The methodology of radioactive tracers is one of most
Transcription
The methodology of radioactive tracers is one of most
,5DGLRSKDUPDFHXWLFDOV 'XULQJ WKH ELHQQLXP KDSSHQHG DW WKH ,(1 5DGLRSKDUPDF\ 'LYLVLRQ VHYHUDORXWVWDQGLQJHYHQWV)LUVWO\LWLVLPSRUWDQWWRSRLQWRXWWKHLQFUHDVHRIRXUWHDPWKDQNV WRWKHDGPLVVLRQRIQHZFRQWUDFWHGDQGWKHWUDQVIHUHQFH RIWKUHHRWKHUSURIHVVLRQDOV FDPH IURP GLIIHUHQW GLYLVLRQV RI ,(1 &RQFHUQLQJ WKH DFWLYLWLHV UHODWHG WR SHUVRQDO IRUPDWLRQ ZH KDGLQWKHSHULRGWKHDFFRPSOLVKPHQW RI ILYH FRXUVHV DW OHYHO RI SRVJUDGXDWLRQ IRU &233( DQG ,0( EHVLGHV FRQWULEXWLQJ IRU WKH DFFRPSOLVKPHQW RI WKH (VFROD GH 9HUmR -RUJH $QGUp 6ZLHFD WRJHWKHU ZLWK RWKHU GLYLVLRQV RI ,(1 ',5( DQG ',65 DQG WKH ,QVWLWXWH RI 3K\VLFV RI 8)5- :H DOVR KDG WKH FRQFOXVLRQ RI WKUHH PDVWHU V GHJUHH WKHVHV ,0( DQG D GRFWRUDWH WKHVLV &233( GHYHORSHG LQ WKH GHSHQGHQFLHV RI WKH 'LYLVLRQ 7KLV ODVW ZRUN UHVXOWHGLQWKHLPSODQWDWLRQRIWKH/DERUDWRU\RI5DGLRWUDo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mR/(% HPDLOEUDQGm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t 1LWHUyL 5- GU\ VHSDUDWHG LQ WZR GLIIHUHQW IUDFWLRQV KHDY\ DQG OLJKW DQG PDUNHG ZLWK /D DQG P$J,QWKHLQLWLDOFRQILJXUDWLRQZKHUHHDFK EDIIOHSODWHLQWKHWDQNDOORZHGDFRPPXQLFDWLRQRI FPEHWZHHQWZRVXFFHVVLYHFRPSDUWPHQWVWKH UHVXOWVIRUWKHGLVSODFHPHQWRIWKHVHZHULQVLGHWKH XQLWIRUWKHGHWHFWRUVDUHVKRZQLQ)LJXUH ( (W ( 3 RVLom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omR 3RVLomR 3 )LJXUH&KDUDFWHULVWLF&XUYHRI6HWWLQJ7DQN 'HWHFWRU SRVLomR 3 ( 3RVLomR 3 ( 'HWHFWRU SRVLomR 3 3RVLomR 'HWHFWRU 3RVLomR 3 ( 'HWHFWRU SRVLomR 3 ( 'HWHFWRU 3RVLomR 3 ( ( (W 'HWHFWRU 3RVLomR 3 3RVLomR 3 ( 5HIHUHQFH >@ /(%%UDQGmR ± '6F 7KHVLV 8)5-&233( -XQH 7KHVLJQUHJLVWHUHGE\WKHGHWHFWRUVLQ3DQG3LW VKRZV WKDW WKH VHWWLQJ SURFHVV RI WKH VROLG SKDVH ZDV KDSSHQLQJ LQVLGH HDFK FRPSDUWPHQW EXW WKH (YDOXDWLRQRIDPL[LQJDQGHTXDOL]H VHZHUWDQN XVLQJUDGLRDFWLYHWUDFHUV %UDQGm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ur va E ( t ) para o m siturador com fase sólida 6.0E-4 E (t) Fração Leve 4.0E-4 Fração P esada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s ) Curva ajustada pelo m odelo "M isturador com Volum e M orto" 2 .0 E-3 E (t) 1 .6 E-3 1 .2 E-3 contribuição devido a canalização direta 8 .0 E-4 M odelo de M isturador com Volum e M orto 4 .0 E-4 0 .0 E+ 0 VHHPVOLNHDSHUIHFW PL[HUEXWWKHPHDQ UHVLGHQFH WLPH PHDVXUHG PLQ LV VPDOOHU WKDQ WKH WKHRUHWLFDOYDOXHWKLVLVGXHDLQWHUQDOFDQDOL]DWLRQV DQGDGHDG]RQHH[LVWLQVLGHWKHWDQN 0 5 00 1000 1500 2000 2500 3000 TEM PO ( s ) )LJXUH (TXDOL]H 7DQN UHVSRQVH WR OLTXLG SKDVH PDUNHGZLWK%U 60 00 &\FORWURQ+H,PSODQWDWLRQ(IIHFWLQ6XSHUFRQGXFWRUV <%D&X2GG 7\SH6WXGLHG%\3RVLWURQV 6DQWRV*5 6DQWRV-&5 HPDLOJRQFDOR#LHQJRYEU MRVHFH]DU#WDXUXVLPHHEEU FRPSDWLEOH ZLWK WKH SUREH IRU PDJQHWLF SHUPHDELOLW\PHDVXUHPHQWV[[PP ',5$,(1 ,QVWLWXWR0LOLWDUGH(QJHQKDULD,0( .H\ZRUGV QHXWURQ UDGLRDFWLYHZDVWH VRXUFH PL[WXUH ,UUDGLDWLRQ3URFHGXUH 7KHLUUDGLDWLRQZHUHGRQHDW,(1¶V&9 &\FORWURQ 7KH SDUWLFOH EHDP ZLWK 0H9 PD[LPXPHQHUJ\ZDVSHULRGLFDOO\GHJUDGHGZLWKD URWDWLQJ GLVN ZLWK DOXPLQXP IRLOV RI GLIIHUHQW WKLFNQHVV7KLVZD\LWZDVSRVVLEOHDKRPRJHQHRXV LRQ LPSODQWDWLRQ LQWR WKH VDPSOH WKLFNQHVV 7KH W\SLFDO FXUUHQWV ZHUH Q$ FRUUHVSRQGLQJ WR D IOX[RI[ FPV DQG ,QWURGXFWLRQ ,Q RXU UDGLDWLRQ GDPDJH UHVHDUFK XVLQJ F\FORWURQ VLPXODWLRQV ZH DUH DFFRPSOLVKLQJ D VWXG\ RI KLJK 7F VXSHUFRQGXFWRU XQGHU SDUWLFOHV¶ LPSODQWDWLRQ DW ,(1¶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Â 9RURQRYD>@ LUUDGLDWHG 1E6Q ZLWK SDUWLFOHV JHWWLQJ PRQRWRQLFDOO\ GHFUHDVLQJ RI 7FRQVHW ZLWK LQFUHDVLQJIOXHQF\ Â &KULVH\>@ LUUDGLDWHG ILOPV RI <%D&X2 ZLWK 0H9 SDUWLFOHV DQG IOXHQF\ ORZHU WKDQFP DQGVKRZHGQRFKDQJHVRQ7FRQVHW Â 0DLVK>@ LUUDGLDWHG <%D&X2 ZLWK SFP SURWRQV DQG REVHUYHG QR HYLGHQFH IRU SKDVH WUDQVLWLRQ GHVSLWH RI FRQWUDGLFWLQJ 9RURQRYD¶V UHVXOWV $V D QH[W VWHS ZDV SHUIRUPHG SRVLWURQ OLIHWLPH PHDVXUHPHQWV DV IXQFWLRQ RI WHPSHUDWXUH WR VWXG\ WKH EHKDYLRU RI 7F DQG LWV FKDQJHV DV FRQVHTXHQFH RI &\FORWURQ +H LPSODQWDWLRQLQWKLVFHUDPLF 5HVXOWV 7KH PDJQHWLF SHUPHDELOLW\ PHDVXUHPHQWV ZHUH SHUIRUPHG XVLQJ D FRQYHQWLRQDO V\VWHP IRU ]HURGHWHFWLRQ³/RFNLQDPSOLILHU3$57KH WHPSHUDWXUHUDQJHZDVIURP WR. $IWHU LUUDGLDWLRQ LW ZDV REVHUYHG VWUXFWXUH¶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¶ IRU WKH WZR UDGLRDFWLYH VSHFLHVFLWHGDERYH Ncc 0DWHULDODQG0HWKRGV 7KH ,0,%* LV ODEHOHG DW ,(1¶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¶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y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± OLIH RI ) ZKLFK FODLPV IRU D YHU\ VKRUW WLPH RI DQDO\VLV DQG WKH VHFXULW\ RI WKH DQDO\VW 7KH WHFKQLTXH RI +LJK 5HVROXWLRQ *DV &KURPDWRJUDSK\ DWWHQGV DOO WKH DERYH UHTXLUHPHQWV 5HIHUHQFHV >@ +DPDFKHU . &RHQHQ + 6W|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i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¶V DVVLVWDQFH WKH 3(7 &HQWHU SURMHFW DOUHDG\ VWDUWHG ZRXOG JDLQ D FRQVLGHUDEOH LPSXOVH WR LWV FRQFOXVLRQ 7KH FRPELQHG HIIRUW ,(1,$($ ZRXOG EHRIJUHDWO\FRQWULEXWLQJWRWKHLPSURYHPHQWRIWKH %UD]LOLDQV¶ KHDOWK FDUH 7KLV FRQWULEXWLRQ WDNHV DFFRXQWWKDWWKH,(1¶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¶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¶V DVVLVWDQFH ZRXOG EH LQGLVSHQVDEOH WR ILQDQFLQJ WKH SURSHU HTXLSPHQWV IRU SRVLWURQ HPLWWHU UDGLRLVRWRSHV¶ SURGXFWLRQ V\QWKHVLV ODEHOLQJ DQG TXDOLW\ FRQWURO 7KH ,$($¶V DVVLVWDQFH ZRXOG EH DOVR YDOXDEOH LQ SHUVRQQHO WUDLQLQJ DV ZHOO DV UHVHDUFKHU¶V LQWHUFKDQJHDQGWHFKQLFDOFRRSHUDWLRQ:LWKWKH &RQWULEXWHWR,PSURYHPHQWRI+HDOWK&DUH6\VWHPDQG 4XDOLW\RI/LIHLQ6WDWHRI5LRGH-DQHLUR 7RJHWPRUHSUHFLVH 'LDJQRVHVZLWK3(7 *2%-(&7,9(6 63(&,),& 2%-(&7,9(6 7RSURGXFH)'*WRPHHWWKH QHFHVVLWLHVRI5LRGH-DQHLURDUHD 7RPDNHDYDLODEOH3(7DQGRU 63(&7VFDQQHUV 352'8&7 &\FORWURQ LQVWDOOHG OLFHQVHG DQGRSHUDWLQJ 5DGLRSKDUPDF\ 8QLW\ LQVWDOOHG OLFHQVHG DQG RSHUDWLQJ 4XDOLW\&RQWURO /DERUDWRU\LQVWDOOHG OLFHQVHGDQGRSHUDWLQJ %XLOGLQJ ,QVWDOODWLRQ SURSHU WR UHFHLYH 3HW 6FDQQHUV &\FORWURQRSHUDWLRQDQG PDLQWHQDQFH 5DGLRSKDUPDF\ /DERUDWRU\ LQVWDOODWLRQ 4XDOLW\ &RQWURO /DERUDWRU\ LQVWDOODWLRQ $&7,9,7,(6 2SHUDWLRQPDLQWHQDQFH RQ WKH5DGLRSKDUPDF\ 2SHUDWLRQPDLQWHQDQFH WUDLQLQJRQ4& 3(763(& 6FDQQHUV /LFHQVHG DQG 2SHUDWLQJ %ORFN'LDJUDP2EMHFWLYH7UHHIRU,(1,$($ VSURMHFWXVLQJ/RJLFDO)UDPHZRUN
Similar documents
The Arrest of Biological Time as a Bridge to Engineered Negligible
XHVXQWLOIXQGDPHQWDOSK\VLFDOOLPLWVDUHUHDFKHGDQ\UHTXLUHGUHSDLUSURFHVVWKDWLV FRQVLVWHQW ZLWK SK\VLFDO ODZ VKRXOG EHFRPH DYDLODEOH WR UHVFXH FRQWHPSRUDU\ SHRSOH ,QFRQVLGHULQJWK...
More informationGovernment - Wisconsin REALTORS® Association
:LWKFRQYHQWLRQZUDSSHGXSHYHU\RQH·VWKRXJKWVDWWKH:5$TXLFNO\WXUQHGWR ZKDW·VEHHQDWWKHWRSRIHYHU\RQH·VPLQG²WKHHOHFWLRQ+RSHIXOO\E\WKHWLPH\RX UHFHLYHWKLVPDJD]LQHWKHVWDWH...
More informationSAFETY HELMETS CHEMICALS ANTI SPATTERS
7RXJK PP WKLFN 6+,(/'IOH[ 39& VWULSV SURYLGH XQPDWFKHG UHVLVWDQFH WR WHDULQJ RU EXUQLQJ ,Q WKHHYHQWWKDWVRPHVWULSVDUHGDPDJHGWKH\FDQEHTXLFNO\DQGHDVLO\UHPRYHGIURPWKH...
More information