Diesel Reference Fuel T-28 - Chevron Phillips Chemical Company

Transcription

SAFETY DATA SHEET
Diesel Reference Fuel T-28
Version 1.10
Revision Date 2014-12-17
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product information
Product Name
Material
:
:
1024272, 1108916, 1024276, 1024273, 1024274, 1024275,
1032194
EC-No.Registration number
Chemical Name
Diesel fuel
Kerosene C9-C16
Distillates (petroleum),
Hydrotreated light
Paraffinic
CAS-No.
EC-No.
Index No.
68476-34-6
270-676-1
649-227-00-2
8008-20-6
232-366-4
649-404-00-4
64742-55-8
265-158-7
649-468-00-3
Legal Entity
Registration number
Chevron Phillips Chemicals International NV
01-2119475502-40-0023
Pre-Registered
01-2119487077-29-0013
Company
:
Chevron Phillips Chemical Company LP
Specialty Chemicals
10001 Six Pines Drive
The Woodlands, TX 77380
Local
:
Chevron Phillips Chemicals International N.V.
Brusselsesteenweg 355
B-3090 Overijse
Belgium
SDS Requests: (800) 852-5530
Technical Information: (832) 813-4862
Responsible Party: Product Safety Group
Email:[email protected]
Emergency telephone:
Health:
866.442.9628 (North America)
1.832.813.4984 (International)
Transport:
North America: CHEMTREC 800.424.9300 or 703.527.3887
Asia: +800 CHEMCALL (+800 2436 2255) China:+86-21-22157316
EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax)
MSDS Number:100000100097
1/17
SAFETY DATA SHEET
Version 1.10
South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600
Responsible Department
E-mail address
Website
:
:
:
Product Safety and Toxicology Group
[email protected]
www.CPChem.com
SECTION 2: Hazards identification
Classification of the substance or mixture
REGULATION (EC) No 1272/2008
Flammable liquids, Category 3
Skin irritation, Category 2
Carcinogenicity, Category 2
Specific target organ systemic toxicity single exposure, Category 3
Specific target organ systemic toxicity repeated exposure, Category 2
Aspiration hazard, Category 1
Chronic aquatic toxicity, Category 2
H226:
Flammable liquid and vapor.
H315:
Causes skin irritation.
H351:
Suspected of causing cancer.
H336:
May cause drowsiness or dizziness.
H373:
May cause damage to organs through prolonged or
repeated exposure.
H304:
May be fatal if swallowed and enters airways.
H411:
Toxic to aquatic life with long lasting effects.
Classification (67/548/EEC, 1999/45/EC)
Flammable
R10:
Flammable.
R45:
May cause cancer.
R65:
Harmful: may cause lung damage if swallowed.
R38:
Irritating to skin.
R67:
Vapors may cause drowsiness and dizziness.
R52/53:
Harmful to aquatic organisms, may cause longterm adverse effects in the aquatic environment.
Carcinogenic Category 2
Harmful
Irritant
Dangerous for the environment
Label elements
Labeling (REGULATION (EC) No 1272/2008)
Hazard pictograms
:
Signal Word
:
Danger
Hazard Statements
:
H226
H304
H315
H336
H351
May be fatal if swallowed and enters
airways.
2/17
SAFETY DATA SHEET
Version 1.10
H373
May cause damage to organs through
prolonged or repeated exposure.
H411
Precautionary Statements
:
Prevention:
P210
P260
P281
Response:
P301 + P310
P331
P370 + P378
Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
Do not breathe
dust/fume/gas/mist/vapor/spray.
Use personal protective equipment as
required.
IF SWALLOWED: Immediately call a
POISON CENTER or doctor/ physician.
Do NOT induce vomiting.
In case of fire: Use dry sand, dry chemical
or alcohol-resistant foam for extinction.
Hazardous ingredients which must be listed on the label:
Alkanes, C14-C16
 90622-46-1
Diesel fuel
 68476-34-6
Kerosene C9-C16
 8008-20-6
91-20-3
Naphthalene

SECTION 3: Composition/information on ingredients
Synonyms
:
Diesel Reference Fuel T
Diesel Reference Fuel T-25, T-26
Molecular formula
:
Mixture
Mixtures
Hazardous ingredients
Chemical Name
CAS-No.
EC-No.
Index No.
Classification
(67/548/EEC)
Diesel fuel
68476-34-6
270-676-1
649-227-00-2
Carc.Cat.3; R40
R38-R20-R51/53R65
Kerosene C9-C16
8008-20-6
232-366-4
649-404-00-4
Xn; R65
Classification
(REGULATION
(EC) No
1272/2008)
STOT RE 2; H373
Flam. Liq. 3; H226
Skin Irrit. 2; H315
Acute Tox. 2; H411
Acute Tox. 4; H332
Skin Irrit. 2; H315
Carc. 2; H351
STOT RE 2; H373
Asp. Tox. 1; H304
Aquatic Chronic 2;
H411
Flam. Liq. 3; H226
Skin Irrit. 2; H315
Asp. Tox. 1; H304
3/17
Concentration
[wt%]
0 - 40
0 - 30
SAFETY DATA SHEET
Version 1.10
Naphthalene
91-20-3
202-049-5
601-052-00-2
Carc.Cat.3; R40
Xn; R22
N; R50-R53
Flam. Sol. 2; H228
Acute Tox. 4; H302
Carc. 2; H351
STOT RE 1; H372
Aquatic Acute 1;
H400
Aquatic Chronic 1;
H410
1- 3
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4: First aid measures
General advice
:
Move out of dangerous area. Show this material safety data
sheet to the doctor in attendance. Material may produce a
serious, potentially fatal pneumonia if swallowed or vomited.
If inhaled
:
Consult a physician after significant exposure. If unconscious
place in recovery position and seek medical advice.
In case of skin contact
:
If skin irritation persists, call a physician. If on skin, rinse well
with water. If on clothes, remove clothes.
In case of eye contact
:
Flush eyes with water as a precaution. Remove contact
lenses. Protect unharmed eye. Keep eye wide open while
rinsing. If eye irritation persists, consult a specialist.
If swallowed
:
Keep respiratory tract clear. Do NOT induce vomiting. Do not
give milk or alcoholic beverages. Never give anything by
mouth to an unconscious person. If symptoms persist, call a
physician. Take victim immediately to hospital.
SECTION 5: Firefighting measures
Flash point
:
81,9 °C (179,4 °F)
Method: ASTM D 93
Autoignition temperature
:
No data available
Suitable extinguishing
media
:
Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical.
Unsuitable extinguishing
media
:
High volume water jet.
Specific hazards during fire
fighting
:
Do not allow run-off from fire fighting to enter drains or water
courses.
Special protective
equipment for fire-fighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Further information
:
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains. Fire residues and
contaminated fire extinguishing water must be disposed of in
4/17
SAFETY DATA SHEET
Version 1.10
accordance with local regulations. For safety reasons in case
of fire, cans should be stored separately in closed
containments. Use a water spray to cool fully closed
containers.
Fire and explosion
protection
:
Do not spray on an open flame or any other incandescent
material. Take necessary action to avoid static electricity
discharge (which might cause ignition of organic vapors).
Keep away from open flames, hot surfaces and sources of
ignition.
Hazardous decomposition
products
:
Hydrocarbons. Carbon oxides.
SECTION 6: Accidental release measures
Personal precautions
:
Use personal protective equipment. Ensure adequate
ventilation. Remove all sources of ignition. Evacuate
personnel to safe areas. Beware of vapors accumulating to
form explosive concentrations. Vapors can accumulate in low
areas.
Environmental precautions
:
Prevent product from entering drains. Prevent further leakage
or spillage if safe to do so. If the product contaminates rivers
and lakes or drains inform respective authorities.
Methods for cleaning up
:
Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
SECTION 7: Handling and storage
Handling
Advice on safe handling
:
Avoid formation of aerosol. Do not breathe vapors/dust. Avoid
exposure - obtain special instructions before use. Avoid
contact with skin and eyes. For personal protection see
section 8. Smoking, eating and drinking should be prohibited
in the application area. Take precautionary measures against
static discharges. Provide sufficient air exchange and/or
exhaust in work rooms. Open drum carefully as content may
be under pressure. Dispose of rinse water in accordance with
local and national regulations.
Advice on protection
against fire and explosion
:
Do not spray on an open flame or any other incandescent
material. Take necessary action to avoid static electricity
discharge (which might cause ignition of organic vapors).
Keep away from open flames, hot surfaces and sources of
ignition.
:
No smoking. Keep container tightly closed in a dry and wellventilated place. Containers which are opened must be
carefully resealed and kept upright to prevent leakage.
Observe label precautions. Electrical installations / working
Storage
Requirements for storage
areas and containers
5/17
SAFETY DATA SHEET
Version 1.10
materials must comply with the technological safety standards.
SECTION 8: Exposure controls/personal protection
Ingredients with workplace control parameters
SK
Súčast
Naphthalene
K
SI
Komponente
Naphthalene
EU
Podstata
Hodnota
Kontrolné parametre
Poznámka
K,
SK OEL
NPEL priemerný
10 ppm, 50 mg/m3
K,
SK OEL
NPEL krátkodobý
15 ppm, 80 mg/m3
Znamená, ze faktor môže byt' l'ahko absorbovaný kožou. Niektoré faktory, ktoré l'ahko prenikajú kožou, môžu spôsobovat' až
smrtel'né otravy, éasto bez varovných príznakov (napr. anilín, nitrobenzén, nitroglykol, fenoly a pod.). Pri látkach s významným
prienikom cez kožu, éi už v podobe kvapalín alebo pár, je osobitne dôležité zabránit' kožnému kontaktu.
Osnova
Vrednost
SI OEL
MV
European Union - mejna vednost določena na ravni Evropske unije
SE
Beståndsdelar
n-Tetradecane
Distillates (petroleum), Hydrotreated
light Paraffinic
Parametri nadzora
Pripomba
10 ppm, 50 mg/m3
EU,
Grundval
Värde
Kontrollparametrar
Anmärkning
SE AFS
SE AFS
NGV
KTV
350 mg/m3
500 mg/m3
18,
18,
SE AFS
NGV
350 mg/m3
18,
SE AFS
KTV
500 mg/m3
18,
38, 39,
SE AFS
NGV
1 mg/m3
38, 39,
SE AFS
KTV
3 mg/m3
18,
SE AFS
NGV
350 mg/m3
n-Pentadecane
18,
SE AFS
KTV
500 mg/m3
18,
SE AFS
NGV
350 mg/m3
n-Tridecane
18,
SE AFS
KTV
500 mg/m3
18,
SE AFS
NGV
350 mg/m3
n-Hexadecane
18,
SE AFS
KTV
500 mg/m3
SE AFS
NGV
10 ppm, 50 mg/m3
Naphthalene
SE AFS
KTV
15 ppm, 80 mg/m3
18 Gränsvärdet avser alifatiska kolväten i ångform, dvs. upp till 12 kolatomer. Vid exponering för kolväten med mer än 12 kolatomer,
som förekommer i form av aerosol, partiklar eller vätskedroppar, tillämpas gränsvärdet för organiskt damm och dimma 5 mg/m3.
Gränsvärdet gäller inte för aromatfri lacknafta (< 2 viktprocent) som har eget gränsvärde.
38 Vissa oljor ger vid upphettning upphov till polycykliska aromatiska kolväten som kan vara cancerframkallande. Dessutom kan
mineraloljor i sig innehålla sådana ämnen.
39 För dimma av vattenhaltig skärvätska eller dylikt, där även andra ämnen än oljor kan ingå, tillämpas värdet som totalhalt på den
vattenfria delen. För ämnen med enskilda lägre gränsvärden tillämpas dessa.
RO
Componente
light Paraffinic
Bază
Valoare
Parametri de control
RO OEL
TWA
5 mg/m3
Naphthalene
RO OEL
RO OEL
STEL
TWA
10 mg/m3
9,5 ppm, 50 mg/m3
PT
Componentes
Bases
Valor
Parâmetros de
controlo
Nota
PT OEL
PT OEL
VLE-MP
VLE-MP
100 mg/m3
200 mg/m3
P, A3,
PT OEL
VLE-MP
5 mg/m3
(O), ( ),
Fuels, diesel, no. 2
Kerosene C9-C16
light Paraffinic
Naphthalene
()
(1)
(O)
(P)
A3
A4
P
PT OEL
VLE_CD
10 mg/m3
PT OEL
VLE-MP
10 ppm,
PT OEL
VLE_CD
15 ppm,
PT DL 305/2007
oito horas
10 ppm, 50 mg/m3
Os valores ou características encontram-se propostos para alteração
Abrangido por legislação nacional específica ou por legislação comunitária não transposta
Amostragem realizada com um método que não recolha vapor
Aplicação restrita às condições nas quais são negligenciáveis as exposições a aerossóis
Agente carcinogénico confirmado nos animais de laboratório com relevância desconhecida no Homem.
Agente não classificável como carcinogénico no Homem.
Perigo de absorção cutânea
PL
Składniki
Kerosene C9-C16
Podstawa
Wartość
Parametry dotyczące
kontroli
PL NDS
NDS
100 mg/m3
6/17
Notă
P, A3, (P),
( ),
(1), P, A4,
(1), P, A4,
Uwaga
SAFETY DATA SHEET
Version 1.10
PL NDS
NDSch
300 mg/m3
light Paraffinic
PL NDS
NDS
5 mg/m3
Aerozol
NDSch
NDS
NDSch
10 mg/m3
20 mg/m3
50 mg/m3
Aerozol
Naphthalene
PL NDS
PL NDS
PL NDS
Nota
NO
Komponenter
n-Tetradecane
light Paraffinic
n-Pentadecane
n-Tridecane
n-Hexadecane
Naphthalene
NL
Bestanddelen
light Paraffinic
Naphthalene
Grunnlag
Verdi
Kontrollparametere
AN 361
TWA
40 ppm, 275 mg/m3
AN 361
TWA
40 ppm, 275 mg/m3
AN 361
AN 361
AN 361
AN 361
AN 361
AN 361
TWA
TWA
TWA
TWA
TWA
TWA
50 mg/m3
1 mg/m3
40 ppm, 275 mg/m3
40 ppm, 275 mg/m3
40 ppm, 275 mg/m3
10 ppm, 50 mg/m3
Damp
Tåke - partikler
Opmerking
Basis
Waarde
Controleparameters
NL MAC
TGG-8 uur
5 mg/m3
NL MAC
NL MAC
TGG-8 uur
TGG-15 min
50 mg/m3
80 mg/m3
MT
Ingredients
Naphthalene
Basis
Value
Control parameters
MT OEL
TWA
10 ppm, 50 mg/m3
LV
Sastāvdaļas
Naphthalene
Bāze
Vērtība
Pārvaldības parametri
LV OEL
AER 8 st
10 ppm, 50 mg/m3
LU
Composants
Base
Valeur
Paramètres de
contrôle
LU OEL
TWA
10 ppm, 50 mg/m3
Pagrindas, bazė
Vertė
Kontrolės parametrai
LT
LT
LT
LT
LT
LT
LT
LT
LT
LT
LT
IPRD
TPRD
IPRD
TPRD
IPRD
TPRD
IPRD
TPRD
IPRD
TPRD
IPRD
350 mg/m3
500 mg/m3
350 mg/m3
500 mg/m3
350 mg/m3
500 mg/m3
350 mg/m3
500 mg/m3
350 mg/m3
500 mg/m3
10 ppm, 50 mg/m3
Naphthalene
LT
Komponentai
n-Tetradecane
Kerosene C9-C16
n-Pentadecane
n-Tridecane
n-Hexadecane
Naphthalene
IE
Ingredients
Kerosene C9-C16
Naphthalene
HU
Komponensek
light Paraffinic
Naphthalene
b
EU1
i
k
OEL
OEL
OEL
OEL
OEL
OEL
OEL
OEL
OEL
OEL
OEL
Note
Piezīme
Note
Pastaba
Basis
Value
Control parameters
IE OEL
IE OEL
IE OEL
OELV - 8 hrs (TWA)
OELV - 8 hrs (TWA)
OELV - 15 min (STEL)
100 mg/m3
10 ppm, 50 mg/m3
15 ppm, 75 mg/m3
Note
Bázis
Érték
Ellenőrzési
paraméterek
Megjegyzés
HU OEL
MK-érték
5 mg/m3
k,
b, EU1, i,
HU OEL
AK-érték
50 mg/m3
b, EU1, i,
HU OEL
CK-érték
400 mg/m3
Bőrön át is felszívódik. Az ÁK-értékek a veszélyes anyagoknak ezt a tulajdonságát, illetve az ebből származó expozíciót csak a
levegőben megengedett koncentrációjuk mértékének megfelelően veszik figyelembe
91/322/EGK irányelvben közölt érték
Ingerlő anyag (izgatja a bőrt, nyálkahártyát, szemet vagy mindhármat)
Rákkeltő
GR
Συστατικά
Naphthalene
Βάση
Τιμή
Παράμετροι ελέγχου
GR OEL
TWA
10 ppm, 50 mg/m3
7/17
Σημείωση
SAFETY DATA SHEET
Version 1.10
FR
Composants
Naphthalene
C2
normal
Base
Valeur
FR VLE
VME
Substances preoccupantes en raison d'effets cancerogenes possibles
Valeurs limites indicatives
FI
Aineosat
Naphthalene
ES
Componentes
Naphthalene
vía dérmica
Paramètres de
contrôle
Note
10 ppm, 50 mg/m3
C2, normal,
Huomautus
Peruste
Arvo
Valvontaa koskevat
muuttujat
FI OEL
FI OEL
HTP-arvot 8h
HTP-arvot 15 min
1 ppm, 5 mg/m3
2 ppm, 10 mg/m3
Base
Valor
Parámetros de control
Nota
ES VLA
ES VLA
VLA-ED
VLA-EC
10 ppm, 53 mg/m3
15 ppm, 80 mg/m3
vía dérmica,
vía dérmica,
Alused
Väärtus
Kontrolliparameetrid
Märkused
Vía dérmica
EE
Komponendid, osad
n-Tetradecane
11,
Piirnorm
350 mg/m3
Lühiajalise
11,
EE OEL
500 mg/m3
kokkupuute piirnorm
EE OEL
Piirnorm
5 mg/m3
11,
EE OEL
Piirnorm
350 mg/m3
n-Pentadecane
Lühiajalise
11,
EE OEL
500 mg/m3
kokkupuute piirnorm
EE OEL
Piirnorm
5 mg/m3
EE OEL
Piirnorm
350 mg/m3
11,
n-Tridecane
Lühiajalise
11,
EE OEL
500 mg/m3
kokkupuute piirnorm
EE OEL
Piirnorm
5 mg/m3
11,
EE OEL
Piirnorm
350 mg/m3
n-Hexadecane
Lühiajalise
EE OEL
500 mg/m3
11,
kokkupuute piirnorm
EE OEL
Piirnorm
5 mg/m3
EE OEL
Piirnorm
10 ppm, 50 mg/m3
Naphthalene
11 Süsivesinike piirnormid on arvutatud auru faasile. Üle 12 süsinikuaatomiga alifaatsetel süsivesinikel (tridekaanid ja kõrgemad) on
20 °C juures küllastussisaldus < 350 mg/m3. Aerosoolsete süsivesinike piirnorm on 5 mg/m3.
DK
Komponenter
Kerosene C9-C16
light Paraffinic
Naphthalene
E
K
Basis
Værdi
Kontrolparametre
DK OEL
GV
25 ppm, 180 mg/m3
DK OEL
GV
1 mg/m3
DK OEL
GV
10 ppm, 50 mg/m3
At stoffet har en EF-grænseværdi
Betyder, at stoffet er optaget på listen over stoffer, der anses for at være kræftfremkaldende.
DE
Inhaltsstoffe
Naphthalene
11
AGS
H
Y
EE OEL
Grundlage
Wert
Zu überwachende
Parameter
DE TRGS 900
AGW
0,1 ppm, 0,5 mg/m3
Note
tåge og partikler
K, E,
Bemerkung
AGS, 11, H, Y, Dampf
und Aerosole,
einatembare Fraktion
Summe aus Dampf und Aerosolen.
Ausschuss für Gefahrstoffe
Hautresorptiv
Ein Risiko der Fruchtschädigung braucht bei Einhaltung des Arbeitsplatzgrenzwertes und des biologischen Grenzwertes (BGW)
nicht befürchtet zu werden
CZ
Složky
light Paraffinic
Naphthalene
Základ
Hodnota
Kontrolní parametry
Poznámka
CZ OEL
PEL
5 mg/m3
Aerosol
CZ OEL
CZ OEL
CZ OEL
NPK-P
PEL
NPK-P
10 mg/m3
50 mg/m3
100 mg/m3
Aerosol
Σημείωση
CY
Συστατικά
Naphthalene
Βάση
Τιμή
Παράμετροι ελέγχου
CY OEL
TWA
10 ppm, 50 mg/m3
CH
Inhaltsstoffe
Grundlage
Wert
Zu überwachende
Parameter
8/17
Bemerkung
SAFETY DATA SHEET
Version 1.10
Naphthalene
Carc.Cat.3
H
H, Carc.Cat.3,
CH SUVA
MAK-wert
10 ppm, 50 mg/m3
Krebserzeugende Stoffe Kategorie 3
Vergiftung durch Hautresorption möglich; Bei Stoffen, welche die Haut leicht zu durchdringen vermögen, kann durch die
zusätzliche Hautresorption die innere Belastung wesentlich höher werden als bei alleiniger Aufnahme durch die Atemwege.
BG
Компоненти
Основа
Стойност
Параметри на
контрол
Бележка
Kerosene C9-C16
Naphthalene
-
BG OEL
TWA
300 mg/m3
-,
BG OEL
TWA
50 mg/m3
-,
BG OEL
STEL
75 mg/m3
Химични агенти, за които са определени гранични стойности във въздуха на работната среда за Европейската общност.
Граничните стойности на тези химични агенти във въздуха на работната среда, определени с наредбата, са съобразени
със съответните стойности, приети за Европейската общност, като могат да бъдат равни или по-ниски от тях.
BE
Bestanddelen
Fuels, diesel, no. 2
Kerosene C9-C16
Naphthalene
D
AT
Inhaltsstoffe
Naphthalene
H
Basis
Waarde
Controleparameters
Opmerking
D,
BE OEL
TGG 8 hr
100 mg/m3
BE OEL
TGG 8 hr
200 mg/m3
D,
D,
BE OEL
TGG 8 hr
10 ppm, 53 mg/m3
D,
BE OEL
TGG 15 min
15 ppm, 80 mg/m3
Opname van het agens via de huid, de slijmvliezen of de ogen vormt een belangrijk deel van de totale blootstelling. Deze opname
kan het gevolg zijn van zowel direct contact als zijn aanwezigheid in de lucht.
Grundlage
AT OEL
Besondere Gefahr der Hautresorption
Wert
Zu überwachende
Parameter
Bemerkung
TMW
10 ppm, 50 mg/m3
H,
Engineering measures
Adequate ventilation to control airborned concentrations below the exposure guidelines/limits.
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job
activities, and other substances in the work place when designing engineering controls and selecting
personal protective equipment. If engineering controls or work practices are not adequate to prevent
exposure to harmful levels of this material, the personal protective equipment listed below is
recommended. The user should read and understand all instructions and limitations supplied with
the equipment since protection is usually provided for a limited time or under certain circumstances.
Personal protective equipment
Respiratory protection
:
Wear a supplied-air NIOSH approved respirator unless
ventilation or other engineering controls are adequate to
maintain minimal oxygen content of 19.5% by volume under
normal atmospheric pressure. Wear a NIOSH approved
respirator that provides protection when working with this
material if exposure to harmful levels of airborne material may
occur, such as:. Air-Purifying Respirator for Organic Vapors.
Use a positive pressure, air-supplying respirator if there is
potential for uncontrolled release, exposure levels are not
known, or other circumstances where air-purifying respirators
may not provide adequate protection.
Hand protection
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves. Please observe
the instructions regarding permeability and breakthrough time
which are provided by the supplier of the gloves. Also take into
consideration the specific local conditions under which the
product is used, such as the danger of cuts, abrasion, and the
contact time. Gloves should be discarded and replaced if there
is any indication of degradation or chemical breakthrough.
Eye protection
:
Eye wash bottle with pure water. Tightly fitting safety goggles.
:
Choose body protection according to the amount and
9/17
Skin and body protection
SAFETY DATA SHEET
Version 1.10
concentration of the dangerous substance at the work place.
Wear as appropriate:. Flame retardant protective clothing.
Footwear protecting against chemicals.
Hygiene measures
:
When using do not eat or drink. When using do not smoke.
Wash hands before breaks and at the end of workday.
SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
Appearance
Physical state
Color
Odor
: Liquid
: Pale yellow to brown (if undyed), red to purple (dyed)
: Mild
Safety data
Flash point
:
Lower explosion limit
: No data available
Upper explosion limit
: No data available
Oxidizing properties
: No
Autoignition temperature
: No data available
Thermal decomposition
81,9 °C (179,4 °F)
Method: ASTM D 93
: No data available
Molecular formula
: Mixture
Molecular weight
: Not applicable
pH
: Not applicable
pour point
: No data available
Boiling point/boiling range
: 191 - 343 °C (376 - 649 °F)
Vapor pressure
: No data available
Relative density
: 0,795, 21 °C(70 °F), ASTM D 1298
Bulk density
: 6,63 L/G
Water solubility
: Negligible
Partition coefficient: noctanol/water
Viscosity, kinematic
: No data available
Relative vapor density
: No data available
: 2,24 mm2/s
at 40 °C (104 °F)
Method: ASTM D 445
10/17
SAFETY DATA SHEET
Version 1.10
Evaporation rate
: No data available
Percent volatile
: > 99 %
SECTION 10: Stability and reactivity
Chemical stability
: This material is considered stable under normal ambient and
anticipated storage and handling conditions of temperature
and pressure.
Possibility of hazardous reactions
Conditions to avoid
: Heat, flames and sparks.
Materials to avoid
: May react with oxygen and strong oxidizing agents, such as
chlorates, nitrates, peroxides, etc.
Thermal decomposition
: No data available
Hazardous decomposition
products
Other data
: Hydrocarbons
Carbon oxides
: No decomposition if stored and applied as directed.
SECTION 11: Toxicological information
Acute oral toxicity
Acute inhalation toxicity
Acute dermal toxicity
Skin irritation
Eye irritation
: LD50: > 5.000 mg/kg
Method: Acute toxicity estimate
: This information is not available.
: Acute toxicity estimate: > 2.000 mg/kg
Method: Calculation method
: Irritating to skin.
: Vapors may cause irritation to the eyes, respiratory system
and the skin.
Sensitization
: No adverse effects expected.
Repeated dose toxicity
: Method: Based on product or component testing, long term
11/17
SAFETY DATA SHEET
Version 1.10
repeated exposure may cause damage to the following
organs:
Target Organs: Eyes, Blood
Estimated based on individual component values.
Carcinogenicity
: Method: Estimated based on individual component values.
Remarks: Suspect cancer hazard
Developmental Toxicity
Diesel fuel
: Species: rat
Application Route: Inhalation
Dose: 0, 86.9, 408.8 ppm
Number of exposures: 6 h/d
Test period: GD 6-15
Method: OECD Guideline 414
NOAEL Teratogenicity: 408.8 ppm
NOAEL Maternal: 408.8 ppm
Information given is based on data obtained from similar
substances.
Species: rat
Application Route: Dermal
Dose: 30, 125, 500, 1000 mg/kg
Exposure time: daily
Method: OECD Guideline 414
NOAEL Teratogenicity: 125 mg/kg
Information given is based on data obtained from similar
substances.
Kerosene C9-C16
Species: rat
Application Route: Inhalation
Dose: 0, 106, 364 ppm
Exposure time: 6 hrs/d
NOAEL Teratogenicity: 364 ppm
NOAEL Maternal: 364 ppm
Naphthalene
Species: rabbit
Application Route: oral gavage
Dose: 40, 200, 400 mg/kg
Test period: 29 d, GD 6-18
NOAEL Teratogenicity: 400 mg/kg
Aspiration toxicity
: Substances known to cause human aspiration toxicity hazards
or to be regarded as if they cause human aspiration toxicity
hazard.
CMR effects
Diesel fuel
: Carcinogenicity: Limited evidence of carcinogenicity in animal
studies
Teratogenicity: Animal testing did not show any effects on
fetal development.
12/17
SAFETY DATA SHEET
Version 1.10
Naphthalene
Further information
Carcinogenicity: Limited evidence of carcinogenicity in animal
studies
: Symptoms of overexposure may be headache, dizziness,
tiredness, nausea and vomiting. Concentrations substantially
above the TLV value may cause narcotic effects. Solvents
may degrease the skin.
SECTION 12: Ecological information
Ecotoxicity effects
Toxicity to fish
: Toxic to aquatic organisms.
Toxicity to daphnia and
other aquatic invertebrates
Toxicity to algae
Elimination information (persistence and degradability)
Biodegradability
: This material is not expected to be readily biodegradable.
Ecotoxicology Assessment
Acute aquatic toxicity
Diesel fuel
: Toxic to aquatic life.
Naphthalene
: Very toxic to aquatic life.
Chronic aquatic toxicity
Diesel fuel
: Toxic to aquatic life with long lasting effects.
Naphthalene
: Very toxic to aquatic life with long lasting effects.
Toxicity Data on Soil
: No data available
Other organisms relevant to
the environment
Impact on Sewage
Treatment
: No data available
Results of PBT assessment
Diesel fuel
Additional ecological
information
: No data available
: Non-classified PBT substance, Non-classified vPvB substance
: An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal., Toxic to aquatic life with
long lasting effects.
SECTION 13: Disposal considerations
The information in this SDS pertains only to the product as shipped.
13/17
SAFETY DATA SHEET
Version 1.10
Use material for its intended purpose or recycle if possible. This material, if it must be discarded,
may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or
other State and local regulations. Measurement of certain physical properties and analysis for
regulated components may be necessary to make a correct determination. If this material is
classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste
disposal facility.
Product
: The product should not be allowed to enter drains, water
courses or the soil. Do not contaminate ponds, waterways or
ditches with chemical or used container. Send to a licensed
waste management company.
Contaminated packaging
: Empty remaining contents. Dispose of as unused product.
Do not re-use empty containers. Do not burn, or use a cutting
torch on, the empty drum.
SECTION 14: Transport information
The shipping descriptions shown here are for bulk shipments only, and may not apply to
shipments in non-bulk packages (see regulatory definition).
Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous
Goods Regulations for additional shipping description requirements (e.g., technical name or names,
etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping
description for the material. Flashpoints for the material may vary slightly between the SDS and the
bill of lading.
US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION)
UN1202, DIESEL FUEL, 3, III
IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS)
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (NAPHTHALENE,
DIESEL FUEL), 9, III, (81,9 °C), MARINE POLLUTANT, (NAPHTHALENE, DIESEL FUEL)
IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION)
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (NAPHTHALENE,
DIESEL FUEL), 9, III
ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE))
UN1202, DIESEL FUEL, 3, III, (D/E), ENVIRONMENTALLY HAZARDOUS,
(NAPHTHALENE, DIESEL FUEL)
RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF
DANGEROUS GOODS (EUROPE))
UN1202, DIESEL FUEL, 3, III, ENVIRONMENTALLY HAZARDOUS, (NAPHTHALENE, DIESEL
FUEL)
ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE
OF DANGEROUS GOODS BY INLAND WATERWAYS)
UN1202, DIESEL FUEL, 3, III, ENVIRONMENTALLY HAZARDOUS, (NAPHTHALENE, DIESEL
FUEL)
14/17
SAFETY DATA SHEET
Version 1.10
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
National legislation
Major Accident Hazard
Legislation
: 96/82/EC
Update: 2003
Flammable.
6
Quantity 1: 5.000 t
Quantity 2: 50.000 t
: 96/82/EC
Update: 2003-12-31
Petroleum products: (a) gasolines and naphthas, (b)
kerosenes (including jet fuels), (c) gas oils (including diesel
fuels, home heating oils and gas oil blending streams)
13
Quantity 1: 2.500 t
Quantity 2: 25.000 t
Water contaminating class
(Germany)
: WGK 3 highly water endangering
Notification status
Europe REACH
United States of America TSCA
Canada DSL
:
:
:
Australia AICS
New Zealand NZIoC
Japan ENCS
Korea KECI
Philippines PICCS
China IECSC
:
:
:
:
:
:
On the inventory, or in compliance with the inventory
On TSCA Inventory
All components of this product are on the Canadian
DSL.
SECTION 16: Other information
NFPA Classification
: Health Hazard: 2
Fire Hazard: 2
Reactivity Hazard: 0
2
2
15/17
0
SAFETY DATA SHEET
Version 1.10
Further information
Legacy SDS Number
:
CPC00523
Significant changes since the last version are highlighted in the margin. This version replaces all
previous versions.
The information in this SDS pertains only to the product as shipped.
The information provided in this Material Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and
release and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.
Key or legend to abbreviations and acronyms used in the safety data sheet
ACGIH
LD50
Lethal Dose 50%
LOAEL
Lowest Observed Adverse Effect
Level
National Fire Protection Agency
CNS
CAS
American Conference of
Government Industrial Hygienists
Australia, Inventory of Chemical
Substances
Canada, Domestic Substances
List
Canada, Non-Domestic
Substances List
Central Nervous System
Chemical Abstract Service
EC50
Effective Concentration
NOAEL
EC50
EGEST
NOEC
OSHA
GHS
Effective Concentration 50%
EOSCA Generic Exposure
Scenario Tool
European Oilfield Specialty
Chemicals Association
European Inventory of Existing
Chemical Substances
Germany Maximum Concentration
Values
Globally Harmonized System
>=
IC50
Greater Than or Equal To
Inhibition Concentration 50%
STEL
SARA
IARC
International Agency for Research
on Cancer
Inventory of Existing Chemical
Substances in China
Japan, Inventory of Existing and
New Chemical Substances
Korea, Existing Chemical
Inventory
TLV
Resource Conservation Recovery
Act
Short-term Exposure Limit
Superfund Amendments and
Reauthorization Act.
Threshold Limit Value
TWA
Time Weighted Average
TSCA
Toxic Substance Control Act
UVCB
<=
Less Than or Equal To
WHMIS
Unknown or Variable Composition,
Complex Reaction Products, and
Biological Materials
Workplace Hazardous Materials
Information System
LC50
Lethal Concentration 50%
AICS
DSL
NDSL
EOSCA
EINECS
MAK
IECSC
ENCS
KECI
NFPA
NIOSH
National Institute for Occupational
Safety & Health
National Toxicology Program
New Zealand Inventory of
Chemicals
No Observable Adverse Effect
Level
No Observed Effect Concentration
Occupational Safety & Health
Administration
Permissible Exposure Limit
NTP
NZloC
PEL
PICCS
Philippines Inventory of
Commercial Chemical Substances
Presumed Not Toxic
PRNT
RCRA
Full text of R-phrases referred to under sections 2 and 3
16/17
SAFETY DATA SHEET
Version 1.10
R10
R20
R22
R38
R40
R45
R50
R51/53
R52/53
R53
R65
R67
Flammable.
Harmful by inhalation.
Harmful if swallowed.
Irritating to skin.
Limited evidence of a carcinogenic effect.
May cause cancer.
Very toxic to aquatic organisms.
Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
May cause long-term adverse effects in the aquatic environment.
Harmful: may cause lung damage if swallowed.
Vapors may cause drowsiness and dizziness.
Full text of H-Statements referred to under sections 2 and 3.
H226
H228
H302
H304
H315
H332
H336
H351
H372
H373
H400
H410
H411
Flammable solid.
Harmful if swallowed.
May be fatal if swallowed and enters airways.
Harmful if inhaled.
Causes damage to organs through prolonged or repeated exposure.
May cause damage to organs through prolonged or repeated exposure.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
17/17

Diesel Reference Fuel T-28 - Chevron Phillips Chemical Company

Transcription

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