BrArvK

BrArvK
oQiqifiHoro oroHeHTa Ha Ancepraqiro JlenuqrKoro Bo.uoAuMl{pa O.nerccifioBrrqa
<<Cuo.uynr{ cr{crerv R-M-C (rt = P3M, lltf = 3d-e"uervreHT Ta ix ri4puArr: cLIHTe3, crpyKTypa
Ta BJractunocril>,
roAaHy Ha:4o6yrrr HayKoBoro cryrreHfl KauApr[ara xiNri.rHLIX HayK
si cneqianrnocri 02.00.01 - ueopraHi.IHa xirvriq
Po6oru, [pprcBflrreHi nus-reHHro cKJraAHr{x Heopraui.rHr,rx cucreM, IrIo cKnaAarorrc.s is
KoMrroHenrin, cyrreBo eiA\diHHr{x 3a csoilar..r BJracrltBocr.flMll, 3aBx{AI,I BIIKJII4KaTIz ui4nulqeny
yBary cepeA HayKoBrlin, ocrilmH ixni pesynrrarur Aarorb 6araro qinnoi in(popvrauii sx e
Qyn4anreHTaJrbHoMy acrrerri, rar i 3 TorrKH 3opy [paKTI4rIHoro BI{KopI,IcraHHs. OAnrarr,r ig
uaupxnariu rrorrryKy HoBr{x rr,rarepialin is [porHo3oBaHpIMpI BJIacrI{BocrqMI4, a raKo}K
qinecnptrMoBaHoro BrrnrlBy Ha xapaKTepI,IcrI{KI{ Bx{e icHyro.rux rraarepialin e
eKclepnuesralsui AocniAxeHHs 6araroxoMrroHeHTHl{x cucreM Ha npeAMer yrBopeHHfl
HoBr4x clonyK Ta BcraHoBJreHHfl B3a€Mo3n'rsr<y ruiN ix cKnaAoM, 6yAosoro ra BJIacrLIBocr.flMH.
Touy reMa Araceprarlifinoi po6orz JIeeHrIrKoro BoroApIMLIpa OnercifioBllqa, rpllcBsr{eHa
KoMrrJreKcHoMy BrrBrreHuro sgaeNaoAii pi4xicno3eMeJlbHl{x ra nepexi4Hux Merarie ig
ByrnerleM Ta BoAHeM e, 6esueperrHo, aKTyanbHoro. Po6ora BI{KoHaHa B paMKax
4epx6roANernoi HayKoBo-AocliAnoi TeMaTLIKLI MOH Vrpainu (HAP ,,BrrLIB 6opy ra
rap6oHy Ha crpyKrypy, BJracrr{Bocri cnrasie Ha ocHosi P3E, d-etev.enrin ra ix rigpla4in"), u
TaKoxc rpoeKTy yrpaincrKo-aBcrpiftcucoi uixypx4oeoi rporpaMld HayKoBo-rexHi'ruoro
cninpo6irnuqrea sa reMoro ,,Iurepuerani.rHi crronyKpl noei HaArlpoBiAuuxz 3
HerleHTpocr{Merpl{rrHoro crpyKTyporo".
lucepranr [ocraBr,rB co6i 3a Mery BcraHoBI{TH 3aKoHoMipuocri yrBopeHHs ra
crpyr<rypui oco6rulnocri cronyK clrcreM R-M-C IIIJItxoM AocliANeHHfl isorepnriqHnx
nepepisin niAnosiAHr,rx AiarpaM craHy, rqo uepe46aualo crlHre3 HoBI{x inrepruerari'rHllx
crroJryK, Br43Haqenns ix Kpr{crarriqnoi crpyKTypu, croco6is yrBopeHHs, KoHllenrpaqifiHl{x ra
reMneparypHrrx MelK icuynauux, a raKoxt ix BoAeHbcop6qifiHllx BJracrllBocrefi. I cnia
3a3HaqI{TIr, rqo is qm\a 3aBAaHHsna eiu ycuiruuo BrlopaBcfl.
B po6ori nueprue no6y.uoBaHo isoreprvriuni nepepisra 4iarpavr craHy 1 1 uorpiftunx
oC
ra Tb-Cr-C, {Tb, Dy}-{Fe, Co' Ni}-C
cr.rcreM Ce-Cr-C, {Gd, Tb, Dy}-Mn-C upra 600
oC, y
.f,Kr4x sHafiAeHo ciru HoBr{x repHapHr{x rap6iain, a raKo)K JloKittrisosaHo
upur 800
cKnaApr rqe 12 Hosux repHapHux cronyx is ueeiAoNanMpr crpyKrypaMl{. Cepe4 oAep}KaHHX
uorpiftuux c[onyK Br.lf,BJreHo ABa HoBLrx crpyKTypHrlx rvrrrkr, Iqo e BaTOMLIM BHecKoM y
Kplrcranoxinairo IMC. CuHregoBaHo 4 Hoei 6inapui cronyKkl Ta yrotlHeHo @parnaenru
4iarpavr craHy rpbox noAnifiru{x clrcrervr Tb-Co, Tb-Fe ra Dy-Ni, xt<i AocliAxyrorbcfl y)Ke
roHaA uincrolirrs. llpone4eHo AocniANesss rap6oHo - Ta ri4poreuoeMHlrtx BJlacrllBocreft
Hrrr3Krir cr4Hre3oBaHrirx cronyK. Anq xea3i6igapuoi cI{creMI{ DyCoC2-DyNiC2 rlpoBeAeHo
KoMrrJreKcHe BrrBrreHHfl crpyKTypHprx ra vrarniruHx BJlacrllBocrefi rpu [epexoAi eia
po3rrl'IHy
$eporuaruirsoro Ao anru(f epouarnirHoro craHy HerlepepBHoro rBepAoro
DyCor-J.{i"Cz. AoclilxeHo BrrJrrlB rpr4poApr KoMnouenriB Ha xapaKrep Sa:onux pinnoBar y
cr.rcreMax R-M-C, I11o rae n4oNrusicm nepeg6auaru Sa:ony uoee4iHry y ue He
AocniAxeHl{x cuopi4HeHllx cplcreMax
25 ,{uceprarlifiHa po6ora Jlenuqrxoro B.O. BI4KnaAeHa Ha 259 cropinrax (is Hrax
rrorl,Ipbox
BllKopzcrauoi
cnucKy
po3Airis,
BI{cHoBKin,
AoAarKr{), i cr<n ataerbcfl. i: ncryuy,
nireparyp u, xrcuit HapaxoBye 3 1 5 nocul a:ab, ra Ao.qarris.
y ncryui o6rpynroBauo aKTyurnbsicrr po6oru, eugHa'reui Mera ra 3aBAaHHq
AocniAxeHgq, rroKa3aHa HayKoBa HoBrr3H a ra npaKTHqHa IlisHicm orpI4MaHI,IX pe3ynrrarin.
y repruoMy po:gi"ui Micrrarucq 1erarlanufi. aHarig lireparypHux AaIJ'|l.X rpo
B3aeMoAiro rolruouenrin y no4ni ft:rtux clrcreMax, uo o6vreNyrorb Aocni4xynani norpifini
clrcreMrr R-M-C, a raKoxr iHQoprvraqir npo siloNai giarpanau craHy ra icuyrovi cuonyKll y
cr{creMax nepexigHrax ra pi4xicno3eMeJrbHprx ereMeHris is Kap6ouonn. Ha ocuoni
Kpnrr.rrrHoro aHanisy nireparypurax AaHrax aBrop po6urr ueo6xilHi y3aranbHeHH.f, Ta
nepe46aueHH-s crocoBuo MoxJrnBoro xapaKrepy Ba€Moaii y vvrlpauux Ans AocliANeHHq
norpifiruax cr.rcrelax R- M-C.
y ApyroMy po:giri AerirJrbHo orucyrorbcr MeroArr rrpkrroryBaHufl spasxin ra
Kourponrc ix Sasonoro ra xiuiqsoro cKnaAy, a raKox{ ocHonni MeroAId, gxi
Br.rKopr{croByBanlrcb Infl AocniANeHHfl Kpr.{cr€rJri.rHoi crpyKrypu croJIyK, ix repvrivnoi
cra6inrsocri, BoAeHbcop6qifiunx, MarHirHHx ra rpaHcrroprHrdx BJracrl4Bocrefi rraarepianin.
!.trs $asonoi ra crpyKrypnoi xapaKreprr3aqii spaxin AprcepraHr BplKopucroByBaB
MeroAr{ peHTreHoSa^:onoro ra peHTreHocrpyKTypHoro ananisy ra eHeproAucnepcifinol
peHrreHincrr<oi crreKTpocr<ouii, a ilnfl. Br4BqeHHr croco6in yreopeHHs IMC ra ix repruiunoi
cra6inrnocri mr4poKo 3acrocoByBaB MeroArir replriunoro ananisy. Cnia ni4:Hauuru, uo
BAurne roeAHaHHfl pienouaHiruux ap6irpaxnux ueroAin AocniAxeHHs uarepialin,
rrpoBeAeHr{x Ha cf{acHoMy HayKoBoMy o6naAuasHi, n roMy .Iplcri y raKI,IX eiAoNdLIx HayKoBLIX
rleHrpax .flK BiAencrrprfi rexni.rHr.rfi yninepcxrer ra @isuKo-MexaHi.r:rtuir. iucrnryr HAH
Vxpainu, pa3oM is Br.rKopr{craHHflM rroryxHr{x KoMr'rorepHlrx nporpaM l.ilfr aHanisy ra
o6po6rn 1a*krx, e naAifisoro rapauriero 4ocronipHocri pe3ynbrarin, orpl{MaHl{x
ALICepTaHToM.
OcHoeHi pesynrrurv Ar.rceprarlifinoi po6oru BHKnaAeHi y por4i"rri 3. Tyr npune4eui
isorepnaiuui nepepisr,r 1 1 uorpifisnx cLIcreM Ce-Cr-C, {Gd, Tb, Dy}-Mn-C, Tb-Cr-C, {Tb,
Dy)-{Fe, Co, Ni}-C ra Kpr4crutJrorpaQivui xapaKrepLIcrI4KLI qiroi HH3KI{ noAsifiHux ra
uorpiftnux iurepnrerari.rHrax crroJryK, cprHTe3oBaHI{x aBTopoM. Cnia niAuiruru Hane}KHy
npucriulunicm 1r4cepraHTa y nusHa.reHHi Sasonoro ra xirrai.{Horo cKnaAy cIlHTe3oBaHLIX
Hr.rM crronyK. Kpinr rpalrauifiuoro peurreHo$a^:onoro aH€ulisy, nin rrl4poKo BrlKopucroBye
MeroA EAPC, ni4rneppreHHflM qoro e Sororpa$ii eiAnosiAHl{x rlrJli$in rop.f,A is 4auunau
xirvriquoro cKJraAy ni4uoniAnprx $as. [ns ycix AocniAxeHl{x Kpncraniqsux crpyKryp HoBnx
rap6iain nepexi4Hlrx ra pi4r<icllo3eMeJrbuprx Mer€ulin, a raKox Ae.aKI4x ri4pIa4in Ha ix ouroni,
rrpr4BoAflTbcr yrorrHeni sHa.reHH.fl aroMHr.rx uapauerpin, uixarovtrrax eillareft, a raKo)K
rpa$i.rui upoexuii eiAuoeiAHux crpyKryp ra KoopAl,IHauifiuux MHororpaHuulcie aroNaie.
Bi4pagno, uo xpina AeraJrbHr.rx crpyKTypHr,rx AocniAxeHb, aBTop raKoxt [poBoAI'ITb
AocniANeHHs reprraiunoi cra6ilrsocri ra reMreparypHr{x Me)K icuynauufl HLI3KI{ uoAeifiHlax
crronyK pi4ricHo3eMeJrbHkrx ra uepexigHrax Meranis. B pos4ini rarox HaBeAeHi pesylrrarkr
Br.rBqeHHq BoAeHbcop6qifinnx ra rraarnirnux BJracrr{Bocrefi AeIKLIX cpIHTe3oBaHI{x
vrarepianin.
Poslir cynpoBoA)Kyerbcq rrr4creHHvrMkr ra6ila.rHr4Mtr [artkrMkr ra rpa$iuHkrMpr
inrocrpaqixuu, xoqa Anfl 3pfrHocri, Aesxi vrarepianl{ Mo)KHa 6yno 6 nunecu4 y AoAarKH.
B posairi 4 <<OdronopeHHfl pe3yJrbraris eKcnepuMeHTy)> aBrop auanisye
oco6manocri yrBopeHnr 6inapuprx i TepHapHHX crroJlyK B AocniAxeHllx cucreMax R-M-C,
KoHqeHrpaUifiui i reuneparypui vreNi ix icuynauHx, Ha ocuosi rroro o6rpyuroByrorbcq
onruua6si yMoBr.r craHre3y spa:nin. llpono4Hrbcfl uopinHr rstrufi, aHarig AocniANeHI4x
cr.rcreM rraix co6oro, a raKolr is cuopigneHrlMlr cr{creMaMll. 3Ha.IHa yBara npr'I4inxerbct
Kprrcrarroxinriunouy aHanisy crpyKrypHr.rx runin HoBpIx rap6iain pi4xicno3eMeJIbHLIX Ta
uepexi4uux ueralin, a raKo)K ik B3aeMo3s'.sgKis is iuuruupt crpyKTypHI4MH TI4TIaMLI
inrepruerari.rHl,Ix c[onyK.
Bci ocnosHi rrorroxeHHfl Aprceprarlii ui4cyrraoByrorbcs y <<BucnoBKax)>, spo6lenux
[ucepraHToM.
OAuar
qr Ayxe qixana i
rreBHr{x ne.uodris.
ao6pe
BrlKoHaH
a [ucepraqifina po6ora He nos6anreHa
1. [ucepraqis ilepeBaHTaxeHa AeflKprMlr, H4 iuifi uorrrflp' ApyropsAHHMIa ra6rH.IHLrMr4 Ta
rpa$iuunMr raHkrvttr, flKi Aerrlo yrpyAHrororb iT qr{TaHH{. Tax, ra6nvui ig AeruuqMl4
yrorrHeHHr Kpr{crariqHux crpyKryp Mox{Ha 6yno 6 arpyuyBarr4 i nusecrv y [o!.arKkr, a
so6paxeuua crpyKTyp ra KoopAr{Harlifisux MHororpaHHut<is Hrr3KIrt go6pe si.{oluux
crpyKrypHr4x rnrie ngarari yuycrurH. Haroivricrb pr4cysru gi cKnaAaMkr cvHTe3oBaHI{x
crroJryK, HaBeAeHi y lolarKax, Aoqinruo 6yno 6 cpricruru is isorepvriqHlaMpl nepepisanau
4iarpau craHy ni4noni4Hr4x cr{creM.
2. MicqflMrr crrocrepiraerncs [eBHa ueniAnosiAHicrr naiN rexcroM ra ra6nuqHI{MLI AaHI,IMI4
3orpenra, Hd c. 57 ra 59 roBoplrrbc.fl, rrlo ,,ni4rnepAlreHHflM o6nacri roMoreHuocri Sas
TbCr-*, GdzCr-* ra GdCr-* e suina rapaMerpin eJreMeHrapHLIX xonaipox", xoya n Ta6. 3.1
rrpr,rBeAeui sHa.reHH{ rrapatvrerpin xonaipxn Jrr{rrre Anfl oAHoro cKJraAy (Ao peui, ueni4ol,to
xroro) xoNuoi Saser.
3..{ononi 4ucrycifiHoro e rpaBonaipuicrr uo6y4onra Sa":onux pinuonar y rHX BI{rIaAKax,
KoJrH He 6yno orpr4MaHo o4no$asuux epasrcin. 3oxpenaa, HO sposytrtilo, tloMy
MaKcr{Marrsnuit gNricr $as" TbrzCrsCrs 6yn BLIflBJreHuir y 3pa3Ky uouiualbHoro cKnaAy
TbDCra+Czq, a He y 3Harruo 6ruN.rrx 3a cKnaAoM 3pa3Kax. lloAi6ne 3ayBaxeHHs
crocyerbcfl BcraHoBJreHH.rr xinai.ruoro cKnaAy HoBpIX cIIoJIyK, BI{flBJIeHI4x y 6araroSa3Hnx
3pa3Kax, aAlxe nnaicr rcap6ony He MoxHa Br3HarII4rI{ MeroAoM EAPC.
4. flopinlfl:e:ns, uapanaerpin eneMeHrapHr.rx rcoiraipox pisuxx spasxin 3a Aankrv'kr
MouoKpprcruurbHoi ra uoponrxonoi au$par<qii (cr. l2l-122) e He sonciNa KopeKrHI{M, rpIM
6ilrrue, KoJrkr ig sroro po6nrrr BLrcHoBoK rrpo Mo)KJIIaBy po3r{I4Huicrr Byrnellrc qta BoAHIo.
ills rlboro cniA craHAaprll3yBaru nuuiproBauHt.
5. PisHi 3HarreHHq Hauinluupkrr 4rasparcuifinux uarcnuyr,tin B crlonyqi -CesCrzCs (c. 124)
soecil{ ne o6os'.f,3KoBo BKa3yrorb Ha Mo}KJrr4Be ix posuelneHus i sHIa}KeHHt clanrerpii ao
rpzr<ninnoi. Tare auisorpoune po3rrrr4peHHfl ninifi Mo)I(e 6ytu HacliArorvt
KoMno3prqiftuprx, repruiunlrx ra eracrprt{sux l,tirpoHalpy}KeHb y Marepiani. Y an'rsry i:
rIr{M, qv He e cilonyKa CezgCreCzs (a : 21.772 A;, rpo sKy fiAerrcs y HacrytlHoMy
naparpa(pi, riero r{ caMoro, uo i nouepeAHq (-CesCrzCs, a : 21J7(3) A;f Aaxe ixni
cKnaApr ra rapaMerppr xy6iunoi eleuesrapnoi rouipru rpaKrl{qHo oAHaKoei. Bapro 6yno
6 Hasecrlr po3paxonasi ilopolllKorpaMl{ o6rAsox cronyK.
6. Anropy cnil 6yno cnpo6ynarn roscHr{rr{ HeMoHoronnufi xapaKrep KoHlleHrpauifinHx
3aJrexHocrefi uaparraerpin eJreMeHrapuoi rouipxu rBepAoro po3tII4Hy DyCor-J'{i"Cz
(c. 1 49-150) na ocHoei ananisy iurulEx crpyKrypHI,IX rapauerpin, 3oKpeMa uiNarounux
eillanefi , r<ytin, rolrlo.
7. CrpyxrypHi xaparrepkrcrvlru prgin iaocrpyrrypHlax cronyK P3E Aoqinrnirue auali:ynaru
B 3€ure)Knocri ni4 paaiycin ioHis R'*, & ne niA ix uporonHoro rrvcila. AAxe caMe raKe
npeAcraBJreHHfl Aa€ Molrlnnicrr, ro-rleprue, "Blucarl4" crpyKTypHi uapauerpl{ cilonyK
Irpiro y cninrni 1^nfl ecix P3E 3aKoHoMipuocri (Puc. 4.1, 4.11), i, ro-Apyre, HaorIHo
upoinrccrpyBarn i noscHraru eiAxnJreHHf,, uoe'qsaui is Haqsuicuo rarionin Ra* a6o R2* e
cronyKax rep6iro ra irep6iro (Pnc. 4.11,n).
8. Xo.{a e rliroNay po6ora Harrr4caHa Ay)Ke xopomoro MoBoIo, B nifi sycrpi'ralorrcx olcpeirai
HeeAani 13vrpa3vr, rari rx ,,rap6ilu sdamui npoaanamu Marnirui neperBopeHna" (c. 46), a
TaKolK rrooAggori neroqnocri ra rroMlrnKlr Apyrcy (:anricrb po3Ain 3.3.1 Ha c. 123 ttae
6yru 3.1.1). OuenuAHo, rrlo KpoK AereKropa 1o, npunetre:auir n Ta6. 3.41 ra3.42 (c. 142,
145) Anr 4z$palcroMerpa APOH-2.O e sBHo 3aBpIIrIeHI{M rIpI{ rl{rlosifi uauiemnplEui
gqspaxqifinux uarcuuyruin 0.15-0.2o. 3auicrr nucrosin Ha KITTTzLIIT "cuolytra
KpucmaJtizyemucn B crpyKrypHoMy rHni ABX', cnil rrkrcarn) IrIo crQnyKa rpI'I AaHLIX
yMoBax "Jt4ae cmpyKmypy rprrry ABX' . AlNe II.s, Ha nepurufi rloulf,A, 4pi6ua ueto'rHictr,
Mae npuHrl1a11oBe 3HarreHH fl y rprx BrrrraAKax, KoJrpI riit. ,rw inmifi cnonyui upuranaaHui
Sa^roni reperBopeHHs.
OAnax cniA 3a3Harrurlr, ilIo [pr,rBeAeHi saynaNeHHs )KoAHHM rII{HoM He BlJILIBarorb Ha
3araJrbHe rro3prrr{BHe BpaxeHHr sia Ar{ceprarlifisoi po6oru, flKa BI{KoHaHa Ha BI{coKoMy
upoSecifiHorvry pieni. ,,{ocronipuicrr oAepx{aurrx pe3ymraris ra rpaBulruicrr spo6neHLIX
nucHosxis He BlrKJrrrKae cyuuinin. Pesyrbrarr{ Ar{ceprallifiHoi po6orn ony6nixonasi y
aBTopr{TerHlrx HayKoBrrx xypHanax, a raKox aupo6onaui Ha qLIcJIeHHI{x HayKoBrIX
xousepenuisx. AnropeQepar Ar.rcepraqii ra ouy6nironaui po6oru uosuicrro niao6paxalorb
sMicr 4ucepraqii. B xoli BrirKoHaHHfl rvceprarlifiHoi po6orn BonoAuMlrp OnexcifioBplrr
rpoflBr,rB ce6e flK n4yururnufi, cauocrifi:rtuit AocniAsI{K ra apinIEft HayKoBeub. flpo fioro
nucor<prfi $axonufi pinenr cniA.rrrr raKo)K sao6yrrfl rpaHry (De4epanbHoro MinicrepcrBa
HayKpr i aocniAlreHb pecuy6nixrE Ancrpir Ha HayKoBe crax{yBaHHt y BiAencrKoMy
rexgi.ruoMy yninepcureri.
Ha niAcrani BrdrrleBrrKnaAeHoro BBa)Karo, tqo AuceprauifiHa po6ora Jlenuqrxoro
: P3M, M : 3d-etrcvresr ra ix
BoloAraMr.rpa Oner<cifioBr,rqa <Cnonyxr4 ctrcrev R-M-C (R
rilpurua: cLrHTe3, crpyKTypa ra BJracrr4Bocri>>, e 3aBepmeHllM HayKoBrlrra AocniAxeHHflIra i sa
o6csrou, Aocronipuicrro orpr{MaHlrx pe:yrnrarin ra rrua6uuoro spo6leHux eucHonrin
silnoeiAae sci1d BLrMoraM, rrlo BlrcyBarorbcfl MOH Yrpaiura Ao KaHAI{AarcbKLIX Al4cepraqifi,
a ii aBrop 3acnyroBye rrplrcyAxreHH.fl HayKoBoro cryrreHfl KaHAI,IAara xirraiqsux HayK sa
cneuiamHicrro 02.00.0 I - neopraniqna xirr,riq.
O$iuifiuufi onoseHr,
AoKrop xiMi.IHIax HayK, upo$ecoP,
npoSecop xa$e4pu naninuponi4Huronoi eneKrpouiru
HV <JlrsiscrKa llonirexuira>
05.06.2015 p.
lliluerc
,/
/,'
,/ lz
Bacure.rxo JI.O.
,/''
AoKropa xiNti.IHux HayK,
llpo$ecopa
BacLUIer{Ka JI. O.
saceiduyn
Bqennfi ceKperap HY <Jlrsiec
Eprannncrrrafi P.B.