Liesegang named in Literature - Christian-Albrechts
Transcription
Liesegang named in Literature - Christian-Albrechts
Please take notice of: (c)Beneke. Don't quote without permission. Liesegang named in Literature (e. g. Liesegang rings, periodic and rhythmic crystallization, Liesegang phenomena, Liesegang pattern, Runge pictures, Belousov-Zhabotinsky-reaction) (Published 1790 – 2003) (nearly a complete list of this literature) Second Edition (with a short new biography of the colloid scientist Raphael Eduard Julius Liesegang in german language) June, 2004 Klaus Beneke Institut für Anorganische Chemie der Christian-Albrechts-Universität der Universität D-24098 Kiel [email protected] Liesegang rings Runge picture 2 Liesegang named in Literature (e. g. Liesegang rings, periodic and rhythmic crystallization, Liesegang phenomena, Liesegang pattern, Runge pictures, Belousov-Zhabotinsky-reaction) (Published 1790 – 2003) (nearly a complete list of this literature) Second Edition (with a short new biography of the colloid scientist Raphael Eduard Julius Liesegang in german language) Klaus Beneke Institut für Anorganische Chemie der Christian-Albrechts-Universität der Universität D-24098 Kiel [email protected] Contents Preface 3 Neue Kurzbiographie über Raphael Eduard Julius Liesegang 6 Notice biographique de Raphael Eduard Julius Liesegang 37 Liesegang named in Literature (e. g. Liesegang-rings, periodic and rhythmic crystallization, Liesegang-phenomena, Liesegangpattern, Runge-pictures, Belousov-Zhabotinsky-reaction) (Published 1790 - 2003) (nearly acomplete list of this literature) 42 3 Preface This literature list was collected during many years I worked in the field of periodic and rhythmic crystallization. The interesting work and life of Raphel Eduard Julius Liesegang encouraged me to write a biography about him. Since 15 years I am searching all materials from him and about him. In the second edition of „Liesegang named in literature“ the Belousov-Zhabotinskyreaction is new in this literature list of all the years. Boris Pavlovič Belousov1 (1893 Sarntow - 1970 Moscow) found 1951 the reaction now named Belousov-Zhabotinskyreaction (BZR), but first published in 19592. He discovered that if citric acid, acidified bromate and a ceric salt were mixed together the resulting solution oscillated periodically between yellow and clear. Anatoli Markovič Zhabotinski (born 1938 in Moscow) made an extended selection of the oscillation reactions3. He refined the reaction, replacing citric acid Boris Pavlovic Belousov with malonic acid and discovering that when a thin, homogenous layer of the solution is left undisturbed, fascinating geometric 1 Boris Pavlovich Belousov was born in Russia during the 19th century and was one of five children. His older brother first interested Belousov in science while constructing an explosive to assasinate the Czar. (It should be noted that they were unsuccessful in this attempt.) After moving to Switzerland, Belousov devoted himself to science and studied chemistry in Zurich. When World War I began, he returned to Russia to .ght, but he was not admitted to the army because of a health problem. He worked in a military laboratory and eventually studied under the famous chemistry professor, Ipatiev. Belousov was quickly recognized for his research and was awarded the very high rank of Combrig. Later in his career, he became head of the Laboratory of Biophysics associated with the USSR Ministry of Health. During his research on the Krebs cycle, he discovered that a solution of citric acid in water (with acidified bromate as oxidant and yellow ceric ions as catalyst) turned colorless and then back to yellow for an hour while effervescing carbon dioxide. The study of oscillating reactions was born. From: Gray Casey R (2001) An analysis of the Belousov-Zahbotinskii reaction. URL: http://www.rose-hulman.edu/mathjournal/2002/vol3-n1/paper1/v3n1-1pd.pdf (03.05.04) 2 Belousov B P (1958) Eine peridische Reaktion und ihr Mechanismus (in Russian). Sbornik referatov po radiacionnojj medicine za 1958 g. Moscow 1959: 145-147. Übersetzt von E. Gey In: F. F. Runge, R. E. Liesegang, B. P. Belousov, A. M Zhabotinsky, Selbstorganisation chemischer Strukturen. Ostwalds Klassiker der exakten Wissenschaften, Band 272. Ausgewählt von L. Kuhnert und U. Niedersen. Verlag Harri Deutsch, Frankfurt (1987): 71-72 3 Zhabotinsky A M (1964) Periodic liquid phase reactions (in Russian) [Eine periodische Oxydationsreaktion in flüssiger Phase] Doklady Akademija Nauk SSSR [Proccedings of the Academy of Science in the USSR] 157: 392-395 4 patterns such as concentric circles and Archemedian spirals propagate across the medium. Therefore, the reaction oscillates both in space and time, a so-called spatiotemporal oscillator. The BZR belongs to the models of the dissipative systems. Anatol M. Zhabotinski Friedlieb Ferdinand Runge Raphael Eduard Julius Liesegang (01.11.1869 Elberfeld, now Wuppertal - 13.11.1947 Bad Homburg vor der Höhe) was a remarkably man and a very active colloid scientist. When he published in 1896 “Alines“4 he started a series of publications also from other authors round the world. But there were authors who published also in this field before 1896. One of this man was the famous chemist Friedlieb Ferdinand Runge (08.02.1795 Billwärder, now Hamburg - 25.03.1867 Oranienburg, near Berlin) who published two books "About the chemistry of colors“ (1850)5, he dedicated king Friedrich Wilhelm IV. (1795 - 1861; king of Prussia 1840 - 1861) and "The urge of development of substances" (1855)6. You find there beautiful colored and structure rich pictures which he created without color and brush. The pictures were painted on special paper (filter paper) by dripping different solutions gradually on the center of 4 Liesegang R E (1896) A-Linien. Liesegang´s Photograph Archiv 37 Nr. 801 (1. Nov. 1896): 321-326 5 Runge F F (1850) Zur Farben-Chemie. Musterbilder für Freunde des Schönen und zum Gebrauch für Zeichner, Maler, Verzierer und Zeugdrucker. 1. Lieferung. Dargestellt durch chemische Wechselwirkung. Verlag E. S. Mittler & Sohn, Berlin 6 Runge F F (1855) Der Bildungstrieb der Stoffe. Veranschaulicht in selbständig gewachsenen Bildern. (Fortsetzung der Musterbilder). Selbstverlag, Oranienburg 5 the paper. "Blots of the professor“ named F. F. Runge some of his very nice and wonderful pictures. Everybody who worked with and made Runge pictures was fascinated about this pictures which can be easily produced and even with few fantasy. Raphael Eduard Julius Liesegang named his periodic precipition “A-lines“. Wilhelm Ostwald (02.09.1853 Riga - 04.04.1932 Großbothen, near Grimma), NobelPrize winner in chemistry 1909, named this phenomena Liesegang-rings in 18977. Since this time this phenomena and periodic precipition is called Liesegang-rings. The next pages you find a new short biography of Raphael Eduard Julius Liesegang in German and an elder biography in French language. I am very grateful to Prof. André Lange, Strasbourg, for the French translation. 7 Ostwald Wi (1897) Besprechung der Arbeit von Liesegangs „A-Linien“. Z Physikal Chem 23: 365 Ostwald Wi (1897) Liesegang-Ringe. In: Lehrbuch der Allgemeinen Chemie. 2. Auflage. Engelmann-Verlag, Leipzig: 768 6 Kurzbiographie über Raphael Eduard Julius Liesegang (März 2004) Klaus Beneke Institut für Anorganische Chemie der Christian-Albrechts-Universität der Universität D-24098 Kiel [email protected] Raphael Eduard Liesegang (01.11.1869 Elberfeld (heute Wuppertal) 13.11.1947 Bad Homburg v. d. Höhe) wurde als Sohn des späteren Fabrikbesitzers Paul Eduard Liesegang (26.06.1838 Elberfeld - 1896 Düsseldorf) geboren. Der Vater hatte in Jena Physik studiert, wobei er Ernst Abbe (23.01.1840 Eisenach 14.01.1905 Jena) kennenlernte, und dadurch in den näheren Kontakt mit der Optik kam und mit dem Bau von Projektionsapparaten begann. Nach dem Studium, er promovierte 1859 zum Dr. phil. in Jena, stieg er in das von seinem Vater Friedrich Wilhelm Eduard Liesegang (1803 - 1869) 1854 gegründete photograpische Atelier in Elberfeld ein. Der Großvater R. E. Liesegangs vergrößerte sein Atelier und stellte außerdem Fotokameras her und lieferte dazu das selbsthergestellte Albuminpapier. Nach dem Tode des Großvaters wurde das Geschäft 1871 vergrößert und nach Düsseldorf verlegt. Somit kam R. E. Liesegang mit zwei Jahren mit zwei seiner Geschwister (zwei weitere wurden in Düsseldorf geboren) nach Düsseldorf und wurde hier 1876 eingeschult. Häufig schwänzte er die Schule und machte seine Hausaufgaben nicht. Ab der dritten Klasse bekam er Nachhilfeunterricht in Mathematik, aber das Verständnis für Zahlen besserte sich nicht. Auf dem Gymnasium, in der Sexta, hatte er große Schwierigkeiten mit dem Schreiben, ein Gedicht auswendig lernen war ihm unmöglich, 7 obwohl er den Sinn behielt, aber nicht die Form. Außerdem konnte er lesen und sprechen, aber nicht vorlesen. Wiederum hatte er, auch noch im hohen Alter, ein ausgezeichnetes fotografisches Gedächtnis. Er blieb in der Sexta sitzen und wurde von der Schule genommen. Nach einem Jahr Privatunterricht wechselte er auf das Realgymnasium, welches er von 1881 bis 1887 mit mäßigem Erfolg und zwischenzeitlichem Sitzenbleiben, mit dem „Einjährigen", dem heutigen Realschulabschluß, verließ. Die Familie verbrachte ihren Urlaub gerne in Holland. Hier erwarb R. E. Liesegang eine in niederländisch geschriebene Grammatik der malayischen Sprache, welche er unter der Schulbank, während des Unterrichts ins Deutsche übersetzte. Diese Grammatik wurde im eigenen Verlag seines Vaters publiziert, der ab 1860 die Zeitschrift Photographisches Archiv herausgab. Dies war das erste der vielen Bücher und Veröffentlichungen Liesegangs, die er während seines Lebens schrieb. Raphael Eduard Liesegang sprach später neben Malayisch noch sechs weitere Sprachen. Während dieser Zeit war es Liesegangs Wunsch, Maler zu werden. Sein Vater richtete ihm in der Dachkammer ein Atelier ein. Sonntags bekam er Unterricht von einem Maler. Hier hatte er Ruhe vor seinen Brüdern und seiner Schwester. Der Vater wollte von dem Beruf des Malers nichts wissen, und so wurde dieser Wunsch langsam aufgegeben. In Grönenbach im Allgäu belegte R. E. Liesegang einen Kurs über Photografie und photomechanische Verfahren und wechselte danach für ein Jahr zu Carl Remigius Fresenius (28.12.1818 Frankurt a. Main - 11.06. 1897 Wiesbaden) nach Wiesbaden, wo er einen Kurs über analytische Chemie belegte. 1888 ging er zum Chemiestudium nach Freiburg, wobei er aber praktisch keine Vorlesungen besuchte. Interessanter fand er das Kaffeehausleben, wo er die Bekanntschaften mit Schauspielerinnen und Schauspielern machte. In den Semesterferien schrieb er wissenschaftliche Arbeiten und Bücher. So u. a. 1888 über Lichtempfindliche organische Silbersalze im PhotoRaphael Eduard Liesegang (um 1903) graphischen Archiv und 1891 das Buch 8 Beiträge zum Problem des electrischen Fernsehens8. Ohne Abschluß, da er ja keine Vorlesungen besuchte und Prüfungen ablegte, aber sehr viele Publikationen schrieb, begann er 1892 in der photographischen Fabrik seines Vaters in Düsseldorf zu arbeiten. Hier entwickelte er 1892 das erste matte Zelloidinpapier und den Hydrochinonentwickler Aristogen. R. E. Liesegang arbeitete an vielen Problemen der Photografie, es erschienen darüber viele Arbeiten. 1896 berichtete er über periodische Fällungserscheinungen in Gelen9, die später von Wilhelm Ostwald (02.09.1853 Riga - 04.04.1932 Großbothen (bei Leipzig)) Liesegangsche-Ringe genannt wurden10. R. E. Liesegang heiratete 1895 Luise Stern (22.01.1870 Düsseldorf 29.12.1936 Düsseldorf), die Schwester des Düsseldorfer Kunstmalers Max Stern (15.06.1872 Düsseldorf - 12. Juni 1943 Düsseldorf. Dieser hatte im Dritten Reich als Jude Malverbot und starb nach einem Bombenangriff der Allierten, da er keinen Luftschutzbunker aufsuchen durfte. Aus der Ehe mit Luise Stern hatte Raphel Eduard Liesegang eine Tochter, Edith Maria Victoria Mara Liesegang (06.04. 1896 Düsseldorf - 09.12.1948 Überlingen am Bodensee), die als Schriftstellerin (Lyrik, Prosa, Laienspiel) tätig war. Die Ehe von R. E. Liesegang mit Luise Stern wurde 1912 geschieden. Max Stern mit Frau Alice 8 Als der Vater 1896 starb, übernahmen R. E. Liesegang und zwei seiner Liesegang R E (1891) Beiträge zum Problem des electrischen Fernsehens. (Probleme der Gegenwart, Band 1). Ed. Liesegang Verlag, Düsseldorf, 1891, 130 Seiten. Preis 3 Mark Liesegang R E (1899) Beiträge zum Problem des electrischen Fernsehens. (Probleme der Gegenwart, Band 1) 2. Auflage Ed. Liesegang Verlag, Düsseldorf/Leipzig 1899, 228 Seiten 9 Liesegang R E (1896) A-Linien. Liesegang´s Photograph Archiv 37 Nr. 801 (1. Nov. 1896): 321-326 10 Ostwald Wi (1897) Besprechung der Arbeit von Liesegangs „A-Linien“. Z Physikal Chem 23: 365 Ostwald Wi (1897) Liesegang-Ringe. In: Lehrbuch der Allgemeinen Chemie. 2. Auflage. Engelmann-Verlag, Leipzig: 768 9 Brüder die Fabrik. Dabei stellte er als erstes die Handpräparation des Zelloidinpapieres auf Maschinenpräparation um, welches sein Vater vorher immer ablehnt hatte. Als die Farbenfabriken Friedrich Bayer & Co. in Leverkusen Interesse an der Photopapier- und Entwicklerabteilung zeigte, verkaufte er diesen Teil der Firma 1904, dem später ältesten Teil der Agfa. Die optische Abteilung wurde von seinen beiden Brüdern Franz Paul Liesegang (05.03.1873 Elberfeld - 31.03. (12.)1949 Düsseldorf) und Albert James Liesegang (1878 Düsseldorf - 1951 Düsseldorf) in Düsseldorf weitergeführt, während Raphael Eduard Liesegang 1908 endgültig aus der Firma ausschied. R. E. Liesegang ging Anfang 1908 nach Frankfurt an das Senckenberg Museum, wo er unter Ludwig Edinger (13.04.1855 Worms - 26.01.1918 Frankfurt a. Main) am Neurologischen Institut durch Silberimprägnationen an Gehirngeweben (Golgi-Methode, Golgi-Färbung) die feinen Verästelungen der Neuronen sichtbar machte11. Im Ersten Weltkrieg leitete R. E. Liesegang u. a. zeitweise die Narkotikaabteilung des Sanitätsdepots in Frankfurt am Main. Nach dem Krieg arbeitete er vorübergehend in der Papierfabrik Schoeller in Gretesch bei Osnabrück, mit deren Familie er schon lange, wohl aus der Zeit in der Firma Liesegang, befreundet war. 1921 wurde er Mitarbeiter am Kaiser-Wilhelm-Institut für Biophysik in Frankfurt am Main und 1937 ebenda Leiter des Instituts für Kolloidforschung. 1944 wurde das Institut nach Bad Homburg verlegt. R. E. Liesegang heiratete am 13.07.1912 in Frankfurt am Main Gertrud Sofie Auguste Möllhausen mit der er die Tochter Eva Martha Carola Hildegard (genannt Ewa) Liesegang (29.12.1909 Biebrich bei Wiesbaden - 29.12.1952 Marburg an der Lahn) hatte. Ewa Liesegang war eine bemerkenswerte und hilfsbereite Frau und ähnelte ihrem Vater. Sie trug nur Hosen, sportliche Hemden und ein rundes rotes Filzkäppi auf dem Kopf, sportlich flache Schuhe oder „Knobelbecher“, wirkte also recht burschikos. Ihre Tätigkeiten erstreckten sich u. a. über journalistische Arbeiten, als Schiffsjunge verkleidet auf einem russischem Schiff welches in Seenot geriet und wissenschafliche Assistentin. Sie arbeitete ab 1942 in einer Arztpraxis und half dem Arzt Dr. Kurt Hanf-Dressler (24.02.1904 Berlin - 24.02.1971 in der Silvretta im Bieltal bei der Abfahrt von der Wiesbadener Hütte mit seiner zweiten Frau Liselotte Wendel und noch zwei Ärzten in einer Staublawine), der trotz seiner antinational11 Liesegang R E (1911) Die Kolloidchemie der histologischen Silberfärbungen. Kolloidchem Beihefte 3 Heft 1/2: 1-46 Liesegang R E (1911) Das Verhalten minimaler Räume bei einigen Färbungen. Z wiss Mikroskop 28 Heft 3: 257-260 10 sozialistischen Einstellung im NS-Ärztebund Mitglied war, Juden und Andersdenkende zu verstecken. Sie versteckten diese u. a. in der 1919 vom Dachdecker Roth gebauten „Rothshütte“ bei Omersbach (gehört heute zu Geiselbach/Bayern) im Spessart, die Dr. Hanf-Dressler etwa 1936/37 erworben hatte. Hier lebte auch die Familie von Dr. Hanf-Dressler (Frau und drei Kinder) und Ewa Liesegang nach der Ausbombung aus Frankfurt. Dr. Kurt Hanf-Dressler war Internist und hatte in Frankfurt eine Praxis und war später auch Arzt an der Viktoriaklinik an der Westendstraße. Dr. Kurt Hanf-Dressler lernte Raphael Eduard Julius Liesegang als Patienten während einer lebensbedrohenden Magenblutung (Magendurchbruch) (1940/41) kennen, er behandelte diesen und beide befreundeten sich. Dr. Kurt Hanf-Dressler war einer der wenigen der das Arbeitszimmer, im Gegensatz zur Familie Liesegang, von Raphael Eduard Liesegang in seinem Haus in Frankfurt betreten. Frau Heide Lauterbach schrieb dazu in einem Brief12: „Liesegang, ein Mensch, der von Wissensdurst besessen sein Leben von morgens bis abends forschend in seinem Arbeitszimmer verbrachte, das für andere Menschen – auch die engste Familie – tabu war. Das Essen musste ihm hereingereicht werden. Mein Vater war einer der wenigen, die Zugang hatten und hat diesen Raum als undurchschaubares Chaos erlebt. Liesegang hatte sein ihm eigenes Ordnungsprinzip, nach dem er auch eine Jahrzehnte zurückliegende Zeitungsnotiz auf Anhieb während des Gesprächs gut nebenbei herausziehen konnte“. Nach der Ausbombung in Frankfurt arbeitete Dr. Kurt Hanf-Dressler am Krankenhaus in Gelnhausen, das ca. 18 Kilometer von Omersbach liegt, und in der Obhut von braunen „Nazischwestern“ lag. Hier regierte mit harter Hand der Gauleiter und Reichstatthalter in Hessen Jakob Spenger (1885 - 1945). Auch hier versteckte Dr. Kurt Hanf-Dressler, wie schon in Frankfurt, jüdische Mitbürger in dem er sie u. a. in der Klinik unter falschen Namen arbeiten ließ. Dort kämpfte er auch für die Menschlichkeit und stellte mehrere Strafanzeigen wegen Mordes an alten Menschen und Gefangenen. Jakob Sprenger rettete seinen „Leibarzt“ persönlich vor der Gestapo und empfahl ihn nach Berlin, wo er dem Generalbevollmächtigten für Hygenie und Gesundheitswesen Dr. Brandt dienstverpflichtet sein sollte. Dieser stand an der Spitze des Vernichtungsapparates der Nationalsozialisten. Dr. HanfDressler lehnte eine Zusammenarbeit mit diesem kategorisch ab und durfte in 12 Karte (handgescheiben) von Frau Heide Lauterbach Frankfurt a. Main, Tochter von Dr. Hanf-Dressler vom 30.06.2003 mit einem Anhang (maschinengeschrieben) ihrer Kindheitserinnerungen über Raphael Eduard Liesegang und ihren Vater Dr. Hanf-Dressler sowie Omersbach. 11 Gelnhausen bleiben. Ewa Liesegang konnte Dr. Hanf-Dressler auch einmal vor einem NS-Spitzel bewahren. Der mutige Arzt Dr. Kurt Hanf-Dressler machte 1952 in Frankfurt eine Praxis auf wurde später Chefarzt und Direktor des Bürgerhospitals in Frankfurt am Main. Er verstarb 1971 beim Skifahren in einer Staublawine in Österreich. Rothshütte bei Omersbach (2003) Valentin Senger (1918 Frankfurt a. Main 04.09.1997 Frankfurt a. Main), der als Jude im Dritten Reich in Frankfurt überlebte, beschrieb in seinem Buch Kaiserhofstraße 12 die Begegnung mit dem Arzt Dr. HanfDressler13 als er diesen in seiner Praxis wegen Magenschmerzen aufsuchen mußte. Dort liest man: „Eines Tages wurden meine Magenschmerzen so schlimm, daß ich sie nicht mehr aushalten konnte. Ich wälzte mich auf meinem Bett, rang nach Luft, massierte den Magen oder legte kochendheiße Tücher auf, daß ich bald aussah wie ein gesottener Krebs, nichts half. Ich mußte einen Arzt aufsuchen, um mir schmerzlindernde Mittel verschreiben zu lassen, es blieb mir keine andere Wahl. Mama war entsetzt, als ich ihr sagte, ich wollte zu einem Arzt gehen, denn sie war sicher, er werde sofort auf meine Beschneidung aufmerksam werden und mich danach fragen. Auch Papa und meine Geschwister waren voller Sorge, aber an Ende sahen sie ein, daß ich mit diesen Schmerzen nicht mehr weiterleben konnte. So wurde der Arztbebesuch von der ganzen Familie beschlossen. Bisher hatten weder Papa, Alex noch ich einen Arzt gebraucht und wir machten uns auch nie Gedanken darüber, wie wir uns in einem solchen Fall verhalten sollten. Von Mama kam die Idee, wie so oft im Ansatz kühn, doch unausgereift und letztlich dilettantisch. In Südrußland gab es zu der Zeit, als Mama dort lebte, noch immer verhältnismäßig große Gemeinden der verbotenen Sekte der Skopzen. Die Anhänger dieser im 17. Jahrhundert gegründeten und völlig im Sühnegedanken verstrikten christlich13 Besuch beim Arzt. In: Valentin Senger, Kaiserhofstraße 12. 2. Auflage. Hermann Luchterhand Verlag Darmstadt und Neuwied 1980, Seite 119-125 12 schwärmerischen Gruppe hatten die schreckliche Angewohnheit, ihren vermeintlichen Schuldanteil an der Erbsünde durch Selbstverstümmelung zu bezahlen. Dieser Brauch hatte sich im Laufe der Zeit auf ein symbolisches Beschneiden der Vorhaut reduziert. Während ich die Fäuste in die Magengrube preßte und dabei stöhnte, schärfte Mama mir ein: „Merck dir gut, Walja, was du dem Arzt zu sagen hast, wenn er nach deiner Beschneidung fragen sollte: deine Eltern, die Wolgadeutsche sind, gehörten der Sekte der Skopzen an, bei denen das Beschneiden üblich war. Das ist der Grund, weshalb auch du beschnitten bist. Wenn der Arzt noch mehr wissen will, sagst du, das sei nach deiner Geburt gemacht worden, irgendwo in einem Frankfurter Krankenhaus. Und sonst sagst du nichts, kein Wort, hast du verstanden?“ Ich merkte mir die Geschichte gut, obwohl ich große Zweifel hatte. Aber wie das in der Familie so üblich war, widersprach ich Mama nicht. Warum, auch? Sollte ich sie noch unglücklicher machen? In einem offiziellen Verzeichnis fanden wir unter der Rubrik „Fachärzte für Magen- und Darmkrankheiten“ den Namen Dr. Kurt Hanf-Dreßler. Mama erinnerte sich, daß auch Frau Volk aus dem Vorderhaus zu ihm ging und ihn gelobt hatte. Seine Praxis war nicht weit von uns entfernt, am Blittersdorfplatz. Der Abschied, den mir meine Familie bereitete, als ich mich auf den Weg zum Arzt machte, war wie bei einer Trennung für immer. Diese fünfzehn Minuten die Mainzer Landstraße hinauf wurden zu einem schweren Gang. Ich hatte Herzklopfen aber keine Magenschmerzen mehr. Sie waren wie weggeblasen, das erste Mal seit vielen Tagen. Ich überlegte, ob ich umkehren solle, aber ich wußte genau, die Schmerzen würden wiederkommen. Also ging ich weiter. Im Wartezimmer des Arztes saßen etwas zwanzig Personen gelangweilt herum und blätterten in Zeitungen und Zeitschriften. Ich war ein wenig erleichtert, denn ich konnte mir ausrechnen, daß ich noch mindestens zwei Stunden oder auch drei bis zur Untersuchung haben würde. Mir war noch eine Frist gegeben. Meine Magenbeschwerden waren inzwischen tatsächlich weg. Viel zu schnell hintereinander wurden die Personen aufgerufen. Nun saßen nur noch fünf vor mir. Die Tür öffnete sich und statt der Sprechstundenhilfe stand der Arzt selbst im Türrahmen, um den nächsten Kranken hereinzubitten. Unter dem weißen Kittel trug er eine braune Uniform, offenbar eine von der SA. Am Hals erkannte man das Braunhemd mit irgendwelchen Chargenspiegeln und an den Beinen über 13 Breecheshosen braune Reitstiefel. - Später erfuhr ich, daß Dr. Kurt Hanf-Dreßler ein Führer in der Frankfurter Reiter-SA war. Bei diesem Anblick kam mir nicht einmal Mamas „Maseltow“ in den Sinn. Verschwinden wäre das einzige Vernünftige gewesen. Noch war Zeit, niemnd hätte mich aufgehalten. Oft habe ich mich gefragt, warum ich in diesem Augenblick nicht gegangen bin. Ich blieb im Wartezimmer sitzen mit den Mark[g]en- und Darmkranken, blätterte in alten, abgegriffenen Zeitschriften, hörte den SA-Doktor im Nebenzimmer hantieren und sprechen, zählte die Patienten, die noch vor mir waren, jetzt noch drei, noch zwei - und wartete, bis ich aufgerufen wurde. Und dann saß ich auf dem Stuhl vor ihm, zwischen uns der Schreibtisch, und erzählte ihm, welche Beschwerden ich hatte. Doktor Hanf-Dreßler hörte, so schien es mir, uninteressiert hin, machte sich noch irgendwo einige Notizen, verstaute eine Karteikarte in der Schublade und sagte: „Nun machen Sie mal den Oberkörper frei und legen sich dort auf die Liege.“ Ich tat wie geheißen. Er beugte sich über mich, und ich sah nichts weiter als die beiden Chargenspiegel auf dem braunen Hemd mit den silbernen Sternen drauf, gefältete Knopfaugen einer bösen Fratze. Seine Finger drückten hier und dort auf den Bauch und ertasteten zwischen den Rippen das Zentrum der Schmerzen. Dann drückte er den unteren Bauch ab. „Tut´s hier auch weh?“ „Nein.“ „Hier?“ „Nein.“ „Öffnen Sie mal die Hose.“ Während ich noch zögernd an den Knöpfen herumnestelte, zog er mir die Hose, wie er es wohl oft machte, nach unten. „Nanu, was ist denn das?“ 14 „Was meinen Sie?“ „Sind Sie beschnitten?“ „Nein - doch.“ „Was heißt das: nein, doch?“ Stotternd begann ich meine Geschichte von den Skopzen, deren Schuldbewußtsein um die Erbsünde so weit ging, daß sie sich selbst entmannten, und daß mich darum meine Eltern hätten beschneiden lassen. Ich weiß nicht, wie weit ich gekommen war, als er mich ärgerlich anfuhr: „Erzählen Sie mir keinen solchen Blödsinn. Sie sind doch in Frankfurt geboren. Wer hat den Schnitt gemacht?“ „Ich wurde in einem Krankenhaus beschnitten.“ „Wenn das von einem Arzt gemacht worden wäre, dann sähe das ganz anders aus. Haben sie daran schon einmal gedacht, wenn Sie solche Geschichten erzählen?“ Ja, aber Sie können mir glauben - „. Scharf unterbrach mich Dr. Hanf-Dreßler: „Jetzt hören Sie endlich auf mit dem dummen Zeug! Passen sie genau auf, was ich Ihnen sage: Jeder Arzt, nicht nur ich, erkennt das einwandfrei als rituellen Schnitt eines jüdischen Beschneiders.“ Und nach einer ganzen Weile: „Solche Geschichten lassen Sie mal in Zukunft.“ Dabei tastete er mich immer weiter ab. „Haben Sie hier Schmerzen?“ „Nein.“ „Und hier?“ „Nein.“ Er zog mir mit einem Ruck die Hose wieder hoch, richtete sich auf, ging ans Waschbecken, wusch sich die Hände und sagte: „Sie können sich wieder anziehen. Ihre Magenbeschwerden scheinen nervöser Natur zu sein. Möglicherweise ist auch eine Gastritis dazugekommen, eine Magenschleimhautentzündung. Ich verschreibe Ihnen eine Rollkur.“ 15 Dann setzte er sich an den Schreibtisch, füllte ein Rezeptformular aus, erklärte mir noch, wie ich die Rollkur machen müsse, welche Diät ich in der nächsten Zeit einhalten solle, und verabschiedete sich mit den Worten. „Wenn´s garnicht besser wird, müssen Sie halt noch mal kommen. Auf Wiedersehen, Herr“- er schaute auf die Karteikarte: „Herr Senger.“ Er öffnete mir die Tür zum Flur, wandte sich an seine Sprechstundenhilfe: „Der nächste Patient!“ und ging in sein Ordinationszimmer zurück. Die Tür schloß sich. Und wieder schien es, als ob wir am Ende angekommen seien. Jeder SAMann hatte einen feierlichen Treueid geleistet, Hitler und dem Dritten Reich zu dienen und die Marxisten und Juden zu bekämpfen, damit die arische Rasse reinerhalten bleibe. So war auch der SA-Mann Dr. Hanf-Dreßler verpflichtet, Meldung über einen getarnten Juden zu machen. Aus seinen Bemerkungen während der Untersuchung war deutlich zu verstehen gewesen, daß er mich als Jude erkannt, wenn man so will: entlarvt hatte. Und noch etwas kam hinzu: in dieser Zeit, es mag Ende 1938 oder Anfang 1939 gewesen sein, war bereits das Gesetz in Kraft getreten, nach dem alle Juden einen kennzeichnenden Vornamen tragen mußten, bei Frauen „Sarah“, bei Männern „Israel“. Mit diesem Vornamen wurden nicht nur die polizeilichen Unterlagen, Pässe und andere Ausweise ergänzt, jedes amtliche oder nichtamtliche Formular, das ein Jude auszufüllen, jede Unterschrift die er zu leisten hatte, mußten mit dem ausgeschriebenen Zwangsvornamen versehen sein. So war es für den Arzt einfach, anhand meines Krankenscheins zu erkennen, daß ich nicht als Jude registriert war, es fehlte der kennzeichnende Vorname Israel. Ich war also, so mußte zwangsläufig seine Schlußfolgerung sein, auf illegale Weise durch die Maschen des Gesetzes geschlüpft, und hier spätestens hörte seine ärztliche Schweigepflicht auf, denn der fehlende Vorname Israel hatte nichts mit meinen Magenbeschwerden zu tun - oder doch nur sehr mittelbar. Zu Hause erzählte ich nichts von meinem Erlebnis. Was würde es auch nützen? Mama bekäme erneut einen Herzanfall, und Papa würde ihr kalte Tücher aufs Herz lehen, im Zimmer auf und ab gehen und stöhnen: O Gott, mit was haben wir das verdient?“ Nur Alex erzählte ich davon. Er war überzeugt, Dr. Hanf-Dreßler würde eine Meldung machen. Gemeinsam warteten wir darauf, daß nunmehr der Ernstfall eintrete. Nach Tagen schrecklicher Ungewißheit mußte ich erkennen, daß der Arzt 16 geschwiegen und so unsere Familie vor der Deportation und damit vor der Vernichtung bewahrt hat. Viele Jahre später erfuhr ich, Dr. Hanf-Dreßler habe, obwohl er in der ReiterSA war, einer Reihe von Juden geholfen, habe sie trotz Verbots in seiner Praxis behandelt, außerhalb der Sprechstunde, und in seinem Jagdhaus im Spessart ein jüdisches Ehepaar über ein halbes Jahr versteckt gehalten, bis sich eine Gelegenheit fand, die beiden illegal über die Grenze zu bringen. Und in seiner Privatklinik im Frankfurter Westend habe er bis zu deren Zerstörung durch amerikanische Bomber eine jüdische Ärztin unter falschem Namen als Krankenschwester beschäftigt. Dr. Hanf-Dreßler hatte nach Kriegsende einige Zeit in der Provinz gearbeitet und war erst in den fünfziger Jahren nach Frankfurt zurückgekehrt. 1967 erfuhr ich zufällig, daß er Chefarzt im Bürgerhospital sei. Da nahm ich mir vor, ihn aufzusuchen, unsere damalige Begegnung in seiner Praxis zu schildern und ihm zu danken. Ich zögerte, zu ihm zu gehen, vielleicht würde er mich mißverstehen. Meine Frau drängte mich. Ein letztes Mal redeten wir um die Weihnachtszeit 1970 darüber. Ich versprach, nun endlich mit Dr. Hanf-Dreßler einen Termin auszumachen. Anfang Februar 1971 rief ich im Bürgerhospital an. Von seiner Sekretärin bekam ich die Auskunft, der Chefarzt sei zur Zeit im Urlaub. Wenn ich ihn sprechen wolle, müsse ich mich in zwei Wochen noch einmal melden. Einige Tage nach diesem Anruf las ich in der „Frankfurter Rundschau“ die Meldung: „Der Chefarzt des Bürgerhospitals, Dr. Kurt Hanf-Dreßler, ist am 24. Februar 1971, an seinem 67. Geburtstag, zusammen mit seiner Frau beim Skilaufen im Silvretta-Gebiet in den österreichischen Alpen durch eine Staublawine ums Leben gekommen.“ Heide Lauterbach, die Tochter von Dr. Hanf-Dreßler schrieb in einem Brief: „Bei dem schweren Bombenangriff auf Frankfurt, am 22. März 1944, wurde sowohl unser Haus am Blittersdorfplatz als auch das von Liesegangs in der Kronberger Straße vollkommen zerstört. Mein Vater, der als Arzt noch sein Auto zur Verfügung hatte, machte nach dem Angriff die Runde bei allen Freunden. Vater Liesegang fand er auf einem Stein sitzend vor seinem zerstörten Haus. Er schrieb ein Gedicht. „Den Ballast bin ich los!“ sagte er zu meinem Vater, und das betraf auch sein gesamtes wissenschaftliches Werk. Die letzte Arbeit war noch gar nicht gedruckt, also unwiederbringlich verloren. Er soll sie aus dem Gedächtnis neu geschrieben haben“. 17 Auch Raphael Eduard Liesegang lebte nach der Ausbombung in Frankfurt (22. März 1944) bei der Bauersfrau Lina Fleckenstein, geb. Bittel (29.11.1914 Omersbach - 01.01.2003 Alzenau-Wasserlos) in Omersbach, deren Mann im Krieg vermißt wurde. Ewa Liesegang hatte ihn dort untergebracht. Mit „Frau Lina“ wie er sie nannte kam er sehr gut aus, sie verwöhnte ihn wo sie nur konnte, was bei seiner kauzigen Art nicht immer leicht war. Er war für sie so etwas wie ein Wesen aus einer anderen Welt, das sie mit aufmerksamerer Ehrerbietung behandelte, seine Eigentümlichkeiten freundlich belächelte und bei jeder Gelegenheit zum Besten gab. „Der Bauernhof mit seinen Bewohnern, die dort sehr ärmliche Landwirtschaft, Kühe, Schafe, Hühner, die pure Natur um ihn herum, schienen für den Naturwissenschaftler ganz neue und viel direktere Perspektiven zu erschließen, die er mit Vergnügen erlebte und erforschte“. Helmut Fleckenstein berichtete, daß Raphael Eduard Liesegang Pilzkulturen im Wald angelegt hatte und ihm gesagt hatte, daß nach 8 Jahren dort Pilze wachsen. Helmut Fleckenstein hat dies aber nicht überprüft. „Hoch aufgerichtet und gravitätisch mit seiner unverzichtbaren „Melone“ auf dem Kopf und einem Gänseblümchen im Knopfloch schritt er durch Wiesen und Felder. Er war schon eine bemerkenswerte Gestalt in dieser Umgebung“, schrieb Frau Heide Lauterbach in einem Brief. Omersbach war 1945 als Raphael Eduard Liesegang dort eintraf ein kleines Dorf mit ca. 250 Einwohnern. Es gab nur unbefestigte Straßen und keine Kanalisation. Omersbach gehört seit 1972 zu Geiselbach im Landkreis Aschaffenburg zum Regierungsbezirk Unterfranken des Freistaates Bayern, und Omersbach (2003) ist unmittelbar an der bayrisch/hessischen Staatsgrenze gelegen. Der Ortsteil Geiselbach hat heute 1 603, der Ortsteil Omersbach 693 Einwohner (insgesamt 2 296 Einwohner; Stand Januar 2004). Zwischen 1799 und 1815 wurde das bayrische Staatsgebiet neu gebildet und es entstanden neue Gemeinden. Aus über 40 000 Gemeinden wurden rund 7 300. Unterfranken war aber vor 1800 Herrschaft und gehörte zum Großherzogtum 18 Hessen-Darmstadt. Im Reichsdeputationshauptausschuß im Jahre 1803 wurde die ehemalige Herrschaft der Abtei Seligenstadt ein Teil des neugebildeten Fürstentums Aschaffenburg. Diese überließ es 1806 dem Großherzogtum Hessen-Darmstadt. Im Rezeß Hessen/Bayern (Frankfurt 1816) fiel die Herrschaft an Bayern. Im Münchner Vertrag von 1816 und einigen Folgeverträgen erhielt Bayern die Rheinpfalz und einige kleinere Gebiete in Unterfranken. Hier in Omersbach ging „Vater Liesegang“, wie er liebevoll von den Kindern genannt wurde seiner Wissenschaft nach. Da in Frankfurt in seinem Haus alles verbrannt war konnte er mit Hilfe seines ausgezeichneten fotographischen Gedächtnisses vieles auf Notizpapier niederschreiben. Er machte auch Spaziergänge, ging in den Wald und sammelte Pilze, Beeren und Brennnesseln. Von letzteren ließ er sich von „Frau Lina“ gerne ein Gemüse machen, was übrig blieb wurde an die Tiere verfüttert. Raphael Eduard Liesegang war überhaupt nicht verwöhnt und beim Essen sehr genügsam auch legte er Fastentage ein. Dieses sah „Frau Lina“ überhaupt nicht gerne, war er doch ein hagerer Mensch. So wurde ihm an den Fastentagen so nebenbei in der Nähe seines Zimmers etwas Eßbares in einer Schüssel hingestellt, wovon er wenn er nicht beobachtet wurde ab und Lina Fleckenstein (um 1945) an heimlich naschte. Mit dem Plumsklo die es damals in Omersbach noch überall gab hatte Raphael Eduard Liesegang so seine Probleme. Vielleicht hatte das auch etwas mit seiner erlittenen Magenblutung (Magendurchbruch) zu tun. Frau Heide Lauterbach schrieb dazu: „Eine weitere außergewöhnliche Empfindlichkeit Liesegangs bezog sich auf seine „Notdurft“. Alles, was damit zusammenhing, war ihm peinlich und musste verheimlicht werden. Selbst das Geräusch der Wasserspülung war ihm unangenehm. Sicher hat es ihm große Schwierigkeiten bereitet, diesen Intimbereich stets vor der Umwelt zu verstecken, was besonders schwierig wurde, als er nach der Ausbombung auf das Dorf zog, wo es nur ein Plumpsklo auf dem Hof gab, das zu benutzen er verweigerte“. Nach dem Krieg ab August 1945 kam es wieder zum brieflichen Kontakt zum Verleger Dietrich Steinkopff (1901 - 1970) in Frankfurt, später in Darmstadt. Jetzt arbeitete Raphael Eduard Liesegang wieder an den Referaten für die Kolloid- 19 Zeitschrift, indem er hoffte, dass diese bald wieder erscheinen können. Auch plante er an Neuauflagen seiner wissenschaftlichen Buchreihe. Leider erfüllte sich beides vor seinem Tod nicht mehr. Dieser Briefwechsel zwischen Raphael Eduard Liesegang und Dietrich Steinkopff ist sehr interessant. Auch hier findet man wieder den „workoholiker“, wie man ihn schon vorher kannte. Ungebrochen vom Verlust seines Hauses in Frankfurt und den ganzen wissenschaftlichen Unterlagen und Sonderdrucken fing er wieder neu an zu arbeiten. Hier in dem kleinen Spessartdörfchen Omersbach schrieb er auch „frei von allen Hemmungen“ eine Autobiographie14. Im Abspann schrieb er: „Die Niederschrift des Lebenslaufs war in achtzehn Tagen entworfen. Das Fehlen der Unterlagen in dem kleinen Spessart-Dorf hatte keine Hemmungen gebracht. Ihr Fehlen erweckte eher das Gefühl des Freiseins von Ballast, die Grundlage für eine Vita nova. Was nicht im eigenen Gedächtnis hängen geblieben ist, das sollte Andere kaum interessieren“. In Omersbach experimentierte er auch wieder mit primitivten Mitteln und stellte seine Kapillarbilder (Runge-Bilder) aus. Nach der Befreiung bekam „Vater Liesegang“ sofort hohen Militärbesuch von den amerikanischen Besatzern, worunter sich auch ein Naturwissenschafter befunden haben soll der ihn aus der Literatur kannte. Dann sollte er wieder an das Institut in Bad Homburg vor der Höhe übersiedeln, um wieder wissenschaftlich zu arbeiten. Hier arbeitete sein Mitarbeiter Rolf Jäger (1905 - 1969), der aber Schwierigkeiten mit den Behörden hatte da er kein promovierter Chemiker war. Für den Umzug nach Bad Homburg wurde verlangt, dass Raphel Eduard Liesegang einen Fragebogen ausfüllen mußte. Das fand „Vater Liesegang“ lächerlich und er beantwortete die Fragen auf seine Art. Z. B. Woher bezogen Sie Ihr Wissen? Beantwortete er: „Aus Rotwein und Brasilzigarren“. Oder: „Wie stehen sie zum Judentum?“ „Selbst zwei jüdische Frauen gehabt“, schrieb mir dazu der Sohn von Dr. Kurt Hanf-Dressler, Tiglo Hanf-Dressler. Lina Fleckenstein war sehr traurig, als man ihn eines Tages abholte und zur Bahn Richtung Frankfurt brachte. Er entkam aber seinen Betreuern, indem er auf der anderen Seite des Zuges wieder ausstieg. „Frau Lina“ hörte ein leises „Piep“, das kann nur „Vater Liesegang“ sein, so wie er sich heimlich bemerkbar machte. Schließlich ging Raphel Eduard Julius Liesegang im November 1946 doch wieder von Omersbach nach Bad Homburg vor der Höhe. Er schrieb „Frau Lina“ noch einige 14 Und doch! Autobiographie von Raphael Eduard Liesegang (1869 - 1947) 20 Briefe, die stets unaufhörlich von ihren geliebten „Lissegang“ erzählen konnte. Auch lud er sie und ihren Sohn Helmut nach Bad Homburg vor der Höhe ein. Dazu kam es aber nicht mehr. Raphael Eduard Julius Liesegang hat bis zum 12. November 1947 gearbeitet. Er war erkältet und verlor in der Nacht das Bewußtsein. Er verstarb am 13. November gegen 18 Uhr an einem Lungeninfarkt. Wie wohl sich Raphael Eduard Liesegang bei Lina Fleckenstein fühlte soll ein Brief von diesem zeigen, den er am 1. November 1947 in Bad Homburg vor der Höhe, also 14 Tage vor seinem Tod, schrieb: „Liebe Lina! Haus der Lina Fleckenstein in Omersbach (2003) Schon Doktor Dressler hatte mir geschrieben, dass Sie so traurig wären. Ich bin davon gerührt, aber nicht einverstanden. Ich habe Sie ja nicht vergessen, wie Sie das fürchteten. Immer habe ich wieder daran gedacht, für ein oder zwei Wochen nach Omersbach zu kommen. Aber es war keine Gelegenheit mit einem Auto. Auch Doktor Dressler klagte wegen Benzinmangel. Sonst hätte er mich besucht. Mit Doktor Jäger entwickelt es sich gut weiter. Aber er ist noch nicht zu meinem Nachfolger ernannt. Das war schon deshalb nicht möglich, weil er die Spruchkammer noch nicht durchgemacht hat. In Osnabrück war ich sechs Wochen15. Da war es noch Sommer und die Tage viel länger. Gewöhnlich bin ich vor Vier aufgestanden. Mich lockte ausser den Versuchen auch die erste Pfeife. Denn dort gab es etwas selbstgebauten Tabak. Schwab (Büdingen) schreibt mir eben, dass der Druck meines Buches16 jetzt endlich fertig werden soll. Endlich! 15 Raphael Eduard Liesegang war vom 13.07.1947 bis 24.08.1947 auf Burg Gretesch bei Osnabrück bei der Papierfirma Schoeller. 21 Wenn Helmut nochmals nach Frankfurt kommen sollte, so möge er doch wirklich seinen alten Kameraden einmal besuchen. Ihnen wage ich das nicht recht anzubieten, da Sie immer noch - leider! - wegen des Kopfes klagen und überhaupt die Bahnfahrt nicht vertragen. Mit herzlichen Grüssen, auch an Opa und Helmut Ihr Raphael Eduard Liesegang“ [Unterschrift] Ewa Liesegang wirkte nach dem Krieg ab 1947 als Erzieherin und später auch als Philosophielehrerin an der Odenwald-Schule in Heppenheim/Ober-Hambach, die 1910 von Paul Geheeb gegründet wurde und heute noch existiert. Ewa Liesegang ging eine zeitlang auch auf diese Schule. Sie war mit den Geheebs befreundet, die 1933 als Juden das Land verließen und in der Schweiz eine ähnliche Schule aufbauten. So wirkte sie eine zeitlang (nach dem Weggang von Paul Geheeb) in der Odenwald-Schule und kümmerte sich u. a. um die Häuser. Leider verunglückte Ewa Liesegang Ende 1952 bei einem Unfall an einem unbeschrankten Bahnübergang mit ihrem kleinen Auto, als sie ein schwangere Frau in die Klinik bringen wollte. Die schwangere Frau und das Neugeborene überlebten, Ewa Liesegang verstarb eine Woche nach dem Unfall im Krankenhaus in Marburg. Hier ordnete sie noch alle Sachen und vererbte der Odenwald-Schule Vermögen (u. a. auch das Erbe von ihrem Vater Raphael Eduard Julius Liesegang), was sich wohl auf 170 000 Deutsche Mark belief. Die Odenwald-Schule finanzierte von dem Geld einen Ausbau (Labortrakt und einen Stiftungsfond). Auch ihre ausführliche Büchersammlung überließ sie der Bibliothek der Odenwald-Schule. Raphael Eduard Liesegang war ein aussergewöhnlicher Mensch. Heute würde man ihn als "workoholiker" bezeichnen. Er schrieb seine über 800 Publikationen z. T. unter verschiedenen Pseudonymen. Die Vielseitigkeit seiner Themen ist beachtlich. Mir ist kein Kolloidwissenschaftler bekannt, der so vielseitig gearbeitet hat. Außerdem schrieb er 14 Dramen. Er war Herausgeber und Mitarbeiter verschiedener Zeitschriften, so schrieb er z. B. für die Kolloid-Zeitschrift über 13 000 Referate. Zudem war er Herausgeber einer wissenschaftlichen Buchreihe von über 50 Bänden im Theodor Steinkopff Verlag, Dresden. 16 Dieses Buch erschien erst 1951. Liesegang R E (1951) Kolloid-Lehre. Einführung in einfachsten Versuchen. Natura-Verlag, Büdingen 1951, 118 Seiten 22 Wolfgang Ostwald schrieb 1929 zum 60. Geburtstag von Raphael Eduard Liesegang17: „Am 1. November [1929] begeht der Entdecker der nach ihm benannten Niederschlagsreaktionen in Gallerten und zahlreicher anderer origineller Erscheinungen, der einzig eifrige Referent auf einem Dutzend verschiedener Gebiete der Naturwissenschaften, Medizin und Technik, der Erfinder wichtiger und zu erheblicher wirtschaftlicher Bedeutung gelangter technischer Verfahren, der nie ermüdete, der stets begeisterte Liebhaber aller neuer wissenschaftlichen Gedanken und Erscheinungen, der Dichter, Schriftsteller, Regisseur, der erstaunliche Idealist Dr. h. c. Raphael Eduard Liesegang seinen 60. Geburtstag. Die „Kolloid-Zeitschrift“ bringt Raphael Eduard Liesegang ihre herzlichen Glückwünsche dar. Sie fügt ihren Dank hinzu für alle Arbeit und alle Förderungen mannigfaltiger Art, welche Raphael Eduard Liesegang ihr seit ihrem Bestehen geschenkt hat. Die „Kolloid-Zeitschrift“ wollte, einem guten Brauche folgend, den vielen Freunden Raphael Eduard Liesegangs zu diesem Tage eine Lebensbeschreibung des zu Feiernden geben. Es erwies sich, daß Raphael Eduard Liesegang ein derartig komplexes, ein derartig polyvariables System darstellt, daß auch seine besten Freunde sich außerstande erklärten, ihn so zu beschreiben, daß ihm gerecht geschähe. Die Redaktion verfiel daher auf den Gedanken, Raphael Eduard Liesegang zu bitten, sich zur Feier seines 60. Geburtstages selbst zu beschreiben. Wenn dieser Plan trotz hartknäckiger wiederholter Ablehnung gelungen ist, so ist hieran zweifellos die Absonderlichkeit des Ansinnens schuld, die Raphael Eduard Liesegang schließlich doch bewogen hat, diesen Wunsch zu erfüllen. Die besonderen Glückwünsche der K o l l o i d - G e s e l l s c h a f t finden sich an anderer Stelle dieses Heftes“. Raphael Eduard Julius Liesegang ließ sich 1929 tatsächlich von Wolfgang Ostwald bereitschlagen und er schrieb eine kurze Autobiographie in seinem ihm typischen Schreibstil und diese wurde in der Kolloid-Zeitschrift veröffentlicht. 17 Ostwald Wo (1929) Zum 60. Geburtstag von Raphel Eduard Liesegang am 1. November 1929. Kolloid-Zeitschrift 49: 224 23 Autobiographisches von Raphael Eduard Liesegang18 „Mein lieber Wolfgang! Damit nicht von Anderen Märchen über mich verbreitet werden, mache ich Dir nun doch die lange gewünschten Angaben: Schon in den ersten Schultagen erregte ich Aufsehen: Die Schulbehörden vernahmen, daß ich oft die Mitschüler mit einem blanken Taler beschenkte. Man war zu Hause mit dem Einschließen nicht vorsichtig genug gewesen. Kleptomanie gab es zu jener Zeit noch nicht. Später habe ich nie die berüchtigten bösen Schulträume gehabt. Ich fühlte mich viel zu sicher vor dem Aufgerufenwerden. Die Lehrer hatten bald bemerkt, daß sie von mir keine Antwort erhalten würden. War einmal ein Schulrat da, so hatte ich gerade das Pech gehabt, mir eine verrostete Feder in die Hand zu stoßen. Wie war es möglich, zu lernen, da das ein Zwang war! Abschreiben vor der Stunde - aber keine Arbeit zu Haus! Mit den Klassenarbeiten ging es oft ganz gut, weil einige der Lehrer, die Nachhilfe erteilten, mich immer nur die zukünftige Klassenarbeit im voraus machen ließen. Zwang war es nicht, wenn ich mich eine Zeitlang hauptsächlich mit der Herkunft der Worte beschäftigte, wovon der Lehrer oft sprach. In Düsseldorf wollten all die Malersöhne selber berühmte Maler werden. Denen winkte bald die goldene Freiheit. Sie gingen frühzeitig ab, um auf der Akademie das Einjährige zu holen. Auch Maler werden, um den verhaßten Zwang loszuwerden! Den ganzen Sonntag Morgen war ich im Atelier eines Malers. Er machte sich vergebliche Mühe. Der Name Raphael19 hatte nicht abgefärbt. Dann machte ein von meinem Vater konstruierter Momentapparat die Mühe des Zeichnens unnötig. Etwas Neigung zur Photographie war wohl von den Vorfahren ererbt. Als ich zur Konformation eine Uhr erhielt, war das erste, das silberne Deckblatt herauszureißen, um damit Heliochromieversuche zu machen. Das dicke Handbuch meines Vaters, das man bei Bekannten entdeckte, mußte wohl auch gestohlen sein. Aber wie hätten wir sonst das Kollodiumverfahren ausüben können! Auch nachdem ich es aufgegeben hatte, Maler werden zu wollen, behielt ich die kleine Dachkammer, die mit ihrer ganz kleinen Luke an der Decke ein Atelier vortäuschen sollte. Eine Zeitlang hatte die verschlossene Tür der Nachbarkammer wieder einen verhaßten Zwang ausgeübt. Dann fand ich einen Schlüssel dazu und konnte mir von dem großen Regal Bücher holen: Astronomie, Geologie usw. Waren 18 Liesegang R E (1929) Autobiographisches von Raphael Eduard Liesegang. Kolloid Z 49: 226-229 19 Raffael, ital. Raffaelo Santi (06.04.1483 Urbino - 06.04.1520 Rom). Weltbekannter Maler der in Florenz und später in Rom unter Papst Julius II. Deckengemälde und Fresken im Vatikan malte. 24 sie auch mindestens fünfzig Jahre alt, so lockten sie mich doch viel mehr als die Schulaufgaben. Was hätte ich frühzeitig aufnehmen können, wenn ich dort einige moderne naturwissenschaftliche Schriften gefunden hätte! Aber das Glück, wenigstens diese längst veralteten Sachen durchstudieren zu können, genügte mir. Man schenkte mir fast das Einjährige, nachdem ich doch nur dreimal sitzen geblieben war. Einen Sommer über war ich auf dem von Pipin erbauten Schloß Grönenbach im Allgäu, wo ich Photographie und photomechanische Verfahren lernte. Dann ein Jahr analytische Chemie bei F r e s e n i u s 20. Eine dicke malaische Grammatik mit Wörterbuch, die ich während der letzten Schultage aus dem Holländischen übertragen hatte, wurde nochmals umgearbeitet. Dann saß ich während der Abende über den chemischen und physikalischen Zeitschriftenbänden, durchblätterte sie Seite für Seite, und holte alles über Photochemie und Fluoreszenz heraus. Die „Photochemie“ war 1888 ein ziemlich vollständiges Buch. Aber es wurde nicht gedruckt. Nur eine Arbeit über die Lichtempfindlichkeit des Jodkaliums erschien in diesem Jahr im „Photographischen Archiv“. Ich wußte tatsächlich nicht, was ich mit den zwanzig Mark Honorar anfangen sollte; denn ich verabscheute das Bier und rauchte noch nicht. Carl Remigius Fresenius 20 Emil Warburg Carl Remigius Fresenius (28.12.1818 Frankurt a. Main - 11.06. 1897 Wiesbaden). Gründete 1848 das noch heute bestehende Untersuchungslabor in Wiesbaden. 25 Von 1888 bis 1892 angeblich zum Chemiestudium in Freiburg. Eine Stunde war ich bei W a r b u r g 21, eine Stunde beim Botaniker. Sonst bin ich nicht in Vorträgen gewesen. Das Kaffeehausleben, der Verkehr mit Schauspielern und Schauspielerinnen war interessanter. Auch das Laboratorium bei K l a u s wurde gemieden. Zum Schluß habe ich aber ein Semester bei H u g o M ü n s t e r b e r g 22 experimentelle Psychologie betrieben. An den tollen Zwang der Vorbereitung zu einem Examen war natürlich nicht zu denken. Hauptsächlich während der Ferien kamen damals allerlei kleinere Arbeiten und auch Bücher (1890 „Beiträge zum Problem des elektrischen Fernsehens“, 1891 „Monismus“, 1892 „Rhapsodie“)23 heraus. Ein Traum war hierfür entscheidend gewesen: Ich erlebte darin ein Instrument zum Telegraphieren von Bildern. Am nächsten Morgen schrieb ich darüber und gab es zum Druck. Vorher glaubte ich, daß ich nie einen eigenen Gedanken haben könne. Mit einen Schlag war nun das innere Hemmnis gefallen. Es war die Zeit der Arbeit am grünen Tisch. Ein Vorbild für jenes Instrument könnte Auge plus Sehnerv sein. Überhaupt versuchte ich nun an den Organen der Lebewesen etwas für die Technik zu lernen. Aber auch das Umgekehrte wurde versucht: Farbenphotographie (1889 Ausbleichverfahren, mit Studien über die Lichtempfindlichkeit von Farbstoffen), Theorie der Farbenempfindung, Farbenanpassung gewisser Lebewesen. Beispiele für diese „Philosophie der Technik“ sind hauptsächlich im „Monismus“ und „Rhapsodie“ niedergelegt, eine botanische Arbeit, welche die Kohlensäurehypothese von A r r h e n i u s 24 vorwegnahm, in den „Photographischen Studien“. Von 1892 an blieb ich in der Fabrik meines Vaters. Etwas später kam die Leitung des „Photographischen Archiv“, von zwei anderen Zeitschriften und einem Jahrbuch 21 Emil Warburg (09.03.1846 Altona - 28.07.1931 Grunau bei Bayreuth). Ab 1872 Professor der Physik an der Universität Straßburg; ab 1876 an der Universität Freiburg, ab 1895 an der Universität Berlin. War von 1905 bis 1922 Präsident der Physikalisch-Technischen Reichsanstalt. Vater des Nobelpreisträgers der Medizin 1931 Otto Heinrich Warburg 08.10.1883 Freiburg - 01.08.1970 Berlin). 22 Hugo Münsterberg (01.07.1863 Danzig - 16.12.1916 Cambridge (Massachusetts/USA). Arzt, Psychologe und Philosoph. Er war ein Schüler des Psychologen Wilhelm Wundt. 23 Liesegang R E (1891) Beiträge zum Problem des electrischen Fernsehens. (Probleme der Gegenwart, Band 1). Ed. Liesegang Verlag, Düsseldorf, 130 Seiten. Preis 3 Mark Liesegang R E (1892) Der Monismus und seine Konsequenzen. 1. Thl.: Die Organologie (Probleme der Gegenwart, Band 2). Ed. Liesegang Verlag, Düsseldorf, 75 Seiten. Preis 2.Mark (1894) Liesegang R E (1894) Rhapsodie. Ed. Liesegang Verlag, Düsseldorf, 63 Seiten. Preis 2.- Mark. (Inhalt: Eine neue Stilistik. Ontogenesis der Philosophie. Verkettung der Wissenschaften. Wissenschaft der Zukunft. Entwickelungsmechanik der Sprache. Physiologische Aesthetik. Mechanistische Teleologie). 24 Svante August Arrhenius (19.02.1859 Gut Wijk (bei Uppsala) - 02.10.1927 Stockholm). Nobelpreisträger der Chemie 1903 für die Theorie der elektrolytischen Dissoziation. 26 hinzu. Bei der Ausarbeitung lichtempfindlicher „Emulsionen“ merkte ich immer wieder, daß die von mir erlernte Chemie zum Verständnis oder zur Vorausberechnung des hier Beobachteten durchaus ungenügend sei. Auch die wenige physikalische Chemie, die zu mir gelangte, genügte nicht. Daß schon Literatur über die hier besonders wichtige Kolloidchemie vorhanden sei blieb mir unbekannt. So mußte ich selbst in dieser Richtung wursteln. War das in den vielen Experimenten, die nun einsetzten, Gefundene nicht für die Fabrik als Geheimnis zu bewahren, so wurde es unter dem eigenen Namen oder unter einigen Pseudonymen in die Zeitschriften gebracht. Neben dem Photographischen blieb immer das Interesse für das Biologische. Auch hierfür schien aus chemischen Reaktionen in Gallerten allerlei zu lernen zu sein. Hugo Münsterberg Einige Stichproben aus jener Zeit: Svante Arrhenius „Struktur der Lea´schen Photosalze“ (Phot. Arch. 34, 85, 1893)25: „- Diese Unterscheidung zwischen einem Molekül und einem Molekülkomplex ist von prinzipieller Bedeutung. C a r e y L e a hat seine Photosalze als chemische Individuen hingestellt. - Betrachten wir jedoch diese eigentümlichen Silbersalze als aus Molekülkomplexen bestehend, die zur Hälfte aus unverändertem Chlorsilber gebildet sind, zur anderen Hälfte aus metallischem Silber, so wird auch dieser Komplex ähnliche Eigenschaften zeigen müssen wie ein chemisch ein25 Liesegang R E (1893) Struktur der Lea´schen Photosalze. Liesegang´s Photogr Arch 34: 85 27 heitlicher Körper. Von einer Mischung muß er sich - unterscheiden.“ - „Über das Reifen der Bromsilbergelatine“ (Phot. Arch. 34, 98, 1893)26: „- Auch bei der physikalischen Entwicklung haben wir solche Pseudolösungen, in welchen das Wachsen und die Ausfällung eines naszierenden Körpers durch die Gegenwart eines größeren Molekülkomplexes beschleunigt wird. Beim Mischen des löslichen Silbersalzes mit Gallussäure entsteht metallisches Silber, welches jedoch in Lösung bleibt. - Die erwähnten Mischungen erwiesen sich, frisch hergestellt, nach der Tyndall´schen Methode geprüft, als optisch rein. Bei längerem Stehen lassen sie jedoch die bekannten schwarzen grösseren Silbermoleküle niederfallen. Die Entstehung der letzteren wird nun dadurch beschleunigt, daß größere Komplexe von Silbermolekülen in die Lösung gebracht werden. Auf diesen erfolgt dann ein rascher Absatz des Silbers der Lösung.“ — Ähnlich heißt es Amateur-Photograph 1893, 81: „Das lösliche Silbersalz wird zu Metall reduziert, welches jedoch nicht direkt ausfällt, sondern eine Zeitlang äußerst fein in der Lösung schwebt. Wir haben eine sogenannte kolloide Lösung, wie es z. B. auch die meisten Tinten sind, vor uns. Die belichteten Chlorsilberteilchen üben nun scheinbar eine Anziehung aus auf diese schwebenden Silberteilchen. Diese setzen sich, ähnlich wie der Wasserdampf als Reif sich niederschlägt, an der durch das Licht zersetzten Chlorsilberschicht ab.“ — „Ag + Br.“ (Phot. Arch. 36, 17, 1895)27: „Chlor, obgleich es an den Silberatomen gebunden ist, hat dadurch seine Eigentümlichkeit nicht verloren, vom Lichte eine größere Affinität zum Wasserstoff zu empfangen. Die Photosynthese: der Aufbau des Chlorwasserstoffs durch das Licht kann also als primärer Vorgang aufgefaßt werden. Die Photolyse wäre dann sekundär, und wir bräuchten dem Silbersalz an sich keine Empfindlichkeit für den Lichtstrahl zuschreiben.“ – „Über Blasenbildung“ [in photographischen Papieren]; (Phot. Arch. 36, 323, 1895)28: „Es sei nur angedeutet, daß diese Arten von Quellung und Entquellung wahrscheinlich auch in den lebenden Organismen vorkommen und dort Erscheinungen veranlassen, welche bisher noch nicht erklärt worden sind, oder welche man auf Osmose zurückführte. Man sollte überhaupt mehr auf die Eigentümlichkeiten der Membranen selbst achten, als nur auf die Wechselwirkungen der dabei beteiligten Flüssigkeiten.“ Schon damals war mehr experimentelle Arbeit für die Fabrik nötig als für Publikationen. 1892 konnte ich das erste matte Zelloidinpapier herausbringen. Mein Vater wollte auch hier mit der Handpräparation durchkommen. Er war immer gegen Maschinen gewesen. Wenn die Besteller auch ein Vierteljahr warten mußten, ließ er 26 Liesegang R E (1893) Über das Reifen der Bromsilbergelatine. Liesegang´s Photogr Archiv 34 Heft 7 Nr. 715: 97-100 27 Liesegang R E (1895) Ag + Br. Liesegang´s Photogr Archiv 36 Heft 2/Nr. 758: 17-20 Liesegang R E (1895) Ag + Br (Fortsetzung von Nr. 758). Liesegang´s Photogr Archiv 36 Nr. 758: 33-34 28 Liesegang R E (1895) Ueber Blasenbildung. Liesegang´s Photogr Archiv 36 Heft 21 Nr. 777: 321-325 28 sein Aristopapier bogenweise anfertigen. 1896 starb er, und ich baute mit zwei Brüdern eine wirkliche Fabrik mit Maschinen. Bei den Entwicklungspapieren, welche nun in den Vordergrund traten, spielte das Kolloidchemische eine ebenso große Rolle wie bei den Aukopierpapieren. Die Polychromie des metallischen Silbers bei verschiedenem Dispersitätsgrad wurde bei einem Papier als bedeutungsvoll erkannt, das je nach verschiedener Belichtungs- und Entwicklungszeit rote, braune, grüne oder schwarze Töne gab (vgl. auch „Die Geburt des Silbers“, Camera obscura 1900, 11)29. Mein Plan war, einige Jahre den Widerwillen gegen das Kaufmännische zu überwinden und so viel zu verdienen, daß ich der Wissenschaft oder vielleicht der schönen Literatur leben konnte. Aber die Überwindung des Widerwillens gelang nicht. Ich war froh, als 1904 F r i e d . B a y e r & C o . Interesse an der Papierabteilung hatte und sie übernahm. Dort ist sie groß geworden. Denn man hat sich jetzt in Leverkusen auf eine Fabrikation von 160 000 Quadratmetern im Monat eingestellt. (Die optische Abteilung in Düsseldorf wird jedoch von meinen Brüdern, die sich einen tüchtigen Kaufmann dazuholten, weitergeführt.) D u i s b e r g 30 schlug mir vor, die Leitung der Leverkuser Abteilung zu übernehmen. Da kam in meiner Antwort wieder die Abneigung gegen Zwang zum Vorschein: „Ich gehe in kein Gefängnis!“ Carl Duisberg 29 Wolfgang Joseph Pauli Liesegang R E (1899/1900) Die Geburt des Silbers. Camera Obscura 1: 841-843 Friedrich Carl Duisberg (29.09.1861 Barmen (heute Wuppertal) - 19.03.1935 Leverkusen). Chemiker und Großindustrieller. Seit 1890 Vorstandsvorsitzender und ab 1912 Generaldirektor der Farbenfabriken Bayer. Initiierte 1925 den Zusammenschluß der sechs großen Teerfarbenfabriken zur I. G. Farbenindustrie A G (I G Farben). 30 29 Diese Befreiung kam 1908. Einige Monate auf der friesischen Insel Ameland brachten noch einen dramatischen Versuch. Ein Jahr in Marburg ließ meine „Beiträge zu einer Kolloidchemie des Lebens“31 entstehen. 1909 wollte ich nach Wien, um bei Pauli32 zu arbeiten. Aber auf der Reise dorthin fesselte mich das Senckenberg-Museum in Frankfurt. Bald wurde ich von E d i n g e r 33 gebeten, das Wesen der Golgi- und anderer Silberfärbungen34 des Gehirns zu untersuchen. Die Kenntnis der Kolloidchemie der physikalischen Entwicklung half mir dabei sehr. Camillo Golgi Carl Adolf von Basedow 31 Liesegang R E (1909) Beiträge zu einer Kolloidchemie des Lebens. 1. Auflage. Theodor Steinkopff Verlag, Dresden und Leipzig, 148 Seiten. Mark 4.-; geb. Mark 5.32 Wolfgang Joseph Pauli (eigentlich Wolf Paschels) (11.09.1869 Prag - 04.11.1955 Zürich). Seit 1906 Professor in Wien. Mediziner der sich mit kolloidalen Sytemen beschäftigte. Vater des Nobelpreisträgers der Physik 1945 Wolfgang Pauli (25.04.1900 Wien - 15.12.1958 Zürich) für die Entdeckung des Ausschließungsprinzips (Pauli-Prinzip). 33 Ludwig Edinger (13.04.1855 Worms - 26.01.1918 Frankfurt a. Main). Neurologe. Ab 1904 Direktor des Neurologischen Instituts der Senckenberg.Gesellschaft, seit 1914 Professor an der neugegründeten Universität Frankfurt a. Main. Bedeutende Arbeiten zur Antomie des Gehirns. 34 Camillo Golgi (07.07.1844 Corteno (Provinz Brescia) - 21.01.1926 Pavia). Ab 1875 Professor für Histologie in Siena und Turin, ab 1877 Professor für Allgemeine Pathologie in Pavia. Durch Anwendung neuer Färbemethoden (Versilberungsfärbung, Golgi-Färbung) klärte er 1873 den Feinbau der Nervenzellen und des Gehirns. Erhielt 1906 gemeinsam mit Santiago Ramón y Cajal (01.05.1852 Petilla de Aragón (Provinz Navarrra) - 17.10.1934 Madrid) den Nobelpreis der Medzin. 30 Bis 1914 arbeitete ich im Neurologischen Institut, teilweise auch (über Thymus35, Basedow36) im Laboratorium der Chirugischen Klinik. Nebenbei entstanden einige Arbeiten über geologische Diffusionen und Achate37 als Protest gegen veraltete Anschauungen, die ich auf diesem Gebiet vorfand. Während des Krieges hatte ich die Leitung der Narkotika-Abteilung des Sanitätsdepots in Frankfurt. Damals war ich wohl der größte Simulant, und zwar mit einem typisch kolloidchemischen Mittel: Die Vorräte an Kautschuk gingen im Sanitätsdepot zur Neige. Auf Veranlassung des Stabsapothekers W. S c h ä f f e r machte ich tausende Versuche, um Leukoplast ohne Kautschuk herzustellen. Gewöhnlich trug ich gegen 80 verschiedene Pflaster auf meinem Körper, um sie miteinander zu vergleichen. Eine kleine Publikation über die Toxidermie der Heftpflaster (Dermatologische Wochenschrift) hat das Wesentliche zusammengefaßt38. Nachkriegszeit und Inflation zwangen auch mich natürlich wieder zum Arbeiten um Geld. Als Berater einer Fabrik39, die Rohpapiere für photographische Zwecke herstellt, machte ich jährlich 10 000 Eintragungen in meine Versuchsbücher. Bei einer pharmazeutischen Fabrik40 war es wenigstens etwas harmloser. Damit soll nur angedeutet werden, daß nur ganz wenig Zeit zum freien Wissenschaftlichen und zum 35 Thymus ist ein zentrales lymphatisches Organ, das für die Entwicklung des Immunsytems von Bedeutung ist. 36 Basedow-Krankheit („Merseburger Trias“) benannt nach Carl Adolf von Basedow (28.03. 1799 Dessau - 14.04.1854 Merseburg/Saale) ist eine determinierte Autoimmunerkrankung der Schilddrüse mit Nachweis von Thyreotropin-Rezeptor-Antikörpern, die eine diffuse Hyperplasie und erhöhte funktionelle Aktivität der Schilddrüsenfollikelzellen hervorrufen. Er empfahl Iodgaben zur Therapie. 37 Liesegang R E (1910) Die Entstehung der Achate. Centralbl Min Geol Paläont (Jg. 1910) Nr. 19: 593-597 Liesegang R E (1911) Die Entwicklungsgeschichte der Achate. Aus der Natur (Z für alle Naturfreunde) 7 Heft 18: 561-566 Liesegang R E (1914) Die Achate. In: Doelter C; Leitmeier H (Hrsg) Handbuch der Mineralchemie, Band 2, Erste Hälfte (Silicate), Steinkopff Verlag, Dresden und Leipzig, 1914: 186-190 Liesegang R E (1915) Die Achate. Theodor Steinkopff Verlag, Dresden und Leipzig 1915, 122 Seiten, 60 Abbildungen. Geh. Mark 4.80; geb. Mark 5.80 38 Liesegang R E (1919) Die Toxidermie durch einige kautschukfreie Pflaster. Dermatolog Wschr 68 Nr. 18: 275-280 Liesegang R E (1919) Das Ankleben leukoplastähnlicher Pflaster an der Rückseite. Pharmaz Zentralhalle 60 Nr. 22: 227-229 Liesegang R E (1919) Die Herstellung einiger kautschukfreier Heftpflaster. Pharmaz Zentralhalle 60 Nr. 36: 385-388 39 Papierfabrik Felix Schöller Burg Gretesch bei Osnabrück 40 Merz-Werke Franfurt-Rödelheim. Mit der Firma Merz hatte R. E. Liesegang ein Patent gegen da braunwerden von Novokain und Suprarenin in Ampullen. "Merz" Novocain-Suprarenin-Lösung nach Raphael Ed. Liesegang. Deutsches-ReichsPatent, Hersteller: Merz-Werke, Chem. Abt. Frankfurt a. M. - Rödelheim (um 1920) 31 Publizieren übrig bleibt. Da ich, bis auf wenige Ausnahmen, alles ohne irgendwelche Hilfe von Anderen mache, habe ich den großen Vorteil, der Kontrolle keine Zeit widmen zu müssen. Auch hier zeigt sich jene Veranlagung meines Vaters: Ich brauche gar keine Apparate. Ein paar Glasplatten, Reagenzgläser und leere Eischalen genügen vollkommen. Ich bin froh, nicht dozieren zu müssen. Ich bin ein freier Student geblieben“. Der Botaniker und Zellforscher Ernst Küster (25.06.1874 Breslau - 06.07.1953 Gießen) beschrieb Raphael Eduard Liesegang in seinem Nachruf (1949) sehr treffend. Er schrieb u. a.41 „Vor etwa vierzig Jahren erhielt ich in der Sommerfrische eine umfangreiche Drucksachensendung - ich entnahm ihr die ersten Schriften, die mir Raphael Eduard Liesegang zu überreichen die Freundlichkeit hatte; eines der Hefte trug die handschriftliche Widmung: „Dem Psychologen in Ernst Küster“ - es waren Liesegangs dramatische Dichtungen. Liesegangs Forschungen und insbesondere das nach ihm benannte Phänomen der Liesegang´schen Ringe waren mir damals schon längst bekannt; von dem Dichter Liesegang hatte ich noch nichts gehört; den Verfasser so zahlreicher Schriften zu sehen oder zu sprechen, hatte ich noch niemals Gelegenheit gehabt. Nicht ohne Befremden blätterte ich in seinen Schriften, ohne den Grund finden zu können, der ihn gerade für diese Erzeugnisse seiner Feder besonderes Interesse bei mir vorraussetzen hieß. Geraume Zeit später wurde ich mit Liesegang bekannt; ich habe in Frankfurt mit ihm die Zeiten erlebt, in welchen die Aussicht für eines seiner Dramen das Interesse eines hervorragenden Musikers gewinnen zu können und es zum Buch einer Oper werden zu sehen, ihn freudig belebte - und ebenso die späteren Jahre, in welchen Liesegang seine poetischen Versuche nicht mehr gelten lassen wollte. Wenn ich trotz solcher Wandlung noch oft an sie zurückgedacht habe, so geschah es vor allem deswegen, weil sie mir das Bild vervollständigen halfen, das ich von der Persönlichkeit ihres Verfassers mir zu machen trachtete. Ein Bild von Liesegangs wissenschaftlichen Leistungen zu entwerfen, ist bereits wiederholt versucht worden. Wir alle bewundern seine unvergleichliche Vielseitigkeit und noch mehr die spielerische Leichtigkeit, mit der er beim Schreiben wie beim Plaudern Verbindungen schlug und Verknüpfungen fand, die auch entlegene Gebiete 41 Küster E (1949) Raphael Eduard Liesegang (1869-1947). Nachruf von Prof. Ernst Küster in den Nachrichten der Gießener Hochschulgesellschaft (1949) 18: 88-93. 32 seines Wissens in überraschender Weise miteinander verbanden - nicht anderes als der Meister am Webstuhl, vor dem die Schifflein herüber-hinüberschießen, die Fäden ungesehen fließen. Wir bewundern seinen Schaffensdrang, der viele Jahrzehnte lang keine Ermüdung kannte, und den Glauben an seine „Sendung“, den er in sich trug; wenn der Umfang seiner Arbeit uns den Eindruck einer seltenen Größe gab, so bestätigte diesen vollends die rührende Bescheidenheit, mit der der wunderbare Mann von seinen Leistungen sprach, und die Anspruchslosigkeit, mit der er hinter seinen Arbeitsgenossen und Gesprächspartnern zurückzutreten für selbstveständlich geboten erachtete. In diese Bewunderung mischte sich freilich dann und wann ein schmerzliches Bedauern, wenn wir selbst nach vieljährigem Verkehr mit ihm immer wieder nur von Liesegangs Können und Wissen, seinen neuen Einfällen und neuen Plänen zu hören bekamen und dabei so wenig über Liesegang selbst erfuhren; über ihn aber mehr zu hören, hätten wir alle, die wir in seine Nähe und seinen Kreis gelangt waren, uns sehr gewünscht, weil wir nicht nur den Gelehrten bewunderten, sondern auch den Menschen liebten; der unermüdlich Gebende schloß aber seine Hand, wenn wir über ihn selbst einmal Kunde zu empfangen fast schon hofften. Wie gern hätten wir etwas gehört von dem, was sein Herz bewegte und sein Inneres erfüllte - vielleicht hofften wir im Stillen, ihm mit Rat oder wenigstens mit Anteilnahme helfen zu können; denn daß auch ihm, dem Fruchtbaren, nicht alle Saaten volle Ernte gebracht hatten, auch ihm nicht alle Blütenträume reifen wollten konnte uns ja nicht entgehen. Aber Liesegang wich solchen Versuchen am liebsten aus und verbarg sein Inneres in unsichtigem Dunkel. Wer war eigentlich Liesegang? Wir wußten es nicht recht und wären wohl zuweilen geneigt gewesen zu glauben, daß im Laufe der Jahre das vielgesuchte Bild sich manchesmal gewandelt hätte, wenn nicht seine Handschrift, dieser unbestechliche Spiegel des inneren Menschen, durch die Jahrzehnte hindurch mit ihrer Unveränderlichkeit uns von der Festigkeit seiner Einstellung zu den Dingen der Welt überzeugt hätte. Auf Reisen führte mich einmal ein willkommener Zufall mit einem langjährigen Freund und Arbeitsgenossen zusammen: Er sprach über seinen Freund, ich über den meinigen: War es derselbe Liesegang? Ich konnte nicht alles gelten lassen, was der andere sagte, und der andere schien dem nicht völlig zustimmen zu können, was ich zu sagen für richtig hielt. „Wer kennt Liesegang?“ fragte er schließlich. Wenn ich in den mit Liesegang geführten Gesprächen den weitgespannten Kreis seiner wissenschaftlichen Interesssen bewunderte und in derselben Stunde die Fremdheit nicht verstehen konnte, mit der er Fragen des Tages und des allgemeinen Interesses gegenüberstand oder gegenüber zu stehen sich den Anschein gab, wurde mir mehr als einmal klar, wie schwer es blieb, Liesegang zu ergründen. Mit mimosenhaftem Zartgefühl sah man ihn oftmals bei Gelegenheiten zurückschrecken, die wahrlich keinen Angriff bedeuteten. Liesegang gehörte zum Geschlecht derer, die das was sie 33 am tiefsten und wirksamsten bewegt, am liebsten verschweigen; cum Tacent, clamant. Keine geringere Zurückhaltung als im Zwiegespräch hat Liesegang in vielen anderen Zusammenhängen bewahrt, in der Meinung, durch solche Zurückhalung sich das von ihm stets heiß begehrte Maß von persönlicher Freiheit am besten sichern zu können. Jahrelang hat er von dem Doktortitel, den ihm die Gießener Philosophische Fakultät honoris causa verliehen hatte, keinen Gebrauch gemacht, und es bedurfte langer Auseinandersetzungen, um ihn aber auch zur Annahme dieser hohen Auszeichnung zu bewegen. Ein schwerer Irrtum wäre es, aus der Zurückhaltung und - sagen wir getrost: Ernst Küster aus der Schüchternheit, die aus Liesegangs Umgangsformen und Gesprächsführung so oft sprach, auf einen Mangel an Kraft oder an Vertrauen zum eigenen Können zu schließen. Richtig ist das Gegenteil: Liesegang war nicht nur ein Mann von unerschöpflicher Arbeitskraft; er wußte um diese Kraft; sie zu betätigen war weniger sein Ehrgeiz als seine Leidenschaft; arbeiten und anderen helfen war ihm ein schwelgerisches Glück, über dem er alle Rauhheiten des Lebens vergaß. War seine Arbeitskraft einmal durch Krankheit bedroht - er achtete seiner Leiden kaum; sein Kraftgefühl war zu groß, als daß eine vorübergehende Einbuße an ihr ihn sonderlich betrübt hätte. Ich habe Zeiten mit Liesegang erlebt, in welchen materielle Not ihn so schwer bedrängte, daß ein anderer von ihr erdrosselt worden wäre - Liesegang ließ kein Wort der Klage jemals laut werden und setzte seine Forschungsarbeit fort - mit hungerndem Magen, aber mit flammendem Herzen. Wunderbar vollends bewährte sich seine Kraft damals, als die apokalyptischen Reiter des Weltkrieges seine Arbeitsstätte und Arbeitsmittel in Asche legten; vorbildlich hat uns Liesegang, der mehr als 70 Jahre alte Forscher, damals gezeigt, daß man in des Schiffsbruchs Knirschen nicht zu zagen und seine Arbeitskraft allen Gewalten zum Trutz zu erhalten die Pflicht hat. 34 35 Zahllose Briefe hat mir Liesegang im Laufe der Jahrzehnte geschrieben - die wichtigsten und inhaltsreichsten fülltem eine schwere Mappe meiner Sammlungen. Nur e i n M a l ,glaube ich, hat aus ihnen der wirkliche, echte Liesegang unverstellt gesprochen - in dem Briefe, mit dem er mich bat, in unserem Verkehr künftighin das Sie mit dem Du zu vertauschen - wie es denn in den letzten zehn Jahren seines Lebens und unseres gemeinschaftlichen Arbeitens geschehen ist. Lauter, reicher, sprudelnder sprach der wahre echte Liesegang von sich selbst aber in den Monologen, die ich in seinen Dichtungen sehen möchte. Mag ihr literarischer Wert bescheiden sein - einen höheren bekommen sie für denjenigen, der Liesegang gekannt hat und hier nun endlich einmal Liesegang von keinem Gesprächspartner in Fesseln geschlagen endlich einmal ungehindert zu Worte kommen und seine Gedanken vor uns ausbreiten sieht - einen Philosophen und einen Psychologen. Was wir auf den Seiten und zwischen den Zeilen seiner Dramen lesen, rundet uns das Bild dessen, der im Laboratorium zu uns sprach, und vervollständigt die Züge, die uns lieb und teuer waren; aus den Dichtungen Liesegangs spricht er, der im Alltag unverbrüchlich schweigsam blieb“. „„Mein zweites Ich überwölbt die Flur und in den Herrlichkeiten der sinkenden Sonne jauchzt mein Schweigen““. „Mit diesen Worten schließt Liesegangs Dichtung „Grishma“, die 1903 erschien“42. Eine vollständige Biographie über diesen großartigen Kolloidwissenschaftler zu schreiben ist sehr schwierig, da Raphel Eduard Julius Liesegang persönlich sehr zurückhaltend lebte und privat sehr wenig über ihn bekannt ist. Trotzdem möchte ich damit in der nächsten Zeit beginnen. In der Zwischenzeit (2003) konnte ich noch mit Augenzeugen sprechen, die ihn noch persönlich kennengelernt hatten und mir wertvolle Anregungen und Hinweise gaben. Für andere Hinweise und ähnliches bin ich ebenfalls sehr dankbar. Danksagung Frau Bürgermeisterin Marianne Krohnen aus Geiselbach/Bayern danke ich für die Vermittlung zu den Augenzeugen. Besonders danke ich dem Sohn von Lina Fleckenstein („Frau Lina“), den Augenzeugen Helmut Fleckenstein und seiner Frau Margarete, geb. Eich für ihre freundliche Aufnahme, Auskünfte, Briefe aus ihrem Besitz und den gemeinsamen Besuch auf der Rothshütte im heißem August 2003 in Omersbach und die Bilder von „Frau Lina“. Frau Heide Lauterbach, Tochter von Dr. Kurt Hanf-Dressler, die ich beim Besuch auf der Rothshütte persönlich kennenlernte und dessen Sohn Tiglio Hanf-Dressler danke ich ganz herzlich für briefliche und 42 Liesegang R E (1903) Grîshma. L. Schwann, Düsseldorf, 11 Seiten 36 telefonische Kontakte und Auskünfte. Frau Margit Rambow danke ich für gute offene Zusammenarbeit. email: [email protected] 37 Notice biographique de Raphael Eduard Julius Liesegang (Elberfeld, 1er novembre 1869 - Bad Homburg v. d. Höhe, 13 novembre 1947). Klaus Beneke Institut für Anorganische Chemie der Christian-Albrechts-Universität der Universität D-24098 Kiel [email protected] Traduction de l'allemand: Prof. André Lange, 16 rue Jean Hultz, 67000 Strasbourg, France URL: http://histv2.free.fr/liesegang/liesegang.htm Raphael Eduard Liesegang est le fils de Paul Eduard Liesegang (1838-1896), qui allait devenir un industriel renommé. Paul Eduard Liesegang avait étudié la physique à Iena, où il fit la connaissance de Ernst Abbe (18401905), grâce à qui il s'initia à l'optique et avec lequel il commença la construction d'appareils de projection. Après ses études, il travailla dans l'atelier de photographie fondé en 1854 par son père Wilhelm Eduard Liesegang. Le grand-père de Raphael Eduard Liesegang avait développé son atelier en produisant des appareils photographiques et du papier d'albumine. Après la mort du grand-père, en 1871, l'entreprise s'est développée et s'est déplacée à Düsseldorf. Raphael Eduard Liesegang avait donc deux ans lorsqu'il arriva à Düsseldorf avec ses quatre cousins germains et c'est là qu'il fit ses classes. Il faisait souvent l'école buissonnière et ne faisait pas ses devoirs. A partir de la troisième, il a suivi des cours de rattrapage en mathématiques, mais la compréhension pour les nombres ne suivait pas. Au lycée, en sixième, il eût de grandes difficultés pour écrire et apprendre par coeur un poème lui était impossible, bien qu'il en retenu le sens mais non la forme. Il savait lire et parler, mais non lire à 38 voix haute. Par ailleurs, il avait une mémoire remarquable. Il resta assis durant la sixième et fut promu. Après une année avec un précepteur particulier, il fut envoyé au Lycée royal, où il étudia de 1881 à 1887 et obtint des résultats moyens, et après avoir redoublé, obtint le "Einjährigen", l'équivalent d'alors du baccalauréat. La famille Liesegang passa ses vacances aux Pays-Bas. R. E. Liesegang acquit une grammaire du Malais écrite en néerlandais, qu'il traduisit en allemand sur les bancs de l'école, durant les pauses. Cette grammaire fut publiée par son père dans sa propre maison d'édition, qui publiait depuis 1860 les Photographisches Archiv. Journal des Allgemeinen deutschen Photographen-Vereins. Ce fut le premier des nombreux ouvrages et publications qu'il allait écrire durant sa vie. A cette époque, Liesegang rêvait de devenir peintre. Son père lui arrangea un atelier dans une chambre mansardée. Le dimanche, il suivait l'enseignement d'un peintre. Là, il était tranquille, loin de ses frères et soeurs. Son père ne voulait cependant rien savoir d'une carrière de peintre, et il abandonna donc sa vocation. R. E. Liesegang suivit un cours de photographie et de techniques photomécaniques à Grönenbach im Allgäu. A Wiesbaden, il fréquenta pendant un an Carl Remigius Fresenius (1818 - 1897), dont il suivit le cours de chimie analytique. En 1888, il s'installa à Freiburg pour suivre des études de chimie, mais, en pratique, il ne fréquenta aucun cours. Il trouvait plus intéressant de fréquenter les cafés pour y rencontrer des acteurs et des actrices. Pendant les vacances, il rédigeait des travaux scientifiques et des livres. Ainsi, en 1888, il publia dans les Photographischen Archiv un article sur le caractère photosensible des sels sels d'argent organiques. En 1891, il publia l'ouvrage Beiträge zum Problem des Raphael Eduard Liesegang (1903) electrischen Fernsehens (c'est à dire : "Contribution sur la question de la télévision électrique"). 39 En conséquence de ce qu'il ne suivait pas les cours et ne suivait pas les examens, il commença en 1892 à travailler dans l'usine de son père. C'est là qu'il développa en 1892 le premier papier cellulaire mat et le développeur hydrochinonique "Aristogen". R. E. Liesegang travailla sur de nombreux problèmes de photographie, sur lesquels il publia de nombreux articles. En 1896, il présentait des rapports périodiques à l'occasion de rencontres à Gelen, qui, par la suite seront appelées le "cercle Liesegang" par Wilhelm Ostwald (1853 - 1932). Lorsque son père mourut en 1896, R. E. Liesegang et deux de ses frères reprirent l'entreprise. C'est alors qu'il remplaça la préparation manuelle du papier cellulaire par une préparation mécanique, que son père avait toujours refusée. Comme les usines de fabrication de couleur Friedrich Bayer & C° à Leverkusen montraient de l'intérêt pour le département papier photographique et développement, il leur vendit en 1907 cette partie de l'entreprise, qui fut par la suite à l'origine de Agfa. Le département d'optique fut transféré par ses frères à Düsseldorf, alors que lui-même se désengageait de l'entreprise. R. E. Liesegang rejoignit en 1908 le Musée Senckenberg de Francfort. Sous la direction de L. Edinger, à l'Institut de neurologie, il rendit visible les ramifications ténues des neurones, grâce à la méthode d'imprégnation par l'argent des tissus cérébraux ("méthode Golgi"). Pendant la Première Guerre mondiale, il dirige le département de narcotique du dépôt sanitaire de Francfort. Par la suite, il travaille de manière provisoire dans une usine de fabrication de papier. En 1921, il devient collaborateur du KaiserWilhelm-Institut für Biophysik à Francfort et à partir de 1937, il dirige l'Institut de recherche sur les colloïdes. En 1944, l'Institut est déménagé à Bad Homburg. R. E. Liesegang a travaillé jusqu'au 12 novembre 1947. Il prit froid et, durant la nuit, perdit conscience. Il mourut le 13 novembre vers 18 heures d'un infarctus pulmonaire. R. E. Liesegang fut un homme hors du commun. Aujourd'hui, on le décrirait comme un "workoholiker". Il a publié plus de 800 titres, sous différents pseudonymes. La multiplicité de ses thèmes est remarquable. Je ne connais aucun chercheur sur la science des colloïdes qui ait travaillé de manière aussi polyvalente. De plus, il a écrit quatorze pièces de théâtre ! Il était éditeur scientifique et collaborateur de différentes publications. Il a notamment écrit pour le KolloidZeitschrift plus de 13 000 recensions. Enfin, il a été l'éditeur scientifique d'une collection scientifique de plus de 50 volumes chez l'éditeur Theodor Steinkopff Verlag, à Dresden et Leipzig. 40 Il est très difficile d'écrire une biographie sur ce grand spécialiste de la science des colloïdes, notamment parce que Liesegang vivait de manière très réservée et on connaît peu de choses sur sa vie privée. Je voudrais néanmoins entreprendre cette tâche dans les temps à venir. Je serrai reconnaissant pour toute indication ou information qui pourrait m'être transmise. Klaus Beneke Institut für Anorganische Chemie Christian-Albrechts-Universitat D24098 Kiel (traduction de l'allemand: André Lange) Publications de Raphael Eduard Liesegang sur la télévision (liste établie par Klaus Beneke). Nous remercions d'avance toute personne qui pourrait nous procurer l'original ou une copie de ces publications. LIESEGANG, R. E., article sur le "Phototel" in Central-Zeitung für Optik und Mechanik, 10, 268, 1889, Nr.23 LIESEGANG, R. E., "Ein Instrument zur Uebertragung eines Linsen-Bildes durch den electrischen Strom". Liesegang´s Photogr Archiv 30 Nr. 632. S. 308-312, 1889. LIESEGANG, R. E., "Das Phototel", Liesegang´s Photogr Archiv, 30 Nr. 634, 1889, p. 345-348. LIESEGANG, R. E., Beiträge zum Problem des electrischen Fernsehens. Probleme der Gegenwart, Band 1. Liesegang Verlag, Düsseldorf, 1891. Cet ouvrage est dédié à Thomas Alva Edison. "Das Telectroscop", Laterna magica, Band XIV, Nr. 54, Leipzig, Mai 1898, pp. 24-26. (attribué à Liesegang par Klaus Beneke). LIESEGANG, R. E., Beiträge zum Problem des electrischen Fernsehens, Probleme der Gegenwart, 2.Auflage, Leipzig, 1899. On notera également : LIESEGANG, R. E., "Phonographie und Photographie", Photographisches Archiv, Liesegang, Düsseldorf, 1890, pp. 284-286 et 302-304. Citations des travaux de Liesegang sur la télévision Une recension assez négative de Beiträge zum Problem des electrischen Fernsehens par le Professeur Adolf Miethe a été publée dans le "Bücherschau" in Prometheus, 2, 1891, 592. Une annonce de Beiträge zum Problem des electrischen Fernsehens figure dans le catalogue des éditions Liesegang, publié à la fin de la brochure LIESEGANG, F. Paul, Die Fernphotographie, Ed. Liesegang Verlag, Düsseldorf 1897, p.19. 41 "Der elektrische Fernseher. Ein Besuch bei Herrn Jan Szczepanik", Neue Wiener Tagblatt, Wien, 17 März 1898. PETERS, O., "Fernsehen und Farbfilm vor 50 Jahren. Zum 70. Geburtstag von Raphael Eduard Liesegang". Deutsche Allgemeine Zeitung 1, November 1939 PETERS, J.-J., A History of Television, site du DVB Group. Liesegang n'est pas cité dans l'ouvrage History of Television de A. Abramson. Dans HERZOGENRATH (W.), GAEHTGENS (T.W.), THOMAS (S.) und HOENISCH (P.) (Hrsgb), TV Kultur. Das Fernsehen in der Kunst seit 1879, Verlag der Kunst, Dresden, 1997, p.19 l'ouvrage Beiträge zum Problemen des electrischen Fernsehens est attribué erronément à son père, Paul E. Liesegang. L'ouvrage de R.W. BURNS, Television, an international history of the formative years, The Institution of Electric Engineers, London, 1998 ne mentionne pas Liesegang dans son chapitre sur les années 1880-1900. Cependant, cet ouvrage mentionne, p.117, que le chercheur russe Rosing, qui fut à l'origine des travaux sur l'application du tube cathodique de Braun, dans sa demande de brevet ("New or improved methods of electrically transmitting to a distant real optical image and apparatus thereof", British Patent 27 570, 13 December 1907) reconnaît sa dette envers Liesegang. Bibliographie On trouvera des informations complémentaires sur Raphael Ed. Liesegang in K. BENEKE, "Die Preise der Kolloid-Gesellschaft und ihre Preisträger" (PDF). Remerciements Je remercie Klaus Beneke, chercheur à l'Université de Kiel, qui m'a transmis la plupart des documents et informations sur Liesegang présentées sur ce site. 42 Klaus Beneke Institut für Anorganische Chemie der Christian-Albrechts-Universität der Universität D-24098 Kiel [email protected] Liesegang named in Literature (e. g. Liesegang-rings, periodic and rhythmic crystallization, Liesegang-phenomena, Liesegang-pattern, Runge-picture, Belousov-Zhabotinsky-reaction (Published 1790 – 2003) (nearly a complete list of this literature) Second Edition (May, 2004) Notice Everybody who has literature in which Liesegang is named and not in this literature list, please send it to me to complete the list. Thank you [email protected] A bibliography of agates will be find under: URL: http://csd.unl.edu/agates/agatebibliographyletter.asp Conservation and Survey Division School of Natural Resources Institute of Agriculture and Natural Resources 113 Nebraska Hall University of Nebraska Lincoln (UNL) Lincoln, Nebraska 68588-0517 USA 43 (1790) Keir J (1790) Experiments and observations on the dissolution of metals in acids, and their precipitations, with a new account of a new compound acid Menstruum, useful in some technical operations of parting metals. 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Springer Series in Synergetics (1981) 12 (Nonlinear Phenom. Chem. Dyn.): 240-246 Clarke B L (1981) Complete set of steady states for the general stoichiometric dynamical system. J Chem Phys 75 (10): 4970-4979 Crowley M F, Field R J (1981) Electrically coupled Belousov-Zhabotinskii oscillators: a potential chaos generator. Springer Series in Synergetics (1981) 12 (Nonlinear Phenom. Chem. Dyn.): 147-153 D'Alba Francesca, Serravalle G (1981) Oxidation of malonic acid from potassium bromate (reaction of Zhabotinskii). Comparison between different catalysts, with electrochemical method (in French). Journal de Chimie Physique et de PhysicoChimie Biologique 78 (2): De Kepper P, Boissonade J (1981) Theoretical and experimental analysis of phase diagrams and related dynamical properties in the Belousov-Zhabotinskii system. J Chem Phys 75 (1): 189-195 Edelson D (1981) Mechanistic details of the Belousov-Zhabotinskii oscillations. IV. Sensitivity analysis. International Journal of Chemical Kinetics 13 (11): 1175-1189 Edelson D, Thomas Valerie M (1981) Sensitivity analysis of oscillating reactions. 1. The period of the Oregonator. J Phys Chem 85 (11): 1555-1558 Farage V J, Janjic D (1981) Effect of mechanical agitation on oscillating chemical reactions in the presence of oxygen or nitrogen (in French). Chimia 35 (8): 289-291 Feeney R, Schmidt S L, Ortoleva P (1981) Experiments on electric field-BZ chemical wave interactions: annihilation and the crescent wave. Physica D: Nonlinear Phenomena 2 D (3): 536-544 Geiseler W, Bar-Eli K (1981) Multistability in flow systems of the BelousovZhabotinskii and related systems. Springer Series in Chemical Physics (1981) 18 (Modell. Chem. React. Syst.): 268-274 Gorshenev V N, Gladyshev T P (1981) Use of the counterdiffusion method for the determination of critical concentrations of precipitating components in periodic reactions (in Russian). Zhurnal Fizicheskoi Khimii 55 (11): 2897-2903 Gottwald B A (1981) KISS - a digital stimulation system for coupled chemical reactions. Simulation 37 (5): 169-173 Gupta V K, Nair P K R, Srinivasulu K (1981) Oscillatory behavior of the reaction of 3alizarinsulfonic acid sodium salt with acidic bromate. Reaction Kinetics and Catalysis Letters 18 (1-2): 45-49 154 Haken H (1981) Erfolgsgeheimnisse der Natur. Stuttgart Hudson J L, Mankin J C (1981) Chaos in the Belousov-Zhabotinskii reaction. J Chem Phys 74 (11): 6171-6177 Hudson J L, Mankin J, McCullough J, Lamba P (1981) Experiments on chaos in a continuous stirred reactor. Springer Series in Synergetics (1981) 12 (Nonlinear Phenom. Chem. Dyn.): 44-48 Jaques A L (1981) Petrology and petrogenesis of cumulate peridotites and gabbros from the Marum ophiolite complex, northern Papua New Guinea. Journal of Petrology 22 (1): 1-40 Kanniah N, Gnanam F D, Ramasamy P, Laddha S (1981) Revert and direct type Liesegang phenomenon of silver iodide. J Colloid Interface Sci 80 (2): 369-376 Kanniah N, Gnanam F D, Ramasamy P (1981) Periodic precipitation of Cobalt(II) oxinate. J Colloid Interface Sci 80 (2): 377-385 Katsuragi S, Miyayama H, Takeuchi T (1981) Picornavirus-like inclusions in polymyositis--aggregation of glycogen particles of the same size. Neurology 31 (11): 1476-1480 Keller J B, Rubinow S I (1981) Recurrent precipitation and Liesegang rings. J Chem Physics 74 (9): 5000-5007 Kendrick G C, Edmond C L (1981) Magma immiscibility in the Shonkin Sag and Square Butte laccoliths [USA]. Geology 9 (12): 615-619 Keszthelyi C P, Soos J, Janossy A S, Vovacs Kristof (1981) Iron catalyst local concentration fluctuations found in dissipative reactions by x-ray microanalysis. Bulletin of the Chemical Society of Japan 54 (1): 321-322 Koros E, Varga Margit, Putirskaya Galina (1981) Perturbation of bromate oscillators. Springer Series in Synergetics (1981) 12 (Nonlinear Phenom. Chem. Dyn.): 207-212 Kovalenko A S, Tikhonova L P, Yatsimirskii K B (1981) Study of simultaneous effect of cerium(III,IV) ions and ferroin in a Belousov-Zhabotinskii oscillating chemical reaction (in Russian). Teoreticheskaya i Eksperimental'naya Khimiya 17 (4): 493-499 Krishnan S, Gnanam F D, Ramasamy P, Laddha G S (1981) Influence of electric field on rhythmic crystallization of calcium carbonate in agar gel. Cryst Res Technol 16 (9): K123-K126 Krishnan S, Gnanam F D, Ramasamy P, Laddha G S (1981) Influence of impurity on rhythmic crystallization of calcium carbonate in agar gel. Cryst ResTechnol 16 (10): 1103-1110 Kuhnert L, Pehl K W (1981) Oscillations in the Belousov-Zhabotinskii system (BZR) catalyzed by bis-bipyridine-silver complexes. Chemical Physics Letters 84 (1): 155158 Kuhnert L, Pehl K W (1981) Bipyridine complexes of osmium and chromium catalyzing the oscillating reaction between bromate and malonic acid. Chemical Physics Letters 84 (1): 159-162 155 Lobry C, Lozi R (1981) Bifurcation of motifs in families of mixed two-vector field. Springer Series in Synergetics (1981) 12 (Nonlinear Phenom. Chem. Dyn.): 67-70 Nakajima K, Sawada Y (1981) Phase diagram for two weakly coupled oscillatory chemical systems. Journal of the Physical Society of Japan 50 (2): 687-695 Noszticzius Z (1981) On the role of bromide ions in the Belousov-Zhabotinskii reaction of malonic acid. Acta Chimica Academiae Scientiarum Hungaricae 106 (4): 347-357 Noszticzius Z, Farkas H (1981) An old model as a new idea in the modelling of the oscillation B Z reaction. Springer Series in Chemical Physics (1981) 18 (Modell. Chem. React. Syst.): 275-281 Patel A R, Venkateswara-Rao A (1981) Studies on gel growth and microstructures of lead iodide (PbI/sub 2/) single crystals. Indian Journal of Pure and Applied Physics 19: 685-693 Patonay G, Noszticzius Z (1981) Effect of stirring on the Belousov-Zhabotinskii reaction. A problem of interpretation. Reaction Kinetics and Catalysis Letters 17 (12): 187-189 Peignoux-Deville J, lallier F, Vidal B (1981) Demonstration of bone tissue in the axial skeleton of a chondrichthian: the dogfish (Scyliorhinus canicula) (in French). C R Seances Acad Sci III, 292 (1): 73-78 Petrovskii V A (1981) Nature of the zonal structure of crystals. Doklady Akademii Nauk SSSR 260 (3): 630-633 Pikovskii A S (1981) A dynamical model for periodic and chaotic oscillations in the Belousov-Zhabotinsky reaction. Physics Letters A 85 A (1): 13-16 Pomeau Y, Roux J C, Rossi A, Bachelart S, Vidal C (1981) Intermittent behavior in the Belousov-Zhabotinskii reaction. Journal de Physique, Lettres 42 (13): 271-273 Preis I R (1981) Study of the chemistry of aerosols by the method of Liesegang rings (in Russian). Trudy Zakavkazskogo Regional'nogo Nauchno-Issledovatel'skogo Instituta 73: 69-74 Rashkova D (1981) Zonal phlogopite crystals from the Rossen copper-molybdenum deposit, district of Bourgas [Bulgaria]. Doklady Bolgarskoi Akademii Nauk 34 (11): 1529-1532 Ross J (1981) Two topics in chemical instabilities. I. Periodic precipitation processes. II. Resonances in oscillatory reactions and glycolysis. Springer Series in Synergetics (Nonlinear Phenom. Chem. Dyn.) 12: 180-185 Ruoff P (1981) Chemical oscillations (in Norwegian). Kjemi (1981) (6): 26-27 Roux J C, Swinney H L (1981) Topology of chaos in a chemical reaction. Springer Series in Synergetics 12 (Nonlinear Phenom. Chem. Dyn.): 38-43 Scott G P (1981) A novel wave form in oscillating "Z" reagent containing poly(acrylic acid). Naturwissenschaften 68 (4): 203-204 156 Schmidt S, Ortoleva P (1981) Electric field effects on propagating BZ waves. Predictions of an Oregonator and new pulse supporting models. J Chem Phys 74 (8): 4488-4500 Seno M, Iwamoto K (1981) Theories for dissipative structures under non-equilibrium states (in Japanese). Kagaku (Kyoto, Japan) 36 (3): 228-231 Seo M (1981) Liesegang phenomena and dissipative structure (in Japanese). Kyoritsu Kagaku Raiburari 19: 185-204 Tikhonova L P, Kovalenko A S, Yatsimirskii K B (1981) Study of the joint action of cerium(III, IV) and manganese(II, III) ions in the Belousov-Zhabotinskii oscillating reaction (in Russian). Teoreticheskaya i Eksperimental'naya Khimiya 17 (3): 348-355 Treindl L, Kaplan P (1981) Kinetics of the oxidation of ethyl ester of 3-oxobutyric acid by the cerium(IV) ions in relation to the Belousov-Zhabotinskii reaction. Chemicke Zvesti 35 (2): 145-152 Treindl L, Kaplan P (1981) Kinetics of oxidation of 2,4-pentanedione with cerium(IV) ions in relation to the Belousov-Zhabotinskii reaction. Collection of Czechoslovak Chemical Communications 46 (8): 1734-1739 Treindl L, Dorovsky V (1981) A chemical oscillator of the Belousov-Zhabotinskii type involving α-ketoglutaric acid. Z Physikalische Chemie (München) 126 (1): 129-131 Turner J S, Roux J C, McCormick W D, Swinney H L (1981) Alternating periodic and chaotic regimes in a chemical reaction - experiment and theory. Physics Letters A 85 A (1): 9-12 Tyson J J (1981) On scaling the Oregonator equations. Springer Series in Synergetics (1981) 12 (Nonlinear Phenom. Chem. Dyn.): 222-227 Vaidyan V K, Ittyachan M A, Mohanan-Pillai K (1981) On the theory of periodic precipitation. J Cryst Growth 54 (2): 239-242 Tsuda I (1981) Chaos of chemical reactions and related problems (in Japanese). Bussei Kenkyu 35 (5): 257-300 Vidal C (1981) Dynamic instabilities observed in the Belousov-Zhabotinskii system. Springer Series in Synergetics (1981) 11 (Chaos Order Nat.): 69-82 Willett R D, Arend H, Ehrensperger M (1981) A migrating precipitation band phenomenon in the gel growth of crystals. Journal of Crystal Growth 53: 437-439 Yatsimirskii K B, Tikhonova L P, Zakrevskaya L N, Lampeka Y D (1981) Homogeneous oscillatory reactions involving bromate and tetraaza macrocyclic complexes of nickel(II) and (III) (in Russian). Doklady Akademii Nauk SSSR 261 (3): 647-649 Yatsimirskii K B, Kovalenko A S, Tikhonova L P (1981) Features of the action of two catalysts in the Belousov-Zhabotinskii oscillatory chemical reaction (in Russian). Doklady Akademii Nauk SSSR 258 (4): 918-923 Zaera F, Rusinek I (1981) Monte Carlo simulation for inhomogeneous chemical kinetics. Application to the Belousov-Zhabotinskii reaction. Journal of Computational Chemistry 2 (4): 402-409 157 Zueva T S, Sipershtein I N (1981) Effect of sec-butyl alcohol on an oscillatory Belousov-Zhabotinskii reaction (in Russian). Teoreticheskaya i Eksperimental'naya Khimiya 17 (2): 277-282 (1982) Abdulkhadar M, Ittyachan M A (1982) Growth of large needles and single crystals of PbCl2 and PbBr2 in silica gel. An improvement of the new gel technique. Cryst Res Technol 17: 33-38 Adamcikova Lubica Sevcik P (1982) Belousov-Zhabotinsky oscillator with mandelic acid. Z Physikalische Chemie (Muenchen, Germany) 132 (2): 251-253 Adamcikova Lubica, Sevcik P (1982) Heterogeneous oscillation reaction in the tartaric acid-potassium bromate-manganese(II) sulfate-sulfuric acid system. Collection of Czechoslovak Chemical Communications 47 (9): 2333-2335 Adamcikova Lubica, Sevcik P (1982) A completely inorganic oscillating system of the Belousov-Zhabotinskii type. International Journal of Chemical Kinetics 14 (7): 735738 Aebi U, Fowler W E, Smith P R (1982) Three-dimensional structure of proteins determined by electron microscopy. Ultramicroscopy 8 (1-2): 191-206. Review Agulova L P, Opalinskaya A M (1982) Experimental study of the effects of a weak, extra-low-frequency magnetic field on the Belousov-Zhabotinskii reaction without mechanical mixing and with hydroquinone addition (in Russian). Deposited Document (1982) (VINITI 5415-82) 15 pp Ambrose S, Kanniah N, Gnanam F D, Ramasamy P (1982) Periodic crystallisation of magnesium hydroxide: Effect of additives and gel. Cryst Res Technol 17: 299 Ambrose S, Kanniah N, Gnanam F D, Ramasamy P (1982) Periodic crystallisation of magnesium hydroxide in agar-agar gel. Cryst Res Technol 17: 609 Ameta S C, Khandia B L (1982) Studies in oscillatory behavior of oxidation of pyrogallic acid by potassium bromate. Z Physikalische Chemie (Leipzig) 263 (2): 410-412 Arora S K, Abraham T, Godebole R S (1982) Mechanism of formation of cadmium oxalate Liesegang rings. Cryst Res Technol 17 (8): 979-985 Bar-Eli K, Geiseler W (1982) Multiple steady states and hysteresis during stirred flow oxidation of cerous ion by bromate. Experiments and models. Acta Chimica Academiae Scientiarum Hungaricae 110 (3): 239-249 Bard A J (1982) Encyclopedia of electrochemistry of the elements, Vol. 9/A. dekker, New York Berg W, Brundig P, Bothor C, Schneider H J (1982) Biological rhythmicity and crystallization - urine profiles and SEM studies on calcium oxalate stone genesis. International Urology and Nephrology 14 (4): 363-372 158 Bolletta F, Balzani V (1982) Oscillating chemiluminescence from the reduction of bromate by malonic acid catalyzed by tris(2,2'-bipyridine)ruthenium(II). J Amer Chem Soc 104 (15): 4250-4251 Budtov V P, Yanovskaya N K (1982) Theory of the formation of periodic precipitates (cylindrical symmetry) (in Russian). Zhurnal Fizicheskoi Khimii 56 (10): 2464-2468 Burger Maria, Racz Krisztina (1982) On the preoscillatory period of the BelousovZhabotinsky reaction. A search for intermediates. Acta Chimica Academiae Scientiarum Hungaricae 110 (3): 315-326 Ebeling W, Feistel R (1982) Physik der Selbstorganisation und Evolution. AkademieVerlag, Berlin Farage V J, Janjic D (1982) Uncatalyzed oscillatory chemical reactions. Effect of different constraints during the oxidation reaction of 1,4-cyclohexanedione by acidic bromate. Chemical Physics Letters 93 (6): 621-624 Field R J, Raghavan N V, Brummer J G (1982) A pulse radiolysis investigation of the reactions of bromine dioxide radical (BrO2) with hexacyanoferrate(II), manganese(II), phenoxide ion, and phenol. J Phys Chem 86 (13): 2443-2449 Försterling H-D, Lamberz H J, Schreiber H, Zittlau W (1982) Bromine dioxide (BrO2) as an intermediate in the Belousov-Zhabotinsky reaction. Acta Chimica Academiae Scientiarum Hungaricae 110 (3): 251-260 Försterling H-D, Lamberz H J, Schreiber H, Zittlau W (1982) Bromine dioxide as an intermediate product of the Belousov-Zhabotinskii reaction (in Hungarian). Kemiai Kozlemenyek 57 (3-4): 283-293 Fontbote L, Amstutz G C (1982) Observations on ore rhythmites of the Trzebionka mine, Upper Silesian-Cracow region, Poland. Special Publication of the Society for Geology Applied to Mineral Deposits (1982) 2 (Ore Genesis: State of the Art): 83-91 Fujioka K (1982) Effect of sulfuric salt in chemical oscillation systems. II (in Japanese). Nippon Bunri Daigaku Kiyo 11 (1): 140-148 Ganapathisubramanian N, Noyes R M (1982) A discrepancy between experimental and computational evidence for chemical chaos. J Chem Phys 76 (4): 1770-1774 Ganapathisubramanian N, Noyes R M (1982) Chemical oscillations and instabilities. Part 48. Reliability of bromide ion-selective electrodes for studying the oscillatory Belousov-Zhabotinsky reaction. J Phys Chem 86 (16): 3217-3222 Ganapathisubramanian N, Noyes R M (1982) Chemical oscillations and instabilities. Part 49. Additional complexities during oxidation of malonic acid in the BelousovZhabotinskii oscillating reaction. J Phys Chem 86 (26) 5158-5162 Ganapathisubramanian N, Noyes R M (1982) Chemical oscillations and instabilities. Part 50. Bromate-driven oscillators in the presence of excess silver ion. J Phys Chem 86 (26): 5155-5157 Geiseler W (1982) Multiplicity, stability, and oscillations in the stirred flow oxidation of manganese(II) by acidic bromate. J Phys Chem 86 (22): 4394-4399 159 Gupta V K, Srinivasulu K (1982) Uncatalyzed and catalyzed bromate driven oscillations in salicylic and 5-sulfosalicylic acid. Reaction Kinetics and Catalysis Letters 19 (1-2): 193-196 Gyorgy P, Gyorgy B, Beck M T (1982) Study of pseudowaves in periodic reactions. Acta Chimica Academiae Scientiarum Hungaricae 110 (3): 277-281 Habashi-Krayenbuhl Dominique, Janjic D (1982) Belousov-Zhabotinskii-type chemical oscillator involving phosphonoacetic acid (in French). Chimia 36 (3): 123124 Kai S, Müller S C, Ross J (1982) Measurements of temporal and spatial sequences of events in periodic precipitation processes. Journal Chemical Physics 76 (3): 13921406 Kanniah N, Ambrose S, Gnanam F D, Ramasamy P (1982) Periodic precipitation of cobalt(II) oxinate in agar gel. Effect of parasitic electrolytes on flocculation. Proc Indian Academy of Sciences, Chemical Sciences 91 (1): 87-99 Kanniah N, Ambrose S, Gnanam F D, Ramasamy P (1982) Periodic precipitation of cobalt(II) oxinate in agar gel. Factors influencing the flocculation. Proc Indian Academy of Sciences, Chemical Sciences 91 (3): 279-287 Kerner B S, Osipov V V (1982) Pulsating heterophase regions in nonequilibrium systems (in Russian). Zhurnal Eksperimental'noi i Teoreticheskoi Fiziki 83 (6): 22012214 Kibalczyc W, Sokolowski T, Wiktorowska B (1982) Calcium hydroxyapatite crystals grown in silica gel. Cryst Res Technol 17 (11): K105-K106 Koros E, Varga Margit (1982) A novel possibility to clarify the role of bromide in bromate oscillators. Reaction Kinetics and Catalysis Letters 21 (4): 521-526 Koros E, Putirskaya Galina, Varga Margit (1982) Perturbation of bromate oscillators. I. Perturbation by γ irradiation. Acta Chimica Academiae Scientiarum Hungaricae 110 (3): 295-303 Krishnan S, Gnanam F D, Ramasamy P, Laddha G S (1982) Anomalious stratification of copper carbonate in agar gel. Cryst Res Technol 17 (3): 307-312 Kubicek M, Stuchl I, Marek M (1982) "Isolas" in solution diagrams. Journal of Computational Physics 48 (1): 106-116 Kurien K V, Vaidyan V K, Ittyachen M A (1982) Factors influencing the periodic precipitation of barium molybdate(VI) crystals in silica gel. Cryst Res Technol 17 (2): 211-216 Kurien K V, Vaidyan V K, Ittyachen M A (1982) Estimation of diffusion coefficient of barium(2+) ions in silica gel from periodic precipitation of barium molybdate(VI). Colloid Polymer Sci 260 (5): 552-556 Kuzien KV, Vaidyan VK, Ittyachan MA (1982) Estimation of diffusion coefficient of Ba++-ions in silica gel from periodic precipitation of BaMoO4. Colloid Polym Sci 260:552-556 Kuz'menko G I (1982) Modeling of a hydrogen atom (in Russian). Deposited Doc. 160 VINITI 827-83) 11 pp Lopez-Acevedo V, Garcia-Ruiz J M (1982) An experimental study of calcium phosphate precipitation using silica gel technique. Estudios Geologicos (Madrid) 38 (3-4): 227-232 Loginov V P, Nafikov U S, Pirozhok P I (1982) Zoning of metasomatites and source of ore-forming iron at the Uchalin pyrite deposit (southern Urals) (in Russian). Probl Vertikal'noi Metasomaticheskoi Zon (1982): 104-126 Mankin J, Lamba P, Hudson J L (1982) Transitions between periodic and chaotic states in a continuous stirred reactor. ACS Symposium Series (1982) 196 (Chem. React. Eng.-Boston): 145-154 Meinhardt H (1982) Models of biological pattern formation. Academic Press, London Mitomo S, Iwamoto K, Seno M (1982) Study on a model reaction system showing double oscillations (in Japanese). Seisan Kenkyu 34 (3): 95-96 Müller S C, Kai S, Ross J (1982) Curiosities in periodic precipitation patterns. Science 216: 635-637 Müller S C, Kai S, Ross J (1982) Periodic precipitation patterns in the presence of concentration gradients. 1. Dependence on ion product and concentration difference. J Phys Chem 86 (20): 4078-4087 Müller S C, Kai S, Ross J (1982) Mesoscopic structure of pattern formation in initially uniform colloids. J Phys Chem 86 (22): 4294-4297 Nagashima H (1982) Experiment on chaotic responses of a forced BelousovZhabotinsky reaction. J Physical Society of Japan 51 (1): 21-22 Neuman M W (1982) Blood: bone equilibrium. Calcif Tissue Int 34: 117-120 Noszticzius Z, Feller A (1982) On the applicability of the Lotka-Volterra scheme for different types of the Belousov-Zhabotinskii reaction. Acta Chimica Academiae Scientiarum Hungaricae 110 (3): 261-275 Orban M, De Kepper P, Epstein I R (1982) Systematic design of chemical oscillators. 10. Minimal bromate oscillator. Bromate-bromide-catalyst. J Amer Chem Soc 104 (9): 2657-2658 Ortoleva P (1982) Solute reaction mediated precipitate patterns in cross gradient free systems. Zeitschrift für Physik B 47: 1-8 Ortoleva P (1982) Solute reaction mediated precipitate patterns in cross gradient free systems. Zeitschrift für Physik B (Condensed Matter) 49 (2): 149-156 Ortoleva P, Chadam J, El-Badewi M, Feeney R, Feinn D, Haase S, Larter R, Merino E, Strickholm A, et al. (1982) Mechanisms of bio- and geo-pattern formation and chemical signal propagation. Instab., Bifurcations, Fluctuations Chem. Syst. (1982), 125-195 Pacault A, Vidal C (1982) Spatial chemical structures. Chemical waves. J Chimie Physique et de Physico-Chimie Biologique 79 (10): 691-707 Peignoux-Deville J, lallier F, Vidal B (1982) Evidence for the presence of osseous tissue in dogfish vertebrae. Cell Tissue Res 222 (3): 605-614 161 Pillai K M, Vaidyan V K, Ittyachan M A (1982) Effect of different parameters on the Liesegang ring formation of lead carbonate crystals. Cryst Res Technol 17 (12): 1529-1534 Rastogi R P, Prasad K (1982) Onset of chemical oscillations in the B-Z reaction. Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical 21 A (11): 1011-1014 Rinzel J, Ermentrout G B (1982) Trigger wave fronts of rapid consumption in a Belousov-Zhabotinskii system. J Phys Chem 86 (15): 2954-2958 Rinzel J, Troy W C (1982) Bursting phenomena in a simplified Oregonator flow system model. J Chem Phys 76 (4): 1775-1789 Ruoff P, Schwitters B (1982) An oscillating Belousov-Zhabotinskii reaction with methylmalonic acid (in German). Z Physikalische Chemie (Muenchen, Germany) 132 (1): 125-127 Ruoff P (1982) Excitability in a closed stirred Belousov-Zhabotinskii system. Chemical Physics Letters 90 (1): 76-80 Ruoff P (1983) Excitability created by oxygen inhibition in the stirred malonic acid Belousov-Zhabotinskii system. Chemical Physics Letters 92 (3): 239-244 Sakanoue S, Endo M (1982) The existence of an unstable limit cycle in the Oregonator model for the Belousov-Zhabotinskii reaction. Bulletin of the Chemical Society of Japan 55 (5): 1406-1409 Salter L F, Sheppard J G (1982) A dual-frequency Belousov Zhabotinskii oscillating reaction with ethyl acetoacetate as organic substrate. International Journal of Chemical Kinetics 14 (8): 815-821 Sevcikova Hana, Suchanova Dana, Marek M (1982) The patterns of phase resetting of oscillations in the Zhabotinskii reaction. Sbornik Vysoke Skoly ChemickoTechnologicke v Praze, K: Chemicke Inzenyrstvi K17: 137-150 Shibuya T, Nishikawa A (1982) Fixation of self-organized chemical wave patterns on cotton cloth. Textile Research Journal 52 (6): 419-420 Simoyi R H, Wolf A, Swinney H L (1982) One-dimensional dynamics in a multicomponent chemical reaction. Physical Review Letters 49(4): 245-248 Smoes M L (1982) The ferroin catalyzed Zhabotinskii system - experimental aspects. Instab., Bifurcations, Fluctuations Chem. Syst. (1982) 83-124 Steven A C, Navia M A (1982) Specificity of stain distribution in electron micrographs of protein molecules contrasted with uranyl acetate. J Microsc 128 Pt 2: 145-155 Stuchl I, Marek M (1982) Dissipative structures in coupled cells. Experiments. J Chem Phys 77 (6): 2956-2963 Stuchl I, Marek M (1982) Experiments on "relative stabilities" in a chemical system. J Chem Phys 77 (3): 1607-1609 Treindl L, Mrakavova M (1982) Kinetic study of the oxidation of malonic acid by manganese(III) ions. Chemicke Zvesti 36 (5): 627-632 Treindl L, Dorovsky V (1982) Kinetics of oxidation of α-ketoglutaric acid with 162 cerium(IV) ions in relation to the Belousov-Zhabotinskii reaction. Collection of Czechoslovak Chemical Communications 47 (11): 2831-2837 Tsuda I, Tomita K (1982) Chaos in the Belousov-Zhabotinsky reaction. Res. Rep. Nagoya Univ., Inst. Plasma Phys. (1982), (IPPJ-578, US-JPN Jt. Inst. Fusion Theory Workshop "Nonequilb. Stat. Phys. Probl. Fusion Plasmas - Stochasticity Chaos - "): 131-137 Tyson J J (1982) Scaling and reducing the Field-Koros-Noyes mechanism of the Belousov-Zhabotinskii reaction. J Phys Chem 86 (15): 3006-3012 Varadi Z, Beck M T (1982) Effect of metal ions forming bromide complexes on the Belousov-Zhabotinskii reaction. 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Physical Review E, Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics 60 (2 Pt A): R 15121515 Korobov A I, Svechkarev D A (1999) Spatial-temporal structures in the ferroincatalyzed Belousov-Zhabotinskii system. Stabilization under UV-irradiation (in Russian). Visnik Kharkivs'kogo Universitetu 437: 182-183 Kravchenko V V, Medvinskii A B, Resketilov A N, Ivanitskii G R (1999) Substrate acidification by a population of dictyostelium discoideum facilitates formation of Liesegang rings. Doklady Biophysics c/c of Doklady Akademii Nauk. SSSR February, 1999; 364 (5): 687-689 (Russian) Kravchenko V V, Emel´yanenko V I, Medvinskii A B, Ivanitskii G R (1999) The folic acid redistribution during formation of Liesegang rings initiated by a population of dictyostelium discoideum. Doklady Biophysics c/c of Doklady Akademii Nauk SSSR January 1999; 364 (1): 114-116 (Russian). 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Wuhan Daxue Xuebao, Ziran Kexueban 45 (6): 799-802; 806 Long K-P, Hu S-J, Duan Y-B, Hui X (1999) Pattern and dynamic changes of integer multiples in spontaneous electric discharge of injured dorsal root ganglion neurons. Shengli Xuebao 51 (5): 481-487 Malyakov J, Belmustakova Hercinta (1999) Petrological and structural features of the Sylistar pluton, southeastern Strandzha Mountain. Geokhimiya, Mineralogiya i Petrologiya 36: 29-44 Manz N, Müller S C, Steinbock O (1999) Pattern formation on curved surfaces. Book of Abstracts, 218th ACS National Meeting, New Orleans, Aug. 22-26 (1999): Matsumura-Inoue T, Nakamura T, Mori Y, Hanazaki I (1999) Effect of pulsed illumination on the Belousov-Zhabotinskii reaction catalyzed with tris(bipyridine)ruthenium(II) in continuous stirred tank reactor. Chemistry Letters (11): 1237-1238 Min M, Wu Y, Zhang G, Geng J (1999) Dense zoned rhythmic intergrowth of coffinite and pitchblende and its genetic significance. 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Book of Abstracts, 218th ACS National Meeting, New Orleans, Aug. 22-26, 1999 Prager R, Liesegang A, Rabsch W, Gericke B, Thiel W, Voigt W, Helmuth R, Ward L, Tschape H (1999) Clonal relationship of Salmonella enterica serovar typhimurium phage type DT104 in Germany and Austria. Zentralbl Bakteriol 289 (4): 399-414 Rachwalska Malgorzata, Kawczynski A L (1999) New types of mixed-mode periodic oscillations in the Belousov-Zhabotinskii reaction in continuously stirred tank reactors. J Phys Chem A 103 (18): 3455-3457 Racz Z (1999) Formation of Liesegang patterns. Physica A 274 (1-2): 50-59 Rambidi N G, Yakovenchuk D (1999) Information-processing capabilities of chemical reaction-diffusion systems. 2. Finding paths in a labyrinth based on reaction-diffusion 286 media. Advanced Materials for Optics and Electronics 9 (1): 27-34 Roll B, Schwemer J (1999) α-crystallin and vitamin A 2 isomers in lenses of diurnal geckos. 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