Ash Shutbah: A possible impact structure in Saudi Arabia
Transcription
Ash Shutbah: A possible impact structure in Saudi Arabia
Meteoritics & Planetary Science 49, Nr 10, 1902–1914 (2014) doi: 10.1111/maps.12369 Ash Shutbah: A possible impact structure in Saudi Arabia Edwin GNOS1*, Beda A. HOFMANN2, Martin SCHMIEDER3, Khalid AL-WAGDANI4, Ayman MAHJOUB4, Abdulaziz A. AL-SOLAMI4, Siddiq N. HABIBULLAH4, Albert MATTER5, and Carl ALWMARK6 1 Natural History Museum Geneva, Route de Malagnou 1, CP 6434, 1205 Geneva 6, Switzerland 2 Natural History Museum Bern, Bernastrasse 15, 3005 Bern, Switzerland 3 Western Australian Argon Isotope Facility, Department of Applied Geology and JdL Centre, Curtin University, GPO Box U1987, Perth, Western Australia 6845, Australia 4 Saudi Geological Survey, P.O. Box 54141, Jeddah 21514, Kingdom of Saudi Arabia 5 Institute of Geological Sciences, University of Bern, Baltzerstrasse 1+3, 3012 Bern, Switzerland 6 Department of Geology, Lund University, S€ olvegatan 12, 223 62 Lund, Sweden * Corresponding author. E-mail: [email protected] (Received 16 October 2013; revision accepted 31 July 2014) Abstract–We have investigated the Ash Shutbah circular structure in central Saudi Arabia (21°370 N 45°390 E) using satellite imagery, field mapping, thin-section petrography, and X-ray diffraction of collected samples. The approximately 2.1 km sized structure located in flat-lying Jurassic Tuwaiq Mountain Limestone has been nearly peneplained by erosional processes. Satellite and structural data show a central area consisting of Dhruma Formation sandstones with steep bedding and tight folds plunging radially outward. Open folding occurs in displaced, younger Tuwaiq Mountain Limestone Formation blocks surrounding the central area, but is absent outside the circular structure. An approximately 60 cm thick, unique folded and disrupted orthoquartzitic sandstone marker bed occurring in the central area of the structure is found 140 m deeper in undisturbed escarpment outcrops located a few hundred meters west of the structure. With exception of a possible concave shatter cone found in the orthoquartzite of the central area, other diagnostic shock features are lacking. Some quartz-rich sandstones from the central area show pervasive fracturing of quartz grains with common concussion fractures. This deformation was followed by an event of quartz dissolution and calcite precipitation consistent with local sea- or groundwater heating. The combination of central stratigraphic uplift of 140 m, concussion features in discolored sandstone, outward-dipping concentric folds in the central area, deformation restricted to the rocks of the ring structure, a complex circular structure of 2.1 km diameter that appears broadly consistent with what one would expect from an impact structure in sedimentary targets, and a possible shatter cone all point to an impact origin of the Ash Shutbah structure. In fact, the Ash Shutbah structure appears to be a textbook example of an eroded, complex impact crater located in flat-lying sedimentary rocks, where the undisturbed stratigraphic section can be studied in escarpment outcrops in the vicinity of the structure. INTRODUCTION Saudi Arabia covers an area of more than two million square kilometers. In 2012, the international Meteorite Impact Database (http://www.passc.net/ EarthImpactDatabase/) contained only the three small, © The Meteoritical Society, 2014. approximately 300-year-old Wabar impact craters located in sand dunes of the Rub al Khali desert (Fig. 1), the impact origin of which had been confirmed on the ground (e.g., Philby 1933a, 1933b; Wynn 2002; Prescott et al. 2004; Gnos et al. 2013). Eight additional circular features (Fig. 1) may represent impact craters: 1902 Ash Shutbah: A possible impact structure in Saudi Arabia 1903 Fig. 1. Overview map of the Arabian Peninsula. Stars indicate locations of the Ash Shutbah structure located south of Al Haddar, and of other possible and proven impact crater sites in Saudi Arabia. The approximately 5 km Jabal Rayah (or Al Madafi), the approximately 2.1 km Ash Shutbah, and the approximately 17 km Wadi Na’am structures have been proposed as possible impact craters on the basis of remote sensing or field mapping studies (Janjou et al. 2004; Schmieder et al. 2009; Gnos et al. 2011; references therein). The approximately 34 km Saqqar structure, the approximately 19 km Jalamid structure, the approximately 16 km Hamidan structure, the approximately 12 km Banat Baqar structure, and the approximately 5 km Zaynan structure, which are all complex subsurface features, have recently been discussed as of possible impact origin based on seismic and drill core evidence (Neville et al. 2014). The purpose of a first field exploration in 2011 was to verify on the ground whether the very prominent, approximately 2.1 km sized, circular Ash Shutbah structure located on the Jabal Tuwaiq plateau south of Riyadh in an area devoid of volcanic rocks or salt diapirism could represent an eroded impact crater. THE ASH SHUTBAH CIRCULAR STRUCTURE The Ash Shutbah circular structure centered at 21°370 N 45°390 E, approximately 50 km S of the village of Al Haddar (Figs. 1 and 2), is located in flat-lying limestones of the middle Jurassic Tuwaiq Mountain Limestone Formation with a local thickness of 87 m (Steinecke and Sanders 1958; Powers et al. 1966; Vaslet Fig. 2. Landsat 7 Thematic Mapper image, bands 7, 4, 2 in red, green, and blue. The image shows the Ash Shutbah impact structure located in Tuwaiq Mountain Limestone Formation near the edge of the Jabal Tuwaiq escarpment. The escarpment to the west mainly consists of dark weathering Dhruma Formation sandstones and limestones. et al. 1985). Its western margin is located approximately 500 m from the approximately 200 m high Jabal Tuwaiq escarpment, an erosional feature forming a several hundred kilometer long, NE-trending, prominent topographic feature (Figs. 2 and 3) in central Saudi Arabia. The Ash Shutbah circular structure is located at the upper end of Wadi Ash Shutbah and was named accordingly (Schmieder et al. 2009; Gnos et al. 2011). The Tuwaiq Mountain Limestone forms the western part of Jabal Tuwaiq (Fig. 2; Table 1). Middle Jurassic Dhruma Formation (Steinecke and Sanders 1958; Powers et al. 1966; Vaslet et al. 1985) (Fig. 2) is exposed in the escarpment below the limestone. Whereas the Tuwaiq Mountain Limestone consists of pure limestones, abundant sandstone beds containing some dolomite characterize the Dhruma outcrops in this area (Vaslet et al. 1985; Table 1). The base of the cliff is formed by Lower Jurassic Marrat Formation comprising sandstones, conglomeratic sandstones, and pedogenic claystone (Table 1). This formation uncomfortably overlies Permo-Triassic strata (Minjur Formation; Steinecke and Sanders 1958; Powers et al. 1966; Vaslet et al. 1985; Table 1). The total thickness of 1904 E. Gnos et al. Fig. 3. N–S and W–E topographic lines across the Ash Shutbah structure. Data are from the Shuttle Radar Topographic Mission. Note the very weak topographic expression of the structure (marked with boxes). Table 1. Lithostratigraphy of the Jabal Rayah area based on Vaslet et al. (1985). Age Formation Lower Kimmeridgian or Tithonian Early Kimmeridgian Oxfordian Arab Middle to Late Callovian Bajocian to Lower Callovian Toarcian Jubaila Limestone Hanifa Tuwaiq Mountain Limestone Dhruma Marrat Thickness (m) 65 112 118 93.5 157 9 sediments below the Tuwaiq Mountain Limestone, and overlying the crystalline basement, is approximately 400 m, consisting of 166 m Jurassic and 230 m of Permo-Triassic (Vaslet et al. 1985). All these sediments are shale- and sandstone-dominated and do not contain significant evaporite layers (Vaslet et al. 1985). The circular Ash Shutbah feature was mapped and interpreted as a circular feature of carstic origin (Vaslet et al. 1985). The structure was independently rediscovered by two of us (B.A.H, M.S.) on satellite imagery available on Google Earth. We then used Lithology White gypsum with white, beige, or gray bioclastic, peletoid, or oolitic limestones and dolomites Cream to brown carbonate sandstone and dolomitic limestone Brown, yellow, and white sandy dolomite or carbonate sandstone with local sandstone beds Cream to white, bioclastic to oolitic limestone with corals Tan, khaki to red-brown sandstones with sandy dolomite and gypsiferous claystone layers White or red sandstones and conglomeratic sandstones with pedogenic claystone satellite data to further characterize the structure and correlate features on satellite imagery with field observations. Remote Sensing Although the Ash Shutbah structure is only approximately 2.1 km in diameter, a circular feature with a central dark dot is easily recognizable on satellite imagery (Fig. 2), where two branches of the upper Wadi Ash Shutbah follow the outermost circular feature. The Ash Shutbah: A possible impact structure in Saudi Arabia 1905 Fig. 4. Landsat 7 ETM+, bands 3, 2, 1 in red, green, and blue, merged with band 8 over Shuttle Radar Topographic Mission (29 vertical exaggeration). Note the dark color in the lower part of the escarpment produced by debris from a 60 cm thick orthoquartzite bed. The same marker bed occurs in the central part of the Ash Shutbah impact crater. morphological expression, as revealed by Shuttle radar data (SRTM), is very weak (Fig. 3). Nonetheless, due to lithological contrast, a dark central area is clearly distinguishable on satellite images. The compositional variability of sedimentary units exposed in the Ash Shutbah structure is particularly apparent in multispectral band ratio images that are commonly used for the “mapping” of arid areas (band ratio image 5/35/7-3/1 in red, green, and blue using the 5/7 “clay mineral” and 3/1 “iron” band ratios; e.g., Gad and Kusky 2006; Schmieder et al. 2013; Fig. S1). Whereas the Tuwaiq Mountain Limestone Formation and the overlying desert regolith and wadi gravels appear in green, yellow, and pale bluish colors, the partially siliciclastic underlying Dhruma Formation exposed near the base of the Tuwaiq escarpment and in the central domain of the Ash Shutbah structure appears in dark crimson (Fig. S1). On a Landsat 7 ETM+ image (bands 3, 2, 1 in red, green, and blue, merged with Landsat band 8 over SRTM), the situation is displayed in a 3-D view in visible color, showing the dark central core (Fig. 4). The dark beds forming the lower part of the escarpment have the same spectral response as the rocks occupying the central part of the Ash Shutbah feature. In this view, it is also well visible that the structure has been eroded to the plain level. Field Observations The Ash Shutbah circular structure was assessed from the direction of Al Haddar village (Fig. 2), from where a gravel road leads onto the Jabal Tuwaiq plateau. Fieldwork was conducted from May 9 to 12, 2011. The visit to the Ash Shutbah area confirmed that the original morphological expression of the circular structure has been strongly eroded by desert alteration and wind erosion (peneplenation). However, the size of the structure as mapped on the ground and the circular features recognizable on satellite images are in good agreement. The circular structure is located in undeformed, essentially flat-lying limestone beds of the Tuwaiq Mountain Limestone, with a regional dip of about 1° to the east (Fig. 2). The relief between hilltops and depressions within the circular feature is <15 m. Nonetheless, small hills stand above the flat plateau and are easily recognizable when approaching by car. The eastern limit of the ring structure and the two branches of Wadi Ash Shutbah forming circular features seem to lie outside of the areas displaying a weak topography (Fig. 3). The geological map shown in Fig. 5 has been produced using a combination of data from compass, GPS and altimeter measurements, and satellite imagery. The center of the circular structure is located at 21°37.140 N/45°39.350 E. The dark-colored central area, approximately 400 m wide (Fig. 6a), consists of strongly folded, cream-colored calcareous sandstone of the Dhruma Formation (Fig. 6b) and is littered with black, desert-varnish–covered debris of a massive, only 60 cm thick, orthoquartzite (quartzcemented sandstone) bed of the Dhruma Formation (Fig. 6c). One possible concave shatter cone was found in a small outcrop of this orthoquartzite (Fig. 6d). It was left intact at its original position at 21°37.130 N/45°39.370 E for future on-site inspection. In comparison to undeformed cream-colored Dhruma Formation samples from the escarpment, rocks from the central area of the ring structure are locally discolored and white (Fig. 6e). 1906 E. Gnos et al. Fig. 5. Geological map of the Ash Shutbah area. Note the location at the edge of an escarpment. This permits us to locate the marker bed outcropping in the central uplift (black line) in an undisturbed stratigraphic section in the escarpment 500 m to the west of the structure. The position of the marker bed is indicated in the cross section. The silicified coral beds are not shown in the profile because several horizons have been described in the Jabal Tuwaiq limestone by Vaslet et al. (1985). Morphologically, the calcareous sandstones forming the central part of the circular feature are more intensely eroded than the surrounding ring of Tuwaiq Mountain Limestone hills (Fig. 6a). Good outcrops permitting a more detailed structural analysis of this central part are lacking. The outer annular ridges of the structure consist of displaced packages of open folded but stratigraphically undisturbed Tuwaiq Mountain Limestone containing abundant, locally silicified, coral beds and occasionally reddish marly beds. Silicified corals are stained with a dark desert varnish. This is the reason why they can be distinguished from the surrounding carbonate beds on satellite images and mapped as a separate subunit (Fig. 5). The structure shows shallow ring-shaped depressions produced by erosion. Because several levels of silicified corals have been reported in the Tuwaiq Mountain Limestone (Vaslet et al. 1985), this information has not been included in the profile (Fig. 5) and was not used for stratigraphic correlation. The unique, black-weathering and disrupted orthoquartzitic Dhruma Formation marker bed present in the central area has been located 140 m deeper in outcrops along the escarpment, a few hundred meters west of the circular structure (see cross section in Fig. 5). Ash Shutbah: A possible impact structure in Saudi Arabia 1907 Fig. 6. a) Panoramic view from the innermost Jabal Tuwaiq limestone hill located east of the structure over the central area consisting of Bajocian to lower Callovian sandstones of the Dhruma Formation (dark) and dislocated Callovian Tuwaiq Mountain Limestone blocks. Note the strong erosion (peneplenation) of the structure and the even stronger erosion of the dark central area. b) Isoclinally folded calcareous Dhruma Formation sandstone beds, located in the outer part of the central area. The fold axis plunges away from the center of the structure (see Fig. 7). c) Weathered, steeply dipping, folded, and disrupted, approximately 60 cm thick orthoquartzite marker bed in Dhruma Formation of the central area. The contrasting dark color of the central area is due to desert varnish on debris from the orthoquartzite marker bed littering the surface (see Fig. 6a). d) Possible shatter cone imprint in orthoquartzite bed in the central area. e) Freshly broken sandstone bed in the central part of the structure. The white color is due to the pervasive fracturing of sand grains in this rock. Structures Whereas folded and boudinaged Dhruma Formation beds (Fig. 6c) stand upright at nearly 90° in the central part of the Ash Shutbah structure, they dip outward at shallower angles in the outer part of the central area (Fig. 7). The beds show tight to isoclinal folding (Fig. 6b), with fold axes plunging radially outward (Fig. 7). The plunging is shallower in a north-northwestern sector of the central area and steeper in the southeastern part. As a whole, the structures resemble a dome-shaped extrusion that shows the characteristics of a sheath fold (e.g., Reber 2012). Rare cross-bedding indicates that the beds are not overturned. In general, the dip of the bedding is decreasing in the outer sections of the structure that consists of displaced Jabal Tuwaiq Limestone packages. Within these limestone blocks, open folds are the most obvious structural feature. They are the reason for the changing dip directions of the local bedding (Fig. 7). Brecciation of the limestone has been observed locally, but does not affect entire limestone packages. Samples and Methods Thin sections of 3 Dhruma Formation sandstones from the escarpment and 20 sandstone samples from the Dhruma Formation collected in the central area (Fig. 5) were analyzed for shock deformation features in transmitted and reflected light using a polarizing microscope. To test for the presence of coesite, sandstone samples were crushed to <5 mm and treated with dilute (10%) hydrochloric acid to remove calcite and subsequently with dilute (8%) hydrofluoric acid for 8–12 h to partially remove quartz. In some cases, the treatment was repeated. The washed residue was placed on a Si-monocrystal holder and analyzed on a Philipps 1908 E. Gnos et al. Fig. 7. Structural data collected over the inner part of the structure. Note the steeper orientation of the beds in the central area and the outward plunging fold axes in the outer part of the central uplifted terrain. The plunging is shallower in the NW sector than in the SE sector. Small white stars indicate sandstone sample locations. Ash Shutbah: A possible impact structure in Saudi Arabia PW1800 X-ray diffractometer (XRD) at low scanning speed. 1909 DISCUSSION Remote Sensing PETROGRAPHY OF SANDSTONES FROM THE ASH SHUTBAH STRUCTURE Sandstones of the Dhruma Formation collected from the undisturbed escarpment section outside the Ash Shutbah structure are mature, with well-rounded sand grains (Fig. 8a), and show various degrees of cementation (porosity), with secondary quartz forming oriented quartz overgrowths on detrital grains. Calcite cement occurs only in minor quantities. No evidence of quartz dissolution was observed. Individual sandstone layers are well sorted. In contrast, discolored, white sandstones from inside the Ash Shutbah structure (Fig. 6e) show strong deformation of sand grains, with few sand grains remaining unaffected (Fig. 8b). The macroscopic discoloration is obviously due to the pervasive cracking of quartz grains on a microscopic scale (Fig. 8c), often expressed as concussion fractures (Fig. 8d) as, for example, described from the Coconino sandstone at Meteor Crater, Arizona (Kieffer 1971). Concussion fractures are characterized by fan-shaped cracking patterns at contact points due to collapse of pore space during shock compaction. This leads to a characteristic impinging of grains (Figs. 8d and 8e). Despite a focussed search in the siliciclastic rocks, planar features (PFs) or planar deformation features (PDFs) in quartz have not been found in the studied samples from Ash Shutbah. The deformed Ash Shutbah sandstones consist of an assemblage of shards (Figs. 8c and 8e) of partly fractured sand grains with a matrix of fragments at all scales down to submicroscopic sizes. Individual detrital grains of quartz, but also of rare accessory minerals, are fragmented into several pieces residing in the vicinity of each other. Deformation of quartz is also indicated by strong undulous extinction (Figs. 8c–e), especially of smaller and strongly deformed grains, which is not observed in undeformed reference sandstones from the Tuwaiq escarpment. Some samples show cohesion without calcite cementation (e.g., Fig. 8c), indicating the presence of a small amount of quartz cement. Fractures in sandstone grains are commonly filled by postdeformational calcite cement consisting of large, several millimeter sized calcite crystals completely filling the porosity in some samples. Cementation with calcite is accompanied by strong preferential dissolution of the smaller and more deformed quartz particles, mainly along cracks (Fig. 8f). XRD analysis of the residue obtained by partially dissolving fragments of discolored and other sandstones from the central area in dilute hydrofluoric acid yielded no indication for the presence of coesite in 24 samples. Satellite images show that the center of the 2.1 km sized circular Ash Shutbah structure (Figs. 3 and S1) is occupied by rocks that have the same spectral reflectance as Dhruma Formation beds exposed in the lower part of the approximately 200 m high escarpment located west of the structure. Field observations showed that a unique, only 60 cm thick orthoquartzite marker bed of the Dhruma Formation, resistant to weathering, has developed a dark desert varnish. The debris of this resistant bed litters the central domain of the Ash Shutbah structure and also covers the lower slopes of the Jabal Tuwaiq escarpment outside the impact structure. This is the reason why these areas appear dark on satellite images (Figs. 3 and S1) and why the central area shows a very distinct spectral color contrast to the surrounding limestone. Stratigraphy and Structures Investigations in the field showed that the central part of the ring structure consists of folded Dhruma Formation sandstones and the outer parts of gently deformed and displaced blocks of Tuwaiq Mountain Limestone Formation. Whereas the Dhruma Formation occurs in the escarpment outcrops in a normal stratigraphic position below the Tuwaiq Mountain Limestone Formation (Table 1), outcrops in the central area of the ring structure are at the same level as Tuwaiq Mountain Limestone Formation outcrops, indicating disturbance of the normal stratigraphy. The mapped size of the ring structure is in agreement with the size estimated from remote sensing. The Dhruma Formation sandstones of the central area show steep bedding and radial orientation of folds with outward-plunging fold axes (Fig. 7). Whereas the orthoquartzitic marker bed is undisturbed and flat-lying in outcrops of the escarpment approximately 500 m west of the Ash Shutbah structure, the bed located 140 m higher in the central area is folded, boudinaged, and disrupted. In this bed, a single possible shatter cone (Fig. 6d) was noted. Considering the minor tilt of the flat-lying strata that build up the Tuwaiq Mountain plateau, as well as erosion following the formation of the circular structure, this direct stratigraphic correlation indicates a minimal structural-stratigraphic uplift of at least approximately 140 m at the very center of the Ash Shutbah structure. Estimates of the sizes of dislocated Tuwaiq Mountain Limestone blocks indicate approximately 1910 E. Gnos et al. Fig. 8. Thin-section photographs displaying microdeformation in sandstone samples. a) Undeformed Dhruma Formation orthoquartzitic sandstone (1105-24) from the escarpment. Note the absence of fractures in sand grains. b) Thin-section photograph of discolored sandstone bed (1105-19) from the central area. Quartz displays abundant irregular, subparallel, and fan-shaped fractures with quartz shards filling the space between larger grains. c) Close-up of quartz grains in 1105-19 showing subparallel cracking. Small quartz shards fill pore space between larger grains. d) Radial concussion fractures in quartz caused by indenting quartz grain to the right (in extinction). Pore space is filled with fine quartz shards (1105-19). e) Quartz grain indenting another quartz grain, resulting in characteristic set of subparallel fractures (1105-19). The stronger grain (light gray) contains only a few fissures. f) Fractured quartz grain in sample 1105-6 that was affected by dissolution and precipitation of calcite cement following a fracturing event. The texture clearly shows that carbonate cementation occurred only after fracturing. 250 9 250–1000 m in lateral extent. The vertical thickness of the packages is difficult to estimate without additional stratigraphic information. The field observations confirm that the deformation is restricted to the ring structure, that it is strongest in the center of the structure, and that the bedding becomes progressively steeper toward the center of the structure, indicating doming. Microstructures At the microscale, there is abundant microfracturing of quartz grains resulting in local, macroscopically observed discoloration of sandstones from cream to white inside the central area. The presence of characteristic concussion fractures in quartz grains (with remnant porosity) suggests maximum shock Ash Shutbah: A possible impact structure in Saudi Arabia pressures of approximately 3 GPa (Grieve et al. 1996) at the present erosion level. Similar concussion fractures in quartz were earlier described from weakly shocked sandstones from Meteor Crater, Arizona, USA (Kieffer 1971), but also occur in Middle Jurassic sandstones that build up the central uplift of the approximately 3.8 km Steinheim impact in Germany, which also lacks other high-pressure shock features (Groschopf and Reiff 1969; Buchner and Schmieder 2010). Comparable texture has also been reported from weakly shock-lithified sand from the smallest, 11 m Wabar crater in Saudi Arabia (Gnos et al. 2013), while at the larger two Wabar craters, abundant PDFs are observed in quartz, in association with coesite and stishovite (e.g., Gnos et al. 2013). Planar fractures and feather features in quartz (e.g., Poelchau and Kenkmann 2011), tentatively associated with shock pressures exceeding approximately 5 GPa, were not observed at Ash Shutbah. Thus, evidence for impact-induced deformation seems to be restricted to the lowest level of shock metamorphism (e.g., French 1998). The effect of apparently weak shock deformation is somewhat similar to the low-grade shock features observed at other complex terrestrial impact structures in sedimentary targets, such as Steinheim (Buchner and Schmieder 2010), the approximately 6 km Tin Bider impact structure in Algeria (Lambert et al. 1981), the approximately 8 km Upheaval Dome impact structure in Utah, USA (Buchner and Kenkmann 2008), the approximately 10 km Uneged Uul structure of likely impact origin in Mongolia (Schmieder et al. 2013), the approximately 12 km Marquez Dome in Texas, USA (Buchanan et al. 1998), or the approximately 15 km Yallalie structure in Western Australia (Dentith et al. 1999). All these structures lack clear evidence for higher levels of shock metamorphism. As for these structures, the shock wave generated during the Ash Shutbah impact could have been attenuated and “buffered” within the porous sedimentary target rocks, probably under water-saturated conditions that would have reduced the physical strength of the target rock (e.g., Kenkmann et al. 2011; Kowitz et al. 2013a, 2013b). While most of the Jurassic sedimentary rocks on the Arabian Platform were deposited in a shallow marine environment (such as the coralliferous Tuwaiq Mountain Limestone; e.g., Alsharhan and Magara 1994), the general paleogeographic conditions became progressively continental during the Early Cretaceous, with a marine transgression from the Late Cretaceous until the Eocene, and following emergence and denudation of the Arabian plate during the Neogene (e.g., Powers et al. 1966). In both shallow marine and continental setting cases, seawater and groundwater, respectively, would have been involved in the impact 1911 process. Quartz dissolution and calcite precipitation in sandstones from the central uplift are consistent with impact shock and postshock heating, followed by seaor groundwater inflow. Because quartz solubility is strongly enhanced by increased temperature (Rimstidt 1997), while calcite solubility decreases (Coto et al. 2012), the interaction of a volume of rock with increased temperature with local sea- or groundwater could explain the observed late-stage quartz dissolution and calcite precipitation. Evidence for an Impact Crater The Ash Shutbah structure shows evidence of intense and localized rock deformation at scales ranging from decameters down to the microscopic scale, within a geological setting otherwise devoid of postdepositional deformation. Even though we have not found PFs or PDFs in quartz or high-pressure phases, the steeply inclined, folded, and uplifted sandstone beds, radially outward plunging fold axes in Dhruma Formation sandstones of the central area, and concussion fractures found in the rocks at the center of the complex circular Ash Shutbah structure are strong evidence for an impact origin. Alternative explanations are unsatisfactory. An origin as a karst feature as suggested by Vaslet et al. (1985) can be clearly excluded. Such an origin is inconsistent with the apparent presence of a central uplift and the observed rock deformations. In the case of the approximately 8 km Upheaval Dome impact structure in Utah, USA, an impact scenario was discussed since Shoemaker and Herkenhoff (1983), but the presence of a salt layer under ground led to another interpretation that the structure represented a dissolved salt dome (e.g., Jackson et al. 1998). This view persisted until eventually shocked quartz was documented (Buchner and Kenkmann 2008). In the case of Ash Shutbah, salt tectonics can be definitely excluded. The Cambrian salt deposits of the Arabian Peninsula only occur farther to the east (e.g., Alsharhan and Kendall 1986). The Ash Shutbah structure is underlain by about 400 m of mainly clastic sediments overlying the crystalline basement (Vaslet et al. 1985). Moreover, the subsurface ascent of magma or mud diapirs and the formation of structural domes that commonly show a complex morphology once eroded are not compatible with the small size and isolated occurrence of this exotic feature on the Tuwaiq Mountain plateau and steeply inclined strata inside the central area. Endogenic models for the formation of structurally complex circular structures on the Earth’s surface (e.g., Schmieder et al. 2013) seemingly cannot explain the formation of the Ash Shutbah structure. 1912 E. Gnos et al. Large-scale structural evidence consistent with impact is the presence of a complex circular structure of approximately 2.1 km diameter with a ground-truthed central uplift, intense deformation including concussion fractures in sandstone, restricted to the circular structure, the unique orthoquartzitic marker bed present in the central uplift and located 140 m below in undisturbed outcrops of the escarpment approximately 500 m west of the Ash Shutbah structure, and the finding of a possible shatter cone (Fig. 6d). Considering the minor tilt of the flat-lying strata that build up the Tuwaiq Mountain plateau and erosion following the formation of the circular structure, this direct stratigraphic correlation indicates a minimal structuralstratigraphic uplift of at least approximately 140 m at the very center of the Ash Shutbah structure. Moreover, the localized occurrence of tightly folded beds in otherwise regionally flat-bedded and essentially undeformed sedimentary rocks is only consistent with the interpretation of the Ash Shutbah circular feature as a strongly eroded complex impact crater. If we assume that the plunging of the folds became steeper at a higher, now eroded level of the structure or that the steeper plunging folds became even overturned folds comparable to those at the Waqf as Suwwan structure (Kenkmann et al. 2010), the structural asymmetry within the thrusts and folds of the eroded central uplift observed and mapped in the field (Fig. 7) would indicate an impactor that arrived from the NW (compare Kenkmann and Poelchau 2009). The deep level of erosion below the structural crater floor would be the reason why impact melt lithologies and impactites of the proximal ejecta blanket are missing. Crater Size Estimate A compilation by Grieve (1987) stated that the transition from simple to complex impact craters occurs at approximately 2 km diameter in a sedimentary target (as exemplified by the BP structure in Libya) and at approximately 4 km in crystalline rocks (as in the case of Brent crater in Ontario, Canada). By using the Holsapple (1993) equations, the transition from simple to complex impact craters occurs at approximately 1.8 km. The equation for a complex impact crater: structural uplift = 0.06*crater diameter1.1 (Grieve 1987) yields a minimal structural uplift for the approximately 2.1 km crater of 136 m. Calculations with the Holsapple (1993) scaling laws for impact craters, assuming that the observed 2.1 km outer diameter of the eroded impact structure also represents the approximate original diameter of the fresh crater, yields for a stony or metallic impactor arriving at an angle of 45° and speeds of 5–15 km s1 a crater rim diameter of approximately 2.8 km with a central peak reaching approximately 25 m above the crater floor. However, based on the facts that the Ash Shutbah circular structure is eroded below the level of the original crater floor (no impactites of the crater-filling breccia lens were encountered in the field) and that the measurable structural uplift of the orthoquartzite marker bed in the central uplift is at least approximately 140 m, it is possible that the original diameter was somewhat larger. However, Ash Shutbah is morphologically comparable to the 2 km diameter BP structure (French et al. 1974; Koeberl et al. 2005). Age of Formation In the absence of any datable material (impactgenerated melt-bearing rocks or shock veins were not detected), the age of the circular structure can only be constrained stratigraphically to younger than the Tuwaiq Mountain Limestone (post-Callovian; <165 Ma; Powers et al. 1966; Vaslet et al. 1985). CONCLUSIONS Even though there is no unequivocal evidence, such as PDFs or confirmed shatter cones, that the Ash Shutbah structure is an impact crater (e.g., French and Koeberl 2010), there are multiple indications that favor an impact origin (1) central stratigraphic uplift of 140 m consistent with estimates using the formula for impact craters (Grieve 1987); (2) concussion fractures in discolored sandstone of the central uplifted terrain, but not in undisturbed sandstone of the outer escarpment; (3) outward-dipping concentric folds in the central ring structure; (4) intense deformation restricted to the rocks of a ring structure; (5) a complex, rather than simple, circular structure of 2.1 km diameter, consistent with the type of impact crater that is expected in a sedimentary target (Holsapple 1993); and (6) a possible shatter cone. The stratigraphic setting indicates a Callovian maximum age for the circular structure. The observed concussion fractures suggest low shock pressure probably reflecting deep erosion and a shock wave buffering effect within the porous and, at that time, possibly “wet” sedimentary target. Strong quartz dissolution and carbonate cementation observed in sandstones of the central uplift with fractured quartz are consistent with postimpact heating and water saturation. The location of the Ash Shutbah structure near the edge of the 200 m high Jabal Tuwaiq escarpment provides a unique situation where the undisturbed stratigraphic sequence and impact-deformed beds can be Ash Shutbah: A possible impact structure in Saudi Arabia studied in close vicinity, comparable to a block diagram (Fig. 4). The geometry and geological situation of the Ash Shutbah circular structure indicate that it is probably a strongly eroded complex impact crater, comparable in size, shape, and structural features to the approximately 2 km BP impact structure in “Nubian Sandstone” of SE Libya (e.g., French et al. 1974; Koeberl et al. 2005). Acknowledgments—Saudi Geological Survey director Dr. Zuhair Nawab, as well as Abdullah al Attas and Saleh al Ghamdi are thanked for granting permission for the project and for logistic support. Mutrif bin Fahad Bin Namsham is thanked for providing accommodation and guidance in Al Haddar. Philippe Wagneur assembled the panoramic view. XRD analyses were performed by Nicolas Greber. This study was supported by the Swiss National Science Foundation grant 200020-119937 and the Natural History Museum of Geneva. T. Kenkmann and W. U. Reimold are thanked for their helpful reviews. Editorial Handling—Dr. W. Uwe Reimold REFERENCES Alsharhan A. S. and Kendall C. G. S. C. 1986. Precambrian to Jurassic rocks of Arabian Gulf and adjacent areas: Their facies, depositional setting, and hydrocarbon habitat. The American Association of Petroleum Geologists Bulletin 70:977–1002. Alsharhan A. S. and Magara K. 1994. The Jurassic of the Arabian Gulf Basin: Facies, depositional setting and hydrocarbon habitat. In Pangea: Global environment and resources, edited by Embry A. F., Beauchamp B., and Glass D. J. Canadian Society of Petroleum Geologists Memoir 17:397–412. Buchanan P. C., Koeberl C., and Reid A. M. 1998. Impact into unconsolidated, water-rich sediments at the Marquez Dome, Texas. Meteoritics & Planetary Science 33:1053– 1064. Buchner E. and Kenkmann T. 2008. Upheavel Dome, Utah, USA: Impact origin confirmed. Geology 3:227–230. Buchner E. and Schmieder M. 2010. Steinheim suevite—A first report of melt-bearing impactites from the Steinheim Basin (SW Germany). Meteoritics & Planetary Science 45:1093– 1107. Coto B., Martos C., Pe~ na J. L., Rodrıguez R., and Pastor G. 2012. Effects in the solubility of CaCO3: Experimental study and model description. Fluid Phase Equilibria 324:1– 7. Dentith M. C., Bevan A. W. R., Backhouse J., Featherstone W. E., and Koeberl C. 1999. Yallalie: A buried structure of possible impact origin in the Perth Basin, Western Australia. Geological Magazine 136:619–632. French B. M. 1998. Traces of catastrophe. A handbook of shock-metamorphic effects in terrestrial meteorite impact structures. LPI Contribution 954. Houston, Texas: Lunar and Planetary Institute. 120 p. 1913 French B. M. and Koeberl C. 2010. The convincing identification of terrestrial meteorite impact structures: What works, what doesn’t, and why. Earth-Science Reviews 98:123–170. French B. M., Underwood J. R., and Fisk E. P. 1974. Shock metamorphic features in two meteorite impact structures, southeastern Libya. Geological Society of America Bulletin 85:1425–1428. Gad S. and Kusky T. 2006. Lithological mapping in the Eastern Desert of Egypt, the Barramiya area, using Landsat thematic mapper (TM). Journal of African Earth Sciences 44:196–202. Gnos E., Al-Wagdani A., Mahjub A., Al-Solami A. A., Allah S. H., Matter A., Hofmann B. A., Schmieder M., and Buchner E. 2011. Ash Shutbah: A new impact crater in Saudi Arabia (abstract #5108). Meteoritics & Planetary Science 46:A79. Gnos E., Hofmann B. A., Tarabulsi Y., Al Halawani M., Hakeem M., Al Shanti M., Greber N., Holm S., Greenwood R. C., and Ramseyer K. 2013. The Wabar impact craters, Saudi Arabia, revisited. Meteoritics & Planetary Science 48:1–15. Grieve R. A. F. 1987. Terrestrial impact structures. Annual Reviews in Earth and Planetary Sciences 15:245–270. Grieve R. A. F., Langenhorst F., and St€ offler D. 1996. Shock metamorphism of quartz in nature and experiment: II Significance in geoscience. Meteoritics & Planetary Science 31:6–35. Groschopf P. and Reiff W. 1969. Das Steinheimer Becken. Ein Vergleich mit dem Ries. Geologica Bavarica 61:400–412. (In German) Holsapple K. A. 1993. The scaling law of impact processes in planetary sciences. Annual Review of Earth and Planetary Sciences 21:333–373. Jackson M. P. A., Schultz-Ela D. D., Hudec M. R., Watson I. A., and Porter M. L. 1998. Structure and evolution of Upheaval Dome: A pinched-off salt diapir. Geological Society of America, Bulletin 110:1547–1573. Janjou D., Wyns R., Halawani M. A., and Memesh A. 2004. A geological curiosity in NW Saudi Arabia: The Jabal Rayah ring structure. Data-file report SGS-DF-2004-3.1-8. Jiddah: Saudi Geological Survey. 8 p. Kenkmann T. and Poelchau M. H. 2009. Low-angle collision with Earth: The elliptical impact crater Matt Wilson, Northern Territory, Australia. Geology 37:459–462. Kenkmann T., Reimold W. U., Khirfan M., Salameh E., Khoury H., and Konsul K. 2010. The complex impact crater Jebel Waqf as Suwwan in Jordan: Effects of target heterogeneity and impact obliquity on central uplift formation. Geological Society of America, Special Papers 465:471–487. Kenkmann T., W€ unnemann K., Deutsch A., Poelchau M. H., Sch€ afer F., and Thoma K. 2011. Impact cratering in sandstone: The MEMIN pilot study on the effect of pore water. Meteoritics & Planetary Science 46:890–902. Kieffer S. W. 1971. Shock metamorphism of the Coconino sandstone of Meteor Crater, Arizona. Journal of Geophysical Research 76:5449–5479. Koeberl C., Reimold U., and Plescia J. 2005. BP and Oasis impact structures, Libya: Remote sensing and field studies. In Impact tectonics, edited by Koeberl C. and Henkel H. Heidelberg: Springer. pp. 161–190. Kowitz A., G€ uldemeister N., Reimold W. U., Schmitt R. T., and W€ unnemann K. 2013a. Diaplectic quartz glass and 1914 E. Gnos et al. SiO2 melt experimentally generated at only 5 GPa shock pressure in porous sandstone: Laboratory observations and meso-scale numerical modeling. Earth and Planetary Science Letters 384:17–26. Kowitz A., Schmitt R. T., Reimold W. U., and Hornemann U. 2013b. First MEMIN shock recovery experiments in dry, porous sandstone at low shock pressure (5-12.5 GPa). Meteoritics & Planetary Science 48:99–114. Lambert P., McHone J. F., Dietz R. S., Briedj M., and Djender M. 1981. Impact and impact-like structures in Algeria – Part II: Multi-ringed structures. Meteoritics 16:203–227. Neville A. S., Cook D. J., Afifi A. M., and Stewart S. A. 2014. Five buried crater structures imaged on reflection seismic data in Saudi Arabia. GeoArabia 19:17–44. Philby H. S. J. 1933a. The empty quarter. London: Constable and Company Ltd. pp. 1–433. Philby H. S. J. 1933b. Rub’ al Khali: An account of exploration in the Great South Desert of Arabia under the auspices and patronage of his majesty ‘Abdul ‘aziz ibn Sa’ud, King of Hejaz and Nejd and its dependencies. The Geographical Journal 81:1–21. Poelchau M. H. and Kenkmann T. 2011. Feather features: A lowshock-pressure indicator in quartz. Journal of Geophysical Research 116:B02201. doi:10.1029/2010JB007803. Powers R. W., Ramirez L. F., Redmond C. D., and Elberg E. L. J. 1966. Sedimentary geology of Saudi Arabia. U.S. Geological Survey Professional Paper 560-D:D1–D147. Prescott J. R., Robertson G. B., Shoemaker C., Shoemaker E. M., and Wynn J. 2004. Luminescence dating of the Wabar meteorite craters, Saudi Arabia. Journal of Geophysical Research 109:1–8. Reber J. E. 2012. Sheath folds in simple shear: An analytical and experimental study. Ph.D. thesis, University of Oslo. 127 p. Rimstidt J. D. 1997. Quartz solubility at low temperatures. Geochimica et Cosmochimica Acta 61:2553–2558. Schmieder M., Buchner E., Hofmann B. A., and Gnos E. 2009. The Ash Shutbah circular feature—A suspected meteorite impact site in Saudi Arabia. Abstract, The First Arab Impact Cratering and Astrogeology Conference. pp. 84–85. Schmieder M., Seyfried H., and Gerel O. 2013. The circular Uneged Uul structure (East Gobi Basin, Mongolia)— Geomorphic and structural evidence for meteorite impact into an unconsolidated coarse-clastic target? Journal of Asian Earth Sciences 64:58–76. Shoemaker E. M. and Herkenhoff K. E. 1983. Impact origin of Upheaval Dome, Utah. Eos (Transactions, American Geophysical Union) 44:747. Steinecke M. and Sanders N. J. 1958. Stratigraphic relations of Arabian Jurassic oil. Habitat of oil. American Association of Petroleum Geologists Symposium. pp. 1294–1329. Vaslet D., Pellaton C., Manivit J., Le Nindre Y.-M., Brosse J.-M., and Fourniguet J. 1985. Geological map of the Sulayymah quadrangle, sheet 21H, Kingdom of Saudi Arabia, with explanatory notes. Jeddah: Saudi Geological Survey. Wynn J. C. 2002. Mapping an iron-meteorite impact site with a magnetometer, and implications for the probability of a catastrophic impact on Earth. Journal of Environmental & Engineering Geophysics 7:143–150. SUPPORTING INFORMATION Additional supporting information may be found in the online version of this article: Fig S1. Multispectral Landsat-7 ETM+ satellite image (scene of path 166, row 045, acquired on 20 February 2005) of the Wadi Ash Shutbah area and the Tuwaiq escarpment in central Saudi Arabia, with a closeup of the Ash Shutbah structure shown in the inset. Both scenes are color composite images of band ratios 5/3, 5/7, 3/1 RGB pan-sharpened with band 8 (15 m ground resolution), in which different lithologic units can be distinguished. Whereas the Tuwaiq Mountain Limestone and overlying gravels appear in green, yellow, and bluish colors, the underlying siliciclastic Dhruma Formation shows a crimson color at the base of the Tuwaiq escarpment due to scree derived from the orthoquartzite bed (crimson color along the slope at approximately 830 m above sea level) and is also exposed in the central area of the Ash Shutbah structure (approximately 970 m above sea level). Image credit: USGS and Global Land Cover Facility.