Ferrate Treatment Technologies - Environmental Technical Sales

Transcription

Oxidation
Fe(VI)
( )
Disinfection
Fe(VI)
Coagulation
Fe(III)
FERRATE SOLVES TREATMENT CHALLENGES IN MULTIPLE
APPLICATIONS ACROSS BROAD GLOBAL INDUSTRIES
Florida Energy Summit – October 15, 2013
Ferrate Treatment Technologies, LLC
www.ferratetreatment.com
Who is FTT?
• Founder and inventor, CEO Luke Daly has developed the on-site
synthesis of Ferrate through the patented Ferrator®.
• In business for over 10 years, he has spent millions of dollars
perfecting this technology.
• Over
O
100 patents
t t iissued
d iin 60 countries.
ti
• Recipient of numerous recognitions:
– World Economic Forum 2011 Technology Pioneer Award.
– Wall Street Journal Best & Brightest Environmental
Technology Innovation Award Worldwide.
– Forbes Magazine One of America’s
America s Most Promising
Companies.
• Corporate office based in Orlando with adjacent fabrication
facility.
2
Treatment Technology Breakthrough
Best and Brightest Environmental
Technology Innovation
ANSI Standard 61 Certified
f
3
Produced From Common Feedstocks
Iron + Bleach + Caustic = Ferrate + Salt + Water
2FeCl3 + 3NaOCl + 10NaOH = 2Na2FeO4 + 9NaCl + 5H2O
(FeO42- Synthesis Stoichiometry)
+
OCl- + OHFerrate Treatment Technologies, LLC
Fe3+
FeO42www.ferratetreatment.com
4
Ferrate Chemistry is Powerful
•
Ferrate chemistry is well documented
•
Over 500 papers published worldwide
•
A Higher Re-dox
Re dox Potential than Ozone
Oxidation
Fe(VI)
Disinfection
Fe(VI)
Coagulation
Fe(III)
•
Extensive governmental and peer review
•
Unlike chlorine, Ferrate does not produce carcinogenic byproducts
•
Ferrate is the only
y environmentally
y friendly,
y, multi-purpose,
p p , multitreatment option for Water and Wastewater Purification
•
As Ferrate’s charge is reduced from 6+ to 3+, it delivers advanced
Oxidation, Disinfection, Coagulation, Dewatering and Deodorization
5
The Breakthrough
• First Ferrate Synthesis Patent: 1953 in the U.S. by Thompson,
Ockerman and Schreyer.
Ockerman,
Schreyer
• Prior Commercialization attempts Failed: ADC, Olin ($12
Million) Battelle,
Million),
Battelle Lyntech,
Lyntech Carus,
Carus and International efforts
efforts….
• Packaging, Transport, and Storage Costs were too high:
Previous
ev ous ferrate
e ate products
p oducts had
ad to be hermetically
e et ca y sealed
sea ed to ship.
s p.
• FTT’s Breakthrough: On-site synthesis eliminated supplychain costs to allow industrial-scale pproduction at the site of use.
• Least Cost Manufacturing Method: Production costs at a
fraction of any other method.
6
How Ferrate (VI) Works
• (OH)FeO42 + H2O  FeO433- + FeO322-  Fe(OH)3
+6
+5
+4
+3
Ferrate(VI)
Oxidant 

Disinfectant
Oxidation d
Fe(VI)
Coagulant

Ferric Hydroxide
Co-precipitate
f
Disinfection
Fe(VI)
Coagulation
l
Fe(III)
7
Ferrate is a Multi-Treatment Process
• Precipitates phosphorus
y metals
• Removes heavy
• Kills spores, bacteria,
viruses and protozoa
• No aquatic toxicity
• Deactivates residual
drugs & pesticides
• Reduces Organics
• Removes color & odors
Untreated Frac Flow
Flow-back
back - Post Ferrate Treatment
• Dewaters Solids
• Results in an Fe(OH)3 or Iron(III) final product that is non-toxic and
environmentally
i
ll benign
b i which
hi h can bbe easily
il filtered
fil d or settled.
l d
8
Applications of Ferrate
• Wastewater Disinfection and Nutrient Removal
• Elimination of Disinfection By-products (DBPs)
• Wastewater Reuse – ASR, Wetlands Restoration, Industrial Feeds
• Drinking Water Disinfection
• CSOs – Distributed Treatment Models
• Odor Control – Oxidizes Sulfides
• Metals Co-Precipitation – As, Pb, Cr, Mn, Fe, Zn, Radionuclides
• Aquatic
A
i Species
S i C
Controll – Quagga
Q
and
d Zebra
Z b M
Mussels
l
• Ballast Water Treatment for bacteria and non-indigenous zooplankton
9
Fe70 Ferrator® Synthesis Schematic
Caustic
Tank
Bleach
Tank
Ferric
Tank
Heat
Exchanger
Reactor
Tank
Chiller
Cooling
Water
Heat
Exchanger
Storage and
Dosing Tank
Cooling
Water
Recirculating
Pump
Recirculating
Pump
Ferrate
Dosing Pump
Untreated
Water
Static
Mixer
Treated
Water
10
Ferrators For All Requirements
FERRATOR SYSTEM
DIMENSIONS in Feet or Meters
CAPACITY in MGD or Mega liters
Nano
(7 x 5 x 6) or (2.1 x 1.5 x 1.8)
2.5 or 9.5
Fe50
(14 x 6 x 8) or (4.2 x 1.8 x 2.4)
12 or 45.5
Fe70
(16 x 7 x 8) or (4.8 x 2.1 x 2.4)
12 or 45.5
Fe150
(18 X 8 X 8) or (5.5 x 2.4 x 2.4)
32 or 121
Fe300
(44 x 8 x 11) or (13.4 x 2.4 x 3.4)
60 or 226
Ferrate and Energy Efficiency
• A fraction of the energy use of other advanced
g , such as UV,, ozone,, or
treatment technologies,
reverse osmosis.
• Si
Since fferrate
t iis effective
ff ti att a llower ddose iin
removal of contaminants, a smaller volume of
solids is generated.
• Since the solids can be reused,, this minimizes
transportation and eliminates disposal costs.
12
Ferrate and Water Efficiency
• Enables the reuse of both domestic and industrial
wastewater.
• Improves the performance of reverse osmosis
t t
treatment
t systems,
t
andd reduces
d
or eliminates
li i t their
th i
concentrate waste.
• Enables the use of lower source water quality for
pp y development.
p
alternative water supply
13
Ferrate in the Energy Industry
• Power plants – source water treatment,
disinfection,, metals removal,, sulfide control
• Mining – metals removal, cyanide removal
• Oil & Gas – metals removal, disinfection, reuse of
produced waters
p
• Radionuclides – Dept. of Energy demonstration at
R k Fl
Rocky
Flats
t N
Nuclear
l F
Facility
ilit
14
Ferrate for Carbon Sequestration
• Ideal for wetland restoration
• NOLA Wastewater
W t
t to
t Wetlands
W tl d Project
P j t–
approximately 28,000 acres of freshwater
wetlands
tl d tto bbe restored
t d
• Tierra Resources has established Carbon Credits
for Restoration of these Wetlands
• C
Carbon
b Credits
C dit could
ld be
b a source off ffunding
di for
f
Everglades or other restoration efforts
15
New Orleans Wetlands Reclamation Project
East Bank plant flooded by Katrina
28,000 Acre Bienville Bayou, New Orleans
• Louisiana DEQ selected Ferrate as the ideal wastewater effluent oxidant for
wetlands restoration.
• Ferrate outperformed chlorine, ozone, and UV in a technology assessment.
• Ferrate’s treatment byproducts are not harmful to the environment.
• Ferrate Treatment deactivates residual drugs and hormones.
16
New Orleans Disinfectant Technology
Cost Comparison
Technology Cost Matrix for Plant Design at 200 MGD Peak Flow
Technology Choice:
Capital Costs
(Cost Per Gallon)
Operations and Maintenance
(Cost per 1,000 Gallons)
Ozone
1.224
0.064
UV
0.670
0.091
*Onsite Hypochlorite Generation
0.681
0.082
*Bulk Hypochlorite
0.318
0.083
Ferrate
0.318
0.062
*The chlorination costs include dechlorination.
Report Prepared by: Tulane University and consulting engineering firm
Waldemar S. Nelson and Company Inc. with technology cost comparisons.
17
Disinfectant Technology Comparison
Feasibility Study by a State Department of Environmental Quality and
Municipal Treatment Authority
STUDY REPORT - ASSESS DISINFECTION ALTERNATIVES AND EVALUATE
ENVIRONMENTAL AND ECONOMIC IMPACTS
Project Design Objectives
1.
2.
3.
4.
5.
6.
LOW COST!
Effective Disinfection prior to Wetlands Discharge
Prevent the formation of Disinfection By-products
Prevent Chlorinated Intermediates that later release Free Chlorine harmful to Aquatic Life
Inactivate microconstituent EDCs and PPCPs
Treat a wide range of influent flow conditions
Conclusions
1 State DEQ determined Ferrate is the ideal oxidant for wastewater effluent for wetlands
1.
restoration
2. Ferrate treatment beat chlorine, ozone and ultraviolet (UV) in a best technology assessment
3. Ferrate’s oxidative byproducts are not harmful to the environment or human health
4 The byproducts of Ferrate treatment are micronutrients that will accelerate plant growth
4.
within the created wetlands
18
Energy, Water - All Connected
Energy and Atmospheric Cycle
Water and Atmospheric Cycle
22
THANK YOU
Ferrate
F
t T
Treatment
t
t Technologies,
T h l i LLC
230 Sunport Lane, Suite 450
O l d FL 32809
Orlando,
Phone: (407) 857-5721
Email: [email protected]
Web: www.ferratetreatment.com
23

Ferrate Treatment Technologies - Environmental Technical Sales

Transcription

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