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Excursion guide Joakim Mansfeld June 2012 J. Mansfeld: The geology of Utö – excursion guide 2 The geology of Utö Introduction Utö exhibits an unique environment in many ways. In the earlier years it was the iron mines that was important, one reason being that they were the mines (of a reasonable size) that were located closest to Stockholm. More than 200 years ago Utö also became interesting to science because of its unusual rock types and richness in rare minerals. Utö also played a roll in the earlier years in the history of how the elements were discovered. Today Utö is still known for its unusual mineralogy and its interesting bedrock, but maybe more for it’s easily accessible localities and beautiful environments. The formation of Utö The bedrock of Utö is part of a large region with volcanic and sedimentary rocks formed around 1900 million years ago (Ma). These rocks was intruded by a old generation of granitoids, more or less contemporaneous with the volcanism. On Utö rocks of this generation comprise felsic volcanic rocks, greywackes and limestones, but very little granitoids. The formation of these rocks was probably the result of a converging plate boundary with a subduction zone to the present southeast of Utö and with a down-plunging direction towards the northwest. This subduction setting created the rocks of the Bergslagen region, a c. 200x300 km large area in the south central part of Sweden. The name Bergslagen derives from ”bergslag”, an ancient Swedish juridical term describing a region with mining privilegies. In the Bergslagen area several thousand old mines are also known, today three is still in production, and one is to re-open within short. The volcanism at Utö and in Bergslagen ceased, but the plates continued to converge and the result was deformation and metamorphism, i.e. mountain Simplified geological map of Bergslagen showing metavolcanic rocks (yellow), metasedimentary rocks (blue), deformed Svecofennian intrusions (brown) and late orogenic granites (pink). Red colours to the west and southwest are rocks belonging to the Transscandinavian Igneous Belt. Grey areas are Palaoezoic sedimentary rocks. Modified after Koistinen et al. (2001). 3 J. Mansfeld: The geology of Utö – excursion guide Geological map of northern Utö, modified from Talbot (2008). Stars indicate the described localities. building. At Utö the metamorphism reached temperatures up to 700°C as evident by metamorphic minerals, which can be found in the greywackes (Barrientos 2011; Engström 2011). The timing of the metamorphism is not well constrained, but probably lies in the range 1860–1840 Ma. This also means that most of the rocks found on Utö really are metamorphic rocks. However, an usual practice in Sweden is to skip the ”meta-” prefix in the rock name. This is also done in this guide. Some time after the peak metamorphic event, and formation of the mountain chain, followed a crustal collapse. We do not know exactly the mechanism behind that, but we can see the result of it – at around 1800 Ma a second generation of granites intruded the older rocks. These granites were probably formed by melting of the lower crust during the collapse event. The composition of these granites varies somewhat, most likely due to the varying composition of the original crust that melted. In most places in Bergslagen this event led to the formation of a younger generation of granites, usually referred to as ”late orogenic” granites. The appearances of these granites varies a lot and many typical granites can be distinghuised in Bergslagen, and those have also got names of their own as e.g. the Stockholm granite. Pegmatites usually accompanies the granites. On Utö there are no granites of this generation, but several different kinds of pegmatites. Pegmatites are the last rocks to form from a granite magma and as such pegmatites act as ”trash cans” for unusual elements that fit poorly in the crystal structures of common magmatic minerals. The fluids that form the pegmatites evolve as more and more material crystallize, thus leaving a fluid with increasing concentrations of unusual elements. The J. Mansfeld: The geology of Utö – excursion guide last pegmatites to form are thus also the most extreme in their compositions, which usually is referred to as most fractionated. On Utö there are a range of pegmatites with different levels of fractionation, from early formed coarse-granied pegmatites with simple mineralogy, to the most extreme fractionated type. The elements that are especially enriched in the fractionated pegmatites on Utö are lithium, boron, tantalum etc. One of the interesting minerals that can be found in the fractionated pegmatites are elbaite, a lithium-bearing turmaline (turmaline is a group of cyclo-silicate minerals with boron). Elbaite forms beautifully colouerd crystals with red, green or blue colours. Formation of the pegmatites was the last rockforming event on Utö. From c. 1800 Ma Utö, and Bergslagen, was part of a stable continental area. Plate tectonic events further away led to short events of fracturing (sometimes accompanied by intrusion of mafic magmas) and faulting. 4 Formation of biogenic carbonates during more quiet periods. The iron ores probably started to form during this period when solutions rich in ferrous iron reacted with the oxygenated sea water. The solutions also carried silica and the result become banded iron formations. 1900 Ma The volcano is now at its peak. It is a large (c. 10 km in diameter?) central volcano with a history of violent pyroclastic eruptions and subsequent caldera collapses (e.g. Allen et al. 1996). Erosion results in sandy greywackes and probably even more coarsegrained deposits. Formation of biogenic carbonates and banded iron ore formations. At this point the small sulphide deposits was also formed as a result of seawater circulation through the volcanic pile. 1905 Ma A small subaquatic rhyolitic volcano has formed and its lavas and ashes mixes with and starts to overlie pelitic greywackes. During periods of quiencence biogenic carbonates form. 1905–1900 Ma The volcano grows and breaches the water surface. Formation of rhyolitic lavas, ashes and ignimbrites. Erosion of the volcanic deposits results in rather coarse-grained psammitic greywackes and conglomerates. The volcano is now a central volcano that sometimes collapses and forms calderas. 1880 Ma The volcano was not long lived, and when volcanism and magmatism ceased in the area the lithosphere cooled and sank, and the area was submerged. Long before the volcano drowned it had become extinct and it’s top was probably eroded flat. The increasing water depth and also increased distances to any land area that could be eroded led to a gradual fining of the sediments deposited. 5 J. Mansfeld: The geology of Utö – excursion guide c. 1850 Ma Plate movements led to collisions of island arcs and volcanic arcs, which led to metamorpism and folding during the Svecofennian Orogeny. The bedrock at Utö experienced a high-temperature low pressure metamorphism with formation of andalusite, garnet and sillimanite. Geomorphology Stockholm Archipelago is characterized by a old peneplain that has been fractured and faulted. The Cambrian peneplain surfaces can still be seen in places, and Cambrian sandstone injections are fond in many places, demonstrating that the amount of erosion since the Cambrian is almost negligible. The fracture and fault zones has, however, been subjected to weathering during varmer and moister climates. The weathering could in places be down over 100 m deep. The Quaternary glaciations cleared these weathered fractures and created broad valleys between fresh and unweathered bedrock hills. The rocks of Utö 1820–1800 Ma Tectonic collapse of the Svecofennian Orogen and heating of the lower crust caused partial melting of the metasedimentary rocks, which on Utö led to formation of granitic fluids. These intruded along fractures and formed the different types of pegmatites found here. Present Utö is eroded down to a small island. In the northwest and southeast the greywackes are found. The central part of the island is characterised by a complicately folded assemblage of interlayered volcanic and carbonate rocks. Here the banded iron formation and the small sulphide deposit are also located. Different types of pegmatites crosscut all other rock types. Greywacke Originated as clayey and sandy sediments (pelites and psammites) in the deeper part of the sea and at the flanks of the volcano. The greywackes are sometimes very well preserved with original sedimentary structures such as conglomerates, bedding, graded bedding, and cross bedding (Allen et al. 1996; Lundström & Koyi 2003). At other places deformation and metamorphism has transformed the greywackes to migmatites. Felsic volcanic rock Different varieties of volcanic rocks can be found on utö, most of it as ashes formed during violent eruptions, either plinian or phreatomagmatic (Allen et al. 1996). A thick sequence of quartz porphyritic rhyolites on the southeastern side of northern Utö is probably a near-surface intrusion, i.e. a magma chamber. Marble The central part of northern Utö is dominated by carbonate rocks. The carbonates are inpure with varying content of silicates. The origin of the carbonate rocks on Utö is unknown because of the high degree of recrystallization. At other places in Bergslagen carbonates are known to be biochemically deposits in the form of stromatolites. Such an origin is also possible on Utö since the carbonate rocks seem to be shallow-water deposits (Allen et al. 1996). J. Mansfeld: The geology of Utö – excursion guide Iron ore The iron ore of Utö was a small ore, but it was strategic important as it was located both close to Stockholm and to the sea. The iron ore itself is a rather common ore of BIF-type, i.e. an iron ore consisting of millimetre thick layers of alternating iron oxides and other minerals, mainly quartz, but also other silicates or sometimes carbonates. On Utö the quartz in the ore is jaspilite, a variety coloured by iron oxides. BIF is an acronym for Banded Iron Formation, and is globally the most important iron ore type. Most of the Worlds BIF ores formed during a period between 2500 and 1800 Ma, i.e. simultaneously with a dramatically rising in oxygen levels in the atmosphere and oceans. The BIF ores are believed to have formed by precipitation of inslouble ferric iron as it formed by oxidation of ferrous iron solved in the oceans. The iron ore of Utö is thus not that spectacular in itself. However, Utö is a very good example that rare and spectacular sites can form by coincidence (see below). Pegmatite Pegmatite is a coarse grained rock formed by magmatic solutions that remained after crystallization of the magmas. Pegmatites have often a mineralogy similar to granites, e.g. quartz, potassic feldspar, plagioclase, muscovite and biotite, but they usually also contain a number of more rare minerals. The most famous of Utö’s pegmatite dykes are the one that crosscut the iron ore, just at the places of the mines. It is of a type called lithium pegmatite (or LCT pegmatite after the elements lithium-caesiumtantalum). LCT pegmatites are rather rare. They are believed to have formed by partial melting of ancient deep sea sediments (such as greywacke) in e.g. subduction zone settings, or during regional metamorphism. A similar pegmatite can be found at Varuträsk outside Skellefteå in northern Sweden. The unique with the pegmatite on Utö is that it happened to intrude an iron ore, which is why Utö exhibits a number of very rare minerals. The iron mines The iron ore of Utö has been known for a long time. The first written documentation is from the middle of the 17th century. There are, however, archaeological evidences that the ore was mined already during the 13th century. The evidences are not from Utö itself, but from Gotland. Here remnants of a furnace for iron production was found together with ore containing minerals unique for Utö. 6 During the years 1711–1878 around 2.1 metric tonnes of of ore were mined, and totally the mines are estimated to have produced a total of 2.5 tonnes (in comparison, this is about 10% of todays annual production in Kiruna and Malmberget, the two largest iron ores in Sweden). The last mining activity was in 1878, but the ore has been subject to later exploration attempts, the last in the 1950th. Today the deepest mines are Nyköpingsgruvan, with its 214 meter, and Finngruvan, 150 meters deep. The minerals of Utö As mentioned above Utö hosts a large variety of minerals, of which some are very rare. Around 70 different minerals has been identified. The minerals can be divided into groups based on their genesis and host rock. Ore minerals Two types of ores are present on Utö, banded iron formation and a small exhalative (Zn-Pb-Ag) sulphide deposit. The iron ore minerals are hematite and magnetite. Amongst the sulphide minerals galena, sphalerite, chalcopyrite, chalcosite, bornite, arsenopyrite, molybdenite, pyrite and silver has been found (Jonsson 1996). Pegmatite minerals The most characteristic of the pegmatite minerals on Utö are the lithium bearing minerals such as spodumene (a pyroxene), petalite (a feldsparlike mineral), lepidolite (a mica), and elbaite (a tourmaline with four varieties; indigolite – blue, rubellite – red, verdelite – green, and achroite – colourless). But the fractionated pegmatites also carries a large number of other minerals, from major minerals such as quartz and feldspar (e.g. the green Pb-bearing microcline variety amazonite), muscovite and schörl (a black turmaline), to minor phases such as beryl, fluoroapatite, cassiterite, arsenopyrite, manganoapatite, manganotantalite, pollucite, topaz and zircon. Rare minerals are e.g. the beryllium minerals mentioned above together with often secondary formed minerals as e.g. cookeite, eucryptite, stokesite, triphyline-lithiophilite and wickmanite (Jonsson 1996). 7 J. Mansfeld: The geology of Utö – excursion guide Minerals formed due to reactions with the lithium pegmatites and surrounding rocks The most famous in this group of minerals is of course holmquistite. But other minerals formed due to reactions between the pegmatite and the country rock are e.g. epidote, schörl and bavenite (Jonsson 1996). Skarn minerals Minerals formed through reaction between carbonate and silicate rocks during metamorphism, or through reaction between carbonates and granitic fluids from the pegmatites. Here minerals such as biotite, actinolite-tremolite, diopside, epidote, fluorite, grossular, almandine, hornblende, calcite and serpentine belong (Jonsson 1996). Utö’s place in the history of science Ores and production of metals have for several centuries been an important part of Sweden’s economy. It was thus natural that many of the most famous Swedish scientists were interested in minerals. Amongst those we e.g. the discoverer of oxygen, Scheele (in the end of the 18th century), and the inventor of the chemical language, Jöns Jakob Berzelius (in the beginning of the 19th century). At that time there were very little difference between a chemists, a mineralogist or a geologist as the subjects were very closely related. The difference between a mineralogist and a chemist was practically none, since both worked with minerals. The period comprising the late 18th century and the early 19th century is also characterized by the discovery of the elements and their systematics. This is especially pronounced in Swedish science at that time since 21 of the 90 naturally occurring elements was discovered here. Utö, with it’s interesting geology and location close to Stockholm, played an important part in this. The discovery of the mineralogical richness of Utö is a fantastic history in itself. It was a Portugese, born in Brazil, Jose Bonifacio de Andrada e Silva that in 1800 was the first to describe some of the more famous minerals of Utö. He visited the island already during the 1790’s as part of a travel in Sweden and Norway (Smeds 1986). He described a long row of new minerals from Utö, most of them are today not valid mineral names, but he is responsible for the description of lepidolite (lithium mica) and spodumene, he also named the blue variety of lithium turmaline (elbaite), indigolit. For the rest of the World, Andrada (who also has been honoured by giving his name to the garnet andradite) is most famous for being the first president of the free nation Brazil. Spodumene also plays a role in the discovery of the elements. It was in spodumene from Utö that one of Berzelius diciples, Johan August Arfvedson, in 1817 first found and described the element lithium. The name was taken from the Greek word ”lithos”, meaning stone, since lithium was the first alkali metal extracted from a mineral. The already known alkali metals natrium and kalium had been extracted from sea salt and plant ash respectively. Today c. 70 different minerals are known from Utö (Jonsson 1996). The most known of these are the lithium minerals. The most famous minerals of Utö is also a lithium mineral – holmquistite. It was discovered by A. Osann during a field trip in 1910, in conjunction with the International Geological Congress in Stockholm and was named after the organizer P. J. Holmquist. During later years some rare beryllium minerals (milarite, chiavennite, bavenite) have also been found on Utö. J. Mansfeld: The geology of Utö – excursion guide 8 Geological map of the central part of northern Utö presented at the excursion during the International Geological Congress 1910. Blue-green – marble, orange – porphyritic volcanic rocks, yellow – sedimentary and volcanoclastic rocks. red – pegmatite. (Holmquist 1910). A selection of localities on Utö Utö hotell – marble Just outside the hotel and c. 100 m from the bridge (Ångbåtsbryggan) a small rounded ridge of marble is easy accessible. The surface of the rock is black and very pitted. The pits and small groves in the marble is karren, a weathering fenomena typical of carbonate rocks. The rock itself is light creamy white. Utö vacation cottages – contact between marble and felsic volcanic rock with skarn The central part of Utö comprises an intermingled assemblage of volcanocalstic rocks and carbonates. During metamorphism the carbonates and silicate rocks have reacted with each other creating a reaction skarn (a metasomatically formed calc-silicate rock). At the end of a row of rental cottages a good example of this is demonstrated. Here a contact between a dense and very fine-grained volcanoclastic rock and an impure marble can be seen. The contact is seen as a c. half meter wide reaction zone with large radially growing amphibole crystals. Stora Persholmen – greywacke and pegmatite On the small island of Stora Persholmen, just to the north of the main bridge, the bedrock is composed of deformed and metamorphosed greywackes. Primary layering can still be seen as compositional changes, but primary sedimentary structures are very hard to detect. Instead deformation structures such as folding, refolded folds, ptygmatic folding, boudinage, and kink bands are common. In the northeastern part of the islet the bedrock is even more deformed and metamorphosed, and can almost be compared with a migmatite. Large irregular dikes and bodies of both white and red coarse-grained pegmatites cut the greywackes. Some of the dykes are themselves deformed pointing to at least two generations of pegmatite intrusions. The mineralogy of the pegmatites are, however, rather poor. Quartz, potasium feldspar, plagioclase, muscovite, biotite and black tourmaline (schörl) can be found. Nyköpingsgruvan – iron ore and lithium pegmatite We will stop on the path just between the two largest mines, Nyköpingsgruvan and Långgruvan. The path itself lies there because the rock left behind is part of the lithium pegmatite cutting the iron ore. The pegmatite can be seen as a powdery withish rock on the southern side of the path. Another body of the same pegmatite type can be seen as a c. 2–3 meter wide rock bridge across the Nyköping mine. 9 J. Mansfeld: The geology of Utö – excursion guide The large waste rock dump (Stora varphögen) Several hundred years of mining on Utö has produced large volumes of rock waste. Most of it is found as large heaps around the large central mines, but smaller waste rock dumps can also be found at other places. Today these dumps are protected as historical remains. Collecting and scavenging in most of the dump is thus forbidden. South of the central mines waste rocks from many of Utös mining operations can be found in a large leveled dump known as ”Stora varphögen”. This large dump is seen as a exception from the general prohibition and here it is possible to look around and pick samples from the mines and surrounding rocks. Most of the finds are iron ore of differing quality, but also pegmatite and samples from the surrounding bedrock can be found. Furthermore, sulphide minerals from a small sulphide mine some hundreds meter to the northeast of the large mines are also found here. Rävstavik – well preserved greywacke Rävstavik is a large area of beautyful exposed outcrops of greywacke. In contrast to Stora Persholmen, much of the rocks here are rather well preserved and primary sedimentary structures such as bedding, cross bedding, graded bedding and conglomerate layers can be seen at may places. The sediment itself is rather coarse-grained, and psammitic layers dominate. Ptygmatic folded quartz veins, however, reveal that also here the amount of deformation is rather large. In more pelitic metamorphic minerals in the form of altered andalusite can be seen as greyish white diffuse blobs. Fårskärsudd – greywacke with garnet South of Rävstavik greywackes that underlie the sediments at Rävstavik can be found. The greywackes here were deposited before the main volcanic phase and are deposited in deeper water farther from land. The greywackes are more pelitic and homogenous in character than the sandy greywackes at Rävstavik. The pelitic composition was also favourable for growth of garnet in some layers. References Allen, R.L., Lundström, I., Ripa, M., Simeonov, A. & Christofferson, H., 1996: Facies analysis of a 1.9 Ga continental margin, back-arc, felsic, caldera province with diverse Zn-Pb-Ag-(Cu-Au) sulfide and Fe oxide deposits, Bergslagen region, Sweden. Economic Geology 91, 979– 1008. Barrientos, N., 2011: Determination of metamorphic conditions in metapelites on Stora Persholmen, NE Utö, with EMPA analysis. Unpubl. batchelor thesis. Department of Geological Sciences, Stockholm University. 29 p. Engström, A., 2011: Investigation of the metamorphic environment conditions of Persholmen, NE Utö, with SEM generated data. Unpubl. batchelor thesis. Department of Geological Sciences, Stockholm University. 21 p. Holmquist, P.J., 1910: Geological Map of the Utö-territory in the southern coast-regions of Stockholm. Geologiska Föreningens i Stockholm Förhandlingar 32, pl. 37. Holmquist, P.J., 1910: Geological Map of the iron-ore-bearing zone of the island Utö, S.E. from Stockholm, Sweden. Geologiska Föreningens i Stockholm Förhandlingar 32, pl. 38. Jonsson, E., 1996: Utös mineralogi. Unpubl. report. Department of geology and geochemistry, Stockholm university. 7 s. Koistinen, T., Stephens, M.B., Bogatchev, V., Nordgulen, Ø., Wennerström, M. & Korhonen, J., 2001: Geological map of the Fennoscandian Shield, scale 1:2 000 000. Geological Surveys of Finland, Norway and Sweden and the NorthWest Department of Natural Resources of Russia. Lundström, I. & Koyi, H., 2003: Vulkanön som blev ett fritidsparadis – några glimtar från Utös allra tidigaste historia. Geologiskt forum 37, 4–13. Lundström, I., Allen, R.L., Persson, P.-O. & Ripa, M., 1998: Stratigraphies and depositional ages of Svecofennian, Palaeoproterozoic metavolcanic rocks in E. Svealand and Bergslagen, south central Sweden. GFF 120, 315–320. Smeds, S.A., 1986: de Andrada e Silva, 1763–1838, mineralog och statsman. Berg-&-dalbladet nr. 4, 3–7. Talbot, C. J., 2008: Palaeoproterozoic crustal building in NE Utö, southern Svecofennides, Sweden. GFF 130, 49–70. J. Mansfeld: The geology of Utö – excursion guide 10