SAFETY DATA SHEET

^
S5:.
1.1
ldentification
Synonyms I
Based on Directive
of
the
200f/58/EC
substance
of
or
the
Comission
the
of
European
preparation:
'7778-80-5
z
: N.A.
:23t-915-5
: TT5900000
NFPA code
Molecular
Formula
1 - 0 - 0( * )
]-74.26
weight
K2S04
Use of the substance
or t,he preparation:
Fertiliser:
EC FERTILTSER (Regulation
No 2003/20o3
and of t.he Council)
1 "3
Company/r.rndertaking
identif
ication:
T E S S E N D E I T L OC H E M I E
T n d r r s i .r i r " n : r k S c h o o n h e e s Z o n e 1
B-3980 Tessenderlo
Tel.
: +:\2 13 61 22 IL
Fax
: +32 13 67 37 49
L.4
Telephone
nurnber for
emergency:
+32 L4 5€] 45 45
Brandweer:informatiecentrum
voor gevaarlijke
Technische Schoolstraat
43 A,
B-2440 GeeI
Hazardous
ingrediente
CAS No.
EINECS/ELINCS
-.^r^-^l
ljv ua-D
Comunities
dipotassium
sulphate
GRANUPOTASSE
CAS No.
EC index No.
EINECS No.
RTECS No.
L.2
SAFETYDATASHEET
sLoffen
Conc.
%
NO.
7778-84-5
!urL,
o.E the
European
(B. I.G.
in
Parliament
)
Hazard
symbol
Riskg
(n-phrases
)
100
231-915-5
No hazard
4 .L
4.2
4.3
D''i
.amni
classificaLion
Eye contarct:
-- If irr:Ltacion
persists:
- Rinse rui-th water
in
accordance
consul-t
Skin conLact:
- If
persists:
irr:Ltation
consultr
- Wash w:LLh water
and soap
Af
-
.lrf
l arl
hrr
a
di-rective
6 ' 7/ 5 4 8 / E E C
a doctor/medical
service
a doctor/medical
service
ter inhralation:
problems
If breathing
develop:
consult
Remove the victim
into
fresh
arr
Unconscious:
maj-ntaj-n adequate
airway
nts i nd
with
a doctor/medicaland
service
respiration
0s-2007
Sfoffen
Brandweerinf ormat.i-ecent rum v o o - c e v a a r r i i k e
B-2440 Geel
Technische SchooLsrraat 43 A,
. / /rr.na
hr ihi a
ha
8 +32 14 58 45 47
rl8
vzvr
n
(BIG)
n:il
ihf^^hi^
h6
4.4
Af
-
5.1-
Suitable
extinguishing
media:
- t r x t i n c r r r i e h i n om c d i a f r r r q r r r r - r r n d i n o f i r c s .
ter ingJestion:
If you feel unwelf: consult a doctor,/medical service
fmmedi,etely after
give lots of water to drink
ingestion:
Never ,3ive water to an unconscious person
Victim is fully
conscious: induce vomitinq
5.2
Unsuitabl.e extinguishing
- No data available
5.3
Special exposure hazards:
- No datil avai-lable
5.4
Instructi.ons:
- Dilute toxic
5.5
:ll
p v i -i n o r l i e h i n o m c d i : : T T n u r e 6 ]
media:
gases with
water
spray
Special. protective
equipment, for firefighters:
- Heat/f:ire
exposure: compressed air/oxygen
apparatus
- Heat/fire
exposure: gas-tight
suit
6.1- Personal protection/precautions:
See heading B.I/B -3/L0.3
5 .2
6.3
Environmerntal precautions:
- Contain released substance, pump over in suitabl-e
- PIug the leak, cut off the supply
- I(nock down/dilute
dust c1oud with water spray
Methods of
--
-
T.L
7.2
oaLt v- Pn
n
cleaning
^rrctuuDu
c fl
u
n tu ru du
up:
!l yr
Showe1 solid
spi1l
Wash down leftovers
v
c vovrLr! er rrr iYu
^-
Handling:
- Observe normal hygiene
- Avoid r.aislnq dust
>allu/
drums
of water
standards
Storage:
- Keep conLainer tightly
cl-osed
- Store at room temperature
- Store :Ln a dry area
- Store :Ln a well-ventilated
area
- K e e p a r , ^ r a yf r o m : h e a L s o u r c e s
Storage t,emperature
limit,g
Quantity
Storage life
Materials
for packaging
^,,.i ! -Lf
^
: wood, glass
-
7 .3
^ ^ - r ' ^ ^ - gt h
qr
"wiI *L Lt I
into
closing
with plenty
to
avoid
Specific uses:
- See inr:ormation
:
:
:
N.D.
N.D.
N.D.
: afuminium
supplied
by the manufacturer
contaj-ners
8.1
Expoeure
limit
valueg:
TLV-TWA
TLV-STEL
TLV-Cei1ing
OES - IJTEIJ
OES - STEI,
:
4
I
MAK
TRK
:
K/J_U
e
1 . 5
a
J_
J
.
A / 4
E
msln:
nslln:
mg/m'
ppm
PPM
ppm
mq/m3
mg/m-
ppm
ppm
ns/nl
ppm
ppm
m9/m'
MAC-TGG €I h
MAC-TGG 1"5 min.
I'IAC-Cei1i.ng
c P/1n r
vME-8 h
VLE- 15 rni.n.
5 A/'rO T
ns1nl
mg/m^
mg/m'
*s4m:
ppm
ppm
mg/m.
GWBB-8 h
GWK-15 mi.n.
Momentary'value
.
?
J
p / 1 n ' l
r r /
r v
r
EC
EC- STEL
ms/nl
msln:
mg/m-
ppm
ppm
ppm
ms/m:
mg/m'
ppm
ppm
Sampling methods:
8.2
and compounds
& Sulf ates
OSHA ]D 121
NIOSH 5OO4
Expoaure controls:
Occupational exposure controls:
- Measure the concentration
in the air
- Work under local exhaust./ventilat.ion
8.2.1
8.2.2
8.3
Pot;rssium
Sulltites.
Environrnental
exposure controls:
reqularl-v
see heading
13
Personal protection:
8.3.1
8.3.2
proEection :
respiratory
- ln case of dust production:
hand protection:
-
^1
^..^^
U I LI V gD
suitable
8.3.3
materials:
Breakthrough time:
Rubber
N.D.
eye protection:
- Safetv qlasses
-
8.3.4
dust mask with
T lur rr L
< f.
u
,
nral_
anf
:.,^
P!vLuuurvE
-^^^1
^YUyyrsD
skin protection:
- Protective
clothing
suitable
materials:
Rubber
filter
type
P2
9.1
General
i.nf ormation:
Appearance
(at 20oC)
Cr\/qf
f ) r r fr
"-
Importanu
health,
safety
and environmental
I i nn
E"l a qhna
yr rvnr i r l un/r
/ l v- rvn+i +' l r r r iY n a
l:l-
2.5/5
1689
N,A.
N,A,
N .D .
N .D .
2 . 1
1.2
11
N .D .
N .D .
N .D .
N .D .
ranno
i rr l-
Explosiorr
limits
Vapour pr:essure
Vapour pressure
Rel-ative density
Rr:lk denslifv
Wacer so1ubiliLy
Soluble
i.n
Pa
i rro
rranarrr
(at 20oC)
(at 50oC)
(at 20oC)
(at
danci
20 oC)
f rr
Viscosit.l'(at
2OoC)
Partitiorr
coeff icient
n-octanol/water
Ewanoraf i on rate
ratio
acetate
to butyl
ratio
to ether
9.3
l t i n-
^ , . ! ^
id
nnwde1.
(1 ?)
oc
oc
VoI%
hPa
hPa
( oC)
kglliEer
g/100 mI
N .D .
N .D .
information:
Other
Ma
sol
information:
pH value
Pni
i-c
Odourless
White
Odour
Colour
9.2
^ll
chamie:l
Y\^i
nf
/ma-l
l- i na
rrnaa
i - - l ! l -
po].nt
AtlE.O- ].gnlE.1On
Saturation
concenLration
:
:
:
1061
N.A.
N.D.
oc
oc
g/m3
1 - 0 .1 C o n d i t i o r r e t o a w o i d / r e a c t i v i t y :
- Stable under normal conditions
10.2 Materialer to avoid:
- Keep ar,vayfrom: heat sources
- Keep ar,vayfrom: aluminium
10.3 HazardouE decomposition products:
- Decomp,cses on exposure to temperature
rise: release of
gases/'i/apours (sul-phur oxides)
- In mol'ten state:
reacLs violenLly
wi-th (some) meLals
toxic
and corrosive
11.1Acute
LD50
LD50
LD50
LC50
LC50
11.2
tori:icity:
oral. rat
dermal rabbit
dermal rabbit
inharlation
rat
inharlatsion rat
Chronic
EC carc.
EC muta.
EC repr.
ms/ks
nslks
6600
N .D .
N .D .
N .D .
N .D .
mg/kg
mg/L/a h
ppm/4 h
LoxiciEy:
not Iist.ed
not. listed
not Iisted
cat.
cat.
cat.
(TLV)
(l{AC)
(VME)
(GWBB)
not
not
not
not
listed
l-isted
Iisted
listed
(MAK)
Carcinogernicity
(MAK)
MutageniciEy
(MAK)
Terat,ogerricity
not
not
not
listed
1i-sted
l-isted
fARC cIa$eification
not
Iisted
Carcinogernicity
Carcinogernicity
Carcinogernicity
Carcinogernicity
l-l-. 3 Routes of: exposure:
ri r- r^\^r -c f- L I U I I ,i ^ -
ri r- r1r .r -q' rl q u fa | - i nvnr r ,
11. 4 Acute ef fects/symptoms :
AFTER INThLATION
AFTER INEIALAT]ON OF DUST:
- Coughi::g
AFTER INGIESTION
AFTER ABSIORPTION
OF HIGH QUANTITIES:
- Gastro:intestinalcomplaints
- Nausea
- Diarrhoea
- Irrita':ion
of the gastric/intescinal
- Decreased renaf function
- Disturlcances of heart rate
AFTER SK]:N CONTACT
- Slight irritaLion
AFTER EYE CONTACT
:
ON CONTII\IUOUSEXPOSURE/CONTACT
- R e d n e s r so f t h e e v e t i s s u e
- Irrit.al;i-on of the eve Lissue
11.5 Chronic erffects:
- No cumulative
effect.
ON CONT]IVUOUSEXPOSURE/CONTACT:
- Skin rash/infl-ammation
-
tr \rv as y<r ! nB ei vr i l l - ^ r \ / . 1
ifficrr"l
iicq
mucosa
a )\ / ee
e
and
skin
12.1 Ecotoxic j.ty:
-
LZ .Z
LC50 (96 h)
ECsO (,48 h)
EC5O ('12 h)
:
:
:
>1000 mg/I
(DAPHNIA MAGNA)
890 mg/1
(SCENEDESMUSSUBSPICATUS)
2900 mg/I
Mobility:
-
VoLatille
-
Soluble
organic
in
compounds (VOC): N.A.
water
For ocher- physicochemical
l _ 2 . 3 Persistence
properties
see section
9
and degradability:
- biodegr:adation
BOD5
: N.A.
- water
: N.D.
-
: N.D.
soil
potential
L2 . 4 Bioaccumrrlative
- Lo9r Po*
_ BCF
:
:
- Not bi-oaccumulative
:
N.D.
N.D.
L 2 . 5 Other adl'erse effects:
-
wGK
Effect
:
on
(classi-f ication
in comp]i-ance wiLh
wassergei-Shrdender Stoffe
Verwaltungsvorschrift
1
ozone
the
of l-7 May 1999)
layer
ot dangerous
: N
-l
rrrar
-
Greenhouse effect
Effect on waste water
:
:
purification
No
22 /
No
No
t/f-nrrnci
\ v v q r r u r !
for
I
the
Pacrr"l
el-i
(vwvwS)
ozone
nn
(Rf-'l
\ s u /
3 0 9 3 / 9 4 . O . . 1. L 3 3 3 0 f
12,/94)
daLa available
daLa avai]abl-e
13.1 Provisiorrs relatinq
to waste:
- Waste rnaterial cbde (t5/442/F-F-C, Counci] Decision 2ool/LLB/F'C, o..]
L47 of
other than those mentioned
16/2/2OOt) | 06 03 14 (solid sal-ts and solutions
i n 0 5 r l 3 1 1 a n d 0 5 0 3 1 3)
- Waste rnaterial code (Flanders):
2I3
13.2 Diepoaal methods:
- Recyclr=/reuse
-
Prcr,inifete/make
-
Remove to
r ! t 5 r r v
e \ 4 v v /
an
insolr:ble
authorized
dump
(Class
I)
13.3 Packaging:
- waste rnaterial code packaging (15/442/EEC, Council
O.,J. L,L] of 16/2/2OOt):
15 01 03 (wooden packaging)
15 01 07 (glass packaging)
Decision
200I/IIB/F-C,
L4.L
Classification
of the
UN number
CLASS
SUB RISKS
PACKING
PROPER S,HIPPING NAME
L4.2
ADR (tra:nsport
by road)
CLASS
PACKING
DANGER L.ABEL TANKS
DANGER L.ABEL PACKAGES
14.3
L4.4
14.5
L4.6
L4.7
substance
in
compliance
NOT SUB.]ECT
ADNR (transport
by inland
CLASS
PACKING
DANGER L.ABEL TANKS
DANGER L.ABEL PACKAGES
wat,erways)
NOT SUB..]ECT
IMDG (maritirne
traneport)
CLASS
SUB RISKS
PACKING
MFAG
EMS
MARINE POI,I,UTANT
precautions
Special
transport
UN Recommendationg
NOT SUBJECT
RrD (Eransport, by rail)
CLASS
PACKING
DANGER L,ABEL TANKS
DANGER L.ABEL PACKAGES
ICAO (air
transport)
CLASS
SUB RISKS
PACKING
PACKING INSTRUCTIONS
PACKING INSTRUCTIONS
with
NOT SUB.fECT
NOT SUB.JECT
PASSENGER AIRCRAFT
CARGO AIRCRAFT
in
connection
with
Not resLricted
international
for any mode o f
trransportr
Labelling
in
accordance
with
directive
67/548/EEC
NoL applicable
provided
The information
on thig
MSDS is correct
information
and belief
to the best of our knowledge,
publication.
at the date of its
given
for
safe
The information
is
only
as a guidance
designed
handling,
use, proceseing,
storage,
transportation,
disposal
and release
and is not to be considered
as a warranty
specific
material
or quality
specification.
The informalion
relates
only
to
the
designated
for euch material
with
any other
material
or in
and may not be valid
used in combination
any process,
unlless specified
in the text.
N.A.
N,D.
*
Exposure
TLV :
OES :
MEI. :
I{AK :
TRK :
MAC :
l/lrfE :
VIJE 3
GWBB:
GitilK :
E C :
=
=
=
NOT APPLICABLE
NOT DETERMINED
INTERNAL CLASSIFICATION
llnlts:
Threshold
Limit
Va1ue - ACGIH USA
- United
OccupationalExposure
Standards
Kingdom
- United
Maximum Exposure Limits
Kingdom
- Germany
Maximale Arbeitsplatzkonzentrationen
- Germany
Technische
Ri.chtkonzentrationen
- The Netherfands
Maximal-e aanvaarde
concentratie
- France
VaLeurs limites
de Moyenne d'Exposition
Valeurs Limites
d'Exposition
a court terme - France
- Belgium
Grenswaarde beroepematige
blootstelling
- Belgium
Grenswaarde kortstondige
blootstelling
Indicative
occupationalexposure limit
vafues - Directive
f : Inha1able
f:raction
R : Respirable
:fraction
C : Ceiling
1im:i.t
a:
d:
du:
fa:
fi:
fu:
p:
Chronic
K
aerosol
damp
dusE
Faser
fibre
fume
poussie:re
toxiclty:
:
List
of
= T : Total dust = E : Einatembarer
Aerosolanteil
= A ! Alveolengangiger
Aerosolanteil/Alveofar
dust
(vapour)
8E:
ve:
(fibre)
va:
om:
on:
part:
the
2000/39/EC
carcinogenic
rnnlr
/P:r
crnF
/ctrrrl-\
rah
vezel
vapour
oil- mis!
oI ienevel /O1nebe1
(fume)
( dusE )
(fibre)
(oi1 mist)
n r r t i d l a d
substances
and processes
The Netherlands