Tulip Flame
Transcription
Tulip Flame
On the “Tulip Flame” Phenomenon CHRISTOPHE CLANET and GEOFFREY SEARBY’ Insitut de Recherche sur les Ph&omLnes Hors Equilibre, Laboratoire de Combustion et SystZmes Riactifs, U.M.R 138 du CNRS - Vniversit& d’Aix-Marseille I et II, Service 252, Campus Universitaire de St. J@me, 13397 Marseille Cedex 20, France We present an experimental study of the “tulip flame” phenomenon using high-speed photography. Contrary to most previous studies, the work is in a simplified quasi-constant pressure configuration in a half-open tube. It is shown that the salient features of the different stages of the flame propagation and shape can be explained by a simple geometrical model of the interaction between the flame front and the gas dynamics. In particular, the tulip flame results from an inversion of the flame front curvature caused by the deceleration related to loss of flame surface area. Finally, the experimental results obtained by other authors in closed vessels are in reasonable agreement with the analysis presented. NOMENCLATURE a(t) “E g(t) k L P R r” S So t0 t sphere t wall ttulip t* v, U,ip Uskirt v, v, time-dependent amplitude of front wrinkling sound speed gas expansion ratio = pu/pb time-dependent acceleration wavenumber length of tube or combustion chamber instantaneous relative pressure at the closed end of the tube radius of tube aspect ratio of combustion chamber = R/L flame surface area cross section area of combustion chamber instant of ignition time at which flame propagation changes from spherical to fingered time at which flame touches side walls of tube time at which tulip flame inversion occurs = tU,/R reduced time laminar burning velocity velocity of flame tip contact velocity of trailing edge of flame skirt volume of burned gases volume of closed combustion chamber Greek Symbols flame front thickness burned mass fraction kinematic viscosity density of unburned and burned gases S/S,, ratio of flame area to burner cross section = & : Characteristic time in the tulip flame experiment time during which flame tip is decelerated = ttulip - twall time delay after which flame front curvature inverses or time between shock and curvature inversion in shock experiment characteristic frequency of Taylor’s instability INTRODUCTION The propagation of flames in tubes was first observed by Mallard and Le Chatelier in 1883 [l]. They noticed that if a flame is ignited at the closed end of a long half-open tube, the * Corresponding author. COMBUSTIONAND axial coordinate of tip of flame axial coordinate of lower edge of skirt zskirt of flame Z wall axial position of flame tip when the flame skirt touches burner wall axial position at which tulip inversion Gulip occurs (flat front) ztip FLAME 105: 225-238 (1996) Copyright 0 1996 by The Combustion Institute Published by Elsevier Science Inc. OOlO-2180/96/$15.00 SSDI OOlO-2180(95)00195-6 226 progression of the flame front is irregular with inversions of the direction of progression of the flame. The first photographs of the shape of a flame propagating irregularly in tubes were published by Ellis in 1928 [2]. He observed that, for closed tubes with a sufficiently high aspect ratio (length/diameter > 2 for closed tubes), the shape of the flame changed suddenly from a forward pointing finger to a backward pointing cusp. After this inversion, the cusped shape remained stable. In 1959 Salamandra et al. [3] coined the name “tulip flame” to describe this curious phenomenon. An example of the formation of a tulip flame is shown in Fig. 1. Various mechanisms have been proposed to explain the formation of the tulip flame. Dunn-Rankin et al. 141proposed that the flame inversion is initiated by a radial gradient of axial velocity just ahead of the curved flame front. Similarly, Gonzales et al. [5] claim that the “squish” flow generated between the curved flame and the tube wall is crucial to the formation of the tulip inversion, Rotman and Oppenheim [6] have claimed that vorticity generation in the unburned gases is responsible for this phenomenon, whereas Oppenheim and Ghonheim [7] invoke the role of Tollmein-Schlichting waves in the boundary layer at the walls. Other authors [8] favor an interpretation in terms of a manifestation of the Darrieus-Landau instability. C. CLANET AND G. SEARBY GuCnoche [9] observed that the tulip effect appears both in closed tubes and also in halfopen tubes. Moreover, to understand the origin of the phenomenon. GuCnoche proposed an analogy between the tulip flame inversion and a shock wave experiment of Markstein [lo]. In this experiment, Markstein investigated the effect of a shock wave on a curved flame front. His pictures show that the flame front also undergoes an inversion of concavity, similar to the tulip phenomenon. The characteristic time for the inversion was shown to decrease as the shock intensity increases. In the case of the tulip flame there is no shock, but we will show that the change in flame surface area after the flame reaches the tube walls creates a deceleration that acts in a similar way via the Taylor instability [ll]. Strehlow 1121and Starke and Roth [13, 141 also believe that the tulip inversion is a manifestation of the Taylor instability. However, none of the above authors has given quantitative evidence to confirm their propositions. One of the main objects of this paper will be to give such a quantitative proof. We first describe the experimental apparatus and qualitatively describe the different stages of flame propagation preceding the tulip flame formation. We then present the experimental results and interpret them using a simple geometrical model. Finally, results are compared with other published experiments. EXPERIMENTAL APPARATUS Fig. 1. Superposition of three images of luminous emission of flame front just before, during and just after formation of tulip flame. High-speed video recording at 4500 images/s. Time between selected images is 2.2 ms. Propane-air flame @ = 0.70, in a tube 1.5 m x 0.05 m radius. Contrary to most previous studies, the work was in a simplified configuration with a halfopen tube. This configuration has the advantage of being at constant pressure and eliminates complications of flame front motion associated with compression of the unburned mixture. The apparatus is shown in Fig. 2. The walls of the burner were uncooled Pyrex glass tubes. The tubes had radii of 2.5 and 5 cm and lengths ranging from 0.6 m to 6 m. The tubes were filled with a premixed propane-air mixture fed into the bottom of the burner through an isolating valve. The equivalence ratio was controlled using sonic nozzles in the air and propane lines. Equivalence ratios were in the range 0.65 < @ < 1.3. The laminar burning velocity ranged from 41 ON THE “TULIP c--- Tulip Flame front 227 FLAME” PHENOMENON I 2.R Unburned gas= . Pyrex tube - Pressure s - Spark electrodes Fig. 2. Apparatus. to 20 cm/s. The flame was spark ignited at the closed end of the tube. A signal from the spark generator synchronized the recording apparatus. A piezoelectric pressure sensor measured the pressure at the closed end of the burner. The signal was recorded on a numerical oscilloscope and post-processed on a microcomputer. Various high-speed imaging devices were used to record the form and position of the flame front as a function of time. QUALITATIVE PRESENTATION ORDERS OF MAGNITUDE AND As can be seen in Fig. 1, the flame front assumes very different shapes between ignition and tulip formation. We distinguish four stages in the propagation of the flame. The first stage occurs just after ignition, t, < t < tsphere. The flame is small, unaffected by the presence of the burner side walls and develops as a hemispherical flame expanding at the velocity of burned gas production, typically tsphere= 10 to 20 m/s. The second stage of propagation occurs as the flame approaches the side walls, t sphere < t < twall* The flame shape changes from hemispherical to finger shaped. The velocity of the tip of the flame increases exponentially and reaches a value (30-50 m/s), nearly two orders of magnitude higher than that of the spherically expanding flame. However, we will not be concerned here with the details of the mechanism by which the front propagation changes from spherical to fingered. The third stage occurs after the skirt of the elongated flame touches the side walls of the tube, twal, < t < ttulip. It is during this stage of the propagation that the inversion of the flame front is initiated. During this stage of propagation, the flame surface area and the propagation velocity decrease steadily. The time at which the tulip inversion occurs is found to be a function of the laminar burning velocity and the radius of the tube. The time scale for ttulip is typically = 40 ms for a stoichiometric flame of propane in a tube of radius 5 cm. The fourth stage of propagation concerns the dynamics of the front after the tulip inversion, t > &,. It is during this last stage that acoustic effects can dominate. The work presented below will be mainly concerned with the second and third stages of propagation, up the formation of the tulip flame. EXPERIMENTAL DISCUSSION RESULTS AND The Role of Viscosity and Boundary Layers The order of magnitude of the Reynolds number as defined by the tube radius and the velocity of the flame tip, R, = 2.R.Qip/v, is typically of order 10 5. Thus, except in the boundary layer at the walls, viscous effects are negligible compared to inertial effects. Numerical simulations of flame propagation in closed vessels have already shown that nonviscous codes can successfully simulate the tulip flame phenomenon 14, 81 and that increasing the numerical fluid viscosity attenuates the tulip phenomenon 151.Moreover, Pocheau and Kwon [15] have shown experimentally that an array of spark igniters can produce an array of tulip flames in which there is no physical boundary between adjacent fingers. We have reproduced their experiment and show an example of such a double tulip flame in Fig. 3. This space C. CLANET AND G. SEARBY Fig. 3. Multiple exposure video image of twin tulip flame formation. Propane-air @ = 1.3 ignited by two sparks symmetrically on left, outside field of view. symmetry confirms that boundary layers are not directly involved in the tulip phenomenon. The Role of the Acoustic Field It has been suggested that the formation of the tulip flame could be due to an interaction between the flame front and acoustic waves in the combustion chamber [16]. This appears to be not so. Figure 4a shows the pressure recorded at the bottom of 1.5 m tube, radius 5 cm, for two different flames. There is an initial pressure rise which is approximately exponential. This pressure rise is associated with the development of the finger flame, see below. It is followed by a sharp pressure drop that precedes the formation of the tulip flame, marked by empty crosses. The pressure drop is followed by strong pressure oscillations at the resonant frequency of the tube and its harmonics. The period of the cold fundamental mode is 0.017 s for this tube. Acoustic oscillations are clearly present for both flames, even before the formation of the tulip flame. However the sharp pressure drop and the tulip inversion occur at a later time for the slower flame in the same tube. Figure 4b shows the same data in reduced coordinates. The time scale has been reduced by R/U,, where R is the radius of the rube and U, is the laminar burning velocity. R/U, is the time scale for the flame to reach the tube walls. The pressure has been reduced by pUUE2,where p,, is the unburned gas density. It can be seen that, in this representation, the transition from quasi-exponential rise to rapid drop occurs at the same reduced time, as does the tulip formation. Figure 4c shows the effect of changing the acoustic time scale. The pressure is recorded in tubes of different length for the same stoichiometric flame. It can be seen that the tulip inversion occurs at a time (real or reduced) which is independent of the tube length. For tube lengths greater than 4 m, the tulip inversion occurs at a time shorter than that required for the pressure disturbances to propagate to the end of the tube and back to the flame. Figure 4c also shows that the tulip formation time does not always coincide with the first pressure minimum, as suggested by Figs. 4a and 4b where it is a coincidence that half the acoustic time, 2.L/c = 8.7 ms, is equal to the tulip inversion time which scales (as will be shown) as R/U,, and is of the order of 8.5 ms for a stoichiometric flame. Figure 4d shows the results of an experiment in which strong acoustic losses are introduced. The burner consists of two aligned tubes separated by a small gap of width e, which was varied from 0 to 10 mm. When e is zero, the burner is the same as before. When e = 10 mm, the fundamental mode of the burner is strongly damped. The tulip flame was formed just after the gap in the burner. This figure shows that the initial pressure rise and the time of tulip formation are little affected even by strong acoustic losses. However, the acoustic oscillations generated after the tulip formation are increasingly damped as the acoustic losses are increased. The above results show that combustion excited pressure waves are present, but they do not provide the driving mechanism for the tulip inversion. Moreover, the time scale for the tulip phenomenon is closely related to the time taken for the flame to reach the walls of the burner and not to an acoustic time. However, acoustic waves play an important role after the tulip formation, as already remarked by Guenoche [9]. In particular, we have observed that the depth of the tulip cusp is enhanced or attenuated according to the direc- ON THE “TULIP 229 FLAME” PHENOMENON Pressure in tube tar two flame velocities Dlfferent burning velocities, reduced coordinates 40000 zS 9 20000 P !! a :: k 0 B s -20000 -o- U, = 0.42 m/s % -10000 I 0.00 0.02 Time 0.04 after -40000 0.06 0.00 0.08 0.10 0.20 Incresslng scoustic losses Different tube lengths, reduced coordinates hllip tlva// , --be=1 -e=2mm 8 -e-L=4Sm -100000 -40000 0.4 0.6 Reduced time t&IL/R 0.50 (b) (a) 0.2 0.40 0.30 Reduced time t+l,IR ignition (see) 0.8 1.0 (c) I--t 0 mm I 0.1 I 0.2 0.3 0.4 Reduced time ML/R (d) Fig. 4. Evidence to show tulip inversion is not related to acoustic phenomena: (a) Pressure at closed end of tube for hvo different burning velocities. Unfilled crosses show formation of tulip flame. Tube 1.5 m x 0.05 m radius. Period of fundamental acoustic mode 17 ms. (b) Same data as a), but in reduced coordinates. (cl Pressure at closed end of tube for stoichiometric propane-air flame in tubes of different lengths. Tube radius = 2.5 cm. Arrows mark time at which flame skirt touches wall, I,.,,, and time at which tulip inversion occurs, ttulip. (d) Pressure at closed end of tube 1.5 m long X 5 cm radius for different acoustic losses, introduced by a cylindrical gap in walls. Gap, of width e, is 0.6 m from the closed end. tion of the acoustic acceleration at the flame front during the tulip inversion. Moreover, in half-open tubes or closed tubes with a high aspect ratio (> 201, the acoustic velocity can be sufficient to periodically reverse the apparent direction of flame propagation and the cusped tulip flame is observed to break into cells, oscillating at the acoustic frequency. These oscillating cells are probably the parametrically excited structures studied experimentally by Searby 117, 181 and observed numerically by Gonzales et al. [19], but are beyond the scope of this present study. The Dynamics of the Flame Tip The global progression of the flame front was filmed using a high speed Kodak video camera at 4500 images per second. Two images are shown in Fig. 5. The lower image shows the finger-shaped flame just after the skirt of the flame has touched the side wall of the tube. At shorter times the luminous flame front extends down to the base of the burner. The upper image shows the flame at a later time, just after the formation of the tulip. We have measured the position of the center of the flame 230 C. CLANET AND G. SEARBY Fig. 5. Two images of luminous emission from finger flame. Ignition on left. Lower image: flame just after skirt of flame reaches tube walls. Upper image: flame just after tulip inversion. Infrared emission from burned gas also visible to left of flame surface. Propane-air mixture, @ = 0.90, tube radius = 2.5 cm. and its area increases exponentially during the development of the finger. The velocity of the flame tip for this flame, of equivalence ratio = 0.7, is of the order of 23 m/s at t = twa,,. For stoichiometric flames, the tip velocity is of the order of 80 m/s. The velocity of the contact point of the skirt of the flame is almost constant. The skirt rises up the tube faster than the tip, = 24 m/s, indicating that the surface area of the flame decreases during this stage. The tulip formation occurs a considerable time after the flame has touched the walls. A GEOMETRICAL MODEL FOR FLAME PROPAGATION The Finger Flame tip and also the position of the trailing edge of the flame skirt as a function of time. A typical result is shown in Fig. 6. These two quantities are plotted along with the pressure at the base of the tube. The acoustic oscillations visible on the pressure signal are not visible on the trajectory of the flame tip. This again confirms that acoustic pressure waves do not control the flame front dynamics at this stage. The maximum pressure coincides almost exactly with the instant, twa,,, at which the flame touches the walls, Before the flame touches the walls, the trajectory of the flame tip is close to exponential. This means that the flame accelerates ~,h,T 3oooo,,,,,,,,,,,,,,,,,,,,,,, “;s ,o z 20000 I- ,,,,,,, 6 .- 14 A^^^_ 1 “U”” E 7 g -10000 p -20000 F J -30000 0 t -Skirt Tip 5 6 e a L 8 Pressure ?? l2 10 position position ,” P P PC -40000 I - 2 -50000 0 We introduce a simple geometrical model for the propagation of the finger flame in a halfopen tube. This model neglects pressure variations and relates the flame propagation speed directly to the production rate of burned gas. During the development of the finger flame, the skirt of the flame is close to the tube walls, see Figs. 1 and 5. The axial velocity of the flame tip (lo-80 m/s> is very much higher then the radial velocity of the skirt, which travels towards the tube wall at a speed close to the laminar burning velocity, U, = 0.2-0.4 m/s. The proximity of the tube wall prevents the flame from pushing the unburned gas radially outwards. The model is presented schematically in Fig. 7. It is supposed, for simplicity, that the flame surface can be represented as a cylindrical finger of radius r with a hemispherical tip. The effect of curvature on the local burning velocity is neglected. Using these hypotheses we calculate the velocity of the flame tip. The mass consumption 0.1 0.2 Reduced 0.3 +’ 0 0.4. Time t.UL/R Fig. 6. Normalized superposition plot of pressure at closed end, positions of center of flame tip and of trailing edge of flame skirt, as functions of time. Flame positions normalized by tube radius. Arrows mark time at which flame skirt touches wall, t,,,,, and time at which tulip inversion occurs, ttullp. Continuous line is a best fit exponential. Tube 1 Flame front Fig. 7. Simplified geometrical times between tSphereand t,,,,. model of flame front at ON THE “TULIP FLAME” PHENOMENON 231 rate of fresh gas is given by p,, * U, . S, where gas density, U, the laminar burning velocity, and S the area of the flame front. This is also equal to the production rate of burned gas. The time variation of the volume of burned gases, V, is given by Growth retee of the finger flame p, is the unburned -di/, dt =E*U,.S, (1) where E = pu/pb is the ratio of unburned to burned gas density. The effect of the small pressure changes on the laminar burning velocity is neglected. Supposing that the flame is cylindrical with a hemispherical cap, the volume of the burned gas is given by V, = m2(ztip - Y) + 2/3rr3, S = 27rrz,i,. (3) dZtip z = U, compared with - and putting r = R, Eq. 1 can be rewritten ,d dZtip dt ‘tip with =I 1 _=7 2EU, R . (4) Equation 4 is easily integrated to yield t-t ztip -_=e R sphere 7 50 100 150 200 250 300 Predicted growth rate (1 I r = 2.E.UL/ R) (8-l) Fig. 8. Measured growth rate of finger flame for various equivalence ratios and tube radii, plotted as function of predicted growth rate. Straight line has a slope of unity. (2) where Ztip is the axial coordinate of the tip and r is the radius of the flame finger. The total flame surface area is given by Neglecting 0 ratios. The results are presented in Fig. 8 which shows the experimentally measured growth rate as a function of the predicted growth rate, l/7 = 2EUJR. The gas expansion ratio, E, was calculated using the burned gas temperatures given in [20]. The laminar burning velocities were taken from [21]. The straight line indicates equality of both times. This equality is verified to within the 10% experimental error bars. It is concluded that the trajectory of the tip of the finger flame between tsphereand t,,,, is exponential with a growth rate that is given, to a good approximation, by a simple geometrical model. (5) The constant of integration, tsphere, is a measure of the time at which the initial spherical flame changes to a finger flame. This simple first order model thus predicts that the locus of the flame tip should follow an exponential trajectory with respect to time. The characteristic time of growth is a simple function of the gas expansion ratio, the laminar burning speed and the radius of the burner. Figure 6 plots an exponential curve over the tip trajectory. It can be seen that the agreement is good until the flame skirt touches the burner wall at t = twa,,. To compare the experimental data with model predictions, we have measured the characteristic growth rate of flames in tubes of radii 2.5 and 5 cm and for different equivalent Measurement of tspherefwa,,, and ttulip The time at which the flame skirt touches the burner wall, twa,,, can be estimated from the high-speed films using a plot of the position of the trailing edge of the flame such as in Fig. 6. The extrapolation to position z = 0 gives twa,,. The relative error in twa,, is of the order of 5%. It is also possible to use the pressure signal, since, as already mentioned, the first maximum of the pressure coincides closely with twa,,. This method is simpler than the previous one but less precise, f 10%. The results obtained with these hvo methods, for two tube radii and for various equivalence ratios, are presented in Fig. 9 as a function of R/U,. It is found that t wall = 0.26(R/U,) f O.O2(R/U,). There is no 232 C. CLANET AND G. SEARBY area after the flame skirt has touched the walls must be known. 0.08 z JE 0.06 d I1 0.04 c r 0 Velocity of the Flame Skirt Contact Point 0.02 0 0 0.05 0.1 0.15 0.2 0.25 0.3 RlUL (s) Fig. 9. Experimental values of time, tsphere, at which flame propagation changes from spherical to finger shaped, t,,,,, time at which flame skirt touches the burner wall and ttUliP, time at which tulip shape is formed. other significant dependence on gas expansion ratio, tube radius, or laminar burning velocity. The characteristic time at which the flame propagation changes from spherical to finger shaped, tsphere, cannot be measured directly but can be evaluated using the model. Equation 5 yields: t sphere = t wall The position of the trailing edge of the skirt of the flame will be denoted Zskirt and its propagation speed Qkirt. Figure 6 suggests that Uskirt is constant. This was always the case in the experiments. Uskirt is constant in one experiment but changes with equivalence ratio. In the geometrical model this implies that the skirt of the flame front is not exactly parallel to the burner wall, as in Fig. 7, but is slightly conical, making a small angle cy with the burner walls. The apparent velocity of the contact point between the front and the wall is then qkirt = U,/sin(cr). From the data in Fig. 6, Uskirt= 24 m/s, U, = 0.223 m/s, it is found that (Y= 10m2 radians, so the angle between the flame and the wall is very small and the previous model remains valid. Suppose that the angle (Y is inversely proportional to the aspect ratio of the flame finger when the flame touches the wall: (6) (7) Z Wallis the position of the flame tip when the skirt touches the wall at time twa,,. This position is directly measured from the films. In Fig. 9 are also plotted tspherecalculated from Eq. 6. It can be seen that tsphere= O.l(R/U’) + O.O2(R/U,), within experimental errors. The inversion of front curvature leading to the formation of the ‘tulip flame’ is a continuous process. The time of formation of the tulip flame, ttulip, is the time at which the curvature of the flame front changes sign, see Fig. 1. This definition is somewhat arbitrary, but has the advantage of being unambiguous and easy to apply. Also plotted in Fig. 9 are values of ttulip. The time at which the tulip inversion occurs is also a linear function of R/U, and we find: ttulip = 0.33(R/U,) * O.O2(R/UJ Some authors consider the tulip formation to coincide with the time that the flame first touches the walls. It can be seen that this is not the case, since ttulip = 1.29t,,,,. To calculate the tulip inversion time from the geometric model, the evolution of the flame where S is a constant, expected to be of order unity, since 2EU, is the propagation velocity of a hemispherical flame cap. Figure 10 shows a plot of the experimental values of the flame contact velocity, Uskirt, as a function of Zwa,,/7. Velocity 0 10 20 of Flame 30 40 Skirt 50 60 70 Fig. 10. Velocity at which contact point of flame skirt moves down the tube as function of characteristic velocity, Zwal,/~. Straight line slope 1.127. ON THE “TULIP The linearity of this plot shows that Eq. 7 is functionally correct and the numerical value of 6 is 1.13 * 0.02. Taylor and Richtmyer Instabilities That the physical origin of the tulip phenomenon is the flame deceleration is supported by an experiment due to Markstein [lo]. This showed that a flame shape inversion can result from the interaction of a curved flame front with a counter propagating planar shock wave. The specific case of the instability of a density interface subjected to a shock wave has been treated, in a different context, by Richtmyer [22]. After recalling the main results concerning the Taylor and Richtmyer instabilities, we construct a parallel between Markstein’s experiment and the tulip instability and establish a comparison of the orders of magnitude obtained in both cases. In a Taylor instability, two fluids of different density are submitted to an acceleration field (along the z axis> perpendicular to their interface. The position of the interface is written: a(x, 1) = a(t).cos(k.x), where a(t) is the timedependent amplitude and k the perturbation wavenumber of (a Fourier component of) a wrinkle on the interface. In the linear case, u(t1.k e 1, neglecting viscosity and surface tension effects, Taylor [ll] obtained the following oscillator equation for the amplitude: d*a(t) dt* = k.g(t). pp+; ;; .u(t), + (8) where g(t) is the z-component of the acceleration and p+,_ are the fluid densities on the +z and -z sides of the interface, respectively. For constant acceleration, Eq. 8 leads to oscillation or exponential growth according to the direction of the acceleration. The corresponding frequency or growth rate is given by ~0’= k.g. P+- P- p++ P- 233 FLAME” PHENOMENON . Richtmyer [22] has considered the case of an impulsive acceleration, that is to say w,,r,,, CK 1, where r,,, is the impulse duration. In this specific case Eq. 8 can be integrated give da - = k.V.u,. dt p+- P- p++ P- once to (9) ’ where V = /;=c g(thdt. If the acceleration is towards the lighter fluid (V.< p+ - p_ 1 < 01, then the amplitude of the wrinkle will pass through zero after a time Tin”: Tinv = ( (p+-P-) -k*V.(p++p_) -l (10) I If the shock intensity is reduced (i.e., I/ decreased), then the time, rinv, after which the flame curvature inverses, is increased. The Inversion Experiment Time in Markstein’s Shock Wave Markstein has observed the interaction of a curved flame front and a shock wave [lo]. Full experimental details are given in the original paper, but the following analysis is new. A stoichiometric butane/air mixture was ignited at one end of a 7.6-cm-square closed tube. The first stage of the propagation is the same as described above. However before the growing finger flame touched the burner walls, the flame was subjected to a shock wave propagating towards the burned gases. It can be seen from Markstein’s pictures that, a short time after the interaction, the flame front changes concavity in a way very similar to the tulip flame. For the stoichiometric butane flame, the inversion of the front (flat flame) occurs 0.16 ms after the passage of the shock wave. Equation 10 can be used to calculate the inversion time in Markstein’s shock wave experiment. The wavenumber, k, can be estimated by assuming that the curved front in the burner tube of width D, represents a period of a corrugation, k = 277/D. Markstein gives the velocity jump, I/, as -97.5 m/s and the ratio p-/p+ is the gas expansion ratio, E = 7.4, for this flame. These values give 7inv = 0.163 ms, which is very close to the measured value. We conclude that Ritchmyer’s model of the Taylor instability gives a good estimation of the flame front inversion time in Markstein’s shock wave experiment. Moreover, there is an apparent simi- 234 C. CLANET AND G. SEARBY larity of the shape and dynamics of the flame front between this experiment and the tulip inversion. The Inversion Time in the Tulip Flame Experiment The main difference between the shock wave and the tulip experiments is in the value of the product oO~acc,where ~0’ is the time governing the evolution of the tip and race is the duration of the acceleration. In the shock wave experiment ~~~~ is very small compared to w; ’. ‘In the case of the tulip flame, the flame is decelerated continuously by loss of flame surface area after the flame has touched the burner walls, so w,,~..,, = 1 and the preceding approximation cannot be used. This difference does not refute that both phenomena may have the same physical origin, but changes the ~order of magnitude of the inversion time. To calculate the tulip inversion time, the acceleration of the flame tip must be calculated. According to the geometric model, the velocity of the flame front is governed by the production of burned gases. After the skirt of the flame has touched the burner walls, the total area of the flame is given by: Equation 11 can be used along with Eqs. 1, 2, and the experimental relation 7 to calculate the velocity of the flame tip after contact with the burner wall: dZtip ‘tip = 7 7 -a- OCCLUS, Tin” = ttulip - ‘k> = $kr”g(t).dt twall: This average acceleration is substituted into Eq. 8. Since the acceleration is negative, the Tulip formation Zwall T2 SiOIl (11) - Z,kirt). S = 2~r(Z*i, This acceleration is time dependent and Eqs. 9 and 13 cannot be solved analytically. Equation 8 is integrated numerically using Eq. 13 for the acceleration and Zwa,, calculated from Eq. 5, using the experimental values for twa,, and &here- It is supposed that the curved front in the tube represents a period of wrinkling, and k is set equal to m/R. The time of inveris found by integrating Eq. 8 sion, ttulip - LII until the amplitude of the wrinkle changes sign. The results of this numerical calculation for ttulip are plotted in Fig. 11 as a function of the experimentally measured values of the tulip inversion time. The model gives the correct value of the phenomenon to within the 10% error bars. The inversion time can also be found more simply as follows: From Eq. 13 the aueruge acceleration (g) seen by the flame front during the interval, 7inv, is calculated between the time at which the flame touches the burner wall and the time the tulip inver- time (12) t, where T has the same meaning as before and 6 = 1.13 is the experimentally measured constant related to the contact velocity of the flame skirt. This equation can be solved explicitly for Ztip and then differentiated to obtain the acceleration of the flame tip, g(t): g(t) = = d2Ztip 7 -(a 0 0 - I)+exp !I.?.!! . i 7 1 -.‘-,.l.,.‘,..‘...i 0.02 0.04 t,u,,p (13) Fig. 11. Calculated values flame inversion occurs. 0.06 0.08 0.1 measured (s) of time ttulip at which tulip ON THE “TULIP 235 FLAME” PHENOMENON solution of Eq. 8 is oscillatory and the tulip inversion time is identified as one quarter of the oscillation period. This leads to an implicit equation for the inversion time: . (15) The values of the inversion time obtained by this approximate method are also plotted in Fig. 11. The values are very close to those obtained by direct numerical integration of Eq. 8. Thus, a simple geometrical model of flame propagation in a half-open tube is sufficient to explain the formation of the exponentially growing finger flame and also the curvature inversion leading to the formation of the tulip flame. This model neglects all viscous and compressible effects. Although acoustic waves generated by the unsteady flame propagation are visible in all but the longest tubes, this model gives the correct order of magnitude for the growth rate and inversion times, showing that acoustic and viscous effects do not drive the initial stages of the tulip flame formation. However, the depth of the tulip cusp is strongly decreased or enhanced according to the sign of the acoustic acceleration at the time of inversion, which in turn depends on the aspect ratio of the tube. In a recent numerical study, Dold and Joulin [23] have remarked that it is necessary and sufficient to include inertial effects to observe the tulip inversion. The model proposed here (Eq. 8) is second order in time, meaning that inertial effects are indeed included. However, of all the mechanisms participating in the Darrieus-Laundau instability [24] we have retained only acceleration effects since the Froude number is not small ((g ). S/ UL’= 1). This assumption reduces the Darrieus-Landau instability to the Taylor mechanism. The last part of this paper will show that the results obtained in the half-open tube can be transposed to experiments performed in closed vessels. COMPARISON WITH EXPERIMENTS CLOSED VESSELS IN This section compares the present results with those of Starke and Roth [13] obtained in the classical closed burner configuration. In their experiment, Starke & Roth used an acetylene/air mixture. The laminar burning velocities were taken from 1251. In these experiments the pressure and density change considerably. It is convenient to express the progression of the flame front in terms of the burned mass fraction, 7. Equation 1 can then be rewritten: (16) where V, is the volume of the closed combustion chamber. The unburned gas density is now a function of the burned mass fraction. In the particular case n K 1, Eq. 16 reduces to Eq. 1. Difficulties arise from the dependence of the thermodynamic properties on n. In order to make the calculation tractable some simplifying assumptions are made: the molecular weight of the products are equal to that of the reactants and the heat capacities cg, cu, do not depend on temperature and pressure during an adiabatic compression. Equation 16 can then be written in a nondimensional form: d?, - = [l + y.(E - l).n]“‘.r*.z, dt* (17) where t* = t.U,/R, Z = S/S,, y = cp/cu, r* = R/L. S, and L are the cross-section area and the length of the combustion chamber, respectively. The surface area of the flame front is evaluated using the same model as for the half-open tube, see Fig. 7. Using the same physical assumptions concerning the shape of the finger flame and neglecting the radial propagation velocity compared to the axial tip velocity, Eq. 17 becomes a first-order homogeneous equation for the burned mass fraction, 7: dv 1+ f i .[l + y.(E - l).?$‘y - (1 - 77) i = 2.dt* (18) 236 C. CLANET AND G. SEARBY Burned mass fraction / 1.0, I ! I d are physically correct. In the initial stage of propagation (77 < 11, the growth rate of the finger flame in a closed vessel is related to that of the open tube by a simple multiplicative constant. Comparison 0.0 0.2 0.4 0.6 0.8 Relative position of flame tip, i&I 1.0 L Fig. 12. Burned mass fraction as function of relative position of flame tip in closed vessel experiment. The solution of Eq. 18 gives the evolution of n with time. This model leads to a relation between the flame tip position and the burned gas fraction: =tip -= L ,,; i 1 (1 - 77) - [l + y.(E - 1).7#y * (19) This relation is plotted in Fig. 12 for E = 7 and y = 1.4. The essential result is that the burned mass fraction remains small, n I 0.2, while the flame tip position is in the first 60% of the combustion vessel, qip/L < 0.6. This allows Eq. 18 to be simplified in the limit 77-=K1, =tip r* + E.77 -=_ L L r* (E - 1) dv -v+a and = 2.E* i l+ where a = 3 E dt*, r* Starke and Roth used cylindrical burners, 5 cm in radius and with two different lengths, 38 and 76 cm. We calculate the magnitude of the correction term for the growth rate of the finger flame. In their experiment, E = 8 and 0.066 < r* < 0.132, so the correction given by Eq. 20 is between 2% and 4%. In the experiments of Starke and Roth, the tulip always appeared in the first 2/3 of the tube and we may compare their data to ours. Their gas velocity measurements are used to obtain the time of arrival of the flame tip at different positions in the vessel and thus deduce the growth rate of the finger flame. It is supposed that the time of arrival of the flame skirt at the burner wall, twa,,, coincides with the time of maximum gas velocity ahead of the flame. These values are summarized in Table 1. Figure 13 plots the growth rate of their finger flame as a function of the value calculated from the present model, Eqs. 4 and 20. The dependence is linear, but the experimental values are a little higher then the calculated values. The numerical simulation of Gonzales et al. [5] shows a growth rate of 1250 s-’ (their Fig. lb), whereas the growth rate calculated by our model is in their case 1095 SK’. Figure 14 plots the value of twa,,, deduced from their data, as function of R/U,. Here also, there is a linear dependence, with a slope of 0.22, not far from the value of 0.27 we found in the These relations 3E + r*.(E - 1). give the tra_jectory of the flame tip and yield the first order correction to the growth rate of the flame finger: These two growth rates are equal in the case of an infinite length tube (r* = 0) or for a non expanding gas mixture (E = 1). These limits with the Data of Starke and Roth TABLE 1 Experimental Data from Starke and Roth 1.0 0.67 0.63 0.50 8.5 7.2 6.9 5.9 130 70.6 61.3 33.6 5 5 5 5 76 38 38 38 590 260 203 89 8.0 18 18 33 ON THE “TULIP FLAME” PHENOMENON Growth ratea of finger flame 700 600 600 400 300 200 100 0 . 0 100 200 Calculated 300 growth 400 600 rate (a-c) Fig. 13. Experimental growth rate of finger flame deduced from Starke and Roth’s data as function of the growth rate given by the geometrical model. Straight line slope 1.26. Arrival 0.04 I 3 E 0.02 of flame , I - .. . . 1 0 0.05 / 0.1 anisotropic finger shape and accelerates. After the skirt of the finger flame touches the side walls, it takes a finite time for the tulip flame to appear. During this period the flame is continuously decelerated. Neither viscosity, nor acoustic effects are dominant in these stages of the development of the tulip phenomenon. It thus follows that, as long as the flame front thickness is small compare to the tube dimensions, the only relevant parameters are the laminar burning velocity U,, the tube radius R and the non dimensional gas expansion coefficient E. A geometrical model predicts the trajectory of the flame tip to be exponential in time during the anisotropic fin er ppFtiThe charB acteristic growth rate is - = L. * L ExperiR skirt at wall J 0 237 J 0.16 RW Cd Fig. 14. Time of arrival of flame skirt at burner wall, t,,,,, deduced from Starke and Roth’s data as a function of R/l&. Straight line through data slope 0.22. present experiments in half-open tubes. It was not possible to estimate the tulip inversion time from their published data. However these comparisons tend to prove that the observed phenomena are the same in the half-open tube and in the closed vessel. x CONCLUSION Tulip flame phenomenon in a half-open tube has been studied with a high speed camera. There are four stages of flame propagation: From ‘0 to ‘sphere the flame develops at a constant speed with a hemispherical shape. the flame has a very From ‘sphere to &vall mental measurements of &here and twa,, show that these times are constant when expressed in units of R/U,. The formation of the tulip flame is a manifestation of the Taylor instability driven by the deceleration of the flame tip. The inversion time for flame curvature, predicted by this mechanism, is in good agreement with the experimental results. The model has been tested and results compared with those of Starke and Roth obtained in the classical closed vessel configuration. There is reasonable agreement. Further work concerns the development of a theoretical model able to predict the experimental values for the times, &here and twa,,, at which the flame changes between regimes. The authors wish to thank Alain Pocheau for helpful discussions. 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