Epimerization of chlorophyll derivatives. V. Effects of the central

Transcription

BULLETIN
OF THE
CHEMICAL SOCIETY
OF JAPAN
Volume 65
1992
Tadamasa SHIDA, Editor-in-Chief
T a r o SAITO, Senior Associate Editor
Editorial Board
Gin-ya ADACHI
Yasuhiro AOYAMA
Toshiaki ENOKI
Ryuichi IKEDA
TsuneoIMAMOTO
Suehiro IWATA
Nobumasa KAMIGATA
T a k a y u k i KAWASHIMA
T a k u j i KAWASHIMA
N a o y u k i KOIDE
Yoshihisa MATSUDA
Kazuko MATSUMOTO
H i d e y u k i MATSUMOTO
Naohiko MIKAMI
A k i r a MIYAMOTO
H i r o m i c h i NAKAHARA
Yoshio NAKAMURA
Koichi NARASAKA
Keiko NISHIKAWA
Hiroshi OGINO
Koichi OHNO
Yoshiteru SAKATA
Mitsuo SERINE
Masahiro TADA
T a k a s h i TAKAHASHI
K a z u y u k i TATSUMI
T o s h i h i r o TOMINAGA
S h i n k i c h i YAMADA
Gaku YAMAMOTO
T a k a k a z u YAMAMOTO
K e n i c h i YOSHIKAWA
Published by
The Chemical Society of Japan
5, Kanda-Surugadai 1-Chome, Chiyoda-ku, Tokyo 101, Japan
©
1992 by The Chemical Society of Japan
December, 1992|
3513
AUTHOR INDEX
AUTHOR INDEX TO VOLUME 65, 1992
In this Author
author of the paper.
Index,
titles of papers are listed after the name of each
For complete authorship
the original papers should be
consulted.
A B D E L A T I F , Fathy F. Molecular Interactions between Triazene 1-Oxides and Tetracyanoethylene 553
A B D E L H A M I D , Hamide Synthesis of 3-(Alditol-l-yl)triazolo[4',3': 2,3]-l,2,4-triazino(5,6-6]indoles 546
A B E , Koji Surface Adsorption and Micelle Formation of Dodecyltrimethylammonium Chloride and Dodecylammonium Chlo
ride Mixture 858
A B E , Masaaki Kinetic Studies on the Terminal Pyridine
Exchange Reactions of Some Oxo-Acetate Bridged Trinuclear
Ruthenium Complexes. Influence of the Metal Oxidation State
and Non-Leaving Terminal Ligand (CO) 1411
A B E , Masaaki X-Ray Structure, Ligand Substitution, and Other
Properties of Trinuclear Ruthenium Complex, [RU3(M3-0)(MCeHsCOOMpyfcKPFe) (py=pyridine), and X-Ray Structure of
Dinuclear Ruthenium Complex, [RîM-CeHsCOO^Cl] 1585
A B E , Masahiko Syntheses of Azobenzene Derivatives Having
Fluoroalkyl Chain and Their Monomolecular Film Formation
at the Air/Water Interface 2141
A B E , Mitsuo Intercalation and Bilayer Formation of Phospholi
pids in 7-Type Layered Transition Metal Phosphates 180
A B E , Noritaka Synthesis and Some Reactions of 2-Amino-lazaazulene-3-carbaldehyde
340
A B E , Noritaka Synthesis and Some Reactions of Ethyl 2-[2(Substituted Methyleneamino)anilino]cyclohepta[^]pyrrole-3carboxylates 1538
A B E , Noritaka Cycloaddition Reactions of 2-Acetylamino-, 2Alkylamino-, 8-Ethylamino-, and 8-Acetylamino-l-azaazulenes
with Dimethyl Acetylenedicarboxylate 1784
A B E , Shigeru The Palladium-Catalyzed Cross-Coupling Reac
tion of Enol Acetates of α-Bromo Ketones with l-Alkenyl-,
Aryl-, or Alkylboron Compounds; A Facile Synthesis of Ketones
and Their Enol Acetates 2863
A B E , Yuriko Kinetics and Mechanism of the Complex Forma
tion Reactions of Cobalt(II) with Chloride, Bromide, Iodide, and
Azide Ions, 2,2'-Bipyridine, 2,2':6',2"-Terpyridine, and Tris(2pyridyl)amine in Hexamethylphosphoric Triamide 2280
A B I K O , Toshiya A Novel Synthesis of Allenic Lactones by Use
of the [2,3]Sigmatropic Rearrangement of Cyclic Propargylsulfonium Ylides 2471
ADACHI, Fumiya Thiolate-Bridged Binuclear Nickel(II) Com
plexes with a Mixed-Spin State 512
ADACHI, Gin-ya Synthesis of Water-Soluble Lanthanide Por
phyrin Sandwich Complexes: Bis(tetrapyridylporphyrinato)
Cerium(IV), [Ce(tpyp)2], and Bis(tetramethylpyridylporphyrinato) Cerium(IV), [Ce(tmpyp) ] 1990
ADACHI, Gin-ya Electrical Properties and Sinterability for
Lithium Germanium Phosphate Lii+ M*Ge2-*(P04)3, M=A1,
Cr, Ga, Fe, Sc, and In Systems 2200
ADACHI, Gin-ya Mutual Separation Characteristics and Mech
anism for Lanthanoid Elements via Gas Phase Complexes with
Alkaline Metal and/or Aluminium Chlorides 2724
ADACHI, Kazuo Studies on Aromatic Sesquiterpenes. XIII.
Synthesis of Lacinilene A and Its Structural Isomer 2851
2
x
A D A C H I , Masahiro Preparation and Characterization of
Cobalt(III) Complexes Containing l,l'-Bis(diphenylphosphino)ferrocene (dppf) or l,l'-Bis(dimethylphosphino)ferrocene (dmpf)
as a Bidentate Ligand, and Molecular Structures of [Co(acac)2(dmpf)]B(C H )4 and [Co(dtc)2(dmpf)]B(C H )4 (acac=2,4pentanedionate ion, dtc=dimethyldithiocarbamate ion) 2037
A G A R W A L A , U. C. Cyanodithioformate Complexes of Cyclopentadienylruthenium(II). Synthesis, Spectral and Electro
chemical Study 3398
A I H A R A , Jun-ichi Stability of Large Polycyclic Aromatic
Hydrocarbons in the Diffuse Interstellar Medium 597
AIMOTO, Saburo Protein Synthesis Using S-Alkyl Thioester of
Partially Protected Peptide Segments. Synthesis of DNABinding Protein of Bacillus stearothermophilus 3055
AIZAWA, Shoichi Abundance of Cadmium in Paleozoic Lime
stones in Japan 2734
A K A I W A , Hideo Slab Optical Waveguide with Octadecylsilane
Coated Surface for Absorption Detector of Flow Analysis 1581
A K A I W A , Hideo Extractive Separation of Trace Amounts of
Cu", Fe , and G a from A l on the Basis of HSAB Rule 2537
A K A I W A , Hideo Abundance of Cadmium in Paleozoic Lime
stones in Japan 2734
A K A I W A , Hideo Copper(II) Complexing Capacity of River
Waters in the Urban Area 3485
A K I M O T O , K e i Electrochemical Investigations of High-Spin
(10,20-Diaryletioporphyrinato II) Iron(III) Complexes 23
Α Κ Ι Υ Α Μ Α , Fuminori Electrochemically Oxidative Polymeriza
tion of 1,2,3,4,-Tetrahydronaphthalene 2872
Α Κ Ι Υ Α Μ Α , Masayasu JV-Hydroxy Amides. X. Synthesis of a
Nonapeptide with an Ala-(HO)Gly-Ala Sequence and Its Spec
tral and Iron(III) Holding Properties 1356
Α Κ Ι Υ Α Μ Α , Takahiko A Chiral Synthesis of D-mjyo-Inositol 1Phosphate Starting from L-Quebrachitol 366
Α Κ Ι Υ Α Μ Α , Takahiko A1C1 -N, A^Dimethylaniline: A Novel
Benzyl and Allyl Ether Cleavage Reagent 1932
Α Κ Ι Υ Α Μ Α , Takeo Photochemical Reduction of (r? -Cyclopentadieny 1)( 1,2-disubstituted
1,2-ethy lenedichalcogenolato)cobalt(III) and (?7 -CyclopentadienylXl,2-benzenedithiolato)cobalt(III) Complexes in the Presence of Triethanolamine
1047
A K I Y O S H I , Kazunari A Water-Soluble Spin Probe Newly De
veloped for Liposomal Studies 1041
A K U T A G A W A , Susumu Syntheses and Structures of Novel
Ruthenium(II)-Chiral Diphosphine Complexes 1595
A K U T S U , Hideo Determination of the Molar Absorption Coeffi
cients of c-Type Cytochromes Using Optically Transparent
Thin-Layer Electrodes 424
A L - K A A B I , Sharifa Soltan Studies on Fused 2(li7)-Pyridenethiones: New Routes for the Synthesis of Fused IHPyrazolo[3,4-6]pyridines and Fused Thieno[2,3-6]pyridines
2241
A L I , Mahammad Kinetics and Mechanism of the Oxidation of
Formate and Malonate with (fra»s-l,2-Cyclohexanediamine6
MI
5
6
m
5
m
3
5
5
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
3514
iV,N,/V'yV'-tetraacetato)manganate(III) in Aqueous Medium
517
A L Y , Dalia Mahmoud A New Synthesis of Pyrazolo[l,5c]pyrimidines from Acetylenic ß-Diketones 3419
Α Μ Α , Tomoharu The Isomerism of the (Ethylenediamine-MWdipropionatoXethylenediamine)cobalt(III) Ion and Its Stereose
lective Isomerization Reaction 175
Α Μ Α , Tomoharu Preparation and Stereochemistry of the
Mixed-Ligand Complex, Ammine(ethylenediamine)(ethylenediamine-N-acetato)cobalt(III) 1920
A M A N O K U R A , Natsuki Direct Iodination of Aromatic Com
pounds with Iodine and Alumina-Supported Copper(II) Chloride
or Sulfate 306
A M B E , Fumitoshi Mössbauer Emission Spectroscopy of Fe
Arising from M n in Metal and Oxides of Chromium 1
A M B E K A R , Salvottam Y . The Reactions of Nitrile OxideQuinone Cycloadducts. I I . The Reactions of 2,5-Di-f-butyl-/>benzoquinone with Nitrile Oxides: 1:2 Cycloaddition and Base
Induced Ring Transformation of the Cycloadducts 2484
ANDO, Kenji Hydrosilylation of 1,4-Bis(trimethylsilyl)butadiyne and Silyl-Substituted Butenynes 1280
ANDO, Tadashi Preparation and Characterization of Cobalt(III)
Complexes Containing l,l,l-Tris(dimethylphosphinomethyl)ethane (mmtp), and the Crystal Structure of [Co(mmtp)2][Co(CN)6]-2.25H 0 2748
ANDO, Takashi Selectivity in Catalytic Dehydrogenation with
Active Manganese Dioxide 1149
A N J I K I , Atsushi Binuclear Nickel(H) Complexes of Schiff Bases
Derived from Salicylaldehydes and l,«-Diamino-«'-hydroxyalkanes (w,«-3,2; 4,2; and 5,3) Having an Endogenous
Alkoxo Bridge and a Pyrazolato Exogenous Bridge 334
ANPO, Masakazu Fluorescence Spectra of 1-Naphthol During
the Sol-Gel Process of a Mixed Aluminum-Silicon Alkoxide
(Si: Al=94:6) 720
A O K I , Izuo Determination of Fluoride Ion by a Flow Injection
Analysis Based on the Formation of a Fluorescent AluminiumSchiff Base Complex 911
A O K I , Masayoshi Reactions of Water and Dinitrogen Monoxide
Adsorbed on Cation-Exchanged Zeolite with Excess Electrons
Generated by Gamma-Radiation 140
A O K I , Yutaka Acyliminium Cyclization of Chiral 5-(4-Alkenyl)5-hydroxy-2-pyrrolidinone Derivatives 2866
AONO, Hiromichi Electrical Properties and Sinterability for
Lithium Germanium Phosphate Lii+JVW^-^POita M=A1>
AONO, Shigetoshi Photoinduced Electron Transfer between
Zinc Protoporphyrin Reconstituted Myoglobin and Methylviologen 591
A O Y A G I , Haruhiko Refolding of Trimeresurus
flavoviridis
Phospholipases A2 2655
A O Y A G I , Toshiaki Aromatization of Ethylene and C4 Hydrocarbons Using a Thermal Diffusion Column 274
A O Y A M A , Hiromu Photochemical Reactions of 4-Oxo Carboxylic Esters: Remote Hydrogen Abstraction and Cis-Trans Isomerization 3498
A O Y A M A , Yasuhiro Multiple Electrostatic Interaction of Polycationic Chitosan Oligomers with Nucleic Acids: Polyamine
Promoted Stabilization of the Α-Form of RNA and DNA in
Aqueous Solutions 1755
A O Y A M A , Yasuhiro Enantioselectivity in the Interaction of
Calf Thymus DNA with Acridine Derivatives Having an Amino
Ester or Amino Alcohol Substituent 2050
A R A I , Gorou Electrochemical Studies of Poly(mercaptohydroquinone) and Poly(mercapto-/>-benzoquinone) Films Prepared by
Electrochemical Polymerization. V I . Electroreduction of LCystine on Thiolates Fixed in the Polymer Film 594
ARAI,
Hiroki Tetrakis(thiolato)nickelate(II), [Ni(RS) ] -;
Ligand Dissociation and Electronic Spectra 1799
A R A I , Masahiko Effects of Surface Pretreatments of a Glass
57
57
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4
2
[Vol. 65, No. 12
Substrate on the Properties of Tin Oxide Film Prepared by
Plasma-Assisted Chemical Vapor Deposition 1141
A R A I , Shigeyoshi Thermal and Infrared Multiphoton Decompo
sitions of 7-Butyrolactone in the Vapor Phase 3112
A R A I , Tatsuo Qualitative Triplet Potential Energy Curves of
Arylethylenes along the Double Bond Twisting 1463
A R A K A W A , Hironori Selective Hydrogenation of Carbon Diox
ide to Methanol on Cu-ZnO/Si02 Catalysts Prepared by Alkox
ide Method 2520
A R A K A W A , Hiroshi The Structure around the Nitrite Ion in
Concentrated Aqueous Solutions 2154
A R A K I , Koji Ru(6,6'-Diamino-2,2'-bipyridine)3 : Effect of Interligand Steric Strain on the Spectroscopic, Photochemical, and
Electrochemical Properties of the Complexes 1220
A R A K I , Shuki Allylation of Carbonyl Compounds with Cata
lytic Amount of Indium 1736
A R A M A T A , Akiko Infrared Spectroscopic Observation of
Adsorbed CO Intermediately Formed in the Electrochemical
Reduction of C 0 at a Nickel Electrode 3008
A R A S E , Akira The Hydroboration of 3-Chloro-l-trimethylsilyl1-propyne with Dialkylboranes and Its Application to the Syn
theses of (£)-3-Trimethylsilyl-2-alkenes and 3-Trimethylsilyl-lalkenes 685
A R A S E , Akira The Hydroboration of 3-Chloro-l-iodo-l-propyne
with Dialkylboranes, and Its Application to the Syntheses of
Some Geminally Dialkylated Propene Derivatives 3294
A R A T O N O , Makoto Surface Adsorption and Micelle Formation
of Dodecyltrimethylammonium Chloride and Dodecylammonium Chloride Mixture 858
A R A T O N O , Yasuyuki Effect of y-Ray Irradiation on the Recoil
Tritium Reaction in Xenon-Hydrogen Mixtures at 77 and 4.2 K.
Competition of the Tunneling Reaction with the Combination
Reaction 735
A R I C H I , Shizuo Solution Properties of Poly(4-vinylpyridine) in
Aqueous Solutions of Sulfuric Acid 3108
A R I F U K U , Fumihiro The Catalytic Electroreduction of Dioxygen on Iron Protoporphyrin IX Modified Glassy Carbon Elec
trodes 1491
A R M O U R , Margaret-Ann Synthesis of 2-Amino-2,5,6-trideoxy5-phenylphosphinyl-L-galactopyranose. The P-in-the-Ring Ana
logue of L-Fucosamine 2922
A R P A D J A N , Sonja Gas Chromatographic Determination of
Solvation Number by an Investigation of the Extraction Proc
esses 2289
A S A D A , Takahiro "Syn-Effect " i n the Conversion of (£)-Vinylic
Sulfones to the Corresponding Allylic Sulfones 75
A S A D A , Takahiro Reactions of (£)-2-Iodo-l-tosyl-l-alkenes as
Useful Synthetic Intermediates 1379
A S A I , Kichizö Mössbauer Emission Spectroscopy of Fe
A S A K A W A , Masumi Enantioselectivity in the Interaction of
A S A O K A , Morio Stereochemical Aspects on the BF · E t 0 Catalyzed Ring Contraction of 5-Substituted 2,3-Epoxycyclohexanones 3206
A S H I D A , Tamaichi Crystal Structures of N-Benzoyl Derivatives of 8-Oxa-6-azabicyclo[3.2.1]octan-7-one, ε-Caprolactam
and 2-Pyrrolidone 886
A S H I D A , Tamaichi Crystal Structure of N-Cinnamoyl-8-oxa-6azabicyclo[3.2.1]octan-7-one 1138
A T A , Masafumi ESR Spectra of Some Allene Radicals in LowTemperature Matrices 2442
A W A D , Ibrahim M.-A. Studies in Vilsmeier-Haack Reaction.
IX. Synthesis and Application of Novel HeterocycloSubstituted Furo^^-c^^-cldipyrazole Derivatives 1652
A Z U M A , Nagao Molecular and Crystal Structure of 3,5,5Trimethyl-2-(2-methyl-2-nitropropyl)-2-cyclohexen-l-one Pos
sessing Molecular Asymmetry 2860
2+
2
57
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December, 1992]
3515
AUTHOR INDEX
A Z U M A , Shigeki Thermodynamic Studies on the Complexation
of o-Phenylenediamine-/V,/v',A^',iV'-tetraacetate with Divalent
Cadmium, Mercury, and Lead Ions in Aqueous Solutions 2333
B A B A , Akio Allylation of Aldehydes by Allyl- and Crotyltributyltin in the Presence of Catalytic Amounts of Bu2SnCl2 Complex
66
B A B A , Kazuhiko Mechanochemical Reaction of Calcium Alginate Hydrogel due to a Counterion Exchange 121
B A B A , Norihisa Crystal Structures of Mono- and Di-nuclear
Nickel(II) Complexes Derived from the Substitution Reaction of
[Ni(Me2[14]dienatoN )JI and Each of Benzoyl Chloride and
Isophthaloyl Dichloride 258
B A B U , Kondapaneni S.-Chandra Studies on w-CdSe/Ti
Semiconductor Septum Based Photoelectrochemical Solar Cell
in Regard to the Influence of Structural and Compositional
Characteristics of the Semiconductor Electrode 1072
B A N D O , Takashi Efficient Synthesis of 2-Vinyl-y-butyrolactones and 2-Vinyl-y-butyrolactams by Palladium-Catalyzed
Decarboxylase Carbonylation 97
B A N E R J E E , Pradyot Kinetics and Mechanism of the Oxidation of Formate and Malonate with (/m«s-l,2-Cyclohexanediamine-iV.MA^'.A^'-tetraacetatoJmanganateilll)
in
Aqueous
Medium 517
B A N E R J E E , Sukhendu Bikash Transfer of Electronic Excitation Energy from 2,2-Diphenylethanol to 2,6-Diphenylpyridine
in Solvents of Different Viscosity 2196
B E R M E J O G O N Z A L E Z , Francisco Efficient Preparation of a
Valuable Intermediate in the Synthesis of (-)-Swainsonine
567
B E R M E J O G O N Z A L E Z , Francisco Stereochemical Outcome
of Aldol Reaction of a 6-C-Substituted D-Mannose Derivative
575
B H A T , Subray Narayan Dye-Surfactant Interaction in Submicellar Concentration Range 1089
B H A T T A C H A R J E E , Ashis Adsorption-Induced Electrical Conductivity of Some Ferrocene Derivatives: Rates of Adsorption
and Desorption of Vapors 3462
B H A T T A C H A R Y Y A , Moni Mohan A New Estimate of Ionic
Values of Viscosity ß-Coefficient, NMR ß'-Coefficient and the
Ion-Solvent Interactions at Extended Temperatures in Aqueous Solutions 1170
B H U T A N I , Punita Studies on Fused ^-Lactams: Synthesis of 1Aza Analogs of Cephem 2246
B O R O V K O V , Victor V. Synthesis and Properties of
Pheophorbide-Quinone Compounds 1533
B O R T U N , Anatoly Ivanovich On the Sorption of d-Metal Ions
on Mixed Phosphates of the 4-th Group Elements 1617
B R A N D I S , Alexander S. Synthesis and Properties of
B U D O V I T S K A Y A , Tatjana Antonovna On the Sorption of dMetal Ions on Mixed Phosphates of the 4-th Group Elements
1617
B U R G E R , Kaiman Utilization of Enzymatic Digestion for the
Study of the Macromolecular Effect in Complexation Processes. Protonation and Copper Coordination Equilibria of Hyaluronate and Its Fragments 2211
B U T S U G A N , Yasuo Allylation of Carbonyl Compounds with
Catalytic Amount of Indium 1736
C A T I V I E L A , Carlos Chiral 2-Cyanocinnamates in Conjugate
Addition Asymmetric Enolate Trapping Reactions 1657
C H A K R A B A R T I , Subhasis Surface-Enhanced Raman Spectra
of Isomeric Picolines Adsorbed on Silver Sols 1697
CHANEV, Ch. Gas Chromatographic Determination of Solvation
Number by an Investigation of the Extraction Processes 2289
C H A U D H U R I , Mihir K. Complex Fluoroberyllates. Synthesis
and Physicochemical Characterization of Mixed-Fluoro Complexes of Beryllium Containing Hydrogenoxalate (HC2O4"),
Glycinate, and Dihydrogenphosphate (H P0 ~) as Co-Ligands
522
4
2
4
CHAUHAN, R a k a m Singh Extractive Separation and Photometric Determination of Vanadium with Benzoylacetone 1033
CHAUHAN, V i r a n d e r Singh Synthesis and Biological Evaluation of Dehydrophenylalanine Containing Substance Ρ Frag
ments 3412
CHEN, Yun Chiral Stationary Phases Derived from {—)-anti
Head-to-Head Coumarin Dimer: Preparation, Characterization,
and Chiral Recognition Ability 3423
CHENG, Pai-hui Mechanistic Study of Acid-Catalyzed Proton
Exchange in Lactams 562
CHIJIMATSU, Tamiko The Role of a Spin-Coupled Interme
diate in a System Consisting of Tetraminecobalt(III) Complexes
and Catechols —A Model Intermediate of Dioxygenase Reac
tion— 1225
C H I K A M A T S U , Hiroaki The Biogenetic-Type Cyclization of
the Unsaturated Monocyclic Alcohol with Formic Acid; Facile
Synthesis of the Tricarbocyclic Alcohol, (+)-2-Epi-allo-cedrol
203
CHOWDHURY, Pradyot Kumar C 0 User Induced Sensi
tized Dissociation of Ethylene Oxide 1691
CHOWDHURY, Pradyot K u m a r Real Time Optical Observa
tion of Nascent Hexafluorobutadiene in the IR Multiphoton
Dissociation of Decafluorocyclohexene 3455
CHUNG, Jong Shik Shape-Selectivity Effect of Highly Reduced
Cobalt-Exchanged Zeolite in the Fischer-Tropsch Reaction
2884
CONCEPCION, Arnel B. Asymmetric Diels-Alder Reaction of
Cyclopentadiene and Methyl Acrylate Catalyzed by Chiral
Organoaluminum Reagents 3501
CORRADINI, Fulvio Viscosities and Activation Energies of
Viscous Flow of the l,2-Ethanediol/yV,/V-Dimethylformamide
Binary Solvent System 503
COSTA, T o n i m ä s o Receptor Interactions of Synthetic Morphiceptin Analogs Containing Phenylalanine Homologs in Position
4 1052
CUI, Ying-She Synthetic Photochemistry. LVIII. Intramolecular
Photocycloaddition of 2-Alkenyl-6-methyl-4i/-l,3-dioxin-4-ones
2940
D A D F A R N I A , Shayessteh Highly Selective Membrane Transport of Z n Ion by a Cooperative Carrier Composed of 1,10Diaza-18-crown-6 and Palmitic Acid 2779
D A E H N E , Lars High Polariton Reflectance in Heptamethinebis(dimethylamino)cyanine Chloride Crystal 2328
D A I A N , Chie Thermochromism of 5,10,15,20-Tetraarylporphyrins at Low Temperature 3358
D A I R O K U N O , T e t s u r o The Substituent Effects on Solvolyses
of /Ara?-2-Aryl-l-rnethylpropyl Brosylates 3072
DAS, Asim K u m a r Study of Equilibria and Kinetics of the
Interactions of Iron(III) with 8-Hydroxyquinoline and 8Hydroxyquinoline-5-sulfonic Acid in HC104-NaC104 Media
2205
DAS, Bijan Studies on the Viscosities, Conductances, and Adiabatic Compressibilities of Some Tetraalkylammonium Perchlorates in 2-Methoxyethanol 3470
DAVE, Jayrang S. Mesomorphic Characteristics of Liquid Crystalline Esters p-Methoxyphenyl/>-Alkoxycinnamates 559
DE, Gauri Sankar Kinetics and Mechanism of Substitution of
Aqua-Ligands
from cw-Diaquobis-[2-(w-tolylazo)pyridine]ruthenium(II) Complex by 1,10-Phenanthroline in Aqueous
Medium 1626
DE, Gouri Sankar Kinetics and Mechanism of Anation of cis[Ru(bpy) (H 0) ] Ion by 8-Quinolinol in Water-Ethanol Mixtures 609
DEJIMA, H i r o s h i Synthesis of 2-(Substituted Methyl)-3,4Disubstituted Pyrroles and Their Conversion into the Corresponding Porphyrins 2660
D H A K E , K. P. Mesomorphic Characteristics of Liquid Crystalline Esters />-Methoxyphenyl />-Alkoxycinnamates 559
D I A Z - D E - V I L L E G A S , Maria Dolores Chiral 2-Cyanocin2
2+
2
2
2
2+
3516
namates in Conjugate Addition Asymmetric Enolate Trapping
Reactions 1657
DING, Meng-Χίη Oxidation of 2,2,3,3-Tetramethyl-l,4-diphenyl-5,6-dithiabicyclo[2.1.1]hexane and Its Oxidation Prod
ucts: An Important Role of 1,3-Transannular Interaction in the
1,3-DithietanePart 3343
DOMEN, Kazunari Photocatalytic Hydrogen Evolution from
Aqueous Methanol Solution on Niobic Acid 1202
D U B E Y , Bharat L a i Solid-State Reaction between Zinc Hydrox
ide and 8-Quinolinol 495
D U T T A , Robin Kumar Dye-Surfactant Interaction in Submicellar Concentration Range 1089
E G U C H I , Shizuko 7-Epidenticulatolide, a New Cembranolide
with a Cyclic Peroxide Function from the Soft Coral Lobophyturn denticulatum 1182
E G U C H I , Taro Molecular Motions in Solid CD NH PbBr as
Studied by H NMR 2264
E I K I , Toshio Cd -Catalyzed Methanolysis of Phenyl Phosphatosulfate. Selectivity of Metal Ion in the Site of Cleavage of P-0
and S-0 Bond 3335
E I N A G A , Hisahiko Framework Structure, Phase Transition,
and Transport Properties in M'^r^POêCompounds (M"=Mg,
Ca, Sr, Ba, Mn, Co, Ni, Zn, Cd, and Pb) 3221
E L A S H R Y , E l Sayed H. Synthesis of 3-(Alditol-l-yl)triazolo[4',3': 2,31-1,2,4-triazino[5,6-6]indoles 546
E L N E M R , Ahmed Synthesis of 3-(AlditoM-y 1 )triazolo[4',3':2,3]-l,2,4-triazino(5,6-61indoles 546
E L R E H I M , Sayed-Sabet-Abd Cyclic Voltammetric Behavior
and Some Surface Characteristics of the Lead Electrode in
Aqueous Nal Solutions 1608
E L - F A H A M , Hassan A. Molecular Interactions between T r i azene l-Oxides and Tetracyanoethylene 553
E L - G H A N A M , Moneim Synthesis and Reactions of 1Heteroaryl-5-pheny 1-4-pentyne-1,3-diones 3509
E L - H A L I M , A. Mohamed-Abd Cyclic Voltammetric Behavior
E L G E M E I E , Galal Eldin-Hamza Studies on Fused 2(1//)
Pyridenethiones: New Routes for the Synthesis of Fused IHPyrazolo[3,4-Z>]pyridines and Fused Thieno[2,3-%>yridines
2241
E M O R I , Shuji Magnetic Properties of Cobalt(II) and Nickel(II)
Benzoate Adducts with Quinoline Analogues 1982
E N D O , Akira Synthesis of Model Compounds of Safflomin C
452
E N D O , Akira Synthesis of Syzygiol; A Skin-Tumor Promotion
Inhibitor 2552
E N D O , Kazutoyo Mössbauer Emission Spectroscopy of Fe
E N D O , K e n Enantioselectivity in the Interaction of Calf Thymus DNA with Acridine Derivatives Having an Amino Ester or
Amino Alcohol Substituent 2050
E N D O , Masayuki A Water-Soluble Spin Probe Newly Developed
for Liposomal Studies 1041
E N D O , Yuji An Isomeric Series of Thiophene-Fused Tetracyanoquinodimethanes. IV. Crystal Structure of 2:3 ChargeTransfer Salt with Tetraethylammonium 2187
E N Y O , Michio Infrared Spectroscopic Observation of Adsorbed
CO Intermediately Formed in the Electrochemical Reduction of
C0 at a Nickel Electrode 3008
E R A B I , Tatsuo Selective Preparation of l-Halo-2,6-dimethoxybenzenes from Bis(2,6-dimethoxyphenyl)dimethyltin 1389
E S U M I , Yasuaki Aromatization of Ethylene and C4 Hydrocarbons Using a Thermal Diffusion Column 274
E T O H , Takumi Thermoanalytical Study of Dioxygencobalt(III)
Complexes with AÂÊthylenebis(salicylideneaminate) and Its
Derivatives 3374
E Z U M I , Kiyoshi Spectroscopic Analysis and Geometry Assignment of the Minimum Energy Conformations of 2-Phenoxy3
3
3
l
2+
57
57
2
[Vol. 65, No. 12
pyridines and Diphenyl Ethers 2697
F A W Z Y , Mohamed Hossam Cyclic Voltammetric Behavior
F E N G , Yiqi Detection of Pitting on Cast Iron with AC Impedance
Spectroscopy 2315
F I R O U Z A B A D I , Habib Zinc Bismuthate Zn(Bi0 ) .1. A Useful
Oxidizing Agent for the Efficient Oxidation of Organic Compounds 1131
F I R O U Z A B A D I , Habib Tetrakis(pyridine)silver(II) Peroxodisulfate, [Ag(py) ]S208, a Reagent for the Oxidative Transformations 2878
F U C H I T A , Yoshio Refinement of the Crystal Structure of Pentaerythritol Tetracetate 2831
F U C H I T A , Yoshio Reactions of Hydridoruthenium(II) Complexes with Alkyl Allylic Sulfides 3027
F U E K I , Kazuo Extraction-Spectrophotometric Determination of
Average Valence of Copper in Superconductor Y-Ba-Cu-0
882
F U E K I , Kenji Effect of γ-Ray Irradiation on the Recoil T r i t i u m
Reaction in Xenon-Hydrogen Mixtures at 77 and 4.2 K. Compe
tition of the Tunneling Reaction with the Combination Reac
tion 735
F U E N O , Takayuki Dual Reactivity of Methoxymethyl Benzenesulfenate in Nucleophilic Substitution 2672
F U G A M I , Keigo Efficient Synthesis of 2-Vinyl-y-butyrolactones
and 2-Vinyl-y-butyrolactams by Palladium-Catalyzed Decarboxylative Carbonylation 97
F U J I E D A , Hiroki Abnormal Diels-Alder Reaction of 5Alkoxyoxazoles with Tetracyanoethylene and X-Ray Crystal
Structure of an Adduct 1771
F U J I I , Tsuneo Fluorescence Spectra of INaphthol During the
Sol-Gel Process of a Mixed Aluminum-Silicon Alkoxide
(Si:Al=94:6) 720
F U J I I , Yasuhiko F Nuclear Magnetic Resonance Study on the
Kinetics of the Fluoride Exchange in Uranium(VI) Fluoro Com
plex 3022
F U J I M I , Kazuhiko Effect of Inhibitors on Azo-Reduction of 4'Dimethylaminoazobenzene-2-carboxylie Acid by Clostridium
Diaphorase 2349
F U J I M O R I , Kunihide Selective Ion Transport in Acetonitrile
Across the Ionophore-Immobilized Polymer Membranes Used
as the Sensor of the Ion-Selective Electrodes 19
F U J I M O T O , Akira Molecular Orbital Considerations on Inter
action of 2-Aminopyridine with Formic Acid in the Ground
State 1002
F U J I M O T O , Akira Band Assignment of Anomalously Strong
Absorption Band of 2,6-Diaminopyridine by Interaction with
Acetic Acid 1685
F U J I M O T O , Toshiyuki Effects of Pd Dispersion on the Cata
lytic Activity of Pd/Si02 for Ethylene Hydroformylation 2565
FUJIMOTO,
Tsutomu Synthesis of [L-a-Aminomyristic
Acid ' ']gramicidin S and Its Interaction with Phospholipid
Bilayer 228
F U J I M O T O , Tsutomu Sequence Dependent CyclizationCleavage of Dipeptides from the Oxime Resin and Its Preven
tion 991
F U J I O , Katsuhiko Size of Micelles of 1-Dodecylpyridinium
Chloride in Aqueous NaCl Solutions 1406
F U J I O , Mizue Solvent Effects on the Solvolysis of Neophyl
Tosylates 46
F U J I O , Mizue The Substituent Effects on Solvolyses of threo-2Aryl-l-methylpropyl Brosylates 3072
F U J I S A W A , Tamotsu Diastereoselective Construction of 2,2,6Trisubstituted Tetrahydropyrans by Intramolecular Alkylation Reaction of Lithium Enolates Generated from a-Alkoxy
Carboxylates 3487
F U J I S H I M A , Akira Detection of Pitting on Cast Iron with AC
Impedance Spectroscopy 2315
3
4
19
3 3
2
December, 19921
AUTHOR INDEX
F U J I S H I M A , Keiko Racemization of Optically Active Aromatic
/V-Acetylamino Acids and Asymmetric Transformation of NAcetyl-2-(4-hydroxyphenyl)glycine via Salt Formation with
Optically Active a-Methylbenzylamine 965
F U J I T A , Hiroshi Synthetic Study on Peptide Antibiotic Nisin.
V. Total Synthesis of Nisin 2227
F U J I T A , Junnosuke Synthesis and Characterization of trans[CoCl2(N4Jc)] (N4j:=l ,4,7,10-Tetraazacycloheptadecane,
-cyclooctadecane, -cyclononadecane, -cycloicosane, -cyclohenicosane,
and -cyclodocosane) 191
F U J I T A , Junnosuke Preparation and Characterization of Palla
dium^) and Platinum(I) Dinuclear Complexes Bridged by 2(Dimethylphosphino)pyridine 1016
F U J I T A , Junnosuke Preparation, Stereochemistry, and Kinet
ics of Isomerization and Racemization of Bis(2,2'-bipyridine
yV,/v"-dioxide)chromium(III) Complexes Containing an Oxalate
or Malonate Ion 1233
F U J I T A , Junnosuke Preparation and Characterization of
[Co(tp)2(Me -en)] (tp=Tropolonate Ion; Me«-en («=1—4)=NMethyl Substituted Ethylenediamine), Inversion and Deutera
tion at Chiral Nitrogen Centers of [Co(tp) (Me-en or Me3-en)] ,
and Crystal Structures of [Co(tp)2(N,MMe2-en)]C104 and
/l(/?)zKS)-[Co(tp) (Me-en)]C10
1572
F U J I T A , Junnosuke Structures of Two Geometrical Isomers of
Dioxo[(S)-A -salicylidene-3-aminopyrrolidine]vanadium(V)
1725
F U J I T A , Junnosuke Molecular Structures of
ΗΤ-[ΜΜΌ (μMe Ppy>2] (MM'=Pd , PdPt, and Pt ; Me Ppy=2-(Dimethylphosphino)pyridine) and 7/r-[Pd Cl2(M-Ph Ppy)2KPh2Ppy=2(Diphenylphosphino)pyridine) 1817
Cobalt(III) Complexes Containing l,r-Bis(diphenylphosphino)ferrocene(dppf)or l,lMBis(dimethylphosphino)ferrocene(dmpf)
as a Bidentate Ligand, and Molecular Structures of [Co(acac) (dmpf)]B(C H )4
and
[Co(dtc) (dmpi)]B(C H5)4 (acac=2,4pentanedionate ion, dtc=dimethyldithiocarbamate ion) 2037
F U J I T A , Junnosuke X-Ray Structural Study of trans-[CoC\ (232N 15)]C10
(232N 15=1,4,8,11-Tetraazacyclotricosane)
2114
FUJITA,
Junnosuke
Bis{2-(dimethylphosphino)ethane-lthiolato)-nickel(II), -palladium(II), and -platinum(II) Complexes,
and Molecular Structure of the Nickel(II) Complex 2272
Cobalt(III) Complexes Containing l,l,l-Tris(dimethylphosphinomethyl)ethane (mmtp), and the Crystal Structure of
[Co(mmtp) ][Co(CN) ] · 2.25H 0 2748
Co(III)-Dimethyldithiocarbamato Complexes Containing 1,2Bis(dimethoxyphosphino)ethane. Molecular Structures of
[Co((CH3)2NC(S)S}{R P(CH )2PR2}2](BF4)2 (R=CH 0 and CH )
3042
F U J I T A , Kazumi Formation of Zinc Oxide by Homogeneous
Precipitation Method 2270
F U J I T A , Makoto An Efficient and Practical Synthesis of L-aAmino Acids Using (#)-Phenylglycinol as a Chiral Auxiliary
2359
F U J I T A , Mitsue Selectivity in Catalytic Dehydrogenation with
Active Manganese Dioxide 1149
F U J I T A , Toshio Analysis of Ortho Effects with a Steric
Parameter Defined by the Acidic Hydrolysis Rate of OrthoSubstituted Benzamides 2343
F U J I T A , Toshio Correlation Analysis of the p/& Values of
Mono- and Di-ortho-Substituted Benzoic Acids 3157
F U J I T A N I , Yoshiteru Effect of y-Ray Irradiation on the Recoil
Reaction 735
F U J I W A R A , Hideaki An NMR Study of the Carbanions Pro
duced from Triphenylethylene and Its Methyl-Substituted
+
+
w
+
2
2
4
r
2
2
2
2
2
2
2
2
6
5
2
6
2
4
4
2
4
6
2
2
2
3
3
3517
Derivatives 2162
F U J I W A R A , Kyoko N,/V'-Di(8-quinolyl)glutararaide Exhibiting
Highly Selective and Efficient Uphill Transport of Cu(II)
through Liquid Membranes 2381
F U K A M I Y A , Narihiko Catalytic Hydrogenation of Dehydro
Quassinoids and Cytotoxic Antitumor Activity of the Hydrogen
ation Products 2684
F U K A S E , Koichi Synthesi of New Serine-Linked Oligosaccha
rides in Blood-Clotting Factors VII and IX and Protein Z. The
Syntheses of 0-a-D-Xylopyranosyl-(l-»3)-D-glucopyranose, O-aD-Xylopyranosyl-(l->3)-0-a-D-xylopyranosyl-(l->3)-D-glucopyranose, and Their Conjugates with Serine 436
F U K A S E , Koichi Synthetic Study on Peptide Antibiotic Nisin.
F U K A S E , Koichi Synthetic Study on Lipoteichoic Acid of Gram
Positive Bacteria. I . Synthesis of Proposed Fundamental Struc
ture of Streptococcus pyogenes Lipoteichoic Acid 2643
F U K A Z A W A , Hiroaki Preparation of New Nitrogen-Bridged
Heterocycles. 29. Reinvestigation on the Dehydrogenation
Reaction of 5,5a-Dihydropyrido[2,l-c]thieno[3,2-e][l,4]thiazine
Derivatives 1244
F U K A Z A W A , Yoshimasa 7-Epidenticulatolide, a New Cembranolide with a Cyclic Peroxide Function from the Soft Coral
Ijobophytu m denticulatum 1182
F U K A Z A W A , Yoshimasa Cycloaddition Reactions of 2Acetylamino-, 2-Alkylamino-, 8-Ethylamino-, and 8-Acetylamino-l-azaazulenes with Dimethyl Acetylenedicarboxylate
1784
F U K U C H I , Takashi Preparation and Characterization of transand nsHalogenobis(vicinal-dioximato)nitrosylruthenium(III)
Complexes 1807
F U K U D A , Takeshi Thermotropic Liquid Crystals Based on
Chito-Oligosaccharides. 1. Synthesis of Chitobiose Octaaikanoates and Chitotriose Undecaalkanoates and Their Thermal
Properties 1939
F U K U H A R A , Masami ENDOR Study of the Cation Radicals of
Vitamin Ε Derivatives. Relation between Antioxidant Activity
and Molecular Structure 2016
F U K U I , Kouta Anodically-Generated Br-Cl Composite Halogenating Reagents 943
F U K U N A G A , Moritaka Deuterium Isotope Effects on Aro
matic C-13 NMR Chemical Shifts. IV. Can the Isotope Shifts Be
Correlated with Bond Lengths? 2894
F U K U N A G A , Sadao Catalytic Conversion of Diethyl Tartrate
into Pyruvate over Silica-Supported Potassium Disulfate
2083
F U K U T A N I , Seishiro Estimation of the Mechanism of Fused
Aromatic Hydrocarbon Formation in Sooting Flames by Molec
ular Orbital Method 2427
F U K U T A N I , Seishiro Fuel Mixing Effects on Propagation of
Premixed Flames. I . Hydrogen+Carbon Monoxide Flames
2569
F U K U T A N I , Seishiro Fuel Mixing Effects on Propagation of
Premixed Flames. I I . Hydrogen+Methane Flames 2573
F U K U Z A W A , Shin-ichi Highly Regioselective Allylation of aEnones and Epoxides with Lithium Tetraallyllanthanoid Ate
Complex 3308
F U K U Z U M I , Shunichi Electron-Transfer Reactions from
Hydroquinone Dianions to 10-Methylacridinium Ion and a
Cobalt(III) Porphyrin 715
F U K U Z U M I , Shunichi Efficient Six-Electron Photoreduction of
Nitrobenzene Derivatives by 10-Methyl-9,10-dihydroacridine in
the Presence of Perchloric Acid 831
F U N A H A S H I , Shigenobu Kinetic Studies of the Incorporation
of the Zinc(II) Ion into Water-Soluble iV-Phenyl-Substituted
Porphyrins. Deformation Effect on the Metallation Rate 771
F U N A K I , Shunji Thiolate-Bridged Binuclear Nickel(II) Com
F U N A K O S H I , Junji A New Annulation Reagent, 2-Oxo-3-
3518
alkenylphosphonates. Reactions with Carbonyl-Stabilized Carbanions or §ilyl Enol Ethers Leading to Cyclohexenones 2456
F U N A S A K I , Noriaki Determination of the Dimerization Constant in Self-Associating Systems 314
F U N A S A K I , Noriaki The Crystal Structures of Cyanide Metmyoglobins Reconstituted with Iron(III) Complexes of Porphyrin, 5,10,15,20-Tetramethylporphyrin, and 5,10,15,20Tetraethylporphyrin 739
F U N A S A K I , Noriaki Stoichiometries and Equilibrium Constants of Cyclodextrin-Surfactant Complexations 1323
F U N A T S U , Kimito Solvent Effects on the Solvolysis of Neophyl
Tosylates 46
F U N A T S U , Tsuyoshi Rotational Distribution of CO(b $sss )
Produced in Energy Transfer Reaction from Ar( P ) to CO
1713
F U R U K A W A , Yoshihiro Motions of Methylammonium Ions in
(CH NH )3Sb2l9 Crystals Studied by H NMR 1707
F U R U S A K I , Akio Attempted Transformation of 2,3,5,6Tetrachloro-4,4-dimethoxypentacyclo[5.4.0.0 ' .0 . 0 ] undecane-8,ll-dione toward Pentaprismane Retaining Chloro
Group 2312
F U R U S A W A , Atsuko Intramolecular Radical Cyclization of
Ketene Dithioacetals 1550
F U R U T A , Hiroyuki Four Different Coordination Modes of 1,1'Bis(diphenylphosphino)ferrocene: Synthesis, X-Ray Crystal
Structure, and Iron-57 Mössbauer Spectroscopy of Four Metal
Carbonyl
Complexes
with
l,l'-Bis(diphenylphosphino)ferrocene (dppfe) 1415
F U S E , Masahiro Ru(6,6'-Diamino-2,2'-bipyridine)3 : Effect of
Interligand Steric Strain on the Spectroscopic, Photochemical,
and Electrochemical Properties of the Complexes 1220
F U S H I M I , Midori The Kinetic Study of the Oxygen-Exchange
Reaction of Some Alkylarsonates and Dialkylarsinates with
Water 1397
F U T A M I , Hiroshi A Time-Resolved EPR Study on the Photochemical α-Cleavage of Benzoin and Related Molecules 1679
F U T A M U R A , Shigeru Photobromination of Side-Chain Methyl
Groups on Arenes with TV-Bromosuccinimide —Convenient and
Selective Syntheses of Bis(bromomethyl)- and (Bromomethyl)methylarenes— 345
F U T A M U R A , Shigeru Chemical Behavior of Aromatic Radical
Cations under Superoxide-Free Electron Transfer Photooxygenation Conditions 1779
G A J U R E L , Chhabi L . An Isomeric Series of Thiophene-Fused
Tetracyanoquinodimethanes. I . Preparation and PhysicoChemical Properties 2168
G A L V E Z , Jose" Antonio Chiral 2-Cyanocinnamates in Conju
gate Addition Asymmetric Enolate Trapping Reactions 1657
G A N E S H , K. Nagappa Regioselective Allylations of Pyrimidine
Ribonucleosides Using Pd(0) Catalyst 1665
G A N G O P A D H Y A Y , Sumana Kinetics and Mechanism of the
Oxidation of Formate and Malonate with (trans-1,2-Cyc\ohexanediamine-AÂ^Â^'-tetraacetatoânganateilll) in Aque
ous Medium 517
G A N G U L Y , Tapan Transfer of Electronic Excitation Energy
from 2,2-Diphenylethanol to 2,6-Diphenylpyridine in Solvents
of Different Viscosity 2196
GAO, Zhiming Thermal Reactions of Toluene by Use of a
Clusius-Dickel Type Thermal Diffusion Column as a Reactor
586
G O C H O U , Seigo Synthesis and Photo Valence Isomerization of
Polyamide Bearing Norbornadiene Unit 2306
GODA, Ken-ichi A Convenient Synthesis of Cationic Vinylidene
and 1,2-Propadienylidene Iron Complexes by Photoreaction of
[CpFe(CO)(dppe)] BF - with 1-Alkynes 2560
G O F U K U , Youko The Kinetic Study of the Oxygen-Exchange
Water 1397
GONDO, Yasuhiko ESR Spectra of Some Allene Radicals in
3
3
3
+
2
X
3
2
6
2+
+
4
3 1 0
5 9
[Vol. 65, No. 12
Low-Temperature Matrices 2442
G O P A L A K R I S H N A N , Mannathusamy Kinetics and Mecha
nism of Oxidation of Ethyl Phenylthioacetates by BromamineB 1096
G O P A L A K R I S H N A N , Vidhya Regioselective Allylations of
Pyrimidine Ribonucleosides Using Pd(0) Catalyst 1665
GOTO, Masafumi Diastereoisomers of Platinum(II) Complexes
with Chiral TV-Substituted 1,2-Diamines. I . Structure and Iso
merization of Dichloro{(i?)-2-[(2-methyl-2-aminopropyl)amino]l-butanol)platinum(II) 1428
GOTO, Masafumi Diastereoisomers of Platinum(II) Complexes
with Chiral TV-Substituted 1,2-Diamines. I I . Structures of
Dichloro[(S)-l-(2-amino-2-methylpropyl)amino-2-propanol]platinum(II) 2118
GOTO, Midori Structural Studies of Arylazo(a,a-dimethylbenzyl)malononitriles. Evidence against the Correlation
between Bond Length and Reactivity in Bond Cleavage Reac
tions 2394
GOTO, Mitsuaki Effect of Artificial Boundary Lipid on the
Membrane Dynamics of Human Glycophorin-Containing Lipo
some 3331
GOTO, Mutsuo Solvent Effects on the Solvolysis of Neophyl
Tosylates 46
G O T O , Mutsuo The Substituent Effects on Solvolyses of threo-2Aryl-l-methylpropyl Brosylates 3072
G O T O , Naomi The Substituent Effects on Solvolyses of threo-2Aryl-l-methylpropyl Brosylates 3072
G O T O , Toshio A Convenient Synthetic Method of 2-Cyano-6methoxybenzothiazole, —A Key Intermediate for the Synthesis
of Firefly Luciferin 392
G O T O , Toshio Synthesis and Chemiluminescence Properties of
6-(4-Methoxy phenyl)-2-methy limidazo[ 1,2-a]pyrazin-3(7//)-one
and
2-Methy l-6-(2-naphthyl)imidazo[ 1,2-a]pyrazin-3(7-ft)-one
2475
GOTO, Toshio Improved Synthetic Methods of Firefly Luciferin
Derivatives for Use in Bioluminescent Analysis of Hydrolytic
Enzymes; Carboxylic Esterase and Alkaline Phosphatase
2604
G R E E N S L A D E , David J. Isothiocarbamido Radicals from
Thiourea: Electron Spin Resonance Spectroscopy of NBenzylidene-/-butylamine-TV-oxide
and 5,5-Dimethyl-l-pyrroline-TV-oxide Spin Adducts 2720
G R I B K O V , Alexander A. Synthesis and Properties of
G U P T A , Upma Chromatographic Separation of α-Amino Acids
on Antimony(V) Phosphate-Silica Gel 'G* Plates from Some
Synthetic Mixtures and Drug Samples 2773
G U R U M U R T H Y , Rajagopal Kinetics and Mechanism of Oxi
dation of Ethyl Phenylthioacetates by Bromamine-B 1096
G U T M A N , Ivan Two Variants of the Topological Index and the
Relations between Them 14
G U T M A N , Ivan Topological Indices of Unbranched Catacondensed Benzenoid Hydrocarbons 2011
HADA, Sakae Determination of the Dimerization Constant in
Self-Associating Systems 314
HADA, Sakae Stoichiometries and Equilibrium Constants of
Cyclodextrin-Surfactant Complexations 1323
H A G I W A R A , Tokio Lithium Alkylamide-Catalyzed Addition
Reaction of Alkylamines to Vinyl Monomers. I I I . Addition Reac
tion of ^-Substituted Benzylamines to Styrene and Divinylbenzenes 1109
HAIGOH, Hisamitsu Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
HAISA, Masao Crystal and Molecular Structures of Acetoacetanilide, and o- and />-Chloroacetoacetanilides: X-Ray Crystallo
graphy and MO Study 3234
H A K I I , Tsuyoshi Mechanism of the Triplet-Sensitized Photoly
sis of N-(l-Naphthylsulfonyl)-A^-phenyl-0-(/)-toluoyl)hydroxylamine 2789
December, 19921
AUTHOR INDEX
H A K U I , Jun-ichi Preparation of New Nitrogen-Bridged Heterocycles. 29. Reinvestigation on the Dehydrogenation Reaction of
5,5a-Dihydropvrido(2,l-f|thieno[3,2-^][l,4]thiazine Derivatives
1244
H A L L E R , Gary L. Time-Resolved Infrared Emission Studies of
CO2 Formed by Catalytic Oxidation of CO on Pt and Pd Sur
faces 2450
H A M A D A , Kaoru Formation of AOT Reversed Micelles and W/
Ο Microemulsions 2715
H A M A D A , Satoshi Effects of Surface Pretreatments of a Glass
Substrate on the Properties of Tin Oxide Film Prepared by
Plasma-Assisted Chemical Vapor Deposition 1141
H A M A G U C H I , Takayoshi Oxidation of Alcohols with Peracetic Acid in Ethyl Acetate in the Presence of Sodium Bromide
703
H A M A I , Sanyo Hydrogen Bonding in Inclusion Complexes of
Heptakis(2,3,6-tri-0-methyl)-j3-cyclodextrin with Chlorophenols in Organic Solvents 2323
H A M A M U R A , Naohiko Crystal Structures and Magnetic Prop
erties of Novel M-Carboxylato-M-Hydroxo-Bridged Binuclear
Copper(II) Complexes with 1,10-Phenanthroline 1214
HAMANA, Hiroshi Lithium Alkylamide-Catalyzed Addition
Reaction of Alkylamines to Vinyl Monomers. I I I . Addition Reac
tion of ^-Substituted Benzylamines to Styrene and Divinylbenzenes 1109
H A M A N O U E , Kumao Solvent Effects on the Formation and
Decay of Ionic Intermediates for the Photoreduction of
Anthraquinone by Triethylamine in Ethanol, Toluene, and
Acetonitrile at Room Temperature 3141
H A N A F U S A , Terukiyo A New Ketyl Radical Probe. Dehalogenation of o-Halobenzophenone 1157
H A N A F U S A , Terukiyo 1:1 Adduct Ion Formation of Simple
Carbohydrate Derivatives with Cations Using FAB Mass Spec
trometry. Comparison of O-Acetyl, N-Butyl, and OMethyl
Modifications 1275
H A N A F U S A , Terukiyo Diastereoselectivity and Reaction Path
way of the Reactions of Benzaldehyde with Allylic Iodides in
the Presence of Sn or Pb 2145
H A N A K I , Hiroko The Kinetic Study of the Oxygen-Exchange
Water 1397
HANAWA, Toshiyuki Theoretical Study of Aluminum-Sodium
Bimetallic Clusters. I . Geometrical and Electronic Structures of
A l N a ( n = l - 4 ) 2578
H A N A Y A , Tadashi Orientation of the Addition of Dimethyl
Phosphonate
to
5,6-Dideoxy-6-nitro-D-hex-5-enofuranoses
1154
H A N A Y A , Tadashi Synthesis of 2-Amino-2,5,6-trideoxy-5phenylphosphinyl-L-galactopyranose. The P-in-the-Ring Ana
HANDA, Makoto Thiolate-Bridged Binuclear Nickel(II) Com
HANDA, Makoto Study of the Charge Transfer Band Observed
in Dialkoxo-Bridged Binuclear Copper(II) Complexes 3241
HANGAI, Katsuaki The Structure around the Nitrite Ion in
HARA, Shoji Organic Synthesis Using Haloboration Reaction.
XXI. A Synthesis of Prostaglandin Bi Methyl Ester by the
Stepwise Cross-Coupling Reaction Using (£)-(2-Bromoethenyl)diisopropoxyborane 2303
HARADA, Kazumasa as- and /rfl«5-Li[Co {L-tart(2-)-0 }2(en) ] Hydrate Separated from the Reaction Products of
[Co (C03)(en) ] with L-Tartaric Acid 2490
HARADA, Kazumasa Structures and Spectral Properties
of Some Bis(carboxylato)copper(II)-Pyrazole Complexes. I .
Preparation of Bis(trifluoroacetato)tetrakis(pyrazole)copper(II)
2638
HARADA, Masayuki F Nuclear Magnetic Resonance Study on
the Kinetics of the Fluoride Exchange in Uranium(VI) Fluoro
w
II1
2
in
2
+
19
1
3519
Complex 3022
H A R A D A , N o b u y u k i Catalytic Acid Fluoride Synthesis via
Carbonylation of Organic Bromides in the Presence of Potas
sium Fluoride 1741
H A R A D A , Tadao Hydrogenation and Isomerization of Disodium Maleate in the Solid Phase over Fine Nickel Powder
1168
H A R A Y A , Kenji Correlation between the ortho-Positronium
Pick-off Annihilation Lifetime and the Free Volume in Molecu
lar Liquids and Polymers 160
HASE, Hirotomo Vibrational and Rotational Raman Spectra of
Trapped Hydrogen in Irradiated Ethanol Crystal at 77 Κ 2526
HASE, Shino The Fluorescence Properties of (2-Nitro-5,10,15,20tetraphenylporphyrinato)zinc 1475
HASE, Sumihiro Synthesis of New Serine-Linked Oligosaccha
rides in Blood-Clotting Factors VII and IX and Protein Z. The
Syntheses of 0-a-D-Xylopyranosyl-(l-»3)-D-glucopyranose, O-ai)-Xy lopyra nosy l-( 1-+3)-Ο-α-D-xylopy ranosyl-(l-»3)-Dglucopyranose, and Their Conjugates with Serine 436
HASEGAWA, Kiyoshi Thermal Behavior and Mass Spectra
Aspects of 1,3,5-Triazine Derivatives Based on Isocyanuric
Acid 1993
HASEGAWA, Koji Syntheses of trans- and os-3-Methoxy-4methylthio-2-piperidinethiones. Previously Proposed Struc
tures for Raphanusanins, Structural Revision, and Biological
Activities of Their Congeners 3064
HASEGAWA, Sadao Selective α-Mono- and α,α-Dialkylations of
1,3-Diketones Using Solid Base Prepared from Sodium Ethoxide and Alumina 1185
HASEGAWA, Tadashi Selective α-Mono- and α,α-Dialkylations
of 1.3-Diketones Using Solid Base Prepared from Sodium
Ethoxide and Alumina 1185
HASEGAWA, Tadashi Oxidative Chlorination of 1,10Phenanthroline and Its Derivatives by Phosphorus Pentachloride in Phosphoryl Chloride 2007
HASEGAWA, Tadashi Photochemical Reactions of 4-Oxo Carboxylic Esters: Remote Hydrogen Abstraction and Cis-Trans
Isomerization 3498
HASEGAWA, Tomoyuki The Biogenetic-Type Cyclization of
the Unsaturated Monocyclic Alcohol with Formic Acid; Facile
Synthesis of the Tricarbocyclic Alcohol, (+)-2-Epi-allo-cedrol
203
HASHIMOTO, Chikao Synthesis of Sperm Whale Myoglobin(77—96)-Eicosapeptide and Circular Dichroism Spectra of the
Related Peptides 1268
HASHIMOTO, Hironobu Stereoselectivities in Catalytic
Hydrogenation of Several Branched-Chain
6-Deoxyhex-5enopyranosides. A Synthesis of Branched-Chain Methyl 6Deoxy-0-L-hexopyranoside 292
HASHIMOTO, Kazuhiko Crystal Structures of N-Benzoyl
Derivatives of 8-Oxa-6-azabicyclo[3.2.1]octan-7-one, ε-Caprolactam and 2-Pyrrolidone 886
HASHIMOTO, Kazuhiko Crystal Structure of N-Cinnamoyl-8oxa-6-azabicyclo[3.2. l]octan-7-one 1138
HASHIMURA, Masayuki Fluorescence Quenching of Europium(III) by Heteronuclear Complex Formation with Copper(II) or
Nickel(II) 1162
HASHIMOTO, Yosuke Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
HASSAN, Alaa A. Molecular Interactions between Triazene 1Oxides and Tetracyanoethylene 553
HATA, Yukari NMR Relaxation Studies for Sodium and Potas
sium Ions and Water Molecules in Concentrated Aqueous Solu
tions of Dibutyl Phosphate 707
HATANAKA, Akihiko One-Pot Synthesis of Optically Active
Cyanohydrin Acetates from Aldehydes via Quinidine-Catalyzed
Transhydrocyanation Coupled with Lipase-Catalyzed Kinetic
Resolution in Organic Solvent 111
H A T T A , Taizo Decomposition of [2.2.2]Cyclophane-l,2-dione
3520
[Vol. 65, No. 12
B U L L E T I N O F T H E CHEMICAL SOCIETY OF JAPAN
Mono- and Bis(tosylhydrazone)s 1469
H A T T O R I , Kazuhisa Lithium Alkylamide-Catalyzed Addition
Reaction of Alkylamines to Vinyl Monomers. III. Addition Reaction of ^-Substituted Benzylamines to Styrene and Divinylbenzenes 1109
H A T T O R I , Kenjiro Enantioface Differentiating Reduction of
Keto Acid in the Presence of 6-Deoxy-6-amino-ß-cyclodextrin
with NaBH in Aqueous Media 2690
H A T T O R I , Makoto Preparation and Properties of Clays Pillared with S i 0 - T i 0 Sol Particles 2494
H A T T O R I , Shigeru Correlation between the oW/zo-Positronium
Pick-off Annihilation Lifetime and the Free Volume in Molecular Liquids and Polymers 160
H A Y A K A W A , Fumie Silicon Effects. IV. Solvolysis of 1(Pentamethyldisilanyl)-2-phenylcyclopropyl Bromide in 2,2,2Trifluoroethanol via $sss(CC)-Assisted and -Unassisted Ionization Processes 959
H A Y A K A W A , Katumitu The Binding Characteristics of
Sodium Decyl Sulfate to Poly(L-ornithine) with l-Alkanesulfonate Counter Ions 1146
H A Y A K A W A , T a k a s h i Synthesis of Alkyl Substituted p>
Benzoquinones from the Corresponding Phenols Using Molecular Oxygen Catalyzed by Copper(II) Chloride-Amine Hydrochloride Systems 1522
H A Y A K A W A , Yoshio Stereoselective Decomposition of Pyrazolines Containing Trifluoromethyl Groups 1999
H A Y A S H I , Hiromichi Complex Formation of Poly(acrylic acid)
with Mg, Mn, and Pb Ions in Dioxane-Water Mixed Solvents
1500
H A Y A S H I , Hiromu Catalytic Conversion of Diethyl Tartrate
2083
H A Y A S H I , Hisashi Mixing State οί 1 Pröpänol Aqueous Solutions Studied by Small-Angle X-Ray Scattering: A New Parameter Reflecting the Shape of SAXS Curve 155
H A Y A S H I , Hisashi SAXS Curve Shape Analysis of 2Butoxyethanol Aqueous Solutions 600
H A Y A S H I , Hisayoshi Modification of α-Chymotrypsin by Bromomethyl Naphthyl Ketones and Behavior of Reporter Groups
in the Active Site 2948
H A Y A S H I , Y a s u h i s a Effect of Ascorbic Acid on the Desorption
of Gold in Graphite Furnace Atomic Absorption Spectrometry
871
H A Y A S H I , Yujiro Acid-Promoted Reactions of Schiffs Bases
with Ketene Dithioacetal, Vinyl Sulfides, and 1,2-Propadienyl
Sulfides 1392
H A Y A S H I , Yujiro Reactions of 1,2-Propadienyl Sulfides with
Aldehydes and Acetals Catalyzed by BF · OEt 2825
H A Y A S H I B E , Satoshi Stereochemical Aspects on the
B F - E t 0 Catalyzed Ring Contraction of 5-Substituted 2,3Epoxycyclohexanones 3206
H A Y A S H I D A , Haruyoshi Asymmetric Synthesis of Benzoin by
Sml -Mediated Enantioselective Protonation 2001
H A Z E K I , Noriko Radical-Based Synthesis of Terpenoids. Ster
eoselectivity in the Trapping of Radicals from Cyclization of 3(l-Ethoxy-2-haloethoxy)cyclohexenes 2421
H A Z R A , Dilip K . Studies on the Viscosities, Conductances, and
Adiabatic Compressibilities of Some Tetraalkylammonium
Perchlorates in 2-Methoxyethanol 3470
H E R M A W A N , I r w a n Preparation of Aromatic Iodoacetyl
Derivatives by Direct Iodination with a Potassium IodidePotassium Iodate-Sulfuric Acid System 1731
H E R M A W A N , I r w a n Halogenation Using Quaternary Ammo
nium Polyhalides. XXXII. Dichlorination of Aromatic Acetyl
Derivatives w i t h Benzyltrimethylammonium Tetrachloroiodate 2549
H I D A K A , Jinsai Stereoselective Formation and Some Properties
of Polynuclear Cobalt(III) Complexes with D-Penicillaminate
794
4
2
2
3
3
2
2
2
H I D A K A , Jinsai Preparation and Stereochemistry of the MixedLigand Complex, Ammine(ethylenediamine)(ethylenediamineiV-acetato)cobalt(III) 1920
H I D A K A , Jinsai Synthesis and Properties of T-Cage-Type SeBridged Polynuclear Co(III) and Rh(III) Complexes with 2Aminoethaneselenolate (aese). Crystal Structure of [{Co(aese) }4Zn 0KCl04)6 3015
H I D A K A , Yukio 1:1 Adduct Ion Formation of Simple Carbohy
drate Derivatives with Cations Using FAB Mass Spectrometry.
Comparison of O-Acetyl, N-Butyl, and O-Methyl Modifications
1275
HIGASHIJIMA, Michio Studies Concerning the Factors Affect
ing the Formation of Cyclohexanone Intermediates in the Cata
lytic Hydrogenation of Phenols. I . Hydrogenation of />-Cresol
over Various Pd-C Catalysts 824
HIGASHIJIMA, Michio Effects of Alcoholic Solvents on the
Formation of Cyclohexanones in the Hydrogenation of Phenols
over Pd-C Catalysts 2955
HIGASHIJIMA, Michio Phenylacetaldehyde and Carbon Mon
oxide as Effective Additives for the Selective Hydrogenation of
Cyclooctadienes to Cyclooctene over Palladium Catalysts
2960
HIGUCHI, Hiroshi Preparation of Cu Thin Films by the Decom
position of Copper Acetylacetonate on Catalytically Active Sub
strate Surfaces 892
H I G U C H I , Hiroyuki *H and CNMR Spectral Behavior and
Isomerism in 7,12-Dimethyl-, 2,7,12-Trimethyl-, and 7,12,15Trimethyl-8,10-bisdehydro[15]annulenones 2388
H I G U C H I , Tai-ichi Exchange-Storage of a Guest Molecule in an
Inclusion
Crystal
of 2,ll,20,29-Tetramethyl-2,l 1,20,29tetraaza(3.3.3.3]paracyclophane 805
HIGUCHI, Takashi Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
H I M E N O , Sadayuki Synthesis and Characterization of
Vanadium-Substituted Heteropoly Molybdosulfate(VI) Com
plexes 799
H I O K I , Takanori Synthesis of a Polycyclic π-Conjugated Sys
tem Containing an Azulene Unit by the Flash Vacuum Pyrolytic Method. I . Synthesis and Properties of Cyclopent[ß]azulenes 1527
tem Containing an Azulene Unit by the Flash Vacuum Pyrolytic Method. I I . Synthesis and Paratropic Properties of 3HCyclopent[fl]azulen-3-one and Its Methyl Derivatives 2131
tem Containing an Azulene Unit by the Flash Vacuum Pyrolytic Method. I I I . Synthesis and Properties of 4-Hydroxy-3#cyclopent[ß ]azulen-3-one 3282
H I R A I , Yoshimasa Cycloaddition Reactions of 2-Acetylamino-, 2-Alkylamino-, 8-Ethylamino-, and 8-Acetylamino-lazaazulenes with Dimethyl Acetylenedicarboxylate 1784
H I R A I W A , Akira Selective Preparation of l-Halo-2,6dimethoxybenzenes from Bis(2,6-dimethoxyphenyl)dimethyltin
1389
H I R A K I , Katsuma Reactions of Hydridoruthenium(II) Complexes with Alkyl Allylic Sulfides 3027
HIRANO, Masao Oxidation of Alcohols with Peracetic Acid in
Ethyl Acetate in the Presence of Sodium Bromide 703
H IR A N O , Masao A Facile Synthesis of Sulfoxides by Oxidation
of Sulfides with Sodium Bromite in an Aprotic Solvent in the
Presence of Clay Minerals 1744
HIRANO, Tsuneo Radical-Based Synthesis of Terpenoids. Stereoselectivity in the Trapping of Radicals from Cyclization of 3(l-Ethoxy-2-haloethoxy)cyclohexenes 2421
H I R A S H I M A , Tsuneaki Novel Reduction of Carboxylic Acids
and Hydroboration of Olefins by Electrolysis of Sodium Borohydride 530
H I R A T A , Kenji Asymmetric Synthesis of Benzoin by Sml Mediated Enantioselective Protonation 2001
3
4
l3
2
December, 1992]
AUTHOR INDEX
H I R A T A , Takaki "Syη-Effect" in the Conversion of (£)-Vinylic
H I R A T A K E , Jun One-Pot Synthesis of Optically Active Cyanohydrin Acetates from Aldehydes via Quinidine-Catalyzed
H I R A T A N I , Kazuhisa N,N'-Di(8-quinolyl)glutaramide Exhibit
ing Highly Selective and Efficient Uphill Transport of Cu(II)
H I R O F U J I , Hajimu AlCl -N,AADimethylaniline: A Novel Ben
zyl and Allyl Ether Cleavage Reagent 1932
H I R O N A K A , Shinji An Isomeric Series of Thiophene-Fused
Tetracyanoquinodimethanes. III. Crystal Structures of ChargeTransfer Complexes with T T F 2180
H I R O O K A , Motoko Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
H I R O S E , Junzo Diastereoisomers of Platinum(II) Complexes
with Chiral TV-Substituted 1,2-Diamines. I . Structure and Iso
merization of Dichloro{(/?)-2-[(2-methyl-2-aminopropyl)amino]1-butanol Iplatinum(II) 1428
H I R O S E , Junzo Diastereoisomers of Platinum(II) Complexes
with Chiral /V-Substituted 1,2-Diamines. I I . Structures of
H I R O S E , Takuji MiV-Di(8-quinolyl)glutaramide Exhibiting
Highly Selective and Efficient Uphill Transport of Cu(II)
H I R O S E , Yuji Catalytic Asymmetric Synthesis of Optically
Active Secondary Alcohols Deuterated on the Secondary Car
bon by the Enantioselective Alkylation of Aldehydes 1734
H I R O T A , Masamichi An Isomeric Series of Thiophene-Fused
Tetracyanoquinodimethanes. I I . The Crystal and Molecular
Structures 2173
H I R O T A , Masamichi An Isomeric Series of Thiophene-Fused
Tetracyanoquinodimethanes. IV. Crystal Structure of 2:3
Charge-Transfer Salt with Tetraethylammonium 2187
H I R O T A , Minoru Photolyses of Polychloro- and Polybromobenzenes. Novel Isomerization in Solvents Resisting against Hy
drogen Abstraction 2926
HIROTA, Noboru The Role of a Spin-Coupled Intermediate in a
System Consisting of Tetraminecobalt(III) Complexes and
Catechols —A Model Intermediate of Dioxygenase Reaction—
1225
HIROTA, Noboru A Time-Resolved EPR Study on the Photo
chemical α-Cleavage of Benzoin and Related Molecules 1679
HIROTA, Reiko Structures and Spectral Properties of Some
Bis(carboxylato)copper(II)-Pyrazole Complexes. I . Preparation
of Bis(trifluoroacetato)tetrakis(pyrazole)copper(II) 2638
H I R O T S U , K e n Exchange-Storage of a Guest Molecule in an
Inclusion
Crystal
of 2,11,20,29-Tetramethyl-2,11,20,29tetraaza[3.3.3.3]paracyclophane 805
H I S A E D A , Yoshio Hydrophobic Vitamin Βι . XI. Preparation,
Characterization, and Enantioselective Alkylation of Hydro
phobic Vitamin B12 Bearing a Binaphthyl Moiety 3094
H I S A T O M E , Masao Prismatic and Antiprismatic [4 ]Ferrocenophanes ([4](1,1')[4](3,3')- and [4](l,10[4](3,40Ferrocenophanes) 3275
HIYAMA, Tamejiro Hydrosilylation of 1,4-Bis(trimethylsilyl)butadiyne and Silyl-Substituted Butenynes 1280
HOGG, Alan M. Synthesis of 2-Amino-2,5,6-trideoxy-5-phenylphosphinyl-L-galactopyranose. The P-in-the-Ring Analogue of LFucosamine 2922
HOJO, Hironobu Protein Synthesis Using S-Alkyl Thioester of
Partially Protected Peptide Segments. Synthesis of DNABinding Protein of Bacillus stearothermophilus 3055
HOLLA, B . Shivarama The Reactions of Nitrile Oxide-Quinone
Cycloadducts. I . Base-Induced Rearrangement of the 1:1-C=CAdducts of Aromatic Nitrile Oxides with Dialkyl-Substituted pBenzoquinones 2480
3
2
2
3521
HONDA, Ichiro Regioselective Hydrogenation of Unsaturated
Compounds Using Platinum-Zeolite Coupled with Organosilicon Alkoxide by CVD Method 1240
HONDA, Kazuhiko Theoretical Study of Structure and Ther
modynamic Properties of Liquid Hydrogen Fluoride 3122
HONDA, Kazumasa Reaction of 1,3-Oxathiolium Salts with
Three Types of Ring Expansion Reagents on a Nitrogen Atom
668
HORAGUCHI,
Takaaki
2,3-Dichloro-5,6-dicyano-/>-benzoquinone as a Mild and Efficient Catalyst for the Tetrahydropyranylation of Alcohols 304
HORI, Toshitaka Synthesis and Characterization of VanadiumSubstituted Heteropoly Molybdosulfate(VI) Complexes 799
HORI, Yoshio Infrared Spectroscopic Observation of Adsorbed
CO2 at a Nickel Electrode 3008
HORIKOSHI, Yoichiro Intramolecular [2+2] Photocycloaddition. 15. Synthesis of l,2-Ethano-9,10-methano[2.2]paracyclophanes 941
HORIMOTO, Shingo Synthetic Study on Peptide Antibiotic
Nisin. V. Total Synthesis of Nisin 2227
HOSHI,
Masayuki The Hydroboration of 3-Chloro-ltrimethylsilyl-l-propyne with Dialkylboranes and Its Applica
tion to the Syntheses of (£>3-Trirnethylsilyl-2-alkenes and 3TrimethylsilylT-alkenes 685
HOSHI, Masayuki The Hydroboration of 3-Chloro-l-iodo-lpropyne with Dialkylboranes, and Its Application to the Syn
theses of Some Geminally Dialkylated Propene Derivatives
3294
HOSHI, Toshihiko Preliminary Analysis of the Electronic
Absorption Spectrum of a Solute in a Biaxially-Stretched Poly
mer Film 463
HOSHI, Töshihikü Dimer Formation of 9-Cyanoanthracene in a
Nonpolar Medium at Low Temperatures 692
HOSHI, Toshihiko Electronic Absorption and Phosphorescence
Spectra of 2-Acetylfuran. Conformations in the Ground and
Excited Triplet States 2067
HOSHINO, Hitoshi Determination of Aluminium in Natural
Waters by Ion-Pair Reversed-Phase Partition HPLC 3192
HOSHINO, Masamatsu Generation and Characterization
of l,3-Di-/-butyl- and l,3-Di-/-butyl-4,6-dimethylthieno[3,4-c]thiophenes 2821
HOSHINO, Masamatsu Oxidation of 2,2,3,3-Tetramethyl-l,4diphenyl-5,6-dithiabicyclo[2.1.1]hexane and Its Oxidation Products: An Important Role of 1,3-Transannular Interaction in the
1,3-Dithietane Part 3343
HOSHINO, Yoshimasa Oxidative Dehydrogenation of Ethylenediamine Coordinated to Ruthenium with Hexafluoroacetylacetonate, Induced by Electrochemical Oxidation of Ruthenium(II) to Ruthenium(III) 876
HOSOYA, Haruo Two Variants of the Topological Index and the
HOSOYA, Haruo Topological Indices of Unbranched Catacondensed Benzenoid Hydrocarbons 2011
HUANG, Chiung-yi Mechanistic Study of Acid-Catalyzed
Proton Exchange in Lactams 562
HUANG, Hsing Hua Rotational Isomerism and Crystal Structures of 2-Methyl-2,3,3-trinitrobutane and 2-Methyl-2,3,3trinitropentane 489
HYUGA, Satoshi Organic Synthesis Using Haloboration Reaction. XXI. A Synthesis of Prostaglandin Bi Methyl Ester by the
I B A T A , Toshikazu Formation and Reaction of Carbonyl Ylides.
Reactions of l-Methoxy-2-benzopyrylium-4-olate with Isothiocyanates 1362
I B A T A , Toshikazu Abnormal Diels-Alder Reaction of 5Alkoxyoxazoles with Tetracyanoethylene and X-Ray Crystal
3522
BULLETIN OK THE CHEMICAL SOCIETY OF JAPAN
I B A T A , Toshikazu Abnormal Diels-Alder Reaction of Oxazoles
with 4-Phenyl-3//-l,2,4-triazole-3,5(4//)-dione and Diethyl Azodicarboxylate, and X-Ray Crystal Structure of an Adduct
2998
I B A T A , Toshikazu Formation of 2-Imino-l,3-oxathioles and
2(3//)-Oxazolethione by the Rhodium(II) Acetate-Catalyzed
Reaction of α-Diazocarbonyl Compounds with Isothiocyanates
3088
I B A T A , Toshikazu Abnormal Diels-Alder Reaction of 5Alkoxythiazoles with Highly Reactive Dienophiles; 4-Phenyl3//-l,2,4-triazole-3,5(4//)-dione, Diethyl Azodicarboxylate, and
Diethyl Oxomalonate 3315
I B U K I , K a z u y a s u Solvent Effects on the Formation and Decay
of Ionic Intermediates for the Photoreduction of Anthraquinone
by Triethylamine in Ethanol, Toluene, and Acetonitrile at
Room Temperature 3141
I C H I D A , Hikaru Stability and Reactivity of Dihydroxobis(trimethylphosphine)platinum(II), an Intermediate Species for the
Synthesis of a Variety of Water-Soluble Phosphine Complexes
3386
I C H I K A W A , Hiroshi Stability of Large Polycyclic Aromatic
Hydrocarbons in the Diffuse Interstellar Medium 597
I C H I K A W A , Kazuhiko Cd -Cataiyzed Methanolysis of Phenyl
Phosphatosulfate. Selectivity of Metal Ion in the Site of Cleav
age of P-0 and S-0 Bond 3335
I C H I K A W A , Masaru Effects of Pd Dispersion on the Catalytic
Activity of Pd/Si0 for Ethylene Hydroformylation 2565
I C H I M U R A , Akio Preparation and Properties of Mixed Ligand
Dinuclear Copper(II) Complexes Bridged by Deprotonated Oximato and Hydroxo or Acetato 3189
I C H I M U R A , Kunihiro Photochromism of Hemithioindigo
Derivatives. I . Preparation and Photochrome Properties in
Organic Solvents 649
I C H I M U R A , Kunihiro Photochromism of Hemithioindigo
Derivatives. I I . Photochromic Behaviors in Bilayer Membranes
and Related Systems 657
I C H I M U R A , Kunihiro Photosensitized Oxygenation of Olefins
with Zinc Tetraphenylporphine-1,4-Diazabicyclo[2.2.2]octane
Complex 1944
I C H I M U R A , Teijiro One-Color and Two-Color ResonanceEnhanced Two-Photon Ionization Studies of Benzene: Sudden
Drop of Photoionization Yield at the Onset of the Third Chan
nel Region 234
I D A , Yutaka Generation and Characterization of 1,3-Di-f-butyland l,3-Di-/-butyl-4,6-dimethylthieno[3,4-c]thiophenes 2821
I D E , Naoko Free Radical Alkylation of 1,3-Dimethyluracils and
Caffeine with Benzoyl Peroxide 2045
I D E H A R A , Tsutomu Study of the Charge Transfer Band
Observed in Dialkoxo-Bridged Binuclear Copper(II) Complexes
3241
I D O U , Yoshiyuki Allylation of Carbonyl Compounds with Cata
lytic Amount of Indium 1736
IGA, Siroh Temperature and Pressure Effects on the Reversible
Reaction of a Parent Phenol (GH) Corresponding to Galvinoxyl
with Aliphatic Amines 2437
I G A R A S H I , Minoru Knoevenagel Reaction of Malononitrile
with Acetone Followed by Double Cyclization Catalyzed by KFCoated Alumina in Aqueous Solution 2934
IG A W A, Manabu Electron Transport and Redox Chain Reac
tions in a Mosaic Membrane 1561
I G A W A , Manabu Selective Permeation Properties of Inorganic
Ions across a Hydrophobic Membrane 1871
I H A R A , Ikuko Selective α-Mono- and α,α-Dialkylations of 1,3Diketones Using Solid Base Prepared from Sodium Ethoxide
and Alumina 1185
I I D A , Ikuo Chiral Hydantoin; A New Dienophile for Diels-Alder
Reaction 935
I I D A , Masayasu NMR Relaxation Studies for Sodium and Po
tassium Ions and Water Molecules in Concentrated Aqueous
2+
2
[Vol. 65, No. 12
Solutions of Dibutyl Phosphate 707
IIDA, Masayasu The Kinetic Study of the Oxygen-Exchange
Water 1397
IIDA, Masayasu Conductometric Study of Ion Association
between Tris(ethylenediamine)cobalt(III) Ion and Monovalent
Anions at Temperatures from 0 to 50 °C 2901
IIJIMA, Masakazu N-Hydroxy Amides. X. Synthesis of a Nonapeptide with an Ala-(HO)Gly-Ala Sequence and Its Spectral
and Iron(III) Holding Properties 1356
I I T A K A , Naoyuki Molecular Structures of //7-[ΜΜΌ1 (μMfcPpyfe] (MM'=Pd , PdPt, and Pt ; Me Ppy=2-(Dimethylphosphino)pyridine) and #T-[Pd Cl (M-Ph Ppy) ](Ph Ppy=2(Diphenylphosphino)pyridine) 1817
I I T A K A , Naoyuki Preparation and Characterization of
as a Bidentate Ligand, and Molecular Structures of [Co(acac) (dmpf)]B(C6H )4 and [Co(dtc) (dmpf)]B(C H5)4 (acac=2,4pentanedionate ion, dtc=dimethy!dithiocarbamate ion) 2037
IJIRO, Kuniharu Preparation of a Lipid-Coated Lipase and
Catalysis of Glyceride Ester Syntheses in Homogeneous
I K A R I Y A , Takao Syntheses and Structures of Novel Ruthenium(II)-Chiral Diphosphine Complexes 1595
I K A W A , Yoshiya Synthesis of Benzochlorin Monomer, Dimer,
and Porphyrin-Benzochlorin Heterodimer from 5-Aryl- and
5,15-Diaryl-octaethylporphyrins 3322
I K E D A, Mitsuhiro The Spectroscopic Properties and Organometallic Reactivities of Cobalt(III) Porphyrins 639
I K E D A , Norihiro Surface Adsorption and Micelle Formation of
Dodecyltrimethylammonium Chloride and Dodecylammonium
Chloride Mixture 858
I K E D A , Shoichi Size of Micelles of 1-Dodecylpyridinium Chlo
ride in Aqueous NaCl Solutions 1406
I K E D A , Shoichiro Framework Structure, Phase Transition,
and Transport Properties in M'^r^PO-OeCompounds ( M - M g ,
Ca, Sr, Ba, Mn, Co, Ni, Zn, Cd, and Pb) 3221
I K E D A , Tomiki Stabilization Energy of the 9,9'-Trimethylenedianthracene Radical Cation Estimated by the Charge
Resonance Band 909
I K E G A K I , Takako Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
I K E G A M I , Satoru Stereoselective Synthesis of (±)-Ireland Alco
hol Using Titanium-Mediated [2,3]Wittig Rearrangement Pro
duct as a Starting Material 1841
I K E M I , Kimiyoshi Solution Properties of Poly(4-vinylpyridine)
in Aqueous Solutions of Sulfuric Acid 3108
I K E N A G A , Koichiro Solvent Effects on the Formation and
I K E N A K A , Tokuji Synthesis of New Serine-Linked Oligosac
charides in Blood-Clotting Factors VII and IX and Protein Z.
The Syntheses of 0-a-D-Xylopyranosyl-(l-»3)-D-glucopyranose,
0-a-D-Xylopyranosyl-(1^3)-0-a-D-xylopyranosyl-(l->3)-Dglucopyranose, and Their Conjugates with Serine 436
I K E N O U E , Shuichi Binuclear Nickel(II) Complexes of Schiff
Bases Derived from Salicylaldehydes and l,«-Diamino-«'hydroxyalkanes (n,n -3,2; 4,2; and 5,3) Having an Endogenous
I K E Z A K I , Youji Preparation of 1,2,3-Naphthalenetriamine,
1,2,5,6- and 1,2,7,8-Naphthalenetetramine, and 5,6,7,8Quinolinetetramine and -Isoquinolinetetramine by Reduction
of the Fused 1,2,5-Thiadiazole Ring 2221
I L L E S , Jänos Utilization of Enzymatic Digestion for the Study
of the Macromolecular Effect in Complexation Processes. Protonation and Copper Coordination Equilibria of Hyaluronate
and Its Fragments 2211
2
2
2
2
2
5
2
2
2
2
2
2
6
1
December, 1992]
AUTHOR INDEX
I M A E D A , K e n i c h i Crystal Structures of TXCVTTF (X=Se,Te)
1482
I M A E D A , K e n i c h i Crystal Structures and Molecular Packing of
Tetrakis(alkylthio)tetrathiafulvalene (TTC„-TTF); Part I
(»=3,4,6) 1878
I M A E D A , K e n i c h i Crystal Structures and Molecular Packing of
Tetrakis(alkylthio)tetrathiafulvalene ( T T C - T T F ) ; (Part II)
(«=7,9,11) 2086
I M A F U K U , K i m i a k i Reactions of 3-Isopropenyl- and 3·
Acetyltropolone with Quarternary Ammonium Tribromides
295
I M A I , Shoji Effect of Ascorbic Acid on the Desorption of Gold in
Graphite Furnace Atomic Absorption Spectrometry 871
I M A I , T a k a h i r o Efficient Seienation of Quinones: Synthesis of
Novel Benzo[6]naphtho[2,3-e]selenintrione and Dibenzo[6,e]seleninone 1291
I M A I Z U M I , F u m i t o s h i Dimer Formation of 9-Cyanoanthracene
in a Nonpolar Medium at Low Temperatures 692
I M A J O , N o r i h i s a A Systematic Study on the Bakers' Yeast
Reduction of 2-Oxoalkyl Benzoates and l-Chloro-2-alkanones
631
I M A M U R A , Hayao Catalytic Properties of Lanthanide Metals
on Silica 244
I M A M U R A , K a z u n o r i Catalytic Hydrogenation of Dehydro
Quassinoids and Cytotoxic Antitumor Activity of the Hydrogen
ation Products 2684
I M A M U R A , K i y o s h i The Reactions of Nitrile Oxide-Quinone
IΜ A N AG A, H i r o t o The Fluorescence Properties of (2-Nitro5,10,15,20-tetraphenylporphyrinato)zinc 1475
I M A N A K A , N o b u h i t o Electrical Properties and Sinterability
for Lithium Germanium Phosphate Lii+ M Ge2-x(P04)3, M=A1,
I M A N A K A , Toshinobu Genesis of Highly Active Cobalt Sulfide
Catalyst for Hydrogenation and Isomerization: Effect of the
Calcination Temperature of Precursor Cobalt Oxide upon the
Catalytic Properties of Cobalt Sulfide 1331
I N A B A , Shinji Bis(l-methylimidazole)iron(II) Complexes of Por
phyrins Substituted with Highly Electron-Withdrawing CF
Groups: Electronic Spectra with Split Q-Bands and MCD Spec
tra with Unusual Features 1915
I M A B A , T a k a s h i An Efficient and Practical Synthesis of L-aAmino Acids Using (i?)-Phenylglycinol as a Chiral Auxiliary
2359
I N A D A , Yasuhiro Kinetic Studies of the Incorporation of the
Zinc(II) Ion into Water-Soluble N-Phenyl-Substituted Porphy
rins. Deformation Effect on the Metallation Rate 771
I N A G A K I , M i n o r u One-Pot Synthesis of Optically Active Cyanohydrin Acetates from Aldehydes via Quinidine-Catalyzed
1NAGAKI, T o m i o Syntheses of trans- and ds-3-Methoxy-4methylthio-2-piperidinethiones. Previously Proposed Struc
I N A M O , Masahiko Kinetic Studies of the Incorporation of the
Zinc(II) Ion into Water-Soluble 7V-Phenyl-Substituted Porphy
I N A M U R A , K a z u h i r o Genesis of Highly Active Cobalt Sulfide
I N O K U C H I , H i r o o Structural and Conducting Properties of
(TTF)(DMeT-DCNQI) 1460
I N O K U C H I , H i r o o Crystal Structures of TXC -TTF (X=Se,Te)
1482
I N O K U C H I , H i r o o Crystal Structures and Molecular Packing of
x
x
3
8
3523
Tetrakis(alkylthio)tetrathiafulvalene ( T T C - T T F ) ; Part I (w=
3,4,6) 1878
I N O K U C H I , Hiroo Crystal Structures and Molecular Packing of
Tetrakis(alkylthio)tetrathiafulvalene ( T T C - T T F ) ; (Part II)
(«=7,9,11) 2086
I N O K U C H I , Tsutomu Electroreductive Deoxygenation of
Methanesulfonates of α-Hydroxy Esters via a Catalytic Selenation-Deselenation Sequence 3200
I N O M A T A , Katsuhiko "Syn-Effect" in the Conversion of (£)Vinylic Sulfones to the Corresponding Allylic Sulfones 75
I N O M A T A , Katsuhiko Reactions of (£)-2-Iodo-l-tosyl-l-alkenes
as Useful Synthetic Intermediates 1379
I N O M A T A , Katsuhiko Synthesis of 2-(Substituted Methyl)-3,4Disubstituted Pyrroles and Their Conversion into the Corre
sponding Porphyrins 2660
INOUE, Hiroyasu Dimer Formation of 9-Cyanoanthracene in a
Nonpolar Medium at Low Temperatures 692
I N O U E , Hiroyasu Energy- and Electron-Transfer Pathways in
the Triplet-Sensitized Photolysis of iV-(l-Naphthoyl)-0-(/>toluoyl)-N-phenylhydroxylarnine with Substituted Benzophenones 1950
INOUE, Hiroyasu Electronic Absorption and Phosphorescence
Spectra of 2-Acetylfuran. Conformations in the Ground and
Excited Triplet States 2067
I N O U E , Hiroyasu Mechanism of the Triplet-Sensitized Photoly
sis of M(l-Naphthylsulfonyl)-N-phenyl-0-(/>-toluoyl)hydroxylamine 2789
I N O U E , Hiroyasu Modification of α-Chymotrypsin by Bromomethyl Naphthyl Ketones and Behavior of Reporter Groups
INOUE, Keiji Syntheses and Magnetic Properties of ImidazolateBridged Binuclear Copperfll) Complexes: Effect of Bridging
Mode upon Magnetic Interaction 1603
INOUE, Keiji Synthesis and Magnetic Property of ImidazolateBridged Cu(II)-M(II)-Cu(II) Complexes (M=Zn, Cu, Ni, Co, Mn)
2283
I N O U E , Satomi Mercury(6 Pi)-Photosensitized Decomposition
of Tetramethyllead 1710
INOUE, Satoru Comparison of IR-Transmission Method with
the Conventional DTA Method (Kissinger Plot) in the Crystalli
zation Study of Iron Tellurite Glass 1927
I N O U E , Takashi Cyclization of N-Terminal Fragments of Elcatonin 1728
I N O U E , Toshinori Complexation Property of a Novel Macrobicyclic Poly ether with Two Amide Moieties toward Alkali Metal
and Alkaline Earth Metal Cations 3490
I N O U E , Yasushi Preparation and Properties of Clays Pillared
with S i 0 - T i 0 Sol Particles 2494
I N O U E , Yukihiko The Reactions of Nitrile Oxide-Quinone
I N O U E , Yukihiko The Reactions of Nitrile Oxide-Quinone
Cycloadducts.
I I . The
Reactions of 2,5-Di-/-butyl-/>benzoquinone with Nitrile Oxides: 1:2 Cycloaddition and Base
I N O U Y E , Yoshinobu Acyliminium Cyclization of Chiral 5-(4Alkenyl)-5-hydroxy-2-pyrrolidinone Derivatives 2866
I N U Z U K A , Kozo Molecular Orbital Considerations on Interac
tion of 2-Aminopyridine with Formic Acid in the Ground State
1002
I N U Z U K A , Kozo Band Assignment of Anomalously Strong
Absorption Band of 2,6-Diaminopyridine by Interaction with
Acetic Acid 1685
I R I E , Masahiro Thermally Irreversible Photochromic Systems.
Substituent Effect on the Absorption Wavelength of 11,12Dicyano-5a,5b-dihydro-5a,5b-dimethylbenzo[l,2-Z>:6,56]bis[l]benzothiophene 430
I R I E , Masahiro Kinetics of Electroless Copper Plating in the
3
2
2
3524
Presence of Excess Triethanolamine 1313
I R I E , Ryo CD Spectral Diagnosis of Absolute Configuration of
Tetrahedral or Pseudo-Tetrahedral Metal Complexes of Salicylideneiminates 606
I R I S A W A , T e r u m i Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
I S A K A , Toshihide Hydrolytic Metalloenzyme Models. Metal
Ion Dependent Site-Selective Acylation of Hydroxyl Groups of
Bis-Imidazole Ligands Catalyzed by Z n and C u in the Reac
tion with />-Nitrophenyl 2-Pyridinecarboxylate in a Cationic
Surfactant Micelle 373
I S H I D A , Akito Synthesis and Properties of PheophorbideQuinone Compounds 1533
I S H I D A , Akito Electron-Laser Dual Beam Irradiation of 2Methylbenzophenone 3186
I S H I D A , Nobumasa Kinetics of Electroless Copper Plating in
the Presence of Excess Triethanolamine 1313
I S H I D A , Wataru Copper(II) Complexing Capacity of River
I S H I G U R O , Shin-ichi A Precise Calorimetric Study of 18Crown-6 Complexes with Sodium, Potassium, Rubidium, Cae
sium, and Ammonium Ions in Aqueous Solution 1173
I S H I G U R O , Shin-ichi X-Ray Diffraction Studies on the Struc
ture of the T r i - and Tetrathiocyanatomanganate(II) Complexes
and Solvated Lithium Ion in MN-Dimethylformamide 1445
I S H I G U R O , Shin-ichi EXAFS and X-Ray Diffraction Studies on
the Structure of the Tetrathiocyanatocadmate(II) Complex in
Dimethyl Sulfoxide 2104
I S H I I , Akihiko Generation and Characterization of 1,3-Di-/butyl- and l,3-Di-/-butyl-4,6-dimethylthieno(3,4-(ithiophenes
2821
I S H I I , Akihiko Oxidation of 2,2,3,3-Tetramethyll,4-diphenyl5,6-dithiabicyclo[2.1.1]hexane and Its Oxidation Products: An
Important Role of 1,3-Transannular Interaction in the 1,3Dithietane Part 3343
I S H I I , Daido Re-evaluation of the Acid Dissociation Constants of
the Hydroxyl Groups in Tetrasodium 25,26,27,28-Tetrahydroxycalix[4]arene-5,ll,17,23-tetrasulfonate 1012
I S H I I , Youichi Syntheses and Structures of Novel Ruthenium(II)-Chiral Diphosphine Complexes 1595
I S H I K A W A , Atsushi Luminol
Chemiluminescence-Delay
Method for Determination of Copper(II) 1591
I S H I K A W A , Jun-ichi Evaluation of Melting and Crystalline
Relaxation Temperatures of Fatty Acid Monolayers on the
Water Surface and Their Importances for Molecular Aggrega
tion States in Monolayers 864
I S H I K A W A , Junji Kinetics of Electroless Copper Plating in the
I S H I K A W A , Sei-ichi A Facile Generation and Stereoselective
Cycloaddition Reactions of 5,6-Dihydro-5,6-bis(methylene)2,4(l//,3#-)-pyrimidinedione Intermediate 2845
I S H I K A W A , Sumio Stability and Resonance Energy of Azulenequinones and the Rule for Topological Charge Stabilization
1151
I S H I K A W A , Yo-ichi Thermal and Infrared Multiphoton
Decompositions of 7-Butyrolactone in the Vapor Phase 3112
I S H I M A R U , Yoshihiro The Spectroscopic Properties and Organometallic Reactivities of Cobalt(III) Porphyrins 639
I S H I M O R I , Tatsujiro as- and fraws-Li[Co {L-tart(2-)-OM2(en) ] Hydrate Separated from the Reaction Products of
[Co (C0 )(en) ] w i t h L-Tartaric Acid 2490
I S H I O K A , Kunie Vibrational and Rotational Raman Spectra of
Trapped Hydrogen in Irradiated Ethanol Crystal at 77 Κ 2526
I S H I T A N I , Akihiko Theoretical Investigation on the Reactions
of Dichlorosilane w i t h Ammonia 3174
I S H I Z U , Kazuhiko ENDOR Study of the Cation Radicals of
I S H I Z U K A , Natsuki Pyrrolizidine Alkaloids. The Synthesis
2+
2+
m
2
Ill
3
2
+
[Vol. 65, No. 12
and Absolute Configuration of All Stereoisomers of 4-Carboxy4 ethyl-3-hydroxy-2-isopropyl-4-butanolide, the Necic Acid
Component of Axillaridine 1761
ISIHARA, Makoto Simple Relationships between CoulsonLonguet-Higgins Polarizabilities in Linear Chains 2432
ISLAM, Nashreen S. Complex Fluoroberyllates. Synthesis
and Physicochemical Characterization of Mixed-Fluoro Com
plexes of Beryllium Containing Hydrogenoxalate ( H C 2 O 4 " ) ,
Glycinate, and Dihydrogenphosphate ( Η Ρ θ Γ ) as Co-Ligands
522
ISMAIL, Mohamed Ismail Effect of Ionizable and NonIonizable Surfactants on the Polarographic Reduction of Some
Metal Ions 2761
I S O B E , Minoru A Convenient Synthetic Method of 2-Cyano-6methoxybenzothiazole, —A Key Intermediate for the Synthesis
I S O B E , Minoru Improved Synthetic Methods of Firefly Lucif
erin Derivatives for Use in Bioluminescent Analysis of Hydro
lytic Enzymes; Carboxylic Esterase and Alkaline Phosphatase
2604
ISOGAMI, Yasushi Abnormal Diels-Alder Reaction of 5Alkoxyoxazoles with Tetracyanoethylene and X-Ray Crystal
ISOGAMI, Yasushi Abnormal Diels-Alder Reaction of Oxazoles
with 4-Phenyl-3//-l,2,4-triazole-3,5(4#)-dione and Diethyl Azodicarboxylate, and X-Ray Crystal Structure of an Adduct
2998
I T A B A S H I , Hiromitsu Slab Optical Waveguide with Octadecylsilane Coated Surface for Absorption Detector of Flow Analysis
1581
ITAHARA,
Toshio Free Radical
Alkylation of
1.3Dimethyluracils and Caffeine with Benzoyl Peroxide 2045
tTO, Haruhiko Pressure-Dependent Intensity Anomalies in the
Β Σ ~ Π Perturbed Rotational Lines of the CN ( Β Σ - Χ Σ ) 1414 Band 481
ITO, Hideaki Semi-preparative Purification and Crystallization
of Synthetic Analogs of Heat-stable Enterotoxins of Enterotox
igenic Escherichia coli 938
ITO, Kaname Framework Structure, Phase Transition, and
Transport Properties in M Zr4(P04)6Compounds ( M = M g , Ca,
Sr, Ba, Mn, Co, Ni, Zn, Cd, and Pb) 3221
ITO, Kazuaki [8+2] Cycloadditions of 2,4,6-Cycloheptatriene-limines with Chloroketenes: Facile and High-Yield One-Pot Syn
thesis of l-Azaazulen-2(l//)-ones 812
ITO, Naoko Synthetic Study on Lipoteichoic Acid of Gram
Positive Bacteria. I . Synthesis of Proposed Fundamental Struc
ture of Streptococcus pyogenes Lipoteichoic Acid 2643
ITO, Satoru The Reactions of Monoalkylthio- or MonoarylthioSubstituted Cyclopropenium Salt with Nitrogen Nucleophiles:
Formation of Polyfunctionally Substituted Pyrroles or Pyrazoles 698
ITO, Suketaka Preparation of New Nitrogen-Bridged Heterocycles. 29. Reinvestigation on the Dehydrogenation Reaction of
5,5a-Dihydropyrido[2,l-c]thieno[3,2-e][l,4]thiazine Derivatives
1244
ITO, Tasuku Magnetic Properties of Oxygen Centered Trinu
clear Ruthenium(III) and Rhodium(III) Complexes 198
ITO, Tasuku Kinetic Studies on the Terminal Pyridine
ITO, Tasuku X-Ray Structure, Ligand Substitution, and Other
Properties of Trinuclear Ruthenium Complex, [RU3(M3O)(MC6H COO)6(py)3](PF ) (py=pyridine), and X-Ray Structure of
Dinuclear Ruthenium Complex, [RîM-CeHsCOO^Cl] 1585
ITO, Tetsuya Volumetric and Thermal Behaviors of Water
Uptaken in Superabsorbent Polymer 2319
ITO, Yasuo Correlation between Positron Annihilation and Gas
Diffusion Properties of a Series of Polyimides 1891
2
2
+
4
2
M
5
6
+
2
u
+
December, 19921
3525
AUTHOR INDKX
I T O , Yoshiaki Crystal Structures of N-Benzoyl Derivatives of 8Oxa-6-azabicyclo[3.2.1 )octan-7-one, f;-Caprolactam and 2-Pyrrolidone 886
I T O , Yoshio A Practical Synthesis of //zra?-3-Amino-2hydroxycarboxylic Acids 360
I T O , Yoshio Kinetic Studies of the Incorporation of the Zinc(II)
Ion into Water-Soluble iV-Phenyl-Substituted Porphyrins.
Deformation Effect on the Metallation Rate 771
I T O H , Akinobu Oxidative Chlorination of 1,10-Phenanthroline
and Its Derivatives by Phosphorus Pentachloride in Phosphoryl
Chloride 2007
I T O H , Kuniaki Titanium(III) Chloride Mediated Reduction of
Dicyanoalkenes 3068
I T O H , Mikio Optical Resolution of Amino Acid Esters by NProtected Aspartylphenylalanine Esters 1751
I T O H , Nobuyuki Choice of Manganese(III) Complexes for the
Synthesis of 4,4'-Biphenyldiols and 4,4'-Diphenoquinones 620
I T O H , Norifumi 1-Haloalkyl A r y l Sulfoxides as Useful Agents
in Synthesis of α-Halo Ketones: A New Synthesis of α-Halo
Ketones, α-Halo α,β-Unsaturated Ketones, and α-Halo Cross
Dienones from Aldehydes 2800
I T O H , Shinobu Functionalization of l//-Pyrrolo[2,3-£]pyridine
2992
IWAIZUMI, Masamoto Solution Equilibrium and EPR Study
of the Dinuclear Copper(II) Complexes of Aminopolycarboxylic
Acids with an Alcohol OH Group in the Alkyl Chain Linkage
2910
I W A K I , Akiko Thermal Behavior and Mass Spectra Aspects of
1,3,5-Triazine Derivatives Based on Isocyanuric Acid 1993
IWAMOTO, Koji Reactions of Hydridoruthenium(II) Complexes
with Alkyl Allylic Sulfides 3027
I WAMOTO, Masako Mössbauer Emission Spectroscopy of Fe
IWAMOTO, Tetsuyuki Topochemical Studies. XV. Structure
of Triclinic Form of the Photodimer of Cinnamamide 2151
IWASA, Seiji Intramolecular Radical Cyclization of Ketene
Dithioacetals 1550
I W A S A K I , Fujiko An Isomeric Series of Thiophene-Fused
Structures 2173
Tetracyanoquinodimethanes. III. Crystal Structures of ChargeTransfer Complexes with T T F 2180
I W A S A K I , Fuminori Lithium Alkylamide-Catalyzed Addition
I W A S A K I , Kentaro Crystal Structures of Metallic and Insulating Molecular Complexes between Naphthaceno[5,6-cd: 11,12c'uf]bis[l,2]diselenole and 4,8-Bis(dicyanomethylene)-4//,8//benzo[l,2-c: 4,5-c1bis[l,2,5]thiadiazole: (TSeN)(BTDA-TCNQ)
and (TSeN)(BTDA-TCNQ)(C H Cl) 3350
I W A S A K I , Kishiroo Thermostable Intramolecular Coupling
Products from Some />-Xylylenebis(anthrylcarboxylate)s and
the Relationship between Their Thermal Stability and Relative
Distortion Energy 3103
I W A S A K I , Noboru Studies on Aromatic Sesquiterpenes. XIII.
I W A S A K I , Tameo Syntheses of Aryltetralin Lignans: Concise
Syntheses of (±)-Isopodophyllotoxone, (±)-Picropodophyllone
and Their Related Compounds 3495
IWASAWA, Naoko Crystal Structures and Molecular Packing
of Tetrakis(alkylthio)tetrathiafulvalene (TTC„-TTF); Part I
(w=3,4,6) 1878
IWASAWA, Naoko Crystal Structures and Molecular Packing
of Tetrakis(alkylthio)tetrathiafulvalene (TTC -TTF); (Part II)
57
57
6
5
M
(w- 7,9,11) 2086
1WATA, Noriyoshi Reactions of (£)-2-Iodo-l-tosyl-l-alkenes as
I W A T A , Suehiro Theoretical Study of Aluminum-Sodium
A l N a ( « = l - 4 ) 2578
IYER, Meera R. Silver(I) Oxide Catalyzed Oxidation of o-Allyland o-(l-Propenyl)phenols 1662
I Z U M I , M i t s u n o r i Cd -Catalyzed Methanolysis of Phenyl Phosphatosulfate. Selectivity of Metal Ion in the Site of Cleavage of
P-O and S-0 Bond 3335
I Z U M I , Taeko Enzymatic Kinetic Resolution of [4](l,2)Ferrocenophane Derivatives 2784
I Z U M I Y A , Nobuo Synthesis of [L-a-Aminomyristic Acid » ']gramicidin S and Its Interaction with Phospholipid Bilayer
228
IZUOKA, A k i r a Crystal Structure of (ImH)[Ni(dmit) ] with
Intercolumnar Interaction through an Imidazolium Counter
Ion 2528
J A I M E , Carlos Attempted Transformation of 2,3,5,6Tetrachloro-4,4-dimethoxypentacyclo[5.4.0.0 .0 . 0 ] undecane-8,ll-dione toward Pentaprismane Retaining Chloro
Group 2312
J A K U B A S , Ryszard Motions of Methylammonium Ions in
(CH3NH3)3Sb l9 Crystals Studied by H NMR 1707
JANA, Pallabi Transfer of Electronic Excitation Energy from
2,2-Diphenylethanol to 2,6-Diphenylpyridine in Solvents of Different Viscosity 2 1 %
JEON, Il-Ryon A Rechargeable Battery Using Electrochemically-Doped Poly(3-vinylperylene) as an Electrode Material 1062
JIANG, Jianzhuang Synthesis of Water-Soluble Lanthanide
Porphyrin Sandwich Complexes: Bis(tetrapyridylporphyrinato)
Cerium(IV), [Ce(tpyp) ], and Bis(tetramethylpyridylporphyrinato) Cerium(IV), [Ce(tmpyp) ] 1990
J I K E I , Mitsutoshi Synthesis of Soluble Poly(thio-2,6-dimethyl1,4-phenylene) by Oxidative Polymerization of Bis(3,5dimethylphenyl) Disulfide 2029
J I N , Dou-man Preparation and Characterization of Cobalt(III)
Complexes Containing l,l'-Bis(diphenylphosphino)ferrocene
(dppf) or l,r-Bis(dimethylphosphino)ferrocene (dmpf) as a
Bidentate Ligand, and Molecular Structures of [Co(acac) (dmpf)]B(C H )
and [Co(dtc) (dmpf)]B(C H )4
(acac=2,4pentanedionate ion, dtc=dimethyldithiocarbamate ion) 2037
J I N , Shun-Ji Allylation of Carbonyl Compounds with Catalytic
Amount of Indium 1736
JING, Shi-Bing Removal of Phosphate from Dilute Phosphate
Solution by an Iron Chitosan Complex to Be Used as an Oral
Sorbent 1866
JOH, Takashi Syntheses and Properties of Heterodinuclear μEthynediyl Complexes Containing Palladium and Platinum
1179
JONG, Yih-ling Mechanistic Study of Acid-Catalyzed Proton
K A E R I Y A M A , K y o j i Preparation of Poly(2,5-diheptyl-l,4phenylenevinylene) by Sulfonium Salt Pyrolysis 853
K A G A W A , Mika The Kinetic Study of the Oxygen-Exchange
Water 1397
K A G A Y A , Shigehiro Determination of Arsenic(III) and Arse
n i c a by Hydride Generation—Atomic Absorption Spectrome
try Following a Rapid Coprecipitation Technique with Hafnium(IV) Hydroxide 1496
K A G E Y A M A , Akihide Modification of α-Chymotrypsin by Bromomethyl Naphthyl Ketones and Behavior of Reporter Groups
K A G E Y A M A , Shunji Synthesis of 3-Deoxy-5-0-mycaminosyltylonolide and 3-Deoxy-5-0-(4-deoxymycaminosyl)tylonolide
3405
w
2+
3
2
2e
3
3
2
1 0
5 , 9
l
2
2
2
2
6
5
4
2
6
5
3526
K A G I M O T O , Hisao Volumetric and Thermal Behaviors of
Water Uptaken in Superabsorbent Polymer 2319
K A I , Yasushi Unique Molecular Structures of Tungsten Phenoxides 1197
K A I D A , Yuriko Optical Resolution by Supercritical Fluid Chro
matography Using Polysaccharide Derivatives as Chiral Sta
tionary Phases 2286
K A I Z A K I , Kiyotaka Photochemical Reactions of 4-Acylstyrenes. Effects of Acyl Substituents on Photocyclodimerization via an Excited Triplet State 837
K A I Z U , Youkoh The Crystal Water Affecting the E -VA
Relaxation in Tris(oxalato)chromate(III) Complexes 3378
K A J I G A E S H I , Shoji Preparation of Aromatic Iodoacetyl Deriva
tives by Direct Iodination with a Potassium Iodide-Potassium
Iodate-Sulfuric Acid System 1731
K A J I G A E S H I , Shoji Halogenation Using Quaternary Ammo
Derivatives with Benzyltrimethylammonium Tetrachloroiodate 2549
K A J I I , Yoshizumi Photocyclization of Diphenylamine Studied
by Time-Resolved Thermal Lensing. Heat of Reaction, Energet
ics, and Reactivity of Intermediates 1084
K A J I I , Yoshizumi Photodissociation of Highly-Excited Triplet
State of Benzophenone Studied by a Time-Resolved Thermal
Lensing Technique 1349
K A J I T A N I , Masatsugu Photochemical Reduction of (r? CyclopentadienylXl,2-disubstituted
1,2-ethylenedichalcogenolato)cobalt(III)
and
(77 -CyclopentadienylXL2-benzenedithiolato)cobalt(III) Complexes in the Presence of Triethanol
amine 1047
K A J I Y A M A , Tisato Evaluation of Melting and Crystalline
Water Surface and Their Importances for Molecular Aggrega
tion States in Monolayers 864
K A K E H I , Akikazu Preparation of New Nitrogen-Bridged Heterocycles. 29. Reinvestigation on the Dehydrogenation Reaction
of 5,5a-Dihydropyrido[2,l-c]thieno[3,2-e][l,4]thiazine Deriva
tives 1244
K A K E H I , Akikazu Synthesis and Some Reactions of Ethyl 2-[2(Substituted Methyleneamino)anilino]cyclohepta[/>]pyrrole-3carboxylates 1538
K A K E H I , Akikazu Cycloaddition Reactions of 2-Acetylamino-,
2-Alkylamino-, 8-Ethylamino-, and
8-Acetylamino-l-azaazulenes with Dimethyl Acetylenedicarboxylate 1784
K A K I H A N A , Hidetake Esterification of Boric Acid with 1,2Propanediol, 3-Amino-l,2-propanediol, and (±)-3-Dimethylamino-l,2-propanediol as Studied by B N M R Spectroscopy
1903
K A K I N A M I , Takaaki Preparation of Aromatic Iodoacetyl
K A K I N A M I , Takaaki Halogenation Using Quaternary Ammo
K A K I S A W A , Hiroshi Acyliminium Cyclization of Chiral 5-(4Alkenyl)-5-hydroxy-2-pyrrolidinone Derivatives 2866
K A K K A R , Lajpat Rai Extractive Separation and Photometric
Determination of Vanadium with Benzoylacetone 1033
K A K K A R , Lajpat Rai Microdetermination of Rhenium with
Sodium Pentacyanonitrosylferrate(III) and Thiocyanate 1631
K A M A D A , Hitoshi ESR Study of Active Oxygen Radicals from
Photoexcited Semiconductors Using the Spin-Trapping Tech
nique 2505
K A M E D A , Yasuo The Intramolecular Structure of Oxonium
Ion in Concentrated Aqueous Deuterochloric Acid Solutions
2021
K A M E D A , Yasuo The Structure around the Nitrite Ion in
2
g
2g
5
5
n
[Vol. 65, No. 12
K A M E T A N I , Shunichi Generation and Cycloaddition Reac
tions of 3-Styryl-l,2-thiaphosphole 2-Sulfide and 1,5-Diphenyl2,4-pentadiene-l-thione 923
K A M I D A T E , Tamio Luminol
K A M I D A T E , Tamio Peroxidase-Catalyzed
Chemilumines
cence-Delay of Luminol for Determination of Traces of Copper(II) 2501
K A M I Y A , Koji High Polariton Reflectance in Heptamethinebis(dimethylamino)cyanine Chloride Crystal 2328
KAMIYA,
Yoshinori Correlation between the orthoPositronium Pick-off Annihilation Lifetime and the Free
Volume in Molecular Liquids and Polymers 160
KAMOCHI, Yasuko Lanthanoids in Organic Synthesis. I . The
Novel Reduction of Carboxylic Acids with Samarium DiiodideBase System 3049
KAMOGAWA, Hiroyoshi Synthesis and Photochromism of
Dibenzylviologen Coupled
with
5,10,15,20-Tetraphenylporphyrin or Its Metal Complex via a Carbonyloxy Spacer 301
KAMOGAWA, Hiroyoshi Spontaneous Color Development
Encountered for Diquaternary Salts of 1,10-Phenanthrolines in
Various Media 623
KAMOGAWA, Hiroyoshi Synthesis and Photo Valence Isomer
ization of Polyamide Bearing Norbornadiene Unit 2306
KANADA, Hiroyuki Deuterium Isotope Effects on Aromatic C13 NMR Chemical Shifts. IV. Can the Isotope Shifts Be Corre
lated with Bond Lengths? 2894
KANAGUCHI, Takeshi The Effect of the Coexistent Gases on
the Thermal Reaction of Toluene or Methane in a ClusiusDickel Type Thermal Diffusion Column 3434
KANAI, Hiroaki Spectrophotometric Determination of Thiocya
nate by Its Oxidation with Iodate 3153
K A N A M U R A , Kiyoshi The Calculation of Temperature and
Thermal Stress Distributions in the Planar Solid Oxide Fuel
Cell 309
KANDA, Kazuhiro Pressure-Dependent Intensity Anomalies in
the Β Σ ~ Π Perturbed Rotational Lines of the CN ( Β Σ - Χ Σ )
14-14 Band 481
K A N E H I S A , Nobuko Unique Molecular Structures of
Tungsten Phenoxides 1197
K A N E K O , Akira Photochromism of Heterocyclic Fulgides
1262
K A N E K O , Akira Effect of Two Electron-Donating Substituents
on Photochromism of Aryl Fulgide, 2-(2,6-Dimethyl-3,5substituted benzylidene)-3-isopropylidenesuccinic Anhydride
2352
K A N E K O , Emiko Determination of Aluminium in Natural
K A N E M A S A , Shuji A New Annulation Reagent, 2-0x0-3alkenylphosphonates. Reactions with Carbonyl-Stabilized Carbanions or Silyl Enol Ethers Leading to Cyclohexenones 2456
KANNO, Hideaki Preparation, Stereochemistry, and Kinetics of
Isomerization and Racemization of Bis(2,2'-bipyridine Ν,Ν'dioxide)chromium(III) Complexes Containing an Oxalate or
Malonate Ion 1233
Κ Α Ν Ο , Kenji Spectroscopic Analysis and Geometry Assignment
of the Minimum Energy Conformations of 2-Phenoxypyridines
and Diphenyl Ethers 2697
K A N Z A K I , Atsuhiro Partial Reduction of Dithioacetals with
Phosphorus Reagents 2842
K A N Z A K I , Yasushi Intercalation and Bilayer Formation of
Phospholipids in y-Type Layered Transition Metal Phosphates
180
K A S A I , Nobutami Unique Molecular Structures of Tungsten
Phenoxides 1197
K A S H I H A R A , Nobuyuki Hydrolytic Metalloenzyme Models.
Metal Ion Dependent Site-Selective Acylation of Hydroxyl
Groups of Bis-Imidazole Ligands Catalyzed by Z n and C u in
the Reaction with /»-Nitrophenyl 2-Pyridinecarboxylate in a
2
+
4
2
2 +
+
2
2 +
+
December, 1992]
Cationic Surfactant Micelle 373
K A S H I N O , Setsuo Topochemical Studies. XV. Structure of
Triclinic Form of the Photodimer of Cinnamamide 2151
K A S H I N O , Setsuo Crystal and Molecular Structures of Acetoacetanilide, and o- and />-Chloroacetoacetanilides: X-Ray Crystallography and MO Study 3234
K A S H I N O , Setsuo Crystal Structure and Molecular Conformation of l-ö-Acetyl-2,3,5-0-benzoyl-ß-D-ribofuranose 3477
K A S H I W A B A R A , Kazuo Molecular Structures of HT[MM'Cl (/i-Me Ppy) ] (MM'=Pd , PdPt, and Pt ; Me Ppy=2(Dimethylphosphino)pyridine) and //T-[Pd Cl (M-Ph Ppy) ](Ph Ppy=2-(Diphenylphosphino)pyridine) 1817
K A S H I W A B A R A , Kazuo Preparation and Characterization of
Cobalt(III) Complexes Containing l,l'-Bis(diphenylphosphino)ferrocene (dppf) or l,T-Bis(dimethylphosphino)ferrocene (dmpf)
as a Bidentate Ligand, and Molecular Structures of [Co(acac) (dmpf)]B(C H )4 and [Co(dtc) (dmpi)]B(C H5)4 (acac=2,4pentanedionate ion, dtc=dimethyldithiocarbamate ion) 2037
K A S H I W A B A R A , Kazuo Bisl2-(dimethylphosphino)ethane-lthiolatol-nickel(II), -palladium(II), and -platinum(II) Complexes,
Cobalt(III) Complexes Containing l,l,l-Tris(dimethylphosphinomethyl)ethane (mmtp), and the Crystal Structure of
[Co(mmtp) ][Co(CN)6]-2.25H 0 2748
[Co{(CH ) NC(S)Sl{R P(CH ) PR l KBF4) (R=CH 0 and CH )
3042
K A S H I W A G I , H i r o s h i Adsorption-Order Dependence of the
Numbers of Spins of Coexisting Two Radical Species on an HY
Type Zeolite 903
K A S U G A , K a z u y u k i N,N'-Di(8-quinolyl)glutaramide Exhibiting Highly Selective and Efficient Uphill Transport of Cu(II)
K A S U G A , K u n i n o b u Study of the Charge Transfer Band
3241
K A T A I , Masaaki Crystal and Molecular Structure of 3,6Dioxograyanotoxin I 2836
K A T A K A W A , Jun'ichi Crystal and Molecular Structure of 3,6Dioxograyanotoxin I 2836
K A T A K A W A , Jun'ichi Crystal and Molecular Structure of 1,5Seco-grayanotoxin-l,3,6,14,16-pentaacetate
3482
K A T A O K A , Masahiro Effects of Electron-Withdrawing Substituents on Bond Alternations in Pentalene and Heptalene
2371
K A T A O K A , Yasutaka Reaction of Tantalum-Alkyne Complexes with Isocyanates or Acyl Cyanides. Stereoselective
Functionalization of Carbon-Carbon Triple Bonds 1543
K A T A O K A , Yosuke Equation of State of the Fluid Defined by
the Modified Buckingham (exp-6) Potential Derived by Molecular Dynamics Simulations 2093
K A T A Y A M A , A t s u s h i Peroxidase-Catalyzed Chemiluminescence-Delay of Luminol for Determination of Traces of Copper(II)
2501
K A T A Y A M A , M e i s e k i Reactivity of the Transient UV-Band
Produced in Irradiated Liquid Carbon Tetrachloride with Various Alcohols 1038
K A T O , A t s u s h i Spontaneous Color Development Encountered
for Diquaternary Salts of 1,10-Phenanthrolines in Various
Media 623
K A T O , Chizuko Comparison of 2,4-Hexadienoic with 1-Hexanoic
Acids as Extractant for Copper(II) 186
K A T O , Chuzo Synthesis of Two Types of Intercalation Compounds of K Nb 0i7 with Tris(2,2'-Dipyridyl) Metal Complex
Ions 322
K A T O , H i r o s h i A Novel Skeletal Rearrangement of 22
2
2
2
2
2
2
2
2
2
2
2
6
2
5
2
3
2
2
\
6
2
4
3527
AUTHOR INDKX
6
2
2
2 2
2
3
3
Azabicyclo[2.2.l)lhe'pt-5-ene-3-carboxylic Acid Derivatives into
2-Oxabicyclo|3,3.tO]<oct-7-en-3-ones under Acidic Conditions 61
KATO, Kazumi Photosensitized Oxidation of Ethanol on
Alkoxy-Derived Ί Π 0 Powders 34
KATO, Koichi Teirmiinal-Terminal Types of Liquid Crystals. I I I .
Thermal and Electrooptical Behavior of Liquid Crystalline
Bis[urethane|s 2259
KATO, Masao Reactivity of Lithium Alkylamide toward Vinylsilane Derivatives 949
KATO, Michiharm A Stereocontrolled Synthesis of (4aS, 8a/f>
( + )-7,7-Ethylenedioxy-4,4,8a-trimethyloctahydro-2(l//)naphthalenone 2071
KATO, Michihanu A Novel Synthesis of Allenic Lactones by Use
of the (2,3|Sigmatropic Rearrangement of Cyclic PropargylsulfoniumYlides 2471
KATO, Michinobu Crystal Structures and Magnetic Properties
of Binuclear Copper(II) Complexes with Alkoxo and Benzoato
or Silanecarboxylato Bridges 2739
K A T O , Nobuo Synthetic Photochemistry. LVIII. Intramolecular
Photocycloaddition of 2-Alkenyl-6-methyl-4#-l,3-dioxin-4-ones
2940
KATO, Shinji Optical Resolution of Phenylalanine and Mandelic
Acid by Complex Formation with Copper(II) Ion 3149
K A T O , Shozo One-Step Hydroamidation of
2-Aza-1,3pentadienes 674
K A T O , Tsutomu Coal Solubilization with Cadmium and Butyl
Iodide under Mild Conditions 1067
KATO, Yoshinori Orientations of a Nematic Liquid Crystal in
Sandwich-Type Cells Studied by Polarized Electronic Absorp
tion Spectra 3135
K A T O H , Akira ^-Hydroxy Amides. X. Synthesis of a Nonapeptide with an Ala-(HO)Gly-Ala Sequence and Its Spectral and
Iron(ifl) Holding Properties 1356
K A T O H , Junya Synthesis of Soluble Poly(thio-2,6-dimethyl-l,4phenylene) by Oxidative Polymerization of Bis(3,5-dimethylphenyl) Disulfide 2029
KATSUBE, M i k i o Correlation between Positron Annihilation
and Gas Diffusion Properties of a Series of Polyimides 1891
KATSUBE, Y u k i t e r u Crystal and Molecular Structure of 3,6Dioxograyanotoxin I 2836
KATSUBE, Y u k i t e r u Crystal and Molecular Structure of 1,5Seco-grayanotoxiη-1,3,6,14,16-pentaacetate 3482
K A T S U K I , Tsutomu CD Spectral Diagnosis of Absolute Config
uration of Tetrahedral or Pseudo-Tetrahedral Metal Complexes
of Salicylideneiminates 606
K A T S U K I , Tsutomu Stereoselective Synthesis of (±)-Ireland
Alcohol Using Titanium-Mediated [2,3]Wittig Rearrangement
Product as a Starting Material 1841
K A U R , Paramjeet Synthesis and Biological Evaluation of
Dehydrophenylaianine Containing Substance Ρ Fragments
3412
K A U R , Verinder Studies on Fused ß-Lactams: Synthesis of 1Aza Analogs of Cephem 2246
K A W A B A T A , Hirosuke Reactions of Hydridoruthenium(II)
Complexes with Alkyl Allylic Sulfides 3027
K A W A G U C H I , Hiroshi The Isomerism of the (Ethylenediamine-iV, iV'-dipropionatoXethylenediamine)cobalt(III) Ion
and Its Stereoselective Isomerization Reaction 175
K A W A G U C H I , Hiroshi Preparation and Stereochemistry of
the Mixed-Ligand
Complex,
Ammine(ethylenediamine)(ethylenediamine-iV-acetato)cobalt(III) 1920
KAWAGUCHI, K e n j i Magnetic Properties of Pyro-Carbons Prepared from Polyvinyl chloride) and Activated Carbon 1144
K A W A I , Takeshi Formation of AOT Reversed Micelles and
W/O Microemulsions 2715
K A W A I , Yasuyuki Metallic Nickel-Catalyzed Reduction of Aryl
Halides with Zinc Powder and Ethanol 1739
K A W A I Z U M I , Fumio A Simple Method for the Evaluation of
Enthalpy of Proton Dissociation in Water 410
2
3528
K A W A K A M I , Shigenobu Thermal Reactions of Toluene by
Use of a Clusius-Dickel Type Thermal Diffusion Column as a
Reactor 586
K A W A K A M I , Shigenobu The Effect of the Coexistent Gases
on the Thermal Reaction of Toluene or Methane in a ClusiusDickel Type Thermal Diffusion Column 3434
K A W A K I T A , Toshio Spectroscopic Analysis and Geometry
Assignment of the Minimum Energy Conformations of 2Phenoxypyridines and Diphenyl Ethers 2697
K A W A M O T O , Atsushi Crystal Structures of Metallic and
Insulating Molecular Complexes between Naphthaceno[5,6-cd:
11,12-c1c/1bis[l,2]diselenole and 4,8-Bis(dicyanomethylene)4//,8#-benzo[l,2-c: 4,5-c1bis[l,2,5]thiadiazole: (TSeN)(BTDATCNQ) and (TSeNXBTDA-TCNQXCeHsCl) 3350
K A W A M O T O , Heizan Synthesis of 2-Amino-2,5,6-trideoxy-5phenylphosphinyl-L-galactopyranose. The P-in-the-Ring Analogue of L-Fucosamine 2922
KAWAMOTO,
Hiroshi Extractive Separation of Trace
Amounts of C u , Fe , and G a from A l on the Basis of HSAB
Rule 2537
K A W A M O T O , Hiroshi Copper(II) Complexing Capacity of
River Waters in the Urban Area 3485
K A W A M U R A , Hideo Volumetric and Thermal Behaviors of
K A W A M U R A , Shigeo Synthesis and Characterization of
Mono-, Bis-, and Trissubstituted Pyridinium and Pyrylium
Dyes 71
K A W A N O , Hiroyuki Syntheses and Structures of Novel Ruthenium(II)-Chiral Diphosphine Complexes 1595
K A W A N O , Hiroyuki Reactions of Hydridoruthenium(II) Complexes with Alkyl Allylic Sulfides 3027
KAWANO,
Shigeki X-Ray Structural Study of trans[CoCl (232N4l5)]C10
(232N 15=1,4,8,11-Tetraazacyclotricosane) 2114
K A W A S A K I , Hidehiro Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
K A W A S H I R O , Katsuhiro Catalytic Conversion of Diethyl Tartrate into Pyruvate over Silica-Supported Potassium Disulfate
2083
K A W A T A , Satoshi A Magnetic Study of the Iron(III) Complexes
of Polyols and Sugars in Aqueous Solution 1898
K A W A T A , Satoshi Solution Equilibrium and EPR Study of the
Dinuclear Copper(II) Complexes of Aminopolycarboxylic Acids
with an Alcohol OH Group in the Alkyl Chain Linkage 2910
K A W A T A , Takashi Crystal Structures and Magnetic Properties of Binuclear Copper(II) Complexes with Alkoxo and Benzoato or Silanecarboxylato Bridges 2739
K A W A T O , Sei-ichi Sodium Tellurite as a Mild and Selective
Oxidizing Agent for Thiols: Its Use in the One-Pot Synthesis of
Unsymmetrical Disulfides 626
K A W A U C H I , Osamu Fluorescence Spectra of 1-Naphthol During the Sol-Gel Process of a Mixed Aluminum-Silicon Alkoxide
(Si:Al=94:6) 720
K A Y A N O , Toshimasa Synthesis and Chemiluminescence
Properties of 6-(4-Methoxyphenyl)-2-methylimidazo[l,2-ß]pyrazin-3(7//)-one and 2-Methyl-6-(2-naphthyl)imidazo[l,2-öjpyrazin-3(7//)-one 2475
K E N J O , Tadao Relaxation Phenomena of the Concentration
Polarization in High Temperature Air Cathodes 995
K H A N , Ashfaq Rabbani Kinetics of the Forward and Reverse
Na(I)-H(I) and K(I)-H(I) Exchanges on Antimony(V) Arsenatophosphate Cation Exchanger 2192
K H A N , Asif Ali Kinetics of the Forward and Reverse Na(I)-H(I)
and K(I)-H(I) Exchanges on Antimony(V) Arsenatophosphate
Cation Exchanger 2192
K H A N , Asif Ali Chromatographic Separation of α-Amino Acids
on Antimony(V) Phosphate-Silica Gel *G' Plates from Some
Synthetic Mixtures and Drug Samples 2773
K H U R A N A , J. P. S. Studies on Fused ^-Lactams: Synthesis of
n
2
,n
4
m
m
4
IVol. 65, No. 12
1-Aza Analogs of Cephem 2246
K I D A , Sigeo Template Synthesis and Structure of a Dinuclear
Lead(II) Complex of Novel Macrocycle Derived from 2,6Diformyl-4-methylphenol and
l,9-Diamino-3,7-diazanonane
1176
K I D A , Sigeo Syntheses and Magnetic Properties of ImidazolateBridged Binuclear Copper(II) Complexes: Effect of Bridging
Mode upon Magnetic Interaction 1603
K I D A , Sigeo Synthesis and Magnetic Property of ImidazolateBridged Cu(II)-M(II)-Cu(II) Complexes (M=Zn, Cu, Ni, Co, Mn)
2283
K I D A , Sigeo Study of the Charge Transfer Band Observed in
Dialkoxo-Bridged Binuclear Copper(II) Complexes 3241
K I D A N I , Yoshinori Diastereoisomers of Platinum(II) Com
plexes with Chiral N-Substituted 1,2-Diamines. I . Structure
and Isomerization of Dichloro((i?)-2-[(2-methyl-2-aminopropyl)amino)- 1-butanol }platinum(II) 1428
K I D A N I , Yoshinori Diastereoisomers of Platinum(II) Com
plexes with Chiral Af-Substituted 1,2-Diamines. I I . Structures
of Dichloro[(S)-l-(2-amino-2-methylpropyl)amino-2-propanol]platinum(II) 2118
K I D O , Fusao A Novel Synthesis of Allenic Lactones by Use of
the [2,3]Sigmatropic Rearrangement of Cyclic Propargylsulfonium Ylides 2471
K I G O S H I , Hideo A New Bromo Diterpene, e/>*'-Aplysin-20, and
ewMsoconcinndiol from the Marine Mollusc Aplysia kurodai
2300
K I H A R A , Sorin Solvent Extraction of Divalent Metals as
Dihydrobis(l-pyrazolyl)borate Chelates 781
K I H A R A , Tetsuji A Water-Soluble Spin Probe Newly Developed
for Liposomal Studies 1041
K I H A R A , Yasuharu Reactivity of Lithium Alkylamide toward
Vinylsilane Derivatives 949
K I J I , Jitsuo Catalytic Acid Fluoride Synthesis via Carbonylation of Organic Bromides in the Presence of Potassium Fluoride
1741
K I J I , Jitsuo Palladium-Catalyzed, Atmospheric Pressure Carbonylation of Allylic Halides under the Influence of Sodium
Hydroxide or Alkoxides. A Facile Synthesis of /^-Unsaturated
Acids 2589
K I J I M A , Masashi Electrochemical Investigations of High-Spin
K I J I M A , Tsuyoshi Intercalation of a Trimethylammoniomethylated Calix[4]arene by Cu(II)-Montmorillonite 2510
K I K U C H I , Ikue Synthesis of a Polycyclic π-Conjugated System
Containing an Azulene Unit by the Flash Vacuum Pyrolytic
Method. I . Synthesis and Properties of Cyclopent[ß]azulenes
1527
K I K U C H I , Ikue Peri-Selective Cycloaddition Reactions of 3Methoxycarbonyl-2i/-cyclohepta[6]furan-2-one with 6,6-Dimethylfulvene 2127
K I K U C H I , Ikue Synthesis of a Polycyclic π-Conjugated System
Method. I I . Synthesis and Paratropic Properties of 3HCyclopent[tf]azulen-3-one and Its Methyl Derivatives 2131
K I K U C H I , Mitsuko Molecular Structures of Dimeric Reduction
Products of Pulegone 1996
K I K U C H I , Osamu Single-Excitation Configuration Interaction
Calculations of Hyperfine Coupling Constants of Small π and σ
Radicals 603
K I K U C H I , Osamu Qualitative Triplet Potential Energy Curves
of Arylethylenes along the Double Bond Twisting 1463
K I K U C H I , Osamu A M I Potential Energy Curves for Cis-Trans
Isomerization of Stilbene Cation Radicals 2267
K I K U C H I , Osamu ESR Spectra and Electronic States of 1,10Phenanthroline Radical Anions 2839
K I K U C H I , Yoichi The Solvent Extraction and Dissociation of
the Ion Pair of Alkali Metal Complex of Monodisperse Poly(oxyethylene) Derivatives with Picrate Ion 1506
December, 1992|
AUTHOR INDEX
K I K U K A W A , Mitsuo Rotational Distribution of CO(b v+) Produced in Energy Transfer Reaction from Ar( P ) to CO 1713
K I M , Young Gul Shape-Selectivity Effect of Highly Reduced
2884
K I M O T O , Eiji High-Pressure Effect on the Radical Reduction of
Spin Probes in Human Erythrocytes 1648
K I M U R A , Hitoshi Cyclization of jV-Terminal Fragments of
Elcatonin 1728
K I M U R A , Manabu Electric Field Orientation of Ionizable Polymers with Three Different Electric Dipole Moments. I . New
Orientation Function and the Steady-State Electric Birefringence of Poly(L-<*-glutamic acid) in Methanolic and Aqueous
Solutions 129
K I M U R A , Masaru Kinetics and Mechanisms of Photo-Induced
Reduction of Iodine by Monoamine-N-polycarboxylate Ions in
an Aqueous Solution 1812
K I M U R A , Masaru The Base-Catalyzed H/D-Exchange of Anisole Moiety of Ruthenium Complex in Cooperation with
Demethylation by Hydroxide Anion in Methanol-^ 2557
K I M U R A , Norio Competitive Intramolecular Electron Transfer
and S 2 Reactions of Radical Anions. Effects of Solvent Polarity on the Reaction Mechanism 1668
K I M U R A , Satoshi Oxidative Coupling of Methane over Various
Barium Salts Mixed with CaO: The Relation with Their Surface Basicities 2251
K I M U R A , Takahide Selectivity in Catalytic Dehydrogenation
with Active Manganese Dioxide 1149
K I M U R A , Takenori The Total Synthesis of Herbimycin A
2974
KINGSFORD-ADABOH,
Robert Crystal Structure and
Molecular Conformation of 10-Acetyl-2,3,5-0-benzoyl*j3-nribofuranose 3477
K I N O S H I T A , Hideki "Syn-Effect" in the Conversion of (£)Vinylic Sulfones to the Corresponding Allylic Sulfones 75
K I N O S H I T A , Hideki Reactions of (£)-2-Iodo-l-tosyl-l-alkenes
as Useful Synthetic Intermediates 1379
K I N O S H I T A , Hideki Synthesis of 2-(Substituted Methyl)-3,4Disubstituted Pyrroles and Their Conversion into the Corresponding Porphyrins 2660
K I N O S H I T A , Masamichi Synthesis and Reactions of Some
Crowded Triorganylbismuthines 3504
KINOSHITA,
Masayoshi
Substituent
Effect
on the
Enantioface-Differentiating Reaction of (#)-[Lithiomethyl pTolyl Sulfoxide] with m- or ^-Substituted Acetophenones 526
K I N O S H I T A , Setsuko Thermoanalytical Study of Dioxygencobalt(III) Complexes with
N, N'-Ethylenebis(salicylideneaminate) and Its Derivatives 3374
K I N O T O , Takao 13/3-Hydroxylation of Milbemycins by Selenium Dioxide 3300
K I N O U C H I , Shigetoshi Knoevenagel Reaction of Malononitrile
K I N U G A S A , Takumi Volumetric and Thermal Behaviors of
K I S E , Hideo Enzymatic Reactions in Aqueous-Organic Media.
XVII. Optical Resolution of Amino Acid Esters by Enzymatic
Hydrolysis in Organic Solvents 2599
K I S H I D A , Satoshi Cyclization of N-Terminal Fragments of
Elcatonin 1728
K I S H I I , Noriyuki Ru(6,6'-Diamino-2,2'-bipyridine) : Effect of
Interligand Steric Strain on the Spectroscopic, Photochemical,
and Electrochemical Properties of the Complexes 1220
K I S H I K A W A , Keiki Oxidative Substitution Reactions of Organostannyl Compounds with Lead Tetraacetate. A Convenient
Route to 5-Alkylidene-2(5#)-furanones 2366
K I S H I K A W A , Keiki Noncatalyzed Conjugate Addition Reaction of Alkylaluminum Compounds to 5-Methylene-2,4imidazolidinedione Derivative 3195
3
3
2
N
3
2+
3529
KISHIMOTO, Hiroshi Mechanochemical Reaction of Calcium
Alginate Hydrogel due to a Counterion Exchange 121
K I T A , Hidetoshi Correlation between Positron Annihilation
K I T A , Hiroyuki The Solvent Extraction and Dissociation of the
Ion Pair of Alkali Metal Complex of Monodisperse Poly(oxyethylene) Derivatives with Picrate Ion 1506
K I T A , Masakazu Molecular Structures of
HT-[MM'C\foMedPpyfcl (MM'=Pd , PdPt, and Pt ; Me Ppy=2-(Dimethylphosphino'jpyridine) and #T-[Pd Cl2(M-Ph Ppy)2](Ph2Ppy=2(Diphenylphosphino)pyridine) 1817
K I T A , Masakazu Preparation and Characterization of Cobalt(III)
(dppf) or l,r-Bis(dimethylphosphino)ferrocene (dmpf) as a
Bidentate Ligand, and Molecular Structures of [Co(acac) (dmpf)]B(C H )4
and
[Co(dtc)2(dmpf)]B(C6H5)4 (acac=2,4pentanedionate ion, dtc=dimethyldithiocarbamate ion) 2037
K I T A , Masakazu Bis{2-(dimethylphosphino)ethane-l-thiolatolnickel(II), -palladium(II), and -platinum(II) Complexes, and
Molecular Structure of the Nickel(II) Complex 2272
K I T A , Masakazu Preparation and Characterization of Cobalt(III) Complexes Containing l,l,l-Tris(dimethylphosphinomethybethane (mmtp), and the Crystal Structure of
[Co(mmtpV4Co(CN) ]· 2.25H 0 2748
K I T A , Masakazu Preparation and Characterization of
(Co{(CH3)2NC(S)S}{R P(CH )2PR } ](BF )2 (R=CH 0 and C\h)
3042
K I T A , Shouichi Pressure Effects on the Aquation Reactions
of Tris(2,2'-bipyndine)chromium(III) Ion and Tris(l,10phenanthroline)chromium(III) Ion 3253
K I T A G A WA, Röüichi Perfluoroalkylation of Olefins by Electrooxidation of Perfluoroalkanoic Acids: Relations between
Product-Selectivity and Current Density and Structures of
Olefins 1976
K I T A G A W A , T e r u h i r o Selective α-Mono- and α,α-Dialkylations of 1,3-Diketones Using Solid Base Prepared from Sodium
Ethoxide and Alumina 1185
K I T A M O R I , Yoichiro Synthesis of a Polycyclic π-Conjugated
System Containing an Azulene Unit by the Flash Vacuum
Pyrolytic Method. I . Synthesis and Properties of Cyclopent[fl]azulenes 1527
K I T A M O R I , Yoichiro Peri-Selective Cycloaddition Reactions
of 3-Methoxycarbonyl-2i/-cyclohepta[6]furan-2-one with 6,6Dimethylfulvene 2127
Pyrolytic Method. I I . Synthesis and Paratropic Properties of
3//-Cyclopent[ö]azulen-3-one and Its Methyl Derivatives 2131
Pyrolytic Method. I I I . Synthesis and Properties of 4-Hydroxy3//-cyclopent[ö ]azulen-3-one 3282
K I T A M U R A , H i r o s h i Fluorescence Spectra of 1-Naphthol During the Sol-Gel Process of a Mixed Aluminum-Silicon Alkoxide
(Si:Al=94:6) 720
K I T A M U R A , M i t s u h a r u Syntheses of Azobenzene Derivatives
Having Fluoroalkyl Chain and Their Monomolecular Film Formation at the Air/Water Interface 2141
K I T A M U R A , Naoko Kinetics and Mechanism of the Complex
Formation Reactions of Cobalt(II) with Chloride, Bromide,
Iodide, and Azide Ions, 2,2'-Bipyridine, 2,2': 6',2"-Terpyridine,
and Tris(2-pyridyl)amine in Hexamethylphosphoric Triamide
2280
K I T A O , Teijiro The Spectroscopic Properties and Organometallic Reactivities of Cobalt(III) Porphyrins 639
K I T A U R A , Kazuo Theoretical Study of Structure and Thermodynamic Properties of Liquid Hydrogen Fluoride 3122
2
2
2
2
2
2
6
5
6
2
2
2
2
2
4
3
3530
[Vol. 65, No. 12
K I T A Z A W A , Manabu Synthetic Study on Peptide Antibiotic
K I T O H , Y a s u s h i 1-Haloalkyl A r y l Sulfoxides as Useful Agents
K O B A Y A S H I , Hanako Magnetic Properties of Oxygen Cen
tered Trinuclear Ruthenium(III) and Rhodium(III) Complexes
198
K O B A Y A S H I , Keiji An Isomeric Series of Thiophene-Fused
Structures 2173
Tetracyanoquinodimethanes. I I I . Crystal Structures of ChargeTransfer Complexes with T T F 2180
K O B A Y A S H I , Kenji Enantioselectivity in the Interaction of
K O B A Y A S H I , Michio Preliminary Analysis of the Electronic
Absorption Spectrum of a Solute in a Biaxially-Stretched Poly
mer Film 463
K O B A Y A S H I , Michio Dimer Formation of 9-Cyanoanthracene
in a Nonpolar Medium at Low Temperatures 692
K O B A Y A S H I , Michio Rate Constants of the Photodegradation
and Photoisomerization of Polyenes Produced in Heat-Treated
PVA Film 1342
K O B A Y A S H I , Michio Electronic Absorption and Phosphores
cence Spectra of 2-Acetylfuran. Conformations in the Ground
and Excited Triplet States 2067
K O B A Y A S H I , Michio Orientations of a Nematic Liquid Crystal
in Sandwich-Type Cells Studied by Polarized Electronic
Absorption Spectra 3135
K O B A Y A S H I , Setsuo Thermostable Intramolecular Coupling
Products from Some />-Xylylenebis(anthrylcarboxylate)s and
the Relationship between Their Thermal Stability and Relative
K O B A Y A S H I , Tomoshige A Novel Skeletal Rearrangement of
2-Azabicyclo[2.2.1]hept-5-ene-3-carboxylic Acid Derivatives into
2-Oxabicyclo[3.3.0]oct-7-en-3-ones under Acidic Conditions 61
K O B A Y A S H I , Toshifumi Reactions of (£)-2-Iodo-l-tosyl-lalkenes as Useful Synthetic Intermediates 1379
K O B A Y A S H I , Yoshinori Correlation between the orthoPositronium Pick-off Annihilation Lifetime and the Free
Volume in Molecular Liquids and Polymers 160
K O B A Y A S H I , Yoshio Mössbauer Emission Spectroscopy of
Fe Arising from M n in Metal and Oxides of Chromium 1
K O B U T A N I , Tadashi One-Step Hydroamidation of 2-Aza-l,3pentadienes 674
K O D A M A , Hiroaki The Resolution and Absolute Configuration
of 2,3-Methanopyroglutamic Acid, 3-Oxo-2-azabicyclo[3,l,0]hexane-l-carboxylie Acid 2668
K O D A M A , Hiroshi Solidification of Iodide Ion by Reaction with
B i 0 3011
K O D A M A , Mitsuaki 7-Epidenticulatolide, a New Cembranolide
with a Cyclic Peroxide Function from the Soft Coral Lobophyturn denticulatum 1182
K O D A M A , Teruyuki Syntheses and Structures of Novel Ruthenium(II)-Chiral Diphosphine Complexes 1595
K O D E R A , Masahito Study of the Charge Transfer Band
3241
K O D O M A R I , Mitsuo Direct Iodination of Aromatic Compounds
with Iodine and Alumina-Supported Copper(II) Chloride or Sul57
57
2
3
fate 306
KOGA, Kazuhi Synthesis and Photochromism of Dibenzylviologen Coupled with 5,10,15,20-Tetraphenylporphyrin or Its Metal
Complex via a Carbonyloxy Spacer 301
KOGA, Osamu Infrared Spectroscopic Observation of Adsorbed
C0 at a Nickel Electrode 3008
K O G A N E , Tamizo Structures and Spectral Properties of Some
Bis(carboxylato)copper(II)-Pyrazole Complexes. I . Preparation
of Bis(trifluoroacetato)tetrakis(pyrazole)copper(II) 2638
K O H , Dong Jun Shape-Selectivity Effect of Highly Reduced
2884
K O H , Lip L i n Rotational Isomerism and Crystal Structures of 2Methyl-2,3,3-trinitrobutane and 2-Methyl-2,3,3-trinitropentane
489
K O H , Tomozo Spectrophotometric Determination of Thiocyanate by Its Oxidation with Iodate 3153
K O H I K I , Shigemi X-Ray Photoelectron Study of the Methane
Interaction with LaCoOe 1295
K O H M O T O , Shigeo Chiral Hydantoin; A New Dienophile for
Diels-Alder Reaction 935
KOHMOTO, Shigeo Intramolecular Radical Cyclization of
KOHMOTO, Shigeo Oxidative Substitution Reactions of Organostannyl Compounds with Lead Tetraacetate. A Convenient
Route to 5-Alkylidene-2(5//)-furanones 2366
KOHMOTO, Shigeo Noncatalyzed Conjugate Addition Reaction
of Alkylaluminum Compounds to 5-Methylene-2,4-imidazolidinedione Derivative 3195
KOHNO, Hiroshi Hydrophobic Vitamin Bi . XL Preparation,
Characterization, and Enantioselective Alkylation of Hydrophobic Vitamin B12 Bearing a Binaphthyl Moiety 3094
KOHNO, Isao Mössbauer Emission Spectroscopy of Fe Arising
from Mn in Metal and Oxides of Chromium 1
KOHNO, Isao Crystal and Molecular Structures of Acetoacetanilide, and 0- and />-Chloroacetoacetanilides: X-Ray Crystallography and MO Study 3234
K Ö H R A , Kiichiro A Systematic Study on the Bakers' Yeast
631
K O H Z U M A , Takamitsu Copper(II)-Thioether Bondings in
Multidentate N,S-Donor Ligand Complexes. Structural
Dependence of the Chemical Properties of the Copper(II) Complexes of l,5-Bis(2-pyridylmethylamino)-3-thiapentane and 2,6Bis(2,6-dithiaheptyl)pyridine 786
K O I D E , Tomoyuki Determination of the Molar Absorption
Coefficients of c-Type Cytochromes Using Optically Transparent Thin-Layer Electrodes 424
K O I K A W A , Masayuki Crystal Structures of Mono- and Dinuclear Nickel(II) Complexes Derived from the Substitution
Reaction of [Ni(Me2[14]dienatoN )]I and Each of Benzoyl Chloride and Isophthaloyl Dichloride 258
K O I K E , Tetsufumi Reaction of Olefins with Dimethyl(methylthio)sulfonium Salts in the Presence of Triphenylphosphine.
Preparation of Vinylphosphonium Salts 2375
K O I K E , Tohru Sonolysis Studies of Alcohols in Aqueous Solutions by Gaseous Products Analysis 3215
K O I Z U M I , Terutake ESR Spectra and Electronic States of 1,10Phenanthroline Radical Anions 2839
K O I Z U M I , Toshiaki Electron Transport and Redox Chain Reactions in a Mosaic Membrane 1561
K O J I M A ; Masaaki Preparation and Characterization of
[Co(tp)2(Me«-en)] (tp^Tropolonate Ion; Me«-en (w=l—4)=NMethyl Substituted Ethylenediamine), Inversion and Deuteration at Chiral Nitrogen Centers of [Co(tp) (N,N-Me2-en)]C10
and Crystal Structures of [Co(tp) (N,7V-Me -en)]C10 and
^(7?)J(S)-[Co(tp) (Me-en)]C10
1572
K O J I M A , Masaaki Structures of Two Geometrical Isomers of
2
2
57
57
4
+
2
2
2
4
4
2
4
December, 19921
AUTHOR INDEX
Dioxo[(S)-iV-salicylidene-3-aminopyrrolidine]vanadium(V)
1725
K O J I M A , T o m o a k i N-Hydroxy Amides. X. Synthesis of a Nonapeptide with an Ala-(HO)Gly-Ala Sequence and Its Spectral
K O J I M A , Yoshitane Two Conformers and Aggregation of Cy
clic Octapeptide, cyc/o(G-eLL-G)2, in Chloroform 917
K O K U S E N , Hisao Solvent Extraction of Divalent Metals as
K O M A , N o r i o Orientations of a Nematic Liquid Crystal in
tion Spectra 3135
K O M A I , T o r u Photochemical Reduction of (^-Cyclopentadienyl)(l ,2-disubstituted
l,2-ethylenedichalcogenolato)cobalt(III)
and
(T7 -Cyclopentadienyl)(l ,2-benzenedithiolato)cobalt(III)
Complexes in the Presence of Triethanolamine 1047
K O M A T S U , M i t s u o Functionalization of l//-Pyrrolo[2,3%yridine 2992
K O M A T S U , Tsuyoshi Complex Formation of Poly(acrylic acid)
with Mg, Mn, and Pb Ions in Dioxane-Water Mixed Solvents
1500
K O M I Y A M A , M a s a h a m Chemical State Analysis of Sn-Sb-0
Solid Surfaces by Auger Electron Spectroscopy: Differentiation
ofSb(III)andSb(V) 2709
K O M U R A , Teruhisa The Fluorescence Properties of (2-Nitro5,10,15,20-tetraphenylporphyrinato)zinc 1475
K O M U R O , E r i k a Action of Fatty Acid Esters of L-Ascorbic Acid
as Antioxidants in Phosphatidylcholine Liposomal Membranes
679
K O N - N O , K i j i r o Formation of AOT Reversed Micelles and W/O
Microemulsions 2715
K O N D O , K o j i Kinetics of Electroless Copper Plating in the
K O N D O , M i c h i o The Resolution and Absolute Configuration of
2,3-Methanopyroglutamic
Acid,
3-Oxo-2-azabicyclo[3,l,0]hexane-l-carboxylic Acid 2668
K O N D O , Shinichi Total Synthesis of Siastatin Β and Its Enantiomer Using Carbohydrate as a Chiral Educt 978
K O N D O , Shoichi A Computational Approach to the Structure
and Motion of Hexakis(pentyloxy)triphenylene(THE5) in Discotic Mesophase 1057
KONDO, Shuji Triphenylselenonium Salts as Effective PhaseTransfer Catalysts 2555
K O N D O , Tadao Improved Synthetic Methods of Firefly Luciferin Derivatives for Use in Bioluminescent Analysis of Hydrolytic Enzymes; Carboxylic Esterase and Alkaline Phosphatase
2604
KONDO, Yasuhiko Structural Studies of Arylazo(a,adimethylbenzyl)malononitriles. Evidence against the Correla
tion between Bond Length and Reactivity in Bond Cleavage
Reactions 2394
K O N D O W , T a m o t s u Pressure-Dependent Intensity Anomalies
in the Β Σ ~ Π Perturbed Rotational Lines of the CN ( Β Σ Κ Σ ) 14-14 Band 481
K Ö N I S H I , T o m o h i r o Catalytic Properties of Lanthanide Metals
on Silica 244
KGNNO, E m i The Selective Separation of Organic Acids
"hrough Liquid Membrane Containing Ferrite in the Presence
)f Alternating Magnetic Field 1556
KONNO, T a k u m i Stereoselective Formation and Some Proper:ies of Polynuclear Cobalt(III) Complexes with D-Peniciliaminate 794
KONNO, T a k u m i Synthesis and Properties of T-Cage-Type
Se-Bridged Polynuclear Co(III) and Rh(III) Complexes with
2-Aminoethaneselenolate
(aese).
Crystal
Structure of
[{Co(aese) }4Zn 0](C104)6 3015
KOSEKI, Shiro Theoretical Investigation on the Reactions of
Dichlorosilane with Ammonia 3174
KOSEMURA, Seiji Citreobenzofurans A, B, and C, First Isola5
2
2
+
4
2
+
3
4
+
3531
tion of Sesquiterpene-Type Metabolites of a Hybrid Strain KO
0031 Derived from Penicillium Citreoviride B. IFO 4692 and
6200 926
KOSHI, Mitsuo A Flash Photolysis Study of CH<-0 Mixtures
behind Shock Waves: Examination of Reaction of CH3+O2
1317
KOSUGI, Hiroshi Solution Equilibrium and EPR Study of the
K O T A N I , Shozo Synthetic Study on Lipoteichoic Acid of Gram
Positive Bacteria. I . Synthesis of Proposed Fundamental Structure of Streptococcus pyogenes Lipoteichoic Acid 2643
KOTO, Shinkiti Dehydrative Glycosylation Using Heptabenzyl
Derivatives of Glucobioses and Lactose 3257
KOUNO, H i r o y u k i Rotational Distribution of CO(b X ) Produced in Energy Transfer Reaction from Ar( P2) to CO 1713
K O Y A N A G I , Motohiko A Time-Resolved EPR Study on the
Photochemical α-C lea vage of Benzoin and Related Molecules
1679
KOZAWA, Kozo Prismatic and Antiprismatic [42]Ferrocenophanes ([4](1,1')[4](3,3')- and [4](U0[4](3,40Ferrocenophanes) 3275
K O Z I M A , Sinpei 1,2-Addition of Ally I and 2-Oxo-2//-pyran-6ylcarbonyl Groups to Cyclic C=N Double Bonds by Means of
Organotin Reagent for Alkaloids Synthesis; A Facile Synthesis
of 8-Oxoprotoberberine and Norketoyobirine (Demethoxycarbonyloxogambirtannine) 298
KOZIOL, Piotr Motions of Methylammonium Ions in
(CH3NH3) Sb l9 Crystals Studied by *H NMR 1707
KOZONO, Ichiro An Efficient and Practical Synthesis of L-aAmino Acids Using (7?)-Phenylglycinol as a Chiral Auxiliary
2359
KOZYREV, A n d r e i N . Synthesis and Properties of
K R U P A D A N A M , Gazula L e v i David DDQ Oxidation of 6- or
8-Allyl-7-hydroxycoumarins. A New Synthesis of Benzodipyrandiones and Furobenzopyranones 1191
K U B O , A k i r a Synthetic Study on Peptide Antibiotic Nisin. V.
Total Synthesis of Nisin 2227
K U B O , M . Kenya Mössbauer Emission Spectroscopy of Fe
Arising from Mn in Metal and Oxides of Chromium 1
K U B O , Satoru Racemization of Optically Active Aromatic NAcetylamino Acids and Asymmetric Transformation of NAcetyl-2-(4-hydroxyphenyl)glycine via Salt Formation with
K U B O , Satoshi New Cholestane Bisdesmosides from the Bulbs
of Ornithogalum thyrsoides 1120
K U B O , Tsuyoshi Rate of Back-Extraction of Tris(acetylacetonato)- and Tris(trifluoroacetylacetonato)chromium(III)
from Carbon Tetrachloride into Aqueous Acid Perchlorate
Solutions 415
K U B O , Yasuo Photochemistry of 1,2:4,5-Benzenebis(dicarboximide). Insertion of Alkenes into the C-N Bond of Ν,Ν'Dihexyl-1,2:4,5-benzenebis(dicarboximide) 2875
K U B O T A , Tanekazu Spectroscopic Analysis and Geometry
Assignment of the Minimum Energy Conformations of 2Phenoxypyridines and Diphenyl Ethers 2697
KUBOZONO, Yoshihiro ESR Spectra of Some Allene Radicals
in Low-Temperature Matrices 2442
KUBOZONO, Yoshihiro Crystal and Molecular Structures of
Acetoacetanilide, and 0- and />-Chloroacetoacetanilides: X-Ray
Crystallographic and MO Study 3234
K U C H I T S U , Kozo Pressure-Dependent Intensity Anomalies in
the Β Σ ~ Π Perturbed Rotational Lines of the CN ( Β Σ - Χ Σ )
14-14 Band 481
K U C H I T S U , Kozo Rate Constants of the Photodegradation and
Photoisomerization of Polyenes Produced in Heat-Treated PVA
Film 1342
K U D O , A k i h i k o Photocatalytic Hydrogen Evolution from Aque2
3
+
3
3
2
57
57
2
+
4
2
+
2
+
3532
[Vol. 65, No. 12
ous Methanol Solution on Niobic Acid 1202
K U D O , Hiroyuki A Facile Synthesis of Sulfoxides by Oxidation
of Sulfides with Sodium Bromite in an Aprotic Solvent in the
Presence of Clay Minerals 1744
K U D O , K e i k o Dehydrative Glycosylation Using Heptabenzyl
K U D O , Tadahiro Lanthanoids in Organic Synthesis. I. The
Novel Reduction of Carboxylic Acids with Samarium DiiodideBase System 3049
K U D O , Toshiaki Total Synthesis of Siastatin Β and Its Enantiomer Using Carbohydrate as a Chiral Educt 978
K U L K A R N I , Shantaram B . Solid State Oscillatory Reaction. I .
Thermal Decomposition Studies of [Co(NH )6)Br and
CoBr -2H 0 1026
K U M A M O T O , Takanobu A New Synthesis of 5-Substituted 3Methyl-2-phenylthio-2-penten-5-olides 2794
K U M A R , A w a d h e s h C 0 Laser Induced Sensitized Dissocia
tion of Ethylene Oxide 1691
K U M A R , Vaijayanti Regioselective Allylations of Pyrimidine
Ribonucleosides Using Pd(0) Catalyst 1665
K U M O N , Toyo Cobalt(III) Complexes with Quadridentate
Ligands. XI. The Preparation and Properties of as-a-lsomer of
the Salicylato(triethylenetetramine)cobalt(III) Complex 283
K U M U R A , Hiromi Radical Intermediates in the Thermal
Decomposition of l,l-Bis(/-butyldioxy)cyclohexane 664
K U N I E D A , Norio Substituent Effect on the EnantiofaceDifferentiating Reaction of (/?)-[Lithiomethyl />-Tolyi Sulfoxide]
with m- or ^-Substituted Acetophenones 526
K U N I M O R I , Kimio Time-Resolved Infrared Emission Studies
of C 0 Formed by Catalytic Oxidation of CO on Ft and Pd
Surfaces 2450
K U N I M O R I , Kimio Partial Oxidation of Methane to Synthesis
Gas over Rhodium Vanadate, RhV0 : Redispersion of Rh Metal
during the Reaction 2562
K U N I M O R I , Kimio Preparation of Niobates of Rhodium and
Nickel by Chemical Mixing Methods 3218
K U N I O S H I , Nilson Fuel Mixing Effects on Propagation of Pre
mixed Flames. I . Hydrogen+Carbon Monoxide Flames 2569
K U N I O S H I , Nilson Fuel Mixing Effects on Propagation of Pre
mixed Flames. I I . HydrogenH-Methane Flames 2573
K U N I S A D A , Hideo Triphenylselenonium Salts as Effective
Phase-Transfer Catalysts 2555
K U N O , Hideyuki Regioselective Hydrogenation of Unsaturated
Compounds Using Platinum-Zeolite Coupled with Organosilicon Alkoxide by CVD Method 1240
K U N O , Y u k i e Diastereoselective Addition of Grignard Re
agents to 3,4-0-Isopropylidene-l-0-triphenylmethyI-L-^/ycero-2tetrulose
and l-0-Benzoyl-3,4-0-isopropylidene-L-^/yc^rö-2tetrulose 2814
K U R A C H I , Saeko Molecular Structures of ΗΤ-[ΜΜΌ\ (μ·
Me Ppy) ] (MM'=Pd , PdPt, and Pt ; Me Ppy=2-(Dimethylphosphino)pyridine) and
i/T-[Pd Cl (M-Ph Ppy) ](Ph Ppy=2(Diphenylphosphino)pyridine) 1817
K U R A C H I , Saeko Preparation and Characterization of
as a Bidentate Ligand, and Molecular Structures of [Co(acac) (dmpf)]B(C H5)4
and
[Co(dtc) (dmpf)]B(C H5)
(acac=2,4pentanedionate ion, dtc=dimethyldithiocarbamate ion) 2037
K U R A C H I , Saeko Preparation and Characterization of Cobalt(III) Complexes Containing l,l,l-Tris(dimethylphosphinomethyl)ethane (mmtp), and the Crystal Structure of
[Co(mmtp) ][Co(CN) ] · 2.25H 0 2748
K U R A C H I , Saeko X-Ray Strucutre and Conformational Anal
yses of Cobalt(III) Complexes Containing 1,3-Propanediamine
and 1,4-Butanediamine 3033
K U R A M O T O , Yasunori Rate Constants of the Photodegradation and Photoisomerization of Polyenes Produced in HeatTreated PVA Film 1342
3
2
3
2
2
2
4
2
2
2
2
2
2
2
2
2
2
2
2
6
2
2
6
2
6
4
K U R I H A R A , Hirondo The Catalytic Electroreduction of Dioxygen on Iron Protoporphyrin IX Modified Glassy Carbon Elec
trodes 1491
K U R I H A R A , Teruo Stability and Resonance Energy of Azulenequinones and the Rule for Topological Charge Stabilization
1151
K U R O D A , Kazuyuki Synthesis of Two Types of Intercalation
Compounds of K Nb 0i? with Tris(2,2'-bipyridyl) Metal Com
plex Ions 322
K U R O D A , Satoru Stereoselective Synthesis of (±)-Ireland Alco
hol Using Titanium-Mediated [2,3]Wittig Rearrangement Prod
uct as a Starting Material 1841
K U R O D A , Shigeyasu Synthesis and Properties of DiaminoSubstituted Dipyrido [3,2-A: 2',3'-c]phenazine 1006
K U R O D A , Shigeyasu Oxidative Chlorination of 1,10Phenanthroline and Its Derivatives by Phosphorus Pentachloride in Phosphoryl Chloride 2007
K U R O D A , Tooru Syntheses of Aryltetralin Lignans: Concise
K U R O K A W A , Hidemoto Optical Resolution by Replacing
Crystallization of (#S)-4-Thiazolidinecarboxylic Acid with LAmino Acids as Cosolute 267
K U R O K A W A , Hidemoto Racemization of Optically Active
Aromatic MAcetylamino Acids and Asymmetric Transforma
tion of iV-Acetyl-2-(4-hydroxyphenyl)glycine via Salt Formation
with Optically Active or-Methylbenzylamine 965
K U R O S A K I , Akito The Effect of the CC1 F-Treatment on Wet
tability of Silica Glass Surface by Water and Organic Liquid
628
K U R O S A W A , Kazu Choice of Manganese(III) Complexes for
the Synthesis of 4,4'Biphenyldiols and 4,4'-Diphenoquinones
620
K U R O S A W A , Kazu Manganese(II and III)-Mediated Synthesis
of Cyclic Peroxides from Alkenes, Active Methylene Com
pounds, and Molecular Oxygen 1371
K U S A K A B E , Satoshi Solvent Extraction and Association of
Nitrophenols with Trioctylphosphine Oxide in Cyclohexane
2534
KUSUMOTO, Masahiko Electroreductive Deoxygenation of
KUSUMOTO, Shoichi Synthesis of New Serine-Linked Oligo
saccharides in Blood-Clotting Factors VII and IX and Protein Z.
The Syntheses of 0-a-D-Xylopyranosyl-(l->3)-D-glucopyranose,
0-a-D-Xylopyranosyl-(l-^3)-0-a-D-xylopyranosyl-(l->3)-Dglucopyranose, and Their Conjugates with Serine 436
K U S U M O T O , Shoichi Synthetic Study on Lipoteichoic Acid of
Gram Positive Bacteria. I . Synthesis of Proposed Fundamental
Structure of Streptococcus pyogenes Lipoteichoic Acid 2643
KUSUMOTO, Tetsuo Hydrosilylation of 1,4-Bis(trimethylsilyl)butadiyne and Silyl-Substituted Butenynes 1280
K U S U Y A M A , Yoshiaki Substituent Effects on the C and
N NMR Spectra of ^-Substituted Phenylacetonitriles 2546
K U W A H A T A , Mitsuyoshi Numerical Formulation of Pigment
Release from Magnetically Anisotropic Gel Beads with Respect
to the Magnetic Moment in an Alternating Magnetic Field 396
K U W A T A , Keiji Time-Resolved ESR Studies on Photosensi
tized Reaction of Maleic Anhydride in Alcohols: CIDEP Memory
Transfer in Spin-Adduct Formation 1672
K U Z U K A W A , Masahiro ESR Studies at High-Pressure. IV.
Spin-Exchange Reactions of Various Types of Nitroxides in
Some Low-Viscosity Solvents 3118
LAM, Y u Lin Rotational Isomerism and Crystal Structures of 2Methyl-2,3,3-trinitrobutane and 2-Methyl-2,3,3-trinitropentane
489
L E E , Bong Stabilization Energy of the 9,9'-Trimethylenedianthracene Radical Cation Estimated by the Charge
Resonance Band 909
4
6
3
13
15
3533
AUTHOR INDEX
December, 1992]
L E E , K u o - H s i u n g Catalytic Hydrogenation of Dehydro Quassinoids and Cytotoxic Antitumor Activity of the Hydrogenation
Products 2684
L E E , Ming-San Metallic Nickel-Catalyzed Reduction of Aryl
LEE, Sannumu Refolding of Trimeresurus flavoviridis Phospholipases A 2655
L E E , Soo-Y. Relation between the Vibrational Wavepacket Propagation Formalism and the Time-Correlation Function Formalism for Absorption and Raman Scattering 1703
LEE, Swee Yong Rotational Isomerism and Crystal Structures
of 2-Methyl-2,3,3-trinitrobutane and 2-Methyl-2,3,3-trinitropentane 489
LEE, Young Seub Shape-Selectivity Effect of Highly Reduced
2884
L I U , Y u n q i Preparation of Bis(phthalocyaninato)lutetium with
Various Substituents and Their Electrochemical Properties
250
LOO, Boon H . Detection of Pitting on Cast Iron with AC Impedance Spectroscopy 2315
LOPEZ B A R B A , Ana Efficient Preparation of a Valuable Intermediate in the Synthesis of (-)-Swainsonine 567
L O W N , J. W i l l i a m Synthesis of a Series of Acodazole and
Naphthothiophene-Deuterioporphyrins and Metalloporphyrins
579
L U N D S T R Ö M , Torsten Growth Conditions of TaaB Single
Crystals Prepared by the Aluminium-Flux Method 421
MA, Guilin Preparation and Characterization of [CcKtpMMenen)| (tp=Tropolonate Ion; Me -en (n-l—4)=N-Methyl Substituted Ethylenediamine), Inversion and Deuteration at Chiral
Nitrogen Centers of [Co(tp)2(Me-en or Me^-en)]" ", and Crystal
Structures of [Co(tp) (/V,A^-Me -en)]C104 and
A(R)J(S)[Co(tp) (Me-en)]C10 1572
M A B U C H I , T o s h i a k i Fluorescence Spectra of 1-Naphthol During the Sol-Gel Process of a Mixed Aluminum-Silicon Alkoxide
(Si:Al=94:6) 720
M A C H I D Ä , K e n - i c h i Mutual Separation Characteristics and
Mechanism for Lanthanoid Elements via Gas Phase Complexes
with Alkaline Metal and/or Aluminium Chlorides 2724
M A C H I D A , Katsunosuke Simulation of Vibrational Spectra of
Acetic Acid by an Extended Molecular Mechanics Method and
Half Band Width Parameters 746
M A C H I D A , K e n - i c h i Synthesis of Water-Soluble Lanthanide
Porphyrin Sandwich Complexes: Bis(tetrapyridylporphyrinato)
Cerium(IV), [Ce(tpyp)2], and Bis(tetramethylpyridylporphyrinato) Cerium(IV), [Ce(tmpyp) ] 1990
M A D I G A N , M i c h a e l T. Substituent Effects on the Aggregation
of Bacteriochlorophyll d Homologues Purified from Chlorobium
limicola 3493
M A E D A , K i y o t o Oxidation of 2,2,3,3-Tetramethyl-l,4-diphenyl5,6-dithiabicyclo[2.1.1]hexane and Its Oxidation Products: An
Important Role of 1,3-Transannular Interaction in the 1,3Dithietane Part 3343
M A E D A , K o k o Thermochromism of 5,10,15,20-Tetraarylporphyrins at Low Temperature 3358
M A E D A , T a m a k i The Binding Characteristics of Sodium Decyl
Sulfate to Poly(L-ornithine) with l-Alkanesulfonate Counter
Ions 1146
M A E D A , Yonezo Fe Mössbauer Spectra, Crystal Structure,
and Spin-Crossover Behavior of [Fe(mbpN)(lut)]BPh 1825
M A E K A W A , T a k a s h i Optical Resolution of Phenylalanine and
Mandelic Acid by Complex Formation with Copper(II) Ion
3149
M A E K A W A , Yasunari Habit Modification of a Diastereomeric
Salt with an Additive in Optical Resolution 1747
M A G A N , Archana Synthesis of a Series of Acodazole and
579
2
4
+
w
1
2
2
2
4
2
57
4
M A H A N T I , Bibekananda Kinetics and Mechanism of Substitution of Aqua-Ligands from as-Diaquobis-[2-(m-tolylazo)pyridine]ruthenium(II) Complex by 1,10-Phenanthroline in
Aqueous Medium 1626
M A H E S H W A R I , Sanjiv M o h a n Chromatographic Separation
of α-Amino Acids on Antimony(V) Phosphate-Silica Gel 'G'
Plates from Some Synthetic Mixtures and Drug Samples 2773
M A L L I C K , Debnath Kinetics and Mechanism of Anation of eis[Ru(bpy)2(H 0)2) Ion by 8-Quinolinol in Water-Ethanol Mix
tures 609
M A L L I K , Biswanath Adsorption-Induced Electrical Conductiv
ity of Some Ferrocene Derivatives: Rates of Adsorption and
Desorption of Vapors 3462
M A L L I K , Gautam K u m a r Transfer of Electronic Excitation
Energy from 2,2-Diphenylethanol to 2,6-Diphenylpyridine in
Solvents of Different Viscosity 2196
M A N , Ho Soc Phenylacetaldehyde and Carbon Monoxide as
Effective Additives for the Selective Hydrogenation of Cyclooctadienes to Cyclooctene over Palladium Catalysts 2960
M A N A B E , Masahiro Volumetric and Thermal Behaviors of
MARCHESELLI, Luigi Viscosities and Activation Energies of
Viscous Flow of the l,2-Ethanediol/N,iV-Dimethylformamide
M A R C H E T T I , Andrea Viscosities and Activation Energies of
Viscous Flow of the 1,2-Ethanediol/N, N-Dimethylformamide
M A R E I , Mohamed Gaber A New Synthesis of Pyrazolo[l,5cJpyrimidines from Acetylenic 0-Diketones 3419
M A R E I , Mohamed Gaber Synthesis and Reactions of 1Heteroaryl-5-phenyl-4-pentyne-l,3-diones 3509
M A R U O , Katsuya Photocatalysis of Perfluorinated 01igo(£Phenylene)s 3439
M A R U O K A , K e i j i On the Mechanism of OrganoaluminumPromoted Claisen Rearrangement of Allylic Vinyl Ethers 541
M A R U O K A , K e i j i Asymmetric Diels-Alder Reaction of Cyclopentadiene and Methyl Acrylate Catalyzed by Chiral Organoaluminum Reagents 3501
M A R U Y A , K e n - i c h i Photocatalytic Hydrogen Evolution from
M A R U Y A M A , Kazuhiro Synthesis and Intramolecular
Electron-Transfer Reaction of Distance-Fixed Quinone-Linked
Porphyrins 2807
M A R U Y A M A , Kazuhiro Synthesis of Benzochlorin Monomer,
Dimer, and Porphyrin-Benzochlorin Heterodimer from 5-Aryland 5,15-Diaryl-octaethylporphyrins 3322
M A R U Y A M A , Kazunori Rate Constants of the Photodegradation and Photoisomerization of Polyenes Produced in HeatTreated PVA Film 1342
M A R U Y A M A , K a z u n o r i Orientations of a Nematic Liquid
Crystal in Sandwich-Type Cells Studied by Polarized Elec
tronic Absorption Spectra 3135
M A R U Y A M A , Noboru The Isomerism of the (Ethylenediamine-N,N'-dipropionato)(ethylenediamine)cobalt(III) Ion
and Its Stereoselective Isomerization Reaction 175
M A R U Y A M A , Yusei Crystal Structures of T X C - T T F
(X=Se,Te) 1482
M A R U Y A M A , Yusei Crystal Structures and Molecular Pack
ing of Tetrakis(alkylthio)tetrathiafulvalene (TTC -TTF); Part
I ( n = 3 , 4 , 6 ) 1878
M A R U Y A M A , Yusei Crystal Structures and Molecular Pack
ing of Tetrakis(alkylthio)tetrathiafulvalene ( T T C - T T F ) ;
(Part II) («=7,9,11) 2086
M A S A K I , N o b u y u k i M . Effect of y-Ray Irradiation on the
Recoil Tritium Reaction in Xenon-Hydrogen Mixtures at 77
and 4.2 K. Competition of the Tunneling Reaction w i t h the
Combination Reaction 735
M A S H I Y A M A , N o r i y u k i Selective Permeation Properties of
Inorganic Ions across a Hydrophobic Membrane 1871
2
2+
8
W
3534
[Vol. 65, No. 12
B U L L E T I N O F THE CHEMICAL SOCIETY OF JAPAN
M A S U D A , Hideki Copper(II)-Thioether Bondings in Multidentate N.S-Donor Ligand Complexes. Structural Dependence of
the Chemical Properties of the Copper(II) Complexes of 1,5Bis(2-pyridylmethylamino)-3-thiapentane
and
2,6-Bis(2,6dithiaheptyl)pyridine 786
MASUDA, Takahiro Reactions of Water and Dinitrogen Monox
ide Adsorbed on Cation-Exchanged Zeolite with Excess Elec
trons Generated by Gamma-Radiation 140
M A S U D A , Yoshiaki A Stereocontrolled Synthesis of (4aS,
8a/?)-(+)-7,7-Ethylenedioxy-4,4,8a-trimethyloctahydro-2(l//)naphthalenone 2071
M A S U D A , Yuzuru The Hydroboration of 3-Chloro-ltrimethylsilyl-l-propyne with Dialkylboranes and Its Applica
tion to the Syntheses of (£)-3-Trimethylsilyl-2-alkenes and 3Trimethylsilyl-l-alkenes 685
M A S U D A , Yuzuru The Hydroboration of 3-Chloro-l-iodo-lpropyne with Dialkylboranes, and Its Application to the Syn
theses of Some Geminally Dialkylated Propene Derivatives
3294
MASUI, Kanji Anion-Selective Field-Effect Transistor Sensor
Using RF-Sputtering Film of Alkali Metal-Free Lead Phosphate
Glass Containing Silver Oxide 2338
M A S U Y A M A , Araki Complexation Property of a Novel Macrobicyclic Polyether with Two Amide Moieties toward Alkali
Metal and Alkaline Earth Metal Cations 3490
M A T A K A , Shuntaro Decomposition of [2.2.2]Cyclophane-l,2dione Mono- and Bis(tosylhydrazone)s 1469
M A T A K A , Shuntaro Preparation of 1,2,3-Naphthalenetriamine,
M A T A K A , Shuntaro A Novel Ring Transformation of 3a,5,6aTriaryl-3,3a-dihydro-2//-furo[3,2-/?]pyrrole-2 6(6a//)diones into
3-Aroyl-2,5-diarylpyrrole Derivatives 2611
MATANO, Yoshihiro Synthesis and Reactions of Some
Crowded Triorganylbismuthines 3504
M A T S U B A , Shigeru Synthesis of Model Compounds of SafflominC 452
M A T S U B A , Shigeru Synthesis of Syzygiol; A Skin-Tumor Pro
motion Inhibitor 2552
M A T S U B A R A , Yoshiharu Novel Reduction of Carboxylic
Acids and Hydroboration of Olefins by Electrolysis of Sodium
Borohydride 530
M A T S U B A Y A S H I , Nobuyuki Selective Hydrogenation of Car
bon Dioxide to Methanol on Cu-ZnO/Si02 Catalysts Prepared
by Alkoxide Method 2520
M A T S U D A , Fuyuhiko A Practical Synthesis of threo-3-Amino2-hydroxycarboxylic Acids 360
M A T S U D A , Haruo Allylation of Aldehydes by Allyl- and Crotyltributyltin in the Presence of Catalytic Amounts of Bu SnCl
Complex 66
M A T S U D A , Keizo Formation of Zinc Oxide by Homogeneous
Precipitation Method 2270
M A T S U D A , Tsuneo Preparation of Cu Thin Films by the
Decomposition of Copper Acetylacetonate on Catalytically
Active Substrate Surfaces 892
M A T S U D A , Yoshihisa ESR Spectra of Some Allene Radicals in
Low-Temperature Matrices 2442
M A T S U I , Hiroyuki A Flash Photolysis Study of CH -0 Mix
tures behind Shock Waves: Examination of Reaction of CH3+0
1317
M A T S U I , Masakazu Solvent Extraction of Divalent Metals as
M A T S U I , Masaki Synthesis and Characterization of Mono-,
Bis-, and Trissubstituted Pyridinium and Pyrylium Dyes 71
M A T S U I , Masaki Stereoselective Decomposition of Pyrazolines
Containing Trifluoromethyl Groups 1999
M A T S U I , Shinichi The Resolution and Absolute Configuration
of 2,3-Methanopyroglutamic Acid, 3-Oxo-2-azabicyclo[3,l,0]>
2
4
2
2
2
hexane-1-carboxylic Acid 2668
M A T S U K I , Kimihiro Fluorescence Quenching in {Ln[Fe(CN) j« H 0 \ (Ln=Eu(III) or Tb(III)) 2278
MATSUMOTO, Akikazu Synthesis and Radical Polymerization
of Itaconates Containing an Adamantyl Ester Group 846
MATSUMOTO, Akira Fluorescence Quenching of Europium(III) by Heteronuclear Complex Formation with Copper(II) or
Nickel(II) 1162
MATSUMOTO,
Akira Fluorescence Quenching in ILn[Fe(CN) |·nti 0\ (Ln=Eu(III) or Tb(III)) 2278
MATSUMOTO, Akira Synthesis, Characterization, and Proper
ties of V O-Ln(III) (Ln=La, Pr, Eu, Gd, Tb) Complexes of Ν,Ν'Bis(3-carboxysalicylidene)ethylenediamine 2514
MATSUMOTO, Kiyoshi The Reactions of Monoalkylthio- or
Monoarylthio-Substituted Cyclopropenium Salt with Nitrogen
Nucleophiles: Formation of Polyfunctionally Substituted Pyr
roles or Pyrazoles 698
MATSUMOTO, Kiyoshi Abnormal Diels-Alder Reaction of 5Alkoxythiazoles with Highly Reactive Dienophiles; 4-Phenyl3//-l,2,4-triazole-3,5(4#)-dione, Diethyl Azodicarboxylate, and
Diethyl Oxomalonate 3315
MATSUMOTO, Naohide Crystal Structures of Mono- and Di
nuclear Nickel(II) Complexes Derived from the Substitution
Reaction of [Ni(Me [14|dienatoN )[I and Each of Benzoyl Chlo
ride and Isophthaloyl Dichloride 258
MATSUMOTO, Naohide Template Synthesis and Structure of
a Dinuclear Lead(II) Complex of Novel Macrocycle Derived
from
2,6-Diformyl-4-methylphenol and
l,9-Diamino-3,7diazanonane 1176
MATSUMOTO, Naohide Syntheses and Magnetic Properties of
Imidazolate-Bridged Binuclear Copper(II) Complexes: Effect of
Bridging Mode upon Magnetic Interaction 1603
MATSUMOTO, Naohide Synthesis and Magnetisms of
Oxamido- and Oxamato-Bridged Binuclear Nickel(II)-Copper(II) Complexes 1988
MATSUMOTO, Naohide Synthesis and Magnetic Property of
Imidazolate-Bridged Cu(II)-M(II)-Cu(II) Complexes (M=Zn,
Cu,Ni, Co,Mn) 2283
MATSUMOTO, Naohide Study of the Charge Transfer Band
3241
MATSUMOTO, Osamu The Crystal Structures of Cyanide
Metmyoglobins Reconstituted with Iron(III) Complexes of Por
phyrin, 5,10,15,20-Tetramethylporphyrin, and 5,10,15,20Tetraethylporphyrin 739
MATSUMOTO, Takahiro Synthetic Study on Lipoteichoic
Acid of Gram Positive Bacteria. I . Synthesis of Proposed Funda
mental Structure of Streptococcus pyogenes Lipoteichoic Acid
2643
MATSUMOTO, Takashi Pyrrolizidine Alkaloids. The Synthe
sis and Absolute Configuration of All Stereoisomers of 4Carboxy-4-ethyl-3-hydroxy-2-isopropyl-4-butanolide, the Necic
Acid Component of Axillaridine 1761
M A T S U M O T O , Takeshi Attempted Transformation of 2,3,5,6Tetrachloro-4,4-dimethoxypentacyclo[5.4.0.0 ' .0 .0 * ]undecane-8,ll-dione toward Pentaprismane Retaining Chloro
Group 2312
M A T S U M O T O , Teruyo A Practical Synthesis of threo-3-Amino2-hydroxycarboxylic Acids 360
M A T S U M U R A , Kazunori Thermodynamic Studies on the
Complexation of Alkaline-Earth Metal Ions with oPhenylenediamine-iV,yV,N', N'-tetraacetate in Aqueous Solu
tions 1722
M A T S U N A G A , Atsuo Optical Resolution by Preferential Crys
tallization of 2-(3,4-Carbonyldioxyphenyl)-2-(phthalimidooxy)acetic Acid, a Key Intermediate of Cephalosporin Antibiotic M14659 3288
M A T S U N A G A , Ken'ichi Synthesis of Optically Active Polymet hacrylates
Bearing
Axially
Dissymmetric
1,1'6
2
x
6
2
x
,v
2
4
2
6
3,lo
5
9
December, 1992)
AUTHOR INDEX
Binaphthalene Skeleton as a Pendant Group and Their Optical
Resolution Ability as Chiral Adsorbent for HPLC 817
M A T S U N A G A , Yoichiro Reactions of 3-Isopropenyl- and 3Acetyltropolone with Quarternary Ammonium Tribromides
295
M A T S U N O , Sho-ichiro A Novel Configuration-Controlled Ster
eoselectivity in Enol Silylation of Ketones. Stereochemistry of
Amine-Promoted Enol Silylation of Meso and Racemic α,α'Dichloro Ketones and of Ketonization of the Resultant Enol
Silyl Ethers 971
M A T S U O , Susumu The Optical Properties of the Bc DDQ Crys
tal and Its Solid Phase Reaction 2157
M A T S U O , T a k u Formation of Through-Ring a-Cyclodextrin
Complexes with α,ω-Alkanedicarboxylate Anion. Effects of the
Aliphatic Chain Length and Electrostatic Factors on the Complexation Behavior 164
M A T S U O , Yoshihisa Generation and Cycloaddition Reactions
of 3-Styryl-l,2-thiaphosphole 2-Sulfide and l,5-Diphenyl-2,4pentadiene-l-thione 923
M A T S U S H I M A , Ryoka Photochrome Properties of 2-Hydroxychalcones in Solution and Polymers 39
M A T S U S H I M A , Ryouka Photochromism of Heterocyclic Fulgides 1262
M A T S U S H I M A , Ryouka Effect of Two Electron-Donating Substituents on Photochromism of Aryl Fulgide, 2-(2,6-Dimethyl3,5-substituted benzylidene)-3-isopropylidenesuccinic Anhy
dride 2352
M A T S U S H I T A , Hajime Reduction of Dicarboxylic Acid Anhy
dride with 2-Propanol over Hydrous Zirconium Oxide 262
M A T S U S H I T A , Hajime Regioselective Hydrogenation of
Unsaturated Compounds Using Platinum-Zeolite Coupled with
Organosilicon Alkoxide by CVD Method 1240
M A T S U Z A W A , Hidenori Theoretical Study of AluminumSodium Bimetallic Clusters. I . Geometrical and Electronic
Structures of Al„Na (w=l—4) 2578
M A Z A K I , Hitoshi Epimerization of Chlorophyll Derivatives. V.
Effects of the Central Magnesium and Ring Substituents on the
Epimerization of Chlorophyll Derivatives 3080
M A Z A K I , Hitoshi Pheophytinization of Eight Chlorophyll
Derivatives in Aqueous Acetone 3212
M A Z A K I , Yasuhiro An Isomeric Series of Thiophene-Fused
M E G N A M I S I - B E L O M B E , Michel Crystal and Molecular
Structure of the Asymmetric Cobaloxime, /raws-Bis(2,3butanedione
dioximato(l-)-N, N)iodopyridinecobalt(III):
[Co(Hdmg) I(py)] 612
M I H A R A , Hisakazu Synthesis of [L-a-Aminomyristic Acid » ']gramicidin S and Its Interaction with Phospholipid Bilayer
228
M I H A R A , Hisakazu Sequence Dependent Cyclization-Cleavage
of Dipeptides from the Oxime Resin and Its Prevention 991
MIJIN, Akihiko Effects of Pd Dispersion on the Catalytic Activ
ity of Pd/Si02 for Ethylene Hydroformylation 2565
M I K I , Eiichi eis- and /rflws-Li[Co" {L-tart(2-)-0 }2(en) ] Hydrate
Separated from the Reaction Products of [Co (C03)(en) ] with
L-Tartaric Acid 2490
M I K I , Sadao A Novel Isobenzofuran Derivative Undergoing
Photovalence Isomerization 932
M I K U R I Y A , Masahiro Binuclear Nickel(II) Complexes of
Schiff Bases Derived from Salicylaldehydes and l,«-Diaminott'-hydroxyalkanes (n,n — 3,2; 4,2; and 5,3) Having an Endoge
nous Alkoxo Bridge and a Pyrazolato Exogenous Bridge 334
M I K U R I Y A , Masahiro Thiolate-Bridged Binuclear Nickel(II)
Complexes with a Mixed-Spin State 512
M I K U R I Y A , Masahiro l,3-Bis(salicylideneamino)-2-propanol
as the Ligand for Manganese(III) Ions 1466
M I K U R I Y A , Masahiro Synthesis, Properties, and Crystal
Structures of a Series of Dinuclear Manganese(III) Complexes
2
2
3
I
1
IU
2
2
+
3
3535
with l,5-Bis(salicylideneamino)-3-pentanol and Various Anions:
Formation of a Tetranuclear Manganese(IlI) Complex 2624
M I K U R I Y A , Masahiro Study of the Charge Transfer Band
3241
M I M A K I , Yoshihiro Tigogenin Hexasaccharides from Camassia cusickii. Structural Elucidation by Modern NMR Tech
niques 458
M I M A K I , Yoshihiro New Cholestane Bisdesmosides from the
Bulbs of Ornithogalum thyrsoides 1120
M I M U R A , Mitsuo One-Pot Synthesis of Optically Active Cyanohydrin Acetates from Aldehydes via Quinidine-Catalyzed
M I N A G A W A , Yukinori Selective Separation of Yttrium Ions
from Other Rare Earth Ions Using Nonequilibrium Extraction
29
M I N A K A T A , Satoshi Functionalization of l//-Pyrrolo[2,36]pyridine 2992
MINODA, Masahiko Thermotropic Liquid Crystals Based on
Chito-Oligosaccharides. 1. Synthesis of Chitobiose Octaalkanoates and Chitotriose Undecaalkanoates and Their Thermal
Properties 1939
M I S H I M A , Kenji Mössbauer Emission Spectroscopy of Fe
M I S H R A , Shuddhodan Prasad Formation of Charged Species
in (η, γ) Activated 2-Bromopropionic Acid: An Atypical Case
3507
M I S H R A , Som Kant Kinetics and Mechanism of Osmium(VIII)
Catalyzed Oxidation of Uric Acid with N-Chloro-/>-toluenesulfonamide (Chloramine-T) in Alkaline Medium 1125
M I S H R I K E Y , Morcos Michael A New Synthesis of Pyrazolo(l,5-c]pyrimidines from Acetylenic j8-Diketones 3419
M I S R A , Tridibendra Narayan Surface-Enhanced Raman
Spectra of Isomeric Picolines Adsorbed on Silver Sols 1697
M I T A N I , Hideo The Base-Catalyzed H/D-Exchange of Anisole
Moiety of Ruthenium Complex in Cooperation with Demethylation by Hydroxide Anion in Methanol-^ 2557
M I T A N I , Tsuyoshi A Magnetic Study of the Iron(III) Complexes
M I T S U H A S H I , Tsutomu Structural Studies of Arylazo(a,adimethylbenzyl)malononitriles. Evidence against the Correla
Reactions 2394
M I T S U N O B U , Oyo Preparation of 1,4-Dienes from 2-(2Hydroxyalkylseleno)benzothiazoles by the Reaction Involving
Se->0 Azaaromatic Ring Rearrangement 3163
M I T S U Z A W A , Shunmei Formation of Zinc Oxide by Homo
geneous Precipitation Method 2270
M I U R A , Hiroshi Preparation of Cu Thin Films by the Decompo
sition of Copper Acetylacetonate on Catalytically Active Sub
strate Surfaces 892
M I U R A , Katsukiyo Isomerization of Olefins by Means of
RaSnH-Et3B and Stereochemical Study on Reduction of
Alkenyl Iodides 349
M I U R A , Katsukiyo Triethylborane Induced Radical Reaction of
Ketene Silyl Acetals with Polyhalomethanes 1513
M I U R A , Yozo First Synthesis and Deodorant Activities of Com
pounds Isolated from Thyme {Thymus Vulgaris L) and Their
Analogues 1159
M I W A , Yoshihisa Simulation of Vibrational Spectra of Acetic
Acid by an Extended Molecular Mechanics Method and Half
Band Width Parameter 746
M I W A T A S H I , Seiji Reaction of Tantalum-Alkyne Complexes
with Isocyanates or Acyl Cyanides. Stereoselective Functionali
zation of Carbon-Carbon Triple Bonds 1543
M I Y A B E , Hajime The Biogenetic-Type Cyclization of the
Unsaturated Monocyclic Alcohol with Formic Acid; Facile Syn
thesis of the Tricarbocyclic Alcohol, (+)-2-Epi-allo-cedrol 203
57
57
IVoL 65, No. 12
BULLETIN OF THE CHKMICAL SOCIETY OF JAPAN
3536
MIYAGAWA,
Kohji Photochemical Reactions of 4-Acylstyrenes. Effects of Acyl Substituents on Photocyclodimerization via an Excited Triplet State 837
M I Y A K E , Hiroyuki Two Conformers and Aggregation of Cyclic
Octapeptide, o>c/o(G-eLL-G)2, in Chloroform 917
M I Y A K E , Takashi Studies on Aromatic Sesquiterpenes. XIII.
M I Y A M A E , Hiroshi Knoevenagel Reaction of Malononitrile
M I Y A M A E , Yoko Diastereoselective Addition of Grignard Rea
gents to 3,4-0-Isopropylidene-l-0-triphenylmethyl-L-^/yc^ro-2tetrulose and l-0-Benzoyl-3,4-0-isopropylidene-L-#/ycero-2tetrulose 2814
M I Y A M O T O , T . K e n Stability and Reactivity of Dihydroxobis(trimethylphosphine)platinum(II), an Intermediate Species for
the Synthesis of a Variety of Water-Soluble Phosphine Com
plexes 3386
M I Y A M O T O , Takeaki Thermotropic Liquid Crystals Based on
Properties 1939
M I Y A M O T O , Toshiro Preparation and Characterization of
[Co(tp) (Me„-en)] (tp=Tropolonate Ion; Me«-en («=1—4)=NMethyl Substituted Ethylenediamine), Inversion and Deutera
tion at Chiral Nitrogen Centers of [CoitpMMe-en or Me -en)] ,
and Crystal Structures of [Co(tp) (N,N-Me -en)]C104 and
/l(/?)J(S)-[Co(tp)2(Me-en)]C104 1572
M I Y A M O T O , Yasushi Novel Synthesis of 2-Phosphinoylphospholane 1-Oxide Derivatives 2004
M I Y A N O , Sotaro Synthesis of Optically Active Polymethacrylates Bearing Axially Dissymmetric Ι,Ι'-Binaphthalene Skel
eton as a Pendant Group and Their Optical Resolution Ability
as Chiral Adsorbent for HPLC 817
M I Y A S A K A , Akiko Photochemical Reduction of (r^-Cyclopentadienyl)(l,2-disubstituted
1,2-ethylenedichalcogenolato)cobalt(III) and (77 -Cyclopentadienyl)(l,2-benzenedithiolato)cobalt(III) Complexes in the Presence of Triethanolamine
1047
M I Y A S H I , Tsutomu Crystal Structures of Metallic and Insulat
ing Molecular Complexes between Naphthaceno[5,6-i:i/: 11,12c'(rf]bis[l,2]diselenole and 4,8-Bis(dicyanomethylene)-4//,8#benzo[l,2-c: 4,5-clbis[l,2,5]thiadiazole: (TSeN)(BTDA-TCNQ)
and (TSeNXBTDA-TCNQXCeHsCl) 3350
M I Y A T A K E , Shinji The Stereochemistry of the Sulfur Atom of
4,7-Dimethyl-6-phenyl-5,6,7,8-tetrahydro-4//-l,3,2,6-dioxathiazocine 2-Oxides 2294
M I Y A T A K E , Yoko Vibrational and Rotational Raman Spectra
of Trapped Hydrogen in Irradiated Ethanol Crystal at 77 Κ
2526
M I Y A U R A , Norio The Palladium-Catalyzed Cross-Coupling
Reaction of Enol Acetates of α-Bromo Ketones with 1-Alkenyl-,
M I Y A Z A K I , A k i r a Crystal Structure of (ImH)[Ni(dmit) ] with
Intercolumnar Interaction through an Imidazolium Counter
Ion 2528
M I Y A Z A K I , Hideya Racemization of Optically Active Aromatic
N-Acetylamino Acids and Asymmetric Transformation of NAcetyl-2-(4-hydroxyphenyl)glycine via Salt Formation with
M I Y A Z A K I , Kazumi Partial Reduction of Dithioacetals with
M I Y A Z A K I , Tetsuo Effect of 7-Ray Irradiation on the Recoil
Reaction 735
M I Y O K A W A , Kikuo Thermoanalytical Study of Dioxygencobalt(III) Complexes with
A^N-Ethylenebis(salicylidene2
+
+
3
2
2
5
2
2
aminate) and Its Derivatives 3374
MIYOSHI, Norikazu Asymmetric Synthesis of Benzoin by
Sml -Mediated Enantioselective Protonation 2001
MIZUKAMI, Fujio Growth Process of ZSM-5 Zeolite Film 146
MIZUMACHI, Kunihiko eis- and /röws-Li[Co {L-tart(2-)OM'2(en)2] Hydrate Separated from the Reaction Products of
[Co (C0 )(en) r with L-Tartaric Acid 2490
MIZUMOTO, Takahiro Synthesis of Novel Polycyclic Selenepinone Compounds 1794
MIZUNO, Atushi Four Different Coordination Modes of 1,1'Bis(diphenylphosphino)ferrocene: Synthesis, X-Ray Crystal
Carbonyl
Complexes
with
l,l'-Bis(diphenylphosphino)f errocene (dppf e) 1415
MIZUNO, Junichi Spontaneous Color Development Encountered for Diquaternary Salts of 1,10-Phenanthrolines in Various Media 623
MIZUTA, Masateru Comparison of 2,4-Hexadienoic with 1Hexanoic Acids as Extractant for Copper(II) 186
MIZUTANI, Junya Syntheses of trans- and ds-3-Methoxy-4methylthio-2-piperidinethiones. Previously Proposed Structures for Raphanusanins, Structural Revision, and Biological
MOCHIDA, Kunio Study of Photochemical Reactions of
Decamethylcyclopentagermane
1642
MOGI, Isao Effects of Pd Dispersion on the Catalytic Activity of
Pd/Si0 for Ethylene Hydroformylation 2565
MOHAMED, Shaaban K. Molecular Interactions between T r i azene 1-Oxides and Tetracyanoethylene 553
MOHAMMADPOUR-BALTORK,
Iraj Zinc Bismuthate
Zn(Bi0 )2.1. A Useful Oxidizing Agent for the Efficient Oxidation of Organic Compounds 1131
M O H A M M A D P O U R - B A L T O R K , Iraj Tetrakis(pyridine)silver(II) Peroxodisulfate, [Ag(py) ]S 08, a Reagent for the Oxidative Transformations 2878
MORI, Akira Synthetic Photochemistry. LVIII. Intramolecular
Photocycloaddition of 2-Alkenyl-6-methyl-4#-l,3-dioxin-4-ones
2940
MORI,
Hideharu Diphenyl (2,3-Dihydro-2-thioxo-3-benzoxazolyl)phosphonate: A New, Reactive Condensing Agent for
the Synthesis of Amides, Esters, Peptides, and 0-Lactams via
Condensation 1636
MORI, Keiko The Catalytic Electroreduction of Dioxygen on
Iron Protoporphyrin IX Modified Glassy Carbon Electrodes
1491
MORI, Satoshi Mechanism on the Efficient Formation of Singlet
Oxygen by Energy Transfer from Excited Singlet and Triplet
States of Aromatic Hydrocarbons 897
MORI, Takehiko Structural and Conducting Properties of
(TTF)(DMeT-DCNQI) 1460
MORI, Takehiko Crystal Structures and Molecular Packing of
Tetrakis(alkylthio)tetrathiafulvalene ( T T C « - T T F ) ; Part I
(w=3,4,6) 1878
MORI, Takehiko Crystal Structures and Molecular Packing of
Tetrakis(alkylthio)tetrathiafulvalene ( T T C » - T T F ) ; (Part II)
(«=7,9,11) 2086
MORI, Wasuke Preparation and Properties of Mixed Ligand
Dinuclear Copper(II) Complexes Bridged by Deprotonated Oximato and Hydroxo or Acetato 3189
MORI, Yasuyoshi A Magnetic Study of the Iron(III) Complexes
MORI, Yoko Dehydrative Glycosylation Using Heptabenzyl
MORI, Yukie Radical-Based Synthesis of Terpenoids. Stereoselectivity in the Trapping of Radicals from Cyclization of 3-(lEthoxy-2-haloethoxy)cyclohexenes 2421
MORI, Yukie Thermochromism of 5,10,15,20-Tetraarylporphyrins at Low Temperature 3358
MORIGUCHI, Isamu Polymers Having pH-Buffering Capability
2
m
m
3
2
2
3
4
2
December, 1992|
3537
AUTHOR INDEX
for Potential Use as Solid-Phase Reagent 2531
M O R I H A R A , Kensaku Footprint Catalysis. IV. Structural
Effects of Templates on Catalytic Behavior of Imprinted Foot
print Cavities 954
M O R I H A S H I , Kenji Single-Excitation Configuration Interac
tion Calculations of Hyperfine Coupling Constants of Small η
and a Radicals 603
M O R I H A S H I , Kenji ESR Spectra and Electronic States of 1,10Phenanthroline Radical Anions 2839
MORIMOTO, Takashi Oxidation of Alcohols with Peracetic
Acid in Ethyl Acetate in the Presence of Sodium Bromide 703
MORIMOTO, Takashi A Facile Synthesis of Sulfoxides by
Oxidation of Sulfides with Sodium Bromite in an Aprotic
Solvent in the Presence of Clay Minerals 1744
M O R I O K A , Tetsuro Reactions of (£)-2-Iodo-l-tosyl-l-alkenes as
M O R I S H I M A , Naohiko Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
M O R I S H I T A , Shinya Reactivity of Lithium Alkylamide toward
M O R I S H I T A , Yumi Substituent Effects on the Aggregation of
Bacteriochlorophyll d Homologues Purified from Chlorobium
limicola 3493
MORITA, Kazuhisa Diastereoselective Construction of 2,2,6Trisubstituted Tetrahydropyrans by Intramolecular Alkylation Reaction of Lithium Enolates Generated from cr-Alkoxy
Carboxylates 3487
MORITA, Mitsunobu The Base-Catalyzed H/D-Exchange of
Anisole Moiety of Ruthenium Complex in Cooperation with
MORIYA, Takeshi Four Different Coordination Modes of Ι,ΓBis(diphenylphosphino)ferrocene: Synthesis, X-Ray Crystal
Carbonyl
Complexes with
l,l'-Bis(diphenylphosphino)ferrocene (dppfe) 1415
M O R I Y A M A , Hideaki The Crystal Structures of Cyanide Metmyoglobins Reconstituted with Iron(III) Complexes of Porphyrin, 5,10,15,20-Tetramethylporphyrin, and 5,10,15,20Tetraethylporphyrin 739
M O R I Y A M A , Satoshi Reactions of 2-[(Phenylthio)methylene]tetralin-l-thione 2056
MOROSAWA, Shiro The Base-Catalyzed H/D-Exchange of Anisole Moiety of Ruthenium Complex in Cooperation with
MOROTOMI, Naoaki Evaluation of Melting and Crystalline
Water Surface and Their Importances for Molecular Aggregation States in Monolayers 864
MOTODA, Ken-ichiro Template Synthesis and Structure of a
Dinuclear Lead(II) Complex of Novel Macrocycle Derived from
2,6-Diformyl-4-methylphenol and l,9-Diamino-3,7-diazanonane
1176
MOTOHASHI, Shigeyasu A Novel Synthesis Including Asymmetric Synthesis of α,β-Unsaturated γ-Hydroxy Carbonyl
Compounds from Enones with Carbon Homologation 2966
MOTOKI, Shinichi Generation and Cycloaddition Reactions of
3-Styryl-l,2-thiaphosphole 2-Sulfide and 1,5-Dipheny 1-2,4pentadiene-l-thione 923
MOTOKI, Shinichi Reactions of 2-[(Phenylthio)methylene]tetralin-l-thione 2056
MOTOMURA, Kinsi Surface Adsorption and Micelle Formation
of Dodecyltrimethylammonium Chloride and Dodecylammonium Chloride Mixture 858
MOTOMURA, Shigeyuki WNMR and X-Ray Crystallographic Studies on the Peroxo Complexes of the Ti-Substituted aKeggin Typed Tungstophosphates 1453
MOTOMURA, Tadahiro Multiple Electrostatic Interaction of
Polycationic Chitosan Oligomers with Nucleic Acids: Polyam ine Promoted Stabilization of the A-Form of RNA and DNA
183
in Aqueous Solutions 1755
MOTOOKA, Itaru Effect of Water Vapor on the Thermal Behav
ior of Manganese ryc/o-Tetraphosphate 777
MOTOOKA, I t a r u Thermal Decomposition of Silver Amidotriphosphate Ag P30 NH
1985
M O U R I , Takashi Growth Process of ZSM-5 Zeolite Film 146
MOUSAAD, A h m e d Synthesis of 3-(Alditol-l-yl)triazolo[4',3': 2,3]-1,2,4-triazino[5,6-6]indoles 546
MOUSAVI, Mir Fazlollah Spectrophotometric Determination
of Trace Amounts of Sulfide Ion Based on Its Catalytic Reduc
tion of Toluidine Blue 2770
M U K A I , Kazuo ENDOR Study of the Cation Radicals of
M U K A I , Masahiro A Time-Resolved EPR Study on the Photo
M U N A K A T A , Hiroshi Oxidative Substitution Reactions of
Organostannyl Compounds with Lead Tetraacetate. A Conve
nient Route to 5-Alkylidene-2(5#)-furanones 2366
M U R A I , Akio Synthesis of (±)-Isopiperitenol by Fluoride Ion
Mediated Cyclization of Allylsilane Moiety Incorporated in Terpene Aldehydes 929
M U R A I , Hisao Time-Resolved ESR Studies on Photosensitized
Reaction of Maleic Anhydride in Alcohols: CIDEP Memory
M U R A I S H I , Haruto Crystallization of Silica Gel in Alkaline
Solutions. Characterization of S1O2-X2 and Other Crystalline
Silicates by Comparing with Kenyaite 761
M U R A K A M I , Hiroshi Equilibrium and X-Ray Structural Stu
dies on Dimeric and Trimeric Species Formed in the Extraction
of Nickel(II) with 2-Methyl-8-quinolinol 3362
M U R A K A M I , Hisamichi Habit Modification of a Diastereomeric Salt With an Additive in Optical Resolution 1747
M U R A K A M I , Kimihiro Optical Resolution by Preferential
Crystallization of 2-(3,4-Carbonyldioxyphenyl)-2-(phthalimidooxy)acetic Acid, a Key Intermediate of Cephalosporin Antibiotic
M-14659 3288
M U R A K A M I , Takahiko A Systematic Study on the Bakers'
Yeast Reduction of 2-Oxoalkyl Benzoates and l-Chloro-2alkanones 631
M U R A K A M I , Yoshiko Micellar Effect on the Formation Rate
of Ni(II) and Co(II) Complexes with 8-Quinolinol and Its 5Alkyloxymethyl-8-quinolinol Derivatives in a Nonionic Surfac
tant Micellar System 286
M U R A K A M I , Yukito Hydrophobic Vitamin B . XL Prepara
tion, Characterization, and Enantioselective Alkylation of
Hydrophobic Vitamin B12 Bearing a Binaphthyl Moiety 3094
M U R A M A T S U , Hiroshige Synthesis and Characterization of
Dyes 71
M U R A M A T S U , Hiroshige Stereoselective Decomposition of
Pyrazolines Containing Trifluoromethyl Groups 1999
MURASE, K u n i a k i Mutual Separation Characteristics and
M U R A T A , Ichiro [14n]Electrocyclization Followed by Preferen
tial [l,9]Hydrogen Migration in the Thermolysis of l-Formyl-4[(2,4,6-cycloheptatrienyl)(phenylsulfinyl)methyl]azulene 3198
M U R A T A , Kazuhisa Magnetic Properties of Pyro-Carbons Pre
pared from Polyvinyl chloride) and Activated Carbon 1144
M U R A T A , Shizuaki The Optical Properties of the Bc DDQ
Crystal and Its Solid Phase Reaction 2157
M U R A T A , Yoshiyuki Correlation Analysis of the p # Values of
M U R A T A N I , Tomomi The Catalytic Electroreduction of Dioxygen on Iron Protoporphyrin IX Modified Glassy Carbon Elec
trodes 1491
MUTO, Yoneichiro Crystal Structures and Magnetic Properties
of Novel μ-Carboxylato-μ-Hydroxo-Bridged Binuclear Cop4
9
2
i2
2
a
3538
BULLETIN OF ΤΗ Κ CHEMICAL SOCIETY OF JAPAN
per(II) Complexes with 1,10-Phenanthroline 1214
N A E M U R A , Koichiro The Biogenetic-Type Cyclization of the
Unsaturated Monocyclic Alcohol with Formic Acid; Facile Syn
thesis of the Tricarbocyclic Alcohol, (+)-2-Epi-allocedrol 203
NAGAI, Mayumi Inclusion Mode of 8-Anilino-l-naphthalenesulfonate (ANS) in the ANS-jS-Cyclodextrin Complex 2869
N A G A M A T S U , Harutoshi Citreobenzofurans A, B, and C,
First Isolation of Sesquiterpene-Type Metabolites of a Hybrid
Strain KO 0031 Derived from Penicillium Citreoviride B. IFO
4692 and 6200 926
N A G A M A T S U , Megumi Crystal Structures and Magnetic
Properties of Binuclear Copper(II) Complexes with Alkoxo and
Benzoato or Silanecarboxylato Bridges 2739
NAGANO, Hajime Radical-Based Synthesis of Terpenoids. Ster
NAGANO, Hajime Diastereoselective Addition of Grignard Rea
gents to 3,4-0-Isopropylidene-l-0-triphenylmethyl-L-^/ycero-2tetrulose and
l-0-Benzoyl-3,4-0-isopropylidene-L-^/yc^ro-2tetrulose 2814
NAGANO, Yoshiaki Synthetic Photochemistry. LVIII. Intramo
lecular Photocycloaddition of 2-Alkenyl-6-methyl-4//-l,3-dioxin4-ones 2940
N A G A O K A , Shin-ichi ENDOR Study of the Cation Radicals of
N A G A S A K I , T a k e s h i Solvent Extraction of Transition Metal
Cations by Calixarene-Based Cyclic Ligands 471
N A G A S A K I , T a k e s h i Intercalation of a Trimethylammoniomethylated Calix[4]arene by Cu(II)-Montmorillonite 2510
N A G A S A K I , Yukio Reactivity of Lithium Alkylamide toward
NAGASAWA, Akira Kinetic Studies on the Terminal Pyridine
N A G A S E , Shigeru Preparation and Isomerization of 3,4Bis(2,4,6-tri-/-butylphenylphosphinidene)cyclobutenes 2297
N A G A S H I M A , Hiroyoshi Lithium Alkylamide-Catalyzed Addi
tion Reaction of Alkylamines to Vinyl Monomers. III. Addition
Reaction of ^-Substituted Benzylamines to Styrene and Divinylbenzenes 1109
N A G A S H I M A , Makiko Choice of Manganese(III) Complexes for
the Synthesis of 4,4'-Biphenyldiols and 4,4'-Diphenoquinones
620
NAGATA, Kozo Genesis of Highly Active Cobalt Sulfide Cata
lyst for Hydrogenation and Isomerization: Effect of the Calcina
tion Temperature of Precursor Cobalt Oxide upon the Catalytic
Properties of Cobalt Sulfide 1331
N A G A T A , Toshi Synthesis and Characterization of DoublyStrapped Porphyrins 385
N A K A B A Y A S H I , Hirotoshi Properties of Acid Sites on T i 0 S1O2 and T1O2-AI2O3 Mixed Oxides Measured by Infrared Spec
troscopy 914
N A K A B A Y A S H I , Kenichi Ring-Splitting Reaction of 2,2Diarylthietane by Electron-Transfer Photosensitization of 9,10Dicyanoanthracene 1472
N A K A B A Y A S H I , Kenichi Triplet Sensitized QuadricyclaneNorbornadiene Valence Isomerization of Methyl 5-(4Biphenylyl)tetracyclo[3.2.0. - 0. - ]heptane-l-carboxylate 3177
N A K A D A , Masahiro Thermal Reactions of Toluene by Use of a
Clusius-Dickel Type Thermal Diffusion Column as a Reactor
586
N A K A D A , Masahiro Photolyses of Polychloro- and Polybromobenzenes. Novel Isomerization in Solvents Resisting against
Hydrogen Abstraction 2926
N A K A D A , Masahiro The Effect of the Coexistent Gases on the
Thermal Reaction of Toluene or Methane in a Clusius-Dickel
Type Thermal Diffusion Column 3434
2
2
7
4
6
[Vol. 65, No. 12
NAKADA, Masami Mössbauer Emission Spectroscopy of * Fe
Arising from Μη in Metal and Oxides of Chromium 1
NAKADAIRA, Yasuhiro Selective Friedel-Crafts Alkylation
on a Vermiculite, a Highly Active Natural Clay Mineral with
Lewis Acid Sites 2833
NAKAGAWA, Genkichi X-Ray Crystal Structure of Silver(I)
Complex with l,3-Bis(8-quinolylthio)propane 2275
NAKAGAWA, Genkichi Equilibrium and X-Ray Structural
Studies on Dimeric and Trimeric Species Formed in the Extrac
tion of Nickel(II) with 2-Methyl-8-quinolinol 3362
NAKAGAWA, Naoya Selective Friedel-Crafts Alkylation on a
Vermiculite, a Highly Active Natural Clay Mineral with Lewis
Acid Sites 2833
NAKAGAWA, Toshio Reactivities of 2-C- and 3-C-Nitro-a- and
ß-D-erytf*>O-Hex-2-enopyranoside Derivatives towards Methanol
and A M I Studies upon Their Stereoselectivities 446
N A K A H A R A , Hiromichi Mössbauer Emission Spectroscopy of
Fe Arising from M n in Metal and Oxides of Chromium 1
N A K A H A R A , Masatsugu Synthesis and Photo Valence Isomerization of Polyamide Bearing Norbornadiene Unit 2306
NAKAHARA, Masayoshi eis- and /raws-Li[Co {L-tart(2-)OM2(en) ] Hydrate Separated from the Reaction Products of
[Co (C0 Xen)2] with L-Tartaric Acid 2490
N A K A H A R A , Masayoshi Structures and Spectral Properties
of Some Bis(carboxylato)copper(II)-Pyrazole Complexes. I .
Preparation of Bis(trifluoroacetato)tetrakis(pyrazole)copper(II)
2638
NAKAHARA, Taketoshi Direct Nebulization of Sample Solution Containing Reductant for the Determination of Mercury
by Inductively Coupled Plasma-Atomic Emission Spectrometry
1165
NAKAJIMA, Kiyohiko Structures of Two Geometrical Isomers
of
Di0X0[(S)-A -säIieyliderte-3-aminopyrrolidine]vanadium(V)
1725
NAKAJIMA, Takeshi Effects of Electron-Withdrawing Substituents on Bond Alternations in Pentalene and Heptalene 2371
N A K A M U R A , Akira Unique Molecular Structures of Tungsten
Phenoxides 1197
N A K A M U R A , Daiyu Motions of Methylammonium Ions in
(CH NH3)3Sb l9 Crystals Studied by Ή NMR 1707
N A K A M U R A , Hideshi Synthesis of (±)-Isopiperitenol by Flu
oride Ion Mediated Cyclization of Allylsilane Moiety Incorpo
rated in Terpene Aldehydes 929
N A K A M U R A , Hiroshi Formation of Through-Ring aCyclodextrin Complexes with α,ω-Alkanedicarboxylate Anion.
Effects of the Aliphatic Chain Length and Electrostatic Factors
on the Complexation Behavior 164
N A K A M U R A , Junji Partial Oxidation of Methane to Synthesis
Gas over Rhodium Vanadate, RI1VO4: Redispersion of Rh Metal
N A K A M U R A , Kazuyoshi Oxidative Coupling of Methane over
Various Barium Salts Mixed with CaO: The Relation with
Their Surface Basicities 2251
N A K A M U R A , Makoto Energy- and Electron-Transfer Path
ways in the Triplet-Sensitized Photolysis of N-(l-Naphthoyl)-0(/>-toluoyl)-N-phenylhydroxylamine with Substituted Benzophenones 1950
N A K A M U R A , Makoto Mechanism of the Triplet-Sensitized
Photolysis of N-(l-Naphthylsulfonyl)-N-phenyl-0-(/>-toluoyl)hydroxylamine 2789
N A K A M U R A , Nobuo The Crystal Structure of Tetraethylene
Glycol Complex of Sodium Tetraphenylborate 3180
N A K A M U R A , Seijiro The Raman Active Intra- and Intermolecular Vibrations of [Ή10]- and [Ή10] /^-Xylenes 280
N A K A M U R A , Shinichiro Thermally Irreversible Photochro
me Systems. Substituent Effect on the Absorption Wave
length of ll,12-Dicyano-5a,5b-dihydro-5a,5b-dimethylbenzo[l,26:6,5-6']bis[l]benzothiophene 430
N A K A M U R A , Tomoyuki Radical Intermediates in the Ther7
δ7
57
57
N,
2
m
+
3
r
3
2
December, 19921
mal Decomposition of l,l-Bis(/-butyldioxy)cyclohexane 664
N A K A M U R A , Toshio Selective Ion Transport in Acetonitrile
Across the Ionophore-Immobilized Polymer Membranes Used
as the Sensor of the Ion-Selective Electrodes 19
N A K A M U R A , Yoshio Oxidative Chlorination of 1,10Phenanthroline and Its Derivatives by Phosphorus Pentachloride in Phosphoryl Chloride 2007
N A K A M U R A , Yoshio Diffusion Coefficient of Benzene around
the Gas-Liquid Critical Temperature 3480
N A K A N I S H I , Kiyoko Footprint Catalysis. IV. Structural
Effects of Templates on Catalytic Behavior of Imprinted Foot
print Cavities 954
NAKANISHI,
Kunihiko Prismatic and Antiprismatic
[4 ]Ferrocenophanes ([4Kl,n[4](3,3> and [4](l,l')[4](3,4')Ferrocenophanes) 3275
NAKANISHI,
Saburo Structural Features of (CH ) Si(C H ) Fe (CO) (C=NR) and (CH ) Si (C H ) Fe (CO) (C=NR)
2309
N A K A N I S H I , Saburo A Convenient Synthesis of Cationic
Vinylidene and 1,2-Propadienylidene Iron Complexes by Photoreaction of [CpFe(COXdppe)] BFr with 1-Alkynes 2560
N A K A N O , Chikako Crystal Structures of TXC -TTF
(X=Se,Te) 1482
N A K A N O , Chikako Crystal Structures and Molecular Packing
of Tetrakis(alkylthio)-tetrathiafulvalene ( T T C M - T T F ) ; Part I
(«=3, 4, 6) 1878
N A K A N O , Chikako Crystal Structures and Molecular Packing
of Tetrakis(alkylthio)tetrathiafulvalene ( T T C „ - T T F ) ; (Part II)
(«=7,9,11) 2086
NAKANO, Hirofumi Formation and Reaction of Carbonyl
Ylides. Reactions of l-Methoxy-2benzopyrylium-4-olate with
Isothiocyanates 1362
N A K A N O , Hirofumi Formation of 2-Imino-l,3-oxathioles and
2(3//)-Oxazolethione by the Rhodium(II) Acetate-Catalyzed
Reaction of α-Diazocarbonyl Compounds with Isothiocyanates
3088
NAKANO, Kenji Study of the Charge Transfer Band Observed
in Dialkoxo-Bridged Binuclear Copper(II) Complexes 3241
NAKANO, Koji Polymers Having pH-Buffering Capability for
Potential Use as Solid-Phase Reagent 2531
NAKANO, Tatsuya Single-Excitation Configuration Interac
tion Calculations of Hyperfine Coupling Constants of Small π
and σ Radicals 603
NAKANO, Yoshiharu Knoevenagel Reaction of Malononitrile
NAKAO, Yasuo Preparation and Properties of Mixed Ligand
Dinuclear Copper(II) Complexes Bridged by Deprotonated Oximato and Hydro or Acetato 3189
N A K A S H I M A , Kin-ichi Refolding of Trimeresurus flavoviridis
Phospholipases A 2655
N A K A S H I M A , Michio Crystal Structures and Magnetic Prop
erties of Novel ^-Carboxylato-M-Hydroxo-Bridged Binuclear
Copper(II) Complexes with 1,10-Phenanthroline 1214
NAKASHIMA, Satoru The Role of Spin-Coupled Intermediate
in a System Consisting of Tetraminecobalt(III) Complexes and
1225
N A K A S H I M A , Y a s u k i Deuterium Isotope Effects on Aromatic
C-13 NMR Chemical Shifts. IV. Can the Isotope Shifts Be
Correlated with Bond Lengths? 2894
N A K A S U K A , Noriyuki Thermodynamic and NMR Studies on
the Complexation of Lanthanoid(III) Ions with o-Phenylenediamine-N,N,N'N'-tetraacetate
in Aqueous Solutions
1566
N A K A S U K A , Noriyuki Thermodynamic Studies on the Com
plexation
of
Alkaline-Earth
Metal
Ions
with
oPhenylenediamine-N,N,N'N'-tetraacetate in Aqueous Solu
tions 1722
2
3
5
4
2
2
3539
AUTHOR INDEX
3
3
2
5
4
2
2
2
2
+
8
2
2
N A K A S U K A , N o r i y u k i Thermodynamic Studies on the Com
plexation of o-Phenylenediamine-AWN'N'-tetraacetate with
Divalent Cadmium, Mercury, and Lead Ions in Aqueous Solu
tions 2333
N A K A T A , Hisao A Convenient Synthetic Method of 2-Cyano-6methoxybenzothiazole, —A Key Intermediate for the Synthesis
N A K A T A , Hisao Improved Synthetic Methods of Firefly Lucif
erin Derivatives for Use in Bioluminescent Analysis of Hydrolytic Enzymes; Carboxylic Esterase and Alkaline Phosphatase
2604
N A K A T A , Masaya The Total Synthesis of Herbimycin A 2974
N A K A T O , T e r u y u k i Synthesis of Two Types of Intercalation
Compounds of ^NbeOn with Tris(2,2'-bipyridyl) Metal Com
plex Ions 322
NAKATSUJI, Yohji Complexation Property of a Novel Macrobicyclic Polyether with Two Amide Moieties toward Alkali Metal
N A K A W A , H i r o y u k i Abnormal Diels-Alder Reaction of 5Alkoxyoxazoles with Tetracyanoethylene and X-Ray Crystal
N A K A Y A M A , Haruo Hydrates of Organic Compounds. XVII.
The Effect of Cations on the Formation of Hydrates of Poly(tetraisopentylammonium acrylate) 2704
N A K A Y A M A , Hiroaki Coal Solubilization with Cadmium and
Butyl Iodide under Mild Conditions 1067
N A K A Y A M A , Hiroaki Thermal Behavior and Mass Spectra
Aspects of 1,3.5-Triazine Derivatives Based on Isocyanuric
Acid 1993
N A K A Y A M A , Hirokazu Molecular Motions in Solid CD3NH3PbBr as St udied by »H NMR 2264
N A K A Y A M A , Juzo Generation and Characterization of 1,3-Di-/butyl- and l,3-Di-/-butyl-4,6-dimethylthieno[3,4-c]thiophenes
2821
N A K A Y A M A , Juzo Oxidation of 2,2,3,3-Tetramethyl-l,4diphenyl-5,6-dithiabicyclo[2.1.1]hexane and Its Oxidation Prod
ucts: An Important Role of 1,3-Transannular Interaction in the
1,3-DithietanePart 3343
N A K A Y A M A , Mitsunobu ESR Spectra and Electronic States
of 1,10-Phenanthroline Radical Anions 2839
N A K A Y A M A , Takeshi Reactions of Water and Dinitrogen
Monoxide Adsorbed on Cation-Exchanged Zeolite with Excess
Electrons Generated by Gamma-Radiation 140
N A K A Y A M A , Toshihiro Solvent Effects on the Formation and
N A K A Y A M A , Yoshisuke A New Bromo Diterpene, epiAplysin-20, and ewMsoconcinndiol from the Marine Mollusc
Aplysia kurodai 2300
N A K A Y A M A , Y u s a k u Fluorescence Quenching of Europium(III) by Heteronuclear Complex Formation with Copper(II) or
Nickel(II) 1162
N A K A Y A M A , Yusuke Fluorescence Quenching in {Ln[Fe(CN) ] · nH 0}* (Ln=Eu(III) or Tb(IIR) 2278
N A K A Y A M A , Yusuke Synthesis, Characterization, and Prop
erties of V O-Ln(III) (Ln=La, Pr, Eu, Gd, Tb) Complexes of
N, N'-Bis(3-carboxysalicylidene)ethylenediamine 2514
N A K A Y A M A , Yuushou Unique Molecular Structures of
Tungsten Phenoxides 1197
NAKAZATO, Chiyoko Reactions of Water and Dinitrogen Mon
oxide Adsorbed on Cation-Exchanged Zeolite with Excess Elec
trons Generated by Gamma-Radiation 140
N A K A Z A W A , Fumiko Kinetics and Mechanisms of PhotoInduced Reduction of Iodine by Monoamine-N-polycarboxylate
Ions in an Aqueous Solution 1812
NAMAZUE, Sakuhiro Crystal and Molecular Structures of
Acetoacetanilide, and 0- and /»-Chloroacetoacetanilides: X-Ray
Crystaltographic and MO Study 3234
3
6
2
,v
3540
[Vol. 65, No. 12
NANBA, Akimichi Oxidative Dehydrogenation of Kthylenediamine Coordinated to Ruthenium with Hexafluoroacetylacetonate, Induced by Electrochemical Oxidation of Ruthenium(II) to
Ruthenium(III) 876
Ν Α Ν Ε N L E N D , Gaspard Crystal and Molecular Structure of
the Asymmetric Cobaloxime, /rö«s-Bis(2,3-butanedione dioximato(l-)-N,yV)iodopyridinecobalt(III): [Co(Hdmg)J(py)l 612
N A R A S A K A , Koichi Acid-Promoted Reactions of Schiffs Bases
Sulfides 1392
N A R A S A K A , Koichi Reactions of 1,2-Propadienyl Sulfides with
Aldehydes and Acetals Catalyzed by BF · OEt 2825
N A R I A I , Hiroyuki Effect of Water Vapor on the Thermal
Behavior of Manganese cyc/o-Tetraphosphate 777
N A R I A I , Hiroyuki Thermal Decomposition of Silver Amidotriphosphate Ag4P 0 NH2 1985
N A R I T A , Tadashi Lithium Alkylamide-Catalyzed Addition
N A S U , Akira Sodium Tellurite as a Mild and Selective Oxidizing
Agent for Thiols: Its Use in the One-Pot Synthesis of Unsymmetrical Disulfides 626
N A T O R I , Keiko ^-Hydroxy Amides. X. Synthesis of a Nonapeptide with an Ala-(HO)Gly-Ala Sequence and Its Spectral and
Iron(III) Holding Properties 1356
N A T S U Y A M A , Hisashi Racemization of Optically Active Aromatic N-Acetylamino Acids and Asymmetric Transformation
of N-Acetyl-2-(4-hydroxyphenyl)glycine via Salt Formation
with Optically Active «-Methylbenzylamine 965
N A T U , Gopal Ν. Solid State Oscillatory Reaction. I. Thermal
Decomposition Studies of [C^NROeJBr.i and CoBr -2H 0
1026
N E G I S H I , Nobuaki Fluorescence Spectra of 1-Naphthol During
the Sol-Gel Process of a Mixed Aluminum-Silicon Alkoxide
(Si:Al=94:6) 720
N E G I S H I , Shin-ichi Cd -Catalyzed Methanolysis of Phenyl
Phosphatosulfate. Selectivity of Metal Ion in the Site of Cleav
age of P-0 and S-0 Bond 3335
N E M O T O , Shuzo Photoinduced Electron Transfer between
Zinc Protoporphyrin Reconstituted Myoglobin and Methylviologen 591
N E M O T O , T a k a s h i Atropisomerism in Doubly />m-Substituted
9-(2-Methylbenzyl)triptycene Derivatives, . 8-Chloro- and 8Bromo-l,4-dimethyl-9-(2-methylbenzyl)triptycenes 1957
N E Y A , Saburo Determination of the Dimerization Constant in
Self-Associating Systems 314
N E Y A , Saburo The Crystal Structures of Cyanide Metmyoglobins Reconstituted with Iron(III) Complexes of Porphyrin,
5,10,15,20-Tetramethylporphyrin, and 5,10,15,20-Tetraethylporphyrin 739
N E Y A , Saburo Stoichiometries and Equilibrium Constants of
N I B U , Yoshinori The Raman Active Intra- and Intermolecular
Vibrations of [Ήιο]- and [ Hi ] />-Xylenes 280
N I H I R A , T a k a y a s u One-Pot Synthesis and Redox Properties of
Conjugation-Extended 4,4'-Bipyridines and Related Com
pounds. New Ligands Consisting of a Heterocyclic Three-Ring
Assembly 1855
N I K A I D O , Tamotsu Tigogenin Hexasaccharides from Camassia cusickii. Structural Elucidation by Modern NMR Tech
niques 458
N I K A I D O , Tamotsu New Cholestane Bisdesmosides from the
N I K I , Etsuo Action of Fatty Acid Esters of L-Ascorbic Acid as
Antioxidants in Phosphatidylcholine Liposomal Membranes
679
NIKI,
Etsuo
FeSrCatalyzed
Hydrocracking of Di(lnaphthyl)methane. Effects of Hydrogen Pressure, Catalyst
3
3
2
9
2
2+
2
0
2
Feed and Reaction Temperature, and Kinetic Study 987
NIKI, Etsuo FeSi-Catalyzed Hydrocracking of «,ω-Diarylalkanes
1114
NIKI, Etsuo Oxidation of Phosphatidylcholine Liposomes in
Aqueous Dispersions Induced by Copper and Iron 1849
NIKI, Katsumi Determination of the Molar Absorption Coeffi
cients of r-Type Cytochromes Using Optically Transparent
N I K I , Seiji Knoevenagel Reaction of Malononitrile with Acetone
Followed by Double Cyclization Catalyzed by KF-Coated Alu
mina in Aqueous Solution 2934
N I K O L I C , Jasmina Topological Indices of Unbranched Catacondensed Benzenoid Hydrocarbons 2011
NISHI, Hiroshi Coal Solubilization with Cadmium and Butyl
Iodide under Mild Conditions 1067
NISHI, Nobuyuki One-Color and Two-Color ResonanceEnhanced Two-Photon Ionization Studies of Benzene: Sudden
nel Region 234
NISHIDA, Masakazu Stereoselective Decomposition of Pyrazolines Containing Trifluoromethyl Groups 1999
NISHIDA, Tetsuaki Comparison of IR-Transmission Method
with the Conventional DTA Method (Kissinger Plot) in the
Crystallization Study of Iron Tellurite Glass 1927
NISHIDA, Tetsuaki Phase Separation of Phosphotellurite
Glass Investigated by Fe-Mössbauer Spectroscopy and DTA
2540
NISHIDA, Tetsuaki Random Packing of Ions in the Ionic Glass
^KNO -(100-x)Sr(NO3)2 (.r-22~60) and the R a y Induced
Cleavage of K-ON0 Bonds 2881
NISHIDA, Yuzo Crystal Structures and Magnetic Properties of
Binuclear Copper(II) Complexes with Alkoxo and Benzoato or
Silanecarboxyiato Bridges 2739
N I S H I D E , Hiroyuki Synthesis of Soluble Poly(thio-2,6dimethyl-l,4-phenylene) by Oxidative Polymerization of
Bis(3,5-dimethylphenyl) Disulfide 2029
NISHIGUCHI, Ikuzo Novel Reduction of Carboxylic Acids and
Hydroboration of Olefins by Electrolysis of Sodium Borohydride 530
NISHIJIMA, Yasunori Photochemical Reactions of 4-Acylstyrenes. Effects of Acyl Substituents on Photocyclodimerization via an Excited Triplet State 837
NISHIJO, Juziro Inclusion Mode of 8-Anilino-l-naphthalenesulfonate (ANS) in the ANS-0-Cyclodextrin Complex 2869
NISHIKAWA, Kazuyoshi Diastereoselectivity and Reaction
Pathway of the Reactions of Benzaldehyde with Allylic Iodides
in the Presence of Sn or Pb 2145
N I S H I K A W A , Sadakatsu Kinetic Study in Aqueous Solutions
of Alcohols with Butyl Group by Ultrasonic Methods 1207
NISHIMORI, Natsu Synthesis of 2-(Substituted Methyl)-3,4Disubstituted Pyrroles and Their Conversion into the Corresponding Porphyrins 2660
NISHIMOTO, Kichisuke Theoretical Study of Structure and
Thermodynamic Properties of Liquid Hydrogen Fluoride 3122
NISHIMURA, Jun Intramolecular [2$HS7C2] Photocycloaddition. 14. Cycloreversion of Cyclophanes Possessing a Cyclobutane Ring at Their Tether 618
NISHIMURA, Jun Intramolecular [2+2] Photocycloaddition. 15.
Synthesis of
l,2-Ethano-9,10-methano[2.2]paracyclophanes
941
NISHIMURA, Norio Mercury(6 Pi)-Photosensitized Decomposition of Tetramethyllead 1710
NISHIMURA, Norio Temperature and Pressure Effects on the
Reversible Reaction of a Parent Phenol (GH) Corresponding to
Galvinoxyl with Aliphatic Amines 2437
NISHIMURA, Norio Thermal and Infrared Multiphoton
Decompositions of 7-Butyrolactone in the Vapor Phase 3112
NISHIMURA, Norio ESR Studies at High-Pressure. IV. SpinExchange Reactions of Various Types of Nitroxides in Some
57
3
7
2
3
December, 1992]
3541
AUTHOR INDEX
Low-Viscosity Solvents 3118
N I S H I M U R A , Shigeo Studies Concerning the Factors Affecting
the Formation of Cyclohexanone Intermediates in the Catalytic
Hydrogenation of Phenols. I . Hydrogenation of />-Cresol over
Various Pd-C Catalysts 824
N I S H I M U R A , Shigeo Effects of Alcoholic Solvents on the For
mation of Cyclohexanones in the Hydrogenation of Phenols
over Pd-C Catalysts 2955
N I S H I M U R A , Shigeo Phenylacetaldehyde and Carbon Monox
ide as Effective Additives for the Selective Hydrogenation of
Cyclooctadienes to Cyclooctene over Palladium Catalysts
2960
N I S H I M U R A , Tetsuo Preparation of Aromatic Iodoacetyl
N I S H I M U R A , Tohru Extractive Separation of Trace Amounts
of Cu", F e , and G a from A l on the Basis of HSAB Rule
2537
N I S H I M U R A , T s u k a s a Preparation and Properties of Mixed
Ligand Dinuclear Copper(II) Complexes Bridged by Deprotonated Oximato and Hydroxo or Acetato 3189
N I S H I M U R A , Yoshinobu Synthesis and Intramolecular
Electron-Transfer Reaction of Distance-Fixed Quinone-Linked
Porphyrins 2807
NISHIMURA, Yoshinobu Xanthene Dye-Sensitized Electron
Transfer to Methylviologen in Aqueous Organic Solution.
Effects of Organic Solvents and Heavy Atoms in the Dyes
2887
NISHIMURA, Yoshio Total Synthesis of Siastatin Β and Its
Enantiomer Using Carbohydrate as a Chiral Educt 978
NISHIMURA, Yukio Rotational Distribution of COCb ^) Pro
duced in Energy Transfer Reaction from Ar( P ) to CO 1713
NISHINO, Hiroshi Choice of Manganese(III) Complexes for the
Synthesis of 4,4'-Biphenyldiols and 4,4'-Diphenoquinones 620
NISHINO, Hiroshi Manganese(II and III)-Mediated Synthesis of
Cyclic Peroxides from Alkenes, Active Methylene Compounds,
and Molecular Oxygen 1371
NISHINO, Norikazu Synthesis of [L-a-Aminomyristic Acid - ']gramicidin S and Its Interaction with Phospholipid Bilayer
228
NISHINO, Norikazu Sequence Dependent Cyclization-Cleavage
of Dipeptides from the Oxime Resin and Its Prevention 991
NISHIO, Takehiko Chiral Hydantoin; A New Dienophile for
NISHIOKA, Takaaki One-Pot Synthesis of Optically Active
Cyanohydrin Acetates from Aldehydes via Quinidine-Catalyzed
NISHIOKA, T a k u y a Hydrophobic Vitamin Βι . XI. Preparation,
phobic Vitamin Bi Bearing a Binaphthyl Moiety 3094
N I S H I U R A , Rie Selective Permeation Properties of Inorganic
NISHIYAMA, Shigeru Syntheses of trans- and m-3-Methoxy-4methylthio-2-piperidinethiones. Previously Proposed Struc
NISHIYAMA, Tomihiro The Stereochemistry of the Sulfur
Atom of 4,7-Dimethyl-6-phenyl-5,6,7,8-tetrahydro-4i/-l,3,2,6dioxathiazocine 2-Oxides 2294
NISHIYAMA, Yoshiyuki The Effect of the CC1 F-Treatment
on Wettability of Silica Glass Surface by Water and Organic
Liquid 628
NISHIYAMA, Yoshiyuki Effects of Surface Pretreatments of a
Glass Substrate on the Properties of Tin Oxide Film Prepared
by Plasma-Assisted Chemical Vapor Deposition 1141
N I T T A , Tomohisa Racemization of Optically Active Aromatic
yV-Acetylamino Acids and Asymmetric Transformation of NAcetyl-2-(4-hydroxyphenyl)glycine via Salt Formation with
m
m
m
3
3
2
3
2
2
3
3
N I W A , Nobuko The Kinetic Study of the Oxygen-Exchange
Water 1397
N Ö D A , Hiroyuki ESR Study of Active Oxygen Radicals from
Photoexcited Semiconductors Using the Spin-Trapping Technique 2505
N Ö D A , Yosuke Fe Mössbauer Spectra, Crystal Structure, and
Spin-Crossover Behavior of [Fe(mbpN)(lut)]BPh 1825
NOGUCHI, M i c h i h i k o A Facile Generation and Stereoselective
Cycloaddition Reactions of 5,6-Dihydro-5,6-bis(methylene)2,4(1//,3//-)-pyrimidinedione Intermediate 2845
NOHIRA, H i r o y u k i Habit Modification of a Diastereomeric Salt
with an Additive in Optical Resolution 1747
NOHIRA, H i r o y u k i Optical Resolution by Preferential Crystallization of 2-(3,4-Carbonyldioxyphenyl)-2-(phthalimidooxy)acetic Acid, a Key Intermediate of Cephalosporin Antibiotic Μ
Ι 4659 3288
NOJIMA, Yasuhiko The Solvent Extraction and Dissociation of
N O K A M I , Junzo Substituent Effect on the EnantiofaceDifferentiating Reaction of (/?)-[Lithiomethyl />-Tolyl Sulfoxide]
with m- or ^-Substituted Acetophenones 526
NOMA, Naoki A Rechargeable Battery Using ElectrochemicallyDoped Poly(3-vinylperylene) as an Electrode Material 1062
NOMURA, Hiroyasu A Simple Method for the Evaluation of
NOMURA, Katsuhiro Framework Structure, Phase Transi
tion, and Transport Properties in M Zr (P0 )6Compounds
(M =Mg. Ca. Sr, Ba, Mn, Co, Ni, Zn, Cd, and Pb) 3221
NOMURA, Tsuyoshi Anion-Selective Field-Effect Transistor
Sensor Using RF-Sputtering Film of Alkali Metal-Free Lead
Phosphate Glass Containing Silver Oxide 2338
N O N A K A , T s u t o m u Anodically-Generated Br-Cl Composite
Halogenating Reagents 943
N O N A K A , Y u j i Optical Resolution of Amino Acid Esters by NProtected Aspartylphenylalanine Esters 1751
NONOGUCHI, H i r o s h i Exchange-Storage of a Guest Molecule
in an Inclusion Crystal of 2,11,20,29-Tetramethyl-2,11,20,29tetraaza[3.3.3.3]paracyclophane 805
NONOSHITA, Katsumasa On the Mechanism of Organoaluminum-Promoted Claisen Rearrangement of Allylic Vinyl
Ethers 541
NORO, Junji Solvent Extraction of Europium(III) with Benzoylacetone and Benzoyltrifluoroacetone into Carbon Tetrachlo
ride in the Absence and Presence of Tetrabutylammonium Ions
1910
NORO, Junji Solvent Extraction of Anionic Chelate Complexes
of Lanthanum(III), Europium(III), Lutetium(III), Scandium(III),
and Indium(III) with 2-Thenoyltrifluoroacetone as Ion-Pairs
with Tetrabutylammonium Ions 2729
NOUR E L - D I N , A h m e d M o u k h t a r Molecular Interactions
between Triazene 1-Oxides and Tetracyanoethylene 553
N O Z A K I , Fumio Vapor-Phase Beckmann Rearrangement of
Cyclohexanone Oxime over an HY Zeolite Catalyst Calcined at
High Temperature 1486
N O Z A K I , Hiroshi Pyrrolizidine Alkaloids. The Synthesis and
Absolute Configuration of All Stereoisomers of 4-Carboxy-4ethyl-3-hydroxy-2-isopropyl-4-butanolide, the Necic Acid Com
ponent of Axillaridine 1761
NOZAKI, K y o k o Isomerization of Olefins by Means of R SnHEt B and Stereochemical Study on Reduction of Alkenyl Iodides
349
NOZAWA, Tsunenori Substituent Effects on the Aggregation
limicola 3493
NOZOE, Tetsuo Stability and Resonance Energy of Azulenequinones and the Rule for Topological Charge Stabilization 1151
57
4
u
4
4
u
3
3
3542
[Vol. 65, No. 12
N U B E R , B e r n h a r d Crystal and Molecular Structure of the
Asymmetric Cobaloxime,
/raws-Bis(2,3-butanedione dioximatoil-^M/Vîodopyridinecobaltdll): [Co(Hdmg) l(py)) 612
O B A R A , Heitaro Synthesis of Model Compounds of Safflomin C
452
O B A R A , Heitaro Synthesis of Syzygiol; A Skin-Tumor Promo
tion Inhibitor 2552
O B I , Kinichi Photocyclization of Diphenylamine Studied by
Time-Resolved Thermal Lensing. Heat of Reaction, Energetics,
and Reactivity of Intermediates 1084
O B I , Kinichi Photodissociation of Highly-Excited Triplet State
of Benzophenone Studied by a Time-Resolved Thermal Lensing
Technique 1349
O B U C H I , K a z u y u k i Stereochemical Aspects on the BF -Et 0
Catalyzed Ring Contraction of 5-Substituted 2,3-Epoxycyclohexanones 3206
O C H I A I , Hisayoshi Preparation of Cu Thin Films by the
O D A , Jun'ichi One-Pot Synthesis of Optically Active Cyanohydrin Acetates from Aldehydes via Quinidine-Catalyzed Transhydrocyanation Coupled w i t h Lipase-Catalyzed Kinetic Resolu
tion in Organic Solvent 111
ODA, Naoko Refolding of Trimeresurus flavovindis Phospholipases A2 2655
O D A N I , A k i r a Copper(II)-Thioether Bondings in Multidentate
N,S-Donor Ligand Complexes. Structural Dependence of the
Chemical Properties of the Copper(II) Complexes of 1,5-Bis(2pyridylmethylamino)-3-thiapentane and 2,6-Bis(2,6-dithiaheptyl)pyridine 786
O G A T A , E i s u k e FeSrCatalyzed Hydrocracking of Di(lnaphthyl)methane. Effects of Hydrogen Pressure. Catalyst
OGATA,
E i s u k e FeS2-Catalyzed Hydrocracking of α,ωDiarylalkanes 1114
O G A T A , T s u y o s h i The Reactions of Monoalkylthio- or
O G A W A , H . I y e h a r a Synthesis of [L-a-Aminomyristic Acid > ']gramicidin S and Its Interaction with Phospholipid Bilayer
228
O G A W A , Tomohisa Refolding of Trimeresurus flavoviridis
Phospholipases A
2655
O G A W A , Toshihiko Effect of Inhibitors on Azo-Reduction of 4'Dimethyiaminoazobenzene-2-carboxylic Acid by Clostridium
Diaphorase 2349
O G I H A R A , Y a s u s h i Solvent Extraction and Association of
Nitrophenols w i t h Trioctylphosphine Oxide in Cyclohexane
2534
O G I K U , T s u y o s h i Syntheses of Aryltetralin Lignans: Concise
O G I N O , Keizo Syntheses of Azobenzene Derivatives Having
O G I N O , K e n j i Hydrolytic Metalloenzyme Models. Metal Ion
Dependent Site-Selective Acylation of Hydroxyl Groups of BisImidazole Ligands Catalyzed by Z n and C u in the Reaction
with />-Nitrophenyl 2-Pyridinecarboxylate in a Cationic Surfac
tant Micelle 373
O G I N O , Y o s h i s a d a Chemical State Analysis of Sn-Sb-0 Solid
Surfaces by Auger Electron Spectroscopy: Differentiation of
Sb(III) and Sb(V) 2709
OGO, Y o s h i a k i First Synthesis and Deodorant Activities of
Compounds Isolated from Thyme {Thymus Vulgaris L) and
Their Analogues 1159
O G O S H I , Hisanobu Bis(l-methylimidazole)iron(II) Complexes
of Porphyrins Substituted w i t h Highly Electron-Withdrawing
2
3
2
3
2
2+
2+
3
CF Groups: Electronic Spectra with Split Q-Bands and MCD
Spectra with Unusual Features 1915
OGUCHI, Yoshiyuki Reaction of Tantalum-Alkyne Complexes
with Isocyanates or Acyl Cyanides. Stereoselective Functionalization of Carbon-Carbon Triple Bonds 1543
OGUNI, Nobuki CD Spectral Diagnosis of Absolute Configura
tion of Tetrahedral or Pseudo-Tetrahedral Metal Complexes of
Salicylideneiminates 606
OGURA, Katsuyuki An Efficient and Practical Synthesis of L-aAmino Acids Using (#)-Phenylglycinol as a Chiral Auxiliary
2359
OHARA, Keishi Time-Resolved ESR Studies on Photosensitized
Reaction of Maleic Anhydride in Alcohols: CIDEP Memory
OHARA, Masakazu Random Packing of Ions in the Ionic Glass
*KNO -(100-;c)Sr(NO ) (*=22-60) and the γ-Ray Induced
Cleavage of K-ONO2 Bonds 2881
OHARA, Shuichi Thermostable Intramolecular Coupling Prod
ucts from Some />-Xylylenebis(anthrylcarboxylate)s and the
Relationship between Their Thermal Stability and Relative
OHASHI, Kazuhiko One-Color and Two-Color ResonanceEnhanced Two-Photon Ionization Studies of Benzene: Sudden
nel Region 234
OHASHI, Masayuki Optical Resolution by Preferential Crystal
lization of 2-(3,4-Carbonyldioxyphenyl)-2-(phthalimidooxy)acetic Acid, a Key Intermediate of Cephalosporin Antibiotic Μ
Ι 4659 3288
OHASHI, Yuji Atropisomerism in Doubly />m-Substituted 9-(2MethylbenzyDtriptycene Derivatives, 8-Chloro- and 8-Bromo1,4-dimethyl-9-(2-methylbenzyl)triptycenes 1957
OHASHI, Y u j i The Crystal Water Affecting the E -> A Relaxa
tion in Tris(oxalato)chromate(III) Complexes 3378
OHBA, Masaaki Syntheses and Magnetic Properties of
OHBA, Masaaki Synthesis and Magnetisms of Oxamido- and
Oxamato-Bridged Binuclear Nickel(II)-Copper(II) Complexes
1988
OHBA, Masaaki Synthesis and Magnetic Property of
Imidazolate-Bridged Cu(H)-M(II)-Cu(II) Complexes (M=Zn,
Cu,Ni,Co,Mn) 2283
OHBA,
Shigeru Preparation and Characterization of
[Co(tp) (Me -en)] (tp=Tropolonate Ion; Me -en (n=l—4)=iVMethyl Substituted Ethylenediamine), Inversion and Deutera
tion at Chiral Nitrogen Centers of [Co(tp)2(Me-en or Me -en)],
and Crystal Structures of [Co(tp) (iV, /V-Me -ena)ClC 1572
OHBA, Shigeru Molecular Structures of
ΗΤ-[ΜΜΌ\ {μMe Ppy) ] (MM'=Pd , PdPt, and Pt ; Me Ppy=2-(Dimethylphosphino)pyridine) and //T-[Pd Cl (M-Ph Ppy) ](Ph Ppy=2(Diphenylphosphino)pyridine) 1817
OHBA, Shigeru Preparation and Characterization of Cobalt(III)
(dppf) or l,l'-Bis(dimethylphosphino)ferrocene (dmpf) as a
Bidentate Ligand, and Molecular Structures of [Co(acac) (dmpf)]B(C H )4 and [Co(dtc) (dmpf)]B(C H )4 (acac=2,4pentanedionate ion, dtc=dimethyldithiocarbamate ion) 2037
OHBA, Shigeru X-Ray Structural Study of trans-[CoC\r
(232N 15)]C10
(232N 15=1,4,8,11-Tetraazacyclotricosane)
2114
OHBA, Shigeru Crystal Structures and Magnetic Properties of
Silanecarboxylato Bridges 2739
OHBA, Shigeru Preparation and Characterization of Cobalt(III)
Complexes Containing l,l,l-Tris(dimethylphosphinomethyl)ethane (mmtp), and the Crystal Structure of [Co(mmtp) ][Co(CN) ]-2.25H 0 2748
OHBA, Shigeru X-Ray Strucutre and Conformational Analyses
3
3
3
2
2
2
+
M
4
6
28
M
3
2
2
2
2
2
2
2
2
2
6
4
4
2
5
2
2
2
2
6
2
5
4
2
6
2
December, 1992)
3543
AUTHOR INDEX
of Cobalt(III) Complexes Containing 1,3-Propanediamine and
1,4-Butanediamine 3033
O H E , Kaoru Intercalation of a Trimethylammoniomethylated
Calix[4)arene by Cu(II)-Montmorillonite 2510
OHGO, Yoshiaki Asymmetric Synthesis of Benzoin by Sml Mediated Enantioselective Protonation 2001
O H I S H I , Syunya Polymers Having pH-Buffering Capability for
O H K I T A , Akira Energy- and Electron-Transfer Pathways in the
Triplet-Sensitized Photolysis of Af-(l-Naphthoyl)-0-(/>-toluoyl)N-phenylhydroxylamine with Substituted Benzophenones
1950
O H K I T A , Noriaki Reactivities of 2-C- and 3-C-Nitro-a- and /3-Dery/Aro-Hex-2-enopyranoside Derivatives towards Methanol
and A M I Studies upon Their Stereoselectivitie 446
O H K U B O , Sakurako Syntheses and Magnetic Properties of
OHMI, Hajime Peri-Selective Cycloaddition Reactions of 3Methoxycarbonyl-2//-cyclohepta[6]furan-2-one
with
6,6Dimethylfulvene 2127
OHMIZU, Hiroshi Syntheses of Aryltetralin Lignans: Concise
OHMORI, Kenji A Flash Photolysis Study of CH -0 Mixtures
behind Shock Waves: Examination of Reaction of CH3#//S7C0
1317
OH Μ Ο Τ Ο , Taichi Tigogenin Hexasaccharides from Camassia
cusickii. Structural Elucidation by Modern NMR Techniques
458
OHMOTO, Taichi New Cholestane Bisdesmosides from the
Bulbs of Ornithogahim fhyrsoides 1120
OHNO, Mina Diastereoselective Addition of Grignard Re
agents to 3,4-0-Isopropylidene-l-0-triphenylmethyl-L-^/ycgro-2tetrulose and l-0-Benzoyl-3,4-0-isopropylidene-L-^/yc^ro-2tetrulose 2814
OHNO, Motonori Refolding of Trimeresurus flavoviridis Phospholipases A 2655
OHNO, Osamu The Fluorescence Properties of (2-Nitro5,10,15,20-tetraphenylporphyrinato)zinc 1475
OHNO, Teruhisa Hydrophobic Vitamin B . XL Preparation,
phobic Vitamin B12 Bearing a Binaphthyl Moiety 3094
O H R A I , Shin-ichiro Transformation of Propargylic Alcohols
into Enones 2594
O H S A K A , Takeo Piezoelectric Admittance Measurements of
Montmorillonite/Poly(vinyl alcohol) Composite Film-Coated
Quartz Crystal Oscillators 1884
O H S A K I , Masako A Practical Synthesis of töra?-3-Amino-2hydroxycarboxylic Acids 360
O H S A K I , Masami Synthesis, Characterization, and Properties
of V O-Ln(III) (Ln=La, Pr, Eu, Gd, Tb) Complexes of Ν,Ν'Bis(3-carboxysalicylidene)ethylenediamine 2514
O H S A K I , Masutaka Cyclization of N-Terminal Fragments of
Elcatonin 1728
OHSHIMA, Kouji Enzymatic Reactions in Aqueous-Organic
Media. XVII. Optical Resolution of Amino Acid Esters by Enzy
matic Hydrolysis in Organic Solvents 2599
OHSHIRO, Yoshiki Functionalization of ltf-Pyrrolo[2,36]pyridine 2992
O H S U K A , Akio Two Conformers and Aggregation of Cyclic
Octapeptide, cyc/o(G-eLL-G) , in Chloroform 917
OHSUMI, Rie Fluorescence Quenching in {Ln[Fe(CN) ] · wH 01*
(Ln=Eu(III) or Tb(III)) 2278
OHTA, Hiroshi Reaction of Olefins with Dimethyl(methylthio)sulfonium Salts in the Presence of Triphenylphosphine. Prepa
ration of Vinylphosphonium Salts 2375
OHTA, Kenjiro Simultaneous Generation of /-BuO- and f-BuOOfrom the Decomposition of 2,2-Bis(/-butyldioxy)propane. A New
2
4
2
2
2
i2
,v
2
6
2
Synthetic Method for Introducing a /-BuOO Group into Organic
Molecules 2063
OHTA, Kyuji Prediction of p/f. Values of Alkylphosphonic Acids
2543
OHTA, Tomoko Conductometric Study of Ion Association
between Tris(ethylenediamine)cobalt(III) Ion and Monovalent
Anions at Temperatures from 0 to 50 °C 2901
O H T A K I , Hitoshi X-Ray Diffraction Studies on the Structure of
the Tri- and Tetrathiocyanatomanganate(II) Complexes and
Solvated Lithium Ion in AWDimethylformamide 1445
O H T A K I , Hitoshi EXAFS and X-Ray Diffraction Studies on the
Structure of the Tetrathiocyanatocadmate(II) Complex in
Dimethyl Sulfoxide 2104
O H T A N I , Takashi "Syn-Effect"'\n the Conversion of (£)-Vinylic
OHTOMO, Katsunori Substituent Effects on the Aggregation of
limicola 3493
O H Y A - N I S H I G U C H I , H i r o a k i The Role of a Spin-Coupled
Intermediate in a System Consisting of Tetraminecobalt(III)
Complexes and Catechols —A Model Intermediate of Dioxygenase Reaction— 1225
O I , Takao Esterification of Boric Acid w i t h 1,2-Propanediol, 3Amino-l,2-propanediol,
and
(±)-3-Dimethylamino-l,2-propanediol as Studied by B NMR Spectroscopy 1903
O I K A W A , Hiroshige Transformation of Propargylic Alcohols
into Enones 2594
O I K A W A , Kazuo ESR Study of Active Oxygen Radicals from
Photoexcited Semiconductors Using the Spin-Trapping Tech
nique 2505
OISHI, Yushi Evaluation of Melting and Crystalline Relaxation
Temperatures of Fatty Acid Monolayers on the Water Surface
and Their importances for Molecular Aggregation States in
Monolayers 864
OJIKA, Makoto A New Bromo Diterpene, e/>i-Aplysin-20, and
ewMsoconcinndiol from the Marine Mollusc Aplysia kurodai
2300
OJIMA, J ü r o H and CNMR Spectral Behavior and Isomerism
in 7,12-Dimethyl-, 2,7,12-Trimethyl-, and 7,12,15-Trimethyl8,10-bisdehydro[15]annulenones 2388
O K A B E , K i y o m i Selective Hydrogenation of Carbon Dioxide to
Methanol on Cu-ZnO/Si0 Catalysts Prepared by Alkoxide
Method 2520
O K A B E , N o b u y u k i Palladium-Catalyzed, Atmospheric Pressure Carbonylation of Allylic Halides under the Influence of
Sodium Hydroxide or Alkoxides. A Facile Synthesis of ß>yUnsaturated Acids 2589
O K A D A , Makoto ESR Spectra of Some Allene Radicals in LowTemperature Matrices 2442
O K A D A , Mutsuo Electric Field Orientation of Ionizable Polymers with Three Different Electric Dipole Moments. I . New
Orientation Function and the Steady-State Electric Birefringence of Poly(L-a-glutamic acid) in Methanolic and Aqueous
Solutions 129
O K A D A , Shigeru Growth Conditions of Ta3B Single Crystals
Prepared by the Aluminium-Flux Method 421
O K A D A , Shin-ichi Selective Friedel-Crafts Alkylation on a
Vermiculite, a Highly Active Natural Clay Mineral w i t h Lewis
Acid Sites 2833
O K A D A , Takuya Mössbauer Emission Spectroscopy of Fe
O K A D A , Yoshiyuki Synthesis of Non-Ester Pyrethroids Having
a 1-Fluoro-l-methylethyl Group Using 1,2-Migration of an Aryl
Group 2401
OKAHARA, M i t s u o Complexation Property of a Novel Macrobicyclic Polyether with Two Amide Moieties toward Alkali Metal
O K A H A T A , Yoshio Preparation of a Lipid-Coated Lipase and
Catalysis of Glyceride Ester Syntheses in Homogeneous
n
l
13
2
4
57
57
3544
O K A J I M A , Takeyoshi Piezoelectric Admittance Measurements
of Montmorillonite/Poly(vinyl alcohol) Composite Film-Coated
O K A M O T O , Hideki The Base-Catalyzed H/D-Exchange of Anisole Moiety of Ruthenium Complex in Cooperation with
O K A M O T O , Hidenori One-Step Hydroamidation of 2-Aza-1,3pentadienes 674
O K A M O T O , Ken-ichi Stereoselective Formation and Some
Properties of Polynuclear Cobalt(III) Complexes with DPenicillaminate 794
O K A M O T O , Ken-ichi Correlation between Positron Annihila
tion and Gas Diffusion Properties of a Series of Polyimides
1891
O K A M O T O , Ken-ichi Preparation and Stereochemistry of the
Mixed-Ligand Complex, Ammine(ethylenediamine)(ethylenediamine-N-acetato)cobalt(III) 1920
O K A M O T O , Ken-ichi Synthesis and Properties of T-Cage-Type
Se-Bridged Polynuclear Co(III) and Rh(III) Complexes with 2Aminoethaneselenolate (aese). Crystal Structure of [{Co(aese) }4Zn 0](C104)6 3015
O K A M O T O , Mitsuko Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
O K A M O T O , Tsuyoshi Preparation of Aromatic Iodoacetyl
O K A M O T O , Tsuyoshi Halogenation Using Quaternary Ammo
O K A M O T O , Yasuaki Genesis of Highly Active Cobalt Sulfide
O K A M O T O , Yoshio Optical Resolution by Supercritical Fluid
Chromatography Using Polysaccharide Derivatives as Chiral
Stationary Phases 2286
O K A M U R A , Hiroaki Stereoselective Synthesis of (±)-Ireland
O K A N O , Masayoshi Catalytic Hydrogenation of Dehydro Quassinoids and Cytotoxic Antitumor Activity of the Hydrogenation
Products 2684
O K A N O , Tamon Catalytic Acid Fluoride Synthesis via Carbonylation of Organic Bromides in the Presence of Potassium
Fluoride 1741
O K A N O , Tamon Palladium-Catalyzed, Atmospheric Pressure
Carbonylation of Allylic Halides under the Influence of Sodium
Hydroxide or Alkoxides. A Facile Synthesis of β,γ-Unsaturated
_ Acids 2589
O K A W A , Hisashi Crystal Structures of Mono- and Di-nuclear
Nickel(II) Complexes Derived from the Substitution Reaction of
[Ni(Me2[14]dienatoN )]I and Each of Benzoyl Chloride and
_ Isophthaloyl Dichloride 258
O K A W A , Hisashi Thiolate-Bridged Binuclear Nickel(II) Com_ plexes with a Mixed-Spin State 512
O K A W A , Hisashi CD Spectral Diagnosis of Absolute Configura
tion of Tetrahedral or Pseudo-Tetrahedral Metal Complexes of
_ Salicylideneiminates 606
O K A W A , Hisashi Fluorescence Quenching of Europium(III) by
Heteronuclear Complex Formation with Copper(II) or Nickel(II)
_ 1162
O K A W A , Hisashi Template Synthesis and Structure of a Dinuclear Lead(II) Complex of Novel Macrocycle Derived from 2,6Diformyl-4-methylphenol and
l,9-Diamino-3,7-diazanonane
_ 1176
O K A W A , Hisashi Syntheses and Magnetic Properties of
3
4
4
[Vol. 65, No. 12
_ Bridging Mode upon Magnetic Interaction 1603
Ö K A W A , Hisashi Synthesis and Magnetisms of Oxamido- and
Oxamato-Bridged Binuclear Nickel(II)-Copper(II) Complexes
_ 1988
OKAWA, Hisashi Fluorescence Quenching in lLn[Fe(CN) ] ·
_ »H Olr(Ln=Eu(IH)orTb(III)) 2278
OKAWA, Hisashi Synthesis and Magnetic Property of
Imidazolate-Bridged Cu(II)-M(II)-Cu(II) Complexes (M=Zn,
_ Cu, Ni, Co, Mn) 2283
OKAWA, Hisashi Synthesis, Characterization, and Properties
of V O-Ln(III) (Ln=La, Pr, Eu, Gd, Tb) Complexes of Ν,Ν'Bis(3-carboxysalicylidene)ethylenediamine 2514
O K A Z A K I , Susumu The Effect of the CC1 F-Treatment on
Wettability of Silica Glass Surface by Water and Organic
Liquid 628
O K A Z A K I , Susumu Oxidative Coupling of Methane over Var
ious Barium Salts Mixed with CaO: The Relation with Their
_ Surface Basicities 2251
OKI, Michinori Structure of Intramolecular Boron-Amine Com
plexes and Proposal of Tetrahedral Character for Correlation
between Molecular Structure and Barrier to Dissociation of the
_ N-B Bonds 1832
OKI, Michinori Dynamic NMR as a Nondestructive Method for
the Determination of Rates of Dissociation. XX. Secondary
isotope Effect on Kinetic Basicity of Amine Ligands in Boron_ ate-Amine Complexes and Ammonium Salts 2215
OKI, Michinori Syntheses of and Restricted C pj-C p» Bond
Rotation in Triptycenes That Carry d-Olefinic Substituent at
_ 9-Position 2616
OKI, Michinori Structure of and Tetrahedral Character of the
Boron Atom in 9-(2-(l-Ethylthiopentyl)phenyl]-9-borabicyclo[3.3.1]nonane 2857
OKI, Kazuo Preparation of Cu Thin Films by the Decomposition
of Copper Acetylacetonate on Catalytically Active Substrate
Surfaces 892
O K U B O , Jun Preliminary Analysis of the Electronic Absorption
Spectrum of a Solute in a Biaxially-Stretched Polymer Film
463
O K U B O , Jun Dimer Formation of 9-Cyanoanthracene in a Nonpolar Medium at Low Temperatures 692
O K U B O , Jun Electronic Absorption and Phosphorescence Spec
tra of 2-Acetylfuran. Conformations in the Ground and Excited
Triplet States 2067
OKUMA, Kentaro Reaction of Olefins with Dimethyl(methylthio)sulfonium Salts in the Presence of Triphenylphosphine.
O K U M U R A , Akiko The Kinetic Study of the Oxygen-Exchange
Water 1397
O K U M U R A , Fumio Preparation and Properties of Clays Pil
lared with S i 0 - T i 0 Sol Particles 2494
O K U M U R A , Yasuo 1:1 Adduct Ion Formation of Simple Car
bohydrate Derivatives with Cations Using FAB Mass Spec
trometry. Comparison of O-Acetyl, N-Butyl, and O-Methyl
Modifications 1275
O K U M U R A , Yoshiyuki Diastereoselective Construction of
2,2,6-Trisubstituted Tetrahydropyrans by Intramolecular Alk
ylation Reaction of Lithium Enolates Generated from a-Alkoxy
Carboxylates 3487
OKUNO, Masaaki Preparation and Characterization of Co(III)Dimethyldithiocarbamato Complexes Containing 1,2-Bis(dimethoxyphosphino)ethane. Molecular Structures of [Co{(CH )2NC(S)SKR P(CH )2PR2}2](BF4)2 (R=CH 0 and CH ) 3042
O K U R A , Ichiro Photoinduced Electron Transfer between Zinc
Protoporphyrin Reconstituted Myoglobin and Methylviologen
591
O K U S A K O , Yoshimi The Substituent Effects on Solvolyses of
//*ra?-2-Aryl-l-methylpropyl Brosylates 3072
O K U S E , Satoshi A Convenient Preparation of 2,4,66
2
,v
3
S
2
S
2
3
2
2
3
3
December, 1992)
3545
AUTHOR INDEX
Trisubstituted 1,3,5-Triselenanes by Treating Aldehydes or
Their Acetals with 2,2,4,4,6,6-Hexamethyl-l,3,5-triselena-2,4,6tristannacyclohexane in the Presence of BF3*OEt and AlCb
2848
O K U Y A M A , F u m i y o Oxidative Dehydrogenation of Ethylenediamine Coordinated to Ruthenium with Hexafluoroacetylacetonate, Induced by Electrochemical Oxidation of Ruthenium(II) to
Ruthenium(III) 876
O K U Y A M A , Tadashi Dual Reactivity of Methoxymethyl Benzenesulfenate in Nucleophilic Substitution 2672
O N A K A , Satoru Four Different Coordination Modes of 1.ΓBis(diphenylphosphino)ferrocene: Synthesis, X-Ray Crystal
Carbonyl
Complexes
with l,l'-Bis(diphenylphosphino)ferrocene (dppfe) 1415
O N D A , K e n - i c h i 1-Haloalkyl Aryl Sulfoxides as Useful Agents
O N I K I , T a k a y u k i Effects of Redox Reagents on ESR Line Shape
of Synthetic Melanins 6
O N I K I , T a k a y u k i Reaction of Synthetic Melanins with Redox
Reagents. I I . ESR Spectra Using Flow Method 476
O N I S H I , T a k a h a r u Photocatalytic Hydrogen Evolution from
O N I T S U K A , K i y o t a k a Syntheses and Properties of Heterodinuclear μ-Ethynediyl Complexes Containing Palladium and Plati
num 1179
ONO, Isamu A Computational Approach to the Structure and
Motion of Hexakis(pentyloxy)triphenylene(THE5) in Discotic
Mesophase 1057
ONO, Isao Dimer Formation of 9-Cyanoanthracene in a Nonpolar
Medium at Low Temperatures 692
ONO, Isao Electronic Absorption and Phosphorescence Spectra
of 2-Acetylfuran. Conformations in the Ground and Excited
Triplet States 2067
ONO, K a t s u h i k o A Novel Skeletal Rearrangement of 2Azabicyclo[2.2.1]hept-5-ene-3-carboxylic Acid Derivatives into
2-Oxabicyclo[3.3.0]oct-7-en-3-ones under Acidic Conditions 61
ONO, Masaaki Reaction of Olefins with Dimethyl(methylthio)sulfonium Salts in the Presence of Triphenylphosphine. Prepa
ration of Vinylphosphonium Salts 2375
ONO, T a k e h i k o Chemical State Analysis of Sn-Sb-0 Solid
Surfaces by Auger Electron Spectroscopy: Differentiation of
Sb(III) and Sb(V) 2709
ONO, Yoshio Thermal Transformation of a Layered Double
Hydroxide Pillared with Decavanadate Isopolyanions 2465
ONODERA, Jun-ichi Synthesis of Model Compounds of SafflominC 452
ONODERA, J u n - i c h i Synthesis of Syzygiol; A Skin-Tumor Pro
motion Inhibitor 2552
ONOUE, K o u i c h i Micellar Effect on the Formation Rate of
Ni(II) and Co(II) Complexes with 8-Quinolinol and Its
5-Alkyloxymethyl-8-quinolinol Derivatives in a Nonionic Sur
factant Micellar System 286
OOGA, Y u k i h i r o A Systematic Study on the Bakers' Yeast
631
OOISHI, Kazuo Crystal and Molecular Structures of Acetoacetanilide, and 0- and />-Chloroacetoacetanilides: X-Ray Crystallographic and MO Study 3234
ORITA, Hideo Synthesis of Alkyl Substituted />-Benzoquinones
from the Corresponding Phenols Using Molecular Oxygen Cat
alyzed by Copper(II) Chloride-Amine Hydrochloride Systems
1522
ORITA, Masaya Synthesis of 3-Deoxy-5-0-mycaminosyltylonolide
and
3-Deoxy-5-0-(4-deoxymycaminosyl)tylonolide
3405
OSA, Tetsuo Thermostable Intramolecular Coupling Products
2
from Some ρ Xylylenebis(anthrylcarboxylate)s and the Rela
tionship between Their Thermal Stability and Relative Distor
tion Energy 3103
OSADA, Katsumi Preparation and Properties of Immobilized
Glucoamylase on a Magnetically Anisotropic Carrier Compris
ing a Ferromagnetic Powder Coated by Albumin 3430
O S A K A I , T o s h i y u k i Synthesis and Characterization of
Vanadium-Substituted Heteropoly Molybdosulfate(VI) Com_ plexes 799
OSAWA, Eiji Attempted Transformation of 2,3,5,6-Tetrachloro4,4-dimethoxypentacyclo(5.4.0.0 .0 .0 ]undecane-8,ll-dione
toward Pentaprismane Retaining Chloro Group 2312
OSAWA, Masatoshi Substituent Effects on the Aggregation of
limicola 3493
OSAWA, Tsutomu Hydrogenation and Isomerization of Disodium Maleate in the Solid Phase over Fine Nickel Powder
1168
O S H I K A W A , Tatsuo Novel Synthesis of 2-Phosphinoylphospholane 1-Oxide Derivatives 2004
OSHIMA, Koichiro Isomerization of Olefins by Means of
RaSnH-EtßB and Stereochemical Study on Reduction of
Alkenyl Iodides 349
OSHIMA, Koichiro Triethylborane Induced Radical Reaction of
Ketene Silyl Acetals with Polyhalomethanes 1513
OSHIO, H i r o k i Fe Mössbauer Spectra, Crystal Structure, and
Spin-Crossover Behavior of [Fe(mbpNXlut)]BPh 1825
OSHIYAMA, Tomohiro A M I Potential Energy Curves for CisTrans Isomerization of Stilbene Cation Radicals 2267
OSUKA, Atsuhiro Synthesis and Intramolecular ElectronTransfer Reaction of Distance-Fixed Quinone-Linked Porphyrins 2807
OSUKA, Ätsuhiro Synthesis of Benzochlorin Monomer, Dimer,
and Porphyrin-Benzochlorin Heterodimer from 5-Aryl- and
5,15-Diaryl-octaethylporphyrins 3322
O S U M I , Tomomasa The Total Synthesis of Herbimycin A
2974
OTSU, Takayuki Synthesis and Radical Polymerization of Itaconates Containing an Adamantyl Ester Group 846
OTSUJI, Atsuo 1,2-Addition of Allyl and 2-Oxo-2#-pyran-6ylcarbonyl Groups to Cyclic C=N Double Bonds by Means of
OTSUJI, Yoshio Structural Features of (CH )2Si(C H ) Fe (CO)3(C=NR) and (CH ) Si (C5H ) Fe (CO) (C=NR)2 2309
OTSUJI, Yoshio A Convenient Synthesis of Cationic Vinylidene
and 1,2-Propadienylidene Iron Complexes by Photoreaction of
[CpFe(CO)(dppe)] BF -with l-Alkynes 2560
OTSUKA, T a k u h i r o The Crystal Water Affecting the E -> A
OYA, Toyohisa Synthesis of (±)-Isopiperitenol by Fluoride Ion
Mediated Cyclization of Allylsilane Moiety Incorporated in Terpene Aldehydes 929
O Y A M A , Kiyotaka Optical Resolution of Amino Acid Esters by
iV-Protected Aspartylphenylalanine Esters 1751
O Y A M A , Noboru Piezoelectric Admittance Measurements of
O Z A K I , Shoichiro A Chiral Synthesis of D-myo-Inositol 1Phosphate Starting from L-Quebrachitol 366
O Z A K I , Shoichiro AlCl -N,iV-Dimethylaniline: A Novel Benzyl
and Allyl Ether Cleavage Reagent 1932
OZAWA, Takehiro Molecular and Crystal Structure of 3,5,5Trimethyl-2-(2-methyl-2-nitropropyl)-2-cyclohexen-l-one Possessing Molecular Asymmetry 2860
OZEKI, Tomoji WNMR and X-Ray Crystailographic Studies
on the Peroxo Complexes of the Ti-Substituted α-Keggin Typed
Tungstophosphates 1453
2,6
3,10
5,9
57
4
3
3
2
4
+
2
2
5
4
2
2
2
4
2
3
183
g
4
2g
3546
[Vol. 65, No. 12
BULLETIN O F THE CHEMICAL SOCIETY OF JAPAN
O Z U T S U M I , Kazuhiko A Precise Caiorimetric Study of 18Crown-6 Complexes with Sodium, Potassium, Rubidium, Cae
sium, and Ammonium Ions in Aqueous Solution 1173
O Z U T S U M I , Kazuhiko Equilibrium and EXAFS Studies of
Mercury(II) Porphyrin in Aqueous Solution 1438
O Z U T S U M I , Kazuhiko EXAFS and X-Ray Diffraction Studies
on the Structure of the Tetrathiocyanatocadmate(II) Complex
in Dimethyl Sulfoxide 2104
P A N D E Y , R a m Nagina Studies on «-CdSe/Ti Semiconductor
Septum Based Photoelectrochemical Solar Cell in Regard to the
Influence of Structural and Compositional Characteristics of
the Semiconductor Electrode 1072
P A R K , Young-seo Simultaneous Formation of a Polypyrrole
Film and a Tantalum Oxide Layer by Electrochemical Oxida
tion 1860
P A T I L , Murlidhar D. Solid State Oscillatory Reaction. I . Ther
mal Decomposition Studies of [Co(NH3)6]Br3 and CoBr · 2H 0
1026
P A T N A I K , Gyanedra K u m a r Synthesis and Biological Eva
luation of Dehydrophenylalanine Containing Substance Ρ Frag
ments 3412
P R A B H U , Peesapati Venkata Seshadri Sekhar Dielectric
Behavior of Aqueous Binary Mixtures of Hydrophobic Solutes
1716
P R A S A D , Rajendra Cyanodithioformate Complexes of Cyclopentadienylruthenium(II). Synthesis, Spectral and Electro
chemical Study 3398
P R A S H A N T , Avula DDQ Oxidation of 6- or 8-Allyl 7-hydroxycoumarins. A New Synthesis of Benzodipyrandiones and Furobenzopyranones 1191
QIAN, Chang-Yi Manganese(II and III)-Mediated Synthesis of
Cyclic Peroxides from Alkenes, Active Methylene Compounds,
and Molecular Oxygen 1371
QIAN, P u Synthesis of Optically Active Polymethacrylates Bear
ing Axially Dissymmetric Ι,Γ-Binaphthalene Skeleton as a
Pendant Group and Their Optical Resolution Ability as Chiral
Adsorbent for HPLC 817
R A D N A I , Tamäs X-Ray Diffraction Studies on the Structure
of the T r i - and Tetrathiocyanatomanganate(II) Complexes and
Solvated Lithium Ion in N,N-Dimethylformamide 1445
R A G H U B I R , R a m Synthesis and Biological Evaluation of
Dehydrophenylalanine Containing Substance Ρ Fragments
3412
R A K I B - U Z - Z A M A N , Md. Formation of Charged Species in (n,
y) Activated 2-Bromopropionic Acid: An Atypical Case 3507
R A M A R A O , Kuchimanchi Venkata Subba C0 Laser
Induced Sensitized Dissociation of Ethylene Oxide 1691
R A M A N A I A H , G. V. Spectrophotometric Determination of
Trace Silver with Sodium 2-(8-Hydroxyquinolin-5-ylazo)benzoate 2291
R A M A N A M U R T I , Medepalli Venkata Dielectric Behavior of
Aqueous Binary Mixtures of Hydrophobic Solutes 1716
RAO, Kemmannu Annaji C 0 Laser Induced Sensitized Disso
ciation of Ethylene Oxide 1691
RAO, Thatavarthi Ramalingeswar Synthetic and Spectro
scopic Studies of Some Lanthanoid Metal Complexes of 2Acetylpyridine Nicotinoylhydrazone 2766
R I S T l C , Lidija Two Variants of the Topological Index and the
R U A N O E S P I N A , Myriam Efficient Preparation of a Valuable
Intermediate in the Synthesis of (—)-Swainsonine 567
R U A N O E S P I N A , Myriam Stereochemical Outcome of Aldol
Reaction of a 6-C-Substituted D-Mannose Derivative 575
S A B U R I , Masahiko Syntheses and Structures of Novel Ruthenium(II)-Chiral Diphosphine Complexes 1595
S A D A O K A , Yoshihiko Electrical Properties and Sinterability
for Lithium Germanium Phosphate Lii#//S7CxM Ge2-x(P04)3,
M=A1, Cr, Ga, Fe, Sc, and In Systems 2200
S A E K I , Masakatsu Effect of γ-Ray Irradiation on the Recoil
2
2
2
jr
2
Reaction 735
S A E K I , Yoshihiro Solvent Effects on the Solvolysis of Neophyl
Tosylates 46
S A E K I , Yoshihiro The Substituent Effects on Solvolyses of
/Ara?-2-Aryl-l-methylpropyl Brosylates 3072
SAGARA, Fumio Re-evaluation of the Acid Dissociation Con
stants of the Hydroxyl Groups in Tetrasodium 25,26,27,28Tetrahydroxycalix[4]arene-5,ll,17,23-tetrasulfonate 1012
SAGARA, Takamasa Determination of the Molar Absorption
Coefficients of c-Type Cytochromes Using Optically Transpar
ent Thin-Layer Electrodes 424
SAHA, Swapan K. Isothiocarbamido Radicals from Thiourea:
Electron Spin Resonance Spectroscopy of /V-Benzylidene-/butylamine-N-oxide and 5,5-Dimethyl-l-pyrroline-N-oxide Spin
Adducts 2720
SAHAL, Dinkar Paper Chromatographic and Ή NMR Study of
Ion Pair Interactions between /V-Dodecanoylhistidine Methyl
Ester and Dodecyl Dihydrogenphosphate in Chloroform 1719
SAID, Abdel-Aziz Ahmed Role of the Structure and Electronic
Properties of Fe 0 -Mo03 Catalyst on the Dehydration of Isopropyl Alcohol 3450
SAIGO, Kazuhiko Habit Modification of a Diastereomeric Salt
SAIMOTO, Hiroyuki Transformation of Propargylic Alcohols
into Enones 2594
SAIMOTO, Hiroyuki Partial Reduction of Dithioacetals with
SAITO, Atsuyoshi Synthesis and Characterization of
Vanadium-Substituted Heteropoly Molybdosulfate(VI) Com
plexes 799
SAITO, Gunzi Crystal Structures of T X C - T T F (X=Se,Te)
1482
SAITO, Gunzi Crystal Structures and Molecular Packing of
Tetrakis(alkylthio)tetrathiafulvalene (TTC*-TTF); Part I
(w=3,4,6) 1878
SAITO, Gunzi Crystal Structures and Molecular Packing of
Tetrakis(alkylthio)tetrathiafulvalene ( T T C » - T T F ) ; (Part II)
(«=7,9,11) 2086
SAITO, Hiroyuki Determination of the Molar Absorption Coeffi
cients of c-Type Cytochromes Using Optically Transparent
SAITO, Junji [147t]Electrocyclization Followed by Preferential
[l,9]Hydrogen Migration in the Thermolysis of l-Formyl-4[(2,4,6-cycloheptatrienyl)(phenylsulfinyl)methyl]azulene 3198
SAITO, Katsuhiro [S$HS7C2] Cycloadditions of 2,4,6-Cycloheptatriene-l-imines with Chloroketenes: Facile and High-Yield
One-Pot Synthesis of l-Azaazulen-2(l//)-ones 812
SAITO, Katsuhiro Ή NMR Study of 2,3-Dicyanobicyclo[2.2.2]octa-2,5,7-triene Partially Oriented in a Nematic Phase
906
SAITO, Koji Structure and Orientation of o-Phenylene Phosphorochloridite and o-Phenylene Phosphorochloridate Dissolved in
a Nematic Phase 1135
SAITO, Reiko Diastereoisomers of Platinum(II) Complexes with
Chiral ^-Substituted 1,2-Diamines. I . Structure and Isomeriza
tion
of Dichloro}(/?>2-[(2-methyl-2-aminopropyl)amino]-lbutanol}platinum(II) 1428
SAITO, Reiko Diastereoisomers of Platinum(II) Complexes with
Chiral TV-Substituted 1,2-Diamines. I I . Structures of
SAITO, Takao Generation and Cycloaddition Reactions of 3Styryl-l,2-thiaphosphole 2-Sulfide
and l,5-Diphenyl-2,4pentadiene-l-thione 923
SAITO, Yasushi The Spectroscopic Properties and Organometallic Reactivities of Cobalt(III) Porphyrins 639
SAITOH, Takayuki Diffusion Coefficient of Benzene around the
2
3
8
December, 1992)
3547
AUTHOR INDEX
Gas-Liquid Critical Temperature 3480
S A K A G U C H I , Kazuyasu Receptor Interactions of Synthetic
Morphiceptin Analogs Containing Phenylalanine Homologs in
Position 4 1052
S A K A G U C H I , Keizo Estimation of the Mechanism of Fused
Aromatic Hydrocarbon Formation in Sooting Flames by Molecular Orbital Method 2427
S A K A I , Haruo Preliminary Analysis of the Electronic Absorption Spectrum of a Solute in a Biaxially-Stretched Polymer
Film 463
S A K A I , K e n i c h i Habit Modification of a Diastereomeric Salt
S A K A I , M u t s u j i Metallic Nickel-Catalyzed Reduction of Aryl
S A K A I , N a o k i Enantioface Differentiating Reduction of Keto
Acid in the Presence of 6-Deoxy-6-amino-0-cyclodextrin with
NaBH in Aqueous Media 2690
S A K A I , N o b u h i k o Mössbauer Emission Spectroscopy of Fe
S A K A I , Shizuyoshi Highly Regioselective Allylation of aEnones and Epoxides with Lithium Tetraallyllanthanoid Ate
Complex 3308
S A K A I , Takashi A Systematic Study on the Bakers' Yeast
631
S A K A I , Takaya Generation and Cycloaddition Reactions of 3Styryl-l,2-thiaphosphole 2-Sulfide
and l,5-Diphenyl-2,4pentadiene-l-thione 923
S A K A I , Yasuzo Numerical Formulation of Pigment Release
from Magnetically Anisotropic Gel Beads with Respect to the
Magnetic Moment in an Alternating Magnetic Field 3%
S A K A I , Yasuzo The Selective Separation of Organic Acids
through Liquid Membrane Containing Ferrite in the Presence
of Alternating Magnetic Field 1556
S A K A I , Yasuzo Preparation and Properties of Immobilized Glucoamylase on a Magnetically Anisotropic Carrier Comprising a
Ferromagnetic Powder Coated by Albumin 3430
S A K A I , Y ö i c h i Mössbauer Emission Spectroscopy of Fe Arising from M n in Metal and Oxides of Chromium 1
S A K A K I B A R A , M a k o t o Efficient Seienation of Quinones: Synthesis of Novel Benzo[£]naphtho[2,3-e]selenintrione and
Dibenzo[6,e]seleninone 1291
S A K A K I B A R A , Makoto Synthesis of Novel Polycyclic Selenepinone Compounds 1794
S A K A K I B A R A , T o h r u Reactivities of 2-C- and 3-C-Nitro-a- and
0-D-ery^ro-Hex-2-enopyranoside Derivatives towards Methanol
and A M I Studies upon Their Stereoselectivities 446
S A K A K I B A R A , Yasumasa Metallic Nickel-Catalyzed Reduction of Aryl Halides with Zinc Powder and Ethanol 1739
S A K A M A K I , Satoshi F Nuclear Magnetic Resonance Study
on the Kinetics of the Fluoride Exchange in Uranium(VI)
Fluoro Complex 3022
S A K A M O T O , Daisuke Synthesis of Two Types of Intercalation Compounds of K NbeOi7 with Tris(2,2'-bipyridyl) Metal
Complex Ions 322
S A K A M O T O , H i r o s h i Receptor Interactions of Synthetic Morphiceptin Analogs Containing Phenylalanine Homologs in Position 4 1052
S A K A M O T O , K a t s u j i Behaviors of α-Fluorocarbenoids Derived
from the Nucleophilic Desulfinylation of a-Chloro-a-fluoroalkyl
Sulfoxides 210
S A K A M O T O , K a t s u j i Nucleophilic Desulfinylation of a-Fluoroj3-(alkoxy and silyloxy) Sulfoxides. Effects of the 0-Oxy Substit
uents on Protonation, 1,2-Hydrogen Migration, and Nucleophile
Addition to the Fluorocarbenoid Centers 218
SAKAMOTO, Masatomi Fluorescence Quenching of Europium(III) by Heteronuclear Complex Formation with Copper(Il) or
Nickel(II) 1162
SAKAMOTO,
Masatomi
Fluorescence Quenching
in
4
57
57
57
57
19
4
S A K A T A , Yoshiteru Synthesis and Properties of PheophorbideQuinone Compounds 1533
S A K A W A K I , A k i r a Electrochemical Investigations of HighSpin (10,20-Diaryletioporphyrinato II) Iron(III) Complexes 23
S Α Κ Ι Υ Α Μ Α , H i r o s h i CD Spectral Diagnosis of Absolute Con
figuration of Tetrahedral or Pseudo-Tetrahedral Metal Com
plexes of Salicylideneiminates 606
S A K I Y A M A , H i r o s h i Template Synthesis and Structure of a
Dinuclear Lead(II) Complex of Novel Macrocycle Derived from
2,6-Diformyl-4-methylphenol and l,9-Diamino-3,7-diazanonane
1176
SAKODA, Masako Syntheses of trans- and as-3-Methoxy-4methylthio-2-piperidinethiones. Previously Proposed Struc
S A K U M A , Shogo Stereoselectivities in Catalytic Hydrogenation
of Several Branched-Chain 6-Deoxyhex-5-enopyranosides. A
Synthesis of Branched-Chain
Methyl 6-Deoxy-ß-L-hexopyranoside 292
S A K U R A G I , H i r o c h i k a Photosensitized Oxygenation of Olefins
with Zinc Tetraphenylporphine-l,4-Diazabicyclo[2.2.2]octane
Complex 1944
S A K U R A G I , H i r o c h i k a Xanthene Dye-Sensitized Electron
2887
S A K U R A G I , Masako Photosensitized Oxygenation of Olefins
with Zinc Tetraphenylporphine-l,4-Diazabicyclo[2.2.2]octane
Complex 1944
S A K U R A I , Hidetaka Piezoelectric Admittance Measurements
of Montmorillonite/Poly(vinyl alcohol) Composite Film-Coated
S A K U R A I , T a d a m i t s u Energy- and Electron-Transfer Pathways in the Triplet-Sensitized Photolysis of N-(l-Naphthoyl)-0(/>-toluoyl)-N-phenylhydroxyiamine with Substituted Benzophenones 1950
S A K U R A I , T a d a m i t s u Mechanism of the Triplet-Sensitized
Photolysis of N-(l-Naphthylsulfonyl)-iV-phenyl-0-0>-toluoyl)hydroxylamine 2789
S A K U R A I , T a d a m i t s u Modification of α-Chymotrypsin by Bromomethyl Naphthyl Ketones and Behavior of Reporter Groups
S A K U R A I , Tosio Cycloaddition Reactions of 2-Acetylamino-, 2Alkylamino-, 8-Ethylamino-, and 8-Acetylamino-l-azaazulenes
with Dimethyl Acetylenedicarboxylate 1784
S A L E H I , Peyman Tetrakis(pyridine)silver(II) Peroxodisulfate,
{Ln[Fe(CN) ] · «Η 0}* (Ln=Eu(III) or Tb(III)) 2278
S A K A M O T O , Masatomi Synthesis, Characterization, and
Properties of V 0 - L n ( I I I ) (Ln=La, Pr, Eu, Gd, Tb) Complexes
of Ν, Ν -Bis(3-carboxysalicylidene)ethylenediamine 2514
S A K A M O T O , M i k a Electrochemical Studies of Poly(mercaptohydroquinone) and Poly(mercapto-/>-benzoquinone) Films Pre
pared by Electrochemical Polymerization. V I . Electroreduction
of L-Cystine on Thiolates Fixed in the Polymer Film 594
S A K A M O T O , N o r i y u k i Solution Properties of Poly(4vinylpyridine) in Aqueous Solutions of Sulfuric Acid 3108
S A K A S H I T A , Shin-ichi The Reactions of Monoalkylthio- or
Nucleophiles: Formation of Polyfunction ally Substituted Pyr
S A K A T A , Shinji Racemization of Optically Active Aromatic NAcetylamino Acids and Asymmetric Transformation of NAcetyl-2-(4-hydroxyphenyl)glycine via Salt Formation with
S A K A T A , Shuichi Catalytic Asymmetric Synthesis of Optically
S A K A T A , Yoshihisa Catalytic Properties of Lanthanide Metals
on Silica 244
6
2
IV
3548
B U L L E T I N OF T H E C H E M I C A L
|Ag(py) |S208, a Reagent for the Oxidative Transformations
2878
S A L I N A S , Esteban Lopez Thermal Transformation of a
Layered Double Hydroxide Pillared with Decavanadate Isopolyanions 2465
S A N E F U J I , Norihiko Surface Adsorption and Micelle Formation of Dodecyltrimethylammonium Chloride and Dodecylammonium Chloride Mixture 858
S A N K H A V A S I , Wongsiri Chiral Hydantoin; A New Dienophile
for Diels-Alder Reaction 935
S A N K H A V A S I , Wongsiri Noncatalyzed Conjugate Addition
Reaction of Alkylaluminum Compounds to 5~Methylene-2,4imidazolidinedione Derivative 3195
SANO, Akihiko Synthetic Study on Peptide Antibiotic Nisin. V.
SANO, Hirotoshi Mössbauer Emission Spectroscopy of Fe
SANO, Tsuneji Growth Process of ZSM-5 Zeolite Film 146
SANO, Yukari Intramolecular [2+2] Photocycloaddition. 14.
Cycloreversion of Cyclophanes Possessing a Cyclobutane Ring
at Their Tether 618
S A R A N , Nil Raghaw Spectrophotometric Determination of
S A R K A R , Uttam Kumar Surface-Enhanced Raman Spectra of
Isomeric Picolines Adsorbed on Silver Sols 1697
S A S A D A , Yoshihiro "Syn-Effect" in the Conversion of (£)Vinylic Sulfones to the Corresponding Allylic Sulfones 75
S A S A K I , Hideyuki Solvent Effects on the Formation and Decay
of Ionic Intermediates for the Photoreduction of Anthraquinone
by Triethylamine in Ethanol, Toluene, and Acetonitrile at
Room Temperature 3141
S A S A K I , Hiroshi Thermostable Intramolecular Coupling Products from Some />-Xylylenebis(anthrylcarboxylate)s and the
Relationship between Their Thermal Stability and Relative
S A S A K I , K e n Metallic Nickel-Catalyzed Reduction of Aryl
S A S A K I , Kenryo Enzymatic Kinetic Resolution of [4](1,2)Ferrocenophane Derivatives 2784
S A S A K I , Makoto Effects of Pd Dispersion on the Catalytic
S A S A K I , Masako Thermochromism of 5,10,15,20-Tetraarylporphyrins at Low Temperature 3358
S A S A K I , Muneo Thermodynamics of Triple-Helix and DoubleHelix Formations by Octamers of Deoxyriboadenylic and Deoxyribothymidylic Acids 535
S A S A K I , Shouich Oxidative Coupling of Methane over Various
Barium Salts Mixed with CaO: The Relation with Their Surface Basicities 2251
S A S A K I , Tomoko Binuclear Nickel(II) Complexes of Schiff
Bases Derived from Salicylaldehydes and l,w-Diamino-w'hydroxyalkanes (n,n — 3,2; 4,2; and 5,3) Having an Endogenous
S A S A K I , Yoichi Magnetic Properties of Oxygen Centered
Trinuclear Ruthenium(III) and Rhodium(III) Complexes 198
S A S A K I , Yoichi Kinetic Studies on the Terminal Pyridine
S A S A K I , Yoichi X-Ray Structure, Ligand Substitution, and
Other Properties of Trinuclear Ruthenium Complex, [RU3(M3OXM-CeHsCOOMpy^FFe) (py=pyridine), and X-Ray Structure
of Dinuclear Ruthenium Complex, [RU2(M-C6H C00) CI] 1585
S A S A K I , Yoshiaki Micellar Effect on the Formation Rate of
Ni(II) and Co(II) Complexes with 8-Quinolinol and Its 5Alkyloxymethyl-8-quinolinol Derivatives in a Nonionic Surfactant Micellar System 286
S A S A K I , Yoshinori Kinetics and Mechanism of the High
4
57
57
2
5
4
SOCIETY OF JAPAN
[Vol.
65, No. 12
Temperature Selenidization of Cobalt 329
SASHIDA, Yutaka Tigogenin Hexasaccharides from Camassia
cuskkii. Structural Elucidation by Modern NMR Techniques
458
SASHIDA, Yutaka New Cholestane Bisdesmosides from the
SASHIWA, Hitoshi Transformation of Propargylic Alcohols
into Enones 2594
SASHIWA, Hitoshi Partial Reduction of Dithioacetals with
S A T A K E , Iwao The Binding Characteristics of Sodium Decyl
Sulfate to Poly(L-ornithine) with 1-Alkanesulfonate Counter
Ions 1146
S A T A K E , Kyosuke The Base-Catalyzed H/D-Exchange of Anisole Moiety of Ruthenium Complex in Cooperation with
S A T H I Y A N A R A Y A N A N , Kulathu Iyer Kinetics and Mecha
nism of Oxidation of Ethyl Phenylthioacetates by BromamineB J096
SATO, Gen P. Oxidative Dehydrogenation of Ethylenediamine
Coordinated to Ruthenium with Hexafluoroacetylacetonate,
Induced by Electrochemical Oxidation of Ruthenium(II) to
Ruthenium(III) 876
SATO, Hiroshi Studies on Nickel-Containing Ziegler-Type Catalysts. I . New Catalysts for High-ds-l,4-polybutadiene 1299
SATO, Hiroshi Studies on Nickel-Containing Ziegler-Type Catalysts. I I . Low Molecular Weight (Liquid) Poly(diene)s with 1,4Microstructure 1307
SATO, Kazuo 13/3-Hydroxylation of Milbemycins by Selenium
Dioxide 3300
SATO, Ken-ichi Stereoselectivities in Catalytic Hydrogenation
of Several Branched-Chain 6-Deoxyhex-5-enopyranosides. A
Synthesis of Branched-Chain Methyl 6-Deoxy-jS-L-hexopyranoside 292
SATO, Kyoko Synthesis and Chemiluminescence Properties of
6-(4-Methoxyphenyl)-2-methylimidazo[l,2-a]pyrazin-3(7//)-one
and
2-Methyl-6-(2-naphthyl)imidazo[l,2-ö]pyrazin-3(7//)-one
2475
SATO, Mamoru Crystal and Molecular Structure of 3,6Dioxograyanotoxin I 2836
SATO, Mamoru Crystal and Molecular Structure of 1,5-Secograyanotoxin-1,3,6,14,16-pentaacetate 3482
SATO, Naohiko Synthesis of Soluble Poly(thio-2,6-dimethyl-l,4phenylene) by Oxidative
Polymerization of Bis(3,5dimethylphenyl) Disulfide 2029
SATO, Ryu Reaction of Cyclic Polysulfides. Oxidation of 6b,9aDihydroacenaphtho[l,2-i/][l,2,3]trithiole 1188
SATO, Satoshi Vapor-Phase Beckmann Rearrangement of Cyclohexanone Oxime over an HY Zeolite Catalyst Calcined at High
Temperature 1486
SATO, Shingo Synthesis of Model Compounds of Safflomin C
452
SATO, Shingo Synthesis of Syzygiol; A Skin-Tumor Promotion
Inhibitor 2552
SATO, Takao The Crystal Structures of Cyanide Metmyoglobins Reconstituted with Iron(III) Complexes of Porphyrin,
SATO, Takashi Semi-preparative Purification and Crystallization of Synthetic Analogs of Heat-stable Enterotoxins of Enterotoxigenic Escherichia coli 938
SATO, Takeo Electrochemical Investigations of High-Spin
SATO, Yasuhiro Perfluoroalkylation of Olefins by Electrooxidation of Perfluoroalkanoic Acids: Relations between ProductSelectivity and Current Density and Structures of Olefins
1976
SATOH, Akira Synthesis and Some Reactions of 2-Amino-lazaazulene-3-carbaldehyde 340
December, 19921
3549
AUTHOR INDEX
S A T O H , Eishi Titanium(III) Chloride Mediated Reduction of
Dicyanoalkenes 3068
S A T O H , Masahiro Temperature and Pressure Effects on the
Reversible Reaction of a Parent Phenol (GH) Corresponding to
Galvinoxyl with Aliphatic Amines 2437
S A T O H , Shin-ichi Reaction of Cyclic Polysulfides. Oxidation
of 6b,9a-Dihydroacenaphtho[l,2-</l[l,2,3]trithiole 1188
S A T O H , Tsuyoshi 1-Haloalkyl Aryl Sulfoxides as Useful
Agents in Synthesis of α-Halo Ketones: A New Synthesis of aHalo Ketones, α-Halo α,β-Unsaturated Ketones, and α-Halo
Cross Dienones from Aldehydes 2800
S A T O H , Tsuyoshi A Novel Synthesis including Asymmetric
Synthesis of α,β-Unsaturated γ-Hydroxy Carbonyl Compounds
from Enones with Carbon Homologation 2966
S A T Y , A b d El Kader Cyclic Voltammetric Behavior and Some
Surface Characteristics of the Lead Electrode in Aqueous Nal
Solutions 1608
S A W A D A , K i y o s h i The Solvent Extraction and Dissociation of
S A W A D A , Masami 1:1 Adduct Ion Formation of Simple Car
Modifications 1275
S A W A K I , Yasuhiko Radical Intermediates in the Thermal
Decomposition of l,l-Bis(/-butyldioxy)cyclohexane 664
S A W A N T , A r u n D. Extraction and Spectrophotometric Deter
mination of Palladium with Pyridine-2-acetaldehyde Salicyloylhydrazone 1622
S A W A R A G I , M i h o k o Thermodynamic Studies on the Complex
ation of Alkaline-Earth Metal Ions with o-PhenylenediamineA/.MN'.iV'-tetraacetate in Aqueous Solutions 1722
SAY Α Μ Α , Kazuhiro Selective Hydrogenation of Carbon Diox
ide to Methanol on Cu-ZnO/Si02 Catalysts Prepared by Alkoxide Method 2520
S A Z A K I , A k i r a Ring-Splitting Reaction of 2,2-Diarylthietane by
Electron-Transfer
Photosensitization
of
9,10-Dicyanoanthracene 1472
SCHEER, Hugo Epimerization of Chlorophyll Derivatives. V.
Effects of the Central Magnesium and Ring Substituents on the
Epimerization of Chlorophyll Derivatives 3080
SCHEER, Hugo Pheophytinization of Eight Chlorophyll Deriva
tives in Aqueous Acetone 3212
SEGAWA, K a t s u n o r i Qualitative Triplet Potential Energy
Curves of Arylethylenes along the Double Bond Twisting
1463
S E K I , T a k a h i r o Photochromism of Hemithioindigo Derivatives.
I. Preparation and Photochromic Properties in Organic Sol
vents 649
S E K I , T a k a h i r o Photochromism of Hemithioindigo Derivatives.
I I . Photochromic Behaviors in Bilayer Membranes and Related
Systems 657
S E K I , T o s h i h i k o Determination of Aluminium in Natural
S E R I N E , A k i k o The Crystal Water Affecting the E - A
S E R I N E , Tatsuya Rate of Back-Extraction of Tris(acetylacetonato)- and Tris(trifluoroacetylacetonato)chromium(III)
Solutions 415
S E K I N E , Tatsuya Solvent Extraction of Europium(III) with
Benzoylacetone and Benzoyltrifluoroacetone into Carbon
Tetrachloride in the Absence and Presence of Tetrabutylammo
nium Ions 1910
S E K I N E , Tatsuya Solvent Extraction and Association of Nitrophenols with Trioctylphosphine Oxide in Cyclöhexane 2534
S E K I N E , Tatsuya Solvent Extraction of Anionic Chelate Complexes of Lanthanum(III), Europium(III), Lutetium(III), Scandium(III), and Indium(III) with 2-Thenoyltrifluoroacetone as Ion2
g
4
2 g
Pairs with Tetrabutylammonium Ions 2729
S E K I Z A K I , H a r u o Cobalt(III) Complexes with Quadridentate
Ligands. XI. The Preparation and Properties of os-a-Isomer of
SEMBA, F u m i h i k o Behaviors of α-Fluorocarbenoids Derived
from the Nucleophilic Desulfinylation of a-Chloro-a-fluoroalkyl
Sulfoxides 210
SENDA, H i t o s h i "Syn-Effect" in the Conversion of (£)-Vinylic
SERA, A k i r a Titanium(III) Chloride Mediated Reduction of
Dicyanoalkenes 3068
SETO, T s u y o s h i Syntheses of Azobenzene Derivatives Having
SETSUNE, J u n - i c h i r o The Spectroscopic Properties and Organometallic Reactivities of Cobalt(III) Porphyrins 639
S H A M S I P U R , Mojtaba Spectrophotometric Determination of
Trace Amounts of Sulfide Ion Based on Its Catalytic Reduction
of Toluidine Blue 2770
S H A M S I P U R , Mojtaba Highly Selective Membrane Transport
of Z n Ion by a Cooperative Carrier Composed of 1,10-Diaza18-crown-6 and Palmitic Acid 2779
S H A R M A , N i d h i Kinetics and Mechanism of Osmium(Vni) Cat
alyzed Oxidation of Uric Acid with iV-Chloro-/>-toluenesulfonamide (Chloramine-T) in Alkaline Medium 1125
S H A R M A , P r e m D u t t Kinetics and Mechanism of Osmium(VIII) Catalyzed Oxidation of Uric Acid with N-Chloro-/>toluenesulfonamide (Chloramine-T) in Alkaline Medium 1125
S H A R M A , S. D. Studies on Fused ß-Lactams: Synthesis of l-Aza
Analogs of Cephem 2246
SHI, Xiaolan Abnormal Diels-Alder Reaction of 5-Alkoxyoxazoles with Tetracyanoethylene and X-Ray Crystal Structure of an Adduct 1771
SHI, Xiaolan Abnormal Diels-Alder Reaction of Oxazoles with 4Phenyl-3//-l,2,4-triazole-3,5(4#)-dione and Diethyl Azodicarboxylate, and X-Ray Crystal Structure of an Adduct 2998
SHI, Xiaolan Abnormal Diels-Alder Reaction of 5-Alkoxythiazoles w i t h Highly Reactive Dienophiles; 4-Phenyl-3#-1,2,4triazole-3,5(4//)-dione, Diethyl Azodicarboxylate, and Diethyl
Oxomalonate 3315
SHIAO, M i n g - T a n g Chiral Stationary Phases Derived from ( - ) anti Head-to-Head Coumarin Dimer: Preparation, Characterization, and Chiral Recognition Ability 3423
S H I B A , T e t s u o Synthetic Study on Peptide Antibiotic Nisin. V.
S H I B A G A K I , M a k o t o Reduction of Dicarboxylic Acid Anhydride with 2-Propanol over Hydrous Zirconium Oxide 262
S H I B A G A K I , M a k o t o Regioselective Hydrogenation of Unsaturated Compounds Using Platinum-Zeolite Coupled with Organosilicon Alkoxide by CVD Method 1240
S H I B A T A , A k i h i r o Triphenylselenonium Salts as Effective
Phase-Transfer Catalysts 2555
S H I B A T A , K a t s u y o s h i Synthesis and Characterization of
Dyes 71
S H I B A T A , K a t s u y o s h i Stereoselective Decomposition of Pyrazolines Containing Trifluoromethyl Groups 1999
S H I B A T A , K o i c h i Preparation of 1,4-Dienes from 2-(2Hydroxyalkylseleno)benzothiazoles by the Reaction Involving
Se->0 Azaaromatic Ring Rearrangement 3163
S H I B A T A , Masao Effect of γ-Ray Irradiation on the Recoil
Reaction 735
S H I B A T A , Masayasu Pressure Effects on the Aquation Reac
tions of Tris(2,2'-bipyridine)chromium(III) Ion and Tris(l,10phenanthroline)chromium(III) Ion 3253
S H I B A T A , T a k a n o r i Acid-Promoted Reactions of Schiff's Bases
2+
[Vol. 65, No. 12
3550
Sulfides 1392
S H I B A T A , Takanori Reactions of 1,2-Propadienyl Sulfides with
Aldehydes and Acetais Catalyzed by BF · OEt 2825
S H I B A T A , Yasuhiro Syntheses of Azobenzene Derivatives
Having Fluoroalkyl Chain and Their Monomolecular Film Formation at the Air/Water Interface 2141
S H I B U Y A , Isao Reaction of 1,3-Oxathiolium Salts with Three
Types of Ring Expansion Reagents on a Nitrogen Atom 668
S H I B U Y A , Isao Preparation of 1,4,2-Dithiazolium Salts 920
S H I B U Y A , Kazuhiko Photocyclization of Diphenylamine Studied by Time-Resolved Thermal Lensing. Heat of Reaction,
Energetics, and Reactivity of Intermediates 1084
S H I B U Y A , Kazuhiko Photodissociation of Highly-Excited Triplet State of Benzophenone Studied by a Time-Resolved Thermal Lensing Technique 1349
SHICHI, Sonoko Dehydrative Glycosylation Using Heptabenzyl
S H I G E H A R A , Kiyotaka Preparation of Bis(phthalocyaninato)lutetium with Various Substituents and Their Electrochemical
Properties 250
S H I G E M A S A , Yoshihiro Transformation of Propargylic Alcohols into Enones 2594
S H I G E M A S A , Yoshihiro Partial Reduction of Dithioacetals
with Phosphorus Reagents 2842
S H I G E M A T S U , Shinji Thiolate-Bridged Binuclear Nickel(II)
Complexes with a Mixed-Spin State 512
S H I G E M U R A , Masao Correlation Analysis of the ptf Values of
SHIMA, Chiemi Magnetic Properties of Cobalt(ü) and Nickel(II)
Benzoate Adducts with Quinoline Analogues 1982
SHIMA, Kensuke Ring-Splitting Reaction of 2,2-Diarylthietane
by Electron-Transfer Photosensitization of 9,10-Dicyanoanthracene 1472
S H I M A D A , Hiroko The Raman Active Intra- and Intermolecular Vibrations of [Ήιο]- and [Ήιο] /^-Xylenes 280
S H I M A D A , Kazuaki A Convenient Preparation of 2,4,6Trisubstituted 1,3,5-Triselenanes by Treating Aldehydes or
Their Acetais with 2,2,4,4,6,6-Hexamethyl-l,3,5-triselena-2,4,6tristannacyclohexane in the Presence of BF · OEt and AlCb
2848
S H I M A D A , Ryoichi The Raman Active Intra- and Intermolecular Vibrations of [Ήιο]- and [Ήιο] /^-Xylenes 280
S H I M A D A , Toyoshi Footprint Catalysis. IV. Structural Effects
of Templates on Catalytic Behavior of Imprinted Footprint
Cavities 954
SHIMAO, Ichiro Synthesis and Properties of DiaminoSubstituted Dipyrido [3,2-a: 2',3'-c]phenazine 1006
SHIMAO, Ichiro Oxidative Chlorination of 1,10-Phenanthroline
and Its Derivatives by Phosphorus Pentachloride in Phosphoryl
Chloride 2007
S H I M A S A K I , Choichiro Thermal Behavior and Mass Spectra
Acid 1993
S H I M B O , Kuniaki Synthetic Study on Peptide Antibiotic Nisin.
S H I M I Z U , Koichi Dehydrative Glycosylation Using Heptaben
zyl Derivatives of Glucobioses and Lactose 3257
S H I M I Z U , Kunio Oxidative Dehydrogenation of Ethylenediamine Coordinated to Ruthenium with Hexafluoroacetylacetonate,
Induced by Electrochemical Oxidation of Ruthenium(II) to
Ruthenium(III) 876
S H I M I Z U , Kunio Photochemical Reduction of (r? -Cyclopentadienyl)(l ,2-disubstituted
1,2-ethylenedichalcogenolato)cobalt(III) and (q -Cyclopentadienyl)(l,2-benzenedithiolato)cobalt(III) Complexes in the Presence of Triethanolamine
1047
S H I M I Z U , Masao Synthesis of Alkyl Substituted pBenzoquinones from the Corresponding Phenols Using Molecu
lar Oxygen Catalyzed by Copper(II) Chloride-Amine Hydro
3
2
a
3
2
5
5
chloride Systems 1522
S H I M I Z U , Nobujiro Silicon Effects. IV. Solvolysis of 1(Pentamethyldisilanyl)-2-phenylcyclopropyl Bromide in 2,2,2Trifluoroethanol via a(CQ-Assisted and -Unassisted Ionization
Processes 959
S H I M I Z U , Nobujiro A Novel Configuration-Controlled Ster
Silyl Ethers 971
S H I M I Z U , Noriyo Mechanism on the Efficient Formation of
Singlet Oxygen by Energy Transfer from Excited Singlet and
Triplet States of Aromatic Hydrocarbons 897
S H I M I Z U , Tamaki Diels-Alder Reaction of (l-Methylene-2propenyl)cobaloxime,
l-Methylene-2-propenyl-bis(dimethylglyoximato)pyridine-cobalt(III) 1252
S H I M I Z U , Yasuko Kinetic Studies of the Incorporation of the
SHIMO, Tetsuro MO Analysis of Photocycloaddition Reactions
of 2-Pyrones 354
S H I M O H I G A S H I , Yasuyuki Receptor Interactions of Syn
thetic Morphiceptin Analogs Containing Phenylalanine Homologs in Position 4 1052
S H I M O H I G A S H I , Yasuyuki Refolding of Trimeresurus flavoviridis Phospholipases A 2655
S H I M O K A W A , Shigezo Diffusion Coefficient of Benzene
around the Gas-Liquid Critical Temperature 3480
S H I M O M U R A , Kin'ya Selective Hydrogenation of Carbon
Dioxide to Methanol on Cu-ZnO/Si0 Catalysts Prepared by
Alkoxide Method 2520
SHIMONISHI, Yasutsugu Semi-preparative Purification and
Crystallization of Synthetic Analogs of Heat-stable Enterotox
ins of Enterotoxigenic Escherichia coli 938
S H I M O Y A M A , Masahide Oxidation of Alcohols with Peracetic
Acid in Ethyl Acetate in the Presence of Sodium Bromide 703
S H I N D O , Hisakazu Preparation of Niobates of Rhodium and
S H I N D O , Mitsuno Synthesis and Antimicrobial Activity of Bactenecin and Its Analogs 615
S H I N D O , Naoaki Formation of AOT Reversed Micelles and W/
Ο Microemulsions 2715
S H I N K A I , Seiji Solvent Extraction of Transition Metal Cations
by Calixarene-Based Cyclic Ligands 471
S H I N K A I , Seiji Re-evaluation of the Acid Dissociation Con
S H I N K A I , Seiji Intercalation of a Trimethylammoniomethylated Calix[4]arene by Cu(II)-Montmorillonite 2510
SHINODA, Kiyonori Vapor Phase Carbonylation of Organic
Halo Compounds 289
S H I N O H A R A , Hisanori One-Color and Two-Color ResonanceEnhanced Two-Photon Ionization Studies of Benzene: Sudden
nel Region 234
S H I N O Z A K I , Kiyoshi Mutual Separation Characteristics and
S H I N T A N I , Y u k i Thermodynamics of Triple-Helix and DoubleHelix Formations by Octamers of Deoxyriboadenylic and Deoxyribothymidylic Acids 535
SHIOJI, Shuhei Surface Alkoxylation of Silicas by Mild Reac
tions with Alcohols 728
S H I O T A , Kenji A Chiral Synthesis of D-wyo-Inositol 1Phosphate Starting from L-Quebrachitol 366
S H I O Z U K A , Michito Synthesis and Magnetisms of Oxamidoand Oxamato-Bridged Binuclear Nickel(II)-Copper(II) Com
plexes 1988
S H I R A I , Kozo A New Synthesis of 5-Substituted 3-Methyl-22
2
December, 1992]
AUTHOR INDEX
phenylthio-2 penten-5-olides 2794
S H I R A I S H I , Kohei Terminal-Terminal Types of Liquid Crys
tals. I I I . Thermal and Electrooptical Behavior of Liquid Crys
talline Bis[urethane]s 2259
SHIRAISHI,
Shinsaku Ru(6,6'-Diamino-2,2'-bipyridine)3 :
Effect of Interligand Steric Strain on the Spectroscopic, Photo
chemical, and Electrochemical Properties of the Complexes
1220
S H I R A I S H I , Shinsaku The Reactions of Nitrile Oxide-Quinone
S H I R A I S H I , Shinsaku The Reactions of Nitrile Oxide-Quinone
Cycloadducts.
I I . The
Reactions of 2,5-Di-i-butyl-/>benzoquinone with Nitrile Oxides: 1:2 Cycloaddition and Base
S H I R A I W A , Tadashi Optical Resolution by Replacing Crystal
lization of (/?S)-4-Thiazolidinecarboxylic Acid with L-Amino
Acids as Cosolute 267
S H I R A I W A , Tadashi Racemization of Optically Active Aro
matic yV-Acetylamino Acids and Asymmetric Transformation
of N-Acetyl-2-(4-hydroxyphenyl)glycine via Salt Formation
with Optically Active a-Methylbenzylamine 965
SHIRO, Motoo X-Ray Crystal Structure of Silver(I) Complex
with l,3-Bis(8-quinolylthio)propane 2275
S H I R O , Motoo Equilibrium and X-Ray Structural Studies on
Dimeric and Trimeric Species Formed in the Extraction of
Nickel(II) with 2-Methyl-8-quinolinol 3362
SHIROTA,
Yasuhiko A Rechargeable Battery
Using
Electrochemically-Doped Poly(3-vinylperylene) as an Electrode
Material 1062
S H I R O T A N I , Ichimin Absorption Spectra and Electrical Resis
tivities of Bis(l,2-dionedioximato)nickel(II) Complexes at High
Pressures 1078
SHIZUMA, Motohiro 1:1 Adduct Ion Formation of Simple
trometry. Comparison of O-Acetyl, N-Butyl, and 0-Methyl
Modifications 1275
SHUNDO, Ryushi Novel Reduction of Carboxylic Acids and
Hydroboration of Olefins by Electrolysis of Sodium Borohydride 530
S I N G H , Dharam Studies on w-CdSe/Ti Semiconductor Septum
Based Photoelectrochemical Solar Cell in Regard to the Influ
ence of Structural and Compositional Characteristics of the
Semiconductor Electrode 1072
SINGH, Vishwakarma Attempted Transformation of 2,3,5,6Tetrachloro-4,4-dimethoxypentacyclo[5.4.0.0 ' .0 .0 ' ]undecane-8,ll-dione toward Pentaprismane Retaining Chloro
Group 2312
SINHA, Sunetra H. Extraction and Spectrophotometric Deter
mination of Palladium with Pyridine-2-acetaldehyde Salicyloylhydrazone 1622
SIPOS, Pal Utilization of Enzymatic Digestion for the Study of
the Macromolecular Effect in Complexation Processes. Proton
ation and Copper Coordination Equilibria of Hyaluronate and
Its Fragments 2211
SOAI, Kenso Catalytic Asymmetric Synthesis of Optically
S O D E S A W A , Toshiaki Vapor-Phase Beckmann Rearrange
ment of Cyclohexanone Oxime over an HY Zeolite Catalyst
Calcined at High Temperature 1486
SOHMIYA, Hajime Selectivity in Catalytic Dehydrogenation
with Active Manganese Dioxide 1149
SOHRIN, Yoshiki Solvent Extraction of Divalent Metals as
S O M E K A W A , Kenichi MO Analysis of Photocycloaddition
Reactions of 2-Pyrones 354
SONDHI, Sham M. Synthesis of a Series of Acodazole and
2+
2
6
3,10
5
9
3551
579
S O N E , Tyo C NMR Study of Chloro- and Methylthiophenium
Ions 3228
SONODA, Yoriko Preparation of Poly(2,5-diheptyl-l,4-phenylenevinylene) by Sulfonium Salt Pyrolysis 853
SONODA, Yoshitaka The Raman Active Intra- and Intermolecular Vibrations of [Ήιο]- and [ Hi ] />-Xylenes 280
S O T O M A T S U , Tomoko Analysis of Ortho Effects with a Steric
Parameter Defined by the Acidic Hydrolysis Rate of OrthoSubstituted Benzamides 2343
S O T O M A T S U , Tomoko Correlation Analysis of the p/£ Values
of Mono- and Di-ortho-Substituted Benzoic Acids 3157
S R I M A N N A R A Y A N A , Gutety DDQ Oxidation of 6- or 8-Allyl7-hydroxycoumarins. A New Synthesis of Benzodipyrandiones
and Furobenzopyranones 1191
S R I V A S T A V A , Madhu Rani Synthetic and Spectroscopic Stud
ies of Some Lanthanoid Metal Complexes of 2-Acetylpyridine
Nicotinoylhydrazone 2766
S R I V A S T A V A , Onkar Nath Studies on w-CdSe/Ti Semicon
ductor Septum Based Photoelectrochemical Solar Cell in
Regard to the Influence of Structural and Compositional Char
acteristics of the Semiconductor Electrode 1072
S T A M M E R , Charles H. The Resolution and Absolute Configu
ration of 2,3-Methanopyroglutamic Acid, 3-Oxo-2-azabicyclo[3,l,0Jhexane-l-carboxylic Acid 2668
S T E W A R D , Omar W. Crystal Structures and Magnetic Proper
ties of Binuclear Copper(II) Complexes with Alkoxo and Benzoato or Silanecarboxylato Bridges 2739
S T R E L K O , Vladimir Vasiljevich On the Sorption of </-Metal
Ions on Mixed Phosphates of the 4-th Group Elements 1617
S T R U C K , Andreas Epimerization of Chlorophyll Derivatives.
V. Effects of the Central Magnesium and Ring Substituents on
the Epimerization of Chlorophyll Derivatives 3080
S T R U C K , Andreas Pheophytinization of Eight Chlorophyll
S U , Huiwen A New Synthesis of 5-Substituted 3-Methyl-2phenylthio-2-penten-5-olides 2794
S U E I S H I , Yoshimi Mercury(6 Pi)-Photosensitized Decomposi
tion of Tetramethyllead 1710
S U E I S H I , Yoshimi Thermal and Infrared Multiphoton Decom
positions of y-Butyrolactone in the Vapor Phase .3112
S U E I S H I , Yoshimi ESR Studies at High-Pressure. IV. SpinExchange Reactions of Various Types of Nitroxides in Some
S U E O K A , Osamu Correlation between Positron Annihilation
S U G A , Hiroyuki Abnormal Diels-Alder Reaction of 5Alkoxyoxazoles with Tetracyanoethylene and X-Ray Crystal
S U G A , Hiroyuki Abnormal Diels-Alder Reaction of Oxazoles
with 4-Phenyl-3//-l,2,4-triazole-3,5(4 f/)-dione and Diethyl Azodicarboxylate, and X-Ray Crystal Structure of an Adduct
2998
S U G A , Hiroyuki Abnormal Diels-Alder Reaction of 5-Alkoxythiazoles with Highly Reactive Dienophiles; 4-Phenyl-3/i-l,2,4triazole-3,5(4#)-dione, Diethyl Azodicarboxylate, and Diethyl
Oxomalonate 3315
S U G A W A R A , Tadashi Crystal Structure of (ImH)[Ni(dmit) ]
with Intercolumnar Interaction through an Imidazolium Coun
ter Ion 2528
S U G A Y A , Toshiaki Electrochemical Studies of Poly(mercaptohydroquinone) and Poly(mercapto-/>-benzoquinone) Films Pre
pared by Electrochemical Polymerization. V I . Electroreduction
S U G I H A R A , Yasushi Radical Intermediates in the Thermal
Decomposition of l,l-Bis(f-butyldioxy)cyclohexane 664
S U G I H A R A , Yoshikazu [147t]Electrocyclization Followed by
Preferential [l,9]Hydrogen Migration in the Thermolysis of 113
2
0
3
J
2
2
3352
Formyl-4-[(2,4,6-cycloheptatrienyl)(phenylsulfinyl)methyl|azulene 3198
S U G I M O R I , Akira Photochemical Reduction of (ij -Cyclopentadienyl)(l ,2-disubstituted
1,2-ethylenedichalcogenolato)cobalt(III) and (i7 -CyclopentadienylXl,2-benzenedithiolato)cobalt(III) Complexes in the Presence of Triethanolamine
1047
S U G I M O R I , Tamotsu Copper(II)-Thioether Bondings in Multidentate N,S-Donor Ligand Complexes. Structural Dependence
of the Chemical Properties of the Copper(II) Complexes of 1,5Bis(2-pyridylmethylamino)-3-thiapentane and 2,6-Bis(2,6-dithiaheptyl)pyridine 786
S U G I M O T O , Eisuke Electrical Properties and Sinterability for
Lithium Germanium Phosphate U\+ M Ge2-x(P04h, M=A1,
S U G I M O T O , Jiro Triethylborane Induced Radical Reaction of
Ketene Silyl Acetais with Polyhalomethanes 1513
S U G I M O T O , Naoki Thermodynamics of Triple-Helix and
Double-Helix Formations by Octamers of Deoxyriboadenylic
and Deoxyribothymidylic Acids 535
S U G I M O T O , Tatsuya Electroreductive Deoxygenation of
S U G I M U R A , Hideyuki A New Synthetic Method for α-Οχο-β,γunsaturated Esters 3209
SUGIURA,
Makiko
Inclusion
Mode of 8-Anilino-lnaphthalenesulfonate (ANS) in the ANS-/3-Cyclodextrin Com
plex 2869
S U G I U R A , Makoto Thermotropic Liquid Crystals Based on
Properties 1939
S U G I Y A M A , Kazuo Terminal-Terminal Types of Liquid Crys
tals. III. Thermal and Electrooptical Behavior of Liquid Crys
talline Bis[urethane]s 2259
S U G I Y A M A , Shigeru Catalytic Conversion of Diethyl Tartrate
2083
S U I S H U , Takaaki MO Analysis of Photocycloaddition Reac
tions of 2-Pyrones 354
S U K E G A W A , Makoto Habit Modification of a Diastereomeric
Salt with an Additive in Optical Resolution 1747
S U M I T O M O , Hiroshi Crystal Structures of ^-Benzoyl Deriva
tives of 8-Oxa-6-azabicyclo[3.2.1]octan-7-one,
e-Caprolactam
SUMITOMO, Hiroshi Crystal Structure of N-Cinnamoyl-8-oxa6-azabicyclo[3.2. l]octan-7-one 1138
S U M I Y O S H I , T a k a s h i Reactivity of the Transient UV-Band
Produced in Irradiated Liquid Carbon Tetrachloride with Var
ious Alcohols 1038
S U N A M O T O , Junzo A Water-Soluble Spin Probe Newly De
veloped for Liposomal Studies 1041
S U N A M O T O , Junzo Effect of Artificial Boundary Lipid on the
Membrane Dynamics of Human Glycophorin-Containing Lipo
some 3331
S U Y A M A , Shuji Radical Intermediates in the Thermal Decom
position of l,l-Bis(f-butyldioxy)cyclohexane 664
S U Y A M A , Shuji Simultaneous Generation of ί-BuO· and tBuOO* from the Decomposition of 2,2-Bis(f-butyldioxy)propane.
A New Synthetic Method for Introducing a t-BuOO Group into
Organic Molecules 2063
S U Z U K I , Akira Organic Synthesis Using Haloboration Reac
tion. XXI. A Synthesis of Prostaglandin Bi Methyl Ester by the
S U Z U K I , A k i r a The Palladium-Catalyzed Cross-Coupling Reac
tion of Enol Acetates of α-Bromo Ketones with 1-Alkenyl-,
5
5
x
x
[Vol. 65, No. 12
S U Z U K I , H i d e k i The Reactions of Monoalkylthio- or
SUZUKI, Hiroshi A Novel Ring Transformation of 3a,5,6aTriaryl-Sâ-dihydro^/Z-furoiS^-^JpyrroleÂoa/^-diones into
S U Z U K I , Hitomi Behaviors of α-Fluorocarbenoids Derived from
the Nucleophilic Desulfinylation of α-Chloro-a-fluoroalkyl Sul
foxides 210
S U Z U K I , Hitomi Nucleophilic Desulfinylation of a-Fluoro-0(alkoxy and silyloxy) Sulfoxides. Effects of the ß-Oxy Substituents on Protonation, 1,2-Hydrogen Migration, and Nucleophile
SUZUKI, Hitomi Sodium Tellurite as a Mild and Selective
Oxidizing Agent for Thiols: Its Use in the One-Pot Synthesis of
Unsymmetrical Disulfides 626
S U Z U K I , Hitomi Synthesis and Reactions of Some Crowded
Triorganylbismuthines 3504
S U Z U K I , Kaoru Pressure-Dependent Intensity Anomalies in the
B v+~<n Perturbed Rotational Lines of the CN (Β*ϊ -Χ*ϊ+)
1414 Band 481
S U Z U K I , Kazunaga Absorption Spectra and Electrical Resistiv
ities of Bis(l,2-dionedioximato)nickel(II) Complexes at High
Pressures 1078
S U Z U K I , Kazunori Theoretical Study of Aluminum-Sodium
A l „ N a ( * = l - 4 ) 2578
S U Z U K I , Keiko Deuterium Isotope Effects on Aromatic C-13
NMR Chemical Shifts. IV. Can the Isotope Shifts Be Correlated
with Bond Lengths? 2894
SUZUKI, Masakazu Photochromic Properties of 2-Hydroxychalcones in Solution and Polymers 39
S U Z U K I , Minoru Thermal and Infrared Multiphoton Decompo
sitions of y-Butyrolactone in the Vapor Phase 3112
SUZUKI, Nobuo Tautomerization and Dissociation Equilibria
of ß-Diketones in Microemulsions 170
S U Z U K I , Nobutaka A Convenient Synthetic Method of 2Cyano-6-methoxybenzothiazole, —A Key Intermediate for the
Synthesis of Firefly Luciferin 392
S U Z U K I , Shinnichiro Preparation and Properties of Mixed
Ligand Dinuclear Copper(II) Complexes Bridged by Deprotonated Oximato and Hydroxo or Acetato 3189
S U Z U K I , Sonoe Dehydrative Glycosylation Using Heptabenzyl
S U Z U K I , Tadashi Photocyclization of Diphenylamine Studied
by Time-Resolved Thermal Lensing. Heat of Reaction, Energetics, and Reactivity of Intermediates 1084
S U Z U K I , Tadashi Photodissociation of Highly-Excited Triplet
State of Benzophenone Studied by a Time-Resolved Thermal
S U Z U K I , Takanori Crystal Structures of Metallic and Insulating Molecular Complexes between Naphthaceno[5,6-ci/: 11,12c'önbis[l,2]diselenole and 4,8-Bis(dicyanomethylene)-4i/,8#benzo[l,2-c: 4,5-c']bis[l,2,5]thiadiazole: (TSeN)(BTDA-TCNQ)
and (TSeNXBTDA-TCNQ)(C H Cl) 3350
SUZUKI, Takayoshi Preparation and Characterization of Palladium(I) and Platinum(I) Dinuclear Complexes Bridged by 2(Dimethylphosphino)pyridine 1016
S U Z U K I , Takayoshi Molecular Structures of
HT-[MMCh(ßMe Ppy) ] (MM'=Pd , PdPt, and Pt ; Me Ppy=2-(Dimethylphosphino)pyridine) and //T-[Pd Cl ( -Ph Ppy) ](Ph Ppy=2(Diphenylphosphino)pyridine) 1817
S U Z U K I , Toshihiro Absorption Spectra and Electrical Resistivities of Bis(l,2-dionedioximato)nickel(H) Complexes at High
Pressures 1078
S U Z U K I , Toshio The Solvent Extraction and Dissociation of the
Ion Pair of Alkali Metal Complex of Monodisperse Poly(oxyethylene) Derivatives with Picrate Ion 1506
+
2
6
2
2
5
2
2
2
2
2
M
2
2
2
AUTHOR INDEX
December, 1992|
S U Z U K I , Tsuneo 2,3-Dichloro-5,6-dicyano-/>-benzoquinone as a
Mild and Efficient Catalyst for the Tetrahydropyranylation of
Alcohols 304
S U Z U K I , Yasuhiro Rate of Back-Extraction of Tris(acetylacetonato)- and Tris(trifluoroacetylacetonato)chromium(III)
Solutions 415
S U Z U K I , Yoshitsugu Stability and Reactivity of Dihydroxobis(trimethylphosphine)platinum(II), an Intermediate Species for
the Synthesis of a Variety of Water-Soluble Phosphine Complexes 3386
T A B A T A , Kenji X-Ray Photoelectron Study of the Methane
Interaction with LaCoOß 1295
T A B A T A , Masaaki Equilibrium and EXAFS Studies of Mercury(II) Porphyrin in Aqueous Solution 1438
T A B U S H I , Iwao Exchange-Storage of a Guest Molecule in an
Inclusion Crystal of 2,11,20,29-Tetramethyl-2,11,20,29-tetraaza[3.3.3.3]paracyclophane 805
T A C H I K A W A , Enzo Effect of 7-Ray Irradiation on the Recoil
Reaction 735
T A D A , Masaru Diels-Alder Reaction of (l-Methylene-2propenyl)cobaloxime,
1 -Methylene-2-propenyl-bis(dimethylglyoximato)pyridine-cobalt(III) 1252
T A G A H A R A , Kiyoshi Catalytic Hydrogenation of Dehydro
Quassinoids and Cytotoxic Antitumor Activity of the Hydrogenation Products 2684
T A G A K I , Waichiro The Reaction of a 10-Methylacridinium Salt
with Tertiary Amines 55
T A G A K I , Waichiro Hydrolytic Metalloenzyme Models. Metal
Bis-Imidazole Ligands Catalyzed by Z n and C u in the Reaction with />-Nitrophenyl 2-Pyridinecarboxylate in a Cationic
T A G A K I , Waichiro Cd -Catalyzed Methanolysis of Phenyl
Phosphatosulfate. Selectivity of Metal Ion in the Site of Cleavage of P-0 and S-0 Bond 3335
T A G A M I , Hiroshi The Effect of the Coexistent Gases on the
Thermal Reaction of Toluene or Methane in a Clusius-Dickel
Type Thermal Diffusion Column 3434
T A G A S H I R A , Shoji Micellar Effect on the Formation Rate of
Ni(II) and Co(II) Complexes with 8-Quinolinol and Its 5Alkyloxymethyl-8-quinolinol Derivatives in a Nonionic Surfactant Micellar System 286
T A G L I A Z U C C H I , Mara Viscosities and Activation Energies of
Viscous Flow of the l,2-Ethanediol/N,A^DimethyIformamide
T A G U C H I , Kazuhiro N, N'-Di(8-quinolyl)glutaramide Exhibiting Highly Selective and Efficient Uphill Transport of Cu(II)
T A G U C H I , Yasushi Syntheses of and Restricted C 3-C p2 Bond
Rotation in Triptycenes That Carry C -01efinic Substituent at
9-Position 2616
T A G U C H I , Yoichi Reaction of 1,3-Oxathiolium Salts with
668
T A G U C H I , Yoichi Preparation of 1,4,2-Dithiazolium Salts 920
T A K A B A Y A S H I , Yasuhiko Electron Transport and Redox
Chain Reactions in a Mosaic Membrane 1561
T A K A D A , Susumu Preparation and Properties of Immobilized
Glucoamylase on a Magnetically Anisotropic Carrier Comprising a Ferromagnetic Powder Coated by Albumin 3430
T A K A G I , Makoto Polymers Having pH-Buffering Capability for
T A K A G I , Masaharu A Convenient Synthetic Method of 2Cyano-6-methoxybenzothiazole, —A Key Intermediate for the
Synthesis of Firefly Luciferin 392
T A K A G I , Masaharu Improved Synthetic Methods of Firefly
2+
2+
2+
sp
4
S
3553
Luciferin Derivatives for Use in Bioluminescent Analysis of
Hydrolytic Enzymes; Carboxylic Esterase and Alkaline Phosphatase 2604
T A K A G I , Shigeru Four Different Coordination Modes of 1.ΓBis(diphenylphosphino)ferrocene: Synthesis, X-Ray Crystal
Carbonyl
Complexes
with
l.l'-Bis(diphenylphosphino)ferrocene (dppfe) 1415
T A K A G I , T a k e s h i N-Hydroxy Amides. X. Synthesis of a Nonapeptide with an Ala-(HO)Gly-Ala Sequence and Its Spectral
T A K A G I , Y u z u r u Aromatization of Ethylene and C Hydrocarbons Using a Thermal Diffusion Column 274
T A K A H A M A , Umeo Effects of Redox Reagents on ESR Line
Shape of Synthetic Melanins 6
T A K A H A S H I , Fujio Numerical Formulation of Pigment Release
from Magnetically Anisotropic Gel Beads with Respect to the
Magnetic Moment in an Alternating Magnetic Field 396
T A K A H A S H I , Fujio The Selective Separation of Organic Acids
T A K A H A S H I , Fujio Preparation and Properties of Immobilized
Glucoamylase on a Magnetically Anisotropic Carrier Comprising a Ferromagnetic Powder Coated by Albumin 3430
T A K A H A S H I , Kazufumi Preparation of 1,2,3-Naphthalenetriamine, 1,2,5,6- and 1,2,7,8-Naphthalenetetramine, and 5,6,7,8Quinolinetetramine and -Isoquinolinetetramine by Reduction
T A K A H A S H I , Kazuhiro Kinetics and Mechanism of the High
Temperature Selenidization of Cobalt 329
T A K A H A S H I , Kazuko One-Pot Synthesis and Redox Properties of Conjugation-Extended 4,4'Bipyridines and Related Compounds. New Ligands Consisting of a Heterocyclic Three-Ring
Assembly 1855
T A K A H A S H I , Kazuo Stereoselectivities in Catalytic Hydrogenation of Several Branched-Chain 6-Deoxyhex-5-enopyranosides. A Synthesis of Branched-Chain Methyl 6-Deoxy-j3-Lhexopyranoside 292
T A K A H A S H I , Keiko Enantioface Differentiating Reduction of
Keto Acid in the Presence of 6-Deoxy-6-amino-0-cyclodextrin
with NaBH in Aqueous Media 2690
T A K A H A S H I , K e n s u k e [8+2] Cycloadditions of 2,4,6Cycloheptatriene-l-imines with Chloroketenes: Facile and
High-Yield One-Pot Synthesis of l-Azaazulen-2(l#)-ones 812
T A K A H A S H I , Kensuke Ή NMR Study of 2,3-Dicyanobicyclo[2.2.2]octa-2,5,7-triene Partially Oriented in a Nematic Phase
906
T A K A H A S H I , Kensuke Structure and Orientation of oPhenylene Phosphorochloridite and o-Phenylene Phosphorochloridate Dissolved in a Nematic Phase 1135
T A K A H A S H I , Kensuke An NMR Study of the Carbanions
Produced from Triphenylethylene and Its Methyl-Substituted
Derivatives 2162
T A K A H A S H I , K e n s u k e Deuterium Isotope Effects on Aro
matic C-13 NMR Chemical Shifts. IV. Can the Isotope Shifts Be
Correlated w i t h Bond Lengths? 2894
T A K A H A S H I , K e n s u k e C NMR Study of Chloro- and Methylthiophenium Ions 3228
T A K A H A S H I , Kohshin The Fluorescence Properties of (2Nitro-5,10,15,20-tetraphenylporphyrinato)zinc 1475
T A K A H A S H I , Kyoko Reduction of Dicarboxylic Acid Anhy
dride with 2-Propanol over Hydrous Zirconium Oxide 262
T A K A H A S H I , Kyoko Regioselective Hydrogenation of Unsatu
rated Compounds Using Platinum-Zeolite Coupled with Organosilicon Alkoxide by CVD Method 1240
T A K A H A S H I , Mareyuki Action of Fatty Acid Esters of LAscorbic Acid as Antioxidants in Phosphatidylcholine Lipo
somal Membranes 679
T A K A H A S H I , Masami Syntheses of Aryltetralin Lignans: Con4
4
13
3554
I Vol. 65, No. 12
eise Syntheses of (±)-Isopodophyllotoxone, (±)-Picropodophyllone and Their Related Compounds 3495
T A K A H A S H I , Nobuo Effects of Pd Dispersion on the Catalytic
T A K A H A S H I , Ohgi Qualitative Triplet Potential Energy
1463
T A K A H A S H I , Ohgi A M I Potential Energy Curves for CisTrans Isomerization of Stilbene Cation Radicals 2267
T A K A H A S H I , Shigetoshi Syntheses and Properties of Heterodinuclear μ-Ethynediyl Complexes Containing Palladium and
Platinum 1179
T A K A H A S H I , Shigetoshi 1:1 Adduct Ion Formation of Simple
Modifications 1275
T A K A H A S H I , Tadahito Colloidal Dispersions of Platinum and
Palladium Clusters Embedded in the Micelles. Preparation and
Application to the Catalysis for Hydrogenation of Olefins 400
T A K A H A S H I , Terumi Epimerization of Chlorophyll Deriva
tives. V. Effects of the Central Magnesium and Ring Substitu
ents on the Epimerization of Chlorophyll Derivatives 3080
T A K A H A S H I , Terumi Pheophytinization of Eight Chlorophyll
T A K A H A S H I , Yasushi Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
T A K A I , Kazuhiko Reaction of Tantalum-Alkyne Complexes
T A K A I , Yoshio 1:1 Adduct Ion Formation of Simple Carbohy
drate Derivatives with Cations Using FAB Mass Spectrometry.
Comparison of O-Acetyl, N-Butyl, and O-Methyl Modifications
1275
T A K A K U R A , Yutaka Ή NMR Study of 2,3-Dicyanobicyclo[2.2.2]octa-2,5,7-triene Partially Oriented in a Nematic
Phase 906
T A K A K U W A , Athushi Extraction-Spectrophotometric Deter
mination of Average Valence of Copper in Superconductor YBa-Cu-0 882
T A K A M U K U , Setsuo Competitive Intramolecular Electron
Transfer and SN2 Reactions of Radical Anions. Effects of Sol
vent Polarity on the Reaction Mechanism 1668
T A K A M U K U , Setsuo Triplet Sensitized Quadricyclane-Norbornadiene Valence Isomerization of Methyl 5-(4-Biphenylyl)tetracyclo[3.2.0. ' 0. - ]heptane-l-carboxylate 3177
T A K A M U K U , Setsuo Electron-Laser Dual Beam Irradiation of
2-Methylbenzophenone 3186
T A K A M U K U , Toshiyuki EXAFS and X-Ray Diffraction Stud
ies on the Structure of the Tetrathiocyanatocadmate(II) Com
plex in Dimethyl Sulfoxide 2104
T A K A M U R A , Hiroshi Stabilization Energy of the 9,9'Trimethylenedianthracene Radical Cation Estimated by the
Charge Resonance Band 909
T A K A N O , Mikako Tautomerization and Dissociation Equili
bria of /3-Diketones in Microemulsions 170
T A K A S E , Kahei Synthesis of a Polycyclic π-Conjugated System
Method. I . Synthesis and Properties of Cyclopent[a]azulenes
1527
T A K A S E , Kahei Peri-Selective Cycloaddition Reactions of 3Methoxycarbonyl-2#-cyclohepta[6]furan-2-one with 6,6-Dimethylfulvene 2127
T A K A S E , Kahei Synthesis of a Polycyclic π-Conjugated System
Method. I I . Synthesis and Paratropic Properties of WCyclopent[fl]azulen-3-one and Its Methyl Derivatives 2131
T A K A S E , K a h e i Synthesis of a Polycyclic π-Conjugated System
Method. I I I . Synthesis and Properties of 4-Hydroxy-3#2 7
4
6
cyclopentjö |azulen-3-one 3282
T A K A S H I M A , Kumiko Photochemical Reactions of 4-Oxo Carboxylic Esters: Remote Hydrogen Abstraction and Cis-Trans
Isomerization 3498
T A K A S H I M A , Yoshimasa Fe Mössbauer Spectra, Crystal
Structure, and Spin-Crossover Behavior of [Fe(mbpNXlut)]BPh 1825
T A K A S H I M A , Yoshimasa Comparison of IR-Transmission
Method with the Conventional DTA Method (Kissinger Plot) in
the Crystallization Study of Iron Tellurite Glass 1927
T A K A S H I M A , Yoshimasa Phase Separation of Phosphotellurite Glass Investigated by Fe-Mössbauer Spectroscopy and
DTA 2540
T A K A S H I M A , Yoshimasa Random Packing of Ions in the Ionic
Glass *KNO -(100-x)Sr(NO ) (*=22-60) and the r R a y
Induced Cleavage of K-ON0 Bonds 2881
T A K A T A , Masaki High-Pressure Effect on the Radical Reduction of Spin Probes in Human Erythrocytes 1648
T A K A T O R I , Yoshiki Photodissociation of Highly-Excited Triplet State of Benzophenone Studied by a Time-Resolved Thermal
T A K A T S U K A , Tsutomu A New Ketyl Radical Probe. Dehalogenation of o-Halobenzophenone 1157
T A K A Y A , Haruo Growth Process of ZSM-5 Zeolite Film 146
T A K E B A Y A S H I , Shigeharu Photochemical Nitration of Benzoic Acid Derivatives by Irradiation to Nitrate Ions 3183
T A K E C H I , Naoto A Chiral Synthesis of D-myo-Inositol 1Phosphate Starting from L-Quebrachitol 366
T A K E D A , Akira A Systematic Study on the Bakers' Yeast
631
T A K E D A , Takuya Esterification of Boric Acid with 1,2Propanediol, 3-Amino-l,2-propanediol, and (±)-3-Dimethylamino-l,2-propanediol as Studied by B N M R Spectroscopy
1903
T A K E D A , Yoshifumi Semi-preparative Purification and Crystallization of Synthetic Analogs of Heat-stable Enterotoxins of
Enterotoxigenic Escherichia coli 938
T A K E H A R A , Zen-ichiro The Calculation of Temperature and
Thermal Stress Distributions in the Planar Solid Oxide Fuel
Cell 309
T A K E H I R A , Katsuomi Synthesis of Alkyl Substituted pBenzoquinones from the Corresponding Phenols Using Molecular Oxygen Catalyzed by Copper(II) Chloride-Amine Hydrochloride Systems 1522
T A K E I , Hisashi Stereochemical Aspects on the BF · Et20 Catalyzed Ring Contraction of 5-Substituted 2,3-Epoxycyclohexanones 3206
T A K E M A T S U , Kiyotaka Vapor-Phase Beckmann Rearrangement of Cyclohexanone Oxime over an HY Zeolite Catalyst
Calcined at High Temperature 1486
T A K E N A K A , Akio The Crystal Structures of Cyanide Metmyoglobins Reconstituted with Iron(III) Complexes of Porphyrin,
T A K E N A K A , Atsushi Thermal Decomposition of Silver Amidotriphosphate Ag4P 0 NH2 1985
T A K E O K A , Shinji Simultaneous Formation of a Polypyrrole
Film and a Tantalum Oxide Layer by Electrochemical Oxidation 1860
T A K E S H I T A , Hitoshi Synthetic Photochemistry. LVIII. Intramolecular Photocycloaddition of 2-Alkenyl-6-methyl-4i/-l,3dioxin-4-ones 2940
T A K E S H I T A , Michinori Treatment of Dimethoxyparacyclophanes with Ammonium Cerium(IV) Nitrate ' 2076
T A K E S H I T A , Naohiro Substituent Effects on the Aggregation
limicola 3493
T A K E U C H I , Hideo The Optical Properties of the Bc DDQ Crys57
4
57
3
3
2
2
n
3
3
9
2
December, 1992|
3555
AUTHOR INDEX
tal and Its Solid Phase Reaction 2157
T A K E U C H I , Hiroshi Reaction of Olefins with Dimethyl(meth
ylthio)sulfonium Salts in the Presence of Triphenylphosphine
T A K E U C H I , Kiyoshi Direct Iodination of Aromatic Compounds
with Iodine and Alumina-Supported Copper(II) Chloride or Sul
fate 306
T A K E U C H I , Manabu Photochemical Nitration of Benzoic Acid
Derivatives by Irradiation to Nitrate Ions 3183
T A K E U C H I , Seiji Asymmetric Synthesis of Benzoin by Sml Mediated Enantioselective Protonation 2001
T A K I , Naobumi Orientations of a Nematic Liquid Crystal in
tion Spectra 3135
T A K I K A W A , Yuji A Convenient Preparation of 2,4,6Trisubstituted 1,3,5-Triselenanes by Treating Aldehydes or
Their Acetais with 2,2,4,4,6,6-Hexamethyl-l,3,5-triselena-2,4,6tristannacyclohexane in the Presence of BF -OEt and A I C I 3
2848
T A K Y U , Toshiyuki Genesis of Highly Active Cobalt Sulfide
T A M A G A K I , Seizo The Reaction of a 10-Methylacridinium Salt
T A M A I , Tetsuro The Total Synthesis of Herbimycin A 2974
T A M A I , Yasufumi Synthesis of Optically Active Polymethacrylates Bearing Axially Dissymmetric Ι,Γ-Binaphthalene Skel
eton as a Pendant Group and Their Optical Resolution Ability
as Chiral Adsorbent for HPLC 817
T A M A K I , Hiroko Syntheses and Magnetic Properties of
T A M A K I , Takashi Photochromism of Hemithioindigo Deriva
tives. I. Preparation and Photochromic Properties in Organic
Solvents 649
T A M A K I , Takashi Photochromism of Hemithioindigo Deriva
tives. II. Photochromic Behaviors in Bilayer Membranes and
Related Systems 657
T A M A R U , Yoshinao Efficient Synthesis of 2-Vinyl-rbutyrolactones and 2-Vinyl-y-butyrolactams by Palladium-Catalyzed
Decarboxylative Carbonylation 97
T A M U R A , Futoshi Enzymatic Kinetic Resolution of [4](1,2>
Ferrocenophane Derivatives 2784
T A M U R A , Hatsue Formation and Reaction of Carbonyl Ylides.
Reactions of l-Methoxy-2-benzopyrylium-4-olate with Isothiocyanates 1362
T A M U R A , Hatsue Abnormal Diels-Alder Reaction of 5Alkoxyoxazoles with Tetracyanoethylene and X-Ray Crystal
T A M U R A , Hatsue Abnormal Diels-Alder Reaction of Oxazoles
with 4-Phenyl-3//-l,2,4-triazole-3,5(4#)-dione and Diethyl Azodicarboxylate, and X-Ray Crystal Structure of an Adduct
2998
T A M U R A , Rui Molecular and Crystal Structure of 3,5,5Trimethyl-2-(2-methyl-2-nitropropyl)-2-cyclohexen-l-one Pos
sessing Molecular Asymmetry 2860
T A N A B E , Seiichi Photochemistry of 1,2:4,5-Benzenebis(dicarboximide). Insertion of Alkenes into the C-N Bond of
N,N'-Dihexyl-1,2:4,5-benzenebis(dicarboximide) 2875
T A N A K A , Akira Photocatalytic Hydrogen Evolution from Aque
ous Methanol Solution on Niobic Acid 1202
T A N A K A , Atsushi Thermodynamics of Triple-Helix and
Double-Helix Formations by Octamers of Deoxyriboadenylic
and Deoxyribothymidylic Acids 535
T A N A K A , Jiro High Polariton Reflectance in Heptamethinebis(dimethylamino)cyanine Chloride Crystal 2328
T A N A K A , Juichi Studies on Aromatic Sesquiterpenes. XIII.
2
3
2
T A N A K A , Katsumi Selective Friedel-Crafts Alkylation on a
Vermiculite, a Highly Active Natural Clay Mineral with Lewis
Acid Sites 2833
T A N A K A , Kazuhiro Correlation between Positron Annihilation
T A N A K A , Kazunori Aromatization of Ethylene and Ca Hydro
carbons Using a Thermal Diffusion Column 274
T A N A K A , Keiko Synthesis and Some Reactions of 2-Amino-1azaazulene-3-carbaldehyde
340
T A N A K A , Kunihiko Action of Fatty Acid Esters of L-Ascorbic
Acid as Antioxidants in Phosphatidylcholine Liposomal Mem
branes 679
T A N A K A , Masashi Absorption Spectra and Electrical Resistivi
ties of Bis(l,2-dionedioximato)nickel(II) Complexes at High
Pressures 1078
T A N A K A , Masashi The Optical Properties of the Bc DDQ
Crystal and Its Solid Phase Reaction 2157
T A N A K A , Masayuki A Novel Configuration-Controlled Ster
Silyl Ethers 971
T A N A K A , Motoharu A Simple Method for the Evaluation of
T A N A K A , Motoharu Kinetic Studies of the Incorporation of the
T A N A K A , Motoharu Thermodynamic and NMR Studies on the
Complexation
of
Lanthanoid(III)
Ions
with
0Phenylenediamine-N,N,AT,/V'-tetraacetate in Aqueous Solu
tions 1566
T A N A K A , Motoharu Thermodynamic Studies on the Complex
ation of Alkaline-Earth Metal Ions with o-PhenylenediamineN, Ν, N', iV'-tetraacetate in Aqueous Solutions 1722
T A N A K A , Motoharu Thermodynamic Studies on the Complex
ation of o-Phenylenediamine-iV,iV,iV' W-tetraacetate with
Divalent Cadmium, Mercury, and Lead Ions in Aqueous Solu
tions 2333
T A N A K A , Nobuo The Crystal Structures of Cyanide Metmyoglobins Reconstituted with Iron(III) Complexes of Porphyrin,
T A N A K A , Shingo Synthesis of 2-(Substituted Methyl)-3,4Disubstituted Pyrroles and Their Conversion into the Corre
sponding Porphyrins 2660
T A N A K A , Shuji Efficient Synthesis of 2-Vinyl-y-butyrolactones
and 2-Vinyl-y-butyrolactams by Palladium-Catalyzed Decar
boxylative Carbonylation 97
T A N A K A , Takanori 1:1 Adduct Ion Formation of Simple Car
Modifications 1275
T A N A K A , Yoshihito Synthesis and Properties of DiaminoSubstituted Dipyrido [3,2-a: 2',3'-c]phenazine 1006
T A N E M U R A , Kiyoshi 2,3-Dichloro-5,6-dicyana/>-benzoquinone
as a Mild and Efficient Catalyst for the Tetrahydropyranylation of Alcohols 304
T A N I G U C H I , Keiko Kinetic Studies of the Incorporation of the
T A N I G U C H I , Masahiko Isomerization of Olefins by Means of
RaSnH-Et3B and Stereochemical Study on Reduction of
Alkenyl Iodides 349
T A N I K I , Y a s u s h i Structural Features of (CH3) Si(C H ) Fe (CO) (C=NR) and (CH ) Si (C H4) Fe (CO) (C=NR) 2309
T A N I M O T O , Satoshi Decomposition of [2.2.2]Cyclophane-l,2dione Mono- and Bis(tosylhydrazone)s 1469
T A N I M O T O , Youichi Evaluation of Melting and Crystalline
2
2
2
3
3
2
5
2
2
2
2
5
4
2
3556
BULLETIN
OF T H E
C H E M I C A L SOCIETY OF JAPAN
Water Surface and Their Importances for Molecular Aggregation States in Monolayers 864
T A N I Z A K I , Yoshie Preliminary Analysis of the Electronic
Absorption Spectrum of a Solute in a Biaxially-Stretched Polymer Film 463
T A N I Z A K I , Yoshie" Rate Constants of the Photodegradation
and Photoisomerization of Polyenes Produced in Heat-Treated
PVAFilm 1342
T A N I Z A K I , Yoshie Orientations of a Nematic Liquid Crystal in
Sandwich-Type Cells Studied by Polarized Electronic Absorption Spectra 3135
T A N O U E , Yasuhiro A Formation of a Fusarubin Carbon Skeleton 2854
T A R A F D E R , Pranab K. Complex Fluoroberyllates. Synthesis and Physicochemical Characterization of Mixed-Fluoro
Complexes of Beryllium Containing Hydrogenoxalate (HC Or),
Glycinate, and Dihydrogenphosphate ( H 2 P O 4 " ) as Co-Ligands
522
T A S H I K A , Haruyoshi Hydroacylation of Alkyl Vinyl Ketones
and Acrylic Esters Using Organotetracarbonylferrates. Synthesis of 1,4-Dicarbonyl Compounds 1257
T A S H I R O , Katsuya Preparation and Isomerization of 3,4Bis(2,4,6-tri-/-butylphenylphosphinidene)cyclobutenes 2297
T A S H I R O , Masashi Decomposition of [2.2.2]Cyclophane-l,2dione Mono- and Bis(tosylhydrazone)s 1469
T A S H I R O , Masashi Treatment of Dimethoxyparacyclophanes
with Ammonium Cerium(IV) Nitrate 2076
T A S H I R O , Masashi Preparation of 1,2,3-Naphthalenetriamine,
T A S H I R O , Masashi A Novel Ring Transformation of 3a,5,6aTriaryl-3,3a-dihydro-2//-furo[3,2-%yrrole-2,6(6a//)-diones into
3-Aroy 1-2,5-diarylpyrrole Derivatives 2611
T A S S I , Lorenzo Viscosities and Activation Energies of Viscous
Flow of the l,2-Ethanediol/N,^Dimethylformamide Binary
Solvent System 503
T A T S U M I , T a k e s h i Optical Resolution by Replacing Crystallization of (i?S)-4-Thiazolidinecarboxylic Acid with L-Amino
T A T S U T A , Kuniaki The Total Synthesis of Herbimycin A
2974
T A Z A W A , Noriko Acyliminium Cyclization of Chiral 5-(4Alkenyl)-5-hydroxy-2-pyrrolidinone Derivatives 2866
TAZUKE,
Shigeo
Stabilization Energy of the 9,9'Trimethylenedianthracene Radical Cation Estimated by the
T E R A D A , Akira A Formation of a Fusarubin Carbon Skeleton
2854
T E R A I , Tadamasa Crystal and Molecular Structure of 1,5-Secograyanotoxin-1,3,6,14,16-pentaacetate 3482
T E R A O , Hiromitsu Pyrrolizidine Alkaloids. The Synthesis and
Absolute Configuration of All Stereoisomers of 4-Carboxy-4ethyl-3-hydroxy-2-isopropyl-4-butanolide, the Necic Acid Component of Axillaridine 1761
T E R A S A K A , Michio Preparation of Cu Thin Films by the
T E R A S H I M A , Shiro A Practical Synthesis of töra>-3-Amino-2hydroxycarboxylic Acids 360
T E T S U M I , Tadahiro Crystal and Molecular Structure of 3,6Dioxograyanotoxin I 2836
T E T S U M I , Tadahiro Crystal and Molecular Structure of 1,5Seco-grayanotoxin-1,3,6,14,16-pentaacetate
3482
T I W A R I , Neeta Solid-State Reaction between Zinc Hydroxide
and 8-Quinolinol 495
T O B I S E , Tatsushi Effects of Pd Dispersion on the Catalytic
T O D O R O K I , Natsuko Surface Adsorption and Micelle Forma2
2
[Vol.65, No. 12
tion of Dodecyltrimethylammonium Chloride and Dodecylammonium Chloride Mixture 858
TOI, Hiroo Bis(l-methylimidazole)iron(II) Complexes of Porphyrins Substituted with Highly Electron-Withdrawing CF3
Groups: Electronic Spectra with Split Q-Bands and MCD Spectra with Unusual Features 1915
TOI, Hiroo Enantioselectivity in the Interaction of Calf Thymus
DNA with Acridine Derivatives Having an Amino Ester or
Amino Alcohol Substituent 2050
T O K A M I , Kenjirou Surface Alkoxylation of Silicas by Mild
Reactions with Alcohols 728
T O K I D A , Nobuko Structures of Two Geometrical Isomers of
Dioxo[(S)-N-salicylidene-3-aminopyrrolidine]vanadium(V)
1725
T O K I I , Tadashi Binuclear Nickel(II) Complexes of Schiff Bases
Derived from Salicylaldehydes and l,«-Diamino-«'-hydroxyalkanes (n,n.'=3,2; 4,2; and 5,3) Having an Endogenous Alkoxo
Bridge and a Pyrazolato Exogenous Bridge 334
T O K I I , Tadashi Crystal Structures and Magnetic Properties of
Novel M-Carboxylato-M-Hydroxo-Bridged Binuclear Copper(II)
Complexes with 1,10-Phenanthroline 1214
T O K I I , Tadashi l,3-Bis(salicylideneamino)-2-propanol as the
Ligand for Manganese(III) Ions 1466
T O K I I , Tadashi Synthesis, Properties, and Crystal Structures
of a Series of Dinuclear Manganese(III) Complexes with 1,5Bis(salicylideneamino)-3-pentanol and Various Anions: Formation of a Tetranuclear Manganese(III) Complex 2624
T O K I I , Tadashi Crystal Structures and Magnetic Properties of
Silanecarboxylato Bridges 2739
T O K I W A , Ayako Magnetic Properties of Oxygen Centered
Trinuclear Ruthenium(III) and Rhodjurn(III) Complexes 198
T O K U D A , Koichi Piezoelectric Admittance Measurements of
T O K U D A , Yoshihiro Efficient Six-Electron Photoreduction of
Nitrobenzene Derivatives by 10-Methyl-9,10-dihydroacridine in
the Presence of Perchloric Acid 831
T O K U M A R U , Katsumi Qualitative Triplet Potential Energy
1463
T O K U M A R U , Katsumi A M I Potential Energy Curves for CisTrans Isomerization of Stilbene Cation Radicals 2267
T O K U M A R U , Katsumi Xanthene Dye-Sensitized Electron
2887
T O K U N A G A , Yu-ichi Catalytic Properties of Lanthanide
Metals on Silica 244
T O K U N A G A , Yukio Perfluoroalkylation of Olefins by Electrooxidation of Perfluoroalkanoic Acids: Relations between
Olefins 1976
T O K U R A , Satoshi Study of Photochemical Reactions of
Decamethylcyclopentagermane
1642
T O K U T A K E , Norio A Novel Synthesis Including Asymmetric
Synthesis of α,β-Unsaturated γ-Hydroxy Carbonyl Compounds
TOMIGUCHI, Akira Optical Resolution by Preferential Crystal
lization of 2-(3,4-Carbonyldioxyphenyl)-2-(phthalimidooxy)acetic Acid, a Key Intermediate of Cephalosporin Antibiotic M14659 3288
TOMINAGA, Takeshi Mössbauer Emission Spectroscopy of
Fe Arising from Mn in Metal and Oxides of Chromium 1
TOMINARI, Shigenori The Raman Active Intra- and Intermolecular Vibrations of [Ή10]- and [Ή10] /^-Xylenes 280
TOMISHIMA, Atsuko Ή NMR Study of 2,3-Dicyanobicyclo[2.2.2]octa-2,5,7-triene Partially Oriented in a Nematic Phase
906
57
57
December, 1992|
AUTHOR INDEX
T O M I T A , Masanori Preparation, Stereochemistry, and Kinetics of Isomerization and Racemization of Bis(2,2'-bipyridine
N,N'dioxide)chromium(III) Complexes Containing an Oxalate
or Malonate Ion 1233
T O M I U C H I , Yoshimasa Enzymatic Reactions in AqueousOrganic Media. XVII. Optical Resolution of Amino Acid Esters
by Enzymatic Hydrolysis in Organic Solvents 2599
T O M I Y A S U , Hiroshi F Nuclear Magnetic Resonance Study on
the Kinetics of the Fluoride Exchange in Uranium(VI) Fluoro
Complex 3022
T O M I Z A W A , Hiroshi eis- and /röws-Li[Co (L-tart(2-)-0 )r
(en) ] Hydrate Separated from the Reaction Products of
[Co (C0 )-(en) ] with L-Tartaric Acid 2490
TOMODA, Akihiko Photochromism of Heterocyclic Fulgides
1262
TOMODA, Akihiko Effect of Two Electron-Donating Substituents on Photochromism of Aryl Fulgide, 2-(2,6-Dimethyl-3,5substituted benzylidene)-3-isopropylidenesuccinic Anhydride
2352
T O R I - I , Akiyoshi Preparation of 1,2,3-Naphthalenetriamine,
T O R I I , Sigeru Electroreductive Deoxygenation of Methanesulfonates of α-Hydroxy Esters via a Catalytic Selenation-Deselenation Sequence 3200
T O R U , Takeshi Efficient Seienation of Quinones: Synthesis of
T O R U , Takeshi Synthesis of Novel Polycyclic Selenepinone
Compounds 1794
TOSHIMA, Naoki Colloidal Dispersions of Platinum and Palla
dium Clusters Embedded in the Micelles. Preparation and
Application to the Catalysis for Hydrogenation of Olefins 400
TOSI, Giuseppe Viscosities and Activation Energies of Viscous
Flow of the 1,2-Ethanediol/N, N-Dimethylformamide Binary
Solvent System 503
T O Y A , Yoshiaki A Convenient Synthetic Method of 2-Cyano-6methoxybenzothiazole, —A Key Intermediate for the Synthesis
T O Y A , Yoshiaki Synthesis and Chemiluminescence Properties
of 6-(4-Methoxyphenyl)-2-methylimidazo[l,2-Ä]pyrazin-3(7i0one and 2-Methyl-6-(2-naphthyl)imidazo[l,2-ö]pyrazin-3(7//)one 2475
T O Y A , Yoshiaki Improved Synthetic Methods of Firefly Luciferin Derivatives for Use in Bioluminescent Analysis of Hydrolytic Enzymes; Carboxylic Esterase and Alkaline Phosphatase
2604
T O Y O D A , Nobuhiko An Isomeric Series of Thiophene-Fused
Structures 2173
T O Y O T A , Eiko Cobalt(III) Complexes with Quadridentate
Ligands. XL The Preparation and Properties of os-a-Isomer of
T O Y O T A , Kozo Preparation and Isomerization of 3,4-Bis(2,4,6tri-/-butylphenylphosphinidene)cyclobutenes 2297
T O Y O T A , Shinji Structure of Intramolecular Boron-Amine
Complexes and Proposal of Tetrahedral Character for Correlation between Molecular Structure and Barrier to Dissociation
of the N-B Bonds 1832
T O Y O T A , Shinji Dynamic NMR as a Nondestructive Method for
the Determination of Rates of Dissociation. XX. Secondary
Isotope Effect on Kinetic Basicity of Amine Ligands in Boronate-Amine Complexes and Ammonium Salts 2215
T O Y O T A , Shinji Syntheses of and Restricted C p3-C p2 Bond
Rotation in Triptycenes That Carry C -01efinic Substituent at
9-Position 2616
T O Y O T A , Shinji Structure of and Tetrahedral Character of the
Boron Atom in 9-[2-(l-Ethylthiopentyl)phenyl]-9-borabicyclo19
,,1
1
2
m
3
2
+
S
4
S
3557
[3.3.1]nonane 2857
T R I V E D I , Girish K. Silver(I) Oxide Catalyzed Oxidation of oAllyl- and o-(l-Propenyl)phenols 1662
T S U B A K I Y A M A , Kyoji Photochemical Reactions of 4Acylstyrenes. Effects of Acyl Substituents on Photocyclodimerization via an Excited Triplet State 837
T S U B O I , Hideki Photochromism of Heterocyclic Fulgides
1262
T S U B O I , Hideki Effect of Two Electron-Donating Substituents
on Photochromism of Aryl Fulgide, 2-(2,6-Dimethyl-3,5substituted benzylidene)-3-isopropylidenesuccinic Anhydride
2352
T S U B O I , Sadao A Systematic Study on the Bakers' Yeast
631
T S U B O Y A M A , Sei The Role of a Spin-Coupled Intermediate in
a System Consisting of Tetraminecobalt(III) Complexes and
1225
TSUCHIDA,
A k i r a Stabilization Energy of the 9,9'Trimethylenedianthracene Radical Cation Estimated by the
T S U C H I D A , E i s h u n Simultaneous Formation of a Polypyrrole
Film and a Tantalum Oxide Layer by Electrochemical Oxidation 1860
T S U C H I D A , E i s h u n Synthesis of Soluble Poly(thio-2,6dimethyl-l,4-phenylene) by Oxidative Polymerization of
T S U C H I D A , Satoru The Selective Separation of Organic Acids
T S U C H I M O T O , Masanobu Synthesis and Characterization of
/rflws-[CoCl2(N Jc)] (N4Jc=l,4,7,10-Tetraazacycloheptadecane,
-cyclooctadecane,
-cyclononadecane,
-cycloicosane, -cyclohenicosane, and -cyclodocosane) 191
T S U C H I M O T O , Masanobu X-Ray Structural Study of
/rfl«s-[CoCl (232N 15)]C10 (232N 15=l,4,8,ll-Tetraazacyclotricosane) 2114
T S U C H I Y A , Susumu Catalytic Properties of Lanthanide
Metals on Silica 244
T S U C H I Y A , Tohru Reaction of 1,3-Oxathiolium Salts with
668
T S U C H I Y A , Tohru Preparation of 1,4,2-Dithiazolium Salts
920
T S U C H I Y A , Tsutomu Synthesis of 3-Deoxy-5-0-mycaminosyltylonolide and 3-Deoxy-5-0-(4-deoxymycaminosyl)tylonolide
3405
T S U D A , Y a s u y u k i Kinetic Studies of the Incorporation of the
Zinc(II) Ion into Water-Soluble N-Phenyl-Substituted Porphyrins. Deformation Effect on the Metallation Rate 771
T S U G E , Otohiko Decomposition of [2.2.2]Cyclophane-l,2-dione
Mono- and Bis(tosylhydrazone)s 1469
T S U H A K O , Mitsutomo Effect of Water Vapor on the Thermal
Behavior of Manganese cyc/o-Tetraphosphate 777
T S U J I , Masaharu Rotational Distribution of CO(b 2 ) Produced
in Energy Transfer Reaction from Ar( P ) to CO 1713
T S U K A H A R A , Keiichi Kinetics and Mechanisms of PhotoInduced Reduction of Iodine by Monoamine-JV-polycarboxylate
Ions in an Aqueous Solution 1812
T S U K A M O T O , Yoshihisa 13/3-Hydroxylation of Milbemycins
by Selenium Dioxide 3300
T S U K U R I M I C H I , Eiichi Thermal Behavior and Mass Spectra
Acid 1993
T S U N O , Shinji Refolding of Trimeresurus flavoviridis Phospholipases A 2655
T S U N O , Yuho Solvent Effects on the Solvolysis of Neophyl
Toisylates 46
+
4
2
4
4
4
3
3
2
2
+
3558
T S U N O , Yuho Silicon Effects. IV. Solvolysis of l-(Pentamethyldisilanyl)-2-phenylcyclopropyl Bromide in 2,2,2-Trifluoroethanol via a(CC)-Assisted and -Unassisted Ionization Proc
esses 959
T S U N O , Yuho A Novel Configuration-Controlled Stereoselectiv
ity in Enol Silylation of Ketones. Stereochemistry of AminePromoted Enol Silylation of Meso and Racemic α,α'-Dichloro
Ketones and of Ketonization of the Resultant Enol Silyl Ethers
971
T S U N O , Yuho The Substituent Effects on Solvolyses of threo-2Aryl-l-methylpropyl Brosylates 3072
T S U N O D A , Kin-ichi Slab Optical Waveguide with Octadecylsilane Coated Surface for Absorption Detector of Flow Analysis
1581
T S U N O D A , Kin-ichi Extractive Separation of Trace Amounts
of Cu", F e , and G a from A l on the Basis of HSAB Rule
2537
T S U N O D A , Kin-ichi Copper(II) Complexing Capacity of River
T S U R U T A , Teiji Reactivity of Lithium Alkylamide toward
T S U Z U K I , Hirohisa Treatment of Dimethoxyparacyclophanes
with Ammonium Cerium(IV) Nitrate 2076
T S U Z U K I , Toshihiro Titanium(IH) Chloride Mediated Reduc
tion of Dicyanoalkenes 3068
T U Y U K I , Masahiko Determination of Fluoride Ion by a Flow
Injection Analysis Based on the Formation of a Fluorescent
Aluminium-Schiff Base Complex 911
U C H I D A , Kengo Pressure Effects on the Aquation Reactions of
Tris(2,2'-bipyridine)chromium(III) Ion and Tris(l,10-phenanthroline)chromium(III) Ion 3253
U C H I D A , Kingo Thermally Irreversible Photochromic Systems.
Substituent Effect on the Absorption Wavelength of 11,12Dicyano-5a,5b-dihydro-5a,5b-dimethylbenzo[ 1,2-6:6,56]bis[l]benzothiöphene 430
U C H I D A , Masaya Hydroacylation of Alkyl Vinyl Ketones and
Acrylic Esters Using Organotetracarbonylferrates. Synthesis
of 1,4-Dicarbonyl Compounds 1257
U C H I D A , Motoko Evaluation of Melting and Crystalline Relaxation Temperatures of Fatty Acid Monolayers on the Water
Surface and Their Importances for Molecular Aggregation
States in Monolayers 864
U C H I D A , Tokiko Prismatic and Antiprismatic [42]Ferrocenophanes ([4](1,1')[4](3,3> and [4](l,l')[4](3,4 )Ferrocenophanes)
3275
U C H I D A , Yasuzo Syntheses and Structures of Novel Ruthenium(II)-Chiral Diphosphine Complexes 1595
U C H I D A , Yoshiki Synthesis and Antimicrobial Activity of Bactenecin and Its Analogs 615
U C H I J I M A , Toshio Partial Oxidation of Methane to Synthesis
U C H I J I M A , Toshio Preparation of Niobates of Rhodium and
UCHINO, Koichiro The Binding Characteristics of Sodium
Decyl Sulfate to Poly(L-ornithine) with 1-Alkanesulfonate
Counter Ions 1146
UCHIO, Yasuto 7-Epidenticulatolide, a New Cembranolide with
a Cyclic Peroxide Function from the Soft Coral Lobophytum
den ticulatu m 1182
U C H I Y A M A , Shin-ichi A Convenient Synthesis of Cationic
Vinylidene and 1,2-Propadienylidene Iron Complexes by Photoreaction of [CpFe(CO)(dppe)] BF ~ with 1-Alkynes 2560
UDA, Hisashi Solution Equilibrium and EPR Study of the Dinuclear Copper(II) Complexes of Aminopolycarboxylic Acids with
an Alcohol OH Group in the Alkyl Chain Linkage 2910
U D A G A W A , Yasuo Mixing State of 1-Propanol Aqueous Solutions Studied by Small-Angle X-Ray Scattering: A New Parameter Reflecting the Shape of SAXS Curve 155
m
m
m
,
4
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[Vol. 65, No. 12
U D A G A W A , Yasuo SAXS Curve Shape Analysis of 2-Butoxyethanol Aqueous Solutions 600
U E C H I , Tetsuo Refinement of the Crystal Structure of Pentaerythritol Tetracetate 2831
U E D A , Hisashi Magnetic Properties of Pyro-Carbons Prepared
from Polyvinyl chloride) and Activated Carbon 1144
U E D A , Joichi Determination of Arsenic(III) and Arsenic(V) by
Hydride Generation—Atomic Absorption Spectrometry Following a Rapid Coprecipitation Technique with Hafnium(IV)
Hydroxide 1496
U E D A , Masayuki Kinetic Study in Aqueous Solutions of Alcohols with Butyl Group by Ultrasonic Methods 1207
U E D A , Mitsuru Diphenyl (2,3-Dihydro-2-thioxo-3-benzoxazolyl)phosphonate: A New, Reactive Condensing Agent for the Synthesis of Amides, Esters, Peptides, and ^-Lactams via Condensation 1636
U E D A , Takahiro Selective Ion Transport in Acetonitrile Across
the Ionophore-Immobilized Polymer Membranes Used as the
Sensor of the Ion-Selective Electrodes 19
U E D A , Takahiro The Crystal Structure of Tetraethylene
Glycol Complex of Sodium Tetraphenylborate 3180
U E D A , Toshitomo Hydrolytic Metalloenzyme Models. Metal
Bis-Imidazole Ligands Catalyzed by Z n and C u in the Reaction with />-Nitrophenyl 2-Pyridinecarboxylate in a Cationic
U E H A R A , Kazuko A Novel Ring Transformation of 3a,5,6aTriaryl-3,3a-dihydro-2//-furo[3,2-61pyrrole-2,6(6a//)-diones into
U E M O T O , Yuichi ENDOR Study of the Cation Radicals of
U E M U R A , Osamu The Intramolecular Structure of Oxonium
Ion in Concentrated Aqueous Deuterochloric Acid Solutions
2021
U E M U R A , Osamu The Structure around the Nitrite Ion in
U E N O , A r i The Total Synthesis of Herbimycin A 2974
U E N O , Keihei Re-evaluation of the Acid Dissociation Constants
of the Hydroxyl Groups in Tetrasodium 25,26,27,28-Tetrahydroxycalix[4]arene-5,ll,17,23-tetrasulfonate 1012
U E N O , Masanori The Reaction of a 10-Methylacridinium Salt
U E N O , Yoshio Efficient Seienation of Quinones: Synthesis of
U E N O , Yoshio Synthesis of Novel Polycyclic Selenepinone Com
pounds 1794
U G A W A , Akito Crystal Structures of Metallic and Insulating
Molecular Complexes between Naphthaceno[5,6-cd: 11,12ctf]bis[l,2]diselenole and 4,8-Bis(dicyanomethylene)-4i/,8//benzo[l,2-c: 4,5-c]bis[l,2,5]thiadiazole: (TSeN)(BTDA-TCNQ)
and (TSeN)(BTDA-TCNQ)(C H Cl) 3350
U J I T A , Hiroki ESR Spectra of Some Allene Radicals in LowTemperature Matrices 2442
U K A J I , Yutaka Diastereoselective Construction of 2,2,6Trisubstituted Tetrahydropyrans by Intramolecular Alkyla
tion Reaction of Lithium Enolates Generated from a-Alkoxy
Carboxylates 3487
U M A S H A N K E R , V. Spectrophotometric Determination of
U M E D A , Shinichi Partial Oxidation of Methane to Synthesis
U M E H A R A , Michiko Structures and Spectral Properties of
Some Bis(carboxylato)copper(II)-Pyrazole Complexes. I . Prepa
ration
of Bis(trifluoroacetato)tetrakis(pyrazole)copper(II)
2638
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December, 1992]
3559
AUTHOR INDEX
U M E M O T O , Kisaburo An Isomeric Series of Thiophene-Fused
U M E Z A W A , Sumio Synthesis of 3-Deoxy-5-0-mycaminosyltylonolide
and
3-Deoxy-5-0-(4-deoxymycaminosyl)tylonolide
3405
U N E M E , Hideki Synthesis of Non-Ester Pyrethroids Having a
1- Fluoro-l-methylethyl Group Using 1,2-Migration of an Aryl
Group 2401
U N E Y A M A , Kenji Perfluoroalkylation of Olefins by Electrooxidation of Perfluoroalkanoic Acids: Relations between ProductSelectivity and Current Density and Structures of Olefins
1976
UNO, Bunji Spectroscopic Analysis and Geometry Assignment
of the Minimum Energy Conformations of 2-Phenoxypyridines
and Diphenyl Ethers 2697
UNO, Hidemitsu Behaviors of α-Fluorocarbenoids Derived from
the Nucleophilic Desulfinylation of α-Chloro-a-fluoroalkyl Sul
foxides 210
UNO, Hidemitsu Nucleophilic Desulfinylation of a-Fluoro-0(alkoxy and silyloxy) Sulfoxides. Effects of the ß-Oxy Substituents on Protonation, 1,2-Hydrogen Migration, and Nucleophile
U R A B E , Yasuaki Halogenation Using Quaternary Ammonium
Polyhalides. XXXII. Dichlorination of Aromatic Acetyl Derivatives with Benzyltrimethylammonium Tetrachloroiodate
2549
U R A K O V l C , Gordana Two Variants of the Topological Index
and the Relations between Them 14
U R U S H I D O , Kunio Cycloaddition Reactions of 2-Acetylamino-,
2- Alkylamino-, 8-Ethylamino-, and
8-Acetylamino-l-azaazulenes with Dimethyl Acetylenedicarboxylate 1784
U R Y Ü , Norikiyo Magnetic Properties of Oxygen Centered Trinuclear Ruthenium(III) and Rhodium(III) Complexes 198
USHIJIMA, Hirobumi Photochemical Reduction of (rj -Cyclopentadienyl)(l,2-disubstituted
1,2-ethylenedichalcogenolato)cobalt(III) and (r] -Cyclopentadienyl)(l,2-benzenedithiolato)cobalt(III) Complexes in the Presence of Triethanolamine
1047
USHIJIMA, Hirobumi Magnetic Properties of Pyro-Carbons
Prepared from Polyvinyl chloride) and Activated Carbon
1144
U S U D A , Yoshimi Selective Permeation Properties of Inorganic
U S U I , Shuji Pyrrolizidine Alkaloids. The Synthesis and Absolute
Configuration of All Stereoisomers of 4-Carboxy-4-ethyl-3hydroxy-2-isopropyl-4-butanolide, the Necic Acid Component of
Axillaridine 1761
USUI, Yoshiharu Mechanism on the Efficient Formation of
Singlet Oxygen by Energy Transfer from Excited Singlet and
Triplet States of Aromatic Hydrocarbons 897
USUI, Yoshiharu Photochemical Nitration of Benzoic Acid
Derivatives by Irradiation to Nitrate Ions 3183
U T A K A , Masanori A Systematic Study on the Bakers' Yeast
631
UTIMOTO, Kiitiro 1,2-Addition of Allyl and 2-Oxo-2#-pyran-6ylcarbonyl Groups to Cyclic C=N Double Bonds by Means of
UTIMOTO, Kiitiro Isomerization of Olefins by Means of
RsSnH-Et3B and Stereochemical Study on Reduction of
Alkenyl Iodides 349
U T I M O T O , Kiitiro Triethylborane Induced Radical Reaction of
Ketene Silyl Acetais with Polyhalomethanes 1513
U T I M O T O , Kiitiro Reaction of Tantalum-Alkyne Complexes
5
5
U T S U M I , F u m i t a k a The Reactions of Monoalkylthio- or
Nucleophiles: Formation of Polyfunctionally Substituted Pyrroles or Pyrazoles 698
U T S U M I , Kazuo Energy- and Electron-Transfer Pathways in
the Triplet-Sensitized Photolysis of N-(l-Naphthoyl)-0-(/>toluoyl )-N-phenylhydroxylamine with Substituted Benzophenones 1950
UTSUNO, Shunji Preparation, Stereochemistry, and Kinetics of
Isomerization and Racemization of Bis(2,2'-bipyridine Ν,Νdioxide)chromium(III) Complexes Containing an Oxalate or
Malonate Ion 1233
V A R S H N E Y , K r i s h n a Gopal Kinetics of the Forward and
Reverse Na(I)-H(I) and K(I)-H(I) Exchanges on Antimony(V)
Arsenatophosphate Cation Exchanger 2192
V A R S H N E Y , K r i s h n a Gopal Chromatographic Separation of
α-Amino Acids on Antimony(V) Phosphate-Silica Gel 'G' Plates
from Some Synthetic Mixtures and Drug Samples 2773
VASSILEVA, E. Gas Chromatographic Determination of Solva
tion Number by an Investigation of the Extraction Processes
2289
VATSA, Rajesh K u m a r CO2 Laser Induced Sensitized Dissocia
tion of Ethylene Oxide 1691
VELEV, V. Gas Chromatographic Determination of Solvation
Number by an Investigation of the Extraction Processes 2289
V E R M A , J y o t i Paper Chromatographic and Ή NMR Study of
Ion Pair Interactions between N-Dodecanoylhistidine Methyl
Ester and Dodecyl Dihydrogenphosphate in Chloroform 1719
V I R A R A G H A V A N , Saroja Ascorbic Acid: A Jaffe Interference
1101
W A D A , Eiji A New Annulation Reagent, 2-Oxo-3-alkenylphosphonates. Reactions with Carbonyl-Stabilized Carbanions
or Silyl Enol Ethers Leading to Cyclohexenones 2456
W A D A , H i r o k o X-Ray Crystal Structure of Silver(I) Complex
with l,3-Bis(8-quinolylthio)propane 2275
W A D A , H i r o k o Equilibrium and X-Ray Structural Studies on
W A D A , K o u A Systematic Study on the Bakers' Yeast Reduc
tion of 2-Oxoalkyl Benzoates and l-Chloro-2-alkanones 631
WADA,
M a s a n o r i Selective Preparation of l-Halo-2,6dimethoxybenzenes from Bis(2,6-dimethoxyphenyl)dimethyltin
1389
W A D A , Y a s u h i r o Intramolecular [2+2] Photocycloaddition. 14.
Cycloreversion of Cyclophanes Possessing a Cyclobutane Ring
at Their Tether 618
WADA,
Y u j i Photocatalysis of Perfluorinated 01igo(/>Phenylene)s 3439
W A H I , A n u Microdetermination of Rhenium with Sodium Pentacyanonitrosylferrate(III) and Thiocyanate 1631
W A K A M I Y A , T a t e a k i Synthetic Study on Peptide Antibiotic
W A K A M O R I , H i r o y u k i Selective Preparation of l-Halo-2,6dimethoxybenzenes from Bis(2,6-dimethoxyphenyl)dimethyltin
1389
W A K A S U G I , T a k a s h i Preparation of Niobates of Rhodium and
W A K I T A , Hisanobu Thermoanalytical Study of Dioxygencobalt(III) Complexes with
tyN-Ethylenebisisalicylideneaminate) and Its Derivatives 3374
W A N G , P i n g Crystal Structures of TXC -TTF (X=Se,Te)
1482
W A N G , W e i - h s i e n Mechanistic Study of Acid-Catalyzed Proton
W A N G , W h e n - m e i Total Synthesis of Siastatin Β and Its
Enantiomer Using Carbohydrate as a Chiral Educt 978
WASA, T a m o t s u Direct Nebulization of Sample Solution Con
taining Reductant for the Determination of Mercury by Induc
tively Coupled Plasma-Atomic Emission Spectrometry 1165
8
3560
W A T A B E , Ritsuko Determination of Aluminium in Natural
W A T A N A B E , Atsusi Acyliminium Cyclization of Chiral 5(4Alkenyl)-5-hydroxy-2-pyrrolidinone Derivatives 2866
WATANABE,
Hiroto Luminol
W A T A N A B E , Hiroto Peroxidase-Catalyzed
Chemilumines
cence-Delay of Luminol for Determination of Traces of Copper(II) 2501
W A T A N A B E , Hiroyuki Synthesis and Radical Polymerization
of Itaconates Containing an Adamantyl Ester Group 846
W A T A N A B E , Junji Thermotropic Liquid Crystals Based on
Properties 1939
W A T A N A B E , Kunihiro Extraction-Spectrophotometric Deter
mination of Average Valence of Copper in Superconductor YBa-Cu-0 882
W A T A N A B E , Kunihiro Determination of Fluoride Ion by a
Flow Injection Analysis Based on the Formation of a Fluores
cent Aluminium-Schiff Base Complex 911
W A T A N A B E , Kunio Volumetric and Thermal Behaviors of
W A T A N A B E , Masami Growth Process of ZSM-5 Zeolite Film
146
W A T A N A B E , Masataka A Stereocontrolled Synthesis of (4aS,
8a/?)-(+)-7,7-Ethylenedioxy-4,4,8a-trimethyloctahydro-2(l//)naphthalenone 2071
WATANABE,
Midori Formation of Through-Ring aCyclodextrin Complexes with α,ω-Alkanedicarboxylate Anion.
Effects of the Aliphatic Chain Length and Electrostatic Factors
on the Complexation Behavior 164
W A T A N A B E , Seiichi Electronic Absorption and PhO§phorg§cence Spectra of 2-Acetylfuran. Conformations in the Ground
and Excited Triplet States 2067
W A T A N A B E , Shunsuke Perfluoroalkylation of Olefins by
Electrooxidation of Perfluoroalkanoic Acids: Relations between
Olefins 1976
W A T A N A B E , Tadashi Epimerization of Chlorophyll Deriva
tives. V. Effects of the Central Magnesium and Ring Substitu
ents on the Epimerization of Chlorophyll Derivatives 3080
W A T A N A B E , Tadashi Pheophytinization of Eight Chlorophyll
W A T A N A B E , Yasumasa Radical Intermediates in the Ther
mal Decomposition of l,l-Bis(f-butyldioxy)cyclohexane 664
W A T A N A B E , Yasumasa Simultaneous Generation of /-BuOand /-BuOO- from the Decomposition of 2,2-Bis(/butyldioxy)propane. A New Synthetic Method for Introducing a
f-BuOO Group into Organic Molecules 2063
W A T A N A B E , Yasuo Mössbauer Emission Spectroscopy of Fe
W A T A N A B E , Yoshihiko Efficient Seienation of Quinones:
Synthesis of Novel Benzo[6]naphtho[2,3-e]selenintrione and
Dibenzo[o,e]seleninone 1291
W A T A N A B E , Yoshihiko Synthesis of Novel Polycyclic Selenepinone Compounds 1794
W A T A N A B E , Yoshihiro Photochemical Reduction of (r? Cyclopentadienyl)(l,2-disubstituted
1,2-ethylenedichalcogenolato)cobalt(III)
and
(77 -Cyclopentadienyl)(l,2-benzenedithiolato)cobalt(III) Complexes in the Presence of Triethanolamine 1047
W A T A N A B E , Yoshihito Synthesis of Alkyl Substituted pBenzoquinones from the Corresponding Phenols Using Molecular Oxygen Catalyzed by Copper(II) Chloride-Amine Hydrochloride Systems 1522
W A T A N A B E , Yuko Synthesis and Properties of T-Cage-Type
Se-Bridged Polynuclear Co(III) and Rh(III) Complexes with 2Aminoethaneselenolate (aese). Crystal Structure of [(Co57
57
5
5
[Vol. 65, No. 12
(aese)3l4Zn 0](C104)6 3015
W A T A R A I , Hitoshi Tautomerization and Dissociation Equilibria of ß-Diketones in Microemulsions 170
WEI,
Xian-Yong FeSi-Catalyzed Hydrocracking of D i ( l naphthyl)methane. Effects of Hydrogen Pressure, Catalyst
WEI,
Xian-Yong FeS -Catalyzed Hydrocracking of α,ωDiarylalkanes 1114
X U , Ming Sequence Dependent Cyclization-Cleavage of Dipeptides from the Oxime Resin and Its Prevention 991
X U , Qiang Molecular Motions in Solid CD3NHsPbBr as Studied
by Ή NMR 2264
X U , Xiao-Hong The Reactions of Nitrile Oxide-Quinone
Cycloadducts.
I I . The
Reactions of 2,5-Di-/-butyl-/>benzoquinone with Nitrile Oxides: 1:2 Cycloaddition and Base
YADA, Satoru Aromatization of Ethylene and C Hydrocarbons
Using a Thermal Diffusion Column 274
YAGI, Takehiko Absorption Spectra and Electrical Resistivities
of Bis(l,2-dionedioximato)nickel(II) Complexes at High Pres
sures 1078
YAGI, Yoshiharu Studies on Nickel-Containing Ziegler-Type
Catalysts. I . New Catalysts for High-cis-l,4-polybutadiene
1299
YAJIMA, Fumikazu Selective Separation of Yttrium Ions from
Other Rare Earth Ions Using Nonequilibrium Extraction 29
Y A K U S H I , Kyuya Crystal Structures of Metallic and Insulat
ing Molecular Complexes between Naphthaceno[5,6-ai: 11,12r'i/]bis[l,2]diselenole and 4,8-Bis(dicyanomethylene)-4//,8//benzo[l,2-c: 4,5-r']bis[l,2,5]thiadiazole: (TSeNXBTDA-TCNQ)
and (TSeNXBTDA-TCNQXCeRsCl) 3350
YAMADA, Akiko The Kinetic Study of the Oxygen-Exchange
Water 1397
YAMADA, Akira Preparation of Bis(phthalocyaninato)lutetium
with Various Substituents and Their Electrochemical Proper
ties 250
YAMADA, Fukiko The Stereochemistry of the Sulfur Atom of
4,7-Dimethyl-6-phenyl-5,6,7,8-tetrahydro-4//-l,3,2,6-dioxathiazocine 2-Oxides 2294
YAMADA, Hiromichi Comparison of 2,4-Hexadienoic with 1Hexanoic Acids as Extractant for Copper(II) 186
YAMADA, Hitoshi 1:1 Adduct Ion Formation of Simple Car
Modifications 1275
YAMADA, Kazutoshi Chiral Hydantoin; A New Dienophile for
YAMADA, Kazutoshi Intramolecular Radical Cyclization of
YAMADA, Kazutoshi Oxidative Substitution Reactions of
Organostannyl Compounds with Lead Tetraacetate. A Conven
ient Route to 5-Alkylidene-2(5//)-furanones 2366
YAMADA, Kazutoshi Noncatalyzed Conjugate Addition Reac
tion of Alkylaluminum Compounds to 5-Methylene-2,4imidazolidinedione Derivative 3195
YAMADA, Keiko Radical-Based Synthesis of Terpenoids. Ster
YAMADA, Kiyoyuki A New Bromo Diterpene, #*-Aplysin-20,
and ewMsoconcinndiol from the Marine Mollusc Aplysia kurodai 2300
YAMADA, Masaki Synthesis and Properties of DiaminoSubstituted Dipyrido [3,2-A: 2',3'-c]phenazine 1006
YAMADA, Masaki Oxidative Chlorination of 1,10-Phenanthroline and Its Derivatives by Phosphorus Pentachloride in Phosphoryl Chloride 2007
YAMADA, Miho Phase Separation of Phosphotellurite Glass
Investigated by Fe-Mössbauer Spectroscopy and DTA 2540
4
2
3
4
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Y A M A D A , Misako Oxidative Coupling of Methane over Var
ious Barium Salts Mixed with CaO: The Relation with Their
Surface Basicities 2251
Y A M A D A , Ryoichi Hydrates of Organic Compounds. XVII. The
Effect of Cations on the Formation of Hydrates of Poly(tetraisopentylammonium acrylate) 2704
Y A M A D A , Sachiko Thermochromism of 5,10,15,20-Tetraarylporphyrins at Low Temperature 3358
Y A M A D A , Takashi Manganese(II and III)-Mediated Synthesis
of Cyclic Peroxides from Alkenes, Active Methylene Com
pounds, and Molecular Oxygen 1371
Y A M A G A T A , Nobutsugu Oxidative Coupling of Methane over
Various Barium Salts Mixed with CaO: The Relation with
Their Surface Basicities 2251
Y A M A G A T A , Satoshi Synthesis and Some Reactions of 2Amino-l-azaazulene-3-carbaldehyde 340
Y A M A G U C H I , Fumihiko First Synthesis and Deodorant Activ
ities of Compounds Isolated from Thyme (Thymus Vulgaris L.)
and Their Analogues 1159
Y A M A G U C H I , Hiromasa The Stereochemistry of the Sulfur
Atom of 4,7-Dimethyl-6-phenyl-5,6,7,8-tetrahydro-4//-l,3,2,6dioxathiazocine 2-Oxides 2294
Y A M A G U C H I , Kazuhiko A New Ketyl Radical Probe. Dehalogenation of o-Halobenzophenone 1157
Y A M A G U C H I , Kazuo Rotational Distribution of CO(b I ) Pro
duced in Energy Transfer Reaction from Ar( P ) to CO 1713
Y A M A G U C H I , Koji Metallic Nickel-Catalyzed Reduction of
Aryl Halides with Zinc Powder and Ethanol 1739
Y A M A G U C H I , Masaru Stereoselective Synthesis of (±)-Ireland
Y A M A G U C H I , Ryohei 1,2-Addition of Allyl and 2-Oxo-2//3
3
+
2
pyran-6-ylcarbonyl Groups to Cyclic C^N Double Bonds by
Means of Organotin Reagent for Alkaloids Synthesis; A Facile
Synthesis of 8-Oxoprotoberberine and Norketoyobirine
(Demethoxycarbonyloxogambirtannine) 298
Y A M A G U C H I , Tadashi Magnetic Properties of Oxygen Cen
tered Trinuclear Ruthenium(III) and Rhodium(III) Complexes
198
Y A M A G U C H I , Tadashi X-Ray Structure, Ligand Substitution,
and Other Properties of Trinuclear Ruthenium Complex,
[RuaWOXM-CeHsCOOMpyMPFe) (py=pyridine), and X-Ray
Structure of Dinuclear Ruthenium Complex, [RU (MC H COO) Cl] 1585
Y A M A G U C H I , Takeo Photochromism of Hemithioindigo Deriv
atives. I . Preparation and Photochromic Properties in Organic
Solvents 649
Y A M A G U C H I , Takeo Photochromism of Hemithioindigo Deriv
atives. I I . Photochromic Behaviors in Bilayer Membranes and
Related Systems 657
Y A M A G U C H I , Takeo High-Pressure Effect on the Radical
Reduction of Spin Probes in Human Erythrocytes 1648
Y A M A G U C H I , Tatsuaki Aromatization of Ethylene and C
Hydrocarbons Using a Thermal Diffusion Column 274
Y A M A G U C H I , Tatsuaki Thermal Reactions of Toluene by Use
of a Clusius-Dickel Type Thermal Diffusion Column as a
Reactor 586
Y A M A G U C H I , Tatsuaki Removal of Phosphate from Dilute
Phosphate Solution by an Iron Chitosan Complex to Be Used as
an Oral Sorbent 1866
Y A M A G U C H I , Tatsuaki The Effect of the Coexistent Gases on
the Thermal Reaction of Toluene or Methane in a ClusiusDickel Type Thermal Diffusion Column 3434
Y A M A K A W A , Koji 1-Haloalkyl A r y l Sulfoxides as Useful
Agents in Synthesis of α-Halo Ketones: A New Synthesis of aHalo Ketones, α-Halo α,/3-Unsaturated Ketones, and α-Halo
Cross Dienones from Aldehydes 2800
Y A M A K A W A , Koji A Novel Synthesis Including Asymmetric
Synthesis of α,/3-Unsaturated 7-Hydroxy Carbonyl Compounds
2
6
5
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AUTHOR INDKX
4
4
Y A M A K A W A , Koji Prismatic and Antiprismatic [4 ]Ferrocenophanes ([4](1,10[4}(3,3> and [4](l,l')l4)(3,4 )Ferrocenophanes) 3275
Y A M A K O S H I , Yukiyasu Relaxation Phenomena of the Con
centration Polarization in High Temperature Air Cathodes
995
Y A M A M O T O , Gaku Atropisomerism in Doubly ên-Substi
tuted 9-(2-Methylbenzyl)triptycene Derivatives, 8-Chloro- and
8-Bromo-1,4-dimethyl-9-(2-methy lbenzyl)triptycenes 1957
Y A M A M O T O , Gaku Rotational Isomerism and Atropisomerism
in Acetal Derivatives of l,2,3,4-Tetrafluorotriptycene-9carbaldehyde 1967
Y A M A M O T O , Gaku Ή and CNMR Spectral Behavior and
Y A M A M O T O , Gaku Structural Studies of Arylazo(a,adimethylbenzyl)malononitriIes. Evidence against the Correla
Reactions 2394
Y A M A M O T O , Hideo Surface Alkoxylation of Silicas by Mild
Reactions w i t h Alcohols 728
Y A M A M O T O , Hiroshi Orientation of the Addition of Dimethyl
Phosphonate
to
1154
Y A M A M O T O , Hiroshi Orientation of the Addition of Dimethyl
Phosphonate
to
1154
Y A M A M O T O , Hiroshi Synthesis of 2-Amino-2,5,6-trideoxy-5phenylphosphinyl-L-galactopyranose. The P-in-the-Ring Ana
Y A M A M O T O , Hiroshi Synthesis of 2-Amino-2,5,6-trideoxy-5phenylphosphinyl-L-galactopyranose. The P-in-the-Ring Ana
Y A M A M O T O , Hiroyuki Ή and C NMR Spectral Behavior and
Y A M A M O T O , Hisashi On the Mechanism of Organoaluminum-Promoted Claisen Rearrangement of Allylic Vinyl
Ethers 541
Y A M A M O T O , Hisashi Asymmetric Diels-Alder Reaction of
Cyclopentadiene and Methyl Acrylate Catalyzed by Chiral
Organoaluminum Reagents 3501
Y A M A M O T O , Ichiro Optical Resolution by Preferential Crys
tallization of 2-(3,4-Carbonyldioxyphenyl)-2-(phthalimidooxy)acetic Acid, a Key Intermediate of Cephalosporin Antibiotic M14659 3288
Y A M A M O T O , K a z u k i Electron-Laser Dual Beam Irradiation of
2-Methylbenzophenone 3186
Y A M A M O T O , Kimihisa Simultaneous Formation of a Polypyrrole Film and a Tantalum Oxide Layer by Electrochemical
Oxidation 1860
Y A M A M O T O , Kimihisa Synthesis of Soluble Poly(thio-2,6dimethyl-l,4-phenylene) by Oxidative Polymerization of
Y A M A M O T O , Koji Synthesis, Characterization, and Properties
of V 0 - L n ( I I I ) (Ln=La, Pr, Eu, Gd, Tb) Complexes of Ν,Ν'Bis(3-carboxysalicylidene)ethylenediamine 2514
Y A M A M O T O , Makoto Chiral Hydantoin; A New Dienophile for
Y A M A M O T O , Makoto Intramolecular Radical Cyclization of
Y A M A M O T O , Makoto Oxidative Substitution Reactions of
Organostannyl Compounds with Lead Tetraacetate. A Conven
ient Route to 5-Alkylidene-2(5//)-furanones 2366
Y A M A M O T O , Makoto Noncatalyzed Conjugate Addition Reac
tion of Alkylaluminum Compounds to 5-Methylene-2,4imidazolidinedione Derivative 3195
Y A M A M O T O , Masahide Photochemical Reactions of 42
/
13
13
IV
3562
[Vol. 65, No. 12
Acylstyrenes. Effects of Acyl Substituents on Photocyclodimerization via an Excited Triplet State 837
Y A M A M O T O , Masahide Stabilization Energy of the 9,9'Trimethylenedianthracene Radical Cation Estimated by the
Y A M A M O T O , Masako The Kinetic Study of the OxygenExchange Reaction of Some Alkylarsonates and Dialkylarsi
nates with Water 1397
Y A M A M O T O , Mineko Thermodynamic and NMR Studies on
the Complexation
of Lanthanoid(III) Ions with oPhenylenediamine-N,N,N',yV'-tetraacetate in Aqueous Solu
tions 1566
Y A M A M O T O , Nobuhiro Re-evaluation of the Acid Dissociation
Constants of the Hydroxyl Groups in Tetrasodium 25,26,27,28Tetrahydroxycalix[4]arene-5,ll,17,23-tetrasulfonate 1012
Y A M A M O T O , Shin-ichi Reaction of Olefins with Dimethyl(methylthio)sulfonium Salts in the Presence of Triphenylphosphine. Preparation of Vinylphosphonium Salts 2375
Y A M A M O T O , Shunzo Mercury(6 Pi)-Photosensitized Decom
position of Tetramethyllead 1710
Y A M A M O T O , Shunzo Temperature and Pressure Effects on
the Reversible Reaction of a Parent Phenol (GH) Corresponding
to Galvinoxyl with Aliphatic Amines 2437
Y A M A M O T O , Shunzo Thermal and Infrared Multiphoton
Decompositions of y-Butyrolactone in the Vapor Phase 3112
Y A M A M O T O , Shunzo ESR Studies at High-Pressure. IV. SpinExchange Reactions of Various Types of Nitroxides in Some
Y A M A M O T O , Takashi Bis(2-(dimethylphosphino)ethane-lthiolato)-nickel(II), -palladium(H), and -platinumflU Complexes,
Y A M A M O T O , Yasushi Optical Resolution of Phenylalanine
3
and Mandelic Acid by Complex Formation with CopptT(II) Ion
3149
Y A M A M O T O , Y a s u s h i A Convenient Method for the Prepara
tion of Hydrogensiloxanes 3203
Y A M A M O T O , Yoshihisa Cobalt(III) Complexes with Quadridentate Ligands. XL The Preparation and Properties of cis-aIsomer of the Salicylato(triethylenetetramine)cobalt(III) Com
plex 283
Y A M A M U R A , Kazuo Exchange-Storage of a Guest Molecule in
an Inclusion Crystal of 2,11,20,29-Tetramethyl-2,11,20,29tetraaza[3.3.3.3]paracyclophane 805
Y A M A M U R A , Shosuke Citreobenzofurans A, B, and C, First
Isolation of Sesquiterpene-Type Metabolites of a Hybrid Strain
KO 0031 Derived from Penicillium Citreo-vinde B. IFO 4692
and 6200 926
Y A M A M U R A , Shosuke Syntheses of trans- and as-3-Methoxy4-methylthio-2-piperidinethiones. Previously Proposed Struc
YAMAMURA,
Takeshi
Tetrakis(thioiato)nickelate(II),
[Ni(RS)4] "; Ligand Dissociation and Electronic Spectra 1799
Y A M A N A K A , Michinari Crystal Structures and Magnetic
Properties of Binuclear Copper(II) Complexes with Alkoxo and
Benzoato or Silanecarboxylato Bridges 2739
Y A M A N A K A , Shoji Preparation and Properties of Clays Pil
Y A M A N E , Kameji Synthesis and Some Reactions of 2-Amino-lazaazulene-3-carbaldehyde
340
Y A M A N E , T a k a s h i Crystal Structures of iV-Benzoyl Deriva
tives of 8-Oxa-6-azabicyclo[3.2.1]octan-7-one, ε-Caprolactam
Y A M A N E , T a k a s h i Crystal Structure of JV-Cinnamoyl-8-oxa-6azabicyclo[3.2. l]octan-7-one 1138
Y A M A N I S H I , Hiroko Halogenation Using Quaternary Ammo
2
2
2
Y A M A O K A , K i w a m u Electric Field Orientation of Ionizable
Polymers with Three Different Electric Dipole Moments. I .
New Orientation Function and the Steady-State Electric Bire
fringence of Poly(L-a-glutamic acid) in Methanolic and Aqueous
Solutions 129
Y A M A S E , Toshihiro WNMR and X-Ray Crystallographic
Studies on the Peroxo Complexes of the Ti-Substituted aKeggin Typed Tungstophosphates 1453
Y A M A S H I T A , Hiroshi Optical Resolution of Phenylalanine and
Mandelic Acid by Complex Formation with Copper(II) Ion
3149
Y A M A S H I T A , Masakazu Hydroacylation of Alkyl Vinyl
Ketones and Acrylic Esters Using Organotetracarbonylferrates. Synthesis of 1,4-Dicarbonyl Compounds 1257
Y A M A S H I T A , Mitsuji Novel Synthesis of 2-Phosphinoylphospholane 1-Oxide Derivatives 2004
Y A M A S H I T A , Tetsushi Two Conformers and Aggregation of
Cyclic Octapeptide, cyc/o(G-eLL-G) , in Chloroform 917
Y A M A S H I T A , Yoshiro Crystal Structures of Metallic and
Insulating Molecular Complexes between Naphthaceno[5,6-c</:
ll,12-c'i/]bis[l,2}diselenole and 4,8-Bis(dicyanomethylene)4//,8//-benzo[l,2-c: 4,5-c]bis[l,2,5]thiadiazole: (TSeNXBTDATCNQ) and (TSeNXBTDA-TCNQXC H Cl) 3350
Y A M A T A K A , Hiroshi A New Ketyl Radical Probe. Dehalogenation of o-Halobenzophenone 1157
Y A M A T A K A , Hiroshi Diastereoselectivity and Reaction Path
way of the Reactions of Benzaldehyde with Allylic Iodides in
the Presence of Sn or Pb 2145
Y A M Α Τ Ο , Yo l,3-Bis(salicylideneamino)-2-propanol as the
Ligand for Manganese(III) Ions 1466
Y A M A T O , Yo Synthesis, Properties, and Crystal Structures of a
Series of Dinuclear Manganese(III) Complexes with 1,5Bis(salicylideneamino)-3-pentanol and Various Anions: Forma
tion of a Tetranuclear Manganese(III) Complex 2624
Y A M A U C H I , Masahiro Optical Resolution by Replacing Crys
tallization of (/?S)-4-Thiazolidinecarboxylic Acid w i t h L-Amino
Y A M A U C H I , Osamu Copper(II)-Thioether Bondings in Multidentate N,S-Donor Ligand Complexes. Structural Dependence
of the Chemical Properties of the Copper(II) Complexes of 1,5*
Bis(2-pyridylmethylamino)-3-thiapentane
and
2,6-Bis(2,6dithiaheptyl)pyridine 786
Y A M A U C H I , Seigo A Time-Resolved EPR Study on the Photo
Y A M A W A K I , Kunihiko Molecular and Crystal Structure of
3,5,5-Trimethyl-2-(2-methyl-2-nitropropyl)-2-cyclohexen-l-one
Possessing Molecular Asymmetry 2860
Y A M A Z A K I , Iwao Synthesis and Intramolecular ElectronTransfer Reaction of Distance-Fixed Quinone-Linked Porphy
rins 2807
Y A M A Z A K I , Masayo Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose 3257
Y A M A Z A K I , Norimasa An Isomeric Series of Thiophene-Fused
Structures 2173
Y A M A Z A K I , Norimasa An Isomeric Series of Thiophene-Fused
Tetracyanoquinodimethanes. I I I . Crystal Structures of ChargeTransfer Complexes with T T F 2180
Y A M O C H I , Hideki Crystal Structures of T X C - T T F (X=Se,Te)
1482
Y A N A G I D A , Shozo Photocatalysis of Perfluorinated 0\igo(pPhenylene)s 3439
Y A N A I , Toshiaki 130-Hydroxylation of Milbemycins by Sele
nium Dioxide 3300
Y A N O , Katsunori Allylation of Aldehydes by Allyl- and Crotyltributyltin in the Presence of Catalytic Amounts of Bu SnCl
Complex 66
Y A S U D A , Hajime Unique Molecular Structures of Tungsten
Phenoxides 1197
183
2
6
5
8
2
2
December, 19921
AUTHOR INDEX
Y A S U D A , Kensei Vapor Phase Carbonylation of Organic Halo
Compounds 289
Y A S U D A , Masahide Ring-Splitting Reaction of 2,2-Diarylthietane by Electron-Transfer Photosensitization of 9,10Dicyanoanthracene 1472
Y A S U D A , Masako Inclusion Mode of 8-AnilinoT-naphthalenesulfonate (ANS) in the ANS-jS-Cyclodextrin Complex 2869
Y A S U D A , N o r i y a s u Solvent Extraction of Divalent Metals as
Y A S U E , Nobuyuki A Facile Generation and Stereoselective
Cycloaddition Reactions of 5,6-Dihydro-5,6-bis(methylene)2,4(l#,3//-)-pyrimidinedione Intermediate 2845
Y A S U I , Masanori An Isomeric Series of Thiophene-Fused
Structures 2173
Y A S U I , Masanori An Isomeric Series of Thiophene-Fused
Y A S U I , Seimei Studies on Nickel-Containing Ziegler-Type Cata
lysts. I I . Low Molecular Weight (Liquid) Poly(diene)s with 1,4Microstructure 1307
Y A S U I , Takaji The Isomerism of the (Ethylenediamine-N, ΛΓdipropionatoXethylenediamine)cobalt(III) Ion and Its Stereose
lective Isomerization Reaction 175
Y A S U I , Takaji Preparation and Stereochemistry of the MixedLigand Complex, Ammine(ethylenediamineXethylenediamineN-acetato)cobalt(III) 1920
Y A S U M O R I , Iwao Electrochemical Studies of Poly(mercaptohydroquinone) and Poly(mercapto-/>-benzoquinone) Films Pre
pared by Electrochemical Polymerization. VI. Electroreduction
Y A S U M O T O , Masahiko Reaction of 1,3-Oxathiolium Salts
with Three Types of Ring Expansion Reagents on a Nitrogen
Atom 668
Y A S U M O T O , Masahiko Preparation of 1,4,2-Dithiazolium
Salts 920
Y A S U N A M I , Masafumi Synthesis of a Polycyclic π-Conjugated
Pyrolytic Method. I . Synthesis and Properties of Cyclopent[a)azulenes 1527
Y A S U N A M I , Masafumi Peri-Selective Cycloaddition Reactions
of 3-Methoxycarbonyl-2//-cyclohepta[o]iuran-2-one with 6,6Dimethylfulvene 2127
Pyrolytic Method. I I . Synthesis and Paratropic Properties of
3//-Cyclopent[ß]azulen-3-one and Its Methyl Derivatives 2131
Pyrolytic Method. I I I . Synthesis and Properties of 4-Hydroxy3//-cyclopent[fl ]azulen-3-one 3282
Y A S U O K A , N o r i t a k e Crystal Structures and Molecular Pack
ing of Tetrakis(alkylthio)tetrathiafulvalene ( T T C „ - T T F ) ; Part
I («=3, 4, 6) 1878
Y A S U O K A , N o r i t a k e Crystal Structures and Molecular Pack
ing of Tetrakis(alkylthio)tetrathiafulvalene ( T T C « - T T F ) ;
(Part II) (»=7,9,11) 2086
Y A T O M E , Chizuko Effect of Inhibitors on Azo-Reduction of 4'Dimethylaminoazobenzene-2-carboxylic Acid by Clostridium
Diaphorase 2349
Y A T S U G I , Ken-ichi Solvent Effects on the Solvolysis of Neophyl Tosylates 46
Y I N , Yuan-Gen Preparation of Niobates of Rhodium and Nickel
by Chemical Mixing Methods 3218
YODO, Hiromi Stoichiometries and Equilibrium Constants of
Y O K O I , Hiroshi A Magnetic Study of the Iron(III) Complexes of
Polyols and Sugars in Aqueous Solution 1898
Y O K O I , Hiroshi Solution Equilibrium and EPR Study of the
3563
Y O K O Y A M A , Haruhiko Conductometric Study of Ion Associa
tion between Tris(ethylenediamine)cobalt(III) Ion and Monova
lent Anions at Temperatures from 0 to 50 °C 2901
Y O K O Y A M A , Isao Simulation of Vibrational Spectra of Acetic
Acid by an Extended Molecular Mechanics Method and Half
Band Width Parameters 746
Y O K O Y A M A , Yukihiro Ή NMR Study of 2,3-Dicyanobicyclo[2.2.2]octa-2,5,7-triene Partially Oriented in a Nematic Phase
906
Y O K O Y A M A , Yukihiro An NMR Study of the Carbanions
Produced from Triphenylethylene and Its Methyl-Substituted
Derivatives 2162
Y O K O Y A M A , Yukihiro ESR Spectra and Electronic States of
1,10-Phenanthroline Radical Anions 2839
Y O N E K U R A , K a z u k i Reaction of Olefins with Dimethyl(methylthio)sulfonium Salts in the Presence of Triphenylphosphine.
Y O N E M O T O , Katsumi Reaction of 1,3-Oxathiolium Salts with
668
Y O N E M O T O , Katsumi Preparation of 1,4,2-Dithiazolium Salts
920
Y O N E M U R A , Toshiaki Stereoselective Formation and Some
Properties of Polynuclear Cobalt(III) Complexes with DPenicillaminate 794
Y O N E M U R A , Yasunobu Spectrophotometric Determination of
Thiocyanate by Its Oxidation with Iodate 3153
Y O N E S E , Masakatsu Mechanochemical Reaction of Calcium
Alginate Hydrogel due to a Counterion Exchange 121
Y O N E Y A M A , Yoshiharu Coal Solubilization with Cadmium
and Butyl Iodide under Mild Conditions 1067
Y O R I S U E , Tomohiro Electron-Transfer Reactions from
Hydroquinone Dianions to 10-Methylacridinium Ion and a
Cobalt(HI) Porphyrin 715
Y O S H I D A , Hiroshi The Reactions of Monoalkylthio- or
Y O S H I D A , Isao Re-evaluation of the Acid Dissociation Con
Y O S H I D A , Kazuhiro A New Synthetic Method for α-Οχο-/3,γunsaturated Esters 3209
Y O S H I D A , Masafumi Solution Properties of Poly(4-vinylpyridine) in Aqueous Solutions of Sulfuric Acid 3108
Y O S H I D A , Masahiro A Novel Isobenzof uran Derivative Under
going Photovalence Isomerization 932
Y O S H I D A , Shin-ichi Syntheses of Aryltetralin Lignans: Con
cise Syntheses of (±)-Isopodophyllotoxone, (±)-Picropodophyllone and Their Related Compounds 3495
Y O S H I D A , Tadayoshi Structure and Orientation of oPhenylene Phosphorochloridite and o-Phenylene Phosphorochloridate Dissolved in a Nematic Phase 1135
Y O S H I D A , T a k e o Aromatization of Ethylene and C4 Hydrocar
bons Using a Thermal Diffusion Column 274
Y O S H I D A , Toshiharu Hydrolytic Metalloenzyme Models.
Metal Ion Dependent Site-Selective Acylation of Hydroxyl
Groups of Bis-Imidazole Ligands Catalyzed by Z n and C u in
the Reaction with />-Nitrophenyl 2-Pyridinecarboxylate in a
Cationic Surfactant Micelle 373
Y O S H I D A , Y a s u k a z u Oxidation of Phosphatidylcholine Lipo
somes in Aqueous Dispersions Induced by Copper and Iron
1849
YOSHIDA,
Zen-ichi Efficient Synthesis of 2-Vinyl-ybutyrolactones and 2-Vinyl-y-butyrolactams by PalladiumCatalyzed Decarboxylative Carbonylation 97
Y O S H I D A , Zen-ichi A Novel Isobenzofuran Derivative Under2+
2+
3564
going Photovalence Isomerization 932
Y O S H I F U J I , Masaaki Preparation and Isomerization of 3,4Bis(2,4,6-tri-/-butylphenylphosphinidene)cyclobutenes 2297
Y O S H I F U J I , Masaaki Synthesis of a Polycyclic π-Conjugated
Pyrolytic Method. I I I . Synthesis and Properties of 4-Hydroxy3//-cyclopent[a ]azulen-3-one 3282
YOSHIHARA,
Nobutoshi Selective α-Mono- and α,αDialkylations of 1,3-Diketones Using Solid Base Prepared from
Sodium Ethoxide and Alumina 1185
Y O S H I I , Mikio Chemical State Analysis of Sn-Sb-0 Solid Sur
faces by Auger Electron Spectroscopy: Differentiation of Sb(III)
andSb(V) 2709
Y O S H I K A W A , Kohji A New Bromo Diterpene, #i-Aplysin-20,
and ewMsoconcinndiol from the Marine Mollusc Aplysia kurodai 2300
Y O S H I K A W A , Mikio Preparation and Properties of Clays Pil
Y O S H I K A W A , Sadao Syntheses and Structures of Novel
Ruthenium(II)-Chiral Diphosphine Complexes 1595
Y O S H I M O T O , Yasuyuki Synthesis and Properties of DiaminoSubstituted Dipyrido [3,2-a: 2',3'-c]phenazine 1006
Y O S H I M U R A , Masabumi A Flash Photolysis Study of C H - 0
Mixtures behind Shock Waves: Examination of Reaction of
2
2
4
CH3+O2
2
1317
Y O S H I M U R A , Takashi Reactions of Hydridoruthenium(II)
Complexes with Alkyl Allylic Sulfides 3027
Y O S H I M U R A , T a k u y a Synthetic Study on Lipoteichoic Acid of
Gram Positive Bacteria. I . Synthesis of Proposed Fundamental
Structure of Streptococcus pyogenes Lipoteichoic Acid 2643
Y O S H I M U R A , Tetsuhiko Bis(l-methylimidazole)iron(Ii) Com
plexes of Porphyrins Substituted with Highly ElectronWithdrawing CF Groups: Electronic Spectra With Split QBands and MCD Spectra with Unusual Features 1915
Y O S H I M U R A , Toshiaki Thermal Behavior and Mass Spectra
Acid 1993
Y O S H I N O , Akihiro Structure and Orientation of o-Phenylene
Phosphorochloridite and o-Phenylene Phosphorochloridate Dis
solved in a Nematic Phase 1135
Y O S H I N O , Akihiro An NMR Study of the Carbanions Produced
from Triphenylethylene and Its Methyl-Substituted Deriva
tives 2162
Y O S H I N O , Akihiro CNMR Study of Chloro- and Methylthiophenium Ions 3228
3
13
[Vol. 65, No. 12
YOSHINO, Norio Syntheses of Azobenzene Derivatives Having
YOSHINO, Takanori Solvent Effects on the Solvolysis of Neophyl Tosylates 46
Y O S H I O K A , Hideki Lattice Parameters of Sol-Gel Derived
Metastable Zr0 -CaO Solid Solutions 2756
Y O S H I O K A , Michikazu Photochemical Reactions of 4-Oxo Carboxylic Esters: Remote Hydrogen Abstraction and Cis-Trans
Isomerization 3498
Y O S H I O K A , Shoji The Calculation of Temperature and Ther
mal Stress Distributions in the Planar Solid Oxide Fuel Cell
309
Y O S H I T O M I , Suehiko Direct Iodination of Aromatic Com
pounds with Iodine and Alumina-Supported Copper(II) Chloride
or Sulfate 306
Y O S H I Z U M I , Kazuyuki Reaction of Tantalum-Alkyne Com
plexes with Isocyanates or Acyl Cyanides. Stereoselective
Functionalization of Carbon-Carbon Triple Bonds 1543
Y O T S U Y A N A G I , Takao Determination of Aluminium in Natu
ral Waters by Ion-Pair Reversed-Phase Partition HPLC 3192
Y U A N , Xinghai Preliminary Analysis of the Electronic Absorp
tion Spectrum of a Solute in a Biaxially-Stretched Polymer
Film 463
Y U C H I , Akio X-Ray Crystal Structure of Silver(I) Complex with
1,3-Bis(8-quinolylthio)propane 2275
Y U C H I , Akio Equilibrium and X-Ray Structural Studies on
Y U K I , Yasuo Triphenylselenonium Salts as Effective PhaseTransfer Catalysts 2555
Z E N , Shonosuke Dehydrative Glycosylation Using Heptabenzyl
ZHANG, Run Ping Synthesis and Intramolecular ElectronTransfer Reaction of Distance-Fixed Quinone-Linked Porphy
rins 2807
ZHOU, Guo-Ding Detection of Pitting on Cast Iron with AC
Impedance Spectroscopy 2315
Z H U A N G , Xiumin Oxidation of Alcohols with Peracetic Acid in
Ethyl Acetate in the Presence of Sodium Bromide 703
ZONG, Zhi-Min Photobromination of Side-Chain Methyl Groups
on Arenes with N-Bromosuccinimide —Convenient and Selec
tive Syntheses of Bis(bromomethyl)- and (Bromomethyl)methylarenes— 345
2
3080
Bull. Chem. Soc. Jpn.. 65, 3080 -3087 (1992)
© 1992 The Chemical Society of Japan
[ V o l . 65, No. 11
E p i m e r i z a t i o n of C h l o r o p h y l l Derivatives. V .
Effects of the Central Magnesium a n d R i n g Substituents
o n the Epimerization of C h l o r o p h y l l Derivatives
H i t o s h i M A Z A K I , Tadashi WATANABE,* T e r u m i TAKAHASHI,
A n d r e a s STRUCK,* and H u g o SCHI-T-R *
Institute of Industrial Science, The University of Tokyo,
Roppongi, Minato-ku, Tokyo 106
t Botanical Institute, The University of Munich,
D-8000 Munich 19, Germany
(Received June 29, 1992)
1
Kinetic and equilibrium features of the epimerization in six C13 -epimer pairs of chlorophyllous pigments,
namely chlorophyll (Chi) a\a\ Chi b/b\ pheophytin (Pheo) aja\ Pheo h\b\ C20-chlorinated Chi (Cl-Chl) a\ a\ and
Cl-Pheo a/a\ catalyzed by bases (triethylamine, pyrrolidine, and piperidine) and by Lewis acids (magnesium
acetylacetonate and magnesium chloride), have been studied in diethyl ether and methanol. A significant difference
was noted in the epimerization rate and equilibrium epimeric composition among the pigment systems. The
difference in the rate constants was rationalized in terms of the ease in C13 -proton detachment, affected by the ring
π-electron density which in turn depends on the electron donation or withdrawal by the central metal and/or ring
substituents. For Lewis acid-catalysis, a dominant factor appears to be the stabilization of the CH'-enolate anion
via formation of a loose complex with extraneous M g . A synergistic action of a base (triethylamine) and a Lewis
acid ( M g ) was observed for the epimerization or enolization of Pheo a/a' in methanol.
2
2
2+
2+
C h l o r o p h y l l o u s p i g m e n t s , except f o r bacteriochlorop h y l l ( B C h l ) c, d, and e l a c k i n g the relevant moieties, are
us to closely
study the features o f e p i m e r i z a t i o n , in
relation to their biosynthetic pathways and s t a b i l i t y in
k n o w n t o u n d e r g o e p i m e r i z a t i o n , namely the reversible
vivo.
stereoisomerization at c a r b o n 13% and an epimer pair is
characterizing the pigments in v i t r o , since this reaction
Epimerization
is also of p r i m a r y concern
in
denoted w i t h a n o n - p r i m e d and p r i m e d s y m b o l , e.g., as
takes place readily under certain c o n d i t i o n s and
c h l o r o p h y l l ( C h i ) α ja'
epimers, despite a nearly identical visible a b s o r p t i o n
p r i m e d pigments
( F i g . 1).
Recent discovery of
as a m i n o r b u t p r o b a b l y
essential
spectrum
in
the
monomeric
state, )
3
behave
quite
c o m p o n e n t o f the higher p l a n t p h o t o s y s t e m I reaction
differently w i t h respect to molecular p o l a r i t y , N M R
center ) a n d o f h e l i o b a c t e r i a l r e a c t i o n centers
C D s p e c t r u m , and intermolecular association. )
1
2)
prompts
the
and
More
4
i m p o r t a n t l y , study of the epimerization kinetics w o u l d
unravel a relationship between the m o l e c u l a r s t r u c t u r e
and electronic properties of c h l o r o p h y l l s , because the
reaction is caused by a nucleophilic a n d / o r e l e c t r o p h i l i c
attack o f extraneous species.
D u e m a i n l y to the lack of an a n a l y t i c a l t o o l e n a b l i n g
r a p i d and reliable assay of the epimeric c o m p o s i t i o n , the
number
limited.
5 - 8
of
works
)
I n view of this we developed a r a p i d , h i g h -
on
Chi
epimerization
has
been
r e s o l u t i o n H P L C technique and a p p l i e d i t t o
tigations o f base-catalysis
9-11
) and self-catalysis
inves
of t w o
12)
pigment systems, C h i aja' and p h e o p h y t i n ( P h e o )
As
an extension
of these w o r k s , we n o w
aja'.
compare
systematically the thermodynamic a n d k i n e t i c features o f
Chi
a\a\
chlorinated
Chi
Chi
b\b\
Pheo
(Cl-Chl)
a\a\
a\a\
Pheo
and
b\b',
C20-
Cl-Pheo
a\a'
epimerizations catalyzed by bases and Lewis acids, t o
probe i n t o the effects of the central m e t a l a n d
substituents on the electronic state o f the
ring
molecules.
The Lewis acid-catalyzed epimerization is w h a t we f o u n d
f o r the C h i a\a' and Pheo aja'
Fig. 1. Structures of Chi a ( R ^ C O O C H s , R = H) and
Chi a' ( R H , R = C O O C H ) with partial carbon
numbering according to the I U P A C system. The Chi
b/b' pair possesses C H O instead of C H at carbon 7.
Replacement of the central M g ion w i t h two protons
gives pheophytins.
2
1 =
2
3
3
2 +
work,
1 2 )
systems i n a f o r e g o i n g
and some preliminary data were presented there.
The choice of C20-chlorinated pigments i n the present
w o r k is based on a possibility t h a t C l - C h l a is
an
intermediate i n the metabolic d e g r a d a t i o n o f C h i a i n
vivo,
1 3 )
t h o u g h the once-claimed
role o f
C13 -hydro2
November, 1992]
Epimerization of Chlorophyll Derivatives
x y l a t e d C l - C h i a as a c o m p o n e n t o f reaction center I
has
been
disproved
later.
1 5 1 6
'
Because
of
a
1 4
'
results
is
limited
to
a
1
1
fairly
c o m p l i c a t e d n a t u r e o f the r e a c t i o n , the discussion o n the
experimental
3081
qualitative
10~
or
.
k
Odl-3)
Τ
if)
\
* 10~
+
Experimental
Chi a and b were extracted from Chlorella.
Their
pheophytinization and epimerization followed by preparative
scale Η PLC purification * gave Chls and Pheos in a, a\ b, and
b' forms. C20-chlorinated Chi a\a' and Pheo a/a! were
prepared according to the procedure described elsewhere. '
Triethylamine, pyrrolidine, and piperidine were used as base
catalysts, and magnesium acetylacetonate (Mg(acac)2) and
anhydrous M g C h were as Lewis acid catalysts.
A l l these
chemicals were of reagent grade and used as received.
The
solvent for epimerization runs was either diethyl ether or
methanol (Wako Pure Chemical Ind.). Further purification
of the solvents was not performed since, in a preliminary
experiment, no difference was noted for the Chi a I a'
epimerization kinetics before and after additional distillation of
diethyl ether.
/
A
4
/
10"
1316
The kinetic and thermodynamic features of epimerization,
expressed for the Chi a I a' system as an example with pseudofirst order rate constants k and k\
5
Η
"
φαι.ο
(1)
?
25 ° C , in E t 0
2
ι
10
I
ι
10"
4
I
1
ι
10
3
1Ö"
2
1
Cßase/M
Fig. 2. Dependence of the Chi b/b' epimerization
rate constant (k+k') on the concentration of amines
(pyrrolidine, piperidine, and triethylamine) used as
catalysts.
rate constant
is p r o p o r t i o n a l t o the catalyst
(base)
c o n c e n t r a t i o n , and the catalytic a c t i v i t y is higher f o r a
value.
a
Chi a ^ Chi a'
k'
-
(10.7)
*
base o f larger pK
k
1
1
Chi b==b'
3
s e m i q u a n t i t a t i v e level, and a t h o r o u g h e l u c i d a t i o n o f the
m o l e c u l a r m e c h a n i s m is b e y o n d the scope o f this paper.
I
1
identical
t o those o f C h i
These features are entirely
α\α'
epimerization, '
and
11
indicate t h a t the C h i b/ b e p i m e r i z a t i o n proceeds v i a base
f
catalysis: A b s t r a c t i o n o f the C 1 3 - p r o t o n b y a base gives
2
were analyzed, via Η PLC measurements of epimeric com
position as a function of time, in terms of the following
formulae: )
9-12
a t r a n s i e n t enolate a n i o n at the ß - k e t o ester system o f the
cyclopentanone
ring,
and
the
enolate
anion,
upon
r e c o m b i n a t i o n o f the 1 3 - c a r b o n w i t h a p r o t o n , yields
2
one
o f the epimers
\a'\ — [«']«>
—
—
= e x p [ - ( * + *')*] = exp(-/ / τ)
[a Jo — [a ]=o
(2)
[a']«> = kl(k + k')
(3)
A
K = [a']oo/[a]«> = klk'
(4)
Figure
energetics.
The
at a p r o b a b i l i t y d e t e r m i n e d
k+k
value
f
for
Chi
bjb
is
r
by
about
sevenfold larger t h a n t h a t f o r C h i α ja' at a c o m m o n base
concentration. '
11
series o f measurements have been p e r f o r m e d b y
selecting
triethylamine (EtsN)
3
illustrates
the
as
results
the
for
u n c h l o r i n a t e d epimer p a i r s , C h i aja\
AG° =-RTlnK
(5)
a', a n d Pheo b/b'.
base
the
catalyst.
four
C h i b/b\
C20-
Pheo a/
A s is seen, f o r each p i g m e n t system
the rate constant e x h i b i t s f i r s t o r d e r dependence o n the
Here [ # ' ] , , [tf']o, and [#']«> denote the mole fraction of the primed
species at time t, at the onset of measurement, and at
equilibrium, respectively, τ the epimerization time constant
defined by (k+k')' ,
Κ the equilibrium constant for reaction (1),
and A G ° the standard Gibbs free energy change by the Chi
a—>a' transformation.
1
As a
epimerization
i n d i e t h y l ether at 25 ° C against the
c o n c e n t r a t i o n o f three amines.
is c o m m o n
among
them.
A
s i m i l a r be
h a v i o r was observed also f o r C 2 0 - c h l o r i n a t e d pigments.
T a b l e 1 summarizes
the k i n e t i c a n d
thermodynamic
parameters o b t a i n e d f o r a t o t a l o f six p i g m e n t systems,
together w i t h those o f t w o b a c t e r i o c h l o r o p h y l l s (BChls)
I t is seen t h a t the e p i m e r i z a t i o n
rate as w e l l as the e q u i l i b r i u m epimer
Base-Catalyzed Epimerization in Diethyl E t h e r .
rate c o n s t a n t (k+k')
mechanism
just for comparison.
Results and Discussion
t y p i c a l e x a m p l e , F i g . 2 depicts the C h i b\V
t r i e t h y l a m i n e c o n c e n t r a t i o n , suggesting t h a t the r e a c t i o n
composition
depends heavily o n the nature o f p i g m e n t .
F o r C 2 0 - u n c h l o r i n a t e d p i g m e n t systems, the order o f
the k+k'
value under i d e n t i c a l c o n d i t i o n s is
The e q u i l i b r i u m m o l e
f r a c t i o n o f C h i b\ [6']°o, was 0.220 at this t e m p e r a t u r e .
Pheo b\ b' > Pheo a/a' > Chi bj b' > Chi a/a'
This is t h e f i r s t case, t o o u r k n o w l e d g e , where the C h i bj
b' e p i m e r i z a t i o n has been studied q u a n t i t a t i v e l y .
The
w i t h a p p r o x i m a t e relative ratios o f 1 5 0 : 4 0 : 7 : 1 .
This
3082
Η . Μ Α Ζ Α Κ Ι , Τ . W A I A N A B I , Τ . TAKAHASHI, Λ . STRUCK, and
Table 1.
I Vol. 65, No. I I
Η . SCHI* R
Kinetic and Thermodynamic Parameters for the Epimerization of Chlorophyll Derivatives
at 2 5 ° C in Diethyl Ether Containing 0.01 Μ Triethylamine
Pigment system
Epimn. rate const
k + k'
Epimn. time const
Γ
Equil. mole fraction
[ A ' ] - or [ / / μ
Δ6'° for
a(b)-+a* (/>')
S"
h
—
kJ mol"
0.127
0.173
0.182
0.220
4.78
3.88
3.73
3.14
0.235
0.240
0.246
0.250
2.86
2.78
2.72
Pheo b/b'
Pheo a/a!
Cl-Pheo a/a'
Chi b/b'
C l - C h l a/a'
Chi a/a'
BCmW
BChl a/a'
1
8.09X10"
2.11X10-
1.82X10"
3.84X10"
8.20X10"
2.10X10"
a)
4
5
34
6
5.42X10"
2.14X10"
a )
0.34
1.3
1.5
7.2
4
4
51
6
130
1300
6
7
1
2.93
a) Unpublished data listed for comparison. BChl g and BChl a are the major pigments in heliobacteria and purple
photosynthetic bacteria, respectively. Since the epimerization rates of these pigments were extremely low, the kinetic
experiments were conducted at a triethylamine concentration of 0.1 M , and the measured rate constants were reduced tenfold.
-
I
1
1
1
>
25 °C
in E t 0
connected
Pheo
and C 1 3
are
1
by a double b o n d , and the C 1 3 - p r o t o n is
I n the enol f o r m the cyclopenta
none r i n g is conjugated w i t h the macrocycle π-system, as
y
b/b'
2
2
transiently detached.
Pheo α/α'
2
10,-3
C n ^ c a r b o n y l takes a f o r m o f C~0~, C13
1
evidenced
by
a
drastic
absorption spectrum.
19 2 0 )
change
in
the
UV-visible
When the molecule is i n a
perfect keto f o r m as i n F i g . 1, carbon 13 lacks π-electron
2
density as seen f r o m ab initio M O calculations o n e t h y l
0)
\
c h l o r o p h y l l i d e a and ethyl pheophorbide a. ')
I n this
2
*-* 1CT
case, therefore, the ring π-electron density c o u l d not
c o n t r o l the e p i m e r i z a t i o n rate.
However, Chls i n p o l a r
organic solvents are k n o w n to be in e q u i l i b r i u m between
C h i b/b'
KT
/
the keto a n d e n o l f o r m s , t h o u g h the f r a c t i o n o f the l a t t e r
P^Chl α / α
is very small i n o r d i n a r y m e d i a .
5
20)
The effect o f the r i n g
π-electron density o n the base-catalyzed e p i m e r i z a t i o n
rate c o u l d thus be rationalized by i n v o k i n g such π ,
I
ι
10'1-3
1
ϊ
ίοCEt N ] /
1
affecting the C13
2
electron density
and
hence the ease i n C 1 3 - p r o t o n detachment, i n the e n o l
2
10"
2
3
conjugation,
f o r m o f C h i derivatives.
Μ
A steric effect, i n a d d i t i o n to the electronic
Fig. 3. Dependence of the triethylamine-catalyzed
epimerization rate constants on the triethylamine
concentration, for the four pigment systems.
effect
m e n t i o n e d above, also may be a cause f o r the accelerated
e p i m e r i z a t i o n o f a Pheo species as compared t o a C h i
species, since an increased f l e x i b i l i t y of the c h l o r i n r i n g i n
the f o r m e r molecule )
16
may
facilitate the
keto/enol
interconversion.
order is clearly inverse t o t h a t o f t h e r i n g π-electron
T h e effect o f C 2 0 - c h l o r i n a t i o n is rather small here.
density, w h i c h is affected b y an i n d u c t i v e effect o f the
T h u s , a 5 0 - % increase and a 10-% decrease i n the rate
central metal ( M g
constant are n o t e d b y C20-chlorination of the C h i
substituent g r o u p s .
i n Chls and
Eb
i n Pheos)
and
T h u s , a Pheo species has a l o w e r
17)
and Pheo aja
f
system, respectively (Table 1).
aja'
The small
π-electron density t h a n a C h i species because o f a higher
effect o f the Cl-substituent, despite its high o
electron
(Pauling's
(0.373), o n the e p i m e r i z a t i o n rate may be due t o a b a c k
electronegativity ^ = 2 . 1 ) as c o m p a r e d w i t h the M g a t o m
d o n a t i o n o f lone p a i r electrons, w h i c h suppresses the
affinity
of
the
hydrogen
atom
P
(χ —\.2).
ρ
S i m i l a r l y , the π-electron density i n a 6-type
p i g m e n t is l o w e r e d b y a higher tendency
o f electron
w i t h d r a w a l b y the C 7 - C H O g r o u p ( H a m m e t t ' s
meta-
substituent constant o = 0 . 3 5 5 ) t h a n b y the C H
group
m
( o = — 0 . 0 6 9 ) i n an α-type p i g m e n t .
m
3
T h i s order is well i n
line w i t h the r e d o x potentials o f the p i g m e n t s . )
18
T h e base-catalyzed e p i m e r i z a t i o n proceeds, as m e n
value
m
i n d u c t i v e effect, a n d / or to a steric hindrance by the b u l k y
chlorine atom. )
13
Temperature
Dependence
merization in Diethyl Ether.
function
of
of
Base-Catalyzed
Figure 4 shows,
r e c i p r o c a l temperature,
Epi
as
epimer c o m p o s i t i o n ([#']«> and [£>']oo i n percent) f o r t h e
f o u r p i g m e n t systems, and the —In Κ
value
derived
t i o n e d above, v i a f o r m a t i o n o f an e n o l (or enolate a n i o n
t h e r e f r o m , i n d i e t h y l ether.
plus p r o t o n ) at the cyclopentanone
a v a i l a b i l i t y , the e q u i l i b r i u m epimeric compositions
r i n g , i n w h i c h the
a
the e q u i l i b r i u m
F o r reasons o f sample
of
November, 1992)
1.0
π
1
1
3083
fable 2. Activation Energies for the TriethylamineCatalyzed Epimerization in Diethyl Ether
r
a)
-26
Activation energy £ / k J m o l
a
Pigment system
Chi a/a'
Chi b/b'
Pheo a/a'
Pheo b/b'
1.2
Chi
b/b'
-1
Forward (k)
Backward (k')
kJ m o l '
43.6
45.1
43.4
39.5
40.2
43.2
39.6
36.8
3.4
1.9
3.8
2.7
a) Temperature range for measurement, 0—34 ° C .
1.4
Φ
c
cn
18 2
c
φ
Pheo α / α '
1.6
CMgtacac^
= 50 mM
Φ
16 Q_
ε
3
1.8-
er
LU
Pheo
t= 5 min
b/b'
12
2.0
_i_
3.3
3.2
JL
3.4
3.5
3.6
Τ / K T Κ"
1
3
3.7
t= 35 m i n
1
Fig. 4. Temperature dependence of the equilibrium
epimeric composition or the equilibrium constant AT in
diethyl ether for the four pigment systems.
C 2 0 - c h l o r i n a t e d species were measured o n l y at 25 ° C ,
t = 65 m i n
and the values f o r C l - C h l a\a' and C l - P h e o a\ä listed i n
T a b l e 1 are f a i r l y close t o those f o r the c o r r e s p o n d i n g
u n c h l o r i n a t e d species.
T h e s t a n d a r d Gibbs free energy change AG
f o r the
0
10 ( m i n )
process a—>a' o r b-*b' is calculated a c c o r d i n g t o E q . 5.
Since Δ G ° is equal t o Δ H ° - TAS°,
where H° denotes the
s t a n d a r d e n t h a l p y and S° the s t a n d a r d e n t r o p y , the AH°
values were calculated f r o m the slope o f a line i n F i g . 3 t o
o b t a i n 3 . 2 , 2 . 0 , 3.6, a n d 2.6 k J m o l " f o r the C h i a\a\ C h i
1
b/b\ Pheo a/a\ and Pheo bj b' systems, respectively.
In
Fig. 5. Temporal evolution of Η P L C traces for C h i b'
in the presence of 50 m M Mg(acac)2 i n methanol.
Question marks denote unidentified side products.
Column, 5-μπι silica (150X4.6 mm i.d.); eluent,
hexane/2-propanol (100/1.5, v / v ) ; flow rate,
1.5 ml m i n ; detection wavelength, 450 n m .
-1
a separate series o f experiments we measured the rate
constant k+k'
as a f u n c t i o n o f t e m p e r a t u r e , a n d t h e
f o r w a r d (k) a n d b a c k w a r d ( & ' ) rate constants
calculated
b y c o m b i n i n g the k i n e t i c d a t a
e q u i l i b r i u m d a t a ( F i g . 4) based o n E q . 3.
were
w i t h the
Activation
energies thus determined are given i n T a b l e 2.
The
difference i n t h e a c t i v a t i o n energy between the f o r w a r d
and b a c k w a r d r e a c t i o n nicely agrees w i t h the AH°
o b t a i n e d above.
p h e n o m e n o n was i n t e r p r e t e d ' as due t o a L e w i s a c i d 12
catalysis,
compound
where
a n e l e c t r o p h i l i c attack
of the M g
at the ß - k e t o ester system o f t h e c y c l o -
pentanone r i n g is f o l l o w e d b y d i s s o c i a t i o n / r e c o m b i n a t i o n o f the C 1 3 - p r o t o n .
2
value
T h e rate constants o f this process have been measured
T h e rate constant at a given t e m
f o r the six p i g m e n t systems i n m e t h a n o l , w h i c h was
perature i n a range f r o m 0 t o 3 4 ° C can be o b t a i n e d b y
employed
c o m b i n i n g Tables 1 a n d 2.
contrast t o the pigments i n neat m e t h a n o l , where a r a p i d
Mg(acac) -Catalyzed
2
Epimerization
in
Methanol.
f o r reasons
o f Mg(acac)2
solubility.
In
a l l o m e r i z a t i o n ( o x i d a t i v e d e g r a d a t i o n o f the c y c l o p e n t a -
C h i a\a' a n d Pheo a\ä u n d e r w e n t e p i m e r i z a t i o n i n the
none r i n g ) takes p l a c e ,
presence o f Mg(acac)2 instead o f an a m i n e , a n d this
sole process i n the presence o f Mg(acac)2.
22,23
' e p i m e r i z a t i o n was a l m o s t the
F o r the Chi
3084
Η . Μ Α Ζ Α Κ Ι , Τ . W V I A N A I U , Τ. TAKAHASHI, Α . STRUCK, and Η . Sc HI ι κ
Table 3.
[ V o l . 65, No. 11
Kinetic and Thermodynamic Parameters for the Epimerization of Chlorophyll Derivatives
at 2 5 ° C in Methanol Containing 0 . 0 1 Μ Magnesium Acetylacetonate
Pigment system
Epimn. rate const
k + k'
Epimn. time const
s-
min
1
Pheo b/b'
Cl-Pheo a/a'
Pheo a/a'
Chi b/b'
Cl-Chl a/a'
Chi a/a'
1.67X104.98X10-
d)
d)
2.07X10-
[a']oo
1.0
2
3.4
8.1
45
62
87
3
3
3.74X102.67X10"
1.91X10"
Equil. mole fraction
Γ
4
4
4
or
AG° for
a(b)-+a'(b')
[b']oo
—
kJ mol
0.10
0.16
0.13
0.16
0.21
5.4
4.1
1
4.7
4.1
3.3
3.9
0.17
a) Rate constants were obtained by extrapolation of the data acquired in a Mg(acac)2 concentration range of 10 —2X10~ M .
4
b\b
f
system
alone,
some a d d i t i o n a l reaction
accom
panied e p i m e r i z a t i o n as noted f o r the Η P L C
s h o w n i n F i g . 5.
traces
T h o u g h these by-products have n o t
for
the six p i g m e n t
systems.
However,
3
a
subtle
difference appears t o exist between the t w o catalyses,
p r o b a b l y reflecting a c o n t r o l o f the r e a c t i o n rate by the
been i d e n t i f i e d , they d i d n o t significantly interfere w i t h
local electron density i n the molecule.
the d e t e r m i n a t i o n o f t h e C h i b\b' epimerization rate
a p i g m e n t system is expressed i n the f o r m o f "central
constant i n the early stage o f t r a n s f o r m a t i o n .
catalysis,
As in base
the e p i m e r i z a t i o n rate constants
k+k'
were
p r o p o r t i o n a l t o the Mg(acac)2 c o n c e n t r a t i o n i n a wide
I n what follows,
metal-substituent(s) at C7 ( a n d C20 f o r chlorinated
species)" f o r convenience.
the C l - P h e o aja'system,
H2~CH.rO
Thus,
denotes
t h o u g h h y d r o g e n is actually not
range o f the l a t t e r , a n d the results obtained f o r the six
a metal.
pigment systems, b o t h kinetic and e q u i l i b r i u m data, are
e p i m e r i z a t i o n rate constant
summarized i n T a b l e 3.
d i t i o n s (Table 1) are as f o l l o w s :
I n triethylamine-catalysis, the ratios o f the
(k+k')
under given
con
F o r the C 2 0 - u n c h l o r i n a t e d pigments, the order o f rate
H -CHO:H2-CH,-Cl:H -CHi = 3.8:0.86: 1
constants is
2
Pheo b\b'> Pheo a\a>C\i\
2
M g - C H O : M g - C H · CI: M g - C H = 7.1:1.5:1
6 / 6 ' > Chi a I a'
3
3
H - C H O : M g - C H O = 21
2
w i t h a p p r o x i m a t e relative ratios o f 8 7 : 1 1 : 2 : 1 .
This is
q u a l i t a t i v e l y w e l l i n line w i t h t h a t f o r the base catalysis
described above.
A l s o , t h e order o f the e q u i l i b r i u m
epimer c o m p o s i t i o n , represented b y
o r [b']
[a']oo
a p p a r e n t l y c o m m o n between the t w o catalyses.
OO,
is
These
findings s t r o n g l y suggest t h a t the mode o f epimerization
is governed b y a c o m m o n f a c t o r , namely the ease i n C13 2
p r o t o n detachment,
catalysis.
i n b o t h base- a n d Lewis
acid-
T e n t a t i v e l y we envisage the f o l l o w i n g picture
f o r the Lewis acid-catalysis.
A l o w e r π-electron density
i n the macrocycle tends t o detach t h e C 1 3 - p r o t o n as
2
discussed above, thereby y i e l d i n g a C O ^ e n o l a t e a n i o n ,
w h i c h is t h e n stabilized b y t h e f o r m a t i o n o f a loose
c o m p l e x w i t h the M g a t o m c a r r y i n g a p a r t i a l l y positive
charge
i n Mg(acac)2.
A
similar
scheme
established as a n i n i t i a t i o n step f o r metal
has been
ion-assisted
allomerization o f Chi. )
24
U p o n C 2 0 - c h l o r i n a t i o n , b o t h C h i aja' and Pheo aja'
became m o r e susceptible
t o Mg(acac)2-catalyzed epi
m e r i z a t i o n by a f a c t o r o f 1.4 and 2.4, respectively.
This
is p a r t i a l l y i n contrast t o base-catalyzed epimerization
(Table
1) where
Cl-Pheo
a\a! exhibits
slower
epi
m e r i z a t i o n t h a n Pheo aj a'.
H2-CH3 · C I : M g - C H · CI = 2 2
3
H2-CH3: M g - C H = 3 9
3
I n s p e c t i o n o f these figures indicates t h a t the effect o f
the substituent is m o r e p r o n o u n c e d i n C h i ( M g - ) species
t h a n i n Pheo ( H 2 - ) species, and the effect o f the central
m e t a l is m o r e d o m i n a n t t h e m o r e the substituent is
electron-donating.
follows.
These
m a y be
Catalysis.
of
Triethylamine-
and M g ( a c a c ) -
r i n g π-electron density, is u n f a v o r a b l e
parameters
is very
similar
2
o f the e l e c t r o n - w i t h d r a w i n g substituent ( C H O o r CI) is
dominant.
S i m i l a r l y , the effect o f the central metal is
conspicuous w h e n the C7 substituent has a l o w electronattracting property (CH3).
epimerization
rate
I n c o n t r a s t , the ratios of the
constant
f o r Mg(acac)2-catalysis
(Table 2) are as f o l l o w s :
H2-CHO: H - C H · CI: H - C H = 8.1:2.4: 1
2
3
2
3
Mg-CHO: Mg-CH · CI: M g - C H = 2.0:1.4 : 1
3
H 2 - C H O : M g - C H O = 45
between
t r i e t h y l a m i n e - a n d Mg(acac)2-catalyzed epimerizations
f o r t h e base-
c o m p o u n d against the C 1 3 - p r o t o n , and hence the effect
2
A s described above, the o r d e r o f kinetic and
thermodynamic
as
catalysis i n i t i a t e d b y t h e n u c l e o p h i l i c attack o f a basic
3
Comparison
rationalized
A C h i species, w h i c h has generally a higher
H - C H · C I : M g - C H · CI = 1 9
2
3
3
November, 1992]
much better ligand f o r M g
H: C H : M g - C H = 11
3
3085
}
oxygen o f Pheo a.
T h e trend here is neatly opposite t o the base-catalysis:
t h a n the C B ' - c a r b o n y l
2 +
I n the M g
2 +
ionic interaction between M g
complex, a fairly strong
a n d an enolate a n i o n
2 +
the effect o f substituents is more p r o n o u n c e d i n Pheos
presumably exists and stabilizes the negative charge o n
t h a n i n C h l s , and the effect o f the central m e t a l is m o r e
the enolate a n i o n , and this effect should be d o m i n a n t f o r
dominant
the m o r e
withdrawing.
the substituent
is
electron-
T h i s m a y well reflect the electrophilic
a t t a c k o f Mg(acac)2 against the C 1 3 - e n o l a t e a n i o n .
A
!
molecular-level e l u c i d a t i o n o f these p h e n o m e n a ,
how-
complex is m o r e stable f o r Pheo b t h a n f o r
2 +
Pheo a (vide i n f r a ) , i n line w i t h the results thus f a r , and
(from M g C b ) o n the epimerization o f C h i
therefore an easier e p i m e r i z a t i o n o f the Pheo bj b' system
2+
2 +
epimerization rate at least.
effect
M g - C a t a l y z e d Epimerization.
Mg
F o r this reason the i n t r i n s i c l o w e r s t a b i l i t y
of the Pheo a {a!) enolate m a y n o t be reflected i n the
The M g
ever, is not possible at the present stage.
of
an enolate a n i o n w i t h a higher π-electron density i n the
chlorin r i n g .
T h e catalytic
derivatives was also studied i n m e t h a n o l .
Since t h e
due to an intrinsic higher s t a b i l i t y o f its enolate m a y be
presence o f M g , i n contrast t o Mg(acac)2
employed
canceled by its slower dissociation
2 +
i n t h e apparent
a b o v e , resulted i n r a p i d a l l o m e r i z a t i o n o f the C h i aja\
reaction rate.
C h i bjb\ a n d C l - C h l a\ä systems i n line w i t h a n o l d
faster Mg(acac)2-catalysis
r e p o r t , ' the data were collected o n l y f o r Pheo species.
c o m m o n M g c o n c e n t r a t i o n (Table 3 and F i g . 6 ) .
2 4
The
rate constants are very s i m i l a r a m o n g
This m a y be related t o the 5 t o 4 0 - f o l d
t h a n the M g - c a t a l y s i s at a
2+
Synergistic Action of Triethylamine and Lewis A c i d in
the three
p i g m e n t systems ( F i g . 6 ) , despite the fact t h a t the Pheo aj
the
a' system underwent e p i m e r i z a t i o n b y a f a c t o r o f 4 t o 8
Epimerization kinetics were investigated i n m e t h a n o l i c
slower t h a n the Pheo b\b' system i n base-catalysis a n d
solutions containing b o t h t r i e t h y l a m i n e and a Lewis acid,
Mg(acac)2-catalysis, as verified above.
mostly o n the Pheo a ja'
T h i s result m a y be accounted f o r as f o l l o w s .
f o u n d in previous w o r k , ' coexistence o f M g
1 2
2 +
As
and Pheo
a leads t o the f o r m a t i o n o f a M g - P h e o a enolate
2+
complex,
20
2 5 )
w h i c h is stable enough t o be observed by
visible spectroscopy and is most
probably
an inter-
mediate i n the course o f M g - c a t a l y s i s , whereas i n the
2+
Mg(acac)2-catalysis such a c o m p l e x was n o t observed i n
the visible s p e c t r u m , suggesting t h a t acetylacetone is a
Epimerization
Pheo a ja'
a n d Enolization
system.
epimerization
of Pheo
Figure 7 shows t h e
rate constant
ι
I
1
k+k
i n the
r
presence and absence o f t r i e t h y l a m i n e (base-catalyst) as a
function o f [ M g ] .
T r i e t h y l a m i n e was used at a single
2 +
concentration o f 0.125 m Μ , and the k+k
value b y this
f
base-catalysis alone was 4.4X10" s
5
- 1
( b r o k e n line).
As
seen, by the coexistence o f this rather weak catalyst, the
rate
of Mg -catalysis
became
2+
magnitude
higher
indicates that M g
2 +
than
that
b y t w o orders-of-
i n its absence.
This
a n d t r i e t h y l a m i n e act cooperatively
or synergistically i n the e p i m e r i z a t i o n .
I
a/a'.
T h e synergistic
1
ο Pheo α / α '
1
ι
I
1
ι
1
Δ P h e o b/b'
• Cl-Pheo α / α '
10"
?^Mg
-
3
10"
3
-
Λ
τ
-
Λ
3
/%
/
~
>^Mg
2 +
—
°c
in
MeOH
x
10
1CT
+ Et N(0.125 mM)
Pheo α / α '
10"
A
f
ω
+
1Cf
2
Et N
3
0.125 mM
25 °C, in MeOH
.
I
ι
-5
I
ι
ι
10"
5
10"
3
ι
I
10"
3
1
10"
1
2
KT
CMg
2
2 f
_
10"
1
:/M
1
CMg2+D / Μ
Fig. 7. Dependence of the Pheo a ja' epimerization rate
constant on the M g concentration i n the presence or
absence of 0.125 m M triethylamine i n methanol.
Broken horizontal line represents the rate constant by
the presence of 0.125 m M triethylamine alone.
2 +
Fig. 6. Dependence of the Pheo a/a', Pheo b/b\ and
Cl-Pheo a I a' epimerization rate constants on the M g
concentration in methanol.
2 +
3086
[Vol. 65, No. I 1
Η . Μ Α Ζ Α Κ Ι , Τ . W A I A N A H I , Γ. TAKAHASHI, Α . SIRUCK, and Η . SCHI ι κ
Pheo b
in MeOH, 25 ° C
500
600
Wavelength (nm)
400
Fig. 8. Absorption spectra of Pheo a in methanol: in
neat methanol (
) , immediately after addition of
67 m M M g (
) , and by simultaneous addition of
67 m M M g plus 33 m M triethylamine (
).
2 +
and t r i e t h y l a m i n e o n t o
2 +
1
_ I
mechanism m a y consist o f almost simultaneous actions
Mg
l
2
of a
Mg -Pheo
a
2 +
( e n o l i z a t i o n ) , observed at high M g
2 +
enolate
1
1
1
25 " C
in MeOH
the C 1 3 - c a r b o n y l
oxygen and the C 1 3 - p r o t o n , respectively.
Formation
700
Fig. 9. Absorption spectra of Pheo b in methanol.
The three curves have the same meanings as in Fig. 8.
2 +
of
500
600
W a v e l e n g t h (nm)
complex
concentrations, is
10~
3
1(T
4
Pheo α / α '
also p r o m o t e d by the a d d i t i o n o f t r i e t h y l a m i n e ( F i g . 8).
W h e n the additive was 67 m M M g
alone, the ff action o f
2 +
the c o m p l e x was as s m a l l as a b o u t 3 0 % immediately after
the a d d i t i o n , a n d was t h e n g r a d u a l l y degraded t o the
spectrum o f i n t a c t Pheo a.
F u r t h e r a d d i t i o n o f 33 m M
t r i e t h y l a m i n e t o this s o l u t i o n , however, gave a spectrum
essentially i d e n t i c a l t o t h a t r e p o r t e d b y Scheer a n d
Katz
2 5 )
as a
peripheral
Mg
2 +
complex
Tn
\
+
—
of methyl
p h e o p h o r b i d e a enolate, a n d t h e spectrum remained
unchanged f o r at least 1 h .
Êt N
0.125 mM
3
W h e n only triethylamine
was present, even w h e n i t was used as solvent, the Pheo a
enolate a n i o n was n o t observed at a l l i n the a b s o r p t i o n
spectrum.
Thus,
at the stage o f e n o l i z a t i o n ,
Mg
10~
5
I
2 +
s h o u l d play a role o f a m a i n catalyst, t r i e t h y l a m i n e being
a secondary catalyst w h i c h supports the a c t i o n o f M g .
2 +
T h i s is p r o b a b l y the case f o r the synergistic epimerization
described above ( F i g . 7 ) .
Under identical conditions,
Pheo b also f o r m e d a p e r i p h e r a l c o m p l e x ( F i g . 9) i n a
m a n n e r similar t o Pheo a, b u t as m u c h as 65% o f the
p i g m e n t was i n the e n o l f o r m o n a d d i t i o n o f 67 m M M g
2 +
alone: T h i s is indeed an i n d i c a t i o n o f a higher stability o f
ι
I
1
1(T*
10"
C Mg(acac) 3/M
1
10~
3
2
2
Fig. 10. Dependence of the Pheo a/a' epimerization
rate constant on the Mg(acac)2 concentration in the
presence ( · ) and absence (O) of 0.125 m M
triethylamine i n methanol. Broken line represents
the rate constant by the presence of 0.125 m M
triethylamine alone.
Pheo b enolate as c o m p a r e d t o Pheo a.
I n contrast, Mg(acac)2 a n d t r i e t h y l a m i n e coexisting i n
m e t h a n o l apparently d i d n o t e x h i b i t a synergistic effect
c o u l d suppress a simultaneous attack o f triethylaminie.
I n m e t h a n o l , a generally observed t r a n s f o r m a t i o n ! o f
o n t h e Pheo aj a! e p i m e r i z a t i o n , as depicted i n F i g . 10.
C h i derivatives is a l l o m e r i z a t i o n . ' >
A
dissolved i n m e t h a n o l c o n t a i n i n g M g
slight
increase
epimerization
rate
in
the
constant
Mg(acac) -catalyzed
2
k+k
f
by
t r i e t h y l a m i n e is almost at a level o f k+k'
addition o f
attained b y
triethylamine-catalysis alone, suggesting t h a t Mg(acac)2
and t r i e t h y l a m i n e act i n d e p e n d e n t l y .
T h i s may be due
t o a f a i r l y large size o f t h e Mg(acac)2 molecule w h i c h
22
a l l o m e r i z a t i o n was indeed
Johnston
and Watson, )
24
23
When Chi a was
2 +
observed
, a fairly r a p i d
as r e p o r t e d b y
a n d this
reaction
was
accelerated b y a d d i t i o n o f t r i e t h y l a m i n e (unpublislhed
results)
in
a
manner
similar
e p i m e r i z a t i o n s h o w n i n F i g . 7.
to
t h e Pheo
This
a\a!
suggests t h a t
November, 1992]
a l l o m e r i z a t i o n and e p i m e r i z a t i o n occur t h r o u g h a
c o m m o n process o f enol f o r m a t i o n as proposed
previously. · · > I n c o n t r a s t , w h e n Mg(acac)2
or
t r i e t h y l a m i n e alone was added t o a C h i a m e t h a n o l i c
s o l u t i o n , no a l l o m e r i z a t i o n was observed.
Despite the
catalytic actions o f t r i e t h y l a m i n e and Mg(acac)2 i n
e p i m e r i z a t i o n , they rather seem t o i n h i b i t
the
a l l o m e r i z a t i o n w h i c h takes place even i n the absence o f
any catalytic c o m p o u n d s i n m e t h a n o l .
* This par
t i c u l a r p r o b l e m is, however, b e y o n d the scope o f the
present c o m m u n i c a t i o n .
23
26
27
22,23
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Epimerization of chlorophyll derivatives. V. Effects of the central

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