NID Modular and Multi-Pollutant Control DFGD Technology
Transcription
NID Modular and Multi-Pollutant Control DFGD Technology
NID™ Modular and Multi-Pollutant Control DFGD Technology – Fundamentals and Operational Experience Jürgen Dopatka, P.E. Manager Process Engineering - DFGD ([email protected] ph. +1 865-694-5342) ALSTOM Power - Steam Environmental Control Systems 1409 Centerpoint Boulevard Knoxville, TN 37932 USA Jiangtian Zhang Unit Technology Manager ([email protected] ph. +86 10 8460 9092) ALSTOM Technical Service (Shanghai) Co.,Ltd. Environmental Control Systems 3F, Qiankun Plaza, No.6 Sanlitun West 6 St. Chaoyang Dist. Beijing 100027 CHINA Presented at: POWER-GEN Asia 2013 Bangkok, Thailand October 2-4, 2013 Page 1 of 20 1. ABSTRACT The NID™ Dry Scrubber System is an advanced dry scrubber process that was developed by Alstom starting in the late 1980s, with commercial units in operation since 1996. The system allows for SO2 removal rates up to 98% while operating with high-sulphur fuels that would be beyond the capabilities of traditional SDA (Spray Dryer Absorber) dry scrubber systems. Continuous innovation and improvement of this dry scrubbing system has allowed it to be applied to the ever-tightening environmental emissions limits in many countries for pulverized coal-fired boilers. Its modular configuration practically sets no limits to the boiler size and allows for great turndown without the need for gas recirculation. Furthermore, the NID system with its integrated fabric filter not only removes SO2, but is very effective in removing other acid gases (SO3, HCl, HF), as well as mercury in the presence of activated carbon, and of course particulate matter (PM). While the majority of the installed NID capacity is on power applications with various fuels, its effective multi-pollutant removal makes it also a great choice for WtE (waste-to-energy) and iron and steel applications. This paper provides an overview of the NID system, highlights recent developments in the technology, and introduces several NID reference units as well as a few new projects currently in execution. Page 2 of 20 2. INTRODUCTION Alstom’s NID system is the integration of a semi-dry desulphurization and particulate removal system into a design characterized by its simplicity and compactness. The development of this system started in the late 1980s, with the first commercial units (2x120 MWe) going into operation in 1996 [1]. Since then, additional key developments have taken place, and a large number of units have been installed and are operating in broad applications including power, waste-to-energy and iron & steel industry applications. In power applications, units using coal, oil, oil-shale and pet coke have been built in excess of 12 GW. In the field of Waste-to-Energy, a variety of waste types are being fired in an installed base totaling over 4 million Nm3/h treated flue gas capacity. Industrial applications such as Iron & Steel have an installed base treating over 1 million Nm3/h of flue gas. This widespread application is largely due to its flexibility and adaptability, and this large experience base is available to further build on. One of the more recent developments is the application of the modular system into multi-modular units that can serve plants with practically no limits to boiler capacity (600-800 MWe and larger) while maintaining good turndown characteristics without the need for flue gas recirculation. Key evaluation criteria that are commonly applied for air pollution control equipment are shown in Table 1. The NID system excels in several of these criteria. Table 1. Evaluation Criteria for AQCS Equipment. 1. Environmental Compliance a. Removal efficiency requirements b. System reliability, availability, and maintainability 2. Cost and Schedule a. Initial capital expense and recurring operating expense b. Delivery and construction time 3. Footprint and General Layout a. Greenfield and retrofit b. Space requirements c. Layout flexibility Page 3 of 20 Key features and benefits of the NID system are summarized in Table 2. Table 2. Key Features and Benefits of the NID Technology. Multi-pollutant control: High efficiency removal of SO2, SO3, PM, HCl, and HF Lime-based semi-dry FGD technology Simple, compact design Modular design o SO2 removal: up to 98%; SO2 emissions 200 mg/Nm3 typical o SO3 emissions: < 1 ppm o PM (filterable): < 15 mg / Nm3 o Patented, integrated hydrator/mixer – no slurry handling o Zero liquid discharge – no waste water/treatment o Low water consumption; ability to use low quality water: CTB, WFGD purge o Small footprint offers retrofit advantage o Low capital cost o Low BOP/construction cost o Low O&M cost o High reliability o Good turndown o No scale-up issues Fuel flexibility of up to 2.5% sulphur coal or higher With the above mentioned key benefits of the NID, the most stringent regulations can be met with minimized cost and smallest footprint, while enabling reliable operation and allowing high fuel flexibility. 3. NID PROCESS AND PERFORMANCE 3.1 NID Process Chemistry The chemical reactions underlying the NID process are the same as for any semi-dry FGD process, such as, for example, in a traditional SDA. They are based on the absorption of SO2 by a dry absorbent containing quicklime (CaO) or hydrated lime, Ca(OH)2. Either of these absorbents may be used, or a fly ash containing an appropriate amount of alkali. The SO2 reacts to calcium Page 4 of 20 sulfite/sulfate solids, and similarly for the other acid gas components. The underlying reactions are shown below. Reagent • • Hydrated Lime - Ca(OH)2 Quick Lime - CaO • CaO + H2O Æ Ca(OH)2 + Heat • SO2(g) + Ca(OH)2 Æ CaSO3 • ½ H2O(s) + ½ H2O(g) • CaSO3 • ½ H2O(s) + ½ O2 + 1.5 H2O(g)Æ CaSO4 • 2 H2O(s) SO3(g) + Ca(OH)2 + H2O Æ CaSO4 • 2 H2O(s) 2 HCl(g) + Ca(OH)2 Æ CaCl2 • 2 H2O(s) 2 HF(g) + Ca(OH)2 Æ CaF2 + 2 H2O(s) Reactions • • • While the reactions make use of hydrated lime, the NID process through its patented, integrated NID Hydrator is able to use the less costly quick lime, which gets converted to hydrated lime just in time when it is demanded from the process. 3.2 Operating Principle of the NID Process Fly ash from the boiler or other gas source is filtered from the flue gas in a Dust Collector, preferably a Fabric Filter (FF), and the ash recycled back into the flue gas duct upstream the FF through the NID Mixer and NID Reactor (Figure 1). Quick lime (CaO) and water is added to the NID Hydrator that is attached to the NID Mixer, and produces hydrated lime (Ca(OH)2). The hydrated lime overflows Figure 1. NID System. into the NID Mixer, where recycle ash and water is continuously added. The moistened mix is dispersed into the NID reactor and cools the NID inlet flue gas temperature by evaporating the water added onto the dry ash particles. Page 5 of 20 The key parameter to be controlled in any dry FGD (DFGD) process is the humidity of the flue gas. In power applications, at a relative humidity of 40-50% the hydrated lime becomes highly activated and can effectively absorb SO2 [2]. The relative humidity of the flue gas is increased by the addition of water into the system. In a conventional spray dry absorption (SDA) process, water and lime is supplied to the flue gas as a slurry (with or without recycle) with a solids content of 35-50%. In the NID process, the same amount of water is added into the flue gas, through distribution onto the surface of dust particles at a water content of only a few percent. Thus, the amount of absorbent that is recycled is much greater than in an SDA process. This means that the surface available for the evaporation is very large. Thereby, the time for drying of the dust added to the flue gas is very short, which in turn makes it possible to use very small reactor vessels compared to conventional spray dryer technology. In fact, the volume is an order of magnitude smaller than the corresponding size for a spray drying system. The resulting increase of the relative humidity of the flue gas is sufficient to activate the lime for absorption of SO2 at typical DFGD operation temperatures of 15-25°C above saturation in power applications. The cooled flue gas then flows to the dust collector, where the particles in the flue gas are removed and recycled back through the NID process. Clean gases from the fabric filter are transported to a stack by means of induced draft (ID) fan. This process provides the appropriate conditions for the required SO2 removal efficiency. A FF hopper level controls the quantity of end products delivered to the end product handling system. The NID process is thus characterized by a very high recycle rate of dry solids, which in turn means that the utilization of the reagent is maximized. The moistened ash is still practically dry, and thus remains free flowing material even after humidification in the NID mixer. The amount of absorbent, which is recycled, is much greater than in a conventional SDA process. Further, the need for sophisticated special equipment is minimized in the NID process (e.g. no high speed machinery or high pressure nozzles), and all equipment that needs operator attention is placed near ground level. Finally, there is no slurry handling with requirements for special pumps etc., since water is added directly to the NID mixer. The high recycle rate also means that only dry material is handled in the system. The system is thus free from build-ups in gas ducts etc., since there is no wet slurry that can impinge on surfaces in the installation. Page 6 of 20 The FF is of high ratio type, and filtration is from the outside of the filter bags, inwards through a dust layer deposited on the surface of the bags and eventually through the felted fabric itself. Bags are cleaned by sending a pulse of compressed air backwards through the bags, which makes the dust fall off the bag into the hopper below. The bags are cleaned on-line to maintain the differential pressure drop over the FF within operating range. 3.3 NID Features and Components The key characteristics of the NID process, as shown in Table 3, make it a versatile and compact DFGD technology. Table 3. Key Characteristics of the NID Process. • Large gas flow range • Unitized compartment design • Compact footprint • Gas cooling by thin film evaporation • Very high solids recirculation • Fluid bed / dust recirculated continuously • No external hydrator • No external dust recycle • No slurry handling • Free flowing dry waste product • No intermediate hydrated lime storage Each NID module size has a wide range of gas flows that it can handle. Putting multiple unitized compartment modules together allows for a very compact footprint while covering a very large range of plant capacity while keeping the system simple without complex pieces of equipment. Page 7 of 20 Each NID module (Figure 2) is independently isolatable, which allows for good turn-down and load-following capabilities without the need for flue gas recirculation. Modules are isolated by dampers upstream of the reactor, and downstream of each FF compartment. Each module, depending on module size, has a nominal gas flow capacity corresponding to 15 – 70 MWel. The system can be designed to achieve emission guarantees at full load with one module out of service. This allows for online maintenance, such as for example replacement of bags. Figure 2. NID System Module. Key components that define the NID system are: • NID Reactor • NID Hydrator • NID Mixer • Fluid Trough • Recycle Feeder • Fabric Filter Page 8 of 20 NID Reactor The NID reactor (Figure 3), in the shape of a J, provides an excellent interface between the flue gas and the humidified recycle dust for SO2 collection, while providing good turndown per module. Each reactor has its dedicated mixer and hydrator. Neither high pressure nor high speed equipment are used. Dust is being recycled continuously by means of the fluidized troughs and recycle Figure 3. NID Reactor. feeders, in order to provide the required flue gas humidity as well as lime reagent for effective acid gas removal. The dust moistening is managed by a constant water-to-recycle ratio controller. The recycle dust and the waste product (calcium sulfite/sulfate) are dry and thus easy to handle. NID Mixer and NID Hydrator The mixer and hydrator are of Alstom’s Rotary Rotary Feeder Feeder proprietary design. The mixer is designed to work in concert with the NID reactor and is bolted onto the reactor walls (Figure 4). Thus wetted ash has a very short distance to be transported before it is dispersed into the flue FDA NID Reactor Reactor Lime Hydrator FDANIDMixe r gas. The recycled ash flows into the mixer through a recycle feeder of rotary valve type, Lime Distributo r Lime Hydrator Figure 4. NID Equipment Arrangement. placed above the mixer. The recycle feeder has the same width as the mixer to achieve an even flow of recycle ash over the entire cross section of the mixer and hence an even distribution into the reactor. Nozzles are used to spray Page 9 of 20 water onto the recycle ash to moisten its surface. The mixer has two shafts with mixing elements that are arranged parallel to the reactor wall. This arrangement, which is based on a rectangular geometry of the reactor and its mixer, is a key feature that allows for easy scale up and standardization of the equipment. Based on this concept a series of standard size reactor, mixer and hydrator modules have been developed (Figure 5). Figure 5. NID Mixer/Hydrator. The cost of dry hydrated lime is higher than that for quick lime, when compared on a molar basis. Moreover, the bulk density of the two reagents are very different; lime is typically 900 to 1200 kg/m3, whereas dry hydrated lime is only 450 to 640 kg/m3. These factors make quick lime the preferred material from a transportation as well as silo storage capacity point of view. To overcome the shortcomings of conventional lime hydrators, the NID Integrated Lime Hydrator Mixer was developed. Lime and water are fed into the hydrator, which comprises two stages; in the first stage water and lime are mixed together and the wetted lime overflows into the second stage. There, the somewhat lumpy material from the first stage literally disintegrates into a very fine powdery material: (dry) hydrated lime. The feed of lime is controlled on an “as needed” basis; i. e. the feeds of lime and water into the hydrator are controlled to match the quantity requested by the NID control system in order to maintain SO2 emissions. Advantages: • No intermediate silo for hydrated lime • No separate silo air filter - venting through NID FF • No transport of hydrated lime - direct overflow into the NID Mixer Page 10 of 20 Fluidizing Trough and Recycle Feeder The fluidizing trough located below the FF hoppers and leading immediately to the NID reactor and by-product removal is a very simple but highly effective means to move the large amounts of solids within the NID system in a reliable manner. The trough (Figure 6) is furnished with a fluidizing cloth that is continuously provided with the required amount of air in order to keep the solids Figure 6. Internal View of Fluidizing Trough. fluidized and moving as required. The trough at the same time acts as the intermediate storage for inventory control. Excess amounts of solids that need to be removed due to the continuous production of by-product and collection of fly ash are removed through the by-product removal (Figure 7) located upstream of the recycle feeder. All remaining materials get recycled back into the NID reactor by means of Figure 7. Byproduct Removal. the Recycle Feeder. High Ratio Fabric Filter (Pulse Jet FF) The FF is associated with each reactor module into an integrated NID module. Each FF compartment/module (Figure 8) consists of several sequentially arranged bag nests. The FF compartment is characterized by • High ratio (high air-to-cloth ratio) • Collects ash particles from the flue gas stream – outside to inside filtration • Fabric and dust layers act as filter – on-line cleaning by means of air pulse • < 10% Opacity • < 15 mg / Nm3 emissions • Bag diameter ~ 0.13m, bag length up to 10 m, bag Page 11 of 20 Figure 8. Fabric Filter Compartments. material: needle felt • Pressure Loss: 1–2 kPa (4–8 in.H2O) • Bag Life: 2–4 years depending on operating conditions Additionally, the dust cake provides a means for second stage reactions, removing additional acid gases (SO2, SO3, HCl, HF) (Figure 9) as well as mercury (Hg) and other trace elements while passing through the cake layer and filter, and removing fly ash and activated carbon (if used) for recycle. Figure 9. Second Stage SO2 Removal across Filter Cake. 4. ALSTOM NID BENEFITS 4.1 Technology Comparison and Evaluation Traditionally, there have been two technology options for desulphurization: Wet FGD and Dry FGD. • WFGD is using limestone as reagent that is being recycled in a spray tower. The byproduct is gypsum which is sold or landfilled, based on market conditions. • DFGD (NID or SDA) is employing quick lime or hydrated lime as the reagent, with the lime being injected into the flue gas stream. The byproduct is a mixture of calcium sulfite and calcium sulfate, which can be used for mine or road fill or soil nutrition, and often is being landfilled. Page 12 of 20 Table 4. FGD Technology Evaluation Criteria. WFGD SDA/FF NID/FF Remedy existing PM emission issue 3 1 1 CO2 capture ready 1 3 2 Load following capability 1 1 1 Byproduct Flexibility 1 3 3 Footprint 2 2 1 Water Consumption 3 1 1 Fuel Flexibility 1 2 2 Reuse existing stack or No GGH 3 1 1 O&M staffing requirements 3 2 1 Project Lead Time 3 1 1 HAPS Capture 2 2 2 1 – Best Score: Product Most Suited 2 – Medium Score: Product Suited 3 – Worst Score: Product Least Suited When evaluated against WFGD and SDA technology, NID technology ends up with the best overall score (Table 4). The individual score for each plant site may vary, depending on the relevance and importance of each criteria for a particular project. The DFGD technologies can remedy existing particulate matter emission issues, while excelling with respect to water consumption, reuse of existing stack, and project lead time. DFGD also doesn’t produce any waste water that needs to be treated and discharged. The NID technology has by far the smallest footprint, which makes it a particularly suitable candidate for retrofit situations where space is very limited. Additionally, due to its simplicity, the NID technology has the lowest O&M requirements. Due to their simplicity and use of less costly materials, the capital investment required for DFGD systems is lower than WFGD systems. In the past, SDA-based DFGD systems were limited to 1.0-1.5% sulphur fuels, thus making the more capital intensive WFGD the only choice for medium and high sulphur fuels. With the introduction of NID, low cost DFGD systems can now Page 13 of 20 be used for medium and high sulphur fuels as well. From an operating cost standpoint, WFGD systems benefit from the use of low cost limestone reagent especially when high sulfur fuels are used. When considering overall lifecycle cost (i.e. capital and operating cost), experience has showed that NID can still be the best economic solution even in medium/high sulphur applications due to the low capital cost. However, a detailed site-specific analysis must be performed to confirm the optimal solution. 4.2 NID Modularization and Design Flexibility The modular feature of the NID system allows for highly flexible arrangements that can suit the restrictive conditions of almost any existing site. Figure 10 shows several examples of how the modules can be arranged into a system. Figure 10. NID Module Arrangement Flexibility. Page 14 of 20 Individual design features as well as customer preferences could result in further variations of the design possibilities. Fabric filters can be designed with top doors to access the bag nests, or alternately with walk-in plenums. Figure 11 shows an arrangement using a top door design with a total of six modules arranged in a symmetrical configuration, all based on the same single module design. Figure 11. Symmetrical NID arrangement with six NID modules. Furthermore, the modularization allows shop fabrication of a number of key components at significantly lower cost than field fabrication. A high degree of shop fabrication (Figure 12) with subsequent truck shipment is possible for the • NID reactors • Inlet ducts • Day Silos for quick lime • Mixers/Hydrators Figure 12. Shop-fabricated reactor section, mixer/hydrator, and lime day silo. If access to shipping by barge is available, further pre-assembly is possible for Fabric Filter compartments as well as Inlet and Outlet plenums. Page 15 of 20 4.3 Summary of NID Benefits Compared to WFGD technology, NID has the following key advantages: • Lower capital expense and lower lifecycle costs for medium-sized, medium-sulphur applications • Multi-pollutant control including PM, SO3 (as well as HCl, and HF) • No waste water requiring treatment • Smaller footprint, better constructability • Ability to reuse existing stack when retrofitting AQCS • Shorter project execution schedule (no items with long lead times, such as ball mill, new stack, etc.) 5. ALSTOM NID EXPERIENCE AND PROJECT PROFILES Alstom’s experience base in DFGD projects encompasses over 130 DFGD units (SDA+NID) totaling over 28 GW, of which 19 units are larger than 450 MW totaling 12 GW. The NID system has been in operation for over 15 years, with the first commercial units going into service in 1996. While a large number of the earlier NID power installations are serving smaller to medium size units (25 … 300 MWe), more recent units have been designed, constructed or operated for boiler capacities ranging up to 400 – 700 MWe. The introduction of NID into higher capacity ranges occurred for a number of reasons, including • Compact, low cost multi-pollutant control • Experience gained in reliably achieving high (up to 98%) SO2 removal efficiencies while using lime stoichiometry that challenge WFGD economics, even when firing fuels with medium/high sulphur contents. • Integration of inlet and outlet plenum as part of the overall NID structure for more compact and lower cost construction. • Leveraging of modularized fabrication and construction. Additionally, the large variety of applications where NID has been applied demonstrates the adaptability of this technology: Page 16 of 20 Fuels/Applications: bituminous, oil shale without lime injection, CFB boilers with limestone injection (without lime addition in NID), heavy fuel oil, Orimulsion, waste fuel, waste-to-energy plants, sintering plants in the iron & steel industry, ESP as dust collector, ESP casing retrofitted to FF, and more. The following is a selection of a few projects that reflect the recent more demanding applications on larger power plants. The Indian River Unit 4 was the first 8-compartment NID system that Alstom delivered [3]. Changes in load of the PC boiler require addition and subtraction of compartments/modules to maintain performance. The resulting control logic challenges required automatic sequences for adding a compartment and to remove a compartment from service. It also required the automatic gas flow balancing of multiple parallel gas paths in order to avoid overload or underload situations on any single module that is in service. Due to an extremely tight site, the placement of the lime day silos had to be compromised. As a result, the lime distribution systems consist of multiple screw conveyors. Most recent designs consider a larger number of smaller lime silos closely located to their respective NID hydrators for shortest conveying distance and quick response. The design of the integrated Fabric Filter was optimized by reviewing the gas and dust distribution within compartments by means of CFD and physical modeling. A view of the Indian River Unit 4 NID installation after completion with one of the two lime silos serving four NID modules in the Figure 13. Indian River Unit 4 NID System. foreground is shown in Figure 13. Four of the eight rectangular NID reactors are shown along the right side of the building, with the FF compartment penthouse being the roof of the structure. Table 5 summarizes key design and performance data of that installation. Page 17 of 20 Table 5. Key Design & Performance Characteristics of Recent Large Power NID Systems. NRG - Indian River Unit 4, USA End-User/Project: Application Unit Size. MWe Fuel Inlet SO2, mg/Nm3 Gas Flow, m3/h Commercial operation Reagent Byproduct NID Modules NTP to PAC EMISSIONS SO2 Removal SO2 Emissions, mg/Nm3 SO3/H2SO4, ppmv HCl / HF, mg/Nm3 Hg, µg/Nm3 Particulates (filterable), mg/Nm3 Opacity PC Boiler 436 (net) Bituminous coal 6800 3900000 Dominion Energy Brayton Point Unit 3, USA PC Boiler 660 Bituminous coal 3800 4100000 EME - Homer City Units 1 & 2, USA Minnesota Power Boswell Unit 4, USA FW PC Boiler 670 (gross) East. Bituminous coal 4950 4453600 PC Boiler 652 (gross) Sub-Bituminous-PRB 1780 3947000 Dec. 2011 Q1 2013 Q4 2014 Q1 2016 Pebble Lime Landfill (7+1) x 4m 26 months Actual 96% at design inlet sulphur Pebble Lime Landfill (7+1) x 4m 35 months Actual Crushed Lime Landfill (9+1) x 4m 34 months Design/Guarantees Crushed Lime Landfill (8+1) x 4m 42 months Design/Guarantees ≥ 98% ≥ 98% ≥ 98.1% ≤ 170 <1 ≤ 1.6 / ≤ 0.9 ≤ 175 ≤ 0.7 << 1 no guarantee, but well below current standards ≤ 1.6 << 15 << 8% ≤ 4.5 / - < 1 (dry) ≤ 2.2 / ≤ 1.1 ≤ 2.2 ≤ 1.3 << 10 ≤ 22 ≤ 26 - - - The Brayton Point Unit 3 NID system benefited from lessons learned at Indian River. A 3D model view of this 8-compartment NID system with four NID modules on each side is shown in Figure 14, and an aerial view near completion in Figure 15 [4]. The integrated inlet and outlet plenum ductwork can be seen in the center bottom and top of the front side. This design has the inlet and outlet interfacing on the same side of the structure, but a design with interfaces on opposing sides is equally possible, depending on site Page 18 of 20 Figure 14. Brayton Point Unit 3 NID System 3D Model View. requirements. The lime day silos are integrated between individual reactor modules for close coupling. Flue gas enters into individual modules perpendicular to the inlet plenum underneath each FF compartment to the NID reactor, from where is enters the FF module and then back to the outlet plenum. Key design and performance parameters are summarized in Table 5. The Homer City Units 1&2 NID system (Figure 16) consists of two units, each with a 10-module symmetrical Figure 15. Brayton Point Unit 3 NID System close to completion. arrangement design. Its design approach follows closely that of Brayton Point. Key design and performance characteristics are summarized in Table 5. The system is under construction, and is scheduled to go into service in late 2014. The NID system currently under design and construction for Minnesota Power’s Boswell Unit 4 station is shown as 3D model view in Figure 17. It shows another unique feature of the NID Figure 16. Homer City Units 1 & 2 NID Systems 3D Model Views. design feasibilities – a 9-module in-line (as opposed to symmetrical) design out of necessity of a very tight site that only offered a narrow plot plan. Its design and performance characteristics are summarized in Table 5. Figure 17. Boswell, Unit 4, NID System 3D Model. Page 19 of 20 6. REFERENCES 1. Åhman, S., C.B. Barranger, and P.G. Maurin, Alstom Power’s Flash Dry Absorber for Flue Gas Desulfurization. Proceedings of IJPGC’02, Phoenix, AZ, 2002. 2. Åhman, S, J. Buschmann, NID – A New Flue Gas Desulfurization System. Proceedings MEGA Symposium, Washington, DC, 1997. 3. Fiedler, M., G. Hopper, Start-Up and Operating Experience: NRG Indian River NID DFGD System. Proceedings DSUA Conference, Providence, RI, 2012. 4. Reynolds, T., B.E. Teixeira, Start-up and Operating Experience with Alstom’s NID DFGD Technology at Brayton Point. To be presented at DSUA Conference, Denver, CO, 2013. Page 20 of 20