MSDS Domtar BioChoice

Transcription

Conforms to HazCom 2012/United States
SAFETY DATA SHEET
Dewatered Lignin
Section 1. Identification
Product identifier used on
the label
: Dewatered Lignin
Trade name
: DCL200, Dewatered Lignin, Lignin, Lignin powder.
Other means of
identification
Product type
: Not available.
: Solid.
Recommended use and restrictions
Identified uses
Includes, but not limited to, research and development, fuel, fuel development, raw material for manufactured
products.
Supplier/Manufacturer
Manufacturing/Locations
Emergency telephone
number (with hours of
operation)
: Domtar Inc.
395 de Maisonneuve Blvd. West,
Montreal, QC
H3A 1L6 Canada
: Plymouth, North Carolina
Tel: (252) 793-8111
: CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7)
CANUTEC: +1-613-996-6666 or *666 (cellular) (24/7)
Domtar: (514) 848-5888
Section 2. Hazards identification
Classification of the
substance or mixture
: SKIN CORROSION/IRRITATION - Category 3
SKIN SENSITIZATION - Category 1
GHS label elements
Hazard pictograms
:
Signal word
: Warning
Hazard statements
: Causes mild skin irritation.
May cause an allergic skin reaction.
Precautionary statements
Prevention
: Wear protective gloves. Avoid breathing dust.
Response
Storage
: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs:
Get medical attention.
: Not applicable.
Disposal
: Not applicable.
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
www.kmkregservices.com www.askdrluc.com www.ghsmart.com
1/11
Dewatered Lignin
Section 2. Hazards identification
Other hazards which do not
result in classification
: Not available.
Section 3. Composition/information on ingredients
Substance/mixture
: Mixture
Other means of
identification
: Not available.
CAS number/other identifiers
CAS number
: 8068-05-1
EC number
: Mixture.
Product code
: Not available.
Ingredient name
%
CAS number
Lignin, alkali
Sulfur
60 - 100
1-3
8068-05-1
7704-34-9
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures
Description of necessary first aid measures
Eye contact
Inhalation
Skin contact
Ingestion
: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20
minutes. If irritation persists, get medical attention.
: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway.
: Wash with plenty of soap and water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 20 minutes. Get medical attention. In the
event of any complaints or symptoms, avoid further exposure.
: Wash out mouth with water. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed
person feels sick as vomiting may be dangerous. Do not induce vomiting unless
directed to do so by medical personnel. If vomiting occurs, the head should be kept
low so that vomit does not enter the lungs. Get medical attention if adverse health
effects persist or are severe. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact
: Causes eye irritation.
Inhalation
: No known significant effects or critical hazards.
Skin contact
: Causes mild skin irritation. May cause an allergic skin reaction.
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
2/11
Dewatered Lignin
Section 4. First aid measures
Ingestion
: Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact
Inhalation
Skin contact
Ingestion
: Adverse symptoms may include the following:
pain or irritation
watering
redness
irritation
redness
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician
Specific treatments
Protection of first-aiders
: Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
: No specific treatment.
: No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Extinguishing media
Suitable extinguishing
media
: Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing
media
: None known.
Specific hazards arising
from the chemical
Hazardous thermal
decomposition products
: Risk of dust explosion in dust-raising operations.
: Decomposition products may include the following materials:
sulfur oxides
carbon oxides
Special protective actions
for fire-fighters
: No special protection is required.
Special protective
equipment for fire-fighters
: Fire-fighters should wear appropriate protective equipment and self-contained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Dusty areas should be wetted down to eliminate any explosion hazard.
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
3/11
Dewatered Lignin
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel
: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel". Emergency responders should wear
NIOSH approved filtering face piece respirators.
Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Small spill
Large spill
: Move containers from spill area. Vacuum or sweep up material and place in a
designated, labeled waste container. Dispose via a licensed waste disposal
contractor. Material may be placed in an approved landfill.
: Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Vacuum or sweep up
material and place in a designated, labeled waste container. Dispose via a licensed
waste disposal contractor. Note: see Section 1 for emergency contact information
and Section 13 for waste disposal.
Section 7. Handling and storage
Precautions for safe
handling
: Put on appropriate personal protective equipment (see Section 8). Note that there is
a risk of dust explosion in dust-raising operations. Avoid generating dust as the
product may form flammable dust/air mixtures. Eating, drinking and smoking should
be prohibited in areas where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating
areas. Persons with a history of skin sensitization problems should not be employed
in any process in which this product is used. Do not get in eyes or on skin or
clothing. Do not ingest. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Empty
containers retain product residue. Use caution in reuse of containers to prevent
over exposure. All containers should be properly cleaned before reuse.
Conditions for safe storage,
including any
incompatibilities
: Store in accordance with local regulations. Store in original container protected
from direct sunlight in a dry, cool and well-ventilated area, away from incompatible
materials (see Section 10) and food and drink. Keep container tightly closed and
sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
4/11
Dewatered Lignin
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name
Exposure limits
Lignin, alkali
ACGIH TLV (United States).
10 mg/m³ Form: Inhalable
3 mg/m³ Form: Respirable.
OSHA PEL (United States).
5 mg/m³ Form: Respirable.
15 mg/m³ Form: Total dust
OSHA
None
Sulfur
Recommended monitoring
procedures
Appropriate engineering
controls
Environmental exposure
controls
: If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment.
: No special ventilation requirements. Good general ventilation should be sufficient to
control worker exposure to airborne contaminants. If this product contains
ingredients with exposure limits, use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure below any recommended or
statutory limits.
: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation.
Individual protection measures
Hygiene measures
Eye/face protection
: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
Skin protection
Hand protection
Body protection
Other skin protection
Respiratory protection
: Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary.
: Personal protective equipment for the body should be selected based on the task
being performed and the risks involved.
: Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved.
: Use a properly fitted, air-purifying or supplied air respirator complying with an
approved standard if a risk assessment indicates this is necessary. Respirator
selection must be based on known or anticipated exposure levels, the hazards of
the product and the safe working limits of the selected respirator.
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
5/11
Dewatered Lignin
Section 9. Physical and chemical properties
Appearance
Physical state
: Solid. [Broken filter cake.]
Color
: Yellow-Brown.
Odor
Odor threshold
pH
: Weak.
: Not available.
Melting point/freezing point
: 3 to 7
: Not available.
Boiling point/boiling range
: Not available.
Flash point
: Closed cup: Not ignitable.
Evaporation rate
: Not available.
Flammability (solid, gas)
: Not available.
Lower and upper explosive
(flammable) limits
: Not available.
Vapor pressure
: Not available.
Vapor density
: Not available.
: Bulk density at 60% dry solids content is 348kg/m3.
Relative density
Solubility
Partition coefficient: noctanol/water
Auto-ignition temperature
: Not soluble under acidic and neutral conditions. Soluble under alkaline conditions.
Soluble in DMSO. Partly soluble in acetone and methanol.
: Not available.
Decomposition temperature
: 1.
Explosion Severity - 20L Sphere
Maximum Explosion Pressure (bar)
Maximum Rate of Pressure Rise (bar/s)
Kst Value (bar.m/s)
a. Minimum Ignition Energy - Dust Cloud (mJ)
b. Minimum Ignition Temperature - Dust Cloud (°C)
a. Limiting Oxygen Concentration (% by volume)
b. Minimum Explosible Concentration (g/m³)
* Indicates test was no performed on the sample
: Not available.
SADT
: Not available.
Viscosity
: Not available.
7.6
684
186
500-1000
470-480
*
70-80
Section 10. Stability and reactivity
Reactivity
: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability
: The product is stable.
Possibility of hazardous
reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
: Dust-raising conditions, static electricity conditions.
Incompatible materials
: Reactive or incompatible with the following materials: oxidizing materials, reducing
materials, drying oils and organic materials.
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
6/11
Dewatered Lignin
Section 10. Stability and reactivity
Hazardous decomposition
products
: Thermal decomposition of Kraft Lignin produces irritating and toxic fumes and
gases including acrid smoke, carbon oxides (CO, CO2), nitrogen oxides (NO, NO2
etc.), sulfur oxides (SO2, SO3 etc.), aldehydes and organic acids. Natural
decomposition of organic materials such as wood may produce toxic gases and an
oxigen deficient atmosphere in enclosed or poorly ventilated areas.
Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
There is no data available.
Irritation/Corrosion
Skin
: There is no data available.
Eyes
Respiratory
Sensitization
Skin
: Skin sensitization may occur.
Respiratory
Mutagenicity
Carcinogenicity
Reproductive toxicity
Teratogenicity
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Aspiration hazard
Information on the likely
routes of exposure
: Routes of entry anticipated: Dermal.
Routes of entry not anticipated: Oral, Inhalation.
Potential acute health effects
Eye contact
: Causes eye irritation.
Inhalation
Skin contact
: Causes mild skin irritation. May cause an allergic skin reaction.
Ingestion
: Irritating to mouth, throat and stomach.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact
Inhalation
pain or irritation
watering
redness
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
7/11
Dewatered Lignin
Section 11. Toxicological information
Skin contact
irritation
redness
Ingestion
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate
effects
Potential delayed effects
Long term exposure
Potential immediate
effects
Potential delayed effects : No known significant effects or critical hazards.
Potential chronic health effects
General
: Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
Carcinogenicity
Mutagenicity
Teratogenicity
Developmental effects
Fertility effects
Numerical measures of toxicity
Acute toxicity estimates
Section 12. Ecological information
Toxicity
Product/ingredient name
Result
Species
Exposure
Sulfur
Acute EC50 >5000 ppm Fresh water
Acute LC50 >180 ppm Fresh water
Daphnia - Daphnia magna - <24 hours
Fish - Lepomis macrochirus - Juvenile
(Fledgling, Hatchling, Weanling)
48 hours
96 hours
Persistence and degradability
Product/ingredient name
Test
Result
Dose
Inoculum
Dewatered Lignin
BOD
COD
11,600 mg/l
19,600 mg/l
-
-
Bioaccumulative potential
Mobility in soil
Soil/water partition
coefficient (KOC)
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
8/11
Dewatered Lignin
Section 12. Ecological information
Other adverse effects
Section 13. Disposal considerations
Disposal methods
: The generation of waste should be avoided or minimized wherever possible.
Significant quantities of waste product residues should not be disposed of in
process sewers or wastewater treatment facilities. Dispose of surplus and nonrecyclable products in approved landfills or via a licensed waste disposal contractor.
Unused product is not a RCRA hazardous waste. Disposal of this product, solutions
and any by-products should comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority
requirements. This material and its container must be disposed of or reused in a
safe manner. Care should be taken when handling empty containers that have not
been cleaned or rinsed out. Empty containers or liners may retain some product
residues. Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
Section 14. Transport information
DOT
IMDG
IATA
UN number
Not regulated.
Not regulated.
Not regulated.
UN proper
shipping name
-
-
-
Transport hazard
class(es)
-
-
-
Packing group
-
-
-
Environmental
hazards
No.
No.
No.
Special
precautions for
user
Not available.
Not available.
Not available.
Additional
information
-
-
-
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
: Not available.
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
9/11
Dewatered Lignin
Section 15. Regulatory information
Safety, health and
environmental regulations
specific for the product
: No known specific national and/or regional regulations applicable to this product
(including its ingredients). Not intended for ingestion or as a food contact material.
U.S. Federal regulations
: TSCA 8(a) IUR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
SARA 302/304/311/312 extremely hazardous substances: No products were
found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Sulfur
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
Sulfur: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health
hazard.
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
: Not listed
Class I Substances
: Not listed
Class II Substances
: Not listed
DEA List I Chemicals
(Precursor Chemicals)
: Not listed
DEA List II Chemicals
(Essential Chemicals)
: Not listed
State regulations
Massachusetts
: The following components are listed: Sulfur
New York
: None of the components are listed.
New Jersey
Pennsylvania
California Prop. 65
No products were found.
Section 16. Other information
HMIS Rating (Scale 0-4)
NFPA Rating (Scale 0-4)
History
: Health : 2 *
: Health : 1
Fire : 2
Fire : 2
Physical hazards : 1
Reactivity : 0
Date of issue mm/dd/yyyy
Date of previous issue
: 09/15/2012
Version
: 1.1
Prepared by
: KMK Regulatory Services Inc.
Key to abbreviations
: 01/08/2012
: ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
10/11
Dewatered Lignin
Section 16. Other information
MARPOL 73/78 = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767)
11/11

MSDS Domtar BioChoice

Transcription

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