Compuestos Luminiscentes
Transcription
Compuestos Luminiscentes
Compuestos luminiscentes :[bWii[Wb[i Z[i[]kh_ZWZWbW C[Z_Y_dW Bioluminiscencia HZXdcdXZedgW^dajb^c^hXZcX^VVaV XVeVX^YVYfjZegZhZciVcVa\jcdh Vc^bVaZhYZegdYjX^gajo# :hiZ[ZcbZcdZhb{hVWjcYVciZZc aV[VjcVbVg^cVfjZZcaViZggZhigZnV fjZ\gVcXVci^YVYYZeZXZh!bdajhXdh! XVaVbVgZh!bZYjhVh!XdgVaZhnhZgZh b^XgdhXe^Xdhi^ZcZcaVegde^ZYVYYZ egdYjX^gajo# :cadhVc^bVaZhbVg^cdhaV[jZciZYZ ajoZhi{VhdX^VYVdW^ZcVaVegZhZcX^V YZWVXiZg^VhfjZk^kZcYZcigdYZZaadh! dVXajaVhZheZX^Va^oVYVhaaVbVYVh [didX^idhnYZcigdYZaVhXjVaZhhZ egdYjXZajo# EZgd fj^o{h Za XVhd b{h XdcdX^Yd YZ W^dajb^c^hXZcX^V hZV Za YZ aVh ajX^gcV\Vh# AV egdYjXX^c YZ ajo Zh eVgiZ YZ jcV gZVXX^c fjb^XV fjZ cZXZh^iVaVegZhZcX^VYZdm\ZcdYZaV^gZ!jcVhjhiVcX^VaaVbVYVajX^[Zg^cVn jcVZco^bVaaVbVYVajX^[ZgVhV# :a dm\Zcd YZa V^gZ eZcZigV Zc Za VeVgVid ajb^cdhd V igVkh YZ adh ijWdh igVfjZVaZh!hZedcZZcXdciVXidXdcaVajX^[Zg^cVnaVdm^YVZcegZhZcX^VYZ aVajX^[ZgVhVfjZVXiVXdbdZco^bVdV\ZciZYZVnjYVeZgdfjZcdeVgi^X^eV ZcaVgZVXX^c# AV ZcZg\V cZXZhVg^V eVgV fjZ hZ egdYjoXV aV gZVXX^c egdk^ZcZ YZa 6IE! ig^[dh[VidYZVYZcdh^cV!fjZhZZcXjZcigVZcidYdhadhh^hiZbVhW^da\^Xdhn XjnVYZhXdbedh^X^c\ZcZgVhjÒX^ZciZZcZg\VeVgVVXi^kVgaVgZVXX^c# JcVkZo[dgbVYVaVajX^[Zg^cVdm^YVYV!hiVhZYZhXdbedcZ^chiVci{cZVbZciZ! gZ\ZcZgVcYdaVajX^[Zg^cV^c^X^Vandm\ZcdnegdYjX^ZcYdjcZmXZhdYZZcZg\V fjZZha^WZgVYVZc[dgbVYZajo# AV ajX^gcV\V cd \ZcZgV XVadg! Vh ejZh idYV aV ZcZg\V fjb^XV Zh igVch[dgbVYVZcajo/aVZÒX^ZcX^VZhYZaX^ZcedgX^ZcnaVajoZh[gV# :aegdeh^idYZZhiZ[ZcbZcdZhaVgZegdYjXX^cdegdeV\VX^cYZaVZheZX^Z! ejZhaVhhZVaZhajb^cdhVhh^gkZcVaVhajX^gcV\VheVgVXdbjc^XVghZ# Compuestos Luminiscentes JcXdbejZhidajb^c^hXZciZZhh^beaZbZciZjcVhjhiVcX^VfjZigVch[dgbV aV ZcZg\V! n ZhV igVch[dgbVX^c YZ aV hZVa ajb^c^hXZciZ Zh h^ZbegZ ajo k^h^WaZ# 9ZeZcY^ZcYd YZa i^ed YZ ZcZg\V fjZ aV dg^\^cV edYZbdh ]VWaVg YZ kVg^Vh XaVhZhYZajb^c^hXZcX^V/ ;DIDAJB>C>H8:C8>6/AVZcZg\VVXi^kVYdgVZhYZdg^\ZcZaZXigdbV\ci^Xd# Adh GVndh M egdYjXZc jcV ^ciZchV ajb^c^hXZcX^V! fjZ eZgb^iZ ZcigZ digVh XdhVh! Y^[ZgZcX^Vg aVh eZgaVh Xjai^kVYVh YZ aVh cVijgVaZh! d aVh e^ZYgVh h^cii^XVh# ;AJDG:H8:C8>6/:hXVjhVYVedgadhgVndhjaigVk^daZiV!nhjcdbWgZegdk^ZcZ YZaVÓjdg^iV!jcb^cZgVafjZegZhZciVZhiVegde^ZYVY# ;DH;DG:H8:C8>6/8jVcYdaVajb^c^hXZcX^VeZgYjgVX^Zgidi^ZbedYZhejh YZ]VWZggZi^gVYdaV[jZciZYZZmX^iVX^c# I:GBDAJB>C>H8:C8>6/ 8^Zgidh bViZg^VaZh Zb^iZc ajo Va hZg XVaZciVYdh! h^ZcYdZaXVadgZaYZhZcXVYZcVciZYZaVgZVXX^c# FJ>B>DAJB>C>H8:C8>6/HZdg^\^cVedggZVXX^dcZhfjb^XVh!njcZ_Zbead ZhaVW^dajb^c^hXZcX^V# IG>7DAJB>C>H8:C8>6/ 8^Zgidh b^cZgVaZh cd bZi{a^Xdh Zb^iZc ajo Va hZg hdbZi^Ydh V VXX^dcZh bZX{c^XVh Xdbd hZg bda^Ydh d gVnVYdh# :A:8IGDAJB>C>H8:C8>6/ :a Z[ZXidZhegdkdXVYdedgaVVXX^c YZXdgg^ZciZhZaXig^XVh# G69>DAJB>C>H8:C8>6/ :c ZhiZ XVhdaVZcZg\VVXi^kVciZegdk^ZcZ YZgZVXX^dcZhcjXaZVgZh# L^aa^Vb8gdfjZhVeg^cX^e^dhYZah^\adMM^ckZcijcVeVgVidXVeVoYZXdciVg jcVheVgiXjaVhbjnZcZg\i^XVhfjZ]dnhZXdcdXZcXdbdÆeVgiXjaVhVa[VÇ#:a [jcX^dcVb^ZcidYZZhiZVeVgVidhZWVhVWVZcaVhegde^ZYVYZhajb^c^hXZciZh YZahja[jgdYZo^cX!fjZZb^iZjcVhZVaYZajok^h^WaZXjVcYdjcVeVgiXjaV Va[VX]dXVXdca#9ZhYZZcidcXZhbjX]dhdigdhXdbejZhidhajb^c^hXZciZh hZ]VcYZhXjW^Zgidn[VWg^XVYd# Aplicaciones J;NJ?B;I 9EC;H9?7B;I Cx:?97I JhdYZXdbejZhidhajb^c^hXZciZheVgVVea^XVX^dcZhbY^XVh# University of Michigan Sistema de detección de la enfermedad del Alzheimer en un cerebro de ratón. Mostrando la electroluminiscencia :aXdgYcajb^cdhdhZ^ajb^cVVaegdedgX^dcVgaZjcVXdgg^ZciZZaXig^XVfjZ ZmX^iVadhZaZXigdcZhYZabViZg^VafjZad[dgbV# JcZ_Zbeadh^b^aVgZhZhiVa{b^cVYZ bViZg^VaZaZXigdajb^c^hXZciZ Quimioluminiscencia 6a]VXZggZVXX^dcVgkVg^VhhjhiVcX^Vh fjb^XVh hZ egdYjXZ jcV gZVXX^c YZ aV fjZ hZ YZhegZcYZ ajo! hdc XdcdX^YVhXdbdajXZhfjb^XVh# ¿Qué hacemos en el ICMA? ;d [b ?9C7 Z[iWhhebbWcei Yecfk[ijei eh]Wdec[j|b_Yei gk[ fh[i[djWd Z_\[h[dj[ifhef_[ZWZ[ifj_YWi"[bYjh_YWiecW]dj_YWi$ Idj[i_iZ[Yecfk[ijeibkc_d_iY[dj[i AVbVndgeVgiZYZadhXdbeaZ_dhYZdgdig^XddgY^cVYdhdXdc^ciZgVXX^dcZh bZiVa"bZiVaegZhZciVc^ciZgZhVciZhegde^ZYVYZhajb^c^hXZciZh#BdY^ÒXVcYd adh a^\VcYdh d adh XZcigdh bZi{a^Xdh Zh edh^WaZ bdYjaVg aV [gZXjZcX^V YZ Zb^h^c!nedgadiVcidZaXdadg!YZZhidhXdbejZhidh# Adh XdbejZhidh ajb^c^hXZciZh hZ ejZYZc egZeVgVg V eVgi^g YZ edabZgdh dg\{c^Xdhajb^c^hXZciZhZcadhfjZhZegdYjXZcigVch^X^dcZh"dVeVgi^g YZ XdbejZhidh YZ XddgY^cVX^c Xdc Y^hi^cidh bZiVaZh! Va\jcdh YZ Zaadh eda^cjXaZVgZhXdcZcaVXZhdXdciVXidhbZiVa"bZiVa#:cZaadhaVajb^c^hXZcX^V VeVgZXZedgigVch^X^dcZhbZiVa"a^\VcYd!a^\VcYd"bZiVada^\VcYd"a^\VcYd# N H2C CH2 P N H2C CH2 N C H2 Au C Cl C Cl RCl = CH2 Cl Cl Cl ;bWXehWZefeh0 ?dij_jkjeZ[9_[dY_WZ[CWj[h_Wb[iZ[7hW]d?9C7 9edi[`eikf[h_ehZ[?dl[ij_]WY_ed[i9_[djÓYWi9I?9 I[Z[9WcfkiFbWpWIWd<hWdY_iYe I[Z[9WcfkiHe;Xhe ;VXjaiVYYZ8^ZcX^Vh EZYgd8ZgWjcV&' *%%%.OVgV\doV :Y^ÒX^dIdggZhFjZkZYd BVgVYZAjcV( *%%&-OVgV\doV IZa[dcd.,+,+&'(& ;Vm/.,+,+')*( ]iie/$$lll#jc^oVg#Zh$^XbV$ :aVWdgVYdedg/ :cXdaVWdgVX^cXdc/ ;^cVcX^VYdedg/