Potencial bioplastike in trendi na področju

Seminar “BIOPLASTIKA” v okviru projekta PLASTiCE
Celje, 21. marec 2012
Potencial bioplastike in
trendi na področju
Janez Navodnik
GIZ Grozd Plasttehnika
Funkcionalni in inteligentni materiali
Novi materiali reagirajo na zunanje vplive (kot so T, svetloba, EM- polje, bio- ali
kemijski vplivi) s spreminjanjem oblike, barve ali pa pretvarjajo energijo (e-papir, ki
sveti ali predvaja film, folija, ki proizvaja elektriko, nit, ki se v telesu sama zavozla)
Prehod se bo zgodil že leta 2011
2
Funkcionalni in inteligentni materiali
Polimeri
imajo med
naprednimi
materiali
vodilno vlogo
3
Polimeri – postajajo najpomembnejši funkcionalni material
Svet: 202 mio ton
Rast 9% - 60 let
EU: 35 mio ton
130 md €
1,6 mio zaposlenih
37.000 firm
SLO: 330.000 ton + polizd.
1600 firm
18.000 zaposlenih
Več kot jeklo, Al, papir…
Polimeri + 1% = HT
+
orodja, stroji
1% = napredni materiali in tehnologije
ter znanje
4
Razvoj
Razvoj bioplastike skozi zgodovino
5
Trenutno stanje
Uporaba bioplastike v Evropi po namenu
uporabe
6
Trenutno stanje
Tržni deleži bioplastike v letu 2011 po namenu
uporabe
7
Trenutno stanje
Razvojni status (v letu 2011) termoplastov iz
bioplastike
8
BIOPLASTIKA
Trg
9
Trenutno stanje
Svetovne proizvodne kapacitete bioplastike
glede na vrsto materiala v 2010
10
Trenutno stanje
Svetovne proizvodne kapacitete bioplastike v
letu 2011 glede na vrsto materiala
11
Tenutno stanje in trendi
Proizvodne kapacitete bioplastike po svetu v letu 2011
in prognoza do 2015
12
Trendi
Proizvodne kapacitete bioplastike po svetu
do 2015
13
Trendi
Trg za bioplastiko bo ostal niša v prihodnjih
letih kljub skokoviti rasti proizvodnje
(predvidena je 44% letna rast)
14
Trendi
Skupne kmetijske površine in teoretično
potrebne kmetijske površine za proizvodnjo
bioplastike v letu 2015
15
Trendi
Komercialni tržni delež različnih bioplastičnih
materialov v letu 2015
16
BIOPLASTIKA
PRIMERI MATERIALOV
17
Primeri bioplastike
Bio-pultruzija (lan)
Solid particles in polyurethan foam mouldings
Hennecke in Bayer MaterialScience
18
Primeri bioplastike
Bio PA + vlakna bambusa
19
Primeri bioplastike
granulat
PE + vlakna soje in PP + vlakna soje
20
Primeri bioplastike
Bio-pultruzija (lan)
21
BIOPLASTIKA
Lesni kompoziti
22
LESNI KOMPOZITI
Primerjava specifične trdnosti in E/modula različnih materialov
23
LESNI KOMPOZITI
Sl. 2: Cene materialov glede na modul
24
LESNI KOMPOZITI
25
LESNI KOMPOZITI
8
E-modulus [GPa]
7
NF-PLA
6
5 NF-Lignin
4
3
2
PLA
PLA+IM
NF-Starch
PLA-, PHB-, Starchcompounds
1
NF-PHB coPHV
PHB coPHV
0
0
10
20
30
40
50
60
70
80
Charpy [kJ/m2]
26
LESNI KOMPOZITI
Furan-Flax Example Parts
Furan-flax prepreg
sandwich panel
Furan-flax
prepreg tubes
Furan-flax prepreg
ambulance panel
PUR sendviči – lesni odpadki
Razvoj poliuretana iz odpadne lesne biomase
BIOPUR: razvoj specialnih
ligninskih kompaundov, kot so
npr. elektroprevodni polimeri,
inženirski plasti in poliuretan.
Input (tons/year)
Cellulignin
20.000
Polyhydrig
alcohols
57.000
Catalyst
1.200
Hardeners
1.800
Output
LIQUEFYING
+
SYNTHESIS
Polyurethane - hard
Polyurethane - soft
Polyurethane - foam
64.000 tons/year, h=80 %
28
WPC – lesni kompoziti
Izbor WCP profilov
29
WPC – lesni kompoziti
Tržne možnosti lesnih kompozitov WPC
30
WPC – lesni kompoziti
Poraba WPC v vseh panogah
31
WPC – lesni kompoziti
Kdo proizvaja WPC
32
WPC – lesni kompoziti
Proizvodnja po državah
33
WPC – lesni kompoziti
Pri WPC Evropa zaostaja
34
WPC – lesni kompoziti
Važen je visok % lesa
35
WPC – lesni kompoziti
Les ni termično stabilen
36
WPC – lesni kompoziti
Proizvajalci po tipih
37
WPC – lesni kompoziti
Primerjava lastnosti
38
BIOPLASTIKA
Lastnosti
39
Lastnosti bioplastike
Barierne lastnosti bioplastike
40
Lastnosti bioplastike
PLA – mehanske lastnosti
41
Lastnosti bioplastike
PLA – mehanske lastnosti
42
Lastnosti bioplastike
PP + celuloza (Tencel FCP) – mehanske
lastnosti
43
BIOPLASTIKA
End-of-life
44
End-of-life
Skupine
odpadkov po
nemški
zakonodaji
45
End-of-life
Možni načini ravnanja z bioplastiko po koncu
uporabe
46
End-of-life
Bioplastiko je možno tudi reciklirati !
47
Biogoriva
Za vsako ceno!
48
Biogoriva
Idealni zaključen krog?
49
Biogoriva
Delež in rast biogoriv
50
Biogoriva
So vsa bio goriva zelena?
51
Biogoriva
Postopki predelave biomase
52
Biogoriva
Delež gozdnih virov
53
Biogoriva
Napovedi so optimistične
Evidence of the growth of biofuel power is underlined by the fact that Ford sold
nearly 250 000 flex fuel vehicles in 2006, while some 37 000 "green" cars designed to run on ethanol - were registered in Sweden, serviced by some
600 filling stations. Currently, the US has about 10 000 ethanol fuels stations,
and race cars competing in the 2007 IndyCar Series are now running on 100%
ethanol.
54
Biogoriva
Po državah ogromne
razlike
In 2005 the US revealed plans to
nearly double ethanol production by
2012, while the European Community
(EC) recently announced that biofuels
are projected to meet 10% of its
transportation fuel needs by 2020.
55
Biogoriva
Vplivi na CO2
emisije –
temnejša plat
medalje
Forget biofuels – burn
oil and plant forests
instead.
19:10 16 August 2007
by Catherine Brahic
56
End-of-life
Količina bioplina pri razgradnji različnih
bioragradljivih plastičnih materialov
57
Biogoriva
Zemlja – temnejša plat medalje
58
BIOPLASTIKA
Evropski raziskovalno razvojni
projekt
59
CENTRAL
EUROPE
Future laboratory for the diffusion and application of innovation in materials
science and engineering
FLAME
CENTRAL
EUROPE
Creating framework conditions for enhancing the development of the
biodegradable plastics market in central europe as an innovative test bed for
new product applications in selected industries
PLASTiCE
CORNET
Polylactic acid (PLA ) for new biobased packaging
Biobased
packing
CORNET
Development of tools to communicate advanced technologies on active and
intelligent packaging to meet the needs and trends in food processing and
retailing and to improve the knowledge transfer especially for smes
AIP –
COMPETENCE
PLATFORM
EUREKA
Advanced simulation methods for part and process development of complex
injection moulded parts tailored for SMEs
Automatic fire extinguisher
ADVANCED
PartSim
AFE
EUREKA
Development of biopolymers from waste wood biomass
BIOPUR
EUREKA
Improved product development and post-production controller system
iPDS
FP6
New classes of composite materials from renewable resources
BIOCOMP
FP6
New closed loop development guidance system for complex injection
moulded plastic parts and moulds applicable by sme
Pro4Plast
FP7
Complex semi-finished structural parts from improved thermoplastic biocomposites – improved wood plastic composites
BIOSTRUCT
www.biostructproject.eu
FP7
Development of a new recyclable long life co-injected high barrier packaging
for food applications, with broad design possibilities and reduced
manufacturing costs
COBAPACK
www.aimplas.es/proyectos/
cobapack
FP7
Whey protein-coated plastic films to replace expensive polymers and
increase recyclability
WHEYLAYER
FP7
Study of recyclability of painted, printed, metallized or laminated plastic parts
CLIPP
using supercritical CO2 technologies and nanofillers
www.clipp-project.eu
Eco-Innovation
Marine debris removal and preventing further litter entry
MarineClean
www.marineclean.eu
IPA SI-AT
Razvoj POLIREGIJE z združitvijo R&R in gospodarskih kapacitet s
poudarkom na MSP-jih na področju polimernih tehnologij, s ciljem
nadgradnje zaloge znanja, infrastrukture ter konkurenčnosti.
PolyRegion
CORNET
www.flameurope.eu
www.plastice.org
www.activepackaging.eu
demos.aitiip.com/eureka-ipds
www.biocomp.eu.com
www.wheylayer.eu
60
Projects
GP is/was involved in the following EU projects about
simulation methods in plastic production:
NEW CLOSED LOOP DEVELOPMENT GUIDANCE
SYSTEM FOR COMPLEX INJECTION MOULDED
PLASTIC PARTS AND MOULDS APPLICABLE BY
SME - Pro4Plast
IMPROVED PRODUCT DEVELOPMENT AND POSTPRODUCTION CONTROLLER SYSTEM - iPDS
ADVANCED SIMULATION METHODS FOR PART AND
PROCESS DEVELOPMENT OF COMPLEX
INJECTION MOULDED PARTS TAILORED FOR SMEs
– ADVANCED PartSim
ended
running
running
61
EUREKA - iPDS
Improved product development and
post production controller system
OBJECTIVES
1. Make a new Obligation Book for assemblies or products, not only parts, which consider their
particularities (Interferences, wear, lubrication, overlapping,…)
2. Develop an improved PDS (IPDS) for simplifying the use of this Obligation Book, including a new
“Stage 5” for post-production managing (logistics, quality control, etc…)
3. Embed the Support Tools into the software open code to be used without the Office pack,
improving them in some cases and creating new ones on others.
62
http://demos.aitiip.com/eureka-ipds/
CORNET – Advanced PartSim
ADVANCED SIMULATION METHODS FOR PART AND PROCESS DEVELOPMENT
OF COMPLEX INJECTION MOULDED PARTS TAILORED FOR SMEs
On the way to virtual prototyping with
• 4 new and highly innovative
• easy-to-use simulation-methods for OEM/SME
• developed on a prototype base
Coming from Pro4Plast Case Studies experience, these
4 methods are the
• most important missing development methods
in Stage 1 and Stage 2
63
Projects
GP is/was involved in the following EU projects about
new plastic materials from renewable resources:
NEW CLASSES OF
COMPOSITE MATERIALS
FROM RENEWABLE
RESOURCES - BIOCOMP
COMPLEX SEMI-FINISHED STRUCTURAL
PARTS FROM IMPROVED
THERMOPLASTIC BIO-COMPOSITES –
IMPROVED WOOD PLASTIC
COMPOSITES - BIOSTRUCT
POLYLACTIC ACID (PLA ) FOR
NEW BIOBASED PACKAGING Biobased packing
ended
As first in the world we
have produced some
wooden products
(loudspeaker) with the
technology of injection
molding of plastics.
running
ended
64
FP6: BIOCOMP
Loudspeaker, 100 % wood
www.biocomp.eu.com
BIO-BASED PACKING
Products
COMPOUNDING
- compounding and adding different
polymers and additives on semi-industrial
compounder
- improvement of mechanical properties,
especially impact strength, thermal
properties and barrier properties
- montmorillonit, CNT, impact modifiers
and n-AG for bactericide
- 32 different compounds
Projects
GP is/was involved in the following EU projects about
plastic materials for food packaging:
DEVELOPMENT OF TOOLS TO COMMUNICATE
ADVANCED TECHNOLOGIES ON ACTIVE AND
INTELLIGENT PACKAGING - AiP Competence Platform
DEVELOPMENT OF A NEW RECYCLABLE LONG LIFE COINJECTED HIGH BARRIER PACKAGING FOR FOOD
APPLICATIONS, WITH BROAD DESIGN POSSIBILITIES AND
REDUCED MANUFACTURING COSTS - COBAPACK
WHEY PROTEIN-COATED PLASTIC FILMS TO
REPLACE EXPENSIVE POLYMERS AND
INCREASE RECYCLABILITY - WHEYLAYER
STUDY OF RECYCLABILITY OF PAINTED, PRINTED,
METALLIZED OR LAMINATED PLASTIC PARTS USING
SUPERCRITICAL C02 AND NANOFILLERS - CLIPP
ended
ended
ended
running
67
FP7: COBAPACK
Development of a new recyclable long life
co-injected high barrier packaging for food
applications,with broad design possibilities
and reduced manufacturing costs
OBJECTIVE:
• Reduction in production costs using cheaper inner material
• Developing the manufacture process in just one step (substituting co-extrusion +
thermoforming by co-injection)
• Increasing products range
• Opening new markets for materials from renewable resources
• Increasing the amount of recycled commodity thermoplastics in the market
www.aimplas.es/proyectos/cobapack
68
FP7: WHEYLAYER
“Research for the Benefit of SMEs”
Aims of the Project
Develop Whey protein-coated plastic films to replace
expensive polymers and increase recyclability
Investigate a new application for whey, a by-product of
dairy industry
Extend food shelf life by addition of active ingredients
Whey
layer
www.wheylayer.eu
FP7: CLIPP
STUDY OF RECYCLABILITY OF PAINTED, PRINTED,
METALLIZED OR LAMINATED PLASTIC PARTS USING
SUPERCRITICAL C02 AND NANOFILLERS - CLIPP
Objective:
to promote a system which allows to use post-industrial wastes coming from scraps, and
reels refused by manufacturers of plastic film for flexible packaging and injected packages.
www.clipp-project.eu
70
Projects
GP is involved in the following EU projects:
running
IPA SI-AT: PolyRegion
Innovative value chain development for
sustainable plastics in Central Europe PLASTiCE
running
71
Projects
Technology centre Poli-Eko is involved in the following EU
project:
Marine debris removal and preventing
furter litter entry - MarineClean
running
www.marineclean.eu
Marine litter
removing
equipment
Edible and
biodegradable
food packaging
Smart
fishing
equipment
Marine Clean Grant Agreement ECO/10/277396/SI2.601543
72
Thank you very
much for your
attention!
Contact:
Slovenian Plasttechnics Cluster
Kidriceva 25a, SI-3000 Celje, Slovenia
phone: +386 3 425 84 00
fax: +386 3 425 84 09
e-mail: [email protected]
web: www.giz-grozd-plasttehnika.si