Scope of Test and Assessment Criteria – SUITABLE FOR ALLERGIC PEOPLE

Transcription

Scope of Test and Assessment Criteria
for the Issue of the TÜV NORD Test Mark
– SUITABLE FOR ALLERGIC PEOPLE –
Foam Mattress tested for allergens and harmful substances
(as at 02/11)
I
General
The aim of these tests, which are performed on a voluntary basis for the manufacturer,
is to make an assessment in terms of material composition and indoor air hygiene of interior plaster with regard to sanitary harmlessness.
To reach this aim, the total product is tested for its allergenic potential and its toxic potential.
II Basis for the test
The tests and examinations to be performed before the TÜV NORD test mark is issued
are based on the recognised technical rules and standards, such as ISO and DIN standards and VDI regulations. In addition, the recognised medical / allergological test
methods relevant to dealing with such problems are used.
The tests and examinations are conducted among other things in accordance with
1)
VDI guideline 2100, Part 1 - 4, "Gaseous ambient air pollution measurement - Indoor air pollution measurement - Gas chromatographic determination of organic
compounds"
2)
DIN 38405-24 (DEV D24), "German standard methods for the examination of water,
waste water and sludge; anions (group D); photometric determination of chromium(VI) using 1,5-diphenylcarbonohydrazide "
Z:\Pool_3.3\pbe\RLH\TN Test Criteria 2011\TAC Foam Mattress 2-11.doc
Scope of Test and Assessment Criteria for the Issue of the TÜV NORD Test Mark
SUITABLE FOR ALLERGIC PEOPLE
Foam mattress tested for allergens and harmful substances (as at 02/11)
page 2 of 18
3)
DIN 38406 – E29, "Water quality – Application of inductively coupled plasma mass
spectrometra (ICP-MS); determination of 62 elements"
4)
DIN 38407-2, "German standard methods for the determination of water, waste water and sludge; jointly determinable substances (group F); determination of low volatile halogenated hydrocarbons by gas chromatography (F 2)"
5)
DIN 38407-13, "German standard methods for the determination of water, waste
water and sludge; jointly determinable substances (group F); determination of selected organotin compounds by gas chromatography (F 13)"
6)
DIN 38414-4 (DEV S4), "German standard methods for the examination of water,
waste water and sludge; sludge and sediments (group S); determination of leachability by water (S 4)"
7)
DIN 53803-1, "Sampling; statistical basis; one-way layout"
8)
DIN 53803-2, "Sampling; practical execution"
9)
DIN 54231,"Textiles – Detection of disperse dyestuffs"
10) DIN EN 12673, "Water quality - Gas chromatographic determination of some selected chlorophenols in water"
11) DIN EN 14362-1, "Textiles – Methods for determination of certain aromatic amines
derived from azo colorants - Part 1: Detection of the use of certain azo colorants accessible with and without extracting the fibres"
12) DIN ISO 16000-3, "Indoor air - Part 3: Determination of formaldehyde and other
carbonyl compounds; Active sampling method"
13) DIN ISO 16000-6, "Indoor air - Part 6: Determination of volatile organic compounds
in indoor and test chamber air by active sampling on Tenax TA® sorbent, thermal
desorption and gas chromatography using MS/FID"
14) DIN EN ISO 105 –E04, "Textiles – Tests for colour fastness – Part E04: Colour fastness to perspiration"
15) DIN EN ISO 6468, "Water quality - Determination of certain organochlorine insecticides, polychlorinated biphenyls and chlorobenzenes - Gas-chromatographic
method after liquid-liquid extraction"
16) DIN EN ISO 10301, "Water quality - Determination of highly volatile halogenated
hydrocarbons - Gas-chromatographic methods"
17) DIN EN ISO 10695, "Water quality - Determination of selected organic nitrogen and
phosphorus compounds - Gas chromatographic methods"
18) DIN EN ISO 11369, "Water quality - Determination of selected plant treatment
agents - Method using high performance liquid chromatography with UV detection
after solid-liquid extraction"
19) DIN EN ISO 16000-9: "Indoor air – Part 9: Determination of the emission of volatile
organic compounds from building products and furnishing – Emission test chamber
method"
20) DIN EN ISO 16000-11, "Indoor air – Part 11: Determination of the emission of volatile organic compounds from building products and furnishing - Sampling, storage of
samples and preparation of test specimens"
21) DIN EN ISO 18856, "Water quality - Determination of selected phthalates using gas
chromatography/mass spectrometry"
page 3 of 18
22) TRGS 402, "Determination and assessment of the concentrations of airborne hazardous substances in working areas"
23) TRGS 905, "Directory of carcinogenic, mutagenic or teratogenic substances"
24) WHO, "Air Quality Guidelines"
25) German Research Foundation, Senate Commission on the Investigation of Health
Hazards of Chemical Compounds in the Work Area: "MAK and BAT Value Lists”
26) DFG S19, "Multimethod for the determination of pesticides, biocides, fungicides, insecticides, herbicides, wood preservatives"
27) Basophile Degranulation Test (BDT) for the estimation of the allergenic potential after extraction by means of blood samples of allergenic people and control samples
28) AgBB: Health-related Evaluation of Emissions of Volatile Organic Compounds (VOC
and SVOC) from Building Products
29) Federal Environment Agency’s German-language guidebook on mould "Leitfaden
zur Vorbeugung, Untersuchung, Bewertung und Sanierung von Schimmelpilzwachstum in Innenräumen"
30) Health department of the German federal state Baden-Württemberg – guidebook on
mould: "Schimmelpilze in Innenräumen – Nachweis, Bewertung, Qualitätsmanagement"
31) ZEK 01.1-08, "Testing and Validation of Polycyclic Aromatic Hydrocarbons (PAH) in
the course of GS-Mark Certification"
32) B82.02-2 (LMBG), "Test method for the detection of certain azo dyes on dyed textiles"
33) B80.68-1 (LMBG), "Determination of monomeric acrylnitrile in polymerides"
34) OSHA 42/47, "DIISOCYANATES, 1,6-HEXAMETHYLENE DIISOCYANATE (HDI),
TOLUENE-2,6-DIISOCYANATE (2,6-TDI), TOLUENE-2,4-DIISOCYANATE (2,4TDI)"
35) Order for conformance of the Ordinance on Hazardous Substance to the EC directive 98/24/EC and other EC directives (Verordnung zum Schutz vor Gefahrstoffen
(Gefahrstoffverordnung – GefStoffV))
36) Directive 67/548/EEC, Council directive of 27th June 1967 on the approximation of
laws, regulations and administrative provisions relating to the classification, packaging and labeling of dangerous substances
page 4 of 18
III
Basic tests
1
Measurement of the allergenic potential
All ticking, foam components, adhesives as well as the total product are determined using
the Basophile Degranulation Test.
2
Investigations of the total product regarding the toxicological harmlessness
Preliminary remarks
1. All tests are performed on representative complete product samples.
2. For substances according to the test points III.2.7.1 to III.2.7.7 emission chamber tests
are performed after 72 hours and – if necessary – after 28 days. The examined sample is under pulsation load.
3. Substances according to the test point III.2.7 which are determined by screening are
quantified by internal or external standards; only substances for which no standards are
available a semi-quantitative estimation of their concentrations is done. In this case, the
peak areas are interpreted by toluene equivalents.
2.1 Biocides, chlorophenoles, alkyltin compounds, flame retardants (cf. Annex 1)
Methods
• Biocides: Analysis according to DIN 38407-2, DIN EN ISO 6468, DIN EN ISO
10695, DIN EN ISO 11369, DFG S19
• Chlorophenoles, orthophenylphenols: Analysis according to DIN EN 12673, DFG S19
• Alkyltin compounds(if the total tin content (Sn) > 10 mg/kg (cf. V.6)): Analysis according to DIN
38407-13
• Flame retardants: according to DFG S19, Analysis by GC-MS
2.2 Material testing for CMR compounds according to Annex I of the directive
67/548/EEC resp. according to § 4a par. 3 of the Ordinance on Hazardous
Substances and to TRGS 905 – EU-classes 1 and 2 (cf. Annex 2 (a))
Methods
Analysis according to ZEK 01.1-08, B80.68-1 (LMBG), DIN EN 14362-1, GC-MS
2.3 Phthalate
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•
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•
•
•
•
•
•
•
•
•
•
•
Dimethyl phthalate (DMP), CAS-No.: 131-11-3
Diethyl phthalate (DEP), CAS-No.: 84-66-2
Dipropyl phthalate (BPP), CAS-No.: 131-16-8
Dibutyl phthalate (DBP), CAS-No.: 84-74-2
Diisobutyl phthalate (DIBP), CAS-No.: 84-69-5
Butylbenzyl phthalate (BBP), CAS-No.: 85-68-7
Dicyclohexyl phthalate (DCHP), CAS-No.: 84-61-7
Diphenyl phthalate (DPP), CAS-No.: 84-62-8
Di-heptyl phthalate (DHP), CAS-No.: 3648-21-3
Di(2-Ethylhexyl) phthalate (DEHP), CAS-No.: 117-81-7
Di-n-octyl phthalate (DNOP), CAS-No.: 117-84-0
Didecyl phthalate (DDP), CAS-No.: 84-77-5
Diisononyl phthalate (DINP),CAS-No.: 68515-48-0
Diisodecyl phthalate (DIDP), CAS-No.: 26761-40-0
page 5 of 18
Methods
Analysis according to DIN EN ISO 18856, extraction in ethyl acetate, analysis by GC/ MS
2.4 Toxicologically questionable dyes (cf. Annex 3)
• Aryl amines originated from azo dyes
• Carcinogenic dyes
• Allergenic dyes
Methods
Analysis according to B82.02-2(LMBG) and DIN 54231 (mod.)
2.5 Heavy metals
• Antimony
• Arsenic
• Lead
• Cadmium
• Chromium
• Chromate (Cr VI)
• Cobalt
• Copper
• Nickel
• Mercury
• Tin (as parameter for alkyltin compounds)
Methods
• Preparation of an acidic perspiration dissolution according to DIN EN ISO 105-E04
• Elution according to DIN 38414-4
• Heavy metals in general: DIN 38406-E29
• Chromate (Cr VI): DIN 38405-24
• Total digestion with nitric acid / microwave
• Lead, Cadmium: DIN 38406-E29
2.6 Polycyclic aromatic hydrocarbons – PAH (cf. Annex 4)
Methods
According to ZEK 01.1-08. Analysis by GC-MS.
2.7 Gaseous emissions
2.7.1 Aldehydes and ketones (cf. Annex 5)
2.7.2 BTXES compounds
• Benzene
• Toluene
• Xylene
• Ethylbenzene
• Styrene
2.7.3 Isocyanates
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•
•
•
Diphenylmethane diisocyanate (MDI); CAS-No.: 101-68-8
Toluyl-2,4-diisocyanate (TDI); CAS-No.: 584-84-9
Toluyl-2,6-diisocyanate (TDI); CAS-No.: 91-08-7
Hexamethylene diisocyanate (HDI); CAS-No.: 822-06-0
page 6 of 18
2.7.4 Material testing for CMR compounds according to Annex I of the directive
67/548/EEC resp. according to § 4a par. 3 of the Ordinance on Hazardous Substances and to TRGS 905 – EU-classes 1 and 2 (cf. Annex 2 (b))
2.7.5 Miscellaneous compounds
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4-Vinylcyclohexene; CAS-No.: 100-40-3
4-Phenylcyclohexene; CAS-No.: 4994-16-5
Butadiene; CAS-No.: 106-99-0
Vinyl chloride; CAS-No.: 75-01-4
2.7.6 Sum of aromatic hydrocarbons
2.7.7 Sum of volatile organic compounds according to Annex 6 and TVOC
2.7.8 Tests according to the AgBB scheme
Methods
• All gaseous emissions: Emission chamber test
• Aldehydes and ketones: Adsorption on Silica conditioned with 2,4-Dinitrophenyl hydrazine according to DIN ISO 16000-3, analysis by HPLC
• BTXES compounds: Adsorption on active carbon, analysis by GC-MS, according to
VDI 2100-2 and/or DIN ISO 16000-6
• 1,3-Butadiene, Vinyl chloride: Adsorption on active carbon, analysis according to
VDI 2100-2 with GC-MS
• Isocyanates: Adsorption on a special glass filter, derivatization, analysis according
to OSHA 42/47
• Aromatic hydrocarbons and TVOC: Analysis by GC-MS, according to VDI 2100-2
and/or DIN ISO 16000-6
IV
Test mark
1 Taking the results as per III and provided the assessment criteria specified in V are
fulfilled, TÜV NORD hereby grants permission to use the TÜV NORD test mark.
2 TÜV NORD will draw up a certificate and release it for duplication for informative
and marketing purposes.
3 The scope of services to be provided by TÜV NORD relates to the foam mattress
submitted for testing. If there are changes in the product, esp. changes of material
components, which could have an impact on the allergological or toxicological characteristics of the product, the basis tests described in III must be performed again.
4 Use of the TÜV NORD test mark involves an annual test of a sample of the foam
mattress taken from production or storage by TÜV NORD.
5 Changes of the composition of the foam mattress , which have no impact regarding
the allergolocical and toxicological characteristics of the product, are tested free of
additional charge in the scope of services provided for the periodic tests.
6 If defects are found during the periodic tests, they must be rectified within three
months.
page 7 of 18
V Assessment criteria
The foam mattress is assessed as part of an interdisciplinary expert appraisal taking account of the current state of recognized environmental-medical threshold values for material and air constituents.
The results of the emission chamber tests – cf. paragraphs V.8 and V.9 – are equivalent
to the reference room of 17,4 m³ according to DIN EN ISO 16000–9 because of the adjusted loading and air change rates.
The following criteria must be fulfilled before the TÜV NORD test mark is awarded:
1
Allergic potential of the total product and of selected components (III.1):
• Basophile Degranulation Test < 15 % (plus < control)
2
Biocides, chlorophenoles, alkyltin compounds, flame retardants (III.2.1)
• The sum of biocides according to Annex 1 must not exceed 0,5 mg/kg.
• Chlorophenols and OPP according to Annex 1 are limited as follows:
- Pentachlorophenol (PCP) .............................................................. < 0,05 mg/kg
- 2,3,5,6-Tetrachlorophenol (TeCP) ................................................. < 0,05 mg/kg
- Orthophenyl phenol (OPP) ............................................................. < 0,50 mg/kg
• The flame retardants specified in Annex 1 must not be present in the product, i.
e. they must be below the following determination limits:
- TRIS, TEPA ................................................................................... < 1,0 mg/kg
- TBP, TCEP, TCPP, TDCP, TBEP, TEHP, TPP, TKP .................... < 0,5 mg/kg
• Alkyltin compounds according to Annex 1 are limited as follows:
- Sum of alkyltin compounds according to Annex 1 .......................... < 10
3
mg/kg
CMR Substances and noxae (III.2.2)
The material must not contain
• compounds listed in Annex I of the directive 67/548/EEC resp. compounds
listed according to § 4a Par. 3 GefStoffV as very toxic, toxic, carcinogenic, mutagenic or reprotoxic,
• compounds listed in TRGS 905 or in MAK-value list of the DFG as follows:
a) carcinogenic acc. to EU-categories Carc.Cat. 1, Carc.Cat. 2, or Carc.Cat. 3
resp. acc. to MAK classifications K1, K2 or K3 or
b) mutagenic acc. to EU-categories Mut.Cat. 1, Mut.Cat. 2, or Mut.Cat. 3 resp.
acc. to MAK classifications M1, M2 or M3 or
c) reprotoxic acc. to EU-categories Repr.Cat. 1, Repr.Cat. 2 or Repr.Cat. 3
resp. to MAK classifications RE/F1, RE/F2 or RE/F3.
I. e. the compounds of Annex 2(a) must not be present in the product.
Limits of detection:
• Acrylamid .............................................................................................. 0,05 mg/kg
• Acrylonitrile ........................................................................................... 0,05 mg/kg
• Aniline ................................................................................................... 0,01 mg/kg
page 8 of 18
•
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•
•
•
4
2-Methoxy ethanol ................................................................................
2-Ethoxy ethanol ...................................................................................
2-Methoxyethyl acetate ........................................................................
2-Ethoxy ethyl acetate ..........................................................................
2-Methoxy-1-propanol ..........................................................................
2-Methoxy-1-propyl acetate ..................................................................
0,1 mg/kg
0,1 mg/kg
0,1 mg/kg
0,1 mg/kg
0,1 mg/kg
0,1 mg/kg
Phthalates (III.2.3)
• The phthalates DEHP, BBP, DBP, DNOP, DINP and DIDP must not be detectable.
Limit of detection: 1 mg/kg
• The sum of further phthalates must not exceed 1.000 mg/kg.
5
Dyes (III.2.4)
The dyes listed in Annex 3 must not be present in the product, i.e. they must be below the detection limits specified below:
• Aryl amines originated from azo dyes .............................................. < 30 mg/kg
• Carcinogenic dyes ........................................................................... < 30 mg/kg
• Allergenic dyes ................................................................................ < 30 mg/kg
6
Heavy metals (III.2.5)
a) Elution with an acidic perspiration dissolution
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Antimony ......................................................................................
Arsenic .........................................................................................
Lead ............................................................................................
Cadmium .....................................................................................
Chromium ....................................................................................
Chromate (Cr VI) must not be present in the product; limit of detection:
Cobalt ..........................................................................................
Copper .........................................................................................
Nickel ...........................................................................................
Mercury ........................................................................................
Tin ................................................................................................
< 1,0 mg/kg
< 2,0 mg/kg
< 1,0 mg/kg
< 1,0 mg/kg
< 2,0 mg/kg
0,2 mg/kg
< 1,0 mg/kg
< 5,0 mg/kg
< 5,0 mg/kg
< 0,5 mg/kg
not applicable *)
*) Parameter for Alkyltin compounds, cf. III.2.1
b) Total digestion
• Lead ............................................................................................
• Cadmium .....................................................................................
7
< 90,0 mg/kg
<100,0 mg/kg
Polycyclic aromatic hydrocarbons (III.2.6)
• Benzo(a)pyrene ................................................................................. ≤ 0,01 mg/kg
• Naphthalene ...................................................................................... ≤ 0,01 mg/kg
• Sum of PAH (EPA) ........................................................................... ≤ 10 mg/kg
page 9 of 18
8
Gaseous emissions after 72 hours (III.2.7)
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Formaldehyde ..................................................................................
Sum of other aldehydes and ketones ...............................................
Benzene ..........................................................................................
Toluene ............................................................................................
Xylene ..............................................................................................
Ethylbenzene ...................................................................................
Styrene ............................................................................................
Vinylcyclohexene .............................................................................
4-phenylcyclohexene .......................................................................
Butadiene ........................................................................................
Vinyl chloride ...................................................................................
Isocyanates must not be detectable; detection limit .........................
Sum of aromatic hydrocarbons ........................................................
Sum of volatile organic compounds acc. to Annex 6 ........................
3
< 50 µg/m
3
< 400 µg/m
3
< 1,0 µg/m
< 10 µg/m3
< 10 µg/m3
< 10 µg/m3
3
< 1,0 µg/m
3
< 1,0 µg/m
< 1,0 µg/m3
< 1,0 µg/m3
< 1,0 µg/m3
< 0,05 µg/m3
< 10 µg/m3
< 100 µg/m3
CMR substances
The compounds in Annex 2(b) must not be emitted by the product.
Limits of detection:
• Naphthalene .........................................................................................
• 2-Methoxyethanol .................................................................................
• 2-Ethoxyethanol ....................................................................................
• 2-Methoxyethyl acetate ........................................................................
• 2-Ethoxyethyl acetate ...........................................................................
• 2-Methoxy-1-propanol ..........................................................................
• 2-Methoxy-1-propyl acetate ..................................................................
9
< 1,0 µg/m³
< 100 µg/m³
< 100 µg/m³
< 100 µg/m³
< 100 µg/m³
< 100 µg/m³
< 100 µg/m³
Gaseous emissions after 28 days (III.2.7)
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Formaldehyde ................................................................................
Sum of other aldehydes and ketones .............................................
Sum of aromatic hydrocarbons ........................................................
Sum of volatile organic compounds acc. to Annex 6 ......................
AgBB – TVOC ...............................................................................
AgBB – SVOC ...............................................................................
AgBB – non-evaluable compounds ................................................
AgBB – NIK compounds (index R) .................................................
< 10 µg/m3
≤ 100 µg/m³
< 10 µg/m3
< 50 µg/m3
< 1.000 µg/m3
< 100 µg/m3
< 100 µg/m3
<1
If the emission results comply to the 28-days limits before then, the emission chamber test may be stopped earlier.
Annex 1
page 10 of 18
Biocides, preservatives, flame retardants (III.2.1)
Pesticides, herbicides
2,4,5-Trichloro-phenoxy acetic acid (2,4,5-T)
2,4-Dichloro-phenoxy acetic acid (2,4-D)
Azinophosmethyl
Azinophosethyl
Aldrin
Bromophos-ethyl
Captafol
Carbaryl
Chlordane
Chlordimeform
Chlorfenvinphos
Coumaphos
Cyfluthrin
Cyhalothrin
Cypermethrin
Tributyltrithio phosphate (DEF)
Deltamethrin
Dichlorodiphenyldichloro ethane (DDD)
Dichlorodiphenyldichloro ethylene (DDE)
Dichlorodiphenyltrichloro ethane (DDT)
Diazinon
Dichloroprop
Dicrotophos
Dieldrin
Dimethoat
Dinoseb and salts
α-Endosulfan
β-Endosulfan
Endrin
Esfenvalerat
Fenvalerat
Heptachloro
Trans-Heptachlorepoxid
Hexachloro benzene
α-Hexachloro cyclohexane
β-Hexachloro cyclohexane
δ-Hexachloro cyclohexane
ε- Hexachloro cyclohexane
Lindan (γ- Hexachloro cyclohexane)
Malathion
Methyl chlorophenoxy acetic acid (MCPA)
Methyl chlorophenoxy butanoic acid (MCBA)
Mecoprop
CAS-No.: 93-76-5
CAS-No.: 94-75-7
CAS-No.: 86-50-0
CAS-No.: 2642-71-9
CAS-No.: 309-00-2
CAS-No.: 4824-78-6
CAS-No.: 2425-06-1
CAS-No.: 63-25-3
CAS-No.: 57-74-9
CAS-No.: 1970-95-9
CAS-No.: 470-90-6
CAS-No.: 56-72-4
CAS-No.: 68359-37-5
CAS-No.: 91465-08-6
CAS-No.: 52315-07-8
CAS-No.: 78-48-8
CAS-No.: 52918-63-5
CAS-No.: 53-19-0, 72-54-8
CAS-No.: 3424-82-6, 72-55-9
CAS-No.: 50-29-3, 789-02-6
CAS-No.: 333-41-5
CAS-No.: 120-36-2
CAS-No.: 141-66-2
CAS-No.: 60-57-1
CAS-No.: 60-51-5
CAS-No.: 88-85-7
CAS-No.: 115-29-7
CAS-No.: 33213-65-9
CAS-No.: 72-20-8
CAS-No.: 66230-04-4
CAS-No.: 51630-58-1
CAS-No.: 76-44-8
CAS-No.: 1024-57-3
CAS-No.: 118-74-1
CAS-No.: 319-84-6
CAS-No.: 319-85-7
CAS-No.: 319-86-8
CAS-No.: 6108-10-7
CAS-No.: 58-89-9
CAS-No.: 121-75-5
CAS-No.: 94-74-6
CAS-No.: 94-81-5
CAS-No.: 93-65-2
Annex 1
page 11 of 18
Metamidophos
Methoxychloro
Mirex
Monocrotophos
Parathion-methyl
Parathion-ethyl
Permethrin
Phosdrin / Mevinphos
Propethamphos
Profenophos
Quinalphos
Toxaphen (Camphechloro)
Trifluralin
CAS-Nr.: 10265-92-6
CAS-No.: 72-43-5
CAS-No.: 2385-85-5
CAS-No.: 6923-22-4
CAS-No.: 298-00-0
CAS-No.: 56-38-2
CAS-No.: 52645-53-1
CAS-No.: 7786-34-7
CAS-No.: 31218-83-4
CAS-No.: 41198-08-7
CAS-No.: 13593-03-8
CAS-No.: 8001-35-2
CAS-No.: 1582-09-8
Chlorophenoles and OPP
Pentachlorophenol (PCP)
2, 3, 5, 6-Tetrachlorophenol (TeCP)
Orthophenylphenol (OPP)
CAS-No.: 87-86-5
CAS-No.: 25167-83-3
CAS-No.: 90-43-7
Alkytin compounds
Monobutyltin
Dibutyltin
Tributyltin
Monooctyltin
Dioctyltin
Trioctyltin
Triphenyltin
CAS-No.: 78763-54-9
CAS-No.: 14488-53-0
CAS-No.: 36643-28-4
CAS-No.: 94410-07-8
CAS-No.: 250252-87-0
CAS-No.: nonexistent
CAS-No.: 668-34-8
Flame retardants
Tris-(2,3-dibrompropyl)phosphate (TRIS)
Tris-(aziridinyl)phosphinoxide (TEPA)
Tributylphosphate (TBP)
Tris(2-chloroethyl)phosphate (TCEP)
Tris(chloropropyl)phosphate (TCPP)
Tris(dichloropropyl)phosphate (TDCPP)
Tris(2-butoxyethyl)phosphate (TBEP)
Tris(2-ethylhexyl)phosphate (TEHP)
Triphenylphosphate (TPP)
Tricresyl phosphate (TKP)
CAS-No.: 126-72-7
CAS-No.: 5455-55-1
CAS-No.: 126-73-8
CAS-No.: 115-96-8
CAS-No.: 26248-87-3
CAS-No.: 13674-87-8
CAS-No.: 78-51-3
CAS-No.: 78-42-2
CAS-No.: 115-86-6
CAS-No.: 1330-78-5
Annex 2
page 12 of 18
Carcinogenic, mutagenic and reprotoxic compounds (III.2.2 and III.2.7)
(a) Material testing (III.2.2)
Acrylamid (K2, M2, R3)
Acrylonitrile (K3)
Aniline (K3)
2-Methoxyethanol (R2)
2-Ethoxyethanol (R2)
2-Methoxyethyl acetate (R2)
2-Ethoxyethyl acetate (R2)
2-Methoxy-1-propanol (R2
2-Methoxy-1-propyl acetate (R2)
CAS-No.: 79-06-1
CAS-No.: 107-13-1
CAS-No.: 62-53-3
CAS-No.: 109-86-4
CAS-No.: 110-80-5
CAS-No.: 110-49-6
CAS-No.: 11-15-9
CAS-No.: 1589-47-5
CAS-No.: 70657-70-4
(b) Emission chamber tests (III.2.7)
Naphthalene (K3)
2-Methoxyethanol (R2)
2-Ethoxyethanol (R2)
2-Methoxyethyl acetate (R2)
2-Ethoxyethyl acetate (R2)
2-Methoxy-1-propanol (R2)
2-Methoxy-1-propyl acetate (R2)
CAS-No.: 91-20-3
CAS-No.: 109-86-4
CAS-No.: 110-80-5
CAS-No.: 110-49-6
CAS-No.: 11-15-9
CAS-No.: 1589-47-5
CAS-No.: 70657-70-4
Annex 3
page 13 of 18
Toxicologically questionable dyes (III.2.4)
Aryl amines originated from azo dyes
4-aminodiphenyl
Benzidine
4-chlor-o-toluidine
2-naphthylamine
o-aminoazotoluene
2-amino-4-nitrotoluene
p-chloroaniline
2,4-diaminoanisole
4,4'-diaminodiphenylmethane
3,3'-dichlorobenzidine
3,3'-dimethoxybenzidine
3,3'-dimethylbenzidine
3,3'-dimethyl-4,4'-diaminodiphenylmethane
p-cresidine
4,4'-methylene-bis-(2-chloraniline)
4,4'-oxydianiline
4,4'-thiodianiline
o-toluidine
2,4-toluylenediamine
2,4,5-trimethylaniline
o-anisidine
2,4-xylidine
2,6-xylidine
CAS-No.: 92-67-1
CAS-No.: 92-87-5
CAS-No.: 95-69-2
CAS-No.: 91-59-8
CAS-No.: 97-56-3
CAS-No.: 99-55-8
CAS-No.: 106-47-8
CAS-No.: 615-05-4
CAS-No.: 101-77-9
CAS-No.: 91-94-1
CAS-No.: 119-90-4
CAS-No.: 119-93-7
CAS-No.: 838-88-0
CAS-No.: 120-71-8
CAS-No.: 101-14-4
CAS-No.: 101-80-4
CAS-No.: 139-65-1
CAS-No.: 95-53-4
CAS-No.: 95-80-7
CAS-No.: 137-17-7
CAS-No.: 90-04-0
CAS-No.: 95-68-1
CAS-No.: 87-62-7
Carcinogenic dyes
C.I. Acid Red 26 (C.I. 16150)
C.I. Basic Red 9 (C.I. 42500)
C.I. Direct Black 38 (C.I. 30235)
C.I. Direct Blue 6 (C.I. 22610)
C.I. Direct Red 28 (C.I. 22120)
C.I. Disperse Blue 1 (C.I. 64500)
C.I. Disperse Yellow 3 (C.I. 1855)
CAS-No.: 3761-53-3
CAS-No.: 25620-78-4
CAS-No.: 1937-37-7
CAS-No.: 2602-46-2
CAS-No.: 573-58-0
CAS-No.: 2475-45-8
CAS-No.: 2832-40-8
Annex 3
page 14 of 18
Allergenic dyes
C.I. Disperse Blue 35
C.I. Disperse Orange 1 (C.I. 11080)
C.I. Disperse Orange 3 (C.I. 11005)
C.I. Disperse Orange 37
C.I. Disperse Orange 76
C.I. Disperse Red 1 (C.I. 11110)
C.I. Disperse Yellow 39
C.I. Disperse Yellow 49
CAS-No.: 2475-45-8
CAS-No.: 2475-46-9
CAS-No.: 3179-90-6
CAS-No.:3860-63-7
CAS-No.:12222-75-2
CAS-No.:12222-97-8
CAS-No.:12223-01-7
CAS-No.:61951-51-7
CAS-No.: 2581-69-3
CAS-No.: 730-40 5
CAS-No.:12223-33-5
CAS-No.:13301-61-6
CAS-No.: 2872-52-8
CAS-No.: 2872-48-2
CAS-No.: 3179-89-3
CAS-No.:119-15-3
CAS-No.: 2832-40-8
CAS-No.: 6373-73-5
CAS-No.:12236-29-2
CAS-No.:54824-37-2
Annex 4
page 15 of 18
Polycyclic aromatic hydrocarbons – PAH (III.2.6)
Naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Dibenzo(a,h)anthracene
Benzo(g,h,i)perylene
Indeno(1,2,3-c,d)pyrene
Sum of PAH (EPA)
CAS-No.: 91-20-3
CAS-No.: 208-96-8
CAS-No.: 83-32-9
CAS-No.: 86-73-7
CAS-No.: 85-01-8
CAS-No.: 120-12-7
CAS-No.: 206-44-0
CAS-No.: 129-00-0
CAS-No.: 56-55-3
CAS-No.: 218-01-9
CAS-No.: 205-99-2
CAS-No.: 207-08-9
CAS-No.: 50-32-8
CAS-No.: 53-70-3
CAS-No.: 191-24-2
CAS-No.: 193-39-5
-
Annex 5
page 16 of 18
Aldehydes and ketones (III.2.7.1)
Formaldehyde
Acetaldeyhde
Acrolein
Propionaldehyde
Butyraldehyde
Benzaldehyde
Valeraldehyde
3-methylbutanal
Hexanal
Heptanal
Octanal
Nonanal
Decanal
2,5-dimethyl-phenylmethanal
Pentandial (Glutardialdehyde)
Acetone
Cyclohexanone
o-Tolualdehyde
m-Tolualdehyde
p-Tolualdehyde
CAS-No.: 50-00-0
CAS-No.: 75-07-0
CAS-No.: 107-02-8
CAS-No.: 123-02-8
CAS-No.: 123-72-8
CAS-No.: 100-52-7
CAS-No.: 110-62-3
CAS-No.: 590-86-3
CAS-No.: 66-25-1
CAS-No.: 111-71-7
CAS-No.: 124-13-0
CAS-No.: 124-19-6
CAS-No.: 112-31-2
CAS-No.: 5779-94-2
CAS-No.: 111-30-8
CAS-No.: 67-64-1
CAS-No.: 108-94-1
CAS-No.: 529-20-4
CAS-No.: 620-23-5
CAS-No.: 104-87-0
Annex 6
page 17 of 18
Volatile organic compounds – VOC (III.2.7.7)
Aromates
Benzene
Toluene
Ethylbenzene
m-,p-Xylene
o-Xylene
Styrener
2-Ethyltoluene
3- Ethyltoluene
4-Ethyltoluene
n- Propylbenzene
Isopropylbenzene (Cumene)
1,3,5- Trimethylbenzene
Naphthalene
CAS-No.: 71-43-2
CAS-No.: 108-88-3
CAS-No.: 100-41-4
CAS-No.: 1330-20-7
CAS-No.: 1330-20-7
CAS-No.: 100-42-5
CAS-No.: 611-14-3
CAS-No.: 620-14-4
CAS-No.: 622-96-8
CAS-No.: 103-65-1
CAS-No.: 98-82-8
CAS-No.: 108-67-8
CAS-No.: 95-63-6
CAS-No.: 526-73-8
CAS-No.: 91-20-3
n-Alkanes / Aliphates C6-C17
n-Heptane
n-Octane
n-Nonane
n-Decane
n-Undecane
n-Dodecane
n-Tridecane
n-Tetradecane
n-Pentadecane
n-Hexadecane
n-Heptadecane
CAS-No.: 142-82-5
CAS-No.: 111-65-9
CAS-No.: 111-84-2
CAS-No.: 124-18-5
CAS-No.: 1120-21-4
CAS-No.: 112-40-3
CAS-No.: 629-50-5
CAS-No.: 629-59-4
CAS-No.: 629-62-9
CAS-No.: 544-76-3
CAS-No.: 629-78-7
Cycloalkanes / Cycloaliphates C6-C7
Methylcyclopentane
Cyclohexane
Methylcyclohexane
CAS-No.: 96-37-7
CAS-No.: 110-82-7
CAS-No.: 108-87-2
Alcoholes
2-Butanol
Iso-Butanol
n-Pentanol
n-Hexanol
Isoamylalcohol
2-Ethyl-1-hexanol
CAS-No.: 78-92-2
CAS-No.: 78-83-1
CAS-No.: 71-41-0
CAS-No.: 111-27-3
CAS-No.: 123-51-3
CAS-No.: 104-76-7
Ketones
Cyclopentanone
Tetrahydrofuran
2-Hexanone
Cyclohexanone
2-Heptanone
CAS-No.: 120-92-3
CAS-No.: 109-99-9
CAS-No.: 591-78-6
CAS-No.: 108-94-1
CAS-No.: 110-43-0
Annex 6
page 18 of 18
Esters / Acetates
Ethylacetate
n-Propylacetate
Iso-Propylacetate
n-Butylacetate
Isobutylacetate
Benzoic acid methyl ester
CAS-No.: 141-78-6
CAS-No.: 109-60-4
CAS-No.: 108-21-4
CAS-No.: 123-86-4
CAS-No.: 110-19-0
CAS-No.: 93-58-3
Chlorinated hydrocarbons
Trichloromethane
Bromodichloromethane
Dibromochloromethane
Tribromomethane
Tetrachloromethane
Trichloroethene
1,1,1-Trichloroethane
Tetrachloroethene
Chlorobenzene
m-Dichlorobenzene
p-Dichlorobenzene
o-Dichlorobenzene
CAS-No.: 67-66-3
CAS-No.: 75-27-4
CAS-No.: 124-48-1
CAS-No.: 75-25-2
CAS-No.: 56-23-5
CAS-No.: 79-01-6
CAS-No.: 71-55-6
CAS-No.: 127-18-4
CAS-No.: 108-90-7
CAS-No.: 541-73-1
CAS-No.: 106-46-7
CAS-No.: 95-50-1
Terpenes
α-Pinene
β-Pinene
3-Carene
Limonene
α-Terpinene
Camphor
CAS-No.: 80-56-8
CAS-No.: 18172-67-3
CAS-No.: 13466-78-9
CAS-No.: 5989-27-5
CAS-No.: 99-86-5
CAS-No.: 76-22-2
Siloxanes
Hexamethylcyclotrisiloxane
Octamethylcyclotetrasiloxane
Decamethylcyclopentasiloxane
Sum of VOC
CAS-No.: 541-05-9
CAS-No.: 556-67-2
CAS-No.: 541-02-6

Scope of Test and Assessment Criteria – SUITABLE FOR ALLERGIC PEOPLE

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