Europe - RT Vanderbilt Holding Company, Inc.

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010
SAFETY DATA SHEET
Europe
English
1.1 Product identifier
SECTION
1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product name
ZETAX® (ZMBT)
Product Code
74431
Chemical name
Other means of identification
2(3H)-Benzothiazolethione, zinc salt
Zinc 2-mercaptobenzothiazole
Product type
Powder.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Accelerator.
1.3 Details of the supplier of the safety data sheet
Vanderbilt Chemicals, LLC
30 Winfield Street
Norwalk, CT 06855
e-mail address of person responsible for this SDS
[email protected]
1.4 Emergency telephone number
National advisory body/Poison Center
Telephone number
Chemtrec: +1-800-424-9300
Outside US: +1-703-527-3887
Supplier
Telephone number
Hours of operation
1-203-853-1400
24 hours
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition
Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
Skin Sens. 1, H317
Classification
Aquatic Chronic 2, H411
Classification according to Directive 1999/45/EC [DPD]
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification
Xn; R22
R43
N; R51/53
See Section 16 for the full text of the R phrases or H statements declared above.
Ingredients of unknown ecotoxicity
Percentage of the mixture consisting of ingredient(s) of unknown hazards to the aquatic environment: 85%
Date of issue/Date of revision
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ZETAX® (ZMBT)
SECTION 2: Hazards identification
2.2 Label elements
Hazard pictograms
Signal word
Hazard statements
Precautionary statements
General
Prevention
Response
Storage
Disposal
Annex XVII - Restrictions
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
2.3 Other hazards
Other hazards which do
not result in classification
Warning
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Not applicable.
Wear protective gloves. Avoid release to the environment. Avoid breathing dust.
IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs:
Get medical attention.
Not applicable.
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Not applicable.
Fine dust clouds may form explosive mixtures with air. Handling and/or processing of
this material may generate a dust which can cause mechanical irritation of the eyes,
skin, nose and throat.
SECTION 3: Composition/information on ingredients
Substance/mixture
Mixture
Classification
Identifiers
Ingredient name
zinc 2-mercaptobenzothiazole EC: 205-840-3
CAS: 155-04-4
2-mercaptobenzothiazole
EC: 205-736-8
CAS: 149-30-4
Index: 613-108-00-3
67/548/EEC
% by
weight
80 - 90
10 - 20
Xn; R22
R43
R43
N; R50/53
Regulation (EC) No.
1272/2008 [CLP]
Acute Tox. 4, H302
Skin Sens. 1, H317
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 1,
H410
Type
[1]
[1]
See Section 16 for the full text of the R-phrases declared above.
See Section 16 for the full text of the H statements declared above.
Type
Date of issue/Date of revision
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ZETAX® (ZMBT)
SECTION 3: Composition/information on ingredients
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures
4.1 Description of first aid measures
Eye contact
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention if irritation occurs.
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband. In case of inhalation of decomposition
products in a fire, symptoms may be delayed. The exposed person may need to be
kept under medical surveillance for 48 hours.
Skin contact
Ingestion
Protection of first-aiders
Wash with plenty of soap and water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if
the exposed person feels sick as vomiting may be dangerous. Do not induce
vomiting unless directed to do so by medical personnel. If vomiting occurs, the head
should be kept low so that vomit does not enter the lungs. Get medical attention if
adverse health effects persist or are severe. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.
No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact
Exposure to airborne concentrations above statutory or recommended exposure
limits may cause irritation of the eyes.
Inhalation
Exposure to airborne concentrations above statutory or recommended exposure
limits may cause irritation of the nose, throat and lungs.
Skin contact
May cause an allergic skin reaction.
Ingestion
No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact
Date of issue/Date of revision
Adverse symptoms may include the following:
irritation
redness
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ZETAX® (ZMBT)
SECTION 4: First aid measures
Inhalation
Skin contact
Ingestion
Adverse symptoms may include the following:
respiratory tract irritation
coughing
Adverse symptoms may include the following:
irritation
redness
No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
No specific treatment.
Specific treatments
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing
media
Unsuitable extinguishing
media
Use dry chemical powder.
Do not use water jet.
5.2 Special hazards arising from the substance or mixture
Hazards from the
substance or mixture
Hazardous thermal
decomposition products
Fine dust clouds may form explosive mixtures with air. This material is toxic to
aquatic life with long lasting effects. Fire water contaminated with this material must
be contained and prevented from being discharged to any waterway, sewer or drain.
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
5.3 Advice for firefighters
Special protective actions
for fire-fighters
Special protective
equipment for fire-fighters
Additional information
Date of issue/Date of revision
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
As with any dry material, pouring or allowing to free-fall or to be conveyed through
chutes or pipes can accumulate and generate electrostatic sparks, potentially
causing ignition of the material itself, or of any flammable materials which may come
in contact with the material or its container.
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ZETAX® (ZMBT)
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
No action shall be taken involving any personal risk or without suitable training.
For non-emergency
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
personnel
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing dust. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment.
If specialized clothing is required to deal with the spillage, take note of any
For emergency responders
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
6.2 Environmental precautions
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities. Collect spillage.
6.3 Methods and materials for containment and cleaning up
Small spill
Move containers from spill area. Use spark-proof tools and explosion-proof
equipment. Avoid dust generation. Using a vacuum with HEPA filter will reduce dust
dispersal. Place spilled material in a designated, labeled waste container. Dispose
of via a licensed waste disposal contractor.
Move containers from spill area. Use spark-proof tools and explosion-proof
equipment. Approach release from upwind. Prevent entry into sewers, water
courses, basements or confined areas. Avoid dust generation. Do not dry sweep.
Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled
waste container. Avoid creating dusty conditions and prevent wind dispersal.
Dispose of via a licensed waste disposal contractor.
Large spill
6.4 Reference to other sections
See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Protective measures
Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid
breathing dust. Avoid release to the environment. Avoid the creation of dust when
handling and avoid all possible sources of ignition (spark or flame). Prevent dust
accumulation. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Electrical
equipment and lighting should be protected to appropriate standards to prevent dust
coming into contact with hot surfaces, sparks or other ignition sources. Take
precautionary measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by grounding and bonding containers and
equipment before transferring material. Empty containers retain product residue and
can be hazardous. Do not reuse container.
Date of issue/Date of revision
2/3/2015.
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ZETAX® (ZMBT)
SECTION 7: Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas. See also Section 8 for additional information on
hygiene measures.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10)
and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.
Seveso II Directive - Reporting thresholds (in tonnes)
Danger criteria
Category
Notification and MAPP
threshold
Safety report threshold
E2: Hazardous to the aquatic environment - Chronic 2
C9ii: Toxic for the environment
200
200
500
500
7.3 Specific end use(s)
Recommendations
Industrial sector specific
solutions
Not available.
Not available.
SECTION 8: Exposure controls/personal protection
The information in this section contains generic advice and guidance. Information is provided based on typical
anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could
significantly increase worker exposure or environmental releases.
8.1 Control parameters
Occupational exposure limits
No exposure limit value known.
Recommended monitoring
procedures
If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to monitoring standards, such as
the following: European Standard EN 689 (Workplace atmospheres - Guidance for
the assessment of exposure by inhalation to chemical agents for comparison with
limit values and measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for the assessment of
exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures
for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be
required.
DNELs/DMELs
No DNELs/DMELs available.
PNECs
No PNECs available.
Date of issue/Date of revision
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ZETAX® (ZMBT)
SECTION 8: Exposure controls/personal protection
8.2 Exposure controls
Appropriate engineering
controls
Use only with adequate ventilation. If user operations generate dust, fumes, gas,
vapor or mist, use process enclosures, local exhaust ventilation or other engineering
controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Individual protection measures
Hygiene measures
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection
Skin protection
Hand protection
Body protection
Other skin protection
Respiratory protection
Environmental exposure
controls
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields. If operating conditions cause high dust concentrations to be produced,
use dust goggles. Recommended: splash goggles
Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately estimated.
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. Recommended: lab coat
Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Use a properly fitted, particulate filter respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator. Recommended: Dust respirator.
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Personal protective
equipment (Pictograms)
Date of issue/Date of revision
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SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
Physical state
Color
Solid. [Powder.]
Cream to light yellow.
Odor
Odor threshold
Not available.
Not available.
pH
Not available.
>200°C
Melting point/freezing point
Initial boiling point and boiling
range
Not available.
Flash point
Closed cup: 170°C [Tagliabue.]
Evaporation rate
Flammability (solid, gas)
Upper/lower flammability or
explosive limits
Not available.
Acrid fumes may develop under fire conditions.
Not available.
Vapor pressure
Vapor density
Not available.
Not available.
Relative density
Solubility(ies)
Partition coefficient: n-octanol/
water
1.7
Insoluble in the following materials: cold water.
Not available.
Auto-ignition temperature
Not available.
Decomposition temperature
Viscosity
Not available.
Not available.
Explosive properties
As with any dry material, pouring or allowing to free-fall or to be conveyed
through chutes or pipes can accumulate and generate electrostatic sparks,
potentially causing ignition of the material itself, or of any flammable materials
which may come in contact with the material or its container.
Not available.
Oxidizing properties
9.2 Other information
No additional information.
SECTION 10: Stability and reactivity
10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability
The product is stable.
10.3 Possibility of
hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid
Avoid the creation of dust when handling and avoid all possible sources of ignition
(spark or flame). Take precautionary measures against electrostatic discharges. To
avoid fire or explosion, dissipate static electricity during transfer by grounding and
bonding containers and equipment before transferring material. Prevent dust
accumulation.
Date of issue/Date of revision
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ZETAX® (ZMBT)
SECTION 10: Stability and reactivity
10.5 Incompatible materials
Reactive or incompatible with the following materials:
oxidizing materials
10.6 Hazardous
decomposition products
Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name
Result
zinc
2-mercaptobenzothiazole
2-mercaptobenzothiazole
Conclusion/Summary
Species
Dose
Exposure
LD50 Dermal
Rabbit
>7940 mg/kg
-
LD50 Oral
LD50 Dermal
LD50 Oral
Rat
Rabbit
Rat
7500 mg/kg
>7940 mg/kg
3800 mg/kg
-
In NTP studies, MBT in corn oil was force fed through a stomach tube to rats and
mice for two years. An increased incidence of tumors in a number of tissues was
seen in rats. No increase in the incidence of tumors was observed in mice. The
strength of the data was evaluated "some", "equivocal", "no" or "inadequate"
evidence of carcinogenicity. Because only a limited response occured, NTP
interpreted these studies as tumor response (e.g.: no effect in mice; some effect in
rats) and other concerns about the conduct of these studies makes it difficult to
clearly assess the significance of the results to those who work with MBT. We
recommend that worker exposure to MBT should be minimized.
Acute toxicity estimates
Not available.
Irritation/Corrosion
Conclusion/Summary
Skin
zinc 2-mercaptobenzothiazole and 2-mercaptobenzothiazole: Non-irritating to the
skin. (Rabbit)
zinc 2-mercaptobenzothiazole and 2-mercaptobenzothiazole: Non-irritating to the
eyes. (Rabbit)
Eyes
Sensitization
Product/ingredient name
zinc
2-mercaptobenzothiazole
2-mercaptobenzothiazole
Route of
exposure
Species
Result
skin
Mouse
Sensitizing
skin
Guinea pig
Sensitizing
Conclusion/Summary
Skin
Not available.
Mutagenicity
Product/ingredient name
zinc
2-mercaptobenzothiazole
2-mercaptobenzothiazole
Test
-
Experiment
Experiment: In vitro
Subject: Bacteria
Experiment: In vitro
Subject: Bacteria
Result
Negative
Negative
Carcinogenicity
Date of issue/Date of revision
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SECTION 11: Toxicological information
Conclusion/Summary
Not available.
Reproductive toxicity
Conclusion/Summary
Not available.
Teratogenicity
Conclusion/Summary
A teratology study in rats with MBT showed negative results. An increase in birth
defects was observed in groups of rats and mice given mercaptobenzothiazole
disulfide by stomach tube, but only at doses that produced adverse effects on
mothers. No effects were observed in the other dose groups. However, an increase
in embryo death and post implantation losses was reported in another study using
rats. Similar results were reported in a fertility study also using rats.
Mice were given MBT at a dosage of 464 mg/kg by subcutaneous injection on days 6
through 15 of gestation. In two strains, increased incidences of fetal malformations
were noted, but only at maternally toxic doses.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.
Routes of entry anticipated: Oral, Dermal, Inhalation.
Information on the likely
routes of exposure
Potential acute health effects
Eye contact
Inhalation
Exposure to airborne concentrations above statutory or recommended exposure
limits may cause irritation of the eyes.
Skin contact
Exposure to airborne concentrations above statutory or recommended exposure
limits may cause irritation of the nose, throat and lungs.
May cause an allergic skin reaction.
Ingestion
No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
Inhalation
Skin contact
Ingestion
Adverse symptoms may include the following:
irritation
redness
Adverse symptoms may include the following:
respiratory tract irritation
coughing
Adverse symptoms may include the following:
irritation
redness
No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate
Not available.
effects
Potential delayed effects
Not available.
Long term exposure
Date of issue/Date of revision
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SECTION 11: Toxicological information
Potential immediate
effects
Not available.
Potential delayed effects
Not available.
Potential chronic health effects
Not available.
Conclusion/Summary
Not available.
General
Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental effects
Fertility effects
Other information
Not available.
SECTION 12: Ecological information
12.1 Toxicity
Product/ingredient name
Result
Species
Exposure
2-mercaptobenzothiazole
Acute EC50 0.25 mg/l
Acute LC50 4.1 mg/l
Acute LC50 0.73 mg/l
Algae
Daphnia
Fish
96 hours
48 hours
96 hours
12.2 Persistence and degradability
Product/ingredient name
Test
Result
Dose
Inoculum
2-mercaptobenzothiazole
-
2 % - 35 days
-
-
12.3 Bioaccumulative potential
Product/ingredient name
LogPow
BCF
Potential
zinc
2-mercaptobenzothiazole
2-mercaptobenzothiazole
5.02
<8
low
2.42
18.35
low
12.4 Mobility in soil
Soil/water partition
coefficient (KOC)
Mobility
Not available.
Not available.
12.5 Results of PBT and vPvB assessment
PBT
Not applicable.
vPvB
12.6 Other adverse effects
Date of issue/Date of revision
Not applicable.
No known significant effects or critical hazards.
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SECTION 13: Disposal considerations
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal
Hazardous waste
Packaging
The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
The classification of the product may meet the criteria for a hazardous waste.
Methods of disposal
Special precautions
The generation of waste should be avoided or minimized wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers.
SECTION 14: Transport information
Regulatory
information
UN number
Proper shipping
name
Classes
DOT Classification
3077
Environmentally
9
hazardous substance,
solid, n.o.s
PG* Label
Additional
information
III
Remarks
Marine pollutant
III
Remarks
Marine pollutant
III
Remarks
Marine pollutant
(2-mercaptobenzothiazole)
TDG Classification
3077
Environmentally
9
hazardous substance,
solid, n.o.s
(2-mercaptobenzothiazole)
ADR/RID Class
Environmentally
9
hazardous substance,
solid, n.o.s
3077
(2-mercaptobenzothiazole)
Date of issue/Date of revision
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ZETAX® (ZMBT)
SECTION 14: Transport information
IMDG Class
Environmentally
9
hazardous substance,
solid, n.o.s
3077
III
Remarks
Marine pollutant
III
Remarks
Marine pollutant
(2-mercaptobenzothiazole
IATA-DGR Class
3077
Environmentally
9
hazardous substance,
solid, n.o.s
(2-mercaptobenzothiazole)
PG* : Packing group
SECTION 15: Regulatory information
Europe inventory
All components are listed or exempted.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorization
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Other EU regulations
Integrated pollution
prevention and control
list (IPPC) - Air
Not applicable.
Listed
Seveso II Directive
This product is controlled under the Seveso II Directive.
Danger criteria
Category
E2: Hazardous to the aquatic environment - Chronic 2
C9ii: Toxic for the environment
National regulations
Germany
Hazard class for water
2 Appendix No. 4
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Date of issue/Date of revision
2/3/2015.
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ZETAX® (ZMBT)
SECTION 15: Regulatory information
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
United States inventory (TSCA 8b)
Canada inventory
Australia inventory (AICS)
China inventory (IECSC)
Japan inventory
Korea inventory
New Zealand Inventory of Chemicals (NZIoC)
Philippines inventory (PICCS)
15.2 Chemical Safety
Assessment
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
This product contains substances for which Chemical Safety Assessments are still
required.
SECTION 16: Other information
Indicates information that has changed from previously issued version.
Abbreviations and acronyms
ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification
Skin Sens. 1, H317
Aquatic Chronic 2, H411
Europe
Full text of abbreviated H
statements
Full text of classifications
[CLP/GHS]
Date of issue/Date of revision
Justification
Calculation method
Calculation method
H317
H400
H410
H411
May cause an allergic skin reaction.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Toxic to aquatic life with long lasting effects.
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Aquatic Chronic 2, H411
Skin Sens. 1, H317
AQUATIC HAZARD (ACUTE) - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 2
SKIN SENSITIZATION - Category 1
2/3/2015.
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ZETAX® (ZMBT)
SECTION 16: Other information
Full text of abbreviated R
phrases
R22- Harmful if swallowed.
R43- May cause sensitization by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Full text of classifications
[DSD/DPD]
History
Xn - Harmful
N - Dangerous for the environment
Date of printing
Date of issue/ Date of
revision
Date of previous issue
Version
2/3/2015.
2/3/2015.
Information contact
Vanderbilt Global Services, LLC
Corporate Risk Management
1-203-295-2143
No previous validation.
1
Notice to reader
Information presented herein has been compiled from sources considered to be dependable and is accurate
and reliable to the best of our knowledge and belief but is not guaranteed to be so. Nothing herein is to be
construed as recommending any practice or any product in violation of any patent or in violation of any law or
regulation. It is the user's responsibility to determine for himself the suitability of any material for a specific
purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to
be obtained in using any material and, since conditions of use are not under our control, we must necessarily
disclaim all liability with respect to the use of any material supplied by us.
Date of issue/Date of revision
2/3/2015.
15/15