James D.E. Beaton 1. INTRODUCTION 2. ADVANTAGES OF
Transcription
James D.E. Beaton 1. INTRODUCTION 2. ADVANTAGES OF
James D.E. Beaton Consultant; Kelowna, B.C. VIW 329, Canada JOSe Espinosa Director;INPOFOS, Quito. 1. INTRODUCTION 2. ADVANTAGESOF FERTIGATION Fertigationis definedasthe additionof fertilizer plant nutrientsto croplandthroughirrigationwater,This method of fertilization hasbecomea well-establishedagronomic practice, Virtually all liquid fertilizers andmost solid fertlizers Application of fertilizers through an irrigation system resultsin many advantagesto growers.However,the advantagesobtainedwill dependon both the type of irrigation systemandthe fertilizer materialbeingapplied.Some of the recognizedbenefitsinclude: when dissolvedcanbe appliedvia irrigation systems.The quality of water,type of fertilizer usedandproceduresfor introducingfertilizer nutrientsmay, however,be different 1- Applied plant nutrients carried directly to the root zone. C ' for the various irrigation methods, 2- Thevariouskinds of irrigation wherefertigationis feasible include' . 3- Lower requirementsand input costsfor energy, labourand equipment. flood irrigation, with water flowing under the influenceof gravity asa sheetor in furrows, - overheadsprinklers(centrepivot, travellinggun and solid set)and - trickle/drip (drippers, emitters,microjets, "T" tape,etc.). th W d . fi .1. d. .b . ateran accompanymgertl Izer IStri utlon over e field is often unevenwith flood and furrow fertigation. In suchsystemsthefirst one-thirdof thewateris appliedwithout fertilizer the following one-third of the water serves as a carrier for the injected fertilizer and the remaining h' d . 1. d . on:ement and rapid method of supplying plant nutrIents. - one-t Ir IS app Ie WIt h out fi ertl ' I Izer. ' S pnn ' kl er Irrigation .. , 4- Greaterflexibility in choiceof time andrateof fertilizer application in accordancewith crop demand,especiallyfor N. 5- Preciseapplication/distributionof nutrients is usually possible. 6- Red~cedleachinglo~sesandim~ro~edfertilizer efficiency through tImely applicationsof mobile nutrientssuch asN, particularly on coarse textured soils ' is commonly used for providing andsuited nutrients large areas while trickle/drip systemswater are better for to smaller areas'involving more frequent and precise application of . 7- Less mechanIcal damage from traffic on established crops and compaction of susceptiblesoils. water and nutrients such as N, 8- Combined application with crop protection chemicals. The objectivesof this paper are to (a) report advantagesand disadvantagesof fertigation, (b) identify fertilizer materials,both liquid and solid, that are commonly used in fertigation, (c) indicate the effectiveness of fertigation and (d) review the generaluse of liquid fertilizers. I 9- Improvedcropproductionbecauseof timely fertilizer additionsandsimplifiedculturalpractices, The financial supportof TessenderloKerley Inc., Phoenix,Arizona in making possiblethis contribution is greatefully acknowledged, X Congreso Naciona/Agron6mico/ II Congreso deSue/os1996 129 Fertigation and the use of... - 3. DISADVANTAGESOF FERTIGATION Potential disadvantages of fertigation that should be evaluated are: .. 1- FertilIzer nutrient distribution ISdependent upon water distribution and will be uneven when fields are not irrigated uniformly. For example, poor system design and plugged lines, nozzles and emitters, etc. will result in irregular distribution. 2- Precise nutrient application rates are not always obtained with the water application system bein~ used: The greatest dif~culties in metering and uniformity of plant nutrIent dosages are generally associated with flood and furrow irrigation. . .. . 3- FertilIzer nutrIents can be lost m runoff water from irrigated areas. 4- . . Tlmmg . . of fertilIzer . . additions . can be disrupted 4. FERTILIZER MATERIALS FOR FERTIGATION Most commercial solid and liquid fertilizer products are suitable for fertigation. A list of criteria to consider in the choice of a fertilizer nutrient source follows. 1- State of the nutrient source, whether it is in solid or liquid form, will determine ease of handling and injection. as well as its storage requirements. 2- Injection method and quantity of material to be applied. 3- Type of irrigation system including its uniformity, application efficiency and distribution method. 4- Product stability and compatability source. 5- Effect on soil, particularly if being applied drip irrigation to a restricted soil zone. with water by trickle/ by weather factors such as unexpected excessive precipitation or strong winds in the caseofsprinkler irrigation. 6- Cost of the fertilizer source. Liquid fertilizers, both solutions (clear liquids) and sus- 5- Investment in injection and ancillary equipment, especially that required to prevent backpressure or backsiphonage into potable water sourceswill likely be necessary. pensions, offer several noteworthy advantages over solid materials including: 1- Manufactured products are ready for use upon delivery by the supplier. 6- Upgrading of management skills.sinc~ pers~nnel must fully understand the calIbration of mjection equipment and the operation of the injector, irrigation system, check valves and backflow prevention equipment. 2- Especially suited for application through trickle/drip or sprinkler irrigation systems. .. . . 3- Excellent carriers of both mlcronutnents and herblcides. 7- Anhydrous or aqua ammonia applied in surface or sprinkler applied water are subject to volatilization losses. Nitrogen Fertilizers: 8- Effectiveness of ammonium containing sources added to the surface of calcareous soils may also be reduced by volatilization ofN. 9- Corrosion of irrigation system components by some fertilizer sources. IO-Stratification or localized concentration near emitters of immobile nutrients such as P,. K and some micronutrients. II-Precipitation and resultant clogging problems may occur when some fertilizer sources (e.g. ammonium polyphosphate-containing liquids) are injected into irrigation waters high in Ca2+, Mg2+and HCO). Table 1 lists the principal fertilizer solutions containing solely N that are available for fertigation . Details on the composition and physical properties of these N solutions are also provided in this table. Urea-ammonium nitrate solutions (28 to 32 % N) are among the most popular liquid sources of N for fertigation purposes. They are usually manufactured commercially but they can be homemade based on the composition information given in Table I. It should be noted that some solid N fertilizers may be treated with inert conditioning agents which can cause clogging problems when used in the preparation ofN solutions for tickle/drip irrigation systems. . . . ApplIcation of anhydrous ammonia or other fertitizer products containing free NH to irrigation waters high in Ca2+,Mg2+and HCO - m;iy result in the precipitation of calcite and/or magne1ite.These precipitates may cause scaling and plugging problems in irrigation equipment including gated pipe, siphon tubes, emitters, etc. Addition of acid can prevent or correct these problems. None of these potential difficulties have seriously restricted the expanding acceptance and usageoffertigation. New developments in irrigation technology combined with irrigation and fertilizer management have lead to improved water and fertilizer use efficiency and consequently attractive economics of this practice. 130 X CongresoNaciona/Agronomico /11 Congresode Sue/os1996 James Beaton Table I. Composition and physical properties ofN solutions Non-ammoniated Solutions AN-20 -Total N" Nil, % NII,NO, % Urea % Water % NltraleN% A",mollla N % U,eaN% Spec. grav. @ 60°f lhl./gal II 60"f UREA-20 UAN 20 20 281 301 32 39.5 30.5 30 7 7 14 1.28 10.66 2.98 42.2 32.7 25.1 7.4 7.4 15.2 1.3 10.83 443 35.4 203 7.8 7.8 164 1.33 11.06 3.25 3.54 57.2 43.5 56.5 42.8 10 10 20 1.12 9.33 1.26 10.5 lbl.N/gal. 0 60"f 2.1 1.87 Vapor pressure I A 100 " f psgw Alnmonlated Solutions (typically noll-prelsure) Crystallization temp., "f 41 I 52 lIS I Aqua Amlnon'a Solutions UAN-30 UAN-32 I I 32' 37 16.6 668 41 22.2 65 20 24.4 20.62 25 12.8 11.4 29.6 75.6 75 ]() 20.6 1.19 9.91 37 15.8 58.5 7.7 18 10.2 23.2 3.6 1.17 9.75 1.14 9.5 0.912 7.6 0.911 7.59 367 3.61 3.9 1.52 1.52 1 2 10 1 2 56 28 2\ -58 -103 166 11.7 25.3 'Used In colderdil"a'el whe,e lal'I"9 ",ay occur. 'Ge"elally lold al 20'lbN solutio" II"ce 10lneammonia1011 InayoccurhI ha,,(111"9 Source: California Fertilizer Association (1995) . The group ofurea-tr1azone slow release N solu- tions (TRISERTR, FORMOLENE-PLUSR, N-SURER and FORM-U-SOLTM containing at least 25 % total N, could be potentially useful in fertigation for controlling rates ofN supply to crops and/or reducing N leaching losses. Th b I. ere are severa d S Th h N 1mpo ( ) rt t an I t. so u - th t 10ns th O a I I supp h t --- '" ~ ~ try and it is ideally suited for application through all types of irrigation systems and (b) ammonium polysulphide or APS (20-0-0-45S) usually added to ~r~pla?ds by way of flood or high-volume sprinkler 1mgatlonsystems. r , polyphosphate solutions . . fert111zer tended . w1th products a sample of the . . 1mga- .. ... tlon water m the same proport10ns as will occur m the system. Orthophosphoric acid has a furthur benefit of keeping the pH of the fertigation solution low enough to minimize the formation of precipitates ofdicalcium or dimagnesium phosphate. Thr ee soI1 ' d P sources,monoammoruum . phosphate At one time, ammonium bisulphite (8.5-0-0-17S) (10 to 11 % Nand 48 to 55 % PO) diammonium phos- was a significant low analysis liquid fertilizer source ofN and S in localized areas close to its point of production. phate (18-46-0) and ammoniftni phosphate sulphate (16-20-0) can be dissolved and used to provide P for fertigation. Attention should be given to the selection C ... and ammonium d 11-37-0) an. It should be noted that precipitation of P compounds can occur when ammonium polyphosphate-containing liquids are introduced into high Ca or Mg water (> 300 ppm). Consequently, a precipitation test should be conducted beforehand by mixing the in- y ot an . ey are a ammoruum 10SUp a e or ATS (12 0 0 26S) h . h . th t I d W 1C 1S e mos popu ar an versatile S-containing product in the fluid fertilizer indus- ," ", c ;:;;~:: if~~ " ",;:";~ % PO) (10-j4-b B tw . t I 41 d 44 b . ht f e een approx1ma e y an y we1g 0 I' d . I h b d. I d d so 1 ammoruum su p ate can e 1SS0ve to pro uce fertilizer solutions containing about 9 % N and 10 % S. . (17 0 0 7 7 t 8 8C ) C aIcrum . ru.trat e soIut 10n - - -. o. a, a . m1xture popular .' of calc rum rutrate . m some areas for ... and ammoruum . . fert1gatlon rutrate, 1S purposes. Phosphorus Fertilizers: .1 bl I . .d Th . . II e mam commerC1a y ava1a e 1qU1 sources d ti ti ct . t . rth h h . .d f P u t 1.I 1ze ' or e 19a 10n are 0 op osp or1c ac1 ( h t d 52 t 54 0/c P 0 ) . h merc an -gra e 0 ;to , ammoruum p osht I t ' (8 24 0) I n2 5 h ' .d (68 t 70 p a e so u 10n - - , po yp osp or1CaC1 0 0 Rand TM of materials free of conditioners I . . d. that impair this requi- site 1SS0utlon. Concentrated or triple superphosphateis not normally a satisfactory P source for fertigation becauseof . d d. I . ti . . its ten ency upon 1SS0 utlon to orm a prec1p1tate 0 f h h h . d. I . 1ca crum I . . p osp ate w . kl Id . I 1Ch can II . I ea d to d pro bl ems . 0f c oggmg m trIC e rIp atera mes an emItters. It is generally agreed that movement of P from fertilizer applied to the soil surface at normal rates is small. .., It 1S mterestmg, ., however, .'. that the concentrated . P solutions appl1ed through tr1ckle 1mgatlon systems . may move as much as 20 cm hor1zontally and 30 cm , vert1ca IIy from t he em1tter . dr1p . pomt, , Trade marks of Tessenderlo Kerley Inc. X CongresoNacional Agronomico / II Congresode SuelosJ996 J3J Fertigation and the use oj... Potassium Fertilizers: . .. Solid potassiummagnesiumsulphateis the most widely usedMg additive in suspensions. The commonly usedSOlIdpotashfertIlIzer salts, potassiumchloride andpotassiumnitrate, arevery water soluble and thus are readily used as K sourcesin Micronutrient Fertilizers: fertigation. Potassiumsulphateis lesssolubleandheating may be requiredfor adequatedissolution. Potassiummay alsobe providedin variouswater soluble solid NPK sources. The variousinorganicsourcesof the micronutrientsB. Cu. Fe, Mn, Zn and Mo are compiledin Table 2. The heavymetalcationsCu. Fe, Mn andZn arealso suppliedin the form of syntheticchelatesand natural organic complexes. Mono and dipotassiumphosphatesolid fertilizers,if they couldbemanufacturedeconomically,would be attractive sourcesof both K and P for fertigation purposes.. It is recommendedthat fertigation of Cu. Fe,Mn and Zn be carried out with trickle/drip irrigation systerns.Chelatesand sulphatesaltsareeffective sources for this purpose. Potassiumthiosulphate(KTS) solution with an analysisof 0-0-25-17Sis compatiblewith most liquid fertilizers and is well suited for trickle/drip irrigation and for foliar application. Potassium polysulphide (KPS) containing22 % K20 and23 % S is anotherrelatively new liquid K sourcewhich hashadlimited usein fertigation. . t and Although C1 IS . an essen t Ia . I pIant nutr Ien . Favo.urab.'e ~esults.,,:ith foliarly appliedNZNTM mtrogen-zmclIqUIdfertIlIzer (15-0-0-5Zn)havebeen recorded and it will likely perform satisfactorily in fertigation applications. Table 2. Inorganic sourcesof micronutrients - high concentrations are beneficial for some crops, C 1free K fertilizer materials a~epreferred for fruit crops and strawberries which are sensitive to this nutrient. Sulphur Fertilizers: . . The prmclpal . sources of plant nutrIent S are multi-nutrient products which are noted in each of the sections on N P 9 M g and micronutrients Although . . , . APS is an excellentsourceof Plant nutrient Sits Pri- Malerl.1 sou",e. of boron Granular boraK- Na,B.O,oIOH,O Sodium lelraboral.. anh!"!rous - Na,B,O, Soluborf1)- Na,B.O,,04H,O Ammonium penlaboral. - NH,B,O.04H,O Sou",.. - Cu50.-5tl,O Cuprouschloride- Cu,CI, Cupric Chlorld.)CuCI, ment. ATS also has favourablesoil amendment Source. of Iron P ro p erties , - F.rrous sulfate Forrous sulfate F.rrlc sulfal. Calcium Fertilizers: - F.SO,oH,O - F.,(SO,J,o9H,O - F.SO,o7H,O Ironoxalate - F..(C,°.J, - CalCIUm chloride (approximately 27 % Ca and 53 % C I) and calcium nitrate (referred to previously) pplication throu gh trickle/ are two materials capableof a F.rrous ammonium sulfate Fe(NH,J,(SO,J,06H,O - F.rriC chloride - FeCI, - MnSO,04H,O - Manganous 5ulfat. drip systemsandwhichwill likely be effectiveunder acId soIl conditIons. Manganous oxide- MnO . .. , MagnesIum , , FertIlIzers: C1), magnesium chloride solution (8 to 9 % Mg), mag(170 . cheIates(2 to , . neSIUm mtrate . - 145M g), synthetlc plexes(4 to 90;<M g) 4 % Mg) andnaturalorganic com , 0 aresatIsfactoryMg sourcesfor fertigationapplicationsNItrogen-magnesium 33 32 86 199 7 (,'\ 250 2" 888 798 6"2 I' I' 1.5 liquid fertilizer or NMGTM (14-0-0-4Mg) is another possible Mg source for 71 :12 31" 80 (,0 201 33 32 199 300 142 344 440 68 18 32 105 32 very'oluhl. 74 - Manganouschloride - MnCI, 246 478 720 43 7 00065 32 I' 77 63 32 397 56 32 543 4" 364 89 774 Sodiummol~al.-Na,MoO,oH,O Ammoniummolybdate- (NH,J.Mo,O"oIH,O Mol~lc SoU"'" oKId. - MoO, 66.0 01\ 77 r", 0 f zinc Zinc,ulfal.-ZnSO,oH,O ZlncoKld.-ZnO ZInc carbonat. - Znco, ZIncchloride- ZnCI, Zinc oxysulfale - Zno-ZnSO, 803 52.\ 480 53.8 I' 0.00\ 432 - 212 60 77 - ZIncammonium sulfat.ZnSO.o{NH,),so,06H,O ZIncnltrale-Zn(NO,J,06H,O \6.3 22.0 9.6 324 "'.-'-"""'"_."'" Source:California Fertilizer Association(1990). 132 77 "72 fertigation. TM :12 sourc.. of molybdenum phate or epsom salts(9.6 % Mg Magnesium sul and 13 % S), magnesium chloride (20 % M g and 74 % , 2.5 13 22 Sourc.. ofmangan... Manganous carbonate MnCO, Mangan...oKlde Mn,O, - 113 215 205 of copper Copper sulfate Cuprous oKlde - Cu,O CuprIc oKtd.- CuO mary uses are as a soil amendment and for water treat- , Elemenl Waler Solubllily 'F ($1 (g/1009 HPI Trademarkof Tessenderlo KerleyInc, X Congreso Naciona/Agronomico/ II Congreso deSue/os1996 32 68 James Beaton 5. FERTILIZER CONCENTRATIONIN IRRIGATION WATER 7. CROPSBEING FERTIGATED Fertigation, especially by trickle/drip systems, is usually confmed to high value crops including tree fruits, vegetables, small fruits and berries, flowers, horticultural and floricultural production in greenhouses and in nurseries. Although susceptibility to root burning from concentrated fertilizers varies with crops, ferblizer sources and irrigation practices, the concentration of a given fertilizer material in irrigation water should not exceed 5 %. It is generally agreed that fertilizer concentrations of I to 2 % at emitters is acceptable. 6. STARTING AND ENDING 8. EFFECTIVENESS OF FERTIGATION In addition to the many advantages that fertigation has on farm and water management generally, crop yields are FERTILIZER INJECTION alsoimprovedsignificantly.Onthebasisoffield trialscon- Th ducted in many parts of the world, this practice will raise I I. h Id b fill d fi t1 t5 . t e supp y mes s ou e I e or a eas mmu es . before startmg t. mue ... mjectlon. When mjectlon th th . . t. . runnIng e e Imga IS t Ion wa fi er 30 or completed . mmu con- t es . m or- der to (a) clear the system of fertilizer solution, Ib) provide . . Yields . at I fi tlona . ertl least 10 .1" Izatlon % met above h d 0 those s suc h obtamed as b an d. mg . with and conven- broadcast- mg. even distribution of applied nutrients and (c) avoid clogging of lines and emitters. -I= u.J 55 <..> 0:: u.J a.. 50 45 u.J 0:: <C 40 35 = ~ 30 Iu.J '"" 0:: <C ~'5 25 20 BAGGED , 0 5 '965 -IN 1970 C L U DES AN '975 H YD R 0 USA 1980 M M 0 N IA 1965 1990 5 Figure 1. Fertilizer use by class in the United States- 1965 to 1995 (Terry et al., 1996) IZ w 70 (.) [!: w 60 Co w DRY BULK 50 [!: < :I: 40 (/) ~ w 30 ~ [!: 20 < ~ 10 0 1965 1970 Figure 2. Multi-nutrient 1975 19BO 1985 1990 1995 fertilizer use by class in the United States-1965 to 1995 (Terry et al. , 1996) X CongresoNaciona/ Agronomico III Congresode Sue/osJ996 J33 Fertigation and the use of... Tickle/dripirrigationcanalsohavea majorimpacton improvingwateruseefficiencyby 30 % or more. 10. REFERENCES 9. LIQUID Beaton,J.D.,L.S.Murphy,E.H.HalsteadandJ.C.W.Keng.1992.Recent NORTH . United FERTILIZER DEMAND IN AMERICA S f ' tates 0 America: SaoPaulo. After a modest beginning in California in the early 1920's, the U.S. liquid fertilizer market grew slowly until the decadeof the 1950's when it expanded rapidly in the Midwest and Pacific Northwest. Plant nutrient . consumption of .. liquid . . fertilizers . Increased at the rate of seven % annually during the 1970's and early 1980's. This growth rate exceeded the 4% annual gain in total plant nutrient consumption which occurred during the .d In 1980 .' 17 % of the fertilizer . " consumed in the U.S. was m the form of liquid products. Fifteen years later in 1995, liquids ( including anhydrous ammonia) accounted for 40 % or 18.4 million metric tons of the 46 million tons of. fertilizer materials consumed . I). CaliforniaFertilizerAssociation.1990.WesternFertilizerHandbook. HorticultureEdition. InterstatePublishers,Inc., Danville, Illinois. California Fertilizer 8th Edition. Association. 1995. Western Fertilizer Handbook. Interstate Publishers, Inc., Danville, Illinois. Hauck,RolandD. 1984.Nitrogenin CropProduction. AmericanSociety of Agronomy, CropScience Societyof AmericaandSoilScience Society of America, Madison, Wisconsin. same perlo . . (Figure developments and trends in fertilization techniques with particular referenceto fluid fertilizers. XX Brazilian Meeting on Soil Fertility and Plant Nutrition. July 27, 1992.Piracicaba, Anhydrous ammonia represented 3.95 Korol, Mau.rice and Lynn Girard. 1996. Canadi~ fertilizer consu~ption, shipments and trade 1994/95. Agriculture and AgII-Food Canada, PolicyBranch.Onawa,Ontario. Randall,GylesW., K.L. Wells andJohnJ. Hanway.1985.Modern techniques in fertilizerapplication. p.521-560. In O.P.Engelstad et al.. (ad.). Fertilizer Technology and Use. Third Science Society of America, Madison, Wisconsin. edition. Soil million metric tons of this total liquid fertilizer usage. . . Multi-nutrient .. . . liquid fertIlizers . or those contam- ing either N-P-K, N-P, N-K and P-K, were first marketed in the U. S. about 40 years ago. Subsequently, I' .d fi rt'l' . tu h . d .d bl Iqui e Ilzer mix res ave game consI era e acceptance as revealed in Figure 2. Since the early 1980's they have had about a 20 % share of the total multi-nutrient market which was 16.7 16.0 17.1 and ll ' tr . t . 19901991' 1994' d 1995 16.9 m'I Ion me IC onsm , , an, respectively. They are also becoming popular in other parts of North America, particularly Canada. Tally, D.L., Paul Z. Yu and Henry S. Spencer. 1996. Commercial Fertilizers 1995. The Association of American Plant Food ControlOfficials.Lexington,Kentucky. Tisdale,S. L., W.L. NelsonandJ.D. Beaton.1985.Soil Fertilityand Fertilizers.Fourthedition.MacmillanPublishingCompany. NewYork,N.Y. Tisdale,S.L.,W.L.Nelson,J.D.BeatonandJohnL. Havlin.1993.Soil Fertility and Fertilizers. Fifth edition. Macmillan Publishing Company. NewYork,N.Y. Canada: van der Gulik, Ted W. 1987.B.C. Trickle IrrigationManual.B.C. Ministry of Agricultureand Fisheries,Abbotsford,British Columbia. According to the 1986 Censusof Agriculture, Canadian farmers used nearly 4 million metric tons offertilizer products. Of this total, 78 % was in solid forms, van der Gulik, Ted W. 1993.ChemigationGuidelinesfor British Columbia.B.C.Ministryof Agriculture,Fisheries andFood, Abbotsford, BritishColumbia. 13 % as pres~uriz~d liquids (anhyd!ous ~~onia and aqua ammonia), 8 Yoas non-pressurized liquids and 0.7 % in the form of suspensions. In 1995, nitrogen and ammonium polyphosphate solutions accounted for at Waterman,PeterF.I994.FertilizationGuidelinesinHighDensityApp and Apple Nurseriesin the Okanagan-Similkameen. B.C. Ministryof Agriculture, Fisheries andFood,Abbotsford, British Columbia. l~ast 6 %.ofthe total fertilizer cons~mption of 4.6 million metric tons. Anhydrous ammonia usageof 553,727 metric tons represented 12.1 % of total fertilizer usage in the same year. Wolf, B., J. FlemingandJ. Batchelor.1985.Fluid FertilizerManual. Volume I and2. NationalFertilizerSolutionsAssociation, Peoria,Illinois. The authors were unable to provide an estimate of the proportion of liquid fertilizers applied through fi 134 . . ertlgatlon . .th m el er country. Young, Ronald D., D.G. Westfall and Gary W. Colliver. 1985. Production,marketinganduseof phosphorus fertilizers.p. 323-376.172.0. P.~~gelstad.et al: (ad).Fert~lizer Technol~gy and Use. Third edition. Madison, Wisconsin. Soil X CongresoNacionalAgronomico / II Congresode Suelos1996 Science Society of America,