Heat transfer and pipe flow
Transcription
Heat transfer and pipe flow
Introduction Mechanisms of heat transfer Heat exchangers Pumps Heat transfer and pipe ow Professor Eric S Fraga Room 2.05 Engineering Front Building Department of Chemical Engineering UCL c 2009 Heat transfer and pipe ow 1 / 104 Introduction Mechanisms of heat transfer Objectives Heat exchangers Pumps What is heat transfer? How is heat transferred? What equipment is used to transfer heat between two uids and how does it work? What is the power required for pumping a uid? Heat transfer and pipe ow 2 / 104 Introduction Mechanisms of heat transfer Heat exchangers Reading material Pumps Coulson, J.M and Richardson J.F. Chemical Engineering Vol. 1, Pergamon Press. Pitts, D. and Sissom, L. Heat Transfer, Schaum's Outlines, McGraw-Hill. Cengel, Y.A. Heat transfer a practical approach, McGraw-Hill. Heat transfer and pipe ow 3 / 104 Introduction Mechanisms of heat transfer Heat exchangers Heat transfer Pumps Heat transfer is concerned with temperature: represents the thermal energy, or heat, that is available, and ow of heat: represents the movement of thermal energy from one place to another. Heat transfer is thermal energy in transit due to a !temperature dierence!. Temperature dierence is the driving force that causes heat to be transferred. Heat transfer plays a major role in the design of process equipment. Heat transfer and pipe ow 4 / 104 Introduction Mechanisms of heat transfer Heat exchangers How is heat transferred? Pumps Heat may be transferred in three dierent ways: conduction transfer of heat as a result of molecular motion and the subsequent transfer of kinetic energy. Conduction is predominant in solid materials and in static uids. convection the ow of heat as a result of macroscopic movement of matter from a hot to a cool region radiation transfer of energy in the form of rays or waves or particles (α, β , γ ) We will consider only conduction and convection. Heat transfer and pipe ow 5 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Conduction through a wall Consider a wall of thickness x and surface area A that has a uniform temperature T1 on one side and T2 on the other: The heat transfer, q (W ), through the wall is k q = A∆T x (1) where k (in mWK ) is the thermal conductivity of the material which gives a measure of the ability of the material to conduct heat and ∆T ≡ T1 − T2 . Heat transfer and pipe ow 6 / 104 Introduction Mechanisms of heat transfer Heat exchangers Thermal conductivity Materials with a large thermal conductivity, Pumps k , are good thermal conductors. These will transfer large amounts of heat over time, e.g. copper. Conversely, materials with low thermal conductivities are poor thermal conductors. These will transfer small amounts of heat over time, e.g. concrete. The ratio k x is called the heat transfer coecient. The inverse of the heat transfer coecient, resistance. x k, is the thermal Heat transfer and pipe ow 7 / 104 Introduction Mechanisms of heat transfer Heat exchangers Composite wall example Pumps Applying eq. 1 to each section of the composite wall: ⇒ k q = i A(Ti − Ti +1 ) i = 1, . . . , 3 xi 1 q = P xi A∆T ki so overall thermal resistance is sum of the individual resistances (analogous to electrical circuits). Heat transfer and pipe ow 8 / 104 Introduction Mechanisms of heat transfer Heat exchangers Heat transfer through convection Pumps Example: heating a pot of water. At rst, when the water is cold and still, it behaves as a solid and heat is transferred by conduction through the bottom of the pot. Bubbles, when created, will transfer heat from the bottom to the top by convection due to buoyancy. Cooler, more dense water at the top will sink to the bottom. Heat transfer and pipe ow 9 / 104 Introduction Mechanisms of heat transfer Heat exchangers Types of convection Pumps Natural convection occurs when the motion of uid is due to buoyancy eects. Example, the cooling of a heated pipe: Forced convection is when the uid motion is produced by an external agent. Heat transfer and pipe ow 10 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Convective heat transfer Heat transfer by convection, q , is q = hA∆T (2) where A (m2 ) is the characteristic area of contact. ∆T ( K ) is the temperature dierence between the solid and the uid. h ( mW2 K ) is the convective heat transfer coecient and is a property of the system, not a property of the uid as is the thermal conductivity, k. Heat transfer and pipe ow 11 / 104 Introduction Mechanisms of heat transfer Heat exchangers Convective heat transfer coecient Pumps The value of h depends on the surface geometry, the properties of the uid and the uid motion regime: Type of convection Material h mW2 K Natural Gases 2-25 Liquids 50-1000 Forced Gases 25-250 Liquids 100-20000 Liquids transfer greater amounts of heat than gases, which are good thermal insulators and forced convection gives greater heat transfer than natural convection for both gases and liquids. Heat transfer and pipe ow 12 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps What aects convective heat transfer? h is a function of the properties of the system and depends on: geometry of the system, i.e. a characteristic length physical properties of the uid: i.e. viscosity, heat capacity, uid regime, i.e. a characteristic velocity To determine µ, cp , and thermal conductivity, k . L. density, ρ, v. h is therefore a complex task and we rely on experiments. Heat transfer and pipe ow 13 / 104 Introduction Mechanisms of heat transfer Heat exchangers Prandtl and Nusselt numbers Pumps The properties of the uids and the dierent forms of heat transfer can be described by some dimensionless numbers: Prandtl the ratio between uid ability to store heat and to transfer heat through conduction, independent of the system geometry: Pr = µ cp k Nusselt ratio between heat transfer through convection and conduction: Nu = hL k Heat transfer and pipe ow 14 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Reynolds and Grashof numbers Other numbers describe uid ow properties: Reynolds The ratio between inertial and viscous forces in the uid which identies the uid ow regime: Re = ρvL µ (3) High values correspond to turbulent ow regime, and therefore to high convection h.t.c. Grashof replaces Re when uid motion is driven by thermal expansion of the uid: Gr = β∆T ρ2 gL3 µ2 where β is the volumetric thermal expansion coecient. Heat transfer and pipe ow 15 / 104 Introduction Mechanisms of heat transfer Heat exchangers Flow patterns and temperature proles Pumps Consider the ow of air over an innite at plate. Ts Tf is the air ow Ts > Tf . is the temperature of the plate, while temperature away from the plate, with Regardless of the type of convection, we analyse the ow pattern and the temperature proles at the wall and away from it. Heat transfer and pipe ow 16 / 104 Introduction Mechanisms of heat transfer Flow layers Heat exchangers Pumps Adjacent to the wall, a laminar sub-layer forms with no uid mixing. Heat transfer across the sub-layer is by conduction only with large resistance to heat transfer and large temperature change. Away from the wall, turbulent ow with large eddies and high uid mixing. Heat transfer is by convection with low resistance to heat transfer and small temperature change. Heat transfer and pipe ow 17 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Overall heat transfer coecient Given a at wall of uniform, homogeneous material having constant thermal conductivity, k , exposed to uids h, at temperature Th , and c , at Tc , on either side: with convective heat transfer coecients hh and hc , wall thermal conductivity, k , and wall thickness, x . What is the overall heat transfer coecient, U ( mW2 K ), for the combined conductive-convective heat transfer: q = UA∆T (4) Heat transfer and pipe ow 18 / 104 Introduction Mechanisms of heat transfer Heat exchangers Assumptions In steady state, the same amount of heat Pumps q must pass through each section. Heat transfer is by convection across the hot and cold lm and by conduction through the solid wall. Th and Tc , are unaected by the heat transfer and are known. The uid temperatures suciently far from the wall, The surface temperatures The heat transfer area, T1 and T2 are unknown. A, is the same for all sections. Heat transfer and pipe ow 19 / 104 Introduction Mechanisms of heat transfer Heat exchangers Overall heat transfer q = hh A(Th − T1 ) k q = A(T1 − T2 ) x q = hc A(T2 − Tc ) Pumps hot lm solid wall ⇓ A(T − T ) q = 1 h x c1 = UA∆T cold lm (solve) hh + k + hc Note: U can be calculated in a manner similar to resistances in electrical networks: 1 X 1 ≡ (5) U i Ui Heat transfer and pipe ow 20 / 104 Introduction Mechanisms of heat transfer Heat exchangers Example: double-paned glass window Pumps Consider a 0.8m-high and 1.5m-wide double-pane glass window consisting of two 4 mm thick layers of glass W ) separated by a 10 mm wide stagnant air space kg = 0.78 mK W (ka = 0.026 mK ). ( Determine the steady rate of heat transfer, q , through the double-pane window and the temperature of its inner surface, T1 , for a day during which the room is maintained at 20 ◦ C while the temperature outside is −10 ◦ C. Take the convection heat transfer coecients on the inner and outer surfaces of the window to be h2 = 40 mW2 K . h1 = 10 mW2 K and Heat transfer and pipe ow 21 / 104 Introduction Mechanisms of heat transfer Heat exchangers Solution: Diagram Pumps Assume that the heat transfer through the window is steady state since the surface temperatures remain constant. Heat transfer and pipe ow 22 / 104 Introduction Mechanisms of heat transfer Heat exchangers Solution: overall thermal resistance From eq. 5, where 1 U ≡ 1 h1 L1 kg L2 k2 L3 kg 1 h2 1 h1 = = = = = + Pumps L1 L2 L1 1 + + + kg k2 kg h2 1 m2 K = 0.100 W W 10 m2 K 0.004m m2 K = 0 . 00513 W 0.78 mWK 0.01m m2 K = 0.385 W W 0.026 m K 0.004m m2 K = 0 . 00513 W 0.78 mWK 1 m2 K = 0.025 W W 40 m2 K Heat transfer and pipe ow 23 / 104 Introduction Mechanisms of heat transfer Heat exchangers Solution: heat transferred Pumps m2 K = 0.52026 U W W U = 1.92 2 mK A = 0.8 m × 1.5 m = 1.2 m2 q = UA(Ti − To ) W = 1.92 2 × 1.2m2 × 30 K mK = 69.12W 1 ⇒ and ∴ Heat transfer and pipe ow 24 / 104 Introduction Mechanisms of heat transfer Heat exchangers Solution: inner surface temperature Pumps q = h1 A(Ti − T1 ) ⇓ T1 = Ti − q h1 A = (20 + 273) K − = 287.24 K = 14.24◦ C 69.12W 10 mW2 K × 1.2 m2 Heat transfer and pipe ow 25 / 104 Introduction Mechanisms of heat transfer Heat exchangers Non-uniform heat transfer area Pumps In some cases, the area for transfer applicable to each media could dier. For example, the radial ow of heat through a thick pipe wall or cylinder. The area of transfer in these cases is a function of position. Heat transfer and pipe ow 26 / 104 Introduction Mechanisms of heat transfer Heat exchangers Example: curved wall Pumps Consider a curved solid wall with constant thermal conductivity k exposed to a convective hot outer uid and a convective cold inner uid: To and Ti ho and hi are the temperatures at ro and ri respectively. are the convective heat transfer coecients in the outer and inner lm, and impact of the thickness of these lms is assumed to be negligible. Heat transfer and pipe ow 27 / 104 Introduction Mechanisms of heat transfer Derivation Start with eq. 1, Heat exchangers Pumps q = kx A∆T , and let x ≡ r . Consider heat transfer over a small part of the pipe and the corresponding change in temperature: dT = q dr kA Integrate over the pipe wall: Z To ⇒ ∴ Z ro ro q q dT = dr = dr ri kA ri 2π rLk Ti q To − Ti = (log ro − log ri ) 2π Lk k q= 2π L (To − Ti ) log(ro /ri ) Z Heat transfer and pipe ow 28 / 104 Introduction Mechanisms of heat transfer Heat exchangers Combined system Pumps Assuming thin lms on either side of the pipe, we can write three equations: q = ho 2πro L(Th − To ) k 2π L(To − Ti ) q= log(ro /ri ) q = hi 2πri L(Ti − Tc ) which have three unknowns, To , Ti and q , so we can solve as usual. Note: the heat transfer coecient will often be given with respect to a specic reference area. Heat transfer and pipe ow 29 / 104 Introduction Mechanisms of heat transfer Heat exchangers Engineers and heat transfer Pumps In practice, engineers often have to design equipment to eect heat transfer, say to achieve a specic temperature change in a uid stream of known mass ow rate, Such equipment will typically be in the form of a heat exchanger and the engineer will need to determine the surface area to transfer heat at a given rate for given uid temperatures and ow rates. predict the outlet temperatures of hot and cold uid streams for a specied heat transfer. Heat transfer and pipe ow 30 / 104 Introduction Mechanisms of heat transfer Heat exchangers Heat exchangers Pumps A heat exchanger is any device that eects transfer of thermal energy between two uids that are at dierent temperature. The two uids do not come in direct contact but are separated by a solid surface or tube wall. Common heat exchangers include: Shell-and-tube (single pass or multi-pass) Flat-plate Finned tubes Heat transfer and pipe ow 31 / 104 Introduction Mechanisms of heat transfer Heat exchangers Double pipe heat exchanger Pumps The simplest form of an heat exchanger consists of two concentric cylindrical tubes, the double pipe heat exchanger: Heat transfer involves convection in each uid and conduction through the wall separating the two uids. Heat transfer and pipe ow 32 / 104 Introduction Mechanisms of heat transfer Heat exchangers Parallel or co-current ow Pumps The uids both ow in the same direction: Heat transfer and pipe ow 33 / 104 Introduction Mechanisms of heat transfer Heat exchangers Counter-current ow Pumps The uids ow in opposite directions: In both cases, the uids are forced to ow using pumps or fans. Heat transfer and pipe ow 34 / 104 Introduction Mechanisms of heat transfer Heat exchangers Shell and tube single pass Heat transfer and pipe ow Pumps 35 / 104 Introduction Mechanisms of heat transfer Heat exchangers Heat transfer and pipe ow Pumps 36 / 104 Introduction Mechanisms of heat transfer Heat exchangers Multi-pass shell and tube Heat transfer and pipe ow Pumps 37 / 104 Introduction Mechanisms of heat transfer Heat exchangers Multi-pass ow arrangement Heat transfer and pipe ow Pumps 38 / 104 Introduction Mechanisms of heat transfer Heat exchangers Heat transfer and pipe ow Pumps 39 / 104 Introduction Mechanisms of heat transfer Heat exchangers Plate heat exchangers Pumps Plate heat exchangers are built up from individual plates separated by gaskets, assembled in a pack and clamped in a frame. They are applied in the energy recovery section of many processes because of low initial cost, high eciency and low maintenance costs. Heat transfer and pipe ow 40 / 104 Introduction Mechanisms of heat transfer Plates Heat exchangers Pumps Thin sheet material, resulting in economic units, particularly when expensive material is involved. Plates are especially corrugated to promote turbulence also at low Re , resulting in: very high heat transfer coecients reduces fouling facilitates chemical cleaning Heat transfer and pipe ow 41 / 104 Introduction Mechanisms of heat transfer Heat exchangers Finned tube heat exchangers Pumps Finned tubes exchangers are employed in large air/liquid heat exchanger systems to give greater heat transfer area because gases, which are good thermal insulators, transfer smaller amounts of heat than liquids. There are various types of nned tubes, depending on the application. Applied in various systems: large air conditioning systems radiators for large truck. Heat transfer and pipe ow 42 / 104 Introduction Mechanisms of heat transfer Heat exchangers Heat transfer in a heat exchanger Pumps Heat exchangers operate for long periods of time with no change in the operating conditions, thus they can be modelled as steady-ow devices: 1 The overall heat transfer coecient, U , is constant throughout the exchanger. 2 The mass ow rate of each uid remains constant. 3 The specic heats of the uids are constant. 4 The temperature of the two uids are constant over a specic cross-section. 5 The outer surface is perfectly insulated, so that any heat transfer occurs between the two uids only. Heat transfer and pipe ow 43 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Energy balance Under these assumptions, it follows that the rate of heat transfer from the hot uid to be equal to the rate of heat transfer to the cold one. The basic design equations for heat exchangers are therefore the energy balance for each uid: q = −ṁh cph (Tho − Thi ) q = ṁc cpc (Tco − Tci ) where (Energy given up by hot uid) (Energy gained by cold uid) ṁ (kg/s) is the mass ow rate and cp specic heat. But what is the driving force, ( kJ kg K ) is the ∆T ? Heat transfer and pipe ow 44 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Temperature prole: co-current ow The temperature dierence ∆T is large at the inlet but decreases exponentially towards the outlet. Temperature of the hot uid decreases and the temperature of the cold uid increases along the heat exchanger. The outlet temperature of the cold uid can never exceed that of the hot uid, no matter how long the heat exchanger. Heat transfer and pipe ow 45 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Temperature prole: counter-current ow The hot and cold uids enter the heat exchanger from opposite ends. The outlet temperature of the cold uid may exceed the outlet temperature of the hot uid, temperature cross. The outlet temperature of the cold uid can never exceed the inlet temperature of the hot uid. Heat transfer and pipe ow 46 / 104 Introduction Mechanisms of heat transfer Design Recall eq. 4, Heat exchangers Pumps q = UA∆T . Need to calculate ∆T for either co-current or counter-current exchange. However, the temperature dierence varies across the range of operation. We introduce the log mean temperature dierence (LMTD), ∆TLM , as an expression of ∆T . Heat transfer and pipe ow 47 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Log mean temperature dierence derivation I At any point along the exchanger: δ q = −ṁh cph δ Th δ q = ṁc cpc δ Tc δ q = U (Th − Tc )δ A (6) Heat transfer and pipe ow 48 / 104 Introduction Mechanisms of heat transfer LMTD II Heat exchangers Pumps Rearrange for δ T in each equation and nd the dierence: δ Th = − δq ṁh cph δq δ Tc = ṁc cpc ⇒ δ Th − δ Tc = −δ q 1 ṁh cph + 1 ṁc cpc δ(Th − Tc ) = −U δ A(Th − Tc ) δ(Th − Tc ) 1 ⇒ = −U δ A + (Th − Tc ) ṁh cph +(6) : 1 + ṁh cph 1 1 ṁc cpc ṁc cpc Heat transfer and pipe ow 49 / 104 Introduction Mechanisms of heat transfer LMTD III Heat exchangers Pumps Let the δ terms be dierentials and integrate along the length of the exchanger: log (Tho − Tco ) − log (Thi − Tci ) = −UA 1 ṁh cph + 1 ṁc cpc which, when combined with overall energy balance on each uid (solve for ṁcp term and substitute): log (Tho − Tco ) − log (Thi − Tci ) = −UA ⇓ log ∆T2 − log ∆T1 = UA (Thi − Tho ) + (Tco − Tci ) q ∆T2 − ∆T1 q Heat transfer and pipe ow 50 / 104 Introduction Mechanisms of heat transfer Heat exchangers ∴ q = UA ∆T2 − ∆T1 log ∆T2 − log ∆T1 or q = UA LMTD IV The term in the box is Pumps ∆T2 − ∆T1 T2 log ∆ ∆T1 ∆TLM , the log mean temperature dierence (LMTD). For counter-current exchangers, the same result is obtained although for dierent ∆T1 and ∆T2 . Heat transfer and pipe ow 51 / 104 Introduction Mechanisms of heat transfer Heat exchangers Correction factor for complex heat exchangers Determination of the average temperature dierence, Pumps ∆TLM , is dicult for complex heat exchangers. It is practice to introduce a correction factor, Ft . The heat transfer rate is then given by: q = UA Ft ∆TLM where ∆TLM is that for the counter ow double-pipe heat exchangers with the same uid inlet and outlet temperatures as in the more complex design. Ft values for several congurations are given in reference books (cf. Perry or Kern). Heat transfer and pipe ow 52 / 104 Introduction Mechanisms of heat transfer Heat exchangers Example: area comparison Pumps Suppose we wish to exchange heat between a hot stream, with Thi = 200 ◦ C and Tho = 150 ◦ C, and a cold stream, with Tci = 80 ◦ C and Tco = 120 ◦ C. Assuming the same heat transfer coecient, and the same amount of heat, U , in both cases q , to be exchanged, what is the ratio of area required for co-current exchange to area required for counter-current exchange? Heat transfer and pipe ow 53 / 104 Introduction Mechanisms of heat transfer Solution co-current ⇒ Heat exchangers Pumps ∆T1 = 200 ◦ C − 80 ◦ C = 120 ◦ C ∆T2 = 150 ◦ C − 120 ◦ C = 30 ◦ C 30 ◦ C − 120 ◦ C ∆Tco-current = ≈ 65 ◦ C ◦ 30 C log 120 ◦C Heat transfer and pipe ow 54 / 104 Introduction Mechanisms of heat transfer Solution co-current Heat exchangers ∆T1 = 200 ◦ C − 80 ◦ C = 120 ◦ C ⇒ ∆T2 = 150 ◦ C − 120 ◦ C = 30 ◦ C 30 ◦ C − 120 ◦ C ∆Tco-current = ≈ 65 ◦ C ◦ counter-current ∆T1 = 200 ◦ C − 120 ◦ C = 80 ◦ C ⇒ Pumps 30 C log 120 ◦C ∆T2 = 150 ◦ C − 80 ◦ C = 70 ◦ C 70 ◦ C − 80 ◦ C ∆Tcounter-current = ≈ 75 ◦ C ◦ C log 70 80 ◦ C Heat transfer and pipe ow 54 / 104 Introduction Mechanisms of heat transfer Solution co-current Heat exchangers ∆T1 = 200 ◦ C − 80 ◦ C = 120 ◦ C ⇒ ∆T2 = 150 ◦ C − 120 ◦ C = 30 ◦ C 30 ◦ C − 120 ◦ C ∆Tco-current = ≈ 65 ◦ C ◦ counter-current ∆T1 = 200 ◦ C − 120 ◦ C = 80 ◦ C ⇒ ∴ Pumps 30 C log 120 ◦C ∆T2 = 150 ◦ C − 80 ◦ C = 70 ◦ C 70 ◦ C − 80 ◦ C ∆Tcounter-current = ≈ 75 ◦ C ◦ C log 70 80 ◦ C q U ∆Tco-current Aco-current = q Acounter-current U ∆T counter-current = ∆Tcounter-current ∆Tco-current ≈ 1.15 Heat transfer and pipe ow 54 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Example: Cooling a hot process uid in a counter-ow heat exchanger A counter-ow double-pipe heat exchanger is used to cool a hot process uid using water. The process uid ows at 18 kgs and is cooled from 105 ◦ C to 45 ◦ C. The water ows counter-currently to the process uid, entering at 25 ◦ C and leaving at 50 ◦ C. 1 Assuming no heat losses, calculate the required ow-rate for the cooling water. The specic heat for water is 4.2 that of the process uid is 2 kJ 3.4 kg K . kJ kg K and Neglecting the tube wall curvature, calculate the required area for heat exchange. Under these conditions, the process uid W m2 K , the cooling W water side heat transfer coecient is 1200 2 . The tube wall mK W thickness is 3 mm and the thermal conductivity is 220 mK . side lm heat transfer coecient is 2500 Heat transfer and pipe ow 55 / 104 Introduction Mechanisms of heat transfer Heat exchangers Solution: Diagram Heat transfer and pipe ow Pumps 56 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Solution: 1. required water ow rate q = −Gf cpf (Tho − Thi ) = 3672kW (heat from hot stream) = Gw cpw (Tco − Tci ) (energy balance) ⇓ Gw = 34.97 kg s (water ow rate required) Heat transfer and pipe ow 57 / 104 Introduction Mechanisms of heat transfer Heat exchangers Solution: 2. heat exchanger area q = UA∆TLM ∆T2 − ∆T1 ∆TLM = ∴ = 34.6 K x 1 + (thermal resistance) U hf k hw W U = 802 2 (overall htc) mK q = 132.3m2 A= U ∆TLM 1 ⇒ T2 log ∆ ∆T1 Pumps = 1 + Heat transfer and pipe ow 58 / 104 Introduction Mechanisms of heat transfer Fouling Heat exchangers Pumps The performance of a heat exchanger depends upon surfaces being clean but deposits form over time. The layer of deposits presents additional resistance to heat transfer and must be accounted for by a fouling factor, Rf (cf. Perry, Kern). 1 U = Rconv,hot uid + Rcond,wall + Rf + Rconv,cold uid Deposits can occur by the precipitation of solid deposits (e.g. calcium in a kettle), corrosion or chemical fouling due to chemical reactions, and the growth of algae, biological fouling. Can apply water treatment, coatings and chemical treatments. Periodic cleaning of exchangers and the resulting down time are additional penalties associated with fouling. Heat transfer and pipe ow 59 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumping of liquid uids Pumps Pumps are the devices used to add energy to a uid in order to maintain ow. Fluids ow in the direction of decreasing pressure. Pumps direct a uid from one vessel to another or through a long pipeline. The energy added to the uid compensates for the mechanical energy losses due to friction and provides an increase in the velocity, the pressure, or the height of the uid. Heat transfer and pipe ow 60 / 104 Introduction Mechanisms of heat transfer Valves Heat exchangers Pumps Valves are used to control the ow rate: On/O valves: gate (30% of all on/o valves) and ball Throttling valves: globe (50%), needle and diaphragm Check valves: allow ow only in one direction Automatic valves Relief valves (for safety): spring loaded, bursting disk. Heat transfer and pipe ow 61 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumping devices for liquids Pumps Liquids used in the chemical industry dier considerably in physical and chemical properties so a variety of pump types exists. Most pumps fall into one of two major classications: Positive-displacement pumps Centrifugal pumps Heat transfer and pipe ow 62 / 104 Introduction Mechanisms of heat transfer Heat exchangers Positive-displacement pumps Pumps Reciprocating pumps involve a back-and-forth motion of a piston in a cylinder. Rotary pumps depend upon a rotating motion. The ow from these pumps is pulsating. The higher the speed of the pump, the higher the ow rate delivered. Deliver a controlled amount of liquid for each stroke or revolution. Used when nearly constant delivery rates are required. Heat transfer and pipe ow 63 / 104 Introduction Mechanisms of heat transfer Examples Heat exchangers Pumps Reciprocating pumps: Diaphragm pump Piston pump Rotary pumps: Gear pump Lobe pump Peristaltic pump Screw pump For details on other types of pump refer to Coulson & Richardson. Heat transfer and pipe ow 64 / 104 Introduction Mechanisms of heat transfer Heat exchangers The Piston pump Pumps In these pumps, the motion of a rotor is converted into a back-and-forward motion of a piston. The rate of liquid delivery is a function of the volume swept out by the piston in the cylinder and the number of strokes the piston make per unit time. For each stroke of the piston, a xed volume of liquid is discharged from the pump. Heat transfer and pipe ow 65 / 104 Introduction Mechanisms of heat transfer Heat exchangers Piston pumps Pumps Piston pumps may be single-acting, with the liquid admitted only to the portion of the cylinder in front of the piston. When the piston moves towards the disk it creates a partial vacuum in the chamber. This allows atmospheric pressure to push the uid from below. On the return half of the cycle the top check valve opens and the bottom one closes. The water is forced up through the pipe. Heat transfer and pipe ow 66 / 104 Introduction Mechanisms of heat transfer Heat exchangers Double-acting piston pumps Pumps Piston pumps can also be double-acting, in which case the feed is admitted to both sides of the piston. As the piston moves downwards, it forces the uid out through the bottom right valve and creates at the same time a partial vacuum in the upper chamber, pushing the uid through the top left valve. When the piston is moving upwards it forces the uid out through the top right valve, while creates at the same time a partial vacuum in the lower chamber, pushing the uid in through the bottom left valve. Heat transfer and pipe ow 67 / 104 Introduction Mechanisms of heat transfer Heat exchangers Piston pump applications Pumps These pumps can deliver the highest pressure of any other pump. Piston reciprocating pumps have long been used in many applications, including pumping of oil, feed water and mud. However, their capacities are relatively small compared to centrifugal pumps. Not used with liquid containing abrasive material as it can damage the machined surfaces of the cylinder and piston. Heat transfer and pipe ow 68 / 104 Introduction Mechanisms of heat transfer Heat exchangers Diaphragm pump Pumps In one section a piston operates in a cylinder in which an inert liquid is displaced. The movement of the uid is transmitted by means of the exible diaphragm. They have been developed to handle corrosive liquids or suspensions with abrasive solids. They are used for example to move gasoline from the gas tank to the carburetor. They are not used for high pressure applications. Heat transfer and pipe ow 69 / 104 Introduction Mechanisms of heat transfer Heat exchangers Rotary pumps: the Gear pump Pumps Has been developed to deal with viscous uids. Two gears operate within a casing. Small packages of uids are carried between the teeth and the casing from the low pressure inlet side to the high pressure delivery side. Heat transfer and pipe ow 70 / 104 Introduction Mechanisms of heat transfer Heat exchangers The 3 lobe pump Pumps Works on the same principle of the gear pump but the gear teeth are replaced by two or three lobes. A small clearance between the lobes can be maintained and wear is reduced. Heat transfer and pipe ow 71 / 104 Introduction Mechanisms of heat transfer Heat exchangers The Peristaltic pump Pumps Delivers ow precisely controlled by the speed of a rotor. An elastic tube is compressed in stages by a rotor. As the rollers rotate, they atten the tube against the track at the points of contact. These ats move the uid along the tube. They are mainly used in labs. They are particularly good in handling biological uids, where all forms of contacts must be avoided. Heat transfer and pipe ow 72 / 104 Introduction Mechanisms of heat transfer Heat exchangers The screw pump Pumps One of the oldest pumps: its usage goes back 2000 years. It consist of a helical screw. Suitable for very viscous uids (e.g. polymers) and also for sewage uids. The uid is sheared in the screw channel and so is raised to the delivery side. Heat transfer and pipe ow 73 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Figure: Example of a screw pump used in a waste water treatment plant. Heat transfer and pipe ow 74 / 104 Introduction Mechanisms of heat transfer Heat exchangers Centrifugal pumps Pumps that cause the pumped uid to rotate Pumps are called centrifugal pumps. Centrifugal pumps are the most widely applied in the chemical and petroleum industry. They are applied for large capacity applications. They pump liquids with very wide-ranging properties and suspensions with high solids content. They cannot handle highly viscous uids. Heat transfer and pipe ow 75 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps A Centrifugal pump has an impeller enclosed by a casing or volute. The impeller consists of a series of curved vanes. The greater the number of vanes, the greater is the control over the direction of motion of the uid. Heat transfer and pipe ow 76 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps The uid is fed to the centre of the rotating impeller and is thrown from the impeller vanes into the casing by centrifugal force. As a result, the liquid acquires a high kinetic energy. This velocity energy is converted in pressure as the uid leaves the impeller and enters the casing. Heat transfer and pipe ow 77 / 104 Introduction Mechanisms of heat transfer Heat exchangers Turbine pump Pumps In the turbine pump, the liquid ows from the impeller into a series of xed vanes, called diusers. These give more gradual change in direction to the uid and more ecient conversion of kinetic energy into pressure energy. Heat transfer and pipe ow 78 / 104 Introduction Mechanisms of heat transfer Heat exchangers Summary of types Heat transfer and pipe ow Pumps 79 / 104 Introduction Mechanisms of heat transfer Pumps Pump characteristics Centrifugal Head Heat exchangers High, single stage up to 600 ft Multistage up to 6000 psi Capacity Low (100 gal/min) to very high (200,000 gal/min) Liquids Clear or dirty, non viscous Reciprocating (piston) Highest available 100,000 psi Rotary (gear or screw) Intermediate up to 600 psi Intermediate (500 gal/min) Low (1 gal/min) to intermediate (500 gal/min) High viscosity, non abrasive Clean no solids Heat transfer and pipe ow 80 / 104 Introduction Pump Mechanisms of heat transfer Heat exchangers Summary of characteristics Pressure delivered Piston very high Diaphragm not high Rotating not high Centrifugal not high Flow delivered pulsating pulsating pulsating continuous Pumps Capacity Fluid not high not high not high very high non-corrosive corrosive highly viscous not viscous Heat transfer and pipe ow 81 / 104 Introduction Mechanisms of heat transfer Heat exchangers Operating characteristics of centrifugal pumps Pumps Centrifugal pumps are the most widely applied in the chemical and petroleum industry. Centrifugal pumps operate at constant speed and the capacity depends upon the total head, H , the design and the suction conditions. Pumps usually achieve maximum eciency at one particular ow rate. Operating characteristics are described through use of characteristic curves. Heat transfer and pipe ow 82 / 104 Introduction Mechanisms of heat transfer Heat exchangers Characteristic curves Pumps For a pump at a particular speed, the characteristic curves show the inter-relation between: Total head and capacity, the H − Q curve. Power input and pump capacity, the P − Q curve. Pump eciency and capacity, the η − Q curve. The duty point shows the optimum conditions for operation. This is the point where the head curve cuts the ordinate through the point of maximum eciency. Heat transfer and pipe ow 83 / 104 Introduction Mechanisms of heat transfer Heat exchangers Characteristic curve graph Pumps For a pump having the characteristics shown above: maximum eciency would occur at a capacity of 2500 gal/min and a total head of 80ft. Heat transfer and pipe ow 84 / 104 Introduction Mechanisms of heat transfer Heat exchangers Variable speeds Pumps When a pump is capable of being operated at variable speeds, then, at higher speed of rotation gives higher capacity and requires more horsepower to supply the increased supply of liquid. Heat transfer and pipe ow 85 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pump design Pumps The energy required for a pump will depend on the height through which the uid raises, the pressure required at the delivery point, the length and diameter of the pipe, the rate of ow, and the physical properties of the uid, density and viscosity. Heat transfer and pipe ow 86 / 104 Introduction Mechanisms of heat transfer Heat exchangers General scenario for pumping Heat transfer and pipe ow Pumps 87 / 104 Introduction Mechanisms of heat transfer Heat exchangers Energy balance Pumps The work done on a uid by a pump is expressed as head, H (m), and is given by the mechanical energy balance (per unit mass): p u2 H=∆ + + z + ∆hfT ρg 2g P2 − P1 u22 − u12 + + (z2 − z1 ) + ∆hfT (7) = ρg 2g where ∆hfT represents the total friction loss in the system and is the sum of the losses in the whole pipe length and other losses due to ttings: ∆hft = ∆hf + ∆htting loss where hf is the frictional head loss. Heat transfer and pipe ow 88 / 104 Introduction Mechanisms of heat transfer Heat exchangers Frictional losses Pumps ∆hf is expressed as a frictional pressure drop: ∆hf = 2cf 1 u2 dg = ∆pf ρg where the Fanning friction factor, cf , is given as a function of the Reynolds number, Re (eq. 3): 16 Laminar ow cf = Re Turbulent ow cf = 0.079Re −0.25 Rough pipes use Moody diagram to estimate the value Heat transfer and pipe ow 89 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Fitting losses Loss due to ttings, such as bends and valves, can generate large-scale turbulence in which energy is dissipated as heat. For turbulent ow, these losses are proportional to the square of the uid velocity and can be expressed as the frictional loss due to an equivalent length of straight pipe, le , estimated as a multiple of the pipe diameter: le = nd so that ∆htting loss = 2cf le u 2 d g Heat transfer and pipe ow 90 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Total friction losses Total friction loss is therefore equal to l + le u 2 ∆hfT = 2cf d g (8) which in terms of pressure losses is ∆pfT = ρg ∆hfT = 2cf l + le 2 ρu d Heat transfer and pipe ow 91 / 104 Introduction Mechanisms of heat transfer Heat exchangers Power requirements Pumps Thus, from eq. 7, the head, H , that must be supplied by the pump is: P2 − P1 u22 − u12 l + le u 2 H= + + (z2 − z1 ) + 2cf ρg 2g d g The power required by the pump to deliver H is given by: Power = ∆Pp Q = H ρg Q where Q is the volumetric owrate of the uid that the pump moves and is known as the capacity of the pump. Heat transfer and pipe ow 92 / 104 Introduction Mechanisms of heat transfer Example Heat exchangers Pumps 2.32 mh of water is pumped in a 35 mm internal diameter pipe through a distance of 125 m in a horizontal direction and then up through a vertical height of 12 m. The friction loss in the 90◦ square elbow may be taken as equivalent to 60 pipe diameters. Also in the line there is a control valve fully open and frictional losses may be taken equivalent to 200 pipe diameters. Calculate the total head ∆hfT to be developed to overcome the total frictional losses in the pipeline. You may assume that for this pipe f = 0.079Re −0.25 . Assume the water to ow in turbulent regime through the pipe. Density and viscosity of water in the pipe are 1000 mkg3 and 0.65 mN m2 s respectively. 3 Heat transfer and pipe ow 93 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pumps Solution: data collection Quantity Volumetric Flow rate Density of water Viscosity of water Value Q 2.32 ρ 1000 µ 0.65 0.65 × 10−3 Internal pipe diameter d 35 0.035 Horizontal pipe length lh 125 Vertical pipe length lv 12 ◦ 90 square elbow friction loss 60d Control valve friction loss 200d Friction coecient cf 0.079Re −0.25 Units m3 h kg m3 mN s m2 N m2 s mm m m m m m Heat transfer and pipe ow 94 / 104 Introduction Mechanisms of heat transfer Solution Heat exchangers Pumps The total friction losses, eq. 8, in the pipeline for turbulent ow regime is expressed as: ∆hfT = 2cf (l + le )u 2 gd with l = lh + lv = 125m + 12m = 137m and le from the denition of the equivalent pipe length: le = 200d + 60d = 200x 0.035m + 60x 0.035m = 9.1m The velocity of the water in the pipe is given by the volumetric ow rate divided by the pipe cross-section area: u= Q π = d 2 2 1h 2.32 mh × 3600 s 3 π× = 0.67 0.035m 2 2 m s Heat transfer and pipe ow 95 / 104 Introduction Mechanisms of heat transfer Solution Heat exchangers Pumps The friction coecient depends on Re , the Reynolds number (eq. 3): 0.035m × 0.67 ms × 1000 mkg3 Re = = 36076 = µ 0.65 × 10−3 mN2 s cf = 0.079Re −0.25 = 0.079 × 36076−0.25 = 0.0057 2cf (l + le )u 2 du ρ ⇒ ⇒ ∆hfT = = gd 2 × 0.0057 × (137 + 9.1)m × (0.67 ms )2 = 2.17m 9.81 sm2 × 0.035m ⇒ ∆pfT = ∆hfT ρg = 2.17m × 9.81 m kg × 1000 s2 m3 = 21287 N m2 Heat transfer and pipe ow 96 / 104 Introduction Mechanisms of heat transfer Heat exchangers Cavitation in centrifugal pumps Pumps Cavitation is the formation of cavities or bubbles in a pumped uid when the pressure on the uid falls below the vapour pressure of the liquid, Pv (or p∗ ). When a centrifugal pump is operated at high capacity, low pressure may develop at the impeller eye or vane tips and so vapourisation may occur. Cavitation leads to: A reduction in pump capacity. A reduction in the head of the pump. A noise that can be heard when the pump is running. Mechanical damage that can be seen on the pump impeller and volute. To avoid cavitation, the pressure at the pump inlet must exceed the vapour pressure of the liquid. Heat transfer and pipe ow 97 / 104 Introduction Mechanisms of heat transfer Heat exchangers Pump congurations Pumps Negative suction head Positive suction head Pump is placed above the reservoir of uid to be pumped, drawing uid up with suction: Pump is placed below the reservoir of uid to be pumped and is fed by gravity action: Heat transfer and pipe ow 98 / 104 Introduction Mechanisms of heat transfer Heat exchangers Net positive suction head (NPSH) Pumps To avoid cavitation, the pressure at the pump inlet must exceed the vapour pressure of the liquid. There are two cases: NPSH is the amount by which the pressure at the suction point of the pump must exceed the vapour pressure of the liquid and is expressed as a head of the liquid to be pumped. For any pump, the manufacturers specify the minimum value of the NPSH required at the impeller eye to avoid cavitation. Heat transfer and pipe ow 99 / 104 Introduction Mechanisms of heat transfer Heat exchangers Typical conguration Pumps P1 , pressure at the tank liquid surface. h1 , height of the liquid surface above the pump centre-line at the suction inlet. u1 , liquid velocity on the surface. u2 , velocity at the pump inlet. hf , total piping friction loss between (1) and (2). Heat transfer and pipe ow 100 / 10 Introduction Mechanisms of heat transfer Heat exchangers Pumps Available NPSH Start with energy balance (per unit mass): P1 ρg u12 + 2g P2 u22 + h1 − hf = + + h2 (9) ρg 2g If the reference plane is taken at h2 , and the liquid velocity in the reservoir, u1 , is negligible compared with u2 : P1 ρg + h1 − hf = P2 ρg + u22 2g (10) The available NPSH is the dierence between the static head and the head corresponding to the vapour pressure of the liquid at the suction inlet. NPSHA = P2 ρg u2 + 2 2g − Pv ρg = P1 − Pv ρg + h1 − hf (11) Heat transfer and pipe ow 101 / 10 Introduction Mechanisms of heat transfer Heat exchangers Pumps Required NPSH - I From eq. 10, the total head at the suction inlet is: P2 ρg = P1 ρg + h1 − hf − u22 2g (12) Cavitation usually occurs at the impeller eye where the pressure will be less than at the suction inlet by ∆P = φ u32 2g (13) Where φ is a pressure drop coecient characteristic of pump geometry and u3 is the uid velocity at the eye. Heat transfer and pipe ow 102 / 10 Introduction Mechanisms of heat transfer Heat exchangers Required NPSH II Pumps Cavitation is probable if the total head at the impeller eye (rhs of eq. 12 minus eq. 13) is equal to or less than the vapour pressure: P1 ρg + h1 − hf − Limiting case therefore is P1 − Pv ρg u22 2g −φ + h1 − hf = u32 2g u22 2g ≤ Pv ρg +φ u32 2g where the right hand side is the NPSH required at the impeller eye: NPSHR = u22 2g +φ u32 2g Heat transfer and pipe ow 103 / 10 Introduction Mechanisms of heat transfer Heat exchangers Avoiding cavitation Pumps In order to avoid cavitation, the NPSHA available has to be greater than the NPSHR required at impeller eye: NPSHA > NPSHR The value of the required NPSHR for the particular pump being used may be obtained from the pump manufacturer. If NPSHA is too low, then cavitation can be avoided by increasing h1 . This is why pumping uids that are close to saturated conditions require that the vessel upstream be elevated . . . . . . or, more generally, that the pump be lowered. Heat transfer and pipe ow 104 / 10