Bestandsaufnahme und Empfehlungen - Schleswig
Transcription
Bestandsaufnahme und Empfehlungen - Schleswig
Bund/Länder-Messprogramm für die Meeresumwelt von Nord- und Ostsee Munitionsbelastung der deutschen Meeresgewässer – Bestandsaufnahme und Empfehlungen (Stand 2011) Claus Böttcher, Tobias Knobloch, Niels-Peter Rühl, Jens Sternheim, Uwe Wichert, Joachim Wöhler 10.4.2.5 G. Carton & A. Jagusiewicz - Historic Disposal of Munitions in U.S. and European Coastal Waters, How Historic Information Can be Used in Characterizing and Managing Risk Dieser Anhang des Ergebnisberichts erscheint an dieser Stelle mit freundlicher Genehmigung des Marine Technology Society Journal. www.munition-im-meer.de PAPER Historic Disposal of Munitions in U.S. and European Coastal Waters, How Historic Information Can be Used in Characterizing and Managing Risk AUTHORS ABSTRACT Geoffrey Carton CALIBRE Systems, Inc. Sea disposal of wastes from industry and government was accepted internationally as a safe and efficient practice until the 1970s. Options available for addressing excess, obsolete, and unserviceable munitions prior to the 1970s were limited to salvage, destruction by open detonation or open burning, or burial on land or at sea. Sea disposal of conventional and chemical munitions and other waste material was considered appropriate until the enactment of the Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter in 1972 and its 1996 Protocol prohibiting sea disposal of chemical and biological agents. The 1993 Chemical Weapons Convention contains a similar ban. Seadisposed munitions pose two types of risk. These are acute—injury or death caused by either detonation or direct exposure to chemical agents—and chronic—adverse health impacts resulting from prolonged exposure to munition constituents. The type and configuration of sea-disposed munitions, disposal location, water body properties (e.g., depth, current), and its usage (e.g., commercial fishing, recreation, pipeline construction) are factors in determining the relative risk posed by munitions. The collection, analysis, and sharing of historical information allow more efficient investigation and management of risks from sea-disposed munitions. Andrzej Jagusiewicz Chief Inspector of Environmental Protection, Poland 1. Introduction S ea disposal of munitions was an internationally accepted practice used from at least the late 1800s through the 1970s. Historic sea disposal of munitions is an emotionally charged subject of global concern because disposals have occurred in most oceans and major seas. Sea disposal of chemical munitions or bulk containers of chemical agents1 (referred to as chemical warfare material (CWM))2 affects as many as 40 countries, and many others are affected by sea disposal of conventional munitions. Expanding use of marine resources 1 A chemical compound that produces lethal or other damaging effects on human beings and is intended for use in military operations through its physiological effects. 2 Items generally configured as a munition containing a chemical compound that is intended to kill, seriously injure, or incapacitate a person. CWM does not include riot control devices; defoliants and herbicides; industrial chemicals not configured as a munition; smoke and other obscuration producing items; flame and incendiary producing items; or media contaminated with low concentrations of chemical agents where no chemical agent hazards exist. 16 drives a need to better understand and manage risks to human health and the environment posed by the munitions and released munitions constituents3. This paper’s premise is that the aggressive investigation, collection, analysis, and sharing of historical information increase the efficient and effective assessment of risks and their management. 3 Munition constituents are materials originating from military munitions, including explosive and non-explosive materials, and emission, degradation, or breakdown products of such munitions. Marine Technology Society Journal 2. Terminology A common understanding of the terminology relating to munitions and sea disposal is important. The United States has codified several terms used in dealing with munitions. The three most important are provided below. In the context of this paper, “munitions” is used, rather than “military munitions,” to include the munitions of all countries. ■ “Military munitions means all ammunition products and components produced for or used by the armed forces … including bulk explosives, and chemical warfare agents … and devices and components thereof.” 4 ■ Unexploded ordnance (UXO) are “military munitions that … have been primed, fuzed, armed, or otherwise prepared for action; … constitute a hazard … and remain unexploded by malfunction, design, or any other cause.”5 ■ Discarded military munitions (DMM) “are military munitions that have been abandoned without proper disposal or removed from storage … for the purpose of disposal.”6 There is an important distinction between DMM and UXO. DMM have not experienced the firing sequence normally required to arm their fuzes. Many are not complete, lacking components required for them to function. UXO have been through the firing sequence required to arm their fuzes. Although both present potential explosive hazards, DMM in general have a significantly lower probability of detonating than UXO. Although this paper focuses on DMM, it is important to recognize that testing and training ranges that may encumber water and areas where combat activities occurred are likely to contain UXO. 3. Risk Evaluation and management of risk can only be addressed through sound historical research and scientific evaluation. Sea-disposed munitions pose four principal types of risks to human health and the environment: ■ health impacts from direct physical contact; 4 10 U.S.C 101(e)(4)(A) through (C) 10 U.S.C 101(e)(5)(A) through (C) 6 10 U.S.C. 2710(e)(2) 5 impact to marine organisms and the environment near the disposal site; ■ consumption of contaminated seafood; and ■ explosions either spontaneous or during handling, which can threaten life and spread contaminants from disposal sites (Helsinki Commission (HELCOM), 1994; MEDEA, 1997; Beddington and Kinloch, 2005). Direct contact with munitions or munition constituents may occur in a number of ways. The effects can be either acute or chronic, depending on proximity to and the effects of a detonation, constituent toxicity, quantity released, route, and levels of exposure. The most common method of direct exposure is the inadvertent recovery of munitions in commercial fishing equipment. The increase in pipeline construction in areas with munitions present carries the potential for encounters and recoveries. These are a concern in the Baltic Sea where conventional and chemical munitions were disposed in relatively shallow water. Munitions and munition constituents wash ashore on the German coast on nearly a daily basis because of the large quantities of conventional ammunition disposed in the nearby waters. Potentially hazardous activities include dredging and beach replenishment, underwater mineral exploitation, and offshore construction. Recreational SCUBA divers have the potential to contact munitions to a depth of about 40 m. Since World War II (WWII), there have been few reported incidents of direct exposure encounters with seadisposed munitions in U.S. waters; however, hundreds have occurred in European waters. There were at least 448 incidents between 1985 and 2007 where fishermen in Danish ■ waters recovered CWMs in their nets (HELCOM at www.helcom.fi/ environment2/hazsubs/en_GB/ chemu/). Most encounters occurred during commercial fishing with some resulting in injury and fatalities. Most reported injuries are from direct contact with chemical munitions or chemi cal agent (e. g., solidified mustard) entangled in nets, explosives, and white phosphorous (WP); the latter washed ashore on beaches. Although several of the injuries that resulted from direct exposure to mustard were serious, reports on sea disposal of chemical agent in the Baltic Sea conclude that chemical agents pose little or no environmental threat because of their degradation, which varies from rapid to gradual, in seawater (MEDEA, 1997; Theobald, 2002; Hart, 2008). This degradation in conjunction with the risks associated with recovery is the basis for the general consensus for leaving the munitions in place. The potential for food chain impacts depends on the quantities of sea-disposed munitions, the physical and chemical characteristics of their munition constituents, and the rate of release of the munition constituents to the environment. Many munition constituents undergo chemical and biological reactions in the environment, degrading to less toxic compounds, and very few appear to bioconcentrate. Thus, food chain contamination does not appear to constitute a significant risk (HELCOM, 1994; Fisheries Research Service, 1996). Certain CWM is arsenic based and there is limited information on the behavior and potential impacts of the residual arsenic in the marine environment. There have also been a number of injurious and fatal accidents involving conventional munitions (Beddington Fall 2009 Volume 43, Number 4 17 and Kinloch, 2005). Incidents are likely to continue as use of the oceans expands into progressively deeper waters. Detonations may be spontaneous or as a result of disturbance. Spontaneous explosions are a possibility particularly when dealing with some of the less stable compounds, such as picric acid, used in World War I (WWI) munitions. A review of seismic data collected near the Beaufort’s Dyke disposal area off of the coast of the United Kingdom between 1992 and 2004 identified 47 underwater explosions, measuring 1.5 or greater on the Richter scale. These explosions included 13 deliberate demolitions with some or all of the remaining being spontaneous explosions (Beddington and Kinloch, 2005; British Geological Survey, 2005). Explosive hazards are instantaneous and can be catastrophic under some circumstances. However, the overall risk of spontaneous detonations is low because of the hydroscopic nature of explosives and the moisture present, which reduces their sensitivity and strength of a detonation (Hart, 2008). Detonation effects are generally localized. Although some information on the types and quantities of munitions and other materials sea disposed at many locations is available, the completeness and accuracy of this information are unknown. Some verification of the historical information may be necessary to refine the evaluation of relative risk. The risk evaluation process must judge the quantity and quality of available data. Given the difficulty of obtaining new data, the technical approach must rely heavily on mining and analyzing existing or historical information (MEDEA, 1997). Factors to be considered and data to be collected include: 18 potential for human or ecological receptors to be exposed to the munition constituents; ■ disposal information—types of munitions, quantities, locations, and length of exposure to the environment; ■ condition of the munitions (e.g., heavily corroded) and spatial distribution on the seafloor; ■ characteristics of disposal site (e.g., current, depth, temperature, geology, and ecology); ■ properties of the munition constituents—mobility, toxicity, and environmental fate; ■ rate and duration of munition constituents released to the environment; and ■ current impacts, if any, to human health and the environment. Even incomplete historical information is useful in determining approximate locations of sea-disposal sites, the munition types and quantities present, and their distribution on the seafloor. Once historical information is collected, much of the remaining data can be gleaned from scientific literature and other documentation. The relative risk posed by a specific site can then be determined and risk management can begin. ■ 4. Reason for Disposal and Available Options The armed forces have always had excess, obsolete, or unserviceable munitions that required disposal. The reasons are primarily a function of mission and include, but are not limited to, an inventory that exceeds requirements, munitions designed for use with weapon systems that became obsolete, munitions that have deteriorated and are unsafe for use or storage, the resources associated with transport Marine Technology Society Journal from theater of operations, and the capture of enemy munitions. The two most significant periods of disposal occurred following the World Wars when large stores of munitions, including captured munitions, required disposal because combat operations ended. Munitions, including CWM, were forward deployed, and at the end of hostilities, much was disposed because of deteriorated casings, required maintenance, and serviceability assessments. Although chemical warfare was limited in WWII, several countries, including Germany, Japan, the Soviet Union, Great Britain, and the United States, maintained large stockpiles of CWM. By the end of WWII, large amounts of CWM and related military chemicals were amassed (Stock, 1996; Lohs and Stock, 1997). Much of this material was sea disposed at the end of hostilities. From at least the early 1900s through the 1970s, many nations considered sea disposal a routine part of inventory management. Although it is likely that specific policies or guidelines (as described below) governed the disposals, documentation of the specific events may be sparse. Records available today lack the detail needed to document all aspects of disposal operations, leaving a disparity, with some disposal sites well documented, while others are not (Brankowitz, 1987; ACDA, 1993). Munitions are inherently dangerous, and their safe destruction has always presented a challenge. Until recently, munition design criteria focused on operational requirements, without consideration of demilitarization. Although other alternatives (burial on land, disposal by detonation, or burning) were considered and often practiced, sea disposal provided a safe and efficient method for disposing of large stocks of excess, obsolete, and unserviceable munitions (Gorodnitsky and Filin, 2002; Zanders, 2002). Sea disposal was thought to be the best method for dealing with chemical agents because they would dissipate at sea (Chepesiuk, 1997). Disposals in U.S. coastal waters occurred as early as the late 1800s and continued through 1970. The Secretary of the Navy prohibited the practice in 1971. Although the early U.S. procedures were quite general, betterdefined and more stringent procedures evolved over time in an effort to reduce the possibility of damage to fisheries, or recovery or accidental contact by the public. Historical records make it clear that U.S. sea-disposal operations followed specific instruction from higher headquarters. 5. Applicable Conventions, Treaties, and Policy Treaty law, rather than customary international law, governs the marine environment. Customary international law obligates nations to cooperate on the high seas, which are an open area for the use of all (Heintze, 1997). Although a growing environmental awareness led to the inclusion of provisions that addressed marine pollution in the 1958 Convention on the High Seas, these provisions proved inadequate to stop marine pollution (Zanders, 2002). This Convention focused on freedom of the high seas and permitted states to dispose of wastes (Heintze, 1997). Sea disposal of munitions, including CWM, continued as an accepted practice in the United States until it was discontinued in 1970. Increasing environmental awareness in the 1960s resulted in a gradual decline in the number of sea-disposal operations conducted throughout the world (Missiaen and Henriet, 2002). In May 1969, the U.S. Department of Defense (DoD) halted a planned Operation Cut Holes and Sink Em (CHASE 7 ) deep water disposal of more than 25,000 tons of CWM. This action was in response to concerns about the potential dangers associated with the transport of CWM and the possible impact on the ocean environment (Baine and Simmons, 2005). Congress and the National Academy of Sciences (NAS) reviewed the need for the operation (Congress, 1969; NAS, 1969). The NAS concluded that there were no viable alternatives for some of the planned disposals but advised avoiding future sea disposal of CWM because the environmental effects were unknown (NAS, 1969). The United States ceased sea disposal of CWM after a final operation in August 1970 and ceased disposal of conventional munitions after September 1970 (RDECOM, 2001). In 1971, the DoD placed a moratorium on deep water disposal of munitions, with the exception of emergencies where munitions placed a vessel or its crew at risk. In the 1970s, concerns over sea disposal of CWM and conventional munitions in the United States and Europe led to several regional laws and conventions. In 1972, Congress passed the Marine Protection, Research, and Sanctuaries Act of 1972 (MPRSA, Public Law 92-532) that prohibited U.S. disposal of munitions and many other materials at sea unless authorized by a permit. No permits have been issued by the DoD for the 7 The name of the operation is somewhat of a misnomer since the ships were scuttled through the opening of valves rather than by cutting holes in the hull. CWM was disposed in four of the vessels between 1967 and 1970. sea disposal of munitions since the MPRSA was enacted (EPA, personnel communication). Most other nations terminated sea disposal at about the same time (Heintze, 1997; Zanders, 2002; Baine and Simmons, 2005). About the time that the United States adopted the MPRSA, European nations established several regional conventions to address marine pollution, including preventing sea disposal. The first was the 1972 Convention for the Prevention of Marine Pollution by Dumping from Ships and Aircraft (Oslo Convention). The 1974 Convention for the Prevention of Marine Pollution from Land-Based Sources (Paris Convention) merged with the Oslo Convention in 1992 to become the Oslo-Paris Convention for the Protection of the Marine Environment of the Northeast Atlantic (OSPAR Convention). The wider international community also raised concerns about the potential impacts of sea disposal of military materials. The Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter (London Convention) opened for signature in 1972 and was enacted in 1975 (Baine and Simmons, 2005). The London conference concluded with the directive, “States [Nations] shall take all possible steps to prevent pollution of the seas by substances that are liable to create hazards to human health, to harm living resources and marine life, to damage amenities or to interfere with other legitimate uses of the sea” (Stub, 1995). The London Convention prohibits the deliberate disposal of certain harmful wastes, including CWM, outside the internal waters of the nations that are parties to the convention. Today, the London Convention and its 1996 Protocol remain the basic international Fall 2009 Volume 43, Number 4 19 framework for controlling sea disposal of chemical and biological agents. In 1974, the first Convention for the Protection of the Marine Environment of the Baltic was signed (Helsinki Convention). In 1992, all the countries bordering on the Baltic Sea and the European Economic Community formed a new Helsinki Convention that was enacted in January 2000. The HELCOM consists of nine member nations and the European Community. The OSPAR Commission is composed of 15 contracting nations and the European Union. HELCOM and OSPAR provide continuing forums for Europeans to collect and exchange information on marine pollution, including sea-disposed munitions, affecting the parties in the convention. HELCOM established an ad hoc Working Group on Dumped Chemical Munitions that compiled available information and developed findings and recommendations in 1995. The recommendations included identification of five areas where no anchoring or fishing with bottom contact gear was advised, and the continued study of the disposalrelated issues (HELCOM, 1995). International steps toward a convention banning chemical weapons in the 1980s culminated with the United Nations-sponsored “Chemical Weapons Convention” (CWC) in 1993. The CWC, which became effective in 1997, prohibits the development, production, stockpiling, and use of CWM for military purposes and calls for the destruction of present stocks (Missiaen and Henriet, 2002; Baine and Simmons, 2005). The CWC clearly excluded CWM that was sea disposed prior to 1985 (Chepesiuk, 1997). Furthermore, the CWC exempts such CWM from declarations and follow-up obligations—the Verifi- 20 cation Annex—as long as the items remain where disposed. The CWC provides no incentives to recover CWMs that were sea-disposed prior to 1985 (Stock, 1996; Missiaen and Henriet, 2002; Zanders, 2002). One author concluded that the CWC’s explicit exclusion of sea-disposed CWM was recognition that the risks and costs associated with recovery would be prohibitive (ACDA, 1993). There is no consensus whether sea-disposed CWM should be handled as an environmental issue or as an arms control and disarmament issue (Hart, 2008). Although the CWC does not address CWM sea disposed before 1985, several European countries believe that the Organization for Prohibition of Chemical Weapons, which assists in the implementation of the CWC, could serve as a forum for voluntary co-operation in addressing the issue of sea-disposed CWM, and Lithuania has put forth an initiative to this effect. The June 2009 European Commission communiqué, The Marine Strategy for the Baltic Region, includes a pilot project to assess the risk posed by seadisposed CWM, which will be led by Poland. This could include characterization, assessment, and recovery. 6. Historic Context of Munitions Disposals Under provisions of the River and Harbor Act of 1899, the U.S. Army Corps of Engineers had the authority to permit or restrict disposal of materials that could interfere with navigation or wash ashore. In 1918, the House and Senate approved the Army appropriation and included a section entitled, “Protection of Life and Property in Waters Endangered by certain Military Operations.” Essentially, this section authorized the Secretary of War to prescribe regulations governing the Marine Technology Society Journal military use of U.S. navigable waters. This Act specifically stated that the regulations issued would not unreasonably interfere with or restrict the food fishing industry (40 Stat. 982; 33 USC3, July 9, 1918). The 1899 Act, hazards to fishermen, and likely protests by the Conservation Commission were cited in prohibiting a private company from disposing munitions in the Chesapeake Bay in 1928. Disposal was recommended in a minimum of 30 m of water, 65 km from shore (Pettis, 1928). As early as 1917, coordination of disposals with port authorities was required prior to disposal. The earliest documents that researchers have found about U.S. policy and guidelines for the disposal of munitions date to the end of WWI. The American Expeditionary Forces (AEF) in France preferred detonation and, if other options were not available, burial (presumably on land) (American Expeditionary Forces, 1917, 1919; Chemical Warfare Service, 1918). A 1920 War Office document identified use as intended or burial (again, presumably on land) as the methods for CWM disposal, and prohibited disposal in water (War Office, 1920). Precautions described in a 1919 New York Times article indicated that early concerns about the potential impacts of CWM disposal were considered in selecting seadisposal sites (New York Times, 1919). “There did remain, however, tons and tons of methyl [lewisite]. What was to be done with it, now that there was no longer any active occasion for exterminating Germans? Cleveland did not want the deadly stuff dumped into Lake Erie, and there seemed no practicable method of neutralizing its deadliness chemically…. The ocean was selected as its catch-basin. Difficulties were met in transporting the stuff from Cleveland to the ocean. Handling such quantities was perilous. So it was put into big iron containers … the containers were stowed gently in a ship and taken fifty miles to sea, where they were lowered over the side into water three miles deep. Rust will eat pinholes into those containers, and there will be a minute and gradual intermixture of water with the fatal contents. In such circumstances … a slow chemical reaction which produces two nontoxic compounds. Experts do not believe even that fish will perish from the presence on the ocean bed of this vast quantity of poison. When the salt water of the Atlantic embraced the last of those iron tanks, finis was written to a chapter in American war effort which, until now, has been a secret scrupulously guarded.” A July 1919 memorandum to the Chemical Warfare Services (CWS) indicated that the lack of commercial uses for mustard agent and the possible danger of keeping large quantities on hand made it necessary to develop a disposal policy. The only satisfactory method identified, sea disposal, began soon thereafter (Edgewood Arsenal, 1919). Some munitions in transit (e.g., from Europe to Canada and the United States) at the end of WWI and WWII were disposed at sea. Munitions sea disposed by the United States included both conventional and chemical munitions. Documentation is sparse, and in some cases, it is unclear on which side of the Atlantic the disposals occurred. A 1933 memorandum refers to a policy requiring munitions to be dis- posed of in a minimum of 55 m of water. This was believed to be of sufficient depth to “safeguard against adversely affecting fishing conditions.” One letter indicated that munitions had been found in water between 22 and 29 m in depth, and that an investigation of a specific incident found that munitions had been disposed of in 44 m of water (Fourth Naval District, 1933). Although a policy that was intended to protect the public was in place, it is clear from the records that it was not always followed. Possible reasons include navigational errors, weather conditions, concern for safety of the vessel, and simple expediency. During the intra-war period between 1919 and 1941, the U.S. military performed research and development, and continued to manufacture and maintain chemical munitions and bulk chemical agents as well as conventional munitions. U.S. military guidance in effect during 1931 and reissued in the latter part of 1941, allowed the disposal of munitions at sea. Consultation with port authorities was required, and the materials were to be removed from packaging prior to disposal to ensure that they sank where disposed (Office of Chief of Ordnance, 1931, 1941). During WWII, the manufacturing, transportation, and storage of munitions dramatically increased, as did the need to dispose of unserviceable munitions, including leaking chemical munitions. War Department guidance in effect during and immediately after WWII stated that the “safest and easiest way to destroy unusable ammunition is to dump it at sea” (War Department, 1944). Documentation supports the contention that, within the various theaters of action, sea disposal was a preferred method of disposal of munitions (ACDA, 1993; Chepesiuk, 1997; RDECOM, 2001). After WWII, Allied nations faced the daunting task of disposing of extensive stocks of excess, obsolete, or unserviceable munitions and CWM as quickly and safely as possible. The 1945 Potsdam Agreement decreed that Germany should be demilitarized, with its war materiel distributed to the Allied powers or destroyed (ACDA, 1993; Stock, 1996). A 1946 Headquarters Allied Sea Command order to theater commanders “authorized disposal of hazardous ammunition by dumping at sea or demolition” (ACDA, 1993; Laurin, 1997). The Allies established the Continental Committee on Dumping to coordinate these disposal operations (Fokin and Babievsky, 1996) and decided that each occupation authority would be responsible for disposing of munitions in its occupied zone (ACDA, 1993; Fokin and Babievsky, 1996). In 1945, the Soviet Union, Great Britain, and the United States established the Allied Control Commission to address the discovery, dismantling, and disposal of German chemical weapon stocks. The Allies were faced with disposing of approximately 300,000 tons of munitions filled with mustard, phosgene, organoarsenic agents, and nerve agents from the German arsenal (Fokin and Babievsky, 1996; Stock, 1996). The Allied Control Commission’s Standing Committee on War Material recommended in November 1945 that the only practical method for disposal of CWM was at sea (Fokin and Babievsky, 1996; Laurin, 1997). The Allies disposed of as much as 85% of the German stockpile in the Baltic and North Seas (Stock, 1996). The United States disposed of 120,000 tons of the German chemical munitions by scrapping, burning, detonation, burial on land, and scuttling Fall 2009 Volume 43, Number 4 21 at sea. The Western Allies preferred to dispose of CWM and weapons by loading them on damaged or unfinished ships and scuttling the ships in deep water (Loucks and Elliott, 1949; ACDA, 1993; Laurin, 1997). Between 1945 and 1947, the United States sea disposed portions of its CWM stockpile in the European and Pacific Theaters, although some CWM was returned to the United States (War Department, 1944; Pease, 1945; RDECOM, 2001). Some excess munitions being returned from the European theater were sea disposed off the U.S. Atlantic coastline at the end of WWII. Between 750,000 and 1,500,000 tons of munitions, nearly exclusively conventional, were disposed of along the German North Sea coast (Liebezeit, 2002). Approximately 90,000 tons of conventional munitions from the Netherlands were disposed in the Baltic Sea (Van Ham, 2002). As the war in the Pacific Theater was fought island to island, munitions storage and supply areas were spread out over vast distances. In some cases, munitions stored at these areas were abandoned as the war progressed. Recovery of these munitions presented additional logistical (e.g., transportation, storage) and security concerns. In some cases, sea disposal was used. Captured stocks of Japanese munitions also required disposal. 6.1. Baltic Sea Following WWII, an estimated 360,000 to 385,000 metric tons of munitions, including about 40,000 metric tons of chemical munitions, are believed to have been disposed of in the Baltic Sea. It is estimated that these chemical munitions contained some 13,000 metric tons of chemical 22 agents. Areas with large quantities of disposed munitions include the Skagerrak Straits and the Bornholm Basin. The quantities present; the progressive corrosion of the munitions and leakage of the fill materials; the shallow depth of the Baltic Sea (55 m average) and slow rate of water exchange within the basin; and its heavy use for recreation, commercial fishing, and commerce have led to a significant concern by bordering countries about potential impacts. Nord Stream AG plans to construct a 1,300-km gas pipeline through the Baltic Sea from Vyborg in the Russian Federation to Greifswald in Germany in 2010-2011 (Figure 1). It is estimated that as much as 100,000 metric tons of munitions lie along the route and approximately 390 million m3 of sediment will be disturbed. Concern over the possible release of munition constituents during or as a result of construction and the possibility of a detonation rupturing the pipeline has arisen. Studies undertake to address these, and other concerns have resulted in a modification of the proposed route (Hart, 2008). The completeness and accuracy of an inventory of CWM along the proposed pipeline route are in question, and there is significant concern about the level of knowledge of the behavior of CWM in the marine environment. There is a broad agreement that given the magnitude of the proposed project, any seabed activities undertaken near the sea-disposed CWM should be subject to a full assessment of the potential risk prior to the approval by national authorities. 6.1.1. Skagerrak Straits Following WWII, an estimated 168,000 metric tons of munitions were sea disposed of in water depths Marine Technology Society Journal of 600 to 700 m in the Skagerrak Strait between the southern coast of Norway and the southern coast of Sweden and the Jutland Peninsula of Denmark. These munitions were disposed in 26 hulks scuttled in the Skagerrak, southeast of Arendal, Norway (OSPAR, 2005). Paetzel (2002) stated that as many as 38 warships and container ships were sunk in the Skagerrak between 1945 and 1947. The ships are estimated to contain as much as 50,000 metric tons of mustard agent and unknown quantities of Tabun and phosgene. 6.1.2. Bornholm Basin Following WWII, an estimated 40,000 metric tons of CWM was disposed of off Bornholm, primarily within a circle with a 5.5-km radius. The munitions are scattered along the transport routes and over a considerably larger area. Initial disposals included munitions still in their packaging, which drifted prior to sinking. These munitions have also been dispersed through fishing activities. In addition, several sunken vessels with munitions on board have been observed within the Bornholm area. These vessels are draped with fishing nets, and munitions fragment were observed around one of the vessels (HELCOM, 1994; Paka and Spiridonov, 2002). 6.2. Paardenmarkt Site Large quantities of munitions remained in Belgium following WWI, and many accidents resulted from their collection and storage. The situation became intolerable in 1919, and a decision was made to dispose of approximately 35,000 metric tons of munitions on a shallow sandbank known as “Paardenmarkt.” Approximately one third of the disposed muni- Fall 2009 Volume 43, Number 4 23 Munition areas in the Baltic Sea and proposed Nord Stream Pipeline Route, courtesy of Nord Stream LLC. FIGURE 1 tions are believed to be CWM. The Paardenmarkt site is 1 to 2 km off the Belgium’s Knokke Beach Resort, a similar distance from the port of Zeebruggee, covers 3 km 2 , and lies in waters that are from 1.5 to 5.5 m in depth. The site was discovered in 1971 during harbor maintenance, and a no anchorage or fishing zone was established. No accidents have been reported here (Missiaen et al., 2002a, b). A 2001 study focused on the geophysical, geochemical, sedimentdynamics, biological, engineering, and ecological aspects of the site. The study concluded that it could take hundreds of years for all of the munitions to corrode completely; in-situ measurements and monitoring are necessary. Although it is unlikely that munitions would be moved by currents or tides, the possibility of mustard agent lumps reaching the shore cannot be ruled out. The final conclusion was that recovery of the disposed munitions would be a costly and highly risky operation, could result in the release of toxic compounds into the environment, and could threaten nearby resorts. The best option appears to be to leave the disposal site untouched and carry out regular monitoring unless an acute risk is found (Zanders, 1997; Missiaen et al., 2002a, b; OSPAR, 2004). 6.3. Beaufort’s Dyke Beaufort’s Dyke, a 200- to 300-m deep trench between Scotland and Northern Ireland, has been used for munitions disposal since the 1920s. The trench is more than 50 km in length and is approximately 3.5 km wide at its broadest point. It is estimated that over 1 million metric tons of munitions were disposed of here to include cartridges, hand grenades, land mines, shells, bombs, bomb casings, 24 and depth charges. Related materials included boxes, and crates or racks containing munitions. During the 1990s, thousands of WP munitions, believed to have been dislodged during installation of a pipeline, washed ashore on the Scottish and Irish coasts. Once dislodged, these munitions, which are positively buoyant, floated to the surface where they were carried ashore by wind and current. They present a risk of burns should they be handled (Fisheries Research Service, 1996; OSPAR, 2005), as reports of beachgoers in Europe being burned from collecting WP testify. 6.4. United States In the post-WWII time period, large quantities of conventional munitions and CWM were sea disposed. These large operations were conducted openly and in coordination with many branches of government (i.e., port authorities, state health departments, U.S. Coast Guard, U.S. Fish and Wildlife Service, and U.S. Surgeon General). Two of the more significant sea-disposal operations were as follows. ■ In December 1948, Operation Geranium, so-named because of the geranium-like odor of lewisite, was conducted. The U.S. Army loaded 3,153 metric tons net chemical agent weight (NCAW) of lewisite aboard a hulk, S.S. Joshua Alexander, and it was scuttled (i.e., intentionally sunk) in the Atlantic Ocean (ACDA, 1993). ■ The DoD sea disposed of thousands of tons of conventional munitions and CWM during separate disposal operations that composed Operation CHASE. Operation CHASE involved the consolidation of munitions and bulk materials in vessels that were scuttled between Marine Technology Society Journal 1964 and 1970. Of the 19 vessels, 8 were sunk off the Pacific coast and 11 off the Atlantic coast. Of the 15 vessels loaded with explosives, 12 detonated during sinking (five intentionally). Four vessels (CHASE 8, 10, 11, and 12) were loaded with CWM and were scuttled in deepwater off the Atlantic coast (ACDA, 1993). The recovery of an unfired 75-mm mustard filled projectile from a clamshell driveway at a residence in Delaware in 2004 led to a review that revealed that hundreds of conventional munitions were recovered from driveways in several Mid-Atlantic States. These munitions originated from clam dredging areas off the Mid-Atlantic coast, primarily New Jersey. The stakeholders cooperated to implement procedures to preclude additional munitions from being distributed to the public domain, and hundreds of munitions were recovered from existing driveways paved with clamshells. Since the investigation, 10 additional 75-mm mustard projectiles and over 100 conventional munitions have been interdicted and brought under DoD control. 7. Characteristics of Disposed Munitions All manner of military munitions and related chemicals have been disposed of at sea. An estimated net weight of 27,000 metric tons of chemical agent was disposed of in U.S. and nearby coastal waters (DoD, 2008). The relative amounts are shown in Figure 2. Research on sea disposal of conventional munitions in U.S. coastal waters is still in its early stages, but the known gross weight disposed already significantly exceeds that of disposed CWM. Common FIGURE 2 Relative quantities of CWC schedule chemicals disposed in U.S. coastal waters. A total of approximately 27,000 metric tons was disposed between 1919 and 1970 (DoD, 2008). conventional munition explosive fillers include TNT, Composition B, Explosive D, and amatol. Generally, the definition of CWM is restricted to only those chemicals listed in the CWC. Chemical munitions, designed for maximum dispersal of their chemical agent fill, are normally thinner skinned than conventional munitions. The fills for conventional munitions include high explosive, smokes, pyrotechnics, and incendiaries. Most munitions are composed of metal parts. U.S. records often identify specific munition types and quantities that were sea disposed. When the specific munitions are known, the design drawings provide information on the items shape and dimensions, as well as information that can be used to estimate the quantity of the materials used in the finished product. This information is useful when evaluating the potential effects on the environment as well as the effects of the environment on the munitions (i.e., corrosion). It is also helpful during the selection of equipment (e.g., SONAR, video) and a chemical analytical suite when characterizing a site. When analyzing the potential for release of munition constituents caused by corrosive processes attacking the casing walls and assuming the materials are the same, it is important to note that thicker walled munitions (e.g., projectiles) are estimated to take five to perhaps ten times longer to corrode to the point of release than thinner-walled munitions (e.g., bombs, rockets) (Epstein, et al., 1973; MEDEA, 1997). It is hypothesized that chemical agent releases in the Baltic Sea are almost entirely caused by the leakage from thin-skinned chemical bombs (MEDEA, 1997). The observation that recoveries of complete bombs in the Baltic Sea have become infrequent and that the thin bombshells, when recovered, are corroded through supports this hypothesis (HELCOM, 2002, 2005). Adverse impacts on the health of individual organisms and population reductions were observed in some Baltic Sea unique species at CWM disposal sites (Barsiene et al., 2008). disposal (Figure 3), and consolidation in and then scuttling of hulks (Figure 4) (RDECOM, 2001). HELCOM indicates that over-the-side disposal from moving vessels may have dispersed munitions over a large area with a variable density (HELCOM, 1994). Individual disposal events ranged from a few items to thousands of tons of munitions. The disposal method significantly affects the distribution of sea-disposed munitions and other material on the seafloor. The fall of munitions or containers through the water column and movement of the vessel causes dispersion, making bounding of over-the-side disposals difficult. The United States used over-the-side disposal and scuttling interchangeably until 1964 (RDECOM, 2001). As a rule, the U.S. military removed munitions from their packaging prior to disposal to ensure that they sank. From 1964 through the last event in 1970, the United States FIGURE 3 Photographs of loose disposal of munitions. 8. Disposal Methods Sea-disposal operations were conducted using one of two methods— over-the-side (also known as “loose”) Fall 2009 Volume 43, Number 4 25 FIGURE 4 Photographs of munitions packed into the hold of a ship prior to scuttling. the disposed munitions may be on or may have penetrated beneath the surface. 9. Disposal Sites used consolidation and scuttling for sea disposal. Scuttling reduces the probability of disposal outside of the planned site, and housing the munitions in the hulk minimizes their spread (HELCOM, 1994). Scuttling in hulks normally resulted in a single, large, and easy to locate target on the bottom. An estimate of the depth of penetration into coarse compact sediments was developed for palletized munitions of various sizes, including 1-ton containers. Calculations concluded that the palletized munitions would penetrate from 0.1 to 4 m into the sediment (MEDEA, 1997). Most, if not all munitions, disposed over-the-side were not palletized and were likely to penetrate deeper into sediments. Complete coverage by sediment would likely reduce the rate of corrosion because of oxygen deficient conditions. Depending on disposal method, bottom type, munition type, and local conditions, 26 The need to protect people and resources from the potential impacts of sea-disposed munitions has been understood since the earliest disposals. The hazardous nature of munitions and their fill was recognized at the time of disposal, as was the ultimate failure of containers. Near the end of WWII, efforts were made to standardize and restrict disposal to specific areas of the ocean to minimize the potential for interference with human activities and impacts on resources. Minimum distance from shore and water depth for disposals was defined. The policies and regulations in force at the time of the specific sea-disposal operations provide ancillary information concerning locations of sea-disposal sites. It is likely that sea-disposal sites annotated on navigational charts were used for disposal of a variety of materials (e.g., munitions, radioactive wastes, industrial waste). For a number of reasons (e.g., level of detail in the logbooks, limited documentation for disposal operations), only the general location of the actual disposal may be known. Additionally, navigational aids available at the time and other factors (e.g., weather conditions) may have caused some disposals, in part or whole, outside the intended disposal sites. Documentation such as charts for most sea-disposal sites indicates that they cover tens of square kilometers of the seafloor, without consideration of the high potential for navigational and documentation errors at the time of disposal (Table 1). U.S. disposal sites are as close as 2 km from shore and vary from 10 to Marine Technology Society Journal 5,100 m in depth. U.S. regulations and policies on sea disposal of munitions changed over the period that sea disposal was allowed, rapidly evolving during WWII and becoming more stringent with each revision. In an April 24, 1945 memorandum, the U.S. Chief of Naval Operations (CNO) instructed all Navy and Coast Guard commands to establish and record the locations of disposals of all “explosives, ammunition, and chemical munitions.” The CNO also required that sea-disposal sites be located outside regular shipping lanes, fishing grounds, submarine operating areas, and well away from marine cables. The sites used were reported to the Government Hydrographic Office, which, in turn, was to use the information to post a Notice to Mariners and indicate them on nautical charts (CNO, 1945). ■ Disposal sites designated at the end of WWII are about 343 km2 and appear on current National Oceanic and Atmospheric Administration (NOAA) charts. ■ Only two CWM sea-disposal operations, one in 1919 and the other in 1944, are known to have occurred at depths of less than 90 m (DoD, 2008). Although little information has been collected on the majority of sea-disposal sites, several sites have been investigated multiple times. Most of the CHASE ships sank straight down and landed on their keels (Donnelly, 1990). The general scientific opinion concerning Operation CHASE was that sea-disposed chemical agents would undergo hydrolysis8 and dilu8 Hydrolysis is a chemical reaction in which a compound is broken down by the addition of a water molecule. Fall 2009 Volume 43, Number 4 27 200 Over 400 160 Over 70 240 100 440 160 Over 400 20 NA NY-01 (Area A) NC-04 (Area B-1) NC-03 (Baker) USS Elinor NJ-02 (Unnamed 1) NJ-X01 NJ-01 (Unnamed 2) VA-01 (Unnamed 3) FL-02 (Unnamed 4) PR-01 Unknown 2 NA HI-06 (Ordnance Reef) HI-X01 (Oahu Unknown) Under 2 80 NA LA-X01 (Braithwaite) AL-X01 (Mobile) Unknown Gulf of Mexico Over 10 HI-05 (Oahu Unnamed) 20 HI-01 (Oahu Area 1) 20 20 AK-03 (Attu) HI-02 (Oahu Area 2) 190 CA-10 (West Coast) Pacific 190 MD-01 (Area 1) Atlantic Sites Estimated Distance from Shore (km) NA 460 20 NA 10 430 Over 460 1,460 1,800 4,100 NA 900 4,800 1,100 3,300 Over 30 2,100 Over 100 1,800 1,800 2,000 1,800 Estimated Minimum Depth (m) NA NA NA NA 10 NA 340 340 340 4,800 NA 340 4,300 340 340 NA 340 Over 3,400 340 270 340 340 Estimated Size (km square) Loose Loose Loose Loose Loose Loose Loose Loose Loose Scuttle/loose Loose Loose Scuttle/? Loose Loose Loose Loose Loose Loose Loose Scuttle Loose Disposal Method X X X X X X X X X X X X X X Artillery Projectiles/ Mortars X X X X X X X X X X X X X X X Aerial Bombs Summary information on U.S. sea-disposal locations. A map showing site locations can be found in DoD 2008. TABLE 1 X X X X X X X X X X X Bulk Container X X X Munition Components X X X X X X X X X X X X X X X X X X X X X CWM X X X X X X X X X Conventional X X Radiological tion. In combination with the density of the chemical agent involved, which prevented it from rising to the surface, this supported the conclusion that CHASE disposals presented only a minimal threat to human health; however, an assessment of long termeffects required further investigation (Donnelly, 1990). Between 1969 and 1975, the DoD performed investigations of several CHASE sites. CHASE 8, 11, 12, and 21 were scuttled at a depth of about 2,100 m. In addition to CWM, approximately 680 metric tons of conventional explosives and other miscellaneous materials were also disposed. Investigations located the intact hulks of CHASE 8, 10, and 11 and the debris field from 21. The sites (CHASE 8 and 11 in 1969, CHASE 12 in 1969 and 1972) were extensively photographed, water and sediment samples were collected and analyzed, and a biological survey was conducted. Chemical analysis did not find any evidence of contamination, and photographs showed an apparently healthy ecosystem. Water current data indicate little possibility of the material reaching the surface (Wilkniss, 1973). The CHASE 10 site is approximately 470 km east of Florida and at a depth of approximately 4,900 m. It was located, sampled, and photographed each year from 1971 through 1975. Chemical analysis found no evidence of contamination, and photographs showed an apparently healthy ecosystem. The site was originally selected because the stable density structure of the vertical water column resulted in a deep, isolated basin where mixing of the bottom waters with overlying upper water masses is comparatively slow and sluggish and would prevent any signi ficant spread of the CWM before hy- 28 drolysis was complete (Linnenbom, 1997). 10. Assessing and Managing Risk Risk management is the process of analyzing the level of potential risk associated with a munitions disposal site and developing a strategy to mitigate potential impacts. Some management strategies (e.g., public education) require relatively little in the way of resources, while others (e.g., recovery and disposal) can be resource intensive. Successful risk management requires resource intensive efforts to be prioritized to address the highest risk and be as effective as possible. In the case of munitions sea-disposal sites, modeling of potential environmental impacts is a tool that can help determine the relative risk posed at each site and prioritize sites for further investigation or response actions. The design of any response action (e.g., investigation, survey, monitoring, and removal) must be based on an analysis of site-specific conditions and evaluation of risk posed to human health and the environment. Worldwide, the majority of responses focus on determining the site conditions, identifying the site, and implementing a public safety education program. A significant concern is that handling could result in a detonation or, in the case of CWM, the catastrophic failure of an item and release of its contents. If sea-disposed munitions pose a significant hazard, then appropriate risk mitigation methods must be identified and implemented. Risk mitigation methods range from education (e.g., marking on nautical charts) and monitoring, to containment or removal and destruction. An important aspect of hazard analysis and risk mitigation Marine Technology Society Journal is establishing the location and boundaries of the munitions disposal sites. In shallow European waters where the potential of encounters is high, it is likely that the policy will be to “recover and destroy” CWM, particularly at sites driven by high value projects such as the construction of the Nord Stream pipeline. Along the German coast, members of the public are injured nearly every year by WP from incendiary devices (Koch, et al., 2008). Between the end of WWII and 1996, there were five incidents where 126 people were burned by mustard agent, which contaminated beaches in Poland. Most of these occurred in the 1960s and 1970 (Witkiewicz and Szarski, 1997). Although it is clear that the general public can be affected by sea-disposed munitions, the greatest risk from seadisposed munitions occurs through inadvertent recovery of munitions or contaminated media during commercial maritime activities. “The consensus of scientific opinion is that munitions on the seabed present no risk to human health or the marine environment if they are left undisturbed. Recovery of dumped munitions is a costly and highly risky operation that could result in the release of large amounts of toxic compounds into the environment – and may even result in the loss of life.” (OSPAR, 2004). Although localized effects are possible, a general consensus is that sea-disposed munitions do not appear to pose a widespread threat to marine ecosystems (HELCOM, 1994, Theobald, 2002). That said, further studies of potential impacts are not only prudent, but also necessary. Effective communication, cooperation, and information sharing is key to educating the public and addressing the sea-disposal issue based on a rational evaluation of risk rather than on an emotional response. An important aspect is providing information in a form that is accessible to the public. Open communication is also important in view of expressed skepticism about the military’s commitment to addressing this issue. Over the past 50 years, there have been a significant number of incidents involving sea-disposed CWM in the Baltic Sea, North Sea, Adriatic Sea, and Sea of Japan. The majority of these incidents involved the recovery of and, in some cases, exposure to mustard by fishing crews (Kurata, 1980; Missiaen and Henriet, 2002). International experience has shown that public education concerning the locations of munitions and CWM disposal sites and procedures to be followed has reduced the number of incidents (ACOPS, 2003; Plunkett, 2003). Between 1972 when information regarding the sea-disposal sites was released to the public and 1980, the Japanese had no injuries from sea-disposed CWM. This compares with several deaths and dozens of injuries reported from contact with sea-disposed chemical agents in the period from WWII to 1972 (Kurata, 1980; Plunkett, 2003). Public concerns about munitions sea-disposal sites will continue to grow until more certainty about the risks presented can be provided. It is important that the public be kept informed of the work being planned and the results of any completed studies (Paetzel, 2002). Care must be taken in performing the historical research, developing site inventories, estimating quantities and types of munitions, identifying munition constituents, and making a determination of relative risk of each site. The sharing of information on disposal of munitions and education of maritime workers is also an important part of risk management. 11. Conclusion The oceans were once considered a safe and reasonable alternative for efficiently disposing of large stocks of munitions, but the question is whether these historic sea disposals are now a significant threat to human health and the environment. It is not possible to identify and remediate all munitions in aquatic environments, and accidental recoveries will continue. Thus, any risk management strategy must include education of the potentially effected population. Several European countries have prepared guidelines for maritime industries on how munitions inadvertently encountered should be handled. Nautical charts are marked with warnings to prevent individuals from inadvertently contacting or recovering munitions. Some countries, such as Denmark and Sweden, instruct fishing vessels to carry specialized first aid and protective equipment for dealing with recovered CWM when fishing at sea-disposal sites (HELCOM, 1994; 1995; OSPAR, 2004). Since 1995, HELCOM has developed a number of publications (www.helcom.fi) that address the hazards associated with sea-disposed munitions and actively tracks incidents and recoveries in the Baltic region. In a similar effort to educate the pu blic, t he DoD de s igne d a n d launched a UXO Safety Education Program web site that provides educators and safety specialists with a packaged toolbox of educational materials for use in classrooms and public forums. The DoD “Maritime Industry: 3Rs Explosives Safety Guide” informs maritime works of the hazards associated with munitions and the steps to be taken if encountered. It is available on the DoD UXO Safety web site (www. denix.osd.mil/uxosafety). The DoD is in contact with NOAA to ensure that all known disposal sites are included on nautical charts. The implementation of an effective education program for potentially affected communities (e.g., emergency responders, commercial maritime industries, and targeted-recreational activities such as SCUBA diving) would mitigate such risks. Affected communities should be informed and periodically reminded how to deal safely with encountered munitions. The DoD has notified federal and state regulators, the commercial fishing industry, and trade organizations about CWM inadvertently recovered during commercial clamming operations off the Mid-Atlantic States, and identified actions to be taken in the event of an encounter. Commercial entities should also educate their workers. This helps ensure the safety of their operations and avoids worker’s compensation claims, potential regulatory fines, and consumer tort actions. The coordination of efforts for outreach and education has proven to be helpful (Baine and Simmons, 2005). It has been over 90 years since WWI and about 65 years since WWII and Europe still faces the legacy munitions from those wars both on land and at sea. The risks posed by the sea-disposed munitions should be fully assessed so that appropriate risk management can be implemented. This may include the recovery and destruction of sea-disposed munitions where the risk is high. It is possible to determine the relative risk posed by sea-disposal sites to human health and the environment Fall 2009 Volume 43, Number 4 29 using available historical information and an understanding of the fate and transport of munition constituents in the marine environment. The potential impacts to human health and environmental and national economies from legacy sea-disposed munitions clearly call for voluntary international cooperation and information exchange. The exchange will minimize duplication of effort and foster development of best practices for risk management that clearly begin with targeted education efforts. This paper is one small step in this direction. Beddington, J., Kinloch, A. 2005. Munitions Dumped at Sea: A Literature Review. Imperial College London Consultants. References Chepesiuk, R. 1997. A sea of trouble? Bull At. Sci. 53(5):40-44. ACDA (U.S. Arms Control and Disarmament Agency). 1993. Special Study on the Sea Disposal of Chemical Munitions. 55 pp. ACOPS (Advisory Committee on Protection of the Sea). 2003. Coastal survey of packaged chemical and other hazardous items 2002/2003. Maritime and Coastguard Agency Research Project No. 488, London. American Expeditionary Forces. 1917. Defensive Measures Against Gas Attacks. France: HQ American Expeditionary Forces. p. 31. American Expeditionary Forces. 1919. Gas Manual: Part II. Use of Gas by the Artillery, A.E.F. No. 1475-2, G-5. 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