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The Museum of Ancient Glass in Zadar (Croatia) Šime Perović Museum of Ancient Glass in Zadar Zadar, Croatia [email protected] Abstract This paper discusses the establishment of a glass museum in Zadar following the discovery of Roman glass finds, and describes its role in the study and conservation of this collection. It outlines the restoration of objects prepared for display in the museum, and provides the results of experiments in reproducing several types of Roman blown and fused glass. Keywords: Zadar, archaeology, Roman glass, restoration, glass museum Introduction A significant quantity of ancient Roman glass has been uncovered in and around Zadar, Croatia, indicating that glass was produced in this area (Fadić 1997, pp. 73–246). The preparation for exhibition of glass finds from the Roman province of Dalmatia prompted a wide range of professional and scientific activities. The Museum of Ancient Glass in Zadar (Fig. 1), which has a large collection of ancient Roman glass (Fig. 2), opened in the spring of 2009. The museum focuses on the manufacturing techniques and aesthetic value of glasses made in the Roman world (Domijan 2009). Most of the objects on display came from excavations at Roman ceme teries in Zadar (Iader), Nin (Aenona), Starigrad (Argyrun tum), and Podgrađe (Asseria). These excavations recovered more than 3,000 complete objects and a comparable number of pieces requiring restoration. Many glass objects were found in rescue excavations in the Relja district of Zadar (Fadić 2006b). About 2,000 graves containing considerable quantities of glass objects Figure 1 Museum of Ancient Glass in Zadar. Figure 2 Part of the museum’s Roman glass collection. 75 Figure 3 Glass urn (olla) on the archaeological site (left) and after restoration (right). were uncovered here. These finds prompted the establishment of the museum for the display and study of these artifacts, including conservation and restoration work. While the excavations in Starigrad and Podgrađe were conducted in the early 1900s, those at the Roman cemetery in Zadar are more recent (Gluščević 2002). At each cemetery, evidence of both inhumation and cremation was found. Both of these burial rituals were practiced during the Roman imperial age, although the former prevailed in the later part of that period. Some inhumations in Dalmatia were accompanied by the construction of graves, while others were not, and cremated remains were found in urns made of ceramics, stone, or glass (Fadić 2006a, pp. 7–91). Above the sepulchers stood several types of tombstones (stella, cippus, ara, and epitaph). The long-term use of the Zadar cemetery is confirmed by the discovery of Liburnian sepulchers dating from the seventh century B.C. and inhumation tombs from the late fifth and sixth centuries A.D. Most of these graves are dated between the first and fourth centuries A.D. The typology of glass artifacts from the cemetery of Zadar is extremely broad. Among the finds are mosaic cups, game counters, bottles, jugs, plates, dishes, beakers, urns, toilet bottles, droppers, amphorae, and decorative pins and other jewelry (Isings 1957). All of them came from tombs (Fadić 1997, pp. 73–246), which also yielded oil lamps, coins, ceramic artifacts, metal objects, and pins 76 Perović made of animal bone. These items were usually offered to assist the deceased in the afterlife, and they reflected his or her social status, occupation, and age. The size of the collection of Roman glass from the wellpreserved cemetery at Zadar is comparable to that of Aqui leia in northern Italy (Mandruzzato and Marcante 2007, pp. 4–94). These burial items were widely used in everyday life. For example, large glass urns (olla), which contained the cremated remains of the dead, were also employed in storing vegetables (Fadić 2006a, pp. 7–91; Fig. 3). Toilet bottles, which contained perfumes and balsams, were also used in cremation, and prismatic jugs served as measuring vessels for liquids and as tableware (Nappo 2004). The Museum of Ancient Glass encompasses a wide range of museological, educational, scientific, and research activities. It includes a facility for the research of ancient glass technologies, a department of restoration, a library, and offices for editorial work on the archaeological periodical Asseria. There is also a workshop in which glassmakers produce about 20 types of Roman glasses; visitors are also invited to make glasses, some of which are filled with olive oil and lavender oil. Glass Restoration The conservation workshop of the Archaeological Museum Zadar has restored items of wood, metal, ceramic, stone, and paper, as well as glass artifacts dating from the Roman and medieval periods (Batović 1980). This work is now also performed in the Museum of Ancient Glass, where the most demanding interventions are made (Pero vić 2008). Special attention is focused on nondestructive chemical and physical analyses, and high-magnification examinations are supplemented with spectroscopic measurements and particle-induced X-ray emission (PIXE) analyses that are made in collaboration with the Ruđer Bošković Institute in Zagreb (Perović forthcoming). These studies provide information on glass compositions, including coloring and opacifying agents (Arletti and others 2006). Our experiments are designed to determine the composition of opaque Roman glasses. We found, for example, that objects made by reheating crumbled glass (pasta vitrea) (Moretti 2002, pp. 61–68) were similar to other opaque glasses (Perović forthcoming). One hundred glass objects were restored for permanent exhibition, and 21 objects required intensive intervention. Although the composition of Roman glass is homogeneous, differences in degradation are normally based on variations in the composition of local soils. Degradation leads to weathering, after the leaching of alkalis from the network of the glass (Pallecchi 2000) caused by the effects of humidity on the glass. The absorption of water is the primary means of forcing alkalis to migrate toward the glass surface, where they leave behind layers that laminate and scale. In addition to weathering, some glasses show Figure 4 Process of devitrification, shown at magnification of 40X. evidence of poor annealing (ibid.). Such objects have a tendency to form microcracks (about 0.1 mm; Fig. 4). They need to be restored to stable microclimatic conditions (relative humidity [RH] of 55%, and temperature of 18°–20°C), so as to slow the degradation processes (Hill 1993). RH values suggested by other authors for the storage of archaeological glass range from 40% (Daintith 1988, pp. 5–18) to 45%–50% (Venturini 2000). We have chosen the value of 55% RH because we are treating mainly fresh archaeological finds that are in good shape, and we want to avoid any stress or shock that might result from changing their microclimatic environment. Stage 1: Stabilization and Cleaning Modern methods of preserving and restoring ancient glass artifacts can be divided into two stages. The first involves the stabilization and cleaning of the object (Daintith 1988, pp. 5–18; Venturini 2000). The most important function of stabilization is to slow the processes of weathering and devitrification. Many of the samples in the Department of Restoration and Research in the Museum of Ancient Glass in Zadar required treatment of this kind. The cleaning was normally done with mechanical tools, motor-driven brushes, and scalpels, while the most delicate interventions were carried out under the microscope. The most resistant impurities were treated in a solution of alcohol and demineralized water. Stage 2: Restoring the Glass The first step in restoring the glass is recomposition by gluing the fragments with a slow-bonding adhesive. This so-called indirect gluing process avoids the mistakes in the angle of the fracture connections that are inevitable in direct gluing. It is impossible to connect all of the fragments at an ideal fracture angle, and thus an object cannot be reassembled properly with direct gluing. We join fragments by the application of a special prosthesis or clamp made of brass or copper. Cyanoacrylate glue is normally used to affix the prosthesis to the surface of the glass, and after all of the fracture angles have been adjusted, we inject the glue into the cracks. The catalysis of the glue requires 24 hours, after which the prosthesis is removed with special solvents (Petek 2004). In the case of objects with very thin walls, which could not survive the use of a metal prosthesis, we employ tape in rejoining fragments. The Museum of Ancient Glass in Zadar (Croatia) 77 Figure 5 Type of integration for structural stability. The next step in restoration is integration, which is carried out for structural stability (Fig. 5) or aesthetics (Fig. 6). In the latter instance, missing parts of objects are replaced with synthetic reconstructions. On a large glass cup (modiolus) of which about 35 percent of the body was missing (Fig. 6a), for example, a replacement was made by injecting epoxy into a two-part silicone mold. The making of such molds is sometimes a complicated pro cedure (Mertik and Lemajič 2007), which involves the preparation of a matrix—a complete positive of the artifact—before the mold is created. Modeling wax or clay is normally used in the production of the matrix. After the positive is designed, the mold is prepared with silicone rubber of sufficient hardness. The mold must then be retouched by a fast-rotating polisher and attached to the damaged artifact. Figure 6b shows the preparation for injecting the synthetic material inside the prepared mold. This type of integration is particularly necessary when objects such as the Zadar modiolus are to be placed on display (Perović 2008; Fig. 6c). Figure 6a (above, left) Type of integration for aesthetics. Figure 6b (above) Processes of recomposition and restoration with two-part silicone molds. Figure 6c (left) The object (modiolus) after intervention. 78 Perović Figure 7 Museum facility for glass experiments. Figure 8 Production of copies of Roman blown glass. Three considerations govern our restoration work: (1) reversibility, (2) minimal intervention, and (3) accentuating reconstructed parts, which must be different in appearance from the original. In our effort to respect the original construction of an object, we sometimes attempt to make a reconstruction that is stable and then create copies made of glass or synthetic materials in the museum’s workshop (Fig. 7). Experiments in the workshop are designed to help us understand how ancient artisans fashioned glass objects, especially by glassblowing (Stern 1995, pp. 34–44). The nearly 20 forms of beakers and other objects (Fig. 8) are made with two- or three-part wooden or metal molds. We work with various recipes, and we are researching the techniques of manufacturing “archaeological” glass described by Moretti (2001). An example of our experimental work is the reproduction of a polychrome glass bowl dating from the first century A.D. (Fig. 9). We applied a cylindrical mold and the fusion technique in order to make a copy of this artifact (Fig. 10). In general, the materials used for fusing glass in molds have different thermal characteristics that create stresses when an object is annealed. To eliminate problems, we tried to choose materials and shapes that can withstand these stresses. Siporex, an aerated concrete that is employed by civil engineers, showed optimal characteristics for this purpose. It is very inexpensive, and that is an important considera tion because the mold, which can be easily shaped, should Figure 9 Dish made of fused polychrome canes: copy (a) and original (b). The Museum of Ancient Glass in Zadar (Croatia) 79 References Arletti and others 2006 Rosella Arletti and others, “Roman Coloured and Opaque Glass: A Chemical and Spectroscopic Study,” Applied Physics A: Materials Science & Processing, v. 83, no. 2, 2006, pp. 239–245. Batović 1980 Šime Batović, “Rad Arheološkog muzeja u Zadru od 1973. do 1976. godine,” Diadora (Zadar), v. 9, 1980, pp. 549–617. Figure 10 Mold for fusing glass. be used only once. For the reproduction of the bowl, we employed a four-part mold (Fig. 10). We placed the decorated glass disk inside the mold and heated it in the kiln. The spaces between the parts of the mold served as absorption areas, which, together with the absorption capability of the aerated concrete, allowed us to successfully reproduce the ancient glass piece. After fusing, the bowl had to be cut to smooth and polish the rim. Conclusion The recently opened Museum of Ancient Glass houses a large collection of Roman glass that was uncovered in sev eral archaeological excavations at ancient cemeteries in and around Zadar. It includes a facility for conducting experiments that are designed to explore ancient glassmaking techniques, as well as a department for restoring broken or damaged objects. About 100 objects have been restored, and 21 have undergone intensive work. In addition to developing all of the museum’s departments, future goals include extending collaborative efforts with other cultural, educational (e.g., Zadar University), and tourist organizations in Zadar. The museum should also become a key Croatian institution for research on glass and glassmaking. Daintith 1988 C. A. Daintith, Conservazione e restauro dei reperti di vetro, Siena, 1988. Domijan 2009 Miljenko Domijan, Izgradnja i otvaranje Muzeja an tičkog stakla u Zadru, Zadar, 2009. Fadić 1997 Ivo Fadić, Trasparenze imperiali: Vetri romani dalla Croa zia, Milan: Skira, 1997. Fadić 2006a Ivo Fadić, Argyruntum u odsjaju antičkog stakla, Zadar: Arheoloski Muzej, 2006. Fadić 2006b Ivo Fadić, “Lokalitet: Zadar-Relja (Relja vrt),” Hrvatski Arheološki Godišnjak (Zagreb), no. 3, 2006, pp. 350–351. Gluščević 2002 Smiljan Gluščević, “Rasprostiranje zadarskih nekropola,” Histria Antiqua (Pula), v. 8, 2002, pp. 381–384. Hill 1993 L. K. Hill, “Briga o zbirkama stakla,” in Osnove zaštite i izlaganja muzejskih zbirki, Zagreb: MDC (Muzejski Dokumentacijski Centar), 1993, pp. 92–95. Isings 1957 Clasina Isings, Roman Glass from Dated Finds, Groningen: J. B. Wolters, 1957. 80 Perović Mandruzzato and Marcante 2007 Luciana Mandruzzato and Alessandra Marcante, Vetri antichi del Museo Archeologico Nazionale di Aquileia: Balsamari, olle e pissidi, Venice: Comitato Nazionale Italiano dell’AIHV, 2007. Mertik and Lemajič 2007 Nina Mertik and Gorazd Lemajič, “Conservation of a Glass Cup Using a Transparent Mould Technique,” Glass and Ceramics Conservation 2007, proceedings of the Interim Meeting of the ICOM-CC Working Group, August 27–30, 2007, Nova Gorica, Slovenia, ed. Lisa Pilosi, Nova Gorica: Grafika Soča, 2007, pp. 83–84. Moretti 2001 Cesare Moretti, “Le techniche di fabricazione dei vetri archeologici,” Vetri di ogni tempo. Atti della V giornata Nazionale di Studio (Massa Martana, Perugia), October 30, 1999, Milan, 2001, pp. 57–71. Drobci antičnega stekla = Fragments of Ancient Glass, Koper, Slovenia: Univerza na Primorske, Znanstveno-raziskovalno središče, Inštitut za dediščino Sredozemlja, 2004, pp. 145–149. Stern 1995 E. Marianne Stern, Roman Mold-Blown Glass: The First through Sixth Centuries, [Rome]: “L’Erma” di Bretschnei der in association with The Toledo Museum of Art, 1995. Venturini 2000 Giuseppe Venturini, “Le fasi operative: La pulitura, la ricomposizione, l’integrazione,” in Vitrum: La materia, il degrado, il restauro, ed. Silvia Vilucchi, Florence: Edifir, 2000, pp. 34–37. Moretti 2002 Cesare Moretti, Glossario del vetro veneziano: Dal Tre cento al Novecento, Venice: Marsilio Editori, 2002. Nappo 2004 S. C. Nappo, “Pompei,” Le guide di Archeo, v. 2, Milan, 2004, pp. 105–107. Pallecchi 2000 Pasquino Pallecchi, “I processi di degrado del vetro archeologico,” in Vitrum: La materia, il degrado, il restauro, ed. Silvia Vilucchi, Florence: Edifir, 2000, pp. 25–28. Perović 2008 Šime Perović, Antičko staklo: Restauracija, Zadar: Mu zej Antickog Stakla, 2008. Perović forthcoming Šime Perović, “Tehnologija proizvodnje neprozirnih stakala u antici,” in Materijali međunarodnog kongresa u Crikvenici o keramičarskim i staklarskim radionicama, Crik venica, forthcoming. Petek 2004 Brigita Petek, “Restavriranje/konserviranje stekla,” in The Museum of Ancient Glass in Zadar (Croatia) 81 Glass and Ceramics Conservation 2010 Interim Meeting of the ICOM-CC Working Group October 3–6, 2010 Corning, New York, U.S.A. Hannelore Roemich, Editorial Coordinator ICOM Committee for Conservation in association with The Corning Museum of Glass © 2010 International Council of Museums ICOM-CC Glass and Ceramics Working Group Committee: Gerhard Eggert Coordinator Hannelore Roemich Editorial Coordinator Review Panel for Papers Renske Dooijes, Leiden, The Netherlands Gerhard Eggert, Stuttgart, Germany Agnès Gall-Ortlik, Barcelona, Spain Isabelle Garachon, Amsterdam, The Netherlands Stephen P. Koob, Corning, New York, U.S.A. Laurianne Robinet, Gif-sur-Yvette, France Kate van Lookeren Campagne, Amsterdam, The Netherlands For The Corning Museum of Glass: Editor: Richard W. Price Design and Typography: Jacolyn S. Saunders Editorial Adviser: David Whitehouse Proofreader: Monica S. Rumsey Reference Librarian: Gail P. Bardhan ISBN: 978-0-87290-182-7 Library of Congress Control Number: 2010931220 All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, whether electronic or mechanical, including photocopying, recording, or otherwise, without the prior permission in writing of the publisher. Cover Image: Cire perdue figure made by Frederick Carder in the 1930s or 1940s, with a repair in which the epoxy is badly yellowed. The Corning Museum of Glass (59.4.426).