Institut für Photonik Technische Universität Wien
Transcription
Institut für Photonik Technische Universität Wien
Proceedings of the 3rd International Conference on the Frontiers of Plasma Physics and Technology (PC/5099) S6-3 Laser Plasma-Initiated Ignition of Engines E. Wintner Photonics Institute Vienna University of Technology Vienna, Austria 3rd Int. Conference on the Frontiers of Plasma Physics and Technology Bangkok, March 5-9, 2007 Institut für Photonik Technische Universität Wien Megawatt gas engine Institut für Photonik Technische Universität Wien Spark voltage vs BMEP spark voltage [kV] 30 250 mg NOx/Nm3 25 20 15 500 mg NOx/Nm3 10 5 0 1 2 BMEP [MPa] Institut für Photonik Technische Universität Wien 3 Potential future ignition systems • Plasma Ignition • High Frequency Ignition • Auto Ignition • Laser Ignition • Pressure Wave Ignition • Diesel Pilot Ignition • …. Institut für Photonik Technische Universität Wien 1st Application: gas engine Production of electricity and heat Æ overall efficiency up to 90 % • Lean mixture • High ignition pressures Æ limited lifetime of the spark plug through electrode erosion • High costs of the ignition system GE Jenbacher Institut für Photonik Technische Universität Wien NOx emission potentials NOX [mg/Nm³] 350 330 300 250 250 240 190 200 150 100 70 50 0 direct pre chamber laser ignition spark ignition Institut für Photonik Technische Universität Wien direct pre chamber diesel pilot ignition Source: GE Jenbacher GmbH & Co OHG 2nd Application: spray-guided combustion Institut für Photonik Technische Universität Wien Goals of this work Design and Construction of a Laser Ignition System • Laser Spark Plug • Pump Beam Multiplexing System • Beam shaping and fiber coupling of the diode laser Institut für Photonik Technische Universität Wien Overview • • • • • • Introduction Principle of laser ignition Realized goals of this work Experimental Remaining questions Fiber transmission of ns optical pulses • Laser development • In-coupling window aspects • Conclusions Institut für Photonik Technische Universität Wien Introduction on laser ignition • Historical J.D. Dale, P.R. Smy, R.M. Clements: Laser-ignited internal combustion engine – an experimental study; SAE Congress, paper 780329, Detroit (1978) by CO2 laser! • Objectives Reliable and efficient ignition with clean exhaust of gas engines (lean burn internal combustion engines) automotive engines (in HCCI mode - homogeneous charge compressed ignition) Institut für Photonik Technische Universität Wien Advantages of laser ignition Free choice of position of ignition point in the cylinder Avoids detrementous quenching effects at electrodes and metal cylinder surfaces Low maintenance efforts when applying diode-pumped solid-state lasers Possibility of ignition of very lean gas mixtures Improvement of timing jitter in HCCI mode substantial reduction of NOx emissions possible! Institut für Photonik Technische Universität Wien Principle of laser ignition convex lens laser beam focused laser beam plasma I>Ithreshold flame kernel E>Eignition mixture burning Institut für Photonik Technische Universität Wien Effects leading to non-resonant breakdown • Electron cascade growth needs initial electrons • multiphoton ionization • electron tunnelling (relevant only at intensities higher than 1014 W/cm2) Institut für Photonik Technische Universität Wien laser energy absorption by impurities in the gas Plasma formation by a focused beam through a sapphire plate Institut für Photonik Technische Universität Wien Spatial and temporal development of a laser-induced plasma Comparing UV emission at 2 pulse energies: left at plasma threshold and right far above Institut für Photonik Technische Universität Wien Experimental setup Measurement of the plasma light emission at 310nm laser beam 150 mm planoconvex lens Camera gate time = 3ns Unseeded Nd:YAG-Laser: 1064nm, 12ns, flat top spatial profile air, atmospheric pressure Institut für Photonik Technische Universität Wien 0 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 20 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 40 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 60 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 80 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 100 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 120 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 140 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 160 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 165 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 170 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 175 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 180 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 185 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 190 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 195 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 200 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 205 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm 210 ns after rising edge of laser pulse pulse energy = 47 mJ 1cm Institut für Photonik Technische Universität Wien pulse energy = 235 mJ 1cm Minimum ignition energy U. Maas/B. Lewis 10 ignition energy [mJ] 2.7 current limit in the combustion vessel propane 1 methane 0,1 H2 0,01 0 0,5 Institut für Photonik Technische Universität Wien 1 1,5 2 A/F-ratio 2,5 3 3,5 4 Combustion chamber net volume = 1.2 dm3 maximum permissible pressure = 300 bar stabilized at 70 °C, 200 °C and 400 °C Institut für Photonik Technische Universität Wien sapphire (lens) windows of 13 mm clear aperture for longitudinal and transversal transmission Experimental setup Institut für Photonik Technische Universität Wien Selected experimental laser systems Q-switched Nd:YAG Laser pulse duration = 6ns wavelengths: 1064 nm, 532 nm, 355 nm beam quality parameter M2=1.8 and later M2=1.1 Institut für Photonik Technische Universität Wien Plasma formation in different gaseous media air N2 methane NO PLASMA N2 1,0 Intensität[1012 W/cm²] 0,8 0,6 10 bar 0,4 0,2 0,0 0 5 10 Zeit [ns] Institut für Photonik Technische Universität Wien 15 20 Transmitted beam intensity at T = 293 K, prel = 10 bar Realized goals by combustion chamber experiments Determination of plasma threshold intensity and minimum laser pulse energy for ignition (MPE) of several fuel gas –air mixtures and mixtures depending on – – – – – methane-air hydrogen-air hydrogen-methane-air biogas isooctane Minimum ignition energy (MIE) not important for practical considerations, however for comparison with theory Institut für Photonik Technische Universität Wien Realized goals by combustion chamber experiments Determination and optimization of – laser wavelength (1064 nm, 532 nm, 355 nm) – focusing optics – MPE dependance on fill pressure (≤4 MPa) – MPE dependance on gas-air equivalence ratio L (especially lean side limit) – MPE dependance on temperature Institut für Photonik Technische Universität Wien Focus intensity for plasma formation vs. pressure 2,0 12 threshold intensity [10 W/cm²] 2,5 1,5 1,0 0,5 0,0 0 5 10 15 20 25 relative pressure [bar] Institut für Photonik Technische Universität Wien 30 Pplasma > 99%, T = 293 K, air Influence of pressure and temperature on plasma formation Plasma Durchbruchsenergie [mJ] 2,5 350 °C 50°C 100°C 150°C 200°C 250°C 50 °C 300°C 350°C 2,0 1,5 1,0 0,5 0,0 0 10 20 Zünddruck [bar] start pressure at ignition Institut für Photonik Technische Universität Wien 30 40 Mininimum pulse energy vs. excess air ratio Λ MPE [mJ] Methane-air, T=473 K, p=30 bar 38 36 34 32 30 28 26 24 22 20 18 16 14 12 10 8 6 4 2 0 1,0 1,2 +/- 0,05 λ Institut für Photonik Technische Universität Wien 1,4 1,6 1,8 λ +/- 0,1 2,0 2,2 2,4 +/- 0,12 Combustion pressure versus time at different Λ excess pressure [bar] (+30 bar) 100 Methane-air, T=473 K, p=30 bar λ=1.73 +/- 0,1 λ=1,88 λ=2,0 λ=2,11 λ=2,3 λ=2,4 +/- 0,12 80 60 40 20 0 0 1000 2000 time [ms] Institut für Photonik Technische Universität Wien 3000 4000 5000 40 40 35 35 30 30 25 20 pinit (bar) pinit (bar) Direct comparison laser ignition – spark plug ignition 25 20 15 15 10 1,40 1,50 1,60 1,70 1,80 1,90 2,00 2,10 2,20 2,30 A/Frel ( ) 0,00 ignition reliability of laser ignition 0,25 0,50 0,75 1,00 10 1,40 1,50 1,60 1,70 1,80 1,90 2,00 2,10 2,20 2,30 A/Frel ( ) 0,00 ignition reliability of spark plug ignition 0,25 0,50 0,75 1,00 Combustion chamber of constant volume; methane-air, Tgas = 200°C; A/Frel =1.77 on the engine for reliable run, maximum BMEP = 19 bar, typical spark duration = 400 – 500 µs; laser M2 < 1.2; laser pulse energy constant 25 mJ well above the plasma breakdown threshold for all conditions, overall ignition attempts: 1201 for spark plug, 642 for laser; Institut für Photonik Technische Universität Wien Plasma and flame kernel diagnostics Schlieren Institut für Photonik Technische Universität Wien Schlieren PLIF Laser ignition – first engine test Institut für Photonik Technische Universität Wien first engine test 08.2000 Laser ignition of lean fuel-air mixtures Problem: • slow flame front propagation Countermeasures: • higher laser energy: undesirable • turbulence already realized in engines • multipoint ignition • addition of hydrogen • “self-ignition“ of the whole volume, improved by laser-initiation Institut für Photonik Technische Universität Wien Approach for multipoint ignition laser fiber sapphire window diffraction grating coupling optics ignition optics Institut für Photonik Technische Universität Wien piston Laser ignition Heat release - single point / multipoint 7 6 dQB [%/°CA] ROHR laser multi point ignition 5 4 ROHR spark ignition 3 2 1 0 -40 -20 0 20 crank angle [CA°] Institut für Photonik Technische Universität Wien 40 60 80 Increase of flame velocity by hydrogen addition % hydrogen replacing methane indicated Institut für Photonik Technische Universität Wien First demo of laser-triggered HCCI Influence of laser plasma on HCCI combustion; weak color: without plasma, intense color: laser plasma at 40° BTDC; A/Frel = 2.3, 90% methane, 10% isooctane. Institut für Photonik Technische Universität Wien First demo of laser-triggered HCCI Laser-stabilized HCCI engine operation at reduced inlet temperature fades away after plasma is turned off (zero value for CA50: no combustion at all; CA50: crank angle at 50% burn point; A/Frel = 2.04, 90% methane, 10% isooctane, plasma at 25° BTDC) Institut für Photonik Technische Universität Wien Remaining questions • Propagation of pulsed radiation via optical fibers • Choice of a compact, robust and economic laser source • Durability of windows Institut für Photonik Technische Universität Wien Various fibers tested • Step index fibers with diameter 100 to 1000 um • Hollow core dielectric capillaries • Hollow glass fibers with cyclic olefin polymer coated silver [1] • Hollow-core photonic crystal fibers, preliminary experiments [2] [1] Cooperation with M. Miyagi, Tohoku University, Sendai, Japan [2] Cooperation with A.M. Zheltikov, Lomonosov Moscow State University, Moscow, Russia; S.O. Konorov et al., J. Phys. D: Appl. Phys. 36 (2003) 1-7 Institut für Photonik Technische Universität Wien Problems encountered with optical fibers The high power of Q-switched laser pulses easily can destroy optical media Countermeasures: •Thick step index fibers: only diameters > 300 µm allowed reliable propagation of the pulses •Hollow capillaries or fibers do not contain solid-state matter within the core Institut für Photonik Technische Universität Wien Beam quality of fiber output Great emphasis was put on high laser beam quality when aiming towards lowest pulse energies for ignition: M2 = 1.1 In all cases of fibers except photonic crystal fiber the output beam quality was M2 ca. 30-50 Institut für Photonik Technische Universität Wien Overview of photonic crystal fibres (PCFs) • are optical fibers that employ a microstructured arrangement of low index material in a background material of higher refractive index. • The backgrond material is undoped silica and the low index region is typically provided by air voids running along the length of the fiber. Institut für Photonik Technische Universität Wien Types of PCF • High index guiding fibres based on modified total internal reflection principle. • Low index guiding fibres based on the Photonic Band Gap (PBG) effect. „The bandgap effect can be found in nature where bright colours that are seen in the butterfly wings are the results of naturally occuring periodic microstructures“. Institut für Photonik Technische Universität Wien Photonic band gap fiber used 2-dimensionally periodic cladding, 5 µm periodicity, 14 µm core diameter, air-filled or evacuated, several passbands, e.g. around 1 µm (Cooperation with Blaze Photonics, Bath, UK) Institut für Photonik Technische Universität Wien Experimental setup Q-Switched Laser Focusing lens f=75mm CCD Camera and/or Energy Detector Collimating lens f=75mm OSC Vacuum Chamber Institut für Photonik Technische Universität Wien Relation between pressure and laser energy for breakdown Institut für Photonik Technische Universität Wien Output from the fiber Institut für Photonik Technische Universität Wien Experimental results on evacuated PCFs Evacuation below 10 mbar allows to propagate up to 600 µJ of 1064 nm ns pulses in single mode shape. Peak intensity >1012 W/cm2 (i.e. ca. 1000 x higher than destruction limit of silica! Care has to be taken when coupling in to avoid destruction of fiber walls. Problem: high coupling loss (80%), propagation loss <0.1 dB/m, recently solved: only 16 % loss; Maximum throughput: 0.6 mJ, still not enough Institut für Photonik Technische Universität Wien Mininimum pulse energy vs. excess air ratio λ for 3 temperatures Allow to define the requirements on the ignition laser MPE [mJ] • < 5ns pulse duration • > 10mJ Pulse energy • Stable against mechanical & thermal stress 20 30 bar 16 12 8 150°C 275°C 400°C 4 0 1,2 Institut für Photonik Technische Universität Wien 1,6 2,0 2,4 λ [−] 2,8 3,2 Prototype: specially designed laser Institut für Photonik Technische Universität Wien Developed scheme of laser ignition Institut für Photonik Technische Universität Wien Laser setup Institut für Photonik Technische Universität Wien Experimental setup for self-developed laser Fiber-coupled, longitudinally diode-pumped, passively Q-switched solid-state laser A schematic view 1: Laser Diode Fiber 4: Passive Q-Switch Cr4+:YAG 2: Collimating Lens 5: Output Coupler 3: Nd:YAG + Input Coupler Institut für Photonik Technische Universität Wien Experimental setup In the laboratory Institut für Photonik Technische Universität Wien Laser spark plug : preliminary design Institut für Photonik Technische Universität Wien Experimental results Dependence (70 W diode) Institut für Photonik Technische Universität Wien of: -- Pulse duration (left) and -- Pulse energy (right) on: -- Reflectivity of output mirror and -- Initial transmission of Q-Switch Experimental results Dependence (300 W Diode) Institut für Photonik Technische Universität Wien of: -- Pulse jitter (left) and -- Pulse energy and wasted energy (right) on: -- Pump duration Experimental results Dependence of: (300 W diode) -- Pulse duration -- Plasma transmission (f = 7.5 mm, E = 1.7 mJ) on: -- Resonator length Institut für Photonik Technische Universität Wien Experimental results Typical beam profiles (300 W diode) Energy E = 6 mJ Energy E = 10 mJ Pulse duration t = 1 ns Pulse duration t = 1.5 ns Institut für Photonik Technische Universität Wien Simulation results Energy distribution - Reflectivity output mirror R=50% - Reflectivity output mirror R=50% - Initial transmission Q-switch I0=40% - Initial transmission Q-switch I0=90% Institut für Photonik Technische Universität Wien Depositions – window temperature Institut für Photonik Technische Universität Wien Laser-induced depositions beam profile Institut für Photonik Technische Universität Wien Laserbeschichtungseffekt: Suprasil Suprasilfenster Suprasil window 6 5 Abbrennen der Ablagerungen 4 3 Bereich des Laserbeschichtungseffektes Laserenergiedichte ED [mJ/mm²] Suprasil 2 1 0 0 5 10 15 Einsatzzeit [h] Institut für Photonik Technische Universität Wien 20 kein Laserbeschichtungseffekt 25 Laserbeschichtungseffekt: SaphirfensterSaphir 5 4 Abbrennen der Ablagerungen 3 Bereich des Laserbeschichtungseffektes Laserenergiedichte ED [mJ/mm²] Saphir Sapphire window 2 vom heißen Brenngas umspültes Linsenfenster (LF blieb sauber) 1 0 0 5 10 Einsatzzeit [h] Institut für Photonik Technische Universität Wien kein Laserbeschichtungseffekt 15 Focusing optics Lens window Ignit ion Plasma Focal lenght Cylinderhead Pist on combined optics (lens-window) Institut für Photonik Technische Universität Wien separate optics Conclusions I Using optimized (aspheric) focusing optics and laser beams of near Gaussian characteristics can Æ minimize the minimum laser pulse energy needed for ignition (MPE) of stoichiometric mixtures down to sub-mJ levels having also been realized in engine operation. Æ The lean side limit for methane-air mixtures for reliable laser ignition was determined as λ = 2.1 (as opposed to spark ignition up to λ = 1.7); for hydrogen-air mixtures even up to λ = 7. Institut für Photonik Technische Universität Wien Conclusions II Fiber delivery represents one of the most critical aspects of laser ignition. As seen from now, only the Æ hollow-core photonic band gap fiber represents an option for transportation of Q-switched laser pulses. It seems more realistic to equip every cylinder with its Æ own laser source which has to be much cheaper than the ones available today. A compact diode-pumped, passively Q-switched Æ Nd:YAG laser has been developed, delivering Ep >10 mJ in τp = 1.5 ns which can potentially be implemented in a laser spark plug. Institut für Photonik Technische Universität Wien Financed by GE Jenbacher GmbH & Co OHG and FFF Austrian Industrial Development Fund Institut für Photonik Technische Universität Wien Coworkers and Collaborators Gabor Ast Soren Charareh Alexander Dozenko Reinhard Gilber Herbert Kopecek Harald Maier Georg Reider Anfisa Stachiv Bernhard Schwecherl Martin Tesch Martin Weinrotter Photonics Institute Christian Forsich Maximilian Lackner Gerhard Totschnig Franz Winter Institute of Chemical Engineering Kurt Iskra Theo Neger Harald Rüdisser Institute of Experimental Physics, Graz University of Technology Institut für Photonik Technische Universität Wien Cooperations Martin Frenz Heinz Weber Jaroslav Bobitski Alexander Manenkov Alexei Zheltikov M. Miyagi Blaze Photonics Bernhard Geringer Institut für Photonik Technische Universität Wien Institute for Applied Physics, Bern University Lvivska Politechnika A. Prokhorov General Physics Institute, Moscow Moscow State University Tohoku University, Sendai, Japan Bath, UK Institute of Internal Combustion Engines, Vienna University of Technology Thank you for your attention! Institut für Photonik Technische Universität Wien