Carco, Inc Safety Data Sheet F-123 Marking Fluid , Red, Blue 1

Transcription

Carco, Inc
Safety Data Sheet
F-123 Marking Fluid , Red, Blue
SDS Revision Date: 1/6/2017
1. Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product Identity
F-123 Marking Fluid Red, Blue
Alternate Names
F-123 Marking Ink, Red, Blue
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use
See Technical Data Sheet.
Application Method
See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet
Carco, Inc
10333 Shoemaker
Company Name
P.O. Box 13859
Detroit, Michigan, USA 48213
Emergency
24 hour Emergency Telephone No.
ChemTel 1-800-255-3924 (MIS0001475)
International +01-813-248-0585
Phone +1 (313) 925-9000
Fax +1 (313) 925-9602
Email: [email protected]
Customer Service: Carco, Inc
2. Hazard identification of the product
2.1. Classification of the substance or mixture
Flam. Liq. 2;H225
Eye Irrit. 2;H319
STOT SE 3;H336
Highly Flammable liquid and vapor.
Causes serious eye irritation.
May cause drowsiness or dizziness.
2.2. Label elements
Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.
Danger
H225 Highly flammable liquid and vapor.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Page 1 of 13
Carco, Inc
Safety Data Sheet
[Prevention]:
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking.
P241 Use explosion-proof electrical / ventilating / light / equipment.
P264 Wash thoroughly after handling.
P280 Wear protective gloves / eye protection / face protection.
[Response]:
P303+361+353 IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin with water / shower.
P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do
- continue rinsing.
P337+313 If eye irritation persists: Get medical advice / attention.
P370+378 In case of fire: Use extinguishing media listed in section 5 of SDS for extinction.
[Storage]:
P403+233 Store in a well ventilated place. Keep container tightly closed.
[Disposal]:
P501 Dispose of contents / container in accordance with local / national regulations.
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and Federal
Hazardous Substances regulations.
Ingredient/Chemical Designations
Ethyl acetate
CAS Number:
Weight %
GHS Classification
Notes
1.0 - 10
Flam. Liq. 2;H225
Eye Irrit. 2;H319
STOT SE 3;H336
[1][2]
1-Methoxy-2-propanol
CAS Number: 0000107-98-2
25 - 50
Flam. Liq. 3;H226
STOT SE 3;H336
[1][2]
Isopropyl Alcohol
CAS Number: 0000067-63-0
25 - 50
Flam. Liq. 2;H225
Eye Irrit. 2;H319
STOT SE 3;H336
[1][2]
Titanium dioxide
CAS Number: 0013463-67-7
10 - 25
[1][2]
Rosin, Fumeric
CAS Number:
1.0 - 10
[1]
800680-57-9
Ethanol
CAS Number:
0000064-17-5
0000141-78-6
1.0 - 10
Flam. Liq. 2;H225
[1][2]
Acetic acid, 1-methylethyl ester
CAS Number: 0000108-21-4
1.0 - 10
Flam. Liq. 2;H225
Eye Irrit. 2;H319
STOT SE 3;H336
[1][2]
Cellulose Nitrate
CAS Number: 0009004-70-0
1.0 - 10
Expl. 1.1;H201
[1]
Page 2 of 13
Carco, Inc
Safety Data Sheet
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.
*The full texts of the phrases are shown in Section 16.
4. First aid measures
4.1. Description of first aid measures
General
In all cases of doubt, or when symptoms persist, seek medical attention.
Never give anything by mouth to an unconscious person.
Inhalation
Move the exposed person to fresh air at once. If not breathing, give artificial respiration. Give
oxygen. Get medical attention if any discomfort continues
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with
plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical
attention if any discomfort continues.
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin
cleanser.
DO NOT INDUCE VOMITING! If swallowed, vomiting may occur spontaneously. If vomiting
occurs, keep head below hips to prevent aspiration into lungs. Rinse mouth thoroughly. Get medical
attention.
Eyes
Skin
Ingestion
4.2. Most important symptoms and effects, both acute and delayed
Overview
Inhalation
Eyes
Ingestion: May cause stomach pain or vomiting. Exposure to solvent vapor concentrations from the
component solvents in excess of the stated occupational exposure limits may result in adverse health
effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue,
muscular weakness, drowsiness and in extreme cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be
absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with
possible reversible damage. See section 2 for further details.
5. Fire-fighting measures
5.1. Extinguishing media
Use foam, extinguishing powder, dry chemicals, or carbon dioxide. Water may be ineffective. Water may be used to keep fire
exposed containers cool.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition: No hazardous decomposition data available.
Page 3 of 13
Carco, Inc
Safety Data Sheet
Keep away from heat / sparks / open flames / hot surfaces - No smoking.
Use explosion-proof electrical / ventilating / light / equipment.
5.3. Advice for fire-fighters
In the event of fire, wear full protective clothing and NIOSH Approved Self-contained breathing apparatus with full face piece
operated in the pressure demand or other positive pressure mode. Move container from fire area if it can be done without risk.
Use water to keep fire exposed containers cool and disperse vapors.
ERG Guide No.
129
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Remove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of a major spill or spillage in
a confined space evacuate the area and check that solvent vapor levels are below the Lower Explosive Limit before re-entering.
6.2. Environmental precautions
Do not allow spills to enter drains or waterways.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled
clothing and wash thoroughly before reuse.
6.3. Methods and material for containment and cleaning up
Avoid sparks, flames, heat and smoking. Ventilate. Wear necessary protective equipment. Absorb in vermiculite, dry sand or
earth and place into containers.
Small Spill: Use a non-combustible material like vermiculite, sand or earth to soak up product and place in a container for later
disposal.
7. Handling and storage
7.1. Precautions for safe handling
Keep in containers lightly closed in a cool, well ventilated place. Do not store with oxidizing agents or acids. Keep in the original
container. Avoid direct sunlight
Store in accordance with the National Fire Protection Association's publication NFPA 30, Flammable and Combustible Liquids
Code. 29 CFR 1910.106 applies to the handling, storage, and use of flammable and combustible liquids.
See section 2 for further details. - [Prevention]:
7.2. Conditions for safe storage, including any incompatibilities
Handle containers carefully to prevent damage and spillage.
Store in a cool dry area, away from heat, sparks and open flame. Keep containers sealed when not in use. Store out of direct
sunlight.
Store in a cool dry place.
Incompatible materials: Store away from oxidizers and acids.
See section 2 for further details. - [Storage]:
7.3. Specific end use(s)
No data available.
Page 4 of 13
Carco, Inc
Safety Data Sheet
8. Exposure controls and personal protection
8.1. Control parameters
Exposure
CAS No.
0000064-17-5
0000067-63-0
0000107-98-2
0000108-21-4
0000141-78-6
0009004-70-0
0013463-67-7
800680-57-9
Ingredient
Ethanol
Isopropyl Alcohol
Ethyl acetate
Cellulose Nitrate
Titanium dioxide
Rosin, Fumeric
Source
Value
OSHA
TWA 1000 ppm (1900 mg/m3)
ACGIH
STEL: 1000 ppm Revised 2009,
NIOSH
TWA 1000 ppm (1900 mg/m3)
Supplier
No Established Limit
OSHA
TWA 400 ppm (980 mg/m3)STEL 500 ppm
ACGIH
TWA: 200 ppmSTEL: 400 ppm Revised 2003,
NIOSH
TWA 400 ppm (980 mg/m3) ST 500 ppm (1225 mg/m3)
Supplier
OSHA
ACGIH
TWA: 50 ppmSTEL: 75 ppm
NIOSH
TWA 100 ppm (360 mg/m3) ST 150 ppm (540 mg/m3)
Supplier
OSHA
TWA 250 ppm (950 mg/m3)
ACGIH
TWA: 100 ppmSTEL: 200 ppm Revised 2003,
NIOSH
no established RELs
Supplier
OSHA
TWA 400 ppm (1400 mg/m3)
ACGIH
TWA: 150 ppm
NIOSH
TWA 400 ppm (1400 mg/m3)
Supplier
OSHA
ACGIH
NIOSH
Supplier
OSHA
TWA 15 mg/m3
ACGIH
TWA: 10 mg/m32B, Revised 2006,
NIOSH
Ca
Supplier
OSHA
ACGIH
Page 5 of 13
Carco, Inc
Safety Data Sheet
NIOSH
Supplier
Carcinogen Data
CAS No.
0000064-17-5
0000067-63-0
0000107-98-2
0000108-21-4
0000141-78-6
0009004-70-0
0013463-67-7
800680-57-9
Ingredient
Ethanol
Isopropyl Alcohol
Ethyl acetate
Cellulose Nitrate
Titanium dioxide
Rosin, Fumeric
8.2. Exposure controls
Respiratory
Eyes
Skin
Source
Value
OSHA
Select Carcinogen: No
NTP
Known: No; Suspected: No
IARC
Group 1: Yes; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
OSHA
NTP
IARC
Group 1: No; Group 2a: No; Group 2b: No; Group 3: Yes; Group 4: No;
OSHA
NTP
IARC
Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;
OSHA
NTP
IARC
OSHA
NTP
IARC
OSHA
NTP
IARC
OSHA
NTP
IARC
Group 1: No; Group 2a: No; Group 2b: Yes; Group 3: No; Group 4: No;
OSHA
NTP
IARC
Atmospheric levels should be maintained below the exposure guideline. When respiratory protection
is required for certain operations, use an approved air-purifying respirator. The following should be
effective types of air purifying respirators: Organic vapor cartridge.
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids.
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. All parts
of the body should be washed after contact. Use gloves chemically resistant to this material when
prolonged or frequently repeated contact could occur. Examples of preferred glove barrier materials
Page 6 of 13
Carco, Inc
Safety Data Sheet
Engineering Controls
Other Work Practices
include: Butyl rubber. Polyethylene/ethyl vinyl alcohol laminate ("PE/EVAL"). Examples of
acceptable glove barrier materials include: Natural rubber ("latex"). Neoprene. Nitrile/butadiene
rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Viton
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of
local exhaust ventilation and good general extraction. If these are not sufficient to maintain
concentrations of particulates and any vapor below occupational exposure limits suitable respiratory
protection must be worn.
Do not smoke, or drink in work area. Keep away from foodstuffs and beverages. Avoid contact with
eyes and skin.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet.
Promptly remove soiled clothing and wash thoroughly before reuse.
See section 2 for further details. - [Prevention]:
9. Physical and chemical properties
Appearance
Odor
Odor threshold
pH
Melting point / freezing point
Initial boiling point and boiling range
Flash Point
Evaporation rate (Ether = 1)
Flammability (solid, gas)
Upper/lower flammability or explosive limits
Vapor pressure (Pa)
Vapor Density
Specific Gravity
Solubility in Water
Partition coefficient n-octanol/water (Log Kow)
Auto-ignition temperature
Decomposition temperature
Viscosity (cSt)
VOC %
% Volatile
Colored Liquid
Sweet alcohol
Not Measured
Not Measured
Not Measured
82 C 160F
10-15C 50-60F Method (Setaflash)
1.0
Not Applicable
Lower Explosive Limit: 3.0
Upper Explosive Limit: 19.0
4.16 kPa Temperature (C) 20
>2
0.810 g/mL Temperature
65-75%
Not Measured
Not Measured
Not Measured
Not Measured
65-75% Approximately 5.9 Lbs/gal
65-75%
9.2. Other information
No other relevant information.
10. Stability and reactivity
Page 7 of 13
Carco, Inc
Safety Data Sheet
10.1. Reactivity
Hazardous Polymerization will not occur.
10.2. Chemical stability
Stable under normal circumstances.
10.3. Possibility of hazardous reactions
No data available.
10.4. Conditions to avoid
High temperatures, fires, and incompatibles.
10.5. Incompatible materials
Store away from oxidizers and acids.
10.6. Hazardous decomposition products
No hazardous decomposition data available.
11. Toxicological information
Acute toxicity
Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may
result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,
liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in
extreme cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation
and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may
cause irritation and soreness with possible reversible damage.
Ingredient
Oral LD50,
mg/kg
Skin LD50,
mg/kg
Ethyl acetate - (141-78-6)
5,600.00, Rat Category: NA
18,000.00, Rabbit
- Category: NA
1-Methoxy-2-propanol - (107-98-2)
5,000.00, Rat Category: 5
13,000.00, Rabbit No data available No data available No data available
- Category: NA
Isopropyl Alcohol - (67-63-0)
4,710.00, Rat Category: 5
Titanium dioxide - (13463-67-7)
Rosin, Fumeric - (800680-57-9)
No data available No data available No data available No data available No data available
Ethanol - (64-17-5)
20,000.00, Rabbit
- Category: NA
Acetic acid, 1-methylethyl ester - (108-21-4)
20,000.00, Rabbit 17,129.60, Rabbit No data available No data available
- Category: NA
- Category: NA
Page 8 of 13
Inhalation
Vapor LD50,
mg/L/4hr
58.60, Rat Category: NA
10,000.00, Rabbit No data available
- Category: NA
Inhalation
Dust/Mist LD50,
mg/L/4hr
Inhalation
Gas LD50,
ppm
No data available No data available
No data available
Carco, Inc
Safety Data Sheet
Cellulose Nitrate - (9004-70-0)
5,000.00, Mouse - No data available No data available No data available No data available
Category: 5
Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in
the calculation of the product's ATE (Acute Toxicity Estimate).
Classification
Category
Hazard Description
Acute toxicity (oral)
---
Not Applicable
Acute toxicity (dermal)
---
Not Applicable
Acute toxicity (inhalation)
---
Not Applicable
Skin corrosion/irritation
---
Not Applicable
Serious eye damage/irritation
2
Respiratory sensitization
---
Not Applicable
Skin sensitization
---
Not Applicable
Germ cell mutagenicity
---
Not Applicable
Carcinogenicity
---
Not Applicable
Reproductive toxicity
---
Not Applicable
STOT-single exposure
3
STOT-repeated exposure
---
Not Applicable
Aspiration hazard
---
Not Applicable
12. Ecological information
12.1. Toxicity
No additional information provided for this product. See Section 3 for chemical specific data.
Aquatic Ecotoxicity
96 hr LC50 fish,
mg/l
48 hr EC50 crustacea,
mg/l
ErC50 algae,
mg/l
100.00, Danio rerio
100.00, Daphnia magna
100.00 (72 hr), Desmodesmus
subspicatus
1,000.00, Oncorhynchus
mykiss
1,000.00 (96 hr), Selenastrum
capricornutum
Isopropyl Alcohol - (67-63-0)
1,400.00, Lepomis
macrochirus
100.00 (72 hr), Scenedesmus
subspicatus
Titanium dioxide - (13463-67-7)
1,000.00, Fundulus
heteroclitus
5.50, Daphnia magna
5.83 (72 hr), Pseudokirchneriella
subcapitata
Ingredient
Ethyl acetate - (141-78-6)
1-Methoxy-2-propanol - (107-98-2)
Rosin, Fumeric - (800680-57-9)
Ethanol - (64-17-5)
Not Available
Not Available
Not Available
42.00, Oncorhynchus
2.00, Daphnia magna
17.921 (96 hr), Ulva pertusa
Page 9 of 13
Carco, Inc
Safety Data Sheet
mykiss
Acetic acid, 1-methylethyl ester - (108-21-4)
Not Available
Not Available
Cellulose Nitrate - (9004-70-0)
Not Available
Not Available
Not Available
579.00 (96 hr), Pseudokirchneriella
subcapitata
12.2. Persistence and degradability
There is no data available on the preparation itself.
12.3. Bioaccumulative potential
Not Measured
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects
No data available.
13. Disposal considerations
13.1. Waste treatment methods
Do not allow into drains or water courses. Wastes and emptied containers should be disposed of in accordance with regulations
made under the Control of Pollution Act and the Environmental Protection Act.
Using information provided in this data sheet advice should be obtained from the Waste Regulation Authority, whether the
special waste regulations apply.
14. Transport information
14.1. UN number
14.2. UN proper shipping
name
14.3. Transport hazard
class(es)
14.4. Packing group
DOT (Domestic Surface
Transportation)
UN1210
Printing ink
IMO / IMDG (Ocean
Transportation)
UN1210
Printing ink
ICAO/IATA
DOT Hazard Class: 3
DOT Label: 3
IMDG: 3
Sub Class: Not Applicable
EmS: F-E, S-D
II
II
Air Class: 3
Packing Instruction:
Cargo Only - 364,
Passenger -353
II
14.5. Environmental hazards
Marine Pollutant: Yes
IMDG
14.6. Special precautions for user
Page 10 of 13
UN1210
Printing ink
Carco, Inc
Safety Data Sheet
No further information
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not Applicable
15. Regulatory information
The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are
represented. All components of this material are either listed or exempt from listing on the TSCA
Inventory.
Regulatory Overview
NFPA Rankings:
B2 D2B
WHMIS Classification
US EPA Tier II Hazards
Fire:
Sudden Release of Pressure:
Reactive:
Immediate (Acute):
Delayed (Chronic):
EPCRA 311/312 Chemicals and RQs (lbs):
Ethyl acetate
( 5,000.00)
N-Butyl Acetate
( 5,000.00)
EPCRA 302 Extremely Hazardous :
(No Product Ingredients Listed)
EPCRA 313 Toxic Chemicals:
Isopropyl Alcohol
Proposition 65 - Carcinogens (>0.0%):
Proposition 65 - Developmental Toxins (>0.0%):
Proposition 65 - Female Repro Toxins (>0.0%):
Proposition 65 - Male Repro Toxins (>0.0%):
Page 11 of 13
Yes
No
No
Yes
No
Carco, Inc
Safety Data Sheet
N.J. RTK Substances (>1%):
Cellulose Nitrate
Ethanol
Ethyl acetate
Isopropyl Alcohol
Titanium dioxide
Penn RTK Substances (>1%):
Cellulose Nitrate
Ethanol
Ethyl acetate
Isopropyl Alcohol
Titanium dioxide
16. Other information
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or
warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility
and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this
product must comply with all applicable health and safety laws, regulations, and orders.
The full text of the phrases appearing in section 3 is:
H201 Explosive; mass explosion hazard.
H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H319 Causes serious eye irritation.
H336 May cause drowsiness and dizziness.
This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not
applicable.
This product is RoHS and REACH compliant. It does not contain any of the RoHS listed substances. It does not contain any
chemical from the candidate list of Substances of Very High Concern (SVHC), Annex XIV, or Annex XVII of Reach.
This information is based on our present knowledge. However, it does not constitute a guarantee for any specific product
properties.
Page 12 of 13
Carco, Inc
Safety Data Sheet
Carco urges the recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to
become aware of and understand the data contained in this SDS and any hazards associated with the product. The information
herein is provided in good faith and believed to be accurate as of the effective date shown above. The use of this product is
beyond the control Carco or it’s distributor, therefore, no warranty, express or implied, is given. Regulatory requirements are
subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities
comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped.
Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the
conditions necessary for the safe use of this product.
End of Document
Page 13 of 13

Carco, Inc Safety Data Sheet F-123 Marking Fluid , Red, Blue 1

Transcription

Similar documents