D10.4 Summer School for Training of Summer School

Transcription

www.cascatbel.eu
D10.
D10.4 Summer School for Training of
young researchers
Version 1.2
1.2
30/06/2014
Project
Acronym
CASCATBEL
Project Title
CAScade deoxygenation process using tailored
nanoCATalysts for the production of BiofuELs from
lignocellullosic biomass
Project
Reference
604307
Call identifier
FP7-NMP-2013-LARGE-7
Theme
Nmp.2013.1.1-1: Exploration, optimization and
control of nano-catalytic processes for energy
applications
Project
coordinator
Dr. David P.Serrano
Phone
+34 917 37 11 22
E-mail
[email protected]
The research leading to these results has received funding
from the European Community's Seventh Framework
Programme FP7/2007-2013 under Grant Agreement n° 604307
Deliverable
Nr.
10.4
Work Package
Task
10
10.1
Date of deliverable
Version (Draft/Final)
Dissemination Level
Contractual
Final
PU
Authors (Partner)
Reviewers
Jiri Cejka (HIPC)
David Serrano (IMDEA Energy); Carolina García
(IMDEA Energy)
Version
1.0
1.1
1.2
Date
19/06/2014
23/06/2014
30/06/2014
Deliverable D10.4 Summer School
Name
Summer School for Training of
young researchers
Dissemination and exploitation
Dissemination and cooperation with
other initiatives.
30/06/14
Actual
Author/Reviewer
Jiri Cejka
Carolina García
David Serrano
30/062014
Description
Draft
Draft
Reviewed
2
Table of Content
1.
INTRODUCTION ................................................................................................................. 4
2.
SUMMER SCHOOL PREPARATION ..................................................................................... 4
2.1
Dates and Location .................................................................................................... 4
2.2
Format ....................................................................................................................... 5
2.3
Agenda....................................................................................................................... 5
2.4
Posters ....................................................................................................................... 8
2.5
Dissemination .......................................................................................................... 10
3.
SUMMER SCHOOL CONTENT .......................................................................................... 12
4.
CONCLUSIONS ................................................................................................................. 19
Figures
Figure 1 Castle Liblice location ...................................................................................................... 4
Figure 2 Castle Liblice .................................................................................................................... 5
Figure 3 CASCATBEL website ....................................................................................................... 10
Figure 4 Summer School website ................................................................................................ 10
Figure 5 Summer School flyer ..................................................................................................... 11
Figure 6 Linkedin snapshot.......................................................................................................... 12
Figure 7 Prof. Serrano ................................................................................................................. 12
Figure 8 Dr. Roth ......................................................................................................................... 13
Figure 9 Prof. Nachtigall .............................................................................................................. 13
Figure 10 Dr. Horvat .................................................................................................................... 14
Figure 11 Dr. Perego.................................................................................................................... 14
Figure 12 Dr. Mitchell .................................................................................................................. 15
Figure 13 Prof. Wilson ................................................................................................................. 15
Figure 14 Prof. Lappas ................................................................................................................. 16
Figure 15 Prof. Huber .................................................................................................................. 16
Figure 16 Prof. Resasco ............................................................................................................... 17
Figure 17 Student presentation .................................................................................................. 18
Figure 18 Attendees (1) ............................................................................................................... 18
Figure 19: Attendees (2) .............................................................................................................. 19
Tables
Table 1 Impact indicator ............................................................................................................. 19
3
1. INTRODUCTION
This document reports on the Summer School on Catalysis of Biomass in
Liblice, Czech Republic, which was the first dissemination event organized by
CASCATBEL.
This event mainly targeted young (predoctoral and postdoctoral)
researchers involved in the CASCATBEL consortium, although it was also open to young
researchers from other groups and institutions external to the project interested in
this topic.
The Summer School focused on reviewing the main catalytic
transformations currently under development for biofuels production, highlighting the
relevance of controlling and tuning catalyst properties to optimize performance
towards the complex feedstock mixtures typically present during biomass conversion.
This deliverable is framed in WP10 “Dissemination and exploitation”.
2. SUMMER SCHOOL PREPARATION
2.1 Dates and Location
The three-days Summer School took place from 8th to 11 th of June. Castle Liblice
was chosen as the venue of the School as it brings optimum place for such school
providing all necessary options including modern lecture hall, number of rooms for
speakers and participants as well as other services.
Figure 1 Castle Liblice location
4
Castle Liblice is one of the most important buildings from the Czech top-baroque
period based on the plans of Italian architect Giovanni Battista Alliprandiho for duke
Arnošt Josef Pacht z Rájova in very early years of 18 century. Since 1945 this castle has
been belonging to the Czech Academy of Sciences.
Figure 2 Castle Liblice
2.2 Format
The main goals of the School were to summarize the up-to-date knowledge of
the development of new catalysts for biomass transformations, to discuss the
appropriate routes in biomass upgrading, and to propose new ways for biomass
utilization.
The program consisted of 12 Plenary lectures, 12 short oral presentations of PhD
students and postdocs, and 16 posters.
2.3 Agenda
June 8
19.30
Welcome Party
June 9
8.45-9.00
Introduction (D. Serrano)
9.00-9.45
Lecture 1 – W.J. Roth (Jagellonian University) - ZEOLITE CATALYSIS TRANSFORMING LABORATORY LEADS INTO INDUSTRIAL REALITY
9.45-10.30
Lecture 2 - P. Nachtigall (Charles University) - UNDERSTANDING THE
CATALYTIC ACTIVITY OF MICROPOROUS CATALYSTS - COMPUTATIONAL
APPROACH
10.30-11.00 Coffee Break + Poster Session
11.00-11.45
Lecture 3 - A. Horvat (Silkem) - ZEOLITE TRANSFORMING FROM
SUSPENSION TO AGGLOMERATES
5
11.45-12.30
Lecture 4 – C. Perego (eni) - ADVANCES IN BIOFUELS
12.30-14.00 Lunch
14.00-14.45
Lecture 5 – J.S. Mitchell (ETH Zurich) - POTENTIAL APPLICATIONS OF
HIERARCHICAL ZEOLITES FOR THE BIOMASS CONVERSION INTO
ADVANCED BIOFUELS
14.45-15.30
Lecture 6 - K. Wilson (University of Aston) - BIOMASS PYROLYSIS
15.30-16.00 Coffee Break + Poster Session
16.00-16.45
Lecture 7 – A.A. Lappas (CERTH) - CHARACTERIZATION AND PROPERTIES
OF BIO-OILS PRODUCED FROM LIGNOCELLULOSE BY PYROLYSIS AND
CATALYTIC PYROLYSIS
16.45-17.00
Oral 1 – H.V. Thang, P. Nachtigall - THEORETICAL INVESTIGATION OF
ACIDOBASIC PROPERTIES OF 3D AND 2D ZEOLITES
17.00-17.15
Oral 2 – M. Shamzhy, M.V. Opanasenko, J. Čejka - PERFORMANCE OF
MOFS IN ACID-CATALYZED REACTIONS: COMPARISON WITH LARGEAND EXTRA-LARGE PORE ZEOLITES
19.00
Barbeque
June 10
8.30-9.15
Lecture 8 – G. Huber (University of Wisconsin) - THERMOCATALYTIC
ROUTES FOR BIOMASS CONVERSION INTO FUELS
9.15-9.30
Oral 3 – K.V. Avramidou, P.A. Lazaridis, S.A. Karakoulia, K. S.
Triantafyllidis - FAST PYROLYSIS OF MIXTURES DERIVED FROM
AQUEOUS PHASE HYDROLYSIS OF BIOMASS WITH SOLID ACID
CATALYSTS
9.30-9.45
Oral 4 – V.B.F. Custodis, P. Hemberger, Z. Ma, J.A. van Bokhoven - THE
DECOMPOSITION MECHANISM OF LIGNIN FAST PYROLYSIS
9.45-10.00
Oral 5 – M. Al-Naji, N. Wilde, R. Gläser - AQUEOUS-PHASE PROCESSING
OF WET WASTE BIOMASS: TOWARDS CATALYSTS WITH IMPROVED
STABILITY
10.00-10.15
Oral 6 – M. Trejda, K. Stawicka, M. Ziolek - TRIACETIN FORMATION
USING DIFFERENT MESOPOROUS SOLIDS CONTAINING SULPHONIC
SPECIES
10.15-10.45 Poster
10.45-11.00
Oral 7 – T.C. Keller, E.G. Rodrigues, S.J. Mitchell, J. Pérez-Ramírez GENERATION OF NOVEL BASIC CENTERS IN HIGH-SILICA ZEOLITES AND
6
THEIR APPLICATION IN BIO-OIL UPGRADING
11.00-11.15
Oral 8 – I.V. Shamanaev, I.V. Deliy, E.Yu. Gerasimov, R.I. Kvon, V.A.
Rogov, G.A. Bukhtiyarova - OPTIMIZATION OF NICKEL PHOSPIDE
CATALYSTS PREPARATION FOR METHYL PALMITATE
HYDRODEOXYGENATION
11.15-11.30
Oral 9 – C. Ochoa- Hernández, P. Pizarro, V.A. de la Peña O’Shea, J.M.
Coronado, D.P. Serrano - ENHANCING THE GREEN DIESEL PRODUCTION
BY ADJUSTING THE Co/H-ZSM-5 PROPERTIES IN THE METHYL ESTERS
HYDROTREATING
11.30-11.45
Oral 10 – L.A. Ciddor, A.F. Lee, K. Wilson - UPGRADING OF BIO-OIL VIA
CATALYTIC ESTERIFICATION
11.45-12.00
Oral 11 – A. Mendoza, G. Vicente, L.F. Bautista, V. Morales - A
SUSTAINABLE ALTERNATIVE FOR BIODIESEL PRODUCTION FROM
OLEAGINOUS MICROORGANISMS USING ENZYME CATALYSTS
12.00-12.15
Oral 12 – I. Deliy, E.N. Vlasova, A.L. Nuzhdin, P.V. Aleksandrov, E.Yu.
Gerasimov, G.A. Bukhtiyarova - THE EFFECT OF RAPESEED OIL ON THE
SRGO HYDROPROCESSING: COMPARATIVE STUDY OF SULFIDE COMO
AND NIMO CATALYSTS
12.30-14.00 Lunch
14.15
Excursion
19.00
Farewell Evening
June 11
8.30-9.15
Lecture 9 – D. Resasco (University of Oklahoma) - BIO-OIL UPGRADING
BY CONDENSATION REACTIONS
9.15-10.00
Lecture 10 – B. Weckhuysen (University of Utrecht) - IN-SITU
SPECTROSCOPIC TOOLS FOR MONITORING CATALYTIC BIOMASS
TRANSFORMATIONS
10.00-10.20 Poster
10.20-11.05
Lecture 11 – D. Kubicka (VÚAnCh Litvínov) - CATALYTIC
DEOXYGENATION OF TRIGLYCERIDES
11.05-11.50
Lecture 12 – R. Rinaldi (MPIK Mulheim) - DEVELOPMENT OF HDO
CATALYSTS FOR BIO-OIL UPGRADING
11.50-12.00
Closing Remarks
12.00-13.15 Lunch
7
13.15
Departure to the Airport
2.4 Posters
P01
N. Wilde, M. Pelz, R. Gläser
ENHANCED CATALYTIC ACTIVITY OF MICRO-/MESOPOROUS TS-1 IN THE
EPOXIDATION OF BIODIESEL WITH H2O2
P02
M. Položij, M. Rubeš, P. Nachtigall
THEORETICAL INVESTIGATION OF LAYERED ZEOLITES WITH MWW
TOPOLOGY: MCM-22P VS. MCM-56
P03
S.D. Stefanidis, S.A. Karakoulia, K.G. Kalogiannis, E.F. Iliopoulou, K.S.
Triantafyllidis, A.A. Lappas
CATALYTIC PYROLYSIS OF BIOMASS USING FRESH AND MODIFIED
NATURAL BASIC MAGNESIUM OXIDE CATALYSTS
P04
H.-Y. T. Chen, S. Tosoni, G. Pacchioni
DEPOSITION OF RUTHENIUM ON ANATASE (101) AND T-ZIRCONIA (101)
SURFACES
P05
R. Jastrzebski, E.J. van den Berg, B.M. Weckhuysen, P.C.A. Bruijnincx
CATALYTIC DIOXYGENATION OF CATECHOL BY NON-HEME IRON(III)
COMPLEXES AS A SUSTAINABLE ROUTE TO DIMETHYL ADIPATE
P06
J.A. Calles, A. Carrero, A.J. Vizcaíno, L. García
HYDROGEN PRODUCTION BY STEAM REFORMING OF
HYDROXYACETONE AS A MODEL COMPOUND OF BIO-OIL USING Ni/SBA15 CATALYSTS
P07
A. Marianou, C. Michailof, E. Iliopoulou, K. Kalogiannis, K. Triantafyllidis,
A.A. Lappas
CONVERSION OF CELLULOSE TO HMF IN POLAR APROTIC SOLVENTS
P08
A. Berenguer, C. Ochoa-Hernández, Y. Yang, I. Moreno, J.M. Coronado,
P. Pizarro, D.P. Serrano
SYNTHESIS OF CATALYSTS BASED ON SUPPORTED TRANSITION METAL
PHOSPHIDES FOR PHENOL HYDRODEOXYGENATION
P09
T. Fakin, V. Kaučič, A. Ristić
RELATIONSHIP BETWEEN ZEOLITE LTA MORPHOLOGY AND THEIR BULK
PROPERTIES
P10
J. Iglesias, J.A. Melero, G. Morales, M. Paniagua, B. Hernández, A.I. del
Río
CATALYTIC REDUCTION OF FURFURAL BY MEERWEIN-PONNDORF-
8
VERLEY H-TRANSFER IN PRESENCE OF Zr-SBA-15
P11
J.A. Hunns, A.F. Lee, K. Wilson
IN-SITU STUDIES OF HYDRODEOXYGENATION CATALYSTS FOR BIOFUELS
SYNTHESIS
P12
M. Kothari, O. Kikhtyanin, Z. Tišler, D. Kubička
EFFECT OF DEALUMINATION BY ACID TREATMENT OF BEA ZEOLITE ON
THE ACIDITY AND ACTIVITY IN THE ALDOL CONDENSATION OF
FURFURAL AND ACETONE
P13
J.A. Botas, J.M. Escola, D.P. Serrano, B. Paredes, M. López-Domínguez
BIOFUELS PRODUCTION BY HDO OF OLEIC ACID OVER Pd SUPPORTED
ON HIERARCHICAL ZEOLITES AND Al-SBA-15
P14
M. Melián-Rodríguez, S. Shunmugavel, S. Kegnæs, A. Riisager
LIGNIN VALORIZATION USING HETEROGENOUS CATALYTIC OXIDATION
P15
T.M. Sankaranarayanan, A. Berenguer, C. Ochoa-Hernández, P. Jana, I.
Moreno, J.M. Coronado, P.Pizarro, D.P. Serrano
HYDRODEOXYGENATION OF ANISOLE AS BIO-OIL MODEL COMPOUND
OVER SUPPORTED NICKEL AND COBALT CATALYSTS
P16
M. Gyngazova, L. Blumenthal, R. Palkovits
MULTIPHASE REACTION SYSTEMS FOR THE EFFICIENT VALORISATION OF
BIOMASS
9
2.5 Dissemination
CASCATBEL Summer School on Catalysis of biomass has been disseminated
through different channels:
CASCATBEL website
Information about the Summer School was displayed in the home banner and in
the news section of the project website.
Figure 3 CASCATBEL website
Summer School website
The Jaroslav Heyrovský Institute website hosted several pages affording relevant
information about the Summer School: Goal; Program; Registration Procedure;
Abstracts submission; Practical information; Key dates.
http://www.jh-inst.cas.cz/cascatbel/
Figure 4 Summer School website
10
Biomass related websites
Some webpages of the biomass transformation world referred to the Summer
School as for instance: Zeo4 (http://www.zeo4.info/); European Biofuels Technology
Platform (http://www.biofuelstp.eu/); Danube-INCO (http://danube-inco.net/);
Societá Chimica Italiana (https://www.soc.chim.it); biomass events (www.biomassevents.com).
The event was also disseminated from the corporative webpages of the project
partners.
EC Research and Innovation was informed about the event although it was not
posted on their website.
Flyer
An informative flyer was prepared and distributed in both digital and print format.
Around 50 printed copies were distributed in the Spanish Energy & Environment
International Fair – GENERA.
Figure 5 Summer School flyer
Mass-mailing to stakeholders
Around 260 informative emails and digital flyers were sent to different
stakeholders.
11
Linkedin
CASCATBEL group in Linkedin served as well as a dissemination platform for the
Summer School
Figure 6 Linkedin snapshot
3. SUMMER SCHOOL CONTENT
The school was opened by Prof. D. Serrano, coordinator of CasCatBel project,
who welcomed all participants and introduced the CasCatBel, its participating
institutions, and goals of the project.
Figure 7 Prof. Serrano
12
The first scientific lecture was delivered by Dr. Wieslaw J. Roth (Jagiellonian
University, Cracow, Poland). Dr. Roth is famous researcher well-known for his
pioneering work and discovery of mesoporous materials at Mobil in early nineties of
the last century.
Figure 8 Dr. Roth
His lecture was dedicated to the transfer of zeolite synthesis knowledge from
laboratory scale to industrial applications. He discussed also some processes, in which
great development was reached in recent years. Probably the most important was the
part discussing pros and cons of zeolite synthesis scaling up assessing the difficulty of
this process.
The second plenary lecture was delivered by Prof. Petr Nachtigall (Faculty of
Natural Science, Charles University, Prague, Czech Republic). His lecture described new
achievements in the field of theoretical description and modelling of the properties of
zeolites, their two-dimensional analogues, and reaction mechanism in reactions
catalyzed by zeolites. P. Nachtigall strongly supported close cooperation between
theoretical chemists and experimentalist in terms of planning the experiments and
proposing the reasonable targets for the joint cooperation.
Figure 9 Prof. Nachtigall
13
While the second plenary lecture was focused on theoretical description of
reaction mechanisms of heterogeneously catalyzed reactions applicable to biomass
transformations, the next lecture deliver by Dr. Andrej Horvat (Silkem, Slovenia)
focused on basic aspects of the preparation of real catalysts. Dr. Horvat discussed
preparation of granules, pellets, spray drying, in laboratory scale and how to perform
the up-scaling of those processes.
Figure 10 Dr. Horvat
Very exciting lecture was delivered by Dr. Carlo Perego (Instituto eni Donegani,
Novara, Italy). The lecture featured recent industrial achievements in transformation
of biomass to biofules. One of the important routes to biomass is based on
hydrotreating of vegetable oils and animal fats. Another routes include hydrolysis of
lignocellulosic biomass into microbial lipids. Alternatively, processes in which the
whole biomass is exploited are also being studied. These processes rely upon some
thermal treatment of the biomass: 1) liquefaction and pyrolysis afford bio-oils,
complex mixtures of products which hopefully, can be up-graded to valuable fuel
components, most probably by some deep hydrotreating; 2) gasification to syngas and
subsequent
Fischer-Tropsch
reaction provide a route to purely
hydrocarbon fuels which, however,
seems to be too expensive unless
some key problems will be solved
(e.g., the difficult trade-off between
plant capacity and biomass
availability and logistics).
Figure 11 Dr. Perego
14
Potential role of hierarchical zeolites
for biomass valorization was discussed by
Dr. Sharon Mitchell (ETH Zurich,
Switzerland). Different routes for the
preparation of hierarchic materials were
discussed showing their advantages and
disadvantages. It is important to recall
that decisive aspects as the scale up into
technically-relevant forms and the
stability under realistic processing
conditions remain to be surpassed.
Figure 12 Dr. Mitchell
Various technical aspects of biomass pyrolysis were discussed by Prof. Karen
Wilson (Aston University, Birmingham, GB). In fast pyrolysis, the objective is to
maximize the organics yield as this provides the energy in the product. The conditions
for fast pyrolysis were summarized as follows: high heating rates, small catalyst
particles, dry biomass, low ash biomass, carefully controlled temperature, and short
hot vapour residence time.
Figure 13 Prof. Wilson
15
While upgrading of biomass is critical for their application, characterization and
determination of properties of bio-oils are critical from the analytical point of view. A
broad combination of methods devoted to bio-oil characterization was highlighted by
Prof. Angelos Lappas (CPERI, Thessaloniki, Greece). Special emphasis was given to the
chemical characterization of the bio-oils using GC-MS or 2DGC-TOFMS techniques.
Details of these techniques were provided along with the method developed in CPERI
for the qualitative and
quantitative
characterizations of bio-oils.
In the presentation, Prof.
Lappas emphasised how
these properties are affected
by
various
pyrolysis
parameters like operating
conditions, feedstock and
catalyst
(for
catalytic
pyrolysis) type.
Figure 14 Prof. Lappas
Thermocatalytic routes for biomass conversion to biofules or chemicals were
corroborated by Prof. G. Huber (University of Wisconsin, Madison, USA). Three main
technologies are used to break apart the biomass: 1) gasification (forming syn-gas); 2)
pyrolysis (forming pyrolysis oil) or 3) hydrolysis (forming aqueous carbohydrates). The
products of these reactions then undergo a variety of catalytic reactions to make a
wide variety of fuels and chemicals.
Figure 15 Prof. Huber
16
Treatment of biomass provides a large portfolio of different compounds, which
require some upgrading to get final products. Prof. Daniel Resasco (University of
Oklahoma, Norman, USA) focused his presentation mainly on condensation reactions.
An attractive approach is to utilize the high reactivity of the oxygen functionalities
before eliminating them. Based on this concept, different catalytic condensation
strategies have been investigated, including: ketonization, transalkylation / alkylation,
aldol condensation, and aromatization / ring contraction. Novel types of catalysts with
high performance in C-C bond forming reactions were discussed.
Figure 16 Prof. Resasco
Last three invited lectures were devoted to the in-situ spectroscopic
characterization of catalytic transformation of biomass. Prof. Bert Weckhuysen
(Utrecht University, The Netherlands) discussed alternative spectroscopic approaches
to get detailed information about the processes in liquid phase upgrading of biomass.
Dr.David Kubicka (VUANCH, Usti nad Labem, Czech republic) discussed catalytic
deoxygenation of triglycerides both from fundamental aspects as well as industrial
perspective. The catalyst structure-activity relationship was analyzed particularly with
respect to hydrogen consumption, which seems to be critical step of this industrial
process.
Last but not least, Dr. Roberto Rinaldi (MPIK Muelheim, Germany) focused on
the prospects for the cost-effective production of synthetic biofuels and platform
chemicals related to the rational utilization of hydrogen in the conversion and upgrade
of plant biomass.
17
In addition to the invited speakers, 12 students were chosen by the organizing
committee consisting of D. Serrano, J. Cejka, and P. Nachtigall. Registration fee of
these students was covered by organizers.
Figure 17 Student presentation
Finally, 16 posters were presented by students in 3 poster sessions.
Figure 18 Attendees (1)
18
Figure 19: Attendees (2)
Summer School lectures have being compiled in a specialized book that has been
distributed among the attendees.
4. CONCLUSIONS
The Summer School can be considered successful in terms of organization,
execution and attendance. The topic drawn the attention of the stakeholders and the
attendees expectations were overwhelmed.
In terms of impact it can be said that the Summer School achieved the objectives
fixed on the Dissemination Plan (D10.1) of the project.
ACTIVITY
Summer School
INDICATOR
Nr. of expected
participants
Nr. of actual participants
60
75
Table 1 Impact indicator
19

D10.4 Summer School for Training of Summer School

Transcription

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