lead-free and tin-lead rework development activities within the nemi
Transcription
lead-free and tin-lead rework development activities within the nemi
LEAD-FREE AND TIN-LEAD REWORK DEVELOPMENT ACTIVITIES WITHIN THE NEMI LEAD-FREE ASSEMBLY AND REWORK PROJECT Jasbir Bath and Mike Wageman, Solectron Corporation; Quyen Chu and Nabel Ghalib, Jabil Circuits; Alan Donaldson, Intel Corp.; Jose Matias and Eddie Hernandez, Hewlett-Packard Corp. ABSTRACT With the upcoming European ROHS legislation and other global movements to lead-free assembly, the NEMI lead-free rework group investigated and developed lead-free rework processes for medium to high-end computer products. The work concentrated on development of lead-free hot air convection rework for PBGA, CBGA, and uBGA, and lead-free hand soldering rework for TSOP and 2512 chip components on 93mil and 135mil thick test vehicle boards. Leadfree and tin-lead rework profiles along with visual and X-ray inspection will be presented and discussed. The lead-free and tin-lead rework was completed successfully and test boards were submitted for ATC reliability testing for up to 6,000 cycles from 0°C to 100°C which is ongoing at this time. INTRODUCTION Numerous investigations have been performed on the assembly of lead-free electrical components onto printed circuit boards using lead-free soldering materials. Few have explored the reworkability of these lead-free assemblies. Array packages are one of the more challenging types of components for rework. For this work lead-free and tin-lead PBGA, uBGA and CBGA component were evaluated. The rework process included removal, site redressing, and part replacement using hot air convection rework equipment. TSOP and 2512 chip rework components were also evaluated for tin-lead and lead-free rework on the same boards. The rework study was performed in two phases. Phase one emphasized the development of the rework profile. Both tin-lead and lead-free (SnAgCu) assemblies on two relatively thick boards (93mil and 135mil) and two surface finishes (Electrolytic NiAu and Immersion Silver) were evaluated. The rework profile was developed with consideration of the component, board, solder paste and standard specifications. Phase two of the study used the profiles and parameters developed in Phase 1 to rework test boards at uBGA, PBGA, CBGA TSOP and 2512 chip locations. Both reworked and first-pass “as-assembled” assemblies were subjected to accelerated thermal cycling (from 0°C to 100°C for 6,000 cycles). Results were compared. J-STD-020B (Ref.1) required that the lead-free soldering peak temperatures for large components (> 350Cumm package volume) stay below 245°C and small components (<350Cumm package volume) stay below 250°C. This experiment aimed to verify if the developed rework profiles conformed to this standard. EXPERIMENTAL Board and Components Used and Rework Locations Rework development was conducted on the NEMI Payette reliability test vehicle. The board is shown in Figures 1 (topside) and 2 (bottomside). Most of the components reworked were on the topside. The bottomside has one PBGA544 component and some TSOP and 2512 chip components. Board specifications are shown below: High Temp Laminate FR4 (Tg: 170°C) Surface Finish: Imm Ag and Electrolytic NiAu Board Thickness: 0.093” and 0.135” Board Dimension: 16.5” x 7.25” Number of copper layers: 14 Component specifications are shown below: PBGA544 1mm pitch, 35 x 35mm body size Ball Alloy: 63Sn37Pb or SnAgCu Board Location: U29 (Topside), U30 (Bottomside) UBGA256 1mm pitch, 17mm x 17mm body size, 256 I/O uBGA (Plastic Overmold), Ball Alloy: 63Sn37Pb or SnAgCu Board Locations: U40 and U41 (Both Topside) CBGA 937 I/O 10Sn90Pb alloy spheres 1mm pitch, 32.5 x 32.5 mm body size 4.33 mm thick (die & substrate) Overall height (including balls) 5.14 mm SnAgCu alloy spheres 1mm pitch, 32.5 x 32.5 mm package size 1.5 mm thick (substrate only) Overall height (including balls) 2 mm Board Locations: U27 and U28 (Both Topside) The rework process, including component removal, site redressing, paste deposition and new component attachment, was evaluated on lead-free assemblies using new process parameters (i.e. increased processing temperatures). Solder Paste Used for PBGA544 and uBGA256 Tin-Lead: (63Sn37Pb) 90wt% metal content Lead-free: (Sn3.9Ag0.6Cu) 89.3wt% metal content Solder Paste Type: No Clean, Type 3 Mini-Stencil used for uBGA256 Thickness: 6mils Aperture opening: 20mil Mini-stencil Printing on Component Sphere for PBGA544 The mini-stencil was cleaned with alcohol and a lintfree wipe after every print to prevent solder paste clogging. The paste volume used was 2493mils. The paste volume to print on the ball spheres was based on the ball diameter. Solder Paste for Paste Dispense Process (In syringes) for CBGA933: 63Sn37Pb: No-clean, 87% metal content Type 4 Sn3.9Ag0.6Cu: No-clean 84% metal content Type 3 Paste Deposition Equipment for CBGA: Paste Dispensing System Localized Hot Air Rework Convection Equipment For BGA Components Rework Atmosphere: Air (for CBGA and PBGA) Rework Atmosphere: N2 (for uBGA) Rework Equipment for TSOP and 2512 Chip: Hand soldering iron and desolder station No-clean cored wire for lead-free Sn3.9Ag0.6Cu No-clean cored wire for tin-lead: Sn37Pb Liquid no-clean rework flux pen rework: Redressing Equipment: Non-contact scavenger system (for CBGA and uBGA) Manual Solder wick (for PBGA) Thermocouple Attachment: Type K Thermocouples – 36 Gauge Thermally Conductive Adhesive Kapton Tape (heat resistant tape) Post Rework Analysis: Electrical Resistance Measurement X-Ray System Visual Inspection Temperature Profiling Criteria and Thermocouple Locations The tin-lead and lead-free rework thermal profiles had to satisfy the J-STD-020B temperature requirements. The temperature on the solder ball joint had to be high enough to guarantee reflow while not exceeding the maximum temperature allowed on the top of the component The values for these requirements were dependent on the solder paste alloy used and the alloy spheres present on the component. Table 1 summarizes the rework temperature profiling criteria. Existing rework equipment used in tin-lead rework was used for the lead-free rework with higher heater settings developed to rework lead-free SnAgCu soldered components. Thermocouple Calibration and Setup Prior to the development of any rework profile, the thermocouples used had to be verified to ensure that proper temperatures were recorded. A simple test was performed using boiling water to verify that all thermocouples used did not deviate more that +/-1°C from 100°C. Thermocouples were placed as shown in Figure 3a and 3b for all three types of BGA components. Thermocouple locations 1 (TC1) and 2 (TC2) were located on solder joints at the outer corners. Thermocouple location 3 (TC3) was at the center solder joint. TC4 and TC5 were attached to the board 150mils from the package. TC6 was attached to the package top and TC7 was attached to the package top corner edge. Solder Wicking Redressing Process PBGA544 A hand solder wicking method was used to clean and flatten excess solder on all the pads after part removal. Additional flux was put on before the wicking process. A no-clean flux pen was used for this process. UBGA256 and CBGA933 For both uBGA and CBGA, a vacuum scavenging system was used that sucked up the residual solder leaving behind a semi-flat surface for solder print and part placement. This tool used a nozzle which blowed hot air to melt the solder while suction was applied by a vacuum tube at the center of the nozzle. This procedure was performed without contacting the board. The noncontact approach helped to minimize the potential of pad damage during site redress. Figure 4 shows a site with the uBGA removed without any disturbance to the site and a site after performing the site redress using the scavenger. It was noted that for the lead-free operation, the scavenger filter was more prone to clogging. It was estimated that the filter would last about 30% longer in the case of tin-lead solder before requiring cleaning as compared to the case of lead-free solder redressing. The choice of rework profile depends on the board thickness and the type of solder alloy and component in question. Paste Printing Process Three different paste printing techniques were used depending on the preference of the individual rework site for the component used. PBGA544 For the PBGA544, paste was printed onto the component spheres. Figures 5a thru 5h show the PBGA544 solder paste printing method. uBGA256 A mini-stencil operation was used to apply solder paste to the board. A mini-steel blade was used to screen the solder through the stencil. Figure 6 shows the uBGA256 rework site before and after screen printing. CBGA933 For the CBGA, the solder paste was deposited using a Paste Dispensing System. The methodology of this system was to dispense dot by dot a solder paste shot on each pad of the array by the means of a solder paste syringe and needle. BGA Rework Process Verification To reduce the temperature difference between the solder joint and the top of the component, the topside of the board was preheated to 150°C by using only the bottom heaters before the top nozzle was engaged to finish the remainder of the rework operation. Multiple trials were performed before finalizing the rework profiles. With the process developed and defined, a sample rework operation was performed to verify the three lead-free rework process steps (remove, redress, and replace) for the PBGA, CBGA and uBGA on a 135mil thick NEMI Payette test board. The reworked PBGA, CBGA and uBGA used for the verification process had resistance values of the daisy–chained components measured which were within the expected value and all reworked components showed no defects during X-ray inspection. Based on this, the reworked test boards were thermally and mechanically tested. TSOP and 2512 Chip Component Hand Soldering Rework For TSOP and 2512 chip components, assembled components were removed using the Desolder Station. The component removal locations were then cleaned using solder wick and the solder station. New components were then replaced using the supplied leadfree components and solder or tin-lead component and solder. Reworked components were then inspected under the microscope at 30X magnification. Electrical resistance measurements were taken and they were within the resistance values expected for the daisy chained parts. Results and Discussion Board Profiling PBGA544 The developed board rework profiles for the PBGA544 component at locations U29 (topside) and U30 (bottomside) for lead-free and tin-lead soldered boards for both board thicknesses are shown in Tables 2 and 3. Temperatures were measured on the component and at the solder joint. Table 2 lists all of the critical lead-free rework profile parameters and the targets. All the PBGA package top edge temperature values exceeded the target of 245°C and one center value was also exceeded. Usually the component top edge temperature is not measured. The time above liquidus temperature of 217°C was near the top end of the target on all the profiles and was slightly exceeded at the U29 location on the 135mil board for lead-free. In addition bottomside component temperatures were measured to see if bottomside PBGA544 component reflowed during topside PBGA544 rework. The results indicated the bottomside PBGA544 did not exceed the lead-free SnAgCu solder melting point. The SnPb PBGA544 critical rework profile parameters and targets are listed in Table 3. Package temperature at the edge of the PBGA top exceeded the target on a couple of the measurements. The time above liquidus temperature of 183°C was near the top end of the target on all the profiles and was slightly exceeded at the U30 location on the 135mil board. The bottomside tin-lead PBGA did not exceed 183°C melting point during any of the tin-lead topside 544I/O PBGA package rework profiling. The PBGA544 rework profiles for SnPb and SnAgCu are shown in Figures 7 and 8 for the 135mil thick board. The board temperatures at 150mils from the reworked component was above the solder melting temperature in all cases for tin-lead and lead-free SnAgCu rework. uBGA256 Rework Profiles All four rework profiles were created on the 93mil and 135mil thick boards, two for SnPb and two for leadfree. The rework reflow profile parameters are summarized in Table 4 and were within the target parameters listed. All top of package temperatures were at or within the target temperatures for tin-lead and lead-free processes. For the lead-free assemblies, the bottom heater’s set-point was set higher to help bring the solder joint temperature to the target condition and to keep the top of the package at or below the 245°C peak temperature target. In general for the profiles developed, the rework parameters were normally at the upper end of the target parameters. The board temperature was also measured and was typically near or over the melting point for the tin-lead or lead-free SnAgCu solder alloy. The board temperatures at 150mils from the component were above the solder melting temperature in three out of four cases. The uBGA256 rework profiles for SnPb and SnAgCu for 135mil thick boards are shown in Figures 9 and 10. CBGA933 The results for the SnPb and SnAgCu CBGA rework profiling on the 93mil and 135mil thick boards are shown in Table 5. As expected, the lead-free rework showed more difficulties than the tin-lead rework process, in part due to the more stringent temperature requirements for the lead-free process. It was difficult trying to comply with the standard J-STD 020B requirements while at the same time maintaining the minimum solder joint temperatures to guarantee solder joint reflow. The temperatures at 150mils away from the reworked component on the board were over the solder melting point in most cases. The CBGA933 SnPb and SnAgCu rework profiles on 135mil thick boards are shown in Figures 11 and 12. The BGA type reworked components were visually inspected and examined using 2-D X-Ray Inspection a n d later subjected to continuity tests (electrical resistance measurements). An example of the X-ray image for a lead-free SnAgCu reworked CBGA is shown in Figure 13. Visual solder joint inspection images of SnPb versus SnAgCu reworked CBGA components are shown in Figure 14. TSOP and 2512 rework TSOP and 2512 chip rework was evaluated on test vehicles. During the initial assessments, there was no difference in the use of SnAgCu versus Sn3.5Ag cored wire for lead-free hand solder rework in terms of the solder tip temperature used. The solder tip temperature used for SnAgCu and Sn3.5Ag was up to 25°F higher than SnPb to account for the increased melting temperature of the lead-free solder. Sn3.9Ag0.6Cu cored rework wire was used in the subsequent reworked reliability test board builds. For lead-free SnAgCu solder TSOP and 2512 rework, the desolder station was set at 800°F to remove parts from the board and the solder iron station was set at 750°F to reattach new parts to the boards. For tin-lead solder TSOP and 2512 rework, the desolder station was set at 750°F to remove parts from the board and the solder iron station was set at 725° to 750°F to reattach new parts to the boards. No real issues were encountered during TSOP or 2512 chip rework with lead-free or tin-lead solder. CONCLUSION For the PBGA544, the rework profiles stayed within all of the targets. The overall tin-lead and lead-free rework process for the PBGA544 component went very well on both 93mil and 135mil thick NEMI Payette boards. No problems were noticed with either board surface finish. Rework profile time was around 6 minutes for SnPb rework and 8 minutes for SnAgCu rework for 135mil thick boards. For the uBGA256, the rework profiles for SnPb and SnAgCu were successfully used to rework various sets of NEMI Payette assemblies. No major issues were found for these reworked uBGAs. Rework profile time was around 7 minutes for SnPb rework and 9 minutes for SnAgCu rework for 135mil thick boards. For the CBGA933, lead-free SnAgCu along with SnPb CBGA rework was feasible. The time taken to preheat the topside of the board to 150°C using only the bottom preheat was fairly long. Rework profile time was around 11 minutes for SnPb rework and 13 minutes for SnAgCu rework for 135mil thick boards. The increase in rework profile time for SnAgCu compared with SnPb rework was due to the higher times to reach the rework peak temperature for SnAgCu rework due to its higher melting point and the need to reach a higher topside board preheat temperature with the bottomside heater before engaging the topside nozzle. For the TSOP and 2512 chip rework, the operators saw no difference between soldering with lead-free versus tin-lead soldered joints apart from a difference during visual inspection, where the lead-free soldered joints appeared more cratered and resembled what a ‘cold’ solder joint may look like during tin-lead soldering while the tin-lead reworked joint appeared smooth and shiny. This would need to be taken into consideration during solder joint inspection training for lead-free. Increased solder iron tip temperatures were needed for lead-free rework, but these were not significantly higher. The temperatures in all cases conformed to J-STD-020B but this work was done by some of the best rework engineers in the industry with optimized rework equipment and nozzles with the active support and codevelopment from the rework equipment suppliers. In addition, rework profiling of thermocoupled boards was conducted over a period of a few months, calibrating thermocouples and taking the time to develop the best rework profiles over multiple rework runs and reverifying these rework runs. In production, it would require hours or days to develop rework profiles and only if a thermocoupled profile board was actually available. It would be difficult to match this quality and quantity of rework profiling optimization for the industry in general. Data from the rework project was supplied to the JSTD-020C standards committee and helped to formulate the temperatures and conclusions developed in this new standard (Ref.2). In recognition of the fact that lead-free rework presented unique issues in terms of reducing component top temperature, J-STD-020C was adopted, which indicates that any size of lead-free component that was not rated to 260°C based on its package volume and thickness has to be tested by the component supplier to at least one reflow pass at 260°C peak to account for lead-free rework. This is shown in Table 6 which compares the ‘old’ J-STD-020B with the ‘new’ J-STD-020C with the current JEITA standard for lead-free component temperature testing. The temperature measured on the board at 150mils from the reworked component (PBGA, uBGA, CBGA) was in many cases above the melting temperature of the solder used on the board (tin-lead or lead-free SnAgCu). Future Work PBGA The rework machine did an acceptable job of reworking all of the tin-lead and lead-free SnAgCu boards, but the time above liquidus was at the high end of the specification. The bottom heater was often used to create the rework profiles and subsequently took a longer time to cool down. Higher bottom heater settings reduced the amount of topside nozzle heat needed which reduced the delta T between the solder joint and the component top. This was also the case for the uBGA and CBGA components. uBGA Future work would need to address higher bottom side heating capabilities (as for PBGA and CBGA) and improvements to the scavenger redressing device to reduce increased clogging encountered for lead-free SnAgCu compared to tin-lead solder. CBGA The rework system could be improved to accelerate the board preheating stage. The system took too long to reach the desired topside temperature of 150°C during the NEMI Payette board rework for both 93 and 135mil thick boards. Some improvements should be made to the machine for better rework thermal performance and control. The paste dispensing system for the CBGA worked well with tin-lead solder paste but it showed more issues during the lead-free SnAgCu solder paste dispensing. Improvement of the paste dispensing system would be needed to better handle the different amount of solder paste required in the paste dispense process for the new collapsing Pb-free SnAgCu CBGAs. ACKNOWLEDGEMENT The authors would like to thank all the partners of the NEMI rework sub-group for their advice and support. Recommendations and support from the rework machine manufacturers, solder paste suppliers and the backup technical staff at the individual rework sites are gratefully acknowledged. The authors would like to acknowledge Terri Zee of Solectron Corp., Rich Parker of Delphi, Jerry Gleason of Hewlett-Packard Corp. and Ron Gedney of NEMI (National Electronics Manufacturing Initiative) for critically reviewing this paper. REFERENCES 1. IPC/JEDEC J-STD-020B July 2002: Moisture/Reflow Sensitivity Classification for Nonhermetic Solid State Surface Mount Devices. 2. IPC/JEDEC J-STD-020C July 2004: Moisture/Reflow Sensitivity Classification for Nonhermetic Solid State Surface Mount Devices. Table 1: Profile Parameters Minimum temperature for solder ball Maximum package temperature top center Maximum temperature delta between solder ball thermocouples (corner to center) Temperature delta between lowest temperature solder ball and package top Time above liquidus (seconds) Heating rate (°C/second) Cooling rate, machine dependent (to be monitored and reported) Soak time (to be monitored and reported)/ sec Sn37Pb 200°C 220°C 10°C SnAgCu 230°C 245°C 10°C 15°C 45-90 0.5-2.5 15°C 45-90 0.5-2.5 120-183°C 150-217°C Table 2 PBGA 544Lead-free Rework Parameters Profile Parameters Target 0.135” 0.135” 0.093” U29 U30 U29 Minimum Temperature for >230°C 232.3°C 232.6°C 236.6°C Solder Ball [°C] Maximum P a c k a g e 245°C T: 245.1°C T: 244.0°C T: 244.5°C Temperature [°C] E: 246.7°C E: 249.7°C E: 245.1°C Maximum Temperature Delta 10°C 6.2°C 4.7°C 4.8°C Between Solder Ball TC (_Tx-y) [°C] Temperature Between Lowest 15°C T: 12.8°C T: 11.4°C T: 8.5°C Solder Ball & Package Top E: 14.4°C E: 17.1°C E: 7.9°C (_Tz) [°C] Time Above Liquidus (TAL) 45-90sec 93.3sec 85.0 sec 88.0sec [sec] Heating Rate [°C/sec] 0.50.8°C/sec 0.8°C/sec 1.2°C/sec 2.5°C/sec Cooling Rate [°C/sec TBD -0.7°C/sec -0.8°C/sec -1.1°C/sec Soak Time (150-217°C) [sec] TBD 108.2sec 103.0sec 91.4sec “T” indicates top center of the component (TC6). “E” indicates the edge of the component top (TC7). Bolded Temperatures and Times indicated a value above the target. Table 3 SnPb PBGA 544 Rework Profile Parameters Profile Parameters Target 0.135” 0.135” 0.093” U29 U30 U29 Minimum Temperature for 200°C 200.5°C 203.8°C 203.3°C Solder Ball [°C] Maximum P a c k a g e 220°C T: 216.3°C T: 217.2°C T: 215.0°C Temperature [°C] E: 219.8°C E: 225.0°C E: 218.1°C Maximum Temperature Delta 10°C 5.1°C 3.6°C 2.2°C Between Solder Ball TC (_Tx-y) [°C] Temperature Between Lowest 20°C T: 15.8°C T: 13.5°C T: 11.7°C Solder Ball & Package Top E: 19.3°C E: 21.2°C E: 14.8°C (_Tz) [°C] Time Above Liquidus (TAL) 45-90sec 84.9sec 90.6sec 83.8sec [sec] Heating Rate [°C/sec] 0.51.3°C/sec 1.1°C/sec 1.3°C/sec 2.5°C/sec Cooling Rate [°C/sec TBD -1.0°C/sec -0.9°C/sec -1.0°C/sec Soak Time (120-183°C) [sec] TBD 80.8sec 83.6 sec 90.0sec “T” indicates top of the component (TC6). “E” indicates the edge of the component (TC7). Bolded Temperatures and Times indicated a value above the target for the PBGA. 0.093” U30 234.1°C T: 244.7°C E: 248.5°C 3.9°C T: 10.6°C E: 14.4°C 74.9sec 1.1°C/sec -1.1°C/sec 96.9sec 0.093” U30 201.6°C T: 216.5°C E: 222.0°C 5.5°C T: 14.9°C E: 20.4°C 79.3sec 1.3°C/sec -1.2°C/sec 86.6sec Table 4 Rework Reflow Profile Parameters (uBGA256) Bolded Temperatures and Times indicated a value above the target for the uBGA. Target Parameters Solder Ball Min. Temp (°C) Package Max. Temp (°C) Max. Temp. Delta Between Solder Ball TCs (°C) Temp. Between Lowest Solder Ball and Pkg Top (°C) Avg. Time over Liquidous (TAL) -sec Avg Joint & Package Heating Rate (°C/sec) Board Temp. 150mils Away from Comp. (°C) Target 200 220 10 20 45 to 90 0.5 to 2.5 <183°C SnPb 93mil 135mil 199 203 213 210 0 2 10 11 86.7 75 2.12 1.22 192 183 Target 230 245 10 15 45 to 90 0.5 to 2.5 <217°C Lead-free SnAgCu 93mil 135mil 229 230 245 245 1 1 16 15 93.3 85.3 2.2 1.8 218 208 Table 5 Rework Reflow Profile Parameters (CBGA933) Bolded Temperatures and Times indicated a value above the target for the CBGA. Target Parameters Solder Ball Min. Temp (°C) Package Max. Temp (°C) Avg. Time over Liquidous (TAL) for Solder Joint -sec Avg. Time over Liquidous (TAL) for Package Top Center -sec Board Temp. 150mils Away from Comp. (°C) Target 200 220 45 to 90 <183°C SnPb 93mil 135mil 199 201 201 202 69 75 74 74 184 206 Target 230 245 45 to 90 <217°C Lead-free SnAgCu 93mil 135mil 239 235 239 238 59 66 64 71 257 212 Table 6 ‘Old’ J-STD020B compared with ‘New’ J-STD-020C versus Existing JEITA standard for lead-free component temperature testing Figure 1 Primary Board Side (Top) Figure 2 Secondary Board Side (Bottom) Figure 3a Thermocouple Locations 1-3 Figure 3b Thermocouple Locations 4-7 Figure 4 uBGA Site Before and After Redressing Figures 5a thru 5h shows the PBGA544 solder paste printing method Figure 6 uBGA Site Before and After Screen Printing Figure 7: PBGA544 SnPb rework profile for the 135mil thick board. Figure 8: PBGA544 SnAgCu rework profile for the 135mil thick board. Figure 9: uBGA256 SnPb rework profile for the 135mil thick board. Figure 10: uBGA544 SnAgCu rework profile for the 135mil thick board. Figure 11: CBGA933 SnPb rework profile for the 135mil thick board (Temp {°C} versus Time {sec}). Figure 12: CBGA933 SnAgCu rework profile for the 135mil thick board(Temp {°C} versus Time {sec}). Figure 13: SnAgCu CBGA933 X-Ray Image After Rework* *Note: Corner joints which show a slightly bigger diameter is actually a visual distortion due to its distance from the center. Figure 14: Visual solder joint inspection images of SnPb (left) versus SnAgCu (right) reworked CBGA components