Complex 2-Component Process Hits the Roof
Transcription
Complex 2-Component Process Hits the Roof
PRODUCTION Injection Compression Molding. Plastic glazing and large decorative parts with high-gloss optics are one of the most attractive growth markets for plastics in the automotive industry. The success of these applications hinges critically on the availabilThe heart of the production installation for polycarbonate elements is a 2-component swivel-platen machine with a clamp force of 23,000 kN (photo: Webasto) ity of manufacturing con- cepts appropriately tailored to the needs of the product. Only then can the potential of this technology – lightweight construction, safety benefits and design freedom – be fully exploited. Complex 2-Component Process Hits the Roof MARKUS BOSS BERND KLOTZ ood optical, mechanical and thermal properties make polycarbonate (PC) a preferred material for the manufacture of optical parts in the automotive industry. In 2003, Webasto AG, Stockdorf, Germany, decided to start processing PC in its plant in Schierling, Germany. The aim was to develop PC roof panels because, with a density of 1.2 g/cm3, the plastic is ideal for use in lightweight constructions. Compared to a glass counterpart, a PC roof can be up to 50 % lighter. The resultant lower weight of the vehicle lowers its center of gravity and leads to improvements in roadholding and handling characteristics – partly because the see-through G Translated from Kunststoffe 3/2010, pp. 96–99 Article as PDF-File at www.kunststoffeinternational.com; Document Number: PE110350 62 areas in roofs have grown increasingly larger in recent years. Many Advantages, One Shortcoming The material has other advantages. It has high impact strength and so is almost unbreakable. It is insensitive to minor damage and stone chipping. In an accident, it even reduces the risk of injury to vehicle occupants. It offers designers greater freedom and constructors more scope for functional integration. One major shortcoming is that PC components are not inherently scratch-proof, so they have to be spray-coated after molding. This entails coating the front and rear side in two operations with a primer and a special hard coat. What was initially a development project on an experimental mold at Webasto’s Center of Plastics Excellence in Schierling soon became a commercial success when the company was awarded a contract in 2005 to make the panoramic roof for the Smart Fortwo; mass production started two years later. Measuring 1.2 m2, this is the largest automotive PC roof panel ever made. More than 250,000 units have since been produced. By virtue of a recently commissioned second production line built around a MXW 2300-17200/8100 SpinForm 2-compo- i Contact Webasto AG D-82131 Stockdorf / Germany TEL +49 89 85794-0 > www.webasto.com KraussMaffei Technologies GmbH D-80997 München / Germany TEL + 49 89 8899-0 > www.kraussmaffei.com © Carl Hanser Verlag, Munich Kunststoffe international 3/2010 PRODUCTION Low Level of Residual Stress in the Molded Part The installation boasts flexible injection compression molding programs for different process variants (figure: KraussMaffei) nent swivel-platen machine (manufacturer: KraussMaffei Technologies GmbH, Munich, Germany), with 23,000 kN clamp force, Webasto has boosted production of PC roof elements to the current level of 320,000 parts per year. The two injection units are positioned on either side of the clamp unit, one being conventionally arranged, while the second is located behind the moving platen and moves along with it. molded-in stresses in this process configuration would warp the molded part and make it unusable. Therefore, the large panes have to be manufactured with very low molded-in stresses. This important quality criterion, which applies to all high-quality optical components, calls for a so-called low-pressure method – namely, injection compression molding. In this technique, the plastic melt is injected into the mold, which ei- A typical PC roof element demonstrates these requirements. Given a wall thickness of 4.5 mm, a flow path of 1,200 mm and one gate, a melt temperature of 300°C and a mold temperature of 95°C, the maximum cavity pressure is 250 bar, while internal pressures across the molded part range from 150 to 200 bar. The holding pressure, too, which in injection compression molding is applied exclusively via the clamp, is identical across the entire component, both close to and away from the sprue. This is therefore known as the clamp holding pressure. The machine is designed to deliver clamping force on this basis. The material composition can be varied to adjust the tinge of the finished pane and adapt it to all kinds of products and designs. Improved infrared absorbers filter out virtually all UV radiation in spite of the high transparency and provide a comfortable indoor climate in the vehicle. To take full advantage of the functional integration, glazing is increasingly being designed as 2-component parts. The design provides for a first, transparent Compression Molding in Different Process Variants When installing the new facility, Webasto drew on experience gained with an existing system to further optimize the process. Up until then, mold construction had been the technology driver – all workflows had involved the 120-ton mold and so were correspondingly difficult to modify. Collaboration with the system supplier, though, has yielded a stable process and shifted the focus more toward system functionality. The new machine features a 40-ton mold for a 0.8 m2 part. The machine setter has four different variants to choose from in the guise of expansion compression, clamping compression, opening compression and force compression. The whole injection process is ultimately tied to the requirements of the subsequent coating step. The reason is that the coating is prepared with solvents that can cause cracking in the plastic under adverse stress conditions, even during coating itself. However, the solvents are essential for ensuring that the coating adheres strongly. The priming and painting stages each require the parts to be heated for about one hour at 130°C. Any Kunststoffe international 3/2010 Injection compression mold, injection molding machine and peripheral equipment add up to a finely balanced production system for PC glazing (photo: Webasto) ther is not yet fully closed or is opening. Mold closing is delayed until freezing sets in. Since the clamping pressure builds up uniformly, the variants of injection compression molding yield parts which have an excellent surface and little mechanical anisotropy, irrespective of the type of plastic. component which is back-molded with a second component (in the case of glass, this is the black marking for hiding unsightly areas). The process must be highly reproducible, because a substantial part of the cavity of the second component is pre-shaped by the first component. Unlike the case for a conventional mold, the > 63 PRODUCTION On the machine control’s display screen, production staff can use four displacement transducers to call up details of the platen parallelism control and the timing of the compression gap in the parting line – a prerequisite for high-fidelity manufactured optical components (figures: Webasto) Preventing the Mold from Tilting Open The quality requirements imposed on the part are no lower than those imposed on the tool and the functionality of the injection molding machine. What is needed is high-fidelity molding, both from shot to shot and across the entire part surface. The part is molded from the side because it is an optical part. When the melt enters the mold, higher pressures closer to the sprue than away from it would cause the mold to tilt open. The installation must compensate for these forces in the mold, so as to prevent mold opening. The difficulty is that fluctuations in wall thickness over the entire part must not exceed 0.02 mm. This requires the use of high-precision, smooth-running, mold platens with a parallelism in the range of 0.01 mm and so the machine must be equipped with a parallelism control unit. KraussMaffei favors recording the com- 64 pression stroke, as measured at the mold gap – because only there, right at the molded part, is it possible to effect control directly via measurement, without the need to consider other possible interferences. Reflective and Transmission Optics as Quality Criteria Only distortion-free surfaces meet the quality demands which car manufacturers and buyers impose on PC roofs. Two criteria are crucial. The first is called reflective optics, and refers to the correct flatness of the surface of the part. For, only an absolutely perfect mirror image conveys a good overall impression of high quality.An important factor is the 2-component process described here in which the second component is injected onto the first and not into a steel mold. The response to the melt, such as one-sided heating and cooling, can influence the surface as well as the described changes in wall thickness. The result is a so-called window effect, i.e. a physical instability that is caused by the back-molded material. The human eye perceives a surface change with a discontinuity of 2 µm as annoying. The second concept is called transmission optics and describes a safety feature, namely, a distortion-free field of view without interfering specks. This is affected by the stress state of the part (birefringence) and the purity of the material (homogeneity). Therefore, plastication and compression technology here are crucial. In the process realized by KraussMaffei 250 Far from sprue Close to sprue bar 200 Cavity pressure cavity for the second component is shaped by the process outcome of the first component. In the second process step, the cavity creates a seal between steel and transparent plastic – if this part is not made to an accuracy of hundredths of a millimeter, this can lead to fluctuations and even to overpacking of the second component. Because the total stress in the molding is determined by the second component as well, it is sometimes an advantage to choose an injection-compression method for the second component. That, combined with a small number of gates, creates a low level of molded-in stress. 150 100 50 0 0 10 20 30 40 50 Time 60 70 s 80 © Kunststoffe Typical cavity pressure during an injection-compression molding process, with the same pressure at the end of compression phase. The flow path between the pressure sensors is roughly 1,200 mm long (source: Webasto) © Carl Hanser Verlag, Munich Kunststoffe international 3/2010 PRODUCTION Polarization optics (here: with monochromatic light) reveals the key advantage of injectioncompression molding: Low molded-in stresses across the entire part surface create ideal conditions for the subsequent scratch-resistant coating (photo: Webasto) and Webasto, the mold floats on the plastic melt until freezing is complete. This leads to distortion-free optical moldings. Special HPS-AT plastication units are used for processing the PC on both injection units. They ensure high melt homogeneity and reproducibility. The compression process makes it possible to maintain a curvature tolerance of ±1.5 mm, as a measure of non-warping across the entire surface of the panoramic roof (72 measuring points). Side and rear windows and other trim panels resembling glass can be produced by this method too. The quality of the PC panes is so high that at present only the current legal situation and the lack of resistance to scratching by wipers prevent its use in windshields. Outlook Injection compression molding is a growing alternative in the production of exte- rior parts. Compression processes are now being used for body-panel areas, such as hoods and fenders.Webasto alone has acquired eight contracts to start mass production of roof elements in the next two years. Other applications which will go into production in the next few years are roof shells for convertibles, a fully opening panoramic roof made of PC and a rear module with spoiler. Current machine technology allows for different compression variants. In all of them, mold cooling and control thereof are a crucial factor. Heightened quality demands are moving another issue centerstage that will significantly influence the process in the future. It is called dynamic mold heating (DMH). In this, the injection molding machine communicates with the temperature control devices in real time via a Varan bus – allowing full flexibility over the temperature profile. THE AUTHORS DIPL.-ING. MARKUS BOSS, born in 1972, works in the Polycarbonate Product Group of Webasto AG in Schierling, Germany. DIPL.-ING. (FH) BERND KLOTZ, born in 1956, works in process development at KraussMaffei Technologies GmbH, Munich, Germany. High-Performance and Biodegradable Biodegradable Plastic. BASF SE, Ludwigshafen, Germany, is now offering a new biodegradable plastic. It goes by the name Ecovio FS and it has joined the existing Ecovio product line. The company has optimized this new plastic for two specific applications: for coating paper and for manufacturing so-called shrink films, which serve to easily wrap packaged goods. For this reason, the first two new plastic types are called Ecovio FS Paper and Ecovio FS Shrink Film. As has been demonstrated in recent composting experiments, the new Ecovio FS biodegrades even more rapidly than its predecessors, and it has a higher content of renewable raw materials. Ecovio FS consists of the likewise new, now biobased Ecoflex FS (a biodegradable polyester made by BASF) and of PLA (polylactic acid), which is extracted from corn starch. The use of the new Ecoflex FS raises the proportion of bio-based material in Ecovio FS Shrink Film to 66 % and that of Ecovio FS Paper to a full 75 %. Translated from Kunststoffe 2/2010, p. 49 Kunststoffe international 3/2010 Paper cups and shrink films are the first two applications for a new biodegradable plastic based on PLA (polylactic acid) and biodegradable polyester (photo: BASF) The experts who developed the new Ecovio FS focused on the properties that are required of these special applications: In order to obtain effective paper coatings, a film made of the new Ecovio FS Paper has to be easy to process and exhibit good adhesion to the paper, even when applied in thin layers. Such coatings are used, for example, on paper cups or cardboard boxes. Ecovio FS Shrink Film, in contrast, has a selected ratio of shrinkage to strength, so that its mechanical load capacity at a film thickness of merely 25 µm is greater than that of a conventional polyethylene film that is 50 µm thick. > www.ecovio.de 65