Hydrocarbon Remediation By Natural Attenuation at Baruwa, Lagos
Transcription
Hydrocarbon Remediation By Natural Attenuation at Baruwa, Lagos
Hydrocarbon Remediation by Natural Attenuation at Baruwa, Lagos Nigeria Uduebor, Micheal A. Department of Civil and Environmental Engineering, The Federal University of Technology, Akure, Ondo State, Nigeria. e-mail: [email protected] Ola Samuel A. Department of Civil and Environmental Engineering, The Federal University of Technology, Akure, Ondo State, Nigeria. e-mail: [email protected] ABSTRACT This research is concerned with characterization and assessment of Natural Attenuation of hydrocarbon contaminated site. The specific study site is Baruwa community in Alimosho Local government area of Lagos state, Nigeria, with a population of over 100,000 people. There are over 150 wells within the community which have been affected by the oil pollution which dates back to 1994, when there was a burst in an N.N.P.C (Nigerian National Petroleum Corporation) Valve pit located at the Federal Housing Estate (Jakande Estate) opposite the study site. Earlier studies carried out by Adekunte (2008) and Balogun (2009) have established a case of the pollution of the groundwater via hydro-chemical analysis and geoenvironmental assessment coupled with stratigraphic characterisation of the contaminated site using wells within the area respectively. This study employed the collection of field data in 2014 from the contaminated site to sufficiently characterize the hydrocarbon contamination within the area. Characterization of the study area was conducted utilizing the methodology prescribed by United States Environmental Protection Agency (USEPA, 2001). 25 Hand dug wells to a depth of 26.5 metres within the area were utilized for the study. Water levels and Free Hydrocarbon Thicknesses were measured with the aid of an oil/water interface meter, Total Petroleum Hydrocarbon (TPH) was also measured both in groundwater and soil vapour using a portable Hydrocarbon Analyser. Comparisons were made with data obtained in 2006 of previous studies and Natural Attenuation occurrence established based on Tiers 1 and 2 criteria (USEPA, 1999). LNAPL thickness decreases of 86.4% to 99.7% were recorded in comparison with that from previous studies (2006 - 2014). TPH surveys carried out in the groundwater are in agreement with LNAPL flow direction. Decreases in TPH concentrations varying from 33.13% to 57.61% were observed in comparison with earlier studies (2006 - 2014). All the wells investigated within the study area indicated that significant Natural Attenuation has occurred over the period (2006 - 2014). KEYWORDS: Petroleum hydrocarbon, Volumetric characterization, Remediation, Natural Attenuation - 501 - Vol. 21 [2016], Bund. 02 502 INTRODUCTION Hydrocarbon contamination originating from the activities of man have entered the subsurface environment through spillage, land application and waste disposal practices, either on purpose or by accident. The presence and transport of these contaminants constitute a potential threat to human health and ecosystems. Protection of public health and ecosystems rely on the ability to predict the transport and distribution of contaminants in the vadose and saturated zones (Van de Weerd, 2000). Light non-aqueous phase liquids affect ground-water quality at many sites across the country. The most common LNAPL related ground-water contamination problems result from the release of petroleum products. These products are typically multicomponent organic mixtures composed of chemicals with varying degrees of water solubility. Some additives (e.g., methyl tertiary-butyl ether and alcohols) are highly soluble. Other components (e.g., benzene, toluene, ethyl benzene, and xylenes) are slightly soluble. Many components (e.g., n-dodecane and n-heptane) have relatively low water solubility under ideal conditions. In general, LNAPLs represent potential long-term sources for continued ground-water contamination at many sites (Newell et al, 1995). The Baruwa area in Lagos, Nigeria is one of such sites where large volume of refined petroleum hydrocarbon has been released into the subsurface of the soil and has so far been transported from the source to the whole area, rendering groundwater practically unusable, with residents having to go through untold hardships and cost to carry out their daily domestic activities because of the contaminated groundwater. The Geoenvironmental Engineering research group in Federal University of Technology, Akure (FUTA), started Geoenvironmental site assessment, geotechnical, background and natural attenuation studies for the site in 2006. Earlier studies carried out by Adekunte (2008) and Balogun (2009) have tried to establish a case of the pollution of the groundwater via hydrochemical analysis and geoenvironemtal assessment coupled with stratigraphic characterisation of the contaminated site using wells within the area respectively. After an extensive site investigation it is important to reliably evaluate the potential efficiency of Monitored Natural Attenuation as a remediation alternative (USEPA, 1999). This step includes the gathering of site specific data to quantify the rate of the attenuation processes and to estimate the period of time required to achieve the defined remediation objectives. The data collected was processed based on three independent but converging lines of evidence, which include (e.g., Wiedemeier at al., 1995, 1997; USDOE, 1998; USEPA, 1999; Pennington et al., 1999; USAirForce, 1999): 1. Historical groundwater and/or soil chemistry data that demonstrate a clear and meaningful trend of decreasing contaminant mass and/or concentration over time at appropriate monitoring points. 2. Hydrogeological and geochemical data that illustrate that geochemical conditions are suitable for biodegradation and to indirectly demonstrate the type(s) and rates of the Natural Attenuation processes active at the site. This often includes; a. depletion of electron donors and acceptors; b. increase in metabolic by-product concentrations; c. decreasing parent compound concentrations; and d. increase in daughter compound concentrations. Vol. 21 [2016], Bund. 02 503 3. Data from field or microcosm studies, which directly demonstrate the occurrence of a particular Natural Attenuation process at the site and to verify the ability of insitu contaminant degradation. For achieving regulatory approval for Monitored Natural Attenuation application, it is generally necessary to provide both historical data (type 1 above) and data characterizing the nature and rates of Natural Attenuation processes active at the site (type 2 above). Where the latter is inadequate or inconclusive, data from microcosm studies (type 3 above) may also be required. In addition to these lines of evidence, analytical or numerical solute transport models can be used to examine the processes influencing the fate and transport of organic contaminants in groundwater (Wiedemeier et al., 1999). METHODOLOGY Description of the Study Area Baruwa area (Latitude 06˚ 35' 12'' N, Longitude 03˚ 16' 21'' E) is located in Ipaja, between the popular Iyana-Ipaja Bus-stop and the Ikotun Area of Alimosho Local Government Council of Lagos State, South West Nigeria. It is about 2.5km from Iyana-Ipaja Bus Terminal and is bounded by Gowon Estate and Abesan Estate to the right and left respectively while coming from Iyana-Ipaja Bus Terminal. It is accessible by a network of roads through Ipaja and Ayobo and is a densely populated residential area with a population of over 100,000 people living in the area. Its existence dates back to the early 20th Century but it became prominent in the 1970s due to population explosion witnessed in Lagos, which led to the development of satellite communities (Adekunte, 2008). Figure 1 shows the map of Baruwa-Lagos indicating the position of the study area (Baruwa).The area has a few cottage industries and small scale enterprises and has fair to good supply of electricity, with a network of earth roads without a proper drainage system leading to impassability of some roads during the rainy season. Vol. 21 [2016], Bund. 02 504 Figure 1a: Map of Nigeria Indicating the Location of Baruwa-Lagos. Figure 1b: Field Schematic showing Locations of Wells Monitored and Direction of Groundwater Flow (2014) Vol. 21 [2016], Bund. 02 505 There are over 150 wells within the community which have been affected by the oil pollution which dates back to 1994, when there was a burst in an N.N.P.C Valve pit located at the Federal Housing Estate (Jakande Estate) opposite the study site. Experimental Programme The study employed the collection of field data from the contaminated site in Baruwa, Lagos employing equipment and methods to sufficiently characterize the hydrocarbon contamination within the area. Characterization of the study area was conducted utilizing the methodology prescribed by United States Environmental Protection Agency (USEPA) (2001). Field Tools and Equipment A GPS device, Garmin II plus was used to determine the position of observed wells within the area globally. This data obtained was used in proper location and identification of the wells, while an Oil/Water Interface meter was employed to measure the ground water levels and the thickness of free hydrocarbon on groundwater in water supply wells. A PHA-100 portable hydrocarbon analyser was utilized to measure levels of Total Petroleum Hydrocarbons (TPH) in soil vapour and water in the field real time (in-situ). The results of the PHA-100 portable hydrocarbon analyser were later confirmed using Gas Chromatography equipped with Flame Ionisation Detector (GC FID) in the laboratory. Study Methods Desktop Study A review of the site contaminant history was conducted; this included potential LNAPL sources at the site and the affected receptors. Historical groundwater levels and quality were obtained from previous studies within the area (Adekunte (2008), Balogun (2009)) as part of the local geohydrological review. Site Survey (Walkover and Visual inspection) This was conducted to verify the validity of the information collected during the desktop study. Emphasis was placed on fixing the exact positions of the wells (utilizing a GPS tracker), linking previous aquifer test carried out on the existing wells within the area. Also additional information from existing wells were collected to further enhance the study. New wells were also identified within the area and substitutes allotted for wells that were no longer available or accessible. Hydrological (Water Table) and Free LNAPL Product Characterization A water table characterization exercise was conducted as an extension of earlier studies utilizing the number of wells that were still available for testing within the area and their characteristic depths to liquid and to bottom. Also apparent free LNAPL thicknesses were measured within the wells with the aid of the interface meter. The results were compared with previous data obtained from the study site. Vol. 21 [2016], Bund. 02 506 Chemical Characterization Chemical water analyses were conducted for the study area. Dissolved hydrocarbon compound analysis (TPH, BTEX and Contaminant Equivalent) was carried out using the PHA100 Hydrocarbon Analyser and confirmed with Gas chromatography Equipped with Flame Ionisation Detectior (GC FID). Contamination levels were also measured in vapour within the wells. RESULTS AND DISCUSSIONS Hydrocensus Water levels measured within the wells with the aid of the interface meter, gave a range of the water table within the study site to be between 21.97m – 24.53m. Plotting of the contour of water table within the area indicated a southwestern flow. This Southwestern flow (Figure 2) is consistent with reports from previous studies. Comparing the water table levels between the separate studies show the range between 20.28m – 25.25m (Adekunte, 2008) and 21.97m – 24.53m from the current study. A table showing the comparison of water table levels for selected wells monitored by the two studies carried out is given in Table 1 below. Figure 2: Water Table Contour of Study Area (2014) Comparison between the two separate study years have shown that there has been no significant change in direction of groundwater flow and the water table elevations to effect a hydro-biased movement of the contaminant plume. This is quite important as this indicates that Vol. 21 [2016], Bund. 02 507 any remediation effort by natural attenuation has not been affected due to a sudden change in the direction of water within the subsurface in the study area. It must also be worthy of note that as LNAPL approaches the water table, entering regions of increasing water saturation, it may migrate laterally (EPA, 1995). Lateral migration is controlled by the LNAPL head distribution and in general, contaminant plume migration is expected to be greatest in the direction of ground-water flow (i.e., maximum decrease in water-table elevation). Distribution of Free LNAPL at the Study Area Comparing the thicknesses of hydrocarbon with those from previous studies (2006), it was observed that the hydrocarbon thickness had reduced significantly in all the wells. The decrease varied from 86.4% in Well No. 20 to 99.7% in Well No. 41 from 2006 to 2014 as shown in Table 2 below. Table 1: Comparison of water table levels for two studies Water Table Levels (m) Owner’s Name Well ID Adekunte Current (2006*) Study (2014*) Alhaji Baruwa 20 24.40 24.33 Mr Ajiboye 30 23.81 24.53 Mr Oyewole 41 24.60 23.46 Alhaji Oluode 76 23.40 *The dates show the actual dates the data were taken 23.42 Table 2: Comparison of Hydrocarbon Thickness Measured Within Wells. WELL OWNER'S HYDROCARBON THICKNESS (m) ID No. NAME CURRENT ADEKUNTE STUDY % DECREASE (2006*) (2014*) Alhaji Baruwa 0.72 0.098 86.39 20 30 41 69 76 Mr Ajiboye 0.2 0.001 99.50 Mr Oyewole 0.35 0.001 99.71 Mr Kunle 0.12 0.001 99.17 Idowu Alhaji Oluode 0.15 0.001 99.33 *Note: The dates show the actual dates the data were taken Vol. 21 [2016], Bund. 02 508 Figure 3a: Free Hydrocarbon Thickness for Monitored Wells within the Study Area (2014) Figure 3b: Free Hydrocarbon Thickness for Monitored Wells Within the Study Area (2006). (from Adekunte, 2008) Vol. 21 [2016], Bund. 02 509 The principal Natural Attenuation processes responsible for this movement of and decrease in contaminant mass is Advection which is characterized by the transport of contaminant due to bulk motion of the flowing groundwater and concentration gradient respectively. This indicates that continuous flow of the groundwater would lead to lower proportions of the free hydrocarbon within the subsurface, which after a period would eventually thin out to sheen levels in all the wells - this is characteristic of natural attenuation studies. The resultant effect would leave only the contamination within the soil strata and residual groundwater within the subsurface which can then be acted upon by microbes if present, degrading the hydrocarbon (USEPA, 2001). Dissolved Contaminants in Groundwater (TPH) Comparing the Total hydrocarbon concentrations with those from previous studies, it is noticed generally that the various concentrations earlier observed within the wells are now reduced, with decreases of up to 57.61%. (See Table 3 below). Table 3: Comparison of Total Petroleum Hydrocarbon (TPH) Measured Within Wells. TOTAL PETORLEUM HYDROCARBON (mg/l) OWNER'S CURRENT ADEKUNTE % NAME STUDY (2006**) DECREASE (2014**) Alhaji Oluode 49.906 27.3 -45.3 Mr Lasun Faremi 95.0* 45.2 -52.43 Famuyiwa E.O 66.4* 35.6 -46.39 Alhaji Owolabi 68.2* 36.7 -46.19 Mr Oyewole 75.079 48.9 -34.87 Hon. Bayo 71.0* 47.5 -33.13 Alhaji Baruwa 144.86 61.4 -57.61 *Results gotten from contour **Actual dates the data were taken Vol. 21 [2016], Bund. 02 510 Figure 4a: Contours of TPH in Groundwater for the Study Area (2014). Figure 4b: Contours of TPH in Groundwater for the Study Area (2006) (from Adekunte, 2008) Dispersion is also responsible for the spread of the contamination across the area. Diffusion also plays a role in spreading the contaminant concentration due to concentration gradient after dispersion. This movement/spread would continue till the concentrations thin out and equilibrium is achieved. The results show the importance of groundwater movement. Vol. 21 [2016], Bund. 02 511 CONCLUSIONS The following conclusions were obtained based on the study; (1) LNAPL thickness decreases of 86.4% to 99.7% were recorded in comparison with that from previous studies (2006 - 2014). (2) TPH surveys carried out in the groundwater are in agreement with LNAPL flow direction. Decreases in TPH concentrations from 33.13% to 57.61% were observed in comparison with earlier studies (2006 - 2014). (3) All the wells investigated within the study area indicated that significant Natural Attenuation has occurred over the period (2006 - 2014). ACKNOWLEDGEMENTS The authors would like to acknowledge the TETFUND National Research Fund of The Prof. S.A. Ola Research Group, Federal University of Technology, Akure referenced TETF/ES/NRF/013/Vol.I for the Research Project titled “Site Remediation in Nigeria: Proven and Innovative Technologies, Recovery of Free Hydrocarbon from Soil/Groundwater.” REFERENCES 1. Adejumo T. E. (2012) “Effect of Crude Oil Contamination on the Geotechnical Properties of Soft Clay Soils of Niger Delta Region of Nigeria.” [J] The Electronic Journal of Geotechnical Engineering, 2012(17):1929-1938. Available at ejge.com. 2. Adekunte, O.A. (2008) “Hydro-chemical Analysis of Shallow Wells for Hydrocarbon Contamination in Baruwa, Lagos, Nigeria”, M.Eng Thesis, Civil Engineering Department, The Federal University of Technology, Akure, Nigeria. 3. Balogun S. (2009) “Geoenvironmental Assessment and Stratigraphic Characterization of a Contaminated Site in Baruwa, Lagos State”, M.Eng Thesis, Civil Engineering Department, The Federal University of Technology, Akure, Nigeria. 4. Environmental Protection Agency (EPA) (1995) “How to Evaluate Alternative Cleanup Technologies for Underground Storage Tank Sites” EPA/510-B-95-007. 5. EPA, (2005) “Historical site assessment” http://www.epa.gov/radiation/marssim/docs/revision1_August_2002correction/chapt er3.pdf.`(Sourced 13/08/14). 6. Newell C. J., Acree S. D., Ross R. R., and Huling S. G. (1995) “Light Non-aqueous Phase Liquids” Ground Water Issue. United States Environmental Protection Agency. Office of Research and Development. : EPA/540/S-95/500. 7. Nur Atikah Mohd Ali, Umar Hamzah, Mohd Amir Asyraf Sulaiman “ Detection of LNAPL Plume by High Resolution Laboratory Electrical Resistivity Measurement” [J] The Electronic Journal of Geotechnical Engineering, 2014(19):1991-2005. Available at ejge.com. 8. Pennington J. C., Zakikhani M., and Harrelson D. W. (1999) “Monitored natural attenuation of Explosives in groundwater – Environmental Security technology Vol. 21 [2016], Bund. 02 512 certification program completion report”, pp. 234. U.S. Army Corps of Engineer Waterways Experiment Station. 9. US Air Force. (1999) “Natural attenuation of fuel hydrocarbons - performance and cost results from multiple Air Force demonstration sites”, pp. 67. U.S. Air Force Centre for contaminated aquifer sediments after inoculation with a benzeneoxidizing enrichment. Applied and Environmental Microbiology 64(2), 775-778. 10. USDOE. (1998) “Technical guidance for the long term monitoring of natural attenuation remedies at Department of Energy sites”, pp. 22. U.S. Department of Energy, Office of Environmental Restoration. 11. USEPA. (1999) “Use of monitored natural attenuation at superfund, RCRA corrective action, and underground storage tank sites”, pp. 32. Office of Solid Waste and Emergency Response. 12. USEPA. (2001) “Cost analyses for selected groundwater cleanup projects: Pump and Treat Systems and Permeable Reactive Barriers”, pp. 23. United States Environmental Protection Agency. 13. Van de Weerd H. (2000) “Transport of reactive carriers and contaminants in groundwater systems: a dynamic competitive happening” Thesis Wageningen University, The Netherlands. ISBN 90-5808-290-3 14. Wiedemeier T. H., Wilson J. T., Kampbell D. H., Miller R. N., and Hansen J. E. (1995) “Technical protocol for implementing intrinsic remediation with long-term monitoring for natural attenuation of fuel contaminant dissolved in groundwater”, pp. 295. U.S. Air Force Centre for Environmental Excellence. 15. Wiedemeier T. H., Swanson M. A., Moutoux D. E., Gordon E. K., Wilson J. T., Wilson B. H., Kambell D. H., Hansen J. E., Haas P., and Chapelle F. H. (1997) “Technical protocol for evaluating natural attenuation of chlorinated solvents in groundwater”, Air Force Centre for Environmental Excellence. 16. Wiedemeier T. H., Rifai H. S., Newell C. J., and Wilson J. T. (1999) “Natural attenuation of fuels and chlorinated solvents in the subsurface”, John Wiley & Sons. © 2016 ejge