Product Brochure - Emery Oleochemicals

Bio-Lubricants
Product Brochure
DRIVING INNOVATION in natural-based
lubricants for a sustainable tomorrow
Leader in Natural-Based Chemistries
Sustainable Lubricant Solutions
Emery Oleochemicals is a leading global provider
of high performance and natural-based chemicals
with a Bio-lubricant platform that enables our
customers to formulate innovative and sustainable
lubricant solutions.
Emery Oleochemicals products are used to improve
processing efficiencies, provide outstanding technical
performance, and enhance environmental safety in
lubricant applications including oilfield chemicals,
hydraulic fluids, base oils, greases, and lube base
stocks. We offer environmentally sustainable
products including azelaic acid, pelargonic acid,
dimer acid, isostearic acid, esters, and other types
of natural-based fatty acids and esters.
CREATING VALUE Naturally
We are committed to CREATING VALUE for
you with our combined strengths in global
manufacturing, research and development,
distribution, marketing, and technical know-how.
Uniquely packaged, our competitive advantage
enables us to offer you innovative and competitive
solutions designed to meet your needs.
CONTENTS
AZELAIC ACIDS
Overview
05
Physical Constants of Dicarboxylic Acids
06
Manufacture of Azelaic Acid & Polymer Intermediates
07
Saponification & Metallic Soap Polymers
09
Preferred Global Partner
Lubricants & Greases
11
Emery Oleochemicals is committed to being your
preferred partner in innovative and high performance
natural-based ingredients for lubricant applications
designed for a sustainable tomorrow.
Finishing & Packaging
12
PELARGONIC ACIDS
Overview
14
Applications
15
Metallic Soaps
16
Activated Oxygen Bleaches
17
Finishing & Packaging
18
DIMER ACIDS
Overview
20
Product Information
21
ESTERS
Overview
23
Product Information
24
OILFIELD
Overview & Product Information
26
Release 08/ 2013
Subject to alteration & errors and omissions excepted.
Disclaimer: The information provided herein is for the sole purpose of presenting Emery Oleochemicals, its products and services. It is given without any express or implied representation, guarantee, or warranty of
completeness, correctness or any other kind of assurance.
All products in the text marked with an ® are trademarks of Emery Oleochemicals. The information on product specifications provided herein is only binding to the extent confirmed by Emery Oleochemicals in a
written Sales Agreement. EMERY OLEOCHEMICALS EXPRESSLY DISCLAIMS ANY RESPONSIBILITY FOR THE SUITABILITY OF THE PRODUCTS FOR ANY SPECIFIC OR PARTICULAR PURPOSES INTENDED BY THE USER.
Suggestions for the use and application of the products and guide formulations are given for information purposes only and without commitment. Such suggestions do not release Emery Oleochemicals’ customers
from testing the products as to their suitability for the customer’s intended processes and purposes. Emery Oleochemicals does not assume any liability or risk involved in the use of its products as the conditions of
use are beyond its control. The user of the products is solely responsible for compliance with all laws and regulations applying to the use of the products, including intellectual property rights of third parties.
AZELAIC ACIDS OVERVIEW
Azelaic acid is a 9-carbon, straight chain, saturated, dibasic acid produced commercially by the ozone
oxidation of oleic acid. Its chemical name is 1,9-nonanedioic acid, or heptane-1, 7-carboxylic acid.
(FIGURE 1)
Azelaic Acids
Azelaic acid is a crystalline, opaque-white
solid, soluble in hot water, alcohols, diethyl
ether, and other polar solvents, as shown in
Table 1. The two carboxyl groups of azelaic
acid limit its solubility in nonpolar solvents
such as naphtha or carbon tetrachloride.
The monomeric derivatives of azelaic acid
generally have lower melting points and
greater solubilities than the corresponding
derivatives of even-carbon dicarboxylic acids.
The influence of the odd-carbon structure
on melting points and physical properties
of aliphatic dibasic acids is shown in Table
2. Table 3 shows the influence of the oddcarbon structure on the melting points of
some simple (monomeric) derivatives.
As Table 3 indicates, the monomeric
azelaic derivative in each instance has a
lower melting point than either of the
corresponding adipic or sebacic derivatives.
Azelaic acid is the preferred aliphatic dibasic
acid for the preparation and modification
of high molecular weight polymers in many
industries. Unlike petroleum based adipic
acid, azelaic acid is derived from replenishable
oleochemical raw materials. Furthermore,
its odd-carbon structure imparts unique
properties to polymers and derivatives that
can be utilized advantageously.
TABLE 1
SOLUBILITY OF EMEROX® 1144 AT 27ºC
FIGURE 1
4
SOLVENT
WT. %
WATER
0.52
ACETONE
1.40
ETHYL ETHER
2.70
TOULENE
5.70
ETHANOL
54.0
DIMETHYLFORMAMIDE
137
5
MANUFACTURE OF AZELAIC ACID & POLYMER INTERMEDIATES
PHYSICAL CONSTANTS OF DICARBOXYLIC ACIDS
TABLE 2
PHYSICAL CONSTANTS OF DICARBOXYLIC ACIDS
FORMULA
SOLUBILITY IN H20
@20°C, G/100G
M.P.ºC
B.P.ºC
IONIZATION
CONSTANT, K1
SUCCINIC
(CH2)2(COOH)2
6.9
185.0
234
4.6X10-5
GLUTARIC
(CH2)3(COOH)2
64.0
99.0
304
6.9X10-5
ADIPIC
(CH2)4(COOH)2
1.44
153.0
2
265
3.7X10-5
PIMELIC
(CH2)5(COOH)2
5.00
106.0
2722
3.1X10-5
SUBERIC
(CH2)6(COOH)2
0.16
144.0
2792
3.0X10-5
AZELAIC
(CH2)7(COOH)2
0.24
106.53
2862
2.5X10-5
SEBACIC
(CH2)8(COOH)2
0.10
134.5
2952
2.3X10-5
ACID
TABLE 3
PHYSICAL CONSTANTS OF DICARBOXYLIC ACIDS
ACID ANILIDE, °C
AMIDE, °C
ESTER, °C
P-NITROBENZYL
ESTER, °C
MALONIC (C3)
224
170
85
-
SUCCINIC (C4)
226
242
88
211
GLUTARIC (C5)
224
174
69
137
ADIPIC (C6)
235
220
106
154
PIMELIC (C7)
155
-
-
137
SUBERIC (C8)
187
216
85
144
AZELAIC (C9)
185
175
44
131
SEBACIC (C10)
198
210
72
147
ACID
P-BROMOPHENACYL
The present line of EMEROX® Azelaic Acids is the result of over 60 years of research by Emery
Oleochemicals, pioneer in the commercial development of azelaic acid. Early in this period, an
economical process to split oleic acid into two completely new commercial products, azelaic and
pelargonic acids, was developed. The initial commercial plant was based on the oxidation of oleic acid
by chromic acid. Further pioneering led to Emery Oleochemicals’ unique ozonolysis-oxidation process.
The first commercial ozone plant for the
continuous production of azelaic acid was
completed in 1953. Other plants have since
been erected, adding substantially to capacity.
Emery Oleochemicals is the world’s largest
commercial producer of azelaic acid, as well
as the world’s largest industrial producer and
consumer of ozone.
This process uses the powerful reactivity of
ozone to cleave oleic acid into azelaic and
pelargonic acids. After extensive separation
and purification operations, the azelaic
acids are flaked and packaged for shipment
in 25 kilogram multiwall paper bags and
700 kilogram Supersacks. A comprehensive
Statistical Quality Control (SQC) program
supplements automatic equipment and
controls throughout the plant to ensure that
each shipment meets specifications.
TABLE 4
SPECIFICATIONS & TYPICAL CHARACTERISTICS OF
EMEROX® 1110, EMEROX® 1112 & EMEROX® 1144 AZELAIC ACIDS
PRODUCT
EMEROX® 1110 EMEROX® 1112 EMEROX® 1144
AZELAIC ACID AZELAIC ACID AZELAIC ACID
SPECIFICATIONS
ACID VALUE, MgKOH/g
COLOR, % TRANS
440/550 nm min.
576 - 591
574 - 591
587 - 594
68/85
80/97
95/99
AZELAIC ACID, %, MIN.
-
-
88
MONOBASIC ACID, %, MAX.
-
0.30
0.05
96
96
95
96 - 103
99 - 100
100 - 102
DIBASIC ACID <C9
7
3
4
DIBASIC ACID C9
79
85
89
DIBASIC ACID >C9
12
12
7
MONOBASIC ACID
2
0.1
0.03
TYPICAL CHARACTERISTICS
EQUIVALENT WEIGHT, g/eq
MELTING POINT, ºC
COMPOSITION (GLC wt %)
Commercial Azelaic Acids
EMEROX® Azelaic Acids are available to meet
the product quality and cost/performance
relationships required for specific applications.
EMEROX® Azelaic Acids are marketed in both
technical and polymer grades. Specifications
and typical characteristics of Emery
Oleochemicals’ azelaic acids are listed
in Table 4.
6
7
Saponification & Metallic Soap Polymers
EMEROX® 1110
A technical grade of azelaic acid which
typically contains 79% azelaic acid, 19%
other dibasic acids and 2% monobasic
acids. EMEROX® 1110 has found extensive
application in the preparation of lowtemperature and polymeric type vinyl
plasticizers, ester-based synthetic lubricants,
and lithium complex grease.
EMEROX® 1112
A grade of azelaic acid which typically contains
85% azelaic acid, 15% other dibasic acids and
0.1% monobasic acids. EMEROX® 1112 has
found extensive application in the preparation
of low-temperature and polymeric type vinyl
plasticizers, ester-based synthetic lubricants,
and lithium complex grease.
FIGURE 2
EMEROX® 1144
This is the purest grade of azelaic acid
commercially available, and was developed
specifically for the preparation and
modification of high molecular weight
polymers. It contains approximately 89%
azelaic acid, 11% other dibasic acids, and a
maximum monobasic acid content of 0.05%
The introduction of a linear odd-carbon
structure of EMEROX® 1144 usually improves
the polymer low-temperature impact
strength, without sacrificing high temperature
performance. For example, 6,9 nylons based
on EMEROX® 1144 possess excellent abrasion
resistance, low water absorption, high impact
resistance, and an excellent overall balance
of properties.
Functional esters of EMEROX® 1144 can be
used as components in urethanes and as a
source of soft segments in co-polyester fibers,
imparting good low temperature performance
and hydrolytic resistance.
Reactions of Azelaic Acid
Reactions of the carboxyl groups of azelaic
acid are by far the most important and are
typical of any aliphatic carboxylic acid. Since
azelaic acid is difunctional, mixed derivatives
such as acid esters, acid amides, and amide
esters can be prepared. In addition, polymers
can be formed by the reaction of azelaic acid
with polyols or polyamines.
8
Azelaic acid saponifies readily with alkali
metals to form alkali metal salts which are
highly water soluble, but which exhibit no
detergency. Salts of calcium, magnesium,
aluminum, and other metals are insoluble in
water and in common organic solvents. Basic
oxides of multivalent metals such as ZnO will
react with azelaic acid to form polymers.
Esterification FIGURE 3
Monohydric alcohols react with azelaic acid
to form relatively high boiling diesters. These
diesters are efficient plasticizers and impart
excellent low temperature flexibility to
vinyls, cellulosics, and neoprene, nitrile,
and butadiene-styrene rubbers. They are
also used as base fluids for synthetic
lubricants and greases where they exhibit
excellent viscosity/temperature relationships
and provide excellent lubrication over wide
temperature ranges.
Glycols and other polyols react with azelaic
acid to yield polyesters. If the resulting
polyester contains an excess of reactive
groups, it can react further with crosslinking agents or extenders. Polyurethane
resins result from the chain extension of
hydroxyl terminated azelaic polyesters with
diisocyanates of isocyanate prepolymers.
Amidation FIGURE 4
Linear polyamides, formed by the reaction of
azelaic acid with diamines, are an increasingly
important group of polymers. These
polyamides usually require polymer grade
EMEROX® 1144 Azelaic Acid which can act
either as the principal dibasic acid component
(e.g., 6,9 nylon) or as a dibasic acid modifier.
Polyamides are also produced by reacting
azelanitrile with formaldehyde. The resulting
poly (methylene azelamide) is reported
to have properties similar to those of
commercial poly (hexamethylene adipamide).
Under suitable conditions, ammonia and
primary or secondary amines react with
azelaic and its derivatives to form amides.
The simplest is azelamide which melts
around 175°C.
Reduction FIGURE 5
Reduction by sodium, hydrogenation over
cupric chromite, or high pressure reduction
of the diester yields the corresponding glycol
(1,9-nonanediol).
This alcohol has a melting point of
approximately 45º and is insoluble in both
water and petroleum ether. The hydroxyl acid
(9-hydroxynonanoic acid) can also be formed
and exhibits solubilities similar to that of
1,9-nonanediol.
Acid Chloride FIGURE 6
Reaction with phosphorus pentachloride or
with thionyl chloride yields the acid chloride
of azelaic acid. This acid chloride may then be
used in the preparation of other derivatives.
9
FIGURE 2
LUBRICANTS & GREASES
Since petroleum oils fail to function effectively over extremely wide temperature ranges, such as those
encountered in the operation of aircraft gas turbine engines, demand for ester-based synthetic lubricants
have shown steady growth. Synthetic basestocks made from azelate diesters exhibit extremely good
viscosity/temperature relationships and therefore outperform petroleum oils in this area.
FIGURE 3
FIGURE 4
FIGURE 5
Among other important advantages of azelate
diesters are low viscosity rise during oxidation,
a low order of corrosive breakdown products,
excellent overall lubricity, low coking
characteristics, high flash points, good additive
response and low peroxide values.
Compounded lubricants and greases
incorporating azelate basestocks are used in
military and commercial aircraft engines of
the turbojet, turbofan, and turboprop varieties
for stationary jet engines, for electrical and
other power requirements, for aircraft and
space vehicle instruments, and for other
equipment and instrumentation requiring
maximum lubrication performance over a
broad temperature range.
Azelaic acid is finding increasing application as a
complexing agent for lithium complex grease.
Other Applications
Among the many miscellaneous applications
of azelaic acid are dielectric fluids, heattransfer fluids, metal to glass fluxes, emulsion
breakers, fungicides, mothproofing agents,
insecticides, polyurethane foams, waxes,
hydraulic fluids, tobacco sheet plasticizers,
special alkyd resins, hot-melt coatings and
adhesives, and water soluble coating resins.
The number of additional patents issued
which are related to the use of azelaic acid
has grown from year to year.
FIGURE 6
10
11
APPLICATION OVERVIEW
PRODUCT
DESCRIPTION
LUBRICANT
BASESTOCKS
LITHIUM
COMPLEX
GREASE
EMEROX ®1110
Azelaic Acid (79% C9D)
x
x
EMEROX® 1112
Azelaic Acid (85% C9D)
x
x
EMEROX® 1144
Azelaic Acid (89% C9D)
x
x
EMEROX® 1175
Azelaic Acid
(70% C9D; 10% C11D)
EMEROX® 1185
Azelaic Acid
(44% C9D, 46% C11D))
EMEROX® 1101
Azelaic Acid
(C6D, C7D, C8D, C9D)
CORROSION
INHIBITORS
FUEL
ADDITIVES
OILFIELD
CHEMICALS
METAL
CLEANING
x
x
x
x
Pelargonic Acids
x
FINISHING & PACKAGING
Food Contact Uses of
Azelaic Acid Derivatives
The following is a list of regulations related
to indirect food contact uses of products
incorporating azelaic acid. Please refer
to Chapter 21 of the Code of Federal
Regulations for specific regulations
including any limitations.
CFR 175.105
Adhesives
CFR 175.320
Resinous and polymeric
coatings for polyolefin films
CFR 177.1390 Polymers
CFR 177.1395 Laminate structures for use
at temperatures between
120°F and 250°F
CFR 177.1500 Nylon resin
CFR 177.1630 Polyethylene phthalate
polymers (film modifier)
CFR 178.3740 Plasticizers in polymeric
substances
CFR 178.3910 Surface lubricants for
the manufacture of
metallic articles
12
Emery Oleochemicals has complied with the
initial inventory requirements of the Toxic
Substances Control Act (TSCA), P.L. 94-469
(90 STAT 2003, 15 U.S.C. 2607 (a), Subsection
8 (b).
Product
1144
1112
1110
CASRN
123-99-9
123-99-9
123-99-9
Technical Service
The information presented in this bulletin
has necessarily been general in nature. Emery
Oleochemicals is prepared to offer counsel
and assistance for your specific azelaic acid
applications. In addition to the products
discussed in this brochure, research efforts
are continuously underway to provide the
industry with new and unique intermediates
for new applications. Any technical questions
pertaining to Emery Oleochemical products
or their performance in your operation will
receive immediate attention.
13
PELARGONIC ACIDS OVERVIEW
Pelargonic acid is a 9-carbon, straight chain, saturated, monobasic acid produced commercially by
Emery Oleochemicals by the ozone oxidation of oleic acid. Its chemical name is nonanoic acid, CAS
number 112- 05-0. (FIGURE 7)
Pelargonic acid is a clear, light colored,
monobasic acid which is liquid at room
temperature. Pelargonic acid derives unique
performance characteristics from its oddcarbon chain length, providing definite
advantages in many quality and performancesensitive applications over short-chain fatty
acids obtained from imported coconut oil.
The nine-carbon structure differs from the
even-carbon chains of coconut fatty acids,
imparting pelargonic acid and its derivatives
with significantly different solubility
characteristics, lower-temperature fluidity,
and low melting points.
Emery Oleochemicals manufactures three
different grades of pelargonic acid: EMERY®
1202 Pelargonic Acid, EMERY® 1203-A
Pelargonic Acid (high purity), and EMERY®
1210 Low Molecular Weight Acids. These
three grades differ in composition as shown
by the representative gas chromatographic
analysis given in Table 5.
Pelargonic acid is used extensively in the
manufacture of low-temperature vinyl
plasticizers and synthetic lubricants with lowtemperature capabilities. The performance of
EMERY® 1202 has been especially outstanding
in high-bake alkyds where hardness,
nonyellowing, and flexibility properties
show substantial improvement.
14
FIGURE 7
TABLE 5
GAS CHROMATAGRPHIC ANALYSIS OF EMERY® PELARGONIC ACIDS
EMERY® 1202
PELARGONIC ACID
EMERY® 1203-A
PELARGONIC ACID
(HIGH PURITY)
EMERY® 1210
LMW ACIDS
CAPROIC ACID (C5H11COOH)
<1
-
27
HEPTANOIC ACID (C6H13COOH)
1
-
31
COMPOSITION, (GLC WT. %)
MONOBASIC ACID
CAPRYLIC ACID (C7H15COOH)
4
<1
12
PELARGONIC ACID (C8H17COOH)
93
98
27
OTHER
2
<1
3
Chemical & Physical Properties
EMERY® Pelargonic Acids are similar in many of
the physical and chemical properties to other
liquid fatty acids. Being completely saturated,
however, they have no double bonds as points
of instability.
Solubility
Pelargonic acid is sparingly soluble in water,
but readily soluble in most organic solvents.
Reactions
The chemical reactions of pelargonic acid at the
carboxyl group involve basic fatty acid chemistry.
The lower molecular weight and odd-carbon
chain length of EMERY® Pelargonic Acids
result in compounds that have markedly
different physical and chemical properties
from those obtained from acids of higher
molecular weight, such as lauric, myristic,
palmitic and stearic.
APPLICATIONS
Synthetic Lubricants
Amine Condensates
The linear, highly saturated and oddcarbon structure of pelargonic acid makes
it particularly suitable as the major acid
component in TMP (trimethylolpropane), PE
(pentaerythritol) and NPG (neopentyl glycol)
polyol esters. These classic polyol structures
dominate jet engine lubricant technology,
and are becoming more important in
synthetic lubricants for industrial and land
transportation applications.
Amine condensates prepared by reacting
EMERY® 1202 with low molecular weight
amines such as monoethanolamine or
isopropanolamine are characterized with
good water solubility.
Emery Oleochemical technical service
representatives are available to assist in the
development of pelargonate polyol esters
for applications in this technology.
The water solubility characteristics of EMERY®
1202 amine condensates can be extended to
blends made with other amine condensates.
Thus, the gellation tendencies of other low
molecular weight amine condensates can
be reduced by partial replacement with the
pelargonic acid counterpart.
The alkali metal salts of EMERY® 1202 are very
soluble in water, but are insoluble in most
organic solvents even with an excess of fatty
acid. Detergency of the short chain length
salts is quite limited. The calcium and heavy
metal salts are insoluble in water.
15
TABLE 6
SPECIFICATIONS OF EMERY® PELARGONIC ACIDS
PRODUCT
ACID VALUE, MG KOH/G
IODINE VALUE (WIJS), MAX
COLOR, PT-CO (APHA), MAX
COLOR, % TRANS, 440/550 NM, MIN
EMERY® 1202
PELARGONIC ACID
EMERY® 1203-A
PELARGONIC ACID
(HIGH PURITY)
EMERY® 1210
LMW ACIDS
345 - 355
345 - 355
400 - 430
0.5
0.5
1.5
-
50
-
90/99
-
90/96
PELARGONIC ACID, %, MIN
90
98
-
IRON, PPM, MAX
1.0
1.0
-
WATER, WT. %, MAX
0.2
0.1
-
8 - 11
-
-
TITER, °C
METALLIC SOAPS
The metallic soaps of pelargonic acids may be made by direct fusion or by double decomposition.
Generally, double decomposition is preferred, resulting in lighter colored and purer end-products. The
mixed barium-cadmium soaps of EMERY® 1202 are effective stabilizers for polyvinyl chloride resins,
particularly when used in conjunction with a chelating type stabilizer. The use of this mixed soap is
more effective than barium-cadmium laurate since it provides plasticized PVC with better resistance
to ultraviolet and heat degradation.
Handling
Pelargonic acid is derivatized with a material
that can serve as a leaving group. This
derivative is then mixed into a detergent
along with an oxygen bleach source, such as
sodium perborate. In the wash, the derivative
undergoes perhydrolysis to generate a
peracid (or peroxygenated acid), which serves
as a more effective bleaching agent than
the peroxide generated from the sodium
perbonate alone.
Pelargonic acid is more irritating to the skin
than the high molecular weight liquid fatty
acids such as oleic acid. The use of protective
eyewear and gloves is recommended in
handling to prevent eye contact and extended
skin exposure. Removal from the skin can be
accomplished by washing with soap and water,
and medical attention should be obtained.
The following study to determine the
corrosive and irritative potentials of EMERY®
1202 Pelargonic Acid was performed by an
independent testing laboratory:
Reduction Products
Pelargonic acid can be reduced to
yield pelargonaldehyde or n-nonanol.
Pelargonaldehyde, which has an orange-rose
odor, is used in perfumes, as well as flavors.
Peroxides
Pelargonyl peroxide can be used as a catalyst
in the polymerization of vinyl chloride.
Flotation
Pelargonic acid is an efficient frothing agent
in the separation of certain ores via the
flotation process.
TABLE 7
TYPICAL CHARACTERISTICS OF EMERY® PELARGONIC ACIDS
EMERY® 1202
PELARGONIC ACID
EMERY® 1203-A
PELARGONIC ACID
(HIGH PURITY)
EMERY® 1210
LMW ACIDS
SPECIFIC GRAVITY, 25/25°C
0.904
0.904
0.916
50/25°C
0.883
0.883
-
100/25°C
0.848
0.848
-
4.75
4.75
-
BOILING POINT, 760 mm Hg. °C
230 - 237
230 - 237
224
BOILING POINT, 4 mm Hg, °C
117 - 125
117 - 125
-
140
140
110
PRODUCT
VISCOSITY, AT 37.8°C, cSt.
FLASH POINT, °C
FIRE POINT, °C
146
146
-
UNSAPONIFIABLE CONTENT, %
0.15
0.15
0.15
WATER, %
0.01
0.01
0.01
ASH, PPM
<25
<25
<25
16
Activated Oxygen Bleaches
1. The corrosive potential of EMERY® 1202
Pelargonic Acid was evaluated in accordance
with the procedure described in Section
173l240 under Title 49 of the Code of
Federal Regulations (Federal Register,
February 12, 1973). EMERY® 1202 Pelargonic
Acid produced the corrosive effects of
blanching, necrosis, and skin thickening at
the majority of sites. Based on these results,
EMERY® 1202 is classified as a corrosive
material as this term is defined in the abovecited regulations.
2. EMERY® 1202 Pelargonic Acid applied
to the eyes of albino rabbits produced
marked irritation. Irritative signs included
iritis, conjunctivitis, and corneal opacity.
The method of Draize (Lehman, A.J., et al,
Appraisal of the Safety of Chemicals in
Foods, Drugs and Cosmetics, Association of
Food and Drug Officials of the U.S., Austin,
Texas, 1959) was used to score the irritative
effects observed in the eye.
17
APPLICATION OVERVIEW
PRODUCT
DESCRIPTION
LUBRICANT
BASESTOCKS
CORROSION
INHIBITORS
METAL CLEANING
EMERY® 1202
Pelargonic Acid (90% C9M)
x
x
x
EMERY® 1203A
Pelargonic Acid (98% C9M)
x
x
x
EMERY® 1210
Pelargonic Acid
(C6,C7, C8, C9)
x
Dimer Acids
FINISHING & PACKAGING
Shipping & Storage
Bulk Storage & Handling
Pelargonic acid is sufficiently reactive with
some metals to necessitate use of corrosionresistant equipment. Aluminum (Alloy 3003)
or baked phenolic lined steel (such as Lastiglas
or Lithcote) are economical materials for
storage tanks, but for reactions at elevated
temperatures, stainless steel (Type 316), glass
or ceramic-lined vessels are recommended.
For major consumers of pelargonic acid, bulk
buying, handling, and storing offer several
economic advantages over the purchasing of
drum quantities. These are realized in a lower
unit purchasing price and in reduced handling
and storage costs.
D.O.T. Classification:
Not Regulated
Shipments of EMERY® Pelargonic Acids
are made in aluminum tankcars, or in
lined 55-gallon drums.
18
For a comprehensive discussion of bulk
handling and storage of EMERY® Pelargonic
Acids, contact a Emery Oleochemicals
representative at one of the locations
listed on the back of this brochure.
19
PRODUCT INFORMATION
DIMER ACIDS OVERVIEW
Emery Oleochemicals is a worldwide leader in Oleochemicals, the class of chemicals made from
natural fats and oils. Emery Oleochemicals uses natural, renewable raw materials; the oils from
soybeans, coconuts and palm kernels as well as fats from tallow, to manufacture an extensive line
of fatty acids, glycerine and oleochemical derivatives.
EMERY® 2003
TECHNICAL
DIMER ACID
EMERY® 2016
DIMER ACID
EMERSOL® 3875
ISOSTEARIC ACID
EMERY® 2932
MONOMER
Clear viscous liquid
Clear viscous liquid
Clear liquid
Clear liquid
180 MIN.
190 - 198
187 - 201
165 - 198
0.5
0.5
0.5
0.5
PRODUCT
SPECIFICATIONS
APPEARANCE, 25°C
ACID VALUE
% MOISTURE, MAX
EMERY® Dimer Acids are the result of the
dimerization of tallow oleic acid to a dibasic
acid containing, on average, a 36 carbon
molecule with two carboxylic acid groups.
Dimer Acids find extensive application in
the areas of Polyamide Resins for Inks and
Adhesives, Curing Agents, Lubricants, Greases,
Oilfield Chemicals, Fuel Additives, Corrosion
Inhibitors, Sealants, Polymer Intermediates
and Personal Care applications.
At Emery Oleochemicals, our salespeople are
experienced and accessible, and our customer
service associates are on hand, in person,
to answer your calls. Our marketing and
technical representatives are ready to provide
not only the products you need, but also
storage and handling advice, formulation and
processing information, and news about our
latest developments.
Emery Oleochemicals Manufactures 4
Dimer Acids:
EMERY® 2003 Technical Dimer Acid —
A general purpose dimer acid where light
color is not critical.
EMERY® 2016 Dimer Acid —
A light-colored general purpose dimer acid.
EMERSOL® 3875 Isostearic Acid —
A light-colored isostearic acid.
EMERY® 2932 Monomer —
A light-colored monomer acid.
COLOR, GARDNER, MAX
8
COLOR, % TRANS, 440/550 NM, MIN
80/85
SAPONIFICATION VALUE
195 - 204
250 - 500
VISCOSITY, CST., 140°F
193 MIN
450 - 510
IODINE VALUE (WIJS), MAX
3 MAX
TITER, °C
10 MAX
40 - 100
TYPICAL PROPERTIES
ACID VALUE
190
201
199
190
SPECIFIC GRAVITY, 25/20°C
0.945
0.945
0.917
0.917
VISCOSITY, CST., 100°F
1,500
1,800
VISCOSITY, CST., 140°F
400
470
VISCOSITY, CST., 210°F
60
75
MONOBASIC ACIDS, %, HPLC
4
4
DIBASIC ACIDS, %, HPLC
80
16
POLYBASIC ACIDS, %, HPLC
ISOSTEARIC ACIDS, %, HPLC
70
APPLICATION OVERVIEW
PRODUCT
DESCRIPTION
LUBRICANT
BASESTOCKS
CORROSION
INHIBITORS
FUEL
ADDITIVE
OILFIELD
CHEMICAL
EMERY® 2003
Dimer Acid (80% C36D)
x
x
x
EMERY® 2016
Dimer Acid (80% C36D)
x
x
x
EMERSOL® 3875
Isostearic Acid
(80% C18 isomers)
x
x
x
EMERY® 2932
Monomer acid
x
x
x
Forms of Delivery
Storage Information
2003 and 2016
412 lb. Drums and bulk containers
Product stored in the original closed
packaging under ambient conditions should
be stable for at least 1 year.
3875 and 2932
400 lb. Drums and bulk containers
20
8
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ESTERS OVERVIEW
Emery Oleochemicals is a worldwide leader in natural-based oleochemical products. Our esters are
the result of the reaction of fatty acids with alcohols and are based on renewable raw materials like
palm/palm kernel, coconut or tallow oils.
Esters
Our product portfolio includes a wide
selection of mono and polyolesters (saturated
and unsaturated). Together with dicarboxylic
acid esters and complex esters, a variety of
lubricant applications can be served.
Emery Oleochemical Esters are environmentally
friendly. They provide good biodegradability
and low aquatic toxicity.
Our Esters are also recognized for good
lubricity and wear protection, with polarity
that results in a high cleaning effect. They are
also miscible in mineral oils and PAO‘s. We
have esters available with high flash points and
low evaporation rates, which reduces the fire
hazard. Emery Esters show good rheological
properties and high viscosity indices. Select
esters show good performance over a wide
range of temperatures.
Based on our long experience in the
ester business, we are looking forward to
developing new and innovative ester solutions
to satisfy our customers needs. Please contact
our marketing and technical representatives
to get more product information and news
about our latest developments.
MONOESTERS
PRODUCT
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DESCRIPTION
DEHYLUB® 1325
2-Ethylhexyltallowate
DEHYLUB® 4002
2-Ethylhexyl-C8-14-ester
DEHYLUB® 4003
2-Ethylhexyllaurate
DEHYLUB® 4003 MY
2-Ethylhexyllaurate (vegetable based)
HYDRAULIC
OILS
METAL
WORKING
STEEL
ROLLING OILS
ALUMINIUM
PROCESSING
x
x
x
x
x
DEHYLUB® 4012
2-Ethylhexyl-oleate
x
DEHYLUB® 4012 MY
2-Ethylhexyl-oleate
x
DEHYLUB® 4018
2-Ethylhexylpalmitate
x
x
x
DEHYLUB® 4018 MY 2-Ethylhexylpalmitate (vegetable based)
x
DEHYLUB® 4033
2-Ethylhexylstearate
x
DEHYLUB® BS 4015
Butylstearate
x
x
DEHYLUB® 4004
Isobutylstearat
x
x
DEHYLUB® 4010
Isotridecylstearate
x
DEHYLUB® 4042 MY
Methylester
x
23
POLYOL ESTERS
PRODUCT
GEAR AND
STEEL
METAL
ALUMINIUM
CHAIN
ENGINE
HYDRAULIC
TRANSMISSION GREASES
WORKING ROLLING
PROCESSING LUBRICANTS OILS
OILS
OILS
OILS
FLUIDS
DESCRIPTION
DEHYLUB® 4016
NPG-dioleate
x
x
x
DEHYLUB® 4016 MY
NPG-dioleate
x
x
x
x
DEHYLUB® 4052
NPG-C8-18-ester
DEHYLUB® 4022
TMP-C8-10-ester
x
DEHYLUB® 4030
TMP-oleate
x
x
x
x
DEHYLUB® 4030 MY
TMP-oleate
(vegetable based)
x
x
x
x
DEHYLUB® 4008
Pentaerythritoldioleate
x
x
DEHYLUB® 4008 MY
Pentaerythritoldioleate
(vegetable based)
x
x
DEHYLUB® 4026
PentaerythritolC8-10-ester
x
DEHYLUB® 4028
Glyceroltrioleate
x
x
x
x
x
x
x
x
DICARBOXYLIC ESTERS
PRODUCT
METAL
WORKING
FLUIDS
HYDRAULIC
FLUIDS
DESCRIPTION
DEHYLUB® 4005
2-Ethylhexylsebacate
DEHYLUB® 1337
Diisotridecyladipate
x
DEHYLUB® 4045
Diisodecyladipate
x
x
ENGINE
OILS
GEAR AND
TRANSMISSION
OILS
GREASES
x
x
x
x
x
x
x
Oilfield
COMPLEX ESTERS
PRODUCT
HYDRAULIC
FLUIDS
DESCRIPTION
DEHYLUB® 4100
Complex Ester
DEHYLUB® 4059
Complex Ester
x
DEHYLUB® 4071
Complex Ester
x
METAL
WORKING
FLUIDS
CHAIN
LUBRICANTS
x
x
ENGINE
OILS
GREASES
x
x
x
x
x
TECHNICAL DATA OF SELECTED ESTERS
DEHYLUB
4018
DEHYLUB
4012
DEHYLUB
4030
DEHYLUB
4026
DEHYLUB
4005
DEHYLUB
4100
COMPOSITION
2-Ethylhexylester
2-Ethylhexyloleate
Trimethylolpropantrioleate
Pentaerythritol
fatty acid ester
2-Ethylhexylsebacate
Complex
ester
APPEARANCE
Clear yellowish
liquid
Clear yellow
liquid
Clear yellow
liquid
Clear light
yellow liquid
Clear
colorless liquid
Clear yellow
liquid
ACID VALUE (MG KOH/G)
SAPONIFICATION VALUE (MG KOH/G)
IODINE VALUE (G I2/100 G)
0 - 0.5
0 - 0.5
0-1
0 - 0.3
0 - 0.2
0 - 0.5
150 - 170
140 - 150
175 - 190
323 - 338
258 - 270
270 - 305
0-2
60 - 71
80 - 90
0 - 0.8
0 - 0.3
0 - 25
0 - 3.5
0-2
0-0.2
#
#
#
<-30
<-40
HYDROXYL VALUE (MG KOH/G)
2-ETHYLHEXYLCONTENT (%)
0 - 0.2
POURPOINT (°C)
DENSITY @ 20°C (G/CM3)
KINEMATIC VISCOSITY
@ 40°C (MM2/S)
24
#
<-70
0.86 - 0.87
0.862 - 0.872
0.914 - 0.920
0.952 - 0.955
@ 25
7.8 - 9.0
7-9
42 - 50
27.5 - 33
0.912 - 0.916
0.96 - 0.98
10.5 - 12.5
425 - 465
25
CREATING VALUE FOR OUR CUSTOMERS,
ANYWHERE IN THE WORLD.
OILFIELD OVERVIEW
Emery Oleochemicals is a global provider of high performance and innovative solutions for oilfield
chemicals. Our products are based on renewable natural resources, thus making oil exploration around
friendly products, without losing performance, even under challenging borehole and formation conditions.
Our business knowledge and technical
expertise in oilfield chemicals span more
than 30 years.
In addition to our commercial products,
technical team, to support both exclusive or
specific needs.
The main applications for our oilfield
chemicals are:
rCarrier Fluids
r&NVMTJưFST
rLubricants
r$MFBOFrs
r3IFPMPHZAdditives
APPLICATION OVERVIEW
PRODUCT
FLUID SYSTEM
DESCRIPTION
FUNCTION
OMC 586 XL
Ester
Carrier fluid
x
OMC 1000
Ester
Carrier fluid
x
OIL BASED
MUDS
WATER BASED
MUDS
FEATURES
GoM permit
Environmentally friendly,
high temperature
applications
T&33A%3*-™ EM 1120
Special surfactant
Emulsifier
x
T&33A%3*-™ EM 1122
Amido amine
Emulsifier
x
T&33A%3*-™ EM 392
Fatty acid
Primary emulsifier
x
DEHYLUB® 1324
Ester based
Lubricant
x
DEHYLUB® 1316
Ester based
Lubricant
DEHYLUB® 1037
Ester based
Lubricant
T&33A%3*-™ S 1118
Surfactant
Borehole cleaner
x
Environmentally friendly
T&33A%3*-™ S 1310
Surfactant
Borehole cleaner
x
Environmentally friendly
T&33A%3*-™ S 809
Surfactant
Borehole cleaner
x
T&33A%3IL™ V 1075
Dimer acid
Low end
rheology modifier
x
T&33A%3*-™ V 300
Fatty acid
Viscosifier
x
T&33A%3*-™ V 988
Special acid
Thinner/ dispersant
x
26
Emery Oleochemicals GmbH
Emery Oleochemicals LLC
Paul-Thomas-Strasse 56, 40599 Düsseldorf, Germany
T | +49 211 5611 2000
F | +49 211 5611 2600
E | [email protected]
4900 Este Avenue, 45232 Cincinnati, OH, USA
T | +1 513 762 2500
F | +1 513 246 3340
E | [email protected]
Emery Oleochemicals (M) Sdn Bhd
x
x
Also for silicate systems
x
Lot 4, Jalan Perak, Kawasan Perusahaan,
42500 Telok Panglima Garang, Selangor, Malaysia
T | +603 3326 8686
F | +603 3326 8787
E | [email protected]
Disclaimer: The content in this document is provided on an “as is” and “as available” basis purely for informational purposes and does not constitute any warranty, whether
express, implied or statutory, including but not limited to warranties or guarantees of merchantability, fitness or suitability for a particular purpose nor any representations of
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advised to carry out any necessary steps to test the suitability of the products for your intended processes and purposes. You are solely responsible for compliance with all
applicable laws and regulations in use of the products including any third party intellectual property rights and shall continue to bear all liability or risk arising from use of the
products. All indications marked with a TM or ® symbol are trademarks belonging to legal entities within the Emery Oleochemicals group of companies.
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