Prof. Dr. Hamdi TEMEL E-mail: [email protected] Web

Prof. Dr. Hamdi TEMEL
E-mail:
[email protected]
Web-Site:
www.hamditemel.com
Research Interest: The synthesis and expanded characterization of various kind Schiff base
ligand have been the important research interest for us. Complexation ability and the other
application properties in physics and biology maintain the investigation of them. Optical and
electrical properties, antibacterial and antifungal properties, and DNA cleavage experiments can be
given as examples of different usability.
The polymer study of the Schiff base ligands is also a novel interest in this field. The
polymerization is conducted with sodium hypochloride media in 10 % of KOH. The polymer
structure is proved with diverse techniques such as FTIR, GPS, and TGA etc.
The Suzuki-Miyaura cross coupling reactions and transfer hydrogenation are one of the main
research subjects for our research team. The catalytic activities of compounds are really important
mission for the industrial developments.
Organic–inorganic hybrid heterojunctions are also fabricated by forming thin films of
ruthenium(II) complexes on n-Si and evaporation of Au as front contact. Current–voltage (I–V)
characteristics of the structures show excellent rectification properties. Electrical parameters
including ideality factor, barrier height and series resistance are determined using I–V and
capacitance–voltage (C–V) data.
Boron compounds and its derivatives are the recent experiments. The synthesis and
characterization of boronic acid compounds with ligands have been investigating since 2012. The
main goal of our study is to increase the usability of boron resources in Turkey which has 70 % of
total in the world.
Environmental protection against harmful and toxic contaminants is one of the most significant
research interests under current conditions in human life. So that our research team work also for
the adsorption of heavy metals such Cu, Co, Cd by natural and modified humic acid compounds.
Also the complexation ability is illuminated.
NH
C
NH
O
R
Mn+
C
Reflux
120 oC
M
X
R
-nH+
(OH)m
O
M=Cu2+
2+
2+
2+
,Cd ,Co ,Ni
X=CH3COO-
Mod-Hum Comp.
proposal
Mod-Hum Complexes
general representetive
of Mod-Hum
Mod-Hum
X
O
The expanded analysis of all compounds is done by our research center’s facilities of DUBTAM.
These can be summarized such; XRD, LC-MS/MS, SEM-EDAX, TGA/DSC, Elemental Analysis,
FTIR, UV-Vis-NIR etc.
Collaborators
Institute of Chemical Sciences named after A.B. Bekturov, Kazakh-British Technical
University, Almaty, Kazakhstan
Hamdi Temel’s Research Group
Master and Doctoral Students
Master Students
PhD Students
Osman OZTURK
Hatice KARA
HAsan KAYA
Salih PASA
Kıvılcım GÖNEN
Eda CAVUS KAYA
Barış KURT
Mustafa A. YILMAZ
Nashwan Aqadhy
Metin ATLAN
Nedim GURLER
Ismail YENER
Mehmet S. SEYITOGLU
Aliya TAUBAEVA(2. Danışman)
Marzhan KUSAİNOVA(2. Danışman)
Hadichahan RAFİKOVA(2. Danışman)
Research Interest
Synthesis of Organic-Inorganic Compounds
HamdiTemel’s research group is interested on various compounds in Chemistry. The
main goal of the group is having a multidisciplinary study with different areas. Schiff base
and their transition complexes, monomer and polymer structures of ligands, boron derivative
compounds, ionic liquids, biodegradable materials can be summarized for the top of the
experiments.
A new structural approach to studying compounds with LC-MS IT-TOF
The HamdiTemel’s research lab combines most of the high technological instruments
to get expanded characterization and analysis for all compounds and materials. For this
purpose the newly joined LC-MS IT-TOF has been using the exact structure analysis with the
general formula of any expected compounds. It has really high resolution, sensitivity and
precision. It can also be used for clinical tests, food analysis and pharmaceutical
investigations.
Res. Assist.
Mehmet Salih SEYİTOĞLU
E-mail:
[email protected]
om
Web-Site:
http://www.siirt.edu.tr/personel_detay.
aspx?pname=+mehmet+salih+seyitoglu
&birim=qwe345th&personel=28824a9
6-d73b-4428-93ac-
f73481d0ba77#.UwT4o_l_us4
Research Interest:
Synthesis and charecterization of polymer-anchored schiff base and
their complexes catalysts for the Suzuki-Miyaura cross-coupling
reaction. Also hybrid device by forming thin films of these
complexes on classical semiconductors and evaporation of Au on the
films. These devices current-voltage measurement under the solar
simulator with AM 1.5 global filter and photodiode devices, a wide
temperature range and temperature sensor based on investigation of
the properties.
B(OH)2
Br
R
Kat.
Baz
R
Res. Assist.
PAŞA
E-mail:
Salih [email protected]
Web-Site:
http://www.dicle.edu.tr/akademikweb/in
dex.php?orta=goster2&gsn=5155&biri
m=7&bolum=8&altbolum=3
Research Interest: The ligands of thio Schiff bases and their transition metal complexes have been
widely investigated and there is currently considerable interest in the coordination chemistry of
polydentate ligands of multifaceted importance and their metal complexes; analytical applications,
synthetic utility and biological activity are of special interest to chemists.
Palladium complexes of some (N,O,S) and (N,O,P) type ligands as they have both type of donor sites,
are already known to show catalytic activity in Suzuki coupling reactions.
And also organic compounds have been used in the fabrication semiconductor devices due to their
unusual electrical, optical, and magnetic properties. Organic–inorganic (OI) semiconductor devices
formed by organic compounds grown on inorganic substrates have extensively been investigated by
many researchers for their potential usage in electronic and optoelectronic technologies.
Boronic acid is one of the unique boric acids bearing alkyl or aryl substituted carbon-boron bonds of the
organoboranes. Boronic acids act as Lewis acids. As a most distinguished aspect of them is the ability to
make reversible covalent bonds with sugars, amino acids, hydroxamic acids(R-CO-NH-OH) or
substituted Lewis base donors (alcohols, amines, carboxylates etc.)
Boron based compounds (boric acid, boronic acid, sodium borohydride etc.) and their derivatives with
various organic ligands have been our one of the most important research subjects. The applicability of
the compounds in physical experiments, pharmacy in the accordance of the spectroscopic data and aldo
the antimicrobial, optical and electrical applications encourage us to focus on this field.
It has also been working of the toxic heavy metals from water with adsorption process by using humic
acid and the zeolite compounds. These studies are the sub research of us that is conducted by the
colloborative partner of Kazakh-British Technical Univeristy under the supervision of Dr. Temel.
The single crystal experiments of obtained compounds during the experiments are also studied. The
exact structure of the crystal data is collected by using a BRUKER APEX II CCD detector with graphite
crystal monochromated Mo Kα radiation from K780 X-ray generator operating at 50 kV and 40 mA.
The structure is solved by direct methods using SHELXS-97 and refined against F2 by full matrix leastsquares using SHELXL-97.
FACILITIES
XRD Powder and Single Diffraction Instruments
LC MS / MS Spectrometer
NMR Instrument (400 MHz)
Scanning Electron Microscope (SEM)
Transmission Electron Microscope (TEM)
Elemental Analysis Instrument
UV-Vis-NIR Spectrophotometer
Thermal Analysis System (TGA / DSC)