy measurements for various cultivars. metals, water and ash in the control sample and the sample 9,00 H[SRVHGWRWKHRSWLPXPPDJQHWLF¿HOGEHIRUHVRZLQJ seeds witout stimulation seeds with 40mT prestimulation 8,00 'XULQJWKHGD\SURFHVVWKHPRVWQRWDEOHZDVWKH 7,00 fourth day of the experiment, when the most pronounced 6,00 difference was observed between the number of seedlings 5,00 in the control sample and the sprouts emerging from mag4,00 QHWLFDOO\VWLPXODWHGVHHGV7DEOH7KHGLIIHUHQFHRIXS 3,00 WRZDVLQIDYRXURIWKHPDJQHWLFDOO\LQGXFHGVHHGV 2,00 The results for all the cultivars, presented in the following VXPPDU\WDEOHFRQ¿UPWKHDERYHVWDWHPHQW 1,00 0,00 Ta b l e 2 . Number of shoots on the fourth day of the experiment LQVDPSOHVVWLPXODWHGZLWKPDJQHWLF¿HOGDQGLQWKHFRQWUROVDPSOH Number of shoots [each] Control sample Sugar beet 40 mT SD – 0 mT cultivar no. PDJQHWLF¿HOG 13 - Milton 0.7 9 8 - Primadonna 23 - Schubert 22 25 - Alegra 14 - Agent 0.9 2 - Janosik 28 'DQXĞND 27 4 - Agnieszka 29 26 - Silvetta 27 - Tadeusz 2.8 SD 2.9 0.8 2.8 2.9 Ca K Mg Na P S Fig. 4. Concentrations of selected macroelements-mean results for the investigated cultivars. The tendency for shoots of plants prestimulated with alWHUQDWLQJPDJQHWLF¿HOGWRDFFXPXODWHVPDOOHUTXDQWLWLHVRI PLQHUDOFRPSRQHQWVLVFRQ¿UPHGE\UHVXOWVRIWKHUPRJUDYLPHWULFDQDO\VLV)LJXUHSUHVHQWVWKHFRQVLVWHQWWHQGHQF\LQ the measurements of total ash in incinerated plant material. 5HVXOWVRIWKHVHDQDO\VHVDUHVWDWLVWLFDOO\VLJQL¿FDQWIRUHDFK RIWKHFXOWLYDUVXQGHUGLVFXVVLRQ 7KHVH¿QGLQJVDUHIXUWKHUFRQ¿UPHGE\PHDVXUHPHQWV RIZDWHUFRQWHQWLQWKHHPHUJLQJVHHGOLQJV$VGHPRQVWUDWHGE\)LJXUHWKHUHVXOWVVKRZHGWKHVHHGOLQJVVXEMHFWHG to stimulation before sowing tended to accumulate greater TXDQWLW\RIIUHHZDWHU,QWKLVVWLPXODWLRQJURXSLQHDFKFDVH seeds witout stimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation 13 13 8 8 23 23 25 25 14 14 2 2 5 sĂƌŝĞƚŝĞƐŶƵŵďĞƌ 5 4 4 26 26 27 27 seeds with 40mT prestimulation seeds witout stimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation 8 8 23 23 25 25 14 14 2 2 5 sĂƌŝĞƚŝĞƐŶƵŵďĞƌ 5 4 4 26 26 27 27 seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation 5 seeds witout stimulation 4 4 26 26 27 27 seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation 23 23 25 25 14 14 2 2 5 sĂƌŝĞƚŝĞƐŶƵŵďĞƌ seeds with 40mT prestimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation $V GHPRQVWUDWHG E\ )LJ seeds witout stimulation 88 seeds with 40mT prestimulation 90 seeds with 40mT prestimulation 86 seeds witout stimulation seeds witout stimulation 8 seeds witout stimulation seeds witout stimulation seeds witout stimulation seeds with 40mT prestimulation 8 seeds with 40mT prestimulation seeds witout stimulation 13 13 seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation 13 13 seeds with 40mT prestimulation seeds with 40mT prestimulation VLJQLILFDQWGHFUHDVHLQWKLVSDUDPHWHUIRUVSURXWVHPHUJLQJIURPVHHGVWUHDWHGZLWKP7 seeds witout stimulation 92 seeds with 40mT prestimulation seeds witout stimulation >ĞǀĞůŽĨǁĂƚĞƌ͕й >ĞǀĞůŽĨĂƐŚ͕й seeds with 40mT prestimulation seeds witout stimulation >ĞǀĞůŽĨǀŽůĂƚŝůĞ͕й DFFXPXODWH VPDOOHU TXDQWLWLHV RI PLQHUDO FRPSRQHQWV SU 0,à26==$5'=(:,$à<*5=(*25==$*8à$&=(6à$:38&+$/6., VLJQLILFDQWIRUHDFKRIWKHFXOWLYDUVXQGHUGLVFXVVLRQ 2,5 3 1,5 2 0,5 1 0 Fig. 5. Results of analyses investigatingash content in the examined beet root seedlings. 98 96 94 WR DFFXPXODWH JUHDWHU TXDQWLW 84 ZDWHUFRQWHQWZDVKLJKHURQDYHUDJHE\LQFRPSDULVRQ Fig. 6. 5HVXOWVRIDQDO\VHVLQYHVWLJDWLQJZDWHUFRQWHQWLQWKHH[DPLQHGVXJDUEHHWVHHGOLQJVDIWHUGU\LQJWHVWDWWHPSHUDWXUHRI& 4 3,5 3 2,5 $QRWKHU LQYHVWLJDWHG SDUDPHWHU ZDV WKH FRQWHQW 2 1,5 1 PLQXW 0,5 $V LOOXVWUDWHG E\ )LJ 0 Fig. 7. 5HVXOWVRIDQDO\VHVLQYHVWLJDWLQJYRODWLOHVFRQWHQWLQWKHH[DPLQHGVXJDUEHHWVHHGOLQJVRIWKHVHOHFWHGFXOWLYDUV 5HVXOWV RI DQDO\VHV LQYHVWLJDWLQJ YRODWLOHV FRQWHQW LQ WKH H[DPLQHG VXJDU EHHW VHHGOLQJV RI WKH Fig. 10. Results of analyses investigating hydrogen content in the dry mass of seedlings. seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation 13 13 8 8 23 23 25 25 14 14 2 2 5 ǀĂƌŝĞƚŝĞƐŶƵŵďĞƌ 5 4 4 26 26 27 27 seeds with 40mT prestimulation seeds witout stimulation seeds witout stimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation 13 13 8 8 23 23 25 25 14 14 2 2 5 ǀĂƌŝĞƚŝĞƐŶƵŵďĞƌ 5 4 4 26 26 27 27 seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation 5 4 4 26 26 27 27 seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation ǀĂƌŝĞƚŝĞƐŶƵŵďĞƌ 23 23 25 25 14 14 2 2 5 ǀĂƌŝĞƚŝĞƐŶƵŵďĞƌ seeds with 40mT prestimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds with 40mT prestimulation seeds witout stimulation 8 seeds with 40mT prestimulation seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation >ĞǀĞůŽĨŶŝƚƌŝƚŝŽŶ͕йĚƌLJŵĂƐƐ >ĞǀĞůŽĨŶŝƚƌŝƚŝŽŶ͕йĚƌLJŵĂƐƐ 8 seeds witout stimulation seeds with 40mT prestimulation seeds witout stimulation >ĞǀĞůŽĨĐĂƌďŽŶ͕йĚƌLJŵĂƐƐ >ĞǀĞůŽĨĐĂƌďŽŶ͕йĚƌLJŵĂƐƐ 13 13 seeds with 40mT prestimulation seeds with 40mT prestimulation seeds witout stimulation >ĞǀĞůŽĨŚLJĚƌŽŐĞŶ͕йĚƌLJŵĂƐƐ ())(&762)35(62:,1*0$*1(7,&67,08/$7,21 7 6 5 4 3 2 1 0 Fig. 8. Results of analyses investigating nitrogen content in the dry mass of seedlings. 45 44 43 42 41 40 39 38 37 36 35 34 Fig. 9. Results of analyses investigating carbon content in the dry mass of seedlings. 8 7 6 5 4 3 2 1 0 ǀĂƌŝĞƚŝĞƐŶƵŵďĞƌ 0,à26==$5'=(:,$à<*5=(*25==$*8à$&=(6à$:38&+$/6., ZDWHUFRQWHQWZDVKLJKHURQDYHUDJHE\LQFRPSDULson with the sample which had not been stimulated with PDJQHWLF¿HOG $QRWKHULQYHVWLJDWHGSDUDPHWHUZDVWKHFRQWHQWVRIYROatiles which were determined in thermogravimetric analyzer E\LQFLQHUDWLQJUDZSODQWVDPSOHDWWKHWHPSHUDWXUHRI& IRUWKHGXUDWLRQRIPLQXWHVLQFRYHUHGFRQWDLQHUV,QWKLV FDVHWKHUHVXOWVZHUHDOVRXQDPELJXRXV$VLOOXVWUDWHGE\ )LJXUHHDFKFXOWLYDUZDVIRXQGZLWKVWDWLVWLFDOO\VLJQL¿cant decrease in this parameter for sprouts emerging from VHHGVWUHDWHGZLWKP7VWLPXODWLRQEHIRUHVRZLQJ Finally, the investigated parameters included the basic building elements impacting the stability of the plants’ tissues and cells, i.e. carbon, hydrogen and nitrogen, which were examined by means of element determinator employing near infrared band to examine dry analytical sample H[SRVHGWRFDUULHUJDVHV7KH¿QGLQJVUHODWHGWRQLWURJHQ content in dried samples of beet seedlings for each cultivar show the content of this element increases as a result RIPDJQHWLFSUHVWLPXODWLRQ)LJXUH7KLVWHQGHQF\LV SDUWLFXODUO\SURQRXQFHGLQFXOWLYDUVDQGZKHUHWKH UHOHYDQWLQFUHDVHUHDFKHVWKHYDOXHRIQRPLQDOO\LQFUHDVHIURPWR Carbon content in dry mass tends to decrease in cultivars DQG,QWKHUHPDLQLQJFXOWLYDUVQRVWDWLVWLFDOO\ VLJQL¿FDQWGLIIHUHQFHZDVIRXQGEHWZHHQVDPSOHVVWLPXODWHG before sowing and those planted without stimulation (FigXUH&KDQJHVLQK\GURJHQFRQWHQWLQWKHVHHGOLQJGU\PDVV DVVRFLDWHGZLWKWKHTXDQWLW\RIZDWHUERXQGHGLQFKHPLFDO compounds of fruit tissue, tended to increase as a result of the applied prestimulation procedure in half of the cultivars RIVXJDUEHHWVLQTXHVWLRQ,QWKHUHPDLQLQJFXOWLYDUVQRVLJQL¿FDQWFKDQJHVZHUHIRXQGIRUWKLVSDUDPHWHU)LJXUH DISCUSSION Many available publications describe studies investing WKHHIIHFWVRIPDJQHWLF¿HOGRQSODQWV5HOHYDQWUHSRUWHG ¿QGLQJVVKRZWKDWLQPRVWFDVHVVKRUWWHUPDSSOLFDWLRQRI the physical factor involving pre-sowing magnetic stimulation of seeds impacts the parameters of seedlings in the investigated plants. :yMFLN>@VKRZHGWKDWVWLPXODWLRQZLWKP7PDJQHWLF¿HOGIRUWKHGXUDWLRQRIVHFRQGVEHQH¿FLDOO\LPSDFWHG capacity for germination, sugar content and overall yield in VXJDUEHHWV$VDUHVXOWRIPDJQHWLFVWLPXODWLRQWKHUHZDV a slight decrease in the content of melassigenic substances. $FFRUGLQJWR5RFKDOVND>@VWLPXODWLRQRIVXJDUEHHWVHHGV ZLWKPDJQHWLF¿HOGRIP7+]SRVLWLYHO\DIIHFWHGWKH vigour of these seeds, chlorophyll content during vegetation DQG¿QDOO\UHVXOWHGLQLQFUHDVHG\LHOGDQGVXJDUFRQWHQW in the roots. .RUQDU]\ĔVNL >@ UHSRUWHG EHQH¿FLDO HIIHFWV RI WKH PDJQHWLF¿HOGRIDQGP7RQJHUPLQDWLRQLQÀRZHULQJSODQWV3RVLWLYHLPSDFWRIPDJQHWLF¿HOGLVSDUWLFXODUO\ visible if seeds germinate in stressful conditions, such as low temperature and shortage of water. Pre-sowing stimulation of seeds improves sprouting capacity in sugarsnap peas, particularly if there is shortage of moisture in the soil. Such treatment seems to be more effective in these conditions than LQDVLWXDWLRQRIRSWLPDOPRLVWXUH>@ $VWXG\FDUULHGRXWE\%LODOLVHWDO>@VKRZHGWKDW PDJQHWLF¿HOGFRXOGUHSODFHKRUPRQHVLQYHJHWDWLYHSURSagation. The obtained results provided evidence for the fact WKDWPDJQHWLF¿HOGVWLPXODWHGWKHURRWLQJSURFHVVLQRUHJDno plants. On the other hand a combined use of magnetic ¿HOGDQGKRUPRQHVOHGWRVLJQL¿FDQWO\ORZHUSHUFHQWDJH RIFRUUHFWO\URRWHGSODQWVWKDQZKHQPDJQHWLF¿HOGDORQH was applied. Magnetic stimulation methods ensuring better oregano seedlings may potentially be useful for producers of planting material, particularly in organic farming where chemical agents are not allowed. $KPHW(VLWNHQDQG0HWLQ7XUDQ>@FRQGXFWHGDVWXG\ LQYHVWLJDWLQJWKHHIIHFWRIPDJQHWLF¿HOGRQWKH\LHOGDQG kation accumulation in strawberry leaves. The experiment was carried out in a greenhouse. The plants were exposed WRPDJQHWLF¿HOGRI77DQG7$OOLQGXFWLRQVRIWKHPDJQHWLF¿HOGLQFUHDVHGWKHPHDQZHLJKWRIIUXLW in comparison with the control sample. The best fruit yield ZDVDFKLHYHGE\DSSO\LQJ7¿HOG0DJQHWLF¿HOGZLWK LQGXFWLRQLQFUHDVHGWR7UHVXOWHGLQKLJKHUFRQWHQWV RI1.&D0J&X)H0Q=Q1DDQGORZHUFRQWHQWRI P and Sin strawberry leaves. Masafumi Muraji et al. [27] investigated the impact of DOWHUQDWLQJPDJQHWLF¿HOGRQWKHJURZWKUDWHRISULPDU\ roots in maize. Maize seedlings were growing in darkness, DWDFRQVWDQWWHPSHUDWXUH&DQGKXPLGLW\ 7KH\ZHUHH[SRVHGWRP7DOWHUQDWLQJPDJQHWLF¿HOGDW IUHTXHQFLHVRIRU+]7KHUDWHVRIURRWJURZWK LQWKHSODQWVVXEMHFWHGWRHDFKIUHTXHQF\RIWKHPDJQHWLF ¿HOGZHUHPHDVXUHGDQGFRPSDUHGZLWKWKHFRQWUROVDPSOH Root growth rate in seedlings developing in the presence of PDJQHWLF¿HOGRIYDULHGIUHTXHQFLHVLQFUHDVHGLQUHODWLRQWR the control group. The highest pace of growth was observed LQVHHGOLQJVH[SRVHGWRDOWHUQDWLQJPDJQHWLF¿HOGRI+] IUHTXHQF\ 0RUHRYHU$ONDVVDE$7DQG$OEDFK'&>@UHVHDUFKHG WKHUHVSRQVHRI0H[LFDQDVWHU&RVPRVELSLQQDWXV$VWHUDFHDHDQG¿HOGPXVWDUG6LQDSLVDUYHQVLV%UDVVLFDFHDHWR PDJQHWLFDOO\WUHDWHGZDWHU07:IURPJHUPLQDWLRQWR ÀRZHULQJ8VHGIRUWUHDWLQJZDWHUDPDJQHWLFWUHDWPHQW GHYLFHLQWKHUDQJHRI±P7 MTW affected growth and several biochemical parameters of treated plants depending on the number of passes of water. Irrigation water MTW resulted in increasing plant height, the amount of leaves and branches per plant and chlorophyll content compared to the control not irrigated water MTW. The present study explicitly demonstrated the effects of pre-sowing stimulation applied to the planting material of VHOHFWHGFXOWLYDUVRIVXJDUEHHWRQSK\VLFRFKHPLFDOSURSHUWLHVRIWKHHPHUJLQJVHHGOLQJV0RVWVLJQL¿FDQWO\P7 PDJQHWLF¿HOGRI+]IUHTXHQF\LPSDFWHGWKHWHQGHQF\ of the examined seedlings to accumulate basic macro and micro elements; the results were also manifested in lower content of total ash. Importantly, the reduced accumulation RIKDUPIXOHOHPHQWVVXFKDV$O&G&U1L3E=QPD\EHRI ())(&762)35(62:,1*0$*1(7,&67,08/$7,21 207 particular importance in a situation when seeds are planted in %LODOLV'.DWVHQLRV1(IWKLPLDGRX$(IWKLPLsoil contaminated by industry, fertilizers or crop protection adis P. & Karkanis A. 2012.: Pulsed electromagnetic ¿HOGVHIIHFWLQRUHJDQRURRWLQJDQGYHJHWDWLYHSURSDJDagents. The previously known methods of preventing heavy metals accumulation, such as liming or soil ionization are WLRQ$SRWHQWLDOQHZRUJDQLFPHWKRG$FWD$JULFXOWXUDH very expensive and may lead to changes in the structure, 6FDQGLQDYLFD6HFWLRQ%±6RLO3ODQW6FLHQFHYRO S+DQGRWKHUVWDUYDWLRQUHODWHGVRLOFRQGLWLRQV> @2QWKHRWKHUKDQGSUHVWLPXODWLRQZLWKRXW 7. Bovelli R. & Bennici A. 2000.: Stimulation of germinainterfering with the soil structure and properties, prevents tion callus growth and shoot regeneration of Nicotiana accumulation of heavy metals which are a major hazard for WDEDFXP/E\3XOVLQJ(OHFWURPDJQHWLF)LHOGV3(0) SHRSOHDQGDQLPDOV$GGLWLRQDOO\DVGHPRQVWUDWHGE\WKHVH +RUWLFXOWXUDO6FLHQFH authors, the faster pace of seed germination following mag- 8. Bujak K. & Frant M.2009.: :Sá\ZSU]HGVLHZQHMVW\netic stimulation suggests another agritechnical advantage. mulacji nasion zmiennym polem magnetycznym na ploThe possibility to achieve faster germination rate allows for QRZDQLHSV]HQLF\MDUHM>(IIHFWRISUHVRZLQJVWLPXODWLRQ higher crops from such seeds. RIVHHGVZLWKDOWHUQDWLQJPDJQHWLF¿HOGRQWKH\LHOGVRI VSULQJZKHDW@$FWD$JURSK\VLFD3ROLVK 9. Bujak K. & Frant M. 2010.: :Sá\ZSU]HGVLHZQHM CONCLUSIONS stymulacji nasion zmiennym polem magnetycznym na SORQRZDQLH L MDNRĞü WHFKQRORJLF]Qą ]LDUQD SV]HQLF\ 3UHVRZLQJVWLPXODWLRQRIVXJDUEHHWVHHGVZDVPRVW R]LPHM>(IIHFWRISUHVRZLQJVWLPXODWLRQRIVHHGVZLWK HIIHFWLYHZLWKWKHDSSOLHGPDJQHWLF¿HOGLQGXFWLRQRI DOWHUQDWLQJPDJQHWLF¿HOGRQ\LHOGDQGWHFKQRORJLFDOP7DQGIUHTXHQF\RI+] TXDOLW\RIJUDLQVLQZLQWHUZKHDW@$FWD$JURSK\VLFD %\XVLQJP7LQGXFWLRQLWZDVSRVVLEOHWRLPSURYH 3ROLVK Byszewski W. 1979.%LRORJLDEXUDNDFXNURZHJR>%LR sugar beet germination rate. logy of sugarbeet]. PWN. 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J. & Grzesiuk S. 1994.:ĝZLDWRZHWHQGHQFMH carbonate on migration of heavy metals to trophic chain]. LNLHUXQNLXV]ODFKHWQLDQLDPDWHULDáyZVLHZQ\FK>*OREDO =HV]\W\3UREOHPRZH3RVWĊSyZ1DXN5ROQLF]\FK trends for enhancing planting materials]. Proceedings ±3ROLVK of the conference “Planting material enhancements”. 2OV]W\Q±.RUWRZRS3ROLVK Belyavskaya N.A. 2004.:%LRORJLFDOHIIHFWVGXHWRZHDN PDJQHWLF¿HOGRQSODQWV$GYDQFHVLQ6SDFH5HVHDUFK Hernandez A. C., Dominguez-Pacheco A, Carballo &$&UX]2UHD$,YDQRY5/ySH]%RQLOOD-/ 208 0,à26==$5'=(:,$à<*5=(*25==$*8à$&=(6à$:38&+$/6., Valcarcel Montañez J. P. 2009.: $OWHUQDWLQJ0DJQHWLF )LHOG,UUDGLDWLRQ(IIHFWVRQ7KUHH*HQRW\SH0DL]H6HHG )LHOG3HUIRUPDQFH$FWD$JURSK\VLFDYRO +HUQDQGH]$&'RPLQJXH]3$&UX]2$,YDQRY5&DUEDOOR&$=HSHGD%5 Laser in DJULFXOWXUH,QWHUQDWLRQDO$JURSK\VLFV 20. 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Selected heavy metals content LQSODQWPDWHULDO@$UFKLZXP2FKURQ\ĝURGRZLVND± 3ROLVK Marks N. & Szecówka P.S. 2010.: Impact of variable PDJQHWLF¿HOGVWLPXODWLRQRQJURZWKRIDERYHJURXQG SDUWVRISRWDWRSODQWV,QWHUQDWLRQDO$JURSK\VLFV Moon J. & Chung H. 2000.: $FFHOHUDWLRQRIJHUPLQDWLRQRISRWDWRVHHGE\DSSO\LQJ$&HOHFWULFDQGPDJQHWLF ¿HOGV-RXUQDORI(OHFWURVWDWLFV 27. Muraji M., Asai T.& Tatebe W. 1998.: Primary root growth rate of zea mays seedlings grown in an alternatLQJPDJQHWLF¿HOGRIGLIIHUHQWIUHTXHQFLHV%LRHOHFWURFKHPLVWU\DQG%LRHQHUJHWLFV 28. 1LHP\VNDàXNDV]XN-:Sá\ZVNáDGXJUDQXORPHWU\F]QHJRLRGF]\QXJOHE\QD]DZDUWRĞüSU]\VZDMDOQ\FKIRUPPHWDOLFLĊĪNLFK>(IIHFWRIJUDQXORPHWULF FRPSRVLWLRQDQGVRLOS+RQWKHFRQWHQWRIDVVLPLODEOH KHDY\PHWDOV@=HV]\W\3UREOHPRZH3RVWĊSyZ1DXN 5ROQLF]\FK±3ROLVK 29. 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COMMISSION OF MOTORIZATION AND ENERGETICS IN AGRICULTURE – 2014, Vol. 14, No. 4, 211–216 Analysis of Oil Leaks in a Variable-Height Gap Between the Cylinder Block and the Valve Plate in a Piston Pump by Means of Author-Designed Software and CFD Fluent Tadeusz Zloto, Damian Sochacki, Piotr Stryjewski Institute of Mechanical Technologies, Czestochowa University of Technology Al. Armii Krajowej 21, 42-201 Czestochowa, e-mail: [email protected] Received December 04.2014; accepted December 19.2014 Summary. The paper presents computational models for obtaining oil leaks intensity in a variable height gap between the cylinder block and the valve plate in an axial piton pump. The computations are based on numerical methods and commercially DYDLODEOHVRIWZDUH&)')OXHQW%\PHDQVRIWKHPRGHOVGHYHORSHGDQDO\VLVRIOHDNÀRZLQWHQVLW\LVSHUIRUPHGIRUYDULDEOH parameters and dimensions of the pump. Key words: oil leaks, gap between the cylinder block and valve plate, piston pump. In piston pumps energy losses occur at the mating surfaces: piston-cylinder, slipper-swash plate and cylinder block-valve plate. The latter forms the valve system, an important part of every hydraulic pump, which deserves special attention in examining the characteristics of hydraulic machines. INTRODUCTION Piston pumps are applied in the drives of complex PDFKLQHVZLWKKLJKGHPDQGVFRQFHUQLQJHI¿FLHQF\DQG reliability. This provides an incentive for continuous development towards improving exploitation parameters of WKRVHPDFKLQHVE\PRGHUQL]LQJWKHLUFRQVWUXFWLRQ>@ The range of applications of piston pumps is wide and still H[SDQGLQJ([DPSOHVRIGHYLFHVHPSOR\LQJSLVWRQSXPSV DUHSUHVHQWHGLQ)LJ>@ The most important applications of hydraulic piston machines include: í DYLDWLRQLQGXVWU\DLUSODQHV í DXWRPRWLYHLQGXVWU\SUHVVHVPDFKLQLQJFHQWUHVLQMHFWLRQPROGLQJPDFKLQHV í KHDY\LQGXVWU\SUHVVXUHIRXQGULHVUROOLQJPLOOVFRNHULHV í FRQVWUXFWLRQLQGXVWU\H[FDYDWRUVORDGHUVH[WHQVLRQ DUPV í IRUHVWLQJDQGDJULFXOWXUHPDFKLQHVFUDQHVHOHYDWRUV GULOOLQJULJVKDUYHVWHUV í PLOLWDU\YHKLFOHVPXOWLIXQFWLRQYHKLFOHVYHKLFOHVXVHG IRUFRQVWUXFWLQJEULGJHV The biggest manufacturers include such companies as 3DUNHUDQG%RVFK5H[URWK Fig. 1. $SSOLFDWLRQVRISLVWRQSXPSV In real conditions, the gap between the cylinder block and the valve plate is of variable height due to differences LQWRUTXHVFRPLQJIURPK\GURVWDWLFSUHVVLQJDQGUHOLHYLQJ IRUFHVZKLFKDIIHFWWKHSRVLWLRQRIWKHF\OLQGHUEORFN> @ When a pump is operating, oil leaks to the outside and LQVLGHRIWKHYDOYHSODWHDIIHFWLQJWKHYROXPHWULFHI¿FLHQF\ of the pump and its other parameters. The paper employs numerical methods and a computational model developed within the software package CFD Fluent for determining oil leaks intensity in the valve system of an axial piston pump. 7$'(86==/272'$0,$162&+$&.,3,275675<-(:6., &20387$7,2102'(/2)2,/)/2: ,17(16,7<,17+(*$3%(7:((1 7+(&</,1'(5%/2&.$1'9$/9(3/$7( 7RGHWHUPLQHRLOÀRZLQWHQVLW\LQWKHJDSEHWZHHQWKH cylinder block and valve plate, a numerical model was deYHORSHG>@7KHIROORZLQJDVVXPSWLRQVZHUHDGRSWHGLQ WKHPRGHO>@ ± WKHÀRZLVODPLQDU ± VXUIDFHVDUHLQ¿QLWHO\ULJLG ± WKHOLTXLGFRPSOHWHO\¿OOVWKHJDS ± WDQJHQWVWUHVVLV1HZWRQLDQ ± WKHOLTXLGLVLQFRPSUHVVLEOH ± LQHUWLDIRUFHVRIWKHOLTXLGDUHQHJOLJLEOH %HVLGHVFDYLWDWLRQDQGKHDWWUDQVIHUSKHQRPHQDZHUH disregarded. In the model developed, the valve plate was divided LQWRIRXU]RQHVRIRLOOHDNÀRZQDPHO\WKHGLVFKDUJHSRUW the inlet port, the upper transition zone and the lower transition zone. In all the four zones oil leaks occur to the inside and outside of the valve plate. In the transition zones, there are also leaks between the discharge and inlet zones. In the transition zones, the oil leak intensity was obtained from the elementary product of the variable-height gap and WKHPHDQÀRZYHORFLW\DVLQWKHIRUPXODEHORZ X M M M H į M DQJOHRIDJLYHQÀRZFURVVVHFWLRQ ݱLQFOLQDWLRQDQJOHRIWKHF\OLQGHUEORFN į±DQJOHEHWZHHQWKHD[LVx and the smallest gap height h, R±UDGLXVRIWKHF\OLQGHUEORFN The computation model of the oil leak intensity was implemented in the programming language C++ with the use of the VCL library. The software so developed PDNHVLWSRVVLEOHWRDQDO\VHWKHOHDNÀRZLQWHQVLW\LQD variable-height front gap in the valve system of different construction variants of a piston pump. The software also enables the user to set the accuracy of computations by prescribing the number n of interpolation intervals. Thanks to using the VCL library, it is possible to represent the results visually in the form of graphs and to save them DVWH[W¿OHV 7KHWRWDOOHDNÀRZLQWHQVLW\LQWKHYDOYHV\VWHPLVREWDLQHGE\DGGLQJWKHOHDNVIURPWKHSDUWLFXODUÀRZ]RQHV &20387$7,2102'(/2)2,//($.)/2: ,17(16,7<(03/2<,1*&)')/8(17 $QDOWHUQDWLYHPHWKRGRIH[DPLQLQJRLOOHDNÀRZLQtensity in the gap between the cylinder block and valve plate was developed on the basis of commercially available software CFD Fluent. The stages of building the model n Q P ¦ X r sr i gap in the CFD Fluent package are of the variable-height ni 0 presented in Fig. 2. The geometrical model of the variable-height gap was where: section area of the gap, P±WRWDOFURVVVHFWLRQDUHDRIWKHJDS FRQVWUXFWHG LQ WKH $XWR&DG SURJUDPPH IRU WZR FRQn±QXPEHURILQWHUSRODWLRQLQWHUYDOV struction types of the valve plate: with positive overlap ȣrsri ±PHDQÀRZYHORFLW\ DQGZLWKUHOLHIJURRYHV)LJ,QERWKFDVHVWKHVDPH dimensions of the radius were applied r Pr2 P r P DQG r P UHVSHF7KHÀRZFURVVVHFWLRQZDVREWDLQHGRQWKHEDVLVRIWKH QXPHULFDOLQWHJUDWLRQE\WUDSH]RLGDOUXOHDFFRUGLQJWR>@ WLYHO\ DQG WKH VDPH OHQJWK RI WKH WUDQVLWLRQ ]RQHV Įm, HTXDOWR>@ º ª h r , M0 h r , Mn n $QXPHULFDOJULGJHQHUDWHGDXWRPDWLFDOO\LQWKHSUR ¦ h r ,M i » P ln « 2 i ¼ ¬ JUDPPH*DPELWZDVWKHQLPSOHPHQWHGRQWKHJHRPHWULFDO model of the variable-height gap. The grid consists of volwhere: h(r, ±KHLJKWRIWKHYDULDEOHKHLJKWJDSDWWKHUDGLXVDQG XPHWULFFHOOVRIWKH+H[:HGJHW\SHVXLWDEOHIRUWKHJDS angle under consideration; VKDSH%HVLGHVWKHUHJLRQVRIERXQGDU\FRQGLWLRQVZHUH 0±DQJOHDWWKHHQWU\RIWKH]RQHXQGHUFRQVLGHUDWLRQ VSHFL¿HGLQWKHSURJUDPPH*DPELW)LJ n±DQJOHDWWKHH[LWRIWKH]RQHXQGHUFRQVLGHUDWLRQ The last stage of constructing the numerical model n±QXPEHURILQWHUYDOVLQWKHQXPHULFDOLQWHJUDWLRQE\WUDS- of the variable-height gap in the valve system is to enter ezoidal rule, the numerical grid with the boundary condition regions ln±OHQJWKRIWKHLQWHUYDOLQWKHQXPHULFDOLQWHJUDWLRQ to the programme Fluent, in which the values of oil h r sin M cos G tgH r cos M sin G tgH RtgH h pressure in the boundary regions are determined and simulations of oil pressure distribution are performed. The gap height in a given interval was obtained from On the basis of the so obtained pressure area on the h r sin M cos G tgH r cos M sin G tgH RtgH h inside and outside of the valve plate, the oil leak flow intensity is determined. where r±FXUUHQWUDGLXVRIDJLYHQFURVVVHFWLRQ Fig. 2. Stages of building the model of the variable-height gap in the CFD Fluent package $1$/<6,62)2,//($.6,1$9$5,$%/(+(,*+7*$3 cylinder block inclination for two constructional variants of the valve plate: the positive overlap variant and the relief groove variant. The following input data were assumed in the computational model: í LQWKHSUHVVXUHSRUWWKHGLVFKDUJHSUHVVXUHpt 03D í LQWKHVXFWLRQSRUWWKHLQOHWSUHVVXUHps 03D í RXWVLGH DQG LQVLGH WKH YDOYH SODWH WKH SUHVVXUH po 0 MPa, í DQJXODUYHORFLW\ȦRIWKHF\OLQGHUEORFNȦ UDGV í RLOG\QDPLFYLVFRVLW\FRHI¿FLHQWȘ 3DV í DQJOHį UDGEHWZHHQWKHD[LVx and the smallest gap height h, í DQJOHEHWZHHQWKHF\OLQGHUEORFNDQGYDOYHSODWHİ UDG í PLQLPDOJDSKHLJKWh āím, í FKDUDFWHULVWLFUDGLXVHVRIWKHYDOYHSODWHLQDJLYHQSXPS are r Pr2 Pr PDQGr P )LJSUHVHQWVWKHYDULDWLRQRIWKHRLOOHDNÀRZLQWHQVLW\ as a function of the discharge pressure pt. Fig. 3. &RQVWUXFWLRQYDULDQWVRIWKHYDOYHSODWHDZLWKSRVLWLYH RYHUODSEZLWKUHOLHIJURRYHV Fig. 4. 1XPHULFDOJULGFRQVLVWLQJRIYROXPHWULFFHOOVRIWKH+H[ Wedge type and boundary condition region 5(68/762)&20387$7,216 Fig. 5. 7RWDORLOOHDNÀRZLQWHQVLW\LQWKHYDOYHV\VWHPDV a function of the discharge pressure pt obtained by means of the programme QP developed by the authors and CFD Fluent QFDSRVLWLYHRYHUODSYDOYHSODWHEYDOYHSODWHZLWKUHOLHI grooves The computational models developed and described DERYHZHUHDSSOLHGIRUGHWHUPLQLQJWKHWRWDORLOOHDNÀRZLQtensity in the gap between the cylinder block and valve plate Increase in the discharge pressure causes linear increase in a hydraulic piston pump. The analysis was performed for LQWKHOHDNÀRZLQWHQVLW\ )LJSUHVHQWVWKHYDULDWLRQRIWKHRLOOHDNÀRZLQWHQvariable dimensions and exploitation parameters such as the discharge pressure ptWKHDQJXODUYHORFLW\ȦRIWKHF\OLQGHU VLW\DVDIXQFWLRQRIWKHDQJXODUYHORFLW\ȦRIWKHF\OLQGHU EORFNWKHG\QDPLFYLVFRVLW\ȘRIRLODQGWKHDQJOHİof the block. 7$'(86==/272'$0,$162&+$&.,3,275675<-(:6., Ș DSRVLWLYHRYHUODS Fig. 6.YDOYHSODWHEYDOYHSODWHZLWKUHOLHIJURRYHV 7RWDORLOOHDNÀRZLQWHQVLW\LQWKHYDOYHV\VWHPDVDIXQFWLRQRIWKHDQJXODUYHORFLW\ȦRIWKHF\OLQGHUEORFNREWDLQHGE\ means of the programme QP developed by the authors and CFD Fluent QFDSRVLWLYHRYHUODSYDOYHSODWHEYDOYHSODWHZLWK relief grooves Increase in the angular velocity of the cylinder block GRHVQRWVLJQL¿FDQWO\DIIHFWWKHOHDNÀRZLQWHQVLW\ )LJSUHVHQWVWKHYDULDWLRQRIWKHRLOOHDNÀRZLQWHQVLW\DVDIXQFWLRQRIWKHG\QDPLFYLVFRVLW\FRHI¿FLHQWȘ of oil. Increase in the dynamic viscosity of oil causes decrease LQWKHRLOOHDNÀRZLQWHQVLW\LQWKHYDOYHV\VWHP )LJSUHVHQWVWKHYDULDWLRQRIWKHRLOOHDNÀRZLQWHQVLW\ as a function of the angle İ of the cylinder block inclination obtained by means of the programme developed by the authors and by means of CFD Fluent. It can be observed that increase in the inclination angle H RIWKHF\OLQGHUEORFNOHDGVWRDVLJQL¿FDQWLQFUHDVHLQWKH LQWHQVLW\RIOHDNÀRZLQWKHYDOYHV\VWHP SRVLWLYHRYHUODSYDOYHSODWHEYDOYHSODWHZLWKUHOLHIJURRYHV +DYLQJREWDLQHGWKHUHVXOWVRIRLOOHDNÀRZLQWHQVLW\ from the two sources, i.e. the programme developed by the authors and from CFD Fluent, we went on to compare them. TheWKH comparison was made by calculating relative differenc+DYLQJ REWDLQHG UH HVEHWZHHQWKHUHVXOWVRIRLOOHDNÀRZLQWHQVLW\REWDLQHG from QP and from CFD Fluent QF. The relative differences were calculated according to: ߜொ ൌ ȁொು ିொಷ ȁ ȁொಷ ȁ ή ͳͲͲΨ Fig. 7. 7RWDORLOOHDNÀRZLQWHQVLW\LQWKHYDOYHV\VWHPDVD IXQFWLRQRIWKHG\QDPLFYLVFRVLW\ȘRIRLOREWDLQHGE\PHDQV of the programme QP developed by the authors and CFD Fluent QFDSRVLWLYHRYHUODSYDOYHSODWHEYDOYHSODWHZLWKUHOLHI groovesH D Fig. 8. 7RWDORLOOHDNÀRZLQWHQVLW\LQWKHYDOYHV\VWHPDVD sents selected relative differences between the results obtained from the of the angle İ at which the cylinder block is inclined 7DEOHSUHVHQWVVHOHFWHGUHODWLYHGLIIHUHQFHVEHWZHHQ function İ the results obtained from the two sources, i.e. the authors’ obtained by means of the programme QP developed by the authors SURJUDPPHDQG&)')OXHQWIRUWKHYDULDEOHDQJOHİRIWKH and CFD Fluent QFDSRVLWLYHRYHUODSYDOYHSODWHEYDOYHSODWH with relief grooves cylinder block inclination. $1$/<6,62)2,//($.6,1$9$5,$%/(+(,*+7*$3 Ta b l e 1 . Relative differences į4 between the values of total OHDNÀRZLQWHQVLWLHVREWDLQHGIURPWKHDXWKRUV¶SURJUDPPHDQG from CFD Fluent depending on the angle İ of the cylinder block inclination for the two variants of the valve plate İ>@ 0 0,0 2 Positive overlap į4 >@ Relief grooves į4 >@ $VFDQEHVHHQWKHYDOXHVRIWKHUHODWLYHGLIIHUHQFHV between the results obtained from the authors’ programme and from CFD Fluent increase with the increase in the angle İof the cylinder block inclination. In the case of a positive RYHUODSYDOYHWKHLQFUHDVHLVIURPWRDERXWDQGLQ the case of a valve with relief grooves the difference groes IURPDERXWWRDERXW CONCLUSIONS The study can be concluded by the following observations: 7KHPRGHOVGHYHORSHGSURYLGHDGHTXDWHWRROVIRUGHWHUPLQLQJWKHÀRZLQWHQVLW\RIRLOOHDNVGHSHQGLQJRQWKH variable parameters and dimensions of the pump. 2. Increase in the cylinder block inclination angle and in the discharge pressure cause increase in the intensity of oil OHDNÀRZ,QFUHDVHLQWKHG\QDPLFYLVFRVLW\FRQWULEXWHV WRGHFUHDVHLQWKHLQWHQVLW\RIOHDNÀRZDQGLQFUHDVH in the angular velocity of the cylinder block does not VLJQL¿FDQWO\DIIHFWLW 7KHLQWHQVLW\RIRLOOHDNVLVJUHDWHUIRUDYDOYHSODWHZLWK relief grooves than for a positive overlap valve plate. 5()(5(1&(6 Ivantysyn J., Ivantysynova M., 2001:+\GURVWDWLF3XPSV DQG0RWRUV$NDGHPLD%RRNV,QWHUQDWLRQDO1HZ'HOKL 2. Jang D.S., 1997:9HUOXVWDQDQDOLVHDQ$[LDONROEHQKHLWHQ 'LVVHUWDWLRQ5:7+$DFKHQ .DF]PDUHN55XWDĔVNL-3RPS\ZLHORWáRF]NRZHRVLRZH3RPLDUJUXERĞFLV]F]HOLQ\ZUR]G]LHODF]X z wykorzystaniem indukcyjnych czujników pomiaroZ\FK3U]HJOąG0HFKDQLF]Q\QU Kondakow L. A., 1975:8V]F]HOQLHQLDXNáDGyZK\GUDXlicznych. WNT, Warszawa. Nikitin G.A., 1982:6]F]LHOHZ\MHLáDELULQWQ\MHXSáRWnienia gidroagregatow. Maszinostrojenie, Moskwa. 0DMFKU]DN(0RFKQDFNL%Metody numeryczne. Podstawy teoretyczne, aspekty praktyczne L DOJRU\WP\ :\GDZQLFWZR 3ROLWHFKQLNL ĝOąVNLHM *OLZLFH 7. Murrenhoff H., 2005:*UXQGODJHQGHU)OXLGWHFKQLN 7HLO+\GUDXOLN6KDNHU9HUODJ$DFKHQ 8. 2VLHFNL$+\GURVWDW\F]Q\QDSĊGPDV]\Q:17 Warszawa. 9. 2VLHFNL$2VLHFNL/ Prace rozwojowe nad QRZąNRQVWUXNFMąSRPSZLHORWáRF]NRZ\FKRVLRZ\FK +\GUDXOLNDL3QHXPDW\ND1UV 2VLSRZ$) Objemnyje gidrowliczieskie masziny. Maszinostrojenie, Moskwa. Pasynkov R.M., 1965: K razczietu torcowych razpriedielitielei aksialno-porszniewych nasosow. Viestnik 0DV]LQRVWURMHQLD1U Pasynkov R.M.,1976: Wlijanie pieriekosa cilindrowowo bloka na rabotu tarcowowo razpriedielitiela aksialno-porszniewoj gidromasziny. Viestnik MaszinoVWURMHQLD1U 3RGROVNL0(8SRUQ\MHSRGV]LSQLNLVNROĪHQLD Leningrad. . Ryzhakov A., Nikolenko I., Dreszer K., 2009: Selection of discretely adjustable pump parameters for K\GUDXOLFGULYHVRIPRELOHHTXLSPHQW3ROVND$NDGHPLD 1DXN7HND.RPLVML0RWRU\]DFMLL(QHUJHW\NL5ROQLFWZD7RP,;V/XEOLQ 6]\GHOVNL=2OHFKRZLF]-(OHPHQW\QDSĊGX i sterowania hydraulicznego i pneumatycznego. PWN, Warszawa. Stryczek S.,1995:1DSĊG+\GURVWDW\F]Q\7RP:17 Warszawa. =KDQJ < 9HUEHVVHUXQJ GHV $QODXI XQG /DQJVDPODXIYHUKDOWHQVHLQHV$[LDONROEHQPRWRUVLQ 6FKUlJVFKHLEHQEDXZHLVHGXUFKNRQVWUXNWLYHXQGPDWHULDOWHFKQLVFKH 0DȕQDKPHQ 'LVVHUWDWLRQ 5:7+ $DFKHQ =ORWR76RFKDFNL' Oil Leakage in a VariaEOH+HLJKW*DS%HWZHHQWKH&\OLQGHU%ORFNDQGWKH 9DOYH3ODWHLQD3LVWRQ3XPS3ROVND$NDGHPLD1DXN 7HND.RPLVML0RWRU\]DFMLL(QHUJHW\NL9RO9QU& /XEOLQ $1$/,=$35=(&,(.Ï:2/(-8:6=&=(/,1,( 52=5=Ą'83203<:,(/27à2&=.2:(- =8:=*/ĉ'1,(1,(0:à$61(*2352*5$08 ,&)')/8(17 Streszczenie. W pracy przedstawiono modele obliczeniowe do RNUHĞODQLDQDWĊĪHQLDSU]HSá\ZXSU]HFLHNyZROHMXZV]F]HOLQLH R]PLHQQHMZ\VRNRĞFLSRPLĊG]\EORNLHPF\OLQGURZ\PLWDUF]ą UR]G]LHODF]DSRPS\ZLHORWáRF]NRZHM:REOLF]HQLDFKZ\NRrzystano metody numeryczne oraz komercyjny program CFD )OXHQW6WRVXMąFRSUDFRZDQHPRGHOHSU]HSURZDG]RQRDQDOL]Ċ QDWĊĪHQLDSU]HSá\ZXSU]HFLHNyZGOD]PLHQQ\FKSDUDPHWUyZ geometryczno-eksploatacyjnych pompy. 6áRZDNOXF]RZHSU]HFLHNLROHMXV]F]HOLQDSRPLĊG]\EORNLHP F\OLQGURZ\PLWDUF]ąUR]G]LHODF]DSRPSDWáRNRZD Spis treści Janusz Bowszys, Teresa Bowszys Drying Faba Bean Seeds in a Silo with a Vertical Air Circulation System .......................................................... 3 Valery Chybiryakov, Anatoly Stankevich, Dmitry Levkivskiy, Vladimir Melnychuk Application of Generalized Method of Lines for Solving the Problems of Thick Plates Thermoelasticity Part 1. Construction of resolving equations ..................................................................................................... 7 Józef Gorzelany, Natalia Matłok, Dagmara Migut Assessment of The Mechanical Properties of Fresh Soil-grown Cucumber Fruits .............................................. 15 Józef Gorzelany, Natalia Matłok, Dagmara Migut, Tomasz Cebulak Quality of Dill Pickled Cucumbers Depending on The Variety And Chemical Composition of Pickle Brine .................................................................................................... 19 Jacek Halbiniak, Bogdan Langier Research on the Frost Resistance of Concretes Modified with Fly Ash ............................................................ 23 Alexander Holoptsev, Alexander Bolshikh, Valeriya Bekirova, Mariya Nikiforova Assessment of Monthly Mean Total Ozone Distribution Changes With Regard to Atlantic Ocean Surface Temperatures Variations ..................................................................... 31 Magdalena Klimek, Leszek Mościcki, Agnieszka Wójtowicz, Tomasz Oniszczuk, Maciej Combrzyński, Marcin Mitrus Dynamic Viscosity of Water and Milk Suspensions of Extruded Corn Porridge ................................................ 37 Andrzej Kornacki The Note on Application of Logistic Model in Agriculture Research ................................................................ 41 Konrad Kowalski, Tadeusz Zloto An Analysis of Pressure Distribution in Water and Water Emulsion In a Front Gap of a Hydrostatic Bearing ......................................................................................................... 45 Konrad Kowalski, Tadeusz Zloto Exploitation and Repair of Hydraulic Cylinders Used in Mobile Machinery ...................................................... 53 Andrzej Kusz, Jacek Skwarcz, Mateusz Gryczan Application of the Computation Procedure in Bayesian Network in Estimation of Total Cost of Natural Stone Elements Production ............................................................................................................ 59 63,675(ĝ&, Khachatur Kyureghyan, Wiesław Piekarski The Analysis of Oil Balance in Crank Bearing ................................................................................................ 65 Anna Leshchyns’ka, Yuliya Zelen’ko, Marina Bezovs’ka, Michael Sandowski The Development of New Technologies for Processing and Disposal of the Oil Containing Wastes Enterprises of Railway Infrastructure ................................................................. 71 Rafał Nadulski, Jacek Skwarcz, Grzegorz Łysiak, Ryszard Kulig Strength Properties of Horse Bean Seeds (Vicia faba L. var. minor) ................................................................ 81 Krzysztof Nęcka, Małgorzata Trojanowska Comparative Analysis of The Variability of Daily Electric Power Loads ............................................................. 87 Krzysztof Nęcka, Małgorzata Trojanowska Short-Term Forecasting of Natural Gas Demand by Rural Consumers Using Regression Models ....................... 93 Ignacy Niedziółka, Wojciech Tanaś, Mariusz Szymanek, Beata Zaklika, Józef Kowalczuk, Jarosław Tatarczak, Janusz Zarajczyk Evaluation of Physical Properties in Briquettes Made from Selected Plant Materials .......................................... 99 Ilya Nikolenko, Ervin Karimov Increase of Reverse Water Supply Systems Effectiveness in Production of Construction Materials ......................................................................................................... 105 Arthur Onischenko, Mykolay Kuzminets, Sergey Aksenov Research on Properties of Bitumen Modified with Polymers Used for Asphalt Concrete Pavement on Bridges ............................................................................................ 113 Tomasz Oniszczuk, Agnieszka Wójtowicz, Leszek Mościcki, Andrzej Rejak, Maciej Combrzyński Characteristics of Selected Rheological Properties of Water Suspensions of Maize TPS Biocomposites .......................................................................................................................... 119 Tomasz Oniszczuk, Agnieszka Wójtowicz, Leszek Mościcki, Andrzej Rejak, Maciej Combrzyński, Marcin Mitrus Characteristics of Selected Rheological Properties of Water Suspensions of Potato TPS Biocomposites ......................................................................................................................... 125 Tomasz Oniszczuk, Agnieszka Wójtowicz, Leszek Mościcki, Andrzej Rejak, Magdalena Klimek, Maciej Combrzyński Characteristics of Selected Rheological Properties of Water Suspensions of Wheat TPS Biocomposites ........................................................................................................................ 131 Halina Pawlak, Piotr Maksym, Jacek Skwarcz Vehicle Transport Organization of Food Requiring Refrigeration ....................................................................... 137 Leonid Pelevin, Mykola Karpenko The Dynamic Vibrations Hydraulic Quencher ................................................................................................. 143 Lyudmila Ryabicheva, Dmytro Usatyuk, Yuri Nikitin Correlation of Plastic Forming and Structure Formation Parameters in Powder Materials ................................... 151 Dmytro Smorkalov Calculation of Deflection of One-Layer and Two-Layer Slabs Supported on Four Sides ..................................... 161 Mykhailo Sukach Working of Deep-Water Minerals with Sectored Way ..................................................................................... 169 Tomasz Szul, Krzysztof Nęcka Comparison of the Usefulness of Cluster Analysis and Rough Set Theory in Estimating the Rate of Mass Accumulation of Waste in Rural Areas ........................................................... 175 63,675(ĝ&, Małgorzata Trojanowska, Dorota Lipczyńska An Analysis of Variability in Demand for Natural Gas at Rural Households ...................................................... 181 Grzegorz Wcisło Determination of the Rheological Properties of Biofuels Containing SBME Biocomponent ................................ 185 Grzegorz Wcisło, Natalia Labak The Determination of Energetic Potential of Waste Wood Biomass Coming from Dębica Forestry Management Area as a Potential Basis for Ethanol Biofuels of II Generation ............................................................................................................... 191 Grzegorz Wcisło, Bolesław Pracuch Determination of the Impact of the Type of Camelina Oil Used for Production of Biofuels on the Fractional Composition of CSME ........................................................ 197 Miłosz Zardzewiały, Grzegorz Zaguła, Czesław Puchalski Effects of Pre-Sowing Magnetic Stimulation on the Growth, Development and Changes in Physicochemical Properties in Sugar Beet Seedlings ........................................... 201 Tadeusz Zloto, Damian Sochacki, Piotr Stryjewski Analysis of Oil Leaks in a Variable-Height Gap Between the Cylinder Block and the Valve Plate in a Piston Pump by Means of Author-Designed Software and CFD Fluent ..................................................... 211 List of the Reviewers 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Leszek Mościcki Janusz Laskowski Ignacy Niedziółka Dariusz Dziki Stanisław Sosnowski Tadeusz Złoto Kazimierz Zawiślak Marek Kuna-Broniowski Andrzej Kornacki V.O. Płoskyi Petro Kulikov A.M. Stankevich Editors of the „TEKA” quarterly journal of the Commission of Motorization and Energetics in Agriculture would like to inform both the authors and readers that an agreement was signed with the Interdisciplinary Centre for Mathematical and Computational Modelling at the Warsaw University referred to as “ICM”. Therefore, ICM is the owner and operator of the IT system needed to conduct and support a digital scientific library accessible to users via the Internet called the “ICM Internet Platform”, which ensures the safety of development, storage and retrieval of published materials provided to users. ICM is obliged to put all the articles printed in the “Teka” on the ICM Internet Platform. ICM develops metadata, which are then indexed in the “Agro” database. Impact Factor of the TEKA quarterly journal according to the Commission of Motorization and Energetics in Agriculture is 2,07 (June 2014). GUIDELINES FOR AUTHORS (2014) The journal publishes the original research papers. The papers (min. 8 pages) should not exceed 12 pages including tables and figures. Acceptance of papers for publication is based on two independent reviews commissioned by the Editor. Authors are asked to transfer to the Publisher the copyright of their articles as well as written permissions for reproduction of figures and tables from unpublished or copyrighted materials. 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