Krazy Glue Single Use Tubes

SAFETY DATA SHEET
_________________________________________________________________________________________________
KRAZY GLUE SINGLE USE (2 TUBES)
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name
Other Names
Product Use
Company Name
Address
Krazy Glue Single Use (2 Tubes)
KG58148INN
Cyanoacrylate adhesive
Pelikan Artline Pty Ltd
2 Coronation Avenue
Kings Park NSW 2148
02 9674 0900
1300 ARTLINE
Telephone Number
Emergency Telephone
2. HAZARDS IDENTIFICATION
Classification of the Substance or Mixture
Exclamation mark
H227 - Combustible liquid
H315 - Causes skin irritation.
H319 – Causes serious eye
irritation.
H335 - May cause respiratory
irritation.
Flammable liquids - Warning - Hazard Category 4
Skin Corrosion/Irritation - Warning - Hazard Category 2
Serious Eye Damage/Irritation - Warning - Hazard Category 2A
STOT (Single Exposure) - Warning - Hazard Category 3
GHS Label Elements Including Precautionary Statements
Prevention
Keep away from sparks and open flames. – No smoking.
Wear protective gloves, eye protection and face protection.
Wash hands thoroughly after handling.
Avoid breathing vapours.
Use only outdoors or in a well-ventilated area.
Response
In case of fire: Use carbon dioxide, dry chemical and foam extinction.
IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse skin with water.
If skin irritation occurs: Get medical attention.
Take off contaminated clothing and wash before reuse.
Mineral oil, vegetable oil, or petroleum jelly may help soften the bonding between skin surfaces.
For skin contact, consider acetone or nitromethane.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
If eye irritation persists: Get medical attention.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell.
Storage
Store in a well-ventilated place. Keep cool.
Keep container tightly closed. Store locked up.
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Disposal
Dispose of contents/container in accordance with local and state government regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Characterisation
Mixture
Hazardous Ingredients
Ethyl 2-cyanoacrylate
Polymethyl methacrylate
Hydroquinone
CAS No
7085-85-0
9011-14-7
123-31-9
Concentration
>95%
<5%
<0.1%
4. FIRST AID MEASURES
Inhalation
If inhaled, remove to fresh air. Give artificial respiration if not
breathing. Seek immediate medical attention.
Wet lips with water. Peel or roll the surfaces apart using a blunt
edge, such as a spatula or spoon handle. Do not pull surfaces apart
with a direct opposing action. If a lump forms in the mouth, turn
head to side. Seek immediate medical attention.
In case of skin contact, immediately remove contaminated clothing.
If bonding occurs, immerse the bonded surfaces in warm soapy
water. Peel or roll the surfaces apart using a blunt edge, such as a
spatula or spoon handle. Do not pull surfaces apart with a direct
opposing action. If burns occur, treat as thermal burns. Seek
medical attention. Launder contaminated clothing before reuse.
In case of eye contact, rinse cautiously with water for several
minutes. If bonding to tissues occurs, wash with large amounts of
warm water. Cover both eyes with sterile, dry bandages. The eye
will open without further action. Do not pull surfaces apart with a
direct opposing action. If burns occur, treat as thermal burns. Seek
medical attention.
Ingestion
Skin
Eyes
5. FIRE FIGHTING MEASURES
Suitable Extinguishing
Media
Hazardous Combustion
Products
Special Protective
Equipment and
Precautions for Fire
Fighters
Unusual Fire or
Explosion Hazards
Hazchem Code
30/10/2012
For major fires call the Fire Brigade. Ensure that an escape path is
available from any fire.
Water spray, carbon dioxide, dry chemical or foam.
Oxides of carbon.
Wear Safe Work Australia approved self-contained breathing
apparatus with positive pressure and full protective clothing.
Combustible liquid. The vapor is heavier than air. Vapors or gases
may ignite at distant ignition sources and flash back. Vapor/air
mixtures are explosive.
Cool fire exposed containers with water spray.
Not allocated.
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6. ACCIDENTAL RELEASE MEASURES
Personal Precautions,
Protective Equipment
and Emergency
Procedures
Environmental
Precautions
Methods and Materials
for Containment and
Cleaning Up
Wear Safe Work Australia approved self-contained breathing
apparatus and full protective clothing. Evacuate all non-essential
personnel from affected area. Ensure adequate ventilation.
Extinguish all sources of ignition. Keep away from sparks and open
flames. – No smoking.
In the event of a major spill, prevent spillage from entering drains or
water courses.
Stop leak if safe to do so and contain spill. Reduce vapors with
water spray. Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal.
7. HANDLING AND STORAGE
Precautions for Safe
Handling
Conditions for Safe
Storage
Use of safe work practices are recommended to avoid eye or skin
contact and inhalation of vapours. Use only outdoors or in a wellventilated area.
Food, beverages and tobacco products should not be stored or
consumed where this material is in use. Always wash hands before
smoking, eating, drinking or using the toilet. Wash contaminated
clothing and other protective equipment before storage or re-use.
Provide eyewash fountains and safety showers in close proximity to
points of potential exposure.
Store in a tightly closed original container in a cool, dry, and well
ventilated area. Protect from heat, sparks, open flames and hot
surfaces. No smoking. Keep away from alcohols, bases, amines
and strong oxidizing agents. Ground container and receiving
equipment. Store locked up.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters Exposure Standards
(Safe Work Australia)
Ethyl 2-cyanoacrylate:
3
TWA: 0.2 ppm / - mg/m ACGIH
3
STEL: - ppm / - mg/m
Hydroquinone:
3
TWA: - ppm / 2 mg/m
3
STEL: - ppm / - mg/m
Engineering Controls
Provide exhaust ventilation or other engineering controls to keep
the airborne concentrations of vapour below occupational exposure
standards.
Personal Protective Equipment (PPE)
Respiratory Protection
Wear a Safe Work Australia approved air purifying respirator with a
tight-fitting face piece, organic vapor cartridge(s) and high-efficiency
particulate filter if ventilation is inadequate to keep the airborne
concentrations of vapour below occupational exposure standards.
See Australian Standards AS/NZS 1715 and 1716 for more
information.
Eye/Face Protection
Safety glasses with top and side shields or goggles. See Australian
Standards AS/NZS 1336 and 1337 for more information.
Skin Protection
Chemical resistant gloves (neoprene rubber), clothing and and
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boots. See Australian Standards AS/NZS 2161, 2210.1 and 2210.2
for more information.
No information available.
Thermal Hazards
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Odour
Solubility in Water
pH
Freezing Point
Initial Boiling Point / Range
Flash Point (TCC)
Evaporation Rate
Lower Flammability or Explosive Limit
Upper Flammability or Explosive Limit
Vapour Pressure
Vapour Density (Air=1)
Relative Density (Specific Gravity)
Volatility
Auto-ignition Temperature
Decomposition Temperature
Viscosity
Colourless liquid
Irritating odour
Negligible
No information available
-20°C
62°C @ 5 mm Hg
83°C
<1
No information available
No information available
0.13 mm Hg @ 20°C
>1
1.05
No information available
485°C
No information available
No information available
10. STABILITY AND REACTIVITY
Chemical Stability
Possibility of Hazardous
Reactions
Conditions to Avoid
Incompatible Materials
Hazardous Decomposition
Products
Stable under recommended storage conditions.
May polymerize. Avoid contact with water or moisture.
Heat, flames, sparks and other sources of ignition, moisture and
water.
Alcohols, bases, amines and strong oxidizing agents.
Oxides of carbon.
11. TOXICOLOGICAL INFORMATION
Toxicity
30/10/2012
Ethyl cyanoacrylate:
Oral LD50 ( rat) = 180 mg/kg
Skin LD50 ( rabbit) = 220 mg/kg
Polymethyl methacrylate:
May cause eye, skin, respiratory and digestive tract irritation. The
toxicological properties of this material have not been fully
investigated.
Hydroquinone:
Intraperitoneal LD50 (rabbit) = 125 mg/kg
Oral LD50 (rat) = 320 mg/kg
Oral LDLo (human) = 29 mg/kg
Skin LD50 (mammal) = 5970 mg/kg
Skin and Eye Irritation Data:
Skin human - 5% - Standard Draize Test – Severe
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Mutation Data:
Micronucleus test - human lymphocytes 75 μmol/ L; DNA damage human bone marrow 500 μmol/ L; DNA damage - human lung 800
μmol/L; DNA inhibition - human HeLa cells 100 μmol/ L
Reproductive Effects Data:
Oral rat TDLo = 2500 mg/kg - Post-implantation mortality;
Oral rat TDLo = 1000 mg/kg - Litter size
Possible carcinogen. Severe skin irritant; allergen. Harmful by
inhalation and ingestion. May cause sensitization. Eye and
respiratory irritant.
Acute Health Effects
Routes of Exposure
Inhalation:
Causes respiratory tract irritation, lung congestion and
allergic reactions.
No information on significant adverse reactions.
Ingestion:
Causes serious eye irritation.
Eye:
Skin:
Causes skin irritation.
Skin Corrosion/Irritation
Causes skin irritation.
Serious Eye
Causes serious eye irritation
Damage/Irritation
Respiratory or Skin
Not expected to be a hazard.
Sensitisation
Germ Cell Mutagenicity
Not expected to be a hazard.
Carcinogenicity
Hydroquinone and polymethyl methacrylate are classified by IARC
as a Group 3 - Not classifiable as to its carcinogenicity to humans.
Reproductive Toxicity
Not expected to be a hazard.
Specific Target Organ
May cause respiratory irritation.
Toxicity (STOT) - Single
Exposure
Specific Target Organ
Not expected to be a hazard.
Toxicity (STOT) Repeated Exposure
Aspiration Hazard
Not expected to be a hazard.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Persistence and Degradibility
Bioaccumulative Potential
Mobility in Soil
No information available.
No information available.
No information available.
No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods and
containers
Special precautions for
landfill or incineration
Dispose according to applicable local and state government
regulations.
Please consult your state Land Waste Management Authority for
more information.
14. TRANSPORT INFORMATION
Not classified as a dangerous good according to the Australian Code for the Transport of
Dangerous goods by road or rail (ADG 7).
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SAFETY DATA SHEET
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UN Number
Proper Shipping Name
Dangerous Goods Class
Subsidiary Risk
Hazchem Code
Packing Group
Special Provisions
Limited Quantities
Packagings & IBCs - Packing Instruction
Packagings & IBCs - Special Packing
Provisions
Portable Tanks & Bulk Containers –
Instructions
Portable Tanks & Bulk Containers –
Special Provisions
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
Not applicable
15. REGULATORY INFORMATION
Ethyl 2-cyanoacrylate, polymethyl methacrylate and hydroquinone are listed in the Australian
Inventory of Chemical Substances (AICS).
Poisons Schedule: 5
16. OTHER INFORMATION
Last Revision of MSDS
Prepared by
Abbreviations Used
Rev 1.0 (30/10/2012)
MSDS.COM.AU Pty Ltd
www.msds.com.au
GHS – Globally Harmonised System of Classification and Labeling
of Chemicals
IARC: International Agency for Research on Cancer
STEL: Short term exposure limit
TWA: Time weighted average
Emergency Contacts
Pelikan Artline Pty Ltd
Pelikan Artline Pty Ltd - Emergency Number
02 9674 0900
1300 ARTLINE
Police and Fire Brigade
Poisons Information Centre
000
13 11 26
The information contained in this material safety data sheet is provided in good faith and is
believed to be accurate at the date of issuance. Jasco Pty Ltd makes no representation of the
accuracy or comprehensiveness of the information and to the full extent allowed by law excludes
all liability for any loss or damage related to the supply or use of the information in this material
safety data sheet. MSDS.COM.AU Pty Ltd is not in a position to warrant the accuracy of the data
herein. The user is cautioned to make their own determinations as to the suitability of the
information provided to the particular circumstances in which the product is used.
This MSDS is prepared in accord with the Safe Work Australia document “Code of Practice for the
Preparation of Safety Data Sheets for Hazardous Chemicals.2011”
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