Introduction to nanophysics
Transcription
Introduction to nanophysics
2234-7 Meeting of Modern Science and School Physics: College for School Teachers of Physics in ICTP 27 April - 3 May, 2011 Introduction to nanophysics Yuri Galperin University of Oslo Oslo Norway What is nanoscience and nanotechnology? EB47789<A<G<BA '4ABF6<8A684A7A4ABG86;AB?B:L4E84??45BHG E8?4G<A:4A78KC?B<G<A:C;8AB@8A49BE@4G8E<4?F;4I<A:BA8GJBBE G;E887<@8AF<BAF E87H687GBG;8A4ABF64?8 Very broad area of science and technology having many branches. This lecture Introduction to Nanophysics 1 Meeting of Modern Science and School Physics: College for School Teachers of Physics in ICTP (27 April - 3 May 2011) 2HE< 4?C8E<A .A<I8EF<GLB9(F?B'BEJ4L I8EL5E<89<AGEB7H6G<BAGBG;8FH5=86G Introductory course in Oslo: http://folk.uio.no/yurig/Nanotechnology/MEF5010.html Introduction to Nanophysics 2 What is nanoscience and nanotechnology? EB47789<A<G<BA '4ABF6<8A684A7A4ABG86;AB?B:L4E84??45BHG E8?4G<A:4A78KC?B<G<A:C;8AB@8A49BE@4G8E<4?F;4I<A:BA8GJBBE G;E887<@8AF<BAF E87H687GBG;8A4ABF64?8 Very broad area of science and technology having many branches. This talk Introduction to Nanophysics 3 0;4G<F'4AB A@ @ 6@ Introduction to Nanophysics 4 '4ABF64?8B5=86GF7BABG9H??L58?BA:GBG;8@<6EB6BF@ &4AL4GB@F8?86GEBAF8G6 4E8<AIB?I87 'H@58E B978:E88FB99E887B@<F?4E:8 ,<M8 'H6?8< '4ABB5=86GF GB@F ?H<7F ELFG4?F ,@4??@B?86H?8F ?4FF8F Introduction to Nanophysics 5 Introduction to Nanophysics 6 '4ABC;LF<6F &4<AGE8A7F4A7 6EBFFEB47F Introduction to Nanophysics 7 '4ABF6<8A68 <FE898EE87GB4F4E8F84E6;4E8478IBG87 GBFGH7<8FB9I4E<BHFC;8AB@8A4<AF@4??F<M878I<68F "G<F46EBFF7<F6<C?<A4EL9<8?7<A6?H7<A:C;LF<6F 6;8@<FGEL4A7GBFB@88KG8AG5<B?B:L -;8;84EGB9A4ABF6<8A68 <F@8FBF6BC<6 C;LF<6F -;8JBE733@8FBE89?86GFG;8946GG;4GG;8F<M8B9 G;8FLFG8@FHA78E6BAF<78E4G<BA<F?B64G8758GJ88A @<6EBF6BC<6 4GB@F4A7 @46EBF6BC<6 F64?8F Introduction to Nanophysics 8 -;8;84EGB9A4ABF6<8A68 <F@8FBF6BC<6 C;LF<6F ;4E46G8E<FG<6F64?8F<AA4ABF6<8A68 Nanometer scale Atoms Molecules & Clusters Micro Length scale Electron mean free path Meso Bulk materials Macro Modern electronic devices belong to mesoscopic scale Introduction to Nanophysics 9 CMOS TECHNOLOGY Intel’s Prescott processor (released March 2004): • 150 million transistors • 90 nm design rules • 3.4 GHz clock frequency DRAM chips: 4 Gb chips demonstrated (~ 109 transistors/cm2) Intel’s Norwood (Pentium 4 - 130 nm) processor 'BJ6;<CF54F87BAG;8 78F<:AEH?8FB9A@4E8 BAG;8J4L "AJ8J8E84?E847L<AF<78A4ABG86;AB?B:L Introduction to Nanophysics 10 &4<A<A:E87<8AGFB9A4AB8?86GEBA<6F N -JB7<@8AF<BA4?8?86GEBA:4F N *H4AGH@J<E8F4A7CB<AG6BAG46GF N *H4AGH@7BGF 'BI8?@4G8E<4?F78I<68F N '4AB8?86GEB@86;4A<64?FLFG8@F N 4E5BA4A7ABA64E5BAA4ABGH58F 4A7BG;8E@B?86H?4E78I<68F N E4C;8A8 N 8I<68FHF<A:FHC8E6BA7H6G<I<GL4A7@4:A8G<F@4GA4ABF64?8 P 8I<68F9BEDH4AGH@6B@CHG4G<BA N ,C<AGEBA<6F P @4A<CH?4G<BA8?86GEBAFC<A Introduction to Nanophysics 11 Examples Introduction to Nanophysics 12 -JB7<@8AF<BA4??86GEBA 4F 4A7:4C8A:<A88E<A: 2DEG is a generic object for new physics 'B58?)E<M8F It serves as a building block for electronic devices Metal-Oxide-Semiconductor (MOS) structures 2DEG is formed at the semiconductor-insulator interface Semiconductor heterostructure 2DEG is formed at the interface between two semiconductors Introduction to Nanophysics 08J<??6B@8546>GB G;8F8FGEH6GHE8F?4G8E 13 More about formation of 2D electron gas Bending of the energy bands at the interface Formation of 2D conduction channel Introduction to Nanophysics 14 E4C;8A8 “most two-dimensional” system imaginable # # !" '& Introduction to Nanophysics 15 ,L@@8GEL@4GG8EF !4CCL94@<?<8F4E84??4?<>88I8ELHA;4CCL94@<?L<F HA;4CCL<A<GFBJAJ4L AA4$4E8A<A4 %<>8E8?4G<I<FG<6C4EG<6?8F -;8'B58?)E<M8<A);LF<6F A7E8 8<@ Introduction to Nanophysics $BAFG4AG<A 'BIBF8?BI 16 *H4AGH@0<E8F4A7)B<AGBAG46GF ?84I87FGEH6GHE8F ,C?<G:4G8FGEH6GHE8F Q46>8A7RC4EGF B9A4AB78I<68F )B<AG6BAG46GF Introduction to Nanophysics 4E5BAA4ABGH58F 17 *H4AGH@BGF %4G8E4?DH4AGH@7BGF BH?B@55?B6>4:8 /8EG<64? "I4E <OI8E Introduction to Nanophysics EG<9<6<4?4GB@FP A8J C8E<B7<6G45?8 18 BH?B@55?B6>478 +8CH?F<BA4GG;87BG 4G8 ?86GEBA BG BFG GGE46G<BAGBG;8:4G8 G G;88A8E:L6BFGI4A<F;8F ,<A:?88?86GEBAGE4AF<FGBE,- Introduction to Nanophysics 19 ,8?94FF8@5?87 DH4AGH@7BGF4E8 C8E<B7<64EE4LFB9Q4EG<9<6<4?4GB@FR -;8L4E86BAF<78E87GB58CEB@<F<A: FLFG8@F9BE;8G8EBFGEH6GHE8?4F8EF (HECEB=86G 8<A,<4EE4LF Introduction to Nanophysics 20 SINGLE-ELECTRON SINGLE-MOLECULE TRANSISTORS J. Park et al. (2002) see also: - E. S. Soldatov et al. (1996) - H. Park et al. (2000) - N. Zhitenev et al. (2002) - S. Kubatkin et al. (2003) SET within the “Orthodox” theory: Introduction to Nanophysics 21 "AFGEH@8AG4G<BA9BEA4ABF6<8A684A7A4ABG86;AB?B:L EBJG; 45E<64G<BA & ;4E46G8E<M4G<BA ,-& % *H4AGH@6BEE4?F $4I?< )E<M8 Introduction to Nanophysics 22 I8A4@B78FGA4AB68AG8E A887F N ,G4EGHC9BE<AFGEH@8AG4G<BA 9BE@<? .,<A 477<G<BAGB4CEBC8E5H<?7<A: N )EBC8EEHAA<A:6BFGF E4G;8E;<:; N +8F84E6;C8EFBAA8?;<:;?LDH4?<9<87 5BG;<A8KC8E<@8AG 4A7G;8BEL -;868AG8EJ<??ABG58899<6<8AG J<G;BHG4?? G;8F8<A:E87<8AGF ,6<8AG<FGP 5HE84H6E4GF6;8@8 Introduction to Nanophysics 23 '8J?4JFB9'4GHE84GA4ABF64?8 "A46?4FF<64?E8F<FGBEG;8E8F<FG4A68<F7H8 GB8?86GEBAF64GG8E<A: (G;8EJ<F88?86GEBAF4E8=HFG4668?8E4G875L G;88?86GE<69<8?7 *&)4EG<6?8BEJ4I8 *H4AGH@@B78F<AG;8J<E8 Introduction to Nanophysics 24 *H4AG<M4G<BAB96BA7H6G4A68IF :4G8IB?G4:8 '8JHA<I8EF4?HA<GB9E8F<FG4A68P Introduction to Nanophysics 25 4F<6CEB5?8@F N '4ABF64?8FLFG8@FE8DH<E8HA78EFG4A7<A: P *H4AGH@GE4AFCBEG P +B?8B98?86GEBA8?86GEBA<AG8E46G<BAJ;<6;<F@BE8 CEBABHA687<A?BJ7<@8AF<BA4?FLFG8@F P +B?8B97<FBE78E P +B?8B96BAG46GF4A78?86GEB@4:A8G<68AI<EBA@8AG N '4AB78I<68F4E8HFH4??LBHGB98DH<?<5E<H@J;<6;E8DH<E8F FC86<4?HA78EFG4A7<A: ??G;8F8<FFH8F4E894E9EB@58<A:9H??LHA78EFGBB7 '8JE8F84E6;4E84J<G;E<6;C;LF<6F4A76;8@<FGEL Introduction to Nanophysics 26 ?86GEBAFC<A Two types of experimental evidence which arose in the 1920s suggested an additional property of the electron. One was the closely spaced splitting of the hydrogen spectral lines, called fine structure. The other was the Stern-Gerlach experiment which showed in 1922 that a beam of silver atoms directed through an inhomogeneous magnetic field would be forced into two beams. It was recognized in the early years of quantum mechanics that atomic spectra measured in an external magnetic cannot be predicted with just orbital quantum numbers. A solution to this problem was suggested in early 1925 by George Uhlenbeck and Samuel Goudsmit, students of Paul Ehrenfest (who rejected the idea), and independently by Ralph Kronig, one of Lame's assistants. Uhlenbeck, Goudsmit, and Kronig introduced the idea of the self-rotation of the electron, which would naturally give rise to an angular momentum vector in 27 addition to the one associated with orbital motion. *H4AGH@&86;4A<6FB9"78AG<64?)4EG<6?8F,C<A4A7,G4G<FG<6F In quantum mechanics spin is a fundamental characteristic property of particles. Spin is a type of angular momentum. When combined with the spin-statistics theorem, the spin of electrons results in the Pauli exclusion principle, which in turn underlies the periodic table of chemical elements. Electrons are fermions, while photons, phonons and magnons are bosons Introduction to Nanophysics 28 '4AB8?86GEB@86;4A<64?FLFG8@F '4AB@4G8E<4?F Encapsulated 4 nm Au particles self-assembled into a 2D array supported by a thin film, Anders et al., 1995 Scheme for molecular manufacturing Introduction to Nanophysics 29 "AA4AB@4G8E<4?F8?86GE<64?4A7@86;4A<64?8A8E:<8F4E86B@C4E45?8 ?86GE<64?4A7@86;4A<64?@B78F4E8FGEBA:?L6BHC?87 '4AB8?86GEB@86;4A<6F BA6E8G8FLFG8@F ?86GEBAQF;HGG?8FR &B?86H?4E@BGBEF Introduction to Nanophysics 4E5BAA4ABGH58F 30 “Shuttle” transfer of electrons A movable cluster “conveys” electron one by one In some cases electro-mechanic instabilities can take place “Shuttle” transport has been observed in several concrete systems Introduction to Nanophysics 31 ,B?4E68??FJ<G;A4ABC4EG<6?8F'4ABC?4F@BA<6F &4<ACE<A6<C?8)?4F@BAE8FBA4A68F7H8GB A4ABC4EG<6?8FFGEBA:?L8A;4A68G;8G<@8 J;<6;C;BGBAFFC8A76?BF8GBG;846G<I8?4L8E &8G4??<6A4ABC4EG<6?8F 8@587787<AG;8;BFG FLFG8@6?BF8GBG;8 46G<I8?4L8E Simulation of increased light intensity beneath a metal nanoparticle on a silicon cell Introduction to Nanophysics Key players: Centre for Sustainable Energy Systems at the Australian National University (ANU) ; Caltech, US; FOM-Institute, AMOLF, the Netherlands. 32 &BE845BHGC;LF<64?F64?8F ?4FF<64??8A:G; P 8?86GEBA@84A9E88C4G; *H4AGH@?8A:G; P 78EB:?<8J4I8?8A:G;B94A 8?86GEBA;4I<A:G;88E@<8A8E:L -;<FF64?8<FE8?8I4AGGBG;8F<M8DH4AG<M4G<BA P DH4AGH@9<?@FJ<E8F4A77BGF Introduction to Nanophysics 33 ABG;8E<@CBEG4AGF64?8P C;4F86B;8E8A68?8A:G; ,64?8<AGEB7H6875LBH?B@5<AG8E46G<BA4A7 78C8A7<A:BAG;878I<6864C46<G4A68 E8?8I4AGGB F<A:?88?86GEBAGHAA8?<A: "AG8EC?4L58GJ88A7<998E8AGF64?8F?847FGB4E<6; C<6GHE8B9GE4AFCBEGG;EBH:;A4ABFLFG8@F -;8FC86<9<6CEBC8EG<8FB97<998E8AGE8:<@8F64A58 HF879BEI4E<BHF4CC?<64G<BAF Introduction to Nanophysics 34 4F<66?4FF<9<64G<BAB9GE4AFCBEGE8:<@8F Introduction to Nanophysics 35 4??<FG<6GE4AFCBEG DH4AGH@CB<AG6BAG46G -BG;8?89GG;8FHE9468GBCB:E4C;LB9 4 4F@<6EB6;<C<FF;BJA -;8C<6GHE8 ;4F588AG4>8AJ<G;4A4GB@<69BE68 @<6EBF6BC8 -;86;<C;BFGF4DH4AGH@9<?@45BHG A@58?BJ<GFFHE9468J;<6;<FE8@BI87 HA78EA84G;G;85E<:;G?<A8F F@4??4A7 F;BEGJ<E8B9?8A:G;A@4A7J<7G; A@6BAA86GFFBHE684A77E4<A -;8@84FHE8@8AGGBG;8E<:;GF;BJFG;86BA7H6G4A68B9G;8J<E84F49HA6G<BA B9G;8:4G8IB?G4:8 G?BJG8@C8E4GHE8F46BA7H6G4A68DH4AG<M4G<BA <AHA<GFB98; <FI<F<5?8 J;<6;I4A<F;8F4EBHA7$ Introduction to Nanophysics 36 -;8DH4AGH@!4??89986GF4A7,;H5A<>BI78!44FBF6<??4G<BAF ?4FF<64? !4??89986G ,;H5A<>BI78!44FBF6<??4G<BAF4A7G;8DH4AGH@!4??89986G 08?BB>4G4 @84FHE8@8AGB9G;8?BA:<GH7<A4?4A7G;8!4??E8F<FG4A68+KK 4A7+LL E8FC86G<I8?LB94GJB7<@8AF<BA4?8?86GEBA:4F4F49HA6G<BAB94@4:A8G<6 9<8?74CC?<87C8EC8A7<6H?4EGBG;8C?4A8B9G;8DH4AGH@9<?@ -;88KC8E<@8AG ;4F588AC8E9BE@874G4G8@C8E4GHE8B9@$ -;8!4??E8F<FG4A68<FDH4AG<M87 <AHA<GFB9;8 Introduction to Nanophysics 37 );4F86B;8E8A68 G?BJG8@C8E4GHE8F -;8E8F<FG4A68B94F@4??E<A:J<G;47<4@8G8EB945BHG@<6EBAG;8?<:;G :E4L4E84F<AG;8<AF8G4F49HA6G<BAB94@4:A8G<69<8?74CC?<87C8EC8A7<6H?4E GBG;8E<A:C?4A8F;BJFC8E<B7<6BF6<??4G<BAF>ABJA4F ;4EBABIB;@ BF6<??4G<BAF -;8L<A7<64G8G;4G4F<:A<9<64AG9E46G<BAB9G;88?86GEBAFGE4I8EF8G;8E<A: C;4F86B;8E8AG?L Introduction to Nanophysics 38 ,<A:?88?86GEBAGHAA8?<A:4A7DH4AGH@7BGF -;8E<:;G<AF8GF;BJF4:4<AG;8 FHE9468GBCB:E4C;LB94F8@< 6BA7H6GBEJ<G;4GJB7<@8AF<BA4? 8?86GEBA:4FHA78EA84G; -;85E<:;G?<A8F8A6?BF84F@4?? <F?4A7 "G<F6BHC?87GBFBHE684A7 7E4<AI<4GJBDH4AGH@CB<AG 6BAG46GF9BE@<A:GHAA8?54EE<8EF 9BEG;88?86GEBAF -;854EE<8EF 4E8GHA875L47=HFG<A:G;8 IB?G4:8F4GG;8:4G8F*?4A7* -;8@4<A9<:HE8F;BJFG;86BA7H6G4A68G;EBH:;G;8<F?4A74F49HA6G<BA B9G;8:4G8IB?G4:8/" 4CC?<87GBE8:<BA " /" GHA8FG;8CBG8AG<4?B9G;8<F?4A7 -;86BA7H6G4A68C84>F<A7<64G8G;4GBA?L 9BE4C4EG<6H?4E<F?4A7CBG8AG<4?8?86GEBAF64A58GE4AF98EE8758GJ88A G;8<F?4A74A7G;8?847F -;8?89G<AF8GF;BJF49<GGB49HA6G<BABA8JBH?78KC86G9BEC84>FG;4G 4E8:BI8EA875LG;8E@4?F@84E<A:B9G;88E@<9HA6G<BA Introduction to Nanophysics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http://folk.uio.no/yurig/Nanotechnology/MEF5010.html Introduction to Nanophysics 40 -BC<6FCE8F8AG875LFGH78AGF ,<A:?86ELFG4?:EBJG; EBJG;B9?4L8E87FGEH6GHE8F8C<G4KL ?<DH<7C;4F88C<G4KL %) @B?86H?4E6;8@<64?I4CBE78CBF<G<BA&(/@B?86H?4E584@ 8C<G4KL &@4:A8GEBAFCHGG8E<A:8G6 %4G8E4?C4GG8EA<A:8?86GEBA584@C4GG8EA<A: 4A75BA7<A: ,4@C?86;4E46G8E<M4G<BA ?86GEBA@<6EBF6BCL-&,& -HAA8?<A:@<6EBF6BCL,-& ,86BA74EL<BA@4FFFC86GEBF6BCL,"&, 1E4LFC86GEBF6BCL ?8@8AGFB96ELB:8A<6F Introduction to Nanophysics 41 Conclusion $# Introduction to Nanophysics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