May - New York Mineralogical Club, Inc.
Transcription
May - New York Mineralogical Club, Inc.
The BULLETIN OF THE NEW YORK MINERALOGICAL CLUB, INC Volume 130 No. 5 May 2016 ZACKRY WIEGAND NEW GEOLOGIST 2016 NYMC MEMBERS WORLD’S FINEST MINERAL See page 13! BLACK IS BACK May 11, 2016 Art of Light & Minerals AUCTION DONATIONS SNOWBALL EARTH America’s Oldest Gem & Mineral Club Founded 1886 Incorporated 1937 Bulletin of the New York Mineralogical Club Founded 1886 Volume 130, No. 5 May 11th Meeting Presentation: Zackry Wiegand: “Subtle Bodies: The Art of Light & Minerals” Subtle Bodies is a collection of sculptural objects incorporating neon lights and minerals that examine our relationship with Earth and Space. Created between 2012-2014 the nine pieces present minerals as relics of nature. Through forced perspective and the use of light the objects become a mb i g u o u s i n scale and infinite in depth. The ability to perceive stars, galaxies, and nebulas in objects that come out of the Earth provides a meaningful and tangible connection to Space by compressing and demystifying our distance from it. Referencing cinematic lighting techniques and narrative tropes found in science fiction, the works simulate nature at its farthest and most ephemeral boundaries. By embracing those narratives and using light as visual tool, you can elevate the perceived significance of your own minerals and document them accordingly. Zackry Wiegand is New York based artist and lighting designer from Vermont. His background in film production and architecture support a deep fascination with light as a creative and narrative tool, and themes of illusion and transition drive his curiosity with nature. His interest in rocks and minerals started early in his life. His family collected wishing rocks (river stones with a complete line going all the way around), pieces of quartz, and other unique stones everywhere they went, and his father is a landscaper who builds stone walls. Rocks became valued objects with the potential to be found, and the process of searching for them created a heightened awareness of the natural world. He continues to be inspired by minerals with unique optical properties and the various associations rocks and minerals have in pop-culture. Ë New York City, New York Ë Incorporated 1937 America’s Oldest Mineral & Gem Club May 2016 Physicists Have Observed a New State of Quantum Matter The new state was observed in crystals By Alfredo Carpineti Physicists have just observed in a real of ruthenium chloride (RuCl3). The team at material a mysterious state of matter that the Oak Ridge National Laboratory shot was first predicted 40 years ago. And if you neutrons at the crystals and looked at the thought quantum mechanics couldn’t get magnetic properties. The results are published in Nature Materials. any weirder, think again. “This is a new addition to a short list of An international team has observed for the first time a quantum spin liquid, a state known quantum states of matter,” said in which electrons break apart and behave Knolle. “It’s an important step for our in a very curious way. Electrons in typical magnetic materials are well aligned when understanding of quantum matter,” added Kovrizhin. “It’s fun to have another new the material is cooled down quantum state that we’ve to absolute zero. But in a never seen before – it quantum spin liquid, presents us with new electrons are not organized. possibilities to try new “This is a new things.” quantum state of matter, The understanding of which has been predicted quantum spin liquid could but hasn’t been seen have consequences for before,” Dr. Johannes Patterns formed by bombarding room-temperature Knolle of Cambridge’s materials in a quantum spin liquid state sup er co n d u c to r s and Cavendish Laboratory, one with neutrons q u a n t u m c o m p u t e r s. of the paper’s co-authors, said in a statement. It should be noted, it is Quantum spin liquid could even be used as not really a “liquid” per se – rather, the term memory storage for quantum computers. indicates that electrons are not lined up as Source: iflscience.com from April 6, 2016 they should be. Electrons are thought of as fundamental indivisible particles, but they can also be Issue Highlights mathematically described by two quasiparticles bound together, one President’s Message. . . . . . . . . . . . . . 2 representing the spin and one the charge. Meeting Minutes. . . . . . . . . . . . . . . . 2 Quasiparticles are essentially the World of Minerals: Mars Update (I). 3 fundamental properties of the electron A New Geologist. . . . . . . . . . . . . . . . 4 acting as individual particles, although they Volcanic Eruption Cause?. . . . . . . . . 4 can’t move freely through space. Even More Elements. . . . . . . . . . . . . 5 In a quantum spin liquid, the spin and Cave Art Volcano.. . . . . . . . . . . . . . . 6 c h ar ge q uasip ar ticle can mo ve Periodic Table Game. . . . . . . . . . . . . 7 independently from each other and the The 100: Black is Back.. . . . . . . . . . . 8 electron is broken. The free spin Topics in Gemology: Rare Watches.. 9 quasiparticle is also a Majorana fermion, a 2016 NYMC Members.. . . . . . . . . . 10 curious excitation that is its own Climate & Gravel. . . . . . . . . . . . . . . 11 antiparticle. The first Majorana fermion was Snowball Earth. . . . . . . . . . . . . . . . . 11 only discovered last October. Lawrence Conklin Reprint. . . . . . . . 13 “Until recently, we didn’t even know Massive Blue Sapphire.. . . . . . . . . . 14 what the experimental fingerprints of a New Low-Density Ice.. . . . . . . . . . . 14 quantum spin liquid would look like,” said March ‘16 Show Dealer Donations. 15 paper co-author Dr. Dmitry Kovrizhin. Banquet Invitation / Preview. . . . . . 15 “One thing we’ve done in previous work is Curium. . . . . . . . . . . . . . . . . . . . . . . 16 to ask, if I were performing experiments on Club & Show Calendars. . . . . . . . . . 17 a possible quantum spin liquid, what would I observe?” 2 Bulletin of the New York Mineralogical Club, Inc. President’s Messages By Mitch Portnoy At last month’s meeting I presented a mock-up screen of a “Members Only” tab on the website that would have classified ads in a variety of categories that only members could place or access. Reaction to this benefit was extremely positive so I will contract our webmaster to program the tab . We will start with a “Rides Offered/Wanted” category with more to follow over the near future. For many years now the Club has produced free postcards advertising the club and given them out at meetings and at mineral shows. I presented 4 designs to a group of members and there was no consensus which to use. However, it turned out it was actually cheaper to produce all four than just two! They will be distributed over the next two years. A large quantity of specimens from the late Mitch Bogen’s collection have been donated to the club. A lot of work has to be done to organize the unbelievably disorganized mess that they currently are in. The minerals will find their way into the auction, raffles, etc over the next few months. At first inspection, I think they will also form the foundation of a special benefit sale that we will have later in the year, perhaps during the summer. I received the above item from esteemed dealer James Zigras as a donation to our archives. Does anybody know what it was used for? Club Meeting Minutes for April 13, 2016 By Vivien Gornitz, Secretary Attendance:45 President Mitch Portnoy presided Announcements: The monthly raffle was held. The meeting day’s historical events were announced. A Mineral Hardness (Mohs 10) game was played, the first of a new series! Information about mineral hardness in general was presented. A special door prize was given, a book about gemstone inclusions relating to the evening’s lecture. A new book about the minerals of New York State and where to collect them will soon be available. The NYMC items for sale (gemstone pens, backpacks, etc.) at the meeting were exhibited. The Club’s upcoming events through March 2017 were presented. Special Lecture: Dr. Roland Scal – “Gemstone Microscopy” In his recent presentation, Dr. Roland Scal, professor at Queensborough Community College, revealed the hidden beauty and important information concealed in tiny inclusions embedded in gemstones. Regarded by many as flaws, these inclusions disclose much about the environment in which these crystals grew and where they originated, whether in nature or a lab, and even in some cases their home country. Knowing this can add value to the stone, particularly for emeralds that originate in Colombia, a demantoid from Russia, or a ruby from Myanmar (Burma). Roland began by pointing out basic instruments used to study inclusions—the optical microscope and the scanning electron microscope (SEM) for viewing at even higher magnifications. The latter instrument also can analyze an inclusion chemically, by bombarding it with x-rays. In general, the microscopist uses darkfield illumination, in which light enters the field of view from an angle, rather than from directly below, to create a high contrast that shows up otherwise overlooked, subtle features. Many colorful slides were shown to illustrate these points. For example, swirls and bubbles usually mean a stone is fake—i.e., glass, but some natural fluid inclusions may freeze into a glassy mass. Randomly oriented, thin rutile needles in sapphire or ruby gives these stones a “sleepy”, milky look, but when they intersect at 120° angles, the resulting star gem becomes highly desirable. The Linde Company manufactured synthetic star rubies and sapphires in the 1950s-1960s that could be easily spotted because they were just too perfect. A zircon inclusion in an Australian sapphire became metamict (lost its crystallinity due to natural radiation), which set up stresses that fractured the host crystal and produced a halo. But tension haloes around rutile, zircon and other high temperature inclusions may also be evidence for heat treatment. (Rutile needles also become fuzzy and indistinct when heated). Black inclusions within a diamond point to graphitization caused by the rapid transit to the surface within a kimberlite eruption that brought the stone into a zone of disequilibrium (i.e., much lower temperatures and pressures than where it first crystallized). In many cases, inclusions in gemstones can indicate the country of origin. For example, Sandawana emeralds from Zimbabwe typically display actinolite needles, whereas Colombian emeralds have 3-phase May 2016 inclusions consisting of trapped brine, gas, and halite. Demantoid garnets from the Urals are characterized by “horsetail” inclusions of chrysotile, whereas demantoids from other locales have needles of actinolite, or other minerals. In both examples, the Colombian and Russian gems are considered more valuable than those from elsewhere. The microscope unveils many other interesting internal features, such as growth zoning, changes of crystal habit during growth, or more importantly, whether a stone is natural or lab-grown. The fairly rare Lechtleiter synthetic emeralds look heavily fractured like broken glass, or “crazy paving stones.” Hydrothermally-grown synthetic emeralds show nail-head inclusions with phenacite, often aligned, which give the stone a roiled, hazy luster. Ramaura-grown rubies contain orangey blobs of flux and metallic Pb, La inclusions. Roland’s journey into the hidden world of gemstones unlocked a whole new dimension and host of fascinating and useful facts about these lovely crystals. Members in the News In 2003, one of John Betts’s mineral photographs was used on a postage stamp of Guinea-Bissau. Renée Newman, who spoke to the NYMC last year about exotic gems, has just had her fourth book in the Exotic Gems series published, focusing on jade and pearls. (More information to follow.) May Meeting Game! May 2016 Bulletin of the New York Mineralogical Club, Inc. 3 The World of Minerals The World of Minerals is a monthly column written by Dr. Vivien Gornitz on timely and interesting topics related to geology, gemology, mineralogy, mineral history, etc. The Minerals of Mars – An Update (Part I) Mars, the Red Planet Mars, a planet of dramatic contrasts, displays heavily-cratered, moon-like terrains in the southern highlands, towering volcanoes, the Valles Marineris canyon system (2000 miles long and 12,000 feet deep) that dwarfs the Grand Canyon, deep channels gouged by biblical-sized floods, dune fields rivaling the Sahara, and smooth, sparsely-cratered northern hemisphere plains. Its thin, mostly carbon dioxide atmosphere has a surface pressure less than one percent that of the Earth. Surface temperatures range from near freezing during southern hemisphere summer to -190E F at the poles in winter. Although once much wetter, the red planet is now bone dry and frigid (Table 1). Any liquid water either seeps into the ground and freezes, or evaporates. Yet copious volumes of water once carved out dendritic (or branched) river valleys–now dry–scattered across much of the cratered southern highlands. Catastrophic floods streamlined teardrop-shaped “islands” in giant outflow channels. River-like formations hint at to a formerly more clement climate—one more hospitable for the origin of early life. Recent mineral discoveries strengthen this possibility. Finding evidence for life on other planets has motivated recent space exploration. “Follow the water” is NASA’s chief guideline for seeking possible life abodes–past or present–on Mars. Certain types of minerals can reveal important clues about past environments and climates of a planet and its potential habitability. Most informative are those minerals, such as clays or evaporites that deposit at or near the surface by interaction with atmosphere and water. Instruments onboard orbiting spacecraft and surface rovers have discovered the presence of sheet silicates, sulfates, and crystalline iron oxides. These minerals date to a very early period in the history of Mars, when water was more abundant. Furthermore, geologic mapping shows not only that some hydrated sheet silicates are much older than sulfates, but that the latter formed under markedly different geochemical environments. As the planet grew drier, new minerals formed under brinier, more acidic conditions, which imply a harsher environment for early life. The overall scarcity of carbonates was also a surprise, since CO2 is the dominant constituent of the martian atmosphere, carbonates generally precipitate from CO2 - H2O solutions, and evidence for aqueous alteration abounds. (Continues next month) Astro Gallery of Gems, now along Fifth Avenue, is to open a second location in a 1,200 square-foot-space on the ground floor of this six-story 1931 apartment building across from the American Museum of Natural History (102 West 79th Street). The gallery, which plans to to sell minerals, fossils and jewelry, as well as items for children there, and is to have a storage basement, has signed a 10-year lease and received a three-month rent concession for its build-out. Approximate annual rent: $171,000. 4 Bulletin of the New York Mineralogical Club, Inc. The Origins of a Geologist: From the Shores of Lake Michigan to the Halls of Oberlin College By Emilie Lozier My love affair with geology began early. Wandering the shores of Lake Michigan as children, my sisters and I would comb our fingers through the coarse sand grains. Occasionally one of us would straighten abruptly, squinting at whatever treasure our sifting hands had unearthed. Sea glass; shelly conglomerates; dull, rounded rocks that turned luminous colors when dunked in the surf. These objects were like precious gems to us, and we stuffed our pockets full to bursting. Years later I had amassed a respectable collection of rocks and minerals. With a backbone of lake stones from my summers of beach combing, it was fleshed out by a number of more “serious” specimens from my grandmother’s neighbor, Mitch. Whenever I would go to stay with my grandma in Manhattan, Mitch would invite me to look through his own considerable collection and choose a mineral to take home. Like many budding collectors, my choices were driven by an appreciation for distinctive shapes and colors. I chose hematite for its globular structure and metallic sheen, wavelite for its radial spray of pale green needles. Months later, I still found myself puzzling over their unique beauty. I wanted to understand the whole story, the series of mechanisms that could create minerals of such startling complexity. This curiosity has stuck with me. As a student at Oberlin College, I have stuffed my schedule full of geology courses, even while pursuing a major in chemistry. In my mind, this approach makes a lot of sense. With an ultimate goal of geochemical research, my foundation in chemistry must be unshakeable – and so I study chemistry. At the same time, it is the tantalizing mystery of the Earth’s processes that drives me to shore up my knowledge of the natural sciences – and so I study geology. In brief, while chemistry is my vehicle, geology is the furnace that keeps the wheels turning. Last summer, with one year at Oberlin tucked away in my pocket, I spent two months helping out in the Department of Earth and Planetary Sciences at the American Museum of Natural History. More specifically, I worked with Jamie Newman, who assists in the curation of the Mineral and Gems collection. Earlier in the year, Mitch had brought me to meet Jamie and get a peek at the collection. May 2016 Although I’d been to see AMNH’s Hall of Minerals many times before, I was completely floored when faced with the museum’s entire collection. Where before I had spent my time marveling at a mere 5,000 specimens, here, ranged in unassuming metal shelves and cabinets, over 100,000 individual minerals stood waiting to be wondered over. Later, my job would be to go through just a subset of this collection, drawer by drawer, removing each mineral from its box, lining it up with its label and catalog number, and snapping a photo to be uploaded to the online database. To some, this duty may seem monotonous, but to me it was a blast of energy, kindling in the fire of my curiosity. Here, I could hold in my hands the very objects of my passion. Every day I encountered new oddities to pique my interest: a carpet of dark, glittering azurites, a pale purple fluorite with a structure like a honeycomb, a septarian concretion all crisscrossed with cracks, and native copper entombed in a perfect, football-shaped crystal of calcite. Even the more humble minerals did not escape my attention, and in the end these were the ones that taught me the most. After handling countless examples of a single variety of mineral, I soon gained an instinctive – albeit rudimentary – feel for its typical hues, densities, and morphologies. One day, when photographing a drawer of calcites, I came across a mineral that provoked my suspicion the moment I picked it up. For its size, the specimen was much heavier than my hands-on understanding of calcites had led me to believe. Turning the mineral over in my hands I realized with a low thrill of excitement that its reverse side was coated with a thick layer of galena, a dense, leadcontaining mineral. Of all my experiences at the museum, moments like these were the ones that reminded me most dramatically of why it is I study the natural sciences. They brought me back to the days spent darting in and out of Lake Michigan waves, holding gleaming wet pebbles up to the sun and marveling at their gemlike colors. To the camping trips at Devil’s Lake State Park in Wisconsin spent puzzling over the ponderous quartzite cliffs. Like the first geologists, my curiosity was purely visceral, stemming from that which I saw and touched and tasted. Today, this sense of primitive wonder remains to me an invitation, and all the motivation I could ever need. What Causes A Volcanic Eruption? By Robin Andrews A team of volcanologists led by the University of Liverpool have released a perhaps controversial Nature study on the causes of volcanic eruptions. Going against the current consensus, they have suggested that it isn’t huge pressure differences that trigger volcanic blasts, but a strange behavior of magma called “frictional heating.” Volcanic eruptions, despite being studied for several thousands of years in one form or another, are still relatively poorly understood phenomena. Although volcanologists have attempted to categorize eruptions as best they can, observing their underlying physical processes is impossible, and can only be interpreted after the act. The arguable “holy grail” of volcanology is to determine why exactly an eruption, particularly an explosive one, occurs, in order to aid our ability to predict when the next one will happen. Volcanic eruptions are largely thought to occur when there is a huge pressure difference (or “gradient”) between the broiling May 2016 Bulletin of the New York Mineralogical Club, Inc. 5 magma within the chamber and the outside world. When this gradient becomes too large for the encasing rock to keep it in, it fractures, allowing the magma to violently decompress onto the surface. “A good analogy to this is peanut butter,” Lavallée said in a statement. “When it is too cold and viscous, we plunge a knife into it and stir to warm it up and make it runnier.” This “frictional heating” caused substantial temperature increases in the laboratory, which had several effects: Primarily, the formation of bubbles is easier when the magma is hotter, or more energetically excitable. The more fluid, less confining magma also permits the more efficient growth of bubbles. In addition, this temperature increase induced the melting of solid crystals within the magma, depositing a huge amount of chemical compounds into the molten phase of the magma. This so-called “supersaturation” causes a chemical imbalance within the magma, which releases these compounds as gassy bubbles in order to redress this. These findings, if corroborated by other independent studies, have the potential to rewrite a key component of volcanological science, potentially transforming how we determine when, and indeed how, the most dangerous volcanoes on Earth erupt. Source: iflscience.com from January 6, 2016 What causes the world's explosive volcanic eruptions, like the 1980s blast at Mount St. Helens, to occur? USGS The Race to Find Even More New Elements to Add to the Periodic Table This chamber pressure is largely controlled by the gas content of the magma, which itself is variably gloopy, or “viscous.” As the magma initially begins to decompress as it rises from the depths of the Earth, gas bubbles form from the magma in a process known as vesiculation, which increases the internal pressure of the magma chamber. The more viscous and gassy the magma is, the greater the pressure gradient will be, and the more explosive the subsequent eruption. By David Hinde In an event likely never to be repeated, four new superheavy elements were last week simultaneously added to the periodic table. To add four in one go is quite an achievement but the race to find more is ongoing. The expanding periodic table of elements. Shutterstock/Olivier Le Queinec Is temperature or pressure more important when it comes to triggering explosive eruptions? Credit: mik ulyannikov / Shutterstock This new study, led by Yan Lavallée, professor of volcanology at the University of Liverpool, has concluded that temperature, not pressure, is the controlling mechanism for vesiculation. Laboratory experiments were set up to melt various types of igneous rocks in various ways. The team looked carefully at how each melting technique produced varying degrees of vesiculation, comparing their results with fieldwork on Santiaguito volcano. Their experiments show that magma and partially molten rocks moving up through a tube or “conduit” heat up as they do so. This temperature increase is caused by the “drag” of the magma against both the walls of the conduit and the internal currents within the magma itself. Back in 2012, the International Unions of Pure and Applied Chemistry (IUPAC) and Pure and Applied Physics (IUPAP) tasked five independent scientists to assess claims made for the discovery of elements 113, 115, 117 and 118. The measurements had been made at Nuclear Physics Accelerator laboratories in Russia (Dubna) and Japan (RIKEN) between 2004 and 2012. Late last year, on December 30, 2015, IUPAC announced that claims for the discovery of all four new elements had been accepted. This completes the seventh row of the periodic table, and means that all elements between hydrogen (having only one proton in its nucleus) and element 118 (having 118 protons) are now officially discovered. After the excitement of the discovery, the scientists now have the naming rights. The Japanese team will suggest the name for element 113. The joint Russian/US teams will make suggestions for elements 115, 117 and 118. These names will be 6 Bulletin of the New York Mineralogical Club, Inc. assessed by IUPAC, and once approved, will become the new names that scientists and students will have to remember. May 2016 The payback from the discovery of these new elements comes in improving models of the atomic nucleus (with applications in nuclear medicine and in element formation in the universe) and testing our understanding of atomic relativistic effects (of increasing importance in the chemical properties of the heavy elements). It also helps in improving our understanding of complex and irreversible interactions of quantum systems in general. The Australian Connection The completed seventh row in the periodic table. Wikimedia Commons Until their discovery and naming, all superheavy elements (up to 999!) have been assigned temporary names by the IUPAC. Element 113 is known as ununtrium (Uut), 115 is ununpentium (Uup), 117 is ununseptium (Uus) and 118 ununoctium (Uuo). These names are not actually used by physicists, who instead refer to them as “element 118", for example. The Superheavy Elements Elements heavier than Rutherfordium (element 104) are referred to as superheavy. They are not found in nature, because they undergo radioactive decay to lighter elements. Those superheavy nuclei that have been created artificially have decay lifetimes between nanoseconds and minutes. But longer-lived (more neutron-rich) superheavy nuclei are expected to be situated at the centre of the so-called “island of stability”, a place where neutron-rich nuclei with extremely long half-lives should exist. Currently, the isotopes of new elements that have been discovered are on the “shore” of this island, since we cannot yet reach the centre. How Were These New Elements Created On Earth? Atoms of superheavy elements are made by nuclear fusion. Imagine touching two droplets of water – they will “snap together” because of surface tension to form a combined larger droplet. The problem in the fusion of heavy nuclei is the large numbers of protons in both nuclei. This creates an intense repulsive electric field. A heavy-ion accelerator must be used to overcome this repulsion, by colliding the two nuclei and allowing the nuclear surfaces to touch. This is not sufficient, as the two touching spheroidal nuclei must change their shape to form a compact single droplet of nuclear matter – the superheavy nucleus. It turns out that this only happens in a few “lucky” collisions, as few as one in a million. There is yet another hurdle; the superheavy nucleus is very likely to decay almost immediately by fission. Again, as few as one in a million survives to become a superheavy atom, identified by its unique radioactive decay. The process of superheavy element creation and identification thus requires large-scale accelerator facilities, sophisticated magnetic separators, efficient detectors and time. Finding the three atoms of element 113 in Japan took 10 years, and that was after the experimental equipment had been developed. The race is now on to produce elements 119 and 120. The projectile nucleus Calcium-48 (Ca-48) – successfully used to form the newly accepted elements – has too few protons, and no target nuclei with more protons are currently available. The question is, which heavier projectile nucleus is the best to use. To investigate this, the leader and team members of the German superheavy element research group, based in Darmstadt and Mainz, recently travelled to the Australian National University. They made use of unique ANU experimental capabilities, supported by the Australian Government’s NCRIS program, to measure fission characteristics for several nuclear reactions forming element 120. The results will guide future experiments in Germany to form the new superheavy elements. It seems certain that by using similar nuclear fusion reactions, proceeding beyond element 118 will be more difficult than reaching it. But that was the feeling after the discovery of element 112, first observed in 1996. And yet a new approach using Ca-48 projectiles allowed another six elements to be discovered. Nuclear physicists are already exploring different types of nuclear reaction to produce superheavies, and some promising results have already been achieved. Nevertheless, it would need a huge breakthrough to see four new nuclei added to the periodic table at once, as we have just seen. Source: iflscience.com from January 5, 2016 36,000 Year Old Cave Art Shows Ancient Volcanic Eruption By Robin Andrews The Chauvet cave system has its own high-resolution replica. Getty Volcanology is a fairly ancient science, with descriptions of dramatic eruptions going back at least as far as the year 79 C.E., when Pliny the Elder sailed into the pyroclastic flows emerging from Vesuvius and his heir detailed the unfolding destruction. Now, a study in PLOS ONE has described what may be the May 2016 Bulletin of the New York Mineralogical Club, Inc. earliest known images of erupting volcanoes. These paintings, found in the Chauvet caves of France, are at least 36,000 years old. This particular cave system was found to contain a series of paintings in 1994. Among them were menageries of animals – a common theme in ancient cave paintings. Examples of human handprints were also found there. However, some of the artwork was at the time too abstract to be properly identified. Nearby, a new geological survey was conducted in the Bas-Vivarais area, which aimed to look at the geological evolution of the area between 30,000 and 40,000 years ago. This coincides with the period of time wherein the Chauvet cave system was occupied by humans. During this time, the geological survey revealed that 35 kilometers (22 miles) away from the cave system, a major volcanic eruption took place in the Vivarais volcanic field, a series of volcanoes spread over 500 square kilometers (193 square miles). This research team, using geological mapping and isotopic dating, managed to provide the most accurate timings and precise eruption characteristics of the volcanic activity of Vivarais to date. They note that the activity ranges from the calm and effusive (lava flows, for example) to the iridescent and violent, with buried water and magma interacting explosively to form volcanoes known as maar volcanoes. The map of the Chauvet cave system (A), the general view of the “Megaloceros panel” (B), and the detail of the spray-like paintings (C). Nomade et al./PLOS ONE Indeed, carbon dating techniques show that the nearby Chauvet cave paintings were created during this time. The later phases of painting focused around an extinct, deer-like creature called a Megaloceros. Painted using a red pigment, perhaps traced with fingers, these Megaloceros appear to have a spray-like feature emerging from their heads. These spray shapes are unique among over 340 ornate cave painting sites in France and Spain, which made their identification problematic for a long time. The authors of this study suggest that they appear to resemble the typical lava fountains reminiscent of Strombolian eruptions, gas slug-induced volcanic explosions. Sebastien Nomade, lead author of the study, told IFLScience: “We noticed that the shape is reminiscent of lava fountains that a young kid could draw.” Although it is impossible to be certain, the authors are cautiously confident of their discovery, noting that the strength of the eruptions could have meant that the original artists likely felt compelled to paint them. Previously, volcanic imagery was found in Catalhoyuk in central Turkey, and dated to be at least 8,000 years old. The 7 Chauvet cave paintings predate this Turkish example by around 28,000 years, and if the Vivarais eruption theory is accepted by the scientific community, its depiction in volcanic art will be the oldest in human history to date. Source: iflscience.com from January 11, 2016 Teach Kids Chemistry with this Homemade Periodic Table Battleship Game By Tom Hale If you teach or have kids of your own, here’s a great way to get them into chemistry. On the homeschooling blog Teach Beside Me, Karyn Tripp shows how to create a Battleship-esque game with a periodic table. All you need to do is print out four periodic tables, which you can easily find on Google Images. Along the left side, you then label the rows alphabetically from a to i. You then set up the a battlestation using two folders facing back-to-back and attached by a paper clip at the top. You can also laminate the sheets to make the game reusable. As Tripp explains on the blog, “The kids can then mark where they want to place their ships by circling rows of 2, 3, 4, and 5 elements on the lower table. They play by calling out coordinates. If they miss they put an X on the spot they chose on the upper table. If they get a hit, they circle it.” After learning to play in this way, you can then use more advanced ways to find the opponent's “battleships,” such as using an element’s atomic number or mass number. You can also make a rule that a “ship” has to be in each group, i.e. one in the noble gases, one in transition metals, etc. Source: iflscience.com from January 14, 2016 Niagara Falls: New York State Park System to Present Plans to ‘Dewater’ American Side of Falls Following a public hearing, the dewatering is expected to occur within three years to replace 115-year-old bridges accessing Goat Island. The falls were first dewatered in 1969 for an erosion study. 8 Bulletin of the New York Mineralogical Club, Inc. May 2016 Collector’s Series – “The 100" The 100 is a monthly feature of interest to mineral collectors written by Bill Shelton, based upon his many years of experience as a mineral collector, educator, author, appraiser, philanthropist and dealer. Comments as well as suggestions for new topics are most welcome. Contact him at [email protected]. Black is Back I would also like to inform serious collectors that some recent samples from Russia have excellent luster and a minimum This curious group of black minerals shares a common of coating present. Such a piece would be prized by many status regarding fluorescence and gemstones - there is nothing to collectors. In addition to Dalnegorsk, the say regarding either! Uranium, the former Soviet Union has other places that element, has a bearing on fluorescence might produce a fine specimen – here I but it is unrelated to the species uraninite. include Rudnyi, Kazakhstan, Uzbekistan Byproducts of course are a different and Ukraine according to the World of matter. Stones magazine. If you like a specimen Stibnite, a popular species for with multiple species present, you will collectors, can have well-formed crystals find quite a few possibilities here ranging that occasionally reach 20 inches or so. from gangue minerals to other potentially Normal specimens and most of those valuable species. At times, the silver known to exist are modest sized singles or content in tetrahedrite is concentrated clusters to a few inches or less. The recent enough to make it a possible ore species influx of Chinese pieces allows an for copper and silver. opportunity for anyone with most any size Uraninite is perhaps best known as a budget to get single crystals or even Stibnite from Nevada source of uranium and probably groups. Prices seem remarkably considered in some circles as dangerous reasonable now that we have a large due to radioactivity. Secondary species supply. Prior to this, a few places had and traces of the uranyl radical are noted samples – France, Japan, Nevada and with bright colors, fluorescence and, Romania are exemplary. They tend to be sometimes, high levels of radioactivity. sparsely represented in dealer stock and This is much less applicable to uraninite. many of these pieces will be expensive. Species such as cuprosklodowskite, Long ago, Sinkankas (1964) said betafite and autunite may actually be “Probably the acquisition of a fine group more radioactive than uraninite. When of Japanese stibnite crystals is to an crystals are found, the price will probably amateur mineralogist an attainment equal be moderate and the quality variable. to an art patron’s acquisition of an old Among some of the samples I have seen, master.” The best pieces are silvery to those from Standpipe Hill, Maine are gray and may be iridescent so some, at most often noted to exhibit high quality. least, are not really black in appearance. I Tetrahedrite from Peru Generally, they are thumbnail sized and can’t imagine a collector not considering have little or no matrix present. Other this as a good addition to their suite. sources in America include several Tetrahedrite is a very interesting pegmatites in Connecticut, North Carolina, species – many elements can enter the Arizona, Colorado, New Mexico and Utah. structure including bismuth, silver and See mindat.org for a very long list of zinc. Arsenic can be present and when known places. Worldwide, Canada, enough is there, the species is properly Congo, England and South Africa are labeled as tennantite. A complete solid notable sources. Pitchblende is a massive, solution series is evidently known to exist. sometimes impure uraninite that may be The massive material may prove to be a bit available but will likely be unattractive. If elusive to identify but crystals are more you decide to own a crystal, say thumbnail readily recognized. It is common for sized, I believe the relative danger to you chalcopyrite to encompass the entire is minute. Perhaps you will be able to crystal and that means an error in identity source one from lesser known and might occur. Fifty years ago, a one inch available places such as Norway. crystal was considered impressive. Not As a group, they may be long ago, I was fortunate to find a two inch underappreciated in the collector beauty from Dalnegorsk, Russia. But don’t community. Black is not the most be overly impressed – the Handbook Uraninite from Maine endearing quality for fancy collection suggests crystals exist more on the order of pieces anyway. Mindat.org reports 2,833 localities for stibnite, six inches in length today. 1,866 for tetrahedrite and 2,503 for uraninite. Does this come as a surprise to you? May 2016 Bulletin of the New York Mineralogical Club, Inc. 9 Topics in Gemology Topics in Gemology is a monthly column written by Diana Jarrett, GG, RMV, based on gemological questions posed to her over the years by beginners and experts alike. Contact her at [email protected]. All the Subtleties of Time knowledgeable personnel, Sarkissian believes. “Service replaces all the discounts in the world. These professionals will follow you Recently, the Washington Post published a report about a shift on your collecting journey whether you own one or 50 in paradigm with ultra-luxe consumers who at one time only timepieces.” sported highly visible status-con labels. Now, they are regarded as Dizzying Details “a little trashy” shoppers were quoted as saying. Instead, the story Limited edition watches fascinate collectors who understand goes, consumers eschew logo-stamped products plastered with their discreet complications. DEVON timepieces deliver a names like Van Cleef & Arpels, Prada, Gucci or Luis Vuitton. patented system known as interwoven Time Belts™. The No Attention Please Ressence, with liquid under its crystal has no crown stem My, how things have changed. In the world of luxury to wind. Instead, the functions happen on the reverse of the goods, manufacturers may have relied wholly on name case. Laurent Ferrier is the only brand offering a double recognition to push their brand to the fore. Status minded spiral tourbillon for enhanced security and accuracy. Both consumers happily participated in prominently flaunting of these brands are produced in very small editions of logos believing it added a certain snob-value to their own between 50 to 100 pieces annually. Girard Perregaux identity. But the recent disinterest toward blatant self Chrono Hawk Hollywoodland pays homage to its promotion visible on couture goods has already been namesake while boasting self-winding manufactured observed with the serious timepiece crowd. calibre with visible oscillating weight. Roger Dubouis’s Knowledgeable, cultivated and affluent, the last thing skeleton tourbillon exhibits dynamic depth of field. savvy watch collectors want is attention focused on Parmigiani Fleurier’s 21 house calibres are the basis of themselves. They are the rare watch connoisseur. the brand’s success today. Bonafide rare timepieces are those of the highest “The coolest development in visual complications manufacture and artistic merit, with discreet complications, Parmigiani Fleurier comes from the guys at Ressence working on a novel way often advanced technology, and crafted in limited editions. to display time,” Sarkissian informs. “Their elegant, extremely People have been interested in knowing what time it is eons. comfortable case houses a beautiful, original and complicated The earliest form of timekeeping was a sundial created in Egypt mechanism presenting time in a completely new way with no around 1450 BC. By the mid 16th century, countless expert crown. The time rotates around the dial 360° while being very watchmakers were busy in Switzerland. The phrase Swiss-made legible.” Top watchmakers are returning to core values of watch still denotes a fine timekeeping instrument. But inexpensive craftsmanship with some inner improvements. “Laurent Ferrier battery-operated fashion watches have become so cheap that people demonstrates that principal,” he says. often toss their watch when its battery goes kaput. Mostly Manly It’s Complicated Each manufacturer’s creations are distinct, but the appeal Still a robust market exists for haute horology sending prices seems skewed towards the male sensibility. “Rare watches are soaring into the six figures. That’s because rare watches have mainly a male thing”, Sarkissian discovered. “Laurent Ferrier complications that enthrall both novice and seasoned collector. An developed the Galet Micro-Rotor with natural escapement in a advanced albeit discreet technology is also a potent draw for lady’s model. The response in the US to the lady’s version has aficionados. But not every fan can play the game. Only those with been lukewarm whereas the man’s model is in great demand. This deep resources make the leap from admirer to high watch collector. trend is shared by just about all brands.” The majority of female Watch expert Andrew Block understands haute-horology and high-end collectors prefer quartz, brand recognition, plus an its dedicated enthusiasts. He draws on 30 years experience in association with couture jewelry. Block concurs. “Women focus luxury brand management as president of California-based Stephen on fashion and style. Women truly understand the entire concept Silver Boutique where he curates a collection of rare watches. “It’s of accessorizing – collecting watches for women goes beyond not an inexpensive passion, but a rewarding one that develops over artistry.” time,” Block finds. “We’re talking about the finest examples of What Next? craftsmanship and art. Once you develop a passion for any art, you What territory remains unconquered for these timekeepers? never loose it. With fine timepieces, the highest forms of watch “It may not be limited to the number of functions per watch,” making are true works of art.” Block considers, “but rather an innovative combining of Today’s discerning collector appreciates cutting-edge complications never seen before. It may be utilizing new materials technology inherent to luxury timepieces, especially when they in combination with new technology. Smart watches are the next themselves are in a related field. Discreet complications resonate frontier to remain a relevant category for a younger demographic with venture capitalists and tech-culture scions. Extraordinarily of luxury consumer.” wealthy, they have no intention of flaunting it, however. The owner is usually the only one who knows how the watch performs. Authority Alexis Sarkissian, CEO, Totally Worth It, has tracked the evolution of rare watches on a global scale. Even first time collectors are an educated set, he says. “More and more novices enter the world of haute horlogerie. In the US especially, consumers educate themselves via the internet’s multiple outlets. My favorite resources are still great salespeople with the passion DEVON Ressence Type 3 and faith to share their craft.” One cannot overstate the value of 10 Bulletin of the New York Mineralogical Club, Inc. May 2016 2016 Members of the New York Mineralogical Club, Inc. Toni Akhibi, Abuja, Nigeria Alicja Andrejczuk, Scarsdale, NY Scott Arsham, New York, NY Carol Bailey, Flushing, NY Linda Barrett, New York, NY Charlotte & Lawrence Bassett, Thornwood, NY Diane Beckman, New York, NY Lorraine Bege, New York, NY Russell Behnke, Meriden, CT Raissa & Dr. Garrett Bennett, New York, NY Ted Berkowitz, New York, NY Philip Betancourt, Moorestown, NJ John Betts, New York, NY Mark Lowenthal & Gail Billig, Englewood, NJ Michael Davis & Alberto Bird, Bronx, NY Richard Blackman, Randolph, NJ Andrew C. Blume & Family, New York, NY Fran Radbell Bolinder, Tuckahoe, NY Richard Bostwick, New York, NY Pauletta Brooks, New York, NY Alan Bronstein, Livingston, NJ Mrs. Dale L. Brown, Bronx, NY Kevan & Claudia Brown, New York, NY Louis J. Brown, Bronx, NY Otis Kidwell Burger, New York, NY Eugene Carmichael, Kew Gardens, NY Elaine Casani, Bohemia, NY Andrew Chait & Family, New York, NY Neil Chalfin, Englewood, NJ Atilio Ciucci, Yonkers, NY Bill Cotrofeld, East Arlington, VT Catherine Corwin & Family, Brooklyn, NY Lillian Cozzarelli, Brooklyn, NY Bob Cullen, Mamaroneck, NY Richard Currier, New York, NY Ralph Dames, Kearny, NJ Joan Daniel, New York, NY Ann Darby, Elmhurst, NY Joan Deignan, Bronx, NY Nick Del Re, Brooklyn, NY Donna Dempsey, New York, NY Christine Domino, Woodside, NY Joshua Dudley, Montclair, NJ Tina Di, Flushing, NY Alissa Duffy, Blairstown, NJ Kevin & DG Duffy, Sunnyside, NY Ray Eginton, Springfield Gardens, NY Philip Elenko, New York, NY Duane Farabaugh, Forest Hills, NY Robert & Estée Fraser, Dupont, WA Sam Gelman, Woodside, NY Gary Golden & Family, Brooklyn, NY Olga González, New York, NY Vivien Gornitz, New York, NY Joel & SusAnna Bernard- Grae, New York, NY Fran Greder, Belleville, NJ Richard Greene, Bronx, NY Raymond Hakimi, Great Neck, NY Dr. Daniel Hall, Columbus, OH Dr. George Harlow, New York, NY Parvin Hartramph, New York, NY Richard Hauck, Franklin, NJ Jeffrey Hayward, Staten Island, NY Tema Hecht, New York, NY Will Heierman, Stafford, TX Howard Heitner, Tuckahoe, NY Erica Hirsch, Ocean Grove, NJ Pablo Hoffman, New York, NY Sidney Horenstein, New York, NY Irving Horowitz, Floral Park, NY Gail Jaffe, New York, NY Diana Jarrett, University Park, FL Rudolph B. Jones, Fayetteville, NC Arlene Joseph, New Milford, NJ Tracy Jukes, Narberth, UK Robert Karlovits, Staten Island, NY Jacob & Ruth Kaufman, New York, NY Michael & Robin Kessler, East Stroudsburg, PA Victor & Margaret Krasan, Jamaica, NY Saul Krotki, Seattle, WA Patricia Dolan & Mark Kucera, Yonkers, NY Alexandra Krummenacker, Glen Cove, NY Matthew Langlois, New York, NY Paul Vitaris & Lee Laurie, New York, NY Delores Lawton, Brooklyn, NY Delphine Leblanc, Hoboken, NJ Barbara Brewka & James Lee, Bronxville, NY Gail Brett Levine, Rego Park, NY Florence Levy, New York, NY The Litvin Family, Englewood, NJ Eduardo Lopez, New York, NY Richard & Marion Lopus, Hicksville, NY Immacula Louisime, Jamaica, NY Donna M. Luisi, Middle Village, NY Robert J. Martinchek, Newington, CT Andrew Mason, Briarcliff Manor, NY Sydney Mazur, New York, NY Dr. Charles Merguerian, Stone Ridge, NY Stephen Milne, New York, NY William Mirabello, Staten Island, NY Miriam Mopper, Forest Hills, NY Robbin C. 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Schneirla, New York, NY Anna Schumate, New York, NY Ronnee Medow Segal, New York, NY Jack Segall, Cedarhurst, NY Charles & Ruth Severson, Gwynedd, PA William Shelton, Tucson, AZ Michael Silver, Los Angeles, CA Helen Skrobut, Brooklyn, NY Candie Smith, Staten Island, NY Charles Snider, New York, NY Alma Barkey Sohmer, New York, NY Paul & Jeannine Speranza, North Bellmore, NY Atida Stein, New York, NY Robin Sternberg, New York, NY Steven B. & Max Stieglitz, New York, NY Matt & Abbey Stolle, New York, NY Kacper Szarejko, Ridgewood, NY Linda Ultee, New York, NY Ann Vitiello, Brooklyn, NY Sam M. Waldman, Brooklyn, NY Jessica Wasserman, New York, NY Lenore Weber, New York, NY Jeffrey P. Wiegand, New Rochelle, NY Susana Wilches, New York, NY Robin Wildes, New York, NY Leonid Zakinov, Forest Hills, NY Vanessa Zannis, New York, NY Theodore Zirnite, New York, NY Anne Marie Zumer, Wantagh, NY May 2016 Bulletin of the New York Mineralogical Club, Inc. New Climate Measuring Technique Uses Gravel Coating Like Tree Rings By Stephen Luntz 11 unlikely reservoir given how ‘messy’ most people think it is there is a mineral that accumulates steadily and creates some of the most detailed information to date on the Earth’s past climates,” Amundson said in a statement. A new technique, if verified, could transform our capacity to understand ancient climates, arming us with far more detailed knowledge of what to expect in a warming world. The method uses carbonate deposits between soil and gravel detritus in arid and semi-arid zones. These are laid down like tree rings, allowing us to learn about the climatic conditions at the time. During a minor ice age a persistant high pressure system over the Canadian ice sheet reversed the dominant pattern of North American precipitation, bringing stronger rain bearing winds from the Gulf of Mexico during summer, and possibly suppressing winter snows from the Pacific. Erik Oerter The carbonate layers of this 3 millimeter sample are like tree rings, but laid down over tens of thousands of years. Credit Oerter et al/PNAS Paleoclimatology, the study of climates before we had widespread thermometers, has been hampered by a shortage of suitable proxy measures. Some tree species store indications of the conditions as they grew in their growth rings. Similarly stalactites, stalagmites, and lake sediments can provide an insight into the local environment when they were laid down. All have their limitations however. The further you go back the less likely it is that there will be tree or coral records, and other measurements tend to be geographically restricted. We have only the vaguest knowledge of the climate over huge areas of the world at crucial points in time. Professor Ronald Amundson of the University of California, Berkeley has published a new method in the Proceedings of the National Academy of Sciences, and used it to chart the temperature and rainfall of Wyoming’s Wind River Basin over the last 120,000 years. Amundson’s technique relies on carbonate layers on the bottom of alluvial gravel debris. These deposits, known as pedothems, are far thinner than tree rings, and consequently give far poorer resolution. Instead of being able to tell what a single year was like, they give an average over a thousand years. “The cool thing that this study reveals is that within soil - an Amundson and his PhD Student Erik Oerter used laser ablation to collect microscopic samples from pedothems. “It is evident that the carbonate coatings formed in concentric bands around the rocks, much like the annual growth rings in a tree, except that these laminations form over timescales of several hundred years,” Oerter said. The ratio of Uranium-234 to Uranium-238 indicates the age of the pedothem, while carbon and oxygen isotopic ratios provide an indication of temperature and rainfall at the time Moreover, plants preferentially remove carbon-13, so lower levels left in the soil are indicative of higher levels of plant productivity, indicating better growing conditions. This analysis revealed oxygen-18 levels spiked coinciding with a “previously hypothesized” period between 55,000 and 70,000 years ago. This has been explained as warm winds bringing summer rain from the Gulf of Mexico replacing winter snows from the Pacific. The minor ice age conditions at the time were very different from anything likely to occur soon. However, Oerter said, “The techniques that we developed can now be applied to similar soil deposits to fill in key gaps in the paleoclimate record,” including local effects of past climatic conditions most similar to the greenhouse effect we anticipate. Source: Iflscience.com from January 13, 2016 Snowball Earth Triggered Underwater Volcanoes? by Explosive By Stuart Gary Extensive underwater volcanism caused by the breakup of an ancient supercontinent may have pushed the Earth into a period of extreme freezing 750 million years ago, according to a new study. The research, reported in the journal Nature Geoscience, may also help explain how animal life began on Earth millions of years later, scientists said. “A Snowball Earth is an extreme event and the planet almost didn’t get out of it,” one of the study’s authors Professor Eelco Rohling, of the Australian National University, said. 12 Bulletin of the New York Mineralogical Club, Inc. “Our hypothesis provides a single mechanism that explains several different aspects of the Snowball Earth state.” According to the Snowball Earth hypothesis, most or all of Earth was covered in ice sheets at least once in the planet’s history, but it is not clear what caused this extreme glaciation. It had been widely thought that the run-off from rivers into the ocean caused by the break-up of the vast supercontinent Rodinia changed the chemistry of the ocean, reducing the amount of carbon-dioxide (CO 2) in the atmosphere, which in turn increased global ice coverage. The vast ice sheets covering the continents reflected sunlight away from the Earth, further cooling the planet. “That kicks the world through a tipping point into a snowball state where the oceans start to freeze over as well,” Professor Rohling said. Key Facts: Volcanic chemicals released in eruptions saturate oceans, removing carbon-dioxide from atmosphere and cooling the planet Chemicals leached from glassy volcanic rock formed sediment on the sea floor The chemicals may also explain high levels of phosphorus in oceans thought to be catalyst for origin of animal life “Our hypothesis provides a single mechanism that explains several different aspects of the Snowball Earth state.” According to the Snowball Earth hypothesis, most or all of Earth was covered in ice sheets at least once in the planet’s history, but it is not clear what caused this extreme glaciation. It had been widely thought that the run-off from rivers into the ocean caused by the break-up of the vast supercontinent Rodinia changed the chemistry of the ocean, reducing the amount of carbon-dioxide (CO 2) in the atmosphere, which in turn increased global ice coverage. The vast ice sheets covering the continents reflected sunlight away from the Earth, further cooling the planet. May 2016 “That kicks the world through a tipping point into a snowball state where the oceans start to freeze over as well,” Professor Rohling said. “Our hypothesis provides a single mechanism that explains several different aspects of the Snowball Earth state.” Professor Eelco Rohling “The sea ice forms because of the large scale glaciation on land.” The Earth stayed locked in this state for millions of years. “Eventually land-based volcanism pumps so much CO 2 into the atmosphere that it pushes the planet out of the Snowball Earth phase,” Professor Rohling said. But the existing hypothesis does not explain how thick deposits of carbonate rock such as limestone — known as cap carbonates — were laid down as the Earth warmed. Volcanoes Altered Ocean Chemistry Simulations by Professor Rohling and colleagues indicated the breakup of the Rodinia supercontinent may have released huge volumes of volcanic chemicals that saturated the oceans and drew CO 2 out of the atmosphere cooling the planet. As the supercontinent Rodinia started to break up, extensive shallow marine volcanic activity produced large amounts of glassy volcanic rock, called hyaloclastite, that readily break down releasing large amounts of chemicals into the ocean. “In the past the big question has been: how could large continental weathering deposit so much mineral into the oceans if the land is covered in icesheets,” Professor Rohling said. “The hyaloclastite eruptions do that — turning the ocean very rich in calcium, magnesium, silicon and phosphorus.” Eventually when the Earth warmed and the ice broke apart, light penetrated the oceans allowing algal life to pick up again and undertake photosynthesis. “The phosphorus [leached from the hyaloclastite minerals] is a nutrient generating huge algal blooms which fix carbon and release oxygen, essential for the development of animal life,” Professor Rohling said. Source: ABC Science Posted January 19, 2016 May 2016 Bulletin of the New York Mineralogical Club, Inc. Lawrence H. Conklin passed away on February 7, 2016. He was a NYMC member, collector, art lover, author, advisor and aesthete. For many decades he was America’s premier mineral dealer. In September of 1994 he was overwhelmingly elected an honorary member of the New York Mineralogical Club. I reprint this engaging article in his memory. – Mitch The World’s Finest Mineral Specimen 13 I had made my best shot at getting them to send the piece to Central Park West, and, it fell, apparently, on deaf ears. Then I did it. I made them an offer they couldn’t refuse. (I love to quote from the “Godfather”) I actually found myself saying that I would forego my substantial appraisal fee if the azurite journeyed westward across town instead of down south and, to my happy surprise, they promptly agreed. By Lawrence H. Conklin Dedicated in Memory of Jay Lininger (1939-2004), Devoted Collector of the Mineral Specimens of Pennsylvania. What is the finest mineral specimen in the world? In my mind there is no question that it is the “Newmont azurite” at the American Museum of Natural History in New York City. Judgments like this are, of course, subjective but there is no question that in my 65 years of examining fine minerals and 50 years of buying and selling them that this is the best. This great piece was found at Tsumeb, South West Africa (now Tsumeb, Namibia) in 1952. It is said that the worker who recovered it, used the piece to pay an overdue bar bill and that it sat in the barroom, properly appreciated for the treasure it was, until the mine boss at that time, Charlie Stott, reclaimed it for the Newmont Mining Company. My personal connection to this specimen goes back to the Winter of 1976-77 when Paul E. Desautels (1920-1991), who was the curator of minerals at the Smithsonian Institution at that time, came to New York for the specific purpose of garnering that great trophy for the collection in Washington, and I was called upon to appraise it. I already had a pleasant and longtime relationship with the Newmont people and other members of the Copper Council. Upon hearing the shocking news that this great piece might escape, I panicked. “This azurite,” I pleaded to the company’s board, “should never leave New York.” I pointed out to them that they had such a fine, long-term relationship with the “American Museum,” and that now was surely not the time to break it. They reminded me that, after all, Desautels would be adding the azurite to “the nation’s collection” and they liked that concept. I am sure that Paul had done his usual great job of public relations. I then told them my tentative evaluation of the specimen, they approved of it, and even approved of my fee which was quite high. I got nowhere, however, in my further attempts to change the ultimate fate of that azurite. Then I made another pitch for them to “throw in” to the deal the magnificent “Newmont gold” an old-timer from Grass Valley, California and they said yes to that suggestion, too. I do not know of a California gold specimen that I like more than this one. On January 13, 1977 I typed and delivered my appraisal of that azurite and described it, simply, as follows: “Azurite, Tsumeb, Southwest Africa. A group of huge magnificent crystals on matrix. 12x12x5 inches. $250,000.00.” At the same time I appraised the Newmont gold, an amazing mass of superb flattened, octahedral crystals with no matrix, of 7x4-1/2x2 inches, for the same price. I heard nothing more of the matter until I was made aware of a negatively-oriented article that appeared in the May, 1980 issue of Jewelers’ Circular-Keystone. I wondered why a jewelry magazine became interested in the story of an appraisal and donation of a mineral specimen, or even how they became aware of it. Nonetheless they published a full-page article about it, with a good color photograph of the specimen, entitled: “The Newmont azurite: As priceless as Mona Lisa?” Of course the article was, in my opinion, nothing more than a “hatchet-job.” To begin, how could any reasonably knowledgeable staff of reporters and editors think that the Mona Lisa was worth only $250,000 in 1980? My sources tell me that $5,000,000 would have been a better guess; and they got many of the facts in the story completely wrong, too. The article quoted my dear, longtime friends, Dave Wilber and Charlie Key as saying my appraised value was too high. Dave got bogged down, as usual, in an invidious comparison with a specimen that he had recently sold and stated that it was finer than the azurite. I did not agree at that time with Dave’s estimation and I still do not agree. The superb phosphophyllite that he sold is surely a wonderful specimen but the main crystal, it must be remembered, needed to be reglued to its rock matrix. Charlie was a little more generous when he explained: “To some extent you’re appraising in a vacuum on a piece like this.” Indeed, appraising the “unique object,” mineral specimen or whatever is, to say the least, quite challenging. 14 Bulletin of the New York Mineralogical Club, Inc. That the museum staff loves the azurite is shown by the fact that it is the only mineral specimen discussed and illustrated on their web site. A rather poor picture and a simple description can be seen at— http://www.amnh.org/exhibitions/expeditions/treasure_fossil/Tre asures/Newmont_Azurite/newmont.html?50. Happily, the Newmont azurite is on everyday display at the museum but in my opinion the lighting of it could be greatly improved. The specimen appears almost black in color and it is not; it is a fine, deep blue. If you agree with my choice for the world’s finest mineral specimen or perhaps, more importantly, if you disagree, I should certainly welcome your comments. Newmont Mining Company deserves much thanks for their generous gifts to the museum. I thank Jamie Newman of the Earth & Planetary Sciences Department at the museum for all her help and encouragement and special thanks to Dr. George E. Harlow. Photographs courtesy of the American Museum of Natural History. Massive Blue Star Sapphire Mined in Sri Lanka Gemologists in Sri Lanka claim that the largest blue star sapphire yet has been discovered in a mine in the country. The gemology institute in the capital Colombo has certified that the gem weighs 1404.49 carats and say they have not certified anything larger. The gem is valued at at least $100m and the current owner estimates that it could sell for up to $175m at auction. Sri Lanka’s gem industry, for which sapphire is the main export, is worth at least £70m ($103m) annually. Blue star sapphires are so named because of the distinctive mark found at their center. “The moment I saw it, I decided to buy,” the current owner, who wishes to remain anonymous, told the BBC World Service’s Newsday program. “When the stone was brought to me I suspected that it might be the world’s largest blue star sapphire. So I took a risk and bought it.” The owner said it was “absolutely confidential” how much he paid for it. The previous record holder weighed 1,395 carats. The new gem was mined in the city of Ratnapura, in southern Sri Lanka, which is known as the City of Gems. It has been named The Star of Adam by its current owner, after a Muslim belief that Adam arrived in Sri Lanka after being sent away from the Garden of Eden. It is claimed he then lived on the slopes of a mountain now known as Adam’s Peak. The owner of the Star of Adam said he bought it thinking “this was not a piece of jewelry but an exhibition piece”. Speaking to the BBC, Armil Samoon, a leading gem and jewelry dealer in Sri Lanka, confirmed this was the largest blue star sapphire in the world. May 2016 A 17kg (37.5 pounds) rock containing sapphires was revealed in 2013, but the final weight of the gems inside is not yet known. Sri Lanka’s Gem and Jewellery Association said in 2011 that the engagement ring for Catherine Middleton, the Duchess of Cambridge, included a sapphire mined in the country in the 1970s. It was previously owned by Diana, Princess of Wales. Super-Low Density Ice Proposed By Stephen Luntz Researchers have raised the possibility of a new form of ice, one that would break the record set two years ago for low-density solid water. Anyone with access to refrigeration is familiar with one form of frozen water, and walking outside in winter at high latitudes or altitudes introduces us to another. We might expect the possible ways to turn The structure of the water dihydrogen monoxide into a solid ends molecules in the proposed new there, but the flexibility of the phase of ice. hydrogen bonds in water have allowed the creation of 17 crystalline phases of water. Now researchers think they have designed another. Two years ago a French-German collaboration produced ice XVI, the least dense form of ice known. However, scientists are always keen to break a record, and now Professor Xiao Cheng Zeng of the University of Nebraska, Lincoln has theorized a form that would have a density of just 0.6 grams per centimeter cubed, 25 percent lighter than ice XVI. “We performed a lot of calculations (focused on) whether this is not just a low-density ice, but perhaps the lowest-density ice to date,” said Zeng in a statement. “A lot of people are interested in predicting a new ice structure beyond the state of the art.” Zeng is the inventor of “Nebraska Ice”, a form that contracts when frozen, rather than expanding. Icebergs made of Nebraska Ice would sink to the bottom of the ocean, rather than float, which would have been good news for the Titanic, but might have unfortunate effects on ocean ecosystems. As with a number of other theoretical ice structures, no one has created the structure Zeng has proposed, but in Science Advances he outlines the conditions under which it might occur. The key to Zeng’s brainchild is for water to freeze under what is referred to as negative pressure. Instead of normal atmospheric pressure pushing in on the freezing material, the pressure goes outward. Improbable as this sounds, it is not impossible to achieve, but the paper noted, “In the laboratory, applying and maintaining very large tension or negative pressure up to -6000 bar would be very difficult.” Atmospheric pressure is 1.01 bar. Moreover, the colder the conditions under which the ice forms, the higher the negative pressure required. At 250K (-10°F) the outward pressure would need to be -3411 bar, four times as much as at the bottom of the Mariana Trench. At colder temperatures the pressure required gets even higher, -5834 bar at near absolute zero. Zeng’s new ice is so light because the water molecules form a near hollow, cage-like structure of 48 molecules. “Water and ice are forever interesting because they have such relevance to human beings and life,” Zeng said. “If you think about it, the low density of natural ice protects the water below it; if it were denser, water would freeze from the bottom up, and no living species could survive. So Mother Nature’s combination is just so perfect.” Source: iflscience.com from February 16, 2016 May 2016 Bulletin of the New York Mineralogical Club, Inc. Dealer Donations for the June ‘16 Benefit Auction The following list includes all the donations that the March 2016 NYC Mineral & Gem Show dealers made to the Club this year: Amazon Imports (2) Faceted Paraiba Tourmalines. . . . . . . . . . . . . . . . Brazil Aurora Minerals 1. Geode. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Brazil 2. Polished Emerald in Matrix.. . . . . . . . . . . . . . Bahia, Brazil AYS International 3. Prehnite Beads. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . NA Bary Gems 4. Carnelian & Silver Earrings. . . . . . . . . . . . . . . . . . . . . India John Betts Fine Minerals 5. Pyromorphite (ex. J. Marshall). . . . . . . . . . . . . . . . Scotland 6. Quartz on Calcite. . . . . . . . . . . . . . . . Anthony’s Nose, NY China South Seas 7. Carved Red Coral / Gold Filled Chain Necklace. . . . China Crystal Circle 8. Several Wonderful Carved Fetishes. . . . . . . . . . . . SW USA 9. Several Wonderful Gemstone Carvings. . . . . . . . . . . . . NA Excalibur Minerals 10. (12) WW Minerals, Fossils, Meteorites, etc... . . . . . . . Misc Exotic Russian Minerals 11. Synthetic Red Quartz. . . . . . . . . . . . . . . . . . . . . . . . . Russia Gems Art Studio 12. Selection of Russian Minerals.. . . . . . . . . . . . . . . . . . Russia (Corundum, Staurolite, Orpiment, Eudialyte, etc.) Great Opals 13. Boulder Opal Pendant. . . . . . . . . . . . . . . . . . . . . . . Ethiopia Highland Rock & Fossil 14. Fossil. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Morocco 15. Serpentine Sphere. . . . . . . . . . . . . . . . . . . . . . . . . . . . China 16. Quartz Drusy. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Arizona 17. Mounted Picture Jasper.. . . . . . . . . . . . . . . . . . . . . . . China 18. Rose Quartz Heart. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . NA 19. Ocean Jasper Drusy.. . . . . . . . . . . . . . . . . . . . . Madagascar Khyber Minerals 20. Nondescript, Useless “Mineral”. . . . . . . . . . . . . . Pakistan? Mahalo Minerals 21. Gemmy Apophyllite. . . . . . . . . . . . . . . . . . . . . . . . . . . India 22. Platy Quartz.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Brazil Malachite & Gems of Africa 23. Velvet Malachite. . . . . . . . . . . . . . . . . . . . . . . . . . . . . Congo 24. Company Pen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . USA Margola Minerals 25. Polished Multicolor Fluorite. . . . . . . . . . . . . . . . . . . . China Alfredo Petrov Rare Minerals 26. Alfredopetrovite. . . . . . . . . . . . . . . . . . . . . . . . . . . . Bolivia 27. R&M Magazine with Article by A. Petrov. . . . . . Periodical Raj Minerals 28. Stilbite. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Pakistan Rocko Minerals 29. Polished Larimar Specimen.. . . . . . . . . Dominican Republic Howard & Betsy Schlansker 30. Large Calcite with Inclusions & etc.. . . . . . . . . . . . . . China Somethings 31. Wide selection of jewelry, especially pendants!. . . . . . . NA [Although not represented at this show (Arlene does the November show only) she contributes nevertheless!] October Banquet Invitation & Preview 15 16 Bulletin of the New York Mineralogical Club, Inc. Curium’s Part in Solar System Formation By Stephen Luntz May 2016 “The possible presence of curium in the early Solar System has long been exciting to cosmochemists, because they can often use radioactive elements as chronometers to date the relative ages of meteorites and planets,” said coauthor Professor Nicolas Dauphas of the University of Chicago. This slice of the Allende meteorite, the largest carbonaceous chondrite ever found, shows the 1.5-centimeter-long (0.59 inch) pink ceramic inclusion that once contained curium. Origins Lab, University of Chicago Curium, an element heavier than any that exist naturally on Earth today, played a part in the formation of the Solar System, traces left behind in a meteorite suggest. The discovery provides us with a better understanding of how the Sun and planets formed, and how giant stars die. Elements heavier than uranium, known as transuranics, exist only in the laboratory on Earth. Curium, jointly named after Marie and Pierre Curie, has an atomic number of 96, four places beyond uranium. “Curium is an elusive element. It is one of the heaviest known elements, yet it does not occur naturally because all of its isotopes are radioactive and decay rapidly on a geological time scale,” said Dr. François Tissot of the Massachusetts Institute of Technology in a statement. Like all transuranics, curium’s isotopes have half-lives short enough that any formed in supernovae, and incorporated into planets at the birth of the Solar System, decayed long ago. Most curium isotopes have half-lives of a few thousand years or less. The longest lived isotope, Cm-247, has a half-life of 15.6 million years, tiny compared to the age of the Solar System (4.6 billion years). However, when Tissot examined the Allende meteorite, he found a portion of it was a ceramic. He dubbed it “Curious Marie,” suspecting it might once have contained curium. In Science Advances, he reveals evidence for this theory. Cm-247 decays via plutonium 243 to eventually become uranium 235. Any material that formed with Cm-247 in it should have more U-235, relative to other isotopes of uranium, than the same material formed in the absence of Cm-247. On Earth, geological mixing obscures such variations, but meteorites preserve a record of the Solar System’s formation. “The idea is simple enough, yet, for nearly 35 years, scientists have argued about the presence of Cm-247 in the early Solar System,” said Tissot. Some studies found excess U-235 in meteorites, but other explanations have been made. Finding traces of curium is hard because it is estimated that even in the early Solar System there was almost 10,000 times less Cm-247 than U-235. Tissot’s approach was to study a portion, known as an inclusion, rich in calcium and aluminum, rather than the whole meteorite. The chemistry of these inclusions excludes most uranium, in this case 99.9 percent, but should incorporate curium. “We were able to resolve an unprecedented excess of U-235,” Tissot said. “A finding that can only be explained by live Cm-247 in the early Solar System.” False color close up of the “Curious Marie” inclusion. Calcium is in red, aluminum is blue, green for magnesium; field of view is 0.5 millimeters (0.01 inches). François L.H. Tissot Dauphas concluded that the quantity of Cm-247 produced indicated it was formed in the same process as iodine 129 and plutonium 244, two other long-decayed isotopes whose legacy we detect. The discovery will help us understand how supernovae form heavy elements. Source: iflscience.com from March 8, 2016 Website of the Month: New York Mineralogical Club The New York Mineralogical Club has existed for 130 years. They have not had a website for that long, but now that they do they are able and willing to share their knowledge with any and all who care to hit their site. The site is very easy to remember http://www.newyorkmineralogicalclub.org/, but this should link you there also. Naturally, they would hope you join and membership information is readily available. But like us, they permit much of their bulletin information to be accessed by all and there appears to be over 50 years of them for you to open on their website. The latest issue has stories on turquoise, rare earth minerals in coal in West Virginia, gold, earthquakes, and a whole lot more. Looking back into last year, I enjoyed a multi-part series on garnets authored by Vivien Gornitz and an interesting article on low temperature minerals in September. But with 175 pages alone in the 2015 file, there is still a lot for me to read. Certainly seems worth the $25 annual membership to have your own Bulletin mailed to you monthly. If you plan to be in the New York City area the first weekend of March they are hosting their Spring NYC Gem and Mineral Show in the Holiday Inn in Midtown Manhattan. Of course if that is too soon for you to plan a trip to the big city they do it all over again this fall, November 12-13 this year: perhaps a good time to plan a trip to the big city. The club currently boasts about 250 members and meets the second Wednesday of most months. Source: Wayne County Gem and Mineral Club News March 2016 May 2016 Bulletin of the New York Mineralogical Club, Inc. 17 2016-17 Club Calendar Date Event Location Remarks & Information May 11 Meeting at 6:45 Holiday Inn Midtown Manhattan Special Lecture: Zackry Wiegand (Artist) – “Subtle Bodies - The Art of Light & Minerals” June 8 Annual Benefit Auction Holiday Inn Midtown Manhattan Details to follow; Online catalog available! July/August Officers Meeting / Open House (?) / Special Sale (?) TBD – Stay tuned! September 14 Meeting at 6:45 Holiday Inn Midtown Manhattan Special Lecture: Eric Rampello (1st Timer!) – “Tips in Building a Mineral Collection” October 19 Annual Banquet Holiday Inn Midtown Manhattan Opal theme; Details to follow November 16 Meeting at 6:45 Holiday Inn Midtown Manhattan Special Lecture: Anne Pizzorusso – “The Renaissance, Dante and Geology” December 14 Meeting at 6:45 Holiday Inn Midtown Manhattan Special Lecture: Howard Heitner– “Pseudo-What?!” January 11, 2017 Meeting at 6:45 Holiday Inn Midtown Manhattan Special Lecture: Mitchell Portnoy– “NYC Parks’ Monument Stones” 2016 Show or Event Calendar Date Event Location Remarks & Information April 23-24 NJESA Mineral Show Franklin School, Franklin, NJ For Info: Russ Brarens – (908) 421-1045 May 21-22 Southern Vermont Mineral, Rock & Gem Show Grace Christian School, Bennington, Vermont For Info: Bill Cotrofeld – (802) 375-6782 June 4-5 Orange County Mineral Society Mineral Show Museum Village, Monroe, NY Complete Mastodon Skeleton! Orange County Mineral Society, Sponsor June 4-5 Gemfest 2016 Greater Canandaigua Civic Center, Canandaigua, NY Gems, Minerals, Fossils, Beads & Jewlery Wayne County Gem & Mineral Club, Sponsor June 11-12 Celinka Gem & Mineral Show Our Lady of Mount Carmel, North Ocean Ave. Patchogue, NY Diverse dealers, 10 am - 5 pm both days July 27-Aug 1 AFMS Convention/Show Albany, Oregon Article Contest Results; Details to Follow July 30-31 Gem & Mineral Show Cutchogue East Elementary School, Cutchogue, New York Sponsor: Long Island Mineral & Geology Society September 24-25 Franklin & Sterling Hill Gem and Mineral Show Franklin Elementary School,50 Washington Ave, Franklin NJ Franklin Mineral Museum sponsors as their only large fundraising event October 21-23 EFMLS Convention/Show Rochester, New York Article Contest Results; Details to Follow November 12-13 Fall NYC Gem, Mineral & Fossil Show Grand Ballroom, Holiday Inn Midtown, New York City 20+ diverse dealers; lectures; wholesale section (with credentials); Club Booth Also, for more extensive national and regional show information check online: AFMS Website: http://www.amfed.org and/or the EFMLS Website: http://www.amfed.org/efmls The New York Mineralogical Club, Inc. Founded in 1886 for the purpose of increasing interest in the science of mineralogy through the collecting, describing and displaying of minerals and associated gemstones. Website: www.newyorkmineralogicalclub.org P.O. Box 77, Planetarium Station, New York City, New York, 10024-0077 2016 Executive Committee President Vice President Secretary Treasurer Editor & Archivist Membership Webmaster Director Director Director Mitchell Portnoy Anna Schumate Vivien Gornitz Diane Beckman Mitchell Portnoy Mark Kucera Joseph Krabak Alla Priceman Richard Rossi Sam Waldman 46 W. 83rd Street #2E, NYC, NY, 10024-5203 27 E. 13th Street, Apt. 5F, NYC, NY, 10003 101 W. 81st Street #621, NYC, NY, 10024 265 Cabrini Blvd. #2B, NYC, NY, 10040 46 W. 83rd Street #2E, NYC, NY, 10024-5203 25 Cricklewood Road S., Yonkers, NY, 10704 (Intentionally left blank) 84 Lookout Circle, Larchmont, NY, 10538 6732 Ridge Boulevard, Brooklyn, NY, 11220 2801 Emmons Ave, #1B, Brooklyn, NY, 11235 email: [email protected]. . . . . . . . . . . . email: [email protected]. . . email: [email protected] . . . . . . . . . . . email: [email protected]. . . . . . . . . . . . email: [email protected]. . . . . . . . . . . . email: [email protected]. . . . . . email: [email protected] email: [email protected]. . . . . . . . . . email: [email protected]. . . . . . . . . . email: [email protected]. . . . . . . . (212) 580-1343 (646) 737-3776 (212) 874-0525 (212) 927-3355 (212) 580-1343 (914) 423-8360 (914) 834-6792 (718) 745-1876 (718) 332-0764 Dues: $25 Individual, $35 Family per calendar year. Meetings: 2nd Wednesday of every month (except July and August) at the Holiday Inn Midtown Manhattan, 57th Street between Ninth and Tenth Avenues, New York City, New York. Meetings will generally be held in one of the conference rooms on the Mezzanine Level. The doors open at 5:30 P.M. and the meeting starts at 6:45 P.M. (Please watch for any announced time / date changes.) This bulletin is published monthly by the New York Mineralogical Club, Inc. The submission deadline for each month’s bulletin is the 20th of the preceding month. You may reprint articles or quote from this bulletin for non-profit usage only provided credit is given to the New York Mineralogical Club and permission is obtained from the author and/or Editor. The Editor and the New York Mineralogical Club are not responsible for the accuracy or authenticity of information or information in articles accepted for publication, nor are the expressed opinions necessarily those of the officers of the New York Mineralogical Club, Inc. Next Meeting: Wednesday, May 11, 2016 from 6:00 pm to 10:00 pm Mezzanine , Holiday Inn Midtown Manhattan (57th St. & Tenth Avenue), New York City Special Lecture: Zackry Wiegand — “Subtle Bodies: The Art of Light & Minerals” New York Mineralogical Club, Inc. Mitchell Portnoy, Bulletin Editor P.O. Box 77, Planetarium Station New York City, New York 10024-0077 FIRST CLASS George F. Kunz Founder