best choice guidelines

BEST CHOICE
GUIDELINES
For the CONSUMER PRODUCTS INDUSTRY
ECacOceCptEedRT
®
ndly
al b el frie
plan
t-ba
sed
Nature-M ade
ble
a
w
e
n
re source
re
.
.
.
f
i
What
biodegradable
new features
Bal pH
ance
TM
thick
thin
e
manipouslitaty
visc
Gels
MULTI
-FUNC
TIONA
L
F
Formi lm
in g
E
OVERCOM L
TECHNICA
HURDLES
e
stabiliz
cling
d
n
e
susp
VERSATILITY
good stuf
f
inc lusions
ff
fun stu
YOU
CAN
BEST CHOICES
F OR THE C O N S U M ER P RO D U C T S I N D U S TR Y
Our Company
With an extensive range of specialty hydrocolloids, CP Kelco brings ideas, products and solutions to a wide variety of
end-use applications. Hydrocolloid technology is based in the science and understanding of rheology, and continues
with innovative products designed to capitalize on this science.
CP Kelco draws on decades of experience at the forefront of developing hydrocolloids for beverages, food, cosmetics,
personal care, oral care, household cleaners, fabric care, pharmaceutical, paper, paints and coatings, oilfield and deep sea
drilling, construction, agrichemicals, mining, … the application space is endless.
With over 200 years accumulated experience in the manufacturing, manipulation and application of multiple
hydrocolloids, CP Kelco offers a deep understanding on the use of our products to provide the results customers
expect from their finished product.
Our mission is to continuously evolve and innovate our product offering, improve our service and application
knowledge, and leverage learnings across our manufacturing and product portfolio to the benefit of the customer.
Our goal is to leverage our fermentation, extraction and cellulosics knowledge to develop products and formulations
that make our customers more competitive in their market space.
With strategically located manufacturing sites, R&D facilities, commercial and corporate offices around the world,
CP Kelco is more than equipped to exceed the global and local requirements of our customers.
CP Kelco’s Application Development and R&D teams thrive on customers who challenge us with their “What If…”.
Recent innovations span across multiple industries:
• Nature-made hydrocolloids for use in personal care and cosmetic industries.
• Novel suspension aids for unique low-viscosity formulations.
• New biopolymers engineered to withstand challenging physical and chemical environments.
• Purified Carboxymethyl Cellulose for improved anti-redeposition on fabrics
CP Kelco’s teams of Chemists, Microbiologists, Chemical Engineers and Application Scientists bring industry training
and decades of experience to develop solutions which fulfill individual customer needs.
LEGEND
Manufacturing Site
Technical Support Center
Lille Skensved, Denmark
Customer Service Center
Center of Excellence
Sales Offices
Äänekoski, Finland
Nijmegen, The Netherlands
Moscow, Russia
Aberdeen, Scotland
Rizhao, Shandong, China
Poznan, Poland
Houston, Texas, USA
Leatherhead, United Kingdom
Okmulgee, Oklahoma, USA
Seoul, Korea
Tokyo, Japan
Großenbrode, Germany
Paris, France
Shanghai, China
Beringen, Belgium
Taixing, Jiangsu, China
San Diego, California, USA
Atlanta, Georgia, USA
Mumbai, India
Corporate Headquarters
Limeira, Brazil
Sibonga, Cebu, Philippines
Singapore
Buenos Aires, Argentina
Melbourne, Australia
One CP Kelco Quality Standard
CP Kelco is a world-wide operation, with manufacturing facilities and a customer base
which spans the globe. This reach requires that CP Kelco abides by one global quality
standard that does not vary by the location of the production facility or the customer
location. Producing consistent, defect-free, high performance ingredients is what differentiates
CP Kelco and creates a sustainable business.
The one CP Kelco Quality Standard ensures the production of safe, high quality ingredients for our customers. The
new global regulatory environment requires elevated compliance and harmonized audit procedures, and requires
accountability and visibility to external parties.
Marketing to regulated industries such food, pharmaceutical and cosmetics, requires compliance with current Good
Manufacturing Practices (cGMPs). Compliance to cGMPs, along with fully developed and audited HACCP plans,
established raw material certification and qualification procedures and participating in customer and third party audits
makes up the foundation of the One CP Kelco Quality Standard.
All CP Kelco manufacturing facilities sustain ISO 9001:2008 certification to ensure compliance to internationally
recognized quality management standards. The benefits of a valid ISO 9001:2008 certificate demonstrate that CP Kelco
follows the most internationally recognized quality management requirements.
GMA-SAFE audits are currently being conducted at all CP Kelco facilities. The GMA-SAFE Assessment is a highly
intensive audit process that provides sufficient information to any customer to determine whether the inspected facility
meets global recognized standards for quality systems and regulatory compliance.
Added focus is being placed on food safety as all CP Kelco facilities are audited for compliance to the Global Food
Safety Initiative, Food Safety System Certification (FSSC) 22000. This global food safety management standard continues
to build on existing quality management systems and validates CP Kelco food safety systems across the globe and has
been audited and certified to the GFSI.
Global
Food Safety
Initiative (GFSI)
(Customer
Requirements)
cGMP and
Prerequisite Programs
To Develop
HACCP Plan for Every Facility
(Regulatory Requirements)
ISO 9001:2008
CP Kelco’s QMS is in compliance to the
Internationally recognized standard
(CP Kelco Requirements)
BEST CHOICES
F OR THE C O N S U M ER P RO D U C T S I N D U S TR Y
Our Philosophy
What if...
Founded over 100 years ago, CP Kelco has continued on
an indelible path of turning your What if… ideas into
YOU CAN! Products.
What If… is about YOU, our Customer. CP Kelco is
committed to helping create the next generation of
products or improve upon existing products to meet
the ever-changing needs of consumers.
The core of What if… is our ability to listen to
your needs, capitalize on our internal capabilities
and established application expertise and allow our
talents to become your tools to implement successful,
differentiated brands.
Our goal as a partner is to provide the Best Choices for
your brands so that your individual What if… becomes
a YOU CAN! reality.
We value our relationships because we know that
strong partnerships cultivate growth and success – for
our customers, our shareholders and our employees.
.
.
.
f
i
t
a
Wh
o
nted t th
a
w
u
i
Yo
ash w
w
h
t
u
o
your m r minerals?
e
c
n
a
enh tanicals o
bo
Y
wit ou
h
C
CG KEL AN
Xa TRO !
Gu ntha L ®
n
m
obtain a
You cou
ingredie silk-like feel fr ld
o
nt foun
d on ca m an
bbage?
t
a
h
W
What
if...
You wanted to have
a powder detergent formulation
that helps eliminate dirt and
stains from clothes?
h
N! w®it
A
C
You
GEL
KELCO um
G
Gellan
YOU CAN!
with FINNFIX® CMC
...you can
What
rea if...Y
te
ou
! with enan
N
A
C
ge
You ® CG Carra
O
UVISC
to c
from beau wa
sea ty m nted
wee ask
s
d?
.
.
.
f
ti
Wh hat if..
.
TM
to
nted st
a
w
You pH po
skin’s ent?
e
h
t
alize
eatm
norm lkaline tr
a
GEN
You
ave
could a xanthan wanted to
gum
hyd
whilst rate in diffi which
cult m
having
shear superior l edia,
ow
viscos
ity?
N! by
You CA lco’s
Ke
using CP ted
n
new pate nced
® Adva
KELZAN ance
Perform
Gum
Xanthan
.
.
.
f
i
t
Wha
h
AN! witTM
C
u
o
Y
Hresh
GENU p
Pectin
BEST CHOICES
F OR THE C O N S U M ER P RO D U C T S I N D U S TR Y
CP Kelco is the innovation leader in the production of polysaccharides by microbial fermentation, extraction from land and sea plants, and
modification of cellulose-based raw materials CP Kelco’s goal is to be the preferred partner for providing innovative products and solutions
through the use of nature-based chemistry.
Our products are derived from natural, renewable raw materials, and CP Kelco strives to provide these products with minimal processing or
modification. These products serve many functions, including suspension, stabilization, film forming, unique spray patterns, and gelation, as well
as providing a range of sensory and texture attributes.
Given this leadership position, CP Kelco has evolved into more than just an ingredient supplier. We pride ourselves on how, with a combination
of a vast product portfolio and our application expertise, we provide solutions to the most creative and difficult product design challenges.
CP Kelco understands how to consider manufacturing needs and consumer desires when selecting the most appropriate product from our extensive
portfolio. Many factors must be taken into consideration, including desired flow behavior or texture, required shelf-life, production equipment available,
compatibility with other ingredients and regulatory compliance. Rheology is defined as the study of the flow of matter: primarily liquid state, but also as
‘soft solids’ or solids under conditions in which they respond with plastic flow rather than deforming elasticity in response to an applied force.
Within the consumer products industry, rheology control is vital. However, selecting the most appropriate rheology modifier from the wide range
commercially available is far from straightforward. Many factors must be taken into consideration, including the desired flow behavior or texture, the
required shelf-life, the production equipment available, compatibility with other ingredients, regulatory compliance and environmental friendliness.
Designed to offer solutions across the consumer products spectrum, CP Kelco’s vast ingredient choices enable the most challenging - and creative household and personal care concepts to become consumer products.
Whether it’s suspending botanicals in the latest new-age bodywash, manipulating gel textures in air fresheners, improving the sprayability of tanning
products, or creating cleaners from bio-based materials, CP Kelco offers a portfolio of products and application expertise to suit the needs of
consumer products manufacturers worldwide.
A Little About Our Chemistries
Rheological Terms
Shear Stress: the amount of force/presure that is applied to a sample
in order to cause movement at some rate.
Shear Rate: the rate or speed of fluid movement.
Viscosity: the relationship of shear rate to the shear stress applied.
Newtonian rheology: at a given temperature, the viscosity measured
is constant as the shear rate vaires (examples are water and thin
motor oil). Newtonian fluids in rality are not very common. Most
fluids are Non-Newtonian; i.e. as the shear rate varies, the shear stress
does not vary proprotionally.
Pseudoplastic rheology: viscosity decreases as shear rate increases
(shear-thinning).
CEKOL® & FINNFIX®
Carboxymethyl Cellulose
CP Kelco’s grades of carboxymethyl cellulose
(CMC) are highly-purified, cold watersoluble polymers derived from cellulose.
Carboxymethyl cellulose is versatile, costeffective way to add viscosity.
Thixotropic rheology: rheology decreases over a measurable period
of time as shear rate increases (time-dependent shear-thinning).
CP Kelco offers the industry’s most extensive range of
viscosity grades, with flow properties ranging from nearly-Newtonian to
pseudoplastic. Depending on the grade, they can have either thixotropic
or non-thixotropic rheology.
Our products are derived from natural, renewable raw materials, and
CP Kelco strives to provide these products with minimal processing
or modification. These products serve many functions, including
suspension, stabilization, film forming, unique spray patterns, and
gelation, as well as providing a range of sensory and texture attributes.
By choosing the right CEKOL or FINNFIX type, the formulator has the
ability to achieve the desired rheology for any aqueous system, including
suspensions and emulsions. Besides controlling the rheology, CEKOL
and FINNFIX are known for excellent water retaining and film forming
capacity. FINNFIX CMC is widely used within the fabric care industry as
the anti-redeposit agent of choice in powder laundry detergents.
Bring your next “What if ...” to CP Kelco.
...you can
GENUVISCO® & GENUGEL®
Carrageenan
KELTROL® & KELZAN®
Xanthan Gum
GENUVISCO® and GENUGEL®
Carrageenan products are a family of
sulphated polysaccharides extracted
from certain species of red seaweed Rhodophyceae.
KELTROL® and KELZAN® Xanthan Gums
are produced by a fermentation process
using the bacterium Xanthomonas campestris.
The composition and structure of xanthan gum
produced by commercial fermentation is identical
Xanthan gum’s pseudoplastic flow behavior provides high viscosities
By using the appropriate carrageenan product, the
formulator can create textures ranging from free-flowing liquids to
solid gels. In addition to offering standard types, CP Kelco works
in conjunction with customers to develop new products and
formulations for specific applications.
at low shear rates to improve suspension and emulsification, and low
•
Kappa carrageenan forms firm gels in the presence of sufficient
levels of ions.
•
Iota carrageenan forms elastic gels and thixotropic fluids in the
presence of sufficient levels of ions.
•
Lambda carrageenan forms viscous, non-gelling solutions.
to the naturally occurring polysaccharide formed by Xanthomonas
campestris on plants belonging to the cabbage family.
viscosities at high shear rates to give good flow properties when
poured or pumped. The slight increase in viscosity resulting from
very low use levels imparts the sensation of enhanced body.
GENU® Pectin
KELCOGEL® Gellan Gum
KELCOGEL® Gellan Gum is a polysaccharide
produced by fermentation of a pure culture
of Sphingomonas elodea. The composition
and structure of native gellan gum produced
by commercial fermentation is identical to
the naturally occurring polysaccharide formed by
Sphingomonas elodea on plants of water lily varieties.
The uniqueness of KELCOGEL is the ability to function while
contributing minimal viscosity via the formation of a uniquely
functioning “fluid gel” network. This network, consisting of a
low concentration of weakly associated molecules, is extremely
pseudoplastic. At rest, the fluid gel has a very high apparent viscosity
resulting in excellent suspension of insoluble ingredients. Because of
the weak molecular associations, the network is easily disrupted upon
agitation, resulting in a low viscosity and a smooth pour.
This multi-functional hydrocolloid can be used at low levels in a
wide variety of products that require gelling, texturizing, stabilizing,
suspending, spraying, film-forming and structuring.
KELCOGEL gellan gum is available in two grades: high and low acyl
content, which form soft and firm gels, respectively.
GENU® Pectins are partially methyl
esterified, anionic polysaccharides derived
from naturally occurring structural
components in fruits and vegetables.
Because of its traditional uses in food
products, pectin is well known by consumers and
accepted as label friendly. The major commercial raw
material source is citrus peel, although CP Kelco also produces
pectin derived from sugar beets.
There are two basic types of GENU pectin, differing in Degree of
methyl Esterification (DE):
•
High methylester (HM) pectin, DE higher than 50, forms gels and structured liquids under conditions of low pH and low water activity (for example, at high concentrations of sugar, sorbitol or glycerol).
•
Low methylester (LM) pectin, DE lower than 50, forms gels in
the presence of divalent cations, such as calcium and magnesium.
KELDENT KELZAN
®
xanthan gum
The exceptional thickening and stabilizing
characteristics of CP Kelco’s xanthan gum family
provides a versatile performance for a range of
consumer products. Xanthan gum solutions are
pseudoplastic. At rest, they are viscous. When mixed,
pumped, sprayed or poured, the solution’s thin. Once
shear is removed, the solution recovers to starting viscosity
almost immediately. Xanthan gum has outstanding stability to
pH, salt and/or heat, and excellent compatibility with other ingredients. It
is readily soluble in both hot and cold water. CP Kelco’s xanthan gum grades are specifically
designed for use as hydrophilic colloids to thicken and stabilize emulsions, foams and suspensions.
Unique combinations of properties allow CP Kelco xanthan gum products to perform beyond
the limits of many other commercially available hydrocolloids.
The KELTROL CG xanthan gum family is designed specifically for cosmetic and personal
care micro requirements. All KELTROL CG products are tested to ensure compliance with
the purity criteria defined in the monographs for xanthan gum in the current editions of the
US Pharmacopoeia/National Formulary (USP/NF) Japanese Pharmaceutical Excipients (JPE),
and European Pharmacopoeia (EP). Formulators can choose from, a family of KELTROL CG
products designed to meet specific needs and processing conditions.
®
®
xanthan gum
KEY FEATURES
•Pseudoplastic rheology
•Soluble in hot or cold
water
•Stable over a range of pH and temperatures
•Functional in systems
containing high
concentrations of salt
•Excellent suspension of
insolubles and stability of oil droplets
•Resistant to enzymatic
degradation
KELZAN® industrial grade xanthan gum products have been designed to meet the demanding
environment of various industrial formulations. KELZAN grades are specially designed to meet formulation criteria including
long-term suspension and emulsion stability in alkaline, acid and salt solutions; temperature resistance and pseudoplasticity.
KELDENT® xanthan gum is designed for use as a toothpaste binder. It gives a smooth, transparent and shiny paste which is
easy to extrude from the tube or dispenser. KELDENT xanthan gum is also compatible with cellulosics, such as CEKOL®
cellulose gum.
The XANTURAL® xanthan gum family has been designed to meet the specific needs of the pharmaceutical industry.
All XANTURAL xanthan gum products are manufactured according to bulk
pharmaceutical excipient guidelines published by the International Pharmaceutical
Excipients Council (IPEC) and are certified to meet the requirements specified in the
USP/NF, European Pharmacopoeia and Japanese Pharmaceutical Excipient monographs.
In addition, certain XANTURAL products also comply with Chapters 61/62 of the
current USP Monograph.
Structure of Xanthan Gum
Xanthan gum is a high molecular weight polysaccharide produced
via fermentation. Its unique functionality compared to other commercial
polysaccharides is provided by the actual structure of
the xanthan gum molecule. The polymer backbone is made up
of -1,4-linked D-glucose residues and, therefore, is identical to
the cellulose molecule. A trisaccharide branch containing one
glucuronic acid unit between two mannose units is linked to
every other glucose unit at the C(3) position.
1
KELTROL CG XANTURAL
®
xanthan gum
®
xanthan gum
The industry thickening and stabilizing standard
Best Choices
PRODUCTDESCRIPTION
A P P L I C AT I O N S
PERSONAL CARE PRODUCTS
KELTROL CG
Standard grade, broad formulation applicability
Skin care, hair care, bath products, emulsions and gels
From translucent to opaque depending on concentration
KELTROL CG-F
Translucent extra-fine particle size, rapid hydration
Skin care, hair care, bath products, emulsions and gels for
processes that demand fine mesh
From translucent to opaque depending on concentration
KELTROL CG-T
Transparent, very low TPC specification, cellulase free
Bath and hair care, cosmetics, sun products, creams, lotions, body wash, products which require a low micro count,
optimal for blending with cellulosic ingredients (cellulase free)
KELTROL CG-RD
Transparent, agglomerated
Disperses easily and hydrates effectively
Skin care, hair care, bath and shower care, for processes
that demand rapid dispersion
KELTROL CG-BT
Transparent, improved hydration in the presence of
high salt or surfactant levels, ability to adjust viscosity at the end of the process
Bath and hair care, cosmetics, sun products, creams, lotions,
high surfactant systems
KELTROL CG-SFT Transparent, formulation aesthetics, exhibits smooth
texture, reduced stringiness and less tack
Bath and shower, hair care, sun care, skin care emulsions,
make up and hand foams, formulations that require high
clarity, smooth rheology and differentiated sensorial and texture attributes
KELTROL SFT 61/62
Broad formulation applicability, transparent
USP Chapter 61/62 compliant
Bath and shower, hair care, cosmetics, sun care, creams, lotions. Specifically designed for higher levels
of regulatory compliance
H OU S E H O L D C L E A N E R S
KELZAN
ADVANCED
PERFORMANCE
Superior low shear rate viscosity, increased hydration rate,
improved solubility in difficult media
Spray cleaners, concentrates, toilet cleaners,
high surfactant systems
KELZAN
Standard grade
Multipurpose cleaners and polishes
KELZAN T
Transparent grade
Multipurpose surface cleaners (kitchen, floor and bathroom)
that require transparency
KELZAN ASX
High viscosity, acid stable
Cleaners and emulsions which require stability in low pH
media (tile cleaners, toilet cleaners and anti-stain products)
KELZAN ASX-T
High viscosity, acid stable, transparent
Cleaners and emulsions that require transparency (low pH,
high surfactant products, auto dish detergents)
KELZAN S
Dispersible. Requires pH adjustment to fully hydrate
Cleaners, emulsions and abrasive systems that require
delayed hydration to fit specific process needs
KELZAN ST
Cleaners, emulsions and abrasive systems that require delayed
hydration to fit specific process needs as well as high clarity
High viscosity, dispersible, transparent. Requires pH adjustment to fully hydrate
KELZAN RD
Dispersible without pH adjustment, transparent, low dust
Multipurpose cleaners, anti-stain cleaners and emulsions
that require fast dispersibility
KELZAN CC
Compatible with cellulosic thickeners
Water-based and emulsion cleaning systems that require
blending with cellulosic ingredients (cellulase free)
KELZAN AR
Smooth flow, less stringy, stable above pH 13, sprayability
Cleaners and emulsions that require compatibility and
stability in high pH media (oven cleaners and drain cleaners)
ORAL CARE PRODUCTS
KELDENT
Binding, smooth/shiny paste, easy to extrude, compatibility a with wide range of toothpaste ingredients
Toothpastes, denture adhesives and mouthwashes, optimal
for blending with cellulosic ingredients (cellulase free)
P H A R M AC E U T I C A L & OT C P R O D U C T S
XANTURAL 180
Standard pharmaceutical grade, transparent
USP Chapters 61/62 compliant
Suspension/stabilization of insoluble actives and particles.
Stabilizes emulsions and foams
XANTURAL 75
Fine particle size, transparent
USP Chapters 61/62 compliant
Controlled release tablets, reconstitutable powders,
direct compression tablet manufacturing
XANTURAL 11K
Agglomerated, transparent, enhanced dispersion and
hydration properties
Direct compression tablet manufacturing, suspension, stabilization
2
GENUVISCO
carrageenan
®
The CP Kelco carrageenan family of products
KEY FEATURES
has an established position within the consumer
• Forms thermally reversible gels
products industry as uniform gelling and texturizing
agents. CP Kelco carrageenans are purified
hydrocolloids extracted from selected species of red
• Wide range of textures
seaweed Rhodophyceae – and are highly purified carrageenans.
• Liquid gels
There are three basic types:
• Inhibits syneresis
• Kappa carrageenan forms firm gels in the presence of sufficient levels of ions.
• Stable under neutral and
alkaline conditions
• Iota carrageenan forms elastic gels and thixotropic fluids in the presence of sufficient
levels of ions.
• Lambda carrageenan forms viscous, non-gelling solutions.
GENUGEL and GENUVISCO
®
®
Derivative of 3-linked
carrageenan products
are the
galactose unit
Derivative of 3-linked
Derivative of 3-linked
galactose unit
Derivative of 4-linked
galactose unit
common
brands
galactose
unitassociated with
Derivative of 4-linked
Derivative of 4-linked
galactose unit
galactose
unit
consumer
products
A P P A Cranging
A R R A G E E Nfree-flowing
AN
manufacturers. By using the appropriate product, the formulator
can create rheologicalKKprofiles
A P P A C A R R Afrom
GEENAN
KAPPA CARRAGEENAN
-
O
- SO
CH
O33SOof textures, setting temperatures
CH22
liquids to thixotropic liquid gels and self-supporting
solid gels with a wide CH
range
and melting
O3SO
2
O
O viscosities and
OH
temperatures. With a single carrageenan product,CH
a 2range
of
CH2OH
CH2OH
O strengths
gel
ingredients in the formulation.
O
O
OH
Structure of Carrageenan
O
O
O
OH
OH
(1→4) linkages. In addition, the
3
O
(1→4) linked
OH
CH2D-galactose
O
O
O
O
OH
groups may be present on some or all galactoseO units. Carrageenans
are typically classified as three main types: kappa, iota and lambda
D-Galactose-4-sulfate
Derivative of 3-linked
galactose unit
-
O3SO
CH2OH
O
CH2
O
OH
O
O
OH
3,6-Anhydro-D-galactose
D-Galactose-2-sulfate
-
3
O
- O3SO
O
CH2
O
O
O
OH
O
O
D-Galactose-4-sulfate
D-Galactose-4-sulfate
3,6-Anhydro-D-galactose-2-sulfat e
HO
O
OH
OH
CH2OH
CH2OH
O
-O
CH2OSO3
HO
-
O
O3SO
O
O
O
O
-
OSO3 OSO3
3,6-Anhydro-D-galactose-2-sulfat e
3,6-Anhydro-D-galactose-2-sulfat e
LAMBDA CARRAGEENAN
LAMBDA CARRAGEENAN
O
O
- O3SO
- O3SO
D-Galactose-2-sulfate
D-Galactose-2-sulfate
D-Galactose-2,6-disulfate
O
O
-
CH2OSO3 CH2OSO3
HO
HO
O
O
-
-O3SO
O3SO
D-Galactose-2,6-disulfate
D-Galactose-2,6-disulfate
Idealized
Idealized Carrageenan
Carrageenan Structures
Structures
Idealized Carrageenan Structures
IOTA CARRAGEENAN
CH2OH
O
-
O
2
CH2
CH2
O
O
OSO3
O
D-Galactose-4-sulfate
O3SO
CH2OH
CH2OH
Derivative of 4-linked
LAMBDA CARRAGEENAN
HO
galactose unit
HO
KAPPA CARRAGEENA
N OH
CH
OH
OH
3,6-Anhydro-D-galactose
3,6-Anhydro-D-galactose
-
O
- 3SO
CHO23SO
units often occur as 3,6-anhydro-D-galactose, and sulphate ester
carrageenans.
O
IOTA CARRAGEENAN
IOTA CARRAGEENAN
Carrageenan is a linear polysaccharide, more specifically IaOgalactan
TA CARRAGEENAN
(1→3) and
O
O
O
O
OH
D-Galactose-4-sulfate
D-Galactose-4-sulfate
3,6-Anhydro-D-galactose
D-Galactose-4-sulfate
with the galactose residues linked with alternating
O SO
O
can be obtained by adjusting
other
O
O
-
GENUGEL
GENU
GUM
carrageenan
refined locust bean gum
®
®
The industry standard for gelling and texturizing
Best Choices
PRODUCTDESCRIPTION
A P P L I C AT I O N S
PERSONAL CARE PRODUCTS
GENUVISCO CG-129
Lambda carrageenan
Newtonian Viscosity
Lubricants, low viscosity milk and sprayable systems
GENUGEL CG-130
Kappa carrageenan, Potassium salt form
Forms firm and brittle gels
Gels, face masks, shower gels, emulsions
GENUVISCO CG-131
Iota carrageenan, Sodium salt form
Elastic, rehealable gels, low tack, light skin feel
Emulsions, surfactant systems, face masks, shaving products,
cosmetics, hair care products, shampoos, dermocosmetics,
SPA products and nutricosmetics
H OU S E H O L D P R O D U C T S
GENUGEL CI-102
Kappa carrageenan
Firm, brittle gels
Molds, encapsulation, air freshener gels
GENUVISCO CI-123
Iota carrageenan
Soft, elastic gels
Dish washing detergents, non-acid pH cleaners
ORAL CARE PRODUCTS
GENUVISCO TPH-1
Iota carrageenan, Sodium salt form
Designed for hot processing
Toothpaste, gels and gummies
GENUVISCO TPC-1
Iota carrageenan, Sodium salt form
Designed for cold processing
Toothpaste, gels and gummies
AIR CARE PRODUCTS
GENUGEL RLV
Kappa Carrageenan, Potassium form
High gel strength
Air Freshener Gels
GENUGEL CI-102
Kappa carrageenan
Firm, brittle gels
Molds, encapsulation, Air Freshener Gels
GENUGEL CI-121
Kappa carrageenan, Mixed salt form
High strength, cohesive gels
Air Freshener Gels
GENUGEL CI-124
Kappa carrageenan, Mixed salt form
Gels with high fragrance content
Air Freshener Gels
GENUGEL CI-125
Kappa carrageenan, Mixed salt form
Firm, transparent gels
Air Freshener Gels
GENUGEL CI-153
Kappa carrageenan (semi-refined), Firm, non-clear gels
Air Freshener Gels
G E N U G U M – R efined L o c u st B ean G u m
GENU Gum RL-60Z
Highly refined locust bean gum, Standard mesh, Sugar-free
Air fresheners gels and other water based systems where excellent clarity is required - synergy in combination with Kappa carrageenan
GENU Gum RL-200Z
Highly refined locust bean gum, Ultra-fine mesh, Sugar-free
Air fresheners gels and other water based systems where excellent clarity is required - synergy in combination with Kappa carrageenan
4
CEKOL
carboxymethyl cellulose
®
All CP Kelco grades of carboxymethyl cellulose
KEY FEATURES
are water-soluble polymers derived from
cellulose by introducing carboxymethyl groups
•Thickening and binding
onto the cellulose backbone. The formed anionic
•Modification/
Improvement of rheology
cellulose molecules hydrates and dissolves readily in
water. Through our manufacturing expertise and a deep
•Foam stabilization
knowledge of end-user requirements, CP Kelco offers the most
extensive range of CMC products in the market today. These versatile products serve as
•Film forming
water soluble stabilizers and thickeners widely used in consumer products applications such as
•Water retention
toothpastes and personal care products.
• Anti-redeposition agent
CEKOL® grades are stable over a wide pH range and can be used in products within a pH
range of 4.0 - 10.0. All CEKOL grades have a purity of minimum 99.5% and fully comply with
FCC and BP/EP/USP regulations.
Specially designed CEKOL toothpaste grades have very good water binding properties and provide a thick mouthfeel, as well as
very good process versatility and compatibility to a wide variety of formulations and processes.
FINNFIX® CMC is a proven anti-redeposition aid. The use of FINNFIX CMC in powder detergents is one of the product’s
oldest and most well-known applications. FINNFIX functions as a soil-suspending, anti-redeposition agent in powder detergent
formulas. The pH of the wash water and the presence of anionic and non-ionic surfactants do not affect the adsorption of
FINNFIX. During the rinse cycle, FINNFIX desorbs from the fabric surface, as a result of the reduced ionic strength. Certain
types of FINNFIX swell on contact with water, allowing them to function as tablet disintegrants.
The Best Choices table on the right is meant to provide ideas on how to get started. CP Kelco offers an extensive range of
CEKOL and FINNFIX products beyond what is listed to meet specific customer demands.
Structure of Carboxymethyl Cellulose
CH2OCH2COONa
O
O
O
OH
OH
5
OCH2COONa CH2OH
O
OH
O
CH2OH
O
OCH2COONa
O
OH
OH
OH
O
CH2OH
FINNFIX
carboxymethyl cellulose
®
The cost effective stabilizer and thickener
Best Choices
PRODUCTDESCRIPTION
A P P L I C AT I O N S
PERSONAL CARE PRODUCTS
CEKOL 150
Low viscosity
Films, low viscosity fluids
CEKOL 150 RX
Low viscosity, USP Chapter 61/62 compliant
Films, low viscosity fluids
CEKOL 2000
Medium-high viscosity, newtonian flow
Creams, lotions, sunscreens, cosmetics, serums,
soap bar mass
CEKOL 30000
High viscosity, rich skin feel
Creams, lotions for extra dry skin, sunscreens,
cosmetics (mascara)
CEKOL 30000 RX
Creams, lotions for extra dry skin, sunscreens,
cosmetics (mascara)
High viscosity, rich skin feel
USP Chapter 61/62 compliant
CEKOL 50000
High viscosity
High viscosity skin care and make up emulsions, heavy
body creams, lotions; high solids systems
CEKOL 100000
Extra high viscosity skin care emulsions
Ultra-high viscosity
ORAL CARE PRODUCTS
CEKOL 500T
Medium viscosity grade, efficient thickening at low use levels,
very good “stand-up” and “non-stringy break”
Non-striped toothpastes, formulations that require
thixotropy control for delayed viscosity build up, ease of
processing and filling of tubes
CEKOL 2000
Traditional toothpaste types
Medium viscosity grade, efficient thickening at low use levels
CEKOL 2000S
Designed for use under severe formulation conditions
Toothpaste which contains very high electrolyte
concentrations
L A U N D RY D E T E R G E N T S
FINNFIX BD
Anti-redeposition agent Technical grade
Powder laundry detergents
FINNFIX BDA
Anti-redeposition agent Technical grade
Powder laundry detergents,
powdered stain removal products
FINNFIX GDA
Anti-redeposition agent, granular mesh Technical grade
Powder laundry detergents
FINNFIX ARD Anti-redeposition agent
Purified grade
Powder laundry detergents
6
KELCOGEL
gellan gum
®
KELCOGEL® gellan gum is a water-soluble
polysaccharide produced by fermentation. This
multifunctional gelling agent can be used alone or
in combination with other products to produce a
wide variety of interesting textures.
KELCOGEL gellan gums are available in two types: low acyl
and high acyl.
Low acyl gellan gum forms firm, non-elastic, brittle gels. High acyl gellan gum forms soft, very
elastic, non-brittle gels. Combining and varying the ratios of the two forms of gellan gum
produces a wide variety of textures. Both low acyl and high acyl grades can be used at low
KEY FEATURES
•High gel strength
•Excellent stability
•Process flexibility and
tolerance
•Sparkling clarity
•Range of textures
available
concentrations to form fluid gels.
•Flexibility in melting and
setting points
Shearing during cooling disrupts gellan gum ’s normal gelation (both types) and results in
•Suspension efficiency
a smooth, homogenous, pourable structured liquid or “fluid gel.” Fluid gels are extremely
pseudoplastic and highly efficient at suspending a wide variety of items including solids and
liquids of differing densities. Suspension occurs without significantly impacting viscosity.
Gentle agitation of a weak gellan gum gel, after it is set, is also sufficient to form a smooth, pourable gel. This means that fluid
gels can be formed using standard filling operations.
KELCOGEL CG products are manufactured to food GMPs and are tested to ensure compliance with the purity criteria
defined in the monograph for gellan gum in the current edition of the US Pharmacopia/National Formulary.
Structure of Gellan Gum
The molecular structure of gellan gum is a linear chain based on repeating glucose, rhamnose and glucuronic acid units. In its
native or high acyl form, two acyl substituents – acetate and glycerate – are present. Both substituents are located on the same
glucose residue, and on average, there is one glycerate per repeat and one acetate per every two repeats. In low acyl gellan gum,
the acyl groups are removed completely. The acyl groups have a profound influence on gel characteristics. The high acyl form
produces soft, elastic, non-brittle gels, whereas the low acyl form produces firm, non-elastic, brittle gels.
7
Innovative opportunities in gelling and stabilizing
Best Choices
PRODUCTDESCRIPTION
A P P L I C AT I O N S
PERSONAL CARE PRODUCTS
KELCOGEL CG-HA
High acyl, opaque, cosmetic grade, NF tested
Forms elastic fluid gels
Sprayable systems, emulsions, face masks, body butters,
fluid gels
KELCOGEL CG-LA
Low acyl, transparent, cosmetic grade, NF tested
Forms water-thin fluid gels
Soaps, body washes, shampoos, emulsions, sprayable
systems; also pharmaceutical & ophthalmology products
H OU S E H O L D P R O D U C T S
KELCOGEL Low acyl, transparent, firm, non-elastic gel textures
Household cleaners (sprayable systems, excellent
compatibility)
KELCOGEL LT-100
Household cleaners (sprayable systems)
High acyl, opaque
AIR CARE PRODUCTS
KELCOGEL AFT
Low acyl, transparent
Forms hard, non-elastic gels, clear
Air freshener gels
MICROBIOLOGICAL PRODUCTS
GELZAN CM
Low acyl, transparent
Agar alternative
STRUCTURE OF NATIVE OR HIGH ACYL
GELLAN GUM
Cultured media
GEL TEXTURE PARAMETERS FOR
LOW AND HIGH ACYL GELLAN GUM
HARDNESS
ACETATE GROUP
ELASTICITY
MODULUS
GLYCERATE GROUP
STRUCTURE OF LOW ACYL GELLAN GUM
BRITTLENESS
High acyl
Low acyl
8
GENU
pectin
®
GENU® pectin is first and foremost a gelling
agent and is used to impart a gelled texture
to products, traditionally used in food products
such as jams and jellies. The gelling ability is further
utilized where stabilization of multi-phases is required,
either in the final product or at an intermediate stage in
the process.
GENU pectins are finding increasing use, particularly as gelling agents, but also as viscosity
KEY FEATURES
•Forms gels under acid
conditions
•Binds water
•Forms films
•Normalizes skin pH
builders, protective colloids and stabilizers in a variety of consumer products.
CP Kelco works in close contact with the industry to develop new pectin types to meet specific technology and regulatory
requirements in the marketplace. To that end, GENU pectin USP/100 and GENU pectin USP/200 are tested to comply with
Chapters 61/62 of the current USP monograph.
Another unique property of GENU pectin is the ability to adjust the skin back to its natural pH when used in products such as
creams, lotions, shaving products, or as a complimentary treatment following harsh products (such as bleaching, dipilatory and
acne products). GENU pHresh™ pectin can be used to help protect the skin’s acid mantle and provide a normalizing effect to
skin pH after being exposed to harsh conditions like washing or abrasion. Unlike other acidic materials such as alpha Hydroxy
acid or citric acid, which penetrate the skin and cause irritations, GENU pectin is a longchain polysaccharide which means it is an
exceptionally mild acid.
Structure of Pectin
Pectin is a purified carbohydrate product obtained by aqueous extraction of appropriate edible plant material – usually citrus
peel. Pectin consists mainly of galacturonic acid and galacturonic acid methyl ester units forming linear polysaccharide chains and is
normally classified according to its Degree of Methoxylation/Esterification (DE).
There are three classifications of pectin:
• HM (High Methoxyl)
• LMC (Low Methoxyl Conventional)
• LMA (Low Methoxyl Amidated)
These pectins vary in their reactivity with calcium and what is required to form a gel. HM pectins require a certain amount of
soluble solids and a low pH for gelation. LMC and LMA are less dependent on pH and soluble solids, but do require the presence
of calcium or other divalent ions for gelation. LMA pectins provide processing tolerance and a controllable gel performance, while
LMC pectins provide a softer, more shear tolerant system.
The Best Choices table on the right is meant to provide ideas on how to get started. CP Kelco offers an extensive range of
GENU pectin products beyond what is listed to meet the individual needs of customers.
9
GENU
pHresh
pectin
TM
Best Choices
PRODUCTDESCRIPTION
A P P L I C AT I O N S
PERSONAL CARE PRODUCTS
GENU pHresh RB
Rapid skin pH normalizing, excellent skin feel
For products designed to accompany shaving products,
acne treatments, depilatory products, bleaching products
(post alkaline treatment)
GENU pHresh DF
Delayed or continuous pH normalizing, excellent skin feel
Product designed to give sustained buffering for
long-term normalizing such as after sun products,
dermatological products, cosmeceuticals , “mencare” and spa products
OT C , P H A R M A C E U T I C A L & M E D I C A L P R O D U C T S
GENU pectin USP/100
Fine mesh, high methoxy pectin, USP Tested
USP Chapters 61/62 compliant
Ostomy devices, wound dressings, throat lozenges,
anti-diarrhea medicines, films, soft gel capsules
(enteric coatings)
GENU pectin USP/200
Ultra-fine mesh (200 ), Ultra-fine mesh, high methoxy pectin, USP Tested, USP Chapters 61/62 compliant
Ostomy devices, wound dressings, throat lozenges,
anti-diarrhea medicines, films
GENU pectin USP-L
Standard mesh HM pectin, USP tested, low viscosity
Pharmaceutical emulsions and suspensions
AIR CARE PRODUCTS
GENU pectin AC-R
High methoxyl pectin, Rapid setting/gelling,
Cold soluble in deionized water, Cold gelation
at soluble solids of 44-55% and pH of 2.0 - 3.0
Cold temperature processed air freshener gels
GENU pectin AC-S
High methoxyl pectin, Slow setting/gelling, Cold soluble in deionized water, Cold gelation
at soluble solids of 44-55% and pH of 2.0 - 3.0
Cold temperature processed air freshener gels
HIGH METHOXYL PECTIN
AMIDATED LOW ESTER PECTIN
10
SELECTION GUIDE
C HOO S I N G THE R I G HT C P K E L C O P RO D U C T
Application Opportunities...How to Get Started
Often, there is more than one way to achieve a given functionality…a lot to contend with. Our Field Sales and Technical Service
Professionals are energized to work with customers to identify the optimum solution for specific and unique formulation needs.
This catalogue is intended to provide a general overview of CP Kelco product offerings for the Consumer Products Industry.
The products presented here are a good starting point for discussions and sampling. Our Sales Staff and Distribution partners will
be happy to discuss specific needs and make technical assessments to find the Best Choice to deliver the desired performance.
PRODUCT PORTFOLIO
• Xanthan gum
• Carrageenan
• Carboxymethyl Cellulose
• Gellan gum
• Pectin
• Specialty products
SERVICES
• Customer service
• Global sales team
• Technical assistance
• Applications research
• Quality assurance/
regulatory support
• Reliable supply chain
Desired Functionality
What functionality do you
expect from your hydrocolloid?
XANTHAN GUM
CARRAGEENAN
EXPERTISE
• Rheology
• Texture analysis
• Hydration/mixing
• Formulation design
• Analytical techniques
• Fermentation science
• Innovative Chemistries
• Nature-Made Technology
CarboxymethylGELLAN GUMPECTIN
Cellulose
•
•
•
Gelling
•
•
Syneresis Control
•
•
•
•
Emulsion Stabilization
•
•
•
•
Low pH Stability
•
•
Heat Stability
•
•
•
•
Salt Tolerance
•
•
•
Suspension
•
•
•
•
Clarity
•
•
•
•
Coating
•
•
•
Binding
•
•
•
•
Melt Resistance
•
•
Film Forming
•
•
•
Encapsulation
•
•
•
Thickening
•
•
•
•
•
•
•
•
•
•
•
•
•
APPLICATION SELECTION GUIDE
resh
pH
NU Pectin
GE
®
®
®
NU
GEPectin
EL
OG um
LC G
KE Gellan ®
®
IX
NFC
FIN CM
X
™
L
KO
CE CMC
®
L
GE
NU
GEarrageenan®
C
O
SC
VI
NU
GE arrageenan
®
C
AL
UR Gum
NT
XA
Xanthan ®
T
EN Gum
LD
KEanthan AN um
LZ G
KE
Xanthan G
® C
L um
RO G
LT
KE Xanthan A P P L I C AT I O N Cosmetics
Eye-makeup
Foundation
Mascara
••
••
••
•
•
•
•••
•••
•••
Hair Care Products
Gels and foams
Shampoo-clear
Shampoo-pearlescent
2-in-1 Shampoo
••••
••
•••
••
Home Care Products
Air-freshener gels• •
Cleaners
•••
•
•
•
•••
Detergents powder•
Detergents liquid
Lotions and Creams
Body lotions and creams
Hand lotions and creams
Shaving products
Sunscreen
••
••
••
••
•
•
•
•
•••
•••
•••
•••
Oral Care
Mouthwashes••••
•
••••
•
Toothpaste-clear••••
Toothpaste-opaque••••
Oral gels
Pharmaceutical/Medical Products
•
• ••
•
•• •
Ostomy
• •
Wound dressings, would care•
Capsules and tablets
Oral suspensions
•
Soaps and Body Washes
Body wash-pearlescent
Feminine soap
Liquid soap-clear
Shower gels
••
• ••
••
•••
••
• ••
ARGENTINA
CP Kelco Argentina S.A.
Bolivar 187 - 6th A
C1066AAC Buenos Aires
Argentina
Tel: + 54 11 4331-8483
Fax: + 54 11 4331-8483
Australia
CP Kelco Australia
41 Devon Street
Cheltenham VIC 3192
Australia
Tel: +61 3 9427 7700
Fax: +61 3 9584 9448
Belgium
CP Kelco Belgium b.v.b.a.
Industrieweg 150
BE-3538 Beringen
Belgium
Tel: +32 11 45 86 56
Fax: +32 11 42 03 61
BRAZIL
CP Kelco Brasil
Rua Teixeira Marques, 845
Caixa Postal 21
Chácara São José, Limeira
São Paulo, Brazil
CEP: 13845-127
Tel: +55 19 3404 4600
Fax: +55 19 3451 1948
China
CP Kelco Shanghai Rep. Office
J.M. Huber Investment (China) Ltd
7F Xingyuan Tech. Plaza
No. 418 Guiping Road
Cao He Jing Hi-Tech Park
Xuhui District,
Shanghai 200233
Tel: +86 21 5175 8488
Fax:+86 21 5175 8499
Denmark
CP Kelco ApS
Ved Banen 16
DK-4623 Lille Skensved
Denmark
Tel: +45 56 16 56 16
Fax: +45 56 16 94 46
Finland
CP Kelco Oy
Kuhnamontie 2
PL 500
FI-44101 Äänekoski
Finland
Tel: +358 14 518-3000
Fax: +358 14 518-3003
France
CP Kelco France
123 rue Jules Guesde
FR-92300 Levallois-Perret
France
Tel: +33 (0) 1 49 03 78 00
Fax: +33 (0) 1 49 03 78 29
Germany
CP Kelco Germany GmbH
Pomosin-Werk 5
DE-23775 Großenbrode
Germany
Tel: +49 4367 715 0
Fax: +49 4367 715 111
INDIA
CP Kelco, Division of
JM Huber (India) Pvt Ltd.
504 Meadows, Sahar Plaza
J.B. Nagar, Andheri – Kurla Road
Andheri (E), Mumbai 400059
India
Tel: +91 22 61415713
Fax: +91 22 61415715
Japan
CP Kelco Japan ApS
Izumi Kamiyacho Bldg.
8-1, Higashi-Azabu 1-chome
Minato-ku,Tokyo 106-0044
Japan
Tel: +81 3 3560 7313
Fax: +81 3 3560 7316
Korea
CP Kelco Korea
Room 525, Officetel,
The 3rd complex, King’s Garden,
Nae-Su Dong, Jong Ro Gu,
Seoul, Korea,110-070
Tel: +82 2 545 6022
MEXICO
CP Kelco México
Torre Zentrum
Av. Santa Fe 495 piso 4
Col. Cruz Manca
Del. Cuajimalpa
México 05349, D.F.
Tel: +(5255) 33007840
Fax: +(5255) 33005510
The Netherlands
CP Kelco B.V.
Postbus 31
6500 AA Nijmegen
The Netherlands
Tel: +31 24 371 9900
Fax: +31 24 371 9999
Poland
CP Kelco Poland Sp. Z.o.o.
Malta Office Park
ul. Abpa. A. Baraniaka 88 C
61-131 Poznan
Tel. +48 61 625 85 55
Fax: +48 61 625 85 57
Russia
CP Kelco ApS
(Moscow Representative Office)
32/2, building 4
Kadashevskaya emb.
Business Center
“Kadashevskaya Sloboda”
RU-115035 Moscow
Russia
Tel: +7 495 937 36 47/48
Fax: +7 495 937 36 27
Singapore
CP Kelco Singapore Pte., Ltd.
151 Lorong Chuan
#06-07 New Tech Park
Singapore 556741
Tel: +65 6491 9100
Fax: +65 6491 910
United Kingdom
CP Kelco UK Limited
Cleeve Court, Cleeve Road
Leatherhead
Surrey KT22 7UD
United Kingdom
Tel: +44 (0) 1372 369 400
Fax: +44 (0) 1372 369 401
UNITED STATES
GLOBAL HEADQUARTERS
CP Kelco U.S., Inc.
Cumberland Center II
3100 Cumberland Boulevard
Suite 600
Atlanta, GA 30339
USA
Tel: (678) 247-7300
Toll Free: (800) 535-2687
Fax: (678) 247-2797
E-mail: [email protected]
www.cpkelco.com
The information contained herein is, to our best knowledge, true and accurate, but all recommendations or suggestions are made without guarantee, since we can neither anticipate
nor control the different conditions under which this information and our products are used.THERE ARE NO IMPLIED OR EXPRESS WARRANTIES OF FITNESS FOR PURPOSE. Each
manufacturer is solely responsible for ensuring that their final products comply with any and all applicable federal, state, and local regulations. Further, we disclaim all liability with regard
to customers’ infringement of third party intellectual property including, but not limited to, patents.We recommend that our customers apply for licenses under any relevant patents.
© 2012 CP Kelco U.S., Inc. (G) Edited 04/12