AdvAnced composites material selector Guide
Transcription
AdvAnced composites material selector Guide
Advanced composites Material Selector Guide Pregregs Thermoplastic fabrics & unitapes Thermoplastic laminates Adhesives Liquid resins Syntactic films Molding compounds Aircraft Space & satellite Radomes Interiors High temperature Design & parts Industrial Protective Fabrics Outdoor Fabrics Advanced Composites Advanced Armour Geosynthetics Grass ADVANCED COMPOSITES TenCate Current Applications and Materials Commercial Aircraft – Applications include primary and secondary structures such as leading edges, keel beams, ribs and engine pylons. • TenCate Cetex® thermoplastic prepregs based upon high performance PPS, PEEK and PEI resins. General Aviation & UAV ’s – Materials used in primary and secondary structures on leading aircraft. • Toughened epoxy out of autoclave prepregs. Interiors – Thermoplastic prepregs for interior side panels, luggage bins, flooring and components. • TenCate Cetex® and TenCate Cetex System3® PEI-based low FST thermoplastic prepregs and PEI honeycomb core. Out of Autoclave/Structural – Applications include primary and secondary structures including floor beams, engine nacelles and structural panels. • TenCate’s low void structural thermoplastic unitapes and vacuum bag cure thermoset prepregs enable out of autoclave and automated tape laying processes. Satellites and Space Antennas – TenCate materials are found on primary satellite structures, solar arrays, antennas and dimensionally stable structures. • Low CTE and low moisture uptake cyanate ester and epoxy prepregs utilizing high modulus carbon, quartz and aramid fibers. Aerospace Molded Parts – Ranging from molded hydraulic clamps to helicopter inserts to missile fins. • Thermoset and thermoplastic bulk molding compounds (BMC), both glass and carbon based materials. Design, tooling and fabrication capabilities – molding ideas into reality. Radomes – Electrically pure prepregs for military aircraft, missile and commercial applications. • Low dielectric, low loss prepregs and adhesives. 2 ADVANCED COMPOSITES | Selector guide TABLE OF CONTENTS TenCate profile 4-7 Aircraft 8 - 11 Space & satellite 12 - 15 Radomes 16 - 19 Interiors 20 - 21 Design & part services 22 Bulk molding compounds 23 High temperature 24 - 25 Performance composites 26 - 27 New products 28 Product listing 29-35 ADVANCED COMPOSITES | Selector guide 3 COMPANY PROFILE << Table of Contents TenCate TenCate is a leading supplier of specialty materials ranging from ballistic armor protection to advanced composites to geosynthetics. TenCate, a company with a rich 300+ year history, employs over 4,200 personnel in 15 countries and has annual sales in excess of $1 billion. All groups focus heavily on innovation, and on delivering value through materials technology. Ten Cate Advanced Composites TenCate Advanced Composites (TCAC) operates four prepreg facilities in North America, one in the Netherlands and one in the U.K. Our aerospace facilities are approved with ISO9001 and AS9100 approvals. The Corporate office for TCAC-USA, along with manufacturing, is located in Morgan Hill, CA which is approximately two hour south of our Fairfield, CA prepreg facilities. The European corporate office is located in Nijverdal, the Netherlands. Each of these facilities has full capability for the production of high performance materials. Both sites in the U.S. maintain carbon-free areas for the production of low-dielectric materials used in radomes and communicationcomposite structure. 4 ADVANCED COMPOSITES | Selector guide TenCate is a leading supplier of high performance prepregs to the following segments: • Commercial & military aircraft • Satellite and space structure • UAV programs • General aviation and helicopter • Aircraft interiors • Aerospace composite compression molded parts • Missile applications • Industrial applications • Radomes for military & commercial aircraft and defense systems TenCate’s thermoplastic technology is based upon fabricbased reinforced thermoplastic prepregs and multi-ply oriented laminates provided out of our Nijverdal Netherlands facility. TenCate’s aerospace grade thermoplastic uni-directional tapes are produced in our Morgan Hill location. PPS-based thermoplastic fabric laminates are used on commercial aircraft leading edges, rib stiffeners, keel beams and interior panels. PEI-based thermoplastic fabric laminates are used primarily on aircraft interiors. Our thermoplastic aerospace grade unitapes are based upon PEEK, PEI, PPS polymers and are manufactured OUR PEOPLE << Table of Contents TenCate People in Morgan Hill. Our success is in our people. The majority of our technical personnel have aerospace industry experience. The advantage to our customers is having experience that aligns with their needs. TenCate has a long history of contributions in the aerospace industry. We are the leading thermoplastic prepreg supplier with several tons of thermoplastic prepregs on each A380. We are qualified and used on both Airbus and Boeing aircraft, from exterior structural assemblies to interiors. Our mission is to be the most responsive, technology driven, global prepreg supplier providing outstanding technical and commercial customer support, always exceeding our customer’s expectations. Our focus on solutions and material systems has proven invaluable in key market segments such as satellites, radomes, UAV’s and general aviation. We have the most modern prepreg equipment in the world, and combine this with responsive customer support and leading product technologies. ADVANCED COMPOSITES | Selector guide 5 MANUFACTURING << Table of Contents Manufacturing TenCate maintains three aerospace qualified manufacturing sites for prepregs and resin production. We have the capability to manufacture 50 inch (127 cm) wide unitapes and up to 64 inch (163 cm) fabric prepregs. Nijverdal manufacturing includes the capacity to provide thermoplastic prepreg fabrics up to 50 inches (127 cm) wide and multi-ply flat thermoplastic laminates up to 4 feet by 12 feet (1220 mm x 3600 mm). • • • Full computer controlled process parameters and feedback. Precision filming and precision prepregging capability. Separate carbon-free area with positive ventilation for glass, quartz and electronic products. 6 ADVANCED COMPOSITES | Selector guide Our www.tencate.com website provides our customers with easy access to product data, MSDS’s, and literature... or download the TenCate Selector Guide apps. << Table of Contents Prepreg Technology TCAC has expertise and experience in both thermoset and thermoplastic prepregs. Our thermoset product lines are based upon cyanate esters, BMI’s, polyimides and epoxy resins serving high end aerospace applications. TCAC utilizes high precision film prepregging capability for the manufacture of tightly controlled resin-content thermoset prepregs. As the aerospace industry shifts to highly automated tape laying and fiber placement, resin content and fiber areal weight control becomes critical to enable these advanced manufacturing processes. Recent Investments Over the last several years, TenCate has made significant investments in both capabilities and capacity to serve the growing composite usage in aerospace. This ensures TenCate’s leading position in aerospace grade thermoplastic advanced materials. Bulk Molding Compounds and Special Resin Technology TenCate acquired YLA, Inc. and CCS Composites. YLA, Inc. provides specialty resin technology with leading positions in satellite and high temperature prepregs. CCS Composites produces both bulk molding compounds with high modulus carbon and glass fiber. Also part design and fabrication services are offered. Composite compression molded parts are in demand as composites move into fuselage and wings, and many of the smaller complex metal parts shift to composites for weight reduction and resistance to galvanic corrosion. Our techniques provide performance with long fiber molding materials that enable breakthrough applications. TenCate prepregs are used on almost every Western world satellite program. Applications include solar arrays, antennas and dimensionally stable structures. TenCate’s epoxy prepregs are used on leading UAV programs for wing, fuselage, radome and control surfaces. In aircraft, TenCate prepregs are used in applications ranging from radomes to interiors, to structural components. TenCate out of autoclave epoxy prepregs are used in general aviation for primary and secondary structure. ADVANCED COMPOSITES | Selector guide 7 AIRCRAFT << Table of Contents Thermoplastic and Epoxy Prepregs TenCate has the most flight experience with out of autoclave prepregs. Tencate’s out of autoclave epoxy prepregs are used to manufacture composite fuselages, wings and control surfaces. TenCate’s precision filming capability and resin chemistry allows cost effective out of autoclave vacuum bag processing to improve part throughput and productivity. TenCate’s prepregs are used in general aviation, commercial and military aircraft, and helicopter construction. TenCate’s Cetex® thermoplastic composites have been used for primary, secondary and tertiary structures for many years, and are qualified at major aircraft manufacturers. We are participants on leading edge aircraft and have positions on the next generation of composite aircraft. 8 ADVANCED COMPOSITES | Selector guide MATERIAL SELECTOR GUIDE: AIRCRAFT << Table of Contents Prepregs Product Name Resin Type Tg Cure Temp/ Cure Time Description Key Resin Characteristics BT250E-1 Epoxy 257°F/125°C • 60 minutes at 250°F/121°C • • • • BT250E-6 NEW Epoxy 268°F/131°C • 120 minutes at 260°F/127°C • High modulus resin system for rotor blade usage • Out of autoclave processible • Toughened epoxy 30 day work life at 77°F/25°C EX-1548 Epoxy 262°F/128°C • 30 minutes at 235°F/113°C or • EX-1548 is a quick cure epoxy with extreme toughness 30 day work life at 77°F/25°C • RS-8HT provides excellent elevated temperature properties with good toughness and moisture resistance • Also available as an RTM resin Fracture Toughness G1c 1.2 in - lb/in2 Elongation 1.2% • Very high temperature properties. Controlled flow with long out time. Fracture Toughness K1c 0.45MPa-m1/2 • • • • • • Gel Time: 6-10 minutes at 265°F/135°C 30 day shelf life at 75°F/25°C Hot/wet Tg 257°F/125°C • 240 minutes at 200°F/93°C, or • 15 minutes at 250°F/121°C RS-8HT RS-9D TC250 BMI 590°F/310°C • 120 minutes at 400°F/204°C, post cure of 360 minutes at 482°F/250°C Cyanate Ester 390°F/199°C or 700°F/371°C with post cure • 120 minutes at 380°F/193°C Optional post cure of 240 minutes at 600°F/316°C Epoxy 284°F/140°C • 60 minutes at 190°F/88°C, or followed by 120 minutes at 265°F/130°C. Optional 374°F/190°C post cure of 60 minutes at with post 350°F/177°Cfor higher Tg cure BT250E-1 is a good moderate service prepreg Self adhesive to core Good toughness MIL-R-9300 qualified 30 day work life at 77°F/25°C 2.0% moisture absorption after 24 hour water boil TC250 is a 250°F/121°C service prepreg. It is designed for vacuum bag cure or autoclave Good surfacing qualities Good toughness Self adhesive to core capability Postcurable ADVANCED COMPOSITES | Selector guide 9 << Table of Contents Prepregs Product Name TC275 NEW TC275-1 NEW TC350 TC350-1 NEW TC550 TC800 BMI+ NEW Resin Type Cure Temp/ Cure Time Tg Description Key Resin Characteristics Epoxy 293°F/145°C or • 360 minutes at 275°F/135°C Optional post cure of 120 338°F/170°C minutes at 350°F/177°C with post cure • Designed for very low voids <0.5% in thick parts with out of autoclave vacuum cures. • May be cured at 275°F/135°C or 300°F/350°C (150°F/177° Very low moisture uptake High hot/wet Tg retention Epoxy 293°F/145°C or • 360 minutes at 275°F/135°C Optional post cure of 120 338°F/170°C minutes at 350°F/177°C with post cure • Designed for a very low voids <0.5% in thick parts with out of autoclave vacuum cures. • May be cured at 275°F/135°C or 300°F/350°C (150°F/177°C) Very low moisture uptake High hot/wet Tg retention Longer tack life and outtime for larger parts 397°F/203°C • 120 minutes at 350°F/177°C • TC350 is a 350°F/177°C service prepreg. It is a toughened high temperature prepreg • Low moisture absorption • Good hot/wet performance • Ideal for autoclave or press cure Gel Time: 10-12 minutes at 350°F/177°C 14 day shelf life at 75°F/25°C Hot/wet Tg 320°F/160°C Epoxy 397°F/203°C • 120 minutes at 350°F/177°C • TC350 is TenCate’s latest 350°F/177°C service out-ofautoclaveprepreg. It is a toughened high temperature prepreg • Low moisture absorption • Good hot/wet performance • Ideal for autoclave or press cure Gel Time: 10-12 minutes at 350°F/177°C 14 day shelf life at 75°F/25° Epoxy 246°F/119°C • 75 minutes at 280°F/138°C • TenCate’s low FST prepreg for interior ducts, meets 12 second vertical burn See data sheet for details. • Out-of-autoclave processible High temperature performance Epoxy BMI 471°F/244°C • 6 hours at 350°F/177°C, followed by 2 hours post cure at 450°F/230°C Thermoplastic Fabrics & Unitapes Product Name TenCate Cetex® TC1000 10 Resin Type Polyethermide (PEI) Cure Temp/ Cure Time Tg 419°F/215°C • Process temp - 600°F/315°C ADVANCED COMPOSITES | Selector guide Description • This is a PEI based resin either on glass or carbon exhibits high temperature capability and features: • Low flammability - V-0 • Good impact toughness • Low moisture absorption of 1.25% • Qualified at Airbus and Boeing • Ideal for interior applications ranging from floor • panels, to seat plyths, to luggage bins Key Resin Characteristics See data sheet for details. << Table of Contents TenCate Cetex® TC1100 Polyphenylene Sulfide (PPS) 194°F/90°C or 419°F/215°C • Process temp - 625°F/330°C • TenCate Cetex® 1100 either on glass or carbon exhibits moderate temperature capability and features: • High impact resistance • Low flammability • Low moisture absorption of 0.02% • Ideal for leading edges, structural aircraft parts • including interior beams and floor panels • TenCate Cetex® TC1100 represents thermoplastic unitapes, fabrics and RTL. either glass, carbon or aramid with PPS resin TenCate Cetex® TC1200 PEEK Polyetheretherketone (PEEK) 290°F/143°C • Process temp - 725°F/385°C • TenCate Cetex® TC1200 represents thermoplastic unitapes either glass, carbon or aramid with PEEK resin See data sheet for details. Epoxy 186°F/86°C • 180 minutes at 180°F/82°C or • 60 minutes at 200°F/93°C, or • 15-20 minutes at 250°F/121°C • BF508 is a toughened 180°F/82°C to 200°F/93°C service temperature resin film adhesive • Available in both supported and unsupported form 21 day shelf life at 77°F/25°C Dielectric Constant 2.8 at 10Ghz, Loss Tangent 0.008 at 10 Ghz Moisture Absorption 1% after 100 hour water boil See data sheet for details. Film Adhesives BF508 BF522 Epoxy 365°F/185°C • 120 minutes at 350°F/177°C • BF522 is a toughened epoxy. Features low dielectric and low moisture absorption. BF548 Epoxy 262°F/128°C • 240 minutes at 180°F/82°C or • 30 minutes at 235°F/113°C, or • 15 minutes at 250°F/121°C • BF548 is a quick cure resin film adhesive, with high toughness and strength 30 day shelf life at 77°F/25°C Dielectric Constant 3.0 at 10 Ghz, Loss Tangent 0.017 at 10 Ghz TC205 Epoxy 275°F/135°C • 30-60 minutes at 190°F/88°C, followed by 120 minutes at 265°F/130°C. • Compatible toughened resin film for TC250 See data sheet for details. TC235F NEW Epoxy 246°F/119°C • 120 minutes at 350°F/177°C • Toughened epoxy resin for structural applications Excellent surfacing under low cure pressure Epoxy 397°F/203°C • 120 minutes at 350°F/177°C • Toughened epoxy resin for structural applications 30 minutes set time at 350°F/177°C RTM Resin RS-50 TenCate Cetex® RTL - Reinforced Thermoplastic Laminate, TenCate Cetex® Thermo-Lite - Represents TenCate's thermoplastic unitapes ADVANCED COMPOSITES | Selector guide 11 SPACE & SATELLITE << Table of Contents High reliability strucural materials TenCate materials are widely used on satellite and space structures and antennae as a result of their performance characteristics and successful flight history. TenCate materials have been used on almost every satellite program in the Western world. The rigors of space require that prepregs and related materials must withstand exposure to extreme temperature cycling and radiation while resisting microcracking and outgassing. TenCate materials have been approved for satellite usage and when combined with ultra high modulus fibers and specialty weaves, make the strongest and lightest weight structures. TenCate prepregs, resins, syntactics and film adhesives are primarily used on bus structure, solar panels, reflectors and a variety of booms, tubes and trusses. TenCate’s line of cyanate ester prepregs provide the ultimate performance, while our epoxy products meet the requirements for space flight while providing a more cost effective alternative to cyanate ester materials 12 ADVANCED COMPOSITES | Selector guide Satellite composite structure must endure extremely harsh environments and thermal cycling. TenCate’s technology in lowoutgassing, dimensionallystable, low moisture prepregs allow the highest performance with unmatched reliability. MATERIAL SELECTOR GUIDE: SPACE/SATELLITE << Table of Contents Prepregs Key Resin Characteristics Product Name Resin Type BTCy-1 Cyanate Ester 374°F/190°C or • 90 minutes at 350°F/177°C Optional post cure of 120 461°F/238°C minutes at 450°F/232°C with post cure BTCy-1A Cyanate Ester 365°F/ 185°C or • 120 minutes at 350°F/177°C • Improved toughness version of BTCy-1, very low void even Optional post cure of 60 400°F/204°C with low pressure cures minutes at 400°F/204°C with post cure Outgassing Data & CTE: • TML: 0.68%, CVCM: 0.00%, WVR: 0.31% • CTE Data: 43 ppm/°F (77 ppm/°C) EX-1515 Cyanate Ester 274°F/134°C or • 180 min at 250°F/121°C Optional post cure 2 hrs at 360°F/182°C 350°F/177°C for final Tg with post cure Outgassing Data & CTE: • TML: 0.179%, VCM: 0.007% • CTE Data: 34 ppm/°F (61 ppm/°C) RS-3 & RS-3C Cyanate Ester performance with good modulus retention after radiation 390°F/199°C or • 120 minutes at 350°F/177°C exposure Optional post cure of 60 490°F/254°C minutes at 450°F/232°C • Features RS-3C a controlled flow version for vacuum bag/ with post cure Outgassing Data & CTE • TML: 0.22%, CVCM: 0.01% • CTE: 24ppm/°F (43 ppm/°C) RS-9D Cyanate Ester 390°F/199°C or • 120 minutes at 380°F/193°C • Very high temperature properties. Controlled flow with Optional post cure of 240 700°F/371°C long out time. minutes at 600°F/315°C with post cure • CTE: 28 ppm/°F (50 ppm/°C) RS-12B Cyanate Ester 293°F/190°C or • 300 minutes at 265°F/129°C • A low tack prepreg with low cure shrinkage, ability to Optional post cure of 95 cure at 265°F, low moisture absorption, excellent modulus 322°F/161°C minutes at 310°F/154°C retention after radiation. with post cure Outgassing Data & CTE • TML: 0.24%, CVCM: 0.00%, WVR: 0.11% • CME: 1410 ppm/% m Tg Cure Temp/ Cure Time Description • Excellent structural properties with low moisture absorption and good resistance to galvonic corrosion • Optimal mechanicals, low microcracking, high radiation resistance and low moisture absorption. High level of cure at 250°F/121°C. High Tg from post cure at 350°F/177°C. • Good balance of toughness and high temperature oven cure and RS-3M, a very low flow autoclave version Outgassing Data & CTE: • TML: 0.36%, CVCM: 0.00%, WVR: 0.33% • CTE Data: 34 ppm/°F (61 ppm/°C) ADVANCED COMPOSITES | Selector guide 13 << Table of Contents Prepregs Product Name Resin Type RS - 17B Epoxy RS - 36 Epoxy Tg Cure Temp/ Cure Time Description 314°F/172°C or • 120 minutes at 275°F/135°C • Very low moisture absorption with balanced mechanical, Optional post cure of 120 390°F/199°C toughness and modulus. minutes at 325°F/163°C with post cure 379°F/193°C • 90 minutes at 350°F/177°C TC410 NEW Cyanate Ester 234°F/112°C or • 3 hours at 250°F/121°C Optional post cure at 358°F/181°C 350°F/177°C with post cure TC420 NEW Cyanate Ester 350°F/177°C or • 3 hours at 350°F/177°C Optional post cure at 610°F/321°C 500°F/260°C with post cure • Epoxy with excellent properties and lower cost than cyanate esters, vacuum processible, and low moisture absorption. • • • • Low stress free cure temperature capable Passes and exceeds space requirements for outgassing Low CTE and CME Extremely low moisture absorption. Resin is asymptotic after 200 days with less than 0.35% moisture absorption in a 75% RH environment. • Very high temperature service • Good resistance to microcracking • Out of autoclave processible Key Resin Characteristics Outgassing Data • TML: 0.71%, CVCM: 0.00%, WVR: 0.34% Outgassing Data • TML: 0.63%, CVCM 0.00% Outgassing Data • TML: 0.29%, CVCM 0.01% WVR: 0.17% • CME: 1205 ppm/% m Ultra high temperature performance Film Adhesives EX-1516 Cyanate Ester 250°F/121°C EX-1543 Cyanate Ester 405°F/207°C with post cure RS-4A Cyanate Ester 397°F/203°C 14 • Toughened cyanate ester with low cure temperature • Features low cure shrinkage • 300 minutes at 250°F/121°C • Low outgassing, good resistance to microcracking and resistance to environmental and radiation exposure • CTE: 56 ppm/°F (100 ppm/°C) • 60-90 minutes at 350°F/175°C Optional postcure of 120 minutes at 400°F/204°C Compatible resin film adhesive with: • Low cure shrinkage • Low moisture absorption • Low outgassing and resistance to cyclic microcracking • CTE: 43 ppm/°F (77 ppm/°C) • 120 minutes at 350°F/177°C • Low tack version, with low cure shrinkage • Good balance of toughness and mechanical strength • Low moisture absorption, low microcracking, reticulatable for lightweight core bonding See data sheet for properties. ADVANCED COMPOSITES | Selector guide << Table of Contents Paste Adhesives EX-1502-1 Cyanate Ester 260°F/127°C • 300 minutes at 250°F/121°C EX-1537 Cyanate Ester 405°F/207°C • 120 minutes at 350°F/177°C • Thixotropic two part paste adhesive See data sheet for properties. EX-1537-1 Cyanate Ester 405°F/207°C • 120 minutes at 350°F/177°C • Low viscosity unfilled version of EX-1537 See data sheet for properties. • Two part paste adhesive, good mechanical performance. Ideal for cryogenic and space applications. See data sheet for properties. Syntactic Films • One part syntactic paste available in four different densities: 11, 13, 17.5 and 24 pcf. Ideal to be used as a foam core. Low outgassing. EX-1541 Cyanate Ester 350°F/177°C • 90-120 minutes at 350°F/177°C SF-5 Cyanate Ester 349°F/176°C • 120 minutes at 350°F/177°C Optional post cure of 120 • Syntactic film compatible with cyanate ester prepregs minutes at 450°F/232°C • 38 pcf density / 0.6 g/cc Outgassing Data • TML: 0.82%, CVCM: 0.01%, WVR: 0.64% Moisture Absorption • 1.4% at saturation • CTE - 7.4x10-6 in/in/°F for 24 pcf/0.38 g/cc RTM Resins EX-1510 Cyanate Ester 380°F/193°C • Toughened resin system with very low 150 cps viscosity at 77°F/25°C • 120 minutes at 350°F/177°C • Good mechanical properties and thermal properties • Low moisture absorption • 24 hr pot life EX-1545 Cyanate Ester 345°F/173°C • 90 minutes at 350°F/177°C Optional post cure at 400°F/204°C RS-16 Cyanate Ester 332°F/167°C • 120 minutes at 275°F/135°C • Low cure temperature followed by 120 minutes at • Two part resin system 300°F/150°C • Toughened resin system, two part system • Full properties with 350°F/177°C cure • Low viscosity of 140 cps at 110°F/43°C Moisture Absorption • 0.85% after 24 hr water boil • Minimum viscosity 30 cps at 220°F/105°C ADVANCED COMPOSITES | Selector guide 15 RADOMES << Table of Contents Competitive-edge components TenCate materials have been used for over twenty years on a variety of military and commercial aircraft radomes as well as in antenna structure. Materials used in radome construction must be free of carbon fiber conductive particles and are made at TenCate in specialized carbon-free areas. Most reinforcements are glass, quartz, polyethylene or aramidbased. Radomes are designed for transmission efficiency. TenCate materials used in radome construction possess low dielectric constants and low moisture absorption allowing increased efficiency from the antenna and exhibit low loss tangents offering very low resistance to electrical energy. 16 ADVANCED COMPOSITES | Selector guide Low Dielectric Materials TenCate low dielectric epoxies and cyanate ester prepregs are used in both commercial and military aircraft as well as defense and ship radar structure. MATERIAL SELECTOR GUIDE: RADOMES << Table of Contents Prepregs Product Name Resin Type Tg Cure Temp/ Cure Time Description Key Resin Characteristics BTCy-1 Cyanate Ester 374°F/190°C or • 90 minutes at 350°F/177°C Optional post cure of 60 461°F/238°C minutes at 450°F/232°C with post cure • Excellent structural properties with low moisture absorption and good resistance to galvanic corrosion Quartz Laminate Dielectric Constant 3.19 at 1.0 Mhz, 3.20 at 10Ghz Loss Tangent 0.001 at 1.0 Mhz, 0.004 at 10.0 Ghz E-Glass Laminate Dielectric Constant 4.30 at 1.0 Mhz Loss Tangent 0.006 at 1.0 Mhz BTCy-1A Cyanate Ester 365°F/185°C or • 120 minutes at 350°F/177°C Optional post cure of 60 400°F/204°C minutes at 400°F/204°C with post cure • Improved toughness version of BTCy-1, very low void content even with low pressure cures. Neat Resin Properties Dielectric Constant 2.7-2.8 at 10 GHz Loss Tangent 0.003 @ 10 GHz Cyanate Ester 374°F/190°C or • 90 minutes at 350°F/177°C Optional post cure of 60 461°F/238°C minutes at 450°F/232°C with post cure • • • • Quartz Laminate Dielectric Constant 3.19 at 1.0 Mhz, 3.20 at 10Ghz Loss Tangent 0.001 at 1.0 Mhz, 0.004 at 10.0 Ghz BTCy-1C BTCy-2 Cyanate Ester EX-1515 Cyanate Ester EX-1522 Epoxy RS-3 & RS-3C Cyanate Ester 375°F/191°C • 90 minutes at 350°F/177°C 274°F/134°C or • 180 min at 250°F/121°C Optional post cure 2 hrs at 360°F/182°C 350°F/177°C for final Tg with post cure 396°F/202°C • 120 minutes at 350°F/177°C 390°F/199°C or • 120 minutes at 350°F/177°C Optional post cure of 60 490°F/254°C minutes at 450°F/232°C with post cure Longer outime, long shelf life version of BTCy-1 Excellent structural properties with low moisture absorption and good resistance to galvanic corrosion • TenCate's lowest dielectric resin. Resin Properties Dielectric Constant 2.70 at 10 GHz Loss Tangent 0.001 at 10 GHz Quartz Laminate Dielectric Constant 3.0 at 10 GHz Loss Tangent 0.001 at 10 GHz • Optimal mechanicals, low microcracking, high radiation Neat Resin Properties resistance and low moisture aborption. High level Dielectric Constant 2.8 at 10 GHz of cure at 250°F/121°C. High Tg from post cure at Loss Tangent 0.004 at 10 GHz 350°F/177°C. • Very low moisture absorption, toughened • Excellent mechanical properties Resin Properties Dielectric Constant 2.8 GHz at 10 GHz Loss Tangent 0.008 at 10 GHz • Good balance of toughness and high temperature performance with good modulus retention after radiation exposure. • Features RS-3C a controlled flow version for vacuum bag/oven cure RS-3M, very low flow autoclave version. Resin Properties Dielectric Constant 2.67 at 9.375 GHz Loss Tangent 0.004 at 9.375 GHz Quartz Laminate Dielectric Constant 3.188 at 9.375 GHz Loss Tangent 0.0051 at 9.375 GHz ADVANCED COMPOSITES | Selector guide 17 << Table of Contents Prepregs Product Name Resin Type Tg Cure Temp/ Cure Time Description Key Resin Characteristics Cyanate Ester 390°F/199°C or • 120 minutes at 380°F/193°C Optional post cure of 240 590°F/310°C minutes at 550°F/288°C with post cure • Controlled flow with long out time. Very high temperature properties Resin Properties Dielectric Constant 3.17 at 9.375 GHz Loss Tangent 0.005 at 9.375 GHz Quartz Laminate Dielectric Constant 3.385 at 9.375 GHz Loss Tangent 0.0089 at 9.375 GHz Cyanate Ester 293°F/190°C or • 300 minutes at 265°F/129°C Optional post cure of 95 322°F/161°C minutes at 310°F/154°C with post cure • A moderate tack prepreg with low cure shrinkage, ability to cure at 265°F, low moisture absorption, excellent modulus retention after radiation Resin Properties Dielectric Constant 2.76 at 9.375 GHz Loss Tangent 0.006 at 9.375 GHz Quartz Laminate Dielectric Constant 3.223 at 9.375 GHz Loss Tangent 0.0056 at 9.375 GHz RS - 17B Modified Epoxy 341°F/172°C or • 120 minutes at 275°F/135°C Optional post cure of 120 390°F/199°C minutes at 325°F/163°C with post cure • Very low moisture absorption with balanced mechanical, toughness and modulus Resin Properties Dielectric Constant 3.1 at 9.375 GHz Loss Tangent 0.016 at 9.375 GHz Quartz Laminate Dielectric Constant 3.2 at 9.375 GHz Loss Tangent 0.0098 at 9.375 GHz RS - 36 Epoxy • Epoxy with excellent properties and lower costs than cyanate esters, vacuum processible, and low moisture absorption Quartz Laminate Dielectric Constant 3.492 at 9.375 GHz Loss Tangent 0.0122 at 9.375 GHz RS-9D RS-12B 379°F/193°C • 90 minutes at 350°F/177°C TC410 NEW Cyanate Ester 234°F/112°C or • 3 hours at 250°F/121°C Optional post cure at 358°F/181°C 350°F/177°C with post cure • • • • • TC420 NEW Cyanate Ester 350°F/177°C or • 3 hours at 350°F/177°C Optional post cure at 610°F/321°C 500°F/260°C with post cure • Very high temperature service • Good resistance to microcracking • Out of autoclave processding 18 ADVANCED COMPOSITES | Selector guide Low stress free cure temperature capable Resin is low in moisture sensitiveity Outgassing Data Passes and exceeds space requirements for outgassing • TML: 0.29%, CVCM 0.01% Low CTE and CME WVR: 0.17% Extremely low moisture absorption. Resin is asymptotic • CME: 1205 ppm/% m after 200 days with less than 0.35% moisture absorption in a 75% RH environment. Ultra high temperature performance << Table of Contents Film Adhesives Product Name Resin Type EX-1516 Cyanate Ester EX-1543 Cyanate Ester RS-4A Cyanate Ester Tg 250°F/121°C Cure Temp/ Cure Time • 300 minutes at 250°F/121°C 500°F/260°C • 60-90 minutes at 350°F/175°C Optional postcure of 120 with post cure minutes at 450°F/232°C Description Key Resin Characteristics • Toughened cyanate ester with low cure temperature • Features low cure shrinkage • Low outgassing, good resistance to microcracking and resistance to severe environmental and radiation exposure Resin Properties Dielectric Constant 2.6-2.7 at 10 GHz Loss Tangent 0.005-0.006 at 10 GHz Compatible resin film adhesive with: • Low cure shrinkage • Low moisture absorption • Low outgassing and resistance to cyclic microcracking Resin Properties Dielectric Constant 2.75 at 10 GHz Loss Tangent 0.003 at 10 GHz Resin Properties Dielectric Constant 2.98 at 10 GHz Dielectric Constant 0.014 at 10 GHz 397°F/203°C • 120 minutes at 350°F/177°C • Low tack version, with low cure shrinkage • Good balance of toughness and mechanical strength • Low moisture absorption, low microcracking, reticulatable for lightweight core bonding Paste Adhesives EX-1502-1 Cyanate Ester 260°F/127°C • 300 minutes at 250°F/121°C • Two part paste adhesive, good mechanical performance. Ideal for cryogenic and space applications. See data sheet for properties. EX-1537 Cyanate Ester 405°F/207°C • 120 minutes at 350°F/177°C • Thixotropic two part paste adhesive See data sheet for properties. EX-1537-1 Cyanate Ester 405°F/207°C • 120 minutes at 350°F/177°C • Low viscosity unfilled version of EX-1537 See data sheet for properties. Syntactics Films EX-1541 Cyanate Ester 350°F/177°C • 90-120 minutes at 350°F/177°C • One part syntactic paste available in five different densities: 11, 13, 17.5, 20 and 24 pcf. Ideal to be used as a foam core. Low outgassing. CTE 7.4x10-6 in/in/°F SF-5 Cyanate Ester 349°F/176°C • 120 minutes at 350°F/177°C Optional post cure of 120 minutes at 450°F/232°C • Syntactic film compatible with cyanate ester prepregs 38 pcf density / 0.61 g/cc EX-1510 Cyanate Ester 500°F/260°C • 120 minutes at 350°F/177°C Optional post cure of 120 minutes at 480°F/249°C • Toughened resin system with very low 150 cps viscosity at 77°F/25°C Moisture Absorption • Good mechanical properties and thermal properties 1.4% at saturation • Low moisture absorption EX-1545 Cyanate Ester 345°F/173°C • 90 minutes at 350°F/177°C Optional post cure at 400°F/204°C • Toughened resin system, two part system • Full properties with 350°F/177°C cure • Low viscosity of 140 cps at 110°F/43°C RTM Resins Moisture Absorption 0.85% after 24 hr water boil. Viscosity at 110°F/43°C is 62 cps ADVANCED COMPOSITES | Selector guide 19 INTERIORS << Table of Contents Fire retardant structural materials TenCate’s Cetex® PPS and PEI based thermoplastic laminates and unitapes are used in a wide variety of aircraft structure ranging from floor panels, keel beams, luggage bins and galley’s. Thermoplastics offer very low FST properties, are easily formable and offer productivity savings with short mold cycles, high quality finishes off tool, excellent moisture resistance and durability. Lightweight option used on current commercial aircraft. TenCate Cetex® PEI skins TenCate Cetex System3 panels represent honeycomb core stiffened panels based upon thermoplastic skins, thermoplastic honeycomb core and thermoplastic adhesives. These honeycomb stiffened panels are used for flooring, seating plynths, galley’s and luggage bins. They possess high strength, lightweight, formability with heat while being fire resistant for interior applications ® Thermoplastic film adhesive Thermoplastic PEI core TenCate Cetex® System3 represents a combination of TenCate Cetex® RTL thermoplastic skins, thermoplastic core and a thermo-plastic adhesive for interior panel construction in luggage bins, galleys and flooring. Thermoplastic fasteners are friction-welded, minimizing core fill and lightening the panel weight. 20 ADVANCED COMPOSITES | Selector guide MATERIAL SELECTOR GUIDE: INTERIORS << Table of Contents Prepregs Product Name TenCate Cetex® TC1000 Resin Type Polyethermide (PEI) Cure Temp/ Cure Time Tg 419°F/215°C Description Key Resin Characteristics • Process temp - 600°F/315°C • This is a PEI based resin either on glass or carbon exhibits high temperature capability and features: • Low flammability - V-0 • Good impact toughness See data sheet for details. • Low moisture absorption of 1.25% • Qualified at Airbus and Boeing • Ideal for interior applications ranging from floor panels, to seat plyths, to luggage bins TenCate Cetex® TC1100 Polyphenylene Sulfide (PPS) 194°F/90°C • Process temp - 625°F/330°C • TenCate Cetex® 1100 either on glass or carbon exhibits moderate temperature capability and features: • High impact resistance • Low flammability See data sheet for details. • Very low moisture aborption of 0.02% • Ideal for leading edges, structural aircraft parts including interior beams and floor panels • TenCate Cetex® TC1100 represents thermoplastic unitapes either glass, carbon or aramid with PPS resin TenCate Cetex® TC925 Polycarbonate (PC) 307°F/153°C • Process temp - 437°F/225°C • TenCate Cetex® TC925 is a lower cost thermoplastic for value oriented interior applications TenCate Cetex® TC1200 PEEK Polyetheretherketone (PEEK) 290°F/143°C • Process temp - 725°F/385°C • TenCate Cetex® TC1200 represents thermoplastic unitapes either glass, carbon or See data sheet for details. aramid with PEEK resin See TenCate Cetex® System3 brochure for details. See data sheet for details. TenCate Cetex® System3 Polyetherimide (PEI) N/A • Mold temp - 300°F/150°C • TenCate Cetex® System3 represents a thermoplastic honeycomb core stiffened panel using: • TenCate Cetex® PEI thermoplastic skins, • PEI thermoplastic honeycomb core with a thermoplastic film adhesive TC550 Epoxy 246°F/119°C • 75 minutes at 280°F/138°C • TenCate's newest low FST prepreg for interiors, meets 12 second vertical burn See data sheet for details. PEI Thermoplastic Core PEI N/A • Low FST • Available in several densities from 3-9 pcf • Low moisture absorption Call for details. Thermoplastic Adhesive Various N/A • Lightweight • Low moisture absorption Call for details. Ancillary Materials N/A • Melt temp - 230°F/110°C Thermoform process Ten Cate TenCate Cetex® System3 Infra-red heating Cavity Rail Rail stop Tool Heater Insulator ADVANCED COMPOSITES | Selector guide 21 DESIGN & PART SERVICES << Table of Contents Lightweight composite part, design & fabrication TenCate has design tooling and fabrication expertise for compression molded parts. TenCate manufactures bulk molding compounds and specializes in high performance, tight tolerance parts with difficult geometries. TenCate has experience in designing parts for space, aircraft, thermal management and industrial/commercial applications. 350 Various Carbon Fiber Molding Compounds Strength vs Stiffness TEMP9015 MS-4F , CE MS-4A MS-4H MS-1A Lytex 4149 275 Compression molding is a common alternative for complex geometry structure that limits the use of laminate style composites. Typical reinforcements are carbon and glass chopped fiber. TEM9015 1/2” Fiber MS-1H, 1/2” AMC 8590 BMI-760 BMI-760 1/2” 200 Tensile Strength (Mpa) Lytex 4179 1/2” Fiber Enduron 4685 - 1/2” MS-2D “High K” TEM9016 1/4” Fiber 135 Design Rules of Thumb • Tolerance, ± 0.007 - 0.010 inches • Routine wall thickness , 0.05 inches • CTE values, 0-6 ppm/°F 22 ADVANCED COMPOSITES | Selector guide MS-1D Lytex 4181 0 14 28 42 Tensile Modulus (Gpa) 56 70 84 TenCate 98 112 Quantum 126 140 Cytec Bulk Molding Compound << Table of Contents TenCate Chopped Composites for use in Compression Molding Bulk molding compounds allow users to design complex parts to replace metal while maintaing the lightweight, high strength of composites. Bulk Molding Compounds guide is available on our website, and as TenCate iPad, iPhone and now Android Apps. Bulk Molding Compounds Product Name Resin Type Tg Description MS-1A Epoxy 327°F/164°C High modulus epoxy Tensile Strength 42 ksi (290 MPa) Tensile Modulus - 19 msi (131 GPa) MS-1H Epoxy 375°F/190°C Fast cure intermediate modulus epoxy Tensile Strength 37 ksi (255 MPa) Tensile Modulus 10 msi (69 GPa) MS-4A Epoxy 327°F/164°C Standard modulus epoxy Tensile Strength 45 psi (310 MPa) Tensile Modulus 9 msi (62 GPa) MS-4H Epoxy 375°F/191°C Fast cure standard modulus epoxy Tensile Strength 44 ksi (303 MPa) Tensile Modulus 6 msi (41 GPa) MS-4J Epoxy 327°F/164°C Fire retardant standard modulus epoxy Tensile Strength 50 ksi (348 MPa) Tensile Modulus 10 msi (66 GPa) TenCate Cetex® MC1100 PPS PPS Thermoplastic bulk molding compound TenCate Cetex® MC1200 PEEK PEEK Thermoplastic bulk molding compound Resin Properties ADVANCED COMPOSITES | Selector guide 23 HIGH TEMPERATURE << Table of Contents Thermally stable materials High temperature resins are used primarily in military missile and jet engine applications where high temperature thermal stability is required. TenCate offers a variety of special resins which exhibit high performance under extreme temperatures. TenCate competencies include high temperature resin systems. These resin systems are utilized in extreme applications and are used in the hottest components of jet engines and aircraft. The resins are combined with carbon fiber unitapes and fabrics. 24 ADVANCED COMPOSITES | Selector guide MATERIAL SELECTOR GUIDE: HIGH TEMPERATURE << Table of Contents Prepregs Key Resin Characteristics Product Name Resin Type EX-1505 Cyanate Ester RS-8HT BMI RS-9D Cyanate Ester 390°F/199°C or • 120 minutes at 380°F/193°C • Very high temperature properties. Controlled flow with Optional post cure of 240 minutes 700°F/371°C long out time. at 600°F/316°C with post cure Fracture Toughness K1c 0.45MPa-m1/2 TC420 NEW Cyanate Ester • Very high temperature service 350°F/177°C or • 3 hours at 350°F/177°C. Optional • Good resistance to microcracking 610°F/321°C post cure at 500°F/260°C with post cure • Out of autoclave processible Ultra high temperature performance TC800 BMI+ NEW BMI 471°F/244°C Various High Temperature Resins RS-51 AFR PE-4 734°F/390°C Tg Cure Temp/ Cure Time Description 365°F/185°C or • 120 min at 350°F/177°C Optional post cure of 120 minutes at • High temperature prepreg system 682°F/361°C 500°F/260°C with post cure 590°F/310°C • 120 minutes at 400°F/204°C, post cure at 360 minutes at 482°F/250°C • 6 hours at 350°F/177°C, followed by 2 hours post cure at 450°F/230°C N/A • RS-8HT provides excellent elevated temperature properties with good toughness and moisture resistance • Also available as an RTM resin See data sheet Fracture Toughness G1c 1.2 Elongation 1.2% • Out-of-autoclave processible High temperature performance • Extremely high service temperature resins High temperature stability • High temperature cyanate for missile and aircraft structure. High temperature performance with post cure Film Adhesive 350°F/177°C or • 120 minutes at 380°F/193°C Optional post cure at 600°F/300°C 600°F/315°C with post cure RS-53 Cyanate Ester TC4015 NEW Cyanate Ester 350°F/177°C • 120 minutes at 350°F/177°C • Space structures • Ablative bonding • High temperature structures High temperature performance with post cure SF-4 BMI 563°F/295°C • 120 minutes at 400°F/204°C and 360 minutes at 452°F/250°C • Compatible with RS-8HT and other BMI systems Low density syntactic film TCF4001 NEW Cyanate Ester (Syntactic Foam) 350°F/177°C • 120 minutes at 350°F/177°C Optional post cure of 60-90 minutes at 450°F/232°C • Compatible with TC420 • Cyanate ester syntactic foam • Packed or injected into tooling cavities and can also be extruded with the proper tooling Low density syntactic film TCF4050 NEW Cyanate Ester (Core Splice) 350°F/177°C • 120 minutes at 350°F/177°C Optional post cure of 60-90 minutes at 450°F/232°C • Core splice adhesive • Tensile strength up to 500°F/260°C • Compatible with TC420 and EX1505 prepreg resin systems Low density syntactic film 22-26 pcf/ (0.35-0.42 g/cc) Syntactics ADVANCED COMPOSITES | Selector guide 25 Performance Composites << Table of Contents Lightweight structure, replacement of metals for high performance TenCate supplies prepregs materials for a variety of applications in oil & gas, infrastructure, medical and recreational products. Composites have become the material of choice as a result of their lightweight, competitive cost and unique performance attributes. Carbon fiber prepregs allow for lightweight and high stiffness in applications ranging from oil and gas to recreational products. The high performance of carbon fiber combined with cost effective tailored epoxy resins provides a high strength / low cost combination. Thermoplastic reinforced composites provide users with the ability to manufacture high volumes with low cost thermoforming processes. 26 ADVANCED COMPOSITES | Selector guide Oil and gas applications require high performance, ideal for thermoset and thermoplastic resins. MATERIAL SELECTOR GUIDE: Performance Composites << (non aerospace materials) Prepregs Product Name Resin Type Tg BT250E-1 Epoxy 257°F/125°C • 60 minutes at 250°F/121°C • • • • EX-1531A Epoxy 266°F/130°C • 15-20 minute cure at 250°F/121°C • EX-1531A is focused for high production rate hardware. It features gel times and flow characteristics similar to 250°F/121°C cure epoxies 30 days shelf life at 77°F/25°C EX-1548 Epoxy 262°F/128°C • 240 minutes at 200°F/93°C, or • 30 minutes at 235°F/113°C or • 15 minutes at 250°F/121°C • EX-1548 is a quick cure epoxy with extreme toughness 30 day shelf life at 77°F/25°C RS-36 Epoxy 379°F/193°C • • 90 minutes at 350°F/177°C • Epoxy with excellent properties and lower costs than cyanate esters, and low moisture absorption See data sheet for details. TC210 Epoxy 262°F/128°C • 60-120 minutes at 250°F/121°C • Toughened epoxy with good fiber property translation • Ideal for sporting goods • Performs well in roll wrapping applications See data sheet for details. TC900 TC1100 TC1200 Nylon 11 PPS PEEK Various • High performance • Oil & gas, industrial usage See data sheets for details. Cure Temp Various melt temperatures Description BT250E-1 is a good moderate service prepreg Self adhesive to core Good toughness MIL-R-9300 qualified Resin Properties More than 30 day shelf life at 77°F/25°C, 2.0% moisture absorption after 24 hour water boil Performance Thermoplastic Composites Nylon 6 Nylon 6 392°F/200°C • 392°F/200°C* • Ideal for automotive application solvent See data sheet for details. Nylon 11 PA11 122°F/50°C • 113-122°F/45-50°C* • Easy low temperture processing See data sheets for details. PC/ABS Polycarbanate ABS N/A • N/A • Good surface application • UL fire retardent See data sheets for details. PET PET 509°F/265°C • 392°F/200°C* • Good impact resistant See data sheets for details. HDPE Polyethylene 410°F/210°C • 253°F/123°C* • Oil & gas applications for pipe wrapping See data sheets for details. PP Polypropylene 158°F/70°C • 318°F/159°C* • Use in high impact applications like truck bodies See data sheets for details. ADVANCED COMPOSITES | Selector guide 27 RECENT PRODUCT INTRODUCTIONS << Table of Contents Innovation The aerospace industry depends upon innovation from suppliers for new materials and processes. TenCate’s customer focus on tailored systems, combined with our comprehensive lab and testing capabilities allow rapid development, customization and database development. TenCate’s broad experience in thermoset and thermoplastic resins, various composite fibers and part design is how TenCate adds value for our customers. TC250E-6: Epoxy prepreg • High modulus epoxy • Ideal for rotor blades TC350-1: Out-of-autoclave epoxy • Out-of-autoclave • High toughness • Long tool life TC800 BMI+: Out-of-autoclave BMI • Out of autoclave • Low void content • Flexible cure schedule 28 ADVANCED COMPOSITES | Selector guide MS-4J: Low FR BMC • Fire resistant epoxy BMC • Structural • Ideal for interiors TenCate Cetex® TC925: Low cost polycarbonate thermoplastic • Good value • Low OSU • Excellent for interiors TenCate Cetex® MC1200: PEEK-Based BMC • Tough thermoplastic • Impact resistant • Solvent resistant MATERIAL SELECTOR GUIDE: product listing << Table of Contents Prepregs - Thermoset Product Name Resin Type Tg BT250E-1 Epoxy 257°F/125°C • 60 minutes at 250°F/121°C • • • • BT250E-6 NEW Epoxy 268°F/131°C • 120 minutes at 260°F/127°C • High modulus resin system for rotor blade usage • Out of autoclave processible • Toughened epoxy BTCy-1 Cyanate Ester 374°F/190°C or • 90 minutes at 350°F/177°C Optional post cure of 120 461°F/238°C minutes at 450°F/232°C with post cure • Excellent structural properties with low moisture absorption and low outgassing, good resistance to galvanic corrosion. BTCy-1A Cyanate Ester 365°F/185°C or • 120 minutes at 350°F/177°C Optional post cure of 60 400°F/204°C minutes at 400°F/204°C with post cure • Improved toughness version of BTCy-1, very low void content even with low pressure cures BTCy-1C Cyanate Ester 374°F/190°C or • 90 minutes at 350°F/177°C Optional post cure of 60 461°F/238°C minutes at 450°F/232°C with post cure • Longer outime, long shelf life version of BTCy-1 • Excellent structural properties with low moisture absorption and good resistance to galvanic corrosion BTCy-2 Cyanate Ester 375°F/191°C Cure Temp/ Cure Time • 90 minutes at 350°F/177°C Description BT250E-1 is a good moderate service prepreg Self adhesive to core Good toughness MIL-R-9300 qualified • TenCate's lowest dielectric resin. EX-1505 Cyanate Ester 365°F/185°C or • 120 min at 350°F/177°C Optional post cure of 60 682°F/361°C minutes at 500°F/260°C with post cure EX-1515 Cyanate Ester 274°F/134°C or • 180 min at 250°F/121°C Optional post cure of 2 hrs at 360°F/182°C 350°F/177°C for final Tg with post cure EX-1522 Epoxy 396°F/202°C • 120 minutes at 350°F/177°C • Very low moisture absorption, toughened • Excellent mechanical properties EX-1531A Epoxy 266°F/130°C • 15-20 minute cure at 250°F/121°C • EX-1531A is focused for high production rate hardware. It features gel times and flow characteristics similar to 250°F/121°C cure epoxies. EX-1548 Epoxy 262°F/128°C • 240 minutes at 200°F/93°C or; • 30 minutes at 235°F/113°C or; • 15 minutes at 250°F/121°C • EX-1548 is a quick cure epoxy with extreme toughness RS-3 & RS-3C Cyanate Ester RS-8HT BMI 390°F/199°C or • 120 minutes at 350°F/177°C 490°F/254°C Optional post cure of 60 minutes at 450°F/232°C with post cure 590°F/310°C • 120 minutes at 400°F/204°C, post cure of 360 minutes at 482°F/250°C • High temperature prepreg system • Optimal mechanicals, low microcracking, high radiation resistance and low moisture absorption. High level of cure at 250°F/121°C. High Tg from post cure at 350°F/177°C. • Good balance of toughness and high temperature performance with good modulus retention after radiation exposure • Features RS-3C a controlled flow version for vacuum bag/oven cure • RS-3M, very low flow autoclave version • RS-8HT provides excellent elevated temperature properties with good toughness and moisture resistance • Also available as an RTM resin ADVANCED COMPOSITES | Selector guide 29 << Table of Contents Prepregs - Thermoset Product Name Resin Type RS-9D Cyanate Ester 390°F/199°C or • 120 minutes at 380°F/193°C Optional post cure of 240 626°F/330°C minutes at 600°F/316°C with post cure • Very high temperature properties. Controlled flow with long out time. RS-12B Cyanate Ester 290°F/143°C or • 300 minutes at 265°F/129°C Optional post cure of 95 322°F/161°C minutes at 310°F/154°C with post cure • A moderate prepreg with low cure shrinkage, ability to cure at 265°F/129°C, low moisture absorption, excellent modulus retention after radiation RS-17B Modified Epoxy 341°F/172°C or • 120 minutes at 275°F/135°C Optional post cure of 120 335°F/168°C minutes at 325°F/163°C with post cure • Very low moisture absorption with balanced mechanical toughness and modulus RS-36 Epoxy 379°F/193°C • 90 minutes at 350°F/177°C • Epoxy with excellent properties and lower costs than cyanatee sters, and low moisture absorption TC210 Epoxy 262°F/128°C • 60-120 minutes at 250°F/121°C • Toughened epoxy with good fiber property translation • Ideal for sporting goods • Performs well in roll wrapping applications Epoxy 284°F/140°C or 374°F/190°C with post cure • 60 minutes at 190°F/88°C, followed by 120 minutes at 265°F/130°C. Optional post cure of 60 minutes at 350°F/177°C for higher Tg • TC250 is TenCate’s latest 250°F/121°C service prepreg, now in NCAMP qualification. It is designed for vacuum bag cure or autocalve cure. • Good surfacing qualities • Good toughness • Self adhesive to core capability Epoxy 293°F/145°C or • 360 minutes at 275°F/135°C Optional post cure of 120 338°F/170°C minutes at 350°F/177°C with post cure • Designed for very low voids <0.5% in thick parts with out of autoclave vacuum cures. • May be cured at 275°F/135°C or 300°F/350°C (150°F/177°C) Epoxy 293°F/145°C or • 360 minutes at 275°F/135°C Optional post cure of 120 338°F/170°C minutes at 350°F/177°C with post cure • Designed for a very low voids <0.5% in thick parts with out of autoclave vacuum cures. • May be cured at 275°F/135°C or 300°F/350°C (150°F/177°C) TC250 TC275 NEW TC275-1 NEW 30 Tg ADVANCED COMPOSITES | Selector guide Cure Temp/ Cure Time Description << Table of Contents Prepregs - Thermoset Product Name RS-17B TC350 TC350-1 NEW TC410 NEW TC420 NEW TC550 TC800 BMI+ NEW Various High Temperature Resins Resin Type Epoxy Epoxy Cure Temp/ Cure Time Tg 397°F/203°C 397°F/203°C Description • 120 minutes at 350°F/177°C • • • • • • 120 minutes at 350°F/177°C • TC350 is TenCate’s latest 350°F/177°C service out-of-autoclaveprepreg. It is a toughened high temperature prepreg • Low moisture absorption • Good hot/wet performance • Ideal for autoclave or press cure Cyanate Ester 234°F/112°C or • 3 hours at 250°F/121°C Optional post cure at 358°F/181°C 350°F/177°C with post cure Cyanate Ester 350°F/177°C or • 3 hours at 350°F/177°C. Optional post cure at 610°F/321°C 500°F/260°C with post cure • • • • • TC350 is a 350°F/177°C service prepreg. It is a toughened high temperature prepreg Low moisture absorption Good hot/wet performance Ideal for autoclave or press cure Low stress free cure temperature capable Resin is low in moisture sensitivity Passes and exceeds space requirements for outgassing Low CTE and CME Extremely low moisture absorption. Resin is asymptotic after 200 days with less than 0.35% moisture absorption in a 75% RH environment. • Very high temperature service • Good resistance to microcracking • Out of autoclave processible Epoxy 246°F/119°C • 75 minutes at 280°F/138°C • TenCate’s newest low FST prepreg for interior ducts, meets 12 second vertical burn BMI 471°F/244°C • 6 hours at 350°F/177°C, followed by 2 hours post cure at 450°F/230°C • Out-of-autoclave processible RS-51 AFR PE-4 752°F/400°C • N/A • Extremely high service temperature resins TenCate Cetex® RTL - Reinforced Thermoplastic Laminate ADVANCED COMPOSITES | Selector guide 31 << Table of Contents Prepregs - Thermoplastic Product Name Resin Type Tg Cure Temp/ Cure Time Description TenCate Cetex® TC1000 Polyethermide (PEI) 419°F/215°C • Process temp - 600°F/315°C • This is a PEI based resin either on glass or carbon exhibitsh high temperature capability and features: • Low flammability - V-0 • Good impact toughness • Low moisture absorption of 1.25% • Low outgassing • Ideal for interior applications ranging from floor panels, to seat plynths, to luggage bins. TenCate Cetex® TC900 Polyamide PA 11 107°F/42°C • N/A • Good toughness, low cost for industrial applications • Good solvent resistance TenCate Cetex® TC1100 Polyphenylene Sulfide (PPS) 194°F/90°C • Process temp - 625°F/330°C • TenCate Cetex® 1100 either on glass or carbon exhibits moderate temperature capability and features: • High impact resistance • Low flammability • Low moisture absorption of 0.02% • Ideal for leading edges, structural aircraft parts including interior beams and floor panels • TenCate Cetex® TC1100 represents thermoplastic unitapes either glass, carbon or aramid with PPS resin TenCate Cetex® TC925 Polycarbonate (PC) 307°F/153°C • Process temp - 437°F/225°C • TenCate Cetex® TC925 is a lower cost thermoplastic for value oriented interior applications TenCate Cetex® TC1200 PEEK Polyetheretherketone (PEEK) 290°F/143°C • Process temp - 725°F/385°C • TenCate Cetex® TC1200 represents thermoplastic unitapes either glass, carbon or aramid with PEEK resin TenCate Cetex® System3 Polyetherimide (PEI) • Mold temp - 300°F/150°C • TenCate Cetex® System3 represents a thermoplastic honeycomb core stiffened panel using: • TenCate Cetex® PEI thermoplastic skins • PEI thermoplastic honeycomb core with a thermoplastic iflm adhesive N/A Film Adhesives 32 BF508 Epoxy 186°F/86°C • 180 minutes at 180°F/82°C or • BF508 is a toughened 180°F/82°C to 200°F/93°C service temperature resin • 60 minutes at 200°F/93°C, or film adhesive • 15-20 minutes at • Available in both supported and unsupported form 250°F/121°C BF522 Epoxy 365°F/185°C • 120 minutes at 350°F/177°C BF548 Epoxy 262°F/128°C • 240 minutes at 180°F/82°C or • BF548 is a quick cure resin film adhesive, with high toughness and strength 30 minutes at 235°F/113°C, BF548 is a toughened quick cure resin film adhesive. or 15 minutes at 250°F/121°C ADVANCED COMPOSITES | Selector guide • BF522 is a toughened epoxy derived from TenCate's EX-1522 and EX-1549 matrix resins. Features low dielectric and low moisture absorptions. << Table of Contents Film Adhesives Cyanate Ester 250°F/121°C • 300 minutes at 250°F/121°C • Toughened cyanate ester with low cure temperature • Features low cure shrinkage • Low outgassing, good resistance to microcracking and resistance to environmental and radiation exposure. EX-1543 Cyanate Ester 405°F/207°C with post cure • 60-90 minutes at 350°F/175°C Optional post cure of 120 minutes at 400°F/204°C • Compatible resin film adhesive with: • Low cure shrinkage • Low moisture absorption • Low outgassing and resistance to cyclic microcracking RS-4A Cyanate Ester 397°F/203°C • 120 minutes at 350°F/177°C • Low tack version, with low cure shrinkage • Good balance of toughness and mechanical strength • Low moisture absorption, low microcracking, reticulatable for lightweight core bonding RS-15H Epoxy N/A • 30 minutes at 150°F/66°C, or plus 12 hours at 176°F/80°C • Good for cure skin bonding • Low temperature cure capable RS-53 Cyanate Ester 350°F/177°C or 600°F/300°C with post cure • 120 minutes at 380°F/193°C Optional post cure at 600°F/315°C • High temperature cyanate for missile and aircraft structure. TC205 Epoxy 275°F/135°C • 120 minutes at 265°F/130°C. • Compatible toughened resin film for TC250 Epoxy 246°F/119°C • 60 minutes at 250°F/121°C • Vacuum cure composite surfacing film Cyanate Ester 350°F/177°C • 120 minutes at 350°F/177°C • Space structures • Ablative bonding • High temperature structures EX-1510 Cyanate Ester 380°F/193°C or 447°F/230°C with post cure • 120 minutes at 350°F/177°C • Optional post cure of 120 • minutes at 480°F/249°C • • • • EX-1545 Cyanate Ester 345°F/173°C • 90 minutes at 350°F/177°C • Toughened resin system, two part system. Full properties with 350°F/177°C cure. Low viscosity of 140 cps at 110°F/43°C RS-16 Cyanate Ester 332°F/167°C • 120 minutes at 275°F/135°C followed by 120 minutes at 300°F/150°C • Low cure temperature • Two part system RS-50 Epoxy 397°F/203°C • 120 minutes at 350°F/177°C • Toughened epoxy resin for structural applications EX-1502-1 Cyanate Ester 260°F/127°C • 300 minutes at 250°F/121°C • Two part paste adhesive, good mechanical performance • Ideal for cryogenic and space applications EX-1537 Cyanate Ester 405°F/207°C • 120 minutes at 350°F/177°C • Thixotropic two part paste adhesive EX-1537-1 Cyanate Ester 405°F/207°C • 120 minutes at 350°F/177°C • Low viscosity unfilled version of EX-1537 EX-1516 TC235F NEW TC4015 NEW RTM Resins Toughened resin system with very low 150 cps viscosity at 77°F/25°C Good mechanical properties and thermal properties Low moisture absorption 24 hr pot life Paste Adhesives ADVANCED COMPOSITES | Selector guide 33 << Table of Contents Syntactics Product Name Resin Type Tg EX-1541 Cyanate Ester 350°F/177°C • 90-120 minutes at 350°F/177°C • One part syntactic paste available in four different densities: 11, 13, 17.5 and 24 pcf • Ideal to be used as a foam core • Low outgassing SF-4 BMI 563°F/295°C • 120 minutes at 400°F/204°C and 360 minutes at 452°F/250°C • Compatible with RS-8HT and other BMI systems SF-5 Cyanate Ester 349°F/176°C • 120 minutes at 350°F/177°C Optional post cure of 120 minutes at 450°F/232°C • Syntactic film compatible with cyanate ester prepregs TCF4001 Cyanate Ester (Syntactic Foam) 350°F/177°C • 120 minutes at 350°F/177°C Optional post cure of 60-90 minutes at 450°F/232°C • Cyanate ester syntactic foam • Packed or injected into tooling cavities and can also be extruded with the proper tooling Cyanate Ester (Core Splice) 350°F/177°C • 120 minutes at 350°F/177°C Optional post cure of 60-90 minutes at 450°F/232°C • Core splice adhesive • Tensile strength up to 500°F/260°C • Compatible with TC420 and EX1505 prepreg resin systems NEW TCF4050 NEW Cure Temp/ Cure Time Description Bulk Molding Compounds MS-1A Epoxy 327°F/164°C • 280°F/138°C • High modulus epoxy MS-1H Epoxy 375°F/191°C • 280°F/138°C • Fast cure intermediate epoxy MS-4A Epoxy 327°F/164°C • 280°F/138°C • Standard modulus epoxy MS-4H Epoxy 375°F/191°C • 280°F/138°C • Fast cure standard modulus epoxy MS-4J Epoxy 327°F/164°C • 280°F/138°C • Fire retardent standard modulus epoxy TenCate Cetex® MC1100 PPS PPS • Thermoplastic bulk molding compound TenCate Cetex MC1200 PEEK PEEK • Thermoplastic bulk molding compound ® Ancillary Materials PEI Thermoplastic Core PEI N/A • N/A • Low FST • Available in several densities from 3-9 pcf • Low moisture absorption Thermoplastic Adhesive Various N/A • Melt temp - 230°F/110°C • Lightweight • Low moisture absorption 34 ADVANCED COMPOSITES | Selector guide << Table of Contents Performance Thermoplastic Composites Nylon 6 PA6 392°F/200°C 392°F/200°C* • Ideal for automotive application solvent Nylon 11 PA11 122°F/50°C 113-122°F/45-50°C* • Easy low temperture processing PC/ABS Polycarbanate ABS N/A N/A • Good surface application • UL fire retardent PET PET 509°F/265°C 392°F/200°C* • Good impact resistant HDPE Polyethylene 410°F/210°C 253°F/123°C* • Oil & gas applications for pipe wrapping PP Polypropylene 158°F/70°C 318°F/159°C* • Use in high impact applications like truck bodies © 2012, Koninklijke Ten Cate nv and/or its subsidiaries This brochure contains proprietary information of Koninklijke TenCate nv and/or its TenCate Cetex, TenCate Thermo-Lite, and all related characters, logo’s and trade subsidiaries (TenCate), including but not limited to trademarks, trade names, and names are claimed and/or registered trademarks and/or trade logo’s of Koninklijke graphic material, as protected by law. Any reproduction, distribution, or sales in Ten Cate nv and/or its subsidiaries. Use of trademarks, trade names and other any form of the content of this brochure without the express written approval of IP rights of TenCate without express written approval of TenCate is strictly TenCate is strictly prohibited. prohibited. All information published in this brochure is selected with the utmost care, however, Photos courtesy of Airbus, Boeing, Cirrus, General Atomics, U.S. Military, NASA no rights whatsoever can be derived from this brochure and/or its content and and ESA. TenCate accepts no liability for it. ADVANCED COMPOSITES | Selector guide 35 advanced composites Ten Cate Advanced Composites bv Campbellweg 30 7443 PV Nijverdal P.O. Box 9 7440 AA Nijverdal The Netherlands Tel: +31 548 633 700 [email protected] Ten Cate Advanced Composites USA, Inc. (TCAC USA) 18410 Butterfield Blvd. Morgan Hill, California 95037 USA Tel: (408) 776-0700 Fax: (408) 776-0107 www.tencate.com 2450 Cordelia Road Fairfield, CA 94534 USA Tel: (707) 359-3400 Fax: (707) 359-3459 [email protected] Ten Cate Performance Composites 1150 Calle Suerte Camarillo CA 93012 USA Tel: + 805 492 1722
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