Annexure-PFR - Environmental Clearances

Transcription

M/S RADHA MADHAV
PROCESSORS PVT. LTD.
Pre-Feasibility Report for Environmental Clearance
(EC) of Proposed Greenfield Project of Chlorinated
and Hydrogenated Derivatives for AgroIntermediates Plant of 11000 MTM at Plot No.D2/CH/6, GIDC Industrial Estate, Dahej II, Taluka:
Vagra, District: Bharuch, State: Gujarat.
AUGUST 2014
Consultant:
Kadam
Environmental
Consultants
www.kadamenviro.com
Environment f or Development
EC FOR PROPOSED GREENFIELD PROJECT OF CHLORINATED AND
HYDROGENATED DERIVATIVES FOR AGRO INTERMEDIATES PLANT
AT GIDC DAHEJ II, TAL:VAGRA, DIST: BHARUCH, GUJARAT
M/S RADHA MADHAV
DECLARATION
M/S RADHA MADHAV PROCESSORS PVT. LTD.
Pre-Feasibility Report for Environmental Clearance (EC) of Proposed
Greenfield Project of Chlorinated and Hydrogenated Derivatives for
Agro Intermediates Plant of 11000 MTM at Plot No: D-2/CH/6, GIDC
Industrial Estate, Dahej II, Taluka: Vagra, District: Bharuch,
Gujarat.
© Kadam Environmental Consultants (‘Kadam’), August 2014
This report is released for the use of M/s Radha Madhav Processors Pvt. Ltd., Regulators and relevant
stakeholders solely as part of the subject project’s Environmental Clearance process of proposed
Greenfield project of Chlorinated and Hydrogenated Derivatives for Agro Intermediates Plant at Plot
No.:D-2/CH-/6, GIDC Industrial Estate, Dahej II, Taluka: Vagra, District: Bharuch, Gujarat.
Information provided (unless attributed to referenced third parties) is otherwise copyrighted and shall
not be used for any other purpose without the written consent of Kadam.
QUALITY CONTROL
Name of
Publication
Project Number
EC of proposed Greenfield project of Chlorinated and Hydrogenated Derivatives for Agro
Intermediates Plant at Plot No.: D-2/CH-/6, GIDC Industrial Estate, Dahej II, Taluka:
Vagra, District: Bharuch, Gujarat
1417961306
Report No.
1
Version
1
Released
Prepared By
Ms. Nazneen Mansuri
Reviewed By
Mr. Jagdish A. Rathi/ Mr. Sangram Kadam
Released By
Mr. Sangram A. Kadam
August,2014
DISCLAIMER
Kadam has taken all reasonable precautions in the preparation of this report as per its auditable quality plan.
Kadam also believes that the facts presented in the report are accurate as on the date it was written. However, it
is impossible to dismiss absolutely, the possibility of errors or omissions. Kadam therefore specifically disclaims
any liability resulting from the use or application of the information contained in this report. The information is not
intended to serve as legal advice related to the individual situation.
KADAM ENVIRONMENTAL CONSULTANTS |AUGUST 2014
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M/S RADHA MADHAV
TABLE OF CONTENT
CONTENTS
1
EXECUTIVE SUMMARY ................................................................................. 5
2
INTRODUCTION OF THE PROJECT ................................................................. 6
2.1
2.2
2.3
2.4
2.5
2.6
2.7
3
IDENTIFICATION OF PROJECT............................................................................. 6
PROJECT PROPONENT. .................................................................................... 6
BRIEF DESCRIPTION OF NATURE OF THE PROJECT ........................................................ 6
NEED FOR THE PROJECT AND ITS IMPORTANCE TO THE COUNTRY AND OR REGION....................... 6
IMPORT VS. INDIGENOUS PRODUCTION .................................................................. 7
DOMESTIC/ EXPORT MARKETS ........................................................................... 7
EMPLOYMENT GENERATION (DIRECT AND INDIRECT) DUE TO THE PROJECT............................. 7
PROJECT DESCRIPTION ............................................................................... 8
3.1
TYPE OF PROJECT ........................................................................................ 8
3.2
LOCATION (MAP SHOWING GENERAL LOCATION, SPECIFIC LOCATION AND PROJECT BOUNDARY &
PROJECT SITE LAYOUT) WITH COORDINATES ..................................................................... 8
3.3 DETAILS OF ALTERNATE SITES CONSIDERED AND THE BASIS OF SELECTING THE PROPOSED SITE. ....... 8
3.4 SIZE OR MAGNITUDE OF OPERATION ..................................................................... 8
3.5
PROJECT DESCRIPTION WITH PROCESS DETAILS (A SCHEMATIC DIAGRAM/FLOW CHART SHOWING THE
PROJECT LAYOUT, COMPONENTS OF THE PROJECT ETC, SHOULD BE GIVEN) .................................... 11
3.6
RAW MATERIAL REQUIRED ALONG WITH, QUANTITY LIKELY SOURCE, MARKETING AREA OF FINAL
PRODUCT/S, MODE OF TRANSPORT OF RAW MATERIAL AND FINISHED PRODUCT. .............................. 77
3.7 RESOURCE OPTIMIZATION/RECYCLING AND REUSE ENVISAGED IN THE PROJECT, ...................... 82
3.8 AVAILABILITY OF WATER ITS SOURCE, ENERGY/POWER REQUIREMENT AND SOURCE SHOULD BE GIVEN 82
3.9
QUANTITY OF WASTES TO BE GENERATED (LIQUID AND SOLID) AND SCHEME FOR THEIR
....................................................................................... 83
MANAGEMENT/DISPOSAL
3.10
SCHEMATIC REPRESENTATIONS OF THE FEASIBILITY DRAWING WHICH GIVE INFORMATION OF EIA
PURPOSE. 86
4
SITE ANALYSIS ......................................................................................... 87
4.1
4.2
4.3
CONNECTIVITY ......................................................................................... 87
LAND FORM, LAND USE AND LAND OWNERSHIP ....................................................... 87
TOPOGRAPHY ........................................................................................... 87
4.4
EXISTING LAND USE PATTERN (AGRICULTURE, NON-AGRICULTURE, FOREST, WATER BODIES (INCLUDING
AREA UNDER CRZ)), SHORTEST DISTANCES FROM THE PERIPHERY OF THE PROJECT TO PERIPHERY OF THE
FORESTS, NATIONAL PARK, WILD LIFE SANCTUARY, ECO SENSITIVE AREAS, WATER BODIES (DISTANCE FROM
HFL OF THE RIVER), CRZ. ..................................................................................... 87
4.5 EXISTING INFRASTRUCTURE ............................................................................ 88
4.6 SOIL CLASSIFICATION .................................................................................. 88
4.7 CLIMATIC DATA FROM SECONDARY SOURCES ........................................................... 88
4.8 SOCIAL INFRASTRUCTURE AVAILABLE .................................................................. 89
5
PLANNING BRIEF ...................................................................................... 90
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5.1
5.2
5.3
6
TABLE OF CONTENT
LAND USE PLANNING (BREAKUP ALONG WITH GREEN BELT ETC) ........................................ 90
ASSESSMENT OF INFRASTRUCTURE DEMAND (PHYSICAL & SOCIAL) ................................... 91
AMENITIES/FACILITIES ................................................................................. 91
PROPOSED INFRASTRUCTURE .................................................................... 92
6.1
6.2
6.3
6.4
6.5
6.6
6.7
6.8
6.9
7
INDUSTRIAL AREA (PROCESSING AREA) ................................................................
RESIDENTIAL AREA (NON- PROCESSING AREA) ........................................................
GREEN BELT ............................................................................................
SOCIAL INFRASTRUCTURE ..............................................................................
CONNECTIVITY .........................................................................................
DRINKING WATER MANAGEMENT ......................................................................
SEWERAGE SYSTEM ....................................................................................
INDUSTRIAL WASTE MANAGEMENT.....................................................................
POWER REQUIREMENT & SUPPLY / SOURCE............................................................
92
92
92
92
92
92
93
93
93
REHABILITATION AND RESETTLEMENT (R & R) PLAN .................................... 94
7.1
POLICY TO BE ADOPTED (CENTRAL/STATE) IN RESPECT OF THE PROJECT AFFECTED PERSONS INCLUDING
HOME OUSTEES, LAND OUSTEES AND LANDLESS. ............................................................... 94
8
PROJECT SCHEDULE & COST ESTIMATES ...................................................... 95
8.1
LIKELY DATE OF START OF CONSTRUCTION AND LIKELY DATE OF COMPLETION......................... 95
8.2
ESTIMATED PROJECT COST ALONG WITH ANALYSIS IN TERMS OF ECONOMIC VIABILITY OF THE PROJECT
95
Economic Viability ........................................................................................ 95
9
ANALYSIS OF PROPOSAL ........................................................................... 96
9.1
FINANCIAL AND SOCIAL BENEFITS WITH SPECIAL EMPHASIS ON THE BENEFIT TO THE LOCAL PEOPLE. . 96
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TABLE OF CONTENT
LIST OF TABLES
Table 3-1: Co-ordinates of the Proposed Project Site ....................................................................... 8
Table 3-2: Size/Magnitude of Proposed Facilities ............................................................................. 9
Table 3-3: Details of Raw material Source and Mode of Transport .................................................. 77
Table 3-4: Details of Finished Goods, Source and Mode of Transport .............................................. 79
Table 3-5: Details of proposed water requirement with approximate quantity .................................. 82
Table 3-6: Details of proposed energy requirement with sources .................................................... 83
Table 3-7: Details of waste water sources with approximate quantity .............................................. 83
Table 3-8: Details of Hazardous waste along with the Category and disposal method ....................... 83
Table 3-9: Details of emissions from process and flue gas stacks along with their mitigation methods84
Table 4-1: Predominant Wind Direction ........................................................................................ 89
Table 5-1: Land break-up ............................................................................................................ 90
Table 8-1: Cost Break-Up ............................................................................................................ 95
Table 8-2: Expected Turnover from the proposed project ............................................................... 95
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TABLE OF CONTENT
LIST OF ANNEXURES
Annexure 1: Map Showing General and Specific Location of Project Site .......................................... 97
Annexure 2: Site Boundary Map ................................................................................................... 98
Annexure 3: Site Layout Map ....................................................................................................... 99
Annexure 4: Copy of Water supply request letter from GIDC ........................................................ 100
Annexure 5: Copy of Temporary DGVCL connection application .................................................... 101
Annexure 6: Copy of land possession letter and receipt from GIDC ............................................... 102
Annexure 7: Soil profile of the region ......................................................................................... 104
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M/S RADHA MADHAV
1
PRE-FEASIBILITY
REPORT
EXECUTIVE SUMMARY
M/s Radha Madhav Processors Pvt. Ltd. a company promoted by director’s having experience in
chemical industrial sector.
The project is a Greenfield having a total area of 3 Ha. at Plot No: D-2/CH/6, GIDC Industrial Estate,
Dahej II, Tal: Vagra, District.
The manufacturing of various products includes inorganic, organic, agrochemical intermediates
produced from Hydrogenation and Chlorination process.
The total production capacity will be 11000 MTM. The water requirement of 2159 KLD will be met
through GIDC reservoir. The power requirement for the proposed project is 1 MW which will be
supplied by Dakshin Gujarat Vij Company Ltd.
The total cost of the project is 95.4 Crores and timeline of project commissioning is 24 months after
getting EC.
The project falls under 5 (F) and 5(b) activity and Category “A” as per EIA notification September
2006, amended till date.
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2
PRE-FEASIBILITY
REPORT
INTRODUCTION OF THE PROJECT
2.1
Identification of project
The project falls under notified area whose public hearing is pending, thus as per EIA notification it
falls under Category “A” of the schedule “Manufacturing/Fabrication”, Project or Activity 5(f), Synthetic
Organic Industry and under Project or Activity 5(b), Pesticide Industry and Pesticide specific
intermediates.
The proposed requires EC for Greenfield Project of Chlorinated and Hydrogenated Derivatives for Agro
Intermediates plant at GIDC Dahej II, Tal:Vagra, Dist: Bharuch, Gujarat
2.2
Project proponent.
Industrial unit promoted by Shri Maulik Jayantibhai Patel and Shri Kaushal Ashish Soparkar, is forming
part of Meghmani Group of companies (Meghmani Group) one leading group of India operating in a
range of diversified industries viz. Pigments, Agro Chemicals, Dyestuffs and Caustic Chlorine. The
flagship company, Meghmani Organics Limited (MOL) is a listed public limited company and is
regarded as one of the leading producers of pigments and agrochemicals in the country. The group
has set up a state of the art Caustic Chlorine Complex (CCC Complex) under Meghmani Finechem Ltd.
(MFL) at Dahej in the state of Gujarat.
The group companies houses a large ‘R&D Laboratory’ and ‘Technical Competence Center’ with
facilities for testing. The group companies equipped with the latest instruments required for product
development and works in close conjunction with customers in meeting. High productivity and
profitability, newer chemistry and huge export potential inspired them to set up a proposed project to
manufacture various Chemicals–Intermediates. This proposed project is tantamount to a logical
forward integration project since three of its raw material viz. Sodium Hydroxide, Hydrogen Gas and
Hydrochloric Acid will be sourced from MFL through pipeline only- the project being located just
adjacent to Caustic Chlorine (CC) complex of MFL.
2.3
Brief description of nature of the project
The proposed is a Greenfield project of Chlorinated and Hydrogenated Derivatives for Agro
Intermediates plant. This products find uses as intermediate products in Pharmaceuticals, Pesticides
and PVC industries. The plant is to be set up on land area of 3 Ha. The water requirement will be
2159 KLD which will be sourced from GIDC reservoir. The estimated 1 MW power consumption will be
supplied by Dakshin Gujarat Vij Company Ltd.
2.4
Need for the project and its importance to the country and or region
The promoters are interested for setting up the project considering the following technical and
economical features of the project:


Increasing demand for the end products in the global as well as local market
Availability of the finance through internal and external sources.
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
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




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PRE-FEASIBILITY
REPORT
The use of environment friendly hydrogenation technology for the manufacturing of dyes and
intermediates.
Availability of Hydrogen gas, Chlorine and Caustic through pipeline by the nearby member
group of company
Availability of major raw material in the nearby vicinity.
Considering the following location base favorable condition, the unit is planning to go for
establishing the manufacturing facilities for above mentioned activities at the said location:
Location within the established notified industrial estate
Availability of common infrastructural facilities of the industrial estate
Availability of good quality water supply in the industrial estate
Availability of un-interrupted power supply in the industrial estate
Availability of authorized solid waste disposal site in nearby area
The proven and safe technology will be utilized. The project will help industrial development in the
region. Various products have export potential and will help in own’s economy by generating foreign
exchange. It will increase employment opportunities in the region.
2.5
Import vs. Indigenous production
The products will comply national and international quality standard norms and have indigenous and
export potential.
2.6
Domestic/ Export Markets
The products which will be manufactured will be of international standards, which will have
acceptability in the export as well as domestic market.
2.7
Employment Generation (Direct and Indirect) due to the Project
It is visualized that around 100 male and female workers will be required during construction phase
which would include unskilled, semi-skilled and skilled work force. These will be sourced from nearby
villages. Technical work force around 100 including engineers, technicians and administrative staff will
be required during operational phase. Local community stands priority in getting employment.
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3
3.1
PRE-FEASIBILITY
REPORT
PROJECT DESCRIPTION
Type of project
The project is a Greenfield Project of Chlorinated and Hydrogenated Derivatives for Agro
Intermediates plant manufacturing unit of 11000 MTM. The project does not include any interlinked or
interdependent projects. The products will be inorganic or organic compounds which have end uses in
Pharmaceutical, Pesticide and Polyvinylchloride manufacturing industries.
3.2
Location (map showing general location, specific location and project boundary
& project site layout) with coordinates
M/s Radha Madhav Processors Pvt. Ltd. intends to set up a Greenfield Project of Chlorinated and
Hydrogenated Derivatives for Agro Intermediates manufacturing unit at Plot No.: D-2/CH/6, Phase II,
GIDC Dahej, Taluka: Vagra, District: Bharuch, Gujarat.
Location map showing general location, specific location of proposed project is given in Annexure 1.
Project boundary map is given in Annexure 2 and Project site layout map is given in Annexure 3.
The co-ordinates of the project site is given in Table 3-1.
Table 3-1: Co-ordinates of the Proposed Project Site
3.3
Code
Latitude
Longitude
A
21°43'33.00"N
72°37'8.20"E
B
21°43'32.50"N
72°36'59.60"E
C
21°43'28.70"N
72°36'59.90"E
D
21°43'29.60"N
72°37'8.50"E
Details of alternate sites considered and the basis of selecting the proposed
site.
The proposed project is to be set up at near vicinity of the existing Caustic Chlorine plant for quick and
easy transportation of Chlorine, Hydrogen and Caustic Soda hence making handling of this products in
more safe and easy manner. Thus, no alternative site is examined.
3.4
Size or magnitude of operation
Capacity of proposed facility is given in Table 3-2
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PRE-FEASIBILITY
REPORT
Table 3-2: Size/Magnitude of Proposed Facilities
Plant Code
Common
Name
Plant A
CPVC
Products
Chlorinated Poly Vinyl Chloride
Capacity
(MTPM)
1500
Benzyl chloride
2,6 Dichloro Phenol
2,4 Dichloro Phenol
2,4 Chloro Phenol
Benzyl Chloride/Benzo Trichloride/Benzal Chloride
Plant B
Chlorination of
Benzene and
Toluene
p-Chorobenzyl Choride/p-Chorobenzal Choride/p-Chloro
Benzotrichloride
2000
o-Chorobenzyl Choride/o-Chorobenzal Choride/o-Chloro
Benzotrichloride
Chloro Benzene/Di Chloro Benzene
Mono Chloro Benzene (MCB)
Dichloro Benzene (DCB) (Ortho/Meta/Para)
p-Chloro Toluene/o-Chloro Toluene
Plant C
Chlorination of
Acetic Acid
Mono Chloro Acetic Acid
Tri Chloro Acetyl Chloride
1500
Iso Phthaloyl Chloride
Phthaloyl Chloride
o-Chlorobenzaldehyde
p-Chlorobenzaldehyde
Benzyl Alcohol
o-Chloro Benzyl Alcohol
p-Chloro Benzyl Alcohol
Benzoyl Chloride
Plant D
Hydrolysis of
Chlorinated
Compound
Benzaldehyde
2-Methoxy 5-Bromo 6-Methyl Benzoyl Chloride
2,4 Dichloro Benzoyl Chloride
1500
4 Methyl Benzoyl Chloride
Propargyl Chloride
Pivaloyl Chloride
4-Chloro Butyryl Chloride
Terephthaloyl chloride
n-Valeroyl Chloride
4-Chloro Benzoyl Chloride
3-Nitro Benzoyl Chloride
4-Nitro benzoyl Chloride
Plant E
Plant F
Amines
Primary Amines
Ethoxylation of Primary Amines
Paracetamol
1000
1000
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Plant Code
Common
Name
Products
PRE-FEASIBILITY
REPORT
Capacity
(MTPM)
4-Chloro 3,5 Dinitro Benzoic Acid
6, Nitro 3,4 Dichloro Aniline
4-Nitro ,5-Chloro, 2-methyl Aniline
2-Nitro 4-Methyl Aniline
1000
3, Nitro 4-Chloro Benzoic Acid
3-Nitro-Para Toluic Acid
2,4 Dichloro 6-Nitro Phenol
Plant G
Nitro
Compounds
1,3 Di Nitro Benzene
Nitro Benzene
2/3/4 Nitro Toluene
3,5 Di Nitro Benzoic Acid
p-Nitro Salicylic Acid
2,5 Dichloro Nitro Benzene
3,4/2,3 Dichloro Nitro Benzene
Para Hydroxy Aniline/O-Hydroxy Aniline
1000
3,4 Dichloro Aniline
3-Iso Propoxy Aniline
o-Toluidine
m-Toluidine
p-Toluidine
Aniline
3,4 Diamine Toluene
2,5 Dimethyl 1,4 Phenylene Diamine
2 Chloro, 5-Methyl, 1,4 Phenylene Diamine
Plant H
Hydrogenation
compounds
2, Chloro 1,4 Phenylene Diamine
2,5 Dichloro 1,4 Phenylene Diamine
500
2,4,5 Trichloro Aniline
6-Methyl 5-Amino Benzimidazolone
5-Amino Benzimidazolone
3-Amino 4-Chloro Benzoic Acid
3-Amino 4-Chloro Benzotrifluoride
3-Amino Benzotrifluoride
3 Amino 4-Methyl Benzoic Acid
Total
11000
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3.5
PRE-FEASIBILITY
REPORT
Project description with process details (a schematic diagram/flow chart
showing the project layout, components of the project etc, should be given)
Project Description:
1. 2,6-dichloro phenol
Brief Process: 2-chloro Phenol react with chlorine gas to give of 2,6 Dichlorophenol . The product is
isolated by distillation to give pure 2,6 Dichloro phenol.
Chemical Reaction:
OH
OH
Cl
Cl
Cl
Chlorination
Cl2
HCl
Mol. Wt.: 36.46
2,6-dichlorophenol
2-chlorophenol
C6H4Cl2O
Mol. Wt.: 163
C6H5ClO
Mol. Wt.: 128.56
Flow Diagram:
2-chloro Phenol
Chlorine gas
Scrubber: sodium
hydroxide in water
solution
Chlorination
HCl
Distillation
Residue
2,6-dichloro phenol
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PRE-FEASIBILITY
REPORT
2. 2,4-dichloro phenol
Brief Process: 2-chloro Phenol react with chlorine gas to give of 2, 4 Dichlorophenol. The product is
isolated by distillation to give pure 2,4 Dichloro phenol.
Chemical Reaction:
OH
OH
Cl
Chlorination
HCl
Cl2
Mol. Wt.: 36.46
Cl
Cl
4-chlorophenol
2,4-dichlorophenol
C6H5ClO
Mol. Wt.: 128.56
C6H4Cl2O
Mol. Wt.: 163
Flow Diagram:
4-chloro Phenol
Chlorine gas
Scrubber: sodium
hydroxide in water
solution
Chlorination
HCl
Distillation
Residue
2,4-dichloro phenol
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PRE-FEASIBILITY
REPORT
3. 2,4-Chloro phenol
Brief Process: The reaction of Phenol with chlorine gas to give mixture of 2-Chloro Phenol, 4-Chloro
Phenol. The mixture is isolated by distillation to give pure 2-Chloro Phenol, and 4-Chloro Phenol.
Chemical Reaction:
OH
OH
Cl
Cl2
chlorination
HCl
Cl
phenol
C6H6O
Mol. Wt.: 94.11
2-chlorophenol
4-chlorophenol
C6H5ClO
Mol. Wt.: 128.56
C6H5ClO
Mol. Wt.: 128.56
ClH
Mol. Wt.: 36.46
Flow Diagram:
Phenol
Chlorine gas
Scrubber: sodium
hydroxide in water
solution
Chlorination
HCl
Distillation
2-chloro phenol
Residue
4-chloro phenol
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PRE-FEASIBILITY
REPORT
4. Benzyl Chloride, Benzo Trichloride and Benzal Chloride
Brief Process: Toluene react with chlorine in presence of UV light to give mixture of Benzylchloride,
Benzalchloride & Benzotrichloride. The mixture is isolated by distillation to give pure Benzylchloride,
Benzalchloride & Benzotrichloride.
Chemical Reaction:
CH2Cl
CH3
Cl2
CCl3
CHCl2
Photochlorination
HCl
Mol. Wt.: 70.91
Mol. Wt.: 92.14
Toluene
Mol. Wt.: 126.58
Mol. Wt.: 161.03
Benzylchloride
Benzalchloride
Mol. Wt.: 195.47
Mol. Wt.: 36.46
Benzotrichloride
Flow Diagram:
Water Caustic
Toluene
Chlorine gas
Photo Chlorination
Scrubber
Hypochlorite
HCl
Benzylchoride
Distillation
Benzyalchoride
Benzotrichoride
Residue
14
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PRE-FEASIBILITY
REPORT
5. p-Chlorobenzyl Chloride, p-Chlorobenzal Chloride and p-Chlorobenzo Trichloride
Brief Process: p-Chlorotoluene react with chlorine in presence of UV light to give mixture of pChlorobenzylchloride, p-Chlorobenzalchloride & p-Chlorobenzotrichloride. The mixture is isolated by
distillation to give pure p-Chlorobenzylchloride, p-Chlorobenzalchloride & p-Chlorobenzotrichloride.
Chemical Reaction:
CH2Cl
CH3
Cl2
CCl3
CHCl2
Photochlorination
HCl
Cl
Cl
Mol. Wt.: 126.58
Mol. Wt.: 161.03
Cl
Cl
Mol. Wt.: 195.47
Mol. Wt.: 229.92
Mol. Wt.: 36.46
p-Chlorobenzylchloride p-Chlorobenzalchloride p-Chlorobenzotrichloride
p-Chlorotoluene
Flow Diagram:
Water Caustic
Toluene
Chlorine gas
Photo Chlorination
Scrubber
Hypochlorite
HCl
p-Chloro Benzylchoride
Distillation
p-Chloro Benzyalchoride
p- Chloro Benzotrichoride
Residue
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PRE-FEASIBILITY
REPORT
6. o-Chloro Benzyl Chloride, o-Chloro Benzal Chloride and o-Chloro Benzo Trichloride
Brief Process: o-Chlorotoluene react with chlorine in presence of UV light to give mixture of oChlorobenzylchloride, o-Chlorobenzalchloride & o-Chlorobenzotrichloride. The mixture is isolated by
distillation to give pure o-Chlorobenzylchloride, o-Chlorobenzalchloride & o-Chlorobenzotrichloride.
Chemical Reaction:
CH3
CHCl2
CH2Cl
Cl
CCl3
Cl
Cl
Cl
Photochlorination
Cl2
Mol. Wt.: 126.58
o-Chlorotoluene
HCl
Mol. Wt.: 161.03
o-Chlorobenzylchloride
Mol. Wt.: 195.47
Mol. Wt.: 229.92
o-Chlorobenzalchloride
Mol. Wt.: 36.46
o-Chlorobenzotrichloride
Flow Diagram:
Water Caustic
Toluene
Chlorine gas
Photo Chlorination
Scrubber
Hypochlorite
HCl
o-Chloro Benzylchoride
Distillation
o-Chloro Benzyalchoride
o-Chloro Benzotrichoride
Residue
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PRE-FEASIBILITY
REPORT
7. Chloro Benzene and O-Dichloro Benzene
Brief Process: The reaction between benzene and chlorine gives the mixture of Chlorobenzene & oDichlorobenzene. The mixture is isolated by distillation to give pure chlorobenzene & oDichlorobenzene.
Chemical Reaction:
Cl
Cl
Cl
Cl2
chlorination
HCl
Mol. Wt.: 78.11
Mol. Wt.: 112.56
Benzene
Chlorobenzene
Mol. Wt.: 147
Mol. Wt.: 36.46
o-dichlorobenzene
Flow Diagram:
Water Caustic
Toluene
Chlorine gas
Chlorination
Scrubber
Hypochlorite
HCl
Chloro Benzene
Distillation
O-Dichloro Benzene
Residue
17
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PRE-FEASIBILITY
REPORT
8. Mono Chloro Benzene
Brief Process: The reaction between benzene and chlorine gives the mixture of Chlorobenzene & oDichlorobenzene. The mixture is isolated by distillation to give pure Chlorobenzene & oDichlorobenzene.
Chemical Reaction:
Cl
Cl
Cl
Cl2
chlorination
HCl
Mol. Wt.: 78.11
Mol. Wt.: 112.56
Benzene
Chlorobenzene
Mol. Wt.: 147
Mol. Wt.: 36.46
o-dichlorobenzene
Flow Diagram:
Water Caustic
Toluene
Chlorine gas
Chlorination
Scrubber
Hypochlorite
HCl
Chloro Benzene
Distillation
O-Dichloro Benzene
Residue
18
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
9. (O/M/P) Dichloro Benzene
Brief Process: The reaction between benzene and chlorine gives the mixture of chlorobenzene & oDichlorobenzene. The mixture is isolated by distillation to give pure Chlorobenzene & oDichlorobenzene.
Chemical Reaction:
Cl
Cl
Cl
Cl2
chlorination
HCl
Mol. Wt.: 78.11
Mol. Wt.: 112.56
Benzene
Chlorobenzene
Mol. Wt.: 147
Mol. Wt.: 36.46
o-dichlorobenzene
Flow Diagram:
Water Caustic
Toluene
Chlorine gas
Chlorination
Scrubber
Hypochlorite
HCl
Chloro Benzene
Distillation
O-Dichloro Benzene
Residue
19
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
10. O/P Chloro Toulene
Brief Process: The reaction between Toluene and chlorine gives the mixture of o-chlorotoluene & pchlorotoluene. The mixture is isolated by distillation to give pure o-chlorotoluene & p-chlorotoluene.
Chemical Reaction:
CH3
CH3
CH3
Cl
Chlorination
HCl
Cl2
Cl
Mol. Wt.: 92.14
Toluene
Mol. Wt.: 126.58
o-Chlorotoluene
Mol. Wt.: 126.58
Mol. Wt.: 36.46
p-Chlorotoluene
Flow Diagram:
Water Caustic
Toluene
Chlorine gas
Chlorination
Scrubber
Hypochlorite
HCl
O Chloro Toulene
Distillation
P Chloro Toulene
Residue
20
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
11. Iso Phthaloyl Chloride
Brief Process: The reaction between Isophthalic acid and Benzotrichloride gives the mixture of
Isophthaloyl chloride & Benzoyl chloride. The mixture is isolated by distillation to give pure oIsophthaloyl chloride & Benzoyl chloride.
Chemical Reaction:
COOH
CCl3
COCl
COCl
HCl
COOH
Mol. Wt.: 166.13
Isophthalic acid
COCl
Mol. Wt.: 195.47
Mol. Wt.: 203.02
Isophthaloyl chloride
Benzotrichloride
Mol. Wt.: 140.57
Mol. Wt.: 36.46
Benzoyl chloride
Flow Diagram:
Phathlic Acid
Benzotrichloride
Exchange Reaction
HCl
Benzol Chloride
Distillation
Residue
21
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
12. Phthaloyl Chloride
Brief Process: The reaction between Phthalic acid and Benzotrichloride gives the mixture of Phthaloyl
chloride & Benzoyl chloride. The mixture is isolated by distillation to give pure o-Phthaloyl chloride &
Benzoyl Chloride.
Chemical Reaction:
CCl3
COCl
COOH
COCl
HCl
COOH
COCl
Mol. Wt.: 166.13
Mol. Wt.: 195.47
Mol. Wt.: 203.02
Phthalic acid
Benzotrichloride
Phthaloyl chloride
Mol. Wt.: 140.57
Mol. Wt.: 36.46
Benzoyl chloride
Flow Diagram:
Phathlic Acid
Benzotrichloride
Exchange Reaction
HCl
Benzol Chloride
Distillation
Phthaloyl Chloride
Residue
22
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
13. o-Chlorobenzaldehyde
Brief Process: o-Chloro Benzal Chloride is hydrolyzed by hydrochloric acid in water. The Organic
layer is separated by phase separation. The Organic layer is distilled to give o-Chloro Benzaldehyde.
Chemical Reaction:
CHO
CHCl2
Cl
Cl
Hydrolysis
HCl
Mol. Wt.: 195.47
HCl
Mol. Wt.: 140.57
Mol. Wt.: 36.46
Mol. Wt.: 36.46
o-Chloro benzaldehyde
o-Chloro benzalchloride
Flow Diagram:
O-Chloro Benzal Chloride
25 % HCl
Reflux
HCl
Separation
Waste Water
O-chlorobenzaldehyde
Distillation
Residue
23
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
14. p-Chloro benzaldehyde
Brief Process: p-Chloro Benzal Chloride is hydrolyzed by hydrochloric acid in water. The Organic
layer is separated by phase separation. The Organic layer is distilled to give p-Chloro benzaldehyde.
Chemical Reaction:
CHO
CHCl2
Hydrolysis
HCl
HCl
Cl
Cl
Mol. Wt.: 195.47
Mol. Wt.: 140.57
Mol. Wt.: 36.46
Mol. Wt.: 36.46
p-Chloro benzaldehyde
p-Chloro benzalchloride
Flow Diagram:
p-Chloro Benzal Chloride
25 % HCl
Reflux
HCl
Separation
Waste Water
p-Chlorobenzaldehyde
Distillation
Residue
24
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
15. Benzyl Alcohol
Brief Process: Benzyl Chloride is hydrolyzed by sodium hydroxide in water. The Organic layer is
separated by phase separation. The Organic layer is distilled to give Benzyl Alcohol.
Chemical Reaction:
CH2Cl
CH2OH
NaOH
Mol. Wt.: 126.58
Hydrolysis
NaCl
H2O
Mol. Wt.:108.06
Mol. Wt.: 40
H2O
Mol. Wt.: 58.44
Benzyl alcohol
Benzyl chloride
Flow Diagram
Benzal Chloride
Caustic
Reflux
Separation
Waste Water
Benzyl Alcohol
Distillation
Residue
25
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
16. o-Chloro Benzyl Alcohol
Brief Process: o-Chlorobenzyl chloride is hydrolyzed by sodium hydroxide in water. The Organic layer
is separated by phase separation. The Organic layer is distilled to give o-Chloro Benzyl Alcohol.
Chemical Reaction:
CH2Cl
CH2OH
Cl
Cl
NaOH
Mol. Wt.: 161.03
Hydrolysis
NaCl
H2O
Mol. Wt.: 40
Mol. Wt.: 142.58
H2O
Mol. Wt.: 58.44
o-Chloro benzyl alcohol
o-Chloro benzyl chloride
Flow Diagram
o- Chloro Benzyl Chloride
Water
Reflux
Separation
Waste Water
Distillation
Residue
26
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
17. p-Chloro Benzyl Alcohol
Brief Process: p-Chlorobenzyl chloride is hydrolyzed by sodium hydroxide in water. The Organic layer
is separated by phase separation. The Organic layer is distilled to give p-Chloro benzyl alcohol.
Chemical Reaction:
CH2Cl
CH2OH
NaOH
Hydrolysis
NaCl
H2O
Cl
Mol. Wt.: 161.03
H2O
Cl
Mol. Wt.: 40
p-Chloro benzyl chloride
Mol. Wt.: 142.58
Mol. Wt.: 58.44
p-Chloro benzyl alcohol
Flow Diagram:
p- Chloro Benzyl Chloride
Water
Reflux
Separation
Waste Water
Distillation
Residue
27
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
18. Benzaldehyde
Brief Process: In a process for preparation of Benzaldehyde, hydrolysis of Benzal chloride is carried
out by hydrochloric acid in water. The Organic layer is separated by phase separation. The Organic
layer is distilled to give Benzaldehyde.
Chemical Reaction:
CHCl2
CHO
HCl
Mol. Wt.: 161.03
Hydrolysis
HCl
Mol. Wt.: 106.12
Mol. Wt.: 36.46
Mol. Wt.: 36.46
Benzaldehyde
Benzalchloride
Flow Diagram:
Benzal Chloride
Water
Reflux
HCl
Separation
Waste Water
Benzaldehyde
Distillation
Residue
28
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
19. 2-methoxy 5-bromo 6-methyl benzoyl chloride
Brief Process: The reaction between 2-methoxy-5-bromo-6-methyl benzoic acid and Benzotrichloride
gives the mixture of 2-methoxy-5-bromo-6-methyl benzoyl chloride & Benzoyl chloride. The mixture is
isolated by distillation to give pure 2-methoxy-5-bromp-6-methyl benzoyl chloride & Benzoyl chloride
Chemical Reaction:
COOH
CCl3
H3C
COCl
OCH3
H3C
COCl
OCH3
HCl
Br
Br
2-methoxy-5-bromo-6-methyl
benzoic acid
Mol. Wt.: 245.07
Benzotrichloride
2-methoxy-5-bromo-6-methyl
benzoyl chloride
Mol. Wt.: 195.47
Benzoyl chloride
Mol. Wt.: 36.46
Mol. Wt.: 140.57
Mol. Wt.: 263.52
Flow Diagram:
2-Methoxy-5-bromo-6-methyl
Exchange reaction
Benzo Trichloride
Benzoic acid
HCl
Distillation
Residue
Benzoyl chloride
2-methoxy-5-bromo-6-methyl benzoyl
chloride
29
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
20. 2,4 Dichloro Benzoyl Chloride
Brief Process: The reaction between 2,4-dichloro benzoic acid and Benzotrichloride gives the mixture
of 2,4-dichloro benzoyl chloride& Benzoyl chloride. The mixture is isolated by distillation to give pure
2,4 dichlorobenzoyl chloride & Benzoyl chloride.
Chemical Reaction:
COOH
COCl
COCl
CCl3
Cl
Cl
HCl
Mol. Wt.: 36.46
Cl
Cl
2,4-dichloro benzoic acid
Mol. Wt.: 191.01
2,4-dichloro benzoyl chloride
Benzotrichloride
Mol. Wt.: 195.47
Mol. Wt.: 209.46
Benzoyl chloride
Mol. Wt.: 140.57
Flow Diagram:
2-Methoxy-5-bromo-6-methyl
Exchange reaction
Benzo Trichloride
Benzoic acid
HCl
Distillation
Residue
Benzoyl chloride
2-methoxy-5-bromo-6-methyl benzoyl
chloride
30
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
21. 4 Methyl Benzoyl Chloride
Brief Process: The reaction between 4-methyl benzoic acid and Benzotrichloride gives the mixture of
4-methyl benzoyl chloride& Benzoyl chloride. The mixture is isolated by distillation to give pure 4methyl benzoyl chloride & Benzoyl chloride.
Chemical Reaction:
COOH
COCl
COCl
CCl3
HCl
Mol. Wt.: 36.46
CH3
CH3
4-methyl benzoic acid
4-methyl benzoyl chloride Benzoyl chloride
Benzotrichloride
Mol. Wt.: 195.47
Mol. Wt.: 136.15
Mol. Wt.: 154.59
Mol. Wt.: 140.57
Flow Diagram:
Exchange reaction
Benzo Trichloride
HCl
Distillation
Residue
Benzoyl chloride
4-methyl benzoyl chloride chloride
31
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
22. Propargyl Chloride
Brief Process: The reaction between pro-2-yn-1-ol and Benzotrichloride gives the mixture of
Propargyl Chloride & Benzoyl chloride. The mixture is isolated by distillation to give pure Propargyl
Chloride & Benzoyl hloride.
Chemical Reaction:
COCl
CCl3
C
C
OH
HCl
Cl
HC
HC
Mol. Wt.: 36.46
prop-2-yn-1-ol
Benzotrichloride
Mol. Wt.: 195.47
Mol. Wt.: 56.06
propargyl chloride
Mol. Wt.: 74.51
Benzoyl chloride
Mol. Wt.: 140.57
Flow Diagram:
Prop-2-yn-1-ol
Exchange reaction
Benzo Trichloride
HCl
Distillation
Residue
Benzoyl chloride
Propargyl chloride
32
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
23. Pivaloyl Chloride
Brief Process: The reaction between Pivalic acid and Benzotrichloride gives the mixture of Pivaloyal
Chloride & Benzoyl Chloride. The mixture is isolated by distillation to give pure Pivaloyal Chloride &
Benzoyl Chloride.
Chemical Reaction:
COCl
CCl3
O
CH3
CH3
H3C
HCl
H3C
COOH
Cl
Mol. Wt.: 36.46
CH3
Benzotrichloride
pivalic acid
Mol. Wt.: 195.47
CH3
Benzoyl chloride
pivaloyl chloride
Mol. Wt.: 140.57
Mol. Wt.: 120.58
Mol. Wt.: 102.13
Flow Diagram:
Pivalic acid
Exchange reaction
Benzo Trichloride
HCl
Distillation
Residue
Benzoyl chloride
Pivaloyl chloride
33
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
24. 4-Chloro Butryl Chloride
Brief Process: The reaction between 4-Chlorobutanoic Acid and Benzotrichloride gives the mixture of
4-Chlorobutyryl Chloride & Benzoyl Chloride. The mixture is isolated by distillation to give pure 4Chloro Butyryl Chloride & Benzoyl Chloride.
Chemical Reaction:
COCl
CCl3
O
Cl
HCl
Cl
COOH
Cl
Mol. Wt.: 36.46
4-chlorobutanoic acid
Mol. Wt.: 122.55
Benzotrichloride
Mol. Wt.: 195.47
4-chloro butyryl chloride
Benzoyl chloride
Mol. Wt.: 141
Mol. Wt.: 140.57
Flow Diagram:
4-chlorobutanoic acid
Exchange reaction
Benzo Trichloride
HCl
Distillation
Residue
Benzoyl chloride
4-chloro butyryl chloride
34
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
25. Terephthaloyl Chloride
Brief Process: The reaction between Terephthalic acid and Benzotrichloride gives the mixture of
Terephthalic Acid & Benzoyl Chloride. The mixture is isolated by distillation to give pure Terephthaloyl
Chloride & Benzoyl Chloride.
Chemical Reaction:
COOH
COCl
COCl
CCl3
HCl
Mol. Wt.: 36.46
COOH
terephthalic acid
Mol. Wt.: 166.13
COCl
Benzotrichloride
Mol. Wt.: 195.47
terephthaloyl chloride
Mol. Wt.: 203.02
Benzoyl chloride
Mol. Wt.: 140.57
Flow Diagram:
Terephthalic acid
Exchange reaction
Benzo Trichloride
HCl
Distillation
Residue
Benzoyl chloride
Terephthaloyl Chloride
35
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
26. n-Valeroyl Chloride
Brief Process: The reaction between N-Valeroyl acid and Benzotrichloride gives the mixture of Nvaleroyl Acid & Benzoyl Chloride. The mixture is isolated by distillation to give pure n-Valeroy Chloride
& Benzoyl chloride.
Chemical Reaction:
COCl
CCl3
O
H3C
HCl
H3C
COOH
Cl
Mol. Wt.: 36.46
N-valeroyl acid
Mol. Wt.: 102.13
Benzotrichloride
Mol. Wt.: 195.47
N-valeroyl chloride
Benzoyl chloride
Mol. Wt.: 120.58
Mol. Wt.: 140.57
Flow Diagram:
n-Valeroyl acid
Exchange reaction
Benzo Trichloride
HCl
Distillation
Residue
Benzoyl chloride
n-Valeroyl Chloride
36
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
27. 4-Chloro Benzoyl Chloride
Brief Process: The reaction between 4-Chlorobenzoicacid and Benzotrichloride gives the mixture of
4-Chlorobenzoyl Chloride& Benzoyl Chloride. The mixture is isolated by distillation to give pure 4Chlorobenzoyl Chloride & Benzoyl chloride.
Chemical Reaction:
COOH
COCl
COCl
CCl3
HCl
Mol. Wt.: 36.46
Cl
Cl
4-chloro benzoic acid
Mol. Wt.: 156.57
Benzotrichloride
Mol. Wt.: 195.47
4-chloro benzoyl chloride Benzoyl chloride
Mol. Wt.: 175.01
Mol. Wt.: 140.57
Flow Diagram:
4-chlorobenzoic acid
Exchange reaction
Benzo Trichloride
HCl
Distillation
Residue
Benzoyl chloride
37
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
28. 3-Nitro Benzoyl Chloride
Brief Process: The reaction between 3-nitrobenzoicacid and Benzotrichloride gives the mixture of 3Nitrobenzoyl Chloride& Benzoyl Chloride. The mixture is isolated by distillation to give pure 3Nitrobenzoyl chloride & Benzoyl chloride.
Chemical Reaction:
COOH
CCl3
COCl
COCl
HCl
NO2
NO2
3-nitrobenzoic acid
Benzotrichloride
Mol. Wt.: 167.12
Mol. Wt.: 195.47
3-nitrobenzoyl chloride
Mol. Wt.: 185.56
Benzoyl chloride
Mol. Wt.: 36.46
Mol. Wt.: 140.57
Flow Diagram:
3-Nitrobenzoic acid
Exchange reaction
Benzo Trichloride
HCl
Distillation
Residue
Benzoyl chloride
38
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
29. 4-Nitro Benzoyl Chloride
Brief Process: The reaction between 4-Nitrobenzoicacid and Benzotrichloride gives the mixture of 4Nitrobenzoyl Chloride & Benzoyl chloride. The mixture is isolated by distillation to give pure 4Nitrobenzoyl Chloride & Benzoyl chloride.
Chemical Reaction:
COOH
COCl
COCl
CCl3
HCl
Mol. Wt.: 36.46
NO2
NO2
4-nitrobenzoic acid
Benzotrichloride
Mol. Wt.: 195.47
Mol. Wt.: 167.12
4-nitrobenzoyl chloride
Mol. Wt.: 185.56
Benzoyl chloride
Mol. Wt.: 140.57
Flow Diagram:
4-nitrobenzoic acid
Exchange reaction
Benzo Trichloride
HCl
Distillation
Residue
Benzoyl chloride
4-Nitro benzoyl chloride
39
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
30. 4-Chloro 3,5 Dinitro Benzoic acid
Brief Process: Nitration of 4-chloro benzoic acid by using conc. sulphuric acid nitric acid.
Chemical Reaction:
COOH
COOH
HNO3
H2O
H2SO4
H2O
O2N
H2SO4
NO2
Cl
Cl
4-chloro benzoic acid
4-chloro-3,5-dinitrobenzoic acid
C7H5ClO2
Mol. Wt.: 156.57
C7H3ClN2O6
Mol. Wt.: 246.56
Flow Diagram:
4-chloroBenzoic acid
Sulphuric acid
Nitration
Nitric acid
Water
Quenching & filtration
Aqueous
4-Chloro 3,5-dinitro benzoic acid
40
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
31. 6, Nitro 3,4 Dichloro Aniline
Brief Process: Nitration of 3,4-dichloro aniline by using mixture of conc. sulphuric acid and nitric acid
to produce 6-nitro-3,4-dichloro aniline.
Chemical Reaction:
NH2
NH2
O2N
H2SO4
H2O
HNO3
H2SO4
Cl
Cl
Cl
Cl
6-nitro-3,4-dichloro aniline
3,4-dichloro aniline
C6H4Cl2N2O2
Mol. Wt.: 207.01
C6H5Cl2N
Mol. Wt.: 162.02
Flow Diagram:
3,4 dichloro aniline
Sulphuric acid
Nitration
Nitric acid
Water
Aqueous
6-nitro 3,4 dichloro aniline
41
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
32. 4, Nitro 5-Chloro 2-methyl Aniline
Brief Process:
: Nitration of 5-chloro-2-methyl aniline by using mixture of conc. Sulphuric acid and
nitric acid to produces 4-nitro-5-chloro-2-methyl aniline.
Chemical Reaction:
NH2
NH2
CH3
CH3
H2SO4
H2O
HNO3
H2SO4
Cl
Cl
NO2
5-chloro-2-methyl aniline
C7H8ClN
Mol. Wt.: 141.6
4-nitro-5-chloro-2-methyl aniline
C7H7ClN2O2
Mol. Wt.: 186.6
Flow Diagram:
5-chloro-2-methyl aniline
Sulphuric acid
Nitration
Nitric acid
Water
Aqueous
4-nitro-5-chloro-02-methyl aniline
42
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
33. 2-Nitro-4-methyl aniline
Brief Process: Nitration of 4-methyl aniline by using mixture of conc. sulphuric acid and nitric acid to
give 2-nitro-4-methyl aniline.
Chemical Reaction:
NH2
NH2
O2N
H2SO4
H2O
HNO3
H2SO4
CH3
CH3
2-nitro-4-methyl aniline
4-methyl aniline
C7H8N2O2
Mol. Wt.: 152.15
C7H9N
Mol. Wt.: 107.15
Flow Diagram:
4-methyl aniline
Sulphuric acid
Nitration
Nitric acid
Water
Aqueous
2.nitro 4-methyl aniline
43
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
34. 3, Nitro 4-Chloro Benzoic Acid
Brief Process: Nitration of 4-chloro benzotrifluoride by using conc. sulphuric acid and nitric acid to
produce 3-nitro-4-chloro benzotrifluoride.
Chemical Reaction:
CF3
CF3
HNO3
H2O
H2SO4
H2O
H2SO4
NO2
Cl
Cl
4-chloro benzotrifluoride
4-chloro-3-nitro benzotrifluoride
C7H4ClF3
Mol. Wt.: 180.55
C7H3ClF3NO2
Mol. Wt.: 225.55
Flow Diagram:
4-chloro benzotrifluoride
Sulphuric acid
Nitration
Nitric acid
Water
Aqueous
3-Nitro-4-chloro benzoic acid
44
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
35. 3, Nitro P Toluic Acid
Brief Process: Nitration of 4-methyl benzoic acid by using conc. sulphuric acid and nitric acid to
give 3-nitro para toluic acid.
Chemical Reaction:
COOH
COOH
HNO3
H2O
H2SO4
H2O
H2SO4
NO2
CH3
CH3
4-methylbenzoic acid
4-methyl-3-nitrobenzoic acid
C8H7NO4
Mol. Wt.: 181.15
C8H8O2
Mol. Wt.: 136.15
Flow Diagram:
Sulphuric acid
Nitration
Nitric acid
Water
Aqueous
3-nitro-para toluic acid
45
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
36. 2,4 Dichloro 6 Nitro Phenol
Brief Process:
: Nitration of 2,4 dichloro phenol by using
conc. Sulphuric acid and nitric acid to give
2,4-dichloro-6-nitrophenol.
Chemical Reaction:
OH
OH
Cl
H2SO4
HNO3
O2N
Cl
H2O
Cl
H2O
H2SO4
Cl
2,4-dichloro-6-nitrophenol
2,4-dichlorophenol
C6H4Cl2O
Mol. Wt.: 163
C6H3Cl2NO3
Mol. Wt.: 208
Flow Diagram:
2,5 di chloro phenol
Sulphuric acid
Nitration
Nitric acid
Water
Aqueous
2,4 dichloro-6-nitro phenol
46
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
Brief Process: Nitration of 2,3-dichloro phenol by using conc. Sulphuric acid and nitric acid to obtain
2,3-dichloro-4-nitro phenol.
Chemical Reaction:
OH
OH
Cl
H2SO4
Cl
HNO3
H2O
H2O
H2SO4
Cl
Cl
NO2
2,3-dichlorophenol
C6H3Cl2NO3
Mol. Wt.: 208
C6H4Cl2O
Mol. Wt.: 163
Flow Diagram:
2,3 di chloro phenol
Sulphuric acid
Nitration
Nitric acid
Water
Aqueous
2,3-dichloro -4-nitro phenol
47
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
Brief Process: Nitration of 2,5-dichloro phenol by using conc. Sulphuric acid nitric acid to obtain 2,5dichloro-4-nitrophenol.
Chemical Reaction:
OH
OH
Cl
H2SO4
Cl
HNO3
H2O
H2O
H2SO4
Cl
Cl
NO2
2,5-dichlorophenol
C6H4Cl2O
Mol. Wt.: 163
C6H3Cl2NO3
Mol. Wt.: 208
Flow Diagram:
2,5 -di chloro phenol
Sulphuric acid
Nitration
Nitric acid
Water
Aqueous
2,5-dichloro -4-nitro phenol
48
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
39. 1,3 Dinitro Benzene
Brief Process: Nitration of benzene by using conc. sulphuric and nitric acid to gives Nitro benzene.
Chemical Reaction:
NO2
NO2
HNO3
H2O
H2SO4
H2O
H2SO4
NO2
nitrobenzene
1,3-dinitrobenzene
C6H5NO2
Mol. Wt.: 123.11
C6H4N2O4
Mol. Wt.: 168.11
Flow Diagram:
Nitro benzene
Sulphuric acid
Nitration
Nitric acid
Water
Spent Acid
Nitro benzene
49
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
40. Nitro Benzene
Brief Process: Nitration of benzene by using conc.sulphuric and nitric acid to get Nitro benzene.
Chemical Reaction:
NO2
HNO3
H2SO4
H2O
H2O
H2SO4
nitrobenzene
benzene
C6H5NO2
Mol. Wt.: 123.11
C6H6
Mol. Wt.: 78.11
Flow Diagram:
Benzene
Sulphuric acid
Nitration
Nitric acid
Water
Spent Acid
1,3 di nitro benzene
50
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
41. 2,3,4 Nitro Toluene
Brief Process: Nitration of toluene by using conc,. Sulphuric and nitric acid to gives 50% 2- nitro
toluene and 45% 4-nitro toluene and 5% 3-nitro toluene, which is then separated by distillation.
Chemical Reaction:
CH3
CH3
CH3
CH3
NO2
HNO3
H2O
H2SO4
H2SO4
NO2
NO2
toluene
C7H8
Mol. Wt.: 92.14
2-nitro toluene
3-nitro toluene
4-nitro toluene
C7H7NO2
Mol. Wt.: 137.14
C7H7NO2
Mol. Wt.: 137.14
C7H7NO2
Mol. Wt.: 137.14
Flow Diagram:
Toluene
Sulphuric acid
Nitration
60% Nitric acid
Water
2 Nitro toluene
Spent Acid
4 Nitro toluene
3 Nitro toluene
51
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
42. 3,5 Di Nitro Benzoic Acid
Brief Process: Nitration of benzoic acid by using conc. Sulphuric acid nitric acid, to gives 3,5-dinitro
benzoic acid.
Chemical Reaction:
COOH
COOH
HNO3
H2O
H2SO4
H2O
O2N
benzoic acid
H2SO4
NO2
3,5-dinitrobenzoic acid
C7H6O2
Mol. Wt.: 122.12
C7H4N2O6
Mol. Wt.: 212.12
Flow Diagram:
Benzene
Sulphuric acid
Nitration
60% Nitric acid
Water
Spent Acid
3,5 Dinitro benzoic acid
52
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
43. P-Nitro Salicylic Acid
Brief Process: Nitration of salicylic acid by using sulfuric acid /nitric acid/ water to gives 5-nitro
salicylic acid.
Chemical Reaction:
OH
OH
COOH
COOH
HNO3
H2SO4
H2O
H2SO4
H2O
NO2
Salicylic acid
5-Nitro salicylic acid
C7H6O3
Mol. Wt.: 138.12
C7H5NO5
Mol. Wt.: 183.12
Flow Diagram:
Salicylic acid
Sulphuric acid
Nitration
60% Nitric acid
Water
Spent Acid
5-Nitro salicylic acid
53
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
44. 2,5 Dichloro Nitro Benzene
Brief Process: Nitration of p-Dichloro benzene by using Nitric acid & sulfuric acid, gives the crude
product of 2,5-dichloro nitro benzene, which is then distilled to get pure 2,5-dichloro nitro benzene.
Chemical Reaction:
Cl
Cl
NO2
H2SO4
HNO3
H2O
H2O
H2SO4
Cl
Cl
1,4-dichlorobenzene
2,5-dichloro nitrobenzene
C6H4Cl2
Mol. Wt.: 147
C6H3Cl2NO2
Mol. Wt.: 192
Flow Diagram:
P- dichlorobenzene
Sulphuric acid
Nitration
60% Nitric acid
Water
Spent Acid
Distillation
Residue
2,5 dichloro Nitro benzene
54
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
45. 3,4/2,3 Dichloro Nitro Benzene
Brief Process: Nitration of o-dichloro benzene by using Nitric acid & Sulfuric acid gives the product
mixture of 3,4-dichloronitro benzene & 2,3-dichloro nitro benzene, which is then separated by
distillation.
Chemical Reaction:
Cl
Cl
Cl
Cl
Cl
Cl
H2SO4
HNO3
H2O
H2O
H2SO4
NO2
NO2
1,2-dichlorobenzene
C6H3Cl2NO2
Mol. Wt.: 192
C6H3Cl2NO2
Mol. Wt.: 192
C6H4Cl2
Mol. Wt.: 147
Flow Diagram:
O- dichlorobenzene
Sulphuric acid
Nitration
60% Nitric acid
Water
Spent Acid
Distillation
Residue
55
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
46. 3,4 Dichloro Anilline
Brief Process: Reduction of 3,4-dichloro nitrobenzene by using catalyst raney nickel in solvent
methanol in presence of hydrogen gas to produce crude 3,4-Dichloro aniline.
Chemical Reaction:
Cl
Cl
Cl
Cl
Raney Ni
H2
NO2
NH2
C6H3Cl2NO2
Mol. Wt.: 192
C6H5Cl2N
Mol. Wt.: 162.02
Flow Diagram:
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filtration
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
56
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
47. 3-iso Propoxy Aniline
Flow Diagram:
3-Iso propoxy nitro benzene
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
3-iso propoxy Aniline
57
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
48. o-Toluidine
Brief Process: Reduction of 2-Nitro toluene by using catalyst raney nickel in solvent methanol by
hydrogen gas to get product o-Toluidine, which is then distilled to get pure o-Toluidine.
Chemical Reaction:
CH3
CH3
NH2
NO2
H2
Raney Ni
o-toluidine
2-nitro toluene
C7H9N
Mol. Wt.: 107.15
C7H7NO2
Mol. Wt.: 137.14
Flow Diagram:
2-nitro toluene
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
o-Toluidine
58
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
49. m-Toluidine
Brief Process: Reduction of 3-Nitro toluene by using catalyst raney nickel in methanol by hydrogen
gas to get product m-Toluidine, which is then distilled to get pure m-Toluidine.
Chemical Reaction:
CH3
CH3
H2
Raney Ni
NO2
NH2
2-nitro toluene
m-toluidine
C7H7NO2
Mol. Wt.: 137.14
C7 H 9 N
Mol. Wt.: 107.15
Flow Diagram:
3-nitro toluene
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
m-Toluidine
59
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
50. p-Toluidine
Brief Process: Reduction of 4-Nitro toluene by using catalyst Raney nickel in solvent methanol in
presence of hydrogen gas to gives crude p-Toluidine, which is then distilled to get pure p-Toluidine.
Chemical Reaction:
CH3
CH3
H2
Raney Ni
NO2
NH2
2-nitro toluene
p-toluidine
C7H7NO2
Mol. Wt.: 137.14
C7H9N
Mol. Wt.: 107.15
Flow Diagram:
4-nitro toluene
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
p-Toluidine
60
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
51. Aniline
Brief Process: Reduction of nitro benzene by using catalyst renay nickel in solvent methanol in
presence of hydrogen gas to gives crude Aniline, which is then distilled to obtain pure aniline.
Chemical Reaction:
NH2
NO2
H2
Raney Ni
nitrobenzene
aniline
C6H5NO2
Mol. Wt.: 123.11
C6H7N
Mol. Wt.: 93.13
Flow Diagram:
Nitro Benzene
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
Aniline
61
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
52. 3,4 Diamino Toluene
Brief Process: Reduction of 3,4-dinitro toluene by using catalyst raney nickel in solvent methanol, in
presence of hydrogen gas to get product of 3,4-diamino toluene.
Chemical Reaction:
CH3
CH3
H2
Raney Ni
NH2
NO2
NH2
NO2
3,4-diamino toluene
3,4-dinitrotoluene
C7H10N2
Mol. Wt.: 122.17
C7H6N2O4
Mol. Wt.: 182.13
Flow Diagram:
3,4-dinitro toluene
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
3,4-dinitro toluene
62
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
53. 2,5, Dimethyl 1,4 Phenylene Diamine
Brief Process: Reduction of 2,5 dimethyl-1-,4 dinitro benzene by using catalyst raney nickel,
methanol in presence of hydrogen gas to get product of 2,5 dimethyl-1,4-phenylene diamine.
Chemical Reaction:
NH2
NO2
CH3
CH3
Raney Ni
H2
H3C
H3C
NH2
NO2
2,5-dimethyl-1,4-phenylene diamine
1-chloro-4-methyl-2,5-dinitrobenzene
C8H12N2
Mol. Wt.: 136.19
C8H8N2O4
Mol. Wt.: 196.16
Flow Diagram:
2,5DM4DNB
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
2,5dimethyl 1,4 phenylene diamine
63
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
54. 2-Chloro, 5 Methyl, 1,4 Phenylene Diamine
Brief Process: Reduction of 1-chloro-4-methy-2,5-dinitro benzene by using catalyst raney nickel in
solvent methanol in presence of hydrogen gas to get product 2-chloro-5-methyl-1,4-phenylene
diamine.
Chemical Reaction:
NH2
NO2
Cl
Cl
Raney Ni
H2
H3C
H3C
NH2
NO2
2-chloro-5-methyl-1,4-phenylene diamine
1-chloro-4-methyl-2,5-dinitrobenzene
C7H9ClN2
Mol. Wt.: 156.61
C7H5ClN2O4
Mol. Wt.: 216.58
NH2
Flow Diagram:
1C4M2,5DNB
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
2-chloro 5-methyl 1,4 phenylene
diamine
64
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
55. 2 Chloro 1,4 Phenylene Diamine
Brief Process: Reduction of 2-chloro-1-,4 dinitro benzene by using catalyst raney nickel, in solvent
methanol, in presence of hydrogen gas to get product of 2-chloro1,4 dinitro benzene.
Chemical Reaction:
NH2
NO2
Cl
Cl
Raney Ni
H2
NH2
NO2
2-chloro-1,4-dinitrobenzene
2-chloro-1,4-phenylene diamine
C6H3ClN2O4
Mol. Wt.: 202.55
C6H7ClN2
Mol. Wt.: 142.59
Flow Diagram:
2C1,4DNB
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
2-chloro 1,4 phenylene diamine
65
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
56. 2, 5 Dichloro 1,4 Phenylene Diamine
Brief Process: Reduction of 2,5 dichloro-1-,4 dinitro benzene by using catalyst raney nickel in solvent
methanol, in presence of hydrogen gas to get product of 2,5-dichloro-1,4-phenylene diamine.
Chemical Reaction:
NH2
NO2
Cl
Cl
Raney Ni
H2
Cl
Cl
NH2
NO2
2,5-dichloro-1,4-phenylene diamine
1,4-dichloro-2,5-dinitrobenzene
C6H6Cl2N2
Mol. Wt.: 177.03
C6H2Cl2N2O4
Mol. Wt.: 237
Flow Diagram:
2,5DC4DNB
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
2,5dichloro 1,4 phenylene diamine
66
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
57. 2,4,5 TriChloro Aniline
Brief Process: Reduction of 2,4,5 tri chloro nitro benzene by catalyst renay nickel in solvent
methanol, in presence of hydrogen gas to get product of 2,4,5 tri chloro aniline.
Chemical Reaction:
NH2
NO2
Cl
Cl
H2SO4
HNO3
H2O
H2O
H2SO4
Cl
Cl
Cl
Cl
2,4,5-trichloro aniline
2,4,5-trichloro nitro benzene
C6H4Cl3N
Mol. Wt.: 196.46
C6H2Cl3NO2
Mol. Wt.: 226.44
Flow Diagram:
2,4,5 TCN
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
2,4,5 tri chloro aniline
67
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
58. 6 Methyl, 5 Amino Benzimidazlone
Brief Process: Reduction of 6-methyl-5-nitro benzimidazolone by using catalyst renay nickel in
solvent methanol in presence of hydrogen gas to get product of 6-methyl-5-amino benzimidazolone.
Chemical Reaction:
Raney Ni
O
H2
H2O
O
N
H
H3C
N
H
H3C
H
N
H2N
H
N
O2N
6-methyl-5-nitro benzimidazolone
H2O
6-methyl-5-amino benzimidazolone
C8H9N3O
Mol. Wt.: 163.18
C8H7N3O3
Mol. Wt.: 193.16
Flow Diagram:
6M5NBZ
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
6-methyl 5-Amino benzimidazolone
68
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
59. 5 Amino Benzimidazlone
Brief Process: Reduction of 5-nitro benzimidazolone by using catalyst renay nickel in solvent
methanol in presence of hydrogen gas to get product of 5-Amino benzimidazolone.
Chemical Reaction:
H2N
H
N
O2N
Raney Ni
O
H2
H
N
H2O
O
N
H
N
H
H2O
5-amino benzimidazolone
5-nitro benzimidazolone
C7H7N3O
Mol. Wt.: 149.15
C7H5N3O3
Mol. Wt.: 179.13
Flow Diagram:
5NBZ
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
5-Amino benzimidazolone
69
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
60. 3 Amino, 4 Chloro Benzoic Acid
Brief Process: Reduction of 3-nitro-4-chloro benzoic acid by using renay nickel ,methanol in
presence of hydrogen gas to get product of 3-Amino-4-chloro benzoic acid.
Chemical Reaction:
COOH
COOH
Raney Nickel
H2
H2O
H2O
NH2
NO2
Cl
Cl
3-amino-4-chlorobenzoic acid
4-chloro-3-nitrobenzoic acid
C7H6ClNO2
Mol. Wt.: 171.58
C7H4ClNO4
Mol. Wt.: 201.56
Flow Diagram:
3N4CBA
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
3-Amino 4-chloro benzoic acid
70
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
61. 3 Amino, 4 Chloro Benzotriflouride
Brief Process: Reduction of 3-nitro-4-chloro benzotrifluoride by using renay nickel ,methanol in
presence of hydrogen gas to get product of 3-Amino-4-chloro benzotrifluoride.
Chemical Reaction:
CF3
CF3
Raney Nickel
H2
H2O
H2O
NH2
NO2
Cl
Cl
3-amino-4-chloro benzotrifluoride
4-chloro-3-nitro benzotrifluoride
C7H5ClF3N
Mol. Wt.: 195.57
C7H3ClF3NO2
Mol. Wt.: 225.55
Flow Diagram:
3N4CBZ
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
3-Amino 4-chloro benzotrifluoride
71
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
62. 3 Amino,Benzotriflouride
Brief Process: Reduction of 3-nitro benzotrifluoride by using renay nickel ,methanol in presence of
hydrogen gas to get product of 3-Amino benzotrifluoride.
Chemical Reaction:
CF3
CF3
Raney Nickel
H2
H2O
H2O
NH2
NO2
3-amino benzotrifluoride
3-nitro benzotrifluoride
C7H6F3N
Mol. Wt.: 161.12
C7H4F3NO2
Mol. Wt.: 191.11
Flow Diagram :
3-NBZ
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
3-Amino benzotrifluoride
72
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
63. 3 ,5 Dichloro Aniline
Brief Process:
: Reduction of 3,5-dichloro nitrobenzene by using catalyst raney nickel in solvent
methanol in presence of hydrogen gas to get crude 3,5-Dichloro aniline, which is purified by
crystallization.
Chemical Reaction:
Cl
NO2
Cl
NH2
Raney Ni
H2
Cl
Cl
C6H3Cl2NO2
Mol. Wt.: 192
C6H5Cl2N
Mol. Wt.: 162.02
Flow Diagram :
3,5 DCNB
Reduction
Rany Nickel
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
73
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
Brief Process: Reduction of 2,5-dichloro nitrobenzene by using catalyst raney nickel in solvent
methanol in presence of hydrogen gas to get crude 2,5-Dichloro aniline, which is ten distilled to give
pure 2,5-Dichloro aniline.
Chemical Reaction:
Cl
Cl
NO2
NH2
Raney Ni
H2
Cl
Cl
C6H3Cl2NO2
Mol. Wt.: 192
C6H5Cl2N
Mol. Wt.: 162.02
Flow Diagram :
2,5 DCNB
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
74
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
Brief Process: Reduction of 2,3-dichloro nitrobenzene by using catalyst Raney nickel, methanol in
presence of hydrogen gas to produce 2,3-Dichloro aniline.
Chemical Reaction:
Cl
Cl
Cl
Cl
Raney Ni
H2
NO2
NH2
C6H5Cl2N
Mol. Wt.: 162.02
C6H3Cl2NO2
Mol. Wt.: 192
Flow Diagram :
2,3 DCNB
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
75
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
66. 3 Amino 4-Methyl Benzoic Acid
Brief Process: Reduction of 3-nitro-4-methyl benzoic acid by using catalyst raney nickel, in solvent
methanol in presence of hydrogen gas to get product of 3-Amino-4-methyl benzoic acid.
Chemical Reaction:
COOH
COOH
Raney Nickel
H2
H2O
H2O
NH2
NO2
CH3
CH3
3-amino-4-methylbenzoic acid
4-methyl-3-nitrobenzoic acid
C8H9NO2
Mol. Wt.: 151.16
C8H7NO4
Mol. Wt.: 181.15
Flow Diagram :
3-Nitro 4-Methyl Benzoic
Rany Nickel
Reduction
Water
Methanol
H2 Gas
Filter
Distillation
Raney Nickel Reco
Methanol
Methanol Loss
Residue
Water
3 Amino 4-Methyl Benzoic Acid
76
M/S RADHA MADHAV
3.6
PRE-FEASIBILITY
REPORT
Raw material required along with, Quantity likely source, marketing area of
final product/s, mode of transport of raw material and finished product.
Raw material and finished goods will be procured from local region and transportation will be through
trucks and tankers.
Details of raw material is given in Table 3-3
Table 3-3: Details of Raw material Source and Mode of Transport
Raw material
State
Quantity Mt/M
Means of Storage
1C4M2,5DNB
2,3 DCNB
Solid
619
Cool & dry place, in tightly closed container
Solid
657.5
2,4,5 TCN
Solid
637.5
2,4-Dichloro Benzoic
Acid
Solid
1530
2,5 DCNB
Solid
575
2,5DC4DNB
Solid
714
2,5DM4DNB
Solid
619
2.3 Dichloro phenol
Solid
826
2.4 Dichloro phenol
Solid
826
2.5 Dichloro phenol
Solid
826
25 % HCl
Liquid
7245
2-Chloro phenol
Liquid
1582
2M5B6MBA
Liquid
1575
2-Nitro Toluene
Liquid
675.5
3,4 DCNB
Liquid
657.5
Solid
869
3,4 DNT
Solid
643.5
3,5 DCNB
Solid
649
3-Iso Propoxy Nitro
Benzene
Solid
666.5
3N4CBA
Solid
652.5
3N4CBZ
Liquid
607.7
3-NBZ
Liquid
659
3-Nitro 4-Methyl Benzoic
Acid
Solid
632.5
3-Nitro Toluene
Liquid
614.4
3-Nitrobenzoic Acid
Solid
1524
4-Chloro Benzoic Acid
Solid
709
4-Chloro Benzotrifluoride
Liquid
888
77
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
4-Chloro Phenol
Solid
1600
4-Chlorobenzoic Acid
Solid
1500
4-Chlorobutanoic Acid
Liquid
1363.5
4-Methyl Aniline
Solid
781
4-Methyl Benzoic Acid
Solid
823
4-Methyl Benzoic Acid
Solid
1417.5
4-Nitro Toluene
Solid
625.5
4-Nitrobenzoic Acid
Solid
1515
5-Chloro-2-Methyl
Aniline
Solid
854
5NBZ
Solid
706.5
60% Nitric Acid
Liquid
946
6M5NBZ
Liquid
696
Benzal Chloride
Liquid
2415
Benzene
Liquid
2124
3555
Benzotrichloride
Carbon
Solid
50
Causitc
Solid
9120
u/N2 atm
Chlorine
gas
4265
FeCl3
Solid
3
Hydrogen gas
gas
285
Iso Phathlic Acid
Solid
1252.5
Methanol
Liquid
2307
ML
Liquid
720
Nitro benzene
Liquid
1410
N-Valeroyl acid
Liquid
1606.5
o-Chloro Benzal Chloride
Liquid
2190
ODCB
Liquid
813
Para Amino Phenol
Solid
2100
u/N2 atm
p-Chloro Benzal Chloride
Solid
2197.5
p-DCB
Solid
813
Phathlic Acid
Solid
1260
Phenol
liquid
1540
Pivalic acid
Solid
1350
PNCB
Solid
7410
Prop-2-yn-1-ol
Liquid
1200
(at 2-8 C)
PVC Resins
Solid
1171.5
Pyridine
Liquid
3
Rany Nickel
Solid
38
78
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
(In Water )
Salicylic acid
Solid
700
SMC
Liquid
370.5
Sulphuric acid
Liquid
Terephthalic acid
Solid
1293
Toluene
Liquid
746
Table 3-4: Details of Finished Goods, Source and Mode of Transport
Product
State
Capacity
Means of Storage
Chlorinated Poly Vinyl
Chloride
Solid
1500
Dry place, at normal
condition.
2,6 dichloro phenol
Solid
Cool & dry place, in tightly
closed container
2,4 dichloro phenol
Solid
closed container
2/4 Chloro Phenol
Solid
closed container u/N2 atm
Benzyl chloride/ Benzo
Trichloride/ Benzal
chloride
Liquid
p-Chorobenzyl Choride/ pChorobenzal Choride/ pChloro Benzotrichloride
Solid
o-Chorobenzyl Choride/oChorobenzal Choride/ oChloro Benzotrichloride
Liquid
closed container
Mono chloro benzene
Liquid
closed container
Ortho Dichloro Benzene
Liquid
closed container
Para Dichloro Benzene
Solid
closed container
p-Chloro Toluene/OChloro Toluene
Liquid
closed container
Mono Chloro Acetic Acid
Solid
closed container
Tri Chloro Acetyl Chloride
Liquid
Liquid
Phthaloyl Chloride
Liquid
closed container
o-Chlorobenzaldehyde
Liquid
closed container
P-Chlorobenzaldehyde
Solid
2000
1500
1500
79
M/S RADHA MADHAV
Product
State
Capacity
PRE-FEASIBILITY
REPORT
Means of Storage
Benzyl Alcohol
Liquid
Solid
closed container
Solid
closed container
Benzaldehyde
Liquid
2-Methoxy-5-Bromo-6Methyl Benzoyl Chloride
Liquid
closed container
2,4 Dichloro Benzoyl
Chloride
Liquid
closed container
4-Methyl Benzoyl Chloride
Liquid
closed container
Propargyl Chloride
Liquid
closed container (at 2-8 C)
Pivaloyl Chloride
Liquid
closed container u/N2 atm.
4-Chloro Butyryl Chloride
liquid
closed container
Terephthaloyl Chloride
solid
closed container
n-Valeroyl Chloride
Liquid
closed container
Liquid
Solid
closed container
Solid
closed container
Paracetamol
Solid
4-Chloro 3,5 Dinitro
Benzoic Acid
Solid
closed container
6-Nitro 3,4 Dichloro Aniline
Solid
closed container
4-Nitro ,5-Chloro, 2-Methyl
Aniline
Solid
closed container
2-Nitro 4-Methyl Aniline
Solid
3-Nitro 4-Chloro Benzoic
Acid
Solid
closed container
3 Nitro Para Toluic Acid
Solid
closed container
2,4 Dichloro 6 Nitro Phenol
Solid
100
100
closed container
closed container
80
M/S RADHA MADHAV
Product
State
Capacity
PRE-FEASIBILITY
REPORT
Means of Storage
closed container
2,3-Dichloro 4-Nitro
Phenol
Solid
closed container
2,5 Di Chloro 4 Nitro
Phenol
Solid
closed container
1,3 Di Nitro Benezene
Solid
closed container
Nitro Benzene
Liquid
closed container
2/3/4- Nitro Toulene
Liquid
closed container
3,5 Di Nitro Benzoic Acid
Solid
closed container
p-Nitro Salicylic Acid
Solid
closed container
2,5 Dichloro Nitro Benzene
Solid
closed container
3,4/2,3 Dichloro Nitro
Benzene
Solid
closed container
p-Hydroxy Aniline/OHydroxy Aniline
Solid
Solid
Cool, dry & dark place, in
tightly closed container
3-Iso propoxy Aniline
Liquid
closed container
o-Toluidine
Liquid
m-Toluidine
Liquid
closed container
p-Toluidine
Solid
closed container
Aniline
Liquid
closed container
3,4 Diamino Toluene
Solid
closed container
2,5 Dimethyl 1,4
Phenylene Diamine
Solid
closed container
2-chloro, 5-Methyl, 1,4
Phenylene Diamine
Solid
closed container (at 2-8 C)
2 Chloro 1,4 Phenylene
Diamine
Solid
closed container
2,5 Dichloro 1,4 Phenylene
Diamine
Solid
closed container
2,4,5 Tri Chloro Aniline
Solid
closed container
1000
500
81
M/S RADHA MADHAV
Product
State
6-Methyl 5-Amino
Benzimidazolone
Liquid
closed container
5-Amino Benzimidazolone
Solid
closed container
3-Amino 4-Chloro Benzoic
Acid
Solid
closed container
3-Amino 4-chloro
Benzotrifluoride
Liquid
closed container
3-Amino Benzotrifluoride
Solid
closed container
Solid
closed container
Solid
closed container
Capacity
PRE-FEASIBILITY
REPORT
Solid
Means of Storage
closed container
(at 250C)
Solid
closed container
3 Amino 4-Methyl Benzoic
Acid
Solid
closed container
3.7
Resource optimization/recycling and reuse envisaged in the project,
There will be no additional usage of resources due to proposed project.
3.8
Availability of water its source, energy/power requirement and source should
be given
Water
The details of water requirement is given in Table 3-5.
Table 3-5: Details of proposed water requirement with approximate quantity
S. No.
Areas of Consumption
Fresh Water (KLD)
1
Domestic
9
2
Manufacturing process
1760
3
Washing
20
4
Cooling Tower
200
5
Boiler
120
6
Gardening
Total
50
2159
The water is supplied by Gujarat Industrial Development Corporation (GIDC), reservoir. A copy of
water supply request letter is attached as Annexure 4
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M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
Power
The details of energy requirement is given in Table 3-6
Table 3-6: Details of proposed energy requirement with sources
S. No.
Requirement
Source
1
1000 KVA (1 MW)
Dakshin Gujarat Vij Company Ltd.
2
250 KVA
D.G sets (As Back-up)
A copy of Temporary DGVCL connection application letter is attached as Annexure 5
3.9
Quantity of wastes to be generated (liquid and solid) and scheme for their
management/disposal
Liquid Waste
The details of waste water generation is given in Table 3-7
Table 3-7: Details of waste water sources with approximate quantity
S.
Influent Quantity
Sources of waste water generation
No.
In KLD
1
Domestic
7.5
2
Manufacturing process
1803
3
Washing
16
4
Cooling Tower
45
5
Boiler
10
6
Gardening
0
Total
1881.5
The waste water will be treated in CETP of two phase. CETP of 1200 KLD capacity will be provide in
first phase and 800 KLD capacity in second phase. Treated effluent will be disposed out through single
outlet into deep sea through Dahej-Vilayat underground pipeline provided by GIDC.
Solid Waste
The details of Solid waste generation is given in Table 3-8
Table 3-8: Details of Hazardous waste along with the Category and disposal method
S. No
Waste Name
Category
Quantity/Year
Source
Disposal Method
1
Process residue
26.1
600
Process
Collection, Storage,
transportation and send to
CHWIF for incineration.
2
Carbon waste
35.3
4452
Process
TSDF.
3
Hypo chlorite
D2
24162.00
Process
Sale to authorized vendors
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PRE-FEASIBILITY
REPORT
4
HCl
D2
98874
Process
5
Acetic Acid
D2
44040.00
Process
6
Spent Acid
D2
68232.00
Process
7
Spent catalyst
35.2
44.4
Process
transportation and send for
regeneration/reactivation to
supplier.
8
Used Oil
5.1
200 Ltrs
Process
Collection, storage, reuse/sell
to authorized recycler
9
Discarded drums and
containers
33.3
12000 Nos
Process
Collection, decontaminations,
storage, reuse/sell to
authorized recycler.
10
ETP waste
34.3
960
ETP
TSDF.
Gaseous Emissions
The details of gaseous emissions is given in Table 3-9
Table 3-9: Details of emissions from process and flue gas stacks along with their mitigation
methods
S.
No.
Stack Attached
to
Stack
Height
(m)
Stack
Diameter
(m)
Pollutants
Probable
Concentration
Air Pollution
Control
Measures
Process Emission
1.
Reactor in MCA
plant
15
0.2
Water
Scrubber
followed by
Alkali scrubber
2.
CPVC plant
reactor
15
0.2
Alkali scrubber
3.
CPVC dryer
15
0.2
4
Chlorination
Reactor in TCAC
plant
15
0.2
5
CAC reactor in
TCAC plant
15
0.2
Caustic and
water
scrubber
6
Benzene
Chlorination
Reactor
15
0.2
Caustic and
water
scrubber
Chlorine
HCL
Less than 9
mg/NM3
Water
scrubber
Less than 20
mg/NM3
Caustic and
water
scrubber
84
M/S RADHA MADHAV
S.
No.
7
Stack Attached
to
Stack
Height
(m)
Stack
Diameter
(m)
Toluene
Chlorination
Reactor
15
0.2
Pollutants
Probable
Concentration
PRE-FEASIBILITY
REPORT
Air Pollution
Control
Measures
Caustic and
water
scrubber
Flue Gas Emission
1
Coal Fire Steam
Boiler
20
1.2
3
Hightem Boiler
15
1.2
4
D.G Set
11
0.2
Dust Collector
PM
150 m/NM3
SOx
100 ppm
None
Nox
50 ppm
Adequate
Stack Height
85
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
3.10 Schematic representations of the feasibility drawing which give information of
EIA purpose.
Government of India, as per its policy has given emphasis on Sustainable Development. While it is
supporting the industrial growth, the environmental protection has been made the integrated criteria
for this support. In line with this policy, Ministry of Environment & Forests has defined elaborated
‘Environmental Clearance (EC)’ framework under The Environment (Protection) Act, 1986
(Environmental Impact Assessment Notification, 2006) for establishing/expanding an
industry/development project. The EC process takes into consideration local conditions, public
concerns, effectiveness of impact assessment and proposed mitigation measures in sustaining
environmental equilibrium. The base documentation/study report, called Environmental Impact
Assessment (EIA) detailing baseline conditions, environmental impacts, mitigation measures and
management plan is required to be prepared for start of EC process. Prior Environmental Clearance is
required from concerned authorities for all projects detailed in the ‘Schedule’ as given in the
‘Notification date 14th September, 2006’. The projects listed as category A or B under EIA notification
require submission of EIA report as per approved TOR for appraisal by expert committee for EC. The
project site is located in Phase II, GIDC Industrial Estate of Dahej.
86
M/S RADHA MADHAV
4
4.1
PRE-FEASIBILITY
REPORT
SITE ANALYSIS
Connectivity
The proposed site is well connected with the roads connecting SH-6 located at an aerial distance of
~1.3 kms towards S and ~2.1 kms towards W.
Nearest railway station is located at Dahej at an aerial distance of ~3.9 kms towards SW. The major
Railways station is located at Bharuch at an aerial distance of ~39.3 kms towards ESE.
The Airport is located at Surat at an aerial distance of ~68.4 kms towards SSE and Vadodara at an
aerial distance of ~91.3 kms towards NE.
4.2
Land Form, Land Use and Land Ownership
Land Form:
Existing land is a flat land located near Gulf of Khambhat.
Land Use:
The site is located in Gujarat Industrial Development Corporation (GIDC), Phase II, Dahej,
Taluka: Vagra District Bharuch, Gujarat. The area has been specially developed for chemical
industries and part of it is declared as Special-Economic Zone (SEZ). Existing landuse is for
industrial development hence there will be no change in the landuse due to the proposed project.
Land Ownership:
The land is owned by M/S Radha Madhav Processors Pvt. Ltd. The Land Ownership document is
attached as Annexure 6
4.3
Topography
Dahej GIDC is located on west of Bharuch district at Gulf of Khambhat. Topographically, the area
is almost flat with gentle slope toward south and southwest i.e. toward Gulf.
Geologically, entire area is covered with recent age deposits of fluvial and marine origin. Major
part of it is covered with dark gray to brown Stiff clayey soil.
4.4
Existing land use pattern (agriculture, non-agriculture, forest, water bodies
(including area under CRZ)), shortest distances from the periphery of the
project to periphery of the forests, national park, wild life sanctuary, eco
sensitive areas, water bodies (distance from HFL of the river), CRZ.
The manufacturing unit is to be installed on the barren and un-developed land/plot which is located in
Gujarat Industrial Development Corporation (GIDC), Phase II Dahej. The existing land is an
undeveloped land which does not include agricultural, forestry, water bodies (including CRZ) and there
87
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
are no forests, national parks, wild life sanctuary, eco sensitive areas, water bodies (distance from HFL
of the river), CRZ within the study area.
4.5
Existing Infrastructure
The proposed project is a new Greenfield project and there are no existing infrastructures on the site.
4.6
Soil Classification
The project area falls under South Gujarat Agro-Climatic Zone-II and AEZ-21(Bharuch District).The
Zone is characterized by 70-80 cm rain fall, 1-3 % soil slope .The soil depth is >100 cm and
predominantly soils are clayey but near port soils are sandy in texture. Majority soils of this area have
developed from the trap and mostly having montmorrilonite predominant clay mineral. The soil salinity
is < 2.0 dS/m but due to ingress of sea water soils are highly saline especially in Lakhigam. At and
around project are soils are barren and Prosopis julifera (Gandobaval) is seen. However, in the
surrounding area sorghum, cotton, tur and fodder crops are grown. The map showing soil of the
region is attached as Annexure 7
4.7
Climatic data from secondary sources
The general agro-climatic zone of the study area is Semi-arid.
Information presented in subsequent paragraphs is from the most recently published Long Term
Climatological Tables for the nearest observatory, Bharuch by the Indian Meteorological Department
(IMD).
Temperature
Mean daily maximum temperature is recorded in the month of April at 40 °C.
From October to December, both day and night temperatures begin to decrease rapidly. January is
generally the coldest month, with a minimum temperature of 11.9 °C.
During the post-monsoon months of October and November, day temperatures remain between 16.922.0 ºC. In winters, i.e. December, January and February, average day temperatures remain between
11.9-14.4 ºC.
88
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
Wind
Table 4-1: Predominant Wind Direction
Month
Predominant Wind
First
January
Second
Third
Morning
Evening
Morning
Evening
Morning
Evening
NE
NE
SE
SW
SW
NW
February
NE
NE
NW
SW
SW
NW
March
SW
SW
NE
NW
NW
NE
April
SW
SW
NW
NW
SE
W
May
SW
SW
NW
NW
S
S
June
SW
SW
S
S
W
S
July
SW
SW
S
S
W
W
August
SW
SW
W
W
NW
NW
September
SW
SW
NW
NW
S
S
October
SW
SW
NE
NE
SE
SE
November
NE
NE
SE
SE
SW
SW
December
NE
NE
SE
NW
NW
NW
Rainfall
The total rainfall in year is observed to be 924.8 mm. Distribution of rainfall by season is 2.3 mm in
winter (December, January, February), 14.3 mm in summer (March, April, May), 869.3 mm in
monsoons (June, July, August, September) and 38.9 mm in post-monsoon (October - November).
Cloud Cover
The area remains cloudy between June - September, which is the active period of the monsoon
season. Cloud cover is 6-8 oktas during monsoon season, while it is 0-2 oktas in post monsoon, winter
and summer season.
Humidity
Most humid conditions are found in the monsoons, followed by post-monsoons, winter and summer in
that order. Mornings are more humid than evenings and humidity ranges from a high of 80-90% in
monsoon mornings to a low of 26-38% in summer evenings. During post-monsoon season, in morning
humidity remains between 68-75% and in the evening it remains between 37-44%.
4.8
Social Infrastructure available
Key infrastructure such as hospitals, schools, bank, places of worship and social/ community facilities
such as park, market, playground etc. education, health care, community development, income
distribution, employment and social welfare are available in nearby area of Dahej Industrial Estate.
89
M/S RADHA MADHAV
5
PRE-FEASIBILITY
REPORT
PLANNING BRIEF
5.1
Land use planning (breakup along with green belt etc)
Table 5-1: Land break-up
Size of Block
S. No
Description
1
Administrative Building/Instrument. O.C
laboratory and R & D laboratory
23×15
345.0
2
Canteen/HT/LT panel room
22×15
330
3
Security cabin
3×6
18
4
4. Pole. STR + Transformer
10×4
40
m×m
Area m2
5
Weigh Bridge
3×17
51
6
Central Utility Block
44×15
660
7
Production Building-1A-Plant H
22×20
440
8
Production Building-1B-Plant I
20×20
440
9
Production Building-2A-Plant F
22×20
440
10
Production Building-2B-Plant G
22×20
440
11
Production Building-3A-Plant D
22×21
462
12
Production Building-3B-Plant E
22×21
462
13
Production Building-4A-Plant A
22×23
506
14
Production Building-4B-Plant C
22×23
506
15
Production Building-5-Plant B
44×23
1012
16
Liquid Tank Farm
44×22
968
17
Explosive Tank Farm
44×21
924
18
Raw material Godown. MCC and control room
22.5×15
337
19
Future Expansion for solid raw material
godown
22.5×15
337
20
Finished product Godown. MCC and control
room
22.5×15
337
21
Future Expansion for solid finished product
godown
22.5×15
337
22
ETP area
37×25
925
23
Coal stock yard & Ash storage area
40×25
1000
24
Boiler house and Thermo pack
25×25
625
25
Overhead water tank
10×10
100
26
Fire hydrant and raw water tank
Total Plot Size
10×10
100
120×250
30000
The total plot area is 30000 m2 (~9 ha).
Greenbelt Area
The green belt area of 9900 m2 (`0.99 ha) will be provided as per the CPCB Guidelines.
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M/S RADHA MADHAV
5.2
PRE-FEASIBILITY
REPORT
Assessment of Infrastructure Demand (Physical & Social)
Project will need to have infrastructure for safe drinking water facilities, sanitation facilities for
employees, occupational health cent and approach road.
5.3
Amenities/Facilities
Basic Amenities like public transport, water supply, telecommunications, educational institutions,
hospitals etc. are available in nearby area of Dahej Industrial Estate.
91
M/S RADHA MADHAV
6
PROPOSED INFRASTRUCTURE
6.1
Industrial Area (Processing area)
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
6.2
4. Pole. STR + Transformer area
Production Building area
Liquid Tank Farm area
Explosive Tank Farm area
Raw material Godown. MCC and control room
Finished product Godown. MCC and control room
ETP area
Boiler house and Thermo pack
Coal stock yard & Ash storage area
Boiler house and Thermo pack area
Residential Area (Non- Processing Area)
1.
2.
3.
6.3
PRE-FEASIBILITY
REPORT
Administrative Building and O.C laboratory
Canteen and
Security cabin
Green Belt
The green belt area of 0.99 Ha will be provided as per the CPCB Guidelines.
6.4
Social Infrastructure
Availability of trained health staff in OH&S center, drinking water facilities, toilets, safe area for taking
food at workplace will be developed and maintained.
6.5
Connectivity
The proposed site is well connected with the roads connecting SH-6 located at an aerial distance of
~1.3 kms towards S and ~2.1 kms towards W.
Nearest railway station is located at Dahej at an aerial distance of ~3.9 kms towards SW. The major
Railways station is located at Bharuch at an aerial distance of ~39.3 kms towards ESE.
The Airport is located at Surat at an aerial distance of ~68.4 kms towards SSE and Vadodara at an
aerial distance of ~91.3 kms towards NE.
6.6
Drinking Water Management
The water will be supplied by Gujarat Industrial development Corporation (GIDC) reservoir.
92
M/S RADHA MADHAV
6.7
PRE-FEASIBILITY
REPORT
Sewerage System
Soak pit will be developed for sewage water disposal.
6.8
Industrial Waste Management
The waste water will be treated in CETP of two phase. CETP of 1200 KLD capacity will be provide in
first phase and 800 KLD capacity in second phase. Treated effluent will be disposed out through single
outlet into deep sea through Dahej-Vilayat underground pipeline provided by GIDC.
The industrial solid waste will be disposed off in Secured Landfill Facility/Common Hazardous waste
Incinerator facility depending on the type of waste.
6.9
Power Requirement & Supply/source
The power requirement is 1 MW which will be procured from Dakshin Gujarat Vij Company Ltd. For
emergency and as back-up D.G set (1 Nos.) of 250 KVA will be installed.
93
M/S RADHA MADHAV
7
7.1
PRE-FEASIBILITY
REPORT
REHABILITATION AND RESETTLEMENT (R & R) PLAN
Policy to be adopted (Central/State) in respect of the project affected persons
including home oustees, land oustees and landless.
Rehabilitation and Resettlement (R&R) plan is not applicable for the proposed project.
94
M/S RADHA MADHAV
8
PRE-FEASIBILITY
REPORT
PROJECT SCHEDULE & COST ESTIMATES
8.1
Likely date of start of construction and likely date of completion
The construction is likely to start after getting Environmental Clearance and NOC/CTE from the
authorized committee. The EIA studies is likely to get completed in 9-14 months.
8.2
Estimated project cost along with analysis in terms of economic viability of the
project
The total investment is envisaged at Rs.95.4 crores with the break-up as given in Table 8-1
Table 8-1: Cost Break-Up
S. No
1
Item
Land
Cost (Rs in Crores)
05
2
Factory Building & other Civil Construction
25
3
Plant & Machinery
50
4
Pre-operative Exps.
15.40
Total – Approx.
95.4
Economic Viability
Turnover of the proposed project is expected to be as per detail given in Table 8-2
Table 8-2: Expected Turnover from the proposed project
S. No
Year
Rs. in Crores
1
2014-2015
40
2
2015-2016
75
3
2016-2017
100
4
2017-2018
125
95
M/S RADHA MADHAV
9
PRE-FEASIBILITY
REPORT
ANALYSIS OF PROPOSAL
9.1
Financial and social benefits with special emphasis on the benefit to the local
people.





There shall be employment generation for the local people during the construction and
operational phase of the proposed facility.
During the constructional phase ~100 and during operational phase ~100 personnel’s will be
hired.
Local skilled and semi-skilled workers will be hired.
The positives impact include enhanced direct employment for technical/administrative
works and indirect employment opportunities for transporters of raw material and
finished goods.
There will be indirect development of small market for various aspects around the site.
96
M/S RADHA MADHAV
EC FOR PROPOSED GREENFIELD PROJECT OF CHLORINATED AND HYDROGENATED DERIVATIVES
FOR AGRO INTERMEDIATES PLANT AT GIDC DAHEJ II, TAL:VAGRA, DIST: BHARUCH, GUJARAT
PRE-FEASIBILITY
REPORT
Annexure 1: Map Showing General and Specific Location of Project Site
97
M/S RADHA MADHAV
EC FOR PROPOSED GREENFIELD PROJECT OF CHLORINATED AND HYDROGENATED DERIVATIVES
FOR AGRO INTERMEDIATES PLANT AT GIDC DAHEJ II, TAL:VAGRA, DIST: BHARUCH, GUJARAT
PRE-FEASIBILITY
REPORT
Annexure 2: Site Boundary Map
98
M/S RADHA MADHAV
EC FOR PROPOSED GREENFIELD PROJECT OF CHLORINATED AND HYDROGENATED DERIVATIVES FOR AGRO INTERMEDIATES PLANT
PRE-FEASIBILITY REPORT
Annexure 3: Site Layout Map
99
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
Annexure 4: Copy of Water supply request letter from GIDC
100
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
Annexure 5: Copy of Temporary DGVCL connection application
101
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
Annexure 6: Copy of land possession letter and receipt from GIDC
102
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
103
M/S RADHA MADHAV
PRE-FEASIBILITY
REPORT
Annexure 7: Soil profile of the region
104
Kadam
Environmental
Consultants
www.kadamenviro.com
Environment f or Development
CONTACT DETAILS
Vadodara (Head Office)
871/B/3, GIDC Makarpura, Vadodara, India – 390 010.
E: [email protected]; T:+91-265-3001000; F: +91-265-3001069
Delhi / NCR
th
Spaze IT Park, Unit No. 1124, 11 Floor, Tower B-3, Sector 49, Sohna Road, Gurgaon, India – 122 002
E: [email protected]; T/F : 0124-424 2430-436

Annexure-PFR - Environmental Clearances

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