Provenance characteristics of the Brumunddal sandstone in the Oslo
Transcription
Provenance characteristics of the Brumunddal sandstone in the Oslo
NORWEGIAN JOURNAL OF GEOLOGY Provenance characteristics of the Brumunddal sandstone in the Oslo Rift 1 Provenance characteristics of the Brumunddal sandstone in the Oslo Rift derived from U-Pb, Lu-Hf and trace element analyses of detrital zircons by laser ablation ICMPS Tom Andersen, Ayesha Saeed, Roy H. Gabrielsen & Snorre Olaussen Andersen, T., Saeed, A., Gabrielsen, R.H. & Olaussen, S.: Provenance characteristics of the Brumunddal sandstone in the Oslo Rift derived from U-Pb, Lu-Hf and trace element analyses of detrital zircons by laser ablation ICMPS. Norwegian Journal of Geology, vol. 91, pp 1-19. Trondheim 2011. ISSN 029-196X. The 800 m thick Brumunddal sandstone is partly an eolian, partly a fluvial sandstone deposited in a fault-bounded basin in the northern part of the Oslo Rift in Permian time.The sandstone is the youngest rift-related deposit in the northern part of the Oslo Rift. Well rounded detrital zircons are common accessory mineral grains in the sandstone. U-Pb dating of detrital zircon from a sample of the Brumunddal sandstone by LAM-ICPMS gives a range of ages from (rare) late Archaean ages to Permian (283±4 Ma). The age and initial εHf pattern of zircons in the sediment match the main rock- forming events in Fennoscandia from Archaean to Phanerozoic time. This kind of diverse provenance was most likely obtained by repeated recycling of clastic sediments of Fennoscandian origin, with Silurian, continental sandstones as the most probable direct precursors. Trace element distributions show a conspicuous absence of patterns with the high level of U and Th enrichment typical of zircon from granitic rocks. This is consistent with a complex transport and redepositional history: High U-Th, metamict zircons were selectively removed by abrasion during repeatedtransport-deposition-erosion cycles. In addition to recycled material, Caledonian syn-orogenic intrusions and Permian intermediate to felsic plutonic rocks in the Oslo Rift itself were minor, but still significant sources of detrital zircon. Tom Andersen & Roy H. Gabrielsen, Department of Geosciences, University of Oslo, PO Box 1047 Blindern, NO-0316 Oslo, Norway (tom.andersen@geo. uio.no). Ayesha Saeed, GEMOC, Macquarie University, NSW-2109, North Ryde, Australia. Snorre Olaussen, The University Centre in Svalbard, P.O. Box 156, N-9171 Longyearbyen, Norway Introduction The Brumunddal sandstone (informal name) is the uppermost preserved member of the late Paleozoic, riftrelated, volcanosedimentary succession in the northern part of the Oslo Rift. It was deposited on a substrate of rhomb porphyry lava, and is preserved in a ca. 6.5 km by 2.5 km, downfaulted block, the Narud halfgraben (Fig. 1). The Brumunddal sandstone consists of red and yellow, cross-bedded, eolian dune deposits and fluvial channel and floodplain deposits (Rosendal 1929, Larsen et al. 2008). Its maximum depositional age is constrained by a Rb-Sr mineral isochron age of the underlying rhomb porphyry lava at 279±9 Ma (Sundvoll et al. 1990). The absence of overlying, datable rocks leaves the younger limit for the age of deposition unconstrained. Larsen et al. (2008) regarded the sandstone as a remnant of graben fill that formed during the main rifting stage of the Oslo Rift, which is characterized by widespread plateau lavas intercalated by continenal deposits. Through the U-Pb and Lu-Hf isotope systems and trace element distribution patterns, detrital zircon grains in a sandstone retain a robust memory of the age, petrogenetic history and compositional characteristics of the magmatic or metamorphic rock(s) in which they formed, i.e. of the protosource (e.g. Fedo et al. 2003, Kinney & Maas 2003, Belousova et al. 2002, 2006). As the youngest pre-Quaternary sedimentary deposit in the northern part of the Oslo Rift, this sandstone may have sampled a range of Precambrian and Paleozoic protosources in the Fennoscandian Shield, the Caledonian nappes and within the Oslo Rift itself. However, detrital zircons in a sedimentary rock may have been recycled through one or more intermediate reservoirs by erosion and redeposition of older sedimentary rocks (e.g. Røhr et al. 2010). In this paper, we present the results of an analytical study applying laser ablation inductively coupled mass spectrometry (LAM-ICPMS) and electron microprobe analysis to detrital zircon in the Brumunddal sandstone. Data include single-zircon U-Pb ages, Lu-Hf isotope ratios and trace element distribution patterns, which provide new insights into the sources and recycling patterns of clastic material in Fennoscandia in late Paleozoic time, and which help to refine the position of the sandstone within the evolutionary history of the Oslo Rift. 2 T. Andersen et al. NORWEGIAN JOURNAL OF GEOLOGY Figure 1 a)Simplified geological map of the southern part of the Rendal graben segment in the Oslo Graben, Norway (after Høy and Bjørlykke 1980). Legend: i: Brumunddal sandstone (Mauset Fm), ii-iv: Permian lavas and volcaniclastic sediments (Bjørgeberg Fm.), v: Bruflat Fm. (Upper Silurian), vi: Ekre shale (Silurian). vii: Pentamerus limestone (lower Silurian), viii: Mjøsa limestone (middle Ordovician), ix: Fluberg Fm (middle Ordovician), x: Cambrian shale and sandstone, xi: Ringsaker quartzite (Neoproterozoic). The broken line is an inferred, unexposed fault. b)Main geological features of the Oslo Rift, after Larsen et al. (2008). Legend: SG Skagerrak Graben, VG: Vestfold Graben, AG: Akershus Graben, RG: Rendal Graben. 1: Mesoproterozoic basement, 2: Hedemark Basin (Neoproterozoic). 3: Cambrian to Silurian sedimentary rocks, 4: Permo-Carboniferous volcanic and sedimentary rocks. 5: Permian intrusive rocks. 6: Central volcanoes (cauldrons), 7: Transfer zones, 8: Brittle faults. The red rectangle marks the position of Fig. 1a. c)The outline of the Oslo Rift system, the preserved parts of the Permian deposits (red and deep purple; after Larsen et al. 2008) and its relation to the tectonostratigraphic units mentioned in the text: Legend: C: Caledonian nappes, H: Hedemark Basin (Neoproterozoic), D: Dala-Trysil basin (Mesoproterozoic). TIB: Transscandinavian Igneous Belt (Late Paleoproterozoic). O: Orsa sandstone (Silurian), Ö: Öved sandstone (Silurian). On-shore lower Paleozoic sediments in the Oslo Rift are shown in pale blue. To evaluate the potential of post-Caledonian continental sediments outside of the rift area as intermediate repositories for detritus in the Brumunddal sandstone, we have also analysed U-Pb and Lu-Hf isotopes in detrital zircons from a sample of the Silurian continental sandstone from Orsa in central Sweden. NORWEGIAN JOURNAL OF GEOLOGY Provenance characteristics of the Brumunddal sandstone in the Oslo Rift Geological background The late Paleozoic Oslo Rift (Fig. 1) encompasses four separate graben units. The southernmost unit (the Skagerrak Graben) is entirely situated offshore and features a symmetrical geometry. In contrast, the three onshore units (Vestfold, Akershus and Rendalen grabens) are half-grabens of contrasting polarities. The graben units are separated by NNW-SSE- and NNE-SSE-striking transfer zones (Fig. 1b). Volcanic rocks and batholiths dominate the the Vestfold and Akershus grabens, whereas the Rendalen Graben is devoid of batholiths. Still, some lava flows exist here, albeit minor in volume as compared to the southern graben units (Larsen et al. 2008). The rift evolution can be divided into several distinct stages (Ramberg and Larsen 1978, Neumann et al. 2004, Larsen et al., 2008). The proto-rift stage is characterized by alluvial and minor marine deposits of Pennsylvanian age, the Asker Group (Olaussen et al., 1994, Larsen et al. 2008). Volcanism during the main rifting stage produced basaltic lava (B1) which form thick sequences in the Vestfold Graben, thinning northwards and to zero around Oslo. These lavas are of late Carboniferous to earliest Permian age (300 ± 1Ma, Corfu & Dahlgren 2008). Graben subsidence continued and large volumes of rhomb porphyry lava (latite) and minor basalt erupted through large fissure volcanoes. Also, thick volcanoclastic and sedimentary units were deposited during this stage. The composite Larvik pluton in the Vestfold graben intruded in this stage, and has been dated to 298-292 Ma by ID-TIMS U-Pb on zircons (Dahlgren et al., 1996, 1998, Dahlgren 2010). In the subsequent central volcano stage, volcanic activity was concentrated in distinct volcaniccentres with local trends of magmatic evolution, terminating in caldera collapse. The centralvolcanoes are preserved as between 15 and 20 cauldron structures, representing sections through subvolcanic magma chambers, ring-dike systems and downfaulted blocks of volcanic rocks. U-Pb ages are not yet available for the rocks that formed during this stage, but Rb-Sr ages suggest a relatively long duration (ca. 280-240 Ma, Sundvoll et al. 1990). The final stages of rift evolution were characterized by emplacement of intermediate to felsic batholiths, ranging in composition from larvikite through syenite to granite. U-Pb ages on zircons from different intrusions suggest emplacement ages between 272 Ma and 286 Ma (Pedersen et al. 1995, Haug 2007, Andersen et al. 2009c), but Rb-Sr isochron ages range down to 241 Ma (Sundvoll et al. 1990). The Rendalen Graben is delineated eastwards by the westerly facing extensional Rendalen fault and is superseded to the north by several smaller sub-graben of varying polarity. One of these, informally termed the Narud halfgraben, occupies the Brumunddalen area, its Permian sequence being preserved in the rotated hanging wall fault block of the westerly dipping Gråkvern fault (Fig. 3 1a). The fill of the Narud halfgraben is subdivided into two formations, namely a lower 250 m thick volcanic unit, the (Bjørgeberget formation) of Early Permian age (Sundvoll et al. 1990), and the upper, conformable c.750 m thick undated Brumunddal sandstone unit, which has been suggested by Eliassen et al. (in prep.) to be renamed the “Mauset formation” (Fig. 2). The Bjørgeberg formation rests unconformably on folded Cambro-Silurian sediments and consists of four rhomb porphyry lava flows (RPx-u; Rosendal 1928), inter calated with up to 30m thick, volcanoclastic conglomerates and sandstones. The conglomerates consist entirely of rhomb porphyry lava clasts while the sandstones contain63-65% quartz, 30-32 % feldspar (mostly plagioclase) and 4-6% lava fragments and hence classify as an arkosic arenite. The volcanoclastic rocks are interpreted as alluvial fans derived from evolving basin-bounding fault escarpments or local highs. Deposition of these fans took place either in interludes between extrusive activity, or represent contemporaneous, lateral variations of the volcanic-sedimentary sequence (Eliassen et al. in prep.). The Mauset formation (informally the Brumunddal sandstone) is dominated by red and yellow sandstones with subordinate mudstones and carbonates. The rocks of the Mauset formation can be subdivided into three units. The lowermost unit (c. 200 m thick) consists of red sandstone with a mineralogical composition and texture similar to that of the arkosic arenites interlayered with the lavas in the Bjørgeberg formation. They are interpreted as wadi deposits characterized by a stable high watertable. This unit is superseded by a 500 m thick sequence of texturally mature, fine to medium grained subarkosic arenite with up to 77% quartz, 21% feldspar and less than 2% lava fragements. The lowermost 250 m of this unit is interpreted as eolian dune, interdune and sandflat deposits interbedded by fluvial stream and alluvial plain sandstones and siltstones with evaporite pseudomorphs. The upper 250 m of the middle unit consists entirely of eolian sands. The Mauset formation is topped by a 50 m thick sequence of texturally and mineralogically im mature sandstones somewhat similar to the lower unit, but which may have more than 40% feldspar and less lava fragments. This arkosic arenite is interbedded by siltstones and carbonates that include fresh-water stromatolites. It was deposited in ephermal lakes, ponds and sabkhas typical of a mixed playa and alluvial environment and is indicative of a second event marked by high water-level (Eliassen et al., in prep.). Taken collectively, the Mauset formation is a typical eolian/fluvial wadi deposit (Rosendahl, 1929, Olaussen et al 1994, Eliassen et al. in prep.) much like what has been described for the Upper Rotliegendes in the Northern and Southern Permian Basins in northern Europe (e.g Glennie 1990). The limited outcrops do not allow interpretation of eolian dune types (e.g as barchans, transverse, seif or dras), nor can reliable determinations 4 T. Andersen et al. NORWEGIAN JOURNAL OF GEOLOGY Figure 2: Stratigraphy of the Brumunddal sandstone of paleo-wind direction be made. A similar uncertainty exists for the sediment transport directions of the ephemeral alluvial stream deposits, which are likely to have been determined by local dune topography and structural grain as developed by graben margin faulting (e.g. Gabrielsen et al. 1995). Still, it is considered unlikely that the 750 m thick eolian/wadi deposit of the Mauset Formation was constrained to the 6.5 x 2.5 km half graben in the Brumundal area alone. It is more likely that the Narud halfgraben is one preserved fragment of a wider desert area that covered most of the northern part of the Oslo Rift and its vicinity. Hence the deposits of the Brumundal sandstone might be interpreted as a northern arm or extension of the Rotliegendes of the Northern Permian Basin (Olaussen et al. 1994, McCann 1998, Larsen et al. 2008, Eliassen et al. in prep). Consistent with this interpretation is the occurrence of up to 1 m thick beds of red coloured, cross-stratified sandstone with well-sorted and well-rounded grains interpreted as eolian or reworked eolian deposits (Olaussen et al 1994). These beds occur within the volcanoclastics interbedded with the lava pile in the Akershus and Vestfold Graben further south in the Oslo Rift. In a reconstructed paleogeographic setting, the provenance for the Mauset Formation is suggested to be both of local origin and from the basin fill of the rift further south. The Orsa sandstone is an erosional remnant of Silurian continental sandstone preserved within the Siljan impact structure in central Sweden (“O” in Fig. 1c). It is the youngest preserved member of the lower Paleozoic sedimentary sequence in the area, unconformably overlying limestones and shales of Llandowery to Wenlock age (Thorslund 1960). The deposit consists of a cross-bedded, conglomeratic to coarse sandy lower part, overlain by a main sequence of loosely consolidated, fine-grained quartz arenite, which is locally carbonate cemented and interlayered with clay-rich units (Hjelmqvist 1966). A NORWEGIAN JOURNAL OF GEOLOGY Provenance characteristics of the Brumunddal sandstone in the Oslo Rift sample was included in this study to evaluate the potential of post-Caledonian sediments as intermediate hosts for detrital material, rather than to establish a detailed provenance history. The Orsa sandstone was chosen as an example rather than other Silurian continental sandstones (e.g. the Öved sandstone in Scania (Jeppson & Laufeld 1986), “Ö” in Fig. 1c; the Ringerrike group in the Oslo Rift) because it is situated between the site of deposition of the Brumunddal sandstone and potential Paleoproterozoic and older protosources in the Svecofennian and Archaean domains of Fennoscandia. The sample studied is a fine-grained, red, friable sandstone without clay or carbonate (Hjelmqvist 1966). Zircon petrography The present study was based on a sample of red, friable sandstone from the upper part of the Mauset formation (N 60° 54.59’, E 10° 58.89’). The sample is a carbonate-cemented quartz sandstone pigmented by finely disseminated iron oxide and containing minor to accessory amounts of detrital zircon. Most detrital zircon Figure 3. Backscattered electron (BSE) images of detrital zircon from the Brumunddal sandstone. Each image is identified by analysis number in tables of the Supplementary Material, U-Pb age and εHf at the U-Pb age. Each image is identified by ana lysis number, U-Pb age and eHf at the U-Pb age. Rare Archaean grains (a) are well-rounded and show little internal structure, except for a weak, BSE bright overgrowth (lower part). Paleoto Mesoproterozoic grains (b, c, d) have well developed, more or less complex oscillatory zoning patterns typical for magmatic zircon, and are commonly well rounded. Permian grains (e, f) vary in shape from angular to well-rounded grain shapes, they show faint oscillatory zoning structures, and contain abundant, BSE-dark inclusions (feldspar, apatite). 5 grains are well rounded, suggesting significant abration during transport (Fig. 3). A few grains giving Permian U-Pb ages are less well-abraded (Fig. 3e), but lack of rounding is not a universal feature of the youngest group of detrital zircons in the sandstone (compare Fig. 3e with Fig. 3f). Most grains show the low-amplitude, short-wavelength oscillatory zoning in backscattered electron (BSE) intensity that is characteristic of magmatic zircons (Fig. 3b, c, d). Complex inner structures seen in some grains suggest that they are fragments of twins or intergrown groups of crystals (Fig. 3b). BSEbright overgrowths occur in some grains (e.g. Fig. 3a,c); these are generally too thin to allow separate analysis by LAM-ICPMS. Mineral inclusions in zircon (e.g. Fig. 3c) were avoided during U-Pb and Lu-Hf analysis, but a few were penetrated during trace element ablations. Inclusions which were large enough to be integrated separately showed elevated phosphorus and middle or light REE, and have therefore been tentatively identified as apatite and monazite, respectively. 6 T. Andersen et al. Analytical methods Sample preparation was done at the Department of Geosciences, University of Oslo, and analysis of zircon by LAM-ICPMS at the GEMOC National Key Centre, Macquarie University and at the Department of Geosciences, University of Oslo. Zircon grains were separated from rock samples by standard crushing and mineral separation techniques, followed by hand-picking under a binocular microscope. Selected grains from the two least magnetic fractions (magnetic and non-magnetic at 1.5 A magnet current in the Franz separator at 15º standard tilt and slope) were cast in epoxy disks for LAM-ICPMS analysis. The mounts were ground and polished to expose the zircons, and thoroughly cleaned before analysis. Zircons were examined in transmitted and reflected light, and by electron backscatter imaging in a Cameca SX50 electron microprobe. Each imaged zircon was assigned a number, which also serves to identify analyses in Tables 2, 3 and 4 of Supplementary Material. Standards were mounted in separate epoxy disks. LAM-ICPMS U–Pb dating. U–Pb dating of the Brumunddal sandstone sample was made with a HP 4500 series 300 inductively coupled plasma quadrupole mass spectrometer (QICPMS), attached to a Merchantec/New Wave LUV213 Nd-YAG laser microprobe at GEMOC. Analytical procedures were as described by Jackson et al. (2004). The analytical protocol allows accurate correction for U/Pb fractionation by sample-standard bracketing. Standard zircon GJ-1 (608 Ma, Jackson et al. 2004) was used for calibration, while standard zircons 91500 (Wiedenbeck et al. 1995) and Mud Tank (Black and Gulson 1978) were run frequently as unknowns to provide an independ ent control on reproducibility and instrument stability. The GLITTER software (Griffin et al. 2008) was used for data reduction and calculation of individual U–Th–Pb ages. The contentsof common lead were estimated from the 3D discordance pattern in 206Pb/238U – 207Pb/ 235U – 208 Pb/232Th space, and corrected accordingly (Andersen 2002). Additional U-Pb analyses of detrital zircon from the the Orsa sandstone were made with a Nu Plasma HR multicollector ICPMS and a NewWave LUV213 laser microprobe at the Department of Geosciences, University of Oslo, using protocols for data acquisition and standardization described by Rosa et al. (2009). Lutetium-hafnium isotopes. Lu-Hf analyses of zircon from the Brumunddal sandstone were made with a NuPlasma multicollector ICPMS attached to a LUV213 Nd-YAG laser microprobe at GEMOC, using protocols described by Griffin et al. (2000) and Andersen et al. (2002b). Ablation conditions were: Beam diameter: 55 μm (aperture imaging mode), NORWEGIAN JOURNAL OF GEOLOGY pulse frequency: 5 Hz, beam energy density: ca. 2 J/cm2, static ablation. Each ablation was preceded by a 30 seconds on-mass background measurement. Masses 172 to 180 were measured in Faraday collectors, using the standard collector block of the NU Plasma mass spectrometer. The total Hf signal obtained was in the range 1.53.0 V. Under these conditions, 120-150 seconds of ablation are required to obtain an internal precision of ≤ ± 0.000020 (1SE). Isotopic ratios were calculated using the Nu Plasma time-resolved analysis software. The raw data were corrected for mass discrimination using an exponential law, the mass discrimination factor for Hf was determined assuming 179Hf/177Hf= 0.7325, the observed 2 SE uncertainty of the Hf mass discrimination factor was better than 0.5%, and was propagated through to the error of the final result. The isobaric interferences on 176Hf by 176Lu and 176Yb were corrected from measurements of interference-free 172Yb and 175Lu. The observed mass discrimination for Hf was used as a proxy for those of Lu and Yb. 176Lu/175Lu= 0.02669 was used for correction of Lu interference on mass 176 (DeBievre & Taylor 1993). The 176Yb/172Yb ratio used in the correction procedure (0.5870) was determined from multiple runs of Yb-doped JM475 Hf standard solutions. Lu-Hf analyses of zircon from the Orsa sandstone were made with the Nu Plasma HR instrument in Oslo, using procedures described by Andersen et al. (2009a) and Heinonen et al. (2010). A value for the decay constant of 176Lu of 1.867 x 10-11 a-1 has been used in all calculations (Söderlund et al. 2004; Scherer et al. 2001, 2007). For the calculation of εHf values we used present-day chondritic 176Hf/177Hf = 0.282785 and 176Lu/177Hf = 0.0336 (Bouvier et al. 2008). We have adopted the depleted mantle model of Griffin et al. (2000), modified to the λ176Lu and chondritic composition used, which produces a present-day value of 176 Hf/177Hf (0.28325, εHf = +16.4) similar to that of average MORB over 4.56 Ga, from chondritic initial hafnium at 176 Lu/177HfDM = 0.0388. Trace elements. Trace elements in zircon were analysed using an Agilent 7500 quadrupole ICPMS and a New Wave Research LUV213 laser microprobe at GEMOC. Ablation conditionswere: Beam diameter: 40 μm (aperture imaging mode), pulse frequency: 5 Hz, beam energy density: ca. 5 J/cm2, giving a laser energy at the sample of 0.07 mJ. A fast scanning protocol was employed, analysing masses from 29 (Si) to 238 (U), with 10 ms dwell times on all masses analysed except 206 (15 ms), 207 (30 ms) and 238 (15 ms). Ablations lasted for 120 seconds, and each was preceded by a 60 seconds background measurement with the laser off. NIST 610 silicate glass was used as external standard, with 29Si as the internal standard, assuming a stoichiometric composition for zircon with 32.78 weight % SiO2. Data reduction was made off-line using the software package GLITTER 4.4 (Griffin et al. 2008). NORWEGIAN JOURNAL OF GEOLOGY 0 a 4 8 12 16 20 24 0.20 2800 0.20 0.16 2800 0.16 0.12 Pb/ 206Pb 2000 0.12 2000 0.08 1200 207 Figure 4. U-Pb data for detrital zircon from the Brumunddal sandstone. a:Tera Wasserburg diagrams showing data for zircon crystals in the magnetic and non-magnetic fractions from the Franz magnetic separator at 1.5 A separately. Note that Permian zircons occur only in the magnetic fraction. b: Conventional concordia diagram showing the Permian fraction. The three grains represented by white fill define a concordia age at 285±4 Ma, the fraction as such a weighted average 206Pb/238U age at 283±4 Ma, which is the preferred estimate of the crystallization age of the source rock(s). 7 Provenance characteristics of the Brumunddal sandstone in the Oslo Rift 0.08 0.04 Magnetic fraction 400 1200 0.04 400 Non-magnetic fraction 0 4 8 12 238 U/ b 0.052 16 20 24 206 Pb Concordia Age = 285 ±4 Ma 320 (2 , decay-const. errs ignored) MSWD of concordance and equivalence = 1.6 238 U 300 0.047 206 Pb/ 280 0.042 0.037 0.26 260 Weighted average 206Pb/ 238U age: 283±4 (95% conf.), 9 of 10 grains Wtd by data-pt errs only, 1 of 10 rej. MSWD = 1.7 240 0.28 0.30 0.32 207 Pb/ Accuracy and external precision of the individual elements estimated from repeated analyses of reference zircon GJ-1 are given in Table 1 of Electronic Supplement. Results Uranium-lead ages of detrital zircons in the Brumunddal sandstone. Of a total of 105 grains dated by U-Pb (Table 2 of Electronic Supplement), 94 were concordant or less than 10 % normally discordant (central discordance). The zircons yield a large range of U-Pb ages, from late Archaean 0.34 0.36 0.38 235 U (2.6 Ga) to Permian (Fig. 4a), with a pronounced frequency maximum at ca. 1 Ga, and subordinate maxima at ca. 1400 Ma, 1600 Ma, 1800 Ma and in the Phanerozoic, with marked hiatuses in the Neoproterozoic and early Paleoproterozoic (Fig. 5a). Although the magnetic and non-magnetic zircon fractions show largely similar age distribution patterns, a distinct group of late Paleozoic zircons (270-310 Ma) has been observed only in the magnetic fraction (Fig. 4a). Of eleven zircons in this group, eight are 10 % or more discordant. The three concordant zircons give a concordia age of 285±4 Ma, and 9 zircons define a weighted average 206Pb/238U age of 283±4 Ma (Fig. 4b, 5b), indistinguishable from the concordia age. Another group of similar size (9 grains) give ages 8 T. Andersen et al. NORWEGIAN JOURNAL OF GEOLOGY a Orsa sandstone, Sweden (Silurian) Brumunddal sandstone 20 Relative probability Number 15 10 5 0 200 600 1000 1400 1800 2200 2600 Figure 5. Accumulated probability distribution diagrams showing: a):The whole population of dated zircons (207Pb/206Pb ages for t> 600 Ma, 206Pb/238U ages for t< 600 Ma), analyses with more than ± 10 % discordance excluded. The colourfilled background histogram shows the age distribution of detrital zircons in the Silurian Orsa sandstone, Sweden (Table 5a of Supplementary material). b): Permian zircons (n=11, including discordant grains). Broken outline indicates zircons that are not used to calculate ages. 3000 Detrital zircon age, Ma 5 b Weighted average 206Pb/238U age: 283±4 Ma Relative probability Number 4 3 2 1 0 250 260 270 Zircon 280 206 Pb/ 290 300 310 238 U age, Ma between 526 and 398 Ma, with a peak at 440 Ma, which is compatible with igneous or metamorphic source rocks in Caledonian nappes (e.g. Gee et al. 2008). Two analyses give ages of 346±4 Ma and 361±4 Ma. These grains do not differ from the Caledonian fraction in terms of trace element distributions and Lu-Hf characteristics (below), and it is therefore suggested that they are Caledonian grains which have suffered sufficient lead-loss in Permian or recent time to modify their ages, while remaining concordant within error. Lutetium-Hafnium isotopes of detrital zircon in the Brumunddal sandstone In Fig. 6 (data from Table 3 of Electronic Supplement), initial 176Hf/177Hf for 82 concordant or near-concordant zircons are plotted at the preferred U-Pb age (i.e. 207 Pb/206Pb ages for zircons older than 600 Ma, 206Pb/238U ages for younger zircons). The late Paleozoic zircons form a coherent group with distinct initial Hf character. When zircons that are more than 10% discordant in U-Pb are included in the calculation, nine zircons give a weighted average 176Hf/177Hf= NORWEGIAN JOURNAL OF GEOLOGY 0.2835 Oslo Rift magmas DM 0.2830 Provenance characteristics of the Brumunddal sandstone in the Oslo Rift Sveconorwegian granites +10 Initial 176Hf/177Hf Granite and rhyolite Telemark block -10 0.2820 Silurian sandstone from Orsa, Sweden Age range of Caledonian magmatism CHUR 0 0.2825 "Gothian" arc magmatism Transscandinavian Igneous Belt (TIB) Magmatic zircon TIB crust 0.2815 Inherited zircon in Sveconorwegian granites 0.2810 0.2805 0 9 500 Inherited zircon in TIB, Intrusions in the Archaean Domain 1000 1500 Late Arcahean granitoids, Finland 2000 2500 3000 Detrital zircon age, Ma Figure 6. Initial 176Hf/177Hf plotted agains U-Pb or Pb-Pb age for detrital zircons in the Brumunddal sandstone (white fill: Non-magnetic fraction, grey fill: Magnetic fraction), compared to fields of initial Hf isotope composition for magmatic rocks in Fennoscandia: Late Archaean granitoids: Patchett et al. (1981), Lauri et al. (2011). Intrusions in the Archaean domain, Finland: Patchett et al. (1981). Transscandinavian Igneous Belt, and inherited zircons therein: Andersen et al. (2009a). Mesoproterozoic “Gothian” arc magmatism, Telemark magmatism and Sveconorwegian granitoids: Andersen et al. (2002, 2004, 2007, 2009b), Pedersen et al. (2009). Oslo Rift magmas: Haug (2007), Andersen et al. (2009c). The fields with diagonal ruling are the observed fields of detrital zircons in a sample of Neoproterozoic sandstone from the Hedmark Basin published by Bingen et al. (2005a). The ages of syn-orogenic Caledonian magmatism are constrained by U-Pb data on subduction-related igneous rocks in the Caledonian nappes (Gee et al. 2008 and references therein). The Hf isotopic composition of these rocks remains unconstrained by data. The broad, open arrow represents the evolution of TIB and related Paleoproterozoic granitioids with time, based on observed 176Hf/177Hf in zircon, and an assumed average 176Lu/177Hf = 0.010. Broken arrows are trends of apparent evolution of 176Hf/177Hf in zircons which have lost all or part of their radiogenic lead during secondary, ancient events. Thin, broken lines are contours of 176Hf/177Hf at 2 epsilon units interval from -10 to +10. The colour-filled background points are zircons from the Silurian Orsa sandstone, Sweden (data from Table 5b of Supplementary Material). 0.28272±0.00004 (95% confidence) or εHf=4.2±1.5, with no rejections. The spread of initial 176Hf/177Hf in this group is comparable to the analytical error, suggesting that these zircons originated from one or more protosource rocks within the rift with homogeneous Lu-Hf characteristics. Zircons older than these show considerable variation in initial 176Hf/177Hf, ranging from well below CHUR (i.e. εHf<0) to values near the depleted mantle growth curve at the crystallization age (Fig. 6), without simple correlation with age. The “Caledonian” age group shows internal variation from εHf= -11 to +1.4, indicating that this age fraction must have come from sources with different crustal histories. An even larger internal variation is seen in the large group of Sveconorwegian zircons, which span 20 epsilon units (-11 to +9). Zircons in the 14001500 Ma age group have positive εHf, except for a small, coherent group with εHf= -3 to -8. These may be early Mesoproterozoic or older zircons that have been affected by lead loss around 1500 Ma. Some of the Paleoproterozoic zircons (1600-2000 Ma) have low-positive initial εHf, but zircons with negative εHf are also present in this age group. Unfortunately, only one single late Archaean grain 10 T. Andersen et al. could be analysed for Hf isotopes, and yielded nearchondritic 176Hf/177Hf at its 207Pb/206Pb age. Trace element compositions of detrital zircon in the Brumunddal sandstone The trace element distribution patterns observed in the analysed samples are typical for magmatic zircon (Hoskin and Schaltegger 2003, Belousova et al. 2002), with positive anomalies for Hf, U, Th and Ce (Fig. 7, data from Table 4 of Electronic Supplement). Hf concentrations range from ca. 0.6 to ca. 2.4 percent, and total REE from 33 to 2000 ppm. Source-dependent trace element combinations spread from the less U and LREE enriched part of the field of variation of zircon from granitoids towards that of zircon from mafic rocks (Fig. 8, fields from Belousova et al. 2002). This is reflected by the CART classification algorithm of Belousova et al. (2002), which gives a dominance of “dolerite” and different types of “granitoids” as suggested source rocks (Table 1). A few zircon analyses indicate source rock types such as “kimberlite” and “carbonatite”. Although both rock types are known to exist in Fennoscandia (e.g. O’Brien et al. 2005, Rukhlov & Bell 2010), they are rare, and unlikely to have yielded significant amounts of detrital material to the Brumunddal sandstone. Zircon grains indicating uncommon source rock types show anomalous REE patterns with low HREE and /or HREE / LREE ratios, combined with Eu/Eu* > 0.5 (NM15A-02, 04, 17, 21, 29, 32, 45, 66, Fig. 9) and probably formed by crystallization from hydrothermal solutions or during metamorphism rather than from magma; the relatively flat HREE pattern in NM15A-32 suggests coexistence with garnet (e.g. Hoskin & Schaltegger 2003). Chondrite normalized REE distribution patterns are strongly enriched in the heavy REE, as is common in zircon; all grains analysed have a marked positive Ce anomaly and a variable, negative Eu anomaly (Fig. 9). A majority of the analyses have (Yb/Sm)CN= 30 to 200, and deep, negative Eu anomalies (Eu/Eu* < 0.4). With the exception of a few grains with apparent LREE enrichment due to the presence of solid inclusions (see below), none of the zircons analysed from the Brumunddal sandstone show the characteristic flattening of the LREE pattern observed in zircons from “granitoids” by Belousova et al. (2002), and the patterns in general resemble those of zircon from “dolerite” and “basaltic” sources (Fig. 9). Anomalous LREE-enrichment seen in a few analyses (e.g. NM15A-57 and -67) are from ablations that have picked up minor amounts of LREE-rich inclusions (monazite?) in the zircon. Other anomalous analyses show relative enrichment of middle REE and a shallow Eu anomaly (e.g. NM15A-37, Fig. 9). Again, this is due to accidental ablation of small inclusions in the zircon, in this case most probably of apatite. The zircons of late Paleozoic age form a consistent NORWEGIAN JOURNAL OF GEOLOGY group with relatively low HREE enrichment (Yb/Sm)CN = 20-30). Of the 11 grains in this group, four have distinctly shallower Eu anomalies than the rest (Eu/Eu*>0.4, compared to Eu/Eu*≤ 0.3, Fig. 9). The patterns of the latter resemble those of Oslo Rift larvikite analysed by Belousova et al. (2002) in terms of pattern curvature and Eu anomaly, but at an overall lower REE enrichment level. The differences in concentration level may, however, be an effect of the different methods of internal standardization used in the two studies (assumed stoichiometric SiO2 value in this study vs. Hf analysed by electron microprobe). U-Pb and Lu-Hf characteristics of Silurian sandstone The age pattern of detrital zircon in the Silurian Orsa sandstone mimics that of the Brumunddal sandstone with age maxima in the late Paleoproterozoic, at ca. 1500 Ma and in the late Mesoproterozoic (Fig. 5a, data from Table 5a of Electronic Supplement). There is also a small contribution of Phanerozoic zircon, presumably from a Caledonian source. The variation of initial Hf isotope character also overlaps that of the Brumunddal sandstone (Fig. 6, data from Table 5b of Electronic Supplement l). The clearest difference between the two distribution patterns is due to a single, highly U-Pb discordant zircon with εHf=-21 at 1376 Ma (Orsa-38, Table 4); this is most probably a late Archaean or Paleoproterozoic zircon that has lost a significant amount of lead in a thermal event in Mesoproterozoic time. Discussion U-Pb, Lu-Hf and potential protosources of detrital zircon in the Brumundal sandstone. The detrital zircon ages from the Brumunddal sandstone range from late Archaean to Phanerozoic, with initial Hf istope signatures from near depleted mantle to crustal ratios. The distribution of age and initial 176Hf/177Hf or εHf in Fig. 6 is, however, far from random, and can be related to known crustal evolution events in Fennoscandia. Precambrian protosources. The near-CHUR initial Hf/177Hf of the single late Archaean detrital zircon analysed for Lu-Hf falls within the age and 176Hf/177Hf range of late Archaean granitoids from eastern Fennoscandia (Patchett et al. 1981, Lauri et al. 2011). Archaean rocks are exposed only in E Finland, NE Sweden N Norway and NW Russia, at considerable distance from their sites of deposition. 176 The Precambrian rocks of the Fennoscandian shield immediately bordering the Oslo Rift (Fig. 1c) belong to the late Paleoproterozoic Transscandinavian Igneous Belt (TIB, Högdahl et al. 2004) and the early Mesoproterozoic (“Gothian”) magmatic arc fragments (Andersen et al. 2004). The TIB was formed by multiple episodes NORWEGIAN JOURNAL OF GEOLOGY 11 1.0 6 ppm in zircon / ppm in chondrite Figure 7. Spider diagrams showing the overall variation of zircon compositions in the Brumunddal sandstone, normalized to chondritic values of McDonough and Sun (1995). The shaded background field is the interquartile range of zircon compositions in granitoids (Belousova et al. 2002). Provenance characteristics of the Brumunddal sandstone in the Oslo Rift 1.0 4 1.0 2 1.0 1.0-2 Pb La Ce Pr Nd Sm Eu Gd Th Dy Y Ho Er U Yb Lu Hf Nb Ta Ti 25000 106 105 104 Granitoids 15000 Mafic rocks Y ppm Hf ppm 20000 10000 10 1 10 2 10 3 Y ppm 10 10 4 1 10 -2 10 5 106 105 105 104 104 103 102 10 10 0.1 1 Nb/Ta 10 1 10 2 10 3 10 4 10 5 103 102 1 10 -1 U ppm 106 Y ppm Y ppm 103 102 5000 0 P 10 100 1 1 10 Yb/Sm 100 103 Figure 8. Source-indicating element and element-ratio plots showing that a significant proportion of the detrital zircons analysed falls between the main fields of zircon derived from granitoid and mafic (i.e. basalt, dolerite) sources (reference fields from Belousova et al. 2002). 12 T. Andersen et al. 104 NORWEGIAN JOURNAL OF GEOLOGY La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu La Ce Pr Nd < 320 Ma 10 Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 320-900 Ma 3 103 NM15A-37 102 NM15A-21 NM15A-32 10 1 102 10 1 10-1 ppm zircon / ppm chondrite 104 Larvikite, interquartile range, Belousova et al. (2002) NM15A-04 104 104 900-1250 Ma 900-1250 Ma 10 10-1 3 NM15A-35: inclusion M15A-01 102 103 NM15A-29 NM15A-67 102 NM15A-57 10 10 1 1 10-1 10-1 Basalt Dolerite Granitoids 104 1400-1500 Ma 10 104 > 1600 Ma 3 102 103 102 NM15A-26 10 10 1 1 10-1 10-2 NM15A-62 La Ce Pr Nd 10-1 Sm Eu Gd Tb Dy Ho Er Tm Yb Lu La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 10-2 Figure 9. Chondrite normalized REE patterns for zircon from the Brumunddal sandstone, divided into six groups (<320 Ma; 320-900 Ma; 900-1250 Ma divided in groups with deep and shallow Eu anomalies, respectively; 1400-1500 Ma; >1600 Ma, see text for further explanation). Reference fields for all except the <320 Ma groups are interquartile ranges of variation of zircon from granitoids, dolerites and basalts; for the <310 Ma group, the interquartile range of zircon from the Oslo Graben larvikite is shown instead (all reference data from Belousova et al. 2002). Analyses have been normalized to the chondrite values of Boynton (1984). NORWEGIAN JOURNAL OF GEOLOGY Provenance characteristics of the Brumunddal sandstone in the Oslo Rift of magmatic intrusion in the period 1.88 to 1.68 Ga; the TIB intrusions close to the Oslo Rift belong to the youngest part of the belt, known as TIB3, with intrusive ages around 1.68-1.67 Ga (Larson and Berglund 1992, Heim et al. 1996, Andersen et al. 2009a). Despite the large size and long time of emplacement of the TIB province, the initial Hf signature of magmatic zircon from TIB granitoids shows little variation, which can be represented by initial εHf= +2±3 at 1.88 Ga and 176Lu/177Hf≈ 0.015 (Andersen et al. 2009a). Given the short distance to potential source rocks within the TIB, the low abundance of TIB-like detrital zircons in the Brumunddal sandstone (Fig. 5a, 6) is somewhat surprising. On the other hand, a small group of Paleoproterozoic zircons with negative εHf overlaps the field of inherited zircon of possible Archaean origin in a TIB intrusion at the eastern margin of the belt in Sweden (Andersson et al. 2006, Andersen et al. 2009a). Furthermore, Paleoproterozoic zircons with such initial Hf characteristics are found in Paleoproterozoic granites within the Archaean domain of Finland (Patchett et al. 1981, Andersen & Lauri 2010). Paleoproterozoic crust with Lu-Hf properties similar to the rocks of the Transscandinavian Igneous Belt or their source in the deep crust has contributed source material to most of the Mesoproterozoic crustal magmatic events that can be recognized in southwestern Fennoscandia, even far west of the present TIB outcrop area (Andersen et al. 2001, 2002a, 2009b, Andersen 2005, Pedersen et al. 2009). Detrital zircons of early Mesoproterozoic age with initial Hf/177Hf approaching the DM curve resemble zircons from both Mesoproterozoic continental margin arc complexes (Andersen et al. 2002b, 2004) and those from felsic rocks from the Telemark block, which are still poorly constrained by Lu-Hf data. A small, coherent group of 1.45-1.50 Ga zircons with εHf= -3 to -8 can either be derived from a coeval, crustal source, or they can be TIBderived zircons that have lost lead in a Mesoproterozoic tectonothermal event. 176 During the Sveconorwegian period, southwestern Fennoscandia was affected by several episodes of mafic and felsic magmatism in different tectonic settings, ranging from ca. 1300 Ma to 920 Ma (Bingen and van Breemen 1998, Andersen et al. 2001, 2002a,b, 2007, 2009b, Vander Auwera et al. 2003, Pedersen et al. 2009). Magmatic events involving crustal underplating with mafic material with a depleted mantle Hf isotope signature (εHf ≈ +12) at 1.3 and 1.22 Ga have been documented in the Telemark block; after each of these events, the initial Hf isotope composition of zircon from magmatic rocks evolved towards less radiogenic compositions due to increasing effects of crustal source components (Andersen et al. 2007, Pedersen et al. 2009). Initial εHf of the large group of Sveconorwegian zircons overlaps well with the combined range of magmatic and inherited zircon from Sveconorwegian granitoids (Andersen et al. 2002a, 2007, Pedersen et al. 2009). 13 Caledonian protosources. Synorogenic intrusions in the nappes of the Scandinavian Caledonides that could be sources of early Paleozoic detrital zircon have been dated to 430-500 Ma (Gee et al. 2008 and references therein). The Caledonian mountain chain was mainly levelled by mid-Carboniferous time (Gabrielsen et al. 2005, 2010), but late Permian – Triassic uplift is likely to have enhanced relief to the west and northwest of the Oslo Graben system (Rohrman et al. 1995, Gabrielsen et al. 2010). By the early Triassic, sediments of Caledonian origin were transported southwards to become deposited in the Central European Basin (Paul et al. 2009). Unfortunately, no Hf isotope data are available from Caledonian intrusions. The considerable range of εHf (+ 1.4 to -11) observed suggests, however, that these zircons either crystallized from magmas with variable amounts of a TIB-like crustal component, or that they are zircons from Sveconorwegian protoliths that have lost lead in Caledonian metamorphism. Within-rift sources. Permian grains make up ca. 10 % of the analysed detrital zircon population (Fig. 5). Rocks from the Larvik pluton have been dated to 292-298 Ma by U-Pb on zircon and baddeleyite (Dahlgren et al. 1998, Dahlgren 2010). This event was, however, followed by the emplacement of syenitic to granitic plutons around 280 Ma (Pedersen et al. 1995, Haug 2007). Magmatic zircon from larvikite, nordmarkite and biotite granite in the ca. 280 Ma Sande and Drammen plutons have εHf in the range - 4 to +6, whereas zircons from pegmatites in the Larvik pluton are slightly more radiogenic at εHf = +8 ± 2 (Andersen et al. 2009b); no evidence has so far been found of hafnium derived from a late Paleozoic depleted mantle reservoir (εHf ≈ + 15) in any of these rocks. The 176Hf/177Hf at 280 Ma of the late Paleozoic zircons falls within the age and Hf isotope range of zircon in the younger group of intermediate to felsic intrusions in the rift. Two distinct types of REE patterns have been observed, with “deep” and “shallow” Eu anomalies, respectively (Fig. 9). The first group has REE pattern geometry similar to that of zircon from larvikite reported by Belousova et al. (2002), and therefore most likely originates from intermediate intrusive rocks. The other type must originate from other syenitic or (alkali) granitic plutonic rocks, which cannot be identified. Recycling of sedimentary rocks Most of the main documented crust-forming events in Fennoscandia are represented in the detrital zircon population of the Brumunddal sandstone, including accessory late Archaean and Paleoproterozoic zircons that must have originated in protosources east of the Transscandinavian Igneous Belt. It is highly unlikely that zircon from such a wide range of sources could have been brought into the rift in a single event of one-way transport from protosource to depositional basin. Rather, zircon must have been recycled through deposition in intermediate, sedimentary reservoirs followed by erosion and 14 T. Andersen et al. NORWEGIAN JOURNAL OF GEOLOGY new transport. This has eventually caused a relatively well mixed sample of the entire Fennoscandian surface to be brought into the Oslo Rift, including far-transported material from eastern Fennoscandia. sediments with a long and complex transport history. The close similarity in age and initial 176Hf/177Hf distribution of detrital zircon in the Brumunddal and Orsa sandstones indicates that Silurian sandstone is a very likely immediate precursor. Silurian, continental deposits may have had a wide distribution in western and central Fennoscandia in post-Caledonian time; outside of the Oslo Rift they are now preserved only as small erosional remnants. Like the Orsa sandstone, the late Silurian Ringerrike Group within the Oslo Rift itself (Davies et al. 2005 and references therein) contains material derived from both Fennoscandian and Caledonian sources (Turner & Whitaker 1976, Dahlgren & Corfu 2001). The Neoproterozoic was a quiet period in Fennoscandia, with little or no production of zircon-fertile igneous rocks. Nevertheless, Neoproterozoic detrital zircon ages have been reported from both the Neoproterozoic Hedmark basin (Bingen et al. 2005a) and from the Carboniferous Asker Group within the Oslo Rift (Dahlgren & Corfu 2001). In the Brumunddal sandstone, such zircons are conspicuously absent. A non-Fennoscandian source for Neoproterozoic zircon has been suggested (Dahlgren & Corfu 2001), but the range of 176Hf/177Hf in Neoproterozoic zircons in the Hedmark Basin with the observed U/Pb ages is fully compatible with Neoproterozoic loss of radiogenic lead in zircon from Sveconorwegian granito ids (Fig. 6). This could be caused by surface weathering prior to deposition, or by interaction with diagenetic fluidswithin the Hedmark Basin. The Silurian continental sediments make up the youngest of several cover sequences in Fennoscandia, ranging in age from Paleoproterozoic (e.g. Claesson et al. 1993, Lundqvist & Persson 1999, Lahtinen et al. 2002, Bergman et al. 2008), through Mesoproterozoic (e.g. Bingen et al. 2001, 2003, 2005b, Kuhonen & Rämö 2005, Andersen et al. 2004, Lamminen & Köykkä 2010) and Neoproterozoic (e.g. Nystuen et al. 2008, Bingen et al. 2005a, Lamminen et al. 2008, 2009) to Phanerozoic (e.g. Thorslund 1960, Bjørlykke 1974a, Turner & Whitaker 1978, Davies et al. 2005). Each of the successive cover sequences must have contained clastic material recycled from older deposits, as well as detritus derived directely from crystalline protosource rocks. Basins such as the late Vendian – Cambrian Peri-Thornquist, and the Pre-Baltic sub-basins (Sliaupa et al. 1997, Poprawa et al. 1999), the southwestern part of the Baltic Basin (Lazauskiene et al. 2002), as well as the Scandinavian (Bjørlykke 1974b, Worsley et al. 1983) and German-Polish Caledonian foreland basins (Lazuskiene et al. 2002) may have acted as intermediate repositories for far-transported detritus, including Paleoproterozoic and Archaean detrital zircons of east Fennoscandian origin. The Caledonian forebulge may have promoted uplift and erosion of these basins, thus releasing zircons of an easterly origin. The most zircon-fertile rocks within each of the protosource-terranes are granitic. Nevertheless, the trace element patterns are more in line with mafic to intermediate source rocks than with granite. Zircons with a relatively less steep LREE pattern are also likely to be more heavily enriched in uranium and thorium (Fig. 7; Belousova et al. 2002), and would therefore more easily become metamict due to internal radiation damage than less U and Th enriched (and hence also more strongly LREE depleted) ones. Metamict zircon is brittle and much more likely to be destroyed by abrasion during transport than grains with an intact crystal structure. A scarcity of typical “granitoid” zircon is therefore to be expected in The significance of Neoproterozoic detrital zircon ages in southwestern Fennoscandia. Time of deposition and tectonostratigraphic status of the Brumunddal sandstone The weighted average U/Pb age of 283±4 Ma (Fig. 3b) confirms the previous estimate of the maximum age limit for sedimentation based on Rb-Sr ages of the underlying rhomb porphyry lavas (Sundvoll et al. 1990, Larsen et al. 2008). By the time of deposition of the Brumunddal sandstone, rocks belonging to the ca. 280 Ma “batholith stage” of rift evolution must have been exposed to erosion at the surface, which suggests that deposition took place during the final stages of rift evolution (stage 6 in the chronology of Larsen et al. 2008), rather than during or immediately after rhomb porphyry volcanism (i.e. in stage 3), which preceded emplacement of the younger, batholitic bodies. Plausible sources of Permian zircon are only exposed to the south of the site of deposition, in the intrusive complexes of the Akershus and Vestfold graben segments. These zircon grains must therefore have been transported from south to north along the rift axis. The observation that some of these zircons are quite severely rounded due to abrasion during transport indicates significant transport for some, but not for all of the young zircons observed. The present data suggest that sediment transport took place from south to north along the graben axis, perhaps suggesting a topographic gradient in this direction. It is of particular interest to note that one of the REE-patterns shows the presence of a deep (plutonic) source, suggesting that plutons became exposed and eroded in the southern part of the graben simultaneously with ongoing volcanism in the Brumunddal area. This situation is not unique and is paralleled in the present East African rift system (Barberi et al. 1970, 1972). NORWEGIAN JOURNAL OF GEOLOGY Provenance characteristics of the Brumunddal sandstone in the Oslo Rift Why are Permian zircons only found in the magnetic fraction? Permian zircons were only found in the magnetic fractionat 1.5 A. With ca. 10% of the total number of analyzedzircons, this fraction is relatively large. However, if each of the two fractions from the magnetic separator are considered individually, their sizes are not sufficient to guarantee detection of even relatively large age fractions in each (Andersen 2005). However, it is still fully possible that the absence of syn-rift zircons from the non-magnetic fraction reflects a real physical property of these zircons. If so, relatively standard use of magnetic separation has efficiently removed them from the least magneticfraction. The tendency of magneticmineral separation to introduce undesirable bias in detrital zircon populations was pointed out by Sircombe and Stern (2002), and the present results could imply that such effects can be due to even a moderate use of the magnetic separator. Conclusions The Brumunddal sandstone was deposited during the final stages of evolution of the Oslo Rift, at a time when plutonic rocks formed during the ca. 280 “batholith” stage were exposed to erosion. The sandstone contains detrital zircon ranging in age from late Archaean to Permian. Combined U-Pb and Lu-Hf data suggest that detrital zircons from most of the region-wide petrogenetic events in Fennoscandia are represented in this single sediment, including zircons formed in events not represented by rocks within reasonable distance from the site of deposition. The likely explanation for this broad distribution of detrital zircon is recycling of material from Phanerozoic sedimentary cover on Fennoscandian basement, which may in turn contain material recycled from still older sedimentary rocks. Repeated transport and deposition has effectively mixed detrital zircon from a wide range of protosources, and depleted the detritus in metamict, high U zircons with typical “granitoid” trace element distribution patterns, leaving a population with a large proportion of zircons having trace element distributions more characteristic of “mafic” source rocks. Acknowledgments. - The research reproted her could be carried out thanks to economic support from the University of Oslo and Macquarie University. Thanks are due to Trine-Lise Knudsen for assistance in the field, Gunborg Bye-Fjeld for technical assistance with mineral sepa ration, Justin Payne for help with the LAM-ICPMS, to Elena Belousova and Norman Pearson for many helpful discussions, and to Bernard Bingenand an anonymous reviewer for helpful comments. T.A. wants to thank GEMOC and its directors S.Y. O’Reilly and W.L. Griffin for repeatedinvitations to spend fruitful research time in Australia. This is publication no. 17 from the Isotope Geology Laboratory at the Departmentof Geosciences, University of Oslo and contribution 696 from the AustralianResearch Council National Key Centre for the GeochemicalEvolution and Metallogeny of Continents (http://www. gemoc.mq.edu.au). 15 References Andersen, T. 2002: Correction of common lead in U-Pb analyses that do not report 204Pb. 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