Proficiency Testing Scheme for Water Analysis - Cooperation IFA

Transcription

Proficiency Testing Scheme
for Water Analysis
Round N131
Major Ions
Sample Dispatch:14 March 2016
University of Natural Resources
and Life Sciences, Vienna
Address:
University of Natural Resources
and Life Sciences, Vienna
Department of Agrobiotechnology
IFA-Tulln
Center for Analytical Chemistry
Head: Prof. Dr. Rudolf Krska
Konrad-Lorenz-Str. 20
3430 Tulln
Austria
Website:
www.ifatest.eu
www.ifa-tulln.ac.at
www.boku.ac.at
Telephone/Fax:
+43 2272 66280 - Ext
+43 2272 66280 - 403
Proficiency Testing (PT) Scheme:
Lab Manager:
Dr. Wolfgang Kandler
Ext 408
[email protected]
Ing. Uta Kachelmeier
Dipl.-HTL-Ing. Andrea Koutnik
Ing. Caroline Stadlmann
Ext 461
Ext 406
Ext 406
[email protected]
[email protected]
[email protected]
This report summarises the results of round N131 (major ions) within the IFA-Test
Proficiency Testing Scheme for Water Analysis. The samples N131A and N131B were
distributed to the participants on Monday, 14 March 2016. Closing date for reporting results
to the IFA-Tulln was Friday, 8 April 2016.
68 laboratories participated in this interlaboratory comparison. All participants submitted
results.
Samples
The samples consisted of artificial ground water. For sample preparation, ultrapure water
was spiked with solutions of salts and standards in order to simulate the ionic composition of
natural Austrian ground water. The following substances were added to the samples:
CaCO3, CaCl2, Ca(NO3)2, MgSO4, Mg(NO3)2, NaCl, KCl, NaHCO3, KHCO3, Na2SiO3,
C6H15PO3, potassium hydrogen phthalate (for DOC), sodium salicylate (for KMnO4-Index)
and certified standard solutions of NaNO2, NH4Cl, KH2PO4 and H3BO3. Both samples, N131A
and N131B, contained free CO2, which was used for dissolving the CaCO3. No other
substances (e.g. preservatives) were added. The samples were stabilised by sterile filtration
and low temperature.
Ammonium and Boron were not added to sample N131A in order to check the analytical
blank values.
Homogeneity, accuracy and stability tests at the IFA-Tulln
Six bottles per sample (N131A and N131B) were analysed for all investigated parameters
prior to shipment to the participants. The results of the measurements are listed in the result
tables and the parameter oriented part of the report (”IFA result”).
After four weeks, total hardness, Ca2+, Mg2+, Na+, K+, DOC, NH4+, NO2-, o-PO43-, Cl-, SO42boron, total-P (as PO43-), silicon and KMnO4-Index were determined in four bottles for N131A
and N131B. The results of the measurements are listed in the result tables and the
parameter oriented part of the report (”Stability test”).
According to our experience the samples remain stable up to 18 months when stored at 4°C
in the dark except for the parameters NH4+, NO2-, o-PO43- and DOC. These parameters
remain stable several weeks, whereas the first changes normally are observed for NH4+.
Results
Data evaluation was based on target concentrations that were calculated from the weights of
the substances and standards used to produce the samples. Their uncertainty intervals
correspond to the expanded uncertainty (coverage factor k = 2) as described in the
EURACHEM/CITAC Guide “Quantifying Uncertainty in Analytical Measurement, 3rd Edition
(2012)”.
The target value of the electrical conductivity was set to the laboratory mean (conventional
value). When calculated from more than 20 results, the laboratory mean has a smaller
uncertainty than our estimate calculated from the target concentrations by Debye-Hückel´s
theory: 2.4 % (p = 95 %). However, the calculated electrical conductivity was 475 µS/cm in
sample N131A and 354 µS/cm in sample N131B.
For the pH no target values can be assigned. The results can be compared on the tables. In
this kind of samples containing CO2 the pH tends to increase slowly over time.
Total phosphorus after digestion had to be determined according to DIN EN ISO 6878.
Diethyl ethylphosphonate (C6H15PO3), which can be determined as phosphate only after
oxidative digestion and potassium dihydrogen phosphate (KH2PO4) were used for
preparation. The target values of total-P were calculated from the weights of the two
substances. The results were given in mg/L o-PO43-.
The concentration of sodium salicylate, which was used as standard substance for the
KMnO4-Index, was 2.51 mg/L in sample N131A and 3.05 mg/L in sample N131B. Assuming
complete oxidation to carbon dioxide, nitrate and water (considering nitrite and ammonium),
the theoretical values were 3.53 mg/L O2 (N131A) and 4.51 mg/L O2 (N131B). However, the
laboratory mean values were taken as reference values in this report: 3.40 mg/L O2 for
N131A and 3.90 mg/L O2 for N131B.
Samples N131B were produced in two charges and had different concentrations of
3orthophosphate, total-P (as PO4 ) and boron. In this report, the corresponding
3target values are assigned to the parameters orthophosphate, total-P (as PO4 ) and
boron, relevant for the laboratory codes A to AH (N131B1 – N131B79) and as
3orthophosphate_1, total-P (as PO4 )_1 and boron_1 for the laboratory codes AI to BP
(N131B80 – N131B158).
Recoveries for individual laboratory results and overall mean values are related to the target
concentrations. The results were tested for outliers by application of the Hampel outlier test
(level of significance 99 %).
In order to check the analytical blank values, target concentrations were set to
<0.01 mg/L NH4+ and <0.02 mg/L Boron in N131A, which meets the minimum quantifiable
values defined by the Austrian ground and river water monitoring program and the
quantification limits of the analytical methods applied in the IFA.
The recoveries of the target concentrations, calculated from outlier-corrected data mean
values ranged between 97.1 % (silicon in sample N131A) and 111.4 % (total-P (as PO43-)_1
in sample N131B).
The between laboratory CVs covered the range between 1.1 % (el. Conductivity in sample
N131A) and 13.4 % (orthophosphate_1 in sample N131B).
All confidence intervals of the outlier-corrected laboratory mean values encompass the
corresponding target values with their uncertainties. Thus for all parameters, statistically, no
difference could be detected between theoretical target concentrations and outlier corrected
laboratory means.
z-scores
The most common approach is to form the z-score given by
z=
z
xi
x
σ
xi − x
σ
z-score
result of laboratory
target value or mean value („consensus value“)
standard deviation
Thus, the z-score is the ratio of the estimated bias (difference between result and target
value) and a standard deviation. The z-score criteria were determined from relative standard
deviations from all interlaboratory comparisons that were organised by the IFA-Tulln in the
period from 2005 to 2015. They represent long-term performance data of all former
participating laboratories. The z-scores are listed together with the recoveries in the tables of
the parameter oriented part.
Additionally, each laboratory obtained for every sample a single sheet that summarises the
z-scores of the laboratory in graphical and tabular form.
The following table lists the z-score criteria as relative standard deviation and their limits of
applicability. Z-scores were only calculated, if the target values were higher than these limits.
For Silicon (Total-Si as Si) z-Score-criteria is not available yet.
Parameter
z-Score-criteria (%)
Lower limit
Alkalinity KS4,3
2.5
0.2
mmol/L
Ammonium
13
0.01
mg/L
Boron
10
0.015
mg/L
Calcium
3.5
9
mg/L
Chloride
3.2
2
mg/L
el. Conductivity
1.4
50
µS/cm
DOC
6.2
1
mg/L
Hydrogen carbonate
3.0
20
mg/L
KMnO4-Index
11
1
mg/L
Magnesium
3.6
1
mg/L
Nitrate
3.5
2
mg/L
Nitrite
5.7
0.005
mg/L
Orthophosphate
11
0.015
mg/L
Potassium
4.9
0.5
mg/L
Silicon
-
-
mg/L
Sodium
3.6
1
mg/L
Sulphate
3.2
3
mg/L
3.0
0.5
13
0.015
Total hardness
Total-P (as
3PO4 )
Unit
°d
mg/L
Normally, a classification based on z-scores is made this way:
|z-Score|
Classification
<2
satisfactory
2<|z|<3
questionable
>3
unsatisfactory
Please note that this evaluation is made on the background of the average performance of
all participants of the IFA-Test-Systems proficiency testing scheme during the period from
2005 to 2015.
Illustration of results
An explanation to the illustration of the results is given on the following page.
The laboratory oriented part contains the measurement results and reported uncertainties
of each individual laboratory for all parameters together with the achieved recoveries in
graphical and tabular form. This part of the report also lists tables with the results originally
reported by the laboratories.
In the parameter oriented part the reported results and corresponding uncertainties are
illustrated together with recoveries of the target values and the z-scores for each parameter
and all laboratories. This information is presented in graphical and tabular form.
Results, which were identified as outliers by the Hampel test are marked with an asterisk.
These values were not considered for the calculation of statistical parameters (mean values.
standard deviations and confidence intervals). Moreover, the parameter oriented part
contains the uncertainties of the target value. The uncertainty intervals correspond to the
expanded uncertainty (coverage factor k = 2) as described in the EURACHEM / CITAC
rd
Guide “Quantifying Uncertainty in Analytical Measurement, 3 Edition (2012)”. The
uncertainty interval of the reference concentration is illustrated in the graphs as a grey band
around the 100 % recovery line.
Results, for which no recoveries could be calculated, are illustrated by one of the following
symbols: FN (false negative), FP (false positive) or • - symbol.
“FN”: A result is considered false negative when the “< result” reported is lower than the
corresponding target value
“FP”: False positive results can only be obtained for compounds that were evaluated on
the basis of a “< target value”. A result is termed FP if it does not include (strike) the
“< target” with its measurement uncertainty.
“•”: All other results for which no recoveries can be calculated are illustrated by this
symbol
Tulln, 19 April 2016
Relative deviation from
target value in percent
Target value obtained from sample preperation
Obtained from sample preperation, U=uncertainty
Determined at IFA prior to shipment of samples
Determined at IFA 3 weeks after sample dispatch
Recovery of target
value in percent
z‐Score of the
laboratory
grey band illustrates uncertainty
intervall of target value
Result ± uncertainty as stated by participant
Diagram 1: Measurement results and their uncertainties
An asterik indicates a result detected as outlier
by Hampel test
Laboratory mean and recovery of target value
with corresponding confidence intervals
(p=99%)
Number of results used for
calculation of statistic parameters
Result neither possible to calculate recovery
nor false positive or false negative
False negative: reported „<‐result“ is
lower than target value
Diagram 2: Recoveries and deviations from target values
EXPLANATION
Between laboratory
standard deviation
Interval expected to
encompass target value
as stated by participant
Illustration of Results
Tables and Parameter Oriented Part
Round N131
Major Ions
Sample Dispatch:14 March 2016
Results Sample N131A
Cond.
totalHardn.
KS 4.3
HCO3
Ca
Mg
Unit
µS/cm
°d
mmol/L
mg/L
mg/L
Target value
479
9.47
1.79
106
481
9.66
1.74
103
pH
IFA result
6.77
Stability test
-
9.74
2+
2+
+
+
-
Na
K
NO3
mg/L
mg/L
mg/L
mg/L
37.5
18.3
26.8
2.52
50.5
38.0
18.8
27.3
2.58
49.2
38.2
19.0
27.5
2.66
A
6.64
486
1.72
B
6.6
483
1.77
C
6.57
471
1.76
D
6.47
490
E
6.55
478
1.78
F
6.58
437
1.73
G
6.54
476
9.24
1.75
H
7.15
483
9.33
1.78
I
6.53
480
J
7.27
477
9.4
1.61
K
6.41
485
9.5
1.77
L
6.51
479
9.2
1.77
M
6.60
474
N
6.07
486
1.77
O
6.6
487
1.68
P
6.69
474
Q
6.52
480
R
6.9
479
9.4
1.78
109
36.6
18.5
26.4
2.42
49.2
S
6.49
484
9.11
1.78
108
35.1
18.3
27.1
2.38
48.2
T
8.01
481
9.83
1.85
109.81
39.38
18.77
26.57
2.54
46.88
U
6.54
498
V
6.7
476
9.2
1.76
104
36.1
18.2
26.0
2.36
49.13
W
6.67
487
9.36
1.81
108
37.6
18.3
26.6
2.47
48.1
X
6.7
484
9.3
1.8
107
37.6
17.5
26.3
2.51
45.2
Y
6.60
459
1.75
106.75
37.10
18.03
26.06
2.36
54.31
9.52
1.75
102
46.3
103.7
38.1
18.0
27.0
2.31
49.55
109
37
18
27
2.5
1.79
9.49
1.74
47.2
49
50.0
98
108
37.7
17.9
49.1
38.1
18.0
46.4
36.9
17.7
37.4
17.0
47
50.0
106.3
38.3
18.0
47
1.76
49.3
48.7
Z
>35
AA
6.54
478
1.79
106
AB
6.6
478
AC
6.66
AD
AE
9.31
1.77
105
37.1
17.9
26.4
2.48
50.9
479
9.60
1.77
105
37.5
18.8
26.8
2.39
48.6
6.3
477
9.6
1.75
104
39
18
27
2
49
6.73
477
9.5
1.77
105
37.7
18.2
26.9
2.42
49.8
475
9.31
1.79
106
37.1
17.9
26.7
2.63
48.9
AF
49.6
AG
6.48
481
9.37
1.79
106
37.5
17.8
25.6
2.71
49.5
AH
6.3
481
9.4
1.67
102.1
37.03
18.23
26.78
2.71
48.823
Uncertainties Sample N131A
Cond.
±
totalHardn.
±
KS 4.3
±
HCO3
±
Ca
±
Mg
±
Unit
µS/cm
°d
mmol/L
mg/L
mg/L
Target value
1
0.07
0.01
1
10
0.58
0.07
4
pH
±
IFA result
0.2
Stability test
-
0.58
A
0.01
3
0.05
B
0.2
5
0.05
0.05
5
0.1
H
0.1
14
I
0.04
5
0.1
10
2+
2+
+
+
-
Na
±
K
±
NO3
±
mg/L
mg/L
mg/L
mg/L
0.3
0.2
0.2
0.03
1
2.3
1.1
1.6
0.21
2
2.3
1.1
1.7
0.21
4
1
2
0.2
3
C
D
E
F
G
0.8
0.07
4
0.05
2
0.8
J
K
L
0.1
0.05
1
1
M
N
0.018
0.502
O
P
0.1
5
0.2
0.1
5
1
0.5
2
10
0.9
0.2
11
3.7
1.9
2.6
0.24
4.9
0.91
0.11
6.5
3.6
1.9
2.8
0.28
2.2
3.9
1.9
2.7
0.27
3.9
Q
R
S
0.06
10
T
0.1
4.51
U
0.33
25
V
0.1
10
0.9
0.18
11
3.6
1.8
2.6
0.24
4.9
W
0.02
4.0
0.03
0.023
1.2
0.10
0.06
0.12
0.03
0.30
X
0.20
14.5
1.4
0.18
10.70
5.6
2.6
3.9
0.4
6.8
0.37
0.23
0.04
0.06
0.07
0.19
4.9
Y
Z
AA
AB
0.3
20
0.4
0.1
4
3
2.2
4
0.4
4
AC
0.27
19
1.73
0.07
4.2
6.8
3.4
4.8
0.43
4.4
AD
0.1
10
1.0
0.12
8.3
1.6
1.1
1.1
0.2
3.4
AE
0.30
14
1.1
0.08
5
3.4
1.7
2.2
0.20
4.5
2.88
0.159
0.005
0.32
0.58
0.59
0.27
0.060
0.57
0.94
0.09
5
3.8
1.8
2.6
0.27
5.0
0.183
15.32
1.481
1.094
1.607
0.271
1.9529
AF
AG
0.13
7
AH
0.38
18.9
Cond.
totalHardn.
KS 4.3
HCO3
Ca
Mg
Unit
µS/cm
°d
mmol/L
mg/L
mg/L
Target value
479
9.47
1.79
106
481
9.66
1.74
103
pH
IFA result
6.77
Stability test
-
9.74
2+
+
+
-
Na
K
NO3
mg/L
mg/L
mg/L
mg/L
37.5
18.3
26.8
2.52
50.5
38.0
18.8
27.3
2.58
49.2
38.2
19.0
27.5
2.66
36.6
18.2
27.6
2.7
38.486
17.586
24.798
2.543
37.5
17.9
26.9
2.5
AI
6.83
483
9.3
1.81
AJ
6.5
479
9.46
1.81
AK
6.54
481
9.35
1.82
107
AL
6.62
483
AM
7.10
86
1.75
104
AN
6.76
482
9.67
1.95
116.1
38.36
18.64
26.83
2.56
49.35
AO
6.64
462
9.2
1.67
102
36.6
17.9
30
2.5
51.2
AP
6.54
478.4
9.5
1.84
112.3
36.9
18.0
27.1
2.77
50.2
AQ
6.65
39.3
17.7
27.0
2.5
47.6
AR
6.60
474
AS
5.75
393
AT
6.7
477
9.2
0.87
AU
7.010
490
9.664
1.7966
AV
6.73
481
9.56
1.77
AX
6.51
471
9.4
1.72
AY
6.58
471
9.5
1.78
AZ
6.6
457
9.4
1.775
105
BA
6.59
458
1.76
100
BB
6.59
483
9.09
1.77
BC
6.5
479
9.3
BD
6.81
430
BE
6.60
BF
9.4
1.8
107.4
2+
49.7
49.3
48.2
109.8
44.1
36.3
18.07
26.8
3.02
65.97
53
35
19
109.6252
38.2966
18.7027
27.8707
7.3105
40.2026
37.80
18.18
26.55
2.47
42.30
36.7
18.4
26.1
2.60
49
38.0
18.2
26.8
2.5
50.5
36.1
19.0
26.6
2.8
49.6
105.0
34.93
18.22
26.46
2.65
50.65
1.75
107
37
18
26
2.6
50
9.60
1.83
112
36.9
17.9
26.0
2.33
49.0
478
9.4
1.86
113.49
37.58
18.21
26.38
2.71
40.33
6.4
481
9.2
1.76
104
37.7
17.5
26.7
2.52
49.6
BG
6.46
490
BH
6.7
479
9.47
1.78
106
37.9
18.4
26.2
2.53
52.9
BI
6.62
477
9.6
1.88
114.7
38.81
18.18
27.12
2.57
50.25
BJ
6.70
475
1.78
109
52.8
AW
102
49.8
BK
48.4
1.793
BL
475.5
9.41
1.80
106.4
36.6
18.7
51.4
BM
7.09
474
9.07
1.65
100
36.8
17.0
24.9
2.68
49.2
BN
6.3
480
9.57
1.72
102
38.5
18.2
27.1
2.51
52.9
41.08
15.68
BO
BP
0.18
6.85
479
1.77
104.9
46.47
Cond.
±
totalHardn.
±
KS 4.3
±
HCO3
±
Ca
±
Mg
±
Unit
µS/cm
°d
mmol/L
mg/L
mg/L
Target value
1
0.07
0.01
1
10
0.58
0.07
4
pH
±
IFA result
0.2
Stability test
-
0.58
AI
10
0.5
0.09
5.4
AJ
2+
2+
+
+
-
Na
±
K
±
NO3
±
mg/L
mg/L
mg/L
mg/L
0.3
0.2
0.2
0.03
1
2.3
1.1
1.6
0.21
2
2.3
1.1
1.7
0.21
1.8
0.9
1.4
0.1
2.287
2.431
2.793
0.270
1.5
AK
AL
AM
0.15
0.09
AN
0.02
11
0.02
0.08
5.2
0.34
0.10
1.00
0.10
0.62
AO
0.03
3
0.1
0.06
4
0.1
0.1
0.2
0.02
0.4
AP
2.1
1.4
1.5
0.15
AQ
4.7
2.1
2.7
0.3
AR
0.056
8.4
AS
0.02
10
1.3
0.079
1.1
4.9
9.0
8.8
0.1
0.15
0.1
0.05
0.15
0.0052
0.0455
0.0450
0.0078
0.0250
0.357
0.916
0.204
0.053
0.451
1.9
1.0
1.4
0.18
2
AT
AU
AV
1.1129
0.0064
0.03
3
0.03
AX
0.09
5
0.5
0.04
AY
0.02
30
0.2
0.02
0.6
0.6
0.2
0.06
0.5
0.120
2.0
2.0
2.0
0.3
3.0
3.48
1.45
2.37
0.24
4.54
AW
AZ
10.0
3
BA
0.12
8.7
BB
0.2
10
BC
0.1
3
1
0.10
3
1
1
2
0.5
2
BD
0.05
2
0.6
0.1
6.1
1.7
0.8
0.8
0.3
0.4
12
0.9
0.2
10
4
2
3
0.3
5
BE
BF
BG
0.05
2.0
3.03
BH
0.3
0.3
0.2
0.08
0.8
BI
BJ
0.13
29
0.036
BK
BL
2.2
3.9
0.01
9.5
0.19
0.04
2.2
0.7
0.4
28.8
0.718
0.163
9.7
2.31
2.19
1.39
0.43
3.1
BM
BN
BO
BP
0.075
14
0.05
1.76
0.251
5.55
0.40
-
NH4
Cl
SO4
2-
o-PO4
Boron
DOC
Unit
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Target value
0.040
<0.01
42.1
39.4
0.090
<0.02
4.06
0.148
3.40
2.28
IFA result
0.040
<0.01
41.8
39.8
0.090
<0.02
4.09
0.159
3.57
2.18
Stability test
0.040
<0.01
43.0
39.7
0.090
<0.02
3.98
0.168
3.51
2.24
A
0.039
<0.02
41.9
B
0.041
<0.025
C
0.0401
<0.03
43.4
0.0954
D
0.045
<0.020
42.5
0.087
E
0.0403
<0.03
0.0907
F
0.041
<0.01
0.087
G
0.0401
<0.026
42.08
39.33
0.0837
H
0.042
<0.030
42
39
0.089
I
0.039
<0.03
42.4
0.096
0.142
J
0.043
0.002
43.8
0.108
0.153
2.17
K
0.038
<0.01
42
0.092
0.146
2.28
L
0.042
<0.02
41.2
0.090
0.147
M
0.041
<0.03
0.092
0.138
N
0.041
<0.03
0.098
0.168
O
0.039
<0.02
0.090
0.153
P
0.041
<0.02
41.9
0.091
0.148
Q
0.040
0.010
41.1
38.3
R
0.040
<0.010
41.1
38.8
S
0.041
<0.025
41.9
38.5
0.094
T
0.040
<0.009
39.71
37.15
0.098
3.91
0.156
U
0.048
<0.012
41.0
39.3
0.089
4.52
0.135
V
0.039
<0.010
40.92
38.8
0.089
4.006
0.141
W
0.040
<0.010
42.0
38.7
0.088
<0.010
4.19
0.139
X
0.04
0.009
38.9
36.60
0.095
<0.02
4.40
0.137
Y
0.04
0.01
41.15
41.47
0.07
4.51
0.13
Z
+
-
<0.01
3-
total-P KMnO43as PO4
Index
NO2
0.088
0.150
0.089
0.147
4.42
<0.05
4.22
<0.002
0.076
4.0
3.99
Silicon
2.22
0.141
3.30
2.26
0.139
3.48
2.18
0.146
2.17
0.1396
2.15
0.15
2.2
3.5
3.48
2.26
2.24
2.1
3.4
0.144
2.23
2.15
3.25
3.20
0.082
0.109
0.086
0.143
AA
0.041
<0.005
41.5
AB
0.041
<0.013
42.6
39.3
0.085
AC
0.039
<0.01
41.0
38.3
0.095
AD
0.041
<0.02
41
37
0.089
AE
0.039
<0.008
42.0
38.8
0.091
AF
0.0394
<0.0064
41.9
39.3
AG
0.0411
<0.010
41.1
AH
0.041
0.005
39.93
3.17
2.19
4.16
0.146
4.28
0.158
3.31
4.26
0.147
3.9
<0.004
4.13
0.150
0.0864
[0.002]
4.22
0.1480
38.9
0.089
<0.020
4.03
0.146
3.48
37.03
0.84
[0.00114]
4.3
0.15
3.5
<0.01
2.25
2.21
2.26
2.2
-
+
NH4
±
Cl
±
SO4
±
2-
o-PO4
±
Boron
±
DOC
±
Unit
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Target value
0.001
0.5
0.5
0.001
0.05
0.002
0.09
0.05
IFA result
0.002
1.7
1.6
0.013
0.41
0.022
0.36
0.17
Stability test
0.002
1.7
1.6
0.013
0.40
0.024
0.35
0.18
A
0.003
0.01
B
0.01
-
2
3-
Index
±
±
NO2
±
Silicon
±
0.003
0.003
0.05
0.01
0.01
0.01
0.005
0.005
0.005
H
0.003
0.004
1
I
0.002
0.01
3
0.003
0.005
0.1
0.05
1
0.005
0.005
0.2
0.1
0.002
0.003
0.01
0.01
0.1
0.2
C
D
E
F
G
2
0.009
0.001
0.2
0.01
0.1
J
K
L
0.005
M
N
0.0004
O
P
0.05
0.02
2
Q
R
0.010
4.1
3.9
S
0.002
2.2
1.7
0.005
T
0.004
4.0
3.7
0.009
0.39
0.015
U
0.013
4.1
3.9
0.015
0.45
0.016
V
0.010
4.1
3.9
0.009
0.40
0.014
W
0.0006
0.16
0.04
0.0002
0.16
0.003
X
0.006
0.001
5.8
5.5
0.014
0.66
0.021
Y
0.00
0.00
0.03
0.04
0.01
0.04
0.00
0.007
0.5
0.32
Z
0.05
0.006
0.004
AA
AB
0.004
4
3
0.012
0.7
0.02
AC
0.004
3.7
3.4
0.009
0.39
0.006
0.3
AD
0.004
3.3
2.2
0.013
0.68
0.019
0.4
AE
0.005
2.1
2.0
0.009
0.37
0.015
AF
0.0009
0.15
0.33
0.0020
0.01
0.0019
AG
0.0062
4.1
3.9
0.013
0.40
0.029
0.35
AH
0.003
2.396
1.481
0.0101
0.34
0.0223
0.5000
<0.006
0.0005
0.2
0.09
0.3
-
+
NH4
Cl
SO4
2-
o-PO4
Boron
DOC
Unit
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Target value
0.040
<0.01
42.1
39.4
0.090
<0.02
4.06
0.148
3.40
2.28
IFA result
0.040
<0.01
41.8
39.8
0.090
<0.02
4.09
0.159
3.57
2.18
Stability test
0.040
<0.01
43.0
39.7
0.090
<0.02
3.98
0.168
3.51
2.24
AI
0.039
<0.03
42.1
39.7
0.089
<0.050
4.07
0.175
3.25
2.36
4.1
0.144
3.64
2.6
-
3-
Index
NO2
AJ
Silicon
<0.005
AK
0.039
<0.01
AL
0.04
<0.05
AM
0.05
<0.01
57.3
AN
0.043
<0.01
39.40
38.72
AO
<0.01
0.012
44.3
41.1
AP
0.04
<0.013
42
39.5
0.03
40.5
38.0
<0.1
41.2
38.3
<0.6
39.49
40.65
0.076
0.146
45
40
0.09
0.17
3.1
0.1656
3.120
AQ
41.8
39.0
0.81
AR
0.043
AS
0.04
AT
0.038
0.01
AU
0.4745
0.0125
AV
0.043
0.1889
AW
0.04
<0.05
AX
0.04
<0.04
40
39
AY
0.035
<0.03
42.6
39.8
AZ
0.050
<0.050
41.6
39.0
35.9927 34.1436
36.45
0.098
0.83
0.086
3.91
0.139
4.75
<0.2
<0.1
0.23
2.11
0.05
0
4.1
0
5.5243
<0.15
35.61
3.2
1.89
2.2752
3.7
0.10
0.08
0.0565
4.25
0.146
3.331
2.2
3.39
2.15
4.48
<0.010
4.13
BA
3.92
BB
0.0394
<0.02
42.21
40.57
0.087
<0.010
3.89
BC
0.04
<0.02
41
40
<0.05
4.1
0.16
BD
0.043
<0.005
40.7
37
4.2
0.151
BE
0.042
<0.05
42.29
32.72
BF
0.041
<0.01
43.1
38.9
4.2
0.17
BG
0.073
0.024
BH
0.043
0.011
42.9
40.1
0.086
BI
0.05
<0.02
43.55
42.46
<0.02
5.58
BJ
0.0419
<0.013
42.9
38.4
0.0919
4.61
0.153
BL
0.039
<0.02
42.8
40.2
0.090
4.13
0.146
BM
0.044
0.016
41.5
39.4
0.113
<0.01
9.71
0.121
BN
0.040
<0.04
44.1
40.6
<0.020
4.13
0.110
42.53
39.07
0.092
3.60
2.31
3.3
2.2
<0.01
0.087
<0.005
0.095
3.44
2.24
0.161
[0.002]
0.122
3.09
2.59
BK
BO
BP
0.040
<0.020
2.51
2.72
-
+
NH4
±
Cl
±
SO4
±
2-
o-PO4
±
Boron
±
DOC
±
Unit
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Target value
0.001
0.5
0.5
0.001
0.05
0.002
0.09
0.05
IFA result
0.002
1.7
1.6
0.013
0.41
0.022
0.36
0.17
Stability test
0.002
1.7
1.6
0.013
0.40
0.024
0.35
0.18
AI
0.004
1.3
1.2
0.009
0.41
0.018
0.33
0.24
0.12
0.006
-
3-
Index
±
±
NO2
±
Silicon
±
AJ
AK
AL
AM
AN
0.03
0.003
AO
0.005
0.2
0.05
0.46
0.44
0.3
0.4
0.002
0.42
AP
0.12
AQ
0.004
5.7
5.3
0.02
AR
0.0077
8.1
7.7
1.2
0.55
AS
0.08
0.2
0.8
0.002
0
0
0.0918
0.1839
0.6410
0.2490
0.003
0.0017
0.1
0.005
0.17
0.03
0.002
0.05
AT
AU
0.6170
0.0461
0.0392
0.0213
AV
0.025
0.004
4.38
0.842
2
2
0.25
3.0
0.03
2.0
2.0
0.50
AW
AX
0.002
AY
0.015
AZ
0.012
0.08
BA
0.37
BB
0.0027
5.04
4.04
BC
0.01
2
3
BD
0.002
0.2
2
4
4
0.003
0.013
0.27
0.54
0.5
0.02
0.002
0.2
0.005
0.009
0.4
0.02
0.3
0.06
BE
BF
0.004
BG
0.031
0.002
BH
0.003
0.003
0.4
0.0042
0.0019
0.010
0.014
1.1
0.002
0.002
1.3
5.8
0.0046
0.92
0.038
0.002
2.6
2.4
0.006
0.17
0.010
0.0040
3.97
3.65
0.248
0.0110
0.60
0.70
0.3
0.2
0.81
BI
BJ
BK
BL
BM
BN
BO
BP
0.003
0.65
Results Sample N131B
Cond.
totalHardn.
KS 4.3
HCO3
Ca
Mg
Unit
µS/cm
°d
mmol/L
mg/L
mg/L
Target value
356
5.40
2.96
177
359
5.44
2.89
173
pH
IFA result
6.68
Stability test
-
5.54
2+
2+
+
+
-
Na
K
NO3
mg/L
mg/L
mg/L
mg/L
27.5
6.73
36.8
7.55
4.87
27.7
6.76
37.4
7.65
4.62
28.1
6.91
37.7
7.87
A
6.61
361
2.83
B
6.5
359
2.88
C
6.63
348
2.91
D
6.45
360
E
6.50
355
2.97
F
6.53
323
2.85
G
6.45
356
5.60
2.90
H
6.99
360
5.46
2.92
I
6.50
359
J
7.25
355
5.5
2.77
K
6.28
355
5.4
2.90
L
6.44
356
5.3
2.92
M
6.52
352
2.85
4.4
N
5.95
359
2.92
4.85
O
6.5
358
2.68
P
6.54
358
Q
6.43
356
R
6.8
357
5.3
2.90
177
26.7
6.76
36.1
7.20
4.7
S
6.45
363
5.13
2.93
179
26.0
6.53
37.9
7.43
4.73
T
8.35
360
5.81
3.00
179.97
29.81
7.11
36.32
7.82
4.94
U
6.58
363
V
6.6
350
5.2
2.91
178
26.5
6.69
35.6
7.12
4.72
W
6.82
353
5.37
2.99
197
27.6
6.77
36.3
7.29
3.90
X
6.6
362
5.4
2.88
173
28.3
6.3
34.4
8.15
4.2
Y
6.58
344
2.92
178.12
32.94
6.19
35.44
35.44
4.47
5.43
2.89
170
4.20
173.3
27.8
6.62
36.3
7.70
4.76
178
28
6.7
36
7.5
2.95
5.43
2.89
4.56
4.7
4.7
169
178
176.5
27.5
7.2
3.8
27.7
6.8
4.82
26.9
6.8
28.0
6.6
4.5
2.94
4.75
4.75
Z
3.81
AA
6.50
356
2.96
177
AB
6.5
356
AC
6.77
AD
AE
5.31
2.79
167
27.2
6.57
36.1
7.55
4.79
356
5.42
2.93
176
27.3
6.91
36.7
7.22
4.87
6.5
356
5.5
2.92
175
28
7
37
7
5
6.65
354
5.5
2.93
176
28.4
6.72
37.0
7.50
4.65
352
5.37
2.93
175
27.4
6.66
36.2
7.63
4.72
AF
4.70
AG
6.45
359
5.34
2.96
178
27.3
6.58
34.7
7.76
4.93
AH
6.2
352
5.3
2.78
169.3
27.1
6.58
38.2
7.51
4.626
Uncertainties Sample N131B
Cond.
±
totalHardn.
±
KS 4.3
±
HCO3
±
Ca
±
Mg
±
Unit
µS/cm
°d
mmol/L
mg/L
mg/L
Target value
1
0.05
0.02
1
7
0.33
0.12
7
pH
±
IFA result
0.2
Stability test
-
0.33
A
0.01
3
0.05
B
0.2
5
0.05
0.05
5
0.1
H
0.1
11
I
0.04
5
0.1
10
2+
2+
+
+
-
Na
±
K
±
NO3
±
mg/L
mg/L
mg/L
mg/L
0.3
0.08
0.3
0.04
0.11
1.7
0.41
2.2
0.61
0.18
1.7
0.41
2.3
0.63
3
0.4
2
0.5
3
C
D
E
F
G
0.5
0.12
7
0.05
0.1
0.1
J
K
L
0.1
0.05
1
0.5
M
N
0.029
0.049
O
P
0.1
5
0.2
0.1
5
1
0.5
2
10
0.5
0.3
18
2.7
0.68
3.6
0.72
0.5
0.51
0.18
10.7
2.7
0.67
3.9
0.88
0.21
3.0
0.7
3.6
0.81
0.4
Q
R
S
0.06
7
T
0.1
4.51
U
0.33
18
V
0.1
10
0.5
0.29
18
2.7
0.70
3.6
0.72
0.5
W
0.02
2.6
0.006
0.006
0.58
0.06
0.01
0.30
0.04
0.06
X
0.20
10.9
0.8
0.29
17.30
4.2
0.9
5.2
1.2
0.6
5.02
0.05
0.22
0.22
0.07
0.30
0.48
Y
Z
0.15
AA
AB
0.3
15
0.3
0.1
6
3
0.8
6
1.2
0.3
AC
0.27
14
0.98
0.12
7.0
4.9
1.2
6.6
1.30
0.44
AD
0.1
7
0.6
0.2
14
1.1
0.4
1.5
0.6
0.2
AE
0.30
11
0.7
0.12
7
2.6
0.65
3.0
0.52
0.42
0.36
0.089
0.005
0.32
0.60
0.138
0.27
0.257
0.09
0.54
0.15
9
2.7
0.66
3.5
0.78
0.49
0.416
25.4
1.084
0.395
2.292
0.751
0.185
AF
AG
0.13
7
AH
0.37
14.1
Cond.
totalHardn.
KS 4.3
HCO3
Ca
Mg
Unit
µS/cm
°d
mmol/L
mg/L
mg/L
Target value
356
5.40
2.96
177
359
5.44
2.89
173
pH
IFA result
6.68
Stability test
-
5.54
2+
+
+
-
Na
K
NO3
mg/L
mg/L
mg/L
mg/L
27.5
6.73
36.8
7.55
4.87
27.7
6.76
37.4
7.65
4.62
28.1
6.91
37.7
7.87
26.4
6.60
37.3
7.9
28.285
6.630
34.591
7.440
27.3
7.1
36.9
7.6
AI
6.82
364
5.2
2.97
AJ
6.5
358
5.43
2.94
AK
6.51
357
5.43
2.96
179
AL
6.57
356
AM
6.96
149
2.98
179
AN
6.78
359
5.56
3.11
186.7
28.28
6.94
36.56
7.45
4.71
AO
6.62
346
5.1
2.79
170
26.1
6.5
41
7.6
4.9
AP
6.43
356.0
5.05
2.98
181.5
26.7
7.15
37.4
7.74
5.05
AQ
6.59
28.6
6.7
37.6
7.5
4.6
AR
6.53
354
AS
5.78
293
AT
7.1
355
5.3
1.43
AU
6.935
362
7.598
2.9033
AV
6.67
353
5.46
2.92
AX
6.44
353
5.4
2.88
AY
6.58
350
5.4
2.93
AZ
6.6
339
5.3
2.927
176
BA
6.57
342
2.90
170
BB
6.55
360
5.12
2.92
BC
6.5
356
5.3
BD
6.78
321
BE
6.60
BF
5.42
3
178.3
2+
4.6
4.8
6.08
183.1
3.45
27.86
6.64
38.07
7.36
5.09
87
25
7.1
177.1496
28.0852
6.9757
38.205
2.3947
6.2260
27.75
6.70
36.36
7.46
4.39
28.2
6.5
36.3
7.9
4.8
27.6
6.6
36.6
7.6
4.8
26.9
6.5
36.5
7.2
4.5
175.5
25.42
6.76
35.26
7.58
4.90
2.90
177
27
6.6
36
7.5
4.8
5.53
2.91
177
27.0
6.7
35.5
6.95
4.8
355
5.2
2.96
180.61
28.18
6.83
37.30
8.53
4.4
6.3
355
5.6
2.88
173
28.7
6.76
36.8
7.81
4.6
BG
6.34
367
BH
6.6
348
5.48
2.93
176
28.3
6.84
34.7
7.40
4.66
BI
6.61
359
5.5
2.92
178.2
28.50
6.52
37.37
7.68
4.95
BJ
6.66
353
2.94
179
5.3
AW
173
5.21
BK
4.71
2.946
BL
357.8
5.38
2.96
177.5
27.3
6.8
4.93
BM
7.10
351
5.02
2.63
160
26.1
5.96
32.3
6.49
4.34
BN
6.5
350
5.55
2.86
172
28.5
6.83
36.8
7.61
4.88
25.05
9.12
BO
BP
0.30
6.80
357
2.93
175.7
4.85
Cond.
±
totalHardn.
±
KS 4.3
±
HCO3
±
Ca
±
Mg
±
Unit
µS/cm
°d
mmol/L
mg/L
mg/L
Target value
1
0.05
0.02
1
7
0.33
0.12
7
pH
±
IFA result
0.2
Stability test
-
0.33
AI
7
0.3
0.15
8.9
AJ
2+
2+
+
+
-
Na
±
K
±
NO3
±
mg/L
mg/L
mg/L
mg/L
0.3
0.08
0.3
0.04
0.11
1.7
0.41
2.2
0.61
0.18
1.7
0.41
2.3
0.63
1.3
0.33
1.9
0.4
2.344
0.230
2.727
0.270
0.1
AK
AL
AM
AN
0.20
4
0.02
0.08
2.6
0.10
0.12
1.38
0.34
0.18
AO
0.03
2
0.1
0.11
7
0.1
0.1
0.2
0.06
0.1
AP
1.5
0.23
0.93
0.24
AQ
3.4
0.8
3.8
0.9
AR
0.056
6.3
AS
0.02
10
0.73
0.098
6.0
0.9
0.89
0.1
0.15
0.1
0.05
0.15
0.0067
0.0832
0.0472
0.0608
0.0119
0.357
0.916
0.109
0.053
0.340
1.5
0.4
1.9
0.4
0.3
AT
AU
AV
0.0159
0.0159
0.02
5
0.01
AX
0.09
5
0.3
0.04
AY
0.02
30
0.2
0.02
0.6
0.6
0.2
0.06
0.5
0.200
2.0
1.0
2.0
0.7
0.5
2.55
0.55
3.19
0.69
0.43
AW
AZ
10.0
3
BA
0.12
6.5
BB
0.2
7
BC
0.1
3
0.5
0.10
4
1
1
2
1
0.8
BD
0.05
2
0.6
0.1
6.1
1.7
0.8
0.8
0.3
0.4
9
0.6
0.3
15
3
0.7
4
0.8
0.5
BE
BF
BG
0.05
2.0
0.317
BH
0.3
0.25
0.2
0.08
0.17
BI
BJ
0.13
21
0.059
BK
BL
3.6
0.38
0.02
7.2
0.11
0.06
3.6
0.5
0.2
21.0
0.416
0.272
16.3
1.71
0.819
1.39
0.43
0.30
BM
BN
BO
BP
0.075
11
0.09
2.39
0.761
0.513
0.40
-
NH4
Cl
SO4
2-
o-PO4
Boron
DOC
Unit
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Target value
0.083
0.050
8.02
22.8
0.071
0.071
2.63
0.076
3.90
4.56
IFA result
0.083
0.051
7.77
23.1
0.072
0.073
2.62
0.079
4.10
4.39
Stability test
0.083
0.051
8.24
22.9
0.073
0.071
2.58
0.084
4.01
4.47
A
0.083
0.05
7.8
B
0.083
0.054
C
0.0811
0.043
9.1
0.0745
D
0.088
0.051
7.8
0.073
E
0.0836
0.049
0.0720
F
0.086
0.054
0.072
G
0.0803
0.062
8.58
23.01
0.0690
H
0.089
0.062
8.0
22
0.070
I
0.082
0.06
7.9
0.080
0.075
J
0.085
0.054
9.6
0.082
0.088
4.38
K
0.078
0.055
8.0
0.073
0.074
4.58
L
0.086
0.048
8.2
0.071
0.079
M
0.082
0.05
8
0.070
0.071
N
0.085
0.044
0.076
0.100
O
0.082
0.060
0.070
0.079
P
0.084
0.05
7.9
0.070
0.077
Q
0.082
0.056
8.33
21.5
R
0.084
0.048
7.8
22.1
S
0.084
<0.025
7.78
22.2
0.076
T
0.083
0.055
7.63
21.99
0.080
2.58
0.083
U
0.092
0.059
7.9
22.6
0.072
3.03
0.073
V
0.082
0.049
7.83
22.1
0.074
2.719
0.080
W
0.083
0.048
7.66
22.0
0.0687
0.072
2.68
0.072
X
0.086
0.055
7.70
21.8
0.077
0.063
2.50
0.077
Y
0.08
0.04
8.69
24.57
0.06
3.12
0.07
Z
+
-
0.054
3-
Index
NO2
0.072
0.074
0.070
0.081
3.05
0.097
2.84
0.072
0.061
2.7
2.31
Silicon
4.47
0.0819
4.23
4.46
0.076
3.96
4.37
0.0754
4.39
0.0758
4.25
0.077
4.4
4.0
4.00
4.67
4.60
4.2
3.9
0.087
4.51
4.29
3.76
3.86
3.80
4.53
4.44
0.066
AA
0.084
0.047
7.63
0.070
AB
0.085
0.052
8.50
23.0
0.069
AC
0.079
0.058
7.62
22.1
0.076
AD
0.084
0.041
8
20
0.067
AE
0.085
0.052
8.47
22.1
0.071
AF
0.0830
0.0508
7.93
22.8
AG
0.0865
0.050
8.05
AH
0.083
0.047
7.74
0.077
2.74
0.076
2.84
0.088
3.88
2.76
0.067
4.1
0.074
2.70
0.077
0.0760
0.068
2.85
0.0790
22.3
0.070
0.069
2.57
0.071
4.16
24.82
0.075
0.084
2.9
0.086
3.9
0.072
4.37
4.51
4.3
-
+
NH4
±
Cl
±
SO4
±
2-
o-PO4
±
Boron
±
DOC
±
Unit
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Target value
0.001
0.001
0.02
0.3
0.001
0.001
0.04
0.001
0.08
0.11
IFA result
0.005
0.004
0.31
0.9
0.010
0.007
0.26
0.011
0.41
0.35
Stability test
0.005
0.004
0.66
0.9
0.010
0.007
0.26
0.012
0.40
0.36
A
0.003
0.01
2
B
0.01
-
3-
Index
±
±
NO2
±
Silicon
±
0.003
0.003
0.05
0.01
0.01
0.01
0.005
0.005
0.005
H
0.005
0.008
0.2
I
0.003
0.01
1
0.003
0.003
0.1
0.08
0.005
0.005
0.5
0.005
0.005
0.2
0.1
0.0009
0.0028
0.001
0.002
0.05
0.02
2
0.01
0.01
0.1
0.2
R
0.010
0.010
0.8
2.2
S
0.004
0.007
0.41
0.95
0.004
T
0.008
0.005
0.8
2.2
0.008
0.26
0.008
U
0.026
0.014
0.8
2.3
0.012
0.30
0.009
V
0.010
0.010
0.8
2.2
0.007
0.27
0.008
W
0.0005
0.0006
0.05
0.05
0.0005
0.001
0.07
0.001
X
0.013
0.008
1.2
3.3
0.012
0.009
0.38
0.012
Y
0.00
0.01
0.10
0.13
0.01
0.02
0.00
0.5
0.009
0.26
0.004
0.35
0.44
0.009
0.41
C
D
E
F
G
1
0.007
0.01
0.2
0.005
0.1
J
K
L
M
N
O
P
Q
Z
0
0.5
0.38
0.18
0.03
0.024
AA
AB
0.007
0.005
0.7
2
0.01
AC
0.007
0.005
0.69
2
0.007
AD
0.08
0.013
0.6
1.2
0.010
AE
0.009
0.008
0.51
1.2
0.007
0.008
0.25
0.008
AF
0.0009
0.0015
0.03
0.34
0.0020
0.002
0.01
0.0019
AG
0.0130
0.008
0.81
2.2
0.011
0.010
0.26
0.014
0.42
AH
0.0067
0.0047
0.31
1.489
0.009
0.0101
0.23
0.0130
0.0600
0.01
0.4
0.18
0.5
3-
total-P
3- KMnO4as PO4
Index
_1
NO2
NH4
Cl
SO4
o-PO4
_1
Boron
_1
DOC
Unit
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Target value
0.083
0.050
8.02
22.8
0.082
0.058
2.63
0.087
3.90
4.56
IFA result
0.083
0.051
7.77
23.1
0.085
0.059
2.62
0.092
4.10
4.39
Stability test
0.083
0.051
8.24
22.9
0.085
0.057
2.58
0.097
4.01
4.47
AI
0.088
0.056
8.1
22.9
0.087
0.059
2.86
0.108
3.91
4.64
2.7
0.095
3.85
6.4
-
+
-
2-
AJ
Silicon
0.060
AK
0.079
0.044
AL
0.09
<0.05
AM
0.10
0.05
12.2
AN
0.086
0.051
7.72
22.44
AO
0.089
0.059
7.9
23.9
AP
0.08
0.065
7.35
19
0.10
7.8
22.5
<0.1
6.6
21.5
<0.6
8.19
23.77
0.071
0.091
<5
23
0.06
0.12
3.6
0.0867
4.140
AQ
8.0
22.5
0.60
AR
0.086
AS
0.08
AT
0.080
0.056
AU
0.4812
0.080
AV
0.055
0.038
AW
0.09
0.07
AX
0.084
0.0524
8.1
22.0
AY
0.068
0.057
8.1
23.0
AZ
0.092
0.060
7.1
22.4
10.7991 23.1698
6.59
0.101
0.62
0.081
2.61
0.088
3.25
<0.2
58.7
<0.2
4.22
0.05
0
2.8
0.0575
4.701
<0.15
19.87
3.6
4.02
4.7503
3.9
0.10
0.078
<0.001
2.85
0.0898
3.766
4.5
3.85
4.23
2.73
0.057
2.65
BA
4.49
BB
0.0790
0.047
7.96
23.68
0.084
0.054
2.51
BC
0.08
0.06
8.1
24
0.07
2.7
0.10
BD
0.088
0.047
7.7
33
2.8
0.095
BE
0.11
<0.05
8.15
17.93
BF
0.085
0.058
7.3
22.1
2.74
0.11
BG
0.117
0.064
BH
0.090
0.056
8.15
22.5
0.082
BI
0.10
0.06
8.8
26.58
0.09
3.28
BJ
0.0854
0.0537
8.50
22.4
0.0889
3.08
<0.15
BL
0.081
0.053
8.31
23.3
0.094
2.75
0.097
BM
0.088
0.027
7.80
21.9
0.108
0.053
5.62
0.110
BN
0.084
0.062
8.28
23.1
0.061
2.65
0.076
7.63
23.21
0.086
3.52
4.80
3.9
4.2
0.061
0.085
0.059
0.091
4.2
4.53
0.104
0.060
0.083
3.81
5.14
BK
BO
BP
0,082
0,050
3.18
11.4
3-
Index
±
_1 ±
NO2
±
NH4
±
Cl
±
SO4
±
o-PO4
_1
±
Boron
_1
±
DOC
±
Unit
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Target value
0.001
0.001
0.02
0.3
0.002
0.001
0.04
0.002
0.08
0.11
IFA result
0.005
0.004
0.31
0.9
0.012
0.006
0.26
0.013
0.41
0.35
Stability test
0.005
0.004
0.66
0.9
0.012
0.006
0.26
0.014
0.40
0.36
AI
0.009
0.006
0.2
0.7
0.009
0.006
0.29
0.011
0.39
0.46
0.14
0.012
-
+
-
2-
AJ
Silicon
±
0.002
AK
AL
AM
AN
0.003
0.004
0.18
0.26
AO
0.007
0.01
0.1
0.2
0.003
0.29
AP
5.1
AQ
0.01
1.1
3.1
0.21
0.02
AR
0.010
1.3
4.3
0.9
AS
0.08
0.2
0.8
0.002
0
0.61
0.002
0.05
AT
AU
0.3958
0
0.0932
0.0141
AV
0.019
0.009
0.019
0.842
AX
0.004
0.003
0.5
1.2
AY
0.015
0.08
0.25
3.0
AZ
0.023
0.020
0.7
2.0
0.0695
0.2198
0.0475
0.1232
0.2686
0.07
0.005
0.17
0.03
AW
0.003
0.03
0.002
0.50
BA
0.43
BB
0.0056
0.007
0.95
2.33
0.012
0.011
0.18
0.54
BC
0.01
0.01
1
2
0.01
0.3
0.02
BD
0.002
0.003
0.2
2
0.002
0.2
0.005
BF
0.008
0.006
0.7
2
0.009
0.3
0.01
BG
0.049
0.005
BH
0.003
0.003
0.27
1.1
0.001
0.0085
0.0081
0.26
3.4
0.0044
0.62
0.038
0.004
0.003
0.50
1.4
0.007
0.11
0.007
0.0084
0.0062
0.746
2.08
0.159
0.0076
0.60
0.70
0.3
0.06
BE
0.006
0.010
0.4
0.4
0.009
0.002
0.002
0.82
BI
BJ
BK
BL
BM
BN
BO
BP
0.005
0.008
0.0085
1.3
Sample N131A
Parameter Conductivity
Target value ± U (k=2)
IFA result ± U (k=2)
Stability test
479 µS/cm ±
1 µS/cm
481 µS/cm ±
10 µS/cm
µS/cm
Lab Code
Result
±
Unit
Recovery
z-Score
A
486
3
µS/cm
101%
1,04
5
B
483
µS/cm
101%
0,60
C
471
µS/cm
98%
-1,19
D
490
µS/cm
102%
1,64
E
478
µS/cm
100%
-0,15
F
437
µS/cm
91%
-6,26
G
476
µS/cm
99%
-0,45
H
483
14
µS/cm
101%
0,60
I
480
5
µS/cm
100%
0,15
J
477
µS/cm
100%
-0,30
K
485
µS/cm
101%
0,89
L
479
µS/cm
100%
0,00
M
474
µS/cm
99%
-0,75
1,04
*
5
10
N
486
µS/cm
101%
O
487
µS/cm
102%
1,19
P
474
µS/cm
99%
-0,75
Q
480
µS/cm
100%
0,15
R
479
10
µS/cm
100%
0,00
S
484
10
µS/cm
101%
0,75
4,51
µS/cm
100%
0,30
25
µS/cm
104%
2,83
T
481
U
498
5
*
V
476
10
µS/cm
99%
-0,45
W
487
4,0
µS/cm
102%
1,19
X
484
14,5
µS/cm
101%
0,75
Y
459
µS/cm
96%
-2,98
*
Z
5%
24,0
Result
[µS/cm]
10%
47,9
15%
71,9
551
15%
527
10%
503
5%
479
Target
value ±
U (k=2)
455
- 5%
431
- 10%
407
- 15%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
AA AC AE AG AI AK AM AO AQ AS AU AW AY BA BC BE BG BI BK BM BO
AB AD AF AH AJ AL AN AP AR AT AV AX AZ BB BD BF BH BJ BL BN BP
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
µS/cm
AA
478
µS/cm
100%
-0,15
AB
478
20
µS/cm
100%
-0,15
AC
479
19
µS/cm
100%
0,00
AD
477
10
µS/cm
100%
-0,30
AE
477
14
µS/cm
100%
-0,30
AF
475
2,88
µS/cm
99%
-0,60
AG
481
7
µS/cm
100%
0,30
AH
481
18,9
µS/cm
100%
0,30
10
AI
483
µS/cm
101%
0,60
AJ
479
µS/cm
100%
0,00
AK
481
µS/cm
100%
0,30
AL
483
µS/cm
101%
0,60
AM
86
µS/cm
18%
-58,60
*
AN
482
11
µS/cm
101%
0,45
AO
462
3
µS/cm
96%
-2,54
AP
478,4
µS/cm
100%
-0,09
AQ
µS/cm
AR
474
AS
393
*
8,4
µS/cm
99%
-0,75
10
µS/cm
82%
-12,82
110
100
90
80
70
60
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
477
µS/cm
100%
-0,30
AU
490
µS/cm
102%
1,64
AV
481
µS/cm
100%
0,30
3
AW
µS/cm
AX
471
5
µS/cm
98%
-1,19
AY
471
30
µS/cm
98%
-1,19
AZ
457
*
10,0
µS/cm
95%
-3,28
BA
458
*
8,7
µS/cm
96%
-3,13
BB
483
10
µS/cm
101%
0,60
BC
479
3
µS/cm
100%
0,00
BD
430
2
µS/cm
90%
-7,31
BE
478
µS/cm
100%
-0,15
BF
481
12
µS/cm
100%
0,30
BG
490
2,0
µS/cm
102%
1,64
BH
479
µS/cm
100%
0,00
BI
477
µS/cm
100%
-0,30
BJ
475
µS/cm
99%
-0,60
µS/cm
99%
-0,52
µS/cm
99%
-0,75
µS/cm
100%
0,15
*
29
BK
µS/cm
BL
475,5
BM
474
BN
480
9,5
28,8
BO
BP
µS/cm
479
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
14
All results
470 ± 17
98,0 ± 3,6
51
10,9
63
µS/cm
100%
Outliers excl.
479 ± 2
100,1 ± 0,4
5
1,1
55
0,00
Unit
µS/cm
%
µS/cm
%
Sample N131B
Parameter Conductivity
Stability test
356 µS/cm ±
1 µS/cm
359 µS/cm ±
7 µS/cm
µS/cm
Lab Code
Result
±
Unit
Recovery
z-Score
A
361
3
µS/cm
101%
1,00
5
B
359
µS/cm
101%
0,60
C
348
µS/cm
98%
-1,61
D
360
µS/cm
101%
0,80
E
355
µS/cm
100%
-0,20
F
323
µS/cm
91%
-6,62
G
356
µS/cm
100%
0,00
H
360
11
µS/cm
101%
0,80
I
359
5
µS/cm
101%
0,60
J
355
µS/cm
100%
-0,20
K
355
µS/cm
100%
-0,20
L
356
µS/cm
100%
0,00
M
352
µS/cm
99%
-0,80
*
5
10
N
359
µS/cm
101%
0,60
O
358
µS/cm
101%
0,40
P
358
µS/cm
101%
0,40
Q
356
µS/cm
100%
0,00
R
357
10
µS/cm
100%
0,20
S
363
7
µS/cm
102%
1,40
5
T
360
4,51
µS/cm
101%
0,80
U
363
18
µS/cm
102%
1,40
V
350
10
µS/cm
98%
-1,20
W
353
2,6
µS/cm
99%
-0,60
X
362
10,9
µS/cm
102%
1,20
Y
344
µS/cm
97%
-2,41
Z
5%
17,8
Result
[µS/cm]
10%
35,6
15%
53,4
409
15%
392
10%
374
5%
356
Target
value ±
U (k=2)
338
- 5%
320
- 10%
303
- 15%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
µS/cm
AA
356
µS/cm
100%
0,00
AB
356
15
µS/cm
100%
0,00
AC
356
14
µS/cm
100%
0,00
AD
356
7
µS/cm
100%
0,00
AE
354
11
µS/cm
99%
-0,40
AF
352
0,36
µS/cm
99%
-0,80
AG
359
7
µS/cm
101%
0,60
AH
352
14,1
µS/cm
99%
-0,80
7
AI
364
µS/cm
102%
1,61
AJ
358
µS/cm
101%
0,40
AK
357
µS/cm
100%
0,20
AL
356
µS/cm
100%
0,00
AM
149
µS/cm
42%
-41,53
*
AN
359
4
µS/cm
101%
0,60
AO
346
2
µS/cm
97%
-2,01
AP
356,0
µS/cm
100%
0,00
AQ
µS/cm
AR
354
AS
293
*
6,3
µS/cm
99%
-0,40
10
µS/cm
82%
-12,64
110
100
90
80
70
60
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
355
µS/cm
100%
AU
362
µS/cm
102%
1,20
AV
353
5
µS/cm
99%
-0,60
AX
353
5
µS/cm
99%
-0,60
AY
350
30
µS/cm
98%
-1,20
AZ
339
*
10,0
µS/cm
95%
-3,41
BA
342
*
6,5
µS/cm
96%
-2,81
BB
360
7
µS/cm
101%
0,80
BC
356
3
µS/cm
100%
0,00
BD
321
2
µS/cm
90%
-7,02
BE
355
µS/cm
100%
-0,20
BF
355
9
µS/cm
100%
-0,20
BG
367
2,0
µS/cm
103%
2,21
BH
348
µS/cm
98%
-1,61
BI
359
µS/cm
101%
0,60
BJ
353
21
µS/cm
99%
-0,60
BL
357,8
7,2
BM
351
BN
350
AW
µS/cm
*
BK
µS/cm
21,0
BO
BP
-0,20
µS/cm
101%
0,36
µS/cm
99%
-1,00
µS/cm
98%
-1,20
µS/cm
357
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
11
All results
350 ± 9
98,4 ± 2,6
28
8,0
63
µS/cm
100%
Outliers excl.
356 ± 2
100,0 ± 0,4
4
1,3
57
0,20
Unit
µS/cm
%
µS/cm
%
Sample N131A
Parameter Total hardness
9,47 °d
±
0,07 °d
9,66 °d
±
0,58 °d
Stability test ± U (k=2)
9,74 °d
±
0,58 °d
Lab Code
Result
±
Unit
A
°d
B
°d
C
D
Result
[°d]
°d
101%
0,18
°d
98%
-0,81
°d
99%
-0,49
°d
99%
-0,25
°d
100%
0,11
°d
97%
-0,95
100%
0,07
°d
G
9,24
H
9,33
0,8
I
°d
J
9,4
K
9,5
L
9,2
0,1
M
°d
N
°d
O
°d
9,49
0,2
Q
°d
10,89
15%
10,42
10%
9,94
5%
9,47
Target
value ±
U (k=2)
9,00
- 5%
8,52
- 10%
8,05
- 15%
A
9,4
0,9
°d
99%
-0,25
S
9,11
0,91
°d
96%
-1,27
T
9,83
°d
104%
1,27
U
C
B
°d
R
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
°d
V
9,2
0,9
°d
97%
-0,95
W
9,36
0,03
°d
99%
-0,39
X
9,3
1,4
°d
98%
-0,60
Y
°d
Z
°d
AA
9,31
0,4
°d
98%
-0,56
AC
9,60
1,73
°d
101%
0,46
AD
9,6
1,0
°d
101%
0,46
AE
9,5
1,1
°d
100%
0,11
AF
9,31
0,159
°d
98%
-0,56
AG
9,37
0,94
°d
99%
-0,35
AH
9,4
°d
99%
-0,25
0,5
AI
9,3
°d
98%
-0,60
AJ
9,46
°d
100%
-0,04
AK
9,35
°d
99%
-0,42
AL
°d
AM
°d
9,67
0,02
°d
102%
0,70
9,2
0,1
°d
97%
-0,95
AP
9,5
°d
100%
0,11
99%
-0,25
°d
1,3
°d
°d
100
90
80
70
60
C
B
AN
9,4
120
A
AO
AQ
130
110
°d
AB
AS
15%
1,421
°d
F
AR
10%
0,947
z-Score
°d
9,52
E
P
Recovery
5%
0,474
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
9,2
°d
97%
-0,95
AU
9,664
°d
102%
0,68
AV
9,56
°d
101%
0,32
-0,25
0,03
AW
°d
AX
9,4
0,5
°d
99%
AY
9,5
0,2
°d
100%
0,11
AZ
9,4
°d
99%
-0,25
BA
°d
BB
9,09
°d
96%
-1,34
BC
9,3
1
°d
98%
-0,60
BD
9,60
0,6
°d
101%
0,46
BE
9,4
°d
99%
-0,25
BF
9,2
°d
97%
-0,95
0,9
BG
°d
BH
9,47
°d
100%
0,00
BI
9,6
°d
101%
0,46
°d
99%
-0,21
°d
96%
-1,41
°d
101%
0,35
Outliers excl.
9,40 ± 0,07
99,3 ± 0,7
0,17
1,8
43
Unit
°d
%
°d
%
BJ
°d
BK
°d
BL
9,41
BM
9,07
BN
9,57
0,19
0,718
BO
°d
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
°d
All results
9,40 ± 0,07
99,3 ± 0,7
0,17
1,8
43
Sample N131B
Parameter Total hardness
5,40 °d
±
0,05 °d
5,44 °d
±
0,33 °d
5,54 °d
±
0,33 °d
Lab Code
Result
±
Unit
A
°d
B
°d
C
D
Result
[°d]
°d
101%
0,19
°d
104%
1,23
°d
101%
0,37
°d
102%
0,62
°d
100%
0,00
°d
98%
-0,62
101%
0,19
°d
G
5,60
H
5,46
0,5
I
°d
J
5,5
K
5,4
L
5,3
0,1
M
°d
N
°d
O
°d
5,43
0,2
Q
°d
6,21
15%
5,94
10%
5,67
5%
5,40
Target
value ±
U (k=2)
5,13
- 5%
4,86
- 10%
4,59
- 15%
A
5,3
0,5
°d
98%
-0,62
S
5,13
0,51
°d
95%
-1,67
T
5,81
°d
108%
2,53
U
C
B
°d
R
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
°d
V
5,2
0,5
°d
96%
-1,23
W
5,37
0,006
°d
99%
-0,19
X
5,4
0,8
°d
100%
0,00
Y
°d
Z
°d
AA
5,31
0,3
°d
98%
-0,56
AC
5,42
0,98
°d
100%
0,12
AD
5,5
0,6
°d
102%
0,62
AE
5,5
0,7
°d
102%
0,62
AF
5,37
0,089
°d
99%
-0,19
AG
5,34
0,54
°d
99%
-0,37
AH
5,3
°d
98%
-0,62
0,3
AI
5,2
°d
96%
-1,23
AJ
5,43
°d
101%
0,19
AK
5,43
°d
101%
0,19
AL
°d
AM
°d
5,56
0,02
°d
103%
0,99
5,1
0,1
°d
94%
-1,85
AP
5,05
°d
94%
-2,16
100%
0,12
°d
0,73
°d
°d
100
90
80
70
60
C
B
AN
5,42
120
A
AO
AQ
130
110
°d
AB
AS
15%
0,810
°d
F
AR
10%
0,540
z-Score
°d
5,43
E
P
Recovery
5%
0,270
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
5,3
AU
7,598
AV
5,46
*
0,01
AW
°d
98%
-0,62
°d
141%
13,57
°d
101%
0,37
0,00
°d
AX
5,4
0,3
°d
100%
AY
5,4
0,2
°d
100%
0,00
AZ
5,3
°d
98%
-0,62
BA
°d
BB
5,12
°d
95%
-1,73
BC
5,3
0,5
°d
98%
-0,62
BD
5,53
0,6
°d
102%
0,80
BE
5,2
°d
96%
-1,23
BF
5,6
°d
104%
1,23
0,6
BG
°d
BH
5,48
°d
101%
0,49
BI
5,5
°d
102%
0,62
°d
100%
-0,12
°d
93%
-2,35
°d
103%
0,93
Outliers excl.
5,38 ± 0,07
99,6 ± 1,2
0,16
3,0
42
Unit
°d
%
°d
%
BJ
°d
BK
°d
BL
5,38
BM
5,02
BN
5,55
0,11
0,416
BO
°d
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
°d
All results
5,43 ± 0,15
100,5 ± 2,9
0,37
6,9
43
Sample N131A
Parameter Alkalinity
1,79 mmol/l ±
0,01 mmol/l
1,74 mmol/l ±
0,07 mmol/l
Stability test
mmol/l
Lab Code
Result
±
Unit
Recovery
z-Score
A
1,72
0,05
mmol/l
96%
-1,56
0,05
B
1,77
mmol/l
99%
-0,45
C
1,76
mmol/l
98%
-0,67
D
1,75
mmol/l
98%
-0,89
E
1,78
mmol/l
99%
-0,22
F
1,73
mmol/l
97%
-1,34
G
1,75
mmol/l
98%
-0,89
H
1,78
0,07
mmol/l
99%
-0,22
I
1,79
0,05
mmol/l
100%
0,00
J
1,61
mmol/l
90%
-4,02
mmol/l
99%
-0,45
mmol/l
99%
-0,45
mmol/l
99%
-0,45
mmol/l
94%
-2,46
mmol/l
97%
-1,12
mmol/l
98%
-0,67
K
1,77
L
1,77
0,1
*
0,05
M
N
1,77
1,68
P
1,74
Q
1,76
R
1,78
0,2
mmol/l
99%
-0,22
S
1,78
0,11
mmol/l
99%
-0,22
0,018
T
1,85
0,19
mmol/l
103%
1,34
0,1
U
15%
0,269
2,06
15%
1,97
10%
1,88
5%
1,79
Target
value ±
U (k=2)
1,70
- 5%
1,61
- 10%
1,52
- 15%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mmol/l
V
1,76
0,18
mmol/l
98%
-0,67
W
1,81
0,023
mmol/l
101%
0,45
X
1,8
0,18
mmol/l
101%
0,22
Y
1,75
mmol/l
98%
-0,89
Z
130
120
mmol/l
AA
1,79
mmol/l
100%
0,00
AB
1,77
0,1
mmol/l
99%
-0,45
AC
1,77
0,07
mmol/l
99%
-0,45
AD
1,75
0,12
mmol/l
98%
-0,89
AE
1,77
0,08
mmol/l
99%
-0,45
AF
1,79
0,005
mmol/l
100%
0,00
AG
1,79
AH
1,67
*
0,09
mmol/l
100%
0,00
0,183
mmol/l
93%
-2,68
0,09
AI
1,81
mmol/l
101%
0,45
AJ
1,81
mmol/l
101%
0,45
AK
1,82
mmol/l
102%
0,67
-0,89
AL
mmol/l
AM
1,75
mmol/l
98%
AN
1,95
*
0,08
mmol/l
109%
3,58
1,67
*
0,06
mmol/l
93%
-2,68
AP
1,84
mmol/l
103%
1,12
101%
0,22
AQ
mmol/l
1,8
0,079
mmol/l
mmol/l
110
100
90
80
70
60
A
0,09
AO
AS
Result
[mmol/l]
10%
0,179
mmol/l
O
AR
5%
0,090
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
0,87
AU
1,7966
AV
1,77
*
1,1129
AW
mmol/l
49%
mmol/l
100%
-20,56
0,15
mmol/l
99%
-0,45
mmol/l
AX
1,72
0,04
mmol/l
96%
-1,56
AY
1,78
0,02
mmol/l
99%
-0,22
AZ
1,775
0,120
mmol/l
99%
-0,34
BA
1,76
mmol/l
98%
-0,67
BB
1,77
mmol/l
99%
-0,45
BC
1,75
0,10
mmol/l
98%
-0,89
BD
1,83
0,1
mmol/l
102%
0,89
BE
1,86
mmol/l
104%
1,56
BF
1,76
mmol/l
98%
-0,67
mmol/l
99%
-0,22
mmol/l
105%
2,01
0,2
BG
mmol/l
BH
1,78
BI
1,88
BJ
1,78
0,036
mmol/l
99%
-0,22
BK
1,793
0,01
mmol/l
100%
0,07
BL
1,80
0,04
mmol/l
101%
0,22
BM
1,65
mmol/l
92%
-3,13
0,163
mmol/l
96%
-1,56
0,075
mmol/l
10%
-35,98
0,05
mmol/l
99%
BN
1,72
BO
0,18
BP
1,77
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
*
*
*
All results
1,73 ± 0,08
96,7 ± 4,6
0,24
13,9
60
Outliers excl.
1,78 ± 0,01
99,2 ± 0,7
0,03
1,9
52
-0,45
Unit
mmol/l
%
mmol/l
%
Sample N131B
Parameter Alkalinity
2,96 mmol/l ±
0,02 mmol/l
2,89 mmol/l ±
0,12 mmol/l
Stability test
mmol/l
Lab Code
Result
±
Unit
Recovery
z-Score
A
2,83
0,05
mmol/l
96%
-1,76
0,05
B
2,88
mmol/l
97%
-1,08
C
2,91
mmol/l
98%
-0,68
D
2,89
mmol/l
98%
-0,95
E
2,97
mmol/l
100%
0,14
F
2,85
mmol/l
96%
-1,49
G
2,90
mmol/l
98%
-0,81
H
2,92
0,12
mmol/l
99%
-0,54
I
2,95
0,05
mmol/l
100%
-0,14
J
2,77
mmol/l
94%
-2,57
mmol/l
98%
-0,81
mmol/l
99%
-0,54
mmol/l
96%
-1,49
mmol/l
99%
-0,54
mmol/l
91%
-3,78
mmol/l
98%
-0,95
mmol/l
99%
-0,27
K
2,90
L
2,92
M
2,85
0,1
*
0,05
N
2,92
O
2,68
0,029
P
2,89
Q
2,94
R
2,90
0,3
mmol/l
98%
-0,81
S
2,93
0,18
mmol/l
99%
-0,41
T
3,00
0,30
mmol/l
101%
0,54
*
0,1
U
V
2,91
0,29
mmol/l
98%
-0,68
2,99
0,006
mmol/l
101%
0,41
X
2,88
0,29
mmol/l
97%
-1,08
Y
2,92
mmol/l
99%
-0,54
Z
15%
0,444
3,40
15%
3,26
10%
3,11
5%
2,96
Target
value ±
U (k=2)
2,81
- 5%
2,66
- 10%
2,52
- 15%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
mmol/l
AA
2,96
mmol/l
100%
0,00
AB
2,79
0,1
mmol/l
94%
-2,30
AC
2,93
0,12
mmol/l
99%
-0,41
AD
2,92
0,2
mmol/l
99%
-0,54
AE
2,93
0,12
mmol/l
99%
-0,41
AF
2,93
0,005
mmol/l
99%
-0,41
AG
2,96
AH
2,78
*
0,15
mmol/l
100%
0,00
0,416
mmol/l
94%
-2,43
0,15
AI
2,97
mmol/l
100%
0,14
AJ
2,94
mmol/l
99%
-0,27
AK
2,96
mmol/l
100%
0,00
mmol/l
101%
0,27
0,08
mmol/l
105%
2,03
0,11
mmol/l
94%
-2,30
mmol/l
101%
0,27
101%
0,54
AL
mmol/l
AM
2,98
AN
3,11
AO
2,79
AP
2,98
*
AQ
AS
Result
[mmol/l]
10%
0,296
mmol/l
W
AR
5%
0,148
0,098
mmol/l
mmol/l
100
90
80
70
60
A
mmol/l
3
110
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
1,43
AU
2,9033
AV
2,92
*
0,0159
AW
mmol/l
48%
-20,68
mmol/l
98%
-0,77
mmol/l
99%
-0,54
mmol/l
AX
2,88
0,04
mmol/l
97%
-1,08
AY
2,93
0,02
mmol/l
99%
-0,41
AZ
2,927
0,200
mmol/l
99%
-0,45
BA
2,90
mmol/l
98%
-0,81
BB
2,92
mmol/l
99%
-0,54
BC
2,90
0,10
mmol/l
98%
-0,81
BD
2,91
0,1
mmol/l
98%
-0,68
BE
2,96
mmol/l
100%
0,00
BF
2,88
mmol/l
97%
-1,08
0,3
BG
mmol/l
BH
2,93
mmol/l
99%
-0,41
BI
2,92
mmol/l
99%
-0,54
BJ
2,94
0,059
mmol/l
99%
-0,27
BK
2,946
0,02
mmol/l
100%
-0,19
BL
2,96
0,06
mmol/l
100%
0,00
BM
2,63
mmol/l
89%
-4,46
0,272
mmol/l
97%
-1,35
0,075
mmol/l
10%
-35,95
0,09
mmol/l
99%
BN
2,86
BO
0,30
BP
2,93
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
*
*
All results
2,84 ± 0,13
96,0 ± 4,5
0,39
13,7
61
Outliers excl.
2,92 ± 0,02
98,6 ± 0,6
0,05
1,5
54
-0,41
Unit
mmol/l
%
mmol/l
%
Sample N131A
Parameter Hydrogen carbonate
Stability test
106 mg/l
±
1 mg/l
103 mg/l
±
4 mg/l
Result
[mg/l]
mg/l
Lab Code
Result
±
Unit
Recovery
z-Score
A
102
3
mg/l
96%
-1,26
98%
-0,72
B
mg/l
103,7
mg/l
E
mg/l
F
mg/l
G
mg/l
H
109
4
I
J
mg/l
98
mg/l
mg/l
mg/l
N
mg/l
O
0,94
92%
-2,52
102%
0,63
100%
0,09
mg/l
106,3
5
Q
mg/l
109
11
mg/l
103%
0,94
108
6,5
mg/l
102%
0,63
T
109,81
mg/l
104%
1,20
U
117
10%
111
5%
106
Target
value ±
U (k=2)
101
- 5%
95
- 10%
90
- 15%
A
C
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mg/l
V
104
11
mg/l
98%
-0,63
W
108
1,2
mg/l
102%
0,63
X
107
10,70
mg/l
101%
0,31
Y
106,75
mg/l
101%
0,24
Z
130
120
mg/l
AA
106
mg/l
100%
0,00
AB
105
4
mg/l
99%
-0,31
AC
105
4,2
mg/l
99%
-0,31
AD
104
8,3
mg/l
98%
-0,63
AE
105
5
mg/l
99%
-0,31
AF
106
0,32
mg/l
100%
0,00
AG
106
5
mg/l
100%
0,00
AH
102,1
15,32
mg/l
96%
-1,23
AI
107,4
5,4
mg/l
101%
0,44
101%
0,31
mg/l
98%
-0,63
5,2
mg/l
110%
3,18
4
mg/l
96%
-1,26
mg/l
106%
1,98
104%
1,19
AJ
110
100
90
80
70
mg/l
107
mg/l
AL
mg/l
AM
104
AN
116,1
AO
102
AP
112,3
*
AQ
AS
15%
B
S
AR
122
mg/l
R
AK
15%
15,9
mg/l
108
M
P
103%
mg/l
K
L
10%
10,6
mg/l
C
D
5%
5,3
A
mg/l
109,8
4,9
mg/l
mg/l
60
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
53
AU
109,6252
*
0,0064
AV
50%
-16,67
mg/l
103%
1,14
96%
-1,26
mg/l
AW
AX
mg/l
mg/l
102
3
AY
mg/l
mg/l
AZ
105
mg/l
99%
-0,31
BA
100
mg/l
94%
-1,89
BB
105,0
mg/l
99%
-0,31
BC
107
3
mg/l
101%
0,31
BD
112
6,1
mg/l
106%
1,89
BE
113,49
mg/l
107%
2,36
BF
104
mg/l
98%
-0,63
10
BG
mg/l
BH
106
mg/l
100%
0,00
BI
114,7
mg/l
108%
2,74
BJ
109
mg/l
103%
0,94
2,2
BK
mg/l
BL
106,4
BM
100
BN
102
2,2
9,7
BO
BP
mg/l
100%
0,13
mg/l
94%
-1,89
mg/l
96%
-1,26
mg/l
104,9
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
105 ± 4
99,2 ± 3,3
9
8,4
45
99%
Outliers excl.
106 ± 1
100,1 ± 1,4
4
3,4
43
-0,35
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Hydrogen carbonate
Stability test
177 mg/l
±
1 mg/l
173 mg/l
±
7 mg/l
Result
[mg/l]
mg/l
Lab Code
Result
±
Unit
Recovery
z-Score
A
170
3
mg/l
96%
-1,32
98%
-0,70
B
mg/l
173,3
mg/l
E
mg/l
F
mg/l
G
mg/l
H
178
7
I
J
mg/l
169
mg/l
mg/l
mg/l
N
mg/l
O
0,19
95%
-1,51
101%
0,19
100%
-0,09
mg/l
176,5
5
Q
mg/l
177
18
mg/l
100%
0,00
179
10,7
mg/l
101%
0,38
T
179,97
mg/l
102%
0,56
U
195
10%
186
5%
177
Target
value ±
U (k=2)
168
- 5%
159
- 10%
150
- 15%
A
C
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mg/l
V
178
W
197
X
173
Y
178,12
*
18
mg/l
101%
0,19
0,58
mg/l
111%
3,77
17,30
mg/l
98%
-0,75
mg/l
101%
0,21
Z
130
120
mg/l
AA
177
AB
167
AC
AD
AE
AF
mg/l
100%
0,00
6
mg/l
94%
-1,88
176
7,0
mg/l
99%
-0,19
175
14
mg/l
99%
-0,38
176
7
mg/l
99%
-0,19
175
0,32
mg/l
99%
-0,38
*
AG
178
9
mg/l
101%
0,19
AH
169,3
25,4
mg/l
96%
-1,45
AI
178,3
8,9
mg/l
101%
0,24
101%
0,38
mg/l
101%
0,38
2,6
mg/l
105%
1,83
7
mg/l
96%
-1,32
mg/l
103%
0,85
103%
1,15
AJ
110
100
90
80
70
mg/l
179
mg/l
AL
mg/l
AM
179
AN
186,7
AO
170
AP
181,5
*
AQ
AS
15%
B
S
AR
204
mg/l
R
AK
15%
26,6
mg/l
178
M
P
101%
mg/l
K
L
10%
17,7
mg/l
C
D
5%
8,9
A
mg/l
183,1
6,0
mg/l
mg/l
60
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
87
AU
177,1496
*
0,0159
AV
49%
-16,95
mg/l
100%
0,03
98%
-0,75
mg/l
AW
AX
mg/l
mg/l
173
3
AY
mg/l
mg/l
AZ
176
mg/l
99%
-0,19
BA
170
mg/l
96%
-1,32
BB
175,5
mg/l
99%
-0,28
BC
177
4
mg/l
100%
0,00
BD
177
6,1
mg/l
100%
0,00
BE
180,61
mg/l
102%
0,68
BF
173
mg/l
98%
-0,75
15
BG
mg/l
BH
176
mg/l
99%
-0,19
BI
178,2
mg/l
101%
0,23
BJ
179
mg/l
101%
0,38
3,6
BK
mg/l
BL
177,5
BM
160
BN
172
3,6
*
16,3
BO
BP
mg/l
100%
0,09
mg/l
90%
-3,20
mg/l
97%
-0,94
mg/l
175,7
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
174 ± 6
98,5 ± 3,3
14
8,3
45
99%
Outliers excl.
176 ± 1
99,5 ± 0,8
3
1,9
40
-0,24
Unit
mg/l
%
mg/l
%
Sample N131A
Parameter Calcium
37,5 mg/l
±
0,3 mg/l
38,0 mg/l
±
2,3 mg/l
38,2 mg/l
±
2,3 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
D
mg/l
mg/l
F
mg/l
G
mg/l
37
4
I
mg/l
102%
37,7
K
38,1
L
36,9
M
37,4
1
N
15%
5,63
43,1
15%
41,3
10%
39,4
5%
37,5
Target
value ±
U (k=2)
35,6
- 5%
33,8
- 10%
31,9
- 15%
0,46
99%
-0,38
mg/l
101%
0,15
mg/l
102%
0,46
mg/l
98%
-0,46
mg/l
100%
-0,08
102%
0,61
mg/l
O
mg/l
38,3
1
Q
mg/l
A
36,6
3,7
mg/l
98%
-0,69
S
35,1
3,6
mg/l
94%
-1,83
T
39,38
3,9
mg/l
105%
1,43
U
C
B
mg/l
R
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mg/l
V
36,1
3,6
mg/l
96%
-1,07
W
37,6
0,10
mg/l
100%
0,08
X
37,6
5,6
mg/l
100%
0,08
Y
37,10
0,37
mg/l
99%
-0,30
Z
130
120
mg/l
AA
110
mg/l
AB
37,1
3
mg/l
99%
-0,30
AC
37,5
6,8
mg/l
100%
0,00
AD
39
1,6
mg/l
104%
1,14
AE
37,7
3,4
mg/l
101%
0,15
AF
37,1
0,58
mg/l
99%
-0,30
AG
37,5
3,8
mg/l
100%
0,00
AH
37,03
1,481
mg/l
99%
-0,36
AI
36,6
1,8
mg/l
98%
-0,69
AJ
38,486
2,287
mg/l
103%
0,75
AK
37,5
mg/l
100%
0,00
AL
mg/l
AM
mg/l
38,36
0,34
mg/l
102%
0,66
36,6
0,1
mg/l
98%
-0,69
AP
36,9
2,1
mg/l
98%
-0,46
AQ
39,3
4,7
mg/l
105%
1,37
97%
-0,91
mg/l
36,3
0,1
mg/l
90
80
70
60
C
B
AN
AR
100
A
AO
AS
10%
3,75
z-Score
mg/l
J
P
Result
[mg/l]
mg/l
38,1
E
H
Recovery
5%
1,88
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
35
mg/l
93%
-1,90
AU
38,2966
0,0052
mg/l
102%
0,61
AV
37,80
0,357
mg/l
101%
0,23
-0,61
AW
mg/l
AX
36,7
1,9
mg/l
98%
AY
38,0
0,6
mg/l
101%
0,38
AZ
36,1
2,0
mg/l
96%
-1,07
BB
34,93
3,48
mg/l
93%
-1,96
BC
37
1
mg/l
99%
-0,38
BD
36,9
1,7
mg/l
98%
-0,46
BE
37,58
mg/l
100%
0,06
BF
37,7
mg/l
101%
0,15
mg/l
101%
0,30
mg/l
103%
1,00
mg/l
98%
-0,69
mg/l
98%
-0,53
2,31
mg/l
103%
0,76
1,39
mg/l
110%
2,73
Outliers excl.
37,3 ± 0,4
99,6 ± 1,1
1,0
2,7
45
Unit
mg/l
%
mg/l
%
BA
mg/l
4
BG
mg/l
BH
37,9
BI
38,81
0,3
BJ
mg/l
BK
mg/l
BL
36,6
BM
36,8
BN
38,5
BO
41,08
0,7
*
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
37,4 ± 0,5
99,8 ± 1,2
1,1
3,1
46
Sample N131B
Parameter Calcium
27,5 mg/l
±
0,3 mg/l
27,7 mg/l
±
1,7 mg/l
28,1 mg/l
±
1,7 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
D
mg/l
mg/l
F
mg/l
G
mg/l
28
3
I
mg/l
101%
27,5
K
27,7
L
26,9
1
0,52
mg/l
100%
0,00
mg/l
101%
0,21
mg/l
98%
-0,62
102%
0,52
mg/l
N
mg/l
O
mg/l
28,0
1
Q
mg/l
15%
30,3
10%
28,9
5%
27,5
Target
value ±
U (k=2)
26,1
- 5%
24,8
- 10%
23,4
- 15%
A
C
B
R
26,7
2,7
mg/l
97%
-0,83
S
26,0
2,7
mg/l
95%
-1,56
T
29,81
3,0
mg/l
108%
2,40
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mg/l
V
26,5
2,7
mg/l
96%
-1,04
W
27,6
0,06
mg/l
100%
0,10
4,2
mg/l
103%
0,83
5,02
mg/l
120%
5,65
99%
-0,31
X
28,3
Y
32,94
*
Z
130
120
mg/l
AA
110
mg/l
AB
27,2
3
mg/l
AC
27,3
4,9
mg/l
99%
-0,21
AD
28
1,1
mg/l
102%
0,52
AE
28,4
2,6
mg/l
103%
0,94
AF
27,4
0,60
mg/l
100%
-0,10
AG
27,3
2,7
mg/l
99%
-0,21
AH
27,1
1,084
mg/l
99%
-0,42
AI
26,4
1,3
mg/l
96%
-1,14
AJ
28,285
2,344
mg/l
103%
0,82
AK
27,3
mg/l
99%
-0,21
AL
mg/l
AM
mg/l
28,28
0,10
mg/l
103%
0,81
26,1
0,1
mg/l
95%
-1,45
AP
26,7
1,5
mg/l
97%
-0,83
AQ
28,6
3,4
mg/l
104%
1,14
101%
0,37
mg/l
27,86
0,1
mg/l
90
80
70
60
C
B
AN
AR
100
A
AO
AS
31,6
mg/l
U
15%
4,13
0,31
102%
M
10%
2,75
z-Score
mg/l
J
P
Result
[mg/l]
mg/l
27,8
E
H
Recovery
5%
1,38
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
25
mg/l
91%
-2,60
AU
28,0852
0,0067
mg/l
102%
0,61
AV
27,75
0,357
mg/l
101%
0,26
0,73
AW
mg/l
AX
28,2
1,5
mg/l
103%
AY
27,6
0,6
mg/l
100%
0,10
AZ
26,9
2,0
mg/l
98%
-0,62
BB
25,42
2,55
mg/l
92%
-2,16
BC
27
1
mg/l
98%
-0,52
BD
27,0
1,7
mg/l
98%
-0,52
BE
28,18
mg/l
102%
0,71
BF
28,7
mg/l
104%
1,25
mg/l
103%
0,83
mg/l
104%
1,04
mg/l
99%
-0,21
mg/l
95%
-1,45
BA
mg/l
3
BG
mg/l
BH
28,3
BI
28,50
0,3
BJ
mg/l
BK
mg/l
BL
27,3
0,5
BM
26,1
BN
28,5
1,71
mg/l
104%
1,04
BO
25,05
1,39
mg/l
91%
-2,55
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
27,5 ± 0,5
100,2 ± 1,9
1,3
4,7
45
Outliers excl.
27,4 ± 0,4
99,7 ± 1,5
1,0
3,7
44
Unit
mg/l
%
mg/l
%
Sample N131A
Parameter Magnesium
18,3 mg/l
±
0,2 mg/l
18,8 mg/l
±
1,1 mg/l
19,0 mg/l
±
1,1 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
D
mg/l
mg/l
F
mg/l
G
mg/l
18
1
I
mg/l
98%
17,9
K
18,0
L
17,7
M
17,0
1
*
N
15%
2,75
21,0
15%
20,1
10%
19,2
5%
18,3
Target
value ±
U (k=2)
17,4
- 5%
16,5
- 10%
15,6
- 15%
-0,46
98%
-0,46
mg/l
98%
-0,61
mg/l
98%
-0,46
mg/l
97%
-0,91
mg/l
93%
-1,97
98%
-0,46
mg/l
O
mg/l
18,0
0,5
Q
mg/l
A
18,5
1,9
mg/l
101%
0,30
S
18,3
1,9
mg/l
100%
0,00
T
18,77
1,9
mg/l
103%
0,71
U
C
B
mg/l
R
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mg/l
V
18,2
1,8
mg/l
99%
-0,15
W
18,3
0,06
mg/l
100%
0,00
X
17,5
2,6
mg/l
96%
-1,21
Y
18,03
0,23
mg/l
99%
-0,41
-0,61
Z
130
120
mg/l
AA
110
mg/l
AB
17,9
AC
18,8
AD
18
AE
AF
2,2
mg/l
98%
3,4
mg/l
103%
0,76
1,1
mg/l
98%
-0,46
18,2
1,7
mg/l
99%
-0,15
17,9
0,59
mg/l
98%
-0,61
*
AG
17,8
1,8
mg/l
97%
-0,76
AH
18,23
1,094
mg/l
100%
-0,11
AI
18,2
0,9
mg/l
99%
-0,15
AJ
17,586
2,431
mg/l
96%
-1,08
AK
17,9
mg/l
98%
-0,61
AL
mg/l
AM
mg/l
18,64
0,10
mg/l
102%
0,52
17,9
0,1
mg/l
98%
-0,61
AP
18,0
1,4
mg/l
98%
-0,46
AQ
17,7
2,1
mg/l
97%
-0,91
99%
-0,35
mg/l
18,07
0,15
mg/l
90
80
70
60
C
B
AN
AR
100
A
AO
AS
10%
1,83
z-Score
mg/l
J
P
Result
[mg/l]
mg/l
18,0
E
H
Recovery
5%
0,92
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
19
mg/l
104%
AU
18,7027
0,0455
mg/l
102%
0,61
AV
18,18
0,916
mg/l
99%
-0,18
AX
18,4
1,0
mg/l
101%
0,15
AY
18,2
0,6
mg/l
99%
-0,15
AZ
19,0
2,0
mg/l
104%
1,06
*
AW
1,06
mg/l
*
BA
mg/l
BB
18,22
1,45
mg/l
100%
-0,12
BC
18
1
mg/l
98%
-0,46
BD
17,9
0,8
mg/l
98%
-0,61
BE
18,21
mg/l
100%
-0,14
BF
17,5
mg/l
96%
-1,21
2
BG
mg/l
BH
18,4
BI
18,18
0,3
BJ
mg/l
101%
0,15
mg/l
99%
-0,18
mg/l
BK
mg/l
BL
18,7
BM
17,0
BN
18,2
BO
15,68
0,4
mg/l
102%
0,61
mg/l
93%
-1,97
2,19
mg/l
99%
-0,15
0,43
mg/l
86%
-3,98
*
*
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
18,1 ± 0,2
98,7 ± 1,2
0,6
3,1
46
Outliers excl.
18,1 ± 0,1
98,9 ± 0,7
0,3
1,7
40
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Magnesium
6,73 mg/l
±
0,08 mg/l
6,76 mg/l
±
0,41 mg/l
6,91 mg/l
±
0,41 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
D
mg/l
mg/l
F
mg/l
G
mg/l
6,7
0,4
I
mg/l
98%
7,2
K
6,8
L
6,8
0,5
-0,12
mg/l
107%
1,94
mg/l
101%
0,29
mg/l
101%
0,29
98%
-0,54
mg/l
N
mg/l
O
mg/l
6,6
0,5
Q
mg/l
15%
7,40
10%
7,07
5%
6,73
Target
value ±
U (k=2)
6,39
- 5%
6,06
- 10%
5,72
- 15%
A
C
B
R
6,76
0,68
mg/l
100%
0,12
S
6,53
0,67
mg/l
97%
-0,83
T
7,11
0,7
mg/l
106%
1,57
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mg/l
V
6,69
0,70
mg/l
99%
-0,17
W
6,77
0,01
mg/l
101%
0,17
X
6,3
0,9
mg/l
94%
-1,77
Y
6,19
0,05
mg/l
92%
-2,23
Z
130
120
mg/l
AA
110
mg/l
AB
6,57
0,8
mg/l
98%
-0,66
AC
6,91
1,2
mg/l
103%
0,74
AD
7
0,4
mg/l
104%
1,11
AE
6,72
0,65
mg/l
100%
-0,04
AF
6,66
0,138
mg/l
99%
-0,29
AG
6,58
0,66
mg/l
98%
-0,62
AH
6,58
0,395
mg/l
98%
-0,62
AI
6,60
0,33
mg/l
98%
-0,54
AJ
6,630
0,230
mg/l
99%
-0,41
AK
7,1
mg/l
105%
1,53
AL
mg/l
AM
mg/l
6,94
0,12
mg/l
103%
0,87
6,5
0,1
mg/l
97%
-0,95
AP
7,15
0,23
mg/l
106%
1,73
AQ
6,7
0,8
mg/l
100%
-0,12
6,64
0,15
99%
-0,37
mg/l
mg/l
90
80
70
60
C
B
AN
AR
100
A
AO
AS
7,74
mg/l
U
15%
1,010
-0,45
100%
M
10%
0,673
z-Score
mg/l
J
P
Result
[mg/l]
mg/l
6,62
E
H
Recovery
5%
0,337
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
7,1
mg/l
105%
AU
6,9757
0,0832
mg/l
104%
1,01
AV
6,70
0,916
mg/l
100%
-0,12
AX
6,5
0,4
mg/l
97%
-0,95
AY
6,6
0,6
mg/l
98%
-0,54
AZ
6,5
1,0
mg/l
97%
-0,95
AW
1,53
mg/l
BA
mg/l
BB
6,76
0,55
mg/l
100%
0,12
BC
6,6
1
mg/l
98%
-0,54
BD
6,7
0,8
mg/l
100%
-0,12
BE
6,83
mg/l
101%
0,41
BF
6,76
mg/l
100%
0,12
0,7
BG
mg/l
BH
6,84
BI
6,52
0,25
BJ
mg/l
102%
0,45
mg/l
97%
-0,87
mg/l
BK
mg/l
BL
6,8
BM
5,96
BN
6,83
BO
9,12
0,2
mg/l
101%
0,29
mg/l
89%
-3,18
0,819
mg/l
101%
0,41
0,43
mg/l
136%
9,86
Outliers excl.
6,73 ± 0,09
100,0 ± 1,3
0,22
3,2
43
Unit
mg/l
%
mg/l
%
*
*
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
6,77 ± 0,17
100,5 ± 2,6
0,43
6,4
45
Sample N131A
Parameter Sodium
26,8 mg/l
±
0,2 mg/l
27,3 mg/l
±
1,6 mg/l
27,5 mg/l
±
1,7 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
D
Result
[mg/l]
mg/l
mg/l
F
mg/l
G
mg/l
27
2
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
mg/l
101%
101%
30,8
15%
29,5
10%
28,1
5%
26,8
Target
value ±
U (k=2)
25,5
- 5%
24,1
- 10%
22,8
- 15%
0,21
A
C
B
26,4
2,6
mg/l
99%
-0,41
S
27,1
2,8
mg/l
101%
0,31
T
26,57
2,7
mg/l
99%
-0,24
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mg/l
V
26,0
2,6
mg/l
97%
-0,83
W
26,6
0,12
mg/l
99%
-0,21
X
26,3
3,9
mg/l
98%
-0,52
Y
26,06
0,04
mg/l
97%
-0,77
Z
130
120
mg/l
AA
110
mg/l
AB
26,4
4
mg/l
99%
-0,41
AC
26,8
4,8
mg/l
100%
0,00
AD
27
1,1
mg/l
101%
0,21
AE
26,9
2,2
mg/l
100%
0,10
AF
26,7
0,27
mg/l
100%
-0,10
AG
25,6
2,6
mg/l
96%
-1,24
AH
26,78
1,607
mg/l
100%
-0,02
1,4
mg/l
103%
0,83
2,793
mg/l
93%
-2,08
mg/l
100%
0,10
AI
27,6
AJ
24,798
AK
26,9
*
AL
mg/l
AM
mg/l
AN
26,83
AO
30
*
mg/l
100%
0,03
0,2
mg/l
112%
3,32
AP
27,1
1,5
mg/l
101%
0,31
27,0
2,7
mg/l
101%
0,21
100%
0,00
mg/l
26,8
0,1
mg/l
90
80
70
60
C
B
1,00
AR
100
A
AQ
AS
15%
4,02
0,21
R
U
10%
2,68
z-Score
mg/l
27,0
E
H
Recovery
5%
1,34
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
mg/l
AU
27,8707
0,0450
mg/l
104%
1,11
AV
26,55
0,204
mg/l
99%
-0,26
AX
26,1
1,4
mg/l
97%
-0,73
AY
26,8
0,2
mg/l
100%
0,00
AZ
26,6
2,0
mg/l
99%
-0,21
BB
26,46
2,37
mg/l
99%
-0,35
BC
26
2
mg/l
97%
-0,83
BD
26,0
0,8
mg/l
97%
-0,83
BE
26,38
mg/l
98%
-0,44
BF
26,7
mg/l
100%
-0,10
mg/l
98%
-0,62
mg/l
101%
0,33
mg/l
93%
-1,97
mg/l
101%
0,31
Outliers excl.
26,7 ± 0,2
99,5 ± 0,8
0,5
1,8
35
Unit
mg/l
%
mg/l
%
AW
mg/l
BA
mg/l
3
BG
mg/l
BH
26,2
BI
27,12
0,2
BJ
mg/l
BK
mg/l
BL
mg/l
BM
24,9
BN
27,1
*
1,76
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
26,7 ± 0,4
99,5 ± 1,4
0,8
3,1
38
Sample N131B
Parameter Sodium
36,8 mg/l
±
0,3 mg/l
37,4 mg/l
±
2,2 mg/l
37,7 mg/l
±
2,3 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
D
Result
[mg/l]
mg/l
mg/l
F
mg/l
G
mg/l
36
2
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
mg/l
99%
98%
42,3
15%
40,5
10%
38,6
5%
36,8
Target
value ±
U (k=2)
35,0
- 5%
33,1
- 10%
31,3
- 15%
-0,60
A
C
B
36,1
3,6
mg/l
98%
-0,53
S
37,9
3,9
mg/l
103%
0,83
T
36,32
3,6
mg/l
99%
-0,36
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mg/l
V
35,6
3,6
mg/l
97%
-0,91
W
36,3
0,30
mg/l
99%
-0,38
X
34,4
5,2
mg/l
93%
-1,81
Y
35,44
0,22
mg/l
96%
-1,03
Z
130
120
mg/l
AA
110
mg/l
AB
36,1
6
mg/l
98%
-0,53
AC
36,7
6,6
mg/l
100%
-0,08
AD
37
1,5
mg/l
101%
0,15
AE
37,0
3,0
mg/l
101%
0,15
AF
36,2
0,27
mg/l
98%
-0,45
AG
34,7
3,5
mg/l
94%
-1,59
AH
38,2
2,292
mg/l
104%
1,06
AI
37,3
1,9
mg/l
101%
0,38
AJ
34,591
2,727
mg/l
94%
-1,67
AK
36,9
mg/l
100%
0,08
AL
mg/l
AM
mg/l
AN
36,56
AO
41
*
mg/l
99%
-0,18
0,2
mg/l
111%
3,17
AP
37,4
0,93
mg/l
102%
0,45
37,6
3,8
mg/l
102%
0,60
103%
0,96
mg/l
38,07
0,1
mg/l
90
80
70
60
C
B
1,38
AR
100
A
AQ
AS
15%
5,52
-0,38
R
U
10%
3,68
z-Score
mg/l
36,3
E
H
Recovery
5%
1,84
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
mg/l
AU
38,205
0,0472
mg/l
104%
1,06
AV
36,36
0,109
mg/l
99%
-0,33
AX
36,3
1,9
mg/l
99%
-0,38
AY
36,6
0,2
mg/l
99%
-0,15
AZ
36,5
2,0
mg/l
99%
-0,23
AW
mg/l
BA
mg/l
BB
35,26
3,19
mg/l
96%
-1,16
BC
36
2
mg/l
98%
-0,60
BD
35,5
0,8
mg/l
96%
-0,98
BE
37,30
mg/l
101%
0,38
BF
36,8
mg/l
100%
0,00
mg/l
94%
-1,59
mg/l
102%
0,43
mg/l
88%
-3,40
mg/l
100%
0,00
Outliers excl.
36,5 ± 0,5
99,1 ± 1,2
1,0
2,8
36
Unit
mg/l
%
mg/l
%
4
BG
mg/l
BH
34,7
BI
37,37
0,2
BJ
mg/l
BK
mg/l
BL
mg/l
BM
32,3
BN
36,8
*
2,39
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
36,5 ± 0,6
99,1 ± 1,7
1,4
3,9
38
Sample N131A
Parameter Potassium
2,52 mg/l
±
0,03 mg/l
2,58 mg/l
±
0,21 mg/l
2,66 mg/l
±
0,21 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
D
Result
[mg/l]
mg/l
mg/l
F
mg/l
G
mg/l
2,5
0,2
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
mg/l
92%
99%
2,90
15%
2,77
10%
2,65
5%
2,52
Target
value ±
U (k=2)
2,39
- 5%
2,27
- 10%
2,14
- 15%
-0,16
A
C
B
2,42
0,24
mg/l
96%
-0,81
S
2,38
0,28
mg/l
94%
-1,13
T
2,54
0,27
mg/l
101%
0,16
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mg/l
V
2,36
0,24
mg/l
94%
-1,30
W
2,47
0,03
mg/l
98%
-0,40
X
2,51
0,4
mg/l
100%
-0,08
Y
2,36
0,06
mg/l
94%
-1,30
Z
130
120
mg/l
AA
110
mg/l
AB
2,48
AC
2,39
AD
2
*
0,4
mg/l
98%
-0,32
0,43
mg/l
95%
-1,05
0,2
mg/l
79%
-4,21
AE
2,42
0,20
mg/l
96%
-0,81
AF
2,63
0,060
mg/l
104%
0,89
AG
2,71
0,27
mg/l
108%
1,54
AH
2,71
0,271
mg/l
108%
1,54
AI
2,7
0,1
mg/l
107%
1,46
AJ
2,543
0,270
mg/l
101%
0,19
AK
2,5
mg/l
99%
-0,16
AL
mg/l
AM
mg/l
2,56
0,10
mg/l
102%
0,32
2,5
0,02
mg/l
99%
-0,16
AP
2,77
0,15
mg/l
110%
2,02
AQ
2,5
0,3
mg/l
99%
-0,16
120%
4,05
mg/l
3,02
*
0,05
mg/l
90
80
70
60
C
B
AN
AR
100
A
AO
AS
15%
0,378
-1,70
R
U
10%
0,252
z-Score
mg/l
2,31
E
H
Recovery
5%
0,126
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
mg/l
AU
7,3105
AV
2,47
*
0,0078
mg/l
290%
38,80
0,053
mg/l
98%
-0,40
AW
mg/l
AX
2,60
0,18
mg/l
103%
0,65
AY
2,5
0,06
mg/l
99%
-0,16
AZ
2,8
0,3
mg/l
111%
2,27
1,05
BA
mg/l
BB
2,65
0,24
mg/l
105%
BC
2,6
0,5
mg/l
103%
0,65
BD
2,33
0,3
mg/l
92%
-1,54
BE
2,71
mg/l
108%
1,54
BF
2,52
mg/l
100%
0,00
mg/l
100%
0,08
mg/l
102%
0,40
0,3
BG
mg/l
BH
2,53
BI
2,57
0,08
BJ
mg/l
BK
mg/l
BL
mg/l
BM
2,68
BN
2,51
0,251
BO
106%
1,30
mg/l
100%
-0,08
Outliers excl.
2,54 ± 0,06
100,6 ± 2,3
0,13
5,0
35
Unit
mg/l
%
mg/l
%
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
mg/l
All results
2,66 ± 0,35
105,5 ± 13,9
0,79
29,8
38
Sample N131B
Parameter Potassium
7,55 mg/l
±
0,04 mg/l
7,65 mg/l
±
0,61 mg/l
7,87 mg/l
±
0,63 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
D
Result
[mg/l]
mg/l
mg/l
F
mg/l
G
mg/l
7,5
0,5
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
mg/l
102%
99%
8,68
15%
8,31
10%
7,93
5%
7,55
Target
value ±
U (k=2)
7,17
- 5%
6,80
- 10%
6,42
- 15%
-0,14
A
C
B
7,20
0,72
mg/l
95%
-0,95
S
7,43
0,88
mg/l
98%
-0,32
T
7,82
0,81
mg/l
104%
0,73
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
mg/l
V
7,12
0,72
mg/l
94%
-1,16
W
7,29
0,04
mg/l
97%
-0,70
1,2
mg/l
108%
1,62
0,22
mg/l
469%
75,39
X
8,15
Y
35,44
*
Z
130
120
mg/l
AA
110
mg/l
AB
7,55
1,2
mg/l
100%
0,00
AC
7,22
1,30
mg/l
96%
-0,89
AD
7
0,6
mg/l
93%
-1,49
AE
7,50
0,52
mg/l
99%
-0,14
AF
7,63
0,257
mg/l
101%
0,22
AG
7,76
0,78
mg/l
103%
0,57
AH
7,51
0,751
mg/l
99%
-0,11
AI
7,9
0,4
mg/l
105%
0,95
AJ
7,440
0,270
mg/l
99%
-0,30
AK
7,6
mg/l
101%
0,14
AL
mg/l
AM
mg/l
7,45
0,34
mg/l
99%
-0,27
7,6
0,06
mg/l
101%
0,14
AP
7,74
0,24
mg/l
103%
0,51
AQ
7,5
0,9
mg/l
99%
-0,14
7,36
0,05
97%
-0,51
mg/l
mg/l
90
80
70
60
C
B
AN
AR
100
A
AO
AS
15%
1,133
0,41
R
U
10%
0,755
z-Score
mg/l
7,70
E
H
Recovery
5%
0,378
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
mg/l
AU
2,3947
AV
7,46
*
0,0608
mg/l
32%
-13,94
0,053
mg/l
99%
-0,24
0,95
AW
mg/l
AX
7,9
0,4
mg/l
105%
AY
7,6
0,06
mg/l
101%
0,14
AZ
7,2
0,7
mg/l
95%
-0,95
BB
7,58
0,69
mg/l
100%
0,08
BC
7,5
1
mg/l
99%
-0,14
BD
6,95
0,3
mg/l
92%
-1,62
BE
8,53
mg/l
113%
2,65
BF
7,81
mg/l
103%
0,70
mg/l
98%
-0,41
mg/l
102%
0,35
mg/l
86%
-2,87
mg/l
101%
0,16
Outliers excl.
7,52 ± 0,12
99,6 ± 1,6
0,26
3,5
34
Unit
mg/l
%
mg/l
%
BA
mg/l
*
0,8
BG
mg/l
BH
7,40
BI
7,68
0,08
BJ
mg/l
BK
mg/l
BL
mg/l
BM
6,49
BN
7,61
*
0,761
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
8,12 ± 2,05
107,5 ± 27,1
4,64
57,1
38
Sample N131A
Parameter Nitrate
50,5 mg/l
±
1,0 mg/l
49,2 mg/l
±
2,0 mg/l
Lab Code
Result
[mg/l]
mg/l
Stability test
Result
±
A
Unit
Recovery
46,3
mg/l
92%
-2,38
D
47,2
mg/l
93%
-1,87
mg/l
98%
-0,54
E
58,1
15%
55,6
10%
53,0
5%
50,5
Target
value ±
U (k=2)
48,0
- 5%
45,5
- 10%
42,9
- 15%
mg/l
F
mg/l
49,55
H
49
2
mg/l
97%
-0,85
I
50,0
0,8
mg/l
99%
-0,28
J
49,1
mg/l
97%
-0,79
K
46,4
mg/l
92%
-2,32
mg/l
93%
-1,98
mg/l
99%
-0,28
mg/l
93%
-1,98
mg/l
98%
-0,68
L
mg/l
M
47
N
50,0
0,502
O
mg/l
P
47
Q
49,3
R
49,2
4,9
mg/l
97%
-0,74
S
48,2
2,2
mg/l
95%
-1,30
2
T
46,88
3,9
mg/l
93%
-2,05
U
48,7
4,9
mg/l
96%
-1,02
V
49,13
4,9
mg/l
97%
-0,78
W
48,1
0,30
mg/l
95%
-1,36
6,8
mg/l
90%
-3,00
0,07
mg/l
108%
2,16
X
45,2
Y
54,31
*
Z
>35
mg/l
AA
49,6
mg/l
•
98%
-0,51
AB
50,9
4
mg/l
101%
0,23
AC
48,6
4,4
mg/l
96%
-1,07
AD
49
3,4
mg/l
97%
-0,85
AE
49,8
4,5
mg/l
99%
-0,40
AF
48,9
0,57
mg/l
97%
-0,91
AG
49,5
5,0
mg/l
98%
-0,57
AH
48,823
1,9529
mg/l
97%
-0,95
AI
49,7
1,5
mg/l
98%
-0,45
98%
-0,68
95%
-1,30
AJ
AK
15%
7,58
mg/l
C
G
10%
5,05
z-Score
mg/l
B
5%
2,53
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
110
100
90
80
70
mg/l
49,3
mg/l
AL
mg/l
AM
48,2
1,1
mg/l
A
AN
49,35
0,62
mg/l
98%
-0,65
AO
51,2
0,4
mg/l
101%
0,40
AP
50,2
AQ
47,6
AR
44,1
AS
65,97
60
mg/l
99%
-0,17
9,0
mg/l
94%
-1,64
*
8,8
mg/l
87%
-3,62
*
0,15
mg/l
131%
8,75
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
AU
AV
52,8
40,2026 *
42,30
*
mg/l
105%
1,30
0,0250
mg/l
80%
-5,83
0,451
mg/l
84%
-4,64
-0,85
AW
mg/l
AX
49
2
mg/l
97%
AY
50,5
0,5
mg/l
100%
0,00
AZ
49,6
3,0
mg/l
98%
-0,51
BB
50,65
4,54
mg/l
100%
0,08
BC
50
2
mg/l
99%
-0,28
0,4
mg/l
97%
-0,85
mg/l
80%
-5,75
BA
mg/l
BD
49,0
BE
40,33
BF
49,6
5
mg/l
98%
-0,51
BG
49,8
3,03
mg/l
99%
-0,40
BH
52,9
0,8
mg/l
105%
1,36
BI
50,25
mg/l
100%
-0,14
BJ
48,4
mg/l
96%
-1,19
*
3,9
BK
mg/l
BL
51,4
BM
49,2
3,1
mg/l
102%
0,51
mg/l
97%
-0,74
BN
52,9
5,55
mg/l
105%
1,36
BO
46,47
0,40
mg/l
92%
-2,28
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
49,0 ± 1,3
97,1 ± 2,5
3,5
7,2
55
Outliers excl.
49,2 ± 0,6
97,4 ± 1,2
1,6
3,3
49
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Nitrate
4,87 mg/l
±
0,11 mg/l
4,62 mg/l
±
0,18 mg/l
Stability test
Lab Code
Result
[mg/l]
mg/l
Result
±
A
Unit
Recovery
15%
0,731
5,60
15%
5,36
10%
5,11
5%
4,87
Target
value ±
U (k=2)
4,63
- 5%
4,38
- 10%
4,14
- 15%
mg/l
C
4,20
mg/l
86%
-3,93
D
4,56
mg/l
94%
-1,82
mg/l
98%
-0,65
E
mg/l
F
mg/l
G
4,76
H
4,7
0,1
mg/l
97%
-1,00
I
4,7
0,1
mg/l
97%
-1,00
J
3,8
mg/l
78%
-6,28
K
4,82
mg/l
99%
-0,29
mg/l
90%
-2,76
mg/l
100%
-0,12
mg/l
92%
-2,17
mg/l
98%
-0,70
*
L
mg/l
M
4,4
N
4,85
0,049
O
mg/l
P
4,5
Q
4,75
2
R
4,7
0,5
mg/l
97%
-1,00
S
4,73
0,21
mg/l
97%
-0,82
T
4,94
0,4
mg/l
101%
0,41
U
4,75
0,48
mg/l
98%
-0,70
V
4,72
W
3,90
*
0,5
mg/l
97%
-0,88
0,06
mg/l
80%
-5,69
X
4,2
0,6
mg/l
86%
-3,93
Y
4,47
0,07
mg/l
92%
-2,35
0,15
mg/l
78%
-6,22
mg/l
97%
-1,00
Z
3,81
AA
4,70
AB
4,79
0,3
mg/l
98%
-0,47
AC
4,87
0,44
mg/l
100%
0,00
AD
5
0,2
mg/l
103%
0,76
AE
4,65
0,42
mg/l
95%
-1,29
AF
4,72
0,09
mg/l
97%
-0,88
*
AG
4,93
0,49
mg/l
101%
0,35
AH
4,626
0,185
mg/l
95%
-1,43
AI
4,6
0,1
mg/l
94%
-1,58
99%
-0,41
125%
7,10
AJ
AK
10%
0,487
z-Score
mg/l
B
5%
0,244
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
110
100
90
80
70
mg/l
4,8
mg/l
AL
mg/l
AM
6,08
mg/l
*
A
AN
4,71
0,18
mg/l
97%
-0,94
AO
4,9
0,1
mg/l
101%
0,18
AP
5,05
AQ
4,6
AR
3,45
AS
5,09
*
60
mg/l
104%
1,06
0,9
mg/l
94%
-1,58
0,89
mg/l
71%
-8,33
0,15
mg/l
105%
1,29
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
5,3
AU
6,2260
mg/l
109%
0,0119
mg/l
128%
AV
7,96
4,39
0,340
mg/l
90%
-2,82
AX
4,8
0,3
mg/l
99%
-0,41
AY
4,8
0,5
mg/l
99%
-0,41
AZ
4,5
0,5
mg/l
92%
-2,17
*
AW
2,52
mg/l
BA
mg/l
BB
4,90
0,43
mg/l
101%
0,18
BC
4,8
0,8
mg/l
99%
-0,41
BD
4,8
0,4
mg/l
99%
-0,41
BE
4,4
mg/l
90%
-2,76
BF
4,6
0,5
mg/l
94%
-1,58
BG
5,21
0,317
mg/l
107%
1,99
BH
4,66
0,17
mg/l
96%
-1,23
BI
4,95
mg/l
102%
0,47
BJ
4,71
0,38
mg/l
97%
-0,94
BL
4,93
0,30
BM
4,34
BN
4,88
BO
4,85
BK
mg/l
mg/l
101%
0,35
mg/l
89%
-3,11
0,513
mg/l
100%
0,06
0,40
mg/l
100%
-0,12
Outliers excl.
4,73 ± 0,09
97,2 ± 1,8
0,23
4,8
50
Unit
mg/l
%
mg/l
%
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
4,71 ± 0,16
96,8 ± 3,2
0,44
9,3
56
Sample N131A
Parameter Nitrite
0,040 mg/l
±
0,001 mg/l
0,040 mg/l
±
0,002 mg/l
0,040 mg/l
±
0,002 mg/l
Result
[mg/l]
Lab Code
Result
±
Unit
Recovery
z-Score
A
0,039
0,003
mg/l
98%
-0,44
0,01
mg/l
103%
0,44
mg/l
100%
0,04
mg/l
113%
2,19
mg/l
101%
0,13
mg/l
103%
0,44
mg/l
100%
0,04
B
0,041
C
0,0401
D
0,045
E
0,0403
F
0,041
G
0,0401
H
0,042
0,003
mg/l
105%
0,88
I
0,039
0,002
mg/l
98%
-0,44
J
0,043
mg/l
108%
1,32
K
0,038
mg/l
95%
-0,88
L
0,042
mg/l
105%
0,88
M
0,041
mg/l
103%
0,44
mg/l
103%
0,44
mg/l
98%
-0,44
mg/l
103%
0,44
mg/l
100%
0,00
*
0,005
0,005
0,0004
N
0,041
O
0,039
P
0,041
Q
0,040
R
0,040
0,010
mg/l
100%
0,00
S
0,041
0,002
mg/l
103%
0,44
T
0,040
0,004
mg/l
100%
0,00
U
0,048
0,013
mg/l
120%
3,51
0,05
*
V
0,039
0,010
mg/l
98%
-0,44
W
0,040
0,0006
mg/l
100%
0,00
X
0,04
0,006
mg/l
100%
0,00
Y
0,04
0,00
mg/l
100%
0,00
Z
15%
0,0060
30%
0,0120
45%
0,0180
0,058
45%
0,052
30%
0,046
15%
0,040
Target
value ±
U (k=2)
0,034
- 15%
0,028
- 30%
0,022
- 45%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
mg/l
AA
0,041
mg/l
103%
0,44
AB
0,041
0,004
mg/l
103%
0,44
AC
0,039
0,004
mg/l
98%
-0,44
AD
0,041
0,004
mg/l
103%
0,44
AE
0,039
0,005
mg/l
98%
-0,44
AF
0,0394
0,0009
mg/l
99%
-0,26
AG
0,0411
0,0062
mg/l
103%
0,48
AH
0,041
0,003
mg/l
103%
0,44
AI
0,039
0,004
mg/l
98%
-0,44
AJ
110
100
FN
90
80
70
mg/l
AK
0,039
mg/l
98%
-0,44
AL
0,04
mg/l
100%
0,00
AM
0,05
mg/l
125%
4,39
1,32
*
AN
0,043
mg/l
108%
AO
<0,01
0,003
mg/l
FN
AP
0,04
mg/l
100%
0,00
AQ
mg/l
AR
0,043
0,0077
mg/l
108%
1,32
AS
0,04
0,08
mg/l
100%
0,00
60
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
0,038
AU
0,4745
*
mg/l
95%
-0,88
0,6170
mg/l
1186%
190,57
0,025
mg/l
108%
1,32
mg/l
100%
0,00
0,002
mg/l
100%
0,00
AV
0,043
AW
0,04
AX
0,04
AY
0,035
*
0,015
mg/l
88%
-2,19
AZ
0,050
*
0,012
mg/l
125%
4,39
BA
mg/l
BB
0,0394
0,0027
mg/l
99%
-0,26
BC
0,04
0,01
mg/l
100%
0,00
BD
0,043
0,002
mg/l
108%
1,32
BE
0,042
mg/l
105%
0,88
BF
0,041
0,004
mg/l
103%
0,44
BG
0,073
0,031
mg/l
183%
14,47
BH
0,043
0,003
mg/l
108%
1,32
BI
0,05
mg/l
125%
4,39
BJ
0,0419
mg/l
105%
0,83
mg/l
98%
-0,44
mg/l
110%
1,75
mg/l
100%
0,00
*
*
0,0042
BK
mg/l
BL
0,039
BM
0,044
BN
0,040
0,002
0,0040
BO
BP
mg/l
0,040
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
0,003
All results
0,049 ± 0,019
121,9 ± 47,4
0,056
114,1
61
mg/l
100%
Outliers excl.
0,041 ± 0,001
101,3 ± 1,3
0,001
3,4
53
0,00
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Nitrite
0,083 mg/l
±
0,001 mg/l
0,083 mg/l
±
0,005 mg/l
0,083 mg/l
±
0,005 mg/l
Result
[mg/l]
Lab Code
Result
±
Unit
Recovery
z-Score
A
0,083
0,003
mg/l
100%
0,00
0,01
B
0,083
mg/l
100%
0,00
C
0,0811
mg/l
98%
-0,40
D
0,088
mg/l
106%
1,06
E
0,0836
mg/l
101%
0,13
F
0,086
mg/l
104%
0,63
G
0,0803
mg/l
97%
-0,57
H
0,089
0,005
mg/l
107%
1,27
I
0,082
0,003
mg/l
99%
-0,21
J
0,085
mg/l
102%
0,42
K
0,078
mg/l
94%
-1,06
L
0,086
mg/l
104%
0,63
M
0,082
mg/l
99%
-0,21
mg/l
102%
0,42
mg/l
99%
-0,21
mg/l
101%
0,21
mg/l
99%
-0,21
0,005
0,005
0,0009
N
0,085
O
0,082
P
0,084
Q
0,082
R
0,084
0,010
mg/l
101%
0,21
S
0,084
0,004
mg/l
101%
0,21
0,05
T
0,083
0,008
mg/l
100%
0,00
U
0,092
0,026
mg/l
111%
1,90
V
0,082
0,010
mg/l
99%
-0,21
W
0,083
0,0005
mg/l
100%
0,00
X
0,086
0,013
mg/l
104%
0,63
Y
0,08
0,00
mg/l
96%
-0,63
Z
15%
0,0125
30%
0,0249
45%
0,0374
0,120
45%
0,108
30%
0,095
15%
0,083
Target
value ±
U (k=2)
0,071
- 15%
0,058
- 30%
0,046
- 45%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
mg/l
AA
0,084
mg/l
101%
0,21
AB
0,085
0,007
mg/l
102%
0,42
AC
0,079
0,007
mg/l
95%
-0,85
AD
0,084
0,08
mg/l
101%
0,21
AE
0,085
0,009
mg/l
102%
0,42
AF
0,0830
0,0009
mg/l
100%
0,00
AG
0,0865
0,0130
mg/l
104%
0,74
AH
0,083
0,0067
mg/l
100%
0,00
AI
0,088
0,009
mg/l
106%
1,06
AJ
110
100
90
80
70
mg/l
AK
0,079
mg/l
95%
-0,85
AL
0,09
mg/l
108%
1,48
AM
0,10
mg/l
120%
3,59
*
AN
0,086
0,003
mg/l
104%
0,63
AO
0,089
0,007
mg/l
107%
1,27
AP
0,08
mg/l
96%
-0,63
AQ
mg/l
AR
0,086
0,010
mg/l
104%
0,63
AS
0,08
0,08
mg/l
96%
-0,63
60
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
0,080
mg/l
96%
-0,63
AU
0,4812
*
0,3958
mg/l
580%
84,17
*
0,019
mg/l
66%
-5,92
mg/l
108%
1,48
0,004
mg/l
101%
0,21
0,015
mg/l
82%
-3,17
0,023
mg/l
111%
1,90
AV
0,055
AW
0,09
AX
0,084
AY
0,068
AZ
0,092
*
BA
mg/l
BB
0,0790
0,0056
mg/l
95%
-0,85
BC
0,08
0,01
mg/l
96%
-0,63
BD
0,088
0,002
mg/l
106%
1,06
BE
0,11
mg/l
133%
5,71
BF
0,085
0,008
mg/l
102%
0,42
BG
0,117
0,049
mg/l
141%
7,19
BH
0,090
0,003
mg/l
108%
1,48
BI
0,10
mg/l
120%
3,59
BJ
0,0854
mg/l
103%
0,51
mg/l
98%
-0,42
mg/l
106%
1,06
mg/l
101%
0,21
*
*
*
0,0085
BK
mg/l
BL
0,081
BM
0,088
BN
0,084
0,004
0,0084
BO
BP
mg/l
0,082
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
0,005
All results
0,091 ± 0,017
110,0 ± 20,7
0,051
55,8
62
mg/l
99%
Outliers excl.
0,084 ± 0,001
101,4 ± 1,5
0,003
4,1
55
-0,21
Unit
mg/l
%
mg/l
%
Sample N131A
Parameter Ammonium
15%
Target value
<0,01 mg/l
IFA result
<0,01 mg/l
Stability test
<0,01 mg/l
45%
Result
±
Unit
Recovery
A
<0,02
0,01
mg/l
•
0,01
B
<0,025
mg/l
•
C
<0,03
mg/l
•
D
<0,020
mg/l
•
E
<0,03
mg/l
•
F
<0,01
mg/l
•
G
<0,026
mg/l
•
H
<0,030
0,004
mg/l
•
I
<0,03
0,01
mg/l
•
J
0,002
mg/l
•
K
<0,01
mg/l
•
L
<0,02
mg/l
•
M
<0,03
mg/l
•
N
<0,03
mg/l
•
O
<0,02
mg/l
•
P
<0,02
mg/l
•
Q
0,010
mg/l
•
R
<0,010
mg/l
•
S
<0,025
mg/l
•
0,02
0,007
T
<0,009
mg/l
•
U
<0,012
mg/l
•
V
<0,010
mg/l
•
W
<0,010
mg/l
•
X
0,009
0,001
mg/l
•
Y
0,01
0,00
mg/l
•
Z
<0,01
mg/l
•
AA
<0,005
mg/l
•
AB
<0,013
mg/l
•
AC
<0,01
mg/l
•
<0,006
AD
<0,02
mg/l
•
AE
<0,008
mg/l
•
AF
<0,0064
mg/l
•
AG
<0,010
mg/l
•
AH
0,005
mg/l
•
AI
<0,03
mg/l
•
0,0005
AJ
z-Score
30%
15%
0,01
Target
value
- 15%
- 30%
- 45%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
110
FP
FP
FP
FP
100
90
80
70
mg/l
AK
<0,01
mg/l
•
AL
<0,05
mg/l
•
AM
<0,01
mg/l
•
mg/l
•
mg/l
•
AN
<0,01
AO
0,012
AP
<0,013
AQ
0,03
AR
<0,1
AS
45%
Result
[mg/l]
Lab Code
0,005
30%
0,03
0,005
0,004
mg/l
•
mg/l
FP
mg/l
•
mg/l
60
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
0,01
AU
0,0125
0,0461
mg/l
mg/l
•
AV
0,1889
0,004
mg/l
FP
AW
<0,05
mg/l
•
AX
<0,04
mg/l
•
AY
<0,03
mg/l
•
AZ
<0,050
mg/l
•
0,08
BA
•
mg/l
BB
<0,02
mg/l
•
BC
<0,02
mg/l
•
BD
<0,005
mg/l
•
BE
<0,05
mg/l
•
BF
<0,01
mg/l
•
BG
0,024
0,002
mg/l
FP
BH
0,011
0,003
mg/l
•
BI
<0,02
mg/l
•
BJ
<0,013
mg/l
•
0,003
0,0019
BK
mg/l
BL
<0,02
mg/l
•
BM
0,016
mg/l
FP
BN
<0,04
mg/l
•
BO
BP
mg/l
<0,020
mg/l
All results
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
•
Outliers excl.
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Ammonium
0,050 mg/l
±
0,001 mg/l
0,051 mg/l
±
0,004 mg/l
0,051 mg/l
±
0,004 mg/l
Result
[mg/l]
Lab Code
Result
±
Unit
Recovery
z-Score
A
0,05
0,01
mg/l
100%
0,00
0,01
B
0,054
mg/l
108%
0,62
C
0,043
mg/l
86%
-1,08
D
0,051
mg/l
102%
0,15
E
0,049
mg/l
98%
-0,15
F
0,054
mg/l
108%
0,62
G
0,062
mg/l
124%
1,85
H
0,062
0,008
mg/l
124%
1,85
I
0,06
0,01
mg/l
120%
1,54
J
0,054
mg/l
108%
0,62
K
0,055
mg/l
110%
0,77
L
0,048
mg/l
96%
-0,31
M
0,05
mg/l
100%
0,00
mg/l
88%
-0,92
mg/l
120%
1,54
mg/l
100%
0,00
mg/l
112%
0,92
-0,31
N
0,044
O
0,060
P
0,05
Q
0,056
0,005
0,005
0,0028
0,02
R
0,048
0,010
mg/l
96%
S
<0,025
0,007
mg/l
FN
T
0,055
0,005
mg/l
110%
0,77
U
0,059
0,014
mg/l
118%
1,38
V
0,049
0,010
mg/l
98%
-0,15
W
0,048
0,0006
mg/l
96%
-0,31
X
0,055
0,008
mg/l
110%
0,77
Y
0,04
0,01
mg/l
80%
-1,54
0
mg/l
108%
0,62
mg/l
94%
-0,46
0,31
Z
0,054
AA
0,047
AB
0,052
0,005
mg/l
104%
AC
0,058
0,005
mg/l
116%
1,23
AD
0,041
0,013
mg/l
82%
-1,38
AE
0,052
0,008
mg/l
104%
0,31
AF
0,0508
0,0015
mg/l
102%
0,12
AG
0,050
0,008
mg/l
100%
0,00
AH
0,047
0,0047
mg/l
94%
-0,46
AI
0,056
0,006
mg/l
112%
0,92
-0,92
AJ
30%
0,0150
45%
0,0225
0,073
45%
0,065
30%
0,058
15%
0,050
Target
value ±
U (k=2)
0,043
- 15%
0,035
- 30%
0,028
- 45%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
U
S
R
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
110
100
FN
90
80
70
mg/l
AK
0,044
mg/l
88%
AL
<0,05
mg/l
•
AM
0,05
mg/l
100%
0,00
AN
0,051
0,004
mg/l
102%
0,15
0,059
0,01
mg/l
118%
1,38
mg/l
130%
2,31
mg/l
200%
7,69
mg/l
•
AP
0,065
AQ
0,10
AR
<0,1
*
0,01
mg/l
60
A
AO
AS
15%
0,0075
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
U
S
R
T
W
V
Y
X
Z
Laboratories
AT
0,056
AU
0,080
AV
0,038
*
mg/l
112%
0
mg/l
160%
0,92
4,62
0,009
mg/l
76%
-1,85
AW
0,07
mg/l
140%
3,08
AX
0,0524
0,003
mg/l
105%
0,37
AY
0,057
0,08
mg/l
114%
1,08
AZ
0,060
0,020
mg/l
120%
1,54
-0,46
BA
mg/l
BB
0,047
0,007
mg/l
94%
BC
0,06
0,01
mg/l
120%
1,54
BD
0,047
0,003
mg/l
94%
-0,46
BE
<0,05
mg/l
•
BF
0,058
0,006
mg/l
116%
1,23
BG
0,064
0,005
mg/l
128%
2,15
BH
0,056
0,003
mg/l
112%
0,92
BI
0,06
mg/l
120%
1,54
BJ
0,0537
mg/l
107%
0,57
0,0081
BK
mg/l
BL
0,053
BM
0,027
BN
0,062
0,003
*
0,0062
BO
BP
mg/l
106%
0,46
mg/l
54%
-3,54
mg/l
124%
1,85
mg/l
0,050
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
0,008
All results
0,054 ± 0,003
107,9 ± 7,0
0,010
18,7
59
mg/l
100%
Outliers excl.
0,053 ± 0,002
106,3 ± 4,7
0,007
12,3
56
0,00
Unit
mg/l
%
mg/l
%
Sample N131A
Parameter Chloride
42,1 mg/l
±
0,5 mg/l
41,8 mg/l
±
1,7 mg/l
43,0 mg/l
±
1,7 mg/l
Result
[mg/l]
Lab Code
Result
±
Unit
Recovery
z-Score
A
41,9
2
mg/l
100%
-0,15
B
43,4
mg/l
103%
0,96
D
42,5
mg/l
101%
0,30
mg/l
100%
-0,01
E
15%
6,32
48,4
15%
46,3
10%
44,2
5%
42,1
Target
value ±
U (k=2)
40,0
- 5%
37,9
- 10%
35,8
- 15%
mg/l
F
mg/l
42,08
H
42
1
mg/l
100%
-0,07
I
42,4
3
mg/l
101%
0,22
J
43,8
mg/l
104%
1,26
mg/l
100%
-0,07
mg/l
98%
-0,67
mg/l
100%
-0,15
mg/l
98%
-0,74
K
42
L
41,2
1
M
mg/l
N
mg/l
O
mg/l
P
41,9
Q
41,1
R
41,1
4,1
mg/l
98%
-0,74
S
41,9
2,2
mg/l
100%
-0,15
2
T
39,71
4,0
mg/l
94%
-1,77
U
41,0
4,1
mg/l
97%
-0,82
V
40,92
4,1
mg/l
97%
-0,88
W
42,0
0,16
mg/l
100%
-0,07
X
38,9
5,8
mg/l
92%
-2,38
Y
41,15
0,03
mg/l
98%
-0,71
Z
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
mg/l
AA
41,5
mg/l
99%
-0,45
AB
42,6
4
mg/l
101%
0,37
AC
41,0
3,7
mg/l
97%
-0,82
AD
41
3,3
mg/l
97%
-0,82
AE
42,0
2,1
mg/l
100%
-0,07
AF
41,9
0,15
mg/l
100%
-0,15
AG
41,1
4,1
mg/l
98%
-0,74
AH
39,93
2,396
mg/l
95%
-1,61
AI
42,1
1,3
mg/l
100%
0,00
99%
-0,22
136%
11,28
AJ
AK
10%
4,21
mg/l
C
G
5%
2,11
110
100
90
80
70
mg/l
41,8
mg/l
AL
mg/l
AM
57,3
AN
AO
A
0,2
mg/l
39,40
0,46
mg/l
94%
-2,00
44,3
0,3
mg/l
105%
1,63
*
60
AP
42
mg/l
100%
-0,07
AQ
40,5
5,7
mg/l
96%
-1,19
AR
41,2
8,1
mg/l
98%
-0,67
AS
39,49
0,2
mg/l
94%
-1,94
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
AU
AV
45
35,9927 *
36,45
*
mg/l
107%
2,15
0,0392
mg/l
85%
-4,53
4,38
mg/l
87%
-4,19
-1,56
AW
mg/l
AX
40
2
mg/l
95%
AY
42,6
0,25
mg/l
101%
0,37
AZ
41,6
2,0
mg/l
99%
-0,37
BB
42,21
5,04
mg/l
100%
0,08
BC
41
2
mg/l
97%
-0,82
BD
40,7
0,2
mg/l
97%
-1,04
BE
42,29
mg/l
100%
0,14
BF
43,1
mg/l
102%
0,74
mg/l
102%
0,59
mg/l
103%
1,08
mg/l
102%
0,59
BA
mg/l
4
BG
mg/l
BH
42,9
BI
43,55
BJ
42,9
0,4
1,3
BK
mg/l
BL
42,8
BM
41,5
2,6
mg/l
102%
0,52
mg/l
99%
-0,45
BN
44,1
3,97
mg/l
105%
1,48
BO
42,53
0,60
mg/l
101%
0,32
Outliers excl.
41,8 ± 0,5
99,3 ± 1,1
1,3
3,0
51
Unit
mg/l
%
mg/l
%
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
41,9 ± 1,0
99,5 ± 2,3
2,7
6,4
54
Sample N131B
Parameter Chloride
8,02 mg/l
±
0,02 mg/l
7,77 mg/l
±
0,31 mg/l
8,24 mg/l
±
0,66 mg/l
Result
[mg/l]
Lab Code
Result
±
Unit
Recovery
z-Score
A
7,8
2
mg/l
97%
-0,86
B
10%
0,802
15%
1,203
9,22
15%
8,82
10%
8,42
5%
8,02
Target
value ±
U (k=2)
7,62
- 5%
7,22
- 10%
6,82
- 15%
mg/l
C
9,1
D
7,8
*
E
mg/l
113%
4,21
mg/l
97%
-0,86
mg/l
107%
2,18
mg/l
F
mg/l
G
8,58
H
8,0
0,2
mg/l
100%
-0,08
I
7,9
1
mg/l
99%
-0,47
J
9,6
mg/l
120%
6,16
mg/l
100%
-0,08
mg/l
102%
0,70
mg/l
100%
-0,08
mg/l
99%
-0,47
mg/l
104%
1,21
K
8,0
L
8,2
M
8
*
0,5
N
mg/l
O
mg/l
P
7,9
Q
8,33
2
R
7,8
0,8
mg/l
97%
-0,86
S
7,78
0,41
mg/l
97%
-0,94
T
7,63
0,8
mg/l
95%
-1,52
U
7,9
0,8
mg/l
99%
-0,47
V
7,83
0,8
mg/l
98%
-0,74
W
7,66
0,05
mg/l
96%
-1,40
X
7,70
1,2
mg/l
96%
-1,25
Y
8,69
0,10
mg/l
108%
2,61
Z
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
mg/l
AA
7,63
mg/l
95%
-1,52
AB
8,50
0,7
mg/l
106%
1,87
AC
7,62
0,69
mg/l
95%
-1,56
AD
8
0,6
mg/l
100%
-0,08
AE
8,47
0,51
mg/l
106%
1,75
AF
7,93
0,03
mg/l
99%
-0,35
AG
8,05
0,81
mg/l
100%
0,12
AH
7,74
0,31
mg/l
97%
-1,09
AI
8,1
0,2
mg/l
101%
0,31
100%
-0,08
mg/l
152%
16,29
AJ
AK
5%
0,401
110
100
FN
90
80
70
mg/l
8,0
mg/l
AL
mg/l
AM
12,2
*
A
AN
7,72
0,18
mg/l
96%
-1,17
AO
7,9
0,1
mg/l
99%
-0,47
AP
7,35
AQ
7,8
AR
6,6
AS
8,19
*
60
mg/l
92%
-2,61
1,1
mg/l
97%
-0,86
1,3
mg/l
82%
-5,53
0,2
mg/l
102%
0,66
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
AU
AV
<5
10,7991 *
6,59
*
mg/l
FN
0,0932
mg/l
135%
10,83
0,019
mg/l
82%
-5,57
0,31
AW
mg/l
AX
8,1
0,5
mg/l
101%
AY
8,1
0,25
mg/l
101%
0,31
AZ
7,1
0,7
mg/l
89%
-3,58
BB
7,96
0,95
mg/l
99%
-0,23
BC
8,1
1
mg/l
101%
0,31
BD
7,7
0,2
mg/l
96%
-1,25
BE
8,15
mg/l
102%
0,51
BF
7,3
0,7
mg/l
91%
-2,81
BH
8,15
0,27
mg/l
102%
0,51
BI
8,8
mg/l
110%
3,04
BJ
8,50
mg/l
106%
1,87
BA
mg/l
BG
mg/l
0,26
BK
mg/l
BL
8,31
BM
7,80
BN
8,28
BO
7,63
0,50
mg/l
104%
1,13
mg/l
97%
-0,86
0,746
mg/l
103%
1,01
0,60
mg/l
95%
-1,52
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
8,10 ± 0,31
101,0 ± 3,9
0,85
10,5
54
Outliers excl.
7,97 ± 0,13
99,4 ± 1,7
0,35
4,3
48
Unit
mg/l
%
mg/l
%
Sample N131A
Parameter Sulphate
39,4 mg/l
±
0,5 mg/l
39,8 mg/l
±
1,6 mg/l
39,7 mg/l
±
1,6 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
mg/l
D
mg/l
E
mg/l
F
Recovery
Result
[mg/l]
39,33
H
39
2
mg/l
100%
-0,06
mg/l
99%
-0,32
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
38,3
R
38,8
S
38,5
97%
-0,87
3,9
mg/l
98%
-0,48
1,7
mg/l
98%
-0,71
T
37,15
3,7
mg/l
94%
-1,78
U
39,3
3,9
mg/l
100%
-0,08
V
38,8
3,9
mg/l
98%
-0,48
W
38,7
0,04
mg/l
98%
-0,56
X
36,60
5,5
mg/l
93%
-2,22
Y
41,47
0,04
mg/l
105%
1,64
15%
43,3
10%
41,4
5%
39,4
Target
value ±
U (k=2)
37,4
- 5%
35,5
- 10%
33,5
- 15%
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
mg/l
AA
110
mg/l
AB
39,3
3
mg/l
100%
-0,08
AC
38,3
3,4
mg/l
97%
-0,87
AD
37
2,2
mg/l
94%
-1,90
AE
38,8
2,0
mg/l
98%
-0,48
AF
39,3
0,33
mg/l
100%
-0,08
AG
38,9
3,9
mg/l
99%
-0,40
AH
37,03
1,481
mg/l
94%
-1,88
AI
39,7
1,2
mg/l
101%
0,24
99%
-0,32
AJ
AK
15%
5,91
45,3
A
mg/l
Z
10%
3,94
z-Score
mg/l
G
5%
1,97
100
90
80
70
mg/l
39,0
mg/l
AL
mg/l
AM
mg/l
60
A
C
B
AN
38,72
0,44
mg/l
98%
-0,54
AO
41,1
0,4
mg/l
104%
1,35
AP
39,5
mg/l
100%
0,08
AQ
38,0
5,3
mg/l
96%
-1,11
AR
38,3
7,7
mg/l
97%
-0,87
AS
40,65
0,8
mg/l
103%
0,99
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
AU
AV
40
34,1436 *
35,61
*
mg/l
102%
0,48
0,0213
mg/l
87%
-4,17
0,842
mg/l
90%
-3,01
-0,32
AW
mg/l
AX
39
2
mg/l
99%
AY
39,8
3,0
mg/l
101%
0,32
AZ
39,0
2,0
mg/l
99%
-0,32
BB
40,57
4,04
mg/l
103%
0,93
BC
40
3
mg/l
102%
0,48
BD
37
2
mg/l
94%
-1,90
BE
32,72
mg/l
83%
-5,30
BF
38,9
mg/l
99%
-0,40
mg/l
102%
0,56
mg/l
108%
2,43
mg/l
97%
-0,79
mg/l
102%
0,63
mg/l
100%
0,00
BA
mg/l
*
4
BG
mg/l
BH
40,1
BI
42,46
1,1
BJ
38,4
5,8
BL
40,2
2,4
BM
39,4
BN
40,6
3,65
mg/l
103%
0,95
BO
39,07
0,70
mg/l
99%
-0,26
*
BK
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
38,8 ± 0,7
98,4 ± 1,8
1,8
4,5
44
Outliers excl.
39,0 ± 0,5
99,1 ± 1,2
1,1
2,9
40
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Sulphate
22,8 mg/l
±
0,3 mg/l
23,1 mg/l
±
0,9 mg/l
22,9 mg/l
±
0,9 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
mg/l
D
mg/l
E
mg/l
F
Recovery
Result
[mg/l]
23,01
H
22
1
mg/l
101%
0,29
mg/l
96%
-1,10
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
21,5
R
22,1
S
22,2
94%
-1,78
2,2
mg/l
97%
-0,96
0,95
mg/l
97%
-0,82
T
21,99
2,2
mg/l
96%
-1,11
U
22,6
2,3
mg/l
99%
-0,27
V
22,1
2,2
mg/l
97%
-0,96
W
22,0
0,05
mg/l
96%
-1,10
X
21,8
3,3
mg/l
96%
-1,37
Y
24,57
0,13
mg/l
108%
2,43
15%
25,1
10%
23,9
5%
22,8
Target
value ±
U (k=2)
21,7
- 5%
20,5
- 10%
19,4
- 15%
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
mg/l
AA
110
mg/l
AB
23,0
AC
22,1
AD
20
*
2
mg/l
101%
0,27
2
mg/l
97%
-0,96
1,2
mg/l
88%
-3,84
AE
22,1
1,2
mg/l
97%
-0,96
AF
22,8
0,34
mg/l
100%
0,00
AG
22,3
2,2
mg/l
98%
-0,69
AH
24,82
1,489
mg/l
109%
2,77
AI
22,9
0,7
mg/l
100%
0,14
99%
-0,41
AJ
AK
15%
3,42
26,2
A
mg/l
Z
10%
2,28
z-Score
mg/l
G
5%
1,14
100
90
80
70
mg/l
22,5
mg/l
AL
mg/l
AM
mg/l
A
C
B
AN
22,44
0,26
mg/l
98%
-0,49
AO
23,9
0,2
mg/l
105%
1,51
AP
19
mg/l
83%
-5,21
AQ
22,5
3,1
mg/l
99%
-0,41
AR
21,5
4,3
mg/l
94%
-1,78
AS
23,77
0,8
mg/l
104%
1,33
*
60
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
23
AU
23,1698
AV
19,87
*
mg/l
101%
0,0141
mg/l
102%
0,51
0,842
mg/l
87%
-4,02
-1,10
AW
0,27
mg/l
AX
22,0
1,2
mg/l
96%
AY
23,0
3,0
mg/l
101%
0,27
AZ
22,4
2,0
mg/l
98%
-0,55
BB
23,68
2,33
mg/l
104%
1,21
BC
24
2
mg/l
105%
1,64
BD
33
*
2
mg/l
145%
13,98
BE
17,93
*
mg/l
79%
-6,67
BF
22,1
mg/l
97%
-0,96
mg/l
99%
-0,41
mg/l
117%
5,18
mg/l
98%
-0,55
BA
mg/l
2
BG
mg/l
BH
22,5
BI
26,58
1,1
BJ
22,4
3,4
BL
23,3
1,4
BM
21,9
*
BK
mg/l
mg/l
102%
0,69
mg/l
96%
-1,23
BN
23,1
2,08
mg/l
101%
0,41
BO
23,21
0,70
mg/l
102%
0,56
Outliers excl.
22,7 ± 0,4
99,5 ± 1,5
0,8
3,5
38
Unit
mg/l
%
mg/l
%
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
22,7 ± 0,9
99,5 ± 3,8
2,1
9,4
44
Sample N131A
Parameter Orthophosphate
0,090 mg/l
±
0,001 mg/l
0,090 mg/l
±
0,013 mg/l
0,090 mg/l
±
0,013 mg/l
Result
[mg/l]
Lab Code
Result
±
Unit
Recovery
z-Score
A
0,088
0,003
mg/l
98%
-0,20
0,01
-0,10
B
0,089
mg/l
99%
C
0,0954
mg/l
106%
0,55
D
0,087
mg/l
97%
-0,30
E
0,0907
mg/l
101%
0,07
F
0,087
mg/l
97%
-0,30
G
0,0837
mg/l
93%
-0,64
H
0,089
0,009
mg/l
99%
-0,10
I
0,096
0,003
mg/l
107%
0,61
J
0,108
mg/l
120%
1,82
mg/l
102%
0,20
mg/l
100%
0,00
mg/l
102%
0,20
mg/l
109%
0,81
mg/l
100%
0,00
mg/l
101%
0,10
mg/l
84%
-1,41
0,40
K
0,092
L
0,090
M
0,092
N
0,098
O
0,090
P
0,091
Q
0,076
0,005
*
0,005
0,002
0,01
R
mg/l
S
0,094
0,005
mg/l
104%
T
0,098
0,009
mg/l
109%
0,81
U
0,089
0,015
mg/l
99%
-0,10
V
0,089
0,009
mg/l
99%
-0,10
W
0,088
0,0002
mg/l
98%
-0,20
X
0,095
0,014
mg/l
106%
0,51
Y
0,07
0,01
mg/l
78%
-2,02
*
Z
0,082
mg/l
91%
-0,81
AA
0,086
mg/l
96%
-0,40
AB
0,085
0,012
mg/l
94%
-0,51
AC
0,095
0,009
mg/l
106%
0,51
AD
0,089
0,013
mg/l
99%
-0,10
AE
0,091
0,009
mg/l
101%
0,10
AF
0,0864
0,0020
mg/l
96%
-0,36
AG
0,089
AH
0,84
AI
0,089
*
0,013
mg/l
99%
-0,10
0,0101
mg/l
933%
75,76
0,009
mg/l
99%
-0,10
109%
0,81
AJ
AK
30%
0,0270
45%
0,0405
0,131
45%
0,117
30%
0,104
15%
0,090
Target
value ±
U (k=2)
0,077
- 15%
0,063
- 30%
0,050
- 45%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
110
100
FN
90
FN
80
70
mg/l
0,098
mg/l
AL
mg/l
AM
0,81
AN
0,086
*
mg/l
900%
72,73
0,002
mg/l
96%
-0,40
mg/l
<0,2
mg/l
AQ
•
mg/l
AR
<0,6
AS
0,076
0,002
60
A
0,05
AO
AP
15%
0,0135
mg/l
•
mg/l
84%
-1,41
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
0,09
AU
0
0
AV
mg/l
100%
mg/l
FN
mg/l
AW
0,10
AX
0,08
0,003
mg/l
111%
1,01
mg/l
89%
-1,01
97%
-0,30
102%
0,20
-0,30
AY
mg/l
AZ
mg/l
BA
BB
mg/l
0,087
0,013
BC
BD
0,00
mg/l
mg/l
0,092
0,002
BE
mg/l
mg/l
BF
0,087
0,009
mg/l
97%
BG
0,095
0,010
mg/l
106%
0,51
BH
0,086
0,002
mg/l
96%
-0,40
BI
<0,02
BJ
0,0919
0,0046
BK
mg/l
FN
mg/l
102%
0,19
mg/l
100%
0,00
mg/l
126%
2,32
mg/l
BL
0,090
BM
0,113
0,006
*
BN
mg/l
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
0,120 ± 0,056
133,3 ± 62,6
0,147
122,6
49
Outliers excl.
0,090 ± 0,002
99,5 ± 2,4
0,005
5,9
44
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Orthophosphate
0,071 mg/l
±
0,001 mg/l
0,072 mg/l
±
0,010 mg/l
0,073 mg/l
±
0,010 mg/l
Result
[mg/l]
Lab Code
Result
±
Unit
Recovery
z-Score
A
0,072
0,003
mg/l
101%
0,13
0,01
B
0,070
mg/l
99%
-0,13
C
0,0745
mg/l
105%
0,45
D
0,073
mg/l
103%
0,26
E
0,0720
mg/l
101%
0,13
F
0,072
mg/l
101%
0,13
G
0,0690
mg/l
97%
-0,26
H
0,070
0,007
mg/l
99%
-0,13
I
0,080
0,003
mg/l
113%
1,15
J
0,082
mg/l
115%
1,41
K
0,073
mg/l
103%
0,26
L
0,071
mg/l
100%
0,00
M
0,070
mg/l
99%
-0,13
mg/l
107%
0,64
mg/l
99%
-0,13
mg/l
99%
-0,13
mg/l
86%
-1,28
N
0,076
O
0,070
P
0,070
Q
0,061
0,005
0,005
0,001
0,01
R
mg/l
S
0,076
0,004
mg/l
107%
0,64
T
0,080
0,008
mg/l
113%
1,15
U
0,072
0,012
mg/l
101%
0,13
V
0,074
0,007
mg/l
104%
0,38
W
0,0687
0,0005
mg/l
97%
-0,29
X
0,077
0,012
mg/l
108%
0,77
Y
0,06
0,01
mg/l
85%
-1,41
0,024
mg/l
93%
-0,64
mg/l
99%
-0,13
-0,26
*
Z
0,066
AA
0,070
AB
0,069
0,01
mg/l
97%
AC
0,076
0,007
mg/l
107%
0,64
AD
0,067
0,010
mg/l
94%
-0,51
AE
0,071
0,007
mg/l
100%
0,00
AF
0,0760
0,0020
mg/l
107%
0,64
AG
0,070
0,011
mg/l
99%
-0,13
AH
0,075
0,009
mg/l
106%
0,51
AI
mg/l
AJ
mg/l
AK
mg/l
AL
mg/l
AM
mg/l
AN
mg/l
AO
mg/l
AP
mg/l
AQ
mg/l
AR
mg/l
AS
mg/l
15%
0,0107
30%
0,0213
45%
0,0320
0,103
45%
0,092
30%
0,082
15%
0,071
Target
value ±
U (k=2)
0,060
- 15%
0,050
- 30%
0,039
- 45%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
110
100
90
80
70
60
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
mg/l
AU
mg/l
AV
mg/l
AW
mg/l
AX
mg/l
AY
mg/l
AZ
mg/l
BA
mg/l
BB
mg/l
BC
mg/l
BD
mg/l
BE
mg/l
BF
mg/l
BG
mg/l
BH
mg/l
BI
mg/l
BJ
mg/l
BK
mg/l
BL
mg/l
BM
mg/l
BN
mg/l
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
0,072 ± 0,002
101,3 ± 3,2
0,005
6,6
33
Outliers excl.
0,072 ± 0,002
101,8 ± 3,0
0,004
6,0
32
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Orthophosphate_1
0,082 mg/l
±
0,002 mg/l
0,085 mg/l
±
0,012 mg/l
0,085 mg/l
±
0,012 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
mg/l
D
mg/l
E
mg/l
F
mg/l
G
mg/l
H
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
mg/l
R
mg/l
S
mg/l
T
mg/l
U
mg/l
V
mg/l
W
mg/l
X
mg/l
Y
mg/l
Z
mg/l
AA
mg/l
AB
mg/l
AC
mg/l
AD
mg/l
AE
mg/l
AF
mg/l
AG
mg/l
AH
mg/l
AI
0,087
0,009
AJ
AK
Result
[mg/l]
30%
0,0246
45%
0,0369
0,119
45%
0,107
30%
0,094
15%
0,082
Target
value ±
U (k=2)
0,070
- 15%
0,057
- 30%
0,045
- 45%
z-Score
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
110
100
90
80
106%
0,55
123%
2,11
mg/l
732%
57,43
mg/l
99%
-0,11
70
mg/l
0,101
mg/l
AL
mg/l
AM
0,60
AN
0,081
*
0,003
AO
AP
mg/l
Recovery
15%
0,0123
A
mg/l
<0,2
mg/l
AQ
•
mg/l
AR
<0,6
AS
0,071
0,002
60
mg/l
•
mg/l
87%
-1,22
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
0,06
AU
0
mg/l
0
AV
0,10
AX
0,078
0,003
mg/l
122%
2,00
mg/l
95%
-0,44
102%
0,22
105%
0,44
AY
mg/l
AZ
mg/l
BA
mg/l
0,084
0,012
BC
BD
-2,44
mg/l
AW
BB
73%
mg/l
mg/l
mg/l
0,086
0,002
BE
mg/l
mg/l
BF
0,085
0,009
mg/l
104%
0,33
BG
0,091
0,010
mg/l
111%
1,00
BH
0,082
0,001
mg/l
100%
0,00
BI
0,09
mg/l
110%
0,89
BJ
0,0889
mg/l
108%
0,76
mg/l
115%
1,33
mg/l
132%
2,88
0,0044
BK
mg/l
BL
0,094
BM
0,108
0,007
BN
mg/l
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
0,117 ± 0,089
142,5 ± 108,0
0,125
107,0
17
Outliers excl.
0,087 ± 0,009
105,7 ± 10,4
0,012
13,4
16
Unit
mg/l
%
mg/l
%
Sample N131A
Parameter Boron
15%
Target value
<0,02 mg/l
IFA result
<0,02 mg/l
Stability test
<0,02 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
D
mg/l
mg/l
F
mg/l
G
mg/l
<0,002
0,001
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
mg/l
R
mg/l
S
mg/l
T
mg/l
U
mg/l
Result
[mg/l]
45%
Recovery
V
15%
•
0,02
- 15%
- 30%
- 45%
A
X
<0,02
mg/l
•
Z
mg/l
mg/l
AB
mg/l
<0,01
AD
mg/l
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Deviation
140
•
AA
E
D
Recovery
[%]
mg/l
mg/l
C
B
mg/l
Y
Target
value
•
<0,010
Recovery
130
120
110
FP
•
100
90
mg/l
AE
<0,004
mg/l
•
AF
[0,002]
mg/l
•
AG
<0,020
mg/l
•
AH
[0,00114]
mg/l
•
AI
<0,050
mg/l
•
AJ
<0,005
mg/l
•
AK
mg/l
AL
mg/l
AM
mg/l
AN
mg/l
AO
mg/l
AP
z-Score
30%
W
AC
45%
mg/l
<0,05
E
H
30%
<0,1
mg/l
AQ
mg/l
AR
mg/l
AS
mg/l
80
70
60
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
•
AT
AU
mg/l
0
0
AV
mg/l
0,0565
0,0017
AY
AZ
•
mg/l
AW
AX
mg/l
mg/l
FP
mg/l
<0,010
mg/l
BA
•
mg/l
BB
<0,010
mg/l
•
BC
<0,05
mg/l
•
BD
mg/l
BE
<0,01
mg/l
•
BF
<0,005
mg/l
•
BG
BH
mg/l
[0,002]
mg/l
BI
mg/l
BJ
mg/l
BK
mg/l
BL
•
mg/l
BM
<0,01
mg/l
•
BN
<0,020
mg/l
•
BO
mg/l
BP
mg/l
All results
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
Outliers excl.
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Boron
0,071 mg/l
±
0,001 mg/l
0,073 mg/l
±
0,007 mg/l
0,071 mg/l
±
0,007 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
D
Result
[mg/l]
mg/l
*
mg/l
F
mg/l
G
mg/l
0,072
0,01
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
mg/l
R
mg/l
S
mg/l
T
mg/l
U
mg/l
V
137%
101%
0,14
X
0,063
0,009
mg/l
89%
-1,13
mg/l
mg/l
AC
0,072
0,01
AD
mg/l
0,082
15%
0,071
Target
value ±
U (k=2)
0,060
- 15%
0,050
- 30%
0,039
- 45%
C
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Deviation
140
101%
AB
30%
Recovery
[%]
mg/l
mg/l
0,092
B
mg/l
Z
45%
A
0,001
AA
0,103
0,14
0,072
mg/l
45%
0,0320
3,66
W
Y
30%
0,0213
z-Score
mg/l
0,097
E
H
Recovery
15%
0,0107
Recovery
130
120
110
101%
0,14
100
90
mg/l
AE
0,074
0,008
mg/l
104%
0,42
AF
0,068
0,002
mg/l
96%
-0,42
AG
0,069
0,010
mg/l
97%
-0,28
AH
0,084
0,0101
mg/l
118%
1,83
AI
mg/l
AJ
mg/l
AK
mg/l
AL
mg/l
AM
mg/l
AN
mg/l
AO
mg/l
AP
mg/l
AQ
mg/l
AR
mg/l
AS
mg/l
80
70
60
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
mg/l
AU
mg/l
AV
mg/l
AW
mg/l
AX
mg/l
AY
mg/l
AZ
mg/l
BA
mg/l
BB
mg/l
BC
mg/l
BD
mg/l
BE
mg/l
BF
mg/l
BG
mg/l
BH
mg/l
BI
mg/l
BJ
mg/l
BK
mg/l
BL
mg/l
BM
mg/l
BN
mg/l
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
0,075 ± 0,011
105,0 ± 16,0
0,010
13,6
9
Outliers excl.
0,072 ± 0,007
101,1 ± 10,5
0,006
8,4
8
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Boron_1
0,058 mg/l
±
0,001 mg/l
0,059 mg/l
±
0,006 mg/l
0,057 mg/l
±
0,006 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
mg/l
D
mg/l
E
mg/l
F
mg/l
G
mg/l
H
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
mg/l
R
mg/l
S
mg/l
T
mg/l
U
mg/l
V
mg/l
W
mg/l
X
mg/l
Y
mg/l
Z
mg/l
AA
mg/l
AB
mg/l
AC
mg/l
AD
mg/l
AE
mg/l
AF
mg/l
AG
mg/l
AH
mg/l
Recovery
Result
[mg/l]
0,34
AP
58,7
*
5,1
mg/l
mg/l
AR
mg/l
AS
mg/l
- 15%
0,041
- 30%
0,032
- 45%
C
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Deviation
Recovery
FN
80
0,17
AQ
0,049
90
103%
mg/l
Target
value ±
U (k=2)
100
102%
mg/l
0,058
110
mg/l
AN
15%
120
mg/l
AO
0,067
130
0,002
mg/l
30%
140
0,006
AM
0,075
Recovery
[%]
0,060
mg/l
45%
B
0,059
mg/l
45%
0,0261
0,084
A
AI
AL
30%
0,0174
z-Score
AJ
AK
15%
0,0087
70
60
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
101207%
10110,69
AT
AU
mg/l
0,0575
0,0695
AV
mg/l
FN
mg/l
0,057
0,002
BA
mg/l
98%
-0,17
mg/l
BB
0,054
BC
0,07
*
0,011
mg/l
93%
-0,69
0,01
mg/l
121%
2,07
mg/l
105%
0,52
mg/l
102%
0,17
103%
0,34
mg/l
91%
-0,86
mg/l
105%
0,52
BD
mg/l
BE
0,061
BF
0,059
0,006
BG
BH
-0,09
mg/l
<0,001
AY
AZ
99%
mg/l
AW
AX
mg/l
mg/l
0,060
0,002
mg/l
BI
mg/l
BJ
mg/l
BK
mg/l
BL
mg/l
BM
0,053
BN
0,061
0,0085
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
4,946 ± 15,198
8527,5 ± 26203,
16,928
342,3
12
Outliers excl.
0,058 ± 0,003
100,3 ± 5,0
0,003
4,8
10
Unit
mg/l
%
mg/l
%
Sample N131A
Parameter DOC
4,06 mg/l
±
0,05 mg/l
4,09 mg/l
±
0,41 mg/l
3,98 mg/l
±
0,40 mg/l
Lab Code
Result
±
A
mg/l
4,22
mg/l
mg/l
G
mg/l
4,0
0,2
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
3,99
mg/l
R
mg/l
S
mg/l
109%
1,43
104%
0,64
99%
5,28
30%
4,67
15%
4,06
Target
value ±
U (k=2)
3,45
- 15%
2,84
- 30%
2,23
- 45%
A
98%
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
0,39
mg/l
96%
-0,60
0,45
mg/l
111%
1,83
V
4,006
0,40
mg/l
99%
-0,21
W
4,19
0,16
mg/l
103%
0,52
X
4,40
0,66
mg/l
108%
1,35
Y
4,51
0,04
mg/l
111%
1,79
Laboratories
Recovery
[%]
4,52
Z
C
B
-0,28
3,91
Deviation
140
Recovery
130
120
mg/l
AA
110
mg/l
AB
4,16
0,7
mg/l
102%
0,40
AC
4,28
0,39
mg/l
105%
0,87
AD
4,26
0,68
mg/l
105%
0,79
AE
4,13
0,37
mg/l
102%
0,28
AF
4,22
0,01
mg/l
104%
0,64
AG
4,03
0,40
mg/l
99%
-0,12
AH
4,3
0,34
mg/l
106%
0,95
AI
4,07
0,41
mg/l
100%
0,04
101%
0,16
AJ
100
90
80
70
mg/l
4,1
mg/l
AL
mg/l
AM
mg/l
3,91
0,12
mg/l
96%
-0,60
4,75
0,42
mg/l
117%
2,74
101%
0,16
AP
mg/l
mg/l
4,1
1,2
mg/l
mg/l
C
B
AN
AQ
60
A
AO
AS
45%
-0,24
T
AR
5,89
z-Score
U
AK
45%
1,827
mg/l
F
H
30%
1,218
mg/l
4,42
D
E
Recovery
Result
[mg/l]
mg/l
B
C
Unit
15%
0,609
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
AU
mg/l
5,5243
*
0,0918
AV
mg/l
136%
5,82
mg/l
AW
mg/l
AX
4,25
0,1
mg/l
105%
0,75
AY
4,48
0,03
mg/l
110%
1,67
AZ
4,13
0,50
mg/l
102%
0,28
BA
mg/l
BB
3,89
0,27
mg/l
96%
-0,68
BC
4,1
0,5
mg/l
101%
0,16
BD
4,2
0,2
mg/l
103%
0,56
103%
0,56
mg/l
137%
6,04
mg/l
114%
2,18
BE
BF
mg/l
4,2
0,4
BG
mg/l
mg/l
BH
mg/l
BI
5,58
BJ
4,61
*
0,92
BK
mg/l
BL
4,13
BM
9,71
BN
4,13
0,17
*
0,248
BO
102%
0,28
mg/l
239%
22,45
mg/l
102%
0,28
Outliers excl.
4,21 ± 0,10
103,6 ± 2,5
0,21
4,9
32
Unit
mg/l
%
mg/l
%
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
mg/l
All results
4,44 ± 0,46
109,4 ± 11,3
0,99
22,3
35
Sample N131B
Parameter DOC
2,63 mg/l
±
0,04 mg/l
2,62 mg/l
±
0,26 mg/l
2,58 mg/l
±
0,26 mg/l
Lab Code
Result
±
A
mg/l
2,84
mg/l
mg/l
G
mg/l
2,7
0,2
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
2,31
mg/l
R
mg/l
S
mg/l
116%
2,58
108%
1,29
103%
3,42
30%
3,02
15%
2,63
Target
value ±
U (k=2)
2,24
- 15%
1,84
- 30%
1,45
- 45%
A
88%
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
0,26
mg/l
98%
-0,31
0,30
mg/l
115%
2,45
V
2,719
0,27
mg/l
103%
0,55
W
2,68
0,07
mg/l
102%
0,31
X
2,50
0,38
mg/l
95%
-0,80
Y
3,12
0,02
mg/l
119%
3,01
Laboratories
Recovery
[%]
3,03
Z
C
B
-1,96
2,58
Deviation
140
Recovery
130
120
mg/l
AA
110
mg/l
AB
2,74
0,5
mg/l
104%
0,67
AC
2,84
0,26
mg/l
108%
1,29
AD
2,76
0,44
mg/l
105%
0,80
AE
2,70
0,25
mg/l
103%
0,43
AF
2,85
0,01
mg/l
108%
1,35
AG
2,57
0,26
mg/l
98%
-0,37
AH
2,9
0,23
mg/l
110%
1,66
AI
2,86
0,29
mg/l
109%
1,41
103%
0,43
AJ
100
90
80
70
mg/l
2,7
mg/l
AL
mg/l
AM
mg/l
AN
2,61
AO
3,25
*
mg/l
99%
-0,12
mg/l
124%
3,80
106%
1,04
mg/l
mg/l
2,8
0,9
mg/l
mg/l
C
B
0,29
AP
60
A
0,14
AQ
AS
45%
0,43
T
AR
3,81
z-Score
U
AK
45%
1,184
mg/l
F
H
30%
0,789
mg/l
3,05
D
E
Recovery
Result
[mg/l]
mg/l
B
C
Unit
15%
0,395
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
AU
mg/l
4,701
*
0,2198
AV
mg/l
179%
12,70
mg/l
AW
mg/l
AX
2,85
0,07
mg/l
108%
1,35
AY
2,73
0,03
mg/l
104%
0,61
AZ
2,65
0,50
mg/l
101%
0,12
BA
mg/l
BB
2,51
0,18
mg/l
95%
-0,74
BC
2,7
0,3
mg/l
103%
0,43
BD
2,8
0,2
mg/l
106%
1,04
104%
0,67
mg/l
125%
3,99
mg/l
117%
2,76
BE
BF
mg/l
2,74
0,3
BG
mg/l
mg/l
BH
mg/l
BI
3,28
BJ
3,08
*
0,62
BK
mg/l
BL
2,75
BM
5,62
BN
2,65
0,11
*
0,159
BO
105%
0,74
mg/l
214%
18,34
mg/l
101%
0,12
Outliers excl.
2,75 ± 0,09
104,6 ± 3,3
0,18
6,4
31
Unit
mg/l
%
mg/l
%
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
mg/l
All results
2,92 ± 0,28
111,0 ± 10,6
0,61
20,8
35
Sample N131A
Parameter Total P (as PO4)
0,148 mg/l
±
0,002 mg/l
0,159 mg/l
±
0,022 mg/l
0,168 mg/l
±
0,024 mg/l
Result
[mg/l]
Lab Code
Result
±
Unit
Recovery
z-Score
A
0,150
0,003
mg/l
101%
0,10
0,01
B
0,147
mg/l
99%
-0,05
C
0,141
mg/l
95%
-0,36
D
0,139
mg/l
94%
-0,47
E
0,146
mg/l
99%
-0,10
mg/l
94%
-0,44
F
G
mg/l
0,1396
H
0,15
0,01
mg/l
101%
0,10
I
0,142
0,005
mg/l
96%
-0,31
J
0,153
mg/l
103%
0,26
K
0,146
mg/l
99%
-0,10
L
0,147
mg/l
99%
-0,05
M
0,138
mg/l
93%
-0,52
mg/l
114%
1,04
mg/l
103%
0,26
mg/l
100%
0,00
mg/l
97%
-0,21
N
0,168
O
0,153
P
0,148
Q
0,144
0,005
0,003
0,01
R
mg/l
S
mg/l
T
0,156
0,015
mg/l
105%
0,42
0,135
0,016
mg/l
91%
-0,68
V
0,141
0,014
mg/l
95%
-0,36
W
0,139
0,003
mg/l
94%
-0,47
X
0,137
0,021
mg/l
93%
-0,57
Y
0,13
0,00
mg/l
88%
-0,94
0,004
mg/l
74%
-2,03
mg/l
97%
-0,26
-0,10
Z
0,109
AA
0,143
AB
0,146
0,02
mg/l
99%
AC
0,158
0,006
mg/l
107%
0,52
AD
0,147
0,019
mg/l
99%
-0,05
AE
0,150
0,015
mg/l
101%
0,10
AF
0,1480
0,0019
mg/l
100%
0,00
AG
0,146
0,029
mg/l
99%
-0,10
AH
0,15
0,0223
mg/l
101%
0,10
AI
0,175
0,018
mg/l
118%
1,40
97%
-0,21
mg/l
561%
35,45
mg/l
94%
-0,47
AJ
AK
30%
0,0444
45%
0,0666
0,215
45%
0,192
30%
0,170
15%
0,148
Target
value ±
U (k=2)
0,126
- 15%
0,104
- 30%
0,081
- 45%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
U
*
15%
0,0222
Deviation
140
Recovery
130
120
110
100
90
80
70
mg/l
0,144
mg/l
AL
mg/l
AM
0,83
AN
0,139
*
0,006
AO
A
mg/l
AP
0,23
*
AQ
0,05
*
AR
<0,15
AS
0,146
0,02
0,002
60
mg/l
155%
4,26
mg/l
34%
-5,09
mg/l
•
mg/l
99%
-0,10
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
0,17
AU
0,1656
0,1839
AV
115%
1,14
mg/l
112%
0,91
99%
-0,10
mg/l
AW
AX
mg/l
mg/l
0,146
0,005
mg/l
AY
mg/l
AZ
mg/l
BA
mg/l
BB
mg/l
BC
0,16
0,02
mg/l
108%
0,62
BD
0,151
0,005
mg/l
102%
0,16
1,14
BE
mg/l
BF
0,17
0,02
mg/l
115%
BG
0,161
0,014
mg/l
109%
0,68
BH
0,122
0,002
mg/l
82%
-1,35
0,153
0,038
103%
0,26
mg/l
99%
-0,10
mg/l
82%
-1,40
mg/l
74%
-1,98
BI
BJ
mg/l
BK
mg/l
mg/l
BL
0,146
BM
0,121
BN
0,110
0,010
*
0,0110
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
0,160 ± 0,038
107,8 ± 25,4
0,099
62,3
50
Outliers excl.
0,148 ± 0,005
99,8 ± 3,1
0,011
7,7
45
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Total P (as PO4)
0,076 mg/l
±
0,001 mg/l
0,079 mg/l
±
0,011 mg/l
0,084 mg/l
±
0,012 mg/l
Result
[mg/l]
Lab Code
Result
±
Unit
Recovery
z-Score
A
0,074
0,003
mg/l
97%
-0,20
0,01
B
0,081
mg/l
107%
0,51
C
0,0819
mg/l
108%
0,60
D
0,076
mg/l
100%
0,00
E
0,0754
mg/l
99%
-0,06
mg/l
100%
-0,02
F
mg/l
G
0,0758
H
0,077
0,005
mg/l
101%
0,10
I
0,075
0,003
mg/l
99%
-0,10
J
0,088
mg/l
116%
1,21
K
0,074
mg/l
97%
-0,20
L
0,079
mg/l
104%
0,30
M
0,071
mg/l
93%
-0,51
mg/l
132%
2,43
mg/l
104%
0,30
mg/l
101%
0,10
mg/l
114%
1,11
N
0,100
O
0,079
P
0,077
Q
0,087
0,005
*
0,002
0,01
R
mg/l
S
mg/l
30%
0,0228
T
0,083
0,008
mg/l
109%
0,71
0,073
0,009
mg/l
96%
-0,30
V
0,080
0,008
mg/l
105%
0,40
W
0,072
0,001
mg/l
95%
-0,40
X
0,077
0,012
mg/l
101%
0,10
Y
0,07
0,00
mg/l
92%
-0,61
45%
0,0342
0,110
45%
0,099
30%
0,087
15%
0,076
Target
value ±
U (k=2)
0,065
- 15%
0,053
- 30%
0,042
- 45%
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
U
Z
15%
0,0114
Deviation
140
Recovery
130
120
mg/l
AA
0,077
mg/l
101%
0,10
AB
0,076
0,009
mg/l
100%
0,00
AC
0,088
0,004
mg/l
116%
1,21
AD
0,067
0,009
mg/l
88%
-0,91
AE
0,077
0,008
mg/l
101%
0,10
AF
0,0790
0,0019
mg/l
104%
0,30
AG
0,071
0,014
mg/l
93%
-0,51
AH
0,086
0,0130
mg/l
113%
1,01
AI
mg/l
AJ
mg/l
AK
mg/l
AL
mg/l
AM
mg/l
AN
mg/l
AO
mg/l
AP
mg/l
AQ
mg/l
AR
mg/l
AS
mg/l
110
100
90
80
70
60
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
mg/l
AU
mg/l
AV
mg/l
AW
mg/l
AX
mg/l
AY
mg/l
AZ
mg/l
BA
mg/l
BB
mg/l
BC
mg/l
BD
mg/l
BE
mg/l
BF
mg/l
BG
mg/l
BH
mg/l
BI
mg/l
BJ
mg/l
BK
mg/l
BL
mg/l
BM
mg/l
BN
mg/l
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
0,078 ± 0,003
102,9 ± 4,4
0,007
8,5
30
Outliers excl.
0,077 ± 0,003
102,0 ± 3,6
0,005
6,9
29
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Total P (as PO4)_1
0,087 mg/l
±
0,002 mg/l
0,092 mg/l
±
0,013 mg/l
0,097 mg/l
±
0,014 mg/l
Lab Code
Result
±
Unit
A
mg/l
B
mg/l
C
mg/l
D
mg/l
E
mg/l
F
mg/l
G
mg/l
H
mg/l
I
mg/l
J
mg/l
K
mg/l
L
mg/l
M
mg/l
N
mg/l
O
mg/l
P
mg/l
Q
mg/l
R
mg/l
S
mg/l
T
mg/l
U
mg/l
V
mg/l
W
mg/l
X
mg/l
Y
mg/l
Z
mg/l
AA
mg/l
AB
mg/l
AC
mg/l
AD
mg/l
AE
mg/l
AF
mg/l
AG
mg/l
AH
mg/l
AI
0,108
0,011
AJ
AK
mg/l
Recovery
15%
0,0131
Result
[mg/l]
30%
0,0261
45%
0,0392
0,126
45%
0,113
30%
0,100
15%
0,087
Target
value ±
U (k=2)
0,074
- 15%
0,061
- 30%
0,048
- 45%
z-Score
A
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
140
Recovery
130
120
110
100
90
80
124%
1,86
109%
0,71
mg/l
713%
47,13
mg/l
101%
0,09
70
mg/l
0,095
mg/l
AL
mg/l
AM
0,62
AN
0,088
*
0,012
AO
A
mg/l
AP
<0,2
AQ
0,05
AR
<0,15
AS
0,091
*
0,02
0,002
60
mg/l
•
mg/l
57%
mg/l
•
mg/l
105%
-3,27
0,35
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
AT
0,12
AU
0,0867
0,0475
AV
138%
2,92
mg/l
100%
-0,03
103%
0,25
mg/l
AW
AX
mg/l
mg/l
0,0898
0,005
mg/l
AY
mg/l
AZ
mg/l
BA
mg/l
BB
mg/l
BC
0,10
0,02
mg/l
115%
1,15
BD
0,095
0,005
mg/l
109%
0,71
2,03
BE
mg/l
BF
0,11
0,01
mg/l
126%
BG
0,104
0,009
mg/l
120%
1,50
BH
0,083
0,002
mg/l
95%
-0,35
<0,15
0,038
BI
BJ
mg/l
BK
mg/l
•
mg/l
BL
0,097
BM
0,110
BN
0,076
0,007
0,0076
BO
111%
mg/l
126%
0,88
2,03
mg/l
87%
-0,97
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
mg/l
All results
0,125 ± 0,091
143,6 ± 104,7
0,129
102,9
17
Outliers excl.
0,097 ± 0,009
111,4 ± 10,5
0,012
12,2
15
Unit
mg/l
%
mg/l
%
Sample N131A
Parameter KMnO4-Index
3,40 mg/l
±
0,09 mg/l
3,57 mg/l
±
0,36 mg/l
3,51 mg/l
±
0,35 mg/l
Lab Code
Result
±
A
Unit
Recovery
Result
[mg/l]
3,30
mg/l
97%
-0,27
D
3,48
mg/l
102%
0,21
E
mg/l
F
mg/l
G
mg/l
H
0,1
mg/l
0,2
mg/l
mg/l
N
mg/l
O
15%
3,40
Target
value ±
U (k=2)
2,89
- 15%
102%
0,21
2,38
- 30%
0,1
mg/l
1,87
- 45%
100%
0,00
A
3,25
0,5
mg/l
96%
-0,40
3,20
0,32
mg/l
94%
-0,53
T
mg/l
U
mg/l
V
0,05
mg/l
X
mg/l
Y
mg/l
Z
mg/l
AA
mg/l
AB
mg/l
93%
-0,61
3,31
0,3
mg/l
97%
-0,24
3,9
0,4
mg/l
115%
1,34
mg/l
mg/l
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
Recovery
130
100
90
AG
3,48
0,35
mg/l
102%
0,21
AH
3,5
0,5000
mg/l
103%
0,27
AI
3,25
0,33
mg/l
96%
-0,40
107%
0,64
AJ
I
H
110
AD
AF
G
F
120
AC
AE
E
D
140
mg/l
3,17
C
B
mg/l
S
80
70
mg/l
3,64
mg/l
AL
mg/l
AM
mg/l
AN
mg/l
AO
mg/l
AP
mg/l
AQ
AS
3,91
0,27
R
AR
30%
103%
mg/l
3,4
Q
AK
4,42
mg/l
3,48
M
W
45%
mg/l
K
P
4,93
mg/l
3,5
J
L
45%
1,530
mg/l
C
I
30%
1,020
z-Score
mg/l
B
15%
0,510
A
0,55
mg/l
mg/l
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
mg/l
3,2
60
94%
-0,53
AT
3,1
AU
3,120
mg/l
91%
-0,80
mg/l
92%
AV
-0,75
3,7
mg/l
109%
0,80
AW
3,331
mg/l
98%
-0,18
AX
3,39
mg/l
100%
-0,03
1,39
0,6410
0,17
AY
mg/l
AZ
mg/l
BA
3,92
0,37
mg/l
115%
BB
3,60
0,54
mg/l
106%
0,53
BC
3,3
0,3
mg/l
97%
-0,27
101%
0,11
91%
-0,83
74%
-2,38
BD
mg/l
BE
BF
mg/l
3,44
0,3
BG
BH
mg/l
mg/l
3,09
0,81
mg/l
BI
mg/l
BJ
mg/l
BK
mg/l
BL
BM
mg/l
2,51
mg/l
*
BN
mg/l
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
3,37 ± 0,15
99,1 ± 4,5
0,28
8,4
26
Outliers excl.
3,40 ± 0,13
100,1 ± 3,7
0,23
6,6
25
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter KMnO4-Index
3,90 mg/l
±
0,08 mg/l
4,10 mg/l
±
0,41 mg/l
4,01 mg/l
±
0,40 mg/l
Lab Code
Result
±
A
Unit
Recovery
Result
[mg/l]
4,23
mg/l
108%
0,77
D
3,96
mg/l
102%
0,14
E
mg/l
F
mg/l
G
mg/l
H
0,1
mg/l
0,2
mg/l
mg/l
N
mg/l
O
15%
3,90
Target
value ±
U (k=2)
3,32
- 15%
103%
0,23
2,73
- 30%
0,1
mg/l
2,15
- 45%
100%
0,00
A
3,76
0,5
mg/l
96%
-0,33
3,86
0,38
mg/l
99%
-0,09
T
mg/l
U
mg/l
V
0,18
mg/l
X
mg/l
Y
mg/l
Z
mg/l
AA
mg/l
AB
mg/l
97%
-0,23
3,88
0,35
mg/l
99%
-0,05
4,1
0,41
mg/l
105%
0,47
mg/l
mg/l
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Recovery
[%]
Deviation
Recovery
130
100
90
AG
4,16
0,42
mg/l
107%
0,61
AH
3,9
0,0600
mg/l
100%
0,00
AI
3,91
0,39
mg/l
100%
0,02
99%
-0,12
AJ
I
H
110
AD
AF
G
F
120
AC
AE
E
D
140
mg/l
3,80
C
B
mg/l
S
80
70
mg/l
3,85
mg/l
AL
mg/l
AM
mg/l
AN
mg/l
AO
mg/l
AP
mg/l
AQ
AS
4,49
0,23
R
AR
30%
103%
mg/l
3,9
Q
AK
5,07
mg/l
4,00
M
W
45%
mg/l
K
P
5,66
mg/l
4,0
J
L
45%
1,755
mg/l
C
I
30%
1,170
z-Score
mg/l
B
15%
0,585
A
0,61
mg/l
mg/l
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
mg/l
3,6
60
92%
-0,70
AT
3,6
AU
4,140
mg/l
92%
-0,70
mg/l
106%
AV
0,56
3,9
mg/l
100%
0,00
AW
3,766
mg/l
97%
-0,31
AX
3,85
mg/l
99%
-0,12
0,1232
0,17
AY
mg/l
AZ
mg/l
BA
4,49
0,43
BB
mg/l
115%
1,38
3,52
0,54
mg/l
90%
-0,89
BC
3,9
0,3
mg/l
100%
0,00
108%
0,70
98%
-0,21
82%
-1,68
*
BD
mg/l
BE
BF
mg/l
4,2
0,4
BG
BH
mg/l
mg/l
3,81
0,82
mg/l
BI
mg/l
BJ
mg/l
BK
mg/l
BL
BM
mg/l
3,18
mg/l
*
BN
mg/l
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
mg/l
All results
3,89 ± 0,14
99,9 ± 3,6
0,26
6,6
26
Outliers excl.
3,90 ± 0,11
100,0 ± 2,7
0,18
4,7
24
Unit
mg/l
%
mg/l
%
Sample N131A
Parameter Silicon
2,28 mg/l
±
0,05 mg/l
2,18 mg/l
±
0,17 mg/l
2,24 mg/l
±
0,18 mg/l
Lab Code
Result
±
Unit
Recovery
A
2,22
0,05
mg/l
97%
B
2,26
mg/l
99%
D
2,18
mg/l
96%
E
2,17
mg/l
95%
F
mg/l
2,15
mg/l
94%
H
2,2
0,1
mg/l
96%
I
2,26
0,05
mg/l
99%
J
2,17
mg/l
95%
K
2,28
mg/l
100%
L
2,24
mg/l
98%
M
2,1
mg/l
92%
0,1
N
mg/l
P
2,23
Q
2,15
0,2
mg/l
98%
mg/l
94%
R
mg/l
S
mg/l
T
mg/l
U
mg/l
V
3,31
45%
2,96
30%
2,62
15%
2,28
Target
value ±
U (k=2)
1,94
- 15%
1,60
- 30%
1,25
- 45%
z-Score
0,006
mg/l
mg/l
Z
99%
96%
mg/l
97%
AC
2,26
0,09
mg/l
99%
100
96%
90
AD
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Deviation
Recovery
mg/l
2,2
0,3
mg/l
AF
mg/l
AG
mg/l
AH
mg/l
2,36
0,24
AJ
mg/l
80
104%
70
mg/l
2,6
mg/l
*
AL
mg/l
AM
mg/l
AN
mg/l
AO
mg/l
2,11
0,12
AQ
mg/l
114%
*
0,05
mg/l
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
93%
mg/l
1,89
60
A
mg/l
AR
AS
K
J
110
mg/l
0,2
AP
I
H
120
2,21
AK
G
F
130
AB
AI
E
D
mg/l
AA
AE
C
B
140
mg/l
2,19
A
Recovery
[%]
mg/l
2,25
X
Y
45%
1,026
mg/l
O
W
Result
[mg/l]
30%
0,684
mg/l
C
G
15%
0,342
83%
AT
AU
mg/l
2,2752
0,2490
AV
mg/l
AW
2,2
AX
2,15
0,03
mg/l
96%
mg/l
94%
AY
mg/l
AZ
mg/l
BA
BB
mg/l
2,31
mg/l
BC
BD
2,2
0,06
mg/l
2,24
0,2
mg/l
mg/l
BH
mg/l
BI
98%
mg/l
2,59
*
0,65
BK
mg/l
114%
mg/l
BL
BM
96%
mg/l
BG
BJ
101%
mg/l
BE
BF
100%
mg/l
mg/l
2,72
mg/l
*
BN
mg/l
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
119%
mg/l
All results
2,25 ± 0,08
98,5 ± 3,5
0,16
7,0
30
Outliers excl.
2,21 ± 0,03
97,1 ± 1,4
0,06
2,7
26
Unit
mg/l
%
mg/l
%
Sample N131B
Parameter Silicon
4,56 mg/l
±
0,11 mg/l
4,39 mg/l
±
0,35 mg/l
4,47 mg/l
±
0,36 mg/l
Lab Code
Result
±
Unit
Recovery
A
4,47
0,05
mg/l
98%
B
4,46
mg/l
98%
D
4,37
mg/l
96%
E
4,39
mg/l
96%
F
mg/l
4,25
mg/l
4,4
0,1
mg/l
96%
I
4,67
0,08
mg/l
102%
J
4,38
mg/l
96%
K
4,58
mg/l
100%
L
4,60
mg/l
101%
M
4,2
mg/l
92%
0,1
N
6,61
45%
5,93
30%
5,24
15%
4,56
Target
value ±
U (k=2)
3,88
- 15%
3,19
- 30%
2,51
- 45%
z-Score
mg/l
O
mg/l
P
4,51
Q
4,29
0,2
mg/l
99%
mg/l
94%
R
mg/l
S
mg/l
T
mg/l
U
mg/l
V
0,03
mg/l
mg/l
Z
99%
97%
mg/l
96%
AC
4,51
0,18
mg/l
99%
100
94%
90
AD
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
Deviation
Recovery
mg/l
4,3
0,5
mg/l
AF
mg/l
AG
mg/l
AH
mg/l
4,64
0,46
AJ
mg/l
80
102%
70
mg/l
6,4
mg/l
*
AL
mg/l
AM
mg/l
AN
mg/l
AO
mg/l
4,22
0,21
AQ
mg/l
140%
0,05
mg/l
C
B
E
D
G
F
I
H
K
J
M
L
O
N
Q
P
S
R
U
T
W
V
Y
X
Z
Laboratories
93%
mg/l
4,02
60
A
mg/l
AR
AS
K
J
110
mg/l
0,4
AP
I
H
120
4,37
AK
G
F
130
AB
AI
E
D
mg/l
AA
AE
C
B
140
mg/l
4,44
A
Recovery
[%]
mg/l
4,53
X
Y
45%
2,052
93%
H
W
Result
[mg/l]
30%
1,368
mg/l
C
G
15%
0,684
88%
AT
AU
mg/l
4,7503
0,2686
AV
mg/l
AW
4,5
AX
4,23
0,03
mg/l
99%
mg/l
93%
AY
mg/l
AZ
mg/l
BA
BB
mg/l
4,80
mg/l
BC
BD
4,2
0,06
mg/l
4,53
0,4
mg/l
mg/l
BH
mg/l
BI
99%
mg/l
5,14
1,3
BK
mg/l
113%
mg/l
BL
BM
92%
mg/l
BG
BJ
105%
mg/l
BE
BF
104%
mg/l
mg/l
11,4
mg/l
*
BN
mg/l
BO
mg/l
BP
Mean ± CI(99%)
Recov. ± CI(99%)
SD between labs
RSD between labs
n for calculation
250%
mg/l
All results
4,75 ± 0,67
104,2 ± 14,6
1,32
27,8
30
Outliers excl.
4,46 ± 0,12
97,7 ± 2,6
0,22
5,0
28
Unit
mg/l
%
mg/l
%
Illustration of Results
Laboratory Oriented Part
Round N131
Major Ions
Sample Dispatch: 14 March 2016
Sample
N131A
Laboratory A
Parameter
Recovery
[%]
Result
±
Unit
Recovery
486
3
µS/cm
101%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
1,72
0,05
mmol/l
96%
Hydrogen carbonate
106
1
102
3
mg/l
96%
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
°d
mg/l
0,039
0,003
mg/l
<0,02
0,01
mg/l
98%
•
41,9
2
mg/l
100%
0,088
0,003
mg/l
mg/l
98%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
0,150
0,003
mg/l
101%
mg/l
2,22
0,05
mg/l
97%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Hydrogen carbonateMagnesium
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Conductivity Alkalinity
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Boron Total P (as PO4)
Silicon
Sample
N131B
Laboratory A
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
361
3
µS/cm
°d
101%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,83
170
0,05
3
mmol/l
mg/l
96%
96%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
0,083
0,003
mg/l
mg/l
100%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,05
7,8
0,01
2
mg/l
mg/l
100%
97%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,072
0,003
mg/l
mg/l
101%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,074
0,003
mg/l
mg/l
97%
Silicon
4,56
0,11
4,47
0,05
mg/l
98%
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory B
Parameter
Recovery
[%]
Result
±
Unit
Recovery
483
5
µS/cm
101%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
°d
1,77
0,05
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
99%
mg/l
0,041
0,01
mg/l
103%
<0,025
0,01
mg/l
•
0,5
Sulphate
mmol/l
mg/l
mg/l
0,089
0,01
mg/l
99%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
0,147
0,01
mg/l
99%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory B
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
359
5
µS/cm
°d
101%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,88
0,05
mmol/l
mg/l
97%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
Ammonium
Chloride
0,050
8,02
0,001
0,02
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
Silicon
4,56
0,11
0,083
0,01
0,054
0,01
0,070
0,01
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
100%
108%
99%
mg/l
mg/l
0,081
0,01
mg/l
mg/l
107%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory C
Parameter
Recovery
[%]
Result
Unit
Recovery
µS/cm
98%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
46,3
mg/l
92%
Nitrite
0,040
0,001
0,0401
mg/l
100%
Ammonium
<0,01
<0,03
mg/l
•
Chloride
42,1
43,4
mg/l
103%
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
471
±
°d
1,76
mmol/l
98%
mg/l
mg/l
0,0954
mg/l
106%
mg/l
DOC
4,06
0,05
4,42
mg/l
109%
Total P (as PO4)
0,148
0,002
0,141
mg/l
95%
KMnO4-Index
3,40
0,09
3,30
mg/l
97%
Silicon
2,28
0,05
2,26
mg/l
99%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory C
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
348
µS/cm
°d
98%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,91
mmol/l
mg/l
98%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,20
0,0811
mg/l
mg/l
86%
98%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,043
9,1
mg/l
mg/l
86%
113%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,0745
mg/l
mg/l
105%
Boron
DOC
0,071
2,63
0,001
0,04
3,05
mg/l
mg/l
116%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,0819
4,23
mg/l
mg/l
108%
108%
Silicon
4,56
0,11
4,46
mg/l
98%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory D
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
490
µS/cm
102%
Total hardness
9,47
0,07
9,52
°d
101%
Alkalinity
1,79
0,01
1,75
mmol/l
98%
Hydrogen carbonate
106
1
103,7
mg/l
98%
Calcium
37,5
0,3
38,1
mg/l
102%
Magnesium
18,3
0,2
18,0
mg/l
98%
Sodium
26,8
0,2
27,0
mg/l
101%
Potassium
2,52
0,03
2,31
mg/l
92%
Nitrate
50,5
1,0
47,2
mg/l
93%
Nitrite
0,040
0,001
0,045
mg/l
113%
Ammonium
<0,01
<0,020
mg/l
•
Chloride
42,1
42,5
mg/l
101%
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
mg/l
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
0,139
mg/l
94%
KMnO4-Index
3,40
0,09
3,48
mg/l
102%
Silicon
2,28
0,05
2,18
mg/l
96%
0,087
mg/l
97%
<0,05
mg/l
•
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory D
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
360
5,43
µS/cm
°d
101%
101%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,89
173,3
mmol/l
mg/l
98%
98%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,8
6,62
mg/l
mg/l
101%
98%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,3
7,70
mg/l
mg/l
99%
102%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,56
0,088
mg/l
mg/l
94%
106%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,051
7,8
mg/l
mg/l
102%
97%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,073
mg/l
mg/l
103%
Boron
DOC
0,071
2,63
0,001
0,04
0,097
mg/l
mg/l
137%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,076
3,96
mg/l
mg/l
100%
102%
Silicon
4,56
0,11
4,37
mg/l
96%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory E
Parameter
Recovery
[%]
Result
478
±
Unit
Recovery
µS/cm
100%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
°d
1,78
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
99%
mg/l
0,0403
mg/l
101%
<0,03
mg/l
•
0,5
Sulphate
mmol/l
mg/l
mg/l
0,0907
mg/l
101%
mg/l
DOC
4,06
0,05
4,22
mg/l
104%
Total P (as PO4)
0,148
0,002
0,146
mg/l
99%
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
2,17
mg/l
95%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory E
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
355
µS/cm
°d
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,97
mmol/l
mg/l
100%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
Ammonium
Chloride
0,050
8,02
0,001
0,02
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,0754
mg/l
mg/l
99%
Silicon
4,56
0,11
4,39
mg/l
96%
0,0836
0,049
mg/l
mg/l
mg/l
mg/l
101%
98%
0,0720
mg/l
mg/l
101%
2,84
mg/l
mg/l
108%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory F
Parameter
Recovery
[%]
Result
±
Unit
Recovery
437
5
µS/cm
91%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
°d
1,73
0,1
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
97%
mg/l
0,041
0,005
mg/l
103%
<0,01
0,005
mg/l
•
0,5
Sulphate
mmol/l
mg/l
mg/l
0,087
0,005
mg/l
97%
mg/l
DOC
4,06
0,05
mg/l
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory F
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
323
5
µS/cm
°d
91%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,85
0,1
mmol/l
mg/l
96%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
Ammonium
Chloride
0,050
8,02
0,001
0,02
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
Boron
DOC
0,071
2,63
0,001
0,04
mg/l
mg/l
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
mg/l
mg/l
Silicon
4,56
0,11
mg/l
0,086
0,005
0,054
0,005
0,072
0,005
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
104%
108%
101%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory G
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
476
µS/cm
99%
Total hardness
9,47
0,07
9,24
°d
98%
Alkalinity
1,79
0,01
1,75
mmol/l
98%
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
49,55
mg/l
98%
Nitrite
0,040
0,001
0,0401
mg/l
100%
Ammonium
<0,01
<0,026
mg/l
•
Chloride
42,1
42,08
mg/l
100%
0,5
mg/l
Sulphate
39,4
0,5
39,33
mg/l
100%
Orthophosphate
0,090
0,001
0,0837
mg/l
93%
Boron
<0,02
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
0,1396
mg/l
94%
mg/l
2,15
mg/l
94%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory G
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
356
5,60
µS/cm
°d
100%
104%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,90
mmol/l
mg/l
98%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,76
0,0803
mg/l
mg/l
98%
97%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,062
8,58
mg/l
mg/l
124%
107%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
23,01
0,0690
mg/l
mg/l
101%
97%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,0758
mg/l
mg/l
100%
Silicon
4,56
0,11
4,25
mg/l
93%
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory H
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
483
14
µS/cm
101%
Total hardness
9,47
0,07
9,33
0,8
°d
99%
Alkalinity
1,79
0,01
1,78
0,07
mmol/l
99%
Hydrogen carbonate
106
1
109
4
mg/l
103%
Calcium
37,5
0,3
37
4
mg/l
99%
Magnesium
18,3
0,2
18
1
mg/l
98%
Sodium
26,8
0,2
27
2
mg/l
101%
Potassium
2,52
0,03
2,5
0,2
mg/l
99%
Nitrate
50,5
1,0
49
2
mg/l
97%
Nitrite
0,040
0,001
0,042
0,003
mg/l
105%
Ammonium
<0,01
<0,030
0,004
mg/l
•
Chloride
42,1
42
1
mg/l
100%
0,5
Sulphate
39,4
0,5
39
2
mg/l
99%
Orthophosphate
0,090
0,001
0,089
0,009
mg/l
99%
Boron
<0,02
<0,002
0,001
mg/l
•
DOC
4,06
0,05
4,0
0,2
mg/l
99%
Total P (as PO4)
0,148
0,002
0,15
0,01
mg/l
101%
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
2,2
0,1
mg/l
96%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory H
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
360
5,46
11
0,5
µS/cm
°d
101%
101%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,92
178
0,12
7
mmol/l
mg/l
99%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28
6,7
3
0,4
mg/l
mg/l
102%
100%
Sodium
Potassium
36,8
7,55
0,3
0,04
36
7,5
2
0,5
mg/l
mg/l
98%
99%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,7
0,089
0,1
0,005
mg/l
mg/l
97%
107%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,062
8,0
0,008
0,2
mg/l
mg/l
124%
100%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
22
0,070
1
0,007
mg/l
mg/l
96%
99%
Boron
DOC
0,071
2,63
0,001
0,04
0,072
2,7
0,01
0,2
mg/l
mg/l
101%
103%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,077
0,005
mg/l
mg/l
101%
Silicon
4,56
0,11
4,4
0,1
mg/l
96%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory I
Parameter
Recovery
[%]
Result
±
Unit
Recovery
480
5
µS/cm
100%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
50,0
0,8
mg/l
99%
Nitrite
0,040
0,001
0,039
0,002
mg/l
98%
Ammonium
<0,01
<0,03
0,01
mg/l
•
Chloride
42,1
42,4
3
mg/l
101%
0,096
0,003
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
°d
1,79
0,05
mmol/l
100%
mg/l
mg/l
mg/l
107%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
0,142
0,005
mg/l
mg/l
96%
KMnO4-Index
3,40
0,09
3,5
0,1
mg/l
103%
Silicon
2,28
0,05
2,26
0,05
mg/l
99%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory I
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
359
5
µS/cm
°d
101%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,95
0,05
mmol/l
mg/l
100%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,7
0,082
0,1
0,003
mg/l
mg/l
97%
99%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,06
7,9
0,01
1
mg/l
mg/l
120%
99%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,080
0,003
mg/l
mg/l
113%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,075
4,0
0,003
0,1
mg/l
mg/l
99%
103%
Silicon
4,56
0,11
4,67
0,08
mg/l
102%
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory J
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
477
µS/cm
100%
Total hardness
9,47
0,07
9,4
°d
99%
Alkalinity
1,79
0,01
1,61
mmol/l
90%
Hydrogen carbonate
106
1
98
mg/l
92%
Calcium
37,5
0,3
37,7
mg/l
101%
Magnesium
18,3
0,2
17,9
mg/l
98%
Sodium
26,8
0,2
Potassium
2,52
0,03
Nitrate
50,5
1,0
49,1
mg/l
97%
Nitrite
0,040
0,001
0,043
mg/l
108%
Ammonium
<0,01
0,002
mg/l
•
Chloride
42,1
43,8
mg/l
104%
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
mg/l
mg/l
mg/l
0,108
mg/l
120%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
0,153
mg/l
103%
mg/l
2,17
mg/l
95%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory J
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
355
5,5
µS/cm
°d
100%
102%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,77
169
mmol/l
mg/l
94%
95%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,5
7,2
mg/l
mg/l
100%
107%
Sodium
Potassium
36,8
7,55
0,3
0,04
Nitrate
Nitrite
4,87
0,083
0,11
0,001
3,8
0,085
mg/l
mg/l
78%
102%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,054
9,6
mg/l
mg/l
108%
120%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,082
mg/l
mg/l
115%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,088
mg/l
mg/l
116%
Silicon
4,56
0,11
4,38
mg/l
96%
mg/l
mg/l
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory K
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
485
µS/cm
101%
Total hardness
9,47
0,07
9,5
°d
100%
Alkalinity
1,79
0,01
1,77
mmol/l
99%
Hydrogen carbonate
106
1
Calcium
37,5
0,3
38,1
mg/l
102%
Magnesium
18,3
0,2
18,0
mg/l
98%
Sodium
26,8
0,2
Potassium
2,52
0,03
Nitrate
50,5
1,0
46,4
mg/l
92%
Nitrite
0,040
0,001
0,038
mg/l
95%
Ammonium
<0,01
<0,01
mg/l
•
Chloride
42,1
42
mg/l
100%
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
mg/l
mg/l
mg/l
mg/l
0,092
mg/l
102%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
0,146
mg/l
99%
mg/l
2,28
mg/l
100%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory K
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
355
5,4
µS/cm
°d
100%
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,90
mmol/l
mg/l
98%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,7
6,8
mg/l
mg/l
101%
101%
Sodium
Potassium
36,8
7,55
0,3
0,04
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,82
0,078
mg/l
mg/l
99%
94%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,055
8,0
mg/l
mg/l
110%
100%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,073
mg/l
mg/l
103%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,074
mg/l
mg/l
97%
Silicon
4,56
0,11
4,58
mg/l
100%
mg/l
mg/l
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory L
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
479
10
µS/cm
100%
Total hardness
9,47
0,07
9,2
0,1
°d
97%
Alkalinity
1,79
0,01
1,77
0,05
mmol/l
99%
Hydrogen carbonate
106
1
108
mg/l
102%
Calcium
37,5
0,3
36,9
1
mg/l
98%
Magnesium
18,3
0,2
17,7
1
mg/l
97%
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
mg/l
0,042
0,005
<0,02
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
41,2
1
0,090
0,005
mg/l
105%
mg/l
•
mg/l
98%
mg/l
mg/l
100%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
0,147
0,005
mg/l
mg/l
99%
KMnO4-Index
3,40
0,09
3,48
0,2
mg/l
102%
Silicon
2,28
0,05
2,24
0,1
mg/l
98%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory L
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
356
5,3
10
0,1
µS/cm
°d
100%
98%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,92
178
0,05
mmol/l
mg/l
99%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
26,9
6,8
1
0,5
mg/l
mg/l
98%
101%
Sodium
Potassium
36,8
7,55
0,3
0,04
Nitrate
Nitrite
4,87
0,083
0,11
0,001
0,086
0,005
mg/l
mg/l
104%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,048
8,2
0,005
0,5
mg/l
mg/l
96%
102%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,071
0,005
mg/l
mg/l
100%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,079
4,00
0,005
0,2
mg/l
mg/l
104%
103%
Silicon
4,56
0,11
4,60
0,1
mg/l
101%
mg/l
mg/l
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory M
Parameter
Recovery
[%]
Result
474
±
Unit
Recovery
µS/cm
99%
Conductivity
479
1
Total hardness
9,47
0,07
°d
Alkalinity
1,79
0,01
mmol/l
Hydrogen carbonate
106
1
Calcium
37,5
0,3
37,4
mg/l
100%
Magnesium
18,3
0,2
17,0
mg/l
93%
Sodium
26,8
0,2
Potassium
2,52
0,03
Nitrate
50,5
1,0
47
mg/l
93%
Nitrite
0,040
0,001
0,041
mg/l
103%
Ammonium
<0,01
<0,03
mg/l
•
Chloride
42,1
mg/l
mg/l
mg/l
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
mg/l
mg/l
0,092
mg/l
102%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
0,138
mg/l
93%
mg/l
2,1
mg/l
92%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory M
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
352
µS/cm
°d
99%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,85
mmol/l
mg/l
96%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,4
0,082
mg/l
mg/l
90%
99%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,05
8
mg/l
mg/l
100%
100%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,070
mg/l
mg/l
99%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,071
mg/l
mg/l
93%
Silicon
4,56
0,11
4,2
mg/l
92%
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory N
Parameter
Recovery
[%]
Result
±
486
Unit
Recovery
µS/cm
101%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
50,0
0,502
mg/l
99%
Nitrite
0,040
0,001
0,041
0,0004
mg/l
103%
Ammonium
<0,01
mg/l
•
Chloride
42,1
°d
1,77
0,018
<0,03
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
99%
mg/l
0,5
Sulphate
mmol/l
mg/l
mg/l
0,098
0,002
mg/l
109%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
0,168
0,003
mg/l
114%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory N
Parameter
Recovery
[%]
Result
±
Unit
Recovery
µS/cm
°d
101%
mmol/l
mg/l
99%
Conductivity
Total hardness
356
5,40
1
0,05
359
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,92
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,85
0,085
0,049
0,0009
mg/l
mg/l
100%
102%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,044
0,0028
mg/l
mg/l
88%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,076
0,001
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
Silicon
4,56
0,11
0,029
mg/l
mg/l
107%
mg/l
mg/l
0,100
0,002
mg/l
mg/l
132%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory O
Parameter
Recovery
[%]
Result
487
±
Unit
Recovery
µS/cm
102%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
°d
1,68
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
94%
mg/l
0,039
mg/l
98%
<0,02
mg/l
•
0,5
Sulphate
mmol/l
mg/l
mg/l
0,090
mg/l
100%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
0,153
mg/l
103%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory O
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
358
µS/cm
°d
101%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,68
mmol/l
mg/l
91%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
Ammonium
Chloride
0,050
8,02
0,001
0,02
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
Silicon
4,56
0,11
0,082
0,060
0,070
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
99%
120%
99%
mg/l
mg/l
0,079
mg/l
mg/l
104%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory P
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
474
5
µS/cm
99%
Total hardness
9,47
0,07
9,49
0,2
°d
100%
Alkalinity
1,79
0,01
1,74
0,1
mmol/l
97%
Hydrogen carbonate
106
1
106,3
5
mg/l
100%
Calcium
37,5
0,3
38,3
1
mg/l
102%
Magnesium
18,3
0,2
18,0
0,5
mg/l
98%
Sodium
26,8
0,2
Potassium
2,52
0,03
Nitrate
50,5
1,0
47
2
mg/l
93%
Nitrite
0,040
0,001
0,041
0,05
mg/l
103%
Ammonium
<0,01
<0,02
0,02
mg/l
•
Chloride
42,1
41,9
2
mg/l
100%
0,091
0,01
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
mg/l
mg/l
mg/l
mg/l
101%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
0,148
0,01
mg/l
mg/l
100%
KMnO4-Index
3,40
0,09
3,4
0,1
mg/l
100%
Silicon
2,28
0,05
2,23
0,2
mg/l
98%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory P
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
358
5,43
5
0,2
µS/cm
°d
101%
101%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,89
176,5
0,1
5
mmol/l
mg/l
98%
100%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,0
6,6
1
0,5
mg/l
mg/l
102%
98%
Sodium
Potassium
36,8
7,55
0,3
0,04
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,5
0,084
2
0,05
mg/l
mg/l
92%
101%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,05
7,9
0,02
2
mg/l
mg/l
100%
99%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,070
0,01
mg/l
mg/l
99%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,077
3,9
0,01
0,1
mg/l
mg/l
101%
100%
Silicon
4,56
0,11
4,51
0,2
mg/l
99%
mg/l
mg/l
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory Q
Parameter
Recovery
[%]
Result
Unit
Recovery
µS/cm
100%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
49,3
mg/l
98%
Nitrite
0,040
0,001
0,040
mg/l
100%
Ammonium
<0,01
0,010
mg/l
•
Chloride
42,1
41,1
mg/l
98%
0,5
480
±
°d
1,76
mmol/l
98%
mg/l
Sulphate
39,4
0,5
38,3
mg/l
97%
Orthophosphate
0,090
0,001
0,076
mg/l
84%
Boron
<0,02
mg/l
DOC
4,06
0,05
3,99
mg/l
98%
Total P (as PO4)
0,148
0,002
0,144
mg/l
97%
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
2,15
mg/l
94%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory Q
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
356
µS/cm
°d
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,94
mmol/l
mg/l
99%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,75
0,082
mg/l
mg/l
98%
99%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,056
8,33
mg/l
mg/l
112%
104%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
21,5
0,061
mg/l
mg/l
94%
86%
Boron
DOC
0,071
2,63
0,001
0,04
2,31
mg/l
mg/l
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,087
mg/l
mg/l
114%
Silicon
4,56
0,11
4,29
mg/l
94%
88%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory R
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
479
10
µS/cm
100%
Total hardness
9,47
0,07
9,4
0,9
°d
99%
Alkalinity
1,79
0,01
1,78
0,2
mmol/l
99%
Hydrogen carbonate
106
1
109
11
mg/l
103%
Calcium
37,5
0,3
36,6
3,7
mg/l
98%
Magnesium
18,3
0,2
18,5
1,9
mg/l
101%
Sodium
26,8
0,2
26,4
2,6
mg/l
99%
Potassium
2,52
0,03
2,42
0,24
mg/l
96%
Nitrate
50,5
1,0
49,2
4,9
mg/l
97%
Nitrite
0,040
0,001
0,040
0,010
mg/l
100%
Ammonium
<0,01
Chloride
42,1
mg/l
•
0,5
<0,010
41,1
4,1
mg/l
98%
38,8
3,9
mg/l
98%
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
mg/l
mg/l
mg/l
3,25
0,5
mg/l
96%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory R
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
357
5,3
10
0,5
µS/cm
°d
100%
98%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,90
177
0,3
18
mmol/l
mg/l
98%
100%
Calcium
Magnesium
27,5
6,73
0,3
0,08
26,7
6,76
2,7
0,68
mg/l
mg/l
97%
100%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,1
7,20
3,6
0,72
mg/l
mg/l
98%
95%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,7
0,084
0,5
0,010
mg/l
mg/l
97%
101%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,048
7,8
0,010
0,8
mg/l
mg/l
96%
97%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
22,1
2,2
mg/l
mg/l
97%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
Silicon
4,56
0,11
mg/l
mg/l
3,76
0,5
mg/l
mg/l
96%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory S
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
484
10
µS/cm
101%
Total hardness
9,47
0,07
9,11
0,91
°d
96%
Alkalinity
1,79
0,01
1,78
0,11
mmol/l
99%
Hydrogen carbonate
106
1
108
6,5
mg/l
102%
Calcium
37,5
0,3
35,1
3,6
mg/l
94%
Magnesium
18,3
0,2
18,3
1,9
mg/l
100%
Sodium
26,8
0,2
27,1
2,8
mg/l
101%
Potassium
2,52
0,03
2,38
0,28
mg/l
94%
Nitrate
50,5
1,0
48,2
2,2
mg/l
95%
Nitrite
0,040
0,001
0,041
0,002
mg/l
103%
Ammonium
<0,01
<0,025
0,007
mg/l
•
Chloride
42,1
41,9
2,2
mg/l
100%
0,5
Sulphate
39,4
0,5
38,5
1,7
mg/l
98%
Orthophosphate
0,090
0,001
0,094
0,005
mg/l
104%
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
mg/l
mg/l
3,20
0,32
mg/l
94%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory S
Parameter
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
363
5,13
7
0,51
µS/cm
°d
102%
95%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,93
179
0,18
10,7
mmol/l
mg/l
99%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
26,0
6,53
2,7
0,67
mg/l
mg/l
95%
97%
Sodium
Potassium
36,8
7,55
0,3
0,04
37,9
7,43
3,9
0,88
mg/l
mg/l
103%
98%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,73
0,084
0,21
0,004
mg/l
mg/l
97%
101%
Ammonium
Chloride
0,050
8,02
0,001
0,02
<0,025
7,78
0,007
0,41
mg/l
mg/l
FN
97%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
22,2
0,076
0,95
0,004
mg/l
mg/l
97%
107%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
Silicon
4,56
0,11
mg/l
mg/l
3,86
0,38
mg/l
mg/l
99%
mg/l
Recovery
[%]
Deviation
Recovery
140
130
120
110
100
FN
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory T
Parameter
Recovery
[%]
Result
±
Unit
Recovery
4,51
µS/cm
100%
°d
104%
mmol/l
103%
mg/l
104%
Conductivity
479
1
481
Total hardness
9,47
0,07
9,83
Alkalinity
1,79
0,01
1,85
Hydrogen carbonate
106
1
109,81
Calcium
37,5
0,3
39,38
3,9
mg/l
105%
Magnesium
18,3
0,2
18,77
1,9
mg/l
103%
Sodium
26,8
0,2
26,57
2,7
mg/l
99%
Potassium
2,52
0,03
2,54
0,27
mg/l
101%
0,19
Nitrate
50,5
1,0
46,88
3,9
mg/l
93%
Nitrite
0,040
0,001
0,040
0,004
mg/l
100%
Ammonium
<0,01
Chloride
42,1
<0,009
0,5
39,71
mg/l
•
4,0
mg/l
94%
Sulphate
39,4
0,5
37,15
3,7
mg/l
94%
Orthophosphate
0,090
0,001
0,098
0,009
mg/l
109%
Boron
<0,02
DOC
4,06
0,05
3,91
0,39
mg/l
96%
Total P (as PO4)
0,148
0,002
0,156
0,015
mg/l
105%
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory T
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
360
5,81
4,51
µS/cm
°d
101%
108%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
3,00
179,97
0,30
mmol/l
mg/l
101%
102%
Calcium
Magnesium
27,5
6,73
0,3
0,08
29,81
7,11
3,0
0,7
mg/l
mg/l
108%
106%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,32
7,82
3,6
0,81
mg/l
mg/l
99%
104%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,94
0,083
0,4
0,008
mg/l
mg/l
101%
100%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,055
7,63
0,005
0,8
mg/l
mg/l
110%
95%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
21,99
0,080
2,2
0,008
mg/l
mg/l
96%
113%
Boron
DOC
0,071
2,63
0,001
0,04
2,58
0,26
mg/l
mg/l
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,083
0,008
Silicon
4,56
0,11
mg/l
mg/l
98%
109%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory U
Parameter
Recovery
[%]
Result
±
Unit
Recovery
498
25
µS/cm
104%
Conductivity
479
1
Total hardness
9,47
0,07
°d
Alkalinity
1,79
0,01
mmol/l
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
48,7
4,9
mg/l
96%
Nitrite
0,040
0,001
0,048
0,013
mg/l
120%
Ammonium
<0,01
Chloride
42,1
mg/l
<0,012
0,5
41,0
mg/l
•
4,1
mg/l
97%
Sulphate
39,4
0,5
39,3
3,9
mg/l
100%
Orthophosphate
0,090
0,001
0,089
0,015
mg/l
99%
Boron
<0,02
mg/l
DOC
4,06
0,05
4,52
0,45
mg/l
111%
Total P (as PO4)
0,148
0,002
0,135
0,016
mg/l
91%
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory U
Parameter
Recovery
[%]
Result
±
Unit
Recovery
363
18
µS/cm
°d
102%
Conductivity
Total hardness
356
5,40
1
0,05
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
mmol/l
mg/l
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,75
0,092
0,48
0,026
mg/l
mg/l
98%
111%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,059
7,9
0,014
0,8
mg/l
mg/l
118%
99%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
22,6
0,072
2,3
0,012
mg/l
mg/l
99%
101%
Boron
DOC
0,071
2,63
0,001
0,04
3,03
0,30
mg/l
mg/l
115%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,073
0,009
Silicon
4,56
0,11
mg/l
mg/l
96%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory V
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
476
10
µS/cm
99%
Total hardness
9,47
0,07
9,2
0,9
°d
97%
Alkalinity
1,79
0,01
1,76
0,18
mmol/l
98%
Hydrogen carbonate
106
1
104
11
mg/l
98%
Calcium
37,5
0,3
36,1
3,6
mg/l
96%
Magnesium
18,3
0,2
18,2
1,8
mg/l
99%
Sodium
26,8
0,2
26,0
2,6
mg/l
97%
Potassium
2,52
0,03
2,36
0,24
mg/l
94%
Nitrate
50,5
1,0
49,13
4,9
mg/l
97%
Nitrite
0,040
0,001
0,039
0,010
mg/l
98%
Ammonium
<0,01
Chloride
42,1
<0,010
0,5
40,92
mg/l
•
4,1
mg/l
97%
Sulphate
39,4
0,5
38,8
3,9
mg/l
98%
Orthophosphate
0,090
0,001
0,089
0,009
mg/l
99%
Boron
<0,02
mg/l
DOC
4,06
0,05
4,006
0,40
mg/l
99%
Total P (as PO4)
0,148
0,002
0,141
0,014
mg/l
95%
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory V
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
350
5,2
10
0,5
µS/cm
°d
98%
96%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,91
178
0,29
18
mmol/l
mg/l
98%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
26,5
6,69
2,7
0,70
mg/l
mg/l
96%
99%
Sodium
Potassium
36,8
7,55
0,3
0,04
35,6
7,12
3,6
0,72
mg/l
mg/l
97%
94%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,72
0,082
0,5
0,010
mg/l
mg/l
97%
99%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,049
7,83
0,010
0,8
mg/l
mg/l
98%
98%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
22,1
0,074
2,2
0,007
mg/l
mg/l
97%
104%
Boron
DOC
0,071
2,63
0,001
0,04
2,719
0,27
mg/l
mg/l
103%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,080
0,008
Silicon
4,56
0,11
mg/l
mg/l
105%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory W
Parameter
Recovery
[%]
Result
±
Unit
Recovery
102%
Conductivity
479
1
487
4,0
µS/cm
Total hardness
9,47
0,07
9,36
0,03
°d
99%
Alkalinity
1,79
0,01
1,81
0,023
mmol/l
101%
Hydrogen carbonate
106
1
108
1,2
mg/l
102%
Calcium
37,5
0,3
37,6
0,10
mg/l
100%
Magnesium
18,3
0,2
18,3
0,06
mg/l
100%
Sodium
26,8
0,2
26,6
0,12
mg/l
99%
Potassium
2,52
0,03
2,47
0,03
mg/l
98%
Nitrate
50,5
1,0
48,1
0,30
mg/l
95%
Nitrite
0,040
0,001
0,040
0,0006
mg/l
100%
Ammonium
<0,01
Chloride
42,1
<0,010
0,5
42,0
mg/l
•
0,16
mg/l
100%
Sulphate
39,4
0,5
38,7
0,04
mg/l
98%
Orthophosphate
0,090
0,001
0,088
0,0002
mg/l
98%
Boron
<0,02
DOC
4,06
0,05
4,19
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
<0,010
mg/l
•
0,16
mg/l
103%
0,139
0,003
mg/l
94%
3,17
0,05
mg/l
93%
2,25
0,006
mg/l
99%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory W
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
353
5,37
2,6
0,006
µS/cm
°d
99%
99%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,99
197
0,006
0,58
mmol/l
mg/l
101%
111%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,6
6,77
0,06
0,01
mg/l
mg/l
100%
101%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,3
7,29
0,30
0,04
mg/l
mg/l
99%
97%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
3,90
0,083
0,06
0,0005
mg/l
mg/l
80%
100%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,048
7,66
0,0006
0,05
mg/l
mg/l
96%
96%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
22,0
0,0687
0,05
0,0005
mg/l
mg/l
96%
97%
Boron
DOC
0,071
2,63
0,001
0,04
0,072
2,68
0,001
0,07
mg/l
mg/l
101%
102%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,072
3,80
0,001
0,18
mg/l
mg/l
95%
97%
Silicon
4,56
0,11
4,53
0,03
mg/l
99%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory X
Parameter
Recovery
[%]
Result
±
Unit
Recovery
101%
Conductivity
479
1
484
14,5
µS/cm
Total hardness
9,47
0,07
9,3
1,4
°d
98%
Alkalinity
1,79
0,01
1,8
0,18
mmol/l
101%
Hydrogen carbonate
106
1
107
10,70
mg/l
101%
Calcium
37,5
0,3
37,6
5,6
mg/l
100%
Magnesium
18,3
0,2
17,5
2,6
mg/l
96%
Sodium
26,8
0,2
26,3
3,9
mg/l
98%
Potassium
2,52
0,03
2,51
0,4
mg/l
100%
Nitrate
50,5
1,0
45,2
6,8
mg/l
90%
Nitrite
0,040
0,001
0,04
0,006
mg/l
100%
Ammonium
<0,01
Chloride
42,1
0,009
0,001
mg/l
•
0,5
38,9
5,8
mg/l
92%
Sulphate
39,4
0,5
36,60
5,5
mg/l
93%
Orthophosphate
0,090
0,001
0,095
0,014
mg/l
106%
Boron
<0,02
mg/l
•
DOC
4,06
0,05
4,40
0,66
mg/l
108%
Total P (as PO4)
0,148
0,002
0,137
0,021
mg/l
93%
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
<0,02
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory X
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
362
5,4
10,9
0,8
µS/cm
°d
102%
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,88
173
0,29
17,30
mmol/l
mg/l
97%
98%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,3
6,3
4,2
0,9
mg/l
mg/l
103%
94%
Sodium
Potassium
36,8
7,55
0,3
0,04
34,4
8,15
5,2
1,2
mg/l
mg/l
93%
108%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,2
0,086
0,6
0,013
mg/l
mg/l
86%
104%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,055
7,70
0,008
1,2
mg/l
mg/l
110%
96%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
21,8
0,077
3,3
0,012
mg/l
mg/l
96%
108%
Boron
DOC
0,071
2,63
0,001
0,04
0,063
2,50
0,009
0,38
mg/l
mg/l
89%
95%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,077
0,012
mg/l
mg/l
101%
Silicon
4,56
0,11
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory Y
Parameter
Recovery
[%]
Result
±
459
Unit
Recovery
µS/cm
96%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
1,75
mmol/l
98%
Hydrogen carbonate
106
1
106,75
mg/l
101%
Calcium
37,5
0,3
37,10
0,37
mg/l
99%
Magnesium
18,3
0,2
18,03
0,23
mg/l
99%
Sodium
26,8
0,2
26,06
0,04
mg/l
97%
Potassium
2,52
0,03
2,36
0,06
mg/l
94%
Nitrate
50,5
1,0
54,31
0,07
mg/l
108%
Nitrite
0,040
0,001
0,04
0,00
mg/l
100%
Ammonium
<0,01
0,01
0,00
mg/l
•
Chloride
42,1
0,5
41,15
0,03
mg/l
98%
°d
Sulphate
39,4
0,5
41,47
0,04
mg/l
105%
Orthophosphate
0,090
0,001
0,07
0,01
mg/l
78%
Boron
<0,02
mg/l
DOC
4,06
0,05
4,51
0,04
mg/l
111%
Total P (as PO4)
0,148
0,002
0,13
0,00
mg/l
88%
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
2,19
mg/l
96%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory Y
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
344
µS/cm
°d
97%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,92
178,12
mmol/l
mg/l
99%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
32,94
6,19
5,02
0,05
mg/l
mg/l
120%
92%
Sodium
Potassium
36,8
7,55
0,3
0,04
35,44
35,44
0,22
0,22
mg/l
mg/l
96%
469%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,47
0,08
0,07
0,00
mg/l
mg/l
92%
96%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,04
8,69
0,01
0,10
mg/l
mg/l
80%
108%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
24,57
0,06
0,13
0,01
mg/l
mg/l
108%
85%
Boron
DOC
0,071
2,63
0,001
0,04
3,12
0,02
mg/l
mg/l
119%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,07
0,00
Silicon
4,56
0,11
4,44
mg/l
mg/l
92%
mg/l
97%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory Z
Parameter
Recovery
[%]
Result
±
Unit
Conductivity
479
1
Total hardness
9,47
0,07
°d
Alkalinity
1,79
0,01
mmol/l
µS/cm
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
mg/l
>35
mg/l
<0,01
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
•
mg/l
mg/l
0,5
Sulphate
Recovery
•
mg/l
mg/l
0,082
mg/l
91%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
0,109
0,004
mg/l
74%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory Z
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
µS/cm
°d
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
mmol/l
mg/l
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
3,81
0,15
mg/l
mg/l
78%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,054
0
mg/l
mg/l
108%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,066
0,024
Boron
DOC
0,071
2,63
0,001
0,04
mg/l
mg/l
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
mg/l
mg/l
Silicon
4,56
0,11
mg/l
mg/l
mg/l
93%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AA
Parameter
Recovery
[%]
Result
Unit
Recovery
µS/cm
100%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
1,79
mmol/l
100%
Hydrogen carbonate
106
1
106
mg/l
100%
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
49,6
mg/l
98%
Nitrite
0,040
0,001
0,041
mg/l
103%
Ammonium
<0,01
<0,005
mg/l
•
Chloride
42,1
41,5
mg/l
99%
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
478
±
°d
mg/l
mg/l
0,086
mg/l
96%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
0,143
mg/l
97%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AA
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
356
µS/cm
°d
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,96
177
mmol/l
mg/l
100%
100%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,70
0,084
mg/l
mg/l
97%
101%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,047
7,63
mg/l
mg/l
94%
95%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
0,070
mg/l
mg/l
99%
Boron
DOC
0,071
2,63
0,001
0,04
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
Silicon
4,56
0,11
mg/l
mg/l
0,077
mg/l
mg/l
101%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AB
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
478
20
µS/cm
100%
Total hardness
9,47
0,07
9,31
0,4
°d
98%
Alkalinity
1,79
0,01
1,77
0,1
mmol/l
99%
Hydrogen carbonate
106
1
105
4
mg/l
99%
Calcium
37,5
0,3
37,1
3
mg/l
99%
Magnesium
18,3
0,2
17,9
2,2
mg/l
98%
Sodium
26,8
0,2
26,4
4
mg/l
99%
Potassium
2,52
0,03
2,48
0,4
mg/l
98%
Nitrate
50,5
1,0
50,9
4
mg/l
101%
Nitrite
0,040
0,001
0,041
0,004
mg/l
103%
Ammonium
<0,01
Chloride
42,1
<0,013
0,5
42,6
mg/l
•
4
mg/l
101%
Sulphate
39,4
0,5
39,3
3
mg/l
100%
Orthophosphate
0,090
0,001
0,085
0,012
mg/l
94%
Boron
<0,02
mg/l
DOC
4,06
0,05
4,16
0,7
mg/l
102%
Total P (as PO4)
0,148
0,002
0,146
0,02
mg/l
99%
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
2,21
0,2
mg/l
97%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AB
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
356
5,31
15
0,3
µS/cm
°d
100%
98%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,79
167
0,1
6
mmol/l
mg/l
94%
94%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,2
6,57
3
0,8
mg/l
mg/l
99%
98%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,1
7,55
6
1,2
mg/l
mg/l
98%
100%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,79
0,085
0,3
0,007
mg/l
mg/l
98%
102%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,052
8,50
0,005
0,7
mg/l
mg/l
104%
106%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
23,0
0,069
2
0,01
mg/l
mg/l
101%
97%
Boron
DOC
0,071
2,63
0,001
0,04
2,74
0,5
mg/l
mg/l
104%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,076
0,009
mg/l
mg/l
100%
Silicon
4,56
0,11
4,37
0,4
mg/l
96%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AC
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
479
19
µS/cm
100%
Total hardness
9,47
0,07
9,60
1,73
°d
101%
Alkalinity
1,79
0,01
1,77
0,07
mmol/l
99%
Hydrogen carbonate
106
1
105
4,2
mg/l
99%
Calcium
37,5
0,3
37,5
6,8
mg/l
100%
Magnesium
18,3
0,2
18,8
3,4
mg/l
103%
Sodium
26,8
0,2
26,8
4,8
mg/l
100%
Potassium
2,52
0,03
2,39
0,43
mg/l
95%
Nitrate
50,5
1,0
48,6
4,4
mg/l
96%
Nitrite
0,040
0,001
0,039
0,004
mg/l
98%
Ammonium
<0,01
Chloride
42,1
<0,01
0,5
41,0
mg/l
•
3,7
mg/l
97%
Sulphate
39,4
0,5
38,3
3,4
mg/l
97%
Orthophosphate
0,090
0,001
0,095
0,009
mg/l
106%
Boron
<0,02
mg/l
•
DOC
4,06
0,05
4,28
0,39
mg/l
105%
Total P (as PO4)
0,148
0,002
0,158
0,006
mg/l
107%
KMnO4-Index
3,40
0,09
3,31
0,3
mg/l
97%
Silicon
2,28
0,05
2,26
0,09
mg/l
99%
<0,01
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AC
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
356
5,42
14
0,98
µS/cm
°d
100%
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,93
176
0,12
7,0
mmol/l
mg/l
99%
99%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,3
6,91
4,9
1,2
mg/l
mg/l
99%
103%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,7
7,22
6,6
1,30
mg/l
mg/l
100%
96%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,87
0,079
0,44
0,007
mg/l
mg/l
100%
95%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,058
7,62
0,005
0,69
mg/l
mg/l
116%
95%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
22,1
0,076
2
0,007
mg/l
mg/l
97%
107%
Boron
DOC
0,071
2,63
0,001
0,04
0,072
2,84
0,01
0,26
mg/l
mg/l
101%
108%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,088
3,88
0,004
0,35
mg/l
mg/l
116%
99%
Silicon
4,56
0,11
4,51
0,18
mg/l
99%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AD
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
477
10
µS/cm
100%
Total hardness
9,47
0,07
9,6
1,0
°d
101%
Alkalinity
1,79
0,01
1,75
0,12
mmol/l
98%
Hydrogen carbonate
106
1
104
8,3
mg/l
98%
Calcium
37,5
0,3
39
1,6
mg/l
104%
Magnesium
18,3
0,2
18
1,1
mg/l
98%
Sodium
26,8
0,2
27
1,1
mg/l
101%
Potassium
2,52
0,03
2
0,2
mg/l
79%
Nitrate
50,5
1,0
49
3,4
mg/l
97%
Nitrite
0,040
0,001
0,041
0,004
mg/l
103%
Ammonium
<0,01
<0,02
<0,006
mg/l
•
Chloride
42,1
41
3,3
mg/l
97%
0,5
Sulphate
39,4
0,5
37
2,2
mg/l
94%
Orthophosphate
0,090
0,001
0,089
0,013
mg/l
99%
Boron
<0,02
mg/l
DOC
4,06
0,05
4,26
0,68
mg/l
Total P (as PO4)
0,148
0,002
0,147
0,019
mg/l
105%
99%
KMnO4-Index
3,40
0,09
3,9
0,4
mg/l
115%
Silicon
2,28
0,05
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AD
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
356
5,5
7
0,6
µS/cm
°d
100%
102%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,92
175
0,2
14
mmol/l
mg/l
99%
99%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28
7
1,1
0,4
mg/l
mg/l
102%
104%
Sodium
Potassium
36,8
7,55
0,3
0,04
37
7
1,5
0,6
mg/l
mg/l
101%
93%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
5
0,084
0,2
0,08
mg/l
mg/l
103%
101%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,041
8
0,013
0,6
mg/l
mg/l
82%
100%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
20
0,067
1,2
0,010
mg/l
mg/l
88%
94%
Boron
DOC
0,071
2,63
0,001
0,04
2,76
0,44
mg/l
mg/l
105%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,067
4,1
0,009
0,41
mg/l
mg/l
88%
105%
Silicon
4,56
0,11
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AE
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
477
14
µS/cm
100%
Total hardness
9,47
0,07
9,5
1,1
°d
100%
Alkalinity
1,79
0,01
1,77
0,08
mmol/l
99%
Hydrogen carbonate
106
1
105
5
mg/l
99%
Calcium
37,5
0,3
37,7
3,4
mg/l
101%
Magnesium
18,3
0,2
18,2
1,7
mg/l
99%
Sodium
26,8
0,2
26,9
2,2
mg/l
100%
Potassium
2,52
0,03
2,42
0,20
mg/l
96%
Nitrate
50,5
1,0
49,8
4,5
mg/l
99%
Nitrite
0,040
0,001
0,039
0,005
mg/l
98%
Ammonium
<0,01
Chloride
42,1
<0,008
0,5
42,0
mg/l
•
2,1
mg/l
100%
Sulphate
39,4
0,5
38,8
2,0
mg/l
98%
Orthophosphate
0,090
0,001
0,091
0,009
mg/l
101%
Boron
<0,02
mg/l
•
DOC
4,06
0,05
4,13
0,37
mg/l
102%
Total P (as PO4)
0,148
0,002
0,150
0,015
mg/l
101%
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
<0,004
mg/l
2,2
0,3
mg/l
96%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AE
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
354
5,5
11
0,7
µS/cm
°d
99%
102%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,93
176
0,12
7
mmol/l
mg/l
99%
99%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,4
6,72
2,6
0,65
mg/l
mg/l
103%
100%
Sodium
Potassium
36,8
7,55
0,3
0,04
37,0
7,50
3,0
0,52
mg/l
mg/l
101%
99%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,65
0,085
0,42
0,009
mg/l
mg/l
95%
102%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,052
8,47
0,008
0,51
mg/l
mg/l
104%
106%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
22,1
0,071
1,2
0,007
mg/l
mg/l
97%
100%
Boron
DOC
0,071
2,63
0,001
0,04
0,074
2,70
0,008
0,25
mg/l
mg/l
104%
103%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,077
0,008
mg/l
mg/l
101%
Silicon
4,56
0,11
4,3
0,5
mg/l
94%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AF
Parameter
Recovery
[%]
Result
±
Unit
Recovery
99%
Conductivity
479
1
475
2,88
µS/cm
Total hardness
9,47
0,07
9,31
0,159
°d
98%
Alkalinity
1,79
0,01
1,79
0,005
mmol/l
100%
Hydrogen carbonate
106
1
106
0,32
mg/l
100%
Calcium
37,5
0,3
37,1
0,58
mg/l
99%
Magnesium
18,3
0,2
17,9
0,59
mg/l
98%
Sodium
26,8
0,2
26,7
0,27
mg/l
100%
Potassium
2,52
0,03
2,63
0,060
mg/l
104%
Nitrate
50,5
1,0
48,9
0,57
mg/l
97%
Nitrite
0,040
0,001
0,0394
0,0009
mg/l
99%
Ammonium
<0,01
Chloride
42,1
<0,0064
0,5
41,9
mg/l
•
0,15
mg/l
100%
Sulphate
39,4
0,5
39,3
0,33
mg/l
100%
Orthophosphate
0,090
0,001
0,0864
0,0020
mg/l
96%
Boron
<0,02
DOC
4,06
0,05
4,22
Total P (as PO4)
0,148
0,002
0,1480
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
[0,002]
mg/l
•
0,01
mg/l
104%
0,0019
mg/l
100%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AF
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
352
5,37
0,36
0,089
µS/cm
°d
99%
99%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,93
175
0,005
0,32
mmol/l
mg/l
99%
99%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,4
6,66
0,60
0,138
mg/l
mg/l
100%
99%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,2
7,63
0,27
0,257
mg/l
mg/l
98%
101%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,72
0,0830
0,09
0,0009
mg/l
mg/l
97%
100%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,0508
7,93
0,0015
0,03
mg/l
mg/l
102%
99%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
22,8
0,0760
0,34
0,0020
mg/l
mg/l
100%
107%
Boron
DOC
0,071
2,63
0,001
0,04
0,068
2,85
0,002
0,01
mg/l
mg/l
96%
108%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,0790
0,0019
mg/l
mg/l
104%
Silicon
4,56
0,11
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AG
Parameter
Recovery
[%]
Result
±
Unit
Recovery
100%
Conductivity
479
1
481
7
µS/cm
Total hardness
9,47
0,07
9,37
0,94
°d
99%
Alkalinity
1,79
0,01
1,79
0,09
mmol/l
100%
Hydrogen carbonate
106
1
106
5
mg/l
100%
Calcium
37,5
0,3
37,5
3,8
mg/l
100%
Magnesium
18,3
0,2
17,8
1,8
mg/l
97%
Sodium
26,8
0,2
25,6
2,6
mg/l
96%
Potassium
2,52
0,03
2,71
0,27
mg/l
108%
Nitrate
50,5
1,0
49,5
5,0
mg/l
98%
Nitrite
0,040
0,001
0,0411
0,0062
mg/l
103%
Ammonium
<0,01
Chloride
42,1
<0,010
0,5
41,1
mg/l
•
4,1
mg/l
98%
Sulphate
39,4
0,5
38,9
3,9
mg/l
99%
Orthophosphate
0,090
0,001
0,089
0,013
mg/l
99%
Boron
<0,02
DOC
4,06
0,05
4,03
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
<0,020
mg/l
•
0,40
mg/l
99%
0,146
0,029
mg/l
99%
3,48
0,35
mg/l
102%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AG
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
359
5,34
7
0,54
µS/cm
°d
101%
99%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,96
178
0,15
9
mmol/l
mg/l
100%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,3
6,58
2,7
0,66
mg/l
mg/l
99%
98%
Sodium
Potassium
36,8
7,55
0,3
0,04
34,7
7,76
3,5
0,78
mg/l
mg/l
94%
103%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,93
0,0865
0,49
0,0130
mg/l
mg/l
101%
104%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,050
8,05
0,008
0,81
mg/l
mg/l
100%
100%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
22,3
0,070
2,2
0,011
mg/l
mg/l
98%
99%
Boron
DOC
0,071
2,63
0,001
0,04
0,069
2,57
0,010
0,26
mg/l
mg/l
97%
98%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,071
4,16
0,014
0,42
mg/l
mg/l
93%
107%
Silicon
4,56
0,11
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AH
Parameter
Recovery
[%]
Result
±
Unit
Recovery
18,9
µS/cm
100%
°d
99%
Conductivity
479
1
481
Total hardness
9,47
0,07
9,4
Alkalinity
1,79
0,01
1,67
0,183
mmol/l
93%
Hydrogen carbonate
106
1
102,1
15,32
mg/l
96%
Calcium
37,5
0,3
37,03
1,481
mg/l
99%
Magnesium
18,3
0,2
18,23
1,094
mg/l
100%
Sodium
26,8
0,2
26,78
1,607
mg/l
100%
Potassium
2,52
0,03
2,71
0,271
mg/l
108%
Nitrate
50,5
1,0
48,823
1,9529
mg/l
97%
Nitrite
0,040
0,001
0,041
0,003
mg/l
103%
Ammonium
<0,01
Chloride
42,1
0,005
0,0005
mg/l
•
0,5
39,93
2,396
mg/l
95%
Sulphate
39,4
0,5
37,03
1,481
mg/l
94%
Orthophosphate
0,090
0,001
0,84
0,0101
mg/l
933%
Boron
<0,02
mg/l
•
DOC
4,06
0,05
4,3
0,34
mg/l
106%
Total P (as PO4)
0,148
0,002
0,15
0,0223
mg/l
101%
KMnO4-Index
3,40
0,09
3,5
0,5000
mg/l
103%
Silicon
2,28
0,05
[0,00114]
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AH
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
352
5,3
14,1
µS/cm
°d
99%
98%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,78
169,3
0,416
25,4
mmol/l
mg/l
94%
96%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,1
6,58
1,084
0,395
mg/l
mg/l
99%
98%
Sodium
Potassium
36,8
7,55
0,3
0,04
38,2
7,51
2,292
0,751
mg/l
mg/l
104%
99%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,626
0,083
0,185
0,0067
mg/l
mg/l
95%
100%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,047
7,74
0,0047
0,31
mg/l
mg/l
94%
97%
Sulphate
Orthophosphate
22,8
0,071
0,3
0,001
24,82
0,075
1,489
0,009
mg/l
mg/l
109%
106%
Boron
DOC
0,071
2,63
0,001
0,04
0,084
2,9
0,0101
0,23
mg/l
mg/l
118%
110%
Total P (as PO4)
KMnO4-Index
0,076
3,90
0,001
0,08
0,086
3,9
0,0130
0,0600
mg/l
mg/l
113%
100%
Silicon
4,56
0,11
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AI
Parameter
Recovery
[%]
Result
±
Unit
Recovery
101%
Conductivity
479
1
483
10
µS/cm
Total hardness
9,47
0,07
9,3
0,5
°d
98%
Alkalinity
1,79
0,01
1,81
0,09
mmol/l
101%
Hydrogen carbonate
106
1
107,4
5,4
mg/l
101%
Calcium
37,5
0,3
36,6
1,8
mg/l
98%
Magnesium
18,3
0,2
18,2
0,9
mg/l
99%
Sodium
26,8
0,2
27,6
1,4
mg/l
103%
Potassium
2,52
0,03
2,7
0,1
mg/l
107%
Nitrate
50,5
1,0
49,7
1,5
mg/l
98%
Nitrite
0,040
0,001
0,039
0,004
mg/l
98%
Ammonium
<0,01
Chloride
42,1
<0,03
0,5
42,1
mg/l
•
1,3
mg/l
100%
Sulphate
39,4
0,5
39,7
1,2
mg/l
101%
Orthophosphate
0,090
0,001
0,089
0,009
mg/l
99%
Boron
<0,02
DOC
4,06
0,05
4,07
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
<0,050
mg/l
•
0,41
mg/l
100%
0,175
0,018
mg/l
118%
3,25
0,33
mg/l
96%
2,36
0,24
mg/l
104%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AI
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
364
5,2
7
0,3
µS/cm
°d
102%
96%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,97
178,3
0,15
8,9
mmol/l
mg/l
100%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
26,4
6,60
1,3
0,33
mg/l
mg/l
96%
98%
Sodium
Potassium
36,8
7,55
0,3
0,04
37,3
7,9
1,9
0,4
mg/l
mg/l
101%
105%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,6
0,088
0,1
0,009
mg/l
mg/l
94%
106%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,056
8,1
0,006
0,2
mg/l
mg/l
112%
101%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
22,9
0,087
0,7
0,009
mg/l
mg/l
100%
106%
Boron_1
DOC
0,058
2,63
0,001
0,04
0,059
2,86
0,006
0,29
mg/l
mg/l
102%
109%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,108
3,91
0,011
0,39
mg/l
mg/l
124%
100%
Silicon
4,56
0,12
4,64
0,46
mg/l
102%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride Orthophosphate_1
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Boron_1Total P (as PO4)_1
Silicon
Sample
N131A
Laboratory AJ
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
479
µS/cm
100%
Total hardness
9,47
0,07
9,46
°d
100%
Alkalinity
1,79
0,01
1,81
mmol/l
101%
Hydrogen carbonate
106
1
Calcium
37,5
0,3
38,486
2,287
mg/l
103%
Magnesium
18,3
0,2
17,586
2,431
mg/l
96%
Sodium
26,8
0,2
24,798
2,793
mg/l
93%
Potassium
2,52
0,03
2,543
0,270
mg/l
101%
mg/l
Nitrate
50,5
1,0
mg/l
Nitrite
0,040
0,001
mg/l
Ammonium
<0,01
Chloride
42,1
0,5
mg/l
Sulphate
39,4
0,5
mg/l
Orthophosphate
0,090
0,001
Boron
<0,02
DOC
4,06
0,05
mg/l
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
mg/l
mg/l
<0,005
mg/l
Deviation
•
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AJ
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
358
5,43
µS/cm
°d
101%
101%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,94
mmol/l
mg/l
99%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,285
6,630
2,344
0,230
mg/l
mg/l
103%
99%
Sodium
Potassium
36,8
7,55
0,3
0,04
34,591
7,440
2,727
0,270
mg/l
mg/l
94%
99%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
mg/l
mg/l
Ammonium
Chloride
0,050
8,02
0,001
0,02
mg/l
mg/l
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
mg/l
mg/l
Boron_1
DOC
0,058
2,63
0,001
0,04
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
mg/l
mg/l
Silicon
4,56
0,12
mg/l
0,060
0,002
mg/l
mg/l
103%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AK
Parameter
Recovery
[%]
Result
±
Unit
Recovery
100%
Conductivity
479
1
481
µS/cm
Total hardness
9,47
0,07
9,35
°d
99%
Alkalinity
1,79
0,01
1,82
mmol/l
102%
Hydrogen carbonate
106
1
107
mg/l
101%
Calcium
37,5
0,3
37,5
mg/l
100%
Magnesium
18,3
0,2
17,9
mg/l
98%
Sodium
26,8
0,2
26,9
mg/l
100%
Potassium
2,52
0,03
2,5
mg/l
99%
Nitrate
50,5
1,0
49,3
mg/l
98%
Nitrite
0,040
0,001
0,039
mg/l
98%
Ammonium
<0,01
<0,01
mg/l
•
Chloride
42,1
41,8
mg/l
99%
0,5
Sulphate
39,4
0,5
39,0
mg/l
99%
Orthophosphate
0,090
0,001
0,098
mg/l
109%
Boron
<0,02
DOC
4,06
0,05
4,1
mg/l
Total P (as PO4)
0,148
0,002
0,144
mg/l
97%
KMnO4-Index
3,40
0,09
3,64
mg/l
107%
Silicon
2,28
0,05
2,6
mg/l
114%
mg/l
101%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AK
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
357
5,43
µS/cm
°d
100%
101%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,96
179
mmol/l
mg/l
100%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,3
7,1
mg/l
mg/l
99%
105%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,9
7,6
mg/l
mg/l
100%
101%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,8
0,079
mg/l
mg/l
99%
95%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,044
8,0
mg/l
mg/l
88%
100%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
22,5
0,101
mg/l
mg/l
99%
123%
Boron_1
DOC
0,058
2,63
0,001
0,04
2,7
mg/l
mg/l
103%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,095
3,85
mg/l
mg/l
109%
99%
Silicon
4,56
0,12
6,4
mg/l
140%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AL
Parameter
Recovery
[%]
Result
483
±
Unit
Recovery
µS/cm
101%
Conductivity
479
1
Total hardness
9,47
0,07
°d
Alkalinity
1,79
0,01
mmol/l
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
mg/l
0,04
mg/l
100%
<0,05
mg/l
•
0,5
mg/l
Sulphate
39,4
0,5
mg/l
Orthophosphate
0,090
0,001
mg/l
Boron
<0,02
DOC
4,06
0,05
mg/l
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AL
Parameter
Recovery
[%]
Result
356
±
Unit
Recovery
µS/cm
°d
100%
Conductivity
Total hardness
356
5,40
1
0,05
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
mmol/l
mg/l
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
Ammonium
Chloride
0,050
8,02
0,001
0,02
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
mg/l
mg/l
Boron_1
DOC
0,058
2,63
0,001
0,04
mg/l
mg/l
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
mg/l
mg/l
Silicon
4,56
0,12
mg/l
0,09
<0,05
mg/l
mg/l
108%
mg/l
mg/l
Deviation
•
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AM
Parameter
Recovery
[%]
Result
±
Recovery
µS/cm
18%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
1,75
Hydrogen carbonate
106
1
104
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
48,2
Nitrite
0,040
0,001
0,05
Ammonium
<0,01
Chloride
42,1
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
86
Unit
°d
0,09
mmol/l
98%
mg/l
98%
mg/l
1,1
mg/l
95%
mg/l
125%
<0,01
0,03
mg/l
•
57,3
0,2
mg/l
136%
0,81
0,05
mg/l
mg/l
900%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
0,83
mg/l
561%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AM
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
149
µS/cm
°d
42%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,98
179
mmol/l
mg/l
101%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
6,08
0,10
mg/l
mg/l
125%
120%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,05
12,2
mg/l
mg/l
100%
152%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
0,60
mg/l
mg/l
732%
Boron_1
DOC
0,058
2,63
0,001
0,04
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
Silicon
4,56
0,12
mg/l
mg/l
0,62
mg/l
mg/l
713%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AN
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
482
11
µS/cm
101%
Total hardness
9,47
0,07
9,67
0,02
°d
102%
Alkalinity
1,79
0,01
1,95
0,08
mmol/l
109%
Hydrogen carbonate
106
1
116,1
5,2
mg/l
110%
Calcium
37,5
0,3
38,36
0,34
mg/l
102%
Magnesium
18,3
0,2
18,64
0,10
mg/l
102%
Sodium
26,8
0,2
26,83
1,00
mg/l
100%
Potassium
2,52
0,03
2,56
0,10
mg/l
102%
Nitrate
50,5
1,0
49,35
0,62
mg/l
98%
Nitrite
0,040
0,001
0,043
0,003
mg/l
108%
Ammonium
<0,01
Chloride
42,1
<0,01
0,5
39,40
mg/l
•
0,46
mg/l
94%
Sulphate
39,4
0,5
38,72
0,44
mg/l
98%
Orthophosphate
0,090
0,001
0,086
0,002
mg/l
96%
Boron
<0,02
mg/l
DOC
4,06
0,05
3,91
0,12
mg/l
96%
Total P (as PO4)
0,148
0,002
0,139
0,006
mg/l
94%
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AN
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
359
5,56
4
0,02
µS/cm
°d
101%
103%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
3,11
186,7
0,08
2,6
mmol/l
mg/l
105%
105%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,28
6,94
0,10
0,12
mg/l
mg/l
103%
103%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,56
7,45
1,38
0,34
mg/l
mg/l
99%
99%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,71
0,086
0,18
0,003
mg/l
mg/l
97%
104%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,051
7,72
0,004
0,18
mg/l
mg/l
102%
96%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
22,44
0,081
0,26
0,003
mg/l
mg/l
98%
99%
Boron_1
DOC
0,058
2,63
0,001
0,04
2,61
0,14
mg/l
mg/l
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,088
0,012
Silicon
4,56
0,12
mg/l
mg/l
99%
101%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AO
Parameter
Result
±
Unit
Recovery
Conductivity
479
1
462
3
µS/cm
96%
Total hardness
9,47
0,07
9,2
0,1
°d
97%
Alkalinity
1,79
0,01
1,67
0,06
mmol/l
93%
Hydrogen carbonate
106
1
102
4
mg/l
96%
Calcium
37,5
0,3
36,6
0,1
mg/l
98%
Magnesium
18,3
0,2
17,9
0,1
mg/l
98%
Sodium
26,8
0,2
30
0,2
mg/l
112%
Potassium
2,52
0,03
2,5
0,02
mg/l
99%
Nitrate
50,5
1,0
51,2
0,4
mg/l
101%
Nitrite
0,040
0,001
<0,01
mg/l
FN
Ammonium
<0,01
Chloride
42,1
0,5
0,012
44,3
41,1
0,005
mg/l
•
0,3
mg/l
105%
0,4
mg/l
104%
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
mg/l
mg/l
4,75
Recovery
[%]
0,42
mg/l
117%
Deviation
Recovery
140
130
120
110
100
FN
90
80
70
60
Nitrite
Total hardness
Potassium
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AO
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
346
5,1
2
0,1
µS/cm
°d
97%
94%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,79
170
0,11
7
mmol/l
mg/l
94%
96%
Calcium
Magnesium
27,5
6,73
0,3
0,08
26,1
6,5
0,1
0,1
mg/l
mg/l
95%
97%
Sodium
Potassium
36,8
7,55
0,3
0,04
41
7,6
0,2
0,06
mg/l
mg/l
111%
101%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,9
0,089
0,1
0,007
mg/l
mg/l
101%
107%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,059
7,9
0,01
0,1
mg/l
mg/l
118%
99%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
23,9
0,2
mg/l
mg/l
105%
Boron_1
DOC
0,058
2,63
0,001
0,04
3,25
0,29
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
mg/l
mg/l
Silicon
4,56
0,12
mg/l
mg/l
mg/l
124%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AP
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
478,4
µS/cm
100%
Total hardness
9,47
0,07
9,5
°d
100%
Alkalinity
1,79
0,01
1,84
mmol/l
103%
Hydrogen carbonate
106
1
112,3
mg/l
106%
Calcium
37,5
0,3
36,9
2,1
mg/l
98%
Magnesium
18,3
0,2
18,0
1,4
mg/l
98%
Sodium
26,8
0,2
27,1
1,5
mg/l
101%
Potassium
2,52
0,03
2,77
0,15
mg/l
110%
Nitrate
50,5
1,0
50,2
mg/l
99%
Nitrite
0,040
0,001
0,04
mg/l
100%
Ammonium
<0,01
<0,013
mg/l
•
Chloride
42,1
42
mg/l
100%
0,5
Sulphate
39,4
0,5
39,5
mg/l
100%
Orthophosphate
0,090
0,001
<0,2
mg/l
•
Boron
<0,02
<0,1
mg/l
•
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
0,23
mg/l
155%
mg/l
2,11
0,12
mg/l
93%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AP
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
356,0
5,05
µS/cm
°d
100%
94%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,98
181,5
mmol/l
mg/l
101%
103%
Calcium
Magnesium
27,5
6,73
0,3
0,08
26,7
7,15
1,5
0,23
mg/l
mg/l
97%
106%
Sodium
Potassium
36,8
7,55
0,3
0,04
37,4
7,74
0,93
0,24
mg/l
mg/l
102%
103%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
5,05
0,08
mg/l
mg/l
104%
96%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,065
7,35
mg/l
mg/l
130%
92%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
19
<0,2
mg/l
mg/l
83%
•
Boron_1
DOC
0,058
2,63
0,001
0,04
58,7
mg/l
mg/l
101207%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
<0,2
mg/l
mg/l
•
Silicon
4,56
0,12
4,22
mg/l
93%
5,1
0,21
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AQ
Parameter
Result
±
Unit
Conductivity
479
1
Total hardness
9,47
0,07
°d
Alkalinity
1,79
0,01
mmol/l
Recovery
µS/cm
Hydrogen carbonate
106
1
Calcium
37,5
0,3
39,3
4,7
mg/l
mg/l
Magnesium
18,3
0,2
17,7
2,1
mg/l
97%
Sodium
26,8
0,2
27,0
2,7
mg/l
101%
Potassium
2,52
0,03
2,5
0,3
mg/l
99%
Nitrate
50,5
1,0
47,6
9,0
mg/l
94%
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
105%
mg/l
0,03
0,004
mg/l
FP
0,5
40,5
5,7
mg/l
96%
38,0
5,3
mg/l
96%
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
mg/l
mg/l
mg/l
0,05
0,02
Recovery
[%]
mg/l
34%
Deviation
Recovery
140
130
120
110
FP
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AQ
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
µS/cm
°d
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
mmol/l
mg/l
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,6
6,7
3,4
0,8
mg/l
mg/l
104%
100%
Sodium
Potassium
36,8
7,55
0,3
0,04
37,6
7,5
3,8
0,9
mg/l
mg/l
102%
99%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,6
0,9
mg/l
mg/l
94%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,10
7,8
0,01
1,1
mg/l
mg/l
200%
97%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
22,5
3,1
mg/l
mg/l
99%
Boron_1
DOC
0,058
2,63
0,001
0,04
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
Silicon
4,56
0,12
mg/l
mg/l
0,05
0,02
mg/l
mg/l
57%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AR
Parameter
Recovery
[%]
Result
±
Unit
Recovery
99%
Conductivity
479
1
474
8,4
µS/cm
Total hardness
9,47
0,07
9,4
1,3
°d
99%
Alkalinity
1,79
0,01
1,8
0,079
mmol/l
101%
109,8
4,9
mg/l
104%
Hydrogen carbonate
106
1
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
44,1
8,8
mg/l
87%
Nitrite
0,040
0,001
0,043
0,0077
mg/l
108%
Ammonium
<0,01
Chloride
42,1
mg/l
<0,1
0,5
mg/l
•
41,2
8,1
mg/l
98%
7,7
mg/l
97%
mg/l
•
Sulphate
39,4
0,5
38,3
Orthophosphate
0,090
0,001
<0,6
Boron
<0,02
mg/l
DOC
4,06
0,05
4,1
Total P (as PO4)
0,148
0,002
<0,15
KMnO4-Index
3,40
0,09
3,2
Silicon
2,28
0,05
1,2
0,55
mg/l
101%
mg/l
•
mg/l
94%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AR
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
354
5,42
6,3
0,73
µS/cm
°d
99%
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
3
183,1
0,098
6,0
mmol/l
mg/l
101%
103%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
3,45
0,086
0,89
0,010
mg/l
mg/l
71%
104%
Ammonium
Chloride
0,050
8,02
0,001
0,02
<0,1
6,6
1,3
mg/l
mg/l
•
82%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
21,5
<0,6
4,3
mg/l
mg/l
94%
•
Boron_1
DOC
0,058
2,63
0,001
0,04
2,8
0,9
mg/l
mg/l
106%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
<0,15
3,6
0,61
mg/l
mg/l
•
92%
Silicon
4,56
0,12
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AS
Parameter
Recovery
[%]
Result
±
Unit
Recovery
393
10
µS/cm
82%
Conductivity
479
1
Total hardness
9,47
0,07
°d
Alkalinity
1,79
0,01
mmol/l
Hydrogen carbonate
106
1
Calcium
37,5
0,3
36,3
0,1
mg/l
Magnesium
18,3
0,2
18,07
0,15
mg/l
99%
Sodium
26,8
0,2
26,8
0,1
mg/l
100%
Potassium
2,52
0,03
3,02
0,05
mg/l
120%
Nitrate
50,5
1,0
65,97
0,15
mg/l
131%
Nitrite
0,040
0,001
0,04
0,08
mg/l
100%
Ammonium
<0,01
Chloride
42,1
0,5
39,49
0,2
mg/l
94%
Sulphate
39,4
0,5
40,65
0,8
mg/l
103%
Orthophosphate
0,090
0,001
0,076
0,002
mg/l
84%
Boron
<0,02
mg/l
97%
mg/l
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
0,146
0,002
mg/l
99%
mg/l
1,89
0,05
mg/l
83%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AS
Parameter
Recovery
[%]
Result
±
Unit
Recovery
293
10
µS/cm
°d
82%
Conductivity
Total hardness
356
5,40
1
0,05
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,86
6,64
0,1
0,15
mg/l
mg/l
101%
99%
Sodium
Potassium
36,8
7,55
0,3
0,04
38,07
7,36
0,1
0,05
mg/l
mg/l
103%
97%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
5,09
0,08
0,15
0,08
mg/l
mg/l
105%
96%
Ammonium
Chloride
0,050
8,02
0,001
0,02
8,19
0,2
mg/l
mg/l
102%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
23,77
0,071
0,8
0,002
mg/l
mg/l
104%
87%
Boron_1
DOC
0,058
2,63
0,001
0,04
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,091
0,002
mg/l
mg/l
105%
Silicon
4,56
0,12
4,02
0,05
mg/l
88%
mmol/l
mg/l
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AT
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
477
µS/cm
100%
Total hardness
9,47
0,07
9,2
°d
97%
Alkalinity
1,79
0,01
0,87
mmol/l
49%
Hydrogen carbonate
106
1
53
mg/l
50%
Calcium
37,5
0,3
35
mg/l
93%
Magnesium
18,3
0,2
19
mg/l
104%
Sodium
26,8
0,2
Potassium
2,52
0,03
Nitrate
50,5
1,0
52,8
mg/l
105%
Nitrite
0,040
0,001
0,038
mg/l
95%
Ammonium
<0,01
0,01
mg/l
•
Chloride
42,1
45
mg/l
107%
0,5
mg/l
mg/l
Sulphate
39,4
0,5
40
mg/l
102%
Orthophosphate
0,090
0,001
0,09
mg/l
100%
Boron
<0,02
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
0,17
mg/l
mg/l
115%
KMnO4-Index
3,40
0,09
3,1
mg/l
91%
Silicon
2,28
0,05
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AT
Parameter
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
355
5,3
µS/cm
°d
100%
98%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
1,43
87
mmol/l
mg/l
48%
49%
Calcium
Magnesium
27,5
6,73
0,3
0,08
25
7,1
mg/l
mg/l
91%
105%
Sodium
Potassium
36,8
7,55
0,3
0,04
Nitrate
Nitrite
4,87
0,083
0,11
0,001
5,3
0,080
mg/l
mg/l
109%
96%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,056
<5
mg/l
mg/l
112%
FN
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
23
0,06
mg/l
mg/l
101%
73%
Boron_1
DOC
0,058
2,63
0,001
0,04
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
Silicon
4,56
0,12
mg/l
mg/l
mg/l
mg/l
0,12
3,6
mg/l
mg/l
138%
92%
mg/l
Recovery
[%]
Deviation
Recovery
140
130
120
110
100
FN
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AU
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
490
µS/cm
102%
Total hardness
9,47
0,07
9,664
°d
102%
Alkalinity
1,79
0,01
1,7966
1,1129
mmol/l
100%
Hydrogen carbonate
106
1
109,6252
0,0064
mg/l
103%
Calcium
37,5
0,3
38,2966
0,0052
mg/l
102%
Magnesium
18,3
0,2
18,7027
0,0455
mg/l
102%
Sodium
26,8
0,2
27,8707
0,0450
mg/l
104%
Potassium
2,52
0,03
7,3105
0,0078
mg/l
290%
Nitrate
50,5
1,0
40,2026
0,0250
mg/l
80%
Nitrite
0,040
0,001
0,4745
0,6170
mg/l
1186%
Ammonium
<0,01
mg/l
•
42,1
0,5
0,0125
35,9927
0,0461
Chloride
0,0392
mg/l
85%
Sulphate
39,4
0,5
34,1436
0,0213
mg/l
87%
Orthophosphate
0,090
0,001
0
0
mg/l
Boron
<0,02
0
0
mg/l
FN
•
DOC
4,06
0,05
5,5243
0,0918
mg/l
136%
Total P (as PO4)
0,148
0,002
0,1656
0,1839
mg/l
112%
KMnO4-Index
3,40
0,09
3,120
0,6410
mg/l
92%
Silicon
2,28
0,05
2,2752
0,2490
mg/l
100%
Deviation
Recovery
140
130
120
110
100
FN
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AU
Parameter
Recovery
[%]
Result
±
Unit
Recovery
µS/cm
°d
102%
141%
Conductivity
Total hardness
356
5,40
1
0,05
362
7,598
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,9033
177,1496
0,0159
0,0159
mmol/l
mg/l
98%
100%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,0852
6,9757
0,0067
0,0832
mg/l
mg/l
102%
104%
Sodium
Potassium
36,8
7,55
0,3
0,04
38,205
2,3947
0,0472
0,0608
mg/l
mg/l
104%
32%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
6,2260
0,4812
0,0119
0,3958
mg/l
mg/l
128%
580%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,080
10,7991
0
0,0932
mg/l
mg/l
160%
135%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
23,1698
0
0,0141
0
mg/l
mg/l
102%
FN
Boron_1
DOC
0,058
2,63
0,001
0,04
0,0575
4,701
0,0695
0,2198
mg/l
mg/l
99%
179%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,0867
4,140
0,0475
0,1232
mg/l
mg/l
100%
106%
Silicon
4,56
0,12
4,7503
0,2686
mg/l
104%
Deviation
Recovery
140
130
120
110
100
FN
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AV
Parameter
Result
±
Unit
Recovery
Conductivity
479
1
481
3
µS/cm
100%
Total hardness
9,47
0,07
9,56
0,03
°d
101%
Alkalinity
1,79
0,01
1,77
mmol/l
99%
Hydrogen carbonate
106
1
Calcium
37,5
0,3
37,80
0,357
mg/l
101%
Magnesium
18,3
0,2
18,18
0,916
mg/l
99%
Sodium
26,8
0,2
26,55
0,204
mg/l
99%
Potassium
2,52
0,03
2,47
0,053
mg/l
98%
Nitrate
50,5
1,0
42,30
0,451
mg/l
84%
Nitrite
0,040
0,001
0,043
0,025
mg/l
108%
Ammonium
<0,01
Chloride
42,1
mg/l
0,1889
0,004
mg/l
FP
0,5
36,45
4,38
mg/l
87%
35,61
0,842
mg/l
90%
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
mg/l
mg/l
mg/l
3,7
mg/l
109%
mg/l
Recovery
[%]
Deviation
Recovery
140
130
120
110
FP
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AV
Parameter
Recovery
[%]
Result
±
Unit
Recovery
5
0,01
µS/cm
°d
99%
101%
mmol/l
mg/l
99%
Conductivity
Total hardness
356
5,40
1
0,05
353
5,46
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,92
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,75
6,70
0,357
0,916
mg/l
mg/l
101%
100%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,36
7,46
0,109
0,053
mg/l
mg/l
99%
99%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,39
0,055
0,340
0,019
mg/l
mg/l
90%
66%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,038
6,59
0,009
0,019
mg/l
mg/l
76%
82%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
19,87
0,842
mg/l
mg/l
87%
Boron_1
DOC
0,058
2,63
0,001
0,04
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
Silicon
4,56
0,12
mg/l
mg/l
3,9
mg/l
mg/l
100%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AW
Parameter
Recovery
[%]
Result
±
Unit
Conductivity
479
1
Total hardness
9,47
0,07
°d
Alkalinity
1,79
0,01
mmol/l
µS/cm
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
mg/l
0,04
mg/l
100%
<0,05
mg/l
•
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
Recovery
mg/l
mg/l
0,10
mg/l
111%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
3,331
mg/l
98%
Silicon
2,28
0,05
2,2
mg/l
96%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AW
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
µS/cm
°d
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
mmol/l
mg/l
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
Ammonium
Chloride
0,050
8,02
0,001
0,02
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
Boron_1
DOC
0,058
2,63
0,001
0,04
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
3,766
mg/l
mg/l
97%
Silicon
4,56
0,12
4,5
mg/l
99%
0,09
0,07
0,10
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
108%
140%
122%
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AX
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
471
5
µS/cm
98%
Total hardness
9,47
0,07
9,4
0,5
°d
99%
Alkalinity
1,79
0,01
1,72
0,04
mmol/l
96%
Hydrogen carbonate
106
1
102
3
mg/l
96%
Calcium
37,5
0,3
36,7
1,9
mg/l
98%
Magnesium
18,3
0,2
18,4
1,0
mg/l
101%
Sodium
26,8
0,2
26,1
1,4
mg/l
97%
Potassium
2,52
0,03
2,60
0,18
mg/l
103%
Nitrate
50,5
1,0
49
2
mg/l
97%
Nitrite
0,040
0,001
0,04
0,002
mg/l
100%
Ammonium
<0,01
Chloride
42,1
<0,04
0,5
40
mg/l
•
2
mg/l
95%
Sulphate
39,4
0,5
39
2
mg/l
99%
Orthophosphate
0,090
0,001
0,08
0,003
mg/l
89%
Boron
<0,02
0,0565
0,0017
mg/l
FP
DOC
4,06
0,05
4,25
0,1
mg/l
105%
Total P (as PO4)
0,148
0,002
0,146
0,005
mg/l
99%
KMnO4-Index
3,40
0,09
3,39
0,17
mg/l
100%
Silicon
2,28
0,05
2,15
0,03
mg/l
94%
Deviation
Recovery
140
130
120
110
FP
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AX
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
353
5,4
5
0,3
µS/cm
°d
99%
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,88
173
0,04
3
mmol/l
mg/l
97%
98%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,2
6,5
1,5
0,4
mg/l
mg/l
103%
97%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,3
7,9
1,9
0,4
mg/l
mg/l
99%
105%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,8
0,084
0,3
0,004
mg/l
mg/l
99%
101%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,0524
8,1
0,003
0,5
mg/l
mg/l
105%
101%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
22,0
0,078
1,2
0,003
mg/l
mg/l
96%
95%
Boron_1
DOC
0,058
2,63
0,001
0,04
<0,001
2,85
0,07
mg/l
mg/l
FN
108%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,0898
3,85
0,005
0,17
mg/l
mg/l
103%
99%
Silicon
4,56
0,12
4,23
0,03
mg/l
93%
Deviation
Recovery
140
130
120
110
100
FN
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AY
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
471
30
µS/cm
98%
Total hardness
9,47
0,07
9,5
0,2
°d
100%
Alkalinity
1,79
0,01
1,78
0,02
mmol/l
99%
Hydrogen carbonate
106
1
Calcium
37,5
0,3
38,0
0,6
mg/l
Magnesium
18,3
0,2
18,2
0,6
mg/l
99%
Sodium
26,8
0,2
26,8
0,2
mg/l
100%
Potassium
2,52
0,03
2,5
0,06
mg/l
99%
Nitrate
50,5
1,0
50,5
0,5
mg/l
100%
Nitrite
0,040
0,001
88%
Ammonium
<0,01
Chloride
42,1
mg/l
101%
0,035
0,015
mg/l
<0,03
0,08
mg/l
•
0,5
42,6
0,25
mg/l
101%
39,8
3,0
mg/l
101%
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
mg/l
mg/l
4,48
0,03
mg/l
110%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AY
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
350
5,4
30
0,2
µS/cm
°d
98%
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,93
0,02
mmol/l
mg/l
99%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,6
6,6
0,6
0,6
mg/l
mg/l
100%
98%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,6
7,6
0,2
0,06
mg/l
mg/l
99%
101%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,8
0,068
0,5
0,015
mg/l
mg/l
99%
82%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,057
8,1
0,08
0,25
mg/l
mg/l
114%
101%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
23,0
3,0
mg/l
mg/l
101%
Boron_1
DOC
0,058
2,63
0,001
0,04
2,73
0,03
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
mg/l
mg/l
Silicon
4,56
0,12
mg/l
mg/l
mg/l
104%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory AZ
Parameter
Recovery
[%]
Result
±
Unit
Recovery
10,0
µS/cm
95%
°d
99%
mmol/l
99%
mg/l
99%
Conductivity
479
1
457
Total hardness
9,47
0,07
9,4
Alkalinity
1,79
0,01
1,775
Hydrogen carbonate
106
1
105
Calcium
37,5
0,3
36,1
2,0
mg/l
96%
Magnesium
18,3
0,2
19,0
2,0
mg/l
104%
Sodium
26,8
0,2
26,6
2,0
mg/l
99%
Potassium
2,52
0,03
2,8
0,3
mg/l
111%
0,120
Nitrate
50,5
1,0
49,6
3,0
mg/l
98%
Nitrite
0,040
0,001
0,050
0,012
mg/l
125%
Ammonium
<0,01
Chloride
42,1
mg/l
•
0,5
<0,050
41,6
2,0
mg/l
99%
39,0
2,0
mg/l
99%
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
mg/l
<0,010
4,13
0,50
mg/l
•
mg/l
102%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory AZ
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
339
5,3
10,0
µS/cm
°d
95%
98%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,927
176
0,200
mmol/l
mg/l
99%
99%
Calcium
Magnesium
27,5
6,73
0,3
0,08
26,9
6,5
2,0
1,0
mg/l
mg/l
98%
97%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,5
7,2
2,0
0,7
mg/l
mg/l
99%
95%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,5
0,092
0,5
0,023
mg/l
mg/l
92%
111%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,060
7,1
0,020
0,7
mg/l
mg/l
120%
89%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
22,4
2,0
mg/l
mg/l
98%
Boron_1
DOC
0,058
2,63
0,001
0,04
0,057
2,65
0,002
0,50
mg/l
mg/l
98%
101%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
mg/l
mg/l
Silicon
4,56
0,12
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BA
Parameter
Recovery
[%]
Result
±
Unit
Recovery
458
8,7
µS/cm
96%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
1,76
mmol/l
98%
Hydrogen carbonate
106
1
100
mg/l
94%
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
mg/l
Nitrite
0,040
0,001
mg/l
Ammonium
<0,01
Chloride
42,1
0,5
mg/l
Sulphate
39,4
0,5
mg/l
Orthophosphate
0,090
0,001
mg/l
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
°d
mg/l
mg/l
mg/l
mg/l
3,92
0,37
mg/l
115%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BA
Parameter
Recovery
[%]
Result
±
Unit
Recovery
6,5
µS/cm
°d
96%
mmol/l
mg/l
98%
96%
Conductivity
Total hardness
356
5,40
1
0,05
342
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,90
170
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
mg/l
mg/l
Ammonium
Chloride
0,050
8,02
0,001
0,02
mg/l
mg/l
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
mg/l
mg/l
Boron_1
DOC
0,058
2,63
0,001
0,04
mg/l
mg/l
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
Silicon
4,56
0,12
4,49
0,43
mg/l
mg/l
115%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BB
Parameter
Recovery
[%]
Result
±
Unit
Recovery
10
Conductivity
479
1
483
µS/cm
101%
Total hardness
9,47
0,07
9,09
°d
96%
Alkalinity
1,79
0,01
1,77
mmol/l
99%
Hydrogen carbonate
106
1
105,0
mg/l
99%
Calcium
37,5
0,3
34,93
3,48
mg/l
93%
Magnesium
18,3
0,2
18,22
1,45
mg/l
100%
Sodium
26,8
0,2
26,46
2,37
mg/l
99%
Potassium
2,52
0,03
2,65
0,24
mg/l
105%
Nitrate
50,5
1,0
50,65
4,54
mg/l
100%
Nitrite
0,040
0,001
0,0394
0,0027
mg/l
99%
Ammonium
<0,01
Chloride
42,1
<0,02
0,5
42,21
mg/l
•
5,04
mg/l
100%
Sulphate
39,4
0,5
40,57
4,04
mg/l
103%
Orthophosphate
0,090
0,001
0,087
0,013
mg/l
97%
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
Silicon
2,28
<0,010
3,89
0,27
0,09
3,60
0,54
0,05
2,31
mg/l
•
mg/l
96%
mg/l
mg/l
106%
mg/l
101%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BB
Parameter
Recovery
[%]
Result
±
Unit
Recovery
7
µS/cm
°d
101%
95%
mmol/l
mg/l
99%
99%
Conductivity
Total hardness
356
5,40
1
0,05
360
5,12
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,92
175,5
Calcium
Magnesium
27,5
6,73
0,3
0,08
25,42
6,76
2,55
0,55
mg/l
mg/l
92%
100%
Sodium
Potassium
36,8
7,55
0,3
0,04
35,26
7,58
3,19
0,69
mg/l
mg/l
96%
100%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,90
0,0790
0,43
0,0056
mg/l
mg/l
101%
95%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,047
7,96
0,007
0,95
mg/l
mg/l
94%
99%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
23,68
0,084
2,33
0,012
mg/l
mg/l
104%
102%
Boron_1
DOC
0,058
2,63
0,001
0,04
0,054
2,51
0,011
0,18
mg/l
mg/l
93%
95%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
3,52
0,54
mg/l
mg/l
90%
Silicon
4,56
0,12
4,80
mg/l
105%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BC
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
479
3
µS/cm
100%
Total hardness
9,47
0,07
9,3
1
°d
98%
Alkalinity
1,79
0,01
1,75
0,10
mmol/l
98%
Hydrogen carbonate
106
1
107
3
mg/l
101%
Calcium
37,5
0,3
37
1
mg/l
99%
Magnesium
18,3
0,2
18
1
mg/l
98%
Sodium
26,8
0,2
26
2
mg/l
97%
Potassium
2,52
0,03
2,6
0,5
mg/l
103%
Nitrate
50,5
1,0
50
2
mg/l
99%
Nitrite
0,040
0,001
0,04
0,01
mg/l
100%
Ammonium
<0,01
Chloride
42,1
mg/l
•
0,5
<0,02
41
2
mg/l
97%
40
3
mg/l
102%
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
mg/l
•
DOC
4,06
0,05
4,1
0,5
mg/l
101%
Total P (as PO4)
0,148
0,002
0,16
0,02
mg/l
108%
KMnO4-Index
3,40
0,09
3,3
0,3
mg/l
97%
Silicon
2,28
0,05
mg/l
<0,05
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BC
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
356
5,3
3
0,5
µS/cm
°d
100%
98%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,90
177
0,10
4
mmol/l
mg/l
98%
100%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27
6,6
1
1
mg/l
mg/l
98%
98%
Sodium
Potassium
36,8
7,55
0,3
0,04
36
7,5
2
1
mg/l
mg/l
98%
99%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,8
0,08
0,8
0,01
mg/l
mg/l
99%
96%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,06
8,1
0,01
1
mg/l
mg/l
120%
101%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
24
2
mg/l
mg/l
105%
Boron_1
DOC
0,058
2,63
0,001
0,04
0,07
2,7
0,01
0,3
mg/l
mg/l
121%
103%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,10
3,9
0,02
0,3
mg/l
mg/l
115%
100%
Silicon
4,56
0,12
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BD
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
430
2
µS/cm
90%
Total hardness
9,47
0,07
9,60
0,6
°d
101%
Alkalinity
1,79
0,01
1,83
0,1
mmol/l
102%
Hydrogen carbonate
106
1
112
6,1
mg/l
106%
Calcium
37,5
0,3
36,9
1,7
mg/l
98%
Magnesium
18,3
0,2
17,9
0,8
mg/l
98%
Sodium
26,8
0,2
26,0
0,8
mg/l
97%
Potassium
2,52
0,03
2,33
0,3
mg/l
92%
Nitrate
50,5
1,0
49,0
0,4
mg/l
97%
Nitrite
0,040
0,001
0,043
0,002
mg/l
108%
Ammonium
<0,01
<0,005
0,003
mg/l
•
Chloride
42,1
40,7
0,2
mg/l
97%
0,5
Sulphate
39,4
0,5
37
2
mg/l
94%
Orthophosphate
0,090
0,001
0,092
0,002
mg/l
102%
Boron
<0,02
DOC
4,06
0,05
4,2
0,2
mg/l
103%
Total P (as PO4)
0,148
0,002
0,151
0,005
mg/l
102%
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
mg/l
2,2
0,06
mg/l
96%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BD
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
321
5,53
2
0,6
µS/cm
°d
90%
102%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,91
177
0,1
6,1
mmol/l
mg/l
98%
100%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,0
6,7
1,7
0,8
mg/l
mg/l
98%
100%
Sodium
Potassium
36,8
7,55
0,3
0,04
35,5
6,95
0,8
0,3
mg/l
mg/l
96%
92%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,8
0,088
0,4
0,002
mg/l
mg/l
99%
106%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,047
7,7
0,003
0,2
mg/l
mg/l
94%
96%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
33
0,086
2
0,002
mg/l
mg/l
145%
105%
Boron_1
DOC
0,058
2,63
0,001
0,04
2,8
0,2
mg/l
mg/l
106%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,095
0,005
mg/l
mg/l
109%
Silicon
4,56
0,12
4,2
0,06
mg/l
92%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BE
Parameter
Recovery
[%]
Result
±
Unit
Recovery
100%
Conductivity
479
1
478
µS/cm
Total hardness
9,47
0,07
9,4
°d
99%
Alkalinity
1,79
0,01
1,86
mmol/l
104%
Hydrogen carbonate
106
1
113,49
mg/l
107%
Calcium
37,5
0,3
37,58
mg/l
100%
Magnesium
18,3
0,2
18,21
mg/l
100%
Sodium
26,8
0,2
26,38
mg/l
98%
Potassium
2,52
0,03
2,71
mg/l
108%
Nitrate
50,5
1,0
40,33
mg/l
80%
Nitrite
0,040
0,001
0,042
mg/l
105%
Ammonium
<0,01
Chloride
42,1
<0,05
mg/l
•
0,5
42,29
mg/l
100%
32,72
mg/l
83%
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
DOC
4,06
0,05
mg/l
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
mg/l
<0,01
mg/l
Deviation
•
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BE
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
355
5,2
µS/cm
°d
100%
96%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,96
180,61
mmol/l
mg/l
100%
102%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,18
6,83
mg/l
mg/l
102%
101%
Sodium
Potassium
36,8
7,55
0,3
0,04
37,30
8,53
mg/l
mg/l
101%
113%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,4
0,11
mg/l
mg/l
90%
133%
Ammonium
Chloride
0,050
8,02
0,001
0,02
<0,05
8,15
mg/l
mg/l
•
102%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
17,93
mg/l
mg/l
79%
Boron_1
DOC
0,058
2,63
0,001
0,04
0,061
mg/l
mg/l
105%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
mg/l
mg/l
Silicon
4,56
0,12
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BF
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
481
12
µS/cm
100%
Total hardness
9,47
0,07
9,2
0,9
°d
97%
Alkalinity
1,79
0,01
1,76
0,2
mmol/l
98%
Hydrogen carbonate
106
1
104
10
mg/l
98%
Calcium
37,5
0,3
37,7
4
mg/l
101%
Magnesium
18,3
0,2
17,5
2
mg/l
96%
Sodium
26,8
0,2
26,7
3
mg/l
100%
Potassium
2,52
0,03
2,52
0,3
mg/l
100%
Nitrate
50,5
1,0
49,6
5
mg/l
98%
Nitrite
0,040
0,001
0,041
0,004
mg/l
103%
Ammonium
<0,01
Chloride
42,1
<0,01
0,5
43,1
mg/l
•
4
mg/l
102%
Sulphate
39,4
0,5
38,9
4
mg/l
99%
Orthophosphate
0,090
0,001
0,087
0,009
mg/l
97%
Boron
<0,02
DOC
4,06
0,05
4,2
Total P (as PO4)
0,148
0,002
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
<0,005
mg/l
•
0,4
mg/l
103%
0,17
0,02
mg/l
115%
3,44
0,3
mg/l
101%
2,24
0,2
mg/l
98%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BF
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
355
5,6
9
0,6
µS/cm
°d
100%
104%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,88
173
0,3
15
mmol/l
mg/l
97%
98%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,7
6,76
3
0,7
mg/l
mg/l
104%
100%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,8
7,81
4
0,8
mg/l
mg/l
100%
103%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,6
0,085
0,5
0,008
mg/l
mg/l
94%
102%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,058
7,3
0,006
0,7
mg/l
mg/l
116%
91%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
22,1
0,085
2
0,009
mg/l
mg/l
97%
104%
Boron_1
DOC
0,058
2,63
0,001
0,04
0,059
2,74
0,006
0,3
mg/l
mg/l
102%
104%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,11
4,2
0,01
0,4
mg/l
mg/l
126%
108%
Silicon
4,56
0,12
4,53
0,4
mg/l
99%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BG
Parameter
Result
±
Unit
Recovery
490
2,0
µS/cm
102%
Conductivity
479
1
Total hardness
9,47
0,07
°d
Alkalinity
1,79
0,01
mmol/l
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
49,8
3,03
mg/l
99%
Nitrite
0,040
0,001
0,073
0,031
mg/l
183%
Ammonium
<0,01
0,024
0,002
mg/l
FP
Chloride
42,1
mg/l
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
mg/l
mg/l
0,095
0,010
mg/l
106%
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
0,161
0,014
Recovery
[%]
mg/l
109%
Deviation
Recovery
140
130
120
110
FP
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BG
Parameter
Recovery
[%]
Result
±
Unit
Recovery
367
2,0
µS/cm
°d
103%
Conductivity
Total hardness
356
5,40
1
0,05
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
mmol/l
mg/l
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
5,21
0,117
0,317
0,049
mg/l
mg/l
107%
141%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,064
0,005
mg/l
mg/l
128%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
0,091
0,010
Boron_1
DOC
0,058
2,63
0,001
0,04
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
Silicon
4,56
0,12
mg/l
mg/l
111%
mg/l
mg/l
0,104
0,009
mg/l
mg/l
120%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BH
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
479
µS/cm
100%
Total hardness
9,47
0,07
9,47
°d
100%
Alkalinity
1,79
0,01
1,78
mmol/l
99%
Hydrogen carbonate
106
1
106
mg/l
100%
Calcium
37,5
0,3
37,9
0,3
mg/l
101%
Magnesium
18,3
0,2
18,4
0,3
mg/l
101%
Sodium
26,8
0,2
26,2
0,2
mg/l
98%
Potassium
2,52
0,03
2,53
0,08
mg/l
100%
Nitrate
50,5
1,0
52,9
0,8
mg/l
105%
Nitrite
0,040
0,001
0,043
0,003
mg/l
108%
Ammonium
<0,01
0,003
mg/l
•
Chloride
42,1
0,011
42,9
40,1
0,086
[0,002]
0,4
mg/l
102%
1,1
mg/l
102%
0,002
mg/l
96%
mg/l
•
0,5
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
0,122
0,002
mg/l
82%
KMnO4-Index
3,40
0,09
3,09
0,81
mg/l
91%
Silicon
2,28
0,05
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BH
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
348
5,48
µS/cm
°d
98%
101%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,93
176
mmol/l
mg/l
99%
99%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,3
6,84
0,3
0,25
mg/l
mg/l
103%
102%
Sodium
Potassium
36,8
7,55
0,3
0,04
34,7
7,40
0,2
0,08
mg/l
mg/l
94%
98%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,66
0,090
0,17
0,003
mg/l
mg/l
96%
108%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,056
8,15
0,003
0,27
mg/l
mg/l
112%
102%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
22,5
0,082
1,1
0,001
mg/l
mg/l
99%
100%
Boron_1
DOC
0,058
2,63
0,001
0,04
0,060
0,002
mg/l
mg/l
103%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,083
3,81
0,002
0,82
mg/l
mg/l
95%
98%
Silicon
4,56
0,12
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BI
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
477
µS/cm
100%
Total hardness
9,47
0,07
9,6
°d
101%
Alkalinity
1,79
0,01
1,88
mmol/l
105%
Hydrogen carbonate
106
1
114,7
mg/l
108%
Calcium
37,5
0,3
38,81
mg/l
103%
Magnesium
18,3
0,2
18,18
mg/l
99%
Sodium
26,8
0,2
27,12
mg/l
101%
Potassium
2,52
0,03
2,57
mg/l
102%
Nitrate
50,5
1,0
50,25
mg/l
100%
Nitrite
0,040
0,001
0,05
mg/l
125%
Ammonium
<0,01
<0,02
mg/l
•
Chloride
42,1
43,55
mg/l
103%
0,5
Sulphate
39,4
0,5
42,46
mg/l
108%
Orthophosphate
0,090
0,001
<0,02
mg/l
FN
Boron
<0,02
mg/l
DOC
4,06
0,05
Total P (as PO4)
0,148
0,002
5,58
mg/l
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
137%
Deviation
Recovery
140
130
120
110
100
FN
90
80
70
60
Orthophosphate
Total hardness
Potassium
Nitrite
Chloride
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BI
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
359
5,5
µS/cm
°d
101%
102%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,92
178,2
mmol/l
mg/l
99%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,50
6,52
mg/l
mg/l
104%
97%
Sodium
Potassium
36,8
7,55
0,3
0,04
37,37
7,68
mg/l
mg/l
102%
102%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,95
0,10
mg/l
mg/l
102%
120%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,06
8,8
mg/l
mg/l
120%
110%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
26,58
0,09
mg/l
mg/l
117%
110%
Boron_1
DOC
0,058
2,63
0,001
0,04
3,28
mg/l
mg/l
125%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
mg/l
mg/l
Silicon
4,56
0,12
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BJ
Parameter
Recovery
[%]
Result
±
Unit
Recovery
475
29
µS/cm
99%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
1,78
0,036
mmol/l
99%
Hydrogen carbonate
106
1
109
2,2
mg/l
103%
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
Nitrate
50,5
1,0
48,4
3,9
mg/l
96%
Nitrite
0,040
0,001
0,0419
0,0042
mg/l
105%
Ammonium
<0,01
<0,013
0,0019
mg/l
•
Chloride
42,1
42,9
1,3
mg/l
102%
0,5
°d
mg/l
Sulphate
39,4
0,5
38,4
5,8
mg/l
97%
Orthophosphate
0,090
0,001
0,0919
0,0046
mg/l
102%
Boron
<0,02
DOC
4,06
0,05
4,61
0,92
mg/l
114%
Total P (as PO4)
0,148
0,002
0,153
0,038
mg/l
103%
KMnO4-Index
3,40
0,09
Silicon
2,28
0,05
mg/l
mg/l
2,59
0,65
mg/l
114%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BJ
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
353
21
µS/cm
°d
99%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,94
179
0,059
3,6
mmol/l
mg/l
99%
101%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,71
0,0854
0,38
0,0085
mg/l
mg/l
97%
103%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,0537
8,50
0,0081
0,26
mg/l
mg/l
107%
106%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
22,4
0,0889
3,4
0,0044
mg/l
mg/l
98%
108%
Boron_1
DOC
0,058
2,63
0,001
0,04
3,08
0,62
mg/l
mg/l
117%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
<0,15
0,038
mg/l
mg/l
•
Silicon
4,56
0,12
5,14
1,3
mg/l
113%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BK
Parameter
Recovery
[%]
Result
±
Unit
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
Hydrogen carbonate
106
1
mg/l
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
mg/l
Nitrite
0,040
0,001
mg/l
Ammonium
<0,01
Chloride
42,1
0,5
mg/l
Sulphate
39,4
0,5
mg/l
Orthophosphate
0,090
0,001
mg/l
Boron
<0,02
DOC
4,06
0,05
mg/l
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
Recovery
µS/cm
°d
1,793
0,01
mmol/l
100%
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BK
Parameter
Recovery
[%]
Result
±
Unit
Conductivity
Total hardness
356
5,40
1
0,05
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
mg/l
mg/l
Ammonium
Chloride
0,050
8,02
0,001
0,02
mg/l
mg/l
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
mg/l
mg/l
Boron_1
DOC
0,058
2,63
0,001
0,04
mg/l
mg/l
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
mg/l
mg/l
Silicon
4,56
0,12
mg/l
Recovery
µS/cm
°d
2,946
0,02
mmol/l
mg/l
100%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BL
Parameter
Recovery
[%]
Result
±
Unit
Recovery
99%
Conductivity
479
1
475,5
9,5
µS/cm
Total hardness
9,47
0,07
9,41
0,19
°d
99%
Alkalinity
1,79
0,01
1,80
0,04
mmol/l
101%
100%
Hydrogen carbonate
106
1
106,4
2,2
mg/l
Calcium
37,5
0,3
36,6
0,7
mg/l
98%
Magnesium
18,3
0,2
18,7
0,4
mg/l
102%
Sodium
26,8
0,2
Potassium
2,52
0,03
Nitrate
50,5
1,0
51,4
3,1
mg/l
102%
Nitrite
0,040
0,001
0,039
0,002
mg/l
98%
Ammonium
<0,01
Chloride
42,1
mg/l
mg/l
<0,02
0,5
42,8
mg/l
•
2,6
mg/l
102%
Sulphate
39,4
0,5
40,2
2,4
mg/l
102%
Orthophosphate
0,090
0,001
0,090
0,006
mg/l
100%
Boron
<0,02
mg/l
DOC
4,06
0,05
4,13
0,17
mg/l
102%
Total P (as PO4)
0,148
0,002
0,146
0,010
mg/l
99%
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BL
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
357,8
5,38
7,2
0,11
µS/cm
°d
101%
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,96
177,5
0,06
3,6
mmol/l
mg/l
100%
100%
Calcium
Magnesium
27,5
6,73
0,3
0,08
27,3
6,8
0,5
0,2
mg/l
mg/l
99%
101%
Sodium
Potassium
36,8
7,55
0,3
0,04
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,93
0,081
0,30
0,004
mg/l
mg/l
101%
98%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,053
8,31
0,003
0,50
mg/l
mg/l
106%
104%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
23,3
0,094
1,4
0,007
mg/l
mg/l
102%
115%
Boron_1
DOC
0,058
2,63
0,001
0,04
2,75
0,11
mg/l
mg/l
105%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,097
0,007
Silicon
4,56
0,12
mg/l
mg/l
mg/l
mg/l
111%
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BM
Parameter
Result
±
Unit
Recovery
Conductivity
479
1
474
µS/cm
99%
Total hardness
9,47
0,07
9,07
°d
96%
Alkalinity
1,79
0,01
1,65
mmol/l
92%
Hydrogen carbonate
106
1
100
mg/l
94%
Calcium
37,5
0,3
36,8
mg/l
98%
Magnesium
18,3
0,2
17,0
mg/l
93%
Sodium
26,8
0,2
24,9
mg/l
93%
Potassium
2,52
0,03
2,68
mg/l
106%
Nitrate
50,5
1,0
49,2
mg/l
97%
Nitrite
0,040
0,001
0,044
mg/l
110%
Ammonium
<0,01
0,016
mg/l
FP
Chloride
42,1
41,5
mg/l
99%
0,5
Sulphate
39,4
0,5
39,4
mg/l
100%
Orthophosphate
0,090
0,001
0,113
mg/l
126%
Boron
<0,02
<0,01
mg/l
•
DOC
4,06
0,05
9,71
mg/l
239%
Total P (as PO4)
0,148
0,002
0,121
mg/l
82%
KMnO4-Index
3,40
0,09
2,51
mg/l
74%
Silicon
2,28
0,05
2,72
mg/l
119%
Recovery
[%]
Deviation
Recovery
140
130
120
110
FP
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BM
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
351
5,02
µS/cm
°d
99%
93%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,63
160
mmol/l
mg/l
89%
90%
Calcium
Magnesium
27,5
6,73
0,3
0,08
26,1
5,96
mg/l
mg/l
95%
89%
Sodium
Potassium
36,8
7,55
0,3
0,04
32,3
6,49
mg/l
mg/l
88%
86%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,34
0,088
mg/l
mg/l
89%
106%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,027
7,80
mg/l
mg/l
54%
97%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
21,9
0,108
mg/l
mg/l
96%
132%
Boron_1
DOC
0,058
2,63
0,001
0,04
0,053
5,62
mg/l
mg/l
91%
214%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,110
3,18
mg/l
mg/l
126%
82%
Silicon
4,56
0,12
11,4
mg/l
250%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BN
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
480
28,8
µS/cm
100%
Total hardness
9,47
0,07
9,57
0,718
°d
101%
Alkalinity
1,79
0,01
1,72
0,163
mmol/l
96%
Hydrogen carbonate
106
1
102
9,7
mg/l
96%
Calcium
37,5
0,3
38,5
2,31
mg/l
103%
Magnesium
18,3
0,2
18,2
2,19
mg/l
99%
Sodium
26,8
0,2
27,1
1,76
mg/l
101%
Potassium
2,52
0,03
2,51
0,251
mg/l
100%
Nitrate
50,5
1,0
52,9
5,55
mg/l
105%
Nitrite
0,040
0,001
0,040
0,0040
mg/l
100%
Ammonium
<0,01
Chloride
42,1
<0,04
mg/l
•
0,5
44,1
3,97
mg/l
105%
40,6
3,65
mg/l
103%
Sulphate
39,4
0,5
Orthophosphate
0,090
0,001
Boron
<0,02
mg/l
•
DOC
4,06
0,05
4,13
0,248
mg/l
102%
Total P (as PO4)
0,148
0,002
0,110
0,0110
mg/l
74%
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
mg/l
<0,020
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BN
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
350
5,55
21,0
0,416
µS/cm
°d
98%
103%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,86
172
0,272
16,3
mmol/l
mg/l
97%
97%
Calcium
Magnesium
27,5
6,73
0,3
0,08
28,5
6,83
1,71
0,819
mg/l
mg/l
104%
101%
Sodium
Potassium
36,8
7,55
0,3
0,04
36,8
7,61
2,39
0,761
mg/l
mg/l
100%
101%
Nitrate
Nitrite
4,87
0,083
0,11
0,001
4,88
0,084
0,513
0,0084
mg/l
mg/l
100%
101%
Ammonium
Chloride
0,050
8,02
0,001
0,02
0,062
8,28
0,0062
0,746
mg/l
mg/l
124%
103%
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
23,1
2,08
mg/l
mg/l
101%
Boron_1
DOC
0,058
2,63
0,001
0,04
0,061
2,65
0,0085
0,159
mg/l
mg/l
105%
101%
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
0,076
0,0076
mg/l
mg/l
87%
Silicon
4,56
0,12
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BO
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
479
1
Total hardness
9,47
0,07
µS/cm
Alkalinity
1,79
0,01
Hydrogen carbonate
106
1
Calcium
37,5
0,3
41,08
1,39
mg/l
110%
Magnesium
18,3
0,2
15,68
0,43
mg/l
86%
Sodium
26,8
0,2
Potassium
2,52
0,03
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
0,5
42,53
0,60
mg/l
101%
Sulphate
39,4
0,5
39,07
0,70
mg/l
99%
Orthophosphate
0,090
0,001
Boron
<0,02
DOC
4,06
0,05
mg/l
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
°d
0,18
0,075
mmol/l
10%
mg/l
mg/l
mg/l
46,47
0,40
mg/l
92%
mg/l
mg/l
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BO
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
µS/cm
°d
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
0,30
0,075
mmol/l
mg/l
10%
Calcium
Magnesium
27,5
6,73
0,3
0,08
25,05
9,12
1,39
0,43
mg/l
mg/l
91%
136%
Sodium
Potassium
36,8
7,55
0,3
0,04
Nitrate
Nitrite
4,87
0,083
0,11
0,001
Ammonium
Chloride
0,050
8,02
0,001
0,02
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
Boron_1
DOC
0,058
2,63
0,001
0,04
mg/l
mg/l
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
mg/l
mg/l
Silicon
4,56
0,12
mg/l
mg/l
mg/l
4,85
0,40
7,63
0,60
23,21
0,70
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
100%
95%
102%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131A
Laboratory BP
Parameter
Recovery
[%]
Result
±
Unit
Recovery
479
14
µS/cm
100%
Conductivity
479
1
Total hardness
9,47
0,07
Alkalinity
1,79
0,01
1,77
Hydrogen carbonate
106
1
104,9
Calcium
37,5
0,3
mg/l
Magnesium
18,3
0,2
mg/l
Sodium
26,8
0,2
mg/l
Potassium
2,52
0,03
mg/l
Nitrate
50,5
1,0
Nitrite
0,040
0,001
Ammonium
<0,01
Chloride
42,1
°d
0,05
mmol/l
99%
mg/l
99%
mg/l
0,040
<0,020
0,003
mg/l
100%
mg/l
•
0,5
mg/l
Sulphate
39,4
0,5
mg/l
Orthophosphate
0,090
0,001
mg/l
Boron
<0,02
DOC
4,06
0,05
mg/l
Total P (as PO4)
0,148
0,002
mg/l
KMnO4-Index
3,40
0,09
mg/l
Silicon
2,28
0,05
mg/l
mg/l
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
Chloride
Orthophosphate
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon
Sample
N131B
Laboratory BP
Parameter
Recovery
[%]
Result
±
Unit
Recovery
Conductivity
Total hardness
356
5,40
1
0,05
357
11
µS/cm
°d
100%
Alkalinity
Hydrogen carbonate
2,96
177
0,02
1
2,93
175,7
0,09
mmol/l
mg/l
99%
99%
Calcium
Magnesium
27,5
6,73
0,3
0,08
mg/l
mg/l
Sodium
Potassium
36,8
7,55
0,3
0,04
mg/l
mg/l
Nitrate
Nitrite
4,87
0,083
0,11
0,001
Ammonium
Chloride
0,050
8,02
0,001
0,02
Sulphate
Orthophosphate_1
22,8
0,082
0,3
0,002
mg/l
mg/l
Boron_1
DOC
0,058
2,63
0,001
0,04
mg/l
mg/l
Total P (as PO4)_1
KMnO4-Index
0,087
3,90
0,002
0,08
mg/l
mg/l
Silicon
4,56
0,12
mg/l
0,082
0,005
0,050
0,008
mg/l
mg/l
mg/l
mg/l
99%
100%
Deviation
Recovery
140
130
120
110
100
90
80
70
60
Total hardness
Potassium
Nitrite
DOC
KMnO4-Index
Calcium
Sodium
Nitrate
Ammonium
Sulphate
Silicon

Proficiency Testing Scheme for Water Analysis - Cooperation IFA

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