03 VAUDE_RSL_March_2013

Transcription

Restricted Substance List
Edition 3.3
Without the use of chemicals in textile manufacturing, the performances
requested by the consumer can’t be attained. However, chemicals can be harmful
to the workers, consumers or even the environment and the correct use of
chemicals requires certain know-how to prevent any risks to workers, consumers
or the environment.
The management of chemicals is very important to protect the consumer and all
involved people as well as the environment during the production phase. To help
suppliers, VAUDE has developed a minimum standard for suppliers regarding
primarily consumer safety of chemicals on finished products. Other aspects like
environmental performance in the production process are not implemented in this
Restricted Substance List.
The Restricted Substance List (RSL) is a minimum requirement for suppliers to
guarantee compliance with the VAUDE standards. It is recommended to adopt
additional policies, particularly regarding water emission, air emission,
occupational health and resource productivity in order to provide risk free
products.
In this context VAUDE recommends to adopt the bluesign® standard. The
independent bluesign® standard takes a solution-oriented approach that relates
exclusively to problem materials and substances relevant to textiles. In particular
the bluefinder™, an online chemicals components selection tool, allows to quickly
find “bluesign® approved” components that will lead to end-products that comply
with the RSL at hand, provided they are applied according to the suppliers
recommendations.
The limits and restrictions have to be applied for each individual component of an
intermediate or finished product.
Producing according to the RSL is a mandatory requirement for doing business
with VAUDE.
In addition to the VAUDE RSL the supplier has to be aware of Regulation EC No
1907/2006 “REACH”. The supplier shall inform VAUDE if supplied articles contain
SVHCs listed in the ECHA candidate list with a concentration above 0.1%.
Suppliers have to take care that they are aware of the actual ECHA candidate list
see http://echa.europa.eu/web/guest/candidate-list-table
Date Issued: March 2013
Page 1 of 29
RSL VAUDE - Edition 3.3 - March 2013
Supplier Compliance Certificate
Company Name:
Address:
Telephone:
Fax:
Contact Person:
Please describe in short words, how compliance with the VAUDE Restricted
Substance List (RSL) is guaranteed in your manufacturing site:
RSL Compliance
We certify that all materials supplied to VAUDE will meet the requirements as
outlined in the attached Restricted Substance List (the “RSL”) including all
appendices. Our signature guarantees compliance for all current and future
materials supplied to VAUDE.
______________________
___________________
Signature
Date
______________________
___________________
Printed Name
Title
SVHC Compliance
We certify that concentration of SVHCs listed in the newest ECHA candidate list is
below 0.1% in all articles supplied to VAUDE.
Note: If noticeable SVHC concentration is known (esp. above a level of 0.1 %) it
must be informed automatically by the supplier.
______________________
___________________
Signature
Date
______________________
___________________
Printed Name
Title
Page 2 of 29
Identification of substances
The following general approach is proposed to identify whether or not
substances, mentioned in the RSL are contained in your materials:
Narrow down the range of substances which could be present in the articles and
thus have to be analysed by applying common knowledge about what could
possibly be present in the materials (as for an example: a phthalate would never
be present in a pure metal).
Exhaust options for obtaining information via the supply chain.
Only as a last resort, conduct targeted analysis to identify whether or not
suspected substances listed in the RSL are present.
The testing matrix (see Annex II) may help to define the relevant items for
testing procedure.
Page 3 of 29
Part I: Restricted substances
LIMIT [mg/kg]
ITEM
A
pH
B
C
4.0-7.5
No unpleasant
odour shall be
emitted from the
products
Odour
TEST METHOD
DIN EN ISO 3071:2006
(Textile)
SNV 195 651
Colour Fastness Properties
For textiles dyed
with disperse or
metal complex dyes:
higher than 4
Property to perspiration
Colour fastness to saliva and
perspiration
Asbestos
listed in Appendix A
yes
Usage Ban
Alkylphenols and Alkyl phenol
ethoxylates (APEOs)
[OP, NP, OPEO, NPEO]
Usage Ban //
Traces: 100
for each
DIN EN ISO 105-E04:200907
§ 64 LFGB; BVL B 82.10-1
REM/EDX
According to BG:
ZH 1/120.31 and
ZH 1/120.46
Solvent extraction / HPLC-MS
Detection Limit: 100 mg/kg
Azo dyes:
Textile – Natural fibres
EN 14362-1:2003
BVL B 82.02-2
Arylamines (as substance for
example in PU and Azo colourants
which, by reductive cleavage of
one or more AZO groups, may
release one or more of the
aromatic amines)
Polyester:
EN 14362-2:2003
BVL B 82.02-4
Usage Ban
Leather:
CEN ISO/TS 17234:2003
listed in Appendix B
BVL B 82.02-3(V)
additional:
BVL B 82.02-9 for 4Aminoazobenzol
Polyurethane: HPLC
Page 4 of 29
LIMIT [mg/kg]
ITEM
A
B
C
TEST METHOD
Usage Ban for
textile finishing
Bisphenol A (CAS 80-05-7)
LC-MS
Detection limit: 1.0 mg/kg
Accessories: 50
Boric acid and derivatives
listed in Appendix C
100 for each
Solvent extraction / GC-MS or
Extraction / ICP
Detection limit: 10 mg/kg
Chlorinated aromatic hydrocarbons
(Carriers)
listed in Appendix D
Usage Ban as carrier
//
other cases: Traces
1.0
Solvent extraction / GC-MS
Detection Limit: 1.0 mg/kg
Sum of each group
of TriCP, TeCP, PCP
Chlorinated phenols
Trichlorophenols (TriCP), all
isomers
(CAS 25167-82-2)
LFBG §64 BVL 82.02.8:2001
(Textile)
ISO 17070:2006 (leather)
Tetrachlorophenols (TeCP,
TetraCP), salts and compounds
(CAS 25167-83-3)
0.05
0.05
0.05
EN 71-11-2005 (Safety of
toys)
Pentachlorophenol (PCP), salts,
esters and compounds
(CAS 87-86-5)
Colourants
Colourants with carcinogenic
potential
Usage Ban
LFBG §64 BVL 82.02.10:2007
(Textile)
listed in Appendix E
EN 71-11-2005 (Safety of
toys)
Colourants with allergenic
potential
Usage Ban
listed in Appendix F
Page 5 of 29
LIMIT [mg/kg]
ITEM
A
Colourants banned for other
reasons
B
C
TEST METHOD
Usage Ban
listed in Appendix G
Dimethylfumarate (CAS 624-49-7)
Usage Ban
Dioxins and Furans
listed in Appendix H
Sum of all traces
group 1:
Group 1
0.1 µg/kg
Sum of all traces
group 1 and 2:
Group 2
1 µg/kg
EPA 8290A (HRGC/HRMS)
Sum of all traces
group 1,2 and 3:
Group 3
1 µg/kg
Sum of all traces
group 4:
Group 4
0.1 µg/kg
Sum of all traces
group 1 and 2:
Group 5
1 µg/kg
Flame retardants
HPLC-MS
Usage Ban
listed in Appendix I
Fluorinated Greenhouse Gases
HPLC-MS
Usage Ban
listed in Appendix J
ISO 14184-1:1998 or JIS
L1041 (Law 112)
Formaldehyde (CAS 50-00-0)
DL
75
300
ISO 14184-2:1998 (Textile)
ISO 17226-1:2008 (Leather)
Page 6 of 29
LIMIT [mg/kg]
ITEM
A
B
Halogenated Biphenyls,
halogenated Terphenyls,
halogenated Naphthalenes
C
TEST METHOD
Solvent extraction / GC-MS,
LC-MS
Usage Ban
Detection Limit: 1 - 5 mg/kg
listed in Appendix K
Halogenated Diarylalkanes
Solvent extraction / GC-MS,
LC-MS
Usage Ban
listed in Appendix L
Isocyanates
Free content applies
to sum of all: 1.0
listed in Appendix M
EN 13130-8-2004 (Plastics)
//
Extraction / Derivatisation /
HPLC
Monomers:
Acrylamide (CAS 79-06-1)
1.0
Ozone Depleting Substances:
listed in Appendix N
Perfluorooctane sulfonates (PFOS)
(CAS 1763-23-1)
Perfluorocarboxylic acid and salts
(PFHxA, PFOA)
(CAS 307-24-4, 335-67-1)
1.0
1.0
Usage Ban
Usage Ban
Traces: 1 [µg/m2]
Usage Ban
Traces: 0.05
Multiple Headspace / GC/MS
0.5 mg/kg
Pesticides
listed in Appendix O
Page 7 of 29
Value applies to
total sum of
pesticides incl.
chlorinated phenols
(TriCP, TeCP and
PCP)
Solvent extraction and
cleaning up GC-MS // GC-ECD
// GC-ELCD
o-Phenylphenol
50
50
50
listed in Appendix P
(each)
LIMIT [mg/kg]
ITEM
A
B
Usage Ban //
Traces: 50
for each
Plasticizer
C
TEST METHOD
Usage Ban //
Traces:
Polyaromatic hydrocarbons (PAHs)
listed in Appendix Q
for sum of all PAHs 10
for Benzo(a)pyrene
-1
Polyvinylchloride
(PVC)
Usage ban for A and
B // not detected
Beilstein’s test / FTIR (Fourier
Transform Infrared)
Solvents
Usage ban in
auxiliaries with
exception of solvent
coating
N,N-Dimethylformamide (DMF)
(CAS 68-12-2)
Limits for solvent
coating:
50
50
50
N-Methylpyrrolidone (NMP)
(CAS 872-50-4)
10
10
100
Toluene
(CAS 108-88-3)
10
50
50
2-Ethoxyethylacetate
(CAS 111-15-9)
Usage Ban
2-Ethoxyethanol
(CAS 110-80-5)
Usage Ban
2-Methoxyethanol
(CAS 109-86-4)
Usage Ban
Page 8 of 29
Trichloroethylene
(CAS 79-01-6)
Usage Ban
LIMIT [mg/kg]
ITEM
A
B
C
TEST METHOD
Tin organic compounds
Monobutyltin compounds
Traces: 1.0
Monooctyltin compounds
Traces: 2.0
Dibutyltin compounds
Traces: 0.2
Dioctyltin compounds
Traces: 1.0
Tributyltin compounds
Usage ban
Triphenyltin compounds
Usage ban
Tetrabutyltin compounds
Usage ban
Tetraoctyltin compounds
Usage ban
Tricyclohexyltin compounds
Usage ban
Page 9 of 29
On the basis of DIN EN ISO
17353:2004
EXTRACTABLE HEAVY METAL(S)
METAL(S)
LIMIT [mg/kg]
A
B
C
TEST METHOD
Usage Ban as flame
retardant
in other cases:
for textiles and leather:
Extraction - DIN EN ISO 105E04-2009 (Acid sweat solution)
Antimony (Sb)
5
10
10
for non-metal parts other
than textiles and leather:
60
Usage Ban as biocide
// ICP
Extraction - EN 71-3 (Acid
solution) // ICP
in other cases:
Arsenic (As)
for non-metal parts
(textiles, leather and
others):
0.2
// ICP
Usage Ban
Cadmium (Cd)
for non-metal parts
others):
Traces: 0.1
Page 10 of 29
// ICP
METAL(S)
LIMIT [mg/kg]
A
B
C
for textiles:
// ICP
0.5
for metal complex dyed
textiles:
1.0
2.0
TEST METHOD
2.0
// ICP
for leather:
-
Chromium, total (Cr)
No regulation
for non-metal parts other
if products are covered with
a metal layer, including a
chromium layer, coating
must be constantly in good
condition
Extraction - EN 71-3 (Acid
solution) // ICP
60
Usage Ban
for non-metal parts others
than leather:
Chromium, VI
Detection Limit: 0.5
for leather:
Detection Limit: 3.0
1.0
Cobalt (Co)
textiles:
1.0
4.0
4.0
No regulation
Page 11 of 29
Extraction - DIN EN ISO
17075-2008
Extraction - DIN EN ISO
17075-2008
// ICP
// ICP
-
METAL(S)
LIMIT [mg/kg]
A
B
C
for textiles, leather and
metal complex dyed
textiles:
25
50
50
TEST METHOD
// ICP
Copper (Cu)
-
No regulation
Usage Ban
Lead (Pb)
Traces:
0.2
1.0
1.0
// ICP
Usage Ban
Mercury (Hg)
for non-metal parts
others):
Traces: 0.02
1.0
Nickel (Ni)
textiles:
1.0
Page 12 of 29
4.0
4.0
// ICP
// ICP
// ICP
HEAVY METAL(S) (TOTAL DIGESTION)
METAL(S)
LIMIT [mg/kg]
TEST METHOD
Usage Ban
for non-metal parts
others):
Total digestion – EN 11222001 // ICP
Total Cadmium (Cd)
Traces: 40
for metal parts:
Total digestion // ICP
Traces: 40
Usage Ban
Traces: 40
Total Lead (Pb)
for metal parts and nonmetal parts others than
textiles and leather:
Traces: 40
Page 13 of 29
HEAVY METAL(S) (RELEASE)
METAL(S)
LIMIT [mg/kg]
TEST METHOD
Usage Ban for active use
for metal parts and nonmetal parts others than
textiles and leather:
Nickel (Ni)
EN 1811-1998+A1-2008
(direct and prolonged skin contact)
in case of impurities –
maximum release of:
0.5 µg/cm²/week
Page 14 of 29
Release - EN 12472-2005 //
Part II: Appendix A to Q
No.
1
2
3
4
5
6
Appendix A: Asbestos
Actinolite
Amosite
Anthophyllite
Chrysotile
Crocidolite
Tremolite
CAS – No.
77536-66-4
12172-73-5
77536-67-5
12001-29-5
12001-28-4
77536-68-6
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Appendix B: Aryl amines
p-Aminoazobenzene
o-Aminoazotoluene
4-Aminobiphenyl
2-Amino-4-nitrotoluene
2-Anisidine
Benzidine
4-Chloroaniline
4-Chlor-2-toluidine
p-Cresidine
2,4-Diaminoanisole
4,4'-Diaminodiphenylmethane
2,4-Diaminotoluene
3,3'-Dichlorobenzidine
3,3'-Dimethoxybenzidine
3,3'-Dimethylbenzidine
3,3'-Dimethyl-4,4'-diaminodiphenylmethane
4,4'-Methylenebis(2-chloraniline)
2-Naphthylamine
4,4’-Oxydianiline
4,4’-Thiodianiline
2-Toluidine
2,4,5-Trimethylaniline
2,4-Xylidine
2,6-Xylidine
CAS – No.
60-09-3
97-56-3
92-67-1
99-55-8
90-04-0
92-87-5
106-47-8
95-69-2
120-71-8
615-05-4
101-77-9
95-80-7
91-94-1
119-90-4
119-93-7
838-88-0
101-14-4
91-59-8
101-80-4
139-65-1
95-53-4
137-17-7
95-68-1
87-62-7
No.
Appendix C: Boric acid and derivatives
1
Boric acid
2
Disodium tetraborate, anhydrous
3
4
Sodium perborate
Sodium perborate, anhydrous
Page 15 of 29
CAS – No.
10043-35-3 //
11113-50-1
1303-96-4 //
1330-43-4 //
12179-04-3
15120-21-5
7632-04-4
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
Appendix D: Chlorinated aromatic hydrocarbons
Monochlorobenzene
Dichlorobenzenes, all isomers
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Trichlorobenzenes, all isomers
1,2,3-Trichlorobenzene
Tetrachlorobenzenes, all isomers
1,2,3,4-Tetrachlorobenzene
Pentachlorobenzene
Hexachlorobenzene
Monochlorotoluenes, all isomers
2-Chlorotoluene
3-Chlorotoluene
4-Chlorotoluene
Dichlorotoluenes, all isomers
2,4-Dichlorotoluene
2,6-Dichlorotoluene
3,4-Dichlorotoluene
Trichlorotoluenes, all isomers
2,3,6-Trichlorotoluene
a,a,a-Trichlorotoluene
Tetrachlorotoluenes, all isomers
a,a,a,2-Tetrachlorotoluene
a,a,a,4-Tetrachlorotoluene
Pentachlorotoluene
CAS – No.
108-90-7
Several
95-50-1
541-73-1
106-46-7
Several
87-61-6
120-82-1
108-70-3
Several
634-66-2
634-90-2
95-94-3
608-93-5
118-74-1
Several
95-49-8
108-41-8
106-43-4
Several
95-73-8
118-69-4
95-75-0
Several
2077-46-5
98-07-7
Several
2136-89-2
5216-25-1
877-11-2
No.
1
2
3
4
5
6
7
8
9
10
Appendix E: Colourants with carcinogenic potential
Acid Red 26
Basic Red 9
Basic Violet 14
Direct Black 38
Direct Blue 6
Direct Red 28
Direct Yellow 1
Disperse Blue 1
Disperse Orange 11
Disperse Yellow 3
CAS – No.
3761-53-3
569-61-9
632-99-5
1937-37-7
2602-46-2
573-58-0
6472-91-9
2475-45-8
82-28-0
2832-40-8
No.
1
2
3
4
5
6
7
8
9
Appendix F: Colourants with allergenic potential
Disperse Blue 3
Disperse Blue 7
Disperse Blue 26
Disperse Blue 35
Disperse Blue 102
Disperse Blue 106
Disperse Blue 124
Disperse Brown 1
Disperse Orange 1
CAS – No.
2475-46-9
3179-90-6
3860-63-7
12222-75-2
12222-97-8
12223-01-7
61951-51-7
23355-64-8
2581-69-3
Page 16 of 29
No.
10
11
12
13
14
15
16
17
18
Appendix F: Colourants with allergenic potential
Disperse Orange 3
Disperse Orange 37/59/76
Disperse Red 1
Disperse Red 11
Disperse Red 17
Disperse Yellow 1
Disperse Yellow 9
Disperse Yellow 39
Disperse Yellow 49
No.
1
2
3
4
5
Appendix G: Colourants for other reasons
Disperse Yellow 23
Disperse Orange 149
Navy Blue
Pigment Yellow 34
Pigment Red 104
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
No.
1
2
3
4
Appendix H: Dioxins and Furans
Group 1:
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
2,3,7,8-Tetrachlorodibenzofuran
2,3,4,7,8-Pentachlorodibenzofuran
Group 2:
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
1,2,3,7,8-Pentachlorodibenzofuran
1,2,3,4,7,8-Hexachlorodibenzofuran
Group 3:
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
1,2,3,4,6,7,8-Heptachlorodibenzofuran
1,2,3,4,7,8,9-Heptachlorodibenzofuran
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
Group 4:
2,3,7,8-Tetrabromodibenzo-p-dioxin
1,2,3,7,8-Pentabromodibenzo-p-dioxin
2,3,7,8-Tetrabromodibenzofuran
2,3,4,7,8-Pentabromodibenzofuran
Group 5:
1,2,3,4,7,8-Hexabromodibenzo-p-dioxin
1,2,3,7,8-Pentabromodibenzofuran
Appendix I: Flame retardants
Bis(2,3-dibromopropyl)phosphate
Chlorinated paraffins, all chain lengths
Paraffin wax, chlorinated, C24
Paraffin, C10-C13, chlorinated (SCCP)
Page 17 of 29
CAS – No.
730-40-5
12223-33-5
2872-52-8
2872-48-2
3179-89-3
119-15-3
6373-73-5
12236-29-2
54824-37-2
CAS – No.
6250-23-3
85136-74-9
118685-33-9
1344-37-2
12656-85-8
CAS – No.
Several
1746-01-6
40321-76-4
51207-31-9
57117-31-4
Several
39227-28-6
57653-85-7
19408-74-3
57117-41-6
70648-26-9
57117-44-9
72918-21-9
60851-34-5
Several
35822-46-9
3268-87-9
67562-39-4
55673-89-7
39001-02-0
Several
50585-41-6
109333-34-8
67733-57-7
131166-92-2
Several
110999-44-5
110999-45-6
110999-46-7
107555-93-1
CAS – No.
5412-25-9
Several
63449-39-8
85535-84-8
No.
5
6
7
8
9
10
11
12
13
14
15
16
17
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
Appendix I: Flame retardants
Paraffin, C14-C17, chlorinated (MCCP)
Paraffin, C18-C28, chlorinated (LCCP)
Hexabromocyclododecan and all isomers
Tetrabromodiphenyl ether (TetraBDE)
Pentabromodiphenyl ether (PentaBDE)
Hexabromodiphenyl ether (HexaBDE)
Heptabromodiphenyl ether (HeptaBDE)
Octabromodiphenyl ether (OctaBDE)
Decabromodiphenyl ether (DecaBDE)
Tetrabromobisphenol A
Triethylenephosphoramide (TEPA)
Tris(chloroethyl)phosphate
Tris(2,3-dibromopropyl)phosphate (TRIS)
Appendix J: Fluorinated Greenhouse Gases
Sulphur hexafluoride – SF6
Perfluoromethane
Perfluoroethane
Perfluoropropane
Perfluorobutane
Perfluoropentane
Perfluorohexane
Perfluorocyclohexane
HFC-23
HFC-32
HFC-41
HFC-43-10mee
HFC-125
HFC-134
HFC-134a
HFC-152a
HFC-143
HFC-143a
HFC-227ea
HFC-236cb
HFC-236ea
HFC-236fa
HFC-245ca
HFC-245fa
HFC-365mfc
CAS – No.
85535-85-9
85535-86-0
25637-99-4
40088-47-9
32534-81-9
36483-60-0
68928-80-3
32536-52-0
1163-19-5
79-94-7
545-55-1
115-96-8
126-72-7
CAS – No.
2551-62-4
75-73-0
76-16-4
76-19-7
355-25-9
678-26-2
355-42-0
115-25-3
75-46-7
75-10-5
593-53-3
138495-42-8
354-33-6
359-35-3
811-97-2
75-37-6
430-66-0
420-46-2
431-89-0
677-56-5
431-63-0
690-39-1
679-86-7
460-73-1
406-58-6
No.
1
2
3
4
5
6
Appendix K: Halogenated Biphenyls, Terphenyls, Napthalenes
Polybrominated biphenyls
Polychlorinated biphenyls
Polybrominated terphenyls
Polychlorinated terphenyls
Polybrominated naphthalenes
Polychlorinated naphthalenes
CAS – No.
Several
Several
Several
Several
Several
Several
No.
1
2
3
Appendix L: Halogenated Diarylalkanes
Monomethyl-dibromo-diphenyl methane
Monomethyl-dichloro-diphenyl methane
Monomethyl-tetrachloro-diphenyl methane
CAS – No.
99688-47-8
81161-70-8
76253-60-6
Page 18 of 29
No.
1
2
3
4
5
6
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
Appendix M: Isocyanates
Diphenylmethane-4,4-diisocyanate (MDI)
Hexamethylene diisocyanate (HMDI)
Isophorone diisocyanate (IPDI)
Tetramethylxylene diisocyanate (TMXDI)
Toluene-2,4-diisocyanate (2,4-TDI)
Toluene-2,6-diisocyanate (2,6-TDI)
CAS – No.
101-68-8
822-06-0
4098-71-9
2778-42-9
584-84-9
91-08-7
Appendix N: Ozone Depleting Substances
Ozone-depleting substances (CFC’s) class I
Trichlorofluoromethane CFC-11
Dichlorofluoromethane CFC-12
1,1,2-Trichloro-1,2,2-trifluoroethane CFC-113
1,1,1-Trichloro-2,2,2-trifluoroethane CFC-113a
1,2-Dichloro-1,1,2,2-tetrafluoroethane CFC-114
1,1-Dichloro-1,2,2,2-tetrafluoroethane CFC-114a
Monochloropentafluoroethane CFC-115
Bromochlorodifluoroethane Halon-1211
Bromotrifluoromethane Halon-1301
Dibromotetrafluoroethane Halon-2402
Chlorotrifluoromethane CFC-13
Pentachlorofluoroethane CFC-111
1,1,2,2-Tetrachloro-1,2-difluoroethane CFC-112
1,1,1,2-Tetrachlorodifluoroethane CFC-112a
Heptachlorofluoropropane CFC-211
Hexachlorodifluoropropane CFC-212
Pentachlorotrifluoropropane CFC-213
Tetrachlorotetrafluoropropane CFC-214
1,1,3-Trichloropentafluoropropane CFC-215
Dichlorohexafluoropropane CFC-216
Monochloroheptafluoropropane CFC-217
Carbon tetrachloride CCl4
1,1,1-Trichloroethane (Methylchloroform)
Methylbromide (CH3Br)
Halon-1211
Halon-1301
Halon-2402
CHFBr2
CHF2Br
CH2FBr
C2HFBr4
C2HF2Br3
C2HF3Br2
C2HF4Br
C2H2FBr3
C2H2F2Br2
C2H2F3Br
C2H3FBr2
C2H3F2Br
C2H4FBr
CAS – No.
Several
75-69-4
75-71-8
76-13-1
354-58-5
76-14-2
374-07-2
76-15-3
353-59-3
75-63-8
124-73-2
75-72-9
354-56-3
76-12-0
76-11-9
422-78-6
3182-26-1
2354-06-5
29255-31-0
76-17-5
1652-81-9
4259-43-2
1599-41-3
661-97-2
422-86-6
56-23-5
71-55-6
74-83-9
Page 19 of 29
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
C3HFBr6
C3HF2Br5
C3HF3Br4
C3HF4Br3
C3HF5Br2
C3HF6Br
C3H2FBr5
C3H2F2Br4
C3H2F3Br3
C3H2F4Br2
C3H2F5Br
C3H3FBr4
C3H3F2Br3
C3H3F3Br2
C3H3F4Br
C3H4FBr3
C3H4F2Br2
C3H4F3Br
C3H5FBr2
C3H5F2Br
C3H6FBr
Chlorobromomethane CH2BrCl
Ozone-depleting substances (CFC’s) class II
Dichlorofluoromethane HCFC-21
Monochlorodifluoromethane HCFC-22
Monochlorofluoromethane HCFC-31
Tetrachlorofluoroethane HCFC-121
Trichlorodifluoroethane HCFC-122
Dichlorotrifluoroethane HCFC-123
Monochlorotetrafluoroethane HCFC-124
Trichlorofluoroethane HCFC-131
Dichlorodifluoroethane HCFC-132
Monochlorotrifluoroethane HCFC-133a
HCFC-141
Dichlorofluoroethane HCFC-141b
HCFC-142
Monochlorodifluoroethane HCFC-142b
HCFC-151
Hexachlorofluoropropane HCFC-221
Pentachlorodifluoropropane HCFC-222
Tetrachlorotrifluoropropane HCFC-223
Trichlorotetrafluoropropane HCFC-224
HCFC-225
Dichloropentafluoropropane HCFC-225ca
Dichloropentafluoropropane HCFC-225cb
Monochlorohexafluoropropane HCFC-226
Pentachlorofluoropropane HCFC-231
Tetrachlorodifluoropropane HCFC-232
Trichlorotrifluoropropane HCFC-233
Dichlorotetrafluoropropane HCFC-234
Monochloropentafluoropropane HCFC-235
Tetrachlorofluoropropane HCFC-241
Trichlorodifluoropropane HCFC-242
Dichlorotrifluoropropane HCFC-243
Page 20 of 29
Several
75-43-4
75-45-6
593-70-4
354-14-3
354-21-2
306-83-2
2837-89-0
359-28-4
1649-08-7
75-88-7
1717-00-6
75-68-3
422-26-4
422-49-1
422-52-6
422-54-8
422-56-0
507-55-1
431-87-8
421-94-3
460-89-9
7125-84-0
425-94-5
460-92-4
666-27-3
460-63-9
460-69-5
97
98
99
100
101
102
103
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
Monochlorotetrafluoropropane HCFC-244
Monochlorotetrafluoropropane HCFC-251
Dichlorodifluoropropane HCFC-252
Monochlorotrifluoropropane HCFC-253
Dichlorofluoropropane HCFC-261
Monochlorodifluoropropane HCFC-262
Monochlorofluoropropane HCFC-271
Appendix O: Pesticides
Aldrine
Azinphos methyl
Azinphos ethyl
Bromophos-ethyl
Captafol
Carbaryl
Chlordane
Chlordecone
Chlordimeform
Chlorfenvinphos
Coumaphos
Cyfluthrin
Cyhalothrin, λCypermethrin
Deltamethrin
Diazinon
o,p'-Dichlorodiphenyldichloroethane (o,p'-DDD)
p,p'-Dichlorodiphenyldichloroethane (p,p'-DDD)
o,p'-Dichlorodiphenyldichloroethylene (o,p'-DDE)
p,p'-Dichlorodiphenyldichloroethylene (p,p'-DDE)
o,p'-Dichlorodiphenyltrichloroethane (o,p'-DDT) and its isomers;
preparations containing DDT and its isomers
p,p'-Dichlorodiphenyltrichloroethane (p,p'-DDT) and its isomers;
preparations containing DDT and its isomers
2,4-Dichlorophenoxyacetic acid, its salts and compounds
Dichlorprop
Dicrotophos
Dieldrine
Dimethoate
Dinoseb and salts
Endosulfan, αEndosulfan, βEndrine
Esfenvalerate
Fenvalerate
Heptachlor
Heptachlor epoxide
Hexachlorobenzene
Hexachlorocyclohexane (HCH), all isomers
Isodrin
Kelevane
Lindane
Malathion
MCPA
MCPB
Mecoprop
Page 21 of 29
134190-50-4
421-41-0
819-00-1
460-35-5
420-97-3
421-02-3
430-55-7
CAS – No.
309-00-2
86-50-0
2642-71-9
4824-78-6
2425-06-1
63-25-2
57-74-9
143-50-0
6164-98-3
470-90-6
56-72-4
68359-37-5
91465-08-6
52315-07-8
52918-63-5
333-41-5
53-19-0
72-54-8
3424-82-6
72-55-9
789-02-6
50-29-3
94-75-7
120-36-2
141-66-2
60-57-1
60-51-5
88-85-7
959-98-8
33213-65-9
72-20-8
66230-04-4
51630-58-1
76-44-8
1024-57-3
118-74-1
608-73-1
465-73-6
4234-79-1
58-89-9
121-75-5
94-74-6
94-81-5
93-65-2
No.
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
Appendix O: Pesticides
Methamidophos
Methoxychlor
Methyl parathion
Mevinophos
Mirex
Monocrotophos
Ethyl parathion
Perthane
Profenophos
Propetamphos
Quinalphos
Strobane
Telodrin
Toxaphene
Tribufos (DEF)
2,4,5-Trichlorophenoxyacetic acid, salts and compounds
Trifluralin
CAS – No.
10265-92-6
72-43-5
298-00-0
7786-34-7
2385-85-5
6923-22-4
56-38-2
72-56-0
41198-08-7
31218-83-4
13593-03-8
8001-50-1
297-78-9
8001-35-2
78-48-8
93-76-5
1582-09-8
No.
1
2
3
4
5
Appendix P: Plasticizer
Butylbenzyl phthalate (BBP)
Dibutyl phthalate (DBP)
Diethylhexyl phthalate (DEHP)
Diisobutyl phthalate (DIBP)
CAS – No.
85-68-7
84-74-2
117-81-7
84-69-5
26761-40-0
68515-49-1
28553-12-0
68515-48-0
131-11-3
84-75-3
117-84-0
71888-89-6
6
7
8
9
10
11
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
Diisodecyl phthalate (DIDP)
Diisononyl phthalate (DINP)
Dimethyl phthalate (DMP)
Di-n-hexy phthalate (DNHP)
Di-n-octyl phthalate (DNOP)
1,2-Benzenedicarboxylic acid, di-C6-8-branched alkyl esters, C7-rich
(DIHP)
1,2-Benzenedicarboxylic acid, di-C7-11-branched and linear alkyl
esters (DHNUP)
Appendix Q: Polyaromatic Hydrocarbons (PAHs)
Naphtalene
Acenaphtylene
Acenaphthene
Fluorene
Phenathrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Indeno(1,2,3-cd)pyrene
Dibenzo(a,h)anthracene
Benzo(ghi)perylene
Benzo(e)pyrene
Page 22 of 29
68515-42-4
CAS – No.
91-20-3
208-96-8
83-32-9
86-73-7
85-01-8
120-12-7
206-44-0
129-00-0
56-55-3
218-01-9
205-99-2
207-08-9
50-32-8
193-39-5
53-70-3
191-24-2
192-97-2
No.
18
Appendix Q: Polyaromatic Hydrocarbons (PAHs)
Benzo(j)fluoranthene
Page 23 of 29
CAS – No.
205-82-3
Edition 3.2 - Annex I
Usage ranges
Three usage ranges (A, B, C) are defined with A being the most stringent
category concerning textile limit values and number of banned substances.
Dermal exposure (exposure to human skin) serves as the main allocation
principle to the three usage ranges – see the following bullet points. Besides
other aspects, the migration rate and lower body weight for babies are the most
important parameters for the allocation based on dermal exposure.
-
A:
next to skin use and baby (0 to 3 years)
-
B:
occasional skin contact
-
C:
no skin contact
Other exposure routes override this allocation if the need for a more stringent
classification results from the respective usage situation.
Note:
A garment is in any case at least usage range B if not wearing properties and
expected consumer behaviour require a classification in usage range A.
Page 24 of 29
Allocations
The following table shows an allocation of various textile goods to the three
usage ranges.
Usage
range
A
Textile good
Automotive door cover
Automotive roof liner
Automotive seat fabric
Baby nappy/diaper
Baby textile articles (all non-clothing textile articles
intended for baby use/contact)
Baby textile toys
Baby wear (0 – 3 years)
Backpack body-face of shoulder straps
Backpack main fabric
Beanie
Bed linen
Bike shorts
Blouse
Bra
Cap
Car seat
Carpet
Cleaning cloth
Curtain
Dish-/kitchen towel
Dress
Furnishing fabric
Filling for Sleeping bag or Jacket
Geotextiles (e.g. building-/constructive textiles, erosion
protection, etc.)
Gloves/Mittens
Hammock (main fabric)
Hard-shell-jacket
Harness
Hat
Headdress
Label
Leggings
Long sleeve T-Shirt
Medical-/hygiene textiles (e.g. bandages, wound dressing,
tampons, etc.)
Mosquito net
Page 25 of 29
Usage
range
B
Usage
range
C
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
Usage
range
A
Textile good
Pants
Pullover
Rain pants
Ropes & Slings
Scarf
Sewing thread
Shirt
Shoes lining
Shoes outer fabric
Skirt
Sleeping bag lining
Sleeping bag filling
Sleeping bag outer fabric
Sleeping Mattress
Socks
Soft-shell-jacket
Sport shirt
Sweatshirt
Tag (e.g. washing instructions)
Tent floor
Tent fly
Tent other parts
Therapeutical-/Health textiles (e.g. support-stockings and bandages, girdle, etc.)
Tie
Tights
Towel
T-Shirt
Underpants (long/short)
Undershirt
Wristband
Zippers (all parts)
Page 26 of 29
Usage
range
B
Usage
range
C
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
Edition 3.2 - Annex II
Recommendations for testing
Test Item
Textiles
and fabric
from
natural
fibres
Textiles
and fabric
from
synthetic
fibres
Printing /
Coating
Leather
pH Value
Plastics and
other synthetic
materials - PU,
PVC, Rubber,
TPU, TPR, EVA,
etc
Metal
parts
–
–
Odour
–
Colour Fastness Properties
Property to perspiration
–
Colour fastness to saliva and
perspiration
–
–
Extractable Heavy Metals
Antimony
–
Arsenic
Cadmium
Chromium, total
–
–
–
–
Wool
Other
–
PA
Other
–
–
Chromium VI
–
Cobalt
–
Copper
–
Lead
Mercury
–
Nickel
–
Heavy Metals (total digestion)
Total Lead
Total Cadmium
Heavy Metals (release)
Nickel
–
–
–
–
–
Asbestos
–
–
–
–
–
Alkylphenols and
Alkylphenolethoxylates
[OP, NP, OPEO, NPEO]
–
Arylamines [24 items]
–
Bisphenol A
–
–
Page 27 of 29
–
–
Boric acid and derivatives
Chlorinated aromatic
Hydrocarbons (carriers)
–
–
–
–
–
Plastics and
other synthetic
materials - PU,
PVC, Rubber,
TPU, TPR, EVA,
etc
Metal
parts
–
–
[with carcinogenic potential]
–
–
[with allergenous potential]
–
–
[banned for other reasons]
–
–
Test Item
Textiles
and fabric
from
natural
fibres
Textiles
and fabric
from
synthetic
fibres
Printing /
Coating
Leather
Chlorinated Phenols [TriCP,
TeCP, PCP]
Colourants
Dimethylfumarate (material
with direct skin contact is
required if the product is
packaged with any form of antimold agent)
Dioxins and Furans
(according 76/769/EC) [25
items]
–
–
–
–
Flame Retardants
[TRIS, TEPA, TetraBDE,
PentaBDE, HexaBDE,
HeptaBDE, OctaBDE, Deca
BDE, Bis(2,3dibromopropyl)-phosphate,
HBCDD,
Tris(chloroethyl)phosphate,
Tetrabrombisphenol A,
Chlorinated paraffins, all
chain lengths incl. SCCP]
(Required if sample declared
with functional finishing)
Fluorinated Greenhouse
Gases (according to
2006/842/EC)
–
–
–
–
–
–
–
–
–
Formaldehyde
–
Halogenated Biphenyls,
Terphenyls and
Naphthalenes
–
Isocyanates
[MDI, HMDI, IPDI, TMXDI, 2,4TDI, 2,6-TDI etc]
(Required for PU and for
relevant functional finishes)
PU
Monomers
[Acrylamide]
Page 28 of 29
–
–
Halogenated Diarylalkanes
Ozone Depleting Substances
–
–
–
PU
–
–
–
–
–
–
–
–
–
Plastics and
other synthetic
materials - PU,
PVC, Rubber,
TPU, TPR, EVA,
etc
Metal
parts
Perfluorooctane sulfonates
(PFOS)
(required if sample declared
with stain/water repellent
finishing)
–
–
Perfluorocarboxylic acid and
salts [PFHxA, PFOA]
(required if sample declared
with stain/water repellent
finishing)
–
–
–
–
–
–
Test Item
Textiles
and fabric
from
natural
fibres
Pesticides
Textiles
and fabric
from
synthetic
fibres
–
Printing /
Coating
Leather
–
o-Phenylphenol
Plasticizer
[BBP, DBP, DEHP, DIBP, DIDP,
DINP, DMP, DNHP, DNOP,
DIHP, DHNUP]
–
–
–
–
Polyaromatic Hydrocarbons
(PAHs) incl. Benzo(a)pyrene
–
–
–
–
Polyvinylchloride (PVC)
–
–
–
–
–
–
Solvents
N,N-Dimethylformamide
[DMF]
1
N-Methylpyrrolidone [NMP]
–
–
Toluene
1
–
2-Ethoxyethylacetate
–
2-Ethoxyethanol
–
2-Methoxyethanol
–
Trichloroethylene
–
Tin Organic Compounds
[MBT, MOT, DBT, DOT, TriBT,
TriPhT, TeBT, TeOT, TricycloHT]
1
Footnotes:
Testing strongly recommended
Testing recommended
–
Substances or group of substances with high probability not relevant
1
only when finishing of leather involves coating with solvents
Page 29 of 29
–

03 VAUDE_RSL_March_2013

Transcription

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