SAFETY DATA SHEET Product Name: EPOXY GLUE, PART A
Transcription
SAFETY DATA SHEET Product Name: EPOXY GLUE, PART A
1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com Print Date 07/27/2015 Safety Data Sheet SDS Number: 133A Revision Date:07/24/2015 Page 1/20 Supersedes Date: 07/16/2012 acc. to OSHA HCS SAFETY DATA SHEET · Product Identifier Complies withBLACK OSHA Hazard Communication · Trade Name: EP11HT A · Application of the Substance or Mixture: Epoxy Resin Revision Date 07/27/2015 Standard 29 CFR 1910.1200 · Details of the Supplier of the Safety Data Sheet Product Name: EPOXY GLUE, PART A (SDS) · Manufacturer or Supplier: Resinlab, LLC N109 W13300 Ellsworth Drive, SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Germantown, WI 53022 1-800-388-8605 www.resinlab.com Product· Information Type: Adhesive Product Safety Department: [email protected] Department: Product· Emergency Name: Telephone Epoxy Glue, PART A (RESIN) Phone: Number: North America Chemtrec: 1-800-424-9300 (24 hours) Part Number(s): 10-347 Part A International - Chemtrec: 01-703-527-3887 (24 hours) Contact: Chemtrec (800) 424-9300 * 2 Hazard(s) identification SECTION 2. HAZARD(S) IDENTIFICATION · Hazard Classification GHS08 Resp. Sens. 1 Muta. 2 Carc. 2 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. GHS09 Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 Eye Irrit. 2A Skin Sens. 1 H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. · Label Elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Pictogram(s) GHS08, GHS09 · Signal Word Danger · Hazard-determining Component(s) Bisphenol-A-(epichlorohydrin) epoxy resin Butylglycidylether · Hazard statements Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing genetic defects. Suspected of causing cancer. Toxic to aquatic life with long lasting effects. · Precautionary statements Part Number(s): Part A Wear10-347 respiratory protection. Avoid breathing dust/fume/gas/mist/vapors/spray Wear protective gloves. Page 1 of 46 GHS09 Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. Morgan Skin Sens. 1Street H317 May cause an allergic skin reaction. 1801 SDS Number: 133A Rockford, 61102 Revision Date:07/24/2015 · LabelIL Elements Phone: · GHS (815) 968-9661 Supersedes Date: 07/16/2012 label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Pictogram(s) GHS08, GHS09 Fax: (815) 968-9731 · Signal Word Danger www.gcelectronics.com · Hazard-determining Component(s) Bisphenol-A-(epichlorohydrin) epoxy resin Butylglycidylether · Hazard Complies with OSHA Hazard Communication Standard statements Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing genetic defects. Suspected of causing cancer. to aquatic life with long lasting effects. 2.Toxic HAZARD(S) IDENTIFICATION SAFETY DATA SHEET 29 CFR 1910.1200 Product Name: EPOXY GLUE, PART A SECTION Safety Data Sheet Page 2/20 acc. to OSHA HCS · Precautionary statements Print Date 07/27/2015 Revision Date 07/27/2015 Wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapors/spray Trade Name: EP11HT BLACK A Wear protective gloves. Wear eye protection / face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. (Contd. of page 1) (Contd. on page 2) Specific treatment (see on this label). US If experiencing respiratory symptoms: Call a poison center/doctor. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. · Hazard Rating System · NFPA System · NFPA Ratings (scale 1 2 0 - 4) Health = 2 Fire = 1 Reactivity = 0 0 NFPA special hazards (water reactivity and oxidizing property): None · HMIS System · HMIS Ratings HEALTH *2 FIRE 1 REACTIVITY 0 (scale 0 - 4) Health = *2 Fire = 1 Reactivity = 0 · Other hazards · Results of PBT and vPvB · PBT: Not applicable. · vPvB: Not applicable. * assessment 3 Composition/information on ingredients · Chemical Characterization: Mixtures on Ingredients · Composition/Information CAS: 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin NLP: 500-033-5 Aquatic Chronic 2, H411 Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Skin Sens. 1, H317 Index Number: 603-074-00-8 CAS: 1317-65-3 Calcium Carbonate EINECS: 215-279-6 RTECS: EV 9580000 CAS: 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica EC number: 614-122-2 CAS: 2426-08-6 Butylglycidylether EINECS: 219-376-4 Flam. Liq. 3, H226 Part Number(s): 10-347 Part A Index Number: 603-039-00-7 Resp. Sens. 1, H334; Muta. 2, H341; Carc. 2, H351 RTECS: TX 4200000 Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Eye Irrit. 2A, H319; Skin Sens. 1, H317 70-80% 10-20% 2.5-5% 2.5-5% Page 2 of 46 Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. · Hazard Rating System · NFPA System · NFPA Ratings (scale 2 1 0 0 - 4) Health = 2 Fire = 1 Reactivity = 0 NFPA special hazards (water reactivity and oxidizing property): 1801 Morgan Street · HMIS System Rockford, IL 61102 · HMIS Ratings (scale 0 - 4) Phone: (815) 968-9661 *2 HEALTH Fax: (815) 968-9731 Health = *2 1 Fire = 1 FIRE www.gcelectronics.comReactivity = 0 REACTIVITY 0 SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 None SAFETY DATA SHEET · Other hazards Complies withvPvB OSHA Hazard Communication · Results of PBT and assessment · PBT: Not applicable. · vPvB: Not applicable. Standard 29 CFR 1910.1200 Product Name: EPOXY GLUE, PART A * 3 Composition/information on ingredients SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS · Chemical Characterization: Mixtures on Ingredients · Composition/Information CAS: 25068-38-6 NLP: 500-033-5 Index Number: 603-074-00-8 CAS: 1317-65-3 EINECS: 215-279-6 RTECS: EV 9580000 CAS: 67762-90-7 EC number: 614-122-2 CAS: 2426-08-6 EINECS: 219-376-4 Index Number: 603-039-00-7 RTECS: TX 4200000 Bisphenol-A-(epichlorohydrin) epoxy resin Aquatic Chronic 2, H411 Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Skin Sens. 1, H317 Calcium Carbonate 70-80% Siloxanes and Silicones, di-Me, reaction products with silica 2.5-5% 10-20% 2.5-5% Butylglycidylether Flam. Liq. 3, H226 Resp. Sens. 1, H334; Muta. 2, H341; Carc. 2, H351 Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4, H332; Eye Irrit. 2A, H319; Skin Sens. 1, H317 Aquatic Chronic 3, H412 Carbon black 1-2.5% Page 3/20 CAS: 1333-86-4 EINECS: 215-609-9 RTECS: FF5800000 CAS: 71-36-3 1-Butyl alcohol acc. to OSHA HCS EINECS: 200-751-6 Flam. Liq. 3, H226 Print Index Date 07/27/2015 Eye Dam. 1, H318 Number: 603-004-00-6 Acute Tox. 4, H302; Skin Irrit. 2, H315; STOT SE 3, H335-H336 RTECS: EO 1400000 Trade Name: EP11HT BLACK Quartz A CAS: 14808-60-7 EINECS: 238-878-4 Carc. 2, H351 RTECS: VV 7330000 Safety Data Sheet 0-<0.1% Revision Date 07/27/2015 0-<0.1% (Contd. of page 2) (Contd. on page 3) · Classification System: US The Classifications were based on the Toxicological and Ecological Data of the substances/mixtures in the Section 11 and 12. * 4 First-aid measures · Description of First Aid Measures · General Information Ensure medical personnel are aware of exposure and take precautions for their personal protection; see Section 8 for the information of personal protection. · After Inhalation Remove victim from exposure to fresh air. Keep person at rest. Provide oxygen if person is not breathing. Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. If breathing is difficult, administer oxygen. Seek immediate medical advice. · After Skin Contact Remove all contaminated clothing and wash before reuse. Wash contaminated skin with water and soap and rinse thoroughly. Seek immediate medical advice. · After Eye Contact Immediately rinse opened eyes for at least 15 minutes under running water. Immediately remove contact lenses if present. Continue rinsing. Part Number(s): 10-347 Part A Do not put any ointments, oils or medication in eyes without specific instructions. IMMEDIATELY transport victim to a hospital even if no symptoms develop. Page 3 of 46 1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com Print Date 07/27/2015 Trade Name: EP11HT BLACK A Safety Data Sheet SDS Number: 133A Revision Date:07/24/2015 Page 3/20 Supersedes Date: 07/16/2012 acc. to OSHA HCS Revision Date 07/27/2015 SAFETY DATA SHEET Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 (Contd. of page 2) · Classification System: The Classifications were based on the Toxicological and Ecological Data of the substances/mixtures in the Section 11 and 12. Product Name: EPOXY GLUE, PART A * 4 First-aid measures SECTION 4. FIRST-AID MEASURES · Description of First Aid Measures · General Information Ensure medical personnel are aware of exposure and take precautions for their personal protection; see Section 8 for the information of personal protection. · After Inhalation Remove victim from exposure to fresh air. Keep person at rest. Provide oxygen if person is not breathing. Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. If breathing is difficult, administer oxygen. Seek immediate medical advice. · After Skin Contact Remove all contaminated clothing and wash before reuse. Wash contaminated skin with water and soap and rinse thoroughly. Seek immediate medical advice. · After Eye Contact Immediately rinse opened eyes for at least 15 minutes under running water. Immediately remove contact lenses if present. Continue rinsing. Do not put any ointments, oils or medication in eyes without specific instructions. IMMEDIATELY transport victim to a hospital even if no symptoms develop. · After Swallowing If victim is unconscious; never give anything by mouth. If victim is conscious; rinse out mouth and give victim small amounts of water. Seek medical treatment in case of complaints. · After Exposure Get medical advice/attention at once. · Information for Doctor Have chemical containers, labels and/or (M)SDS ready when calling or visiting a medical center. · Indication of any Immediate Medical Attention and Special Treatment Needed After frequent or high intense exposure, the following medical tests are recommended: respiratory system tests Skin, Eye, and Reproductive system · Additional Information For additional information, please consult the corresponding first aid measures in the most current version of Emergency Response Guidebook which is produced by the US Department of Transportation. * 5 Fire-fighting measures · Extinguishing Media · Suitable Extinguishing Agent(s) Use fire fighting measures and extinguishing agents that suit the environment. In case of fire, suitable extinguishing agents are: Alcohol resistant foam. Dry chemical or fire-extinguishing powder. Carbon dioxide (CO₂). Water spray or water fog. · Unsuitable Extinguishing Agent(s) Water with full jet · Firefighting Procedures Isolate fire and deny unnecessary entry. Part Number(s): 10-347 Part A Immediately withdraw all personnel from the area in case of rising sound from venting safety device. Eliminate all ignition sources if safe to do so. Page 4 of 46 · After Skin Contact Remove all contaminated clothing and wash before reuse. Wash contaminated skin with water and soap and rinse thoroughly. Seek immediate medical advice. · After Eye Contact Immediately rinse opened eyes for at least 15 minutes under running water. Immediately remove contact lenses if present. Continue rinsing. Do not put any ointments, oils or medication in eyes without specific instructions. IMMEDIATELY transport victim to a hospital even if no symptoms develop. After Swallowing 1801 Morgan Street SDS Number: 133A If victim is unconscious; never give anything by mouth. If victim is conscious; rinse out mouth and give victim small amounts of water. Rockford, IL 61102 Revision Date:07/24/2015 Seek medical treatment in case of complaints. Phone: (815) 968-9661 Supersedes Date: 07/16/2012 · After Exposure Get medical advice/attention at once. Fax: (815) 968-9731 · Information for Doctor Have chemical containers, labels and/or (M)SDS ready when calling or visiting a medical center. www.gcelectronics.com · · Indication of any Immediate Medical Attention and Special Treatment Needed After frequent or high intense exposure, the following medical tests are recommended: respiratory system tests Skin, Eye, and Reproductive system SAFETY DATA SHEET Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 · Additional Information For additional information, please consult the corresponding first aid measures in the most current version of Emergency Response Guidebook which is produced by the US Department of Transportation. Product Name: EPOXY GLUE, PART A * 5 Fire-fighting measures SECTION 5. FIRE-FIGHTING MEASURES · Extinguishing Media · Suitable Extinguishing Agent(s) Use fire fighting measures and extinguishing agents that suit the environment. In case of fire, suitable extinguishing agents are: Alcohol resistant foam. Dry chemical or fire-extinguishing powder. Carbon dioxide (CO₂). Water spray or water fog. · Unsuitable Extinguishing Agent(s) Water acc. HCS withto fullOSHA jet Print· Firefighting Date 07/27/2015Procedures Page 4/20 Safety Data Sheet Isolate fire and deny unnecessary entry. Trade Name: EP11HT BLACK A Immediately withdraw all personnel from the area in case of rising sound from venting safety device. Eliminate all ignition sources if safe to do so. Do not extinguish fire unless flow can be stopped. Fight fire remotely due to the risk of explosion. Burning liquids may be moved by flushing with water; protect personnel and minimize property damage. Contain fire water runoff if possible to prevent environmental pollution. Revision Date 07/27/2015 (Contd. of page 3) (Contd. on page 4) US · Special Hazards Arising in Fire Will not burn unless preheated. In case of fire, following can be released: Phenolic compounds Formaldehyde, a skin and lung sensitizer and a regulated carcinogen, may be formed during fires. Carbon dioxide (CO₂) and Carbon monoxide (CO) Calcium oxide (CaO) Silicon oxide (SiO₂) · Advice for Firefighters If employees are expected to fight fires, they must be trained and equipped as stated in the OSHA fire brigades standard (29 CFR 1910.156). As with any fire, wear positive-pressure self-contained breathing apparatus and full protective gear that are NIOSH approved. · Additional * Information Be Caution! Finely dispersed substance may form explosive mixtures in air. 6 Accidental release RELEASE measuresMEASURES SECTION 6. ACCIDENTAL · Personal Precautions Do not breathe gas, vapors, dusts or mists if their inhalable particles occur during use. Ensure personnel take precautions for their personal protection during clean up; see Section 8 for the specific requirements. · Environmental Precautions Keep away from sewage system or other water courses; do not penetrate ground/soil. Inform respective authorities in case of any seepage to the environment. · Cleaning Up Methods Ensure adequate ventilation. Eliminate all ignition sources. Keep unauthorized personnel away. Allow molten product to cool. Absorb residues with liquid-binding materials. Avoid confined spaces, such as sewers, because of the possibility of an explosion. Ventilate and wash area after clean-up is complete. Part Number(s): Collect spills 10-347 in suitablePart and A properly labeled containers. Do not use solvents unless following safe handling practices and within the recommended exposure guidelines. Dispose contaminated chemicals as waste according to Section 13. Page 5 of 46 In case of fire, following can be released: Will not burn unless preheated. Phenolic compounds In case of fire, following can be sensitizer released: and a regulated carcinogen, may be formed during fires. Formaldehyde, a skin and lung Phenolic compounds Carbon dioxide (CO₂) and Carbon monoxide (CO) Formaldehyde, a skin and lung sensitizer and a regulated carcinogen, may be formed during fires. Calcium oxide (CaO) ) and Carbon monoxide (CO) Carbon dioxide (CO Silicon oxide (SiO ₂) ₂ Calcium oxide (CaO) · Silicon oxide ₂) Advice for(SiO Firefighters employees are expected to fight fires, they must be trained and equipped as stated in the OSHA fire brigades standard (29 CFR · If Advice 1910.156).for Firefighters If are expected to fight fires, they must breathing be trainedapparatus and equipped stated ingear the that OSHA brigades standard (29 CFR Asemployees with any fire, wear positive-pressure self-contained and fullasprotective are fire NIOSH approved. 1910.156). As with any fire, wear positive-pressure self-contained breathing apparatus protective gear that are NIOSH approved. Information Be Caution! Finely dispersed substance mayand formfull explosive mixtures in air. 1801· Additional Morgan Street SDS Number: 133A · Additional Information Be Caution! Finely dispersed substance may form explosive mixtures in air. Revision Date:07/24/2015 Rockford, IL 61102 * Phone: (815) 968-9661 Supersedes Date: 07/16/2012 6 Accidental release measures * Fax: (815) 968-9731 6· Personal Accidental release measures Precautions www.gcelectronics.com Do not breathe gas, vapors, dusts or mists if their inhalable particles occur during use. · Personal Precautions Ensure personnel take precautions for their personal protection during clean up; see Section 8 for the specific requirements. Do not breathe gas, vapors, dusts or mists if their inhalable particles occur during use. · Environmental Ensure personnel take precautions for their personal protection during clean up; see Section 8 for the specific requirements. Precautions Keep away from sewage system or other water courses; do not penetrate ground/soil. Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 · Environmental Precautions Inform respective authorities in case of any seepage to the environment. Keep away from sewage system or other water courses; do not penetrate ground/soil. · Cleaning Inform respective authorities in case of any seepage to the environment. Up Methods adequate ventilation. · Ensure Cleaning Methods Eliminate all Up ignition sources. Ensure adequate ventilation. Keep unauthorized personnel away. Eliminate all ignition Allow molten productsources. to cool. Keep unauthorized personnel away. SECTION 6.residues ACCIDENTAL RELEASE Absorb with liquid-binding materials. MEASURES (CONTINUED) Allow product to such cool. as sewers, because of the possibility of an explosion. Avoid molten confined spaces, Absorb with liquid-binding materials. Ventilateresidues and wash area after clean-up is complete. Avoid as sewers, because of the possibility of an explosion. Collectconfined spills in spaces, suitable such and properly labeled containers. Ventilate and wash area after clean-up is complete. Do not use solvents unless following safe handling practices and within the recommended exposure guidelines. Collect in suitablechemicals and properly labeled containers. Disposespills contaminated as waste according to Section 13. Do not use solvents unless following safe handling practices and within the recommended exposure guidelines. Dispose contaminated chemicals as waste according to Section 13. SAFETY DATA SHEET Product Name: EPOXY GLUE, PART A * * 7 Handling and storage SECTION 7. HANDLING AND STORAGE 7· Handling Handling and storage · Precautions for Safe Handling · Handling special instruction before use; do not handle until all safety precautions have been read and understood. · Obtain Precautions forvapors, Safe Handling Do not breathe gas, dusts or mists if their inhalable particles occur during handling. Obtain special use; or docontents not handle until wearing all safetyappropriate precautionspersonal have been read and understood. Avoid any bodyinstruction contact ofbefore containers unless protective equipment. Do not breathe gas, vapors, dustshandling. or mists if their inhalable particles occur during handling. Wear respiratory protection when Avoid away any body of containers or contents unless wearing appropriate personal protective equipment. Keep fromcontact incompatible material(s). Wear respiratory protection when handling. Avoid any release into the environment. Keep away incompatible material(s). Observe all from the personal protection requirements in Section 8. any release into the environment. · Avoid Information about Protection AgainstinExplosions and Fires Observe all the personal protection requirements Section 8. Page 5/20 Will not burn unless preheated. · Information about Protection Against Explosions and Fires Keep away from heat, sparks, open flame and other ignition sources during handling. Will unlesswith preheated. Dustnot canburn combine air to form an explosive mixture. to OSHA HCS Keep away from heat, sparks, open flame andacc. other ignition sources during handling. · Dust can combine with air to form an explosive mixture. Print DateStorage 07/27/2015 Revision Date 07/27/2015 · Requirements to be Met by Storerooms and Receptacles · Storage in a well-ventilated Trade Name: EP11HT BLACK A place; provide ventilation for receptacles. · Store Requirements to be Met by Storerooms and Keep stored in accordance with local, regional, national, andReceptacles international regulations. Store in a well-ventilated place; provide ventilation for receptacles. (Contd. on page 5) Keep stored in accordance with local, regional, national, and international regulations. (Contd. of page 4) US (Contd. on page 5) · Information about Storage in One Common Storage Facility US Store away from incompatible material(s). Store away from foodstuffs. Avoid release to the environment. Safety Data Sheet · Additional * Information No further relevant information. 8 Exposure controls/personal protection · Engineering · Exposure Measures or Controls Limit Values that Require Monitoring at the Workplace 1317-65-3 Calcium Carbonate TEEL Short-term value: 15.0 mg/m³ Long-term value: 60.0 mg/m³ SCAPA, 2008 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica OSHA PEL Short-term value: 15 mg/m³ US ACGIH Short-term value: 10 mg/m³ 2426-08-6 Butylglycidylether PEL Long-term value: 270 mg/m³, 50 ppm PartREL Number(s): 10-347 Part30 A Ceiling limit value: mg/m³, 5.6 ppm *15-min TLV Long-term value: 16 mg/m³, 3 ppm Page 6 of 46 1801 Morgan Street Rockford, IL 61102 Print Date 07/27/2015 Phone: (815) 968-9661 Fax: Name: (815) 968-9731 Trade EP11HT BLACK A www.gcelectronics.com Safety Data Sheet acc. to OSHA HCS SAFETY DATA SHEET · Information about Storage in One Common Storage Facility Store away from incompatible material(s). with OSHA Hazard Communication Standard Store awayComplies from foodstuffs. Avoid release to the environment. Page 5/20 SDS Number: 133A Revision Date:07/24/2015 Revision Date: Date 07/27/2015 Supersedes 07/16/2012 (Contd. of page 4) 29 CFR 1910.1200 · Additional Information No further relevant information. Product Name: EPOXY GLUE, PART A * 8 Exposure controls/personal protection SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION · Engineering · Exposure Measures or Controls Limit Values that Require Monitoring at the Workplace 1317-65-3 Calcium Carbonate TEEL Short-term value: 15.0 mg/m³ Long-term value: 60.0 mg/m³ SCAPA, 2008 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica OSHA PEL Short-term value: 15 mg/m³ US ACGIH Short-term value: 10 mg/m³ 2426-08-6 Butylglycidylether PEL Long-term value: 270 mg/m³, 50 ppm REL Ceiling limit value: 30 mg/m³, 5.6 ppm *15-min TLV Long-term value: 16 mg/m³, 3 ppm Skin; DSEN 1333-86-4 Carbon black PEL Long-term value: 3.5 mg/m³ REL Long-term value: 3.5* mg/m³ *0.1 in presence of PAHs;See Pocket Guide Apps.A+C TLV Long-term value: 3* mg/m³ *inhalable fraction 71-36-3 1-Butyl alcohol PEL Long-term value: 300 mg/m³, 100 ppm REL Ceiling limit value: 150 mg/m³, 50 ppm Skin TLV Long-term value: 61 mg/m³, 20 ppm 14808-60-7 Quartz PEL see Quartz listing REL Long-term value: 0.05* mg/m³ *respirable dust; See Pocket Guide App. A TLV Long-term value: 0.025* mg/m³ *as respirable fraction · Additional Information for the Limit Values As a SUSPECTED CARCINOGEN, there may be NO safe level of exposure; reduce all contact to the lowest possible level. · Other Engineering Measures or Controls Ventilation rates should be matched to conditions. If applicable, use process enclosure(s), local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. · Personal Protective · General Protective and Hygienic Measures Avoid any contact with skin or eye. Do not eat, drink or smoke during work. Contaminated work clothing is not allowed out of workplace. Clean hands and exposed skin thoroughly after work and before breaks. (Contd. on page 6) US Part Number(s): 10-347 Part A Page 7 of 46 1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET Safety Data Sheet Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Page 6/20 6/20 Page acc. to OSHA HCS Print Print Date Date 07/27/2015 07/27/2015 Product Name: EPOXY GLUE, PART A Trade Name: EP11HT BLACK A Revision Revision Date Date 07/27/2015 07/27/2015 EP11HT BLACK A SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION (CONTINUED) (Contd. 5) (Contd. of of page page 5) ·· Personal Protective Equipment (PPE) ·· Breathing Equipment Where the the potential potential for for over-exposure over-exposure exists, exists, use use a a NIOSH NIOSH approved approved supplied-air supplied-air respirator respirator with with a a full full facepiece facepiece operated operated in in a a Where pressure-demand pressure-demand or or other other positive-pressure positive-pressure mode. mode. ·· Hand Protection Protective Protective gloves gloves Selection Selection of of glove glove material material should should take take into into consideration consideration the the penetration penetration times, times, rates rates of of diffusion, diffusion, and and the the degradation. degradation. Suggested glove glove type(s): type(s): Suggested Nitrile Gloves Gloves Nitrile Butyl Butyl Rubber Rubber Gloves Gloves ·· Eye Protection Brief Brief or or short short term term use: use: Tightly Tightly sealed sealed goggles goggles Intensive Intensive or or long long term term use: use: Tightly Tightly sealed sealed goggles goggles and and Face Face Shields Shields ·· Body Protection Chemical Chemical resistant resistant apron; apron; cover cover exposed exposed skin. skin. ·· Additional Information All All protective protective clothing clothing (suits, (suits, gloves, gloves, footwear, footwear, headgear) headgear) should should be be clean, clean, available available every every day, day, and and put put on on before before work. work. The The Engineering Engineering measures measures or or controls, controls, and and PPE PPE recommendations recommendations are are only only guidelines guidelines and and may may not not apply apply to to every every situation. situation. For For additional additional information, please please consult consult the the corresponding corresponding requirements requirements under under OSHA OSHA 29 29 CFR CFR 1910.94-95, 1910.94-95, and and 29 29 CFR CFR 1910.132-138. 1910.132-138. information, ** 9 Physical and chemical properties PROPERTIES SECTION 9. PHYSICAL AND CHEMICAL ·· Information on Basic Physical ·· Appearance: ·· Form: ·· Color: ·· Odor: ·· Odor Threshold: ·· PH-Value: and Chemical Properties Paste Paste Black Black Mild Mild epoxy epoxy odor odor Not determined. determined. Not Not determined. determined. Not ·· Change in Condition: ·· Melting Point: ·· Boiling Point: ·· Flash Point: Not determined. determined. Not Not determined. determined. Not > > 93 93 °C °C (> (> 199 199 °F) °F) ·· Decomposition Temperature: Not determined. Not determined. ·· Flammability: Not determined. determined. Not Part Number(s): 10-347 Part A ·· Explosion: Not determined. Not determined. ·· Explosion Limits: Page 8 of 46 Intensive or long term use: Tightly sealed goggles and Face Shields · Body Protection Chemical resistant apron; cover exposed skin. · Additional Information All protective clothing (suits, gloves, footwear, headgear) should be clean, available every day, and put on before work. The Engineering measures or controls, and PPE recommendations are only guidelines and may not apply to every situation. For additional 1801 Morgan Street information, please consult the corresponding requirements under OSHA 29 CFR 1910.94-95, and 29 CFR 1910.132-138. SDS Number: * Rockford, IL 61102 Phone: (815) 968-9661 9 Physical and chemical properties Fax: (815) 968-9731 · Information on Basic Physical and Chemical Properties www.gcelectronics.com · Appearance: · Form: · Color: · Odor: Complies · Odor 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 Paste SAFETY DATA SHEET Black with OSHA Hazard Standard 29 CFR 1910.1200 Mild Communication epoxy odor Threshold: Not determined. Not determined. Product Name: EPOXY GLUE, PART A · PH-Value: · Change in Condition: · Melting Point: Not determined. SECTION 9.· Boiling PHYSICAL PROPERTIES (CONTINUED) Point:AND CHEMICALNot determined. · Flash Point: > 93 °C (> 199 °F) · Decomposition Temperature: Not determined. · Flammability: Not determined. · Explosion: Not determined. · Explosion Limits: acc. to OSHA HCS acc. to OSHA HCS · Lower: Not determined. Print Date 07/27/2015 · Upper: Print Date 07/27/2015 Not determined. Trade· Name: EP11HT BLACK A Vapor Pressure: Not determined. Trade Name: EP11HT BLACK A · Vapor Density: not determined Page 7/20 Page 7/20 Safety Data Sheet Safety Data Sheet · Density at 25 °C (77 °F): 1.26 g/cm³ (10.515 lbs/gal) ·· Density at 25 °C (77 °F): Solubility in or Miscibility with 1.26 g/cm³ (10.515 lbs/gal) · Solubility · Water: in or Miscibility with Not miscible or difficult to mix. · Water: Not miscible or difficult to mix. · Viscosity: · Viscosity: · Dynamic at 20 °C (68 °F): 600000 mPas ·· Dynamic at 20 °C (68 °F): 600000 mPas Kinematic: Not determined. · Kinematic: Not determined. · Additional Information No further relevant information. · Additional Information No further relevant information. * * Revision Date 07/27/2015 Revision Date 07/27/2015 (Contd. of page 6) (Contd. (Contd.on of page page 7) 6) US 10 Stability and reactivity 10 Stability reactivity SECTION 10. and STABILITY AND REACTIVITY · Physical Hazard(s) Not a regulated reactive or physical hazard under GHS. · Physical Hazard(s) Not a regulated reactive or physical hazard under GHS. · Hazardous Reactivity and Chemical Stability May polymerize when heated. · Hazardous Reactivity and Chemical Stability May polymerize when heated. · Thermal Decomposition and Conditions to be Avoided · Thermal and Conditions to be Avoided Keep away Decomposition from incompatible material(s). Keep awaydecomposes from incompatible Thermally duringmaterial(s). fire or high heat; keep away from heat, sparks, open flame and other ignition sources. Thermally decomposes during fire or high heat; keep away from heat, sparks, open flame and other ignition sources. · Possibility of Other Hazardous Reaction(s) · Possibility of Other Hazardous Reaction(s) May ignite on contact with fluorine. May ignite relevant on contact with fluorine. No further information available. No further relevant information available. · Incompatible Material(s) · Amines. Incompatible Material(s) Amines. Mercaptans Mercaptans Oxidizing agents Oxidizing agents Acids Acids Bases (Alkalis) Bases (Alkalis) Ammonium salts, Mercury/hydrogen mixture, and Magnesium Alum, Fluorine, Alum, Fluorine, Ammonium salts, Mercury/hydrogen mixture, and Magnesium · Hazardous Decomposition Product(s) · Hazardous Irritating fumes Decomposition Product(s) Irritating Thermallyfumes decomposes during fire or very high heat. See Section 5 for fire hazards evolved during thermal decomposition. Thermally decomposes during fire or very high heat. See Section 5 for fire hazards evolved during thermal decomposition. * * 11 Toxicological information 11 Toxicological information Toxicity Part· Acute Number(s): 10-347 Part A · Acute Toxicity · Oral · Oral Page 9 of 46 * 10 Stability and reactivity · Physical Hazard(s) Not a regulated reactive or physical hazard under GHS. · Hazardous Reactivity and Chemical Stability May polymerize when heated. · Thermal Decomposition and Conditions to be Avoided Keep away from incompatible material(s). Thermally decomposes during fire or high heat; keep away from heat, sparks, open flame and other ignition sources. 1801 Morgan of Street · Possibility Other Hazardous Reaction(s) May ignite on contact Rockford, IL 61102with fluorine. No further relevant information available. Phone: (815) 968-9661 · Incompatible Material(s) Fax: Amines. (815) 968-9731 Mercaptans www.gcelectronics.com SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 Oxidizing agents Acids Bases (Alkalis) Alum, Fluorine, Ammonium salts, Mercury/hydrogen mixture, and Magnesium SAFETY DATA SHEET Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 · Hazardous Decomposition Product(s) Irritating fumes Thermally decomposes during fire or very high heat. See Section 5 for fire hazards evolved during thermal decomposition. Product Name: EPOXY GLUE, PART A * 11 Toxicological informationINFORMATION SECTION 11. TOXICOLOGICAL · Acute Toxicity · Oral 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Oral LD50 11400 mg/kg (rat) 15600 mg/kg (mouse) Reference: NLM Toxnet (2010). 1317-65-3 Calcium Carbonate Oral LD50 6450 mg/kg (rat) Reference: Imerys (M)SDS (2008). Safety Data Sheet Page 8/20 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica acc. to OSHA HCS Oral LD50 >5000 mg/kg (rat) (test method not specified) Print Date 07/27/2015 Revision Date 07/27/2015 Reference: Cabot (M)SDS (2012). 2426-08-6 Butylglycidylether Trade Name: EP11HT BLACK A Oral LD50 1530 mg/kg (mouse) 1660 mg/kg (rat) Reference: NLM Toxnet (2011). (Contd. of page 7) (Contd. on page 8) 1333-86-4 Carbon black US Oral LD50 > 10000 mg/kg (rat) (Toxicity not anticipated under normal conditions) No mortality or clinical signs of toxicity were observed after an oral administration with 10000 mg/kg bw of the substance to rats. Reference: OECD SIDS (2006). · Potential Health Effect(s): Not a classified acute oral hazard. · Dermal 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Dermal LD50 20000 mg/kg (rabbit) (Test guideline not available) > 1270 mg/kg (mouse) > 2000 mg/kg (rat) > 1600 mg/kg (rabbit); however, there was no fixed test result available; classification was not possible without further information. 1317-65-3 Calcium Carbonate Dermal LD50 (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Dermal LD50 (Test species: n/a) (Toxicity not expected based on acute oral data) Based on the acute oral toxicity test, it was expected that toxicity to mammals via dermal application of the substance was not a significant concern and resulted in a similar lack of acute toxicity. Thus, the substance was not classified as an acute dermal hazard as a wetted form. 2426-08-6 Butylglycidylether Dermal LD50 2290 mg/kg (rabbit) (Estimated from LD50 of 2.52mL/kg) > 2150mg/kg (rabbit) Reference: ChemID (2011). 1333-86-4 Carbon black Dermal LD50 > 3000 mg/kg (Test species: n/a) (Toxicity not anticipated under normal conditions) Reference: ChemID (2010). · Potential Health Effect(s): Not a classified acute dermal hazard. · Inhalative Part Number(s): 10-347 Part A 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Inhalative LC50/4 h (Test species: n/a) (Toxicity not expected based on the acute oral data) Page 10 of 46 No mortality or clinical signs of toxicity were observed after an oral administration with 10000 mg/kg bw of the substance to rats. Reference: OECD SIDS (2006). · Potential · Dermal Health Effect(s): Not a classified acute oral hazard. 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Dermal LD50 20000 mg/kg (rabbit) (Test guideline not available) > 1270 mg/kg (mouse) > 2000 mg/kg (rat) > 1600 mg/kg (rabbit); however, there was no fixed test result available; classification was not possible without further 1801 Morgan information. Street SDS Number: 133A 1317-65-3 Calcium Carbonate Rockford, IL 61102 Revision Date:07/24/2015 Dermal LD50 (-) Phone: (815)No968-9661 Supersedes Date: 07/16/2012 data available. Fax: (815) 968-9731 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica www.gcelectronics.com Dermal LD50 (Test species: n/a) (Toxicity not expected based on acute oral data) Based on the acute oral toxicity test, it was expected that toxicity to mammals via dermal application of the substance was not a significant concern and resulted in a similar lack of acute toxicity. Thus, the substance was not classified as an acute dermal hazard as a wetted form. Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 2426-08-6 Butylglycidylether Dermal LD50 2290 mg/kg (rabbit) (Estimated from LD50 of 2.52mL/kg) > 2150mg/kg (rabbit) Reference: ChemID (2011). 1333-86-4 Carbon black Dermal LD50 > 3000 mg/kg (Test species: n/a) (Toxicity not anticipated under normal conditions) SECTION 11. TOXICOLOGICAL INFORMATION (CONTINUED) Reference: ChemID (2010). · Potential Health Effect(s): Not a classified acute dermal hazard. SAFETY DATA SHEET Product Name: EPOXY GLUE, PART A · Inhalative 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Inhalative LC50/4 h (Test species: n/a) (Toxicity not expected based on the acute oral data) 1317-65-3 Calcium Carbonate Inhalative LC50/4 h (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Inhalative LC50/4 h (Test species: n/a) (Toxicity not expected based on acute oral data) Due to wetted form of the substance, inhalative effects from dust form can be seen as negligible. Meanwhile, based on the acute oral toxicity test, it was expected that toxicity to mammals via inhalation of the substance was not a significant concern and resulted in a similar lack of acute toxicity. Thus, the substance was not classified as an acute inhalation hazard. 2426-08-6 Butylglycidylether Inhalative LC50/4 h 10.96 mg/l (rat) (LC50/4 hrs; calculated from LC50/8 hrs of 1030 ppm) Reference: ChemID and EnviChem (2011). 1333-86-4 Carbon black Page 9/20 Inhalative LC50/4 h (Test species: n/a) (Toxicity not expected based on acute oral data) Due to wetted form of the substance, inhalative effects from dust form can be seen as negligible. Meanwhile, based on the acute oral toxicity test, it was expected that toxicity to mammals via inhalation of the substance was not a significant concern and resulted acc. in a similar lack of acute toxicity. Thus, the substance was not classified as an acute to OSHA HCS inhalation hazard as a wetted form. Print Date 07/27/2015 Revision Date 07/27/2015 · Potential Health Effect(s): wheezing Trade Name: EP11HT BLACK A incoordination fainting Not a classified acute inhalative hazard. (Contd. of page 8) (Contd. on page 9) No further relevant information; classification is not possible. US cough, headache, sore throat, and passing out · Skin Corrosion or Irritation Safety Data Sheet 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Corrosion/Irritation irritating (rabbit) Acute skin irritation was mild, through repeated and prolonged exposure may cause severe irritation. The substance was classified as Category 2 by GHS-J. Reference: HSNO CCID (2010) and GHS-J (2006). 1317-65-3 Calcium Carbonate Corrosion/Irritation moderately (-) The substance is moderately irritating based on the PH = 9.5 with concentration of 50g/L of water at 20C. moderately (rabbit) (Draize test) 500 mg/24h, the pure substance shows no irritating effect, however, the impurities or degradation products may lead to irritant effects on the sweating skin due to alkalinity. Reference: IUCLID dataset of CAS No. 471-34-1 (2000). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Corrosion/Irritation Non-irritating (Test species: n/a) (Primary irritation index=0) mildly irritating (rabbit) (Read across from CAS 63148-62-9) No test detail available; for safety reasons, the substance was classified as mildly irritating (Category 3) to rabbit skin. Part Number(s): 10-347 Part A Page Reference: HSNO CCID (2010). 2426-08-6 Butylglycidylether Corrosion/Irritation irritating (rabbit) (Draize test) 11 of 46 Page 9/20 Safety Data Sheet acc. to OSHA HCS Print Date 07/27/2015 Revision Date 07/27/2015 Trade Name: EP11HT BLACK A (Contd. of page 8) 1801 Morgan Street SDS Number: 133A No further relevant information; classification is not possible. headache, sore throat, and passing out Rockford,cough, IL 61102 Revision Date:07/24/2015 · Skin Corrosion or Irritation Phone: (815) 968-9661 Supersedes Date: 07/16/2012 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Fax: (815) 968-9731 Corrosion/Irritation irritating (rabbit) www.gcelectronics.com Acute skin irritation was mild, through repeated and prolonged exposure may cause severe irritation. The substance was classified as Category 2 by GHS-J. Reference: HSNO CCID (2010) and GHS-J (2006). 1317-65-3 Calcium Carbonate Complies with Corrosion/Irritation moderately (-) OSHA Hazard Communication Standard 29 CFR 1910.1200 The substance is moderately irritating based on the PH = 9.5 with concentration of 50g/L of water at 20C. SAFETY DATA SHEET moderately (rabbit)GLUE, (Draize test) PART A Product Name: EPOXY 500 mg/24h, the pure substance shows no irritating effect, however, the impurities or degradation products may lead to irritant effects on the sweating skin due to alkalinity. Reference: IUCLID dataset of CAS No. 471-34-1 (2000). SECTION 11. TOXICOLOGICAL INFORMATION (CONTINUED) 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Corrosion/Irritation Non-irritating (Test species: n/a) (Primary irritation index=0) mildly irritating (rabbit) (Read across from CAS 63148-62-9) No test detail available; for safety reasons, the substance was classified as mildly irritating (Category 3) to rabbit skin. Reference: HSNO CCID (2010). 2426-08-6 Butylglycidylether Corrosion/Irritation irritating (rabbit) (Draize test) Draize score was 3.3; thus, the substance was classified as a Category 2 skin irritant. irritating (human) Reference: HSNO CCID (2011). 1333-86-4 Carbon black Corrosion/Irritation not irritating (rabbit) (None showed any signs of skin irritation) Reference: OECD SID (2006). · Potential Health Effect(s): Causes skin irritation. In contact with skin, may cause: redness and pain · Eye Serious Damage or Irritation 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Damage/Irritation irritating (rabbit) The substance caused eye irritation (Category 2A) based on the dermal effect to rabbit skin. 1317-65-3 Calcium Carbonate Damage/Irritation slightly (Human) The substance is slightly irritating to the eyes. Reference: IUCLID Dataset of CAS No. 471-34-1 (2000). not irritating (rabbit) No toxic effect when applied to surface of rabbit eyes Reference: ACToR of CAS No. 471-34-1 (2010). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Damage/Irritation slightly irrit. (Human) (Read across from CAS 63148-62-9) non-irritating (Primary irritation index=0) Transient ocular irritation was observed in humans, rabbits, dogs, and monkeys after injection of the substance to their eye bodies. However, those effects can be seen as negligible based on regular use of the substance. When applying lower viscosity substance-oil mixture to human and rabbit eyes, there was no cornea injury, but a delay of healing of the existed corneal erosion observed. For safety reasons, the substance was classified as a slight eye irritant (Category 2B). Reference: ACToR (2011) and Cabot (M)SDS (2012). (Contd. on page 10) US Part Number(s): 10-347 Part A Page 12 of 46 1317-65-3 Calcium Carbonate Corrosion/Irritation moderately (-) The substance is moderately irritating based on the PH = 9.5 with concentration of 50g/L of water at 20C. moderately (rabbit) (Draize test) 500 mg/24h, the pure substance shows no irritating effect, however, the impurities or degradation products may lead to irritant effects on the sweating skin due to alkalinity. Reference: IUCLID dataset of CAS No. 471-34-1 (2000). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica 1801 Morgan Street SDS Number: 133A Corrosion/Irritation Non-irritating (Test species: n/a) (Primary irritation index=0) mildly irritating (rabbit) (Read across from CAS 63148-62-9) Rockford, IL 61102 No test detail available; for safety reasons, the substance was classified as mildly irritatingRevision (Category 3)Date:07/24/2015 to rabbit skin. Reference: HSNO CCID (2010). Phone: (815) 968-9661 Supersedes Date: 07/16/2012 2426-08-6 Butylglycidylether Fax: (815) 968-9731 Corrosion/Irritation irritating (rabbit) (Draize test) www.gcelectronics.com Draize score was 3.3; thus, the substance was classified as a Category 2 skin irritant. irritating (human) Reference: HSNO CCID (2011). 1333-86-4 Carbon black Complies with OSHA Communication Corrosion/Irritation not irritating (rabbit) (NoneHazard showed any signs of skin irritation) Standard Reference: OECD SID (2006). acc. to OSHA HCS · Potential Health Effect(s): Print Date 07/27/2015 Causes skin irritation. In contact withBLACK skin, may Trade Name: EP11HT A cause: redness and pain · Eye 11. SECTION TOXICOLOGICAL INFORMATION (CONTINUED) Serious Damage or Irritation SAFETY DATA SHEET Safety Data Sheet Product Name: EPOXY GLUE, PART A Page 10/20 29 CFR 1910.1200 Revision Date 07/27/2015 (Contd. of page 9) 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin 2426-08-6 Butylglycidylether Damage/Irritation (rabbit) Damage/Irritation irritating mildly irrit. (rabbit) The irritation (Category 2A) based on theapplied dermalaseffect to rabbit skin. The substance substance caused caused eye reversible damage to rabbit eyes when drops. 1317-65-3 CalciumReference: CarbonateHSDB (2011). 1333-86-4 Carbonslightly black (Human) Damage/Irritation substance is slightly irritating to Damage/Irritation The slightly irrit. (rabbit) (discoloration of the lids eyes. and slight conjunctiva) Reference: Dataset of CAS No. of 471-34-1 (2000). No irritatingIUCLID effect was observed in any test animals at any observation. (human) Theirritating substance particles may cause discoloration of lids and slight conjunctiva to human eyes. not (rabbit) Fortoxic safety reason, the substance was classified as mildly irritating to eyes (Category 2B). No effect when applied to surface of rabbit eyes OECD SIDS (2006). Reference: ACToR of CAS No. 471-34-1 (2010). · Potential Health Effect(s): 67762-90-7 Siloxanes Causes seriousand eyeSilicones, damage. di-Me, reaction products with silica In contact slightly with eye, may cause: (Read across from CAS 63148-62-9) Damage/Irritation irrit. (Human) decrease or loss of vision non-irritating (Primary irritation index=0) redness, pain and severe burnswas observed in humans, rabbits, dogs, and monkeys after injection of the substance to their Transient oculardeep irritation eye bodies. However, those effects can be seen as negligible based on regular use of the substance. When applying · Respiratory or Skin Sensitization lower viscosity substance-oil mixture to human and rabbit eyes, there was no cornea injury, but a delay of healing of the 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin existed corneal erosion observed. For safety reasons, the substance was classified as a slight eye irritant (Category Sensitization Skin2B). sensitizing (Human) Based on positive results from skin sensitization tests on human volunteers and guinea pigs, GHS-J classified Reference: ACToR (2011) and Cabot (M)SDS (2012). the substance as a dermal sensitizer. (Contd. on page 10) Reference: GHS-J (2006). US Respiratory (No data available) 1317-65-3 Calcium Carbonate Sensitization Skin (-) No data available. Respiratory (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Sensitization Skin (No data available) Primary irritation index=0 Non-irritating. Cabot MSDS (2012) Respiratory (No data available) 2426-08-6 Butylglycidylether Sensitization Skin sensitizing (Human) (Patch test) 5 out of 5 human subjects treated with neat substance showed positive reactions; 17 out of 25 human subjects treated with 10% concentrated solution of the substance showed positive reactions. Thus, the substance was classified as a skin sensitizer to humans. Reference: HSDB (2011). Respiratory (No data available) 1333-86-4 Carbon black Sensitization Skin not sensitizing (Human) (There were no allergies reported in humans) Reference: OECD SIDS (2006). Respiratory (No data available) · Potential Health Effect(s): May cause an allergic skin reaction. Repeated skin contact may cause dermatitis, skin rash or itchiness. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Part Number(s): 10-347 Part A Page · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 13 of 46 Sensitization Skin sensitizing (Human) Based on positive results from skin sensitization tests on human volunteers and guinea pigs, GHS-J classified the substance as a dermal sensitizer. Reference: GHS-J (2006). Respiratory (No data available) 1317-65-3 Calcium Carbonate Sensitization Skin (-) No data available. Respiratory (-) 1801 Morgan Street No data available. 67762-90-7 Rockford, ILSiloxanes 61102 and Silicones, di-Me, reaction products with silica Sensitization Skin (No data available) Phone: (815) 968-9661 Primary irritation index=0 Non-irritating. Cabot MSDS (2012) Fax: (815) 968-9731 Respiratory (No data available) www.gcelectronics.com 2426-08-6 Butylglycidylether Sensitization Skin SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 sensitizing (Human) (Patch test) 5 out of 5 human subjects treated with neat substance showed positive reactions; 17 out of 25 human subjects treated with 10% concentrated solution of the substance showed positive reactions. Thus, the substance was Compliesclassified with OSHA Standard 29 CFR 1910.1200 as a skinHazard sensitizer toCommunication humans. Reference: HSDB (2011). Respiratory (No data available) 1333-86-4 Carbon black Sensitization Skin not sensitizing (Human) (There were no allergies reported in humans) Page 11/20 Reference: OECD SIDS (2006). SECTION 11. Respiratory TOXICOLOGICAL INFORMATION (CONTINUED) (No data available) acc. to OSHA HCS · Potential Health Effect(s): Print Date 07/27/2015 Revision Date 07/27/2015 May cause an allergic skin reaction. Repeated skin contact may cause dermatitis, skin rash or itchiness. Trade Name: EP11HT BLACK A May cause allergy or asthma symptoms or breathing difficulties if inhaled. · OSHA-Ca (Occupational Safety & Health Administration) SAFETY DATA SHEET Product Name: EPOXY GLUE, PART A Safety Data Sheet None of the ingredients is listed. · Germ Cell Mutagenicity (Contd. of page 10) (Contd. on page 11) 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Mutagenicity positive (Chinese hamster lung fibroblast cells) (In Vitro (Chromosomal Aberration)) In Vitro (Chromosomal Aberration; Chinese hamster lung fibroblast cells) - Positive without metabolic activation; negative with metabolic activation. Positive (salmonella typhimurium) (In Vitro (Ames assay)). Due to the absence from In Vivo tests, it was not possible to make a conclusion of mutagenicity of the substance. Reference: NLM CCRIS (2010). 1317-65-3 Calcium Carbonate Mutagenicity negative (-) The pure substance is not listed as a carcinogen by NTP, IARC or OSHA. Reference: Imerys (M)SDS (2008). US 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Mutagenicity negative (Chinese Hamster) (In Vitro (AMES Test)) negative (Chinese Hamster) (In Vitro (Chromosomal aberration in ovary cells)) Reference: Cabot (M)SDS (2012). 2426-08-6 Butylglycidylether Mutagenicity positive (salmonella typhimurium) (In Vitro (Ames test)) Studies on Butyl Glycidyl Ether showed it to be mutagenic and genotoxic in bacterial and mammalian cell systems. (Germ cell mutagen Group 2) positive (Human) (In Vivo (DNA repair with mononucleated leukocytes)) negative (mouse) (In Vivo (Dominant lethal&Micronucleus assay)) REACh CLP, NIOSH ICSC, NJ-RTK, GHS-J, and NLM Toxnet all listed the substance as a suspected mutagen. When considering all of the evidence, the substance was classified as a suspected mutagen for safety reason. Reference: NLM CCRIS (2011) and GHS-J (2006). 1333-86-4 Carbon black Mutagenicity negative (salmonella typhimurium) (In Vitro (Ames test)) In Vitro (Sister chromatid exchange assay; Chinese Hamster) - negative with and without metabolic activation. In Vitro (Mouse Lymphoma assay) - negative with and without metabolic activation. Reference: OECD SIDS (2006). · Potential Health Effect(s): Suspected of causing genetic defects. · Carcinogenicity 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Carcinogenicity negative (Test species: n/a) (Not listed by ACGIH, IARC, NTP, or OSHA) (Mouse) 1 out of 4 cases with female mice showed positive carcinogenic results after a repeated dermal application with 10% concentration of the substance for two years. When considering all of the evidence, the substance was not classified as a carcinogen. 1317-65-3 Calcium Carbonate Carcinogenicity negative (salmonella typhimurium) (Preincubation) In Vitro - Negative with and without metabolic activation. Reference: NLM TOXNET of CAS No. 471-34-1 (2010). Part Number(s): 10-347 Part A Page 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Carcinogenicity (Test species: n/a) (Not listed by IARC, NTP, OSHA or ACGIH) 14 of 46 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Mutagenicity negative (Chinese Hamster) (In Vitro (AMES Test)) negative (Chinese Hamster) (In Vitro (Chromosomal aberration in ovary cells)) Reference: Cabot (M)SDS (2012). 2426-08-6 Butylglycidylether Mutagenicity positive (salmonella typhimurium) (In Vitro (Ames test)) Studies on Butyl Glycidyl Ether showed it to be mutagenic and genotoxic in bacterial and mammalian cell systems. (Germ cell mutagen Group 2) positive (Human) (In Vivo (DNA repair with mononucleated leukocytes)) negative (mouse) (In Vivo (Dominant lethal&Micronucleus assay)) 1801 MorganREACh Street SDS Number: CLP, NIOSH ICSC, NJ-RTK, GHS-J, and NLM Toxnet all listed the substance as a suspected mutagen. When 133A considering all of the evidence, the substance was classified as a suspected mutagen for safety reason. Rockford, IL 61102 Revision Date:07/24/2015 Reference: NLM CCRIS (2011) and GHS-J (2006). Phone: (815) 968-9661 Supersedes Date: 07/16/2012 1333-86-4 Carbon black Mutagenicity negative (salmonella typhimurium) (In Vitro (Ames test)) Fax: (815) 968-9731 In Vitro (Sister chromatid exchange assay; Chinese Hamster) - negative with and without metabolic activation. www.gcelectronics.com In Vitro (Mouse Lymphoma assay) - negative with and without metabolic activation. Reference: OECD SIDS (2006). · Potential Health Effect(s): Suspected of causing genetic defects. · Carcinogenicity SAFETY DATA SHEET Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Carcinogenicity negative (Test species: n/a) (Not listed by ACGIH, IARC, NTP, or OSHA) (Mouse) 1 out of 4 cases with female mice showed positive carcinogenic results after a repeated dermal application with 10% concentration of the substance for two years. When considering all of the evidence, the substance was not classified as a carcinogen. SECTION TOXICOLOGICAL INFORMATION (CONTINUED) 1317-65-311. Calcium Carbonate Carcinogenicity negative (salmonella typhimurium) (Preincubation) In Vitro - Negative with and without metabolic activation. Reference: NLM TOXNET of CAS No. 471-34-1 (2010). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Carcinogenicity (Test species: n/a) (Not listed by IARC, NTP, OSHA or ACGIH) 2426-08-6 Butylglycidylether Carcinogenicity (dynamic) N/A (Test species: n/a) Page 12/20 The substance was listed as a suspected Carcinogen by IARC (Group 2). Substance is listed as Group 2 carcinogen by CLP regulations. 1333-86-4 Carbon black acc. to OSHA HCS positive (rat) Print Carcinogenicity Date 07/27/2015 Revision Date 07/27/2015 Application: Inhalation Exposure time: 2 years Trade Name: EP11HT BLACK A Target Organ: Lungs Source: Dow Corning Q3-6611 SDS This substance is inextricably bound within a product and will not contribute to an inhalation hazard. (Contd. of page 11) (Contd. on page 12) (Human) US This substance is inextricably bound within a product and will not contribute to an inhalation hazard. IARC Group 2B Possibly carcinogenic to humans. Based on inhalation studies with animals. · Potential Health Effect(s): Suspected of causing cancer. Product Name: EPOXY GLUE, PART A Safety Data Sheet · Reproductive Toxicity 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Reproductive Toxi. negative (Test species: n/a) (no reproductive or developmental effect observed) There was no reproductive or developmental effect observed at dosing levels that were toxic to parental animals. Reference: GHS-J (2006). 1317-65-3 Calcium Carbonate Reproductive Toxi. (rat) Up to 1.25% diet of the substance for 6 weeks prior to mating and during gestation and found no adverse effects. Reference: ACToR of CAS No. 471-34-1 (2010). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Reproductive Toxi. (No data available) 2426-08-6 Butylglycidylether Reproductive Toxi. Positive (Test species: n/a) (A known chemical to reproductive males) The substance was a listed chemical to male reproductive toxicity by California Proposition 65. Suspected of causing genetic defects. Royce SDS 2014. 1333-86-4 Carbon black Reproductive Toxi. negative (Test species: n/a) (Incapable of reaching reproductive organs) It was very unlikely that the substance particles can reach the reproductive organs under In Vivo conditions, nor were capable of skin penetration the reproductive system. Thus, the substance was unlikely to pose a reproductive toxicity. Reference: OECD SIDS (2006). · Potential Health Effect(s): Not a known Reproductive hazard. · Specific Target Organ Toxicity - Single Exposure 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin STOT-Single Target: None (Rats and Mice) (No effect after single oral doses) Somnolence (general depressed activity) and dyspnea were observed after a single oral application with 11400 mg/kg to rats, or 15600 mg/kg to mice of the substance. However, the dose levels were both outside of the guidance value ranges. Part Number(s): 10-347 Reference: Part A Page NLM Toxnet (2010). 1317-65-3 Calcium Carbonate STOT-Single (Human) 15 of 46 (Contd. of page 11) (Human) This substance is inextricably bound within a product and will not contribute to an inhalation hazard. IARC Group 2B Possibly carcinogenic to humans. Based on inhalation studies with animals. · Potential Health Effect(s): Suspected of causing cancer. Toxicity · Reproductive 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Reproductive Toxi. negative (Test species: n/a) (no reproductive or developmental effect observed) There was no reproductive or developmental effect observed at dosing levels that were toxic to parental animals. 1801 Morgan Street SDS Number: 133A Reference: GHS-J (2006). 1317-65-3IL Calcium Carbonate Rockford, 61102 Revision Date:07/24/2015 Reproductive Toxi. (rat) Phone: (815) 968-9661 Supersedes Date: 07/16/2012 Up to 1.25% diet of the substance for 6 weeks prior to mating and during gestation and found no adverse effects. Reference: ACToR of CAS No. 471-34-1 (2010). Fax: (815) 968-9731 www.gcelectronics.com 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Reproductive Toxi. (No data available) 2426-08-6 Butylglycidylether ReproductiveComplies Toxi. Positive with (Test species: (A known Communication chemical to reproductiveStandard males) OSHAn/a)Hazard 29 CFR 1910.1200 The substance was a listed chemical to male reproductive toxicity by California Proposition 65. Suspected of causing genetic defects. Royce SDS 2014. 1333-86-4 Carbon black Reproductive Toxi. negative (Test species: n/a) (Incapable of reaching reproductive organs) It was very unlikely that the substance particles can reach the reproductive organs under In Vivo conditions, nor were capable of skin penetration the reproductive system. Thus, the substance was unlikely to pose a reproductive toxicity. SECTION 11. TOXICOLOGICAL INFORMATION (CONTINUED) Reference: OECD SIDS (2006). · Potential Health Effect(s): Not a known Reproductive hazard. SAFETY DATA SHEET Product Name: EPOXY GLUE, PART A · Specific Target Organ Toxicity - Single Exposure 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin STOT-Single Target: None (Rats and Mice) (No effect after single oral doses) Somnolence (general depressed activity) and dyspnea were observed after a single oral application with 11400 mg/kg to rats, or 15600 mg/kg to mice of the substance. However, the dose levels were both outside of the guidance value ranges. Reference: NLM Toxnet (2010). 1317-65-3 Calcium Carbonate STOT-Single (Human) Inhalation 0.005 mg/L for 3 hours: target organs - systemic toxicity May affect nasal function and cause nasal symptoms. Ingested up to 15g of the substance: target organs - systemic toxicity Symptoms included: fatigue, anorexia, nausea and vomiting, an elevated blood pressure, hemoconcentration, leukocytosis, metabolic alkalosis, elevated body weight and hypokalemia. Reference: ACToR of CAS No. 471-34-1 (2010). (rat) Exposed to 0.0812 mg/L for 90 minutes/ after 21 hr. No effect on lung weight, macrophage concentration, or histopathology. Reference: ACToR of CAS No. 471-34-1 (2010). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica STOT-Single (dynamic) (No data available) 2426-08-6 Butylglycidylether STOT-Single (mouse) (Respiratory tract irritation via Inhalation) Target Organs: Respiratory tract irritation (Category 3) Inhalation with 260 mg/m³ of the substance caused somnolence, dyspnea, and respiratory depression in mice. Reference: NLM Toxnet (2011) and ESIS CLP/GHS. (Contd. on page 13) US Part Number(s): 10-347 Part A Page 16 of 46 1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET Safety Data Sheet Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Page 13/20 acc. to OSHA HCS Print Date 07/27/2015 Product Name: EPOXY GLUE, PART A Revision Date 07/27/2015 Trade Name: EP11HT BLACK A SECTION 11. TOXICOLOGICAL INFORMATION (CONTINUED) (Contd. of page 12) 1333-86-4 Carbon black STOT-Single Target: None (rat) (No effect after oral with 10000 mg/kg) Target organs: None No clinical sign of toxicity was observed after a single oral administration with 10000 mg/kg of the substance. Reference: OECD SIDS (2006). · Potential Health Effect(s): Not a known hazard to organs upon single exposure. · Specific Target Organ Toxicity - Repeated Exposure 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin STOT-Repeated Target: N/A (guinea pig) (insufficient data for classification) With dermal application of the substance for 55 days, increased seromucoid concentrations, decreased lactatedehydrogenase (LDH), and decreased leucylnaphthylamidase (LNA) were observed in the test animals. Meanwhile, the substance caused a toxic effect on blood components of female guinea-pigs with greater effects on pregnant animals. However, there was no detail available regarding the dose level or test guideline, classification was thus not possible. Reference: HSNO CCID (2010). 1317-65-3 Calcium Carbonate STOT-Repeated (Human) Target organs - Systemic toxicity Symptoms: Infrequent instances of hypercalcemia with alkalosis, calcinosis, azotemia, renal dysfunction, GI hemorrhage and vomiting or aspiration through nasogastric tube seem to predispose to the disorder. Reference: ACToR of CAS No. 471-34-1. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica STOT-Repeated (No data available) 2426-08-6 Butylglycidylether STOT-Repeated (Test species: n/a) (Insufficient data for classification) NOAEL (Inhalation) = 0.52 mg/L/day. 1. Rats - Decreased body fat, thymic size, and lymphoid organs; abdominal and thoracic viscera; evidence of pneumonia and lethargy; emaciation; liver necrosis; significant increase in kidney/body and lung/body weight ratios; and high incidence of testicular atrophy and bronchopneumonia. 2. Rabbits - Decreased liver weights; decreased body fat and fecal material in GI tract; exudative rhinitis; and lethargy. 3. Mice - Decreased liver weights; decreases body fat, thymic size and lymphoid organs; postural and gait changes. No test method available; meanwhile, EU or HMIS didn't classify the substance as a chronic hazard. Without further information, classification is not possible. Reference: HPVIS (2011) and HSDB (2011). 1333-86-4 Carbon black STOT-Repeated Target: None (Rats and Mice) (No effect after repeated oral with 2050mg/kg/day) · Potential Health Effect(s): No further relevant information; classification is not possible. · Aspiration Hazard 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Aspiration Hazard (No data available) 1317-65-3 Calcium Carbonate Aspiration Hazard (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Aspiration Hazard (No data available) 2426-08-6 Butylglycidylether Aspiration Hazard (No data available) Part 1333-86-4 Number(s): 10-347 Carbon blackPart A Aspiration Hazard (No data available) Page 17 of 46 Reference: ACToR of CAS No. 471-34-1. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica STOT-Repeated (No data available) 2426-08-6 Butylglycidylether STOT-Repeated (Test species: n/a) (Insufficient data for classification) NOAEL (Inhalation) = 0.52 mg/L/day. 1. Rats - Decreased body fat, thymic size, and lymphoid organs; abdominal and thoracic viscera; evidence of pneumonia and lethargy; emaciation; liver necrosis; significant increase in kidney/body and lung/body weight ratios; and high incidence of testicular atrophy and bronchopneumonia. 2. Rabbits - Decreased liver weights; decreased body fat and fecal material in GI tract; exudative rhinitis; andNumber: lethargy. 1801 Morgan Street SDS 133A 3. Mice - Decreased liver weights; decreases body fat, thymic size and lymphoid organs; postural and gait changes. Rockford, IL 61102 Revision No test method available; meanwhile, EU or HMIS didn't classify the substance as a chronic hazard. Date:07/24/2015 Without further information, classification is not possible. Phone: (815) 968-9661 Supersedes Date: 07/16/2012 Reference: HPVIS (2011) and HSDB (2011). Fax: (815) 968-9731 1333-86-4 Carbon black STOT-Repeated Target: None (Rats and Mice) (No effect after repeated oral with 2050mg/kg/day) www.gcelectronics.com · Potential Health Effect(s): No further relevant information; classification is not possible. · Aspiration Hazard SAFETY DATA SHEET 25068-38-6 Bisphenol-A-(epichlorohydrin) resinCommunication Complies with OSHA epoxy Hazard Aspiration Hazard (No data available) 1317-65-3 Calcium Carbonate Aspiration Hazard (-) No data available. Standard 29 CFR 1910.1200 Product Name: EPOXY GLUE, PART A 67762-90-7 and Silicones, di-Me, reaction products with silica SECTION 11.Siloxanes TOXICOLOGICAL INFORMATION (CONTINUED) Aspiration Hazard (No data available) 2426-08-6 Butylglycidylether Aspiration Hazard (No data available) acc. to OSHA HCS 1333-86-4 Carbon black Print Aspiration Date 07/27/2015 Hazard (No data available) · Potential Health Effect(s): No relevant information; classification is not possible. Trade Name: EP11HT BLACK A · Additional Information No further relevant information. Safety Data Sheet * Page 14/20 Revision Date 07/27/2015 (Contd. of page 13) US (Contd. on page 14) SECTION 12. ECOLOGICAL 12 Ecological informationINFORMATION · Aquatic Environmental Toxicity 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Algae Toxicity (No data available) Crustacean Toxicity 1.4 - 1.7 mg/l (Daphnia magna (water flea)) (EC50 (48 hrs)) Fish Toxicity 1.41 mg/l (Oryzias latipes (Rice fish)) (LC50 (96 hrs)) 3.1 mg/l (Pimephales promelas (fathead minnow)) (LC50 (96 hrs)) Based on the non-rapid degradability and the acute LC50 < 10 mg/L, the substance is classified as a Chronic-2 environmental hazard. Reference: CHRIP (2010). 1317-65-3 Calcium Carbonate Algae Toxicity (static) 56000 mg/l (Gambusia affinis (western mosquitofish)) (LC50 (24 - 96 hrs)) Reference: ACToR of CAS No. 471-34-1 (2010). (Poecilia Latipinna (Sailfin molly)) Exposure period: 96 hrs. NOEC > 200 mg/L Reference: IUCLID Dataset of CAS No. 471-34-1 (2000). Crustacean Toxicity (-) The substance is not toxic to aquatic organisms. Reference: Canada DSL of CAS No. 471-34-1 (2007). Fish Toxicity (-) The substance is not toxic to aquatic organisms. Reference: Canada DSL of CAS No. 471-34-1 (2007). Micro-organism toxi (-) The substance is not toxic to aquatic organisms. Reference: Canada DSL of CAS No. 471-34-1 (2007). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Algae Toxicity > 10000 mg/l (Scenedesmus subspicatus) (ErC50 (24 hrs), OECD 201) Crustacean Toxicity > 1000 mg/l (Daphnia magna (water flea)) (EC50 (24 hrs), OECD 202) Fish Toxicity > 10000 mg/l (Brachydanio rerio (Zebra fish)) (LC50 (96 hrs), OECD 203) Reference: Cabot (M)SDS (2012). 2426-08-6 Butylglycidylether Algae Toxicity 35 mg/l (Selenastrum capricornum) (LC50 (96 hrs); OECD TG 201) Toxicity 3.9Part mg/l A (Daphnia magna (water flea)) (EC50 (48 hrs); OECD TG 202) Part Crustacean Number(s): 10-347 Page Based on the acute EC50 < 10 mg/L and the rapid degradability, the substance is classified as a Chronic-3 environmental hazard. 18 of 46 environmental hazard. Reference: CHRIP (2010). 1317-65-3 Calcium Carbonate Algae Toxicity (static) 56000 mg/l (Gambusia affinis (western mosquitofish)) (LC50 (24 - 96 hrs)) Reference: ACToR of CAS No. 471-34-1 (2010). (Poecilia Latipinna (Sailfin molly)) Exposure period: 96 hrs. NOEC > 200 mg/L Reference: IUCLID Dataset of CAS No. 471-34-1 (2000). 1801 Morgan Street Crustacean Toxicity (-) Rockford, IL 61102The substance is not toxic to aquatic organisms. Reference: Canada DSL of CAS No. 471-34-1 (2007). Phone: (815) 968-9661 Fax: (815) 968-9731 Fish Toxicity (-) The substance is not toxic to aquatic organisms. www.gcelectronics.com Reference: Canada DSL of CAS No. 471-34-1 (2007). Micro-organism toxi (-) SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET The substance is not toxic to aquatic organisms. Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Reference: Canada DSL of CAS No. 471-34-1 (2007). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Product Name:>EPOXY GLUE, PART A Algae Toxicity 10000 mg/l (Scenedesmus subspicatus) (ErC50 (24 hrs), OECD 201) Crustacean Toxicity Fish Toxicity > 1000 mg/l (Daphnia magna (water flea)) (EC50 (24 hrs), OECD 202) > 10000 mg/l (Brachydanio rerio (Zebra fish)) (LC50 (96 hrs), OECD 203) SECTION 12. ECOLOGICAL INFORMATION Reference: Cabot (M)SDS (2012). 2426-08-6 Butylglycidylether Algae Toxicity 35 mg/l (Selenastrum capricornum) (LC50 (96 hrs); OECD TG 201) Crustacean Toxicity 3.9 mg/l (Daphnia magna (water flea)) (EC50 (48 hrs); OECD TG 202) Based on the acute EC50 < 10 mg/L and the rapid degradability, the substance is classified as a Chronic-3 environmental hazard. Reference: HPVIS (2011) Fish Toxicity (No data available) Page 15/20 1333-86-4 Carbon black Algae Toxicity >1000 mg/l (Selenastrum capricornum) (LC50 (96 hrs, suspensions)) acc.(water to OSHA HCS Crustacean Toxicity 5600 - 10000 mg/l (Daphnia magna flea)) (EC50 (24 hrs), OECD TG 202) Fish Toxicity >1000 mg/l (Brachydanio rerio (Zebra fish)) (LC50 (96 hrs, suspensions)) Print Date 07/27/2015 Revision Date 07/27/2015 · Aquatic Environmental Toxicity Assessment: Toxic to aquatic life with long lasting effects. Trade Name: EP11HT BLACK A · Degradability and Stability Safety Data Sheet 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin Biodegradation non-biodegrad. (Test species: n/a) (Biodegradation (OECD TG 302B; 28 days) = 12%) (Activated Sludge) (OECD TG 301C; 4 weeks; Conc. 100 mg/L) Biodegradation (Indirect Analysis from BOD) = 0% Biodegradation (Direct Analysis from HPLC) = 0% The substance is non-biodegradable. Reference: CHRIP (2010). Persistence (Test species: n/a) (This substance is persistent) Reference: Canada DSL (2007) and CHRIP (2010). Photodegradation 6.69E-11 cm³/molecule-sec (OH radical) (Half-life (T1/2) = 1.92 hrs) However, photolysis in water is negligible. Stability in water (No data available) 1317-65-3 Calcium Carbonate Biodegradation (-) The test is not applicable since this substance is inorganic and not soluble in water. Reference: IUCLID Dataset of CAS No. 471-34-1 (2000). (Contd.on of page (Contd. page 14) 15) US Photodegradation positive cm³/molecule-sec (-) The substance is persistent. Reference: ACToR of CAS No. 471-34-1 (2010). Stability in water (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Biodegradation (No data available) Persistence (Test species: n/a) (The substance is not persistent) Reference: Canada DSL (2007). Photodegradation (No data available) Stability in water (No data available) 2426-08-6 Butylglycidylether Biodegradation readily biodeg. (Test species: n/a) (Biodegradation (OECD TG 301C) ≥ 40%) Biodegradation (Direct Analysis from TOC and GC; 28 days) = 56% and 68% Biodegradation (Indirect Analysis from BOD; 28 days) = 40% The substance is readily biodegradable. Part Number(s): 10-347 Part A Reference: CHRIP (2011). Persistence (Test species: n/a) (The substance is not persistent) Page 19 of 46 (Activated Sludge) (OECD TG 301C; 4 weeks; Conc. 100 mg/L) Biodegradation (Indirect Analysis from BOD) = 0% Biodegradation (Direct Analysis from HPLC) = 0% The substance is non-biodegradable. Reference: CHRIP (2010). Persistence (Test species: n/a) (This substance is persistent) Reference: Canada DSL (2007) and CHRIP (2010). Photodegradation 6.69E-11 cm³/molecule-sec (OH radical) (Half-life (T1/2) = 1.92 hrs) However, photolysis in water is negligible. Stability in water (No data available) 1317-65-3 Calcium Carbonate 1801 Morgan Street Biodegradation (-) The test is not applicable since this substance is inorganic and not soluble in water. Rockford, IL 61102 Reference: IUCLID Dataset of CAS No. 471-34-1 (2000). Phone: (815) 968-9661 Photodegradation positive cm³/molecule-sec (-) Fax: (815) 968-9731 The substance is persistent. www.gcelectronics.com Reference: ACToR of CAS No. 471-34-1 (2010). Stability in water (-) No data available. SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Biodegradation (No data available) Persistence (Test species: n/a) (The substance is not persistent) Reference: Canada DSL (2007). Photodegradation (No data available) SECTION ECOLOGICAL INFORMATION (CONTINUED) Stability in12. water (No data available) 2426-08-6 Butylglycidylether Biodegradation readily biodeg. (Test species: n/a) (Biodegradation (OECD TG 301C) ≥ 40%) Biodegradation (Direct Analysis from TOC and GC; 28 days) = 56% and 68% Biodegradation (Indirect Analysis from BOD; 28 days) = 40% The substance is readily biodegradable. Reference: CHRIP (2011). Persistence (Test species: n/a) (The substance is not persistent) Reference: Canada DSL (2007). Photodegradation 1.99E-11 cm³/molecule-sec (Test species: n/a) Half-life (1.5E6 OH/cm³; calculated by EPIWIN program) = 6.47 hours Reference: NLM Toxnet (2011) and HPVIS (2011). Stability in water stable (Test species: n/a) (Half-life (OECD TG 111; PH=7) = 486.7 hours) Thus, the substance is hydrotically stable in the aquatic environment. Reference: HPVIS (2011). 1333-86-4 Carbon black Biodegradation non-biodegrad. (Test species: n/a) (Due to being an inorganic elemental carbon) Persistence persistent (Test species: n/a) Photodegradation (Test species: n/a) (Photolysis is not expected) Stability in water stable (Test species: n/a) (Due to being an inorganic elemental carbon) Product Name: EPOXY GLUE, PART A · Bioaccumulation and Distribution 25068-38-6 Bisphenol-A-(epichlorohydrin) epoxy resin BCF 0.56-42 (Cyprinus carpio) (The substance is low-bioaccumulative) BCF (28 days; Concentration: 10 μg/L) = 0.56 - 0.67, 3.3 - 4.2 BCF (28 days; Concentration: 1 μg/L) = 5.6 - 6.8, 33 - 42 Reference: CHRIP (2010). Koc 1800 - 4400 L/kg (soil) Potential for mobility in soil is moderate. LogPow 3.7 - 3.9 (Test species: n/a) (Contd. on page 16) US Part Number(s): 10-347 Part A Page 20 of 46 1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET Safety Data Sheet Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Page 16/20 acc. to OSHA HCS Print Date 07/27/2015 Product Name: EPOXY GLUE, PART A Revision Date 07/27/2015 Trade Name: EP11HT BLACK A SECTION 12. ECOLOGICAL INFORMATION (CONTINUED) (Contd. of page 15) 1317-65-3 Calcium Carbonate BCF (-) No data available. Environment fate (-) No data available. Koc (-) No data available. LogPow (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica BCF (No data available) (The substance is not bioaccumulative) Reference: Canada DSL CCR (2011). Koc (No data available) LogPow (No data available) 2426-08-6 Butylglycidylether BCF 3.16 (Test species: n/a) (The substance is not bioaccumulative) Reference: Canada DSL (2007) and CCR (2011). Koc (No data available) LogPow 0.63 (Test species: n/a) Reference: NLM Toxnet (2011). 1333-86-4 Carbon black BCF (Test species: n/a) (The substance is not bioaccumulative) Reference: OECD SIDS (2006). Koc (Test species: n/a) (Primarily partitions to soil, or sediment) LogPow (Not applicable) (Due to being an inorganic elemental carbon) · Degradability and Bioaccumulation Assessment: Non-rapidly degradable, and low bioaccumulative. · Additional * Information No further relevant information. 13 Disposal considerations · Hazardous Waste List · Description: It may be necessary to contain and dispose of the substance/mixture as a hazardous waste. · RCRA Waste: 2426-08-6 Butylglycidylether 71-36-3 1-Butyl alcohol D001 2.5-5% U031 (n-Butyl alcohol (I)) 0-<0.1% · Waste Treatment Recommendation: Generation of waste should be avoided or minimized wherever possible. Chemical waste, even small quantities, is neither allowed to be poured down drains, sewage system or waterways; nor disposed with household garbage. Dispose of contents/containers in accordance with local, regional, national, and international regulations. · and10-347 Uncontaminated Packagings PartUnused Number(s): Part A · Recommendation Dispose of according to your local waste regulations. Page 21 of 46 US LogPow (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica BCF (No data available) (The substance is not bioaccumulative) Reference: Canada DSL CCR (2011). Koc (No data available) LogPow (No data available) 2426-08-6 Butylglycidylether 1801 Morgan Street SDS Number: 133A BCF 3.16 (Test species: n/a) (The substance is not bioaccumulative) Reference: Canada DSL (2007) and CCR (2011). Rockford, IL 61102 Revision Date:07/24/2015 Koc (No data available) Phone: (815) 968-9661 Supersedes Date: 07/16/2012 LogPow 0.63 (Test species: n/a) Fax: (815) 968-9731 Reference: NLM Toxnet (2011). 1333-86-4 Carbon black www.gcelectronics.com BCF (Test species: n/a) (The substance is not bioaccumulative) Reference: OECD SIDS (2006). Koc (Test species: n/a) (Primarily partitions to soil, or sediment) Complies with (Due OSHA Hazard Communication LogPow (Not applicable) to being an inorganic elemental carbon) Standard 29 CFR 1910.1200 · Degradability and Bioaccumulation Assessment: Non-rapidly degradable, and low bioaccumulative. SAFETY DATA SHEET · Additional Information Product Name: EPOXY GLUE, PART A No further relevant information. * SECTION 13. DISPOSAL CONSIDERATIONS 13 Disposal considerations · Hazardous Waste List · Description: It may be necessary to contain and dispose of the substance/mixture as a hazardous waste. · RCRA Waste: 2426-08-6 Butylglycidylether 71-36-3 1-Butyl alcohol D001 2.5-5% U031 (n-Butyl alcohol (I)) 0-<0.1% Page 17/20 · Waste Treatment Recommendation: Generation of waste should be avoided or minimized wherever possible. Chemical waste, even small quantities, is neither allowed to be poured down drains, sewage system or waterways; nor disposed with acc. to OSHA HCS household garbage. of contents/containers in accordance with local, regional, national, and international regulations. Print DateDispose 07/27/2015 Revision Date 07/27/2015 · Unused and Uncontaminated Packagings Trade Name: EP11HT BLACK A · Recommendation Dispose of according to your local waste regulations. Safety Data Sheet US (Contd. of page 16) (Contd. on page 17) * 14 Transport informationINFORMATION SECTION 14. TRANSPORT · UN-Number · DOT, ADR, IMDG, IATA · UN Proper Shipping Name · DOT, ADR, IMDG, IATA · Transport · DOT, UN3082 Environmentally hazardous substances, liquid, n.o.s. (Bisphenol-A(epichlorohydrin) epoxy resin) hazard class(es) IMDG, IATA · Class · Label 9 Miscellaneous dangerous substances and articles 9 · ADR · Class · Label · Packing · DOT, group ADR, IMDG, IATA · Environmental Hazards: · Marine Pollutant: 9 (M6) Miscellaneous dangerous substances and articles 9 III Yes Part Number(s): 10-347 Part A Symbol (fish and tree) · Special Marking (ADR): Symbol (fish and tree) Page 22 of 46 * 14 Transport information · UN-Number · DOT, ADR, IMDG, IATA · UN Proper Shipping Name · DOT, ADR, IMDG, IATA · Transport UN3082 Environmentally hazardous substances, liquid, n.o.s. (Bisphenol-A(epichlorohydrin) epoxy resin) hazard class(es) 1801 ·Morgan Street DOT, IMDG, IATA Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com · Class · Label · ADR SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 9 Miscellaneous dangerous substances and articles 9 SAFETY DATA SHEET Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Product Name: EPOXY GLUE, PART A · Class 9 (M6) Miscellaneous dangerous substances and articles SECTION 14. TRANSPORT INFORMATION (CONTINUED) · Label 9 · Packing · DOT, group ADR, IMDG, IATA · Environmental Hazards: · Marine Pollutant: · Special · Special Marking (ADR): Marking (IATA): · Special Precautions: · Danger Code (Kemler): · EMS Number: III Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles 90 F-A,S-F · Transport in Bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional · DOT · Quantity Information: limitations Safety Data Sheet · Remarks: · ADR · Excepted Print Date 07/27/2015 quantities (EQ) Trade Name: EP11HT BLACK A · IMDG · Limited quantities (LQ) · Excepted · UN * On passenger aircraft/rail: No limit On cargo aircraft only: No limit Special marking with the symbol (fish and tree). quantities (EQ) "Model Regulation": Page 18/20 acc. to OSHA HCS Code: E1 Revision Date 07/27/2015 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml (Contd. of page 17) (Contd. on page 18) US UN3082, Environmentally hazardous substances, liquid, n.o.s. (Bisphenol-A(epichlorohydrin) epoxy resin), 9, III 15 Regulatory information · USA Regulation Lists (Superfund Amendments and Reauthorization Act of 1986) · Section 302 (Extremely Hazardous Substances) · SARA None of the ingredients is listed. · Section 313 (Toxics Release Inventory (TRI) reporting) 71-36-3 1-Butyl alcohol · Section 311/312 (Hazardous Chemical Inventory Reporting) Bisphenol-A-(epichlorohydrin) epoxy resin Part25068-38-6 Number(s): 10-347 Part A 1317-65-3 Calcium Carbonate 2426-08-6 Butylglycidylether 0-<0.1% A, C 70-80% Page A, C 10-20% A, C, F 2.5-5% 23 of 46 1801 Morgan Street Rockford, IL 61102 Print Date 07/27/2015 Phone: (815) 968-9661 Trade Name: EP11HT BLACK A Fax: (815) 968-9731 www.gcelectronics.com · Excepted · UN quantities (EQ) Safety Data Sheet acc. to OSHA HCS Page 18/20 SDS Number: 133A Revision Revision Date:07/24/2015 Date 07/27/2015 Supersedes Date: 07/16/2012 (Contd. of page 17) Code: E1 SAFETY Maximum DATAnetSHEET quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 "Model Regulation": UN3082, Environmentally hazardous substances, liquid, n.o.s. (Bisphenol-A(epichlorohydrin) epoxy resin), 9, III Product Name: EPOXY GLUE, PART A * 15 Regulatory information SECTION 15. REGULATORY INFORMATION · USA Regulation Lists (Superfund Amendments and Reauthorization Act of 1986) · Section 302 (Extremely Hazardous Substances) · SARA None of the ingredients is listed. · Section 313 (Toxics Release Inventory (TRI) reporting) 71-36-3 1-Butyl alcohol · Section 25068-38-6 1317-65-3 2426-08-6 1333-86-4 311/312 (Hazardous Chemical Inventory Reporting) Bisphenol-A-(epichlorohydrin) epoxy resin Calcium Carbonate Butylglycidylether Carbon black · Hazard Abbreviations for SARA A - Acute Health Hazard C - Chronic Health Hazard F - Fire Hazard R - Reactive Hazard S - Sudden Release of Pressure Hazard · TSCA 0-<0.1% A, C A, C A, C, F A, C 70-80% 10-20% 2.5-5% 1-2.5% 311/312 (Toxic Substances Control Act) All ingredients are listed. · Proposition 65 · Chemicals Known to Cause Cancer This product may also contain extremely small amounts of one or more naturally occurring materials known to the State of California to cause cancer, birth defects or other reproductive harm. 1333-86-4 Carbon black 14808-60-7 Quartz 106-89-8 1-chloro-2,3-epoxypropane · Chemicals Known to Cause Reproductive Toxicity for Females · Chemicals Known to Cause Reproductive Toxicity for Males · Chemicals Known to Cause Developmental Toxicity None of the ingredients is listed. 106-89-8 1-chloro-2,3-epoxypropane None of the ingredients is listed. · Carcinogenic · EPA Categories (Environmental Protection Agency) 71-36-3 1-Butyl alcohol · IARC 14808-60-7 Quartz · NTP (International Agency for Research on Cancer) (National Toxicology Program) 14808-60-7 Quartz Part Number(s): 10-347 Part A D 1 K (Contd. on page 19) PageUS24 of 46 1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET Safety Data Sheet Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Page 19/20 acc. to OSHA HCS Print Date 07/27/2015 Product Name: EPOXY GLUE, PART A Revision Date 07/27/2015 Trade Name: EP11HT BLACK A SECTION 15. REGULATORY INFORMATION (CONTINUED) · TLV (Threshold Limit Value Established by ACGIH) 1333-86-4 Carbon black 14808-60-7 Quartz · NIOSH-Ca 14808-60-7 Quartz · International A4 A2 (National Institute for Occupational Safety and Health) · Canadian Regulation Lists Domestic Substance Listings: · Canadian Ingredient Disclosure list (limit 0.1%) · Canadian Ingredient Disclosure list (limit 1%) 25068-38-6 1317-65-3 67762-90-7 1333-86-4 71-36-3 14808-60-7 (Contd. of page 18) Bisphenol-A-(epichlorohydrin) epoxy resin Calcium Carbonate Siloxanes and Silicones, di-Me, reaction products with silica Carbon black 1-Butyl alcohol Quartz 2426-08-6 Butylglycidylether 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica 1333-86-4 Carbon black · Chinese Chemical Inventory of Existing Chemical Substances: All ingredients are listed. · Japanese All ingredients are listed. · Korean Existing and New Chemical Substance List: Existing Chemical Inventory: All ingredients are listed. · European All ingredients are listed. · REACh Pre-registered substances: - Substances of Very High Concern (SVHC) List: None of the ingredients is listed. · Restriction of Hazardous Substances Directive (RoHS) list: None of the ingredients is listed. * 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department Issuing (M)SDS: Product Safety Department · Contact: [email protected] · Abbreviations and acronyms: Part Number(s): 10-347 Part A ACGIH: American Conference of Governmental Industrial Hygienists ADR: European Agreement Concerning the International Carriage of Dangerous Goods by Road CAS: Chemical Abstracts Service (division of the American Chemical Society) Page 25 of 46 14808-60-7 Quartz · Canadian Ingredient Disclosure list (limit 0.1%) · Canadian Ingredient Disclosure list (limit 1%) 2426-08-6 Butylglycidylether 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica 1333-86-4 Carbon black · Chinese Chemical Inventory of Existing Chemical Substances: All ingredients are listed. 1801 Morgan Street Existing and New Chemical Substance List: · Japanese All ingredients are listed. Rockford, IL 61102 · Korean Phone: (815) 968-9661 Existing Chemical Inventory: All ingredients are listed. Fax: (815) 968-9731 · European Pre-registered substances: www.gcelectronics.com SDS Number: 133A Revision Date:07/24/2015 Supersedes Date: 07/16/2012 All ingredients are listed. · REACh SAFETY DATA SHEET - Substances of Very High Concern (SVHC) List: None of the ingredients is listed. Complies with · Restriction OSHA Hazard Communication Standard 29 CFR 1910.1200 of Hazardous Substances Directive (RoHS) list: None of the ingredients is listed. Product Name: EPOXY GLUE, PART A * 16 Other 16. information SECTION OTHER INFORMATION This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department · Issuing (M)SDS: Product Safety Department · Abbreviations and acronyms: ACGIH: American Conference of Governmental Industrial Hygienists Page 20/20 ADR: European Agreement Concerning the International Carriage of Dangerous Goods by Road CAS: Chemical Abstracts Service (division of the American Chemical Society) DOT: US Department of Transportation acc. to OSHAMaterials HCS Identification System HMIS: US National Paint & Coatings Association (NPCA) Hazardous IARC: International Agency for Research on Cancer developed by United Nations World Health Organisation (WHO) Print Date 07/27/2015 Revision Date 07/27/2015 ICAO-TI: Technical Instructions (TI) by the International Civil Aviation Organization (ICAO) IMDG: International Maritime Dangerous Goods; the principal international rules for International Carriage of Dangerous Goods by SEA Trade Name: EP11HT BLACK A under the Recommendations on the Transport of Dangerous Goods by United Nations (RTDG) LC50/LD50: Lethal Concentration/Dose, 50 percent N/a: Not available or Not applicable (Contd. of page 19) (Contd. on page 20) NFPA: US National Fire Protection Association US NIOSH: US National Institute of Occupational Safety and Health OSHA: US Occupational Safety and Health Administration P: Marine Pollutant RCRA: Resource Conservation and Recovery Act (USA) REACh: EU Registry, Evaluation and Authorisation of Chemicals SARA: US Superfund Amendments and Reauthorization Act TEEL: Temporary Emergency Exposure Limit developed by US Subcommittee on Consequence Assessment and Protective Actions (SCAPA) of US Department of Energy (DOE) TSCA: US Toxic Substance Control Act ECHA: European Chemicals Agency’s Dissemination portal with information on chemical substances registered under REACH IUCLID: EU REACh International Uniform Chemical Information Database NLM TOXNET: US National Library of Medicine Toxicology Data Network ACToR: US EPA Aggregated Computational Toxicology Resource BCF: Bioconcentration Factor CCRIS: US NLM TOXNET Chemical Carcinogenesis Research Information System CHRIP: Japan NITE Information on Biodegradation and Bioconcentration of the Existing Chemical Substances in the Chemical Risk Information Platform DSL: Canada Domestic Substance List ESIS: European Chemical Substances Information System HSDB: US NLM TOXNET Hazardous Substances Databank HSNO CCID: New Zealand Hazardous Substances and New Organisms Chemical Classification Information Database IATA-DGR: Dangerous Goods Regulations (DGR) by the International Air Transport Association (IATA) ICSC: International Chemical Safety Cards Koc: Partition coefficient, soil Organic Carbon to water NITE: National Institute of Technology and Evaluation, Japan OECD: Organisation for Economic Co-operation and Development RID: the Regulations Concerning the International Carriage of Dangerous Goods by Rail; published by the Central Office for International Carriage by Rail (OTIF) RTDG: the Recommendations on the Transport of Dangerous Goods by United Nations (UN) RTECS: US Registry of Toxic Effects of Chemical Substances SIDS: OECD existing chemicals Screening Information Data Sets SVHC: EU ECHA Substance of Very High Concern TOXLINE: US NLM bibliographic database search system · Date of preparation / last revision 07/27/2015 / 3 Safety Data Sheet US Part Number(s): 10-347 Part A Page 26 of 46 DSL: Canada Domestic Substance List ESIS: European Chemical Substances Information System HSDB: US NLM TOXNET Hazardous Substances Databank HSNO CCID: New Zealand Hazardous Substances and New Organisms Chemical Classification Information Database IATA-DGR: Dangerous Goods Regulations (DGR) by the International Air Transport Association (IATA) ICSC: International Chemical Safety Cards Koc: Partition coefficient, soil Organic Carbon to water NITE: National Institute of Technology and Evaluation, Japan OECD: Organisation for Economic Co-operation and Development RID: the Regulations Concerning the International Carriage of Dangerous Goods by Rail; published by the Central Office for International Carriage by Rail (OTIF) RTDG: the Recommendations on the Transport of Dangerous Goods by United Nations (UN) RTECS: USStreet Registry of Toxic Effects of Chemical Substances 1801 Morgan SDS Number: 133A SIDS: OECD existing chemicals Screening Information Data Sets Rockford, Revision Date:07/24/2015 SVHC:IL EU61102 ECHA Substance of Very High Concern NLM bibliographic database search system Phone:TOXLINE: (815)US968-9661 Supersedes Date: 07/16/2012 · Date of preparation / last revision 07/27/2015 / 3 Fax: (815) 968-9731 www.gcelectronics.com US SAFETY DATA SHEET Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Product Name: EPOXY GLUE, PART A SECTION 16. OTHER INFORMATION (CONTINUED) GC Electronics believes that the information contained herein is accurate and reliable as of the date of this material safety data sheet, but no representation guarantee or warranty, express or implied, is made as to the accuracy, reliability or completeness of the information. Persons receiving information are encouraged to make their own determination as to the information’s suitability and completeness for their particular application. NO INFORMATION CONTAINED HEREIN CONSTITUTES A PRODUCT WARRANTY OF ANY KIND, WHETHER EXPRESS OR IMPLIED; AND ALL IMPLIED WARRANTIES OF MERCHANT ABILITY AND OF FITNESS FOR A PARTICULAR PURPOSE ARE HEREBY DISCLAIMED BY GC ELECTRONICS. Part Number(s): 10-347 Part A Page 27 of 46 1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com Print Date 04/02/2015 Safety Data Sheet SDS Number: 133B Revision Date:07/24/2015 Page 1/15 Supersedes Date: 07/16/2012 acc. to OSHA HCS SAFETY DATA SHEET · Product Identifier Complies with OSHA Hazard Communication Standard · Trade Name: EP11HT BLACK B · Application of the Substance or Mixture: Epoxy Hardener Revision Date 04/02/2015 29 CFR 1910.1200 · Details Product Name: EPOXY GLUE, PART B (SDS) of the Supplier of the Safety Data Sheet · Manufacturer or Supplier: Resinlab, LLC N109 W13300 Ellsworth Drive, SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Germantown, WI 53022 1-800-388-8605 Product· www.resinlab.com Type: Adhesive Emergency Information Department: Product Safety Department: [email protected] Phone: Product· Emergency Name: Telephone Epoxy Glue, PART A (HARDENER) Number: North America Chemtrec: 1-800-424-9300 (24 hours) Part Number(s): 10-347 Part B International - Chemtrec: 01-703-527-3887 (24 hours) * Contact: Chemtrec (800) 424-9300 2 Hazard(s) identification SECTION 2. HAZARD(S) IDENTIFICATION · Hazard Classification GHS09 Environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 Eye Irrit. 2A H315 Causes skin irritation. H319 Causes serious eye irritation. · Label Elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Pictogram(s) GHS07 GHS09 · Signal Word Warning · Hazard statements Causes skin irritation. Causes serious eye irritation. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Part · Precautionary statements Wear protective gloves. Wear eye protection / face protection. Avoid release to the environment. Wash thoroughly after handling. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see on this label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. If on 10-347 skin: Wash withB plenty of water. Number(s): Part Page Collect spillage. Take off contaminated clothing and wash it before reuse. 28 of 46 GHS09 Environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 H315 Causes skin irritation. 1801 Eye Morgan SDS Number: 133B Irrit. 2A Street H319 Causes serious eye irritation. Rockford, 61102 Revision Date:07/24/2015 · LabelIL Elements Phone: · GHS (815) 968-9661 label elements The product is classified and labeled according to the Globally Harmonized Supersedes Date: 07/16/2012 System (GHS). · Pictogram(s) Fax: (815) 968-9731 www.gcelectronics.com GHS07 GHS09 Complies with SAFETY DATA SHEET OSHA Hazard Communication Standard 29 CFR 1910.1200 · Signal Word Warning · Hazard statements Causes skin irritation. Causes serious eye irritation. Very toxic to aquatic life. 2.Very HAZARD(S) (CONTINUED) toxic to aquaticIDENTIFICATION life with long lasting effects. Product Name: EPOXY GLUE, PART B SECTION · Precautionary statements Wear protective gloves. Wear eye protection / face protection. Page 2/15 Avoid release to the environment. Wash thoroughly after handling. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. acc. to OSHA HCS Specific treatment (see on this label). If skin irritation occurs: Get medical advice/attention. Print Date 04/02/2015 Revision Date 04/02/2015 If eye irritation persists: Get medical advice/attention. If on skin: Wash with plenty of water. Trade Name: EP11HT BLACK B Collect spillage. Take off contaminated clothing and wash it before reuse. Dispose of contents/container in accordance with local/regional/national/international regulations. (Contd. of page 1) (Contd. on page 2) · Prevention US Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Wash thoroughly after handling. · Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Safety Data Sheet · Hazard Rating System · NFPA System · NFPA Ratings (scale 1 3 0 - 4) Health = 3 Fire = 1 Reactivity = 0 0 NFPA special hazards (water reactivity and oxidizing property): None · HMIS System · HMIS Ratings HEALTH 3 FIRE 1 REACTIVITY 0 (scale 0 - 4) Health = 3 Fire = 1 Reactivity = 0 · Other hazards · Results of PBT and vPvB · PBT: Not applicable. · vPvB: Not applicable. * assessment 3 Composition/information on ingredients · Chemical Characterization: Mixtures on Ingredients · Composition/Information CAS: 68410-23-1 Part Number(s): 10-347 CAS: 1317-65-3 EINECS: 215-279-6 RTECS: EV 9580000 Fatty acids, C18 unsatd., dimers, reaction products with polyethylenepolyamines Aquatic Acute 1, H400; Aquatic Chronic 1, H410 Skin Irrit. 2, H315; Eye Irrit. 2A, H319 Part B Calcium Carbonate 60-70% Page 29 of 46 30-40% ·· Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. ·· Hazard Rating System Hazard Rating System ·· NFPA System NFPA System ·· NFPA Ratings (scale NFPA Ratings (scale 3 1 0 0 0 -- 4) 4) Health Health = =3 3 Fire Fire = =1 1 Reactivity Reactivity = =0 0 NFPA special NFPA special hazards hazards (water (water reactivity reactivity and and oxidizing oxidizing property): property): 1801 Morgan Street ·· HMIS System HMIS System Rockford, IL 61102 ·· HMIS Ratings (scale 0 - 4) HMIS968-9661 Ratings (scale 0 - 4) Phone: (815) 3 HEALTH 3 Health = 3 HEALTH Fax: (815) 968-9731 Health = 3 1 FIRE = 1 Fire FIRE =1 1 www.gcelectronics.comFire Reactivity Reactivity = =0 0 REACTIVITY 0 REACTIVITY 0 None None SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET ·· Other hazards Other hazards ·· Results Complies withvPvB OSHA Hazard Communication of assessment Results of PBT PBT and and vPvB assessment ·· PBT: Not applicable. PBT: Not applicable. ·· vPvB: Not applicable. vPvB: Not applicable. Standard 29 CFR 1910.1200 Product Name: EPOXY GLUE, PART B ** 3 Composition/information on ingredients 3 Composition/information on ingredients SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS ·· Chemical Characterization: Mixtures Chemical Characterization: Mixtures ·· Composition/Information on Ingredients Composition/Information on Ingredients CAS: CAS: 68410-23-1 68410-23-1 60-70% 60-70% Fatty Fatty acids, acids, C18 C18 unsatd., unsatd., dimers, dimers, reaction reaction products products with with polyethylenepolyamines polyethylenepolyamines Aquatic Acute Acute 1, 1, H400; H400; Aquatic Aquatic Chronic Chronic 1, 1, H410 H410 Aquatic Skin Irrit. Irrit. 2, 2, H315; H315; Eye Eye Irrit. Irrit. 2A, 2A, H319 H319 Skin Calcium Carbonate Calcium Carbonate CAS: 1317-65-3 1317-65-3 CAS: EINECS: 215-279-6 215-279-6 EINECS: RTECS: EV EV 9580000 9580000 RTECS: CAS: 67762-90-7 67762-90-7 Siloxanes and and Silicones, Silicones, di-Me, di-Me, reaction reaction products products with with silica silica CAS: Siloxanes EC number: number: 614-122-2 614-122-2 EC Classification System: System: ·· Classification The The Classifications Classifications were were based based on on the the Toxicological Toxicological and and Ecological Ecological Data Data of of the the substances/mixtures substances/mixtures in in the the Section Section 11 11 and and 12. 12. ** 4 First-aid measures SECTION 4. FIRST-AID MEASURES Safety Data Sheet 30-40% 30-40% 5-<10% 5-<10% Page 3/15 ·· Description of First Aid Measures Description of First Aid Measures ·· General Information acc. to OSHA HCS General Information Ensure medical of exposure exposure and and take 8 information of medical personnel personnel are are aware aware of take precautions precautions for for their their personal personal protection; protection; see see Section Section 8 for for the the information of Print DateEnsure 04/02/2015 Revision Date 04/02/2015 personal personal protection. protection. Trade··Name: EP11HT BLACK B After After Inhalation Inhalation Remove victim victim from from exposure exposure to to fresh fresh air. air. Keep Keep person person at at rest. rest. Provide Remove Provide oxygen oxygen if if person person is is not not breathing. breathing. In In case case of of unconsciousness unconsciousness place place patient patient stably stably in in side side position position for for transportation. transportation. (Contd. of page 2) Supply fresh fresh air; air; consult consult doctor doctor in in case case of of complaints. complaints. Supply (Contd. on page page 3) 3) · After Skin Contact (Contd. on US US Remove all contaminated clothing and wash before reuse. Wash contaminated skin with water and soap and rinse thoroughly. Seek medical treatment in case of complaints. · After Eye Contact Immediately bathe eyes for 15 minutes under running water. Immediately remove contact lenses if present. Continue rinsing. Seek immediate medical advice. · After Swallowing If victim is unconscious; never give anything by mouth. If victim is conscious; rinse out mouth and give victim small amounts of water. Seek medical treatment in case of complaints. · After Exposure Seek medical treatment in case of complaints. · Information for Doctor Have chemical containers, labels and/or (M)SDS ready when calling or visiting a medical center. · Indication of any Immediate Medical Attention and Special Treatment Needed After frequent or high intense exposure, the following medical tests are recommended: eye tests skin tests Check section 11 Toxicological Information for further relevant information. · Additional Information For additional information, please consult the corresponding first aid measures in the most current version of Emergency Response Guidebook which is produced by the US Department of Transportation. * Part Number(s): 10-347 Part B 5 Fire-fighting measures Page 30 of 46 acc. to OSHA HCS Print Date 04/02/2015 Revision Date 04/02/2015 Trade Name: EP11HT BLACK B (Contd. of page 2) · After Skin Contact Remove all contaminated clothing and wash before reuse. Wash contaminated skin with water and soap and rinse thoroughly. Seek medical treatment in case of complaints. Morgan Street 1801 · After Eye Contact Rockford, IL 61102 Immediately bathe eyes for 15 minutes under running water. Phone: Immediately (815) 968-9661 remove contact lenses if present. Continue rinsing. immediate medical advice. Fax: Seek (815) 968-9731 · After Swallowing www.gcelectronics.com If victim is unconscious; never give anything by mouth. SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 If victim is conscious; rinse out mouth and give victim small amounts of water. Seek medical treatment in case of complaints. SAFETY DATA SHEET · AfterComplies Exposure Seek treatment in case of complaints. withmedical OSHA Hazard Communication Standard 29 CFR 1910.1200 · Information for Doctor Have chemical containers, labels and/or (M)SDS ready when calling or visiting a medical center. · Indication of any Immediate Medical Attention and Special Treatment Needed After frequent or high intense exposure, the following medical tests are recommended: eye tests skin tests section 11 MEASURES Toxicological Information for further relevant information. SECTION 4.Check FIRST-AID (CONTINUED) Product Name: EPOXY GLUE, PART B · Additional Information For additional information, please consult the corresponding first aid measures in the most current version of Emergency Response Guidebook which is produced by the US Department of Transportation. * 5 Fire-fighting measures SECTION 5. FIRE-FIGHTING MEASURES · Extinguishing Media · Suitable Extinguishing Agent(s) Use fire fighting measures and extinguishing agents that suit the environment. In case of fire, suitable extinguishing agents are: Alcohol resistant foam. Dry chemical or fire-extinguishing powder. Carbon dioxide (CO₂). Water spray or water fog. · Unsuitable Extinguishing Agent(s) No relevant information. · Firefighting Procedures Isolate fire and deny unnecessary entry. Eliminate all ignition sources if safe to do so. Do not extinguish fire unless flow can be stopped. Fight fire remotely due to the risk of explosion. Burning liquids may be moved by flushing with water; protect personnel and minimize property damage. Contain fire water runoff if possible to prevent environmental pollution. No information available. Fight fire from protected location or safe distance. Contain fire water runoff if possible to prevent environmental pollution. · Special Hazards Arising in Fire In case of fire, following can be released: Ammonia gas may be liberated at high temperatures. acc. to OSHA HCS hydrocarbons nitric acid Print Date 04/02/2015 Carbon oxides, Nitrogen oxides, and Hydrogen if mixed with metals. Formaldehyde, a skin BLACK and lungBsensitizer and a regulated carcinogen, may be formed during fires. Trade Name: EP11HT Calcium oxide (CaO) Silicon oxide (SiO₂) Calcium oxide (CaO) Page 4/15 Safety Data Sheet Revision Date 04/02/2015 (Contd. of page 3) (Contd. on page 4) · Advice for Firefighters US If employees are expected to fight fires, they must be trained and equipped as stated in the OSHA fire brigades standard (29 CFR 1910.156). As with any fire, wear positive-pressure self-contained breathing apparatus and full protective gear that are NIOSH approved. · Additional * Information Ensure adequate and functional fire fighting facilities equipped in working area at all times. 6 Accidental release measures · Personal Precautions Do not breathe gas, vapors, dusts or mists if their inhalable particles occur during use. Ensure personnel take precautions for their personal protection during clean up; see Section 8 for the specific requirements. · Environmental Precautions Part Number(s): 10-347 Part B Keep away from sewage system or other water courses; do not penetrate ground/soil. Inform respective authorities in case of any seepage to the environment. Page 31 of 46 Safety Data Sheet Safety Data Sheet acc. to OSHA HCS 1801 Morgan Street Print Date 04/02/2015 Rockford, IL 61102 Print Date 04/02/2015 Phone: (815) 968-9661 Trade Name: EP11HT BLACK B Trade Name: EP11HT BLACK B Fax: (815) 968-9731 www.gcelectronics.com acc. to OSHA HCS Page 4/15 Page 4/15 SDS Number: 133B Revision Date 04/02/2015 Revision Date:07/24/2015 Revision Date 04/02/2015 Supersedes Date: 07/16/2012 (Contd. of page 3) (Contd. of page 3) · Advice for Firefighters · Advice for Firefighters If employees are expected to fight fires, they must be trained and equipped as stated in the OSHA fire brigades standard (29 CFR If employees are expected to fight fires, they must be trained and equipped as stated in the OSHA fire brigades standard (29 CFR 1910.156). Complies with OSHA Hazard Communication 29 CFR 1910.156). As with any fire, wear positive-pressure self-contained breathing apparatus andStandard full protective gear that are1910.1200 NIOSH approved. As with any fire, wear positive-pressure self-contained breathing apparatus and full protective gear that are NIOSH approved. · Additional Information Ensure adequate and functional fire fighting facilities equipped in working area at all times. · Additional Information Ensure adequate and functional fire fighting facilities equipped in working area at all times. SAFETY DATA SHEET Product Name: EPOXY GLUE, PART B * * 6 Accidental release measures 6 Accidental release RELEASE measuresMEASURES SECTION 6. ACCIDENTAL · Personal Precautions · Personal Precautions Do not breathe gas, vapors, dusts or mists if their inhalable particles occur during use. Do not breathe gas, vapors, dusts orformists their inhalable particles occur during use. Ensure personnel take precautions theirifpersonal protection during clean up; see Section 8 for the specific requirements. Ensure personnel take precautions for their personal protection during clean up; see Section 8 for the specific requirements. · Environmental Precautions · Environmental Precautions Keep away from sewage system or other water courses; do not penetrate ground/soil. Keep away from sewage system or other water courses; doenvironment. not penetrate ground/soil. Inform respective authorities in case of any seepage to the Inform respective authorities in case of any seepage to the environment. · Cleaning Up Methods · Cleaning Up Methods Ensure adequate ventilation. Ensure adequate ventilation. Eliminate all ignition sources. Eliminate all ignitionpersonnel sources. away. Keep unauthorized Keep unauthorized personnel away. For large spills: For large spills: of leak if safe to do so. Shut off source Shut off source of leak if safe to do so. Dike and contain. Dike and with contain. Remove vacuum trucks or pump to storage/salvage vessels. Remove with product vacuumto trucks Allow molten cool.or pump to storage/salvage vessels. Allow molten product cool. Absorb residues with to liquid-binding materials. Absorb residues For small spills: with liquid-binding materials. For small and spills: Ventilate wash area after clean-up is complete. Ventilate wash area afterfor clean-up is complete. Store in aand sealed containers disposal. Store a sealed containers for disposal. Do notinuse solvents unless following safe handling practices and within the recommended exposure guidelines. Do not use solvents unless following safe handling practices and13. within the recommended exposure guidelines. Dispose contaminated chemicals as waste according to Section Dispose contaminated chemicals as waste according to Section 13. · Additional Information No further relevant information. · Additional Information No further relevant information. * * 7 Handling and storage SECTION 7. HANDLING AND STORAGE 7 Handling and storage · Handling · Handling · Precautions for Safe Handling · Precautions for Safe Handling Obtain special instruction before use; do not handle until all safety precautions have been read and understood. Obtain special instruction before do notif handle until all particles safety precautions have been read and understood. Do not breathe gas, vapors, dustsuse; or mists their inhalable occur during handling. Do notrespiratory breathe gas, vapors,when dustshandling. or mists if their inhalable particles occur during handling. Wear protection Wear away respiratory protection when handling. Keep from incompatible material(s). Keep away from incompatible material(s). Avoid any release into the environment. Avoid anyallrelease into theprotection environment. Observe the personal requirements in Section 8. Observe all the personal protection requirements Section 8. · Information about Protection AgainstinExplosions and Fires · Information about Protection Against Explosions and Fires Will not burn unless preheated. Page 5/15 Will burnfrom unless preheated. Keepnot away heat, sparks, open flame and other ignition sources during handling. Keep away from heat, sparks, open flame and other ignition sources during handling. · Storage · Storage acc. to OSHA HCS · Requirements to be Met by Storerooms and Receptacles · Requirements to be Met by Storerooms and Receptacles Print DateStore 04/02/2015 Revision Date 04/02/2015 in a well-ventilated place; provide ventilation for receptacles. Store stored in a well-ventilated place; ventilation for receptacles. Keep in accordance with provide local, regional, national, and international regulations. Keep stored in accordance national, and international regulations. Trade·Name: EP11HT BLACKStorage Bwith local, Information about inregional, One Common Storage Facility · Information about Storage in One Common Storage Facility Store away from incompatible material(s). Store away away from from foodstuffs. incompatible material(s). Store (Contd. of page 4) Store from foodstuffs. Avoid away release to the environment. Avoid release to the environment. (Contd. on page 5) · Additional Information No further relevant information. (Contd. on page 5) US Safety Data Sheet US * 8 Exposure controls/personal protection Part Number(s): 10-347 Part B · Engineering Measures or Controls · Exposure Limit Values that Require Monitoring at the Workplace Page 32 of 46 1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com Safety Data Sheet SDS Number: 133B Revision Date:07/24/2015 Page 5/15 Supersedes Date: 07/16/2012 acc. to OSHA HCS Print Date 04/02/2015 Trade Name: EP11HT BLACK B Revision Date 04/02/2015 SAFETY DATA SHEET Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 (Contd. of page 4) · Additional Information No further relevant information. Product Name: EPOXY GLUE, PART B * 8 Exposure controls/personal protection PROTECTION SECTION 8. EXPOSURE CONTROLS/PERSONAL · Engineering · Exposure Measures or Controls Limit Values that Require Monitoring at the Workplace 1317-65-3 Calcium Carbonate TEEL Short-term value: 15.0 mg/m³ Long-term value: 60.0 mg/m³ SCAPA, 2008 · Other Engineering Measures or Controls Ventilation rates should be matched to conditions. If applicable, use process enclosure(s), local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. · Personal Protective · General Protective and Hygienic Measures Do not eat, drink or smoke during work. Keep food, drink or feed away from working area. Contaminated work clothing is not allowed out of workplace. Avoid any skin contact. Clean hands and exposed skin thoroughly after work and before breaks. · Personal Protective Equipment (PPE) · Breathing Equipment Caution! Improper use of respirators is dangerous. In case of brief exposure or low pollution, use a respiratory filter device. In case of intensive or longer exposure, use a positive-pressure respiratory protective device that is independent of circulating air. Suggested respirator type(s): Full Facepiece APR with high efficiency filters Self-contained breathing apparatus (SCBA) · Hand Protection Protective gloves Selection of glove material should take into consideration the penetration times, rates of diffusion, and the degradation. Suggested glove type(s): Nitrile Gloves Butyl Rubber Gloves · Eye Protection Tightly sealed goggles · Body Protection Where the potential for over-exposure exists, the following protective work clothing is recommended: Tyvek® Coveralls · Additional Information All protective clothing (suits, gloves, footwear, headgear) should be clean, available every day, and put on before work. The Engineering measures or controls, and PPE recommendations are only guidelines and may not apply to every situation. For additional information, please consult the corresponding requirements under OSHA 29 CFR 1910.94-95, and 29 CFR 1910.132-138. Part Number(s): 10-347 Part B US Page 33 of 46 (Contd. on page 6) Clean hands and exposed skin thoroughly after work and before breaks. · Personal Protective Equipment (PPE) · Breathing Equipment Caution! Improper use of respirators is dangerous. In case of brief exposure or low pollution, use a respiratory filter device. In case of intensive or longer exposure, use a positive-pressure respiratory protective device that is independent of circulating air. Suggested respirator type(s): Full Facepiece APR with high efficiency filters Self-contained breathing apparatus (SCBA) · Hand Protection 1801 Morgan Street SDS Number: 133B Rockford, IL 61102 Protective gloves Revision Date:07/24/2015 Phone: (815) 968-9661 Supersedes Date: 07/16/2012 Fax: (815) 968-9731 Selection of glove material should take into consideration the penetration times, rates of diffusion, and the degradation. Suggested glove type(s): www.gcelectronics.com Nitrile Gloves Butyl Rubber Gloves · Eye Protection SAFETY DATA SHEET Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Tightly sealed goggles Product Name: EPOXY GLUE, PART B · Body Protection Safety Data Sheet Where the potential for over-exposure exists, the following protective work clothing is recommended: Page 6/15 acc. to OSHA HCS SECTION 8.Tyvek® EXPOSURE PROTECTION (CONTINUED) Coveralls CONTROLS/PERSONAL Print Date 04/02/2015 Information · Additional Revision Date 04/02/2015 All protective clothing (suits, gloves, footwear, headgear) should be clean, available every day, and put on before work. Trade The Name: EP11HT BLACK B Engineering measures or controls, and PPE recommendations are only guidelines and may not apply to every situation. For additional information, please consult the corresponding requirements under OSHA 29 CFR 1910.94-95, and 29 CFR 1910.132-138. (Contd. of page 5) US (Contd. on page 6) * SECTION 9. PHYSICAL AND CHEMICAL 9 Physical and chemical properties PROPERTIES · Information on Basic Physical · Appearance: · Form: · Color: · Odor: · Odor Threshold: · PH-Value and Chemical Properties Paste Beige Amine-like Not determined. at 20 °C (68 °F): · Change in Condition: · Melting Point: · Boiling Point: · Flash Point: >7 · Decomposition Temperature: · Flammability: · Explosion: · Explosion Limits: · Lower: · Upper: Not determined. 140 °C (284 °F) 266 °C (511 °F) Not determined. Not determined. Not determined. Not determined. Not determined. · Vapor Pressure: Not determined. · Density at 25 °C (77 °F): 1.27 g/cm³ (10.598 lbs/gal) · Solubility in or Miscibility with · Water: Soluble. · Viscosity: · Dynamic at 20 °C (68 °F): 550000 mPas · Kinematic: Not determined. · Additional * Information No further relevant information. 10 Stability and reactivity · Physical Hazard(s) Not a regulated reactive or physical hazard under GHS. · Hazardous Reactivity and Chemical Stability Stable under normal conditions of use, storage and temperatures. · Thermal Decomposition and Conditions to be Avoided Keep away from incompatible material(s). Thermally decomposes during fire or high heat; keep away from heat, sparks, open flame and other ignition sources. Part Number(s): 10-347 Part B · Possibility of Other Hazardous Reaction(s) May ignite on contact with fluorine. Page 34 of 46 · PH-Value at 20 °C (68 °F): >7 · Change in Condition: · Melting Point: · Boiling Point: · Flash Point: · Decomposition Temperature: · Flammability: · Explosion: · Explosion Limits: 1801 Morgan Street · Lower: Rockford, IL 61102 · Upper: Not determined. 140 °C (284 °F) 266 °C (511 °F) Not determined. Not determined. Not determined. Not determined. Not determined. Phone: (815) 968-9661 · Vapor Pressure: Not determined. Fax: · Density (815)at968-9731 25 °C (77 °F): 1.27 g/cm³ (10.598 lbs/gal) · Solubility in or Miscibility with www.gcelectronics.com · Water: · Viscosity: · Dynamic at 20 °C (68 °F): Complies with OSHA · Kinematic: · Additional Information SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 Soluble. SAFETY DATA SHEET 550000 mPas Hazard Communication Standard 29 CFR 1910.1200 Not determined. No further relevant information. Product Name: EPOXY GLUE, PART B * 10 Stability reactivity SECTION 10. and STABILITY AND REACTIVITY · Physical Hazard(s) Not a regulated reactive or physical hazard under GHS. · Hazardous Reactivity and Chemical Stability Stable under normal conditions of use, storage and temperatures. · Thermal Decomposition and Conditions to be Avoided Keep away from incompatible material(s). Thermally decomposes during fire or high heat; keep away from heat, sparks, open flame and other ignition sources. · Possibility of Other Hazardous May ignite on contact with fluorine. No further relevant information available. Reaction(s) · Incompatible Material(s) Page 7/15 Oxidizing agents, Acids, Cyanides Strong reducing agents Acid anhydrides Strong bases acc. to OSHA HCS Hydrogen fluoride (HF) Print Catechol Date 04/02/2015 Revision Date 04/02/2015 Alum, Fluorine, Ammonium salts, Mercury/hydrogen mixture, and Magnesium Trade Name: EP11HT BLACK B · Hazardous Decomposition Product(s) Irritating fumes Thermally decomposes during fire or very high heat. See Section 5 for fire hazards evolved during thermal decomposition.(Contd. of page 6) (Contd. on page 7) · Hazardous Polymerization Product(s) No relevant information. Safety Data Sheet US · Additional * Information No further relevant information. 11 Toxicological informationINFORMATION SECTION 11. TOXICOLOGICAL · Acute Toxicity · Oral 1317-65-3 Calcium Carbonate Oral LD50 6450 mg/kg (rat) Reference: Imerys (M)SDS (2008). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Oral LD50 >5000 mg/kg (rat) (test method not specified) Reference: Cabot (M)SDS (2012). · Potential Health Effect(s): While not a classified acute oral hazard, the product may cause the following symptom(s): See acute inhalative effect(s) for further information · Dermal 1317-65-3 Calcium Carbonate Dermal LD50 (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Dermal LD50 (Test species: n/a) (Toxicity not expected based on acute oral data) Based on the acute oral toxicity test, it was expected that toxicity to mammals via dermal application of the substance was Part Number(s): not 10-347 Part B a significant concern and resulted in a similar lack of acute toxicity. Thus, the substance was not classified as an Page acute dermal hazard as a wetted form. · Potential Health Effect(s): 35 of 46 (Contd. of page 6) * · Hazardous Polymerization Product(s) No relevant information. · Additional Information No further relevant information. 11 Toxicological information · Acute Toxicity · Oral 1801 Morgan Street 1317-65-3 Calcium Carbonate Rockford, IL 61102 Oral LD50 6450 mg/kg (rat) Reference: Imerys (M)SDS (2008). Phone: (815) 968-9661 Fax: (815) 968-9731 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica www.gcelectronics.com Oral LD50 >5000 mg/kg (rat) (test method not specified) Reference: Cabot (M)SDS (2012). · Potential Health Effect(s): While not a classified acute oral hazard, the product may cause the following symptom(s): Complies OSHA Hazard Communication Standard 29 See acute inhalativewith effect(s) for further information SAFETY DATA SHEET SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 CFR 1910.1200 · Dermal Product Name: EPOXY GLUE, PART B 1317-65-3 Calcium Carbonate Dermal LD50 (-) No data available. SECTION 11.Siloxanes TOXICOLOGICAL INFORMATION (CONTINUED) 67762-90-7 and Silicones, di-Me, reaction products with silica Dermal LD50 (Test species: n/a) (Toxicity not expected based on acute oral data) Based on the acute oral toxicity test, it was expected that toxicity to mammals via dermal application of the substance was not a significant concern and resulted in a similar lack of acute toxicity. Thus, the substance was not classified as an acute dermal hazard as a wetted form. · Potential Health Effect(s): Not a classified acute dermal hazard. See acute inhalative effect(s) for further information. · Inhalative 1317-65-3 Calcium Carbonate Inhalative LC50/4 h (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Inhalative LC50/4 h (Test species: n/a) (Toxicity not expected based on acute oral data) Due to wetted form of the substance, inhalative effects from dust form can be seen as negligible. Meanwhile, based on the acute oral toxicity test, it was expected that toxicity to mammals via inhalation of the substance was not a significant concern and resulted in a similar lack of acute toxicity. Thus, the substance was not classified as an acute inhalation hazard. · Potential Health Effect(s): Page 8/15 While not a classified inhalative acute toxicity hazard, the product may cause the following symptoms: Silicosis Tuberculosis acc. to OSHA HCS Decreased pulmonary function · Print DateSkin 04/02/2015 Revision Date 04/02/2015 Corrosion or Irritation Safety Data Sheet 68410-23-1 Fatty acids, C18 unsatd., dimers, reaction products with polyethylenepolyamines Corrosion/Irritation (Not applicable) (OECD Test Guideline 431) Not considered to be corrosive to skin in the in vitro skin model EpiDermTM. Source: ECHA REACH Dossier GLP Study 2012 Trade Name: EP11HT BLACK B (Contd. of page 7) (Contd. on page 8) 1317-65-3 Calcium Carbonate US Corrosion/Irritation moderately (-) The substance is moderately irritating based on the PH = 9.5 with concentration of 50g/L of water at 20C. moderately (rabbit) (Draize test) 500 mg/24h, the pure substance shows no irritating effect, however, the impurities or degradation products may lead to irritant effects on the sweating skin due to alkalinity. Reference: IUCLID dataset of CAS No. 471-34-1 (2000). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Corrosion/Irritation Non-irritating (Test species: n/a) (Primary irritation index=0) mildly irritating (rabbit) (Read across from CAS 63148-62-9) No test detail available; for safety reasons, the substance was classified as mildly irritating (Category 3) to rabbit skin. Reference: HSNO CCID (2010). · Potential Health Effect(s): Causes skin irritation. In contact with skin, may cause: redness and pain · Eye Serious Damage or Irritation 1317-65-3 Calcium Carbonate slightlyPart (Human) Part Damage/Irritation Number(s): 10-347 B The substance is slightly irritating to the eyes. Reference: IUCLID Dataset of CAS No. 471-34-1 (2000). Page 36 of 46 Page 8/15 Safety Data Sheet acc. to OSHA HCS Print Date 04/02/2015 Revision Date 04/02/2015 Trade Name: EP11HT BLACK B (Contd. of page 7) 1317-65-3 Calcium Carbonate 1801 Morgan Street SDS Number: 133B Corrosion/Irritation moderately (-) Rockford, IL 61102 Date:07/24/2015 The substance is moderately irritating based on the PH = 9.5 with concentration of 50g/L Revision of water at 20C. Phone: (815) 968-9661 Supersedes Date: 07/16/2012 moderately (rabbit) (Draize test) Fax: (815) 968-9731 500 mg/24h, the pure substance shows no irritating effect, however, the impurities or degradation products may lead to irritant effects on the sweating skin due to alkalinity. www.gcelectronics.com Reference: IUCLID dataset of CAS No. 471-34-1 (2000). SAFETY DATA SHEET 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Corrosion/Irritation Non-irritating species: n/a) (Primary irritation index=0) Standard 29 CFR 1910.1200 Complies with(Test OSHA Hazard Communication mildly irritating (rabbit) (Read across from CAS 63148-62-9) No test detail available; for safety reasons, the substance was classified as mildly irritating (Category 3) to rabbit skin. Reference: HSNO CCID (2010). · Potential Health Effect(s): Causes skin irritation. In contact with skin, may cause: SECTIONredness 11. TOXICOLOGICAL INFORMATION (CONTINUED) and pain · Eye Serious Damage or Irritation Product Name: EPOXY GLUE, PART B 1317-65-3 Calcium Carbonate Damage/Irritation slightly (Human) The substance is slightly irritating to the eyes. Reference: IUCLID Dataset of CAS No. 471-34-1 (2000). not irritating (rabbit) No toxic effect when applied to surface of rabbit eyes Reference: ACToR of CAS No. 471-34-1 (2010). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Damage/Irritation slightly irrit. (Human) (Read across from CAS 63148-62-9) non-irritating (Primary irritation index=0) Transient ocular irritation was observed in humans, rabbits, dogs, and monkeys after injection of the substance to their eye bodies. However, those effects can be seen as negligible based on regular use of the substance. When applying lower viscosity substance-oil mixture to human and rabbit eyes, there was no cornea injury, but a delay of healing of the existed corneal erosion observed. For safety reasons, the substance was classified as a slight eye irritant (Category 2B). Reference: ACToR (2011) and Cabot (M)SDS (2012). · Potential Health Effect(s): Causes serious eye irritation. In contact with eye, may cause: redness and pain · Respiratory or Skin Sensitization 1317-65-3 Calcium Carbonate Sensitization Skin (-) No data available. Respiratory (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Sensitization Skin (No data available) Primary irritation index=0 Non-irritating. Cabot MSDS (2012) Respiratory (No data available) · Potential Health Effect(s): No relevant information for respiratory sensitization; classification is not possible. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. (Contd. on page 9) US Part Number(s): 10-347 Part B Page 37 of 46 1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET Safety Data Sheet Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Page 9/15 acc. to OSHA HCS Print Date 04/02/2015 Product Name: EPOXY GLUE, PART B Revision Date 04/02/2015 Trade Name: EP11HT BLACK B SECTION 11. TOXICOLOGICAL INFORMATION (CONTINUED) · Germ (Contd. of page 8) Cell Mutagenicity 1317-65-3 Calcium Carbonate Mutagenicity negative (-) The pure substance is not listed as a carcinogen by NTP, IARC or OSHA. Reference: Imerys (M)SDS (2008). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Mutagenicity negative (Chinese Hamster) (In Vitro (AMES Test)) negative (Chinese Hamster) (In Vitro (Chromosomal aberration in ovary cells)) Reference: Cabot (M)SDS (2012). · Potential Health Effect(s): No further relevant information; classification is not possible. · Carcinogenicity 1317-65-3 Calcium Carbonate Carcinogenicity negative (salmonella typhimurium) (Preincubation) In Vitro - Negative with and without metabolic activation. Reference: NLM TOXNET of CAS No. 471-34-1 (2010). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Carcinogenicity (Test species: n/a) (Not listed by IARC, NTP, OSHA or ACGIH) · Potential Health Effect(s): Not a known Carcinogen. · Reproductive Toxicity 1317-65-3 Calcium Carbonate Reproductive Toxi. (rat) Up to 1.25% diet of the substance for 6 weeks prior to mating and during gestation and found no adverse effects. Reference: ACToR of CAS No. 471-34-1 (2010). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Reproductive Toxi. (No data available) · Potential Health Effect(s): No further relevant information; classification is not possible. · Specific Target Organ Toxicity - Single Exposure 1317-65-3 Calcium Carbonate STOT-Single (Human) Inhalation 0.005 mg/L for 3 hours: target organs - systemic toxicity May affect nasal function and cause nasal symptoms. Ingested up to 15g of the substance: target organs - systemic toxicity Symptoms included: fatigue, anorexia, nausea and vomiting, an elevated blood pressure, hemoconcentration, leukocytosis, metabolic alkalosis, elevated body weight and hypokalemia. Reference: ACToR of CAS No. 471-34-1 (2010). (rat) Exposed to 0.0812 mg/L for 90 minutes/ after 21 hr. No effect on lung weight, macrophage concentration, or histopathology. Reference: ACToR of CAS No. 471-34-1 (2010). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica (No data available) Part STOT-Single Number(s):(dynamic) 10-347 Part B · Potential Health Effect(s): No further relevant information; classification is not possible. Page 38 of 46 Potential Health Effect(s): Not a known Carcinogen. Toxicity · Reproductive 1317-65-3 Calcium Carbonate Reproductive Toxi. (rat) Up to 1.25% diet of the substance for 6 weeks prior to mating and during gestation and found no adverse effects. Reference: ACToR of CAS No. 471-34-1 (2010). 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Reproductive Toxi. (No data available) · Potential Health Effect(s): No further relevant information; classification is not possible. 1801 ·Morgan Street Specific Target Organ Toxicity - Single Exposure Rockford, 61102 1317-65-3IL Calcium Carbonate STOT-Single (Human) Phone: (815) 968-9661 Inhalation 0.005 mg/L for 3 hours: Fax: (815) 968-9731 target organs - systemic toxicity May affect nasal function and cause nasal symptoms. www.gcelectronics.com SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 Ingested up to 15g of the substance: target organs - systemic toxicity Symptoms included: fatigue, anorexia, nausea and vomiting, an elevated blood pressure, hemoconcentration, Complies with OSHA Hazard Standard 29 CFR 1910.1200 leukocytosis, metabolic alkalosis,Communication elevated body weight and hypokalemia. Reference: ACToR of CAS No. 471-34-1 (2010). SAFETY DATA SHEET Product Name: EPOXY GLUE, PART B (rat) Exposed to 0.0812 mg/L for 90 minutes/ after 21 hr. No effect on lung weight, macrophage concentration, or histopathology. Safety Safety Data Data Sheet Sheet Page 10/15 Page 10/15 Reference: ACToR of CAS No. 471-34-1 (2010). acc. OSHA SECTION 11. TOXICOLOGICAL INFORMATION acc. to to(CONTINUED) OSHA HCS HCS Print 67762-90-7 Date 04/02/2015 Revision Date 04/02/2015 Siloxanes and Silicones, di-Me, reaction products with silica Print Date 04/02/2015 Revision Date 04/02/2015 STOT-Single (dynamic) (No data available) Trade Name: EP11HT BLACK B Trade Name: EP11HTHealth BLACK Effect(s): B · Potential No further relevant information; classification is not possible. (Contd. of page 9) Some target organs may be exclusive due to low concentration of the hazardous component(s). (Contd. of page 9) (Contd. on page 10) · Specific Target Organ Toxicity - Repeated Exposure · Specific Target Organ Toxicity - Repeated Exposure US 1317-65-3 Calcium Carbonate 1317-65-3 Calcium Carbonate STOT-Repeated (Human) STOT-Repeated Target (Human) organs - Systemic toxicity Target organs - Systemic toxicity of hypercalcemia with alkalosis, calcinosis, azotemia, renal dysfunction, GI hemorrhage Symptoms: Infrequent instances Symptoms: instances hypercalcemia alkalosis, calcinosis, azotemia, and vomitingInfrequent or aspiration throughofnasogastric tubewith seem to predispose to the disorder.renal dysfunction, GI hemorrhage and vomiting or aspiration nasogastric tube seem to predispose to the disorder. Reference: ACToR of CASthrough No. 471-34-1. Reference: ACToR of CAS No. 471-34-1. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica STOT-Repeated (No data available) STOT-Repeated (No data available) · Potential Health Effect(s): No further relevant information; classification is not possible. · Potential Health Effect(s): No further relevant information; classification is not possible. · Aspiration Hazard · Aspiration Hazard 1317-65-3 Calcium Carbonate 1317-65-3 Calcium Carbonate Aspiration Hazard (-) Aspiration Hazard No (-) data available. No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Aspiration Hazard (No data available) Aspiration Hazard (No data available) · Potential Health Effect(s): No relevant information; classification is not possible. · Potential Health Effect(s): No relevant information; classification is not possible. · Additional Information No further relevant information. · Additional Information No further relevant information. * * 12 information SECTION 12. ECOLOGICAL 12 Ecological Ecological informationINFORMATION · Aquatic Environmental Toxicity · Aquatic Environmental Toxicity 1317-65-3 Calcium Carbonate 1317-65-3 Calcium Carbonate Algae Toxicity (static) 56000 mg/l (Gambusia affinis (western mosquitofish)) (LC50 (24 - 96 hrs)) Algae Toxicity (static) 56000 mg/l ACToR (Gambusia affinis mosquitofish)) (LC50 (24 - 96 hrs)) Reference: of CAS No.(western 471-34-1 (2010). Reference: ACToR of CAS No. 471-34-1 (2010). (Poecilia Latipinna (Sailfin molly)) (Poecilia Latipinna Exposure period: 96(Sailfin hrs. molly)) Exposure period: 96 NOEC > 200 mg/L hrs. NOEC > 200 mg/L Dataset of CAS No. 471-34-1 (2000). Reference: IUCLID Reference: IUCLID Dataset of CAS No. 471-34-1 (2000). Crustacean Toxicity Crustacean Toxicity (-) (-) substance is not toxic to aquatic organisms. The The substance is notDSL toxicoftoCAS aquatic organisms. Reference: Canada No. 471-34-1 (2007). Reference: Canada DSL of CAS No. 471-34-1 (2007). Fish Toxicity Fish Toxicity (-) (-) substance is not toxic to aquatic organisms. The The substance is notDSL toxicoftoCAS aquatic organisms. Reference: Canada No. 471-34-1 (2007). Reference: Canada DSL of CAS No. 471-34-1 (2007). Part Micro-organism Number(s): 10-347 toxi (-)Part B Micro-organism toxi The (-) substance is not toxic to aquatic organisms. The substance is not toxic to aquatic organisms. Reference: Canada DSL of CAS No. 471-34-1 (2007). Reference: Canada DSL of CAS No. 471-34-1 (2007). Page 39 of 46 · Aspiration Hazard 1317-65-3 Calcium Carbonate Aspiration Hazard (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Aspiration Hazard (No data available) · Potential Health Effect(s): No relevant information; classification is not possible. · Additional * Information No further relevant information. 1801 Morgan Street Rockford, IL 61102 12 Ecological information Phone: (815) 968-9661 · Aquatic Environmental Toxicity Fax: (815) 968-9731 1317-65-3 Calcium Carbonate www.gcelectronics.com Algae Toxicity (static) 56000 mg/l (Gambusia affinis (western mosquitofish)) (LC50 (24 - 96 hrs)) SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 Reference: ACToR of CAS No. 471-34-1 (2010). SAFETY DATA SHEET (Poecilia Latipinna (Sailfin molly)) Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Exposure period: 96 hrs. NOEC > 200 mg/L Reference: IUCLID Dataset of CAS No. 471-34-1 (2000). Product Name: EPOXY GLUE, PART B Crustacean Toxicity SECTION 12. (-) The substance is not toxic to aquatic organisms. Reference: Canada DSL of CAS No.(CONTINUED) 471-34-1 (2007). ECOLOGICAL INFORMATION Fish Toxicity (-) The substance is not toxic to aquatic organisms. Reference: Canada DSL of CAS No. 471-34-1 (2007). Micro-organism toxi (-) The substance is not toxic to aquatic organisms. Reference: Canada DSL of CAS No. 471-34-1 (2007). Safety Data Sheet Page 11/15 to OSHA HCS 67762-90-7 Siloxanes and Silicones, di-Me, reactionacc. products with silica Print Algae Date 04/02/2015 Revision Date 04/02/2015 Toxicity > 10000 mg/l (Scenedesmus subspicatus) (ErC50 (24 hrs), OECD 201) Crustacean Toxicity > 1000 mg/l (Daphnia magna (water flea)) (EC50 (24 hrs), OECD 202) Trade Name: EP11HT BLACK B Fish Toxicity > 10000 mg/l (Brachydanio rerio (Zebra fish)) (LC50 (96 hrs), OECD 203) Reference: Cabot (M)SDS (2012). · Aquatic Environmental Toxicity Assessment: Very toxic to aquatic life with long lasting effects. (Contd. of page 10) (Contd. on page 11) · Degradability and Stability 1317-65-3 Calcium Carbonate Biodegradation (-) The test is not applicable since this substance is inorganic and not soluble in water. Reference: IUCLID Dataset of CAS No. 471-34-1 (2000). US Photodegradation positive cm³/molecule-sec (-) The substance is persistent. Reference: ACToR of CAS No. 471-34-1 (2010). Stability in water (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Biodegradation (No data available) Persistence (Test species: n/a) (The substance is not persistent) Reference: Canada DSL (2007). Photodegradation (No data available) Stability in water (No data available) · Bioaccumulation and Distribution 1317-65-3 Calcium Carbonate BCF (-) No data available. Environment fate (-) No data available. Koc (-) No data available. LogPow (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Part BCF Number(s): 10-347 Part B (No data available) (The substance is not bioaccumulative) Reference: Canada DSL CCR (2011). Koc (No data available) Page 40 of 46 Photodegradation positive cm³/molecule-sec (-) The substance is persistent. Reference: ACToR of CAS No. 471-34-1 (2010). Stability in water (-) No data available. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Biodegradation (No data available) Persistence (Test species: n/a) (The substance is not persistent) Reference: Canada DSL (2007). 1801 Morgan Street Photodegradation (No data available) Rockford, IL 61102 Stability in water (No data available) Phone: (815) 968-9661 · Bioaccumulation and Distribution Fax: (815) 968-9731 1317-65-3 Calcium Carbonate www.gcelectronics.com BCF (-) No data available. Environment fate (-) No data available. Complies with OSHA Koc (-) LogPow (-) No data available. SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET Hazard Communication Standard 29 CFR 1910.1200 No data available. GLUE, PART B Product Name: EPOXY SECTION 12. ECOLOGICAL INFORMATION (CONTINUED) 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica BCF (No data available) (The substance is not bioaccumulative) Reference: Canada DSL CCR (2011). Koc (No data available) LogPow (No data available) · Degradability and Bioaccumulation Assessment: No further relevant information; assessment is not possible. · Additional * Information No further relevant information. 13 Disposal considerations SECTION 13. DISPOSAL CONSIDERATIONS Page 12/15 · Hazardous Waste List Page 12/15 · Description: The product has not been evaluated for its hazardsacc. whento disposed as aHCS waste by RCRA. OSHA to OSHA HCS waste based on the Hazard Identification in Section 2. However, it is necessary to contain and dispose ofacc. the product as a hazardous Print Date 04/02/2015 Revision Date 04/02/2015 · Waste Print Date 04/02/2015 Revision Date 04/02/2015 Treatment Recommendation: Trade Name: EP11HT BLACK Generation of waste shouldBbe avoided or minimized wherever possible. Trade Name: BLACK B quantities, is neither allowed to be poured down drains, sewage system or waterways; nor disposed with ChemicalEP11HT waste, even small household garbage. (Contd. of page 11) Dispose of contents/containers in accordance with local, regional, national, and international regulations. (Contd.on of page (Contd. page 11) 12) · Unused and Uncontaminated Packagings US · Unused and Uncontaminated Packagings · Recommendation Dispose of according to your local waste regulations. · Recommendation Dispose of according to your local waste regulations. Safety Data Sheet Safety Data Sheet * * 14 Transport information SECTION 14. TRANSPORT 14 Transport informationINFORMATION · UN-Number · UN-Number · DOT, ADR, IMDG, IATA · DOT, ADR, IMDG, IATA · UN Proper Shipping Name · UN Proper Shipping · DOT, ADR, IMDG, Name IATA · DOT, ADR, IMDG, IATA · Transport hazard class(es) · Transport hazard class(es) · DOT, IMDG, IATA · DOT, IMDG, IATA · Class ·· Class Label · Label · ADR · ADR UN3082 UN3082 Environmentally hazardous substances, liquid, n.o.s. (Polyamide Resin) Environmentally hazardous substances, liquid, n.o.s. (Polyamide Resin) 9 Miscellaneous dangerous substances and articles 9 9 Miscellaneous dangerous substances and articles 9 Part Number(s): 10-347 Part B · Class 9 (M6) Miscellaneous dangerous substances and articles 9 ·· Class Label 9 (M6) Miscellaneous dangerous substances and articles Page 41 of 46 Print Date 04/02/2015 Revision Date 04/02/2015 Trade Name: EP11HT BLACK B (Contd. of page 11) · Unused and Uncontaminated Packagings · Recommendation Dispose of according to your local waste regulations. * 1801 Morgan Street 14 Transport information Rockford, IL 61102 · UN-Number Phone: (815) 968-9661 · DOT, ADR, IMDG, IATA Fax: (815) 968-9731 · UN Proper Shipping Name www.gcelectronics.com · DOT, ADR, IMDG, IATA · Transport · DOT, hazard class(es) SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 UN3082 Environmentally hazardous substances, liquid, n.o.s. (Polyamide Resin) SAFETY DATA SHEET IMDG, IATA with OSHA Hazard Communication Standard 29 CFR 1910.1200 Complies Product Name: EPOXY GLUE, PART B · Class 9 Miscellaneous dangerous substances and articles SECTION 14. TRANSPORT INFORMATION (CONTINUED) · Label 9 · ADR · Class · Label · Packing · DOT, 9 (M6) Miscellaneous dangerous substances and articles 9 group ADR, IMDG, IATA · Environmental Hazards: · Marine Pollutant: · Special · Special Marking (ADR): Marking (IATA): · Special Precautions: · Danger Code (Kemler): · EMS Number: III Yes Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree) Warning: Miscellaneous dangerous substances and articles 90 F-A,S-F · Transport in Bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional · DOT · Quantity Information: limitations Print Date 04/02/2015 · Remarks: Trade·Name: ADR EP11HT BLACK B · Excepted quantities (EQ) · IMDG · Limited quantities (LQ) · Excepted quantities (EQ) · UN * "Model Regulation": Safety Data Sheet Page 13/15 On passenger acc. to OSHA HCSaircraft/rail: No limit On cargo aircraft only: No limit Special marking with the symbol (fish and tree). Revision Date 04/02/2015 Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml (Contd. of page 12) (Contd. on page 13) 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml US UN3082, Environmentally hazardous substances, liquid, n.o.s. (Polyamide Resin), 9, III 15 Regulatory information · USA Regulation Lists · SARA10-347 (Superfund Amendments and Reauthorization Number(s): Part B Part · Section 302 (Extremely Hazardous Substances) None of the ingredients is listed. Act of 1986) Page 42 of 46 Page 13/15 Safety Data Sheet acc. to OSHA HCS Print Date 04/02/2015 Revision Date 04/02/2015 1801 Morgan Street Trade Name: EP11HT BLACK B Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 · IMDG www.gcelectronics.com · Limited quantities (LQ) quantities (EQ) · Excepted · UN SDS Number: 133B Revision Date:07/24/2015 Supersedes(Contd. Date:of 07/16/2012 page 12) 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer29 packaging: ml Communication Standard CFR 1000 1910.1200 SAFETY DATA SHEET Complies with OSHA Hazard "Model Regulation": UN3082, Environmentally hazardous substances, liquid, n.o.s. (Polyamide Resin), 9, III Product Name: EPOXY GLUE, PART B * 15 Regulatory informationINFORMATION SECTION 15. REGULATORY · USA Regulation Lists (Superfund Amendments and Reauthorization Act of 1986) · Section 302 (Extremely Hazardous Substances) · SARA None of the ingredients is listed. · Section 313 (Toxics Release Inventory (TRI) reporting) None of the ingredients is listed. · Section 311/312 (Hazardous Chemical Inventory Reporting) 1317-65-3 Calcium Carbonate 112-24-3 Triethylenetetramine · Hazard Abbreviations for SARA A - Acute Health Hazard C - Chronic Health Hazard F - Fire Hazard R - Reactive Hazard S - Sudden Release of Pressure Hazard · TSCA 1317-65-3 67762-90-7 14808-60-7 112-24-3 A, C 30-40% A 0-<0.1% 311/312 (Toxic Substances Control Act) Calcium Carbonate Siloxanes and Silicones, di-Me, reaction products with silica Quartz Triethylenetetramine · Proposition 65 · Chemicals Known to Cause Cancer This product may also contain extremely small amounts of one or more naturally occurring materials known to the State of California to cause cancer, birth defects or other reproductive harm. 14808-60-7 Quartz · Chemicals Known to Cause Reproductive Toxicity for Females · Chemicals Known to Cause Reproductive Toxicity for Males · Chemicals Known to Cause Developmental Toxicity None of the ingredients is listed. None of the ingredients is listed. None of the ingredients is listed. · Carcinogenic · EPA Categories (Environmental Protection Agency) None of the ingredients is listed. · IARC 14808-60-7 Quartz (International Agency for Research on Cancer) 1 (Contd. on page 14) US Part Number(s): 10-347 Part B Page 43 of 46 1801 Morgan Street Rockford, IL 61102 Phone: (815) 968-9661 Fax: (815) 968-9731 www.gcelectronics.com SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET Safety Data Sheet Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Page 14/15 acc. to OSHA HCS Print Date 04/02/2015 Product Name: EPOXY GLUE, PART B Revision Date 04/02/2015 Trade Name: EP11HT BLACK B SECTION 15. REGULATORY INFORMATION · NTP (National Toxicology Program) · TLV (Threshold Limit Value Established by ACGIH) 14808-60-7 Quartz 14808-60-7 Quartz · NIOSH-Ca 14808-60-7 Quartz · International K A2 (National Institute for Occupational Safety and Health) · Canadian Regulation Lists Domestic Substance Listings: · Canadian Ingredient Disclosure list (limit 0.1%) · Canadian Ingredient Disclosure list (limit 1%) 1317-65-3 67762-90-7 14808-60-7 112-24-3 (Contd. of page 13) Calcium Carbonate Siloxanes and Silicones, di-Me, reaction products with silica Quartz Triethylenetetramine None of the ingredients is listed. 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica · Chinese 1317-65-3 67762-90-7 14808-60-7 112-24-3 Chemical Inventory of Existing Chemical Substances: Calcium Carbonate Siloxanes and Silicones, di-Me, reaction products with silica Quartz Triethylenetetramine · Japanese 1317-65-3 67762-90-7 14808-60-7 112-24-3 · Korean 1317-65-3 67762-90-7 14808-60-7 112-24-3 Existing Chemical Inventory: Calcium Carbonate Siloxanes and Silicones, di-Me, reaction products with silica Quartz Triethylenetetramine · European 1317-65-3 67762-90-7 14808-60-7 112-24-3 Existing and New Chemical Substance List: Calcium Carbonate Siloxanes and Silicones, di-Me, reaction products with silica Quartz Triethylenetetramine Pre-registered substances: Calcium Carbonate Siloxanes and Silicones, di-Me, reaction products with silica Quartz Triethylenetetramine · REACh - Substances of Very High Concern (SVHC) List: None of the ingredients is listed. · Restriction of Hazardous Substances Directive (RoHS) list: Part Number(s): 10-347 Part B None of the ingredients is listed. Page 44 of 46 None of the ingredients is listed. · Canadian Ingredient Disclosure list (limit 1%) 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica · Chinese Chemical Inventory of Existing Chemical 1317-65-3 67762-90-7 14808-60-7 112-24-3 Calcium Carbonate Siloxanes and Silicones, di-Me, reaction products with silica Quartz Triethylenetetramine Substances: · Japanese Existing and New Chemical Substance List: 1801 Morgan Street 1317-65-3 Calcium Carbonate Rockford, IL 61102 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica Phone: (815) 968-9661 14808-60-7 Quartz 112-24-3 Triethylenetetramine Fax: (815) 968-9731 · Korean Existing Chemical Inventory: www.gcelectronics.com · 1317-65-3 67762-90-7 14808-60-7 112-24-3 Calcium Carbonate Siloxanes and Silicones, di-Me, reaction products with silica Quartz Complies with OSHA Hazard Communication Triethylenetetramine SDS Number: 133B Revision Date:07/24/2015 Supersedes Date: 07/16/2012 SAFETY DATA SHEET · European Standard 29 CFR 1910.1200 Pre-registered substances: Product EPOXY GLUE, PART B 1317-65-3Name: Calcium Carbonate 67762-90-7 Siloxanes and Silicones, di-Me, reaction products with silica 14808-60-7 Quartz SECTION 15.Triethylenetetramine REGULATORY INFORMATION 112-24-3 · REACh - Substances of Very High Concern (SVHC) List: None of the ingredients is listed. · Restriction of Hazardous None of the ingredients is listed. * Print Date 04/02/2015 Substances Directive (RoHS) list: 16 Other 16. information SECTION OTHER INFORMATION Safety Data Sheet Page 15/15 acc. to OSHA HCS Revision Date 04/02/2015 Trade Name: EP11HT BLACK B This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. (Contd. of page 14) Issuing (M)SDS: Product Safety Department ·· Department Contact: [email protected] (Contd. on page 15) · Abbreviations and acronyms: US US ACGIH: American Conference of Governmental Industrial Hygienists ADR: European Agreement Concerning the International Carriage of Dangerous Goods by Road CAS: Chemical Abstracts Service (division of the American Chemical Society) DOT: US Department of Transportation HMIS: US National Paint & Coatings Association (NPCA) Hazardous Materials Identification System IARC: International Agency for Research on Cancer developed by United Nations World Health Organisation (WHO) ICAO-TI: Technical Instructions (TI) by the International Civil Aviation Organization (ICAO) IMDG: International Maritime Dangerous Goods; the principal international rules for International Carriage of Dangerous Goods by SEA under the Recommendations on the Transport of Dangerous Goods by United Nations (RTDG) LC50/LD50: Lethal Concentration/Dose, 50 percent N/a: Not available or Not applicable NFPA: US National Fire Protection Association NIOSH: US National Institute of Occupational Safety and Health OSHA: US Occupational Safety and Health Administration P: Marine Pollutant RCRA: Resource Conservation and Recovery Act (USA) REACh: EU Registry, Evaluation and Authorisation of Chemicals SARA: US Superfund Amendments and Reauthorization Act TEEL: Temporary Emergency Exposure Limit developed by US Subcommittee on Consequence Assessment and Protective Actions (SCAPA) of US Department of Energy (DOE) TSCA: US Toxic Substance Control Act ECHA: European Chemicals Agency’s Dissemination portal with information on chemical substances registered under REACH IUCLID: EU REACh International Uniform Chemical Information Database NLM TOXNET: US National Library of Medicine Toxicology Data Network ACToR: US EPA Aggregated Computational Toxicology Resource BCF: Bioconcentration Factor CCRIS: US NLM TOXNET Chemical Carcinogenesis Research Information System CHRIP: Japan NITE Information on Biodegradation and Bioconcentration of the Existing Chemical Substances in the Chemical Risk Information Platform DSL: Canada Domestic Substance List ESIS: European Chemical Substances Information System HSDB: US NLM TOXNET Hazardous Substances Databank HSNO CCID: New Zealand Hazardous Substances and New Organisms Chemical Classification Information Database IATA-DGR: Dangerous Goods Regulations (DGR) by the International Air Transport Association (IATA) ICSC: International Chemical Safety Cards Koc: Partition coefficient, soil Organic Carbon to water NITE: National Institute of Technology and Evaluation, Japan OECD: Organisation for Economic Co-operation and Development RID: the Regulations Concerning the International Carriage of Dangerous Goods by Rail; published by the Central Office for 45 Part Number(s): 10-347 Part B Page International Carriage by Rail (OTIF) RTDG: the Recommendations on the Transport of Dangerous Goods by United Nations (UN) RTECS: US Registry of Toxic Effects of Chemical Substances of 46 IARC: International Agency for Research on Cancer developed by United Nations World Health Organisation (WHO) ICAO-TI: Technical Instructions (TI) by the International Civil Aviation Organization (ICAO) IMDG: International Maritime Dangerous Goods; the principal international rules for International Carriage of Dangerous Goods by SEA under the Recommendations on the Transport of Dangerous Goods by United Nations (RTDG) LC50/LD50: Lethal Concentration/Dose, 50 percent N/a: Not available or Not applicable NFPA: US National Fire Protection Association NIOSH: US National Institute of Occupational Safety and Health OSHA: US Occupational Safety and Health Administration P: Marine Pollutant RCRA: Resource Conservation and Recovery Act (USA) REACh: EUStreet Registry, Evaluation and Authorisation of Chemicals 1801 Morgan SDS Number: 133B SARA: US Superfund Amendments and Reauthorization Act Rockford, 61102 Emergency Exposure Limit developed by US Subcommittee on Consequence Assessment TEEL:IL Temporary and Protective Actions Revision Date:07/24/2015 of US Department of Energy (DOE) Phone:(SCAPA) (815) 968-9661 Supersedes Date: 07/16/2012 TSCA: US Toxic Substance Control Act European Chemicals Agency’s Dissemination portal with information on chemical substances registered under REACH Fax: ECHA: (815) 968-9731 IUCLID: EU REACh International Uniform Chemical Information Database www.gcelectronics.com NLM TOXNET: US National Library of Medicine Toxicology Data Network ACToR: US EPA Aggregated Computational Toxicology Resource BCF: Bioconcentration Factor CCRIS: US NLM TOXNET Chemical Carcinogenesis Research Information System CHRIP: Japan NITE Information on Biodegradation and Bioconcentration ofStandard the Existing Chemical Substances in the Chemical Risk Complies with OSHA Hazard Communication 29 CFR 1910.1200 Information Platform DSL: Canada Domestic Substance List ESIS: European Chemical Substances Information System HSDB: US NLM TOXNET Hazardous Substances Databank HSNO CCID: New Zealand Hazardous Substances and New Organisms Chemical Classification Information Database IATA-DGR: Dangerous Goods Regulations (DGR) by the International Air Transport Association (IATA) ICSC:16. International Chemical Safety Cards (CONTINUED) SECTION OTHER INFORMATION Koc: Partition coefficient, soil Organic Carbon to water NITE: National Institute of Technology and Evaluation, Japan OECD: Organisation for Economic Co-operation and Development RID: the Regulations Concerning the International Carriage of Dangerous Goods by Rail; published by the Central Office for International Carriage by Rail (OTIF) RTDG: the Recommendations on the Transport of Dangerous Goods by United Nations (UN) RTECS: US Registry of Toxic Effects of Chemical Substances SIDS: OECD existing chemicals Screening Information Data Sets SVHC: EU ECHA Substance of Very High Concern TOXLINE: US NLM bibliographic database search system · Date of preparation / last revision 04/02/2015 / 4 SAFETY DATA SHEET Product Name: EPOXY GLUE, PART B US GC Electronics believes that the information contained herein is accurate and reliable as of the date of this material safety data sheet, but no representation guarantee or warranty, express or implied, is made as to the accuracy, reliability or completeness of the information. Persons receiving information are encouraged to make their own determination as to the information’s suitability and completeness for their particular application. NO INFORMATION CONTAINED HEREIN CONSTITUTES A PRODUCT WARRANTY OF ANY KIND, WHETHER EXPRESS OR IMPLIED; AND ALL IMPLIED WARRANTIES OF MERCHANT ABILITY AND OF FITNESS FOR A PARTICULAR PURPOSE ARE HEREBY DISCLAIMED BY GC ELECTRONICS. Part Number(s): 10-347 Part B Page 46 of 46